TW418094B - Perfumed liquid household cleaning fabric treatment and deodorizing compositions packaged in polyethylene bottles modified to preserve perfume integrity - Google Patents

Abstract

Bottled aqueous household cleaning, fabric treatment and deodorizing compositions comprising surfactant, and a perfume which contains a substantial proportion of hydrophobic perfume ingredients having a ClogP of greater than 3. The bottles are made of high density polyethylene wherein the bottles have a continuous inner surface layer of nylon, polyetheneterephthalate or fluorinated polyethylene in order to prevent migration into and/or transmission through the high density polyethylene of the hydrophobic perfume ingredients.

Description

4 18 0 9 4 a? __——- Β7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (1) Field of the invention The present invention relates to stable water-containing aromatic household cleaning and deodorizing composition 'its Contains surfactants and fragrances. This perfume is a dissolved or emulsified state and contains a substantial proportion of a hydrophobic perfume material to impart a clean, desirable odor to the substrate on which the product is to be applied. This composition is packaged in a polyethylene bottle, where the interior of the bottle has been modified to prevent unwanted changes in the fragrance 'This change is due to the hydrophobic ingredient being absorbed and / or passed into and / or via polyethylene during storage caused. Background: Xian believes that consumers will like household cleaning, fabric treatment and deodorizing products. It will give the surface treated with the product a pleasant odor. It has been found that in perfume formulations for products, the use of a substantial proportion of hydrophobic perfume materials in the perfume is satisfactory = for convenience and elasticity during use, it is highly desirable to make household cleansing and deodorization and fabrics The treatment composition becomes liquid and is packaged in a plastic bottle. For price considerations, polyethylene is an advantageous material for the manufacture of bottles for such compositions. However, it has been found that hydrophobic perfume materials may be in the liquid state due to inhalation and / or transmission of polyethylene during the storage of the composition. The tendency to lose in the product. This results in a change in the odor characteristics of the composition and reduces the aroma advantage, which would otherwise be obtained on the surface treated with the composition. All documents identified herein are incorporated herein by reference and all percentages and ratios are by weight unless otherwise specified. I 1--Film--install --- !! Order ·! • Han (Please read the precautions on the back before / ¾ this page) This paper size applies to Chinese national standards (CNS> A4 size (210 X 297 mm) ) A7 B7 A member of the Zou Intellectual Property Bureau and a consumer cooperative print 10% of the active agent of the odorous product of the present invention, and it is selected from the surface layer of abc. Detailed description of the invention According to the present invention, water and household cleanliness, polyethylene (Η Those It has about 3. This is obviously because the aromatic bottles containing real quality spices do not like the plastic of plastic containers. Now the bottles can be essentially 1. Description of the invention (2) Summary: Invention about a bottle containing water Household cleaning, fabric treatment or addition, in addition to water, it includes 0.01% to 50% surface and 0.003% to 5% fragrance, wherein the fragrance contains at least one or more having a Clog P greater than 3 In the hydrophobic perfume ingredient of the product, the product is stored in a high-density polyethylene bottle, and the bottle has a continuous inner material of a group consisting of nylon) polyethylene terephthalate and fluorinated high-density polyethylene Has been found to include water, surfactants and perfumes When the processing or deodorizing composition is packaged in a general high-density DPE bottle, some hydrophobic perfume ingredients (that is, those with a larger clop P) will tend to be lost from the perfume and / or be polymerized. Caused by vinyl bottle material. When such perfume ingredients are used in perfumes, this loss significantly alters the perfume characteristics. Polyethylene terephthalate (ρ ET) or glass has such a destructive effect on perfumes. However, consumers are more than glass, and polyethylene is less expensive than PET. Finding: Eliminating the loss of these hydrophobic perfume ingredients by using HDPE with a modified inner surface. This paper size is applicable to Chinese National Standard (CNS) A4 size coffee x 297 public love ---------------- installation -1 Ι Ι 1 order ·--(Please read the note on the back first Matters are not included on this page) 4 1 8 1. ^ 4 18 0 9 4 A7 _______ B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (3) The present invention is a bottled water-containing household cleaner, fabric treatment Or deodorizing composition, which, in addition to water, includes 0 to 0% to 50% surfactant and 0.003% to 5% fragrance, wherein the fragrance contains at least 10% of one or more compounds having a Clog P greater than 3 A hydrophobic perfume ingredient, and the composition is present in a high-density polyethylene bottle, wherein the bottle has a group selected from the group consisting of a) nylon b) polyethylene terephthalate and c) fluorinated high-density polyethylene Continuous inner facing of the material. A. Surfactant The surfactant suitable for use in the composition of the present invention may be any suitable for domestic cleaning, fabric treatment or deodorizing composition. These include anionic, nonionic, cationic, amphoteric, and zwitterionic detergents. Examples of the anionic detergent include C 8 -C 2 2 alkyl sulfates, alkyl benzene sulfonates having 9 to 15 carbon atoms in the alkyl group, and 8-2 2 carbon atoms in the alkyl group. Alkyl oxyethylene ether sulfates and C 8 and (: 22 fatty acid soaps in the chain and having 1 to 30 ethylene oxide. Examples of nonionic surfactants include 3 to 30 moles of ethylene oxide and 8 to Condensates of aliphatic alcohols of 2 2 carbon atoms, condensates of 5 to 30 moles of ethylene oxide and alkylphenols (where the alkyl group contains 9 to 15 carbon atoms), and (: 8 and C 2 2 alkyl Dimethylamine oxide. Ampholytic and zwitterionic surfaces (please read the notes on the back before this page) This paper is fully compliant with China National Standard (CNS) A4 (210 X 297 mm) 41 8 094 A7 _ B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs ^ V. Description of Invention (4) Examples of active agents are found in US Patent 3,9266666666 666666666666669,678, Laughlin et al, published on December 30, 1975, published on Examples of cationic surfactants in column 19, line 38 to column 22, line 4 to 8 are those having at least one 8-2 A tetraalkylquaternary ammonium salt of an atomic alkyl chain, where other alkyl groups may contain 1 to 2 2 carbon atoms and wherein the anionic counterion is halogen, ethyl sulfate or methyl sulfate. In this article, 'household 淸Cleaning and fabric treatment and the term 'odor composition' include fabric cleaning, soft and new composition, and flooring, carpet and other household surface treatment compositions, where it is desired to clean and / or impart a surface Beneficial treatment or properties. Depending on the intended use of the product, use surfactants ranging from 0.01% to 50%. Typical levels are 0.1% to 30% and 5% to 20%. Additional surfactants Disclosed in U.S. Patent 3,6 6,4,96,1, Norris, published on May 23, 1972. B. Fragrance The composition of the present invention contains from 0.03% to 5%, advantageously from 0 to 003% to 1% and more advantageously 0.05% to 0.2% fragrance. The fragrance contains a substantial proportion of fragrance ingredients with a Clog P of at least 3 (at least about 10%, advantageously at least 50%, more advantageously At least 70%). Log P for many fragrance ingredients has been reported; for example, can be obtained from Daylight Chemical Information System, In c. (Day light CIS), Irvine, California, Pomona 92 database and citations to the original documents are very easy — II ------ i IIH! II-[III ^ r Please read the note on the back first Matters again. This page is larger than the Chinese paper standard (CNS) A4 (210x297 mm) 41 A7 B7 5. The invention is described in more details (5). However, 'log P' is very commonly borrowed from the Pamona Med Chem / Daylight ^ CLOGP " Project 'version 4.22 from Biobyte Corporation, Charemont, California to calculate. "This project also displays 10 gp of experimental" when they Available in the Pomona 92 database. The calculation of iOg (ciOg P) is determined by the study of Hansch and Leo (cf ,, A. Leo, in Comprehensive Medicinal Chemistry, Vol. 4, C. Hansch ^. G. Sammens. JB Taylor and CARamsden, Eds., P. 295, Pergamon Press, 1990, incorporated herein by reference). This snippet is based on the chemical structure of each perfume ingredient, considering the number and form of atoms, atomic connectivity and chemical bonds. In selecting the perfume ingredients useful in the present invention, it is advantageous to use Clog Plog (which is the most reliable and widely used estimate of this physicochemical property), rather than self-log P experiments. The following table contains examples of perfume ingredients (which have at least 3 clog P, which are used in the present invention) ------------ --- (Please read the precautions on the back before (For this page). '-Embroidery-Printed by the Consumers' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper is printed in accordance with China National Standard (CNS) A4 (210 * 297 g) 4 1 8 Μ Α7 Β7 Ministry of Economic Affairs Wisdom Description of invention printed by the Consumer Cooperative of the Property Bureau (6) Table 1 Ingredients C102 Lemongrass 3.25 Vertenex 4.06 Terpine acetate 3.58 Nigeryl acetate 3,72 Diphenylmethane 4.06 Lilial (P, T.Bucinal) 3.86 Hexylcinnamaldehyde 4.85 Cedar Acetate 5.48 Tonalid 6.25 d-Ninene 4.35 Tetrahydroalcohol 3.52 Dihydrogerenol 3.03 Benzyl salicylate 4.21 T Monomethylionone 4.02 Hexenyl-salicylate 4.61 Hexyl cinnamon Aldehyde 4.85 Pheniolide 5.98 Phenylethylphenylacetate 3.77 Paracetamol 4.0 7 a ~ Μ 4.18 Isononyl alcohol 3.08 {Please read the precautions on the back first, '" this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 41 8 ^ a? B7 V. Description of the invention (7) C. Optional ingredients In addition to surfactants and fragrances, the water-containing detergent, fabric treatment and deodorant composition of the present invention may be contained in such a composition. Discovered ~ general adjuvant. These include components (such as phosphate, citrate, polycarboxylate, silicate, etc.), soil suspending agents (such as carboxymethyl cellulose), and antibacterial agents (such as 〇7 <: 1〇1 ^ 11 < ^ 116, biguanide, etc.), hydrotrope (such as sodium cumene dilute salt, propylene glycol), enzymes (such as protease) and polar solvents (such as ethanol, ethylene glycol + monobutyl ether). In addition to perfume ingredients having a Clog P greater than 3, perfumes may contain perfume ingredients having a Clog P less than 3. Examples of such ingredients are shown in Table 2. The amount of fragrance ingredients with less than 3 Clog P can reach 90% of the fragrance in this article »-— IJIIIIII1 — — — 1111111 — — — — — — — — {Please read the notes on the back before this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs? The paper size of the cloth is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) -1U-Member of the Intellectual Property Bureau of the Ministry of Economic Affairs x Consumption Cooperation Printed A7 B7 Invention Description (8) Table 2 Ingredients Clog Amyl Acetate 2.30 Anise Aldehyde 1.7B benzyl acetate 1.96 cinnamyl alcohol 1.41 eucalyptol 2.76 citral 2.95 ethyl benzoate 2.64 camphor gum 2.18 dimethylbenzyl methanol 1.89 eugenol 2.40 hexyl acetate 2.83 isoamyl alcohol 1.22 methyl alcohol 2.58 methylpentyl Ketone 1.91 Nerolidol 2.77 P-cresol 1.97 Phenylethyl alcohol 2.13 In this article, a favorable composition that has a particularly good deodorizing effect on surfaces that have been treated with the composition (such as fabrics, carpets, Counter tops, etc.) Contains cyclodextrin. In addition to the perfume in the composition providing the desired odor to the treated surface, cyclodextrin provides the odor to the treated surface '---------- ---! 111 Order-- ------ ί Please read the notes on the back before / i)) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -11-41 8 094 A7 Intellectual Property of the Ministry of Economic Affairs Printed by the Bureau ’s Consumer Cooperatives_ B7___ V. Description of the invention (9) Those existing in sweat, urea, etc. have absorption power. Advantageously, the cyclodextrin used in the present invention is highly water-soluble, such as α —Cyclodextrin and / or its derivatives, r-cyclodextrin and / or its derivatives, derivatized ~ cyclodextrin, and / or mixtures thereof. Derivatives of cyclodextrin mainly include certain OH groups of which Molecules that are converted to radicals. Cyclodextrin derivatives include, such as those with short-chain alkyl groups such as methylated cyclodextrin and ethylated cyclodextrin, where R is methyl or ethyl; those with hydroxyalkyl substitution Such as hydroxypropylcyclodextrin and / or hydroxyethylcyclodextrin, where R is —CH2-CH (OH) —CH3 or —CH2CH2〇H ; Branched cyclodextrin, such as maltoose-bonded cyclodextrin: cationic cyclodextrin, such as those containing 2-hydroxy-3- (2-methylamino) propyl ether, where R is at low pH is Cationic C Η 2-CH (OH) — CH2 — N CCH3) 2; Quaternary ammonium such as 2-hydroxy-3-(trimethylamino) propyl ether chloride, where R is CH2-CH (OH)-CH2 -N + CCH3) 3C 1 '; anionic cyclodextrin such as carboxymethyl cyclodextrin, cyclodextrin sulfate, and cyclodextrin succinate; amphoteric cyclodextrin such as carboxymethyl / quaternary ammonium cyclodextrin; Dextrin, where at least one glucopyranose unit has a 3-6—anhydromaltosyl structure, such as a single 3-6—anhydrocyclodextrin, such as " Optimal Performances with Minimal Chemical Modification of Cyclodextrins ^, F, Diedaini- Pilard and B, Perly, The Internati na 1 C yc 1 odextrin S ymposium A bstracts, April 19, 1994, disclosed on page 49, which reference is incorporated herein by reference; and mixtures thereof. Other cyclodextrin derivatives are disclosed in U.S. Patent 3,426, Cm, Parmerter --I--I ----- Pack- --------- Order! 1! 11 * Green (Please read the notes on the back first Reprint this page > This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 Gongchu) -ΊZ-418094 Α7 Β7 5. Description of the invention (1〇) et al., February 1969 Published on the 4th; 3,453,257; 3,453,258; 3,453,259; and 3,453,269, all in the name of Pamerteretal; and all announced on July 1, 1969; 3,459,73 1,0 ^ 11 ^ 13 6131., August 5, 1969 ; 3,553,191, Parmerter ei al., Published on January 5, 1971; 3,565,887, Parmerteret al., Published on February 23, 1971; 4,535,152, Szejili et al., Published on August 13, 1985; 4,616,008, 114 & 16131., published on October 7, 986; 4,678,598, Ogino et al., Published on July 7, 1987; 4,638,058, Brandt et al., Published on January 20, 1987; and 4,746,734, Tsuchiyama et al., published May 24, 988; all of these patents are incorporated herein by reference. Highly water-soluble cyclodextrins are those that have at least room temperature Water soluble in 10 g / 100 ml of water, advantageously at least about 20 g / 100 ml of water at room temperature, more favorably water soluble in at least about 25 g / 100 ml of water The availability of dissolved, uncomplexed cyclodextrin is necessary for effective and adequate odor control. When deposited on surfaces, especially on fabrics, dissolved water-soluble cyclodextrin is more soluble than non-water soluble Cyclodextrins may have more sufficient odor control efficacy. Examples of advantageous water-soluble cyclodextrin derivatives suitable for use herein are cyclodextrin, methylated cyclodextrin, methylated / 3-cyclodextrin Ethyl, hydroxyethyl / 3-cyclodextrin, and hydroxypropylcyclodextrin. Hydroxyalkylcyclodextrin derivatives advantageously have substitutions of from about 1 to about 14, and more advantageously from about 1.5 to about 7. Degree, where the total number of OR groups in each cyclodextrin is defined as the degree of substitution. Methylated cyclodextrin derivatives typically have a degree of substitution of from about 1 to about 18, advantageously from about 3 to about 16. The known Methylation; δ-cyclodextrin is 柒 _2, 6-dioxo-methyl-one-cyclodextrin. (Usually known as ------------- floc-- (Please read the note on the back first Matters on this page).-Chuo. Printed on paper scales of the Intellectual Property Bureau of the Ministry of Economic Affairs, Behr Consumer Cooperative, this paper applies Chinese National Standard (CNS) A4 (210 X 297 mm) 418094 A7 _B7_____ 5. Description of the invention (11 > DIMEB), wherein each glucose unit has about 2 methyl groups and the degree of substitution is about 14. An advantageous' more commercially available schenification; 5-cyclodextrin is random methylation / 3-cyclodextrin (commonly known as RAMEB), which has different degrees of substitution, usually about 12.6 »RAMEB is more advantageous than D IMEB because D IMEB affects more than the surface activity of favorable surfactants = favorable cyclodextrin can be obtained from sources such as Cerestar USA, Inc. and Wacker Chemicals (US A), Inc. . It is also advantageous to use a mixture of cyclodextrin. The amount of cyclodextrin used in the composition ranges from 0.01% to about 20%. If the composition is intended to be diluted before use, it will contain 3% to 20%, advantageously 5% to 10%. Compositions that are intended to be used in a dilute form will usually contain from 0.01% to 5%, advantageously from 0.1% to 3%, more advantageously from 0.5% to 2%. When formulating a composition with a cyclodextrin, it is desirable to use a surfactant, which has particularly good compatibility with cyclodextrin. A suitable surfactant compatible with cyclodextrin can be easily identified by the fact that cyclodextrin has no effect on the surface tension provided by the surfactant. This is achieved by: determining the surface tension (unit d y n e / cm 2) of the aqueous solution of the surfactant in the presence and absence of about 1% of the specific cyclodextrin in the solution. The aqueous solution contains surfactants at concentrations of about 0.5%, 0.1%, 0.01%, and 0.005%. Cyclodextrin can affect the surface activity of a surfactant by increasing the surface tension of the surfactant solution. If the surface tension at a specific concentration in water and II in a 1% cyclodextrin solution --- IHIHI-Φ ^ ·! Ιιιιιι ^^ ΙΙ!-M. (Please read the "Precautions on the back and then / .¾ This page) This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm)--4-Printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs A7 ___B7__ 5. Description of the invention (12> Same surface activity If the surface tension of the agent is more than about 10%, it indicates that there is a strong interaction between the surfactant and the cyclodextrin. In this paper, a favorable surfactant should have a surface tension in the aqueous solution, which is equal to that containing 1 % Cyclodextrin has a difference (reduction) of less than about 10%, advantageously less than about 5%, and more advantageously less than about 1% (reduction). (A) Block copolymer and cyclodextrin Non-limiting examples of finely compatible nonionic surfactants include block copolymers of ethylene oxide and propylene oxide. Suitable block polyoxyethylene-polyoxypropylene polymerized surfactants (which are compatible with most Dextrin compatible) including those based on ethylene glycol, propylene glycol, glycerin Methyl alcohol propane and ethylenediamine are the starting reactive hydrogen compounds. It is made by the sequential ethoxylation and propoxylation of the starting compound with a single reactive hydrogen atom such as a C 12-18 aliphatic alcohol. Polymeric compounds are generally not compatible with cyclodextrin. Certain block polymer surfactant compounds named Pluronic and Tetronic® manufactured by BASF-Wyandotte Corp., Wyandotte, Michigan are readily available. This type is related to cyclodextrin Non-limiting examples of compatible surfactants include: Pluronic surfactants having the general formula Η (EO) n (P0) m (E〇) nH2 Pluronic surfactants, where EO is an oxyethylene group, PO is an propylene oxide group, and η And m is the number of the average number of groups in the surfactant. Typical examples of Pluronic surfactants compatible with cyclodextrin are: -------------- Hua ·! -OJ *! -Han (Please read the precautions on the back, then: '" This page) This paper size applies to China National Standard (CNS) A4 (210 X 297 public love) _ 15 " 7 41809 ^ A7 B7 V. Description of the invention (13) Name average MW average average L-101 3,800 4 59 L-81 2,750 3 42 L-44 2,200 1 0 23 L-43 1,850 6 22 F-38 4,700 43 16 P-84 4,200 19 43, and mixtures thereof Tetronic surfactants having the general formula: H (EO) n (PO gas / (P0) post 0) ηΗ

NCH2CH2N

Η (ΕΟ) η (ΡΟ) πι V ((PO) m (EO) nH where EO, PO, n and m have the same meaning as above.) A typical example of a Tetronic surfactant compatible with cyclodextrin is: I -------- Equipped ·-! 丨 — 対 ·!-Line (please read the precautions on the back first and then this page) Employees of Intellectual Property Bureau of the Ministry of Economic Affairs Consumer Cooperation Du printed name average MW average average 901 4,700 3 18 908 25,000 114 22, and its mixtures Inverse Pluronic and Teironic surfactants have the following general formula: -Id-This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) A7 B7 Ministry of Economic Affairs Printed by the Intellectual Property Bureau's Consumer Cooperatives V. Invention Description (14) Η (ΡΟ) π (ΕΟ) '/ (£ 〇〇〇)

/ NCH2CH2N

H (PO) n (EO) ni \ (EO) m (PO) riH where EO, Po, η and m have the same meaning as above. Typical examples of inverse Pluronic and inverse Tetronic surfactants compatible with cyclodextrin are: Inverse Pluronic surfactant: Name average MW average average 10R5 1,950 8 22 25R1 2,700 21 6 Inverse Tetronic surfactant name average MW average average 130R2 7,740 9 26 70R2 3,870 4 13 and mixtures thereof. (B) Siloxane surfactants. A favorable class of nonionic surfactants compatible with cyclodextrin is alkylene oxide polysiloxy, which has a dimethyl ether. Polysilane hydrophobic part and one or more and hydrophilic polyalkenyl side chains and have the following general formula: R1— < CH3) 2SiO — [(CH3) 2SiO], — [(^ XR ^ SiOjb-Si ( CH3) 2-R 'where a ten b is about 1 to about 50, advantageously about 3 to about 30, — — — — — — — — — — — — — — — 1 — — — — — — — — — (Please read the notes on the back first and then mine for this page> This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm)-Ί 广 · 41809 ^ A7 B7 V. Description of the invention (more advantageously about 10 to about 2 5 and each is the same or different, and In the group consisting of free methyl groups and poly (ethylene oxide / propylene oxide) copolymer groups having the general formula: ♦ ·.-(CH2) n 〇 (〇2 H4 0) c (C3 H6 〇) d r2 and At least one R1 is a poly (ethylene oxide / propylene oxide) copolymer group 'and η in 萁 is 3 or 4' advantageously 3; all C (for all polyoxyalkylene side groups) have 1 to about 1 〇〇, advantageously about 6 to about 100; all d is 0 to about 14, advantageously 0 to about 3: and more advantageously d is 0; all c + d has about 5 to About 1 50, advantageously about 9 to about 100, and each R2 is the same or different and is selected from the group consisting of hydrogen, an alkyl group having 1 to 4 carbon atoms, and ethynyl, advantageously hydrogen and methyl Examples of this type of surfactant are Silwet® surfactants, which are available from Osi Specialties, Inc., Danbury, Connecticut. Representative Silwet surfactants are as follows. --------- ----- Equipment --- < Please read the notes on the back φν, this page) tr: -Embroidery _ Printed on the paper by the Shelley Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, China Paper Standards (CNS> A4 Case (210 ^ 297 public love) 4 1 Β υ ^ ^ 4 1 3 0 9 4 Α7 __________ V. Description of invention (16) Name average MW average average total L-7608 600 1 9 L-7607 1,000 2 17 L-77 600 1 9 L-7605 6,000 20 99 L-7604 4,000 21 53 L-7600 4,000 11 68 L-7657 5,000 20 76 L-7602 3,000 20 29 (Please read the notes on the back first and then mine for this page) Ministry of Economy Member of the Intellectual Property Bureau, Consumer Cooperative, printed polyalkyleneoxy (R1) with a molecular weight of less than or equal to about 1 0,0 0 0 »Advantageously, the molecular weight of polyalkyleneoxy is less than or equal to about 8,000 And most advantageously in the range of about 300 to about 5,000. Therefore, the 値 of c and d may be those which will provide molecular weights in this range. However, the number of ethoxylated units (C2H2O ~) in the polyether chain (R1) must be sufficient to make the polyoxyalkylene polysiloxane water-dispersible or water-soluble. If the propyleneoxy groups are present in the polyalkyleneoxy chain, they may be randomly distributed in the chain or present as blocks. Advantageous Silwet surfactants are L-7600, L-7602, L-7604 'L-7605 and mixtures thereof. In addition to surface activity, polyoxyalkylene polysiloxanes can also provide other benefits such as antistatic benefits, lubricity and softness to fabrics. The preparation of polyoxyalkylene polysiloxanes is well known in the art. The size of this paper applies Chinese national standard (CNS > A4 size (210x 297). Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, printed A7 B7. 5. Description of the invention (17) The polyoxyalkylene polysiloxane invented can be manufactured in accordance with the United States. Prepared by the procedures outlined in patents 3, 299, 11 and 12, which are incorporated herein by reference. Typically, the polyoxyalkylene polysiloxane of the surfactant blends of the present invention is susceptible to hydrogenation. Siloxane (i.e., siloxane containing silicon-bonded hydrogen) and alkoxy or hydroxyl-terminated polyoxyalkylene alkenyl ethers (such as vinyl, allyl, or methallyl ether) ). The reaction conditions used in this type of addition reaction are well known in the art and usually cover the presence of a platinum catalyst ('such as chloroplatinic acid) and a solvent (such as toluene). The reactants are heated under heat (eg, at a temperature of about 85eC to 110 ° C). (C) Non-limiting example of an anionic surfactant compatible with cyclodextrin is an alkyldiphenyl Oxide disulfonate, which has the following general formula:

Where R is alkyl. Examples of surfactants of this type are available under the trade name Dowfax® from Dow Chemical Comp any, where R is a linear or branched C6-C16 alkyl. An example of these cyclodextrin-compatible anionic surfactants is Dowfax 3B2, whose R is approximately linear C !. base. When antibacterial activity or preservatives are cationic to minimize interaction with cationic actives, these anionic surfactants are advantageously not used because the effects of the surfactants and actives are reduced. The above surfactants have a weak interaction with cyclodextrin (the paper size of the surface sheet is in accordance with the Chinese National Standard (CNS) A4 specification (210 X 297 mm) I--1 !!! Install-! Order-!! I! Green (Jing first read the precautions on the back and then vib this page) A7 4 1 8 094 ________B7___ V. Description of the invention (18) The force has a lift of less than 5%) or the C surface tension without interaction has less than 1% increase). General surfactants such as sodium dodecyl sulfate and dodecanol poly (6) ethoxylate in typical cyclodextrin such as hydroxypropyl cold-cyclodextrin and methylated / 5-cyclodextrin In the presence of a very strong interaction 1 the surface tension is increased by more than 10%. Typical concentrations of cyclodextrin-compatible surfactants in useful compositions are from about 0.01% to about 2% by weight of the composition, advantageously from about 0.3% to about 0.6%. More advantageously, from about 0.05% to about 0.3%. Typical concentrations of the cyclodextrin-compatible surfactants in the concentrated composition are from about 0.1% to about 8% by weight of the concentrated composition 1 advantageously from about 0.2% to about 4%, more advantageously About 0.3% to about 3%. The cyclodextrin-containing deodorant composition is more fully described in the co-pending provisional Application 60/109834, applicants November 25, 1998. HDPE bottle. (d) High-density polyethylene bottles The modified HD PE bottles used in the present invention are modified by: having an inner surface selected from nylon, polyethylene terephthalate or fluorinated polyethylene as a protection Inhale and / or pass through the barriers of HD PE. This type of HD PE bottle is known for this technique. HD PE bottle with nylon or PET inner layer can be made by blow molding method, in which HDPE softened by heating, the adhesive and the concentric layer of nylon or PET are formed into a parison and co-extruded into the mold in the form of hollow tubes In the cavity, the bottle is formed by pressing the pressurized air against the cavity wall of the mold. The bottle is cooled to solidify to form nylon.-II ---- I-- — IIIIII — —— — — — ί — {Please read the precautions on the back before / consumption of this page) Intellectual Property Bureau, Ministry of Economic Affairs, Consumer Consumption Cooperative Print

This paper size applies to China National Standard (CNS) A4 (210 X 297 public love) ZT Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 41 8 0 9 4 A7 ___ B7 V. Description of the invention (19) or the inside of PET HDPE bottle. An HD PE bottle having an inner surface of fluorinated HD PE can be made by a known method by which the inner surface of a preformed HDPE bottle heated by this method is brought into contact with fluorine gas. Fluorine reacts with polyethylene to form a fluorinated polyethylene layer. See Surface Treatment Inproves Polyethylene Barrier Protection Package Engineering. 1998.11.11.64. See also U.S. Patent 4,08 1 * 674, published on March 28, 1964, and 3,998,180, published on December 21, 1976. The inner layer of nylon, PE T or fluorinated polyethylene should be continuous and have a thickness of at least about 0.005 inches. The following examples are presented for illustration and are in no way intended to limit the scope of the invention.

Example I In this example, the following fragrance deodorizing composition (such as carpets, cloths, counter tops, etc.) deodorizing composition was evaluated for the loss of fragrance ingredients in HD PE bottles, in which the fragrance was reduced by about 75% A composition with a Clog P of greater than 3 and a composition of about 25% with a Clog P of less than 3. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) !!-pack! —Order — — — Thread < Please read the precautions on the back // This page) 41809 ^ A7 B7 V. Description of the invention (20) Silwet 7600 * 0.10 Hydroxypropyl / 3-cyclodextrin 1.10 Two Ethylene Glycol 0.38 Kathon CG ** 0.0003 HC1 0.001 Fragrance + 0.065 Ethanol 3.00 Water Top Up * Oxidized Polyethylene-Polymethylmethoxone Surfactant from Osi Specialties Inc. ** Antibacterial agent from Rhom and Hass. This composition was stored in HD PE bottles for 8 weeks at room temperature. After storage, gas chromatography analysis was used to determine the amount of various different fragrance components remaining in the composition and calculate the approximate loss based on the amount of each component originally present. --------------- Install --- (Please read the precautions on the back before you know this page) Order. • Embroidery. Printed by a member of the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives Standards apply to China National Standard (CNS) A4 specifications (210 x 297 mm)-41809 ^ A7 B7 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (21) Eucalyptus with Clog P < 3 Brain agarol camphor 2,3-dimethyloctyl_α-iS product fermented methyl dihydrojasmonate nerol carboxylic acid garnet ester eugenol phthalate diethyl dihydroephthaldehyde phenylethyl alcohol-terpene Benzyl acetate

MPCA acetate

Sanjinol

Helional Average Loss% Lost = < 10 Fragrance Vertenex Acetate Terpyl Acetate M Nigerate Diphenyl Methane Hexyl Cinnamaldehyde Phentolid Cedar Methyl Cetonate Tonali d Salicylic Acid Phenyl Ethyl Phenylacetate T -decalactone T -methylionone Cold-ionone Fleuramone α-methylionone Frutene dibenzyl ether cis-hexenyl salicylate benzoic acid; Exaltolide > 50 Pack --- ------ Order --------- Line (please read the precautions on the back and then V. for this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ) -Z4-4 Ί 8 094 A7 ___ Β7 V. Description of the invention ((谙 Read the precautions on the back, then r, this page) This test shows that when stored in HD FE bottles, the fragrance ingredients with a0gp greater than 3 are significant. loss.

Example II In this example, the composition of the same basic formula as above (containing 0.06 5% of the same flavor) was placed in several changed bottles and stored at 70 T and 120 ° F, respectively. under. It has been observed in advance that perfume ingredients having a Clog P of more than 3 tend to make the composition cloudy, so that the transmittance of light can be increased to indicate the loss of these ingredients in the composition. The% light transmittance of the products stored in various bottles is shown below. % Transmittance% Transmittance @ 70Τ @ 120Τ Glass 2 13 HDPE 97 99 PVC 92 98 HDPE w / Fh treated interior 2 32 HDPE w / nylon interior 2 25 Polyethylene terephthalate 2 12 Ministry of Economy Wisdom The printed results of the employee's consumer cooperative of the Property Bureau prove the advantages of using the improved HD p according to the present invention. This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 4 1 8 094 A7 B7 Intellectual property of the Ministry of Economic Affairs Printed by the staff of the Bureau Cooperatives 5. Description of the invention (23) Example III Applicable to the preparation of fruit lemon flavors in the present invention such as τ component dihydrogeraniol-victoria parahydroisoisanol nonhydrogen tetrahydroagarol d -Ninene Verdox Camphor Gum Dimethyl Benzyl Methanol Eucalyptol Dimetol Parts 1.0 2 · 5 0.5 0.5 4 5.0 4 4.0 1.0 0.5 1.0 1. 0 Example I v The liquid fabric softener according to the present invention is formulated according to the following formula Made and packaged in HDPE bottle with PET inner surface》 Ingredients -------- 11 --- J — II! Order 111 --- — (Please read the precautions on the back before copying this (Page) Fragrance of Example III 5.25 1.00 The paper size is suitable Chinese National Standard (CNS) A4 size (210 X 297 mm) A7 B7 to 100 V. invention is described in (24)

Water Example V The liquid laundry detergent of the present invention was prepared according to the following formula and packaged in a bottle having a fluorinated polyethylene inner surface. ------------- Fruit ----- I Xuan --------- turn < please read the precautions on the back before V, this page) Ministry of Economic Affairs Intellectual Property The paper size printed by the Bureau ’s Consumer Cooperatives applies the Chinese National Standard (CNS) A4 (210 X 297 mm) ^ I Η 09 4 Α7 _Β7 V. Description of the Invention (25) Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Parts K / Na C13 Linear Alkylbenzene Sulfonate 7.2 1 (/ Heart (: 14-15 Alkyl Polyhydroxyethyl Acid (2,25) Sulfonate 10.8 C 12-13 Alcohol Poly (6.5) Hydroxyethyl 6.5 C12 alkyltrimethylammonium chloride 1.2 C12-14 fatty acid 13.0 oleic acid 2.0 citric acid (anhydrous) 4.0. Diethylene triamine pentaacetic acid 0.23 enzyme 0.91 ethoxylated tetraethylene Amine (15-1 8 Molar EO per 1.5 —H) Monoethanolamine 2.0 Propylene glycol 7.25 Ethanol 7.75 Formic acid .066 Calcium ion 0.03 Example III perfume 0.65 Water and small amount to 100 (Please read the precautions on the back first Re-r, this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm)

Claims (1)

Α8 Β8 C8 D8 6. Scope of patent application1. A bottled liquid household cleaning, fabric treatment or deodorizing composition 'wherein this composition contains from 0.1 to 50% surfactant and 0 · 0 0 3% to 5% perfume, wherein the perfume contains at least 10% of one or more hydrophobic perfume ingredients having a Clog P greater than 3 'and wherein the composition is contained in a high-density polyethylene bottle> where The bottle has an inner surface layer selected from the group consisting of: a) nylon b) polyethylene terephthalate c) fluorinated high density polyethylene. 2. The bottled composition according to item 1 of the scope of patent application, wherein the amount of fragrance in the composition is from 0.3 to 1%. 3. The bottled composition according to item 2 of the patent application range, wherein the fragrance contains at least 50% of a fragrance ingredient having a Clog P of greater than 3. 4. The bottled composition according to item 3 of the patent application scope, wherein the fragrance contains at least 70% of a fragrance ingredient having a Clog P of greater than 3. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 418094 4 1 8 (please read the precautions on the back before ^ 丨 this page) 5. If the bottled composition of the third scope of the patent application, the fragrance concentration in the composition It is 0.05 to 0.2% and wherein the composition additionally contains 0.1% to 20% cyclodextrin and 0.15 to 20% of a fragrance compatible with cyclodextrin. 6. The bottled composition according to item 5 of the patent application scope, wherein the inner surface of the bottle is nylon. 7 The bottled composition according to item 5 of the patent application, wherein the inner surface of the bottle is polyethylene terephthalate. 8. If the bottled composition of item 5 in the scope of patent application, among which bottle -29- This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 g). 6. The surface layer in the scope of patent application is fluorinated. Polyethylene A8 Β8 C8 D8 ------; -------- install --------- order --------- line (please read the precautions on the back before filling f. This page) Printed by a member of the Intellectual Property Bureau of the Ministry of Economic Affairs and a Consumer Cooperative, the paper size applies to the Chinese National Standard (CNS) A4 (210x297 mm) -30 ·