TW445286B - Radiation-polymerizable composition, film produced thereform and method for forming a coating on a substrate using the composition - Google Patents

Abstract

A radiation-polymerizable composition contains at least one radiation curable acrylate resin oligomer prepared by reacting an alkoxylated polyol with a first acid component which includes an ethylenically unsaturated carboxylic acid; and a rheology modifier prepared by reacting a diepoxide with a second acid component which includes an ethylenically unsaturated carboxylic acid or reactive derivative thereof in the presence of a polyamide based on a polymerized fatty acid. The ethylenically unsaturated carboxylic acids of the first and second acid components are preferably acrylic acid or methacrylic acids. The diepoxide is preferably a diglycidyl ether such as bisphenol A. Colorants such as pigments or dyes optionally may be incorporated into the composition to form a printing ink which is curable by ultraviolet (UV) or electron beam radiation.

Description

445 2 〇4 45286, printed by I Industrial and Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (f) 1 1 I1JSL Back m. Η I 1 Elaboration 1 1 The present invention is related to the radiation polymerizable composition t. Do not use As the way 1 Pioneer or Ink »which contains radiation curable acrylate resin oligomer reading 1 book, -3b η 1 component and it can be polymerized rheological improvement m component 〇 more special 1¾! Of 1 Invented the pseudo-m in the α-doped into this radiation polymerizable composition in the oil I I 1 ink 0 and then 1 fill out this 1 ink is usually made of colored substances &lt; such as dispersed or dissolved in the vehicle Page '· I [Composed of pigments or dyes 0 Ink may be called fluid or paste 1 1 It is separately on a kind of substrate 1 such as paper 9 plastic P metal or ceramic 1 1 and then dried 〇 1-? Τ According to the substrate or the method of applying the ink to which it is intended to be applied * May ^ j 1 classify the ink as 0 For example, 1—, you can pass the ink through the relief (for example, live 1 1 printing ♦ rubber m rotation printing), from the flat surface (offset printing)! I 1 white concave surface (groove engraving) or It is applied through the engraved template (silk mesh). [Application 〇 Different application methods and different substrates require different ink properties ι! 1 The substrate and the method of application Λ Printing inks are usually non-Newtonian if &gt; This means that the velocity of the 1 ft ink flow ABT body is not proportional to the applied stress ΰ therefore * some ink thixotropy is required) This pseudo s, refers to the viscosity of the ink decreases with the increase of 1S ι 1. Other inks are dilatant fluids »Where the increase of t agitation 1 m or m cut increases the viscosity and makes the oil Bnf ink flow less 0 J! I 3 1 1 1 1 This paper size applies to China National Standards (CNS) Λ4 specification (210 × 2 (Π)) &gt; 4452 8 6 ΙΓ Printed by the Consumers' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 51 V. Description of the invention () 1 1 Today Three main engineering technologies being applied (which resulted in a large amount of coatings 1 1 ί coating ink and adhesive α industry> is a solvent medium, water medium and zero 1 1 volatile organic compounds &lt; V oc) 〇 mainly form a thin film The process is to dry 1 (evaporate the solvent from the polymer solution) or cure (read 1 anti-nfic M from two or more components to form a thermosetting polymer). 0 From waste and pollution stand, although back] i 1 Water media The system is more environmentally friendly and acceptable1 But the solvent and the attention 1 I The two water-based systems are energy-intensive and require a drying oven to remove the solvent 1 1 or water. In recent years * Yes --- species The driving force of industrial technology to remove the solvent is to fill in this package and water 1 卽: Develop a zero zero V0C system. Energy curing is--a kind of industrial page 1 I technology 1 This technology is researched when there is such a big target in mind. 0% of the energy can be solidified. 1 In the system, the field is exposed to white visible light source or ultraviolet (UV) light source or 1 I When under the energy of the electron beam (EB) * Instantly transform the relevant fluid formulations 1 Order 1 into m cross-linked polymers. This technology eliminates less waste and requires very little m energy consumption. In many instances It greatly improves the production rate 1 1 and produces a variety of properties such as »high gloss and excellent abrasion resistance. Therefore, I can cure the amount of workmanship for many applications, such as wooden home! \ With floor tiles 9 Magazine cover 9 CD labeling and singing M set t high-gloss optical m-line I-dimensional 1 electronic sealing material and stereoscopic □ Χύ lithography Λ *-temple coating 〇UV or EB 1 1 curing can be via free radical 1 cation * Anion t or charge The process of waiting for 1 to achieve 0 1 I is important for inks and any other coating materials m is 1 adhesion 0 the ink is sufficiently adhered to porous materials such as paper or cloth because 1 | 1 to some extent * The ink m penetrates the m dimension of the substrate. However »Use a substrate without 1 | pores such as plastic m or metal. * Adhesion may be a problem. 0 1 1 4 1 1 1 1 This paper size applies the Chinese National Standard (CNS) standard. UIOXW7 male;) ΙΓ Seal of the Ministry of Economic Affairs, Central Standards and Leather Industry Bureau, Goods and Consumers Cooperative Association, Table V. Description of the invention () 1! Rheology improvement (R Η) additives are often used to control fluid flow 1 flat 1 1 Printing and screen printing and other oily soils. In printing presses * 1 1 C 1 V cured ink undergoes high shear, which reduces its viscosity and the ink loses. 1 The most suitable consistency must be used. Inorganic additives such as t silica are used to control viscosity, but <flTT · M machine additives exhibit problems. 9 For example, J reduces the gloss on the back of the finished product and increases the viscosity for a long time. Item 1 ftL Item 1 and then according to the present invention, a radiation polymerizable composition is provided. It includes filling in this article with a substantially uniform blend of items a) and b) below. Page 1 | a) at least one type of radiation The curable acrylate resin oligomer has a negative value of 1 1 obtained by reacting a gas-based polyhydric alcohol with the first acidic component including the first kind of ethylenic acid [and the first acidic component of a carboxylic acid and 1 Order 1 b) When subjected to radiation polymerization conditions »Rheology of copolymerization with radiation-curable acrylate resin oligomers (a) Modified oligomer, the rheological 1 I modified oligomer through a __L ring gas and a second acidic component including a second ethylenic! Unsaturated carboxylic acid or its reactive derivative y is obtained by reacting in the presence of I 1. polymamine derived from white polymerized fatty acids. Line I can be formed on the substrate 1 1 by using the aforementioned composition as a coating material in any manner by applying this The composition is placed on a substrate and the composition i is exposed to the polymerized radiation ττΟ Radiation such as I u V or electron beam radiation. 1 I toner such as j pigment or dye can be combined into the composition to produce a supply. Use 1 for inks used in live print printing, flat eye printing, etc. 〇1 1 • W · The rheology-improved oligomer component of the composition must be eliminated or reduced 1 | Inorganic additives and / or additives Thickener and becomes warp Shot polymerization of group I 1 5 1 1! 1 applies the present paper China National Standard Scale (CNS) Λ4 Specification (Ox 2 Shu River male Qiongzhuea 7) 445 286

The Central Bureau of Standards of the Ministry of Economics and Industry only prints and prints the cooperatives. V. Description of the invention (4) 1! The molecular structure of the finished product-m The whole part ο 1 1 The wording "radiation polymerizable" should be understood in this article, including Resin 1 1-like composition Μ m under radiant energy * In the resin-like composition, reactions such as polymerization and curing of 1 r are required. 0 Read [Random order-description back if; I of 1 The first picture is a picture The graph shows the hardness grades of several films derived from the composition of the radiation-polymerizable note-4. Re · 1 I of the present invention. ○ Item 1! Then the second _ 疋 __- chart shows: Bai Yizhaoben Invention r Radiation polymerizable Fill the solvent resistance (methyl ethyl ketone) of the film derived from the composition of this package. Page 1 I Figure 3 is a picture The table shows that according to the present invention, the film derived from the radiation polymerizable 1 1 m product is adhered to the substrate. 0 1 I Figure 4 shows-* The graph shows that according to the present invention, radiation polymerizable 1 The achievable adhesion enhancement of the product. Figure 5 is a graph showing the water-absorbability of the composition of the radiation polymerizable according to the present invention. 1 Figure 6 shows a graph showing In the present invention, the viscosity of the radiation polymerizable 1 composition VS the relationship between temperature and temperature. Line I Figure 7 is a chart showing that when compared with 1 1 ink containing no rheology-improving resin, i contains 眧 Μ "In the present invention, the rheology-improved resin oil 1 ink composition shear stress VS shear rate m 0 II Figure 8E Comparison of oxygen di 1 acrylate oligomers when compared with rheological 1 | modified oligomers prepared according to the present invention »Shear stress 1 of a certain i {± lm modified modified resin | VS cut speed僳 〇1 6 1 1 1 1 This paper size is applicable to National Standards (CNS) Λ4 ^ grid (210 x 297 and) 4452 8 6 R- Central Bureau of Standards, Ministry of Economic Affairs, separate labor and consumption cooperation. (R) 1! Figure 9 is a graph showing: When compared with high viscosity ring gas diacrylate 1 1 tb t according to the present invention »Viscosity of radiation polymerizable composition VS cut 1 1 速 关 惓 1 ί Please refer to Example 1 for details. Although the present invention is not applicable to printing inks, you should know: Read the back side 1] r 1 1 for any coating for printing or non-printing applications. Material (with or without color Note 11) are within the scope of the present invention. Unless otherwise stated. Matter 1 1 Percentage of reprinted material by weight 0 Remarks Except in the examples and fill in 1 Pack h This is not indicated otherwise 4 All quantities appearing below should be paged! 1 Known as the term " "Approximately" is limited. 0 1 1 The coating composition in this article includes — a radiation polymerizable vehicle 1 1 (which grants basic mechanical properties and acts as a binder) and at least J ~ — rheology 1 Modified (R M) resin 〇 Other ingredients 9 Optional include reaction diluent &gt; 1 Photoinitiator tm Wet agent flow and leveler »Adhesion promoter T Material 1 丨 and coloring substances such as t S Used in inks or coatings Any of the pigments 1 1 or dyes 0 1 are suitable for use in the present invention as a vehicle for the acrylic resin low-line I poly The substance can be obtained by using acrylic acid and diacids such as »adipic acid> azelaic acid 1 1 sebacic acid and dimer acid (available from E e Kei Company as EHP0L1008) Alcohols such as t Μ propoxylated glycerol 1 jt oxidized trimethylolpropanone acetylated-dihydroxy [methylpropane and / or isocyanuric acid tris, hydroxyethyl esters, and their advanced formulas Alkoxy 1 I-based derivatives can be synthesized. Others such as hexanoic acid 1 t * lauric acid 1 stearic acid can be used in the esterification reaction. Useful oligomers can have 1 1 7 I 1 1 1 paper怅 The scale is applicable to Chinese National Standard (CNS) A4 «L grid (2IOX2M)

\ V \ V Central Standards Bureau of the Ministry of Economic Affairs, only printed by consumer cooperatives 445286 V. Description of invention (b) Number average molecular weight ranging from 200 to 50,000, more preferably from 400 to 20,000, most preferably from 5 0 0 to 10, 0 00. The polymerizable carrier is preferably a UV-curable acrylate resin oligomer. Examples of suitable oligomers include: low-viscosity reactive diluent acrylate (e.g., available from PA State, Amber City, Ke Nkel, Ph H0T0MER 40 28), high-viscosity epoxy diacrylate resin (Such as PHOTOMER ® 3016 available from Henkel), fatty acid modified oxo diacrylate (PH 0 TOMER® 3072), acrylate polyester such as the following 0 Typical properties are listed in Table 1 below: ^ L Color Acid Value Viscosity Functionality Vehicle (Gardner) (mg KOH / g) (centipoise) (Theoretical) Molecular Weight Compound A 3 &lt; 20 2, 500-4,500 4 1, 300 Compound B 2 &lt; 20 200, 500-220,500 4 1,400 Compound C 3 &lt; 20 20, 500-30,500 6 1,300 Compound D 1 &lt; 20 400-700 4 800 Compound E 12 85-90 7,000 -10,000 2 1,000

Compound A, Compound B and Compound C are polyester acrylates based on modified fatty acids designed to have balanced hydrophobic and hydrophilic genes in the main chain. This allows it to be used in lithographic printing inks. In this case, this kind of balance is very important for the performance of the online printing machine. Compound D 8-This paper applies the Chinese National Standard (CNS) / \ 4 specifications (21〇). x2y7 公 部) ------------ t ------ Order ------. ^ (Please read the notes on the back before filling this page) Printed by the Bureau of Consumer Cooperatives 4452 86 1Γ 5. Description of the invention (7) Designed as a general purpose resin for use in transparent overprint coatings and as a modifier for other oligomers. The viscosity (each) of these oligomers is increased by about an order of magnitude, allowing a wide range of formulations by blending various resins and reactive diluents. Compound A is an exemplary member of the polyester composition produced by esterification of the following items (a) to (C): (a) Polycarboxylic acid (consisting of a diacid having more than 12 atomic atoms) And a reactive derivative thereof (for example, an alkyl ester thereof, in which the alkyl group has 1 to 4 master atoms), a selected polycarboxylic acid member in the group, (b) is ethylenically unsaturated A selected ethylenically unsaturated member of the group consisting of a monocarboxylic acid and a reactive derivative thereof (for example, an alkyl ester thereof in which the alkyl group has 1 to 4 carbon atoms), and c) An ethoxylated alkanetriol having each hydroxyl group and an ethoxylated group of ethoxylated alkanetriol species. Broadly speaking, these polyesters are prepared by forming a mixture of a polycarboxylic acid or a reactive derivative, an ethylenically unsaturated acid or its derivative, and a hydroxyethyl alkylated triol. Acid group: The equivalent ratio of hydroxyl groups should be pseudo-single, so that the reaction product is mainly composed of species that do not have free acid or hydroxyl functionality (or the low In the case of alkyl esters, there is no residual low sulfoalkyl ester functionality) c. In addition, it is preferable to use approximately 1: 2: 3 polycarboxylic acid: ethylenically unsaturated acid: ethyl gasification The ratio of the children to the triol. Therefore, the main product of the reaction should be "end-capped" with the ethoxylated alkanetriol at the end of the fluorene and the product of the ethoxylated alkanetriol. Garden Home Standard (CNS) A4 # L 格 (2I0X) -l · — I_. --------- 士 K -----— 丁 ------ί US. (Please read the precautions on the back before filling out this page)

V. Description of the invention (f) 1 1 Yupinyl sulfonium reacts with ethylenically unsaturated acids. However, this reaction produces 1! The compound will be a kind of composite mixture which contains higher oligomers and unreacted i [Reacted or partially reacted acid and ethyl chlorinated courtyard—7 alcohol 0 read 1 polycarboxylic acid t, especially its diacid should have -εΓ hydrophobicity of the same fatty acid read 1 quality 0 so 1 it It should contain polycarboxylic acid species with 12 to 90 sulfonium atoms. Back 1¾ f I 1 More preferably, it has from 18 to 54 carbon atoms. 0 Polycarboxylic acid radicals may be saturated. Note 1 1 or unsaturated and straight or branched鐽 〇 In addition to the two matters with more than 12 m atoms 1 1 Sun acid, it also typically contains species with S 1 to 6 p-carboxyl group (Fill in this book 1 more typical from 1 to 4. 値 carboxyl group ) It is also possible to use functional derivatives Page 1 1 instead of free acids &gt; e.g. * m-based halide 1 anhydride &gt; ester t salts etc. 0 1 typical at least 90 e Q% and most typically at least 92 eq% to 98 e & lt ί% 〇ί I A better diacid with a higher degree of radical bonding is described in Polymer Science and 1 Contractor U Technology Encyclopedia Vol. 11 t P. 476-489 (1988 4 New York 1 State I New York Jo h η W i 1 ey S ο η S company), the content of which is incorporated into this text for reference. 0 The preferred diacids include dimer acids (produced by polymerizing fatty acids f 1 such as oleic acid, which results in a Diacid (which is a divalent hydrocarbon with 36 primordial 1 I ions), tridecane diacid (produced by pseudo-decomposition of erucic acid) Line I 1 C 19 diacid (Through use-gasified sulfonate Hydrogenation of oleic acid produces 1 I) and C 21 diacid (produced by reaction of tall oil fatty acid with acrylic acid 1). The preferred diacid is a dimer acid. Dimer acid is also described in detail in US Patent No. 5, 138, 02 7 (Va η Be ek), which is incorporated into this article for reference. Q 1 I term "polymerized fatty acid" »Properties The above is intended to be an attribute and a pseudo acid 1 1 and a polymer acid obtained from a fatty acid, and the composition mainly includes dimerization 1 1 -1 0- 1 1 1 I This paper is suitable if] China National Standards (CMS) Λ4蚬 (Public Waste) Du Yin ¾ A452 B to V. Consumers' cooperation on work and work of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (9) Fatty acids with trimeric fatty acids and residual monomers which have less tritium. The term "fatty acid" refers to saturated, ethylenically unsaturated and acetylene unsaturated unsaturated, naturally occurring and synthetic monovalent aliphatic carboxylic acids containing from S to 24 carbon atoms. Although in this application, the polymerized fatty acids obtained from Cis fatty acid are not mentioned, it should be understood that the method of the present invention can also be applied in conjunction with other polymerized fatty acids. The preferred starting acids for preparing the polymeric fatty acids used in the present invention are oleic acid and linoleic acid because of their rapid availability and relatively easy polymerization. A mixture of oleic acid and linoleic acid is found in tall oil fatty acids, and it is a convenient commercial source of these acids. Fatty acids can be polymerized using a variety of well-known catalytic and non-catalytic polymerization methods. The typical composition of the polymerized tall oil fatty acid that can be used in the present invention as a starting material for the polymerization of the acid is: C18 —Meta acid (monomer) 0-15% c3e dibasic acid (monomer) When preparing a polymerized fatty acid with a weight of 60-95% C5 (or higher carbon) trimer or polyol at a weight of 0.2-35%, the best physical properties are obtained in the finished product. The preferred ones are: The starting polymerized fatty acid contains a dimer (C3Q two-day) acid as high as possible, for example, at least 90% by weight. In addition to the polymerized fatty acids, various other dicarboxylic acids or their anhydrides can be used in smaller equivalent quantities (eg, from 0 to 20 equivalent percentages of total diacid equivalents) to prepare reaction products, including aliphatic, cycloaliphatic, and Aromatic difluoric acid, representative of these acids (which may contain 2 to 22 carbon atoms) -11- This paper is applicable in the national standard (CNS) Λ4 specification (2 丨 〇297 and) ί --- ------- install ------ order ------ line (read the precautions on the back before filling this page) 4 452 86

A

B Printed by the Central Bureau of Standards, Ministry of Economic Affairs, and printed by the Industrial and Consumer Goods Cooperatives. 5. Description of the invention () 1 1 is oxalic acid 1 glutaric acid * malonic acid i adipic acid t octyl succinate-acid 1 1 sebacate Ϊ azelate Acid t pimelic acid »terephthalic acid t isophthalic acid 1 ten 1 1 dicarboxylic acid and m phthalic acid (methane) acid t naphthalenedicarboxylic acid and 1, 4 or 1, 3 -cyclohexyl 1 Carboxylic acid 〇m m The conjugator is an example of various anhydrides and j such as t read i phthalic anhydride * succinic anhydride maleic anhydride f pentyl-anhydride t octene backing and I-based succinic anhydride, decasulfenyl Succinic anhydride m m Anhydride 9 Tetrahydro o; i 1 1 Phthalic anhydride f • Hydrophthalic anhydride and methyltetrahydro o-phthalic anhydride — anhydride 0 Passing matter 1 1 Ethane triol organic compounds mainly Contains 3 hydroxyl groups in the molecule Examples of these include glycerol »dimethylolethane and trimethylolpropane. 1 The adduct of cyclohexidine and alkanediol is a well-known 1 I substance that can be prepared by microchemistry. The related methods to obtain the acetylation of alcohols are widely discussed in Polymer Science and Technology. Volume 1 vol. 6 t P. 225 to 273 (New York, New York, 1986 i City of Jo h η W i 1 ey &amp; S ons)) incorporated its content in this article 1 I for reference ο on an industrial scale 9 they typically pass between 1 20 το to 1 I 180t: temperature and In the presence of a basic catalyst at a pressure of 1 to 5 bar in the presence of a basic catalyst »Ethyl triol is gasified to produce a basic catalyst. For example, line 1 1 such as lithium hydride * potassium hydride» sodium methoxide> (Benzene) Phenol, or 1 1 Hydrogenated slider stone, which has been burned, 0, in acetylation Post »The product can be neutralized by adding acid (phosphoric acid, acetic acid, or pseudo-lactic acid) through 0 ii. In the case of the present invention, it has proven to be of special interest to use a flat average of 2.1 to 3.9 moles. Central Gas B and typical * average 2.5 Moore to 3.5 1 1 Moore 1 more typical 疋 average 2. δ to 3.2 Moore's Triol adduct 〇1 I trimethylol The propane 3 E 0 adduct is pseudo-preferred. This adduct has an average of 2.9 1 I -1 2-1 1 1 1 This paper size applies to the Chinese National Standard (CNS) Λ4 specification (2) OX297. Five 4452 8 6 Mingingane ethyl gas ring ear molybdenum residue residues ethoxylated ethyl alcohol containing 3 can reach the children of the tl species points the main substance combined this in each of the alcohol trioxane reason, triexane Another. The chemical base 1 is about 3 alkane, which is the main alcohol of chlorine, and the chemical base is chlorine, and the chemical base is hydrogen chloride. The less alkane, the basic type gas, as in the classic example, is the alcohol based cocoa alcohol trialkane, the basic type B is less than the pseudo-type basic type gas. The t-long W t 1 2W can be modified in Yu Shao-shao's style-the esters of the acid and the allyl alcohol are all three, the reason is that the sulfonium is divided into groups of 00 to All three things are naturally self-generating and are members of the reaction type. They are acid-forming and carboxylic acid-saturated and carboxylic acids are not selected from the carboxylic acid. As a result, __ 例 游 («halogen-based There are 醯 containing acids such as the above examples. The amount of acid when the carboxyl group and the alkenyl alkenyl-fluorene or alpha group are all acid groups. Allyl is a better example than the group-like phase or salt ester. Anhydride acid \ ί · 气 * ΐ! Π ο There is an acid with an allyl group and methane and its acid. Among them, for example, the ester of the alkyl group is better to be treated. Base 4 A to the first / | \ Ρ 合 中 聚 ▲ _ 百 Η 基 的 甲 程 α Ϊ UX® Science? Coprop ^ 0 Consolidated standard at 4 ', 23, 1-acid 21, etc. This volume. (Please read the precautions on the back before filling out this page.) The binding line city New York, New York, and New Year's sales company S η ο Central Standards Bureau of the Ministry of Economic Affairs Cooperatives print alcohol trioxane and acetic acid and acids. Carboxyl test is provided by the reference and the full text is not an alkenyl group, the acid is contained in the carboxyl group, which will be capped, and more The ambassador can calculate the MS number and calculate the sfii. It is a learner. On the basis of this research, it is based on the type code. Acid: π 1 Ϊ1-saturated 5 no: 0 1 1 ene is : Polymerization of acid type carboxylic acid,, tb This alcoholic alcohol trialkylated base gas is a type code. The paper size is applicable to Chinese National Standard (CNS) Λ) specifications (210x2y7-; M; i) &gt; 445 2 8 6 ΪΓ Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of invention ()! 1 0 .8 -1 .2 2, 7-3. 3, or even more typically 1: 0. 9-1.1, 1 1 2. 9-3, 1 〇 1 1 Various processes can be used to produce fatty acid-modified polyester propylene. 1 Acrylic acid In a typical one-step process, t will be roughly Each reading of a chemical calculation For example, 1 mole of diacid, 2 moles of acetylated backing 1¾ I of 1 alkanol and 4 moles of ethylenically unsaturated fluorene carboxylic acid), there is a kind of self-care i I by -Based polymerization inhibitors (eg, hydrogen awakening, cuprous oxide, etc.) _- species of esterification item 1 1 recatalyst (sulfuric acid, benzenesulfonic acid, etc.) and selective prevention of the coloration of the obtained product filled in this 1 In the presence of an additive (for example, triphenyl phosphite, page 1 1 etc.), it is heated in an organic, water-entrained solvent (eg, * benzene, 1 I toluene or the like). The reaction can be performed at atmospheric pressure, more typically under a reduced pressure &gt; typically at a temperature of 65 0 to 140 1 for a period of 2 to 1 and a period of 25 hours, more typically 12 to 18 hours. To remove the esterified water under the solvent i »Usually r This reaction is performed in the presence of gas 1 I to inhibit the polymerization of ethylenically unsaturated acids 0 This reaction is in the presence of a suitable 1 1 when the inhibitor It is carried out in the presence to prevent polymerization of the hydroxyalkyl acrylate double bond. Inhibitors such as t include monomethyl ether t benzene m of hydrogen stick, hope Hi hydrazine &gt; methyl line I hydrogen m »2, 5-di-* _ second-butyl alcohol and the institute Other well-known 1 1 ordinary free radical inhibitors, the content of the inhibitor used is typically less than ί 2000 PP m (for example &gt; 1 0 0 to 1 5 0 0 p P H1) 0-the desired ester is obtained At the 1 degree of Ionization (measured according to the amount of the esterified water collected or the acid value of the product), Rieter terminates the reaction. 1 1 After removing the solvent in a well-known manner »catalyst, excess inhibitor and 1 j excess olefin m unsaturated monophosphonic acid &gt; A product of the present invention is obtained, 1 ί 1-4-1 1 1 1 paper Standards are applicable to China National Standard Leather (CNS) M specifications (2Ι0χ 297 males); jv Λ45 2 8 .. A &quot; clearly stated that the five applications should be cm-1 each of which should be used to make the post-purification purely appropriate or &gt; ηι 1 Treat it properly. The way can be used to display the color spectrum of the sub-quantitative method. The color of the gel is transparent. The gel can be produced by the material. The material can be produced as expected. Feng Yi uses 0. This is based on the internal content of c. Fan Mingfa's version of this is also discussed in the pseudo-discussion-in the text. It is a good method and method. The main step is to base the basic phase on the gas phase B in the classics-the first implementation of the first example, in fact, the body of the orderly I ester. The method described in the above method is listed in the following two steps: the alcohol formula, the three alkanes, and the α-acetylacetic acid ethyl carboxylate, which is then fully saturated, without the ester enoic acid. Residual esters of alcohols based on triolane residues Carboxylic acid Carboxylic acid of monocarboxylic acids and residues of hydroxylated residues of alkenyl alcohols Will be the first to be the first *-Huayuan Ning seed hair from the same can be produced in the same phase as the material produced by the same method, according to the amount of antifangzi in the same type without the same type and atypical description can now be found Presented. The display of Chinese goods shows the spectrum of the classics produced by the top grade. The acidified material penetrated by the obtained ester is not only a trivalent or radical of the monoalkanoate and the same alcohol such as the trialkyl ester, but also the ester and the ethyl ester are the second kind of acid Single form of carboxylate and (please read the precautions on the back before filling in this page). Packing. Ordering 丨 The Ministry of Economic Affairs Central Standards Bureau β Industry Consumers Cooperative Co., Ltd. printed OH · rfi's ethics The material of the alkane is derived from the basic gas species B and so on: When compared with eil, it is better and unique 0 &gt; In the more existing ratio and the amount of si is less, it should be more acidified. The acid can wait-here the process is separated by a square acid. The two steps of the anti-step acid of the two or more carboxylic acids have been described very little earlier, and they are full, but not at t 1/1 ^ ZΓ instead of anhydride or lower M® &gt; 7 · — moderate P Circumstance 40 Low Yuji, 0 Shi Yikou and other examples to be mentioned. The paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (2ΙΟχΜ7). Alkenes or gas are suitable alternatives. 1 S March • 445286 Printed by the Central Standards Bureau of the Ministry of Economic Affairs for the Industrial and Consumer Cooperatives. 5. Description of the invention (a) In this case, it is advantageous. In the presence of an acid acceptor (such as pyridine, triethylamine, etc.) For esterification. In addition, the compounds described herein can also be obtained by transesterification of an ethoxylated alkanetriol with a low sulfoalkyl ester of an acid. In this case, the transesterification is performed pseudo-in a solvent with a sufficiently high boiling point (such as toluene or the like) to ensure that the reaction takes place at a sufficient rate at the boiling temperature of the mixture and that the transesterification takes place An azeotropic mixture is formed which contains no low sulfonyl alcohol. The rate of transesterification is monitored by measuring the amount of lower alcohol thus released (collecting it). The reaction can be performed at atmospheric pressure, but higher or lower pressures can be used. If the free acid form or the low-alkane form of the acid reactant is used, the by-products of the tritium reaction are each gas water or a lower alcohol. Removal of by-product water or lower alcohol will easily force the reaction to completion. Therefore, distilling this by-product is a concrete example of the method of the present invention. Compound E has the formula: ΟII r, -c.R5 where R s has the formula: CiOjOH-O-tCHjJs-CtOjO-l.-CHjCHj-OtOjC-CH ^ CH, C (0) 0H where a is from 2 to An integer of 20. Compound E is an exemplified member of such a polymer compound having the formula:

This paper size applies to China Gujia Standard (CNS) / \ 4 specifications (210χ: 2ΐ / 7. »牦)! Please read the precautions before filling in this page_ ί *-° Γ ί 4452 86 Α ·] Γ Male labor consumer cooperation with Central Standards Bureau of the Ministry of Economic Affairs, printed by Du. V. Invention Description (&lt; ^ H2 = CH (R1) -C (0) C &gt; -R2 ^ 0C (〇) -R ^ 〇C {0 ) ^ {M0 (0) C) rn &quot;: R4 x where: R 1 is hydrogen or methyl, R 2 is an alkyl group or a substituted alkylene group (typically having less than 6 sulfonium atoms) , More typically has 2 or 3 sulfonic atoms), R3 is an alkylene group or a substituted alkylene group (typically has less than 10 値 carbon atoms, more typically has from 4 to 6 sulfonic atoms) R4 is an aromatic atomic group (for example, having a functionality of η and u which is half of the total, M is η and Z is y is in which, the basic group, the generalized ester function of the free acid compound, aromatic polycarboxylate The residue of acid polyfluorene), the counter ion of hydrogen or a salt of a compound, π is an integer from 2 to 4 (typically 2 or 3), 2 and an integer from 1 to 5. Among the compounds within the range of the above formula (1) are those compounds, which are hydrogen, which is an ethylidene group, R3 is a pentyl group, and R4 is a benzenetetracarboxylic dianhydride or a dibenzoyltetracarboxylic dianhydride. One of residue and m 毎 is 2, Z is 1 and y is 2. The compound is preferably in the form. That is, where M is hydrogen, but it may be in the form of the salt, that is, M may be an alkali, alkaline earth or ammonium ion. In other words, this oligomer is made of a mixture of acrylate or methacrylic acid and a monohydroxy-functional polyester oligomer and polycarboxylic polyanhydride. 17- This paper size is applicable to the Chinese Standard (CNS) Λ4 specification ( 210X 297 public garbage) IL ---------- Install -------- Order ------- ^ (Read the precautions on the back before filling this page) 445286 1Γ Ministry of Economic Affairs Printed by the Bureau of Standards and Standards of the People's Republic of China. "Invention (1) 1 1 is prepared and then the two components of the f mixture are reacted in the presence of an m-catalyst 1 1-magent. 0 The product typically contains polym and carboxylic acid 1 i salt functionality while the ester and carboxylic acid salt functionality are substantially equal. In addition, the better than 1 is the acid anhydride hydroxyl functional propylene M 1 acid J 1 with a fcb ratio of approximately 1 1 fil 〇 Therefore »the main product of the reaction should be" open, and each acid anhydride produces 1 f of 1 to form di 81 (diacid However, the reaction product may typically be noted 1 1-a complex U compound f which contains residual hydroxy-functional acrylic matters 1 i and 1 esters r, fill in the formula used in the preparation of the acrylates of the present invention The polymer olefin m unsaturation Page 1 1 The compound may be C3E3 military or polymer form, and its content is m-dicarboxylic acid I ί An anhydride-reactive part such as »__. 痼 active hydrogen group &gt; For example, 9 hydroxyl 1 1 group, the cxtr early active hydrogen group should be a hydroxyl group. C3Q early 1 order unsaturated unsaturated reactive hydroxyl group of carboxylic anhydride reactive addition polymerization aa early formula 1 organic compound An example is 2-hydroxyethyl acrylate &gt; 4-hydroxyl acrylate 1 1 butanol t 4-hydroxybutyl methacrylate methacrylate 2-t 7T31 ethyl ester 1 1 2-hydroxypropyl acrylate Methacrylic acid 2-hydroxypropane m% isopentaerythritol tripropene 1 acrylate 9 N-hydroxymethyl propylene m amine 9 N-m TIL 1 単 ethylene glycol methacrylate t glycerol — methyl 1 1 acrylate t zr m methylpropane dimethacrylate acrylic acid or 1 1 methacrylic acid reaction product of polyglycol 0 1 I is preferred Olefin unsaturated compounds are lactone-denatured propylene 1 l acid or methacrylic acid esters (hereinafter referred to as "lactones") prepared by reacting an appropriate m with acrylic acid or methacrylic acid m. -Acrylate adduct 1 I thing ',) 0 1 1 &quot; 18- 1 1! 1 This paper size applies the Chinese National Standard (CNS) to the present standard (2 丨 0x29D &gt; ^). The compound in the ester is ο all the acid I allyl I ester. Prepared for use 于 = 0 C- ^ c (RH CH ( acj to It's own or Qi is 7 R to middle 4 Its SR and its base are the best esters of the ester-based internal alkane than the original C. The sun is the one and the remaining hydrogen is 6 less There is a super 12 g. However, there is no super number. There is a total radical containing the primary carbon. The base is not substituted. The β is better than the 40 ring. Residual and its basic esters, protons, internal sulphurs, etc. In each of them, the esters have ε, the ethane has been hydrogenated,-, ε R of ㈤ ii Generation ⑽ Extraction agent chemical and gas &gt; jCJ generation _ 0 The derivation of the corresponding acid phase is based on the fact that the base has been passed through the hydroxyl group-two 0 6 3 12 is the ester of the acid inside the Ming e hair seed preparation is prepared in the ester. Heji * 1-^ is suitable for the most popular custom of e `` Reverse extraction = via ester propylhexyl mono

'IT protons ^ ε, 2 by 1 S to 1 hexane 1 own group containing ε group. Esteryl alkanoyl ethyl is used as an example of ester hexanoate and ester hexanoyl propyl hexane S ^ (T-methyl alkane) two esters in its esters. Hexyl alkane. 丨 Central Ministry of Economic Affairs, Central Bureau of Standards, M Co., Ltd., printed carbon-based carbon Mia, which should not be used as a raw material. Make the same or not. Or take the same sibling as the original in sulfo. Take the original. The sulfo takes 3 double or 2 in the original carbocyclic ring. The ester will be 5 @ δ S 内 内 己 (. Ί ο 'Λ ε 佳The most important thing is the two non-esters, hexyl alkane: the thing is the anti-chopsticks, and the vinegar is the only one. The inner generation of each is 4. Z is the Chinese ester, which is the base of methyl or acid allyl. Acrylic acid and esters are prepared in the paper used in the paper. The standard of the Chinese National Standards (CNS) Λ4 (210X297) is printed by the staff of the Central Bureau of Standards of the Ministry of Economic Affairs. / 4452 8 6 A &quot; ΗΊ V. Invention Description ('ί) Propylene ether esters contain from 1 to 3 acrylaldehyde or alpha Instead of acryl and 2 or 2 hydroxyl groups, these esters are commercially available and / or can be quickly synthesized. Commercially available esters include hydroxyalkyl acrylate or hydroxyalkyl methacrylate Esters, in which the alkyl group contains from 2 to 10 carbon atoms, preferably from 2 to 6 sulfonic atoms. Acrylic and hydroxyalkyl methacrylates have the formula: CH 2 = -CR 1 -C (0) 0- R 2 -0Η where R1 is hydrogen or methyl and R2 is a straight or branched alkylene group having 2 to 10 値 carbon atoms, preferably from 2 to 6 値 carbon atoms. Suitable acrylic and methacrylic hydroxyl groups Examples of alkyl esters include 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, 3-hydroxypropyl acrylate, 2-hydroxybutyl acrylate, 4-hydroxybutyl acrylate, 3-hydroxypentyl acrylate, and 6- Hydroxynonyl ester, 2-hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate, 3-hydroxypropyl methacrylate, 2-hydroxybutyl methacrylate, 2-hydroxypentyl methacrylate, formazan 5-hydroxypentyl acrylate, 7-hydroxyheptyl methacrylate and 5-hydroxydecyl methacrylate. The comparative lactone / acrylate adduct has the formula: CH a = CR 1 -C (0 ) 0-R 2-(0-C (0) R 3) 2 _〇Η where R1, ϊ2, and R3 are all as described above. Lactone / acrylate adducts in the presence of a catalyst with less than about 200 PPII It is prepared by reacting lactone with hydroxyalkyl acrylate. Catalysts that can be used include one or more organometallic compounds and other metal compounds such as, for example, vaporized tin or iron and other Lewis (L e Wis) or protonic acids. The preferred catalysts include stannous octoate, dibutyl dilaurate-20-This paper size is applicable to the Chinese National Standard (CNS), six or four grids (210X21; 7mm and) —1--1 I ·-----1 II-V. J---1 HI I US. I (Please read the precautions on the back before filling out this page) 445286 Λ &quot; ίΓ Printed by the Consumers ’Co-operative Society of the Ministry of Economic Affairs, China

V. Description of the invention (19) 1 1 1 Based tin »and other tin compounds titanates such as t-isopropyl titanate and 1 1 m butyric acid etc. 0 1 1 The reaction% is between 10 ° C to 40 0¾ It should be carried out at a temperature of 12 °. 1 to 13 0 TC. The reaction can be carried out at atmospheric pressure, but only using a pressure higher or lower than reading 1. 0 Usually &gt; The reaction is in the presence of oxygen. In the following, JL ~ η 1¾-1 is performed to inhibit the polymerization of hydroxyethyl acrylate. This anti-n £ c β is usually carried out for 2 minutes! During the period of 1 to 20 hours, the reaction is performed in the presence of a suitable inhibitor 1] and then 1 | to prevent the polymerization of hydroxyethyl acrylate double bonds. These inhibitors include the monomethyl m »benzene m, benzene m, pankazine T methyl hydrogen m» 2, 5-di 1Γ-1 1 _ tertiary-butyl m &gt; hydrogen m &gt; Benzene and other well-known 1 1 ordinary free radical inhibitors in this technology. The content of the inhibitor used is less than 1000 ppm 1! &Gt; Should be less than 8 00 p P m » Should be less than 600p pm 〇 Molar ratio of t lactone m-based esters in esters 1 0.1 1 1 to 1 5 are typically used. 1 a 1: 0.3 to 1 · 3 0 ί I for use in A 1 1 1 example of a preferred lactone / acrylate adduct in the present invention is caprolactone_propionic acid 2-I] I provided by Union Sulfa Ethyl adduct 5 is commercially known as TONEM- 100, which has the following formula: LINE CH2 = = CH- C (0) 0- CH 2 ~ ch2- (0 -C (0)-CH 2) 5 ) 2 ^ 0H 1 1 react the polycarboxylic polyanhydride aromatic compound with the inner m / acrylic acid adduct 1 to introduce the ester and white from the carboxylate functionality into the compound. Therefore 1 I »R 1 is- -Aromatic aromatic radicals. Typically, R 4 may contain § 6 to 36 carbon atoms i more typically from 6 to 13 sulphur atoms. 0 R "typically-1 hydrocarbon 1 class I or heterocyclyl group 0 R 'preferably from phenyl , Substituted phenyl, phenyl II _ (a phenyl group having a--fluorenone substituent) &gt; and a substituted 1 1 -21-I 1 1 I This paper is again applicable to the Chinese national standard 隼«CNS) Λ4 condition (210X2W male): 445286

Printed by the Ministry of Economic Affairs Bureau of Standards and Loss Cooperatives. 5. Description of the Invention (&);-The benzoyl group (for example, benzophenone group) is selected from this group. In a preferred embodiment, R4 contains an aromatic ketone functionality, such as a benzophenone group or an acetophenone group. Appropriate polycarboxylic polyanhydride aromatic compounds preferably contain, on average, 2 to 4 tetradentate anhydride groups. Examples of suitable such compounds are pyromellitic dianhydride or benzophenonetetracarboxylic dianhydride. In order to react with polycarboxylic polyanhydride aromatic compounds, a mixture of lactone / acrylate adducts is used in an esterification catalyst (preferably a third amine, such as an aromatic amine) which catalyzes several children. For example, in the presence of dimethylaminopyridine or a trialkylamine such as triethylamine), it is typically heated to a temperature from 40T to 150T :, typically 801). The number of anhydride equivalents of the polycarboxylic acid polyanhydride aromatic compound, on an equivalent basis, is substantially equal to the hydroxyl equivalent of the lactone / acrylate adduct. In this way, a product is produced, which is mainly composed of fluorene molecules (wherein the ester and free carboxylate have the same functionality). The reaction is allowed to exotherm, and then it is typically heated, for example, to a temperature of ιοου to 14〇υ, more typically from 120t to 140C and maintained at a temperature of from 10 minutes to 2 hours, more typically from 20 minutes to 1 hour, until the theoretical value of The anhydride content is &lt; 0, 5 wt%. For example, as calculated from the acid value of the product measured or by a spectral analysis method (eg, Fourier transform infrared spectroscopy), the total reaction time is typically 30 minutes to 4 hours, more typically from about 1 to 2 hours. Thereafter, the product was cold-headed before storage. The reaction with the polycarboxylic acid polyanhydride aromatic compound is usually in the presence of a catalyst that can promote the formation of an ester, such as dimethylaminopyridine, at -22- This paper is applicable to China National Standard Leather (CNS) Λ4%格 （210XW 公 部） 1 I —. I Private ^, r Order.] 'Tie (Please read the notes on the back before filling out this page) 印 Printed by the Central Laboratories of the Ministry of Economic Affairs and the Goods and Consumers Cooperatives () I 1 is performed at moderate temperature. The reaction order is mostly unimportant »Maybe at the beginning of 1! F Add human hydroxy olefinic compound S in the middle of the procedure or as a reaction reaction. 1 All these changes in this item The technique is familiar to all of you. In this article, t 1 is used first.] Polycarboxylic polyanhydride aromatic compounds and materials that react with them are often used in stoichiometric quantities and the reaction is continued until the anhydride functionality is substantially unrecognizable. I detected «&gt; Use at reaction temperature: &lt; c. Note that the reactants of 1 liquid atst wax or osmium solvent solution should be appropriately and conveniently carried out. ○ Item 1 I \ I Generally * This reaction is performed in the presence of gas to suppress acrylate filling. % Polymerization of this product or methacrylate functionality. This reaction should be carried out in the presence of a Shida Page 1 1 inhibitor to prevent acrylate or methacrylate double bonds [1. Polymerization of these. Including the Army of hydrogen m * Benzene f phenoxazine 1 | Ϊ methyl hydrogen alcohol ♦ 2, 5-__ _ second butyl amine t hydrogen hydrazine 1 benzene m and other common items known in the ordering art The inhibitory content used by the white base inhibitor 〇 is less than 1000 PP m, preferably less than 800 PP IQ &gt; most preferably less than 1 1 60 Op P m 〇1 the compound should be% free acid form I 卽 where each-Μ is hydrogen, 1 \ but may say 疋 the salt form of the compound &gt; 卽 M may 疋 a base &gt; ti I alkaline earth or m ion. If necessary &gt; can be achieved using an appropriate base to And 1 1 compounds in free acid form-値 Η counter ions 0 1 1 The compounds of the present invention can be applied to a variety of substrates. For example, &gt; 1 I These substrates include porous materials such as paper and cardboard 1 wood and Wooden products 1 I »Metals such as aluminum &gt; Copper and m and plastics_ such as P VC, Polyester, Acrylic [| enoic acid% compounds, etc. 0 after adding a suitable photoinitiator i such as 1 i» PH0T0MBR51 Brand photoinitiator (, dimethyl diamine shrinking) will be chemical 1 1 -23- 1 I! 1 This paper is suitable for Sichuan, China, Yan Jiabiao (CNS), AW Brother (2 丨 0 ×) and 6 8 2 5 4 4 Explain that the 'Five Brush-Based Printed Laminates are coated with concave classics and the original rubber production plant , Will be painted on the 0 stick, the mass shot base spray as in the example of the selection method of each one to ΓΠ Q injection force application method combined formula _ This addition will add 0 to the solidification-lower fat shot tree The spokesman, the girl, the girl, the girl, or the girl, V ur is in the shape of the mix, and the paper is as it is, and the material is solid, and there are some bright hairs of this material. The tincture is optimized by gas, such as salt in the example application, or the base section of the garden. Tttt- difficult to swim, contains the body of gadolinium acetate, methylenediphenyl, p-steel aluminum, as compared with b U t ί Phase ester ramification is based on the formation of thin film polyester. The component display group is condensed to gather other materials, such as the compound of this tune, the compound of the compound, the compound of the Jing Jingfa, and the nA9 5i alone, which can be changed. Sub-release or dilute olefins should be vice versa and used for fullness without making them olefinic. There is a practical example of a mixed type, such as the example of a single-family aromatic compound that combines ft, Ί Λ \ I, and the three groups of groups. Ethyl, styrene, ethyl phenyl, ethyl phenyl, methyl α Digas, monophenyl-allyl allyl methyl,, nitrile allyl acrylic acid such as allyl cyano nitrile methyl, -ester ester acid vinyl acid propylene dipropanol, diester hexamethylene, ester olefin Ethyl propionate, ene (please read the notes on the back before filling out this page). Install 'ΐτ Line Ministry of Economic Affairs, Central Standards Bureau, Consumer and Cooperative Work, Du Printed Base, Ethyl Acetate, Ethyl Acetate Acetic acid esters and acetic acid esters * and acid esters such as monoesters, ethylenic esters, saturated nitriles and propylene esters, propionic acid, maleic acid fat-stearic acid-maleic acid horse oil, Polybutyrate and Butene Isobutyrate: Propyl methylene, Acetic acid Examples Dishanghe and esters are mono-acid kangshiyi wine-, iso-acid-like propyl limonene, methyl methanoate, benzene_hydropropane, and acid Dangkang xiangyi. The paper size of this paper applies Chinese national standards. (CNS) Λ4 specification () 4452 86 The work of the Central Standards Bureau of the Ministry of Economic Affairs, the consumer cooperation, and the printing of di-based diacid ether propyl ester can release two to its reverse 1. The phase of hydroxy is more important, it has 1 urine sgK ^ 8 or above? A-ics &amp; 30 esters have azinepinene diene moieties 31 acid compounds per 613 ^ type body to mono-ma-tri, acetic acid diene Uene yields: M ε A single ¾ acid, as cool as the ester-to-bacteria acid transpropyl. _Propyl alcohol ^ alcohol 1 ¥? Column, Μ® is more than the sex of the chemical properties of the chemical compounds I and III, which are rich in ethylene, ether, and benzene. ^ The amount should be the same as that in the main alkane 10, and the neighbourhoods such as 10 and the diacid group are reversely added to 3, about 5 literary theories in the acid and acid isopropyl bromide. \ — Calculate it These big 13 groups come in the form of rich or alkenyl quaternary and f, or or -f because of 2, and the body code j.LCT ^ D Ji- Mama-diene, cultural relics Good acid P. Combining 38 substances,; -Nitrile straight acid ethyl ester with ethylene 5 «carbenete ifci margin 4, the use of polymerization such as diurethane, ethylene dipropylene and polygas 2 and C … Residual process should be able to make the ester base gas, phenolene ring to the base of the case and so on, and so on, such as the di-ester of the auryl and C0 chemical compounds Fantastic ¾ ijTO radicals are like the examples of benzoic acid polyalmo, or Jiajiji. The amount of Dinghua is rich in examples of inter-dipropoxy molybdenum β \ \ \ 〇 qi country. Heavier)- Eye-of-ether ether, phenylyne. 3 compound and 211 ethylene-ethyl mecoryl body change 50 ^ group and amine polysheng-ether 郯 bromide to 0 adduct ΚΪ are all in the presence of mono-ubiquitin (Ethylamine, co-derivative, and other basic chlorine insoluble ¥ 1 of the raw Er 52, showing that the species contains Guang Shaoming, the di-cocoate malonate can be even sg) Yes, it is said that it is basically based on urinary propylene, alkenes or flatness. Including the standard system or the best thing, the propionate of melamine and methylenediene diester is Ϊ2 *. 2 can be based on the number of hairs such as esters of the three-based-flux alcohol 2 react to the fluorene-based group of a pair of five τ ^ ii ii (please read the precautions before filling in On this page 3 This paper standard is applicable to China National Standards Corporation (CNS) ΛΟ see grid (2 丨 0 &gt; &lt; 297 public 玷) [β 4 4 5 2 8 6 A ΪΓ Printed by the cooperative V. Description of the invention (&gt; 4-) IIS% and more typically in the range of 15% to 25% by weight 〇 The novel derivative of the present invention can be cured or alone or with other 単Polymer or ί! The polymer blend is converted to m and becomes infusible «that is, via acr early alone, please be exposed to the radiation or in the presence of a catalyst that generates radicals, such as i» benzoin ether 1 Ch 1 er ring. The free radical inhibitors are typically pseudo-based on the backside i I 1 radiation-curable component from 0.01 by weight. % To 20% and there are 0 i ideas i Examples of radiation used include ultraviolet light and call m Frtt radiation such as via X Xia term and 1 I light machine electron accelerator such as va η de Graaf machine t Wave-type accelerators »especially the type 1 natural and synthetic radioactive materials such as cobalt 60 and the like described in page 1 I of US Patent Nos. 2, 7 3 6 and 6 0. This guarantees that the composition is not premature. Polymerization f __- white base inhibitor 1 1 can be added to the polymerizable composition. Examples of suitable inhibitors include hydrogen 1 and its methyl ether or butylated hydroxy toluene. Pseudo-polymerizable 1-component by weight from 5 p P m to 2 0 0 0 pp ΪΠ 〇 Various additives can also be used 1 1 _ »For extending the week of the composition» It is particularly useful »For example, purple 1 outside Light stabilizers such as P 1 〇rs from Kr. tab ϋ V -I 1〇1 1 The composition of the present invention is used in the preparation of molded »m cast 9 laminates and 'ice I coated products as an adhesive 1 impregnants and protective coatings 0 others ί f can be used alone or in combination with the following materials: Filler 1 dyes and pigments! Sunscreen 1 Lubricant t Plasticizer &gt; Tian Yao or synthetic resin or other 1 I modified jrttfr m Ο Ί in According to the invention • In the method of coating a seed substrate ♦ A composition containing 1 1 with a photoinitiator is optionally applied to the surface of the substrate t followed by 1 I exposure to a radiation source * until the adherent is dried »polymerized The film is formed on the base 1 i -26- 1 i 1 i This paper size is applicable to China® Home Standard (C'NS) / \ 4 圯 Grid (210X 297-> &gt; ^) 'β 445 2 8 6 A' R ~ Printed by the Consumers' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (χΓ) 1 1 The mass of radiation energy suitable for initiating curing formulations has been extensively described. 1 1 In the literature §. It is well known to those skilled in the art. These include ί [usually less than 700 millimeters of produced particles and non-particles. The wavelength of the radiation please 1 first 1 various sources 0 to be useful is the actinic radiation in the range of 180 to 440 PP m reading 1 radiation t which can be passed through a number of commercial purposes which are particularly intended for this huge use 1 of! One of the UV light sources supplied — and convenient to get 0. These include low T, medium and high Ji. Italian [I m mercury vapor lamps> He-Cd and A, laser, xenon arc lamps, etc. Generally, the photoinitiator with the corresponding sensitivity to the item 1 I and then 1 in the light in this band% m is filled in this 1 in a human preparation and when it is irradiated 9 results in the formation of g can be initiated to polymerize Page 1 I is a reactive species similarly. The polymerization of white radicals can be induced by exposure to the electron beam without the use of a photoinitiator. It can produce a region between 150 1 I and 300 K eV. The equipment of the electronic screen of energy is particularly suitable for this giant and its [ordered use is fully contained in the literature 〇1 Jiajia's radiation source emits electromagnetic radiation mainly in the ultraviolet light wave 〇1 j When using this source &gt; polymerizable The composition should contain a photoinitiator that is susceptible to UV radiation 1 I, such as benzoin ♦ benzoin mta »c 1-dimethyl 1 (air-CX-phenylacetophenone diethyl gas Phenethyl mia -Hydroxy-α 9 Line 1 a-Dimethylphenethyl 1 -Benzamidine cyclohexanol and photoinitiator based on aryl halogenated oxygen 1 &gt; For example, white B AS F company Available 1 1 LUCERIN Ding μ τρο) 〇! M ran * The amount of radiation necessary to cure the composition will be based on the angle of exposure to radiation 1 &gt; The thickness of the coating to be applied m The polymerizable A in the coating composition α 1 1 The number t of the garden and the presence or absence of the white-based catalyst ο 1 I Determination of any specified composition after exposure to the radiation source y 1 1 -27-1 1 1 1 Size of this paper Applicable to Chinese garden standards (CNS) Λ4 ^ grid (21〇κ2π &gt; &gt; ^) Printed by Shiyang Standard Bureau of the Ministry of Economic Affairs, printed only by consumer cooperatives 4452 8 6 Λ 1Γ 5. Description of the invention (A) Uncured radiation Experiments on the number of sensitive 7T bonds are the best way to determine the required radiation and hold time. Typically, an ultraviolet light source ('e.g., a filtered mercury arc lamp) with a wavelength between 200 and 4OnnSi is directed onto a coated surface that is misplaced on a conveyor strip, which provides The passing rate passes through an ultraviolet light source suitable for the radiation absorption distribution of the composition (this distribution is affected by the degree of curing required, the thickness of the coating to be cured, and the polymerization yield of the composition). Compound D can be synthesized by using adipic acid and acrylated glycerol propoxylate in the presence of 4-methoxyphenol, PTS A, and hypophosphorous acid and has the formula: (CHi &gt; t- [C ( 0) 〇-CH {CH3) -CHJ-0-CHrCH (0CHlCH (CHj) -0 (0) CH = CH1jCHi (0CH, CHiCH3})-Compound B can be passed at 98-1021C, preferably in a solvent such as toluene Or hexane) in the presence of a catalyst [for example, p-toluenesulfonic acid (PTSA)], which is prepared by reacting trihydroxyethyl urate with acrylic acid and a dimer acid. Compound B has The following formula:

Compound C can be obtained by combining di-, trimethylolpropane with acrylic acid and dimer at 98-102X, preferably in a solvent (such as toluene or cyclohexane) and in the presence of a catalyst (such as PTSA). The acid reacts to the standard of this paper. Applicable to the Chinese standard (CNS) Λ4 grid (21 × 2 (J7)) ----.------ t ------ IT --- ----. ^ (Please read the notes of Beinan before filling this page) AA52 8 6

A7 IP 5. Description of the invention (

Preparation, Compound C has the formula H, C

CH, polymer residue

The compound rheology-improved resin Γ1ΪΜ resin ") is a coating composition that imparts enhanced thixotropic properties to oligomers that can be copolymerized with a vehicle resin. That is, such RM resins have undergone adequate Shear thinning, for example, as seen in lithographic inks on printing presses, for example, RM resin can be obtained by using a polyamide (for example, VERSAHID ™ 335 from Henkel) It is caused by co-reaction of gas resin and acrylic acid. Typical properties of suitable RM resin are listed in Table 2. The Central Standards Bureau of the Ministry of Economic Affairs, I, Industrial and Consumer Cooperation, Table 2 Color acid value (mg, RM resin ( Gardner) KOH / g) Compound F 5 5 Compound G 4 5 Compound Η 7 5 Viscosity functional group (Po, at 601) (theoretical value) Appearance 250-450 400-600 500-700 2 The R M resin listed in this article contains a diepoxide and an acid group that react in the presence of polyamines derived from polymerized fatty acids. 29- This paper applies to China National Standards #standard (CN'S) Λ4 Specifications (210xm) ----------- Shang ------ Order ------ line (please read the intent of the matter before filling in this page) 4452 8β Ministry of Economic Affairs ~ ' Printing of the local co-operative consumer cooperatives 5. Description of the invention () 1 1 reaction (including ethylenically unsaturated carboxylic acid or its reactive derivative) 1 product The poly M amine typically has less than 10,000 Gram / mol number-average molecule i [Most 0 Read 1 The first useful epoxide is glycidol m of both polyphenols and polyols Read 1 ΐ Ring-gasified fatty acid or dry oleic acid &gt; Gasified diolefins and 1 I 1 t cyclic gasified di-unsaturated acid esters and epoxidized unsaturated polyesters, / '1 means 1 I should contain fluorene molecules on average over fluorene ring gas bases. Based on whether the filial term 1 I ring gas resin is essentially carcass or polymerized to a certain degree, the better ring fill in this i gas The compound may have a molecular weight of 300 to 600 and a page of 1 50 to 1,200. Tritium equivalents. Representative examples of ring gaseous compounds include 1 1 condensation products of polyphenol and (methyl) epichlorohydrin. 〇About polyphenols ♦ Bisphenol A, 2,2'-vitamin (4 1 order phenyl) methane (bisphenol F), halogenated bisphenol A, resorcinol, tetrahydroxy (group) 1 Phenylacetin &gt; Novolac m varnish resin cresol novolac »Bisphenol A 1 j Phenol IS varnish and Bisphenol F phenol varnish 〇 司 · Listed: from polyhydric alcohols (eg I f And polyalkylene glycol) available alcohol ether type ring gas compounds 1 1) such as white glycol t 1, 2-propanediol &gt; 1, 3-propanediol »1, 4-butane 1 glycol 1, 6-Hexyl alcohol neopentyl glycol &gt; glycerol ΐ polyethylene glycol polypropylene 1 1 glycol &gt; polytetrahydrofuran (i.e. poly (1,4-butanediol) (which is available from DuPont 1 i To obtain the commercial QM m TERΑΤ0ΗΝ Ε®, the alkylene oxide adducts of bisphenol i 1 and (methyl) epihydric alcohol = glycidylamines available from white aniline such as &gt;. Diaminodiphenyl Jiayuan »Diaminophenyl m and p-aminophenol and (1 1 methyl) epilol: glycidyl esters based on anhydrides, for example, benzenebenzene 1 I anhydride and tetrakis or 1 ^ 郯 benzene Diacid anhydride and cycloaliphatic gaseous compounds such as 1 1 -30- 1 I i 1 This paper size is applicable to the Chinese National Standard (CNS) A4ML grid (2 丨 〇χ 2 [) 7 public waste) 4452 86局 3 Bureau 9- &quot; Consumer Cooperative Seal ^ V. Inventive Seal (&gt;?) 1 1, 3, 4-Cycloamino-6-methylcyclohexylmethyl ester and carboxylic acid 3,4-cyclochlorine -6-I 1 Methylcyclohexyl Se C 1 1 Glycidyl polyether of polyhydric phenol Pseudo-polyol and epilol or glycerol ih 1 First-demineralized alcohol reacts with a sufficient amount of caustic m to It can be combined with halogenated alcohols to produce 1 glycinyl ether of 0 polyols by combining at least 1 2 moles of epimolecular alcohol and 1 mole of polyols (such as ethylene glycol, Isoprene notices 1 1 tetral, etc.) reaction, followed by dehydrohalogenation. Item 1 Removal of polycyclic gaseous compounds caused by white alcohols or phenols and epihalohydrins 1 Packing of polycyclic gaseous products caused by the well-known peracid method is also suitable. Page «· 1 I Unsaturated class 1 Polycool * Ring gaseous compounds such as diolefins can be prepared by reacting unsaturated 1 1 and its compounds with a peracid. 0 Preparation of polycyclic gaseous compounds via peracid method i I is described in various journals And patent case »And these compounds of 1 ij such as butadiene» ethyl linoleate and di- or tri-unsaturated dry 1 oil or dry oleic acid> ester and poly m can be converted into polymer Epoxides 0 ί 1 Tritium gasified dry oils are also known »According to US Patent No. 1 j 2, 5 6 9, 50 2, these polycyclic gaseous compounds are often pseudo-acid Example 1 1 Line 1 If peracetic acid or performic acid reacts with unsaturated dry oil In a specific embodiment, the diepoxide contains unsaturated lipids. [1] The cyclic gasified triglyceride of a fatty acid 01 〇 The cyclic gasified triglyceride 1 1 ester may be epoxidized by one or A variety of plant or animal sources of diglyceride i [m are produced. Only — a large percentage of bicyclic gasification i I compounds should be stored. The starting materials can also contain saturated components. 1 Fatty acid glycerol with 50 to 15 0 iodine number (preferably 8 to 11 5 iodine number) 1 I Ring gas of vinegar. For example, -Ar c5 contains 2% to 10% by weight 璟 1 \- 3 1-1 1 1 1 This paper music scale is applicable to China® furniture: ί :. ·· (CNS &gt; AMU * / (210χ 公 # &gt; &gt; '445286! Γ Central Department of the Ministry of Economic Affairs &quot; Bureau. HT -· Printed by Cooperative Cooperative V. Description of the invention (&gt; 1 ^ &gt;) 1) Ring gasified triglycerides of chlorine In general, this ring gas oxygen 1 1 contains the most suitable starting point by using glycerol rr acid m with a relatively low iodine value as the starting material 1 and fully ring gasifying them or by using glycerol having a high threshold value 'h \ 1 1 Trimeric esters are used as starting materials and only their parts are reacted to form ring gas. 1 is determined. For example, these products can be produced from the following fats and oils 1 (based on their starting iodine The values are listed in order of order) Tallow 9 Palm oil 1 Emu oil Note 1 1 mn ^ r Dripping oil 1 Biochemical oil 1 Canola oil and preferably cottonseed oil Soy oil »Whale Ψ Item Re 1 I Bone fat» Sunflower oil &gt; Linseed oil. An example of a typical ring-gasified oil is a fill-in pack. M Ring-gasified soybean oil with a cyclization value of 5.8 to 6.5 »has 5.6 pages 1 to 6.6 Epoxidized epoxidized sunflower oil with 8.2 to 8. 6 1 I Ring-gasified linseed oil with a ring-M value and ring-gasified whale bone fat with a ring-value of 6.3 to 6.7 Ring-value 1 1 Order 1 J Additional examples of polycyclic gas-containing compounds Of glycerol or dipropylene glycol-&gt; diglycidyl with a molecular weight of 9 up to eg 2,000 polypropylene glycol 1! Mt glycerol diglycidyl ether * m-benzene di m i [glycidol_ t 4,4'-isopropylidenedidiol diglycidyl ether, ring 1 1. 1 y phenol m varnish j such as 4, 4,-methylene diphenol and epigasol condensation products and 4, 4 '' Condensation of isopropylidene phenol and epihydrin alcohol 1 Shrinkage of cashew oil 1 I glyceryl ether 〇Cyclized soybean oil m »η7Γ: chen oxidation unsaturated poly ΘΙ 1! 1 vinyl cyclohexene Monoxide »Dicyclopentadiene digas t Dipent 1 ί Diene digas * Epoxidized polybutene and T * U * m gas The m-condensed 1 I compounds are, for example, 1methyl-3!) 4, -epoxidized hexanecarboxylic acid 3,4 -cyclophenylhexyl ester. 1 1 Glycidyl ether of bisphenol, bisphenol, a compound of type 1 I &gt; which is interconnected via an aliphatic bridge inserted through a —-pair of 1 i -32- 1 I i 1 This paper size is applicable to Lao Guo® House: quasi (CNS) Ad Kuo () ^ AA5 2 8 6 Η 'Central Ministry of Economic Affairs ^ ^' Bureau K Industrial and consumer cooperation. ^ Printed in V. Invention Description (Λ ί) 1 1 is composed of phenol group m. Although any bisphenol can be used, the hydrazone compound r 1 1 2, 2-m (p-hydroxyphenyl) propane-generally known as bisphenol A is the most commercially available! I widely available Supply item. Poly (glycidyl ether) can be used for better γΛ hybridization, but v &gt; 1 I is better to use-air glycidyl ether first. The best is to say diarrhea liquid m bisphenol A / epidermal condensation 1 back The compound has a molecular weight ranging from 300 to 600, and the acidic component is called by an ethylenically unsaturated acid. 〇 恃 别 1VK Suitable Notes 1 1 Things 1 Unsaturated acf Early carboxylic acids are α, β-unsaturated monobasic acids. Examples of such aar early carboxy term and 1 acid Otr m body include acrylic acid 1 β -Acrylic oxypropionic acid, methyl propyl fill in this 1 pack! Enoic acid t butenoic acid and alpha-acrylic acid. Preferable examples are acrylic acid I 1 1 and methacrylic acid. The acid components of the acrylic acid are hydroxy acrylic m or methyl 1 1 hydroxy acrylic acrylate and dicarboxylic acid anhydride (for example, the following example). 1 j adduct phthalic anhydride i succinic anhydride 9 maleic anhydride »glutaric acid m [order 1 I * octenyl succinic anhydride, dodecenyl succinic anhydride S n m m acid anhydride tetragas phthalic anhydride 1 hydrogen Phthalic anhydride and methyltetrahydrophthalic acid 1 1 anhydride. These adducts can be prepared by methods known in the art for the preparation of organic compounds 1 1 acid components can also contain other Carboxylic acids. In certain embodiments, the acid component may contain a lesser amount of 1 such as 1 less than 5096 fatty acids in total acid fields. More typically less than 20% of total acid equivalents. 1! Fatty acid Θ 疋 Saturated and / or unsaturated fats containing 8 to 2 4 atomic atoms! Monocarboxylic acids or saturated or unsaturated hydroxyl groups containing 8 to 2 4 atom atoms 1 1 Carboxylic acids such as ΓΛ 眈 and / or hydroxyacetic acid may be more natural and / or μ ·· 〇V · &lt; Λι An example of a suitable source carboxylic acid is octanoic acid> 2-ethylhexanoic acid t dec 1! Acid 9 lauric acid »tetradecanoic acid» palmitic acid ί P a 1 3 Γ g on ic II Oleic acid * Stearic acid t Isostearic acid * Oleic acid »Petroleum acid> Petrosinic acid 1 I -33-1 1 I 1 This paper is suitable for China National Samples (CNS) Mlt 彳 ft ί 210 / 2 扪 ':. &Gt; fried) l &gt; A452 B 6

IP Department of the Ministry of Economic Affairs, Central Bureau of Industry and Economics, only the Consumers' Cooperative Press &quot; V. Description of the Invention () 1 ί Oil * Linseed »» Tungstic acid t C 0 n J uene fatty acid 1 cis-mouric acid, 1 1 I peanut Acid f 廿 enoic acid I 廿 dicarbonic acid ♦ Erucic acid and pasenoic acid and its technical grade mixture obtained by 1 * When pressurized hydrolysis of natural fats and oils 4! Ί Yu gasification from R oel e η ϋ 合成 合成 合成 & & & & gt 作为 作为 作为 作为 作为 时 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 早 在 在 在 待 in the specific embodiment of the preferred embodiment 1 fat surface I 1 fatty acid pseudo white Derived from technical-grade mixtures of fatty acids »It is noted that 1 1 After hydrolyzing oils and fats of animal or plant origin under pressure 9 is typically in the form of technical-grade mixtures encountered in oil re 1 I chemistry Get this type of junk or tan manuscript 1 pack of oil and fat from sources such as coconut oil r palm kernel oil t sunflower oil t menu ^ _- · 1 I oil & rapeseed oil, ±± vulgar oil and tallow 0 However, fatty acid may also contain 1 1 1 chain of fatty acid residues. For example »2-ethylhexanoic acid isosalic acid or isostearic acid 1! Residues of fatty acids 〇1 玎 The preferred fatty acid is natural Mixtures obtained from demon sources 9 For example * 1 palm oil »standard coix seed oil * coconut oil rapeseed oil (from old high erucic acid plant 1 1 or new white erucic acid plant) erucola oil), sunflower oil (Lai Bai Lao 1 | Low Oil Sandalwood or Come @ 新 高 油 植物), Castor Oil Soybean Oil, Cottonseed Oil 1! Brigade 1 1 Peanut Oil &gt; Olive Oil i Coriander Oil m Sesame Oil &gt; Plant Ranch Foam J Oil Mould Oil »Tea Seed Oil ♦ Linseed Oil 1 Tallow &gt; Emu Oil 1 Fish Oil, etc. 〇 days The fatty acids produced are typically present as glycerol 1 oleic acid triesters of lipid-antacid mixtures> in which all fatty acids have an even number of carbon atoms 1 I mesh. On a weight basis 1 the larger part of the acid has 12 to 18 white Atomic and 傜 i I saturated or αα 単 &gt; — ^ or tri-unsaturated 0 1 1 The preferred ring gas resin, which is caused by white bisphenol k may have 1 1 atom per 2 ring gas groups 〇 Therefore t and acrylic or methacrylic acid \ 1 I _34_ 1 i ί 1 This paper size is applicable to China National Pillow (CNS) Λ4 Now · (2 丨) 445286 / \ Ί ΙΓ V. Description of the invention (W) The product will contain a ring gas (meth) acrylate compound, which has a single main chain of a polycyclic gas and the antimony ends of each of the two ring (meth) acrylate groups, thus forming a diacrylate plus The stoichiometric number of the acrylic acid of the compound is most likely to be two moles of acid in terms of two ring gas groups. In practice, however, it is better to use a slightly larger amount of acid than necessary to cover two epoxy groups. Therefore, the number of acrylic acid reacted is typically between 2.001 moles and 2.1 moles per two ring gas groups, and more typically between 2.01 and 2.05 moles. The reaction of the ring gas with the acid occurs in the presence of polyamines derived from polymerized fatty acids. The polyaldimine preferably has a number average molecular weight of less than 10,000 g / mole. Low-melting polyamide resins which melt in the approximate range of 90t: to 13 ° can be prepared from polymerized fatty acids and aliphatic polyamines. Typical polyamines that can be used are ethylenediamine, diethylenetriamine, triethylenetetraamine, tetraethyleneethylpentamine, 1,4-diaminobutane, 1,3-diamine Butane, hexamethylenediamine-1,6-nazine, isophordiamine, 3- (N-isopropylamine) -propylamine, 3,3'-iminobispropylamine, etc. A preferred class of these low-melting polyamides is pseudo-derived from polymerized fatty acids and ethylenediamine and sold at room temperature. Suitable such polyamides are commercially available under the trade designation VERSA MU ID polyamine resins, such as VERSA MU ID 3 35, 7 50 and 7 4 4 with pseudo-average molecular weights of up to 10,000. Amber resin for children (preferably from 1,000 to 4,000) and softening point from below room temperature to 190¾. The preferred polyamide is VERSAMID 335 polyamide, which is commercially available from Henkel and has an amine number of 3, a number average molecular weight of 1699 -35- this paper ί / ί Applicable to China S Standard (CNS) A4R Move (2 丨 0 X: Public) II --------- ^ ------ IX ------ i (-&quot; Read the notes on the back and fill out this page) 4452 36 Η 7 Printed by the Ministry of Central Standards and Leather Industry Bureau, K. Co., Ltd. Co., Ltd. V. Description of the Invention (々 4) 1 1, such as 姅 measured by the G-method (G PC) method using polystyrene 1 1 as standard) and polydispersity of 1.90. 1 1 Preparation 丨 Equivalent VERS AH ID polymamine resins are well known &gt; By changing the functionality of ih I t acid and / or polyamine »can obtain a variety of viscosity» molecular weight u \ If 1 1ϊ · 1 and The content of active amino-based paintings spaced along the resin molecules is typical and 1 to 1 used in this article. V ER SAH ID Polyamine resin has an amine meaning of 0 to 25. 1 thing 1 value »should be 0 to 10 More preferably m 0 to 5. From about 1 to 30 poises (at 1 68 1C), the viscosity of I 1 and polydispersity less than 5 0 amine value and number-average numerator of polymamine Fill in this 1 Pack 1 It can be measured as described in U.S. Patent Nos. 4, 652, 492 (issued to Seiner, etc.), and its contents are incorporated herein by reference. Combined weight based on cyclogas acid component and polyamine 1 1 Scenery »Not more than 50% by weight blended into the composition. Yi Yi Shao 1 order i does not exceed 25% by weight and the best is from 5% to 15% by weight. 1 1 The inverse m between ring gas and acid can be at a wide range of temperatures, such as 1 1 from 40 to 15 t :, more typically from 50 t: to 1 30 V, and preferably between 90 and 1 1 line 1 11 0C It should be carried out under atmospheric pressure, negative pressure or super-atmospheric pressure. It should be applied in an inert atmosphere. Continue until the acid 1 2 value of 2 to 15 is obtained. This reaction usually occurs within 8 to 15 hours. Prevents premature or 1 1 polymerization of unwanted products or reactants. Adds a vinyl inhibitor 1 to the reaction mixture. 0 Proper vinyl polymerization inhibitors are included! 1 Third-butyl catechol, hydrogen roller , 2,5 Butyl hydrogen m Hydrogen mt 1 tlO m B _ etc. 0 Favorable t will be inhibitor t Based on the total amount of the reaction agent * 1 |. In your weight basis 0.005 to 0 1% concentration comprising the reaction mixture. 1 \ -36-1 1 1 1 The standard of this paper is applicable to the national standard of China (CNS) (210XW). A7 B7 The seal of the K Industrial Consumer Cooperative of the Central Bureau of Standards and Development of the Ministry of Economic Affairs. 5. Description of the invention () 1 1 During pre-catalysis »The reaction between m gas and acid slowly progresses * but 1 I can be accelerated by dropping b =? Catalysts» suitable Shida catalysts »Take 1 1 for example 1 various kinds of —Γ bases» for example Diethylamine dibutylaminopyridine-η 1 first j-pyridine »dimethylaniline 9 tris (: dimethylaminomethyl) phenol * diphenylhydrazone 1 —: butyl reading 1 jl ·. 1 base o 1 dibutyl Kiebb's * Alcohols such as »Sodium methoxide sodium butoxide and 1 to 1 various quaternized ammonium CJ substances such as sodium methyl methoxide, such as tetramethylammonium bromide. Note i 1 t Atomized tetramethylammonium 9 Atomized benzene Methyl-trimethylammonium and the like. Based on the reactant term 1 1 Total weight »at least 0.01% This type of catalyst needs f should be at least 0.1% ο Complete this 1 Pack | Can be used and added before or during the reaction or after the reaction A typical example of a suitable monomer as an anti-m-diluent in a 1-m compound is an ethylenically unsaturated vinyl or vinylidene monomer containing 1 1 1. The composition of this composition with 1 1 is styrene * vinyl toluene t --- butylbenzene 1 ethylene t-methylstyrene, -styrene, distyrene, di-i vinyl Benzene * Ethyl9 Vinylbenzene »Diisopropenylbenzene ♦ Acrylic acid 1 1 Cool * Ethyl acrylate 甲酯 Methyl methacrylate ethyl methacrylate &gt; 1 I Acrylonitrile methacrylonitrile &gt; Various vinyl Esters such as vinyl acetate 1 1 and saturated and unsaturated aliphatic *- Polyvinyl monovinyl vinegar t soul i For example, the following various acids are ethyl esters of propionic acid »isobutyric acid &gt; hexanoic acid» oil 1 I acid »stearic acid ♦ acrylic acid 1 methacrylic acid &gt; butenoic acid 9 Succinic acid I 1 1 Maleic acid * Itaconic acid fumarate, citrate hydroquinone * Tartrate I acid, etc. * and equivalent allyl i methallyl esters of the aforementioned acids 1 1 Class &lt; Itaconic acid αβ Early esters and diesters such as methyl ethyl ester «Ethyl butyl butyl ester and other I 1 maleic acid and mongolic acid tltl early m 1 diester and its amine and nitrile compounds t such as 1 | Malay Diethyl acid f malea m radical 9 Tetramethyldiamine amine t Tianma m radical di 1 1 -37- 1 1 1 1

The size of this paper is applicable to the National Standard of the Central Circle (CNS) / \ 4 叱 Grid (I 4452 8 6 ΛΊ Η7) Printed by the Central Bureau of Standards of the Ministry of Economic Affairs of the Consumer Affairs Bureau, printed on the fifth, the description of the invention (hb) 1 1 Nitrile * Fumaric acid Dimethyl urethane derivatives have at least ___- copolymerizable unsaturated groups that are directly or indirectly connected to the triazine IS 15¾ 1) i.e. diallyl ethyl urate t 氡Ethers such as uric acid triallyl m, such as 1 1 vinyl, allyl m »divinyl m 1 diallyl» isophenylene 1 1 first m divinyl m, etc. Amino acid diallyl Kb 0H &gt; Tetragas phthalate 1 back 1 propyl m, Tetrabromophthalate diallyl propyl t-bromopropargyl acrylate and 1 1 1 and the part of the BO carcass listed above Serving can be melted or soluble, polymerizable polymerization attention! I Henry 1 物 等 Λ Item 1 I In the preparation of a polymerizable composition containing the reaction product of the present invention I and one or more of the types of αα early bodies listed above 1 Page 1 of each monomer | Relative number can be wide Change 〇However> In general, DTPJ * (each) att early body image 1 is less than 50% by weight of the new product and used 9 is typically in the range of about 1% to 30% by weight 1 I, and More typically within the range of 5% to 15% 1 by weight. The novel derivative of the present invention can be cured or αα alone or pre-capped with other Sfel or 1! Polymer blends to convert it into an unmelted state. J is exposed to radiation via early insolation 1 1 T or in the presence of a catalyst that generates white radicals, for example] 1 line 1 jasmine marriage 1 benzene decay marriage m and Mi ch 1 er ketone. Free radical initiators are typically 0.01 to 20% by weight of radiation-curable components and I [ΓΊ Examples of useful radiation include ultraviolet light and ionizing radiation such as those generated by a 1 τ prior machine &gt; Electron accelerators such as ν a η de G re af machine 1 ♦ Traveling Wave Isolation Line Accelerator 1 To be bid farewell to US Patent No. 2, 7 3 6, 6 0 9 No. 1 | 4 days for this type Demon and synthetic radioactive materials such as cobalt 6 0 etc. 0 is 1 1 guarantees: the composition will not polymerize prematurely 1 can be added to the white base inhibitor 1 I &gt; 38- I 1 1 1! Wood paper scale is applicable 0® furniture:?: Quasi (CNS) AWUft (2 丨 () 乂) 445286 Λ 7 ί! 7 V. Description of the invention) Polymerizable composition. Examples of suitable inhibitors include: Hydrogen and its methyl M, or butylated hydroxytoluene, the content of which is a polymerizable component by weight, from 5 P P m to 2 0 0 0 ρ ρ Π). Additives can also be used, which are expected to be particularly useful for applications that mimic extensional compositions. For example, ultraviolet light stabilizers such as Flo "stabu V-II from Kromachei®. Compound H It is prepared by reacting with acrylic acid, a C12-Cis alkyl fatty acid and VERSAMIDE 335 polyamine and containing a compound of the formula: (ch3) 2c [-r6-o-ch2ch (oh) ch2-o (o) cch = ch2] 2 together with its derivatives grafted with polyamide. Compound F can be obtained by bisphenol A ~ diglycidyl ether and acrylic acid, 1,4-butanediol diglycidyl ether and VERSAMIDE 335 polyamine The reaction is prepared and includes each compound having the following formula: (ch3) 2c [-R6-〇-CH2 CH (0H) CH2-0 (0) CCH: CH2] 2 and CH2 = CHC (0) CH2CH (0H) CH2-0- (CH3) 4'-0-CH3CH (0H) CH-0 (0) CCH = CH〇 together with its derivative grafted with polyamine. Compound G can be obtained by bisphenol A-diglycidyl The ether reacts with acrylic acid and VERSAMIDE 335 polyamine to prepare and includes a compound of the formula: (CH) C [-R -0-CH CH (0H) CH -0 (0) CCH = CH] cured The importance of UV film The film properties are hardness, solvent resistance, and adhesion. These are provided in Figures 1 to 3. The UV-cured paper size of these oligomers is applicable to China® House: Special (CNS) Λ4 ^ 怙 (210χ297 (Public film) Printed by the Ministry of Economic Affairs of the Ministry of Economic Affairs of the M Cooperative Consumer Cooperative: * '445 2 ai — Λ 7 ^ 4 5 9 ft 6 ________ H: ______________________________ 5. Description of the Invention (w) The hardness of the film is from the relatively soft compound A to The fairly hard compound D varies. Figure 1 U Among fatty acid-modified oligomers, compound B produces the hardest film. This may be due to the alicyclic nature of the polyols used in this oligomer. The difference in hardness between compound D, compound C, and compound A may be attributed to the higher acrylate equivalents in compound D and compound C, which results in a denser crosslinked network. Solvent resistance of UV-cured films The properties follow the same general trend (Figure 2). Except for Compound A, the high methyl ethyl ketone (HEK) solvent part of all oligomers. Due to the hydrophobicity of polyesters, these polyesters resist the passing of MEK, a polarity Solvent and part due to the formation of a A densely crosslinked network that resists solvent diffusion in human polymer bonds. The polarity of the polyesters listed above is as follows: Compound E &gt; &gt; Compound A, Compound D, &gt; &gt; Compound B, Compound C. Acrylate resin oligomers have excellent adhesion to concrete. Adhesion to aluminum can be moderate to poor. Due to their higher polarity, compound D and compound A adhere to aluminum better than most of their hydrophobic counterparts. The rapid and volume shrinkage of the cross-linking reaction resulting from this result leads to poor adhesion of the UV-cured polymer (Figure 3). However, compound E in a clear coating mitigates this problem. This product has inherent photoinitiator residues that, when present as such, or together with other monomers and oligomers, initiate polymerization on their own. It also has acidic groups that increase the polarity of the formulation and strengthen the adhesion to metals. Finally, the two acrylate groups are copolymerized with other UV curable components in the formulation. This means that after photolysis, the initiator residue is still covalently incorporated into the crosslinked polymer. Contains this _ 4 0 _ This paper size is applicable to the Chinese National Cricket (CNS) Λ4 Current 牯 (21〇χ2Μ: Μί ·) — ^ 1-it I. ^ Pn ^ i] ^ i ijn ^-ϋ ^ —-i I ^ ~ ^ ϊ IH ^ E-I i-(Please read the precautions before filling in this page) 445286

A ΙΓ 5. Description of the Invention (θ?) The formulation of commercial products can have potential uses in various applications, such as radiation polymerizable coatings for food packaging. In this case, photolytic initiator residues remain Migration trends of substances may present practical problems ^ When compared with the use of standard photoinitiators. When present in reactive diluents (PHOTOMER 4028), acrylate polyesters (compound D), acrylate ring vapors (卩 110 Compound E was noticeably improved in the presence of butane 0 (^ 1? 3〇3 8) and acrylic urethane ([&gt;}] 〇1 '(^ £ 1? 621〇) oligomers, etc. Colorants are optional components of coating materials and may be in the form of insoluble finely ground pigments or soluble dyes. For example, xylylene blue pigments milled to a particle size range from about 1 to 4 microns ( As measured on a Hegmann meter) is suitable for use in conjunction with the oligomeric vehicle described above. Compound B and Compound C wet the xylylene blue pigment very well. In addition, in lithographic inks, a water bag is formed Oil emulsion is the main step to obtain the most suitable printer performance. To determine this, for the formulations of ochre, a test of water pick-up called the Su M and test can be carried out. The Sur 1 and test includes the number of children and the rate of M absorption of water under low shear conditions. Additional information on this trial can be found in the following literature: New York, Chapman &amp; Hall, Inc. (1993), RH, Leach, and J. Women's Workers' Consumers Cooperatives, Central Standards Bureau, Ministry of Economic Affairs, India (-First (Read the back-to-back precautions before writing 4 more c)

Pie "ce (eds) printed manual P.3680. Now referring to Figure 5. It shows that the hydrolytic properties of compound B and compound C are shown in the straight part of the figure. The two oligomers show similarities. Water absorption. The two oligomers initially show rapid absorption of water and then reach equilibrium. This is an indication: a satisfactory stonemonger printing ink. The following examples of chromium are shown for the purpose of illustrating the invention, Unless—4 1 The Ministry of Economic Affairs wins the bid; printed by the F Bureau ’s Consumer Cooperatives

Vv 4452 Si 1 Λ '. ΙΓ V. Description of the invention (π) Explain in other cases. All the numbers and percentages of the composition are the most contrived examples ... 1 ... Compound A has the formula Compound:

Moreover, it was caused according to the following procedure: The following compounds were added to a reactor: 156.8S g of 3 mol, ethoxylate of Sanxiang Methylpropane (eq. WT. 63.75g / eq.), 180.12 Grams of dimer acid (0. .1; .282.478.6 &lt; 1. (which has about 94% by weight of dimer acid, about 2.5% by weight of higher polymerized acid and about 3.5% by weight of monomer Fatty acids, available from Henkel Company, Chromium ^ (卩 01 ^ 1 008; and 91.82 grams of acrylic acid (6 &lt; 1 ^ 282.47), 218.69 grams of toluene, 0.13 grams of hydrogen _ (200 ?? 111, as polymerization Inhibitor), 0.52 grams of hydroalcohol monomethyl S_ (800 ppm, as a polymerization inhibitor) and 3.2S grams of hypophosphorous acid as a color reducing agent. At 25 ml per minute, an air spray reactor was used. The heating reactor contained Content to 55 to 60Ί3 and add 8.56 grams of p-toluenesulfonic acid (combined weight of 2% by weight of each acid and ethyl trimethylolpropane). Heat the contents of the reactor to 98 scoops Continue heating until the reaction rate is slow, as measured by the collected esterified water. Apply a slight vacuum of 2 ”H g to each step [in (starting at 4 1UU up to 6 ”maintains the reaction temperature between 95 ~ 9810. Applying" 42 "wood paper standards are applicable to China's national standard (CNS) A4UL imitation ()-^ -------- pack ------- --- Order ------ Wei (fill in this page for the first thing you need to read and remember) 4452 86 Λ 巧 ΙΠ Central Ministry of Economic Affairs, Standards, Industry, Investment and Cooperation Cooperation Seal ^

V. Description of the invention (4ί) 1 1 Vacuum not more than 16 to 18 "Η g 〇 After 6 hours of reaction, check the acid value of the product every 2 hours 1 After 10 -1 2 hours, check the output every 1 hour 1 [The acid value of the product Γ »When the acid value of the product is less than 12 hours, the reaction is completed. 1 First 1 Cool the reactor to room temperature. Adding toluene is sufficient to cause 1 1 by weight! '4 Read 1 1 reaction The solvent-to-solvent ratio is calculated from the theoretical amount of the initial batch weight of the collected water, which is less than 1 °. Warm the reactor to 40 ° C. Caustic salt is injected into the 1 1 aqueous solution (which contains 0.5 (wt% sodium hydroxide and 16 wt. black sodium chloride) added to the reactor and its amount equal to 20% of the weight of the tiller, less than the value of the theoretical DTfx value 1 filled with esterified water. Mix for 2 to 5 minutes f then let the pages 1 I split. Break it Place at 45 ° -50 ° C for about 30 minutes and decante the water phase. I 1 Measure the acid value of ifefjr. If necessary, repeat the caustic brine wash to reduce the acid value of 1 to 4- 50. Warm the organic phase. Heat to 40. Add a saline solution (which contains 1 to 16 wt. Sodium sodium sulphate) into the reactor (a quantity equal to 20% in batches 1 of vinegarized water that weighs less than the theoretical value) and mix slowly歴 歴 3-5 1 minute, after demon Oi · »let the phases split. Let it stand at 45 ° -50 t 歴 about 30 1 | spectroscope and decante the water phase 0 in 5 ml of isopropanol and 5 I 1 t in ml of toluene caused a dissolution line of hydrogen hydrazone and methyl hydrogen of the same number as those added earlier! Liquid 〇 was added to the reactor and the contents were heated to 50 t 0 to 30 ΐ I / πι i η 1 | The air was sprayed into the reactor at a rate and a vacuum was applied to a Hg column 1 of 29 -30 ″ to distill off the toluene. The temperature was gradually increased to 82 〇 no more than 85 〇 followed by entanglement distillation through the upper gas chromatographic separation method shows: toluene is 1 1 less than 10 PP ΠΙ 〇 the thermal product and 1. V t% fill agent such as powdery clay ( Example 1 I (C e 1 it Θ © brand), which is available from Ce 1 ite company, is stirred and filtered. 1 1 xiao Example_2— 1 1 | Compound E and § The thin film derived from it is prepared according to the following method. 1 1 _ 4 3 ~ 1 I The thick scale of this paper applies the Chinese National Standard (CNS) to wither U10a2) Λ ΛΑ5286 V. Description of the invention U: The highest number is 24. 58 (76.3 millimoles). Benzene _ Read the back of the note and then fill in the booklet. Tetracarboxylic dianhydride is mixed with the following compounds: 5 2 3 parts by weight (1 5 2 mol) by the United Shuohua Company Supply of caprolactone / 2-hydroxyethyl acrylate adduct, whose trade name is ΤΝΕ M-100, 0.76 parts by weight (6.22 mmol) of dimethylamino-pyridine And 0.19 parts by weight of methyl hydrogen poor. The mixture was stirred vigorously, sprayed with dry air and gradually heated to SOC. Note the initial exotherm of approximately 10T :. A portion of the bis-mesterone tetraacetic dianhydride appears to be undissolved. The mixture is then heated to UOt to 120t in approximately 30 minutes. The undissolved material was then dissolved and the solution clarified to a dark orange color. The heating was stopped and, with stirring, 22.17 parts by weight of hexanediol diacrylate was added until the solution was homogeneous again. The acid value of the product should be from 80 to 95 meq / g K0Η. The product was then cooled. The composition was drawn down on paper to produce a 1 mil dry film and photocured. Practice .13 — Compound B was prepared in accordance with the same procedure as listed above in Example 1 except that the following reactants and several children were added to the reactor. Central Standards of the Ministry of Economic Affairs, Industrial Engineering and Consumption, Hezhu Co., Ltd. Printed Trihydroxyethyl Isopropionate 9 1.96 g E 0 P 0 L 10 0 8 7 9, 5 4 g acrylic acid 5 5. 7 6 g p-toluene Sulfuric acid 4, 54 grams of methyl octane 0.28 grams «m 0.07 grams hypophosphite (50% aq.) 1. 16 grams of toluene 114. 92 grams 44 This paper is applicable to the standard threshold CNS) Λ4 圯 printed by the Ministry of Consumer Affairs, Central Jingzhun Bureau, K & F Cooperative &gt; 445286 * Λ7 ΪΡ 5. Description of the invention (〇) Example Λ. Except adding the following reactants and quantities to the reactor, compounds C. It was prepared according to the same procedure as specified above in Example 1. Trimethylolpropane 207,64g EMP0L 1008 97.75¾ Acrylic acid 209.75g p-Toluenesulfonic acid 10.30g Methyl hydrazone 0.56g S 0.10g Hypophosphonic acid (50% aq. ) 3.50 grams of toluene 1 7 3.68 grams using Photomer 3016 (high viscosity ring gas diacrylate) and Photonier 3072f fatty acid modified ring gas diacrylate) as the basic resin and stupid dimethyl blue pigment. Three lithographic inks. Ink Ai does not contain RM resin, and Ink Bi contains 18% of compound Η as RM resin. The ink does not contain RM resin but has 1.8% δ yishi as a thixotropic additive. The rheology test was performed on a Carri-Med CSL100 rheometer using the cone-plate method. Regarding the viscosity temperature distribution, the samples were prestressed at 6500 d y ne s / cm 2 and the viscosity IJ was 25. And 50 0 t. Based on the amount of shear stress, the sample was equilibrated at 2510 before stress sweeping was performed. When compared with other oligomer compounds C (polyester acrylate) and compound U (aromatic urethane acrylate), except for compound F-45-This paper is applicable to the Fujian Standard (CNS) 4 坭 (2I0X? (; 7,:. &Gt;)) --------- install -------- order ------ line (please read the precautions for the back first) (Fill in this page) 4452 Θ i 'A &quot; Printed by the Central Bureau of Standards of the Ministry of Industry and Labor Cooperatives 5. V. INTRODUCTION OF THE INVENTION (44) 1! 1 resin modified by chemistry is shown in the temperature range of 25 -4 5P Higher 1 1 Viscosity distribution 1 As shown in Figure 6, compounds Η and Ph 0 t 0 HI er 3 0 7 2 1 1 stress / shear-blowing bfc shows more pseudoplastic properties in both resins 1 1 »As shown in Figure 8, 0 Dj j Μ resin compound Η has a wide range between-;. A. 1 if 1 hysteresis loop, which is notable as a significant thixotropy in this resin 0 therefore, and 1 No. 1 when When using R Μ resin as a rheology modifier, before the thinning of 1 t 1 is taken into account in the printing press, the higher initial viscosity of these resins allows the term to be further maintained. In the ink 0 When the shear is removed (for example, by filling the ink onto the substrate via transfer filling), the ink obtains a gel structure. R M resin in the coloring page 1 I (blue ink)% Strengthening performance in the system The shearing shown in Figure 7-1 1 is clearly visible in the force-passing. In the ink tested, BL containing RM resin 1 1 compound Η BL ·. When the cutting speed increases, the warp to the lowest shear The cutting force should be set at a fixed level. Conversely, the oil containing silica is up * m C. Even at low cutting speeds, it experiences 1 to a large cutting stress. This may damage the performance of the ink. »In the printer 1 1 Unwanted Points Benefit IIII Figure 9-Cap Chart It is shown that other oligomers of A 〇 can be polymerized with 1 1 ray! Pho I t 0 me r 3 076 tb Compared with »About Μ oligomers F and compounds G, the viscosity decreases at higher Cheddar . These oligomers eliminate the need for 1 I-ordinary and annoying m-free fillers such as talc and silica 〇1 ί Because of the »» Polyester compound D of acrylate and AQ compound A have the properties of solidified 1 1 film Good combination of 1 and suitable m can be blended with r. They can be used in oil tSBi inks and transparent coatings for wood paper and plastics. 0 Compound E 1 1 itself triggers UV curing and dramatically improves adhesion. 0g of cured UV in clear coatings with oligomers and reactive diluents of all categories 1 | [1 -48-1 1 1 1 Wood paper size applies to Chinese National Standard (CNS) Λ4Κ 彳 Μ 2Ι〇 Χ2M> &gt;/; · 1 Through the shallow central government bureau of Fufu S industrial consumer cooperation Du Yinu 4452 36 5. Description of the invention Ur) Resin avoiding cesium requires a photosensitizer such as benzophenone (which may leave an odor, cause By-products in resin). Therefore, the radiation polymerizable composition containing the vehicle resin and the RM resin can be formulated without a large amount of addition cutting. When cured, it may not form a chemically bonded part of the polymer structure, The higher viscosity oligomer compounds B and C have a good hydrophilic / lipophilic balance and can be used as basic resins in UV inks such as print printing, web selling, letterpress and rubber printing. The rheology-modified resin grants improved printing and functional benefits to UV inks without the use of silica and other inorganic additives. U.S. Patent Nos. 3,952,032 and 4,082,710, both of which are incorporated herein by reference, show the use of compounds with many acrylic atomic states as photopolymerizable adhesives in UV-curable inks and coatings. Other components of the ink compositions shown in these patents include inert polymers and plasticizers, pigments and inorganic ballasts, various other conventional additives for photoinitiators and inks, and many of them are used in Invented. The rheological properties of the ink of the present invention can be changed through these materials as long as the filler does not react with the photoinitiator. Although the above description contains many species, these species should not be construed as limiting the scope of the invention, but merely as illustrations of their preferred hip embodiments. Those skilled in the art can anticipate many other possible changes, which are within the scope and gist of the present invention, as defined by the scope of the patent application. This paper size is applicable to China House Pillows (CNS) Λ 扣 L Lifting (2 丨 pieces) (#Notes for reading first, please fill out this page)

Claims (1)

OQ fi___ if 〇 〇 K θ year shift δ day% f ABCD 6. Application for patent protection-~ No. 87113 794 "radiation polymerizable composition, a film made of it, and using this composition to form on a substrate "Painting method" patent case (please read the precautions on the back before filling this page) (Amended in February 89) Λ Patent application scope 1. A radiation polymerizable composition, which includes the combination of a) and b)倂 Product: a) 90 to 10% by weight of at least one radiation curable acrylate resin oligomer, which is an alkoxylated polyol and a first acid component (which includes the first olefin Is an unsaturated carboxylic acid); and b) 10 to 90% by weight of a rheology-modified oligomer that reacts with radiation-curable acrylate resin oligomer U when subjected to radiation polymerization conditions. ) Copolymerizable, the rheologically modified oligomer is derived by polymerizing a diepoxide with a second acid component (which includes a second ethylenically unsaturated carboxylic acid or a reactive derivative thereof) Obtained by reacting fatty acid polyamines; wherein: first and The first and second ethylenic unsaturated carboxylic acids of the acid component are a group consisting of acrylic acid, methacrylic acid, and hydroxyalkyl acrylate or an addition product of hydroxyalkyl methacrylate and dicarboxylic acid anhydride. Selected by the Ministry of Economic Affairs, Intellectual Property Bureau, Consumer Cooperatives. The diepoxide is a diglycidyl ether of bisphenol A. It is a diglycidyl group selected from the group consisting of the following compounds. Ethers: ethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,4-butanediol '1,6-hexanediol, neopentyl glycol, glycerol' polytetrahydrofuran, polyethylene glycol and polypropylene glycol It is printed by a paper containing 2 to 10% by weight of epoxidized paper. Applicable to China National Standard (CNS) A4 (210X297 mm). The Central Consumers Bureau of the Ministry of Economic Affairs's Consumer Cooperatives print t!-»'4 4 Ρ. 5 2 B β_§ ___ #, epoxidized triglyceride consisting of oxygenated unsaturated fatty acids, or an epoxidized oil selected from the group consisting of the following oils: Fats and oils derived from tallow, coconut oil Lard, castor oil, peanut oil, rapeseed oil, cottonseed oil, soybean oil, whale bone fat, sunflower oil, and linseed oil: The polyamide has a number average molecular weight of 1,000 to 4,000, and a range of 90 to 130 ° C Melting point, and amines from 0 to 25. 2. For the composition in the scope of patent application item i, the diepoxide is selected from the group consisting of soybean oil, whale bone fat, sunflower oil and linseed oil. An epoxidized oil. 3. The composition according to item i of the patent application, wherein the second acid component further comprises a member selected from the group consisting of the following acids: containing 12 to 18 carbons Atom saturated aliphatic monocarboxylic acid, unsaturated aliphatic monocarboxylic acid containing 12 to 18 carbon atoms, saturated hydroxycarboxylic acid containing 12 to 18 carbon atoms and unsaturated hydroxycarboxylic acid containing 12 to 18 carbon atoms Acid = 4. The composition of item 1 in the scope of the patent application, wherein the second acid component additionally includes a selected member of the group consisting of the following acids: fatty acids having an even number of carbon atoms and by weight , Most acids have 12 18 carbon atoms, wherein all of the fatty acid is a saturated or mono-, di- or tri-unsaturated. 5. If the composition of the scope of patent application item 1, wherein the second acid component additionally contains lauric acid. 6. The composition according to item 1 of the scope of patent application, wherein polyamine is derived from the polymerized fatty acid and ethylenediamine. -2- —. ^^ 1-n I--1-f I -I--ml I ί Please read the note on the back first and then fill out this page) This paper size applies to China National Standard (CNS) A4 specifications (210X297 mm) ... 厶 45 2 8 6 is, · 0〇 —__ £? ___ VI. Application for patent scope 7. The composition of item 1 in the scope of patent application, in which the polyamide has a content of 0 to 5 8- If the composition of the scope of the patent application, item 1, also includes a coloring agent, (please read the precautions on the back before filling out this page) At least one selected additive. 9. The composition according to item 1 of the patent application, including a photoinitiator. 10. The composition according to item 9 in the patent application, wherein the photoinitiator is composed of the following compounds. Selected from the group: benzyl-dimethyl ketal, benzoin, benzoin ether, β, α-dimethoxy-α-phenylacetophenone, diethoxyacetophenone1 α-Hydroxy-dimethylacetophenone,% 1-Benzamidine cyclohexanol and photoinitiator based on arylphosphine oxygen. 11, as in the scope of patent application The composition of item 1 includes an additional material. 12. The composition of item 1 in the scope of patent application, wherein the composition does not contain any significant amount of any additives, which is in combination with radiation curable acrylate resin oligomers It cannot be chemically combined. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 13. A kind of film, which includes a copolymerized binder resin and a rheology-modified resin, wherein the binder resin is at least one kind of radiation polymerizable resin. Derived from an acrylate resin oligomer, the radiation polymerizable oligomer starts with an alkoxylated polyol and a first acid component (which includes the first ethylenically unsaturated carboxylic acid) The rheologically modified resin is obtained by reacting a diepoxide with a second acid component (which includes a second ethylenically unsaturated carboxylic acid or a reactive derivative thereof) in a self-polymerizing process. Derived from oligomers prepared by reacting polyamines derived from fatty acids in the presence of -3-, this paper size applies to China National Standard (CNS) A4 specification (210X297 mm) Printed by the Industrial and Commercial Cooperatives' 4452 8 g ll D8 6. Scope of patent application Among them, the first and second ethylenically unsaturated carboxylic acids of the first and second acid components are each made of acrylic acid and methacrylic acid. The selected group * and the diepoxide and polyamide are as defined in the scope of patent application No. 1. 14. The thin film of scope of patent application No. 13 further contains a coloring agent. 15. Such as The film under the scope of patent application No. 13 in which the film does not contain any significant amount of any additives (it cannot be chemically combined with the binder resin). 16. —A method for forming a coating on a substrate, comprising: a) providing a radiation polymerizable composition containing a combination of the following: at least one radiation curable acrylate resin oligomer ( It is made by reacting an alkoxylated polyol with a first acid component (which includes the first ethylenically unsaturated carboxylic acid), and when subjected to radiation polymerization conditions, reacts with the Radiation-curable acrylate resin oligomers are copolymerizable rheology-modified oligomers. The rheology-modified oligomers are prepared by combining a diepoxide with a second acid component (which includes the first Two olefinic and carboxylic acids, or their reactive derivatives) are obtained by reacting in the presence of polyamines derived from polymerized fatty acids: b) applying the composition to a substrate; and 〇 Exposing the composition to a radiation source for polymerization; wherein the first and second olefinic unsaturated carboxylic acids of the first and second acid components are each composed of acrylic acid and methacrylic acid. Selected from the group, and the diepoxide and polyamide It is as defined in Item 1 of the scope of patent application. -4-(Please read the precautions on the back before filling this page) This paper uses the Chinese National Standard (CNS) A4 specification (2I0X297 mm) Α8 Β8 C8 D8 445 2 8 6 Scope of patent application 丄 7. The method according to item 16 of patent scope, wherein the radiation is selected from ultraviolet radiation and electron beam radiation. 1 &amp; The method of claim 16 in which the composition further includes a colorant. ia The method according to item 16 of the patent application, wherein the composition additionally includes a photoinitiator. 20. The method according to item 16 of the patent application, wherein the composition does not contain any additives (which is compatible with radiation-curable acrylic acid). Ester resin oligomers cannot be chemically bonded). 21. A compound prepared by reacting trihydroxyethyl isocyanurate with acrylic acid and dimer acid at 98-102 ° C and having the following formula: &lt; Please read the notes on the back before filling in this page) 0 Dimer residue 22. A compound prepared by reacting di- and trimethylolpropene with acrylic acid and dimer acid and having the following formula: Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs -5-