TW432095B - Compositions of polyphenylene ether resin and syndiotactic polystyrene - Google Patents

Compositions of polyphenylene ether resin and syndiotactic polystyrene Download PDF

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Publication number
TW432095B
TW432095B TW87119729A TW87119729A TW432095B TW 432095 B TW432095 B TW 432095B TW 87119729 A TW87119729 A TW 87119729A TW 87119729 A TW87119729 A TW 87119729A TW 432095 B TW432095 B TW 432095B
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Taiwan
Prior art keywords
hardness
polyphenylene ether
nicks
compositions
ether resin
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TW87119729A
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Chinese (zh)
Inventor
Takashi Ohtomo
Hiroshi Morokuma
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Ge Plastics Japan Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/06Polystyrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08L71/12Polyphenylene oxides
    • C08L71/123Polyphenylene oxides not modified by chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08L71/12Polyphenylene oxides

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)

Abstract

The present invention provides a resin composition containing (A) a polyphenylene ether resin and (B) a syndiotactic styrene polymer, characterized in that (1) the composition also contains (C) a high-impact styrene resin; and (2) the comopsition contains (C) in the amount of 90-10 parts by weight with respect to 10-90 parts by weight of (A) and (B) in the amount of 5 to 60 parts by weight with respect to a total of 40 to 95 parts by weight of (A) and (C).

Description

M432095 101年4月12日修正 的物理條件可能會不相同,因此使用單一種類的藥水對不同材 質的雜效果不同,若_效果太差可能無法使被磨除汽、機 7件上的文子圖案或冗號顯跡,腐钮效果太強可能使被 磨除機車之料上的文字、随或記號完全被雜(或腐 兹穿透零件)也無法顯跡。 【新型内容】 替換頁M432095 The physical conditions revised on April 12, 101 may be different, so the use of a single type of potion will have different effects on different materials. If the effect is too bad, it may not be possible to remove the steam pattern on the machine and the 7 items. Or the number is marked, and the effect of the rot button is too strong, so that the text, random mark on the material of the locomotive that has been worn away can be completely mixed (or the corrosion penetrates the part), and the mark cannot be displayed. [New content] Replace page

為解決此.問題,本創作提供一種物件之刻麵跡系統,該 物件之刻痕還原系統包括_硬度測量打,—磨平裝置結合在 硬度測量裝置-侧,-加錄置結合在硬度測量裝置一側,一 冷卻裝置結合在加餘置—側,—额L合在冷卻裝置一 側,一清洗裝置結合在腐蝕裝置一側。In order to solve this problem, this creation provides an object's facet tracking system. The object's notch reduction system includes _ hardness measurement,-a flattening device is combined with the hardness measurement device-side, and-plus recording is combined with hardness measurement On the device side, a cooling device is combined on the plus-side, the amount of L is combined on the cooling device side, and a cleaning device is combined on the corrosion device side.

本創作物件之細嶋統,整合式的緣使得使用 者能夠配合量_硬度值觸物件的#f,進—步決定物件所 =加熱溫度與腐靖需的藥水種類,如此_降低損壞物件 或腐蝕過度使刻痕無法顯跡的問題。 【實施方式】The detailed system of this creative object, the integrated edge allows the user to cooperate with the quantity_hardness value to touch #f of the object, and further determines the heating temperature of the object and the type of potion needed for decay, so _ to reduce damage to the object or corrosion The problem that the nicks cannot be seen too much. [Embodiment]

以下所有赋細於解釋本創作基本教導而已,圖式中 =成較_例之耕的數目、錢·、及尺寸之延 後相關之變化實施 二,。另外’在閱讀及了解本創作的敎導後配合特 變亦屬業界技能。 之精奴寸及尺寸比例之改 4 M432095 】0】年4月J2曰修正替換頁 在不同圖式中係以相同標號來標示相同或類似元件,·另外 請了解文尹諸如“第一,,、“第二”、“上下,,、 “前,,、“後,,、“内,,、“外,,、“端”、“部”、“段”、 長度、顺、”侧,’等等及類似用語係僅便於看圖者 參考圖中構造以及僅用於幫助描述本創作而已。 依據第-圖所示,本創作物件之刻痕顯跡系統包括一硬度 測量裝置2 2,該硬度測量裝置2 2係用來測量被磨除刻痕後 之-物件2 G的表面硬度,並且域所#測得狀硬度判斷製 造物件20的材質。 、 _第-_示’物件之刻痕顯跡系統進—步包括安裝在 硬度測讀置2 2 -側的-解打2 4,磨平裝置2 4可由 0 =如=持式砂輪機所構成。由於物件2 ◦被磨除的刻痕處表面 Γ處與贿落差過大,耻料奸2 4係要對將物件2 、面被磨除_痕處再磨平以獲得較為平整的表面。 旦 圖所示’物件之刻痕顯跡系統也包括結合在硬度 置2 6,加熱助係用來對 物件2 0表耐麵_痕處作局部的加熱,摊所需⑽产 硬度值關斷的材質‘ 獲之結果各刪賴原實驗所 依據弟一圖所示,物件 裝置2 6 冷卻裝X铺跡編包括結合在加熱 ’係將物件2 0表面被磨除的 M432095 替換頁 丄丁 4乃1乙y修正 刻痕處冷卻至常溫,冷卻穿 氽…一 據不同的材質特性採用 水冷或工冷蝴鳴件2卩較,使得物件2 〇 表面被磨除的刻痕處的結晶狀態改變而有利於以藥水顧。 據第®所不,物件之刻痕顯跡系統更包括結合在冷卻 裝置2 8 一側的一顧裝置3 〇,顧裝置3 〇係依據物件2 〇的材質加人對於物件2 〇材質具有適當顧速度的藥水,且 舰裝置3 0係在物件2 〇表面被磨除的刻痕處(已改變結晶All the following details are only used to explain the basic teaching of this creation. In the figure, the changes related to the number, money, and size of the farming that is a comparative example are implemented. In addition, it is also an industry skill to cooperate with special changes after reading and understanding the instructions of this creation. The change of the size and size ratio of the fine slave 4 M432095] 0] In April, J2 said that the replacement page was marked with the same reference numerals in different drawings to indicate the same or similar elements. Also, please understand that Wen Yin, such as "First, , "Second", "up and down,", "front ,,," back, "," inside, "," outside, "," end "," department "," paragraph ", length, forward, side, 'Etc. and similar terms are only for the convenience of the viewer to refer to the structure in the figure and are only used to help describe the creation. According to the figure-the notch marking system of the creation object includes a hardness measuring device 22, The hardness measuring device 22 is used to measure the surface hardness of the object 2 G after being scratched, and the hardness measured by the field # judges the material of the manufactured object 20. _ 第 -_ 示 'the moment of the object The trace system further includes: installed on the hardness measurement reading 2 2-side-unbundling 2 4, the flattening device 2 4 may be composed of 0 = such as = a holding grinder. Because the object 2 ◦ is being removed The gap between the surface of the score and the distance between Γ and the bribe is too large. The shame 2 and 4 are to remove the object 2 and the surface. In order to obtain a relatively flat surface, the 'marking system of the object' shown in the figure also includes a combination of a hardness setting of 2, 6 and a heating aid to locally heat the surface of the object's surface. It is necessary to produce the material with the hardness value cut off. The results obtained are based on the original figure shown in the figure. The object device 2 6 is cooled and installed with X-printing. M432095 Replacement sheet 丄 丁 411yY Correct the nicks to cool down to normal temperature, cooling through 氽 ... According to different material characteristics, water-cooled or industrial-cooled butterfly parts 2 are used to make the surface of the object 〇 ground. The crystalline state at the nick is changed, which is beneficial to medicinal solution. According to No. ®, the nick-marking system of the object further includes a gu device 3 〇 integrated on the cooling device 2 8 side, and the gu device 3 〇 is based on the object. The material of 2 〇 is added with a potion with proper speed for the material of 2 〇, and the ship device 30 is at the nick of the surface of the object 2 0 (the crystal has been changed)

狀態)塗上腐谢生的藥水,使得物件2 〇表面被磨除的刻痕處 被藥水腐蝕。(State) Coat the potion with rotten raw so that the scratches on the surface of the object 20 are worn away by the potion.

依據第-®所示,物件之刻痕顯跡系統包括結合在腐银裝 置2 ◦一側的—清洗裝置3 2,清洗裝置3 2係在物件2⑽ -疋時間的雜之後彻清水續腐鋪水具有巾和效果的 化子藥#U洗’使得物件2 〇表面被磨除_痕處不會繼續腐 蝕’如此可以肉眼觀察物件2 〇表面被磨除的.刻痕處表示文 字、數字或圖案的刻痕是否有顯示,若物件2 〇表面被磨除的 刻痕處未文字、數字鱗可再重複將物件2 Q送入腐钱裝 置3 0内再次腐钱後再以清洗裝置3 2清洗,如此反覆至物件 2 0表面被磨除的刻痕處表示文字、數字或圖案顯跡。 為了方便說明,本創作係假設一種已知的狀態說明物件2 〇表面的文子、數字或圖案被磨除’而物件.2 〇利用硬度測量 裝置2 2測得知硬度值為8 〇 Η B,藉由所獲之硬度值及物件 2 0的外觀、質感等特性综合判斷物件2 〇是由紹合金材質所 6 M432095 • · 101年4月12日修正替換頁 / 製成,而物件2 0的厚度為2·。首先利用磨平裝置2 4將 • 物件20表面被磨除的刻痕處磨平’再將物件20表面被磨除 _痕處加熱至9G<後,_冷卻裝置28以水冷方式使。 物件2 0冷卻至常溫,而腐钱裝置3 〇則在物件2 〇被磨除的 職處塗上氫氧 (NaQH)躲,使物件2 Q表面被氯氧 化_#’最後麵清洗裝置3 2將錄錢藥水與物件2 〇 2腐錢_質去除後就可使物件2 Q上被磨除用來顯示文 • 子、數字或圖案的刻痕顯跡,此外若顯跡的刻痕以肉眼觀察仍 ' 無法辨識者,也能狗過諸如顯微鏡觀察顯跡後的刻痕,藉以辨 識這些刻痕所表示的文字‘、數字或圖案。 々本創作的物品刻痕還原系統除了應用在》丸、機車或諸如鐵 鱗零件上触磨_刻麵跡之外,也能顧在其它地方, .2如腳踏車的金屬或非金屬零件(塑膠)上的刻痕被磨除時也 飞 月匕用本創作的物件之物品還原系統使被磨除的刻痕顯跡。 鲁 &本創作物件之刻痕顯跡系統,利用整合式的系統使得使用 .•句里測的硬度值判斷物件的材質,進一步決定物件所 需的加熱溫度與顧所需的藥水種類,如此能夠降低損壞物件 或顧過度使刻痕無法顯跡的問題。 由於說明書揭示的本創作可在未麟賴作精神或大體 力=、形絲實施,且這些特定财的—些形式已經 被丸出,所以,說蚩 一 ° 句揭不的實施例應視為舉例說明而非限 '本創作的範圍是由所附的申請專利範圍界定 ’而不是由上 7 M432095 101年3月20曰修正替換頁 述說明所界定,對於落入申請專利範圍的均等意義與範圍的所 有改變仍將包含在其範圍之内。 M432095 101年3月20曰修正替換頁 % 8 M452095 101年3月20日修正替換頁 【圖式簡單說明】 第一圖係本創作刻痕還原系統的系統示意圖。 【主要元件符號說明】 20物件 22硬度測量裝置 24磨平裝置 26加熱裝置 28冷卻裝置 30腐蝕裝置 3 2清洗裝置 9 M432095 公告本 101年3月20曰修正替換頁 新型專說明·卜’年岭月乂日According to No.-®, the object scoring system includes a silver rot device 2 ◦ one side—a cleaning device 3 2 which is cleaned after the object 2⑽-⑽ The water has a towel and the effect of the chemical medicine #Uwash 'makes the surface of the object 2 〇 worn away _ marks will not continue to corrode' so that the surface of the object 2 〇 can be observed by the naked eye. The nicks indicate words, numbers or Whether the pattern's nicks are displayed. If the surface of the object 2 has no text or digital scales on the surface, the object 2 Q can be repeatedly sent to the money rot device 3 0 and the money can be rotten again, and then the cleaning device 3 2 Wash, so repeatedly until the scratches on the surface of the object 20 are abraded to indicate the marked characters, numbers or patterns. For the convenience of explanation, this creation assumes a known state to explain that the surface of the object 2 〇 the surface, the number or the pattern is worn away and the object. 2 〇 Use the hardness measuring device 22 2 to determine the hardness value of 8 〇 B, Based on the obtained hardness value and the appearance, texture and other characteristics of the object 20, the object 2 〇 was judged by Shao Alloy Material Institute 6 M432095 • · April 12, 101 revised replacement page / made, and the object 2 0 The thickness is 2 ·. First use the flattening device 24 to flatten the nicks of the surface of the object 20 ', and then grind the surface of the article 20. After the nicks are heated to 9G, the cooling device 28 is water-cooled. The object 20 is cooled to normal temperature, and the money rot device 3 〇 is coated with hydrogen (NaQH) to hide the position of the object 2 〇, so that the surface of the object 2 Q is oxidized by chlorine. After removing the money-recording potion and object 2 〇2 rotten money_ After removing the quality, the object 2 Q can be worn away to display the marks of the text, numbers, or patterns. In addition, if the marked marks are visible to the naked eye Observation is still 'unrecognizable', and can also be used to observe the nicks after visible marks such as a microscope to identify the words, numbers or patterns represented by these nicks. The article scoring reduction system created by 々 Ben is not only used in the "maru, locomotives, or parts such as iron scales", but also can be used in other places. .2 Such as bicycle metal or non-metal parts (plastic When the nicks on) were abraded, Feiyue Dagger used the item restoration system of the original creation to make the abraded nicks visible. Lu & The scoring system of the created object uses an integrated system to make use of the hardness value measured in the sentence to determine the material of the object, and further determine the heating temperature required for the object and the type of medicine required. It can reduce the problem of damaging the object or excessively making the nick not visible. Since the creation disclosed in the specification can be implemented in Wei Linlai's spiritual or physical strength, and the form of these special properties, some forms of these specific properties have been shot out. Therefore, the example that cannot be explained by the sentence should be regarded as Illustrate, but not limit, the scope of this creation is defined by the scope of the attached patent application, not by the above 7 M432095 March 20, 2011, Amendment and Replacement Page Description, which has the same meaning as falling within the scope of patent application. All changes in scope will still be included in its scope. M432095 Modified replacement page on March 20, 101% 8 M452095 Modified replacement page on March 20, 101 [Brief description of the diagram] The first diagram is a system diagram of the original scoring reduction system. [Description of symbols of main components] 20 objects 22 hardness measuring device 24 grinding device 26 heating device 28 cooling device 30 corrosion device 3 2 cleaning device 9 M432095 Announcement March 20, 2011 Revised replacement page new special description Month and Day

(本說明書格式、順序,請勿任意更動,※記號部分請勿填寫)一 ※申請案號:州2^0|ί^Γ| ^PC 分類:7/知(2〇〇6.01j ※申請曰:π。、/〇、之心 饮八物:.,, 一、 新型名稱:(中文/英文) 物件之刻痕顯跡系統 二、 中文新型摘要: 本創作係關於一種物件之刻痕顯跡系統,該刻痕顯跡系統包 括一硬度測量裝置,結合在硬度測量裝置一侧的一磨平裝置,結 ♦ 合在硬度測量裝置-側的-加熱裝置,結合在加熱裝置一側的一 冷卻襄置’結合在冷卻裝置-侧的—腐歸置,以及結合在腐钱 裝置一側的一清洗裝置,使物件可配合硬度測量裝置所測得的硬 度值判斷製造材質,進一步依據製造材質決定所需的加熱溫度與 腐蝕藥水的種類’以達到最佳的顯跡效果。 三、英文新型摘要: •六、申請專利範圍: 料咖咐替換頁 -1硬;之刻痕顯跡系統,包括: 一硬度測量裝置(2 2); —f :ί ί ((U )) ’結合在硬度測量裝置(2 2 ) 一側; 2 3 2 )結合在腐#裝置(3 0 ) -側ό 其中硬制系統, 表面硬度,磨平萝罟r9/f不,則里一物件(20)的 面的被磨除的刻痕處進行磨平處理被2上)件表 整狀’加熱裝置(2 6 ) ’係丄 磨除, 加熱後的物件(2 〇 )冷卻至常溫,二上8 ):=來將 冷卻後之齡(2 ο)獅除_痕處來將 水,以被磨除的刻痕處表面,清洗裝(置(3 刻i顯跡件(2 〇)表面之腐_水’以使被磨除的 10 M432095 * . i七、圖式 101年3月20日修正替換頁(Please do not change the format and order of this manual. ※ Please do not fill in the marked part.) 1. ※ Application number: State 2 ^ 0 | ί ^ Γ | ^ PC Category: 7 / 知 (200〇6.01j ※ Application said : Π., / 〇, the heart drinks eight things:. ,, I. New name: (Chinese / English) Marking system of objects II. Abstract of Chinese new style: This creation is about the marking of an object System, the scoring system includes a hardness measuring device combined with a flattening device on the side of the hardness measuring device combined with a heating device on the hardness measuring device side and a cooling device on the heating device side The combination of the “setting” on the cooling device side and the “rotating” setting, and a cleaning device on the side of the money rot device, enable the object to determine the manufacturing material with the hardness value measured by the hardness measuring device, and further determine based on the manufacturing material The required heating temperature and the type of corrosive potion 'to achieve the best visible effect. 3. New English abstracts: • Sixth, the scope of patent application: material replacement command -1 hard; the notch display system, including : A hardness measuring device (2 2); —f: ί ί ((U)) 'combined with the side of the hardness measuring device (2 2); 2 3 2) combined with the rot #device (3 0)-side, where the hardened system, the surface If the hardness is not flattened, r9 / f is not smoothed, then the nicks of the surface of the inner object (20) are smoothed and polished. The surface is shaped as the 'heating device (2 6)' system. Grinding, the heated object (20) is cooled to normal temperature, two times 8): = to cool the age (2 ο) lion to remove the _ marks to water, to the surface of the nicks to be abraded, Cleaning equipment (set (3 engraved _ water on the surface of the visible piece (2)) to remove the 10 M432095 *. I. VII, drawing, revised on March 20, 2011

寸<N CNICNl OCJ≪ N CNICNl OCJ

% 11 M432095 101年3月20日修正替換頁 四、指定代表圖: (一) 本案指定代表圖為:第(一)圖。 (二) 本代表圖之元件符號簡單說明: 20物件 22硬度測量裝置 24磨平裝置 26加熱裝置 28冷卻裝置 30腐蝕裝置 3 2清洗裝置% 11 M432095 Revised replacement page on March 20, 101 4. Designated Representative Map: (1) The designated representative map in this case is: (1). (II) Brief description of the component symbols of this representative picture: 20 objects 22 hardness measuring device 24 flat device 26 heating device 28 cooling device 30 corrosion device 3 2 cleaning device

TW87119729A 1997-11-27 1998-11-27 Compositions of polyphenylene ether resin and syndiotactic polystyrene TW432095B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP34084797A JP4364319B2 (en) 1997-11-27 1997-11-27 Polyphenylene ether resin composition

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Publication Number Publication Date
TW432095B true TW432095B (en) 2001-05-01

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JP4042195B2 (en) * 1997-12-19 2008-02-06 住友化学株式会社 Polyphenylene ether resin composition and method for producing the same
DE19941444A1 (en) * 1999-08-30 2001-03-01 Basf Ag Flame-retardant thermoplastic molding compounds
JP4629846B2 (en) * 2000-10-05 2011-02-09 出光興産株式会社 Method for producing transparent styrene resin molded body and transparent styrene resin molded body
JP2002371679A (en) * 2001-06-14 2002-12-26 Fukuvi Chem Ind Co Ltd Void-including resin molding for building
US6894102B2 (en) 2002-05-20 2005-05-17 General Electric Syndiotactic polystyrene blends
JP4007877B2 (en) 2002-08-07 2007-11-14 日本ジーイープラスチックス株式会社 Resin composition for wire and cable coating materials
JP2004161929A (en) * 2002-11-14 2004-06-10 Ge Plastics Japan Ltd Resin composition for cladding material of wire and cable
US20070100070A1 (en) * 2005-11-02 2007-05-03 Todt Michael L Poly(arylene ether) blend and method of making same
CN111909502B (en) * 2020-06-30 2022-05-17 会通新材料股份有限公司 PPO-sPS composition and preparation method thereof
CN114410099B (en) * 2022-01-10 2023-10-20 上海金山锦湖日丽塑料有限公司 Transparent flame-retardant MPPO resin composition and preparation method thereof

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AU628651B2 (en) * 1989-10-13 1992-09-17 Idemitsu Kosan Co. Ltd Styrene polymer composition

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