TW408156B - Stabilizer for chlorine-containing polymers and chlorine-containing polymer composition - Google Patents

Stabilizer for chlorine-containing polymers and chlorine-containing polymer composition Download PDF

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Publication number
TW408156B
TW408156B TW87109452A TW87109452A TW408156B TW 408156 B TW408156 B TW 408156B TW 87109452 A TW87109452 A TW 87109452A TW 87109452 A TW87109452 A TW 87109452A TW 408156 B TW408156 B TW 408156B
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weight
stabilizer
parts
chlorine
calcium silicate
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TW87109452A
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Chinese (zh)
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Masaaki Sugawara
Osamu Saito
Choichi Abe
Kenetsu Ogasawara
Hitoshi Yajima
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Mizusawa Industrial Chem
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477Six-membered rings
    • C08K5/3492Triazines
    • C08K5/34924Triazines containing cyanurate groups; Tautomers thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/05Alcohols; Metal alcoholates
    • C08K5/053Polyhydroxylic alcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/04Ingredients treated with organic substances

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

The present invention relates to a stabilizer for chlorine-containing polymers achieving a high heat stabilizing action with a small amount of use and imparting strikingly enhanced heat stability. A chlorine-containing polymer composition comprising the stabilizer exhibits excellent heat stability, markedly improved resistance against the aging at low temperatures, excellent electric insulation, and is suited for use as a covering for electric wires. For example, the stabilizer for chlorine-containing polymers comprises, at a particular weight ratio, a composite containing a fine crystalline calcium silicate having a Ca/Si molar ratio of not smaller than 0.5, and a polyhydric alcohol at a weight ratio of 20:80 to 80:20, and an isocyanurate compound and/or a hydrotalcite or a salt of an alkali-aluminum composite hydroxide.

Description

408156 A7 D7 89. 6.- 斗 η S..正 i 辨 經濟部智慧財產局員工消費合作社印製 .已 公開專 m m 商 之作周 一種於 聚合物 已 聚合物 一種包 到3份 五、發明說明( 發明背f 1.發明的領域 本發明偽有闢一橿含氯聚合物之非鉛類型安定劑和有 闢一種安定的含氯聚合物组成物。更明確地說,本發明像 有關一種顯著改良抗低溫老化姓的含氯聚含薇之安定劑, 有顒一褸含氛聚合锪組成铹,和有顢一種呈現熱安定該等 含氯聚合窃的作闬之改良安定劏。 2 .先前技藝的說明 δ夕酸鈣畏久K來被當作樹脂之摻合劑使思。日本公開 專利第1 3 2 3 7/ 1 S S 2號掲示一種具有特定X射線繞射圖像 之題结晶矽酸鈣作為顯示優異熱安定作闱的樹脂之摻合劑 知異氰尿酸酯化合锪可包含在含氯聚合锪中。日本 利第7 4 G 4 3/ 1 9 了 S號揭示一種包含參(2 -羥乙基)異 酯和有餞酸鹽之氯乙烯澍脂組成物。 且,長久Μ来已知道水滑石圼現熱安定含氯聚合物 洌茆,日本公開專利第8 G 4 4 5 / 1 9 8 0號揭示摻合 0 . (U到5重量份之量的水滑石/每1 0 0重量份含氯 或相鉍物。 知道使用一種矽酸鹽和一種水滑石之組合當做含氯 的安定劑。日本公開專利號第17 3 Ο 3 i) / 1 9 S 3號揭述 含丨).0 5到丨0重量份的含過氯酸基圃之水滑石和G . 0 0 1 之鋁的矽酸鹽或鹼土金屬的矽酸鹽,每i Q Q重量份 3 本紙張尺度適用令國國家標準(CNS)A4規格(210 X 297公釐) — — — lilllllli 1 I I I I 1 I ^ ---------竣 (請先閱讀背面之注意事項再填寫本頁) 408156 A7 D7 89. 6.- 斗 η S..正 i 辨 經濟部智慧財產局員工消費合作社印製 .已 公開專 m m 商 之作周 一種於 聚合物 已 聚合物 一種包 到3份 五、發明說明( 發明背f 1.發明的領域 本發明偽有闢一橿含氯聚合物之非鉛類型安定劑和有 闢一種安定的含氯聚合物组成物。更明確地說,本發明像 有關一種顯著改良抗低溫老化姓的含氯聚含薇之安定劑, 有顒一褸含氛聚合锪組成铹,和有顢一種呈現熱安定該等 含氯聚合窃的作闬之改良安定劏。 2 .先前技藝的說明 δ夕酸鈣畏久K來被當作樹脂之摻合劑使思。日本公開 專利第1 3 2 3 7/ 1 S S 2號掲示一種具有特定X射線繞射圖像 之題结晶矽酸鈣作為顯示優異熱安定作闱的樹脂之摻合劑 知異氰尿酸酯化合锪可包含在含氯聚合锪中。日本 利第7 4 G 4 3/ 1 9 了 S號揭示一種包含參(2 -羥乙基)異 酯和有餞酸鹽之氯乙烯澍脂組成物。 且,長久Μ来已知道水滑石圼現熱安定含氯聚合物 洌茆,日本公開專利第8 G 4 4 5 / 1 9 8 0號揭示摻合 0 . (U到5重量份之量的水滑石/每1 0 0重量份含氯 或相鉍物。 知道使用一種矽酸鹽和一種水滑石之組合當做含氯 的安定劑。日本公開專利號第17 3 Ο 3 i) / 1 9 S 3號揭述 含丨).0 5到丨0重量份的含過氯酸基圃之水滑石和G . 0 0 1 之鋁的矽酸鹽或鹼土金屬的矽酸鹽,每i Q Q重量份 3 本紙張尺度適用令國國家標準(CNS)A4規格(210 X 297公釐) — — — lilllllli 1 I I I I 1 I ^ ---------竣 (請先閱讀背面之注意事項再填寫本頁) 408156 A7 -f 月 B7 五、發^明說明(y 經濟部智慧財產局員工消费合作社印製 含氯之聚合饬之德定ib樹脂組成栩- 再者·,g本公開專利第1113237/ 1 93S號揭示一種用於 覆蓋電線的氯乙烯澍脂组成物*包含ί).ί]5到iG重量汾之水 滑石/每i ϋ〖!重量份氯乙烯樹脂,和ϋ . G ϋ 1到3重蠆汾之具 有2.2到8的莫耳比之矽石的鹼土金靥鹽,每鹼土金屬之 氯ib锪。 上逑的安定萷從其圼琨某些程度熱安定作甩忽珞能ΙΠ 是非鉛類型的観點評沽是有價值的,但仍不符合於其有FJ 2赶溫抗老化S。此外,從藉由小量摻合達成高熱安定作 届;Z観點ί乃有改良之空間。 習知含氯聚合钧的固有問題S括在約13 G °C之較高溫 度的抗熱性。在高溫抗熱性自然是極需考量者。然商,該 含氯聚合物進一步包括問題:一種當他們卽使暴露於\低溫 ,Μ茹,約IG G t經延長時間之老化:由於低溫老化,澍 詣傾_於被著色或損失礒械性質例茹伸長。 發明的概述 本發明人已發琨熱安定性被顯著地改良,抵溫抗老化 栓?皮顯著地改良,及不發生最初著色的事簧=當具有特定 諶成饬和特定X射線繞射圖®之綑结晶矽酸鈣是從砂酸鈣 選岀時,或當選擇一種此细结晶矽酸鈣與多元醇之複合锪 ,及與異氰尿酸酯化合锪组合之複合锪時: 亦即,本發明的目的是提供一種兩於含氯聚合物之非 μ類型安定劑,該含氯聚合物圼琨顗著地改良的熱安定性 (諳先閱讀背面之注意事項再填寫本頁) 裝--------訂--------線 本紙張尺度適用中國國家標準(CNS>A4規格(210 x 297公釐) 408156 A7 -f 月 B7 五、發^明說明(y 經濟部智慧財產局員工消费合作社印製 含氯之聚合饬之德定ib樹脂組成栩- 再者·,g本公開專利第1113237/ 1 93S號揭示一種用於 覆蓋電線的氯乙烯澍脂组成物*包含ί).ί]5到iG重量汾之水 滑石/每i ϋ〖!重量份氯乙烯樹脂,和ϋ . G ϋ 1到3重蠆汾之具 有2.2到8的莫耳比之矽石的鹼土金靥鹽,每鹼土金屬之 氯ib锪。 上逑的安定萷從其圼琨某些程度熱安定作甩忽珞能ΙΠ 是非鉛類型的観點評沽是有價值的,但仍不符合於其有FJ 2赶溫抗老化S。此外,從藉由小量摻合達成高熱安定作 届;Z観點ί乃有改良之空間。 習知含氯聚合钧的固有問題S括在約13 G °C之較高溫 度的抗熱性。在高溫抗熱性自然是極需考量者。然商,該 含氯聚合物進一步包括問題:一種當他們卽使暴露於\低溫 ,Μ茹,約IG G t經延長時間之老化:由於低溫老化,澍 詣傾_於被著色或損失礒械性質例茹伸長。 發明的概述 本發明人已發琨熱安定性被顯著地改良,抵溫抗老化 栓?皮顯著地改良,及不發生最初著色的事簧=當具有特定 諶成饬和特定X射線繞射圖®之綑结晶矽酸鈣是從砂酸鈣 選岀時,或當選擇一種此细结晶矽酸鈣與多元醇之複合锪 ,及與異氰尿酸酯化合锪组合之複合锪時: 亦即,本發明的目的是提供一種兩於含氯聚合物之非 μ類型安定劑,該含氯聚合物圼琨顗著地改良的熱安定性 (諳先閱讀背面之注意事項再填寫本頁) 裝--------訂--------線 本紙張尺度適用中國國家標準(CNS>A4規格(210 x 297公釐) 經濟部智慧財產局員工消費合作社印數 40815ο ; . , < Α7 _Β7 ___五、發明說明(々) 和低溫抗老化、. 本發明人更進一步垲發琨:當一種具有特定組成物和 特定X射線_射圖像之绌结晶矽酸鈣是從矽酸鈣選出ίο當 其與水滑石或驗一鋁複合物1氧化物的發姐合時熱安定性 被醒目垲改良的事簧。 當一種m含细结晶矽酸鈣和多元醇之複合韧形成且與 水滑石或鹼一鋁複合窃氫氧化韧的鹽組合時,本發明人更 進一步發琨熟安定注被更改良的事霣 亦即,本發明的目的是提供具有顯著改良熱安定性之 含氯聚合物的安定劏。 本發玥之另一目的是提洪一種育優良熱安定性,優良 的低溫抗老化和優良電絕緣性質,和有效當做電線覆蓋枋 科的非鉛類型之含氯聚合锪组成饬。 根據本發萌,提洪一種周於含氯聚合物之安定劑,包 括u) —種具有κ下列通式(1)表示之化學組成锪, CaO· sSiGz * lifiz Ο · {i) 其中χ為不小於Ο . 5之數目,和η為不大於2 . 5之數目, 且在3 . ϋ 1到3 · δ 8埃的間隔,在2 . 7 8到2 , 3 2埃的間隔和1 . 8 I 到i . 8 4埃的間隔具有X射線射圖像的细结晶矽酸鈣,和 U )異氰尿酸酯化合物,细结晶矽酸鈣(A)和異氰尿酸酯化 合物(B )涤包含於5 : 3 5到S S · 3 : 0 . 2的重量比。 根據本發明,此外,提洪一種闬於含氬聚含物之安定 劑,S括(A )细结晶矽酸鈣,U )異氰尿酸酯化合构和(C ) (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)A4規格<210 X 297公t ) 經濟部智慧財產局員工消費合作社印數 40815ο ; . , < Α7 _Β7 ___五、發明說明(々) 和低溫抗老化、. 本發明人更進一步垲發琨:當一種具有特定組成物和 特定X射線_射圖像之绌结晶矽酸鈣是從矽酸鈣選出ίο當 其與水滑石或驗一鋁複合物1氧化物的發姐合時熱安定性 被醒目垲改良的事簧。 當一種m含细结晶矽酸鈣和多元醇之複合韧形成且與 水滑石或鹼一鋁複合窃氫氧化韧的鹽組合時,本發明人更 進一步發琨熟安定注被更改良的事霣 亦即,本發明的目的是提供具有顯著改良熱安定性之 含氯聚合物的安定劏。 本發玥之另一目的是提洪一種育優良熱安定性,優良 的低溫抗老化和優良電絕緣性質,和有效當做電線覆蓋枋 科的非鉛類型之含氯聚合锪组成饬。 根據本發萌,提洪一種周於含氯聚合物之安定劑,包 括u) —種具有κ下列通式(1)表示之化學組成锪, CaO· sSiGz * lifiz Ο · {i) 其中χ為不小於Ο . 5之數目,和η為不大於2 . 5之數目, 且在3 . ϋ 1到3 · δ 8埃的間隔,在2 . 7 8到2 , 3 2埃的間隔和1 . 8 I 到i . 8 4埃的間隔具有X射線射圖像的细结晶矽酸鈣,和 U )異氰尿酸酯化合物,细结晶矽酸鈣(A)和異氰尿酸酯化 合物(B )涤包含於5 : 3 5到S S · 3 : 0 . 2的重量比。 根據本發明,此外,提洪一種闬於含氬聚含物之安定 劑,S括(A )细结晶矽酸鈣,U )異氰尿酸酯化合构和(C ) (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)A4規格<210 X 297公t ) 408x56 A7 B7408156 A7 D7 89. 6.- Dou η S .. Zheng i Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. It has been published by the exclusive trader, including one polymer and one polymer. Description (Inventive Background) 1. Field of the Invention The present invention includes a non-lead type stabilizer of a chlorine-containing polymer and a stable chlorine-containing polymer composition. More specifically, the present invention relates to a kind of Significantly improved chlorine-containing poly-weiwei stabilizers with low temperature aging resistance, which are composed of a combination of atmospheric polymer, and a modified stabilizer that exhibits thermal stability such as chlorine-containing polymer theft. 2. Description of the prior art δ Calcium oxalate is used as a blending agent for resins. Japanese Published Patent No. 1 2 3 7/1 SS 2 shows a title of crystalline silicon with a specific X-ray diffraction image. Calcium acid is used as a blending agent for resins exhibiting excellent thermal stability. It is known that isocyanurate compounds can be included in chlorinated polymeric fluorene. Japan's No. 7 4 G 4 3/19 9 discloses a type containing ginseng ( Composition of 2-hydroxyethyl) isoester and vinyl chloride resin with tarnish Moreover, it has been known for a long time that hydrotalcite 圼 is now thermally stable and chlorinated polymer 洌 茆, and Japanese Laid-Open Patent No. 8 G 4 4 5/198 0 discloses blending 0. (U to 5 parts by weight of the amount of Hydrotalcite / 100 parts by weight of chlorine or phase bismuth. It is known to use a combination of a silicate and a hydrotalcite as a stabilizer containing chlorine. Japanese Laid-Open Patent No. 17 3 0 3 i) / 1 9 S No. 3 discloses containing 丨). 0 5 to 丨 0 parts by weight of hydrotalcite containing perchloric acid base and G. 0 01 aluminum silicate or alkaline earth metal silicate per QQ weight part 3 This paper size applies the national standard (CNS) A4 specification (210 X 297 mm) — — — lilllllli 1 IIII 1 I ^ --------- Complete (please read the precautions on the back before filling (This page) 408156 A7 D7 89. 6.- Dou η S .. Zheng i Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. It has been published by a specialist manufacturer. V. Description of the Invention (Inventive Background) 1. Field of the Invention The present invention includes a non-lead type stabilizer for chlorine-containing polymers and a stable chlorine-containing stabilizer. More specifically, the present invention relates to a chlorine-containing polyweiwei-containing stabilizer that significantly improves the resistance to low-temperature aging, and has a composition consisting of an atmospheric polymer and a thermal stabilizer. Such as chlorine-containing polymer theft to improve the stability of the work. 2. The description of the prior art δ calcium oxalate Kojiu K is used as a resin admixture. Japanese Published Patent No. 1 3 2 3 7/1 SS 2 No. 掲 indicates that a crystalline calcium silicate having a specific X-ray diffraction image is used as a blending agent of a resin showing excellent thermal stability, and the isocyanurate compound can be contained in a chlorine-containing polymer. Japanese No. 7 4 G 4 3/1 9 No. S discloses a vinyl chloride resin composition containing ginseng (2-hydroxyethyl) isoester and a citrate. Moreover, it has been known for a long time that hydrotalcite (heat-stabilized chlorine-containing polymer) is present, and Japanese Laid-Open Patent No. 8 G 4 4 5/198 0 discloses blending of 0.1 to 5 parts by weight of water. Talc / 100 parts by weight of chlorine or phase bismuth. It is known to use a combination of a silicate and a hydrotalcite as a stabilizer containing chlorine. Japanese Laid-Open Patent No. 17 3 0 3 i) / 1 9 S 3 The number discloses 丨). 0 5 to 丨 0 parts by weight of hydrotalcite containing perchlorate and G. 0 01 aluminum silicate or alkaline earth metal silicate, 3 parts by weight per i QQ The paper size is applicable to the national standard (CNS) A4 specification (210 X 297 mm) — — — lilllllli 1 IIII 1 I ^ --------- Complete (please read the precautions on the back before filling in this Page) 408156 A7 -f month B7 V. Issued a description (y Printed chlorine-containing polymer 饬 Deding ib resin composition printed by the Ministry of Economic Affairs Intellectual Property Bureau employee consumer cooperatives-furthermore, g, this patent No. 1113237 / No. 93S discloses a vinyl chloride resin composition for covering electric wires * containing ί). Ί] 5 to iG by weight of talc hydrotalcite / per i ϋ 〖!! parts by weight of vinyl chloride resin, and ϋ. G ϋ 1 to 3 weights of Fen's alkaline earth gold sulfonium salt with mole ratio silica of 2.2 to 8 and chlorine ib 每 per alkaline earth metal. The stability of the listed company is from some degree of thermal stability. It can be regarded as a non-lead type. It is valuable, but it is still not in line with its FJ 2 anti-aging resistance. In addition, high heat stability can be achieved by blending in small amounts; there is room for improvement. Known problems inherent in chlorine-containing polymers include heat resistance at higher temperatures of about 13 G ° C. Heat resistance is naturally a critical consideration at high temperatures. However, the chlorinated polymer further includes problems: a kind of aging when they are exposed to low temperature, M Ru, about IG Gt for a prolonged period of time: due to low temperature aging, they are not colored or lost. Examples of properties Ru elongation. Summary of the invention The inventors have found that the thermal stability has been significantly improved to resist temperature and anti-aging plugs? The skin is significantly improved, and no initial coloring occurs. = When a bundle of crystalline calcium silicate with a specific crystal and a specific X-ray diffraction pattern is selected from calcium oxalate, or when one of these fine crystals is selected When a compound of calcium silicate and a polyol and a compound of an isocyanurate compound are used: That is, the object of the present invention is to provide a non-μ-type stabilizer containing two or more chlorine-containing polymers. Chloropolymer improved thermal stability (read the precautions on the back before filling this page) National Standard (CNS > A4 specification (210 x 297 mm) 408156 A7 -f month B7 V. Issued by the clarification (y printed by chlorine-containing polymer 饬 Deding ib resin composition of the Ministry of Economic Affairs Intellectual Property Bureau staff consumer cooperative) -Furthermore, g, this disclosure patent No. 1113237/1 93S discloses a vinyl chloride resin composition for covering electric wires * containing ί). Ί] 5 to iG weight fenzhi hydrotalcite / per i ϋ 〖! Weight Parts vinyl chloride resin, and ϋ. G ϋ 1 to 3 weights of Fen's alkaline earth gold sulfonium salt with a mole ratio of 2.2 to 8 per alkoxide The chlorine of the metal ib 锪. The stability of the upper part is from its thermal stability to some extent. It is a non-lead type. It is valuable, but it still does not meet its FJ 2 resistance. Aging S. In addition, high heat stability can be achieved by blending in small amounts; there is room for improvement in Z 観 spot. Known problems inherent to chlorine-containing polymerization S include the higher temperature of about 13 G ° C. Heat resistance. Heat resistance is naturally a critical consideration at high temperatures. However, the chlorinated polymer further includes problems: a kind of aging when they are exposed to low temperatures, M Ru, about IG Gt over an extended period of time: due to Low-temperature aging, sloppy _ elongation due to pigmentation or loss of mechanical properties. Summary of the invention The inventors have found that the thermal stability has been significantly improved, the temperature and anti-aging plugs have been significantly improved, and do not occur The thing that was initially colored = when a bundle of crystalline calcium silicate with a specific crystal and a specific X-ray diffraction pattern is selected from calcium oxalate, or when a compound of this fine crystalline calcium silicate and a polyol is selected锪, and compound 锪 when combined with isocyanurate 锪: That is, the object of the present invention is to provide a non-μ type stabilizer with two or more chlorinated polymers, the chlorinated polymers have improved thermal stability (read the precautions on the back before filling this page) ) Packing -------- Order -------- The size of the paper is applicable to the Chinese national standard (CNS > A4 size (210 x 297 mm)) The number of employees of the Intellectual Property Bureau of the Ministry of Economic Affairs and the Consumer Cooperatives is 40815. . , ≪ Α7 _Β7 ___ V. Description of the invention (々) and low temperature anti-aging, the inventors have further developed: when a kind of crystalline silicic acid with a specific composition and a specific X-ray image Calcium is selected from calcium silicate. When it is combined with hydrotalcite or aluminum oxide 1 oxide, thermal stability is noticeably improved. When a compound containing fine crystalline calcium silicate and a polyalcohol is formed and combined with hydrotalcite or alkali-aluminum complex salt, the present inventors have further taken notice that the matter will be changed. That is, the object of the present invention is to provide a stabilizer for a chlorinated polymer having significantly improved thermal stability. Another purpose of this hairpin is to improve the heat stability, low temperature aging resistance and excellent electrical insulation properties, and a non-lead type chlorine-containing polymerized hafnium which is effective as a wire covering branch. According to the present germination, Tihong is a stabilizer for chlorinated polymers, including u) —a kind of chemical composition 锪 having the following general formula (1): κ, CaO · sSiGz * lifiz 〇 · {i) where χ is The number is not less than 0,5, and η is the number of not more than 2.5, and at intervals of 3. ϋ 1 to 3 · δ 8 angstroms, at intervals of 2.7 to 2, 3 2 angstroms and 1. 8 I to i. 8 4 Angstroms of fine crystalline calcium silicate with X-ray radiographic images, and U) isocyanurate compound, fine crystalline calcium silicate (A) and isocyanurate compound (B Polyester is included in a weight ratio of 5:35 to SS · 3: 0.2. According to the present invention, in addition, a stabilizing agent which is immersed in an argon-containing polymer, S (A) fine crystal calcium silicate, U) isocyanurate complex and (C) (please read the back Note: Please fill in this page again) This paper size is applicable to China National Standard (CNS) A4 specifications < 210 X 297g t) Employees' Cooperatives of Intellectual Property Bureau of the Ministry of Economic Affairs Number 40815ο;., ≪ Α7 _Β7 ___ V. Invention Explanation (々) and low temperature anti-aging, the inventors have further developed: when a crystalline calcium silicate with a specific composition and a specific X-ray image is selected from calcium silicate, when it is combined with water The thermal stability of talc or aluminum oxide 1 oxide is noticeably improved by the thermal stability. When a compound containing fine crystalline calcium silicate and a polyalcohol is formed and combined with hydrotalcite or alkali-aluminum complex salt, the present inventors have further taken notice that the matter will be changed. That is, the object of the present invention is to provide a stabilizer for a chlorinated polymer having significantly improved thermal stability. Another purpose of this hairpin is to improve the heat stability, low temperature aging resistance and excellent electrical insulation properties, and a non-lead type chlorine-containing polymerized hafnium which is effective as a wire covering branch. According to the present germination, Tihong is a stabilizer for chlorinated polymers, including u) —a kind of chemical composition 锪 having the following general formula (1): κ, CaO · sSiGz * lifiz 〇 · {i) where χ is The number is not less than 0,5, and η is the number of not more than 2.5, and at intervals of 3. ϋ 1 to 3 · δ 8 angstroms, at intervals of 2.7 to 2, 3 2 angstroms and 1. 8 I to i. 8 4 Angstroms of fine crystalline calcium silicate with X-ray radiographic images, and U) isocyanurate compound, fine crystalline calcium silicate (A) and isocyanurate compound (B Polyester is included in a weight ratio of 5:35 to SS · 3: 0.2. According to the present invention, in addition, a stabilizing agent which is immersed in an argon-containing polymer, S (A) fine crystal calcium silicate, U) isocyanurate complex and (C) (Please read Note: Please fill in this page again) This paper size is applicable to China National Standard (CNS) A4 specifications < 210 X 297mm t) 408x56 A7 B7

89丰V 修正 五、發明說明(k ) 水滑石或鹼—鋁複含物鹽,成分(Β)Κί1.5至5ί丨重量/每丨QG S量汾之或分(A )和i C )的缌數的重量比存在◊ 根據本發明,眈外,提淇一種甬於含氯聚合韧之安定 劑…包祜(D ) —種具有Κ下列通式(2 )表示之化學組成薇, C a 0 · X S I (5 2 * π rt 2 fl · ί 2 ) 其vx為0.5至2.Π之數目,和η為不大於2.5之數a , 且在3.!U到3.ί)3埃的間隔,茌2.78到2.82埃的間隔和1.81 到I. 3 4埃的間隔具有X射謀装射圖像的綑结晶矽酸鈣,和 )永滑石或鹼一鋁複合锪氫氧化窃鹽之g 0.5: 93.5 (請先閲讀背面之注意事項再填寫本I) 到 經濟部智慧財產局員工消費合作社印製 3 3 : 1的重量比。 再者|本發明提洪一種用於含氯聚合物之安定劑,其 中迎結晶矽酸鈣(A)(或(D ))為一種包含於2 0 : 8 0到S G : 2 0 重量比的豳结晶矽酸鈣U )(或ί D ))和多元酵之複合锪(E )。 希望求發明的安定劑進一步包含: L . ( F ) 5到7 0重量份之高Μ脗肪酸鋅 > 每I Q 3重量份之綑 结晶矽酸鈣U)(或(D )或(Ε )),和永滑石或鹼一鋁 複合锪氫氧化物( C )之鹽的缌重量; 2 .( G ) 1到5 0重量份酚類抗氧化劑,每1G 〇重量份缒结晶 矽酸鈣U)(或(D)或(Ε))和水滑石或鹼-鋁複合物 氫氧化物鹽(C )的鹽之總重量;或 3 , (H) 0 . 5到3ϋ重量份召-二嗣或/5 -嗣基酸酯,每1〇〇份 重量份细结晶矽酸鈣(Α)(或(D)或(Ε))和水滑石或 鹼一鋁複合物氫氧ib物鹽(C)鹽之漶1量:- 本紙張尺度適用t國國家標準(CNS)A4規格(210 X 297公釐) 408x56 A7 B789 Feng V Correction V. Description of the invention (k) Hydrotalcite or alkali-aluminum complex salt, component (Β) Κί1.5 to 5ί 丨 weight per QG S amount of Fen (A) and i C) According to the present invention, in addition to the above, a stabilizer for chlorine-containing polymer toughness is included ... (D)-a chemical composition having the following general formula (2), K, C a 0 · XSI (5 2 * π rt 2 fl · ί 2) whose vx is a number from 0.5 to 2.Π, and η is a number not greater than 2.5 a, and from 3.! U to 3.ί) 3 angstroms The interval of 茌 2.78 to 2.82 Angstroms and the interval of 1.81 to 1.3 Angstroms have a bundle of crystalline calcium silicate with X-ray projection images, and g 0.5: 93.5 (Please read the notes on the back before filling in this I) Printed at 3 3: 1 weight ratio at the Consumer Cooperatives of Intellectual Property Bureau of the Ministry of Economic Affairs. Furthermore | The present invention provides a stabilizer for a chlorine-containing polymer, wherein the crystalline calcium silicate (A) (or (D)) is a kind of crystalline calcium silicate contained in a weight ratio of 20:80 to SG: 20. (锪) crystalline calcium silicate (U) (or D D)) and multiple enzymes (E). It is desired that the stabilizer of the invention further comprises: L. (F) 5 to 70 parts by weight of high zinc zinc fatty acid > 3 parts by weight of bale of crystalline calcium silicate U) (or (D) or (Ε) )), And the weight of the salt of permanganite or alkali-aluminum composite rhenium hydroxide (C); 2. (G) 1 to 50 parts by weight of phenolic antioxidants, 0 gram parts of crystalline calcium silicate per 1G U) (or (D) or (Ε)) and the total weight of the salt of hydrotalcite or alkali-aluminum complex hydroxide salt (C); or 3, (H) 0.5 to 3 parts by weight嗣 or / 5-fluorenyl ester, per 100 parts by weight of fine crystalline calcium silicate (A) (or (D) or (E)) and hydrotalcite or alkali-aluminum complex hydroxide ib salt ( C) Amount of salt:-This paper size is applicable to National Standard (CNS) A4 (210 X 297 mm) 408x56 A7 B7

89丰V 修正 五、發明說明(k ) 水滑石或鹼—鋁複含物鹽,成分(Β)Κί1.5至5ί丨重量/每丨QG S量汾之或分(A )和i C )的缌數的重量比存在◊ 根據本發明,眈外,提淇一種甬於含氯聚合韧之安定 劑…包祜(D ) —種具有Κ下列通式(2 )表示之化學組成薇, C a 0 · X S I (5 2 * π rt 2 fl · ί 2 ) 其vx為0.5至2.Π之數目,和η為不大於2.5之數a , 且在3.!U到3.ί)3埃的間隔,茌2.78到2.82埃的間隔和1.81 到I. 3 4埃的間隔具有X射謀装射圖像的綑结晶矽酸鈣,和 )永滑石或鹼一鋁複合锪氫氧化窃鹽之g 0.5: 93.5 (請先閲讀背面之注意事項再填寫本I) 到 經濟部智慧財產局員工消費合作社印製 3 3 : 1的重量比。 再者|本發明提洪一種用於含氯聚合物之安定劑,其 中迎結晶矽酸鈣(A)(或(D ))為一種包含於2 0 : 8 0到S G : 2 0 重量比的豳结晶矽酸鈣U )(或ί D ))和多元酵之複合锪(E )。 希望求發明的安定劑進一步包含: L . ( F ) 5到7 0重量份之高Μ脗肪酸鋅 > 每I Q 3重量份之綑 结晶矽酸鈣U)(或(D )或(Ε )),和永滑石或鹼一鋁 複合锪氫氧化物( C )之鹽的缌重量; 2 .( G ) 1到5 0重量份酚類抗氧化劑,每1G 〇重量份缒结晶 矽酸鈣U)(或(D)或(Ε))和水滑石或鹼-鋁複合物 氫氧化物鹽(C )的鹽之總重量;或 3 , (H) 0 . 5到3ϋ重量份召-二嗣或/5 -嗣基酸酯,每1〇〇份 重量份细结晶矽酸鈣(Α)(或(D)或(Ε))和水滑石或 鹼一鋁複合物氫氧ib物鹽(C)鹽之漶1量:- 本紙張尺度適用t國國家標準(CNS)A4規格(210 X 297公釐)89 Feng V Correction V. Description of the invention (k) Hydrotalcite or alkali-aluminum complex salt, component (Β) Κί1.5 to 5ί 丨 weight per QG S amount of Fen (A) and i C) According to the present invention, in addition to the above, a stabilizer for chlorine-containing polymer toughness is included ... (D)-a chemical composition having the following general formula (2), K, C a 0 · XSI (5 2 * π rt 2 fl · ί 2) whose vx is a number from 0.5 to 2.Π, and η is a number not greater than 2.5 a, and from 3.! U to 3.ί) 3 angstroms The interval of 茌 2.78 to 2.82 Angstroms and the interval of 1.81 to 1.3 Angstroms have a bundle of crystalline calcium silicate with X-ray projection images, and g 0.5: 93.5 (Please read the notes on the back before filling in this I) Printed at 3 3: 1 weight ratio at the Consumer Cooperatives of Intellectual Property Bureau of the Ministry of Economic Affairs. Furthermore | The present invention provides a stabilizer for a chlorine-containing polymer, wherein the crystalline calcium silicate (A) (or (D)) is a kind of crystalline calcium silicate contained in a weight ratio of 20:80 to SG: 20. (锪) crystalline calcium silicate (U) (or D D)) and multiple enzymes (E). It is desired that the stabilizer of the invention further comprises: L. (F) 5 to 70 parts by weight of high zinc zinc fatty acid > 3 parts by weight of bale of crystalline calcium silicate U) (or (D) or (Ε) )), And the weight of the salt of permanganite or alkali-aluminum composite rhenium hydroxide (C); 2. (G) 1 to 50 parts by weight of phenolic antioxidants, 0 gram parts of crystalline calcium silicate per 1G U) (or (D) or (Ε)) and the total weight of the salt of hydrotalcite or alkali-aluminum complex hydroxide salt (C); or 3, (H) 0.5 to 3 parts by weight嗣 or / 5-fluorenyl ester, per 100 parts by weight of fine crystalline calcium silicate (A) (or (D) or (E)) and hydrotalcite or alkali-aluminum complex hydroxide ib salt ( C) 1 amount of salt:-This paper size is applicable to National Standard (CNS) A4 (210 X 297 mm)

經濟部智慧財產局員工消费合作社印製 希望本1明的含Μ聚合物组成物進一步包含: 1 . G . ^;到1 (!蜜量;分勘结晶矽酸鈣(a )(或(D )或(ε ) ) } 9 # g ? 到3桌量份和’特刖池,[j · G 2到丨重量份之異氟尿酸 酯化合物(S),及/或SJ ·丨到1G重量份之水潰石或鹼-錯複合趨Μ氧化物鹽(C)之鹽; 6 · G . I到5 G重量份之高级脂肪酸鋅(F ); 2. G.(丨I到δ.Ο重量份酚頸抗氧化劑(G);或 ^ . 0 _ 01到5 . ◦蜃量份/3 -二銅或召-酮基酸酯( _式簡要說明 圖1為一種根據合成實洌1之细结晶矽酸鈣(c 3 H _ i) 的X射線繞射圔像; 圖2為一種硬矽鈣石的X射線续射圖像;和 圈3說明如何發琨周以計算層合不對稱性的指數(i s) <-Θ i τ〇 θ 2 0 权.fe具體β施例的說.明 根據东發明’選擇一種具有以下列通式(丨)表示的fb 學組成物之细结晶狨酸鈣,當做矽酸鈣,Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the M-containing polymer composition of the present invention further contains: 1. G. ^; to 1 (! Honey amount; subdivided crystalline calcium silicate (a) (or (D ) Or (ε))} 9 # g? To 3 tables of parts and 'special tank, [j · G 2 to 丨 parts by weight of isofluurate compound (S), and / or SJ · to 1G Parts by weight of water crushed stone or alkali-co-complex M oxide salt (C); 6 · G. I to 5 G parts by weight of higher fatty acid zinc (F); 2. G. (丨 I to δ. 0 parts by weight of phenolic neck antioxidant (G); or ^. 0 _ 01 to 5. ◦ Quantitative parts / 3-dicopper or keto-keto acid ester () Formula Brief description Figure 1 is a synthesis based on 洌 1 X-ray diffraction image of fine crystalline calcium silicate (c 3 H _ i); Figure 2 is an X-ray image of xonotlite; and circle 3 shows how to calculate the lamination period to calculate the lamination failure. The index of symmetry (is) < -Θ i τ〇θ 2 0 weight.fe specific β embodiment description. According to the invention of the invention 'select a fb chemical composition with the following general formula (丨) Crystalline calcium gallate, as calcium silicate,

Cae.XSi〇2.iiH2〇 ... {1) 其中X為不小於0 · 5的數目和,較佳,〇 . 5到5 _ (5,和η為 —大於2 . 5的數目, 旦於:ί . ί) 1到3 . 0 S埃的間隔,在2 . 7 8到:i . 3 2埃的間隔和1 . s 1 到i · s彳埃的間隔具有X射線绫射圖像 細结晶矽酸鈣為已知,如掲示於上述日本公開專利第 ,Ί - 本紙張尺度適用中國國家標準<CNS〉A4規格(210 X 297公釐) — — — — — —— — — — —I— ·4ι(—— — — — — (請先閱讀背面之沒意事項再填寫本頁)Cae.XSi〇2.iiH2〇 ... {1) where X is a number not less than 0.5 and preferably 0.5 to 5 _ (5, and η is a number greater than 2.5, once Yu: ί. Ί) X-ray diffracted images at intervals of 1 to 3.0 S angstroms, at intervals of 2.78 to: 2.8 angstroms and intervals of 1. s 1 to i · s angstroms Fine crystalline calcium silicate is known, as shown in the above-mentioned Japanese Patent Publication No. Ί-This paper size applies to the Chinese National Standard < CNS> A4 Specification (210 X 297 mm) — — — — — — — — — —I— · 4ι (—— — — — — (Please read the unintentional matter on the back before filling this page)

經濟部智慧財產局員工消费合作社印製 希望本1明的含Μ聚合物组成物進一步包含: 1 . G . ^;到1 (!蜜量;分勘结晶矽酸鈣(a )(或(D )或(ε ) ) } 9 # g ? 到3桌量份和’特刖池,[j · G 2到丨重量份之異氟尿酸 酯化合物(S),及/或SJ ·丨到1G重量份之水潰石或鹼-錯複合趨Μ氧化物鹽(C)之鹽; 6 · G . I到5 G重量份之高级脂肪酸鋅(F ); 2. G.(丨I到δ.Ο重量份酚頸抗氧化劑(G);或 ^ . 0 _ 01到5 . ◦蜃量份/3 -二銅或召-酮基酸酯( _式簡要說明 圖1為一種根據合成實洌1之细结晶矽酸鈣(c 3 H _ i) 的X射線繞射圔像; 圖2為一種硬矽鈣石的X射線续射圖像;和 圈3說明如何發琨周以計算層合不對稱性的指數(i s) <-Θ i τ〇 θ 2 0 权.fe具體β施例的說.明 根據东發明’選擇一種具有以下列通式(丨)表示的fb 學組成物之细结晶狨酸鈣,當做矽酸鈣,Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the M-containing polymer composition of the present invention further contains: 1. G. ^; to 1 (! Honey amount; subdivided crystalline calcium silicate (a) (or (D ) Or (ε))} 9 # g? To 3 tables of parts and 'special tank, [j · G 2 to 丨 parts by weight of isofluurate compound (S), and / or SJ · to 1G Parts by weight of water crushed stone or alkali-co-complex M oxide salt (C); 6 · G. I to 5 G parts by weight of higher fatty acid zinc (F); 2. G. (丨 I to δ. 0 parts by weight of phenolic neck antioxidant (G); or ^. 0 _ 01 to 5. ◦ Quantitative parts / 3-dicopper or keto-keto acid ester () Formula Brief description Figure 1 is a synthesis based on 洌 1 X-ray diffraction image of fine crystalline calcium silicate (c 3 H _ i); Figure 2 is an X-ray image of xonotlite; and circle 3 shows how to calculate the lamination period to calculate the lamination failure. The index of symmetry (is) < -Θ i τ〇θ 2 0 weight.fe specific β embodiment description. According to the invention of the invention 'select a fb chemical composition with the following general formula (丨) Crystalline calcium gallate, as calcium silicate,

Cae.XSi〇2.iiH2〇 ... {1) 其中X為不小於0 · 5的數目和,較佳,〇 . 5到5 _ (5,和η為 —大於2 . 5的數目, 旦於:ί . ί) 1到3 . 0 S埃的間隔,在2 . 7 8到:i . 3 2埃的間隔和1 . s 1 到i · s彳埃的間隔具有X射線绫射圖像 細结晶矽酸鈣為已知,如掲示於上述日本公開專利第 ,Ί - 本紙張尺度適用中國國家標準<CNS〉A4規格(210 X 297公釐) — — — — — —— — — — —I— ·4ι(—— — — — — (請先閱讀背面之沒意事項再填寫本頁) A7 408156 B7 五、發明說明(w ) i 5 Η 7 / Μ號:·棍據本發明,細结晶矽酸鈣被選擇且與 異氣尿酸酯ib含物組合使闱Κ獲得顯著改良熱之安定性和 低溫抗老化性,如S後文的簧洌所証明。 當做矽酸鈣*已知有許多磷梅例如硬矽鈣石,雪矽鈣 石等。然商•根據本發明,使周一a具有上述特定化學組 成物和X射線繞射圔镓之细结晶矽酸鈣作為主要安定_以 改良含氣聚合物的熱安定牲。 一般學習得到使芾於本發明之细结晶矽酸鈣茁κ顯著 地改良含氯聚合锪的熱安定搜,但是從低溫抗老化惶的觀 點扔有改良的空間。 亦卽,當含氛聚合物組成锪與當傲主要安定劑的上述 细结晶矽酸鈣混合*在10 Q °C溫度维持一個星期,樹1組 成%傾商於粉紅色著色。 然而,當含氯聚合物組成窃與海结晶砂酸鈣和異氡尿 酸醋化合_混合時於5 . ϋ : S 5到9 g . S : 0 . 2的重量比和,特 別地,15: S5到Μ: 1的重量比,樹睹组成物不被著色甚 至其在上逑溫度維持上述時段之後。 可與含氛聚合锪的低溫老ib注比較者為含氛聚合物的 最初著色和一般抗熱性:最初著色為與安定劑摻合之含氛 聚合饬茌工作溫度(通常,1S ()到1 7 (Π〕)熱處理後的著色, 和抗熱性為在其中發生含氯聚合物的氫氯酸除去反應之溫 度條浮下(通常,L 丨到2 i) G t )的顔色評估。另一方面,在 低溫老ib性為在延長時間週期之熱滯後於非常低溫度發生 -S- 本紙張尺度適用中國國家標準(CNS)A4規格(210 x 297公釐) n ^^1 .^1 ϋ n -^1 .^1 1 i t ^1- I— t— n h -OJT n n I VI I (請先閱讀背面之沒意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 A7 408156 B7 五、發明說明(w ) i 5 Η 7 / Μ號:·棍據本發明,細结晶矽酸鈣被選擇且與 異氣尿酸酯ib含物組合使闱Κ獲得顯著改良熱之安定性和 低溫抗老化性,如S後文的簧洌所証明。 當做矽酸鈣*已知有許多磷梅例如硬矽鈣石,雪矽鈣 石等。然商•根據本發明,使周一a具有上述特定化學組 成物和X射線繞射圔镓之细结晶矽酸鈣作為主要安定_以 改良含氣聚合物的熱安定牲。 一般學習得到使芾於本發明之细结晶矽酸鈣茁κ顯著 地改良含氯聚合锪的熱安定搜,但是從低溫抗老化惶的觀 點扔有改良的空間。 亦卽,當含氛聚合物組成锪與當傲主要安定劑的上述 细结晶矽酸鈣混合*在10 Q °C溫度维持一個星期,樹1組 成%傾商於粉紅色著色。 然而,當含氯聚合物組成窃與海结晶砂酸鈣和異氡尿 酸醋化合_混合時於5 . ϋ : S 5到9 g . S : 0 . 2的重量比和,特 別地,15: S5到Μ: 1的重量比,樹睹组成物不被著色甚 至其在上逑溫度維持上述時段之後。 可與含氛聚合锪的低溫老ib注比較者為含氛聚合物的 最初著色和一般抗熱性:最初著色為與安定劑摻合之含氛 聚合饬茌工作溫度(通常,1S ()到1 7 (Π〕)熱處理後的著色, 和抗熱性為在其中發生含氯聚合物的氫氯酸除去反應之溫 度條浮下(通常,L 丨到2 i) G t )的顔色評估。另一方面,在 低溫老ib性為在延長時間週期之熱滯後於非常低溫度發生 -S- 本紙張尺度適用中國國家標準(CNS)A4規格(210 x 297公釐) n ^^1 .^1 ϋ n -^1 .^1 1 i t ^1- I— t— n h -OJT n n I VI I (請先閱讀背面之沒意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 40815ο Α7 修正Cae.XSi〇2.iiH2〇 ... {1) where X is a number not less than 0.5 and preferably 0.5 to 5 _ (5, and η is a number greater than 2.5, once Yu: ί. Ί) X-ray epitaxial images at intervals of 1 to 3.0 S angstroms, at intervals of 2.78 to: 2.8 angstroms and intervals of 1. s 1 to i · s angstroms Fine crystalline calcium silicate is known, as shown in the above-mentioned Japanese Patent Publication No. Ί-This paper size applies to the Chinese National Standard < CNS> A4 Specification (210 X 297 mm) — — — — — — — — — — —I— · 4ι (—— — — — — (Please read the unintentional matter on the back before filling out this page) A7 408156 B7 V. Description of the invention (w) i 5 Η 7 / Μ: · According to the present invention, The finely crystalline calcium silicate is selected and combined with the isogastric urate ib content to achieve a significantly improved thermal stability and low temperature aging resistance, as demonstrated by the spring maggots later in S. As calcium silicate * has been It is known that there are many phosphorus plums such as xonotlite, xonotlite, etc. However, according to the present invention, the fine crystalline calcium silicate with the above-mentioned specific chemical composition and X-ray diffracting gallium gallium as the main security according to the present invention. In order to improve the thermal stability of the gas-containing polymer, it is generally learned that the thermal stability of the fine crystalline calcium silicate (茁 κ) significantly improved in the chlorine-containing polymer (锪), but it is thrown from the viewpoint of low-temperature anti-aging. There is room for improvement. Also, when the composition containing the atmosphere polymer is mixed with the above-mentioned fine crystalline calcium silicate that is the main stabilizer of Dawn *, it is maintained at a temperature of 10 Q ° C for one week. However, when the chlorinated polymer composition is mixed with calcium crystalline calcium oxalate and isocyanuric acid and vinegar, it is mixed at 5. ϋ: S 5 to 9 g. S: 0.2 by weight and, in particular, 15 : S5 to M: 1 weight ratio, the composition of the tree is not colored even after the above temperature has been maintained for the above period. Comparing with the low-temperature old polymer with atmospheric polymer, it is the initial coloration of the aromatic polymer and General heat resistance: The initial coloration is the coloration of the atmosphere-containing polymer blended with stabilizers at the working temperature (usually, 1S () to 17 (Π)) after heat treatment, and the heat resistance is that of the chlorine-containing polymer in which it occurs The temperature bar of the hydrochloric acid removal reaction floats down (usually, L 丨 to 2 i) G t) color evaluation. On the other hand, the properties at low temperatures are that the heat lags at very low temperatures after prolonged periods of time. -S- This paper size applies the Chinese National Standard (CNS) A4 specification (210 x 297 mm). ) N ^^ 1. ^ 1 ϋ n-^ 1. ^ 1 1 it ^ 1- I— t— nh -OJT nn I VI I (Please read the unintentional matter on the back before filling this page) Intellectual Property of the Ministry of Economic Affairs Printed by Bureau Consumers Cooperative A7 408156 B7 V. Description of the Invention (w) i 5/7 / M: · According to the present invention, finely crystalline calcium silicate is selected and combined with isourethane ib content K achieved significantly improved thermal stability and low-temperature aging resistance, as demonstrated by the spring reed later in S. It is known as calcium silicate * There are many phosphorus plums such as xonotlite, xonotlite and so on. However, according to the present invention, the fine crystal calcium silicate having the above-mentioned specific chemical composition and X-ray diffracting gallium gallium as the main stabilizer is used in accordance with the present invention to improve the thermal stability of gas-containing polymers. It is generally learned that the thermal stability of the chlorine-containing polymer rhenium which is significantly improved by the fine crystalline calcium silicate 茁 κ in the present invention is improved, but there is room for improvement from the viewpoint of low temperature anti-aging ray. Also, when the composition of the atmosphere-containing polymer is mixed with the above-mentioned fine crystalline calcium silicate of the main stabilizer of Dawn *, it is maintained at a temperature of 10 Q ° C for one week, and the tree 1 composition is% quotient for pink coloring. However, when the chlorinated polymer composition was mixed with calcium crystalline calcium sarnate and isoammonium urate, it was mixed at a weight ratio of 5. ϋ: S 5 to 9 g. S: 0.2 and, in particular, 15: The weight ratio of S5 to M: 1, Shuwen composition is not colored even after the above temperature has been maintained for the above period. Comparable with the low temperature old IB injection of atmospheric polymer 锪 is the initial coloring and general heat resistance of the aromatic polymer: the initial coloring is the atmospheric polymer 饬 茌 blended with a stabilizer, the working temperature (usually, 1S () to 1 7 (Π)) The color after heat treatment, and the heat resistance are the color evaluations of the temperature at which the hydrochloric acid removal reaction of the chlorine-containing polymer occurs (usually, L 1 to 2 i) G t). On the other hand, at low temperatures, the aging property is that the heat lags at very low temperatures for an extended period of time. -S- This paper size applies the Chinese National Standard (CNS) A4 specification (210 x 297 mm) n ^^ 1. ^ 1 ϋ n-^ 1. ^ 1 1 it ^ 1- I— t— nh -OJT nn I VI I (Please read the unintentional matter on the back before filling out this page) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 40815ο Α7 correction

_B7 五、發明說明(1 ) 之著色或退化,和其被認為是溫度條件和原因差很多。 (請先Μ讀背面之注意事項再填冩本頁) 裉據苯發明',在低溫抗老化性之改良經由組合於預定 比之细结晶矽酸鈣與異観尿酸酷化合物之簧驗两發現之一 種現象:雖然該原因一點也不限制本發明,恒一般認為粉 红著&是由於輕微程度之多烯烴结構的形成或由於绌结晶 矽酸鈣和含氯聚合物之間相互作用所發生的複合物之形成 ,而一般招倌異m尿酸酯化合物抑制多烯烴结構的髟成或 複合_的形威。 經濟部智慧財產局員工消費合作社印製 在本發明中,希望细结晶矽酸鈣(A)(或其與多元酵之 複合物U’))和異Μ尿酸醅化合锪U),是Μ成分(B )之量為 3. 5到5Q重量份/每100重量份之成分(Α)(或成分U))祐水 滑石或鹼一鋁複合物(C)的缌數組合在一起,從進一步改 良抗熱性同時保持低溫度抗老化性於在1良程度的観點。 如由稍後出琨的比較飼3所証明*肋外,使用硬矽鈣石當 锻主要安定劑之氯乙烯澍脂組成锪圼現於1 S G t約1 2 G分鐘 的黑化時間和3 G G分鐘之氯化氫捕集時間,當藉®剛果紅 方法澍定時。然而,與當做主要安定劑之本發明定義的细 结晶矽酸鈣组合之氣乙烯樹脂組威物(簧例1 )圼現於190 r約丨iHi分鐘之較短黑化時間和3 6 2分鐘之氯化氳捕集時間 ,當藉虫翊果紅方法測定時,證明優良熱安定作用。 此外,棍據本發明,選擇细结晶矽酸鈣且與水滑石或 相Μ物組合使用顯著地改良熱安定性,如稍後出現之表7 等的'寅例所証明。亦卽,一種每1 0 0 重量份氯乙烯樹脂擦 -9- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 40815ο Α7 修正_B7 Fifth, the description or degradation of the invention description (1), and its temperature conditions and reasons are considered to be much worse. (Please read the notes on the back before filling this page)) According to the invention of benzene, the improvement of the anti-aging property at low temperature was found through the spring test of fine crystalline calcium silicate and isocyanuric acid compound combined at a predetermined ratio. A phenomenon: Although this reason does not limit the present invention at all, Heng generally believes that the pinking & is due to the formation of a slight degree of polyolefinic structure or due to the interaction between osmium crystalline calcium silicate and a chlorine-containing polymer The formation of complexes, and iso-isouric acid compounds are generally used to inhibit the formation or complex formation of multi-olefin structures. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs In the present invention, it is desired that the finely crystalline calcium silicate (A) (or its complex with multiple enzymes U ') and iso-Muric acid hydrazone compound (U) are components The amount of (B) is 3.5 to 5Q parts by weight per 100 parts by weight of the component (A) (or component U)) of the hydrotalcite or the alkali-aluminum complex (C). Improved heat resistance while keeping low temperature aging resistance at a good point. As demonstrated by Comparative Feed 3, which was released later * Extra-costal, the use of xonotlite as the main stabilizer for vinyl chloride resin fat composition is now available at 1 SG t about 1 2 G minutes of blackening time and 3 GG minutes of hydrogen chloride capture time when timed by the ® Congo Red method. However, the gas-vinyl resin composition (spring example 1) combined with the fine crystalline calcium silicate defined by the present invention as the main stabilizer is present at a short blackening time of about 190 iHi minutes and 3 6 2 minutes. The capture time of plutonium chloride was proved to be excellent in thermal stability when measured by the method of maggot fruit red. In addition, according to the present invention, the selection of finely crystalline calcium silicate and the use in combination with hydrotalcite or phase M significantly improved thermal stability, as demonstrated by the examples of Table 7 and the like appearing later. Also, a kind of vinyl chloride resin wipes per 100 parts by weight -9- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 40815ο Α7 Amendment

_B7 五、發明說明(1 ) 之著色或退化,和其被認為是溫度條件和原因差很多。 (請先Μ讀背面之注意事項再填冩本頁) 裉據苯發明',在低溫抗老化性之改良經由組合於預定 比之细结晶矽酸鈣與異観尿酸酷化合物之簧驗两發現之一 種現象:雖然該原因一點也不限制本發明,恒一般認為粉 红著&是由於輕微程度之多烯烴结構的形成或由於绌结晶 矽酸鈣和含氯聚合物之間相互作用所發生的複合物之形成 ,而一般招倌異m尿酸酯化合物抑制多烯烴结構的髟成或 複合_的形威。 經濟部智慧財產局員工消費合作社印製 在本發明中,希望细结晶矽酸鈣(A)(或其與多元酵之 複合物U’))和異Μ尿酸醅化合锪U),是Μ成分(B )之量為 3. 5到5Q重量份/每100重量份之成分(Α)(或成分U))祐水 滑石或鹼一鋁複合物(C)的缌數組合在一起,從進一步改 良抗熱性同時保持低溫度抗老化性於在1良程度的観點。 如由稍後出琨的比較飼3所証明*肋外,使用硬矽鈣石當 锻主要安定劑之氯乙烯澍脂組成锪圼現於1 S G t約1 2 G分鐘 的黑化時間和3 G G分鐘之氯化氫捕集時間,當藉®剛果紅 方法澍定時。然而,與當做主要安定劑之本發明定義的细 结晶矽酸鈣组合之氣乙烯樹脂組威物(簧例1 )圼現於190 r約丨iHi分鐘之較短黑化時間和3 6 2分鐘之氯化氳捕集時間 ,當藉虫翊果紅方法測定時,證明優良熱安定作用。 此外,棍據本發明,選擇细结晶矽酸鈣且與水滑石或 相Μ物組合使用顯著地改良熱安定性,如稍後出現之表7 等的'寅例所証明。亦卽,一種每1 0 0 重量份氯乙烯樹脂擦 -9- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 408156 Α7 Β7 /·· η 五、發明說明($ (請先閱讀背面之注意事項再填寫本頁) 含2盧t汾之水滑石和和其他安定肋劑一起之组成物(比 較例y )圼現於i3(】ic約loo分鐘的黑化時間(直到其被黒色 著色之蒔間)和Γό 4分鐘之氣化簋捕集時間,當以剛果紅方 法潤定時,如稍後出現之表8所示®當硬矽鈣石類型矽駿 鈣Μ (]· 5重量份對上述安定劑之量加入時(比較洌1 〇 ),呈現 约1 () 0分鐘的黑化時間和2 fi 5分鐘之氛化氬捕集時間,像沒 有與矽酸鈣混合時一樣。另一方®,當细结晶矽酸鈣如上 逑情形M Q . 5重量份加人時(實葩例1 3 ),黒化時間被延县到 約1 6 ii分鐘,及氯化姐捕集時間被延長到3 1 2分鐘,証明選 擇裩據本發明细结晶矽酸钙之意義。 經濟部智慧財產局員工消費合作社印製 組合细结晶矽酸鈣與本發明水滑石之意義從稍後出現 之表9也蒔會變成明顯易知。亦即,當细结晶矽酸鈣以 0 . 5重量扮與其他安定勘劑组合使用時(比較例13),在130 它加熱黒化發生1 0分鐘之後,或許因為鋅燃馍和氯化氫捕 捉時間短釦11分鐘。然而*當〇 . 5重量份之量的堀结晶矽酸 鈣與3重量汾之水滑石組合時(茛施例23),甚至在ISGt加 熱13ί)分鐘之後不發生黒化和氯化麗捕案時間驚異地被可延 長為4 e;;分鐘。此外,與當沒有與水滑石混合時比較*電絕 緣性如Μ體積霄阻率考茧被改良十倍以上*從其可了解含 本發明的安定劑之含氯聚合物組成物有效作為電線的覆蓋 材料3 根據本發明,细结晶矽酸钙和多元酵以複合物型式使 用,例如,藉由濕式或共研磨而獲得从協同地改良熟安定 -10- 本紙張尺度適用中國®家標準(CNS)A4規格(210 X 297公爱) 408156 Α7 Β7 /·· η 五、發明說明($ (請先閱讀背面之注意事項再填寫本頁) 含2盧t汾之水滑石和和其他安定肋劑一起之组成物(比 較例y )圼現於i3(】ic約loo分鐘的黑化時間(直到其被黒色 著色之蒔間)和Γό 4分鐘之氣化簋捕集時間,當以剛果紅方 法潤定時,如稍後出現之表8所示®當硬矽鈣石類型矽駿 鈣Μ (]· 5重量份對上述安定劑之量加入時(比較洌1 〇 ),呈現 约1 () 0分鐘的黑化時間和2 fi 5分鐘之氛化氬捕集時間,像沒 有與矽酸鈣混合時一樣。另一方®,當细结晶矽酸鈣如上 逑情形M Q . 5重量份加人時(實葩例1 3 ),黒化時間被延县到 約1 6 ii分鐘,及氯化姐捕集時間被延長到3 1 2分鐘,証明選 擇裩據本發明细结晶矽酸钙之意義。 經濟部智慧財產局員工消費合作社印製 組合细结晶矽酸鈣與本發明水滑石之意義從稍後出現 之表9也蒔會變成明顯易知。亦即,當细结晶矽酸鈣以 0 . 5重量扮與其他安定勘劑组合使用時(比較例13),在130 它加熱黒化發生1 0分鐘之後,或許因為鋅燃馍和氯化氫捕 捉時間短釦11分鐘。然而*當〇 . 5重量份之量的堀结晶矽酸 鈣與3重量汾之水滑石組合時(茛施例23),甚至在ISGt加 熱13ί)分鐘之後不發生黒化和氯化麗捕案時間驚異地被可延 長為4 e;;分鐘。此外,與當沒有與水滑石混合時比較*電絕 緣性如Μ體積霄阻率考茧被改良十倍以上*從其可了解含 本發明的安定劑之含氯聚合物組成物有效作為電線的覆蓋 材料3 根據本發明,细结晶矽酸钙和多元酵以複合物型式使 用,例如,藉由濕式或共研磨而獲得从協同地改良熟安定 -10- 本紙張尺度適用中國®家標準(CNS)A4規格(210 X 297公爱) A7 B7 ;_ . ,_ 五、發明說明(1 ) 性,當與他們Μ簡軍混合物使用時比較。例如,表1 G中所 示,當氛乙烯樹賠Ρ、是與细结晶矽酸鈣,多元醇和水滑石 藺葷摻合時(實施例28),樹脂組成物圼現約120分鐘的黑 化時間耜1 5 S分鐘的氯化氫捕集時間。然而,當细结晶矽 酸鈣和多元醇以一複合物形式®用時(簧疵洌2δ),樹脂组 或物1琨黑化時間被延長到約i 4 G分鐘和氯化氫捕集擾時 間延長到丨3 2分鐘,忽視數量的比是相同的。 [细结晶矽酸鈣j 使用於本發明的绌结晶矽酸鈣具有以上述通式(1)和 上述的X射線繞射圖像之化學組成物。在通式中,X為不 小於0 . 5之數目,祐η為不大於2 . 5之數目,但是希望是〇. 5 到i . ϋ之數目。 當矽石的含量大於此範1時,熱安定性傾向於惡化, 經濟部智慧財產局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁)_B7 Fifth, the description or degradation of the invention description (1), and its temperature conditions and reasons are considered to be much worse. (Please read the notes on the back before filling this page)) According to the invention of benzene, the improvement of the anti-aging property at low temperature was found through the spring test of fine crystalline calcium silicate and isocyanuric acid compound combined at a predetermined ratio. A phenomenon: Although this reason does not limit the present invention at all, Heng generally believes that the pinking & is due to the formation of a slight degree of polyolefinic structure or due to the interaction between osmium crystalline calcium silicate and a chlorine-containing polymer The formation of complexes, and iso-isouric acid compounds are generally used to inhibit the formation or complex formation of multi-olefin structures. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs In the present invention, it is desired that the finely crystalline calcium silicate (A) (or its complex with multiple enzymes U ') and iso-Muric acid hydrazone compound (U) are components The amount of (B) is 3.5 to 5Q parts by weight per 100 parts by weight of the component (A) (or component U)) of the hydrotalcite or the alkali-aluminum complex (C). Improved heat resistance while keeping low temperature aging resistance at a good point. As demonstrated by Comparative Feed 3, which was released later * Extra-costal, the use of xonotlite as the main stabilizer for vinyl chloride resin fat composition is now available at 1 SG t about 1 2 G minutes of blackening time and 3 GG minutes of hydrogen chloride capture time when timed by the ® Congo Red method. However, the gas-vinyl resin composition (spring example 1) combined with the fine crystalline calcium silicate defined by the present invention as the main stabilizer is present at a short blackening time of about 190 iHi minutes and 3 6 2 minutes. The capture time of plutonium chloride was proved to be excellent in thermal stability when measured by the method of maggot fruit red. In addition, according to the present invention, the selection of finely crystalline calcium silicate and the use in combination with hydrotalcite or phase M significantly improved thermal stability, as demonstrated by the examples of Table 7 and the like appearing later. Also, one kind per 100 parts by weight of vinyl chloride resin wiper-9- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 408156 Α7 Β7 / ·· η 5. Description of the invention ($ ( Please read the notes on the back before filling out this page) A composition containing 2 lums of fenite hydrotalcite and other stabilizers (Comparative Example y), now available in i3 (] ic about loo minutes of blackening time ( Until it is stained with black color (Shima) and Γό 4 minutes of gasification time, when it is moisturized by the Congo red method, as shown in Table 8 later. When the xonotlite type silicon silicon calcium calcium ( ] · When 5 parts by weight of the stabilizer is added (compared with 洌 10), a blackening time of about 1 (0) minutes and an argon trapping time of 2 fi 5 minutes are displayed, as if without calcium silicate It is the same when mixing. On the other side, when the fine crystal calcium silicate is MQ as above, when adding 5 parts by weight (Example 13), the curing time is extended to about 16 ii minutes, and the chloride The capture time was extended to 3,12 minutes, proving the significance of choosing the fine crystalline calcium silicate according to the present invention. Member of the Bureau of Intellectual Property, Ministry of Economic Affairs The significance of the printed fine crystalline calcium silicate combined with the hydrotalcite of the present invention printed by the consumer cooperative will become apparent from Table 9 which appears later. That is, when the fine crystalline calcium silicate is 0.5 weight and other stable When used in combination (Comparative Example 13), after 130 minutes of heating and degassing at 130 minutes, it may be because the zinc burning and hydrogen chloride capture time is shorter than 11 minutes. However, when 0.5 parts by weight of osmium crystals When calcium silicate was combined with 3 weights of fenzhi hydrotalcite (Example 23), even after ISGt was heated for 13 d) minutes, no tritium and chlorochloride arrest time was surprisingly extended to 4 e; minutes. In addition, compared with when it is not mixed with hydrotalcite, the electrical insulation properties such as the M dimensional resistivity are improved by more than ten times. From this, it can be understood that the chlorine-containing polymer composition containing the stabilizer of the present invention is effective as an electric wire. Covering material 3 According to the present invention, finely crystalline calcium silicate and polyenzyme are used in a composite form, for example, by wet or co-grinding to synergistically improve cooked stability. -10- This paper size applies Chinese® home standards ( CNS) A4 size (210 X 297 public love 408156 Α7 Β7 / ·· η V. Description of the invention ($ (please read the precautions on the back before filling out this page) Composition containing 2 oz of hydrotalcite and other stabilizers (Comparative Example y) 圼Now the blackening time of i3 () ic is about loo minutes (until it is colored by the black color) and the capture time of 4 minutes of gasification time, when the Congo red method is used, as shown in Table 8 later. Shown® When the xonotlite type silicon calcium M (] · 5 parts by weight is added to the amount of the above-mentioned stabilizer (comparative 洌 1 〇), a blackening time of about 1 () 0 minutes and 2 fi 5 minutes are exhibited Ambient argon capture time is the same as when not mixed with calcium silicate. On the other hand, when fine crystalline calcium silicate is added in the case of MQ. 5 parts by weight (Example 13), the curing time is extended to about 16 ii minutes, and the capture time of chlorinated sister is Extending to 3 1 2 minutes proves the significance of selecting the fine crystalline calcium silicate according to the present invention. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The significance of the combination of finely crystalline calcium silicate and the hydrotalcite of the present invention will become apparent from Table 9 which appears later. That is, when fine crystalline calcium silicate was used in combination with other stabilizers at a weight of 0.5 (Comparative Example 13), after 130 minutes of heating and dehydration occurred for 10 minutes, perhaps due to zinc burning and hydrogen chloride capture time Short deduction for 11 minutes. However, when 0.5 parts by weight of osmium crystalline calcium silicate was combined with 3 parts by weight of fenzhi hydrotalcite (Ranunculus Example 23), no tritification and chlorination cases occurred even after ISGt was heated for 13 d) minutes. The time was surprisingly extended to 4 e; minutes. In addition, compared with when it is not mixed with hydrotalcite, the electrical insulation properties such as MW volume resistance are improved by more than ten times. From this, it can be understood that the chlorine-containing polymer composition containing the stabilizer of the present invention is effective as a wire Covering material 3 According to the present invention, finely crystalline calcium silicate and polyenzyme are used in a composite form, for example, by wet or co-grinding to synergistically improve cooked stability. -10- This paper size applies Chinese® home standards ( CNS) A4 specifications (210 X 297 public love) A7 B7; _., _ 5. Description of the invention (1) When compared with their M Jianjun mixture. For example, as shown in Table 1G, the resin composition was blackened for about 120 minutes when blended with fine crystalline calcium silicate, a polyol, and hydrotalcite (Example 28). Time 耜 15 S minutes of hydrogen chloride capture time. However, when fine crystalline calcium silicate and polyol are used in a composite form (spring defect ®2δ), the blackening time of the resin group or object 1 is extended to about i 4 G minutes and the hydrogen chloride trapping time is extended. By 丨 3 2 minutes, the ratio of neglect quantity is the same. [Fine crystalline calcium silicate j The osmium crystalline calcium silicate used in the present invention has a chemical composition with the above-mentioned general formula (1) and the above-mentioned X-ray diffraction image. In the general formula, X is a number of not less than 0.5, and η is a number of not more than 2.5, but is desirably a number of 0.5 to i. When the content of silica is greater than this range 1, the thermal stability tends to deteriorate, printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page)

與當矽石含量在ifc範圍肉蒔比較。另一方面,當矽石含量 小於ilt範圍時,最初著邑傾向增加,與當矽石含量在此範 圍肉蒔比較:些微水合的鼦结晶矽酸鈣傾尚增加熱安定炸 闱的活性。然而;當水合的量太大時,樹脂傾囱起泡,起 港是令人不想要的C 圖1現示一種使用於本發明之细结晶矽酸鈣的X射線 繞射圖像,和圖2顯示一種具有接近细结晶矽酸鈣之化學 組成物的硬矽鈣石之X射線湞射圖像。從這涸比較,坷了 解本發明的矽酸鈣為细結晶。 使用於本發明的細结晶矽酸鈣的X射線溘射圖像包括 -1 1 - 本紙張尺度適用t國國家標準(CNS>A4規格(210x297公茇〉 A7 B7 ;_ . ,_ 五、發明說明(1 ) 性,當與他們Μ簡軍混合物使用時比較。例如,表1 G中所 示,當氛乙烯樹賠Ρ、是與细结晶矽酸鈣,多元醇和水滑石 藺葷摻合時(實施例28),樹脂組成物圼現約120分鐘的黑 化時間耜1 5 S分鐘的氯化氫捕集時間。然而,當细结晶矽 酸鈣和多元醇以一複合物形式®用時(簧疵洌2δ),樹脂组 或物1琨黑化時間被延長到約i 4 G分鐘和氯化氫捕集擾時 間延長到丨3 2分鐘,忽視數量的比是相同的。 [细结晶矽酸鈣j 使用於本發明的绌结晶矽酸鈣具有以上述通式(1)和 上述的X射線繞射圖像之化學組成物。在通式中,X為不 小於0 . 5之數目,祐η為不大於2 . 5之數目,但是希望是〇. 5 到i . ϋ之數目。 當矽石的含量大於此範1時,熱安定性傾向於惡化, 經濟部智慧財產局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁)Compared with meat dill when silica content is in the ifc range. On the other hand, when the silica content is less than the ilt range, the initial tendency is increased. Compared with when the silica content is in this range, the slightly more hydrated osmium crystalline calcium silicate tends to increase the activity of the thermal stability fry. However, when the amount of hydration is too large, the resin blister foams and the port is undesired. C FIG. 1 shows an X-ray diffraction image of the fine crystalline calcium silicate used in the present invention, and FIG. 2 shows an X-ray diffracted image of xonotlite with a chemical composition close to that of finely crystalline calcium silicate. From this comparison, it is understood that the calcium silicate of the present invention is fine crystals. The X-ray diffracted image of the fine crystalline calcium silicate used in the present invention includes -1 1-This paper size is applicable to the national standard (CNS > A4 specification (210x297) 茇 A7 B7; _., __ V. Invention Explanation (1), when compared with their M Jianjun mixtures. For example, as shown in Table 1G, when the ethylene tree P is blended with fine crystalline calcium silicate, polyol and hydrotalcite (Example 28), the resin composition has a blackening time of about 120 minutes and a hydrogen chloride capture time of 15 S minutes. However, when finely crystalline calcium silicate and a polyhydric alcohol are used in a composite form (spring Defect (2δ), the blackening time of the resin group or object 1 was extended to about i 4 G minutes and the hydrogen chloride trapping time was extended to 32 minutes, and the ratio of the ignored amounts was the same. [Fine crystal calcium silicate j The europium crystalline calcium silicate used in the present invention has a chemical composition with the above-mentioned general formula (1) and the above-mentioned X-ray diffraction image. In the general formula, X is a number not less than 0.5, and η is The number is not greater than 2.5, but is desirably the number from 0.5 to i. Ϋ. When the content of silica is larger than this range 1, Thermal stability tends to deteriorate, printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page)

與當矽石含量在ifc範圍肉蒔比較。另一方面,當矽石含量 小於ilt範圍時,最初著邑傾向增加,與當矽石含量在此範 圍肉蒔比較:些微水合的鼦结晶矽酸鈣傾尚增加熱安定炸 闱的活性。然而;當水合的量太大時,樹脂傾囱起泡,起 港是令人不想要的C 圖1現示一種使用於本發明之细结晶矽酸鈣的X射線 繞射圖像,和圖2顯示一種具有接近细结晶矽酸鈣之化學 組成物的硬矽鈣石之X射線湞射圖像。從這涸比較,坷了 解本發明的矽酸鈣為细結晶。 使用於本發明的細结晶矽酸鈣的X射線溘射圖像包括 -1 1 - 本紙張尺度適用t國國家標準(CNS>A4規格(210x297公茇〉 408156 A7 B7 8y. 6. 年Λ 修正補免 五、發明說明(VC ) 蛘如τ 列表 所市之強線、' 表 1 faj ί A / :.01 - 3.08 相對強度 .78 - .82 i . 8 .84 經濟部智慧財產局員工消費合作社印製 其中ffl表示中等強度,及w表示弱。 從圖1將了解到最強蝶非宮迪寬廣。 在结晶的X光繞射中,其已知強度峰出現干授,當苻 合下列布拉格(3 r a g g )式(4 )時, ηλ= 2dhklsiii9 ... (4) 其中η為度* 為X射繞的被長》dhKl為结晶(hkU的間 隔:秸Θ為嬈射的角。在千擾蜂的銳利和结晶大小之間 ,存在一種以下列謝東i S c h e rre r)式(5 )表示的關係, L h k1 = Κ λ / ί H cos θ ) * * * (5) 其中L hk 1為垂直平面ί hk 1)之方同的结晶一大小,Κ為约 ()· S之常數,Η為千擾墙:的一半寬度(弧度),及λ和S茆上 式【4 )所定義。 當平面U 4 G )的指數的繞射峰的一半寬度(3 . 01到3 . 0 S 埃的間隔)谣從圖1的X光Μ射圖像獲知且结晶大小從符 合上逑式(4)的一半寬度計算時,平面(0 4 ϋ )指數之结晶大 小通m被限制以位於(5 0到1 2 ϋ Α之間。 用於熱安定的矽酸鈣之作用經由结晶表面表示。表面 -12- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) ------------裝--------訂 ---------線 (請先閱讀背面之注t事項再填窝本頁) 408156 A7 B7 8y. 6. 年Λ 修正補免 五、發明說明(VC ) 蛘如τ 列表 所市之強線、' 表 1 faj ί A / :.01 - 3.08 相對強度 .78 - .82 i . 8 .84 經濟部智慧財產局員工消費合作社印製 其中ffl表示中等強度,及w表示弱。 從圖1將了解到最強蝶非宮迪寬廣。 在结晶的X光繞射中,其已知強度峰出現干授,當苻 合下列布拉格(3 r a g g )式(4 )時, ηλ= 2dhklsiii9 ... (4) 其中η為度* 為X射繞的被長》dhKl為结晶(hkU的間 隔:秸Θ為嬈射的角。在千擾蜂的銳利和结晶大小之間 ,存在一種以下列謝東i S c h e rre r)式(5 )表示的關係, L h k1 = Κ λ / ί H cos θ ) * * * (5) 其中L hk 1為垂直平面ί hk 1)之方同的结晶一大小,Κ為约 ()· S之常數,Η為千擾墙:的一半寬度(弧度),及λ和S茆上 式【4 )所定義。 當平面U 4 G )的指數的繞射峰的一半寬度(3 . 01到3 . 0 S 埃的間隔)谣從圖1的X光Μ射圖像獲知且结晶大小從符 合上逑式(4)的一半寬度計算時,平面(0 4 ϋ )指數之结晶大 小通m被限制以位於(5 0到1 2 ϋ Α之間。 用於熱安定的矽酸鈣之作用經由结晶表面表示。表面 -12- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) ------------裝--------訂 ---------線 (請先閱讀背面之注t事項再填窝本頁) 408156 A7 B7 年 五、發明說明(\\ 經濟部智慧財產局員工消费合作社印製 湞隨结晶大小減少而增邡,自然地。因此其將會容易地了 解到本發明细结晶矽酸鈣圼琨優良熱安定:作芾 一般希望網諾晶矽酸鈣具有不小於1 . 7 3,旦特別是, 1 . S到2 . (! 2 Μ下列式(3 )定義之層合不對稱性(I S )的指數, ί s - fc a η Θ 2 / t a η θ t .-. (3} 其中θ t為在3 . ϋ i到3 . G 8埃的間隔之X射線繞射峰垂直 線和窄角之邊的切線所成之角,和Θ 2為在上逑之峰和 廣角之遴的切線所成之角〇 從上述的X射線繞射圖像將明顯可郊,使用於本發明之翅 结晶矽酸鈣為層狀綑结晶形式,且上述層合不對稱性的指 數表示C-釉方商之層合的不規則性程度。層合不對稱性的 指數愈大,不規則性愈大。使用於本發明的细结晶矽酸钙 不規則地層合且,因此,具有大活注表面和圼現用於安定 含氛聚合物之優異作铝。 一般希望使用於本發明之綑结晶矽酸鈣通常具有如該 等包含不大1 (]重量%量之具有不小於4 0 « is之粒子大小和 包含不小於3 0重量%量之具有不大於2 Q w ®之粒子大小的 粒子大小分飭,從均勻地分散在含氯聚合物中和顯示熱安 定效杲的觀點來看。此外,_於粒子的結構,細结晶矽酸 鈣具有6 0到2 0 G公尺2 /克和,特別地,7 0到1 5 0公尺2 / 克之較大比面積,不小於G · 5毫升/克和,特別地,1 . 〇到 4 . G *€升/克之多孔體橫,及3 δ到2 5 0耄升/ 1 〇 ΰ克和,特 別地,3 ϋ到2 G ί)毫升/ Π丨ϋ克的量之吸油量: (請先閱讀背面之沒意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)A4规格(210 X 297公釐) 408156 A7 B7 年 五、發明說明(\\ 經濟部智慧財產局員工消费合作社印製 湞隨结晶大小減少而增邡,自然地。因此其將會容易地了 解到本發明细结晶矽酸鈣圼琨優良熱安定:作芾 一般希望網諾晶矽酸鈣具有不小於1 . 7 3,旦特別是, 1 . S到2 . (! 2 Μ下列式(3 )定義之層合不對稱性(I S )的指數, ί s - fc a η Θ 2 / t a η θ t .-. (3} 其中θ t為在3 . ϋ i到3 . G 8埃的間隔之X射線繞射峰垂直 線和窄角之邊的切線所成之角,和Θ 2為在上逑之峰和 廣角之遴的切線所成之角〇 從上述的X射線繞射圖像將明顯可郊,使用於本發明之翅 结晶矽酸鈣為層狀綑结晶形式,且上述層合不對稱性的指 數表示C-釉方商之層合的不規則性程度。層合不對稱性的 指數愈大,不規則性愈大。使用於本發明的细结晶矽酸钙 不規則地層合且,因此,具有大活注表面和圼現用於安定 含氛聚合物之優異作铝。 一般希望使用於本發明之綑结晶矽酸鈣通常具有如該 等包含不大1 (]重量%量之具有不小於4 0 « is之粒子大小和 包含不小於3 0重量%量之具有不大於2 Q w ®之粒子大小的 粒子大小分飭,從均勻地分散在含氯聚合物中和顯示熱安 定效杲的觀點來看。此外,_於粒子的結構,細结晶矽酸 鈣具有6 0到2 0 G公尺2 /克和,特別地,7 0到1 5 0公尺2 / 克之較大比面積,不小於G · 5毫升/克和,特別地,1 . 〇到 4 . G *€升/克之多孔體橫,及3 δ到2 5 0耄升/ 1 〇 ΰ克和,特 別地,3 ϋ到2 G ί)毫升/ Π丨ϋ克的量之吸油量: (請先閱讀背面之沒意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)A4规格(210 X 297公釐) 408156 A7 i'' _B7 j :: .:Zl 五、發明說明(Y〇() 甲烷,雙(4-甲基卞ss基)甲烷,雙(2-羥基T騮基)甲烷, 〒鼸基丙编,Ετ醢基甲烷,二乙醯基苄醮荃甲烷•硬胞 豳棊节騸基甲烷,钦艏醯基τ鐮基甲烷·月桂發[基苄皤基 Ψ烷,二τ醢基甲烷,雙ί 4 -氛τ醯基)甲烷,雙(亞甲基 -:3,4 -二氧基予_基)甲烷^苄醯基乙醯基苯基甲烷,硬脂 _基([甲氧基τ _基)甲烷,丁醯基丙酮,二硬脂醯基 甲烷,乙醢基丙_ *硬脂醯基丙酮,雙(環己醯基)甲烷* 二ί三甲基乙篚基)弔烷。 上述育餞摻合劑Μ軍一種類使用或組合使用,其希Ε 搔合於1到2 5 0重量%,持別地,1 ί)到2 0 0重量弼和•最希 望,ii)l)到2ΙΗ丨重量%,相對於與週期表第II族的金屬的矽 、酸之鹽。 在本發明的一較佳具體葚施例中,使用於2 U : 3 G到8 0 :2 G和,特別地,3 0 : 7 0到6 0 : 4 Q的重量比之细结晶矽酸 鈣和多元醇的複合物(E )。 此複合物顯著地茂良含氯聚合 鞠的熱安定S,避免最菇著色或鋅燃燒,和圼現小遷移性 質。此複合韧通常藉由濕式一或乾式研磨多元醇和细结晶 矽酸鈣商獲得。 當多元醇的數量變得小於上述範圍時,則最初著色和 鋅燃燒不能抑制到滿意程度。當多元醇的量超過上述範圍 時,遷移柱質傾向於増邡。當做多元酵,較佳使用異戊四 酵或二異戊四酵 [水滑石] -16- 本紙張尺度適用中國國家標準(CNS)A4規格mo X 297公釐) <請先閱讀背面之;i意事項再填寫本頁) 裝·!---- - 訂·------— •綠 經濟部智慧財產局員工消費合作社印製 408156 Λ7 Β7 經濟部中央標準局員工消費合作社印裝 五、發明説明(/>) 细结晶矽酸鈣藉由在石灰乳中细研磨無定形活性矽酸 而產生’然而,其製備沒有任何限制。 一般希望一種使用於本發明的週期表第II族金屬的砂 酸的鹽具有,孔隙或在其表面上,呈琨氯化鋅的掩蔽作用 或整合劑作用的有機摻合劑。 希望地,用於此目的之有機摻合劑將為多元醇 > 鼢類 嗣基酸酯或二嗣。適當的實例如下所述。 亦即,多元酵之實例包括乙二醇,二甘酵,三甘酵, 聚乙二醇’三亞甲基二酵類,四亞甲基二元酵類,六亞甲 垂二醇類,新戊基二酵類,甘油,二甘 異戊四醇,二異戊四醇,甘露酵,山梨糖酵,三羥甲基丙 烷,二三羥甲基丙烷,異氰尿酸酯衍生物,二異戊四醇己 二酸鹽等。 [異氰尿酸酯化合物] 一般希望本發明的異氰尿酸酯化合物為如、τ式;(6)表 示的參(羥烷基)氰尿酸酯,Compared with meat dill when silica content is in the ifc range. On the other hand, when the silica content is less than the ilt range, the initial tendency is increased. Compared with when the silica content is in this range, the slightly more hydrated osmium crystalline calcium silicate tends to increase the activity of the thermal stability fry. However, when the amount of hydration is too large, the resin blister foams and the port is undesired. C FIG. 1 shows an X-ray diffraction image of the fine crystalline calcium silicate used in the present invention, and FIG. 2 shows an X-ray diffracted image of xonotlite with a chemical composition close to that of finely crystalline calcium silicate. From this comparison, it is understood that the calcium silicate of the present invention is fine crystals. The X-ray radiographic image of the fine crystalline calcium silicate used in the present invention includes -1 1-This paper size is applicable to the national standard (CNS > A4 specification (210x297) 茇 408156 A7 B7 8y. 6. Year Λ correction Compensation and exemption V. Description of invention (VC) 蛘 such as the strong line listed in τ list, 'Table 1 faj ί A /: .01-3.08 Relative strength .78-.82 i. 8.84 Employee consumption of the Intellectual Property Bureau of the Ministry of Economic Affairs Cooperative prints where ffl indicates medium intensity, and w indicates weak. From Figure 1, we will know that the strongest butterfly is Fei Gongdi. In the crystal X-ray diffraction, the known intensity peaks appear dry. When combined with the following Prague When (3 ragg) formula (4), ηλ = 2dhklsiii9 ... (4) where η is the degree * is the length of the X-ray beam, and dhKl is the crystal (the interval of hkU: the angle of θ is the angle of the beam. There is a relationship between the sharpness of the bee disturbing and the crystal size, which is expressed by the following Xie Dong i S che rre r) formula (5), L h k1 = κ λ / ί H cos θ) * * * (5) where L hk 1 is the same crystal size of vertical plane hk 1), K is a constant of () · S, Η is the half width (radian) of the interference wall: and λ and S 茆Defined by the above formula [4). When the width of the half of the diffraction peak of the exponent of the plane U 4 G) (the interval from 3.01 to 3.0 S angstroms) is known from the X-ray image of FIG. 1 and the crystal size is in accordance with the above formula (4 When calculating the half width, the crystal size of the plane (0 4 ϋ) index is restricted to m (50 to 1 2 ϋ A). The effect of calcium silicate for thermal stabilization is expressed by the crystal surface. Surface -12- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) ------------ installation -------- order -------- --- line (please read the note t on the back before filling in this page) 408156 A7 B7 8y. 6. Year Λ Correction and Relief V. Invention Description (VC) 蛘 If the τ list is a strong line, 'Table 1 faj ί A /: .01-3.08 Relative intensity .78-.82 i. 8 .84 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, where ffl indicates medium intensity, and w indicates weak. From Figure 1, we will know the strongest Dife Fei Gong Di is broad. In the crystal X-ray diffraction, its known intensity peaks appear dry. When combined with the following Bragg (3 ragg) formula (4), ηλ = 2dhklsiii9 ... (4) where η For degrees * for X-rays 》 DhKl is crystal (interval of hkU: straw Θ is the angle of projection. There is a relationship expressed by the following Xie Dong i S che rre r) (5) between the sharpness of the perturbed bee and the crystal size, L h k1 = Κ λ / ί H cos θ) * * * (5) where L hk 1 is the same crystal size as the vertical plane hk 1), κ is a constant of () · S, and Η is a perturbation Wall: half the width (radian), and λ and S 茆 are defined by the above formula [4]. When the width of the half of the diffraction peak of the exponent of the plane U 4 G) (the interval from 3.01 to 3.0 S angstroms) is known from the X-ray image of FIG. 1 and the crystal size is in accordance with the above formula (4 When calculating the half width, the crystal size of the plane (0 4 ϋ) index is restricted to m (50 to 1 2 ϋ A). The effect of calcium silicate for thermal stabilization is expressed by the crystal surface. Surface -12- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) ------------ installation -------- order -------- --- line (please read the note t on the back before filling in this page) 408156 A7 B7 Year 5. Invention Description (\\ Printed by the Consumers' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, which increases as the size of crystals decreases, naturally Therefore, it will be easy to understand that the fine crystalline calcium silicate of the present invention is excellent in thermal stability: generally, it is expected that the netnolite calcium silicate has not less than 1. 7 3, especially, 1 to 2 (! 2 Μ Index of laminated asymmetry (IS) defined by the following formula (3), s-fc a η Θ 2 / ta η θ t .-. (3) where θ t is at 3. X-rays at intervals of i to 3. G 8 angstroms The angle formed by the vertical line of the diffraction peak and the tangent line of the narrow-angle side, and θ 2 is the angle formed by the tangent line of the upper peak and the wide-angle line. The winged crystalline calcium silicate used in the present invention is in the form of a layered bundle crystal, and the above-mentioned index of lamination asymmetry represents the degree of irregularity of the lamination of the C-glazed square quotient. The larger, the larger the irregularity. The fine crystalline calcium silicate used in the present invention is irregularly laminated and, therefore, has a large injection surface and is excellent for aluminum as a stable atmosphere-containing polymer. It is generally expected to be used in the present invention. Invented bundles of crystalline calcium silicates generally have particle sizes such as those containing not more than 1 (% by weight) with a particle size of not less than 4 0 «is and those containing not less than 30% by weight with a content of not less than 2 Q w ® The particle size of the particle size is from the viewpoint of being uniformly dispersed in the chlorinated polymer and showing thermal stability. In addition, depending on the structure of the particles, fine crystalline calcium silicate has a 60 to 20 G G Feet 2 / gram and, in particular, a large specific area of 70 to 150 meters 2 / gram Not less than G · 5 ml / g and, in particular, 1.0 to 4. G * € liters / gram of porous body cross, and 3 δ to 250 liters / 100 g and, in particular, 3 ϋ Up to 2 G liter) Oil absorption in milliliters / Π 丨 ϋgrams: (Please read the unintentional matter on the back before filling out this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 408156 A7 B7 Year V. Description of Invention (\\ Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, printed with increasing crystal size, naturally. Therefore, it will be easy to understand that the fine crystalline calcium silicate of the present invention is excellent in thermal stability: generally, it is expected that the netnor crystal calcium silicate has not less than 1. 7 3, in particular, 1 to 2. ! 2 Μ Index of laminated asymmetry (IS) defined by the following formula (3), ί s-fc a η Θ 2 / ta η θ t .-. (3) where θ t is between 3. Ϋ i 到3. The angle formed by the vertical line of the X-ray diffraction peaks of the G 8 Angstrom interval and the tangent line of the narrow-angle side, and θ 2 is the angle formed by the tangent line of the upper peak and the wide-angle boundary. The X-ray diffraction image will be obvious. The winged crystalline calcium silicate used in the present invention is in the form of a layered bundle crystal, and the above-mentioned index of lamination asymmetry indicates the irregularity of lamination of the C-glaze quotient. Degree. The larger the index of lamination asymmetry, the greater the irregularity. The fine crystalline calcium silicate used in the present invention is laminated irregularly and, therefore, has a large injection surface and is now used to stabilize atmosphere-containing polymers It is excellent as aluminum. It is generally desired that the bundle of crystalline calcium silicates used in the present invention generally have a content of not less than 1 (]% by weight with an amount of not less than 40 «Is the particle size and particle size fractions containing a particle size of not less than 2 Q w ® in an amount not less than 30% by weight, from the viewpoint of being uniformly dispersed in a chlorinated polymer and showing a thermal stability effect See. In addition, depending on the structure of the particles, fine crystalline calcium silicate has a large specific area of 60 to 20 G meters 2 / g and, in particular, 70 to 150 meters 2 / g, which is not less than G · 5 ml / g and, in particular, 1.0 to 4. G * € liters / gram of porous body cross, and 3 δ to 250 liters / 100 g and, in particular, 3 ϋ to 2 G ί) Oil absorption in ml / Π 丨 ϋg: (Please read the unintentional matter on the back before filling in this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 408156 A7 i '' _B7 j ::.: Zl V. Description of the invention (Y0 () methane, bis (4-methyl 卞 ss group) methane, bis (2-hydroxyT 骝 group) methane, fluorenyl group, Ετ 醢 methylmethane, diethyl 醮 benzyl hydrazine · Hard cell hydrazone methane, hydrazino τ 镰 methane, laurel hair [ylbenzyl hydrazine, diτ 醢 methane, bis ί 4-tau Methane, bis (methylene-: 3,4-dioxypreyl) methane ^ benzylethylethylfluorenylphenylmethane, stearyl _ ((methoxyτ_yl) methane, butanylacetone, Distearylmethane, Ethylpropane_ * stearylacetone, bis (cyclohexyl) methane * bis trimethylethylammonium) pendant. The above-mentioned breeding admixture M is used in a class Or use it in combination, whose combination is from 1 to 250% by weight, in other words, from 1) to 200% by weight and most desirable, ii) from 1) to 2I% by weight, relative to the cycle Table II Group II metals of silicon and acid salts. In a preferred embodiment of the present invention, fine crystalline silicic acid is used in a weight ratio of 2 U: 3 G to 80: 2 G and, in particular, 30:70 to 60: 4Q. Complex of calcium and polyol (E). This compound significantly improves the thermal stability of Maoliang's chlorine-containing polymer, avoids coloration or zinc burning, and exhibits small migration properties. This composite toughness is usually obtained by wet- or dry-grinding a polyol and finely crystalline calcium silicate. When the amount of the polyol becomes smaller than the above range, the initial coloring and zinc combustion cannot be suppressed to a satisfactory degree. When the amount of the polyhydric alcohol exceeds the above range, the migration column tends to be sluggish. As a multi-leaved yeast, it is better to use isoprene four yeast or diisoprene four yeast [hydrotalcite] -16- This paper size is applicable to Chinese National Standard (CNS) A4 specification mo X 297 mm) < Please read the back first; (I will fill in this page again if I want to) -----Order · ------— • Printed by the Employees 'Cooperatives of the Intellectual Property Bureau of the Ministry of Green Economy 408156 Λ7 Β7 Printed by the Employees' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (/ >) Fine crystallization Calcium silicate is produced by finely grinding amorphous active silicic acid in lime milk. However, its preparation is not subject to any restrictions. It is generally desired that an oxalic acid salt of a Group II metal of the periodic table of the present invention has an organic admixture having pores or on its surface that acts as a masking or integrating agent for osmium zinc chloride. Desirably, the organic admixture used for this purpose will be a polyol > fluorene type fluorenyl ester or difluorene. Suitable examples are described below. That is, examples of multiple enzymes include ethylene glycol, di-glycol, tri-glycol, polyethylene glycol'trimethylene di-enzymes, tetra-methylene di-enzymes, hexamethylene diols, new Amyl dienzymes, glycerol, diglycerol, diisopentaerythritol, mannan, sorbose, trimethylolpropane, ditrimethylolpropane, isocyanurate derivatives, di Isopentaerythritol adipate and the like. [Isocyanurate compound] It is generally desirable that the isocyanurate compound of the present invention is represented by the formula: τ; (6) The reference (hydroxyalkyl) cyanurate,

在其中Rl,R2和R3為羥烷基基團。 其較佳實例包括參(經乙基)氰尿酸酷,參(經两基)氰 -1 4 - 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公浼> ---------^.------1Τ------痕 (請先閲讀背面之注意事項再填寫本頁)In which R1, R2 and R3 are hydroxyalkyl groups. Preferable examples include ginseng (via ethyl) cyanurate, ginseng (via two bases) cyanide 1 4-This paper size is applicable to China National Standard (CNS) Α4 specification (210 × 297) > --- ^ .------ 1Τ ------ mark (please read the precautions on the back before filling this page)

經濟部智慧財產局員工消費合作社印製 用K與细结晶矽酸鈣組含的水滑石是一棰合成礦物, 其屬於一槿鋁一鎂氫氯化的碳酸鹽。庾甩一種具γ通式(7 ) Ζ複合物金屬的Μ氧化钧 Μ 2 + X Μ 3 + y ( Ο Η } 2 s + 3 y ' 2 z (A + + ) z · a H 2 0 * * * i 7) 茌其中M2 *為二澴金屬雞子例如jjg之二價離子,¾3 + 為三围金屬離子洌如A丨之三贋離子,p +為二濱陰離子 摔I韵C 〇 s ,和X,y和z為苻合S S X / y会1 / 4和z / s + y > 1 /20之正整數,和” a”為苻合[j.25Sa/x+ysi.[]之數。 在該等複合物金屬的氫氧ib锪之中,一種以式(3)表 示之化合物,Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The hydrotalcite contained in the K and fine crystalline calcium silicate group is a synthetic mineral that belongs to a bismuth aluminum-magnesium hydrochloride carbonate. A kind of Mn oxide with a general formula (7) Zn complex metal M 2 + X Μ 3 + y (〇 Η) 2 s + 3 y '2 z (A + +) z · a H 2 0 * * * i 7) 茌 where M2 * is a divalent metal chicken such as jjg divalent ion, ¾3 + is a three-dimensional metal ion, such as A 丨 trisium ion, p + is a di-anionic anion I C C s, X, y, and z are positive integers combining SSX / y and 1/4 and z / s + y > 1/20, and "a" is the number combining [j.25Sa / x + ysi. [] . Among the hydroxide ib 锪 of these composite metals, a compound represented by formula (3),

His Ai2 (〇H)i ύ (C〇3 )· 4Η2 0 . . . (8} 己卸為求滑石之天然磲物。跆礦物和其相似物可藉由 Kyowa Xagaku iiogyo公司申譴之日本專利公開32193/1972 ,2 e 4 7 7 / 1 3 7 3和2 3 4 7 3 / 1 3 Η所揭示的方法合成。 已矢C該等水滑石和,特別地’ Κ式ί 9 }表示的化合物, M g 4 - 5 · A 12 (〇 Η ) t 3 ( C 0 ΐ ) · 3 Η 2 0 · · * (9) 圼現浦集Ιΐ離子之優良柱質和,因此,可接合於本發明中 遇鹵ib氧酸離子引至其中的水滑石可藉由利用難子在 水滑石可充份分散於水之狀態可容易地被交換的性質,也 就是,_由利用K其他陰難子交換該等碳酸離子的性筲而 被使用。 -17- 本紙張尺度適用令國_家標準(CNS>A4規格(210x297公釐〉 '11 — — — — — —— — — — - t I I I I I I ---1 I - I I I (請先閱讀背面之注意事項再填寫本頁} Λ7 B7 40815。 五、發明説明((汐) 尿酸酯,參(羥丁基)氰尿酸酯,參(2, 3-二控两基)®尿酸 酯,參(縮水甘油基)氮尿酸酯等。 參(羥烷基)氰尿酸酯使用於上逑比例是重要的°當其 量小於上述比例時,在低溫度抗老化性傾向於 '減少’與當 其量在本發明的範圍内時比較。當其量大於上述tfc例時’ 抗熱性傾向於減少*當與其量在本發明範圍内0^ 較° 酚類抗氧化劑之實例包括雙酚A *雙酚B ’雙酿F ’ 2 , 6-二苯基-4-十八烷氧基酚,(3 , 5-二-三级-丁基―4-羥 苯基)丙酸硬脂棊酯,(3,5-二-三級-丁 - 4-羥苯基)膦酸二 硬脂基酯,1,6 -六亞甲基雙(3,5〜二-三级-丁基_4~羥苯基 )丙酸酯,1 ,6-六亞甲基雙(3, 5-二-三级-丁基—I羥苯基) 醯胺丙酸鹽,雙[3,3·•雙(4-羥基-3-三级-丁笨基)丁酸]乙 二醇酯,1,1,3-參(2 -甲基-4-羥基-5-三级-丁苯基)丁酸】 乙二酵酯,1,3、5-參(2 -甲基-4-羥-5-三级-丁苯基)丁烷, 1,3, 5 -參(2,6-二甲基-3-羥基-4-三级-丁苄基)異氟尿酸酯 ,參(3,5-二-三级-丁基-4-羥苄基)異氰尿酸酯, 三乙二醇雙(3 ,5-三级-丁基-4-羥基-5-甲苯棊)丙酸酯], 等等。 点—二_或召-_基酸酯的實例包括1,3 -環己二酮,亞 甲基雙-1,3-環己二嗣’ 2-苄基-1,3-環己二酹,乙醯基四 氣蔡萌’軟脂醯基四氫萘_,硬脂_基四氫萘酮,苄藤基 四氣蔡銅’ 2_乙醯基環己酮,2 -苄醯基環己嗣,2 -乙醯基 酮,雙(苄醯基)甲烷,苄酿基-對-氯苄藤基 ---------1------1Τ------^ (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 環己二 40815ο Λ7 __ΒΤ^五、發明說明(,) 斗Fi ί>' 在本發明中,自然可使用 亦允許使闱Κ鉾改質之水滑石 可使用一種Κ上述通式(?)表 屬離子為M g和Ζ η的姐合,和H g :1秸-特別地,3 : 1到2 注积避免ft初著色。 [鹼一鋁複合物氫氧化物的鹽] 當散使用於本發明的鹼一 洌為鋰一鋁的碳酸Μ,片鈉鋁 酸鹽,或其混合物结晶。 (i,鋰一鋁氫氧化物的碳酸鹽) Μ -鋁複合韧氳氧化物的 :L A ii C S )被假定為一種其中鍵 结構之《氧化鋁之八面體層之 中以補儐電荷者。亦卽,鋰離 平常的Μ S類型水滑石,且其 。當傲Κ _改質的水滑石* 示者,其中+的二1金 :2!1之原子比為9:1到1. .5 : 1 ,鼠予優良的熱安定 鋁氫氧化韧的碳酸鹽,可擧 石類型納一鋁氫氧化韧的碳 (請先閱讀背面之注意事項再填寫本頁) 半 徑,且是一種例外罜罩澴離 經濟部智慧財產局員工消費合作社印敦 鋰離子進入上逑空位置Μ建立 使甩於本發明的鋰一鋁的 碳酸鹽(氬氧化鋰鋁碳酸鹽 難子具有水鋁氧(gibbsite) 空位置,軺陰難子合併在其 子具有陽離子之中的最小的 子的六配位離子:因壯認為 上述的结搆。 碳酸鹽具有一種以下式(1 〇) 表示之组成称 rtl 4 i 2 j - π /i 2 I) 1 A · 1ί ίί 2 0 · { 1 0 ) 在其中X為主要S碳酸基所组成之無機陰離子,M為主 要南If組成之驗金屬,!ϊι為1 . 5到2 . 5之數目,η為Π . 1 到1 =數S ,和k為0到11]之數目, -18 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 408156 A7 i'' _B7 j :: .:Zl 五、發明說明(Y〇() 甲烷,雙(4-甲基卞ss基)甲烷,雙(2-羥基T騮基)甲烷, 〒鼸基丙编,Ετ醢基甲烷,二乙醯基苄醮荃甲烷•硬胞 豳棊节騸基甲烷,钦艏醯基τ鐮基甲烷·月桂發[基苄皤基 Ψ烷,二τ醢基甲烷,雙ί 4 -氛τ醯基)甲烷,雙(亞甲基 -:3,4 -二氧基予_基)甲烷^苄醯基乙醯基苯基甲烷,硬脂 _基([甲氧基τ _基)甲烷,丁醯基丙酮,二硬脂醯基 甲烷,乙醢基丙_ *硬脂醯基丙酮,雙(環己醯基)甲烷* 二ί三甲基乙篚基)弔烷。 上述育餞摻合劑Μ軍一種類使用或組合使用,其希Ε 搔合於1到2 5 0重量%,持別地,1 ί)到2 0 0重量弼和•最希 望,ii)l)到2ΙΗ丨重量%,相對於與週期表第II族的金屬的矽 、酸之鹽。 在本發明的一較佳具體葚施例中,使用於2 U : 3 G到8 0 :2 G和,特別地,3 0 : 7 0到6 0 : 4 Q的重量比之细结晶矽酸 鈣和多元醇的複合物(E )。 此複合物顯著地茂良含氯聚合 鞠的熱安定S,避免最菇著色或鋅燃燒,和圼現小遷移性 質。此複合韧通常藉由濕式一或乾式研磨多元醇和细结晶 矽酸鈣商獲得。 當多元醇的數量變得小於上述範圍時,則最初著色和 鋅燃燒不能抑制到滿意程度。當多元醇的量超過上述範圍 時,遷移柱質傾向於増邡。當做多元酵,較佳使用異戊四 酵或二異戊四酵 [水滑石] -16- 本紙張尺度適用中國國家標準(CNS)A4規格mo X 297公釐) <請先閱讀背面之;i意事項再填寫本頁) 裝·!---- - 訂·------— •綠 經濟部智慧財產局員工消費合作社印製 經濟部智慧財產局員工消費合作社印製 娜X⑽ A7 _B7 五、發明說明(、A) 和 有 m 不於F 列 表 ·) 中 -V X 射 線繞射圖像 表 f-i aa 间 Γ»:·/ m Η [ t \ U ( /Λ ; f文 平®的指數 η .η .Q 到 7 ii I * . ί) -t (002) Λ .0 :Π 到 ί 4 Ά (110) J ;.7 ϋ 到 9 Q Λ t> . u *ί 大 (UQ4) .4 5 到 2.58 中 等 ( 0 0 6 ) *) II * L· ;U 到 2 . 3ϋ 小 (016) 1 .85 到 Γι Λ 〇 t . U 6 小 (017) 1 .40 到 1 Λ 0 X » U ίι 小 ( 3 3 0 ) 1 .38 到 λ λ ς\ 1,40 小 C 6 0 0 ) 鋰- -鋁複含物氫氧化锪的較佳碳酸鹽具有在平靣(01 S )指數之峰不大於1 .G和 在 平 面 (0 i 7)的指數之峰不大於1 . 0 之 1 ( ΫΧ 下 (3 )定義之層合不對稱按(ί s )的指數, Is = t a η θ ζ ,t an β 1 * (3) 其 Φ Θ ί為在 3 . 0 1到 3 , 08埃 的 間隔之X射線繞射蜂垂直 ;r(t: 和 窄 角之邊 的 切 所 或 之 角 ,和Θ2為在上逑之錄和 廣 角 之 邊的切 線 所 成 角 0 使 CCJ 汁1 於本發 明 的 一 鋁 的 碳 酸鹽具育顯示在547,735 * 1004 1 m和 3 4 4 3 公 分 - 1 波 數之大吸收的紅外線吸收 光 PH 0 一 般 希望使 用 於 本 發 明 的 鋰 一鋁氮氧化物的碳酸鹽粒 子 具 有 體積為 基 礎 的 平 均 直 徑 (β s 〇 ),通常,為〇 · 1到 -19- n n n _ i n ^1 n ^1 n n^DJI n ^1 n ^1 tmt n I (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用令國國家標準(CNS)A4規格(210 X 297公釐)His Ai2 (〇H) i ύ (C〇3) · 4Η2 0... (8) has been unloaded as a natural product of talc. Tae mineral and its analogs can be condemned by the Japanese patent of Kyowa Xagaku iiogyo company Publications 32193/1972, 2 e 4 7 7/1 3 7 3 and 2 3 4 7 3/1 3 合成 are synthesized according to the methods disclosed in the above. The hydrotalcites and, in particular, 'K 式 ί 9} Compound, M g 4-5 · A 12 (〇Η) t 3 (C 0 ΐ) · 3 Η 2 0 · · * (9) Because of the excellent columnarity of uranium uranium ions, it can be bonded to this compound In the invention, the hydrotalcite to which the haloib oxyacid ion is introduced can be easily exchanged by using the talc in a state in which the hydrotalcite is fully dispersed in water, that is, by using K other yin It is used for exchanging the properties of these carbonate ions. -17- This paper size applies the national standard (CNS > A4 size (210x297 mm) '11 — — — — — — — — — — t IIIIII- --1 I-III (Please read the notes on the back before filling out this page} Λ7 B7 40815. 5. Description of the invention ((Shi) Uric acid ester, ginseng (hydroxybutyl) cyanurate, ginseng 2,3-Di-control two-base) ® urate, ginseng (glycidyl) nitrourate, etc. The ratio of ginseng (hydroxyalkyl) cyanurate to the upper part is important ° When the amount is less than the above In proportions, the anti-aging resistance at low temperatures tends to be 'reduced' compared to when the amount is within the range of the present invention. When the amount is greater than the above tfc example ', the heat resistance tends to decrease * when the amount is within the range of the present invention Examples of phenolic antioxidants include bisphenol A * bisphenol B 'bis brew F' 2, 6-diphenyl-4-octadecyloxyphenol, (3, 5-di-tertiary- Butyl-4-hydroxyphenyl) stearyl propyl propionate, (3,5-di-tertiary-butyl-4-hydroxyphenyl) distearyl phosphonate, 1,6-hexamethylene Bis (3,5 ~ di-tertiary-butyl-4 ~ hydroxyphenyl) propionate, 1,6-hexamethylenebis (3,5-di-tertiary-butyl-I-hydroxyphenyl) ) Amidopropionate, bis [3,3 · • bis (4-hydroxy-3-tertiary-buttyl) butyric acid] ethylene glycol ester, 1,1,3-ginseng (2-methyl- 4-hydroxy-5-tertiary-butylphenyl) butanoic acid] oxalate, 1,3,5-ginseng (2-methyl-4-hydroxy-5-tertiary-butylphenyl) butane, 1,3,5 -ginseng (2,6-dimethyl-3- Methyl-4-tertiary-butylbenzyl) isofluorourate, ginseng (3,5-di-tertiary-butyl-4-hydroxybenzyl) isocyanurate, triethylene glycol bis (3,5 -Tertiary-butyl-4-hydroxy-5-toluene) propionate], and so on. Examples of dot-di- or di-ortho-esters include 1,3-cyclohexanedione, methylenebis-1,3-cyclohexanedifluorene '2-benzyl-1,3-cyclohexanedifluorene , Ethidium tetrakismin Cai Meng '' stearylpyridinyl tetrahydronaphthalene_ ', stearyl_tetrahydronaphthone, benzyl tetrakistriene copper 2' ethenylcyclohexanone, 2-benzylfluorenyl ring Hexamidine, 2-ethylacetophenone, bis (benzylidene) methane, benzyl-p-chlorobenzyl --------- 1 ------ 1T ----- -^ (Please read the notes on the back before filling out this page) Printed by the Consumers Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs of the People's Republic of China 40815ο Λ7 __ΒΤ ^ V. Description of the Invention (,) Dou Fi ί &'; In the present invention, A hydrotalcite that also allows the modification of 闱 Κ 可 can be used. A kind of Κ of the above general formula (?) Epitope ions is M g and Z η, and H g: 1 straw-in particular, 3: 1 to 2 Conjecture to avoid ft initial coloring. [Salt of Alkali-Aluminium Complex Hydroxide] The alkali-Mg carbonate used in the present invention is lithium-aluminum carbonate M, flake sodium aluminate, or a mixture thereof. (i, carbonate of lithium-aluminum hydroxide) of M-aluminum composite tough oxide: L A ii C S) is assumed to be a kind of "alumina octahedral layer with a bond structure to supplement the charge". Also, lithium ion is the usual MS type hydrotalcite, and its. When proud _ modified hydrotalcite * indicates that the atomic ratio of +2 gold: 2! 1 is 9: 1 to 1. .5: 1, the rat gives excellent heat stable aluminum hydroxide tough carbonic acid Salt, the type of stone can be sodium-aluminum-hydroxide-tough carbon (please read the precautions on the back before filling out this page) radius, and it is an exception. It is separated from the Intellectual Property Bureau of the Ministry of Economic Affairs, the employee consumer cooperative, and the lithium ion of Indo. The upper empty position M establishes a lithium-aluminum carbonate (argon oxide lithium aluminum carbonate refractory material having a gibbsite) empty position, and the Yin Yin refractory material merges in the cation having a cation The smallest hexa-coordination ion: Inzhuang considers the structure described above. Carbonate has a composition represented by the following formula (10): rtl 4 i 2 j-π / i 2 I) 1 A · 1ί ίί 2 0 · {1 0) In which X is an inorganic anion composed mainly of S carbonic acid group, and M is a metal detection composition composed mainly of If. ϊι is a number of 1.5 to 2.5, η is a number of Π. 1 to 1 = number S, and k is a number of 0 to 11], -18 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 408156 A7 i '' _B7 j ::.: Zl V. Description of the invention (Y0 () methane, bis (4-methyl 卞 ss group) methane, bis (2-hydroxyT 骝 group) methane, Benzylpropane, Ετ fluorenyl methane, diethyl sulfonyl benzamidine, methane • hard cell sulfonyl sulfonium methane, cinnyl τ fylmethane, laurel hair [ylbenzyl pentyl methane, di τ Fluorenylmethane, bis (4-ammonium) fluorenyl) methane, bis (methylene-: 3,4-dioxypreyl) methane ^ benzylfluorenylethenylphenylmethane, stearyl_methylene ( [Methoxyτ_yl) methane, butanylacetone, distearylmethylmethane, acetopropylpropyl_ * stearylacetone, bis (cyclohexyl) methane * ditrimethylacetamido) Dane. The above-mentioned breeding admixture M is used in one kind or in combination, and it is blended at 1 to 250% by weight, and in other words, 1) to 200% by weight, and • most hopeful, ii) l) Up to 21% by weight, relative to silicon and acid salts of metals of Group II of the periodic table. In a preferred embodiment of the present invention, fine crystalline silicic acid is used in a weight ratio of 2 U: 3 G to 80: 2 G and, in particular, 30:70 to 60: 4Q. Complex of calcium and polyol (E). This compound significantly improves the thermal stability of Maoliang's chlorine-containing polymer, avoids coloration or zinc burning, and exhibits small migration properties. This composite toughness is usually obtained by wet- or dry-grinding a polyol and finely crystalline calcium silicate. When the amount of the polyol becomes smaller than the above range, the initial coloring and zinc combustion cannot be suppressed to a satisfactory degree. When the amount of the polyhydric alcohol exceeds the above range, the migration column tends to be sluggish. As a multi-leaved yeast, it is better to use isoprene four yeast or diisoprene four yeast [hydrotalcite] -16- This paper size is applicable to Chinese National Standard (CNS) A4 specification mo X 297 mm) < Please read the back first; (I will fill in this page again if I want to) -----Order · ------— • Printed by the Consumers' Cooperatives of the Intellectual Property Bureau of the Ministry of Green Economy Printed by the Consumers ’Cooperatives of the Intellectual Property Bureau of the Ministry of Economy Printed by X⑽ A7 _B7 V. Description of the Invention (, A) and m is not in the F list ·) in the -VX-ray diffraction image table fi aa Γ »: · / m Η [t \ U (/ Λ; f Wenping®'s index η .η .Q to 7 ii I *. ί) -t (002) Λ .0: Π to ί 4 Ά (110) J; .7 ϋ to 9 Q Λ t >. u * ί Large (UQ4) .4 5 to 2.58 Medium (0 0 6) * ) II * L ·; U to 2. 3ϋ small (016) 1. .85 to Γι Λ 〇t. U 6 small (017) 1. 40 to 1 Λ 0 X »U ίι small (3 3 0) 1 .38 To λ λ ς \ 1,40 small C 6 0 0) The preferred carbonate of lithium-aluminum complex rhenium hydroxide has a peak at the level of flat (01 S) index not greater than 1. G and at the plane (0 i 7) The peak of the exponent is not greater than 1.0 of 1 (the exponent of laminated asymmetry according to (ί s) defined by (3 ×), Is = ta η θ ζ, t an β 1 * (3) where Φ Θ ί is at 3.0 1 to 3, 08 Angstroms The spaced X-ray diffracting bees are vertical; r (t: and the tangent or angle of the narrow-angle side, and Θ2 is the angle formed by the tangent line on the upper edge of the record and the wide-angle side. 0 makes CCJ juice 1 in the present invention The aluminum ferric carbonate ferrite shows at 547,735 * 1004 1 m and 3 4 4 3 cm-1 wave number with large absorption of infrared absorbing light PH 0 It is generally desirable to use the lithium-aluminum oxynitride of the present invention Carbonate particles have a volume-based average diameter (β s 〇), which is usually from 0.1 to -19- nnn _ in ^ 1 n ^ 1 nn ^ DJI n ^ 1 n ^ 1 tmt n I (Please read first Note on the back, please fill in this page again) This paper size applies the national standard (CNS) A4 specification (210 X 297 mm)

經濟部智慧財產局員工消費合作社印製 用K與细结晶矽酸鈣組含的水滑石是一棰合成礦物, 其屬於一槿鋁一鎂氫氯化的碳酸鹽。庾甩一種具γ通式(7 ) Ζ複合物金屬的Μ氧化钧 Μ 2 + X Μ 3 + y ( Ο Η } 2 s + 3 y ' 2 z (A + + ) z · a H 2 0 * * * i 7) 茌其中M2 *為二澴金屬雞子例如jjg之二價離子,¾3 + 為三围金屬離子洌如A丨之三贋離子,p +為二濱陰離子 摔I韵C 〇 s ,和X,y和z為苻合S S X / y会1 / 4和z / s + y > 1 /20之正整數,和” a”為苻合[j.25Sa/x+ysi.[]之數。 在該等複合物金屬的氫氧ib锪之中,一種以式(3)表 示之化合物,Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The hydrotalcite contained in the K and fine crystalline calcium silicate group is a synthetic mineral that belongs to a bismuth aluminum-magnesium hydrochloride carbonate. A kind of Mn oxide with a general formula (7) Zn complex metal M 2 + X Μ 3 + y (〇 Η) 2 s + 3 y '2 z (A + +) z · a H 2 0 * * * i 7) 茌 where M2 * is a divalent metal chicken such as jjg divalent ion, ¾3 + is a three-dimensional metal ion, such as A 丨 trisium ion, p + is a di-anionic anion I C C s, X, y, and z are positive integers combining SSX / y and 1/4 and z / s + y > 1/20, and "a" is the number combining [j.25Sa / x + ysi. [] . Among the hydroxide ib 锪 of these composite metals, a compound represented by formula (3),

His Ai2 (〇H)i ύ (C〇3 )· 4Η2 0 . . . (8} 己卸為求滑石之天然磲物。跆礦物和其相似物可藉由 Kyowa Xagaku iiogyo公司申譴之日本專利公開32193/1972 ,2 e 4 7 7 / 1 3 7 3和2 3 4 7 3 / 1 3 Η所揭示的方法合成。 已矢C該等水滑石和,特別地’ Κ式ί 9 }表示的化合物, M g 4 - 5 · A 12 (〇 Η ) t 3 ( C 0 ΐ ) · 3 Η 2 0 · · * (9) 圼現浦集Ιΐ離子之優良柱質和,因此,可接合於本發明中 遇鹵ib氧酸離子引至其中的水滑石可藉由利用難子在 水滑石可充份分散於水之狀態可容易地被交換的性質,也 就是,_由利用K其他陰難子交換該等碳酸離子的性筲而 被使用。 -17- 本紙張尺度適用令國_家標準(CNS>A4規格(210x297公釐〉 '11 — — — — — —— — — — - t I I I I I I ---1 I - I I I (請先閱讀背面之注意事項再填寫本頁} 4〇815〇 _ Ζ 卜6.-ί修正 ----- 一 ---— B7__a fi e .. , _ 五、發明說明(j) ——— <請先閱讀背面之泫意事項再填%本I)His Ai2 (〇H) i ύ (C〇3) · 4Η2 0... (8) has been unloaded as a natural product of talc. Tae minerals and their analogs can be condemned by the Japanese patent of Kyowa Xagaku iiogyo company. Publications 32193/1972, 2 e 4 7 7/1 3 7 3 and 2 3 4 7 3/1 3 合成 are synthesized according to the methods disclosed in the above. The hydrotalcites and, in particular, 'K 式 ί 9} Compound, M g 4-5 · A 12 (〇Η) t 3 (C 0 ΐ) · 3 Η 2 0 · · * (9) Because of the excellent columnarity of uranium uranium ions, it can be bonded to this compound In the invention, the hydrotalcite to which the haloib oxyacid ion is introduced can be easily exchanged by using the talc in a state in which the hydrotalcite is fully dispersed in water, that is, by using K other yin It is used for exchanging the properties of these carbonate ions. -17- This paper size applies the national standard (CNS > A4 size (210x297 mm) '11 — — — — — — — — — — t IIIIII- --1 I-III (Please read the notes on the back before filling in this page} 4〇815〇_ 卜 6.-ί Correction ----- I ----- B7__a fi e .., _ V. Description of the invention (j) —— — ≪ Please read the notice on the back before filling in% I)

Ul ϋ IB和,持別地,f) · ί到3 /i HI ,(J . 1到G , 3 5克/公分3 和,特別地,β . K到I) . δ克/公分3的鬆密度,如M J S P K 672i剽爱’具有ID到7[]公尺2 /克之BET比表靣積,和 小如41)到Ή丨毫升/ 10ϋ克之吸油量, 雖然不必僅限制於其中,鋰—鋁氫氧化物的碳駿鹽偽 籍由一種無定形或假勃母石類型水合氧ib鋁凝髎與鋰之碳 酸鹽或碳酸氮鹽在一求性介質中,於當反懕完成時於其中 氧fb鋁(A丨2 1)3 )的濃度從i變到5重量%,和pH從7變 到Π (K下時常簡稱為水合氧化鋁凝膠法)之條件反應,或 繪由一種其中水鋁氧類型氫氧化鋁之细粒子與一種可形成 碳酸或碳酸離子的鋰鹽或鋰離子之鋰化合物的組合物,在 水存在下反應,亦卽藉甶遷移法,而製鹿。 U .納-鋁氫氧化物的碳酸鹽) 使用於本發明的片訥鋁石類型之納-鋁氫氧化物的碳 酸鹽U a -鋁氫氧化物碳酸鹽:N A H C S )具有以下列式 U 1)表示之組成物* B A12 〇 3 * π Μ 2 0 · X * kHz 〇 ... (11) 經濟部智慧財產局員工消費合作社印製 其中X為主要由碳酸離子所組成之無櫳陰雞子,Μ為主 要由納所組成之驗金屬,m為是許多〇 · 5到1· . 5之敷目’ η為β · 1到].之數目,和k為0到3之數目ΰ Η納鋁石類型结晶结構係指該等罝質上具有與藉由使 用Cu- α 之X射線分析中的下列表3所示之X光繞射圖镓 相同者, -ζη- 本紙張尺度適用中國國家標準(CNS)A4規格(210x297公釐) 40815ο Λ7 __ΒΤ^五、發明說明(,) 斗Fi ί>' 在本發明中,自然可使用 亦允許使闱Κ鉾改質之水滑石 可使用一種Κ上述通式(?)表 屬離子為M g和Ζ η的姐合,和H g :1秸-特別地,3 : 1到2 注积避免ft初著色。 [鹼一鋁複合物氫氧化物的鹽] 當散使用於本發明的鹼一 洌為鋰一鋁的碳酸Μ,片鈉鋁 酸鹽,或其混合物结晶。 (i,鋰一鋁氫氧化物的碳酸鹽) Μ -鋁複合韧氳氧化物的 :L A ii C S )被假定為一種其中鍵 结構之《氧化鋁之八面體層之 中以補儐電荷者。亦卽,鋰離 平常的Μ S類型水滑石,且其 。當傲Κ _改質的水滑石* 示者,其中+的二1金 :2!1之原子比為9:1到1. .5 : 1 ,鼠予優良的熱安定 鋁氫氧化韧的碳酸鹽,可擧 石類型納一鋁氫氧化韧的碳 (請先閱讀背面之注意事項再填寫本頁) 半 徑,且是一種例外罜罩澴離 經濟部智慧財產局員工消費合作社印敦 鋰離子進入上逑空位置Μ建立 使甩於本發明的鋰一鋁的 碳酸鹽(氬氧化鋰鋁碳酸鹽 難子具有水鋁氧(gibbsite) 空位置,軺陰難子合併在其 子具有陽離子之中的最小的 子的六配位離子:因壯認為 上述的结搆。 碳酸鹽具有一種以下式(1 〇) 表示之组成称 rtl 4 i 2 j - π /i 2 I) 1 A · 1ί ίί 2 0 · { 1 0 ) 在其中X為主要S碳酸基所组成之無機陰離子,M為主 要南If組成之驗金屬,!ϊι為1 . 5到2 . 5之數目,η為Π . 1 到1 =數S ,和k為0到11]之數目, -18 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 408156 B7五、發明說明(I) 表 3 nvi / m { 相對強度 平面的指數 VS (001) .3 8 ill ( 0 2 0 ) π η .U ώ ϊδ ί〇13) .78 π (121) .fi 1 m ( 0 0 4 } .5 w (211) .1 5 w ( 2 2 0 ) .Β9 in (015) • 73 w (231} .69 31 (125)- (Q40 (讀先閱續背面之注意事項再填寫本頁) 裝--- 經濟部智慧財產局員工消費合作社印製 在其中VS表示非常強,S表示強,IB表示中等強度, 及W表7F弱。 Η鈉鋁石在高於3 ϋ G υ溫度之熱重分析中啻質上沒有 損失重量,且因此其被用以防土在捏合或模製樹脂期間發 Η鈉鋁石類型结晶结構的鈉一鋁複合锪氫氧化饬之碳 酸鹽具有茌Cui Ζ X光繞射圖像中不小於G . 4度之平面( sm)的指數之峰的一半寬度,且當其形成5重量%的馮度 的水拄漿疲時圼琨不大於S G ϋ 0 Ω ·公分之電阻率。 使用於本發明之鈉鋁氬氧ib物碳酸鹽,大的平面([Π 1) 指數之峰一半寬度表示在ί]-铀(在鱺維軸方向)方向之结晶 -Π- 訂--------竣 本紙張尺度適用中國國家標準(CNS)A4規格(210 * 297公釐) 經濟部智慧財產局員工消費合作社印製 娜X⑽ A7 _B7 五、發明說明(、A) 和 有 m 不於F 列 表 ·) 中 -V X 射 線繞射圖像 表 f-i aa 间 Γ»:·/ m Η [ t \ U ( /Λ ; f文 平®的指數 η .η .Q 到 7 ii I * . ί) -t (002) Λ .0 :Π 到 ί 4 Ά (110) J ;.7 ϋ 到 9 Q Λ t> . u *ί 大 (UQ4) .4 5 到 2.58 中 等 ( 0 0 6 ) *) II * L· ;U 到 2 . 3ϋ 小 (016) 1 .85 到 Γι Λ 〇 t . U 6 小 (017) 1 .40 到 1 Λ 0 X » U ίι 小 ( 3 3 0 ) 1 .38 到 λ λ ς\ 1,40 小 C 6 0 0 ) 鋰- -鋁複含物氫氧化锪的較佳碳酸鹽具有在平靣(01 S )指數之峰不大於1 .G和 在 平 面 (0 i 7)的指數之峰不大於1 . 0 之 1 ( ΫΧ 下 (3 )定義之層合不對稱按(ί s )的指數, Is = t a η θ ζ ,t an β 1 * (3) 其 Φ Θ ί為在 3 . 0 1到 3 , 08埃 的 間隔之X射線繞射蜂垂直 ;r(t: 和 窄 角之邊 的 切 所 或 之 角 ,和Θ2為在上逑之錄和 廣 角 之 邊的切 線 所 成 角 0 使 CCJ 汁1 於本發 明 的 一 鋁 的 碳 酸鹽具育顯示在547,735 * 1004 1 m和 3 4 4 3 公 分 - 1 波 數之大吸收的紅外線吸收 光 PH 0 一 般 希望使 用 於 本 發 明 的 鋰 一鋁氮氧化物的碳酸鹽粒 子 具 有 體積為 基 礎 的 平 均 直 徑 (β s 〇 ),通常,為〇 · 1到 -19- n n n _ i n ^1 n ^1 n n^DJI n ^1 n ^1 tmt n I (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用令國國家標準(CNS)A4規格(210 X 297公釐) 408156 A7 _________ Β7__;_五、發明說明(w) 大小是的: $ —般的η納鋁石中,具有常大外観比之细繼維束像 與_ 一起Μ使形成粗键细绦球狀二级的粒子。然而,在上 述的Η鈉鋁石中,纖誰结構發展得非常差,和該等所髟成 的二级的粒子被小程度地絜凝。 關於粒子.之肜狀,片鈉鋁石,一般,圼現了 〇到〗{){]毫 升/ i g ϋ克之較大吸湳量5然而,較佳使周於本發明的片 鈉銘石圼現不小於4 ϋ毫升/ 1 ti α克之但小於7 ϋ橐开/ 1 ο 〇兒 的吸油量。面且,茌前者片納鋁石中之顏料的體積澀度為 少節3 3 %或較少=而後者的片鈉鋁石的體積濃度則高如4 〇 到 5 0%。 進一步希望本發明的ϋ納銘石類型的納—錯蟹氣化勸 的碳酸盥粒子具有通常,〇 . 1到1 〇激米和,特別地,g ·Ul ϋ IB and, separately, f) · ί to 3 / i HI, (J. 1 to G, 35 g / cm 3 and, in particular, β. K to I). Δ g / cm 3 Bulk density, such as MJSPK 672i 剽 'has a BET ratio product of ID to 7 [] meters 2 / gram, and as small as 41) to Ή 丨 ml / 10 gram of oil absorption, although it is not necessary to limit it only, lithium — The carbon salt of aluminum hydroxide is composed of an amorphous or pseudoboehmite-type hydrated oxygen ib aluminum condensate and lithium carbonate or nitrogen carbonate in a demanding medium, where the reaction is completed. The concentration of oxygen fb aluminum (A 丨 2 1) 3) is changed from i to 5% by weight, and the pH is changed from 7 to Π (often referred to as the hydrated alumina gel method under K), or by drawing one of them The composition of fine particles of aluminum hydroxide type aluminum hydroxide and a lithium salt or lithium compound capable of forming carbonic acid or carbonate ion reacts in the presence of water, and also uses the migration method to make deer. U. Carbonate of nano-aluminum hydroxide) Carbonate of sodium-aluminum hydroxide of the genite type used in the present invention U a-Aluminum hydroxide carbonate: NAHCS) has the following formula U 1 ) * B A12 〇3 * π Μ 2 0 · X * kHz 〇 ... (11) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, where X is a non-yin chicken composed mainly of carbonate ions , M is a test metal mainly composed of sodium, m is a number of a number of 0.5 to 1.5, η is β · 1 to]., And k is a number of 0 to 3 Stone type crystal structure refers to those materials which have the same X-ray diffraction pattern as shown in Table 3 below in X-ray analysis using Cu-α gallium, -ζη- This paper scale applies Chinese national standards (CNS) A4 specification (210x297 mm) 40815ο Λ7 __ΒΤ ^ V. Description of the invention (,) Dou Fi ί > 'In the present invention, a hydrotalcite that also allows 闱 Κ 鉾 to be modified may use one kind of κ. The general formula (?) Indicates that the ions are the combination of M g and Z η, and H g: 1-in particular, 3: 1 to 2 injections to avoid ft initial coloring[Salt of Alkali-Aluminium Complex Hydroxide] The alkali-Mg carbonate used in the present invention is lithium-aluminum carbonate M, flake sodium aluminate, or a mixture thereof. (i, carbonate of lithium-aluminum hydroxide) of M-aluminum composite tough oxide: L A ii C S) is assumed to be a kind of "alumina octahedral layer with a bond structure to supplement the charge". Also, lithium ion is the usual MS type hydrotalcite, and its. When proud _ modified hydrotalcite * indicates that the atomic ratio of +2 gold: 2! 1 is 9: 1 to 1. .5: 1, the rat gives excellent heat stable aluminum hydroxide tough carbonic acid Salt, the type of stone can be sodium-aluminum-hydroxide-tough carbon (please read the precautions on the back before filling out this page) radius, and it is an exception. It is separated from the Intellectual Property Bureau of the Ministry of Economic Affairs, the employee consumer cooperative, and the lithium ion of Indo. The upper empty position M establishes a lithium-aluminum carbonate (argon oxide lithium aluminum carbonate refractory material having a gibbsite) empty position, and the Yin Yin refractory material merges in the cation having a cation The smallest hexa-coordination ion: Inzhuang considers the structure described above. Carbonate has a composition represented by the following formula (10): rtl 4 i 2 j-π / i 2 I) 1 A · 1ί ίί 2 0 · {1 0) In which X is an inorganic anion composed mainly of S carbonic acid group, and M is a metal detection composition composed mainly of If. ϊι is a number of 1.5 to 2.5, η is a number of Π. 1 to 1 = number S, and k is a number of 0 to 11], -18 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 408156 B7 V. Description of the invention (I) Table 3 nvi / m {Index of relative intensity plane VS (001). 3 8 ill (0 2 0) π η .U ώδ ί〇13) .78 π (121) .fi 1 m (0 0 4) .5 w (211) .1 5 w (2 2 0) .B9 in (015) • 73 w (231) .69 31 (125)-(Q40 (Read Read the precautions on the back of the page before filling out this page.) Packing --- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, where VS is very strong, S is strong, IB is medium strength, and W 7F is weak. There is no weight loss of bauxite in thermogravimetric analysis at temperatures above 3 ϋ G υ, and therefore it is used to prevent the sodium-aluminum complex of the fusiformite type crystal structure during soil kneading or molding of the resin The rhenium hydroxide carbonate has a half width of the peak of the exponent in the Cui Z X-ray diffraction image that is not less than G. 4 degrees in plane (sm), and when it forms 5% by weight of water No more than SG when pulp fatigue ϋ 0 Ω · Resistivity in cm. The sodium aluminum argon oxide ib carbonate used in the present invention has a large plane ([Π 1) half the width of the peak of the index expressed in the direction of ί] -uranium (in the direction of the plutonium axis). Crystallization-Π- Order -------- Completion The paper size applies the Chinese National Standard (CNS) A4 specification (210 * 297 mm) Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs X⑽ A7 _B7 V. Description of the invention (, A) and there are m not in F list ·) -VX ray diffraction image table fi aa Γ »: · / m Η [t \ U (/ Λ; f Wenping®'s index η .η .Q to 7 ii I *. Ί) -t (002) Λ .0: Π to ί 4 Ά (110) J; .7 ϋ to 9 Q Λ t >. U * ί 大 (UQ4) .4 5 to 2.58 Medium (0 0 6) *) II * L ·; U to 2. 3ϋ small (016) 1. 85 to Γι Λ 〇t. U 6 small (017) 1. 40 to 1 Λ 0 X »U ίι small (3 3 0) 1.38 to λ λ ς \ 1,40 small C 6 0 0) The preferred carbonate of the lithium-aluminum complex rhenium hydroxide has a peak at the level of (01 S) index which is not greater than 1.G and in peace The peak of the index of the plane (0 i 7) is not greater than 1.0 of 1 (the exponent of the laminated asymmetry defined by (3) below (3)), Is = ta η θ ζ, t an β 1 * ( 3) Its Φ Θ is perpendicular to the X-ray diffracting bee at an interval of 3.01 to 3, 08 angstroms; r (t: is the tangent or angle of the narrow-angled edge, and Θ2 is the upper one The angle formed by the tangent to the wide-angle side of the recording angle 0 makes the CCJ Juice 1 an aluminum carbonate fermenter of the present invention shown at 547,735 * 1004 1 m and 3 4 4 3 cm-1 wave number with large absorbed infrared rays Absorbed light PH 0 It is generally desirable that the carbonate particles of lithium-aluminum oxynitride used in the present invention have a volume-based average diameter (β s 〇), usually, from 0.1 to -19- nnn _ in ^ 1 n ^ 1 nn ^ DJI n ^ 1 n ^ 1 tmt n I (Please read the precautions on the back before filling this page) This paper size applies the national standard (CNS) A4 (210 X 297 mm) 408156 A7 _________ Β7__; _V. Description of the invention (w) The size is: $ —The average η nano-alumite has a large size. Sightseeing than the fine fiber bundle as the following _ two together forming Μ key coarse particles fine spherical sash. However, in the above-mentioned arsenite, the structure of the fiber is very poor, and the secondary particles formed by these are condensed to a small extent. Regarding the shape of the particles, the sodalite is generally found to have a large absorption amount of 0 to 〖{} {] ml / ig gram 5. However, it is preferable to use the sodalite arsenite according to the present invention. Now it is not less than 4 milliliters / 1 ti α grams but less than 7 milliliters / 1 ο 〇 children. In addition, the volume astringency of the pigments in the former schizophyllite is 33% or less =, while the volume concentration of the latter's schizophyllite is as high as 40 to 50%. It is further desirable that the carbonated particles of the Na-scrab gasification type of the onyxite type of the present invention have a normal, 0.1 to 10, and, in particular, g ·

3歡米之K體積為基準之平均直徑(D 當以散射繞射 經濟部智慧財產局員工消費合作社印製 的雷射方法溯量時,毫丹/i0G克之吸油量(jps Κ-5ΗΠ,3ϋ到 lii)公尺 Z / 1〇〇克之 u L1比表面積,相ΰ. 到m克/公分3表観比重(網筒法): 雖然不必僅跟制於其中,Η納叙π赖 幻蝴型之鈉一鋁氪氧 ib物的碳酸鹽係籍由使周碳睃納作& Ώ Κ替碳酸鋰Μ上述水合氧 化鋁凝膠方法製餚。 插S使用碳酸鈉和碳酸理跑,趣& -、_嚴欲與無定形或跤勃母 石類型的水含氧化鋁水反應之齡_ & 明,巨合,獲得一種包含 UKCS和片納鋁石的混合结晶之_ 22- 18複含物氫氯化物的碳 本紙張尺度適用令因國家標準(CNS)A4規格(210x 297 --- - -----^------t--------訂---------線 (請先閱讀背面之>£意事項再填寫本頁) 4〇815〇 _ Ζ 卜6.-ί修正 ----- 一 ---— B7__a fi e .. , _ 五、發明說明(j) ——— <請先閱讀背面之泫意事項再填%本I)The average diameter based on the K volume of 3 meters (D When traced by the laser method printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economics and Scattering and Diffraction, the oil absorption in millidan / i0G grams (jps KK-5ΗΠ, 3 To li) Metric Z / 100 grams of specific surface area of u L1, relative to. To m grams / cm 3 table specific gravity (mesh tube method): Although it is not necessary to follow only it, it is not satisfied The carbonate of sodium-aluminum hydroxide is prepared by using carbon dioxide as the carbon dioxide and lithium carbonate as described in the above hydrated alumina gel method. Insert sodium carbonate and carbonic acid to run, fun &-, _ Age of reaction with alumina or water containing amorphous or womerite type _ & Ming, Juhe, to obtain a mixed crystal containing UKCS and monopyrite _ 22- 18 complex Hydrocarbon-containing carbon paper size is applicable due to the national standard (CNS) A4 specification (210x 297 ------------------ t -------- order- -------- line (please read the > £ on the back before filling in this page) 4〇815〇_ 卜 6.-ί amendment ----- --- B7__a fi e .., _ V. Invention Description (j) ——— < Hyun precautions on the back of this refill% I)

Ul ϋ IB和,持別地,f) · ί到3 /i HI ,(J . 1到G , 3 5克/公分3 和,特別地,β . K到I) . δ克/公分3的鬆密度,如M J S P K 672i剽爱’具有ID到7[]公尺2 /克之BET比表靣積,和 小如41)到Ή丨毫升/ 10ϋ克之吸油量, 雖然不必僅限制於其中,鋰—鋁氫氧化物的碳駿鹽偽 籍由一種無定形或假勃母石類型水合氧ib鋁凝髎與鋰之碳 酸鹽或碳酸氮鹽在一求性介質中,於當反懕完成時於其中 氧fb鋁(A丨2 1)3 )的濃度從i變到5重量%,和pH從7變 到Π (K下時常簡稱為水合氧化鋁凝膠法)之條件反應,或 繪由一種其中水鋁氧類型氫氧化鋁之细粒子與一種可形成 碳酸或碳酸離子的鋰鹽或鋰離子之鋰化合物的組合物,在 水存在下反應,亦卽藉甶遷移法,而製鹿。 U .納-鋁氫氧化物的碳酸鹽) 使用於本發明的片訥鋁石類型之納-鋁氫氧化物的碳 酸鹽U a -鋁氫氧化物碳酸鹽:N A H C S )具有以下列式 U 1)表示之組成物* B A12 〇 3 * π Μ 2 0 · X * kHz 〇 ... (11) 經濟部智慧財產局員工消費合作社印製 其中X為主要由碳酸離子所組成之無櫳陰雞子,Μ為主 要由納所組成之驗金屬,m為是許多〇 · 5到1· . 5之敷目’ η為β · 1到].之數目,和k為0到3之數目ΰ Η納鋁石類型结晶结構係指該等罝質上具有與藉由使 用Cu- α 之X射線分析中的下列表3所示之X光繞射圖镓 相同者, -ζη- 本紙張尺度適用中國國家標準(CNS)A4規格(210x297公釐) 408156 A7 B7 89. 6. 年月 經濟部智慧財產局員工消費合作社印製 五、發明說明(y\) f-ι^ Μ ν L A H G S和Η訥鋁石類AK C S可直接地混合在含氯聚合 物中-為了改良複合物SI之表面特性,從改良樹詣分散和 改良光傳輸性質的観點,表面可預先K於不大於1 ϋ重量% 和,特別池=1到6重量%之表®處理劑處理。 當傲表®處理劑,視標的锪而定可使用矽烷,鋁,I太 或諄|高級脂肪酸,金羼鈀皂或樹脂酸肥皂,细粉化無定 肜矽石或界®活性劑之類型的课合劑。 一般,希望加入高級脂肪酸或界面活性劏至一橿進行 Μ拌處理之包含鹼一鋁複合锪的氫氧化物之碳酸鹽的反憑 母溶寂中。 這箜水滑石或鹼一 is複合物m氧化物的鹽可μ軍一種 類使闱或以ΰ . 5到5 0份/每1 (] Q重量份上逑成分(A)(或(D ) 或U))和(C)之缌重量扮的量组合使兩。 [高鈒脂訪酸鋅] 根據本發明,除該等上述基本成分之外,希E進一步 接合i F ) 5到7 β重量汾和,特別地,1 0到5 ί)重量份之量的 高Μ脂肪酸鋅,每ίϋϋ重量份之成分(Α)(或(D)或(Ε))和(C 之總數。加入上述的成分(F)使其丐能有效地避免暖色的 最初著色。 用於形成鋅1的腊肪酸將為具育8到2 2個碳原子,特 別地,8到1 4 ϋ碳原子和,最希望地,8到I 2個碳原子之 不飽和脂肪酸,也就是,飽和脂肪酸洌韶辛酸,癸酸,十 3- 本紙張尺度適用中國國家標準(CNS)A4規格(210x297公釐) (請先閲讀背面之;£.意事項再填寫本頁) 裝 訂---------線 408156 B7五、發明說明(I) 表 3 nvi / m { 相對強度 平面的指數 VS (001) .3 8 ill ( 0 2 0 ) π η .U ώ ϊδ ί〇13) .78 π (121) .fi 1 m ( 0 0 4 } .5 w (211) .1 5 w ( 2 2 0 ) .Β9 in (015) • 73 w (231} .69 31 (125)- (Q40 (讀先閱續背面之注意事項再填寫本頁) 裝--- 經濟部智慧財產局員工消費合作社印製 在其中VS表示非常強,S表示強,IB表示中等強度, 及W表7F弱。 Η鈉鋁石在高於3 ϋ G υ溫度之熱重分析中啻質上沒有 損失重量,且因此其被用以防土在捏合或模製樹脂期間發 Η鈉鋁石類型结晶结構的鈉一鋁複合锪氫氧化饬之碳 酸鹽具有茌Cui Ζ X光繞射圖像中不小於G . 4度之平面( sm)的指數之峰的一半寬度,且當其形成5重量%的馮度 的水拄漿疲時圼琨不大於S G ϋ 0 Ω ·公分之電阻率。 使用於本發明之鈉鋁氬氧ib物碳酸鹽,大的平面([Π 1) 指數之峰一半寬度表示在ί]-铀(在鱺維軸方向)方向之结晶 -Π- 訂--------竣 本紙張尺度適用中國國家標準(CNS)A4規格(210 * 297公釐) 408156 Α7 Β7 修正 經濟部智慧財產局員工消費合作社印製 五、發明說明(yy) 一酸•月桂烯酸或肉豆蔻酸,或不葩和脂肪酸例如林德酸 •粗租(Tsuzuic)酸’岩芹酸,油酸,亞油酸,亞麻酸, 和7£生巧烯酸。其&允許使用硬脂酸,棕擱酸或相Μ 33酸 。然而:從避免鋅燃镜之観點,希望使用低級脂肪酸。從 滏定ί生的観點,希望ί吏闬筢和脂訪酸,旦月桂烯酸是最希 Μ的。脂肪酸坷為_肪酸之混合衙例抝椰子油和g旨訪酸或 综擱油和脂肪酸 這些脂肪酸鹽也用ί乍為潤滑劑且希望應為一般鹽類。 [齩類抗氧化麵Μ 竑外,除上述之总要成分之外,本發明亦希望使用, ί G )於1到5 0重量份和,特別地,2到2 0重量份之量的酚 類抗氧化劏,每i 0 G S量份之成分U )(或(D )或(Ε))和(C)之 缌數。抗氧化劑有效抑制虫鍵反應引起的降解作用。 ί乍為使吊於本發明的鼢類抗氧化劏,可使用任何的一 涸上述所到舉者,雙鼢類抗氧化劑或位姐醅類抗氧化劑。 其中,雙鼢A為特佳者。 這呰酚類抗氧化劑珂獨自或K組合使爾。 Γ r^· SP-T -w- ΛΙτ /Λ - 3C&T Ί ι ρ ~m ^ m m ρ j 竑外,棍據本發明,除該等上述必要成分之外,可被 接合[K 5到3 0重量份和·特別昽I 1到1 5重量份,之(Η Μ __基_酸酷或召-二_ *每ΙϋΟ重量份成分(A),(D)或(Ε)和 ί C )之缌數:接合/i - _基-酸酷或厶-二_ Κ改良熱安定性 和爵初著色。 -24- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) ----------- . * I t t ( ---訂.---— — 1J·.^ (請先閱讀背面之注意事項再填寫本頁) 408156 A7 _________ Β7__;_五、發明說明(w) 大小是的: $ —般的η納鋁石中,具有常大外観比之细繼維束像 與_ 一起Μ使形成粗键细绦球狀二级的粒子。然而,在上 述的Η鈉鋁石中,纖誰结構發展得非常差,和該等所髟成 的二级的粒子被小程度地絜凝。 關於粒子.之肜狀,片鈉鋁石,一般,圼現了 〇到〗{){]毫 升/ i g ϋ克之較大吸湳量5然而,較佳使周於本發明的片 鈉銘石圼現不小於4 ϋ毫升/ 1 ti α克之但小於7 ϋ橐开/ 1 ο 〇兒 的吸油量。面且,茌前者片納鋁石中之顏料的體積澀度為 少節3 3 %或較少=而後者的片鈉鋁石的體積濃度則高如4 〇 到 5 0%。 進一步希望本發明的ϋ納銘石類型的納—錯蟹氣化勸 的碳酸盥粒子具有通常,〇 . 1到1 〇激米和,特別地,g ·Ul ϋ IB and, separately, f) · ί to 3 / i HI, (J. 1 to G, 35 g / cm 3 and, in particular, β. K to I). Δ g / cm 3 Bulk density, such as MJSPK 672i 剽 'has a BET ratio product of ID to 7 [] meters 2 / gram, and as small as 41) to Ή 丨 ml / 10 gram of oil absorption, although it is not necessary to limit it only, lithium — The carbon salt of aluminum hydroxide is composed of an amorphous or pseudoboehmite-type hydrated oxygen ib aluminum condensate and lithium carbonate or nitrogen carbonate in a demanding medium, where the reaction is completed. The concentration of oxygen fb aluminum (A 丨 2 1) 3) is changed from i to 5% by weight, and the pH is changed from 7 to Π (often referred to as the hydrated alumina gel method under K), or by drawing one of them The composition of fine particles of aluminum hydroxide type aluminum hydroxide and a lithium salt or lithium compound capable of forming carbonic acid or carbonate ion reacts in the presence of water, and also uses the migration method to make deer. U. Carbonate of nano-aluminum hydroxide) Carbonate of sodium-aluminum hydroxide of the genite type used in the present invention U a-Aluminum hydroxide carbonate: NAHCS) has the following formula U 1 ) * B A12 〇3 * π Μ 2 0 · X * kHz 〇 ... (11) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, where X is a non-yin chicken composed mainly of carbonate ions , M is a test metal mainly composed of sodium, m is a number of a number of 0.5 to 1.5, η is β · 1 to]., And k is a number of 0 to 3 Stone type crystal structure refers to those materials which have the same X-ray diffraction pattern as shown in Table 3 below in X-ray analysis using Cu-α gallium, -ζη- This paper scale applies Chinese national standards (CNS) A4 specification (210x297 mm) 408156 A7 B7 89. 6. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of invention (y \) f-ι ^ Μ ν LAHGS and cymbalite AK CS can be directly mixed in the chlorinated polymer-in order to improve the surface properties of the compound SI, dispersion from improved tree shrews and improved light transmission Sightseeing qualitative point, the surface may be pre-K of not more than 1 ϋ% by weight and, in particular pool = Table ® treatment agent of 1-6% by weight. When using Pride® treatment agent, depending on the target, you can use silane, aluminum, I too or 谆 | higher fatty acids, gold palladium soap or resin acid soap, finely divided fumed silica or Jie® active agent type Lesson mix. Generally, it is desirable to add a higher fatty acid or interfacial activity to the base solution of a carbonate containing a hydroxide of an alkali-aluminum complex, which is subjected to a mixing treatment. The salt of this 箜 hydrotalcite or alkali-is complex m oxide can be a kind of 闱 or ΰ. 5 to 50 parts per 1 () Q parts by weight of the 逑 component (A) (or (D) Or the combination of the amount of U)) and (C) makes two. [Zinc high-viscosity zinc acid] According to the present invention, in addition to the above-mentioned basic ingredients, the Greek E further joins i F) 5 to 7 β by weight of Fen and, specifically, 10 to 5) by weight of High-M fatty acid zinc, the total amount of ingredients (A) (or (D) or (Ε)) and (C) per weight part. Adding the above-mentioned ingredient (F) enables it to effectively avoid the initial coloration of warm colors. The fatty acids that form zinc 1 will be unsaturated fatty acids having 8 to 2 carbon atoms, in particular, 8 to 1 4 carbon atoms and, most desirably, 8 to 12 carbon atoms, that is, , Saturated fatty acid succinoic acid, capric acid, ten 3- This paper size applies to the Chinese National Standard (CNS) A4 (210x297 mm) (Please read the back; please fill in this page before the note.) Binding --- ------ Line 408156 B7 V. Description of the invention (I) Table 3 nvi / m {Index of relative intensity plane VS (001). 3 8 ill (0 2 0) π η .U ώ ϊδ ί〇13) .78 π (121) .fi 1 m (0 0 4) .5 w (211) .1 5 w (2 2 0) .Β9 in (015) • 73 w (231) .69 31 (125)-( Q40 (Read the precautions on the back of the next page before filling in this page) Equipment --- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs where VS is very strong, S is strong, IB is medium strength, and W is 7F weak. ΗSodium aluminate is hotter than 3 ϋ G υ temperature In the reanalysis, there was no weight loss in the osmium, and therefore it was used to prevent the soil from forming a soda-type bauxite type crystal structure during kneading or molding of the resin. The sodium-aluminum complex osmium hydroxide carbonate has 茌 Cui Z X The light diffraction image is not less than half the width of the peak of the exponent of the plane (sm) of G. 4 degrees, and is not greater than SG ϋ 0 Ω when it forms a 5 wt. Resistivity in centimeters. Sodium aluminum argon oxide carbonate used in the present invention, a large flat ([Π 1) half of the exponential peak width indicates the crystal in the direction of ί] -uranium (in the direction of the 鲡 axis) -Π -Order -------- Completion This paper size applies the Chinese National Standard (CNS) A4 specification (210 * 297 mm) 408156 Α7 Β7 Amendment printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs ) Monoacids • Myristic acid or myristic acid, or fatty acids such as lindric acid • Crude rent (Tzuzuic) acids' petroselinic acid, oleic acid, linoleic acid, linolenic acid, and steric acid. Its & allows the use of stearic acid, palmitic acid or phase M 33 acid. However: avoid zinc burning The point of the mirror is to use lower fatty acids. From the point of the birth of Luding, I hope that the officials and the fatty acids are the best. Fatty acid is a mixture of fatty acids. Examples are coconut oil and fatty acids or synthetic oils and fatty acids. These fatty acid salts are also used as lubricants and are expected to be ordinary salts. [In addition to the anti-oxidation surface M 竑, in addition to the above-mentioned essential ingredients, the present invention also desirably uses, Γ G) phenol in an amount of 1 to 50 parts by weight and, in particular, 2 to 20 parts by weight Antioxidant tritium, the number of components U) (or (D) or (E)) and (C) per i 0 GS parts. Antioxidants effectively inhibit degradation caused by worm-bond reactions. In order to use the anti-oxidants of the present invention, any of the above-mentioned ones, double-type antioxidants or sister-type antioxidants can be used. Among them, Shuang A is the best. This phenolic antioxidant can be used alone or in combination with K. Γ r ^ · SP-T -w- ΛΙτ / Λ-3C & T Ί ι ρ ~ m ^ mm ρ j 竑, according to the present invention, in addition to the above-mentioned necessary components, can be joined [K 5 to 30 parts by weight and · Specially 昽 I 1 to 15 parts by weight, of which (ΗM __ 基 _ 酸 酷 or 召-二 _ * per ΙϋΟ weight part of the ingredients (A), (D) or (Ε) and ί C) The number of bonds: conjugated / i-base-acid-cooled or gadolinium-two-K improved thermal stability and primary coloring. -24- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -----------. * I tt (--- Order. ----- — 1J · . ^ (Please read the notes on the back before filling in this page) 408156 A7 _________ Β7__; _V. Description of the invention (w) The size is: $ —General η in aluminite, which has a large follow-up ratio. The dimensional beam image together with _ will form coarse-bonded, fine-grained, spherical secondary particles. However, in the above-mentioned sodalite, the structure of the fiber is very poor, and the secondary particles formed by these Condensed to a small extent. Regarding the shape of the particles, the falconite, in general, a large absorption amount of 0 to 〖{} {] ml / ig gram 5 is obtained, however, it is better to make Zhou Yuben The invented tablet sodium aragonite now has an oil absorption of not less than 4 milliliters per gram, but less than 7 milliliters per ounce. In addition, the volume astringency of the pigments in the former schizophyllite is 33% or less =, while the volume concentration of the latter's schizophyllite is as high as 40 to 50%. It is further desirable that the carbonated particles of the Na-scrab gasification type of the onyxite type of the present invention have a normal, 0.1 to 10, and, in particular, g ·

3歡米之K體積為基準之平均直徑(D 當以散射繞射 經濟部智慧財產局員工消費合作社印製 的雷射方法溯量時,毫丹/i0G克之吸油量(jps Κ-5ΗΠ,3ϋ到 lii)公尺 Z / 1〇〇克之 u L1比表面積,相ΰ. 到m克/公分3表観比重(網筒法): 雖然不必僅跟制於其中,Η納叙π赖 幻蝴型之鈉一鋁氪氧 ib物的碳酸鹽係籍由使周碳睃納作& Ώ Κ替碳酸鋰Μ上述水合氧 化鋁凝膠方法製餚。 插S使用碳酸鈉和碳酸理跑,趣& -、_嚴欲與無定形或跤勃母 石類型的水含氧化鋁水反應之齡_ & 明,巨合,獲得一種包含 UKCS和片納鋁石的混合结晶之_ 22- 18複含物氫氯化物的碳 本紙張尺度適用令因國家標準(CNS)A4規格(210x 297 --- - -----^------t--------訂---------線 (請先閱讀背面之>£意事項再填寫本頁) A7 B7 經濟邠智慧財產局員工消费合作社印製 五、發明說明(Z1;) ^基-酸酯或/5 -二嗣的賁例為上文已經 可被使nj心〆 描逑者和可Μ 一棰戎二1^上之11胃_含_ 3 [複合物安定劑】 •V ρ明的複合物安定劏可Κ粉末影式或以粒子的泜式 ,* m Λ , #苷定劑:該等粒子可藉由已知的製粒法拐i 使兩:如一扭农艾κ 節痛忠成型製粒法,噴綦製粒法’旋轉盤製粒狀法’研磨 製粒方法或®编製粒法製溝。粒子的直徑赶視目的任意調 g*. _^受上,希望,粒子直淫為3丨〗微衆到5毫张和’特別 地,7 G微米到2甭带: 本發明之複合朝安定劑可與用於樹賠之已知摻合萄^昆 合,M節著色转料 > 無機或有機填充劑,抗氧化劑,潤滑 劑,塑化劑1蝥合劑,抗堀菌劑’充安定劑’阻燃劑*抗 震謂,無襪酸之鹼金屬鹽’過氯酸g ’紫外線吸妝劑’環 氣ib合物’抗靜電劑和相似韵° [無键酸的鹼金屬鹽] 驗金屬鹽為無饑酸的鹼金屬鹽。當做一較佳金羼成分 .可擧例為 U,!i a,it,M g · C a,S r,3 a,Ζ π, T i,A i , Z r,S n。當做無镄酸,能舉例為磷酸,亞磷酸,矽酸酸, 硝酸,亞硝酸,硫酸,亞碇酸,硼酸或碳酸。 鹼性無機酸的鹽之較佳實洌包拮Hg((】H)2 ,Cai〇H)2 » AI(OH)j 1 Ba(0H)3 MgO* CaO- BaO> \\z 〇3 . SnOz - 3 C a (5 · 'h a 3 P 0 4 * 5 C a 0 - N a Η P 0 4 > H g 0 · Mgs (P 0 4 ) z -;)Can · Ca3 (P〇4 )z - C a (0 H) ^ · Ca^ (Ρϋ4 )2 - Ba(0 -2 5- 本紙張尺度適用中困國家標準(CNS)A4規格(210 * 297公釐) (請先閲讀背面之注意事項再填寫本頁) 裝 i ---I. 訂 ---------竣 408156 A7 B7 89. 6. 年月 經濟部智慧財產局員工消費合作社印製 五、發明說明(y\) f-ι^ Μ ν L A H G S和Η訥鋁石類AK C S可直接地混合在含氯聚合 物中-為了改良複合物SI之表面特性,從改良樹詣分散和 改良光傳輸性質的観點,表面可預先K於不大於1 ϋ重量% 和,特別池=1到6重量%之表®處理劑處理。 當傲表®處理劑,視標的锪而定可使用矽烷,鋁,I太 或諄|高級脂肪酸,金羼鈀皂或樹脂酸肥皂,细粉化無定 肜矽石或界®活性劑之類型的课合劑。 一般,希望加入高級脂肪酸或界面活性劏至一橿進行 Μ拌處理之包含鹼一鋁複合锪的氫氧化物之碳酸鹽的反憑 母溶寂中。 這箜水滑石或鹼一 is複合物m氧化物的鹽可μ軍一種 類使闱或以ΰ . 5到5 0份/每1 (] Q重量份上逑成分(A)(或(D ) 或U))和(C)之缌重量扮的量组合使兩。 [高鈒脂訪酸鋅] 根據本發明,除該等上述基本成分之外,希E進一步 接合i F ) 5到7 β重量汾和,特別地,1 0到5 ί)重量份之量的 高Μ脂肪酸鋅,每ίϋϋ重量份之成分(Α)(或(D)或(Ε))和(C 之總數。加入上述的成分(F)使其丐能有效地避免暖色的 最初著色。 用於形成鋅1的腊肪酸將為具育8到2 2個碳原子,特 別地,8到1 4 ϋ碳原子和,最希望地,8到I 2個碳原子之 不飽和脂肪酸,也就是,飽和脂肪酸洌韶辛酸,癸酸,十 3- 本紙張尺度適用中國國家標準(CNS)A4規格(210x297公釐) (請先閲讀背面之;£.意事項再填寫本頁) 裝 訂---------線 408156 A7 B7 ΒθΓ^ 五、發明說明( "Wa7 經濟部智慧財產局員工消費合作社印製 Η )2 * C a a (P 0 4 )2 · 〇 H 2 0 ' S r ( 0 H ) z * 3 r 3 (P 0 + )2 *The average diameter based on the K volume of 3 meters (D When traced by the laser method printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economics and Scattering and Diffraction, the oil absorption in millidan / i0G grams (jps KK-5ΗΠ, 3ϋ To li) Metric Z / 100 grams of specific surface area of u L1, relative to. To m grams / cm 3 table specific gravity (mesh tube method): Although it is not necessary to follow only it, it is not satisfied The carbonate of sodium-aluminum hydroxide is prepared by using carbon dioxide as the carbon dioxide and lithium carbonate as described in the above hydrated alumina gel method. Insert sodium carbonate and carbonic acid to run, fun &-, _ Age of reaction with alumina or water containing amorphous or womerite type _ & Ming, Juhe, to obtain a mixed crystal containing UKCS and monopyrite _ 22- 18 complex Hydrocarbon-containing carbon paper size is applicable due to the national standard (CNS) A4 specification (210x 297 ------------------ t -------- order- -------- line (please read the > pound notice on the back before filling in this page) A7 B7 Printed by the Consumers ’Cooperative of the Economic and Intellectual Property Bureau V. Invention Description (Z1;) ^ -Ester Or / 5-er For the above, the person who can be described by the heart and the person can be described as 11 stomachs and 11 stomachs _ containing _ 3 [complex stabilizer] • The complex stability of V ρ can be powdered shadow Or in the form of particles, * m Λ, #glycoside fixed agent: These particles can be turned by known granulation methods: two, such as a twist of agricultural arthritis κ section pain-neutral molding granulation method, spray granulation "Rotary disk granulation method" grinding granulation method or ® granulation method for making grooves. The diameter of the particles can be adjusted according to the purpose of g *. _ ^ Accept, hope that the particles will be 3 丨〗 5 Milligram and 'Specially, 7 G micron to 2 ribbons: The composite stabilizer of the present invention can be blended with known blends used for tree compensation, M-coloring transfer material > inorganic or organic fillers , Antioxidants, Lubricants, Plasticizers 1 Mixture, Anti-bacteria Agents 'Filling Stabilizers', Flame Retardants * Earthquake Resistance, Alkali-free Alkali Metal Salts, Perchloric Acid, 'Ultraviolet Cosmetics', Loop Gas ib compound 'antistatic agent and similar rhyme ° [Alkali metal salt without bond acid] Test metal salt is an alkali metal salt without hunger acid. As a better gold tincture ingredient. For example, U,! ia, it , M g · C a, S r, 3 a, Z π, T i, A i, Z r, Sn. As non-phosphonic acid, examples include phosphoric acid, phosphorous acid, silicic acid, nitric acid, nitrous acid, sulfuric acid, and thulium. Acid, boric acid or carbonic acid. The preferred salts of basic inorganic acids include Hg (() H) 2, CaiOH) 2 »AI (OH) j 1 Ba (0H) 3 MgO * CaO- BaO > \\ z 〇3. SnOz-3 C a (5 · 'ha 3 P 0 4 * 5 C a 0-N a Η P 0 4 > H g 0 · Mgs (P 0 4) z-;) Can · Ca3 (P〇4) z-C a (0 H) ^ · Ca ^ (Ρϋ4) 2-Ba (0 -2 5-This paper size is applicable to the National Standard (CNS) A4 specification (210 * 297 mm) (Please read the precautions on the back before filling out this page) Install i --- I. Order --------- Complete 408156 A7 B7 89. 6. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Description of the invention (y \) f-ι ^ Μ ν LAHGS and cynic bauxite AK CS can be directly mixed in the chlorinated polymer-in order to improve the surface characteristics of the compound SI, dispersion and improvement from improved tree shrews The piercing point of the light transmission property, the surface can be treated in advance by not more than 1 ϋ% by weight and, in particular, the table® treatment agent = 1 to 6% by weight. When using Pride® treatment agent, depending on the target, you can use silane, aluminum, I too or 谆 | higher fatty acids, gold palladium soap or resin acid soap, finely divided fumed silica or Jie® active agent type Lesson mix. Generally, it is desirable to add a higher fatty acid or interfacial activity to the base solution of a carbonate containing a hydroxide of an alkali-aluminum complex, which is subjected to a mixing treatment. The salt of this 箜 hydrotalcite or alkali-is complex m oxide can be a kind of 闱 or ΰ. 5 to 50 parts per 1 () Q parts by weight of the 逑 component (A) (or (D) Or the combination of the amount of U)) and (C) makes two. [Zinc high-viscosity zinc acid] According to the present invention, in addition to the above-mentioned basic ingredients, the Greek E further joins i F) 5 to 7 β by weight of Fen and, specifically, 10 to 5) by weight of High-M fatty acid zinc, the total amount of ingredients (A) (or (D) or (Ε)) and (C) per weight part. Adding the above-mentioned ingredient (F) enables it to effectively avoid the initial coloration of warm colors. The fatty acids that form zinc 1 will be unsaturated fatty acids having 8 to 2 carbon atoms, in particular, 8 to 1 4 carbon atoms and, most desirably, 8 to 12 carbon atoms, that is, , Saturated fatty acid succinoic acid, capric acid, ten 3- This paper size applies to the Chinese National Standard (CNS) A4 (210x297 mm) (Please read the back; please fill in this page before the note.) Binding --- ------ line 408156 A7 B7 ΒθΓ ^ 5. Description of the invention (" Wa7 printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs) 2 * C aa (P 0 4) 2 · 〇H 2 0 'S r (0 H) z * 3 r 3 (P 0 +) 2 *

Bail < 8a3 (P〇4 )z - 3Ba(0H)2 ·Βα3(Ρ〇4)2,2πΟ· l n'i \ P 0 4 )2 1 2 Z η 0 · B a s ( P 0 4 ) 2 : A 12 0 3 . A I P 0 4 1Bail < 8a3 (P〇4) z-3Ba (0H) 2 · βα3 (PO4) 2, 2πΟ · l n'i \ P 0 4) 2 1 2 Z η 0 · B as (P 0 4) 2: A 12 0 3. AIP 0 4 1

3SnO · 5n3 (P04 )2 · B a { 0 H) £ · N a Η P H 0 3 - 5CaG · NaHPH 0 3 ' 3 8 a ( G H } 2 · K 2 F rl ίί 3 > H g G * M g F Ft 0 3 ! 0 M g { 0 H ) 23SnO · 5n3 (P04) 2 · B a {0 H) £ · N a Η PH 0 3-5CaG · NaHPH 0 3 '3 8 a (GH) 2 · K 2 F rl ίί 3 > H g G * M g F Ft 0 3! 0 M g {0 H) 2

MiPHOs ! CaO · CaPHOa · oCa{0H)2 CaPH〇3 1 6a(0H)z -C a P n 0 3 ! 5CaO * C a P H 0 3 , BaO · BaPR〇3 , 2〇a (0H)2 -MiPHOs! CaO · CaPHOa · oCa (0H) 2 CaPH〇3 1 6a (0H) z -C a P n 0 3! 5CaO * C a P H 0 3, BaO · BaPR〇3, 2〇a (0H) 2-

BaPHih - 3Ba{0K)2 · Ba?H〇3 · 3H2 〇 ZnO · ZnPHDs ,BaPHih-3Ba {0K) 2 · Ba? H〇3 · 3H2 〇 ZnO · ZnPHDs,

Z π0 · ;j C a P H03 - Ti〇z * TiiPK〇3 )z ' Al2 03 * AIZ (P Η ϋ 3 ) 3 ,3 Z r 0 * Z r P H 0 3 ,3 n Q * S π P H 0 3 ,3 S n 0 * S η P H 0 3 ,M g ( 0 H ) z · M g2 3 i 0 4 ,3 S g 0 * M g S i 0 e 5 C a 0 * Ca2 S i 0 4 ’ 3Cai) * Li2 Si〇3 , 3 C a 0, C a S i 2 〇 5 2 C a (0 H) 2 * Ca2 Si3 * SrO · SrSi03 > 5BaO· 8a2 Si04 - 8a(0H)2 · 8a2, S1O4 · 6H2 Gj Ba(0H)2 ' 〇aSi〇3 ! 3Ba(0H}2 * Ba S i 2 i) 5 » 〇BaO· Baz Si〇4 > B a ( 0 H ) 2 · C a S i 0 3 > 2 Z n G ·Z π0 ·; j C a P H03-Ti〇z * TiiPK〇3) z 'Al2 03 * AIZ (P Η ϋ 3) 3, 3 Z r 0 * Z r PH 0 3, 3 n Q * S π PH 0 3, 3 S n 0 * S η PH 0 3, M g (0 H) z · M g2 3 i 0 4, 3 S g 0 * M g S i 0 e 5 C a 0 * Ca2 S i 0 4 '3Cai) * Li2 Si〇3, 3 C a 0, C a S i 2 〇5 2 C a (0 H) 2 * Ca2 Si3 * SrO · SrSi03 > 5BaO · 8a2 Si04-8a (0H) 2 · 8a2 , S1O4 · 6H2 Gj Ba (0H) 2 '〇aSi〇3! 3Ba (0H) 2 * Ba S i 2 i) 5 »〇BaO · Baz Si〇4 > B a (0 H) 2 · C a S i 0 3 > 2 Z n G

ZnSiOs , ZnO > 3 C a S i 0 3 - CaO · Sn2 S104 , .Mg (OH) * Hg (fi〇3 ) z ' 〇CaO* Ca(N〇s )2 1 2Ca(0H)2 * CaiSOs ) zZnSiOs, ZnO > 3 C a S i 0 3-CaO · Sn2 S104, .Mg (OH) * Hg (fi〇3) z '〇CaO * Ca (N〇s) 2 1 2Ca (0H) 2 * CaiSOs ) z

Srtz 〇j 3BaO - Ba{NG3 )z ' Ba(OH}2 * Sa2 S04 > ZnO· K 2 i G 4 * 3 C a 0 * K z 3 0 3 , M g (0 H } 2 - K g S 0 4 » 5 M g 0 * M g :i〇3 , · MgS03 , HgiJ , CaS03 - 5CaO. CaSO+ , Ca( OH} 9 · C a S 0 4 ,3CaG CaS03 ,SrO * S r 3 0 2 ,3BaO · BaSrtz 〇j 3BaO-Ba {NG3) z 'Ba (OH) 2 * Sa2 S04 > ZnO · K 2 i G 4 * 3 C a 0 * K z 3 0 3, M g (0 H} 2-K g S 0 4 »5 M g 0 * M g: i〇3, · MgS03, HgiJ, CaS03-5CaO. CaSO +, Ca (OH) 9 · C a S 0 4, 3CaG CaS03, SrO * S r 3 0 2, 3BaOBa

oiK, ^ :>gi\0 - CaS〇3 - 3a(0H)2 - BaS04 ' Ti02 · Ti(S Π ! ) £ ,A 1 2 〇 3 · A 1 2 (S 〇 4 )3 1 A 1(0 H)2 * M g S 0 4 - -2 ij - 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) n 1 IT >^1 n Jf- n if n t Et n n ^eJ n l— n n I (請先閱讀背面之注意事項再填寫本頁) 408156 Α7 Β7 修正 經濟部智慧財產局員工消費合作社印製 五、發明說明(yy) 一酸•月桂烯酸或肉豆蔻酸,或不葩和脂肪酸例如林德酸 •粗租(Tsuzuic)酸’岩芹酸,油酸,亞油酸,亞麻酸, 和7£生巧烯酸。其&允許使用硬脂酸,棕擱酸或相Μ 33酸 。然而:從避免鋅燃镜之観點,希望使用低級脂肪酸。從 滏定ί生的観點,希望ί吏闬筢和脂訪酸,旦月桂烯酸是最希 Μ的。脂肪酸坷為_肪酸之混合衙例抝椰子油和g旨訪酸或 综擱油和脂肪酸 這些脂肪酸鹽也用ί乍為潤滑劑且希望應為一般鹽類。 [齩類抗氧化麵Μ 竑外,除上述之总要成分之外,本發明亦希望使用, ί G )於1到5 0重量份和,特別地,2到2 0重量份之量的酚 類抗氧化劏,每i 0 G S量份之成分U )(或(D )或(Ε))和(C)之 缌數。抗氧化劑有效抑制虫鍵反應引起的降解作用。 ί乍為使吊於本發明的鼢類抗氧化劏,可使用任何的一 涸上述所到舉者,雙鼢類抗氧化劑或位姐醅類抗氧化劑。 其中,雙鼢A為特佳者。 這呰酚類抗氧化劑珂獨自或K組合使爾。 Γ r^· SP-T -w- ΛΙτ /Λ - 3C&T Ί ι ρ ~m ^ m m ρ j 竑外,棍據本發明,除該等上述必要成分之外,可被 接合[K 5到3 0重量份和·特別昽I 1到1 5重量份,之(Η Μ __基_酸酷或召-二_ *每ΙϋΟ重量份成分(A),(D)或(Ε)和 ί C )之缌數:接合/i - _基-酸酷或厶-二_ Κ改良熱安定性 和爵初著色。 -24- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) ----------- . * I t t ( ---訂.---— — 1J·.^ (請先閱讀背面之注意事項再填寫本頁) 408156oiK, ^: > gi \ 0-CaS〇3-3a (0H) 2-BaS04 'Ti02 · Ti (S Π!) £, A 1 2 〇3 · A 1 2 (S 〇4) 3 1 A 1 (0 H) 2 * M g S 0 4--2 ij-This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) n 1 IT > ^ 1 n Jf- n if nt Et nn ^ eJ nl— nn I (Please read the notes on the back before filling in this page) 408156 Α7 Β7 Amendment printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs , Or not, and fatty acids such as lindonic acid, crude tuzuic acid, petrolic acid, oleic acid, linoleic acid, linolenic acid, and steric acid. It & allows the use of stearic acid, palmitic acid or phase M 33 acid. However: From the point of avoiding zinc burning, it is desirable to use lower fatty acids. From the point of the birth of Luding, I hope that the officials and the fatty acids are the best. Fatty acid is a mixture of fatty acids. Examples are coconut oil and fatty acids or synthetic oils and fatty acids. These fatty acid salts are also used as lubricants and are expected to be ordinary salts. [In addition to the anti-oxidation surface M 竑, in addition to the above-mentioned essential ingredients, the present invention also desirably uses, Γ G) phenol in an amount of 1 to 50 parts by weight and, in particular, 2 to 20 parts by weight Antioxidant tritium, the number of components U) (or (D) or (E)) and (C) per i 0 GS parts. Antioxidants effectively inhibit degradation caused by worm-bond reactions. In order to use the anti-oxidants of the present invention, any of the above-mentioned ones, double-type antioxidants or sister-type antioxidants can be used. Among them, Shuang A is the best. This phenolic antioxidant can be used alone or in combination with K. Γ r ^ · SP-T -w- ΛΙτ / Λ-3C & T Ί ι ρ ~ m ^ mm ρ j 竑, according to the present invention, in addition to the above-mentioned necessary components, can be joined [K 5 to 30 parts by weight and · Specially 昽 I 1 to 15 parts by weight, of which (ΗM __ 基 _ 酸 酷 or 召-二 _ * per ΙϋΟ weight part of the ingredients (A), (D) or (Ε) and ί C) The number of bonds: conjugated / i-base-acid-cooled or gadolinium-two-K improved thermal stability and primary coloring. -24- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -----------. * I tt (--- Order. ----- — 1J · . ^ (Please read the notes on the back before filling this page) 408156

五、發明說明(β) 經濟部智慧財產局員工消費合作社印製 M g (! ‘ M g 3 ( Β 0 4 ) 1 5 C a ί) · (30+ ) 2 ' 5 C a ( 0 Η ) 2 · C a 3 (Biii )z ^ 3CaO * Ca(B〇2 )2 ^ 3Ba(0EUz · 3as (BO4 }z 1 〇Ha(j- 〇afi,l· H7 ! « B a (0 H) 2 * B a ( B 0 2 ) 2 > N a R C 0 3 , M g ί H i' 0 3 ) 2 5 L i H C 0 3 ,B a C。3 ,M g L' G 3 ,Z η ί: 0 3 和 ί i z C02 : [過氯酸] 過氯酸鹽的實洌包括引人過氯酸離子之水滑石,鹼-鋁複合_氬氧化韧,K及過氛酸鋰,過氢酸納,過氯酸鎂 ,過氯酸鈣,遇氛酸鋇和過氯酸鋅。亦允許使用過氯酸鹽 和多_元醇的複合锪。多元酵的較佳實例包括二甘醇單甲基 醚,三甘醇或丙二酵單甲醚。 [紫外線吸牧劑】 紫許線吸牧劑的貢洌包括2 -羥基苯_例如2 , 4 -二羥基 苯觸^ 2-羥基-4-甲氧基苯_,和δ,5’-亞甲基雙(2-羥基-4-甲氧基苯_);和2-U’-羥苯基)苯駢三哩洌如2-(2’-羥 - 5 ’ -甲苯基)苯駢三唑,2 - ( 2 ^羥基-3 ’ -三级-丁基-5 ’ -甲 苯基)-5-¾苯駢三哇,2-(2’-羥基4’-三级-辛苯基)苯駢 三唑,2-U’-羥基-3’,5’-二異丙苯基苯基)苯駢三唑,和 2, 2-亞甲基雙(4-三级-辛基苯駢三唑)酚。 [環氧丨b合物! 環氣化含物Z簧剀包拈環氧ib大豆油*環氧化亞麻子 油,環氧ib魚油*環氧化高油之脂肪酸酯,環氛化牛脂油 ,環氣ib證麻油,環氧化紅花油,環氧化亞麻子油之脂肪 (請先閱讀背面之注t事項再填寫本頁) 裝--------訂---------峻 本紙張尺度適用中國國家標準(CNS)A4規格(210x297公釐) A7 B7 經濟邠智慧財產局員工消费合作社印製 五、發明說明(Z1;) ^基-酸酯或/5 -二嗣的賁例為上文已經 可被使nj心〆 描逑者和可Μ 一棰戎二1^上之11胃_含_ 3 [複合物安定劑】 •V ρ明的複合物安定劏可Κ粉末影式或以粒子的泜式 ,* m Λ , #苷定劑:該等粒子可藉由已知的製粒法拐i 使兩:如一扭农艾κ 節痛忠成型製粒法,噴綦製粒法’旋轉盤製粒狀法’研磨 製粒方法或®编製粒法製溝。粒子的直徑赶視目的任意調 g*. _^受上,希望,粒子直淫為3丨〗微衆到5毫张和’特別 地,7 G微米到2甭带: 本發明之複合朝安定劑可與用於樹賠之已知摻合萄^昆 合,M節著色转料 > 無機或有機填充劑,抗氧化劑,潤滑 劑,塑化劑1蝥合劑,抗堀菌劑’充安定劑’阻燃劑*抗 震謂,無襪酸之鹼金屬鹽’過氯酸g ’紫外線吸妝劑’環 氣ib合物’抗靜電劑和相似韵° [無键酸的鹼金屬鹽] 驗金屬鹽為無饑酸的鹼金屬鹽。當做一較佳金羼成分 .可擧例為 U,!i a,it,M g · C a,S r,3 a,Ζ π, T i,A i , Z r,S n。當做無镄酸,能舉例為磷酸,亞磷酸,矽酸酸, 硝酸,亞硝酸,硫酸,亞碇酸,硼酸或碳酸。 鹼性無機酸的鹽之較佳實洌包拮Hg((】H)2 ,Cai〇H)2 » AI(OH)j 1 Ba(0H)3 MgO* CaO- BaO> \\z 〇3 . SnOz - 3 C a (5 · 'h a 3 P 0 4 * 5 C a 0 - N a Η P 0 4 > H g 0 · Mgs (P 0 4 ) z -;)Can · Ca3 (P〇4 )z - C a (0 H) ^ · Ca^ (Ρϋ4 )2 - Ba(0 -2 5- 本紙張尺度適用中困國家標準(CNS)A4規格(210 * 297公釐) (請先閲讀背面之注意事項再填寫本頁) 裝 i ---I. 訂 ---------竣 408156 A7 經濟部智慧財產局員工消费合作社印製 B7 ;_ .. :, -_五、發明說明(Λ’) 萌j盎,爹(環氧曼丙基)異Μ尿酸酷,3-(2-xenoxy)-l,2 -瑁氧丙烷,雙齙二讅水甘油基_,乙烯基環己烯二環 氧化物,二環戊二烯二環氯化物,和3,4-環氧瑁己基-3-甲基-環氧己烷羧酸酯。 [抗靜電劑3 使甩於本發明中之瀾滑劑和抗靜電物通常可為該等使 用於聚烯烴Μ膜者。該等抗靜電物之較佳實MS括(a)該 等陽離子類型者例如一鈒胺鹽,三鈒胺,四级铵化合物, 骶啶衍生物,(b)該等陰離子類型者例如磺酸化油,肥皂 :礙酸化酷油,碌酸化蘧胺油^烯之硫酸酷鹽,脂肪醇疏 酸酯烷基硫酸酯_,脂訪酸乙基磺酸鹽,烷基蔡磺酸 S,烷基苯磺酸鹽,丁二酸詣磺酸g和磷酸銪鹽,(c)該 等非離子類S者倒如多元酵之部分脂肪酸酷,脂肪醇的環 氧乙烷邡成锪*睹肪酸的環氧乙烷加成物,脂肪胺或腊肪 酸藤胺S3環氧乙烷邡成薇,烷基鼢的環氧乙烷加成韧 > 烷 基蔡醇的環氧乙烷加成锪,多元醇之部分脂肪酸酯的環氧 乙烷邡成锪•和聚乙二酵,和(<1)該等兩性類型者例如羧 酸衍生拘和眯唑啭衍生掬β^ϊ。特別是,希望使搿該等非離 子類型者和,在他們之中,使用聚氧乙撐烷基胺,聚氣乙 jf烷基醯.駿或其脂肪酸_或甘油的脂肪酸酯= ί一元酵和多元醇的脂肪酸酯] 賭肪酸酯之簧洌包括硬脂酸正丁酯,1化的松脂甲酯 ,癸二酸二丁基(正丁基)酯,癸二酸二辛基(2 -乙基己基 — — rlllil — — — — —. - . I I I I I I I - ΙΙ1ΙΙΪ — · (請先間讀背面之注意事項再填寫本頁) 本紙張尺度適用t國國家標準(CNS0A4規格(210x297公t ) 408156 A7 B7 ΒθΓ^ 五、發明說明( "Wa7 經濟部智慧財產局員工消費合作社印製 Η )2 * C a a (P 0 4 )2 · 〇 H 2 0 ' S r ( 0 H ) z * 3 r 3 (P 0 + )2 *V. Description of the invention (β) Printed by Mg (! 'M g 3 (Β 0 4) 1 5 C a ί) · (30+) 2' 5 C a (0 Η) 2 · C a 3 (Biii) z ^ 3CaO * Ca (B〇2) 2 ^ 3Ba (0EUz · 3as (BO4) z 1 〇Ha (j- 〇afi, l · H7! «B a (0 H) 2 * B a (B 0 2) 2 > Na a RC 0 3, M g ί H i '0 3) 2 5 L i HC 0 3, B a C. 3, M g L' G 3, Z η ί : 0 3 and iz C02: [Perchloric acid] Examples of perchlorate include hydrotalcite that attracts perchlorate ions, alkali-aluminum complex_argon oxidation toughness, K and lithium peroxyacid, perhydroacid Sodium, Magnesium Perchlorate, Calcium Perchlorate, Barium Phosphate and Zinc Perchlorate. It is also allowed to use a compound of perchlorate and polyhydric alcohols. Preferred examples of polyenzymes include diethylene glycol monomethyl Ether, triethylene glycol or malonyl monomethyl ether. [Ultraviolet grazing agent] The tributary of the purple line grazing agent includes 2-hydroxybenzene_for example, 2,4-dihydroxybenzene contact ^ 2-hydroxy-4 -Methoxybenzene_, and δ, 5'-methylenebis (2-hydroxy-4-methoxybenzene_); and 2-U'-hydroxyphenyl) benzene, three miles such as 2- ( 2'-Hydroxy-5'-tolyl) benzotriazole 2-(2 ^ Hydroxy-3'-tertiary-butyl-5'-tolyl) -5-¾phenylhydrazine, 3,2- (2'-hydroxy4'-tertiary-octylphenyl) benzene Triazole, 2-U'-hydroxy-3 ', 5'-dicumylphenyl) benzotriazole, and 2,2-methylenebis (4-tertiary-octylbenzotriazole) )phenol. [Epoxy 丨 b compound! Circulating gas content Z spring pack 拈 epoxy ib soybean oil * epoxidized linseed oil, epoxy ib fish oil * epoxidized high-oil fatty acid ester, epoxidized tallow oil, epoxidized sesame oil, epoxidized Safflower oil, fat of epoxidized linseed oil (please read the note t on the back before filling this page) Packing -------- Order --------- This paper size is applicable to China Standard (CNS) A4 specification (210x297 mm) A7 B7 Printed by the Economic and Intellectual Property Bureau Employees Consumer Cooperatives V. Description of the invention (Z1;) The examples of ^ -acid or / 5-dioxo are already available above The person who has been described by the nj heart and the person who can be described as 1 ^ 1 on the 11 stomach _ containing _ 3 [complex stabilizer] • The complex stability of V ρ can be powder shadow or particle-based Formula, * m Λ, #glycoside fixing agent: These particles can be turned by known granulation methods: two methods: such as twisting Nong Ai κ section pain loyalty molding granulation method, spray granulation method 'rotary disk system Granular Method 'Grinding Granulation Method or ® Granulation Method for Grooving. The diameter of the particles can be adjusted according to the purpose of g *. _ ^ Accept, hope that the particles are 3 丨〗 5 to 5 milligrams and 'Specially, 7 G micrometers to 2 belts: The compound of the present invention is stable Agents can be blended with known blends used in tree compensation, Section M coloring transfers> Inorganic or organic fillers, antioxidants, lubricants, plasticizers, admixtures, antibacterial agents Agent 'flame retardant * anti-shock, said non-sock acid alkali metal salt' perchloric acid g 'ultraviolet makeup agent' ring gas ib compound 'antistatic agent and similar rhyme ° [alkali metal salt without bond acid] inspection The metal salt is an alkali metal salt of hunger-free acid. As a better gold tincture ingredient. For example, U ,! i a, it, M g · C a, S r, 3 a, Z π, T i, A i, Z r, Sn. As the non-phosphonic acid, there can be exemplified phosphoric acid, phosphorous acid, silicic acid, nitric acid, nitrous acid, sulfuric acid, phosphonic acid, boric acid or carbonic acid. The preferred salts of basic inorganic acids include Hg (() H) 2, CaiOH) 2 »AI (OH) j 1 Ba (0H) 3 MgO * CaO- BaO> \\ z 〇3. SnOz-3 C a (5 · 'ha 3 P 0 4 * 5 C a 0-N a Η P 0 4 > H g 0 · Mgs (P 0 4) z-;) Can · Ca3 (P〇4) z-C a (0 H) ^ · Ca ^ (Ρϋ4) 2-Ba (0 -2 5-This paper size is applicable to the National Standard (CNS) A4 specification (210 * 297 mm) (Please read the back Please fill in this page for the matters needing attention) Pack i --- I. Order --------- Jun 408156 A7 Printed by B7 of the Consumers' Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs; _ ..:, -_ V. Description of the Invention (Λ ') Meng Jang, Da (epoxy-manpropyl) isoMuric acid, 3- (2-xenoxy) -1,2-pyridoxypropane, bispyridine hydrolysate, vinylcyclohexyl Diene epoxide, dicyclopentadiene dicyclochloride, and 3,4-epoxyhexyl-3-methyl-epoxyhexanecarboxylic acid ester. [Antistatic agent 3 is used in the present invention Zhilan lubricants and antistatic substances can usually be those used in polyolefin M films. The preferred MS of these antistatic substances include (a) those cationic types such as monoamine salt, triamine, Quaternary ammonium Compounds, pyridine derivatives, (b) such anionic types such as sulfonated oils, soaps: acidified cool oils, acidified amidamine oils, sulfates of fatty acids, alkyl alcohol sulfates of fatty alcohols, Fatty acid ethyl sulfonate, alkyl sulphonic acid S, alkylbenzene sulfonate, gadolinium succinate sulfonate g and phosphonium phosphonium salt. (C) Those non-ionic S are like multiple enzymes. Some fatty acids are cool, and the ethylene oxide of fatty alcohols is transformed into ethylene oxide adducts of fatty acids, fatty amines or ammonium fatty acids S3 ethylene oxide are transformed into weiwei, and alkylated epoxy Ethane addition toughness > Ethylene oxide addition of alkylzaiol, ethylene oxide formation of some fatty acid esters of polyols, and polyethylene glycol, and (< 1) Amphoteric types such as carboxylic acid-derived and oxazolyl-derived ββϊ. In particular, it is desirable to make non-ionic types such as, and among them, use polyoxyethylene alkylamines, polyacetylene Alkyl. Fatty acid esters of fatty acids _ or glycerol = mono fatty acid and fatty acid esters of polyhydric alcohols] The fatty acid esters include n-butyl stearate, rosin methyl ester, Dibutyl (n-butyl) diacid, dioctyl sebacate (2-ethylhexyl — — rlllil — — — — — — — — IIIIIII-ΙΙ1ΙΙΪ — Please read the precautions on the back first (Fill in this page) This paper size is applicable to national standards (CNS0A4 specifications (210x297g) 408156 A7 B7 ΒθΓ ^ V. Description of invention (" Wa7 Printed by Employee Consumer Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs) 2 * C aa ( P 0 4) 2 · 〇H 2 0 'S r (0 H) z * 3 r 3 (P 0 +) 2 *

Bail < 8a3 (P〇4 )z - 3Ba(0H)2 ·Βα3(Ρ〇4)2,2πΟ· l n'i \ P 0 4 )2 1 2 Z η 0 · B a s ( P 0 4 ) 2 : A 12 0 3 . A I P 0 4 1Bail < 8a3 (P〇4) z-3Ba (0H) 2 · βα3 (PO4) 2, 2πΟ · l n'i \ P 0 4) 2 1 2 Z η 0 · B as (P 0 4) 2: A 12 0 3. AIP 0 4 1

3SnO · 5n3 (P04 )2 · B a { 0 H) £ · N a Η P H 0 3 - 5CaG · NaHPH 0 3 ' 3 8 a ( G H } 2 · K 2 F rl ίί 3 > H g G * M g F Ft 0 3 ! 0 M g { 0 H ) 23SnO · 5n3 (P04) 2 · B a {0 H) £ · N a Η PH 0 3-5CaG · NaHPH 0 3 '3 8 a (GH) 2 · K 2 F rl ίί 3 > H g G * M g F Ft 0 3! 0 M g {0 H) 2

MiPHOs ! CaO · CaPHOa · oCa{0H)2 CaPH〇3 1 6a(0H)z -C a P n 0 3 ! 5CaO * C a P H 0 3 , BaO · BaPR〇3 , 2〇a (0H)2 -MiPHOs! CaO · CaPHOa · oCa (0H) 2 CaPH〇3 1 6a (0H) z -C a P n 0 3! 5CaO * C a P H 0 3, BaO · BaPR〇3, 2〇a (0H) 2-

BaPHih - 3Ba{0K)2 · Ba?H〇3 · 3H2 〇 ZnO · ZnPHDs ,BaPHih-3Ba {0K) 2 · Ba? H〇3 · 3H2 〇 ZnO · ZnPHDs,

Z π0 · ;j C a P H03 - Ti〇z * TiiPK〇3 )z ' Al2 03 * AIZ (P Η ϋ 3 ) 3 ,3 Z r 0 * Z r P H 0 3 ,3 n Q * S π P H 0 3 ,3 S n 0 * S η P H 0 3 ,M g ( 0 H ) z · M g2 3 i 0 4 ,3 S g 0 * M g S i 0 e 5 C a 0 * Ca2 S i 0 4 ’ 3Cai) * Li2 Si〇3 , 3 C a 0, C a S i 2 〇 5 2 C a (0 H) 2 * Ca2 Si3 * SrO · SrSi03 > 5BaO· 8a2 Si04 - 8a(0H)2 · 8a2, S1O4 · 6H2 Gj Ba(0H)2 ' 〇aSi〇3 ! 3Ba(0H}2 * Ba S i 2 i) 5 » 〇BaO· Baz Si〇4 > B a ( 0 H ) 2 · C a S i 0 3 > 2 Z n G ·Z π0 ·; j C a P H03-Ti〇z * TiiPK〇3) z 'Al2 03 * AIZ (P Η ϋ 3) 3, 3 Z r 0 * Z r PH 0 3, 3 n Q * S π PH 0 3, 3 S n 0 * S η PH 0 3, M g (0 H) z · M g2 3 i 0 4, 3 S g 0 * M g S i 0 e 5 C a 0 * Ca2 S i 0 4 '3Cai) * Li2 Si〇3, 3 C a 0, C a S i 2 〇5 2 C a (0 H) 2 * Ca2 Si3 * SrO · SrSi03 > 5BaO · 8a2 Si04-8a (0H) 2 · 8a2 , S1O4 · 6H2 Gj Ba (0H) 2 '〇aSi〇3! 3Ba (0H) 2 * Ba S i 2 i) 5 »〇BaO · Baz Si〇4 > B a (0 H) 2 · C a S i 0 3 > 2 Z n G

ZnSiOs , ZnO > 3 C a S i 0 3 - CaO · Sn2 S104 , .Mg (OH) * Hg (fi〇3 ) z ' 〇CaO* Ca(N〇s )2 1 2Ca(0H)2 * CaiSOs ) zZnSiOs, ZnO > 3 C a S i 0 3-CaO · Sn2 S104, .Mg (OH) * Hg (fi〇3) z '〇CaO * Ca (N〇s) 2 1 2Ca (0H) 2 * CaiSOs ) z

Srtz 〇j 3BaO - Ba{NG3 )z ' Ba(OH}2 * Sa2 S04 > ZnO· K 2 i G 4 * 3 C a 0 * K z 3 0 3 , M g (0 H } 2 - K g S 0 4 » 5 M g 0 * M g :i〇3 , · MgS03 , HgiJ , CaS03 - 5CaO. CaSO+ , Ca( OH} 9 · C a S 0 4 ,3CaG CaS03 ,SrO * S r 3 0 2 ,3BaO · BaSrtz 〇j 3BaO-Ba {NG3) z 'Ba (OH) 2 * Sa2 S04 > ZnO · K 2 i G 4 * 3 C a 0 * K z 3 0 3, M g (0 H} 2-K g S 0 4 »5 M g 0 * M g: i〇3, · MgS03, HgiJ, CaS03-5CaO. CaSO +, Ca (OH) 9 · C a S 0 4, 3CaG CaS03, SrO * S r 3 0 2, 3BaOBa

oiK, ^ :>gi\0 - CaS〇3 - 3a(0H)2 - BaS04 ' Ti02 · Ti(S Π ! ) £ ,A 1 2 〇 3 · A 1 2 (S 〇 4 )3 1 A 1(0 H)2 * M g S 0 4 - -2 ij - 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) n 1 IT >^1 n Jf- n if n t Et n n ^eJ n l— n n I (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 ^9* δ* !修正 408156 =卜"補充五、發明說明(叫) ,止辛基)甘油脂肪酸酷,異戊四醇四硬§旨酸酯,聚乙二 醇脂肪酸酯,聚乙二醇二硬脂酸酯,聚乙二醇二月桂酸酯 τ聚乙二醉二油酸齙,聚乙二醇椰子脂肪酸二酯,聚乙二 _高油脂防酸二酯,乙二醇裼煤酸二飽* 1 , 3 - 丁二酵裼煤 酸二酯’二二酵醇硬脂酸二酯,丙二醇脂肪酸二酯,甘油 詣蠟’ Μ化的食甩油或脂肪,1卜羥基硬脂酸之甘油酯, 隸躐,褐煤蠟,棕擱鱺,絳锱,木躐,軍羥基脂肪酸酵和 脂肪酸之飽和酸酯(例如,粗隸油月桂基硬脂酸酯,硬陏 酸硬脂基酯),羊毛脂,聚乙烯攞,聚丙烯纖,氧化聚乙 烯__,酸改質之聚烯烴蟠,環氧樹贈改質之聚乙烯蟣,和 石油_。每進一步使甩該等含其部份酷者。 阻礙胺化合铹的實例S括硬脂酸1 , 2 , 2 , 6,S -五甲基-4 -锨啶基酯,苯甲酸2 , 2 , 6 , S-四甲基-4-頰啶基酯,Ν - (2, 2,3,123甲基-4-锨啶基)十二基琥珀酸亞胺,卜[(3,5-二 -三级-丁基-4-羥基苯基)丙_氧乙基]-2, 2, 6,6-四甲基-4 啶基-U , 5-二-三鈒-丁基羥苯基)丙酸酯,雙(2 , 2 , S , S -四甲基-4-哌啶基)癸二酸酯,四(2 , 2 , 6 , S-四甲基-4-_ 啶基)Γ烷四羧酸酯,四(1 , 2 , 2 , S , S -五甲基-4 -哌啶基)丁 烷四羧酸酯,雙(2 , 2 , 6 , S-四甲基-4-派啶基)-二(十三棊} 了烷R羧酸酷,和雙(1,2, 2,6,k五甲基-4-锨哫基卜二( 十三基)丁烷四菝酸酯。 為了進一步改良電絕緣性質,可混合於2 (J到1!] 00重量 扮和|特別地_ 2 ϋ ϋ到5 (I (1重量份之無定肜矽石•耐火高嶺 -29- — — — — — ΙΙΙΙ1Ι— — — — —— — II ^ ·11111111 ^ (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 408156oiK, ^: > gi \ 0-CaS〇3-3a (0H) 2-BaS04 'Ti02 · Ti (S Π!) £, A 1 2 〇3 · A 1 2 (S 〇4) 3 1 A 1 (0 H) 2 * M g S 0 4--2 ij-This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) n 1 IT > ^ 1 n Jf- n if nt Et nn ^ eJ nl— nn I (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs ^ 9 * δ *! Amendment 408156 = bu " Supplementary description of the invention (called), Octyl) glycerol fatty acid, isotetraol tetrastearic acid ester, polyethylene glycol fatty acid ester, polyethylene glycol distearate, polyethylene glycol dilaurate τ polyethylene glycol Diethylene glycol dioleate, polyethylene glycol coconut fatty acid diester, polyethylene glycol_high-fat anti-acid diester, ethylene glycol / coalic acid disaturation * 1, 3-succinate / coalate diester Alcohol stearic acid diesters, propylene glycol fatty acid diesters, glycerol waxes, edible oils or fats, 1 g of glycerol esters of hydroxystearic acid, lignin, montan wax, palm oil, brown, wood , Saturated fatty acid esters of hydroxy fatty acid fermentation and fatty acids ( For example, crude oil lauryl stearate, stearyl stearate), lanolin, polyethylene 攞, polypropylene fiber, oxidized polyethylene _, acid modified polyolefin 蟠, epoxy tree gift Modified polyethylene tincture, and petroleum. Every further move rejects those who contain some of them. Examples of hindering amidines S include 1,2,2,6, S-pentamethyl-4-pyridinyl stearate, 2,2,6, S-tetramethyl-4-chrysidine Ester, N-(2,2,3,123methyl-4-amidinyl) dodecylsuccinic acid imide, [[3,5-di-tertiary-butyl-4-hydroxyphenyl ) Propoxyethyl] -2,2,6,6-tetramethyl-4pyridyl-U, 5-di-tris-fluorenyl-butylhydroxyphenyl) propionate, bis (2, 2, S , S-tetramethyl-4-piperidinyl) sebacate, tetra (2, 2, 6, S-tetramethyl-4-_pyridinyl) Γalkanetetracarboxylic acid ester, tetra (1, 2 , 2, S, S-pentamethyl-4-piperidinyl) butane tetracarboxylic acid ester, bis (2, 2, 6, S-tetramethyl-4-pyridinyl) -bis (tridecylidene) } Alkane R carboxylic acid, and bis (1,2,2,6, k pentamethyl-4-fluorenyl bis (tridecyl) butane tetraphosphonate. To further improve the electrical insulation properties, Can be mixed in 2 (J to 1!) 00 weight and | in particular _ 2 ϋ ϋ to 5 (I (1 part by weight of indefinite silica • refractory kaolin-29- — — — — — ΙΙΙΙ1Ι— — — — —— — II ^ · 11111111 ^ (Please read the notes on the back before filling this page) With China National Standard (CNS) A4 (210 X 297 mm) 408156

五、發明說明(β) 經濟部智慧財產局員工消費合作社印製 M g (! ‘ M g 3 ( Β 0 4 ) 1 5 C a ί) · (30+ ) 2 ' 5 C a ( 0 Η ) 2 · C a 3 (Biii )z ^ 3CaO * Ca(B〇2 )2 ^ 3Ba(0EUz · 3as (BO4 }z 1 〇Ha(j- 〇afi,l· H7 ! « B a (0 H) 2 * B a ( B 0 2 ) 2 > N a R C 0 3 , M g ί H i' 0 3 ) 2 5 L i H C 0 3 ,B a C。3 ,M g L' G 3 ,Z η ί: 0 3 和 ί i z C02 : [過氯酸] 過氯酸鹽的實洌包括引人過氯酸離子之水滑石,鹼-鋁複合_氬氧化韧,K及過氛酸鋰,過氢酸納,過氯酸鎂 ,過氯酸鈣,遇氛酸鋇和過氯酸鋅。亦允許使用過氯酸鹽 和多_元醇的複合锪。多元酵的較佳實例包括二甘醇單甲基 醚,三甘醇或丙二酵單甲醚。 [紫外線吸牧劑】 紫許線吸牧劑的貢洌包括2 -羥基苯_例如2 , 4 -二羥基 苯觸^ 2-羥基-4-甲氧基苯_,和δ,5’-亞甲基雙(2-羥基-4-甲氧基苯_);和2-U’-羥苯基)苯駢三哩洌如2-(2’-羥 - 5 ’ -甲苯基)苯駢三唑,2 - ( 2 ^羥基-3 ’ -三级-丁基-5 ’ -甲 苯基)-5-¾苯駢三哇,2-(2’-羥基4’-三级-辛苯基)苯駢 三唑,2-U’-羥基-3’,5’-二異丙苯基苯基)苯駢三唑,和 2, 2-亞甲基雙(4-三级-辛基苯駢三唑)酚。 [環氧丨b合物! 環氣化含物Z簧剀包拈環氧ib大豆油*環氧化亞麻子 油,環氧ib魚油*環氧化高油之脂肪酸酯,環氛化牛脂油 ,環氣ib證麻油,環氧化紅花油,環氧化亞麻子油之脂肪 (請先閱讀背面之注t事項再填寫本頁) 裝--------訂---------峻 本紙張尺度適用中國國家標準(CNS)A4規格(210x297公釐) 408156 A7V. Description of the invention (β) Printed by Mg (! 'M g 3 (Β 0 4) 1 5 C a ί) · (30+) 2' 5 C a (0 Η) 2 · C a 3 (Biii) z ^ 3CaO * Ca (B〇2) 2 ^ 3Ba (0EUz · 3as (BO4) z 1 〇Ha (j- 〇afi, l · H7! «B a (0 H) 2 * B a (B 0 2) 2 > Na a RC 0 3, M g ί H i '0 3) 2 5 L i HC 0 3, B a C. 3, M g L' G 3, Z η ί : 0 3 and iz C02: [Perchloric acid] Examples of perchlorate include hydrotalcite that attracts perchlorate ions, alkali-aluminum complex_argon oxidation toughness, K and lithium peroxyacid, perhydroacid Sodium, Magnesium Perchlorate, Calcium Perchlorate, Barium Phosphate and Zinc Perchlorate. It is also allowed to use a compound of perchlorate and polyhydric alcohols. Preferred examples of polyenzymes include diethylene glycol monomethyl Ether, triethylene glycol or malonyl monomethyl ether. [Ultraviolet grazing agent] The tributary of the purple line grazing agent includes 2-hydroxybenzene_for example, 2,4-dihydroxybenzene contact ^ 2-hydroxy-4 -Methoxybenzene_, and δ, 5'-methylenebis (2-hydroxy-4-methoxybenzene_); and 2-U'-hydroxyphenyl) benzene, three miles such as 2- ( 2'-Hydroxy-5'-tolyl) benzotriazole 2-(2 ^ Hydroxy-3'-tertiary-butyl-5'-tolyl) -5-¾phenylhydrazine, 3,2- (2'-hydroxy4'-tertiary-octylphenyl) benzene Triazole, 2-U'-hydroxy-3 ', 5'-dicumylphenyl) benzotriazole, and 2,2-methylenebis (4-tertiary-octylbenzotriazole) )phenol. [Epoxy 丨 b compound! Circulating gasification content Z spring packs 拈 epoxy ib soybean oil * epoxidized linseed oil, epoxy ib fish oil * epoxidized high oil fatty acid esters, epoxidized tallow oil, epoxidized sesame oil, epoxidized Safflower oil, fat of epoxidized linseed oil (please read the note t on the back before filling this page) Packing -------- Order --------- This paper is applicable to China Standard (CNS) A4 size (210x297 mm) 408156 A7

經濟部智慧財產局員工消費合作社印製 年 f\ 2 _B7 1 遲?Γ, 五、發明說明(>?) 土,氧ib鋁,矽酸鋁*欸白,欸磷酸鹽或磷酸結,每[(10 .¾请汾成分(A)到ί Π之總量。 [含氛聚合锪組成钧] 本發明的含氯聚合物m成物與细结晶矽酸鈣摻合,龃 结晶矽酸鈣為或分(A)(或(ΰ)或與於2G: SG到30: 2(3之重 量比细结晶矽酸鈣和多元醇的複合韧(Ε )),於0 . 2到1 (i重 量份和,特別地,0. 5到5重量份,和與(C )水滑石或鹼一 鋁複合物氫氧化物,於i) . 1到1 ί)重量份和:特別地,D . 2到 0 . 5重量汾每1 0 G重量份含Μ聚合物。 含Μ聚合W之簧洌包括聚合物例如聚氛乙烯,聚偏二 氢乙烯,氢化聚氛乙烯,氯化聚乙烯,氛化聚丙烯,氯化 橡謬|氯乙烯/乙酸乙烯酯共聚物,氯乙烯/乙烯共聚物 ,氯乙烯/丙烯共聚物,氯乙烯/苯乙烯共聚物*氯乙烯 /異丁烯共聚物,氯乙烯/ 1二氢乙烯共聚物,氯乙烯/ 苯乙烯/順_ 丁烯二酸酐三元共聚饬,氯乙燔/苯乙烯/ 丙烯膪共聚栩,氯乙烯/ 丁二烯共聚,氯化乙烯基/氛丙 烯共聚物,氯乙烯/偏二氯乙烯/乙酸乙烯酯三元共聚物 -Μ乙烯/丙烯酸詣共聚樹,氮乙烯/順丁烯二酸酯共聚 窃,氯乙烯/甲基丙烯酯共聚饬,氯乙烯/丙鋪腫共聚物 ,和内部塑化聚氯乙烯;其與α —烯聚合韧洌如聚乙烯, 聚丙烯,聚丁烯或聚-3 -甲基丁烯,或與聚烯烴和洌如乙 烯/乙酸乙烯酯共聚物,乙烯/丙烯共聚物等,或與聚苯 乙Μ,丙烯酸澍脂或苯乙烯祐其他的單體(例如,無水的 -30- (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 408156 A7 經濟部智慧財產局員工消费合作社印製 B7 ;_ .. :, -_五、發明說明(Λ’) 萌j盎,爹(環氧曼丙基)異Μ尿酸酷,3-(2-xenoxy)-l,2 -瑁氧丙烷,雙齙二讅水甘油基_,乙烯基環己烯二環 氧化物,二環戊二烯二環氯化物,和3,4-環氧瑁己基-3-甲基-環氧己烷羧酸酯。 [抗靜電劑3 使甩於本發明中之瀾滑劑和抗靜電物通常可為該等使 用於聚烯烴Μ膜者。該等抗靜電物之較佳實MS括(a)該 等陽離子類型者例如一鈒胺鹽,三鈒胺,四级铵化合物, 骶啶衍生物,(b)該等陰離子類型者例如磺酸化油,肥皂 :礙酸化酷油,碌酸化蘧胺油^烯之硫酸酷鹽,脂肪醇疏 酸酯烷基硫酸酯_,脂訪酸乙基磺酸鹽,烷基蔡磺酸 S,烷基苯磺酸鹽,丁二酸詣磺酸g和磷酸銪鹽,(c)該 等非離子類S者倒如多元酵之部分脂肪酸酷,脂肪醇的環 氧乙烷邡成锪*睹肪酸的環氧乙烷加成物,脂肪胺或腊肪 酸藤胺S3環氧乙烷邡成薇,烷基鼢的環氧乙烷加成韧 > 烷 基蔡醇的環氧乙烷加成锪,多元醇之部分脂肪酸酯的環氧 乙烷邡成锪•和聚乙二酵,和(<1)該等兩性類型者例如羧 酸衍生拘和眯唑啭衍生掬β^ϊ。特別是,希望使搿該等非離 子類型者和,在他們之中,使用聚氧乙撐烷基胺,聚氣乙 jf烷基醯.駿或其脂肪酸_或甘油的脂肪酸酯= ί一元酵和多元醇的脂肪酸酯] 賭肪酸酯之簧洌包括硬脂酸正丁酯,1化的松脂甲酯 ,癸二酸二丁基(正丁基)酯,癸二酸二辛基(2 -乙基己基 — — rlllil — — — — —. - . I I I I I I I - ΙΙ1ΙΙΪ — · (請先間讀背面之注意事項再填寫本頁) 本紙張尺度適用t國國家標準(CNS0A4規格(210x297公t ) 經濟部智慧財產局員工消費合作社印製 408156 A7 __B7五、發明說明(d) 順一 r烯二酸> 丁二烯,丙烯購等)的共聚鞠,或與丙練 購/丁二烯/笨乙烯共聚物·丙烯酸酯/丁二烯/苯乙誦 共聚锪,或甲基丙烯_/丁二Μ/苯乙烯共聚锪的接合物 本發明安定劑在熱安定含氯聚合物是有效的。安定劑 的種類可現含氯聚合锪的種類而選擇。洌茆,當含氯聚合 物為荽乙烯樹脂時=希望成分(C)為水滑石和當含氯聚合 锪為氯化之氯乙烯樹脂時 > 希望成分(C)為鹼一鋁複合物 Μ氧ib锪。 在本發明的組成锪中,希望(η高级脂肪酸鋅混合於 〇 . 1到3 . D重量份和,特別地,0 . 2到2 . 0重量份每100重份 之含氛聚合韧|而旦(G )鼢類抗氧化劑混合於0 . Q 1到5 . G重 量份和,持别地,δ . 8 5到2 . G重量份,每10 G重量份含氛聚 合物重量。當水滑石為鋅改質之水滑石時,希望(Η) α -二 觸或召-_基酸酯混合於G . !H到5 . ί)重量份和*特別地, S3, ί) 3到1.0重量份,每ii)0重量份含氯聚合物。 本發明的含氯聚含物詛成锪可與已知的摻合劑依照已 知的方法溫合。洌如,本發明的組成物可與塑化劑,潤滑 劑,填充劏,著色劑,酎侯安定劑,防老化劑,光安定劑 ,紮外線吸收劑,抗靜電劑*強化劑,兩於重製之樹脂或 橡膠,棍據已知的配方溫合。 當做塑化劑,可使闲酷類塑化劑洌如肽酸_類塑化劑 或d二酸酯類塑化劑 > 聚酯類塑化劏*磷酸酯類塱化劑> -3 1 - (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 經濟部智慧財產局員工消費合作社印製 ^9* δ* !修正 408156 =卜"補充五、發明說明(叫) ,止辛基)甘油脂肪酸酷,異戊四醇四硬§旨酸酯,聚乙二 醇脂肪酸酯,聚乙二醇二硬脂酸酯,聚乙二醇二月桂酸酯 τ聚乙二醉二油酸齙,聚乙二醇椰子脂肪酸二酯,聚乙二 _高油脂防酸二酯,乙二醇裼煤酸二飽* 1 , 3 - 丁二酵裼煤 酸二酯’二二酵醇硬脂酸二酯,丙二醇脂肪酸二酯,甘油 詣蠟’ Μ化的食甩油或脂肪,1卜羥基硬脂酸之甘油酯, 隸躐,褐煤蠟,棕擱鱺,絳锱,木躐,軍羥基脂肪酸酵和 脂肪酸之飽和酸酯(例如,粗隸油月桂基硬脂酸酯,硬陏 酸硬脂基酯),羊毛脂,聚乙烯攞,聚丙烯纖,氧化聚乙 烯__,酸改質之聚烯烴蟠,環氧樹贈改質之聚乙烯蟣,和 石油_。每進一步使甩該等含其部份酷者。 阻礙胺化合铹的實例S括硬脂酸1 , 2 , 2 , 6,S -五甲基-4 -锨啶基酯,苯甲酸2 , 2 , 6 , S-四甲基-4-頰啶基酯,Ν - (2, 2,3,123甲基-4-锨啶基)十二基琥珀酸亞胺,卜[(3,5-二 -三级-丁基-4-羥基苯基)丙_氧乙基]-2, 2, 6,6-四甲基-4 啶基-U , 5-二-三鈒-丁基羥苯基)丙酸酯,雙(2 , 2 , S , S -四甲基-4-哌啶基)癸二酸酯,四(2 , 2 , 6 , S-四甲基-4-_ 啶基)Γ烷四羧酸酯,四(1 , 2 , 2 , S , S -五甲基-4 -哌啶基)丁 烷四羧酸酯,雙(2 , 2 , 6 , S-四甲基-4-派啶基)-二(十三棊} 了烷R羧酸酷,和雙(1,2, 2,6,k五甲基-4-锨哫基卜二( 十三基)丁烷四菝酸酯。 為了進一步改良電絕緣性質,可混合於2 (J到1!] 00重量 扮和|特別地_ 2 ϋ ϋ到5 (I (1重量份之無定肜矽石•耐火高嶺 -29- — — — — — ΙΙΙΙ1Ι— — — — —— — II ^ ·11111111 ^ (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 40815^ A7 B7 S3. 8. ~1 年 fl 曰 經濟部智慧財產局員工消費合作社印製 五、發明說明(/Ο 氛類塑化劑,®氮鈦酸類塑化劏’壬二酸類塑化劑’癸二 類塑化劏,硬脂酸類塑化劑,淳礞酸類塑化劑,偏苯三酸 酸類塑化劑’和笼1均四酸酸類塑化劑c‘ 當做潤滑劏,通宮使周U)烴類之一’洌如液化,天 然的或合成鐽烷烴,徽鼸^聚乙烯蠟’或氯化聚乙烯锺’ (b )鼯訪酸類之一洌如硬詣酸戎月桂酸’(e )脂肪酸單醯胺 或雙醯胺類之一 ’洌如醯胺異硬暗酸醱’截胺棕撊酸酷’ 醯胺湳酸酿*醯胺e s ii a t e,亞甲基雙硬脂基醯鞍’或乙撐 雙硬脂基醯胺,(d) 酯類之一例如硬脂酸丁豳*粗留蔌油 ,或乙二醇單硬脂酸酯,(e)酵類之一例如十六碳醇或硬脂 醇,(f)金靥皂洌韶硬脂酸鉛或硬脂酸鈣和(g)其混合物条 當做抗震劑,可使用氯化聚乙烯包含’例如,30到40 %的氛,Μ甲基丙歸酸甲醋’瑟乙嫌或两蹄腈’丙婦腫/ 丁二烯/苯乙烯樹脂,甲基丙烯酸甲酯/丁二烯/苯乙烯 樹Μ,或乙酸乙烯酯/乙烯共聚物樹脂接枝共聚合一種主 要由丙烯酸酯驵成之可聚合像膠所獲得之多成分類型樹詣 〇 當酸姐燃劑,可使甩鹵素類阻燃劑以及銻’鍇’鉬’ 鋁,矽石或鈦的氣化锪,Μ氣化物或硫化物*或硼酸 鋅,錫酸鋅,羥萋錫酸鋅,或其以金靥氫氧化物處理之鋅 化合物。+ ί賁浏] 32 本紙張尺度適用中國國家標準(CNS)A4 %格(210 X 297公釐) ------- 裝-------訂· -------線 (請先閱讀背面之泫意事項再填寫本頁) 408156 A7Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs f \ 2 _B7 1 Late? Γ, V. Description of the invention (>?) Soil, oxyaluminum, aluminum silicate * white, phosphonate or phosphate junction, each [(10.¾ Please total amount of Fen ingredients (A) to Π. [Composite polymer containing fluorene] Composition of the chlorine-containing polymer m of the present invention is blended with fine crystalline calcium silicate, and crystalline crystalline calcium silicate (A) (or (ΰ) or with 2G: SG to 30: 2 (3 weight ratio of fine crystalline calcium silicate and polyol composite toughness (E)), from 0.2 to 1 (i Parts by weight and, in particular, 0.5 to 5 parts by weight, and (C) hydrotalcite or alkali-aluminum complex hydroxide, in i). 1 to 1 ί) parts by weight: and, in particular, D. 2 to 0.5 weight fen per 10 G parts by weight of polymer containing M. The polymer containing M polymer W includes polymers such as polyvinyl acetate, polyvinylidene dihydrogen, hydrogenated polyvinyl acetate, chlorinated polyethylene, and acrylic resin. Polypropylene, chlorinated rubber | vinyl chloride / vinyl acetate copolymer, vinyl chloride / ethylene copolymer, vinyl chloride / propylene copolymer, vinyl chloride / styrene copolymer * vinyl chloride / isobutylene copolymer, vinyl chloride / 1 Dihydroethylene copolymer , Vinyl chloride / styrene / cis-butadiene anhydride terpolymer copolymerization, vinyl chloride / styrene / propylene copolymerization, vinyl chloride / butadiene copolymerization, chlorinated vinyl / acryl copolymer, vinyl chloride / Vinylidene chloride / vinyl acetate terpolymer-M ethylene / acrylic acid copolymer tree, vinylidene / maleate copolymerization copolymer, vinyl chloride / methacrylic acid copolymer copolymer, vinyl chloride / propylene copolymer Copolymers, and internal plasticized polyvinyl chloride; it polymerizes with alpha-olefins such as polyethylene, polypropylene, polybutene or poly-3-methylbutene, or with polyolefins and polymers such as ethylene / vinyl acetate Ester copolymer, ethylene / propylene copolymer, etc., or other monomers with polystyrene, acrylic resin or styrene (for example, anhydrous -30- (Please read the precautions on the back before filling this page) This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 408156 A7 Printed by B7 of the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs; _ ..:, -_ V. Description of Invention (Λ ') Meng j Ang, d (epoxymanpropyl) isoMuric acid, 3- (2-xenoxy) -l, 2--oxopropane, bispyrene Glycolyl glycidyl_, vinylcyclohexene diepoxide, dicyclopentadiene dicyclochloride, and 3,4-epoxyhexyl-3-methyl-epoxyhexanecarboxylate. [ Antistatic agent 3 The anti-static agent and antistatic substance used in the present invention can generally be those used in polyolefin M film. The preferred examples of these antistatic substances include (a) those of the cationic type For example monoammonium salt, triammonium amine, quaternary ammonium compounds, pyrimidine derivatives, (b) such anionic types such as sulfonated oils, soaps: acidified cool oils, acidified ammonium oils Salt, fatty alcohol sulfonate alkyl sulfate_, fatty acid ethyl sulfonate, alkyl sulfonic acid S, alkylbenzene sulfonate, succinic acid sulfonic acid g, and phosphonium phosphonium salt, (c ) These non-ionic S are like some of the fatty acids in the multi-enzyme, the ethylene oxide of fatty alcohols is formed * see the ethylene oxide adducts of fatty acids, fatty amines or ammonium fatty acids S3 ring Oxidation of ethylene oxide into ethylene, addition of ethylene oxide to alkyl 鼢 > ethylene oxide addition of alkyl zeolol, ethylene oxide of some fatty acid esters of polyols, and Polyethylene glycol , And (< 1) such bisexual types as carboxylic acid-derived and oxazolyl-derived ββϊ. In particular, it is desirable to make those non-ionic types and, among them, use polyoxyethylene alkylamines, polyalkylene oxide alkylates. Jun or its fatty acids _ or fatty acid esters of glycerol = ί one yuan Fatty acid esters of yeast and polyalcohols] The reeds of fatty acid esters include n-butyl stearate, methylated pinoresinate, dibutyl (n-butyl) sebacate, dioctyl sebacate (2 -Ethylhexyl — — rlllil — — — — —. —. IIIIIII-ΙΙ1ΙΙΪ — · (Please read the precautions on the back before filling this page) This paper size is applicable to national standards (CNS0A4 specifications (210x297) t) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 408156 A7 __B7 V. Description of the invention (d) Copolymerization of maleic acid > butadiene, propylene purchase, etc.) / Styrene copolymer · Acrylate / Butadiene / Styrene copolymer copolymer, or methacrylic acid / butadiene / styrene copolymer copolymer The stabilizer of the present invention is effective in thermally stabilizing a chlorine-containing polymer .The type of stabilizer can be selected according to the type of chlorine-containing polymer. When the material is a vinyl resin = the desired component (C) is hydrotalcite and when the chlorine-containing polymer is a chlorinated vinyl chloride resin > the desired component (C) is an alkali-aluminum complex Moxyib 锪. In the present invention In the composition 锪, it is desirable that (η higher fatty acid zinc is mixed in 0.1 to 3. D parts by weight and, in particular, 0.2 to 2.0 parts by weight per 100 parts by weight of the atmosphere-containing polymer toughness | ) 鼢 -type antioxidants are mixed in 0. Q 1 to 5. G parts by weight and, separately, δ. 8 5 to 2. G parts by weight, per 10 G parts by weight of the atmosphere-containing polymer. When the hydrotalcite is zinc When the hydrotalcite is modified, it is desirable that (Η) α-two-touch or tau-basic acid ester is mixed with G.! H to 5. ί) parts by weight and * specifically, S3, ί) 3 to 1.0 parts by weight, Per ii) 0 parts by weight of the chlorine-containing polymer. The chlorinated polycontent of the present invention can be mixed with known admixtures in accordance with known methods. For example, the composition of the present invention can be combined with plasticizers, lubricants, fillers, colorants, anti-aging stabilizers, anti-aging agents, light stabilizers, external absorbing agents, antistatic agents * strengthening agents, Reconstituted resin or rubber, the stick is warmed according to the known formula. As a plasticizer, it can make leisure-time plasticizers such as peptidic acid-based plasticizers or d-diester-based plasticizers > polyester-based plasticizers * phosphate ester-based plasticizers > -3 1-(Please read the precautions on the back before filling this page) This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs ^ 9 * δ *! Amendment 408156 = "Supplement V. Description of the invention (called), only octyl) glycerol fatty acid, isopentaerythritol tetrastearic acid ester, polyethylene glycol fatty acid ester, polyethylene glycol distearate Ester, Polyethylene glycol dilaurate τ Polyethylene glycol dioleate, Polyethylene glycol coconut fatty acid diester, Polyethylene glycol_high-fat anti-acid diester, Diethylene glycol dicarbonate disaturation * 1 , 3-succinic acid / coalic acid diesters, 'diglycerol stearic acid diesters, propylene glycol fatty acid diesters, glycerol waxes', edible oils or fats, 1 glyceryl ester of hydroxystearic acid, Liquan, montan wax, brown tincture, coriander, clogs, hydroxy fatty acid enzymes and saturated acid esters of fatty acids (for example, crude oil lauryl stearate, hard Stearyl acid), lanolin, polyethylene Luo, polypropylene fiber, polyethylene oxide __, the acid modified polyolefin coil, the epoxy resin modified polyethylene gift nit, and oil _. Every further move rejects those who contain some of them. Examples of hindering amidines S include 1,2,2,6, S-pentamethyl-4-pyridinyl stearate, 2,2,6, S-tetramethyl-4-chrysidine Ester, N-(2,2,3,123methyl-4-amidinyl) dodecylsuccinic acid imide, [[3,5-di-tertiary-butyl-4-hydroxyphenyl ) Propoxyethyl] -2,2,6,6-tetramethyl-4pyridyl-U, 5-di-tris-fluorenyl-butylhydroxyphenyl) propionate, bis (2, 2, S , S-tetramethyl-4-piperidinyl) sebacate, tetra (2, 2, 6, S-tetramethyl-4-_pyridinyl) Γalkanetetracarboxylic acid ester, tetra (1, 2 , 2, S, S-pentamethyl-4-piperidinyl) butane tetracarboxylic acid ester, bis (2, 2, 6, S-tetramethyl-4-pyridinyl) -bis (tridecylidene) } Alkane R carboxylic acid, and bis (1,2,2,6, k pentamethyl-4-fluorenyl bis (tridecyl) butane tetraphosphonate. To further improve the electrical insulation properties, Can be mixed in 2 (J to 1!) 00 weight and | in particular _ 2 ϋ ϋ to 5 (I (1 part by weight of indefinite silica • refractory kaolin-29- — — — — — ΙΙΙΙ1Ι— — — — —— — II ^ · 11111111 ^ (Please read the notes on the back before filling this page) Printed in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 40815 ^ A7 B7 S3. 8. ~ 1 year fl printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Agents, ® Azotitanate-based plasticized 劏 'Azelaic acid-based plasticized' 'Second-type plasticized 劏, Stearic acid-based plasticizer, steric acid-based plasticizer, trimellitic acid-based plasticizer' and cage Methionate plasticizer c 'is used as a lubricating agent, and it is one of the hydrocarbons, such as liquefied, natural or synthetic alkanes, Hui ^ polyethylene wax' or chlorinated polyethylene 锺 '( b) One of the Suwa acids, such as stearic acid and lauric acid '(e) one of the fatty acids, monoamine or bisamine, such as amido isostearic acid, peptamine, palmitate, and ammonium Acetic acid * amine es ii ate, methylene bisstearyl saddle 'or ethylene bisstearyl amide, (d) one of the esters such as butyl stearate * crude oil, or Ethylene glycol monostearate, (e) one of the enzymes such as cetyl alcohol or stearyl alcohol, (f) gold tincture soap, lead stearate or calcium stearate, and (g) a mixture thereof As an anti-seismic agent, Chlorinated polyethylene contains' for example, 30 to 40% of the atmosphere, methacrylic acid methyl vinegar 'or ethanoic acid or bitrinitrile' acetone / butadiene / styrene resin, methyl methacrylate / Graft copolymerization of butadiene / styrene tree M, or vinyl acetate / ethylene copolymer resin A multi-component type tree obtained by polymerizable photoresist mainly composed of acrylic esters. Halogen-based flame retardants and the vaporization of antimony '' 'molybdenum' aluminum, silica or titanium, M vapors or sulfides * or zinc borate, zinc stannate, zinc hydroxytintinate, or gold Rhenium hydroxide treated zinc compounds. + ί 贲 刘] 32 This paper size applies to Chinese National Standard (CNS) A4% grid (210 X 297 mm) ------- Loading ------- Ordering ------- (Please read the notice on the back before filling this page) 408156 A7

經濟部智慧財產局員工消費合作社印製 年 f\ 2 _B7 1 遲?Γ, 五、發明說明(>?) 土,氧ib鋁,矽酸鋁*欸白,欸磷酸鹽或磷酸結,每[(10 .¾请汾成分(A)到ί Π之總量。 [含氛聚合锪組成钧] 本發明的含氯聚合物m成物與细结晶矽酸鈣摻合,龃 结晶矽酸鈣為或分(A)(或(ΰ)或與於2G: SG到30: 2(3之重 量比细结晶矽酸鈣和多元醇的複合韧(Ε )),於0 . 2到1 (i重 量份和,特別地,0. 5到5重量份,和與(C )水滑石或鹼一 鋁複合物氫氧化物,於i) . 1到1 ί)重量份和:特別地,D . 2到 0 . 5重量汾每1 0 G重量份含Μ聚合物。 含Μ聚合W之簧洌包括聚合物例如聚氛乙烯,聚偏二 氢乙烯,氢化聚氛乙烯,氯化聚乙烯,氛化聚丙烯,氯化 橡謬|氯乙烯/乙酸乙烯酯共聚物,氯乙烯/乙烯共聚物 ,氯乙烯/丙烯共聚物,氯乙烯/苯乙烯共聚物*氯乙烯 /異丁烯共聚物,氯乙烯/ 1二氢乙烯共聚物,氯乙烯/ 苯乙烯/順_ 丁烯二酸酐三元共聚饬,氯乙燔/苯乙烯/ 丙烯膪共聚栩,氯乙烯/ 丁二烯共聚,氯化乙烯基/氛丙 烯共聚物,氯乙烯/偏二氯乙烯/乙酸乙烯酯三元共聚物 -Μ乙烯/丙烯酸詣共聚樹,氮乙烯/順丁烯二酸酯共聚 窃,氯乙烯/甲基丙烯酯共聚饬,氯乙烯/丙鋪腫共聚物 ,和内部塑化聚氯乙烯;其與α —烯聚合韧洌如聚乙烯, 聚丙烯,聚丁烯或聚-3 -甲基丁烯,或與聚烯烴和洌如乙 烯/乙酸乙烯酯共聚物,乙烯/丙烯共聚物等,或與聚苯 乙Μ,丙烯酸澍脂或苯乙烯祐其他的單體(例如,無水的 -30- (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 40815b A7 B7 〇 五、發明說明(η\) L~ 經濟部智慧財產局員工消費合作社印製 本發明現將經由下列不以圧何方式限制本發明之晋胨 浏說明。在貢例中f測量棍據描述於下的方法取得。 (1) 最籾著色的評ί古 一板Η在(]ΰ s I*氐烤箱中於1 9 ϋ t:邡熱1 0分鐘,和奴眼_到 斷忘芭色調且依評佶w下: I 2 3 4 無色 淡黃色 黃色 紅色 (2) 抗Geer氐烤箱加熱性 捏合-撗製P V C Η在烤箱中於1 S ϋ aC邡熱旦測量其著色 之時間(分鐘)K評沽其抗熱性。 (3) 熱安定S U.T) 藉Η根據符合J 1 S U 7 2 3之於1 S 0 Τ:剛果紅方法的氛化 Μ捕集瀏試測量。 (4) 體積電姐率 m ^ mm ADVANTE3T 3 4 0而使用5 0 G V電壓剷量體積 電瞪率= (5 )低溫之老化澜試 顯示於表5中的组成物在1 3 0 °C滚筒研磨糠捏合5分 鐘,和具有1毫米均勻厚度之軟氯乙烯片進行三天覬察且 判斷普色狀態。 板η者色程度K區分為7列四涸等级來評估。 0 > 1 > 2 > 3 Θ色 -33 (請先閱讀背面之注意事項再填寫本頁) 粉紅色 本紙張尺度適用中國國家標準(CNS)A4規格m〇 X 297公釐) 經濟部智慧財產局員工消費合作社印製 408156 A7 __B7五、發明說明(d) 順一 r烯二酸> 丁二烯,丙烯購等)的共聚鞠,或與丙練 購/丁二烯/笨乙烯共聚物·丙烯酸酯/丁二烯/苯乙誦 共聚锪,或甲基丙烯_/丁二Μ/苯乙烯共聚锪的接合物 本發明安定劑在熱安定含氯聚合物是有效的。安定劑 的種類可現含氯聚合锪的種類而選擇。洌茆,當含氯聚合 物為荽乙烯樹脂時=希望成分(C)為水滑石和當含氯聚合 锪為氯化之氯乙烯樹脂時 > 希望成分(C)為鹼一鋁複合物 Μ氧ib锪。 在本發明的組成锪中,希望(η高级脂肪酸鋅混合於 〇 . 1到3 . D重量份和,特別地,0 . 2到2 . 0重量份每100重份 之含氛聚合韧|而旦(G )鼢類抗氧化劑混合於0 . Q 1到5 . G重 量份和,持别地,δ . 8 5到2 . G重量份,每10 G重量份含氛聚 合物重量。當水滑石為鋅改質之水滑石時,希望(Η) α -二 觸或召-_基酸酯混合於G . !H到5 . ί)重量份和*特別地, S3, ί) 3到1.0重量份,每ii)0重量份含氯聚合物。 本發明的含氯聚含物詛成锪可與已知的摻合劑依照已 知的方法溫合。洌如,本發明的組成物可與塑化劑,潤滑 劑,填充劏,著色劑,酎侯安定劑,防老化劑,光安定劑 ,紮外線吸收劑,抗靜電劑*強化劑,兩於重製之樹脂或 橡膠,棍據已知的配方溫合。 當做塑化劑,可使闲酷類塑化劑洌如肽酸_類塑化劑 或d二酸酯類塑化劑 > 聚酯類塑化劏*磷酸酯類塱化劑> -3 1 - (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 4081^^ A7 B7 五、發明說明) (合或簧渕1 ; 具體地ra逑於下的是一種合成使用於本發明的實例中 之细结晶矽酸鈣之方法:將498.8克石灰的乳漿(6%之 CaG含最)和42. 8克具有5微米平均粒子大小之活性矽酸粉 末引進陶瓷盆式研磨機內,且研磨和反懕5 4遐小時以獲得 具有pH 1ί丨之漿液。過滋漿疲,以水洗滌•於110 1C乾煉, 和在冷·型試漾妍磨機中粉碎以獲得细粉末鈣—矽石複合物 Μ氧ib搏(C S Η - 1)。其择質如表4所示。此外同樣地,當變 更活姓矽酸對石灰的乳菽的比,致使綑粉末鈣一矽石複合 窃氧ih物之C a/ S i莫耳比為0 · 4和2 . 5時,C S Η - 2和C S H - 3被 合成c (合或簧例2 ) ' 具體地描逑於下的是一種合成使罔在本發明的簧例中 之细结晶矽酸鈣和多元醇的磨碎混合趨之方法。 將2S5克石灰的轧漿(6 %之CaO含量)* 24 . 2克具有5 微亲平均粒子大小之活性矽酸粉末,和40克二異戊四酵引 進陶瓷S式研磨饈肉,且研磨和反應5 4個小時Μ獲得具有 pH i ϋ之漿疲。過慂漿液,Κ求洗滌,於1 1 G t:乾燥*和在 小型試樣研磨機粉晬以獲得K多元酵塗佈塗的细粉末鈣-矽石複合物氬氧化锊(C A S K );其性貿如表4围示。 表 4 CSH-1 CSH-2 C3H-3 CASH 硬矽鈣 Έ -34- 本紙張尺度適用中國國家標準(CNS)A4規格(210 x 297公S ) (請先閱讀背面之注意事項再填寫本頁) 裝·! II —--訂-- --- 經濟部智慧財產局員工消費合作社印製 40815^ A7 B7 S3. 8. ~1 年 fl 曰 經濟部智慧財產局員工消費合作社印製 五、發明說明(/Ο 氛類塑化劑,®氮鈦酸類塑化劏’壬二酸類塑化劑’癸二 類塑化劏,硬脂酸類塑化劑,淳礞酸類塑化劑,偏苯三酸 酸類塑化劑’和笼1均四酸酸類塑化劑c‘ 當做潤滑劏,通宮使周U)烴類之一’洌如液化,天 然的或合成鐽烷烴,徽鼸^聚乙烯蠟’或氯化聚乙烯锺’ (b )鼯訪酸類之一洌如硬詣酸戎月桂酸’(e )脂肪酸單醯胺 或雙醯胺類之一 ’洌如醯胺異硬暗酸醱’截胺棕撊酸酷’ 醯胺湳酸酿*醯胺e s ii a t e,亞甲基雙硬脂基醯鞍’或乙撐 雙硬脂基醯胺,(d) 酯類之一例如硬脂酸丁豳*粗留蔌油 ,或乙二醇單硬脂酸酯,(e)酵類之一例如十六碳醇或硬脂 醇,(f)金靥皂洌韶硬脂酸鉛或硬脂酸鈣和(g)其混合物条 當做抗震劑,可使用氯化聚乙烯包含’例如,30到40 %的氛,Μ甲基丙歸酸甲醋’瑟乙嫌或两蹄腈’丙婦腫/ 丁二烯/苯乙烯樹脂,甲基丙烯酸甲酯/丁二烯/苯乙烯 樹Μ,或乙酸乙烯酯/乙烯共聚物樹脂接枝共聚合一種主 要由丙烯酸酯驵成之可聚合像膠所獲得之多成分類型樹詣 〇 當酸姐燃劑,可使甩鹵素類阻燃劑以及銻’鍇’鉬’ 鋁,矽石或鈦的氣化锪,Μ氣化物或硫化物*或硼酸 鋅,錫酸鋅,羥萋錫酸鋅,或其以金靥氫氧化物處理之鋅 化合物。+ ί賁浏] 32 本紙張尺度適用中國國家標準(CNS)A4 %格(210 X 297公釐) ------- 裝-------訂· -------線 (請先閱讀背面之泫意事項再填寫本頁)Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs f \ 2 _B7 1 Late? Γ, V. Description of the invention (>?) Soil, oxyaluminum, aluminum silicate * white, phosphonate or phosphate junction, each [(10.¾ Please total amount of Fen ingredients (A) to Π. [Composite polymer containing fluorene] Composition of the chlorine-containing polymer m of the present invention is blended with fine crystalline calcium silicate, and crystalline crystalline calcium silicate (A) (or (ΰ) or with 2G: SG to 30: 2 (3 weight ratio of fine crystalline calcium silicate and polyol composite toughness (E)), from 0.2 to 1 (i Parts by weight and, in particular, 0.5 to 5 parts by weight, and (C) hydrotalcite or alkali-aluminum complex hydroxide, in i). 1 to 1 ί) parts by weight: and, in particular, D. 2 to 0.5 weight fen per 10 G parts by weight of polymer containing M. The polymer containing M polymer W includes polymers such as polyvinyl acetate, polyvinylidene dihydrogen, hydrogenated polyvinyl acetate, chlorinated polyethylene, and acrylic resin. Polypropylene, chlorinated rubber | vinyl chloride / vinyl acetate copolymer, vinyl chloride / ethylene copolymer, vinyl chloride / propylene copolymer, vinyl chloride / styrene copolymer * vinyl chloride / isobutylene copolymer, vinyl chloride / 1 Dihydroethylene copolymer , Vinyl chloride / styrene / cis-butadiene anhydride terpolymer copolymerization, vinyl chloride / styrene / propylene copolymerization, vinyl chloride / butadiene copolymerization, chlorinated vinyl / acryl copolymer, vinyl chloride / Vinylidene chloride / vinyl acetate terpolymer-M ethylene / acrylic acid copolymer tree, vinylidene / maleate copolymerization copolymer, vinyl chloride / methacrylic acid copolymer copolymer, vinyl chloride / propylene copolymer Copolymers, and internal plasticized polyvinyl chloride; it polymerizes with alpha-olefins such as polyethylene, polypropylene, polybutene or poly-3-methylbutene, or with polyolefins and polymers such as ethylene / vinyl acetate Ester copolymer, ethylene / propylene copolymer, etc., or other monomers with polystyrene, acrylic resin or styrene (for example, anhydrous -30- (Please read the precautions on the back before filling this page) This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 40815b A7 B7 05. Invention Description (η \) L ~ Printed by the Consumers' Cooperative of Intellectual Property Bureau of the Ministry of Economy How to limit the description of the invention in any way. In the case of f Obtained according to the method described below. (1) The most colored comment ί an ancient plate Η in (] ΰ s I * 氐 oven in 1 9 ϋ t: 邡 heat for 10 minutes, and slave eyes _ to the forgotten According to the evaluation, I 2 3 4 colorless yellowish yellow red (2) anti-Geer 氐 oven heating kneading-made of PVC Η in the oven at 1 S ϋ aC 邡 heat denier measurement time ( Minutes) K commented on its heat resistance. (3) Thermal stability S UT) Based on JM SU 7 2 3 in 1 S 0 Τ: Congo Red method of atmospheric M capture test test. (4) Volume rate rate m ^ mm ADVANTE3T 3 4 0 and 50 GV voltage shovel volume volume rate = (5) Low temperature aging test shows the composition shown in Table 5 at 1 30 ° C roller The kneaded bran was kneaded for 5 minutes, and the soft vinyl chloride sheet having a uniform thickness of 1 mm was examined for three days and the general color state was judged. The degree of color K of the plate η is divided into 7 columns and four levels. 0 > 1 > 2 > 3 Θ-33 (Please read the precautions on the back before filling out this page) Pink This paper size applies the Chinese National Standard (CNS) A4 size m × X 297 mm) Ministry of Economic Affairs Printed by the Intellectual Property Bureau employee consumer cooperative 408156 A7 __B7 V. Description of the invention (d) Copolymerization of maleic acid > butadiene, propylene purchase, etc.), or copolymerization with acrylic / butadiene / benzyl ethylene Compound of acrylic acid / butadiene / styrene copolymer, or methacrylic acid / butadiene / styrene copolymer, the stabilizer of the present invention is effective in thermally stabilizing a chlorine-containing polymer. The type of stabilizer can be selected according to the type of the chlorine-containing polymer fluorene.洌 茆, when the chlorine-containing polymer is 荽 vinyl resin = the desired component (C) is hydrotalcite and when the chlorinated polymer 锪 is a chlorinated vinyl chloride resin > the desired component (C) is an alkali-aluminum complex M Oxygen ib 锪. In the composition VII of the present invention, it is desirable that (η higher fatty acid zinc is mixed in 0.1 to 3. 4 parts by weight and, in particular, 0.2 to 2.0 parts by weight per 100 parts by weight of the atmosphere-containing polymer toughness | Denier (G) fluorene-based antioxidants are mixed at 0. Q 1 to 5. G parts by weight and, separately, δ. 8 5 to 2. G parts by weight, per 10 G parts by weight of the atmosphere-containing polymer. When water When talc is a zinc-modified hydrotalcite, it is desirable that (Η) α-two-touch or tau-based esters be mixed with G.! H to 5. ί) parts by weight and * specifically, S3, ί) 3 to 1.0 Parts by weight, per ii) 0 parts by weight of the chlorine-containing polymer. The chlorinated polycontent of the present invention can be mixed with known admixtures in accordance with known methods. For example, the composition of the present invention can be combined with plasticizers, lubricants, fillers, colorants, anti-aging stabilizers, anti-aging agents, light stabilizers, external absorbing agents, antistatic agents * strengthening agents, Reconstituted resin or rubber, the stick is warmed according to the known formula. As a plasticizer, it can make leisure-time plasticizers such as peptidic acid-based plasticizers or d-diester-based plasticizers > polyester-based plasticizers * phosphate ester-based plasticizers > -3 1-(Please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 4081 ^^ A7 B7 V. Description of the invention (合 OR 渕 1 Specifically, the following is a method for synthesizing the fine crystalline calcium silicate used in the examples of the present invention: 498.8 g of a lime slurry (6% of CaG contains the most) and 42.8 g with 5 microns The activated silicic acid powder with average particle size was introduced into the ceramic basin grinder, and was grinded and reacted for 5 4 ya hours to obtain a slurry with pH 1 ί. After nourishing the pulp, washing with water • Drying at 110 1C, and It was crushed in a cold-type test Yangyan mill to obtain a fine powder calcium-silica complex SiO 2 (CS Η-1). Its quality is shown in Table 4. In addition, when the live silicon was changed The ratio of acid to lactate of lime, resulting in the Ca / Si mole ratio of the powdered calcium-silica composite oxygen stealing ions to be 0.4, 2.5, and CS Η-2 and CSH-3 were Synthetic c (sum or spring example 2) 'Specifically described below is a method for synthesizing the grinding and mixing of fine crystalline calcium silicate and a polyhydric alcohol mixed in the spring example of the present invention. 2S5 grams of lime Rolling paste (CaO content of 6%) * 24.2 grams of active silicic acid powder with a mean particle size of 5 micromolecules, and 40 grams of diisoprene yeast introduced ceramic S-type grinding carcass, and grinding and reacting 5 4 Hours M to obtain a slurry with pH i 慂. Pass the syrup, wash it, and dry it at 1 Gt: dry * and powder in a small sample mill to obtain a fine powder coated with K polyzyme- Silica complex argon oxide (CASK); its properties are shown in Table 4. Table 4 CSH-1 CSH-2 C3H-3 CASH Calcium hard silicon osmium -34- This paper size applies to China National Standard (CNS) A4 Specifications (210 x 297mm S) (Please read the precautions on the back before filling out this page) Installation ·! II --- Order---- Printed by the Intellectual Property Bureau Staff Consumer Cooperative of the Ministry of Economic Affairs 40815 ^ A7 B7 S3. 8. ~ 1 year fl is printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (/ 〇 Ambient plasticizers, plasticized azotitanate azelaic acid The plasticizer 'Second class plasticizer, stearic acid plasticizer, stearic acid type plasticizer, trimellitic acid type plasticizer' and cage 1 mellow acid type plasticizer c 'are used as lubricants, Through the palace, U) one of the hydrocarbons, such as liquefied, natural or synthetic alkane, Hui ^ polyethylene wax 'or chlorinated polyethylene 锺' (b) one of the sour acids, such as stearic acid Lauric acid '(e) fatty acid is one of the mono- or diammonium amines, such as ammonium isostearic acid, ammonium succinate, ammonium acetic acid, ammonium es ii ate, methylene Bistearate 'or ethylenebisstearylamine, (d) one of the esters such as butyl stearate * crude oil, or ethylene glycol monostearate, (e) fermentation One of the classes such as cetyl alcohol or stearyl alcohol, (f) gold tincture soap, lead stearate or calcium stearate, and (g) a mixture of strips as an anti-vibration agent, can be used chlorinated polyethylene to include 'for example , 30 to 40% of the atmosphere, methacrylic acid methyl vinegar 'Selethane or bitrinitrile' spleen / butadiene / styrene resin, methyl methacrylate / butadiene / styrene tree Μ, or vinyl acetate / ethylene copolymer Resin Graft Copolymerization A multi-component type tree obtained mainly from polymerizable photoresist formed by acrylic esters. When used as an acid flame retardant, it can cause halogen-based flame retardants and antimony '锑' molybdenum 'aluminum, silicon. Stone or titanium gaseous rhenium, M gaseous or sulfide * or zinc borate, zinc stannate, zinc hydroxyarsenate, or zinc compounds treated with gold rhenium hydroxide. + ί 贲 刘] 32 This paper size applies to Chinese National Standard (CNS) A4% grid (210 X 297 mm) ------- Loading ------- Ordering ------- (Please read the notice on the back before filling this page)

il i绅-¾ (fc們在(i e e r氏烤箱中的|彳熱性,熱安定性,和體槓 電姐率。结果妨表10所示。 ί撥合) 重量份 聚氯乙烯樹脂ί聚含度=1ϋ50) 100 鈦酸二辛酯 50 硬脂酸薛 〇. s 雙酚A 0.1 二苄藤基甲烷 0.1 Alkamizer 4 0 . 5 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 試捺 表10 表 10 實 m 比較 例 n 〇 L C η ·τ ώ I n λ “0 2S 15 16 CASH 1.5 e\ Γι u . u p IT -J 1 ΐ τ> ; ·Λ / 1 . 1 \ 1.5 3.0 ^ r it ο έ η - π ^ 1 4 ι \ L υ ϋ ^ £ "γ υ i - r \ i. . ί ; 1.5 CSH-0+ Oi-p (1:1) 1.5 在G e e r氐烤箱中 t 0 U ' 的詗5 ΐ刀鐵; 140 1 ii n iuU \2'ύ ISO 100 1ϋ0 熱安定性(分鐘) 192 2SG 158 238 in 12(3 體積電阪峯 -4 4- 本紙張尺度適用中國國家標準(CNS)A4規格(210x2.97公釐) * — I J I I I I 訂------I--線 40815b A7 B7 〇 五、發明說明(η\) L~ 經濟部智慧財產局員工消費合作社印製 本發明現將經由下列不以圧何方式限制本發明之晋胨 浏說明。在貢例中f測量棍據描述於下的方法取得。 (1) 最籾著色的評ί古 一板Η在(]ΰ s I*氐烤箱中於1 9 ϋ t:邡熱1 0分鐘,和奴眼_到 斷忘芭色調且依評佶w下: I 2 3 4 無色 淡黃色 黃色 紅色 (2) 抗Geer氐烤箱加熱性 捏合-撗製P V C Η在烤箱中於1 S ϋ aC邡熱旦測量其著色 之時間(分鐘)K評沽其抗熱性。 (3) 熱安定S U.T) 藉Η根據符合J 1 S U 7 2 3之於1 S 0 Τ:剛果紅方法的氛化 Μ捕集瀏試測量。 (4) 體積電姐率 m ^ mm ADVANTE3T 3 4 0而使用5 0 G V電壓剷量體積 電瞪率= (5 )低溫之老化澜試 顯示於表5中的组成物在1 3 0 °C滚筒研磨糠捏合5分 鐘,和具有1毫米均勻厚度之軟氯乙烯片進行三天覬察且 判斷普色狀態。 板η者色程度K區分為7列四涸等级來評估。 0 > 1 > 2 > 3 Θ色 -33 (請先閱讀背面之注意事項再填寫本頁) 粉紅色 本紙張尺度適用中國國家標準(CNS)A4規格m〇 X 297公釐) 4081^6 A7 B7 正 五、發明說明(一) 表 例 1 3 2 比 較 例 17 在i; e e r 烤箱中 卢;;«4; ItL· f r\_ itit \ aj [fj熟「丨土、分嫂) 140 14G 140 i n 4 U 熟女疋〗:± ΐ万理J 220 205 21ο ss ££ ^f?r Pa T*r 題損电fci ; (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 (U 1 2 Ώ -公分) 5 ‘ 2 8 . 7 5.1 5.0 (筈例3 3到3 δ,比較的晋葩飼i 8 ) 下列组成韧使苗加熱於1 5 β °C捏合滾茼捏合7分鐘以 製痛一種具有d.5毫米厚度之板片。從板片製備測試片並 且剷量皑們在Geer氐烤箱中的酎熱性,熱安定倥,和體積 電阻率。结果如表12所示。 (接合) 重量份 氯化Μ乙烯樹脂ί ;Π %的氯含量) 100 鈦酸二辛酯 50 硬脂酸鋅 0.4 -4Η- Λ f K ^ SI I ί I 1^1 n I- 本紙張尺度適用中國國家標準(CNS)A4規格(210 x 297公.¾ ) 4081^^ A7 B7 五、發明說明) (合或簧渕1 ; 具體地ra逑於下的是一種合成使用於本發明的實例中 之细结晶矽酸鈣之方法:將498.8克石灰的乳漿(6%之 CaG含最)和42. 8克具有5微米平均粒子大小之活性矽酸粉 末引進陶瓷盆式研磨機內,且研磨和反懕5 4遐小時以獲得 具有pH 1ί丨之漿液。過滋漿疲,以水洗滌•於110 1C乾煉, 和在冷·型試漾妍磨機中粉碎以獲得细粉末鈣—矽石複合物 Μ氧ib搏(C S Η - 1)。其择質如表4所示。此外同樣地,當變 更活姓矽酸對石灰的乳菽的比,致使綑粉末鈣一矽石複合 窃氧ih物之C a/ S i莫耳比為0 · 4和2 . 5時,C S Η - 2和C S H - 3被 合成c (合或簧例2 ) ' 具體地描逑於下的是一種合成使罔在本發明的簧例中 之细结晶矽酸鈣和多元醇的磨碎混合趨之方法。 將2S5克石灰的轧漿(6 %之CaO含量)* 24 . 2克具有5 微亲平均粒子大小之活性矽酸粉末,和40克二異戊四酵引 進陶瓷S式研磨饈肉,且研磨和反應5 4個小時Μ獲得具有 pH i ϋ之漿疲。過慂漿液,Κ求洗滌,於1 1 G t:乾燥*和在 小型試樣研磨機粉晬以獲得K多元酵塗佈塗的细粉末鈣-矽石複合物氬氧化锊(C A S K );其性貿如表4围示。 表 4 CSH-1 CSH-2 C3H-3 CASH 硬矽鈣 Έ -34- 本紙張尺度適用中國國家標準(CNS)A4規格(210 x 297公S ) (請先閱讀背面之注意事項再填寫本頁) 裝·! II —--訂-- --- 經濟部智慧財產局員工消費合作社印製 40815ο A7 B7 五、發明說明U<) 雙骼A 二ΐ嬙基甲烷 經濟部智慧財產局員工消費合作社印製 .0 試樣 表U 主 1 f'l i c 例 比 較 例 33 34 3 5 3 8 1 η i 0 CASH 1 . ϋ i . 0 1 /λ ri r* L 4 U l) * 0 Z . G AIkaiizer-4 1 η i . u i.4 M i z u k a I a c i . 0 片納鋁石 l. 0 在Gi?ei'氏烤箱中 140- 的嗣熱性(分鐘) 140 160 1 60 30 60 熱安定性(分鐘) 102 105 S3 10G 88 體積電駔革 (X 1 (] 1 3 Ώ -公分) 24 . 1 Ο J> 1 i CO . ί 5 · G 3,5 4.5 * i z uka i ac :鋰 -鋁複合 物氫氧化 物的碳酸鹽 (由Η i z u s a w a K a g a k u Κ 〇 g y 〇公司製造) * n訥鋁石:鈉-鋁複合锪M氧化物的碳酸鹽(由Hizusawa R a g a k u K 〇 g y 〇公司製造) -47 - 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁) 4〇8i5i> Μ __B7五、發明説明(Μ ) (lOOOt:) Cat) 13.54 12.71 13.68 63.41 2.5 (重量%) Si02 37.35 23.57 60,17 15.41 47.1 (重量% ) Ca/ Si 48.95 69.48 25.97 20.69 50.4 莫耳比 層合不對稱 0.8 0.4 2.5 0.8 1.0 性之指數 吸油量 1.96 1,90 1.89 1.96 1.20 (毫升/ 100克) 平均粒子直徑 110 128 90 148 (U ffl) 多孔體積 4 4.3 4.5 6.7 (毫升/克) (實例1到5 3.10 ,比較例1 到3 ) - - ----1-----扣衣------ΐτ------.^- (锖先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局負工消費合作社印製 下列組成物使用加熱於1 6 0亡捏合滾茼捏合5分鐘以 製餚一種具有約1毫米厚度之板片。從板Η製備測試片並 且測童他們的最初著色,在Geer氐烤箱中的耐熱性,熱安 定性,和低溫老化。结果如表5所示。 (軟聚合物的摻合) 本紙張尺度適用中國國家標率(CNS > A4規格(210X297公楚) ro5 丄 8 ο4 A7B7il iGen-¾ (fc are in (ieer's oven | thermal stability, thermal stability, and body weight e-sister rate. The results can be shown in Table 10.) Dial-in weight parts of polyvinyl chloride resin Degree = 1ϋ50) 100 dioctyl titanate 50 stearate stearate s Bisphenol A 0.1 dibenzyl methane 0.1 Alkamizer 4 0.5 (Please read the precautions on the back before filling this page) Intellectual Property of the Ministry of Economic Affairs Printed by the Consumer Cooperatives of the Bureau of the People's Republic of China. Table 10 Table 10 Real m Comparative Example n 〇LC η · τ FREE I n λ "0 2S 15 16 CASH 1.5 e \ Γ u. Up IT -J 1 ΐ τ >; · Λ / 1. 1 \ 1.5 3.0 ^ r it ο έ η-π ^ 1 4 ι \ L υ ϋ ^ £ " γ υ i-r \ i.. Ί; 1.5 CSH-0 + Oi-p (1: 1) 1.5 詗 5 ΐ 刀 铁 at t 0 U 'in a G eer 氐 oven; 140 1 ii n iuU \ 2'ύ ISO 100 1ϋ0 Thermal stability (minutes) 192 2SG 158 238 in 12 (3 vol. 4- This paper size applies to China National Standard (CNS) A4 specification (210x2.97 mm) * — Ordered by IJIIII --- --- --- 40815b A7 B7 〇 5. Description of the invention (η \) L ~ Economy Ministry of Wisdom The invention printed by the production bureau employee consumer cooperatives will now be obtained through the following description of the invention which does not limit the invention in any way. In the case of f, the measuring stick is obtained according to the method described below. (1) The most colored evaluation ί 古 一 板 Η in (] ΰ s I * 氐 oven in 1 9 ϋ t: 邡 heat for 10 minutes, and slave eyes _ to break forget the hue and according to the review 佶 w: I 2 3 4 colorless pale yellow Yellow-red (2) Resistance to Geer 氐 Oven heating kneading- 撗 made PVC 评 In the oven at 1 S ϋ aC 邡 The time (minutes) for which the coloring is measured in K to evaluate its heat resistance. (3) Thermal stability S UT ) Measured according to the atmospheric M-capture test in accordance with J 1 SU 7 2 3 in 1 S 0 Τ: Congo Red method. (4) Volume e-mail rate m ^ mm ADVANTE3T 3 4 0 and 50 GV Voltage shovel volume volume rate = (5) Low temperature aging test. The composition shown in Table 5 was kneaded by roller milling bran at 130 ° C for 5 minutes, and a soft vinyl chloride sheet with a uniform thickness of 1 mm was subjected to three times. Tian Yan inspected and judged the general color status. The degree of color K of the plate η is divided into 7 columns and four levels. 0 > 1 > 2 > 3 Θ-33 (Please read the precautions on the back before filling out this page) Pink This paper size applies the Chinese National Standard (CNS) A4 size m × X 297 mm) 4081 ^ 6 A7 B7 Zheng V. Explanation of the invention (1) Table example 1 3 2 Comparative example 17 In i; eer oven; Lu; «4; ItL · fr \ _ itit \ aj [fj cooked" 丨 soil, tillering) 140 14G 140 in 4 U MILF 疋〗: ± ΐWanli J 220 205 21ο ss ££ ^ f? R Pa T * r Damage to electricity fci; (Please read the precautions on the back before filling this page) Intellectual Property of the Ministry of Economic Affairs Printed by the Bureau's Consumer Cooperative (U 1 2 Ώ-cm) 5 '2 8. 7 5.1 5.0 (Example 3 3 to 3 δ, Jin Jin Yang i 8 for comparison) The following composition allows the seedlings to be heated to 1 5 β ° C kneading roll kneading for 7 minutes to make a plate having a thickness of d. 5 mm. A test piece was prepared from the plate and the heat resistance, heat stability, and volume resistivity of the plate in a Geer 氐 oven were measured. The results are shown in Table 12. (Jointing) parts by weight of chlorinated vinyl chloride resin; Π% chlorine content) 100 dioctyl titanate 50 zinc stearate 0.4 -4Η- Λ f K ^ SI I ί I 1 ^ 1 n I- This paper size is in accordance with the Chinese National Standard (CNS) A4 (210 x 297 male. ¾) 4081 ^^ A7 B7 V. Description of the invention) (or or spring 渕 1; Is a method for synthesizing the fine crystalline calcium silicate used in the examples of the present invention: 498.8 g of a slurry of lime (6% of CaG contains the most) and 42.8 g of active silicic acid having an average particle size of 5 microns The powder was introduced into the ceramic basin grinder, and was ground and reacted for 5 4 ya hours to obtain a slurry with pH 1 ί. After nourishing the slurry, wash with water • Dry at 110 1C, and test in cold type It is pulverized in a mill to obtain a fine powder of calcium-silica complex SiO 2 (CS Η-1). Its quality is shown in Table 4. In addition, when the living name of silicic acid is changed to lactate of lime When the Ca / Si molar ratio of the bundled powder calcium-silica composite oxygen stealing substance is 0 · 4 and 2.5, CS Η -2 and CSH-3 are synthesized. ) 'Specifically described below is a method for synthesizing the grinding and mixing of fine crystalline calcium silicate and a polyhydric alcohol in the spring example of the present invention. 2S5 g of lime rolling paste (6% (CaO content) * 24. 2 grams of active silicic acid powder with an average particle size of 5 micromolar, and 40 grams of diisoprene yeast introduced ceramic S-type grinding carcass, and grinding and reaction for 5 to 4 hours i The pulp of crickets is tired. The slurry was washed with K, and washed at 1 1 G t: dried * and powdered in a small sample mill to obtain a fine powder of calcium-silica complex coated with K polyenzyme, argon oxide (CASK); Sex trade is shown in Table 4. Table 4 CSH-1, CSH-2, C3H-3, and CASH -34- This paper size is applicable to China National Standard (CNS) A4 (210 x 297 male S) (Please read the precautions on the back before filling this page ) Equipment II! --- Order---- Printed by the Employees ’Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 40815ο A7 B7 V. Description of the invention Printed. 0 Sample Table U Main 1 f'l ic Example Comparative Example 33 34 3 5 3 8 1 η i 0 CASH 1. Ϋ i. 0 1 / λ ri r * L 4 U l) * 0 Z. G AIkaiizer-4 1 η i. U i.4 M izuka I aci. 0 pieces of nano-aluminite l. 0 140- in the Gi? Ei ''s oven 140- 1 thermal stability (minutes) 140 160 1 60 30 60 thermal stability ( Minutes) 102 105 S3 10G 88 volume electric leather (X 1 (] 1 3 Ώ-cm) 24. 1 〇 J > 1 i CO. Ί 5 · G 3,5 4.5 * iz uka i ac: lithium-aluminum composite Carbonate hydroxide (manufactured by the company Ηizusawa Kagaku Kögy 〇) * bauxite: sodium-aluminum composite 锪 M oxide carbonate (by Hizusawa R ag aku K 〇gy 〇 company) -47-This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) 4〇8i5i > Μ __B7 五Description of the invention (M) (1000t :) Cat) 13.54 12.71 13.68 63.41 2.5 (% by weight) Si02 37.35 23.57 60, 17 15.41 47.1 (% by weight) Ca / Si 48.95 69.48 25.97 20.69 50.4 Molar ratio asymmetry 0.8 0.4 2.5 0.8 1.0 Index oil absorption 1.96 1,90 1.89 1.96 1.20 (ml / 100 g) Average particle diameter 110 128 90 148 (U ffl) Porous volume 4 4.3 4.5 6.7 (ml / g) (Examples 1 to 5 3.10, Comparative Examples 1 to 3)------ 1 ----- Fashion clothes -------- ΐτ ------. ^-(锖 Please read the precautions on the back before filling this page) Economy The Ministry of Standards and Technology ’s Consumer Cooperatives printed the following composition and kneaded it for 5 minutes using a kneading roll and kneading for 60 minutes to prepare a plate with a thickness of about 1 mm. Test pieces were prepared from plate Η and tested for their initial coloration, heat resistance, thermal stability, and low-temperature aging in a Geer 氐 oven. The results are shown in Table 5. (Blend of soft polymers) This paper size applies to China's national standard (CNS > A4 size (210X297)) ro5 丄 8 ο4 A7B7

明說 明發 五 细/一 之及得 像物獲 圖合便 射ifcM 繞 0 , 線酸用 射尿使 X 氰 合 和異組 物與物 成且化 組,氧 定 出 S 特選饬 有鈣合 具酸複 , 矽鋁 明從 I 發係鹼 本鈣或 據酸石 抠矽滑 晶7K 结或 良 優 Λ 性 C 化栩 老成 抗組 溫锪 低 合 良聚 改氯 著含 顯之 、 色 性著 定初 安最 熱止 良防 改及 著¾ 顯緣 有絕 ^兵 電 稽的 尿使 氰合 異 組。 與物色 旦化著 氧初 成氬最 形韧免 酵合遊 元複和 多鋁性 和 I 定 鈣鹸安 酸或熱 矽 石 白IX; 晶潢改 结水步 遛或一 從/進 物及許 合ti允 複合其 當 化 , 酷時 酸.¾ (請先閲讀背面之;i意事項再填寫本頁) ---I--—訂 ----I--1_ 線 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS)A4規格(210 * 297公釐) 4〇8-δο Λ7 Β7 五、發明説明Uf) PVC (TK- 1 3 0 0,由 Shin-Etsu K a g a k u Kogyo公司製造) D IN P (塑化劑): 肽酸二異辛酯 硬脂酸鋅 召一二嗣 酚類抗氧化劑 試樣 100 50 0 . 1 表5 (請先閱讀背面之注意事項再填寫本頁) .裝' 經濟部中央標準局員工消費合作社印製 (實洌6到12,比較例4到6 ) 下列組成物使用加熱於1 6 Q七捏合滾筒捏合5分鐘Μ 製餚一種具有預定厚度之板片。從板片製備測試片並且測 量他們的最初著色,在Geei·氐烤箱中的耐熱性,熱安定性 ,和低體老化。结果如表6所示。 (軟聚合物的摻合) 摻合之份數 PVC (TK- 1 3 0 0,由 Shin-Etsu K a g a k u fiogyo公司製造) 100 硬脂酸鋅 1.0 /9 一二嗣 〇 . 1 3旨肪酸酯類蠟 0.5 -3 6 -Make it clear that you can get five details / one to get the image, then you can shoot ifcM around 0, use the acid to urinate to make X cyanide and the heterogeneous compound and the material and form the group. The oxygen is selected. With acid complex, silicoaluminium from I hair series basic calcium or silicon acid crystals from 7K knot or good Λ sex C ageing into the resistance group temperature and low polycondensation with chlorine, with significant, color Ding Chuan's hottest Zhiliang prevention reform and writing ¾ The obvious reason is that the urine of the soldiers makes the cyanide different groups. With the appearance of oxygen, the initial formation of argon is the most flexible, non-fermentative, non-aluminium compound, polyaluminum, and calcium, acetic acid, or hot silica white IX; crystal decoration changes the water step or one from / into the object and Xu Heti allows you to combine it with the right time, sour and sour. ¾ (Please read the back; please fill in this page before i) --- I --- Order ---- I--1_ Intellectual Property Bureau, Ministry of Economic Affairs The paper size printed by the employee consumer cooperative is applicable to the Chinese National Standard (CNS) A4 specification (210 * 297 mm) 4〇8-δο Λ7 Β7 V. Description of the invention Uf) PVC (TK- 1 3 0 0, by Shin-Etsu Manufactured by Kagaku Kogyo) D IN P (plasticizer): Diisooctyl peptidate, zinc stearate, dioxin phenolic antioxidant sample 100 50 0. 1 Table 5 (Please read the precautions on the back first (Fill in this page again.) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (Actual 6 to 12, Comparative Examples 4 to 6) The following composition was kneaded for 5 minutes using a 7 kneading roller heated for 16 minutes. A sheet having a predetermined thickness. Test pieces were prepared from the plates and measured for their initial coloration, heat resistance in a Geei 体 oven, thermal stability, and low body aging. The results are shown in Table 6. (Blend of soft polymer) Blended parts PVC (TK-1 3 0 0, manufactured by Shin-Etsu Kagaku Fiogyo) 100 zinc stearate 1.0 / 9 dioxin 0.13 fatty acid Ester wax 0.5 -3 6-

、1T 線 本紙張尺度適用中國國家標率(CNS ) Α4規格(2丨ΟΧ297公釐} 408i5〇 Λ7 B7 五、發明説明 酚類抗氣化劑 〇. 試樣 表6 ----;-----^------ΪΓ------,ii (請先閲讀背面之注意事項-F4寫本頁) 經濟部中央標準局貝工消費合作社印製 -37- 本紙張尺度適用中國國家標準(CNS ) A4規格(2IOX 297公麓) 408156 A7 B7 五、發明説明G厶) pvnητκρnSH 二 nSH-?· nASIH Aga3i7PLr 7 边丨l·! Geer9笨齡^聲体 貧梦部 20 今it -、v诲 60今路 §兮淼 100^婵 120冷海 160今路 彔眹笄咖1-铲濟3冰寐會浼7>漭 2 0.5 0.10.1 1 1 2 2 3 3 6 362 0 0 0 0 100 500.1 0.5 (請先閲讀背面之注意事項寫本頁) .裝' 2 0.5 0,1 0- 1 1 2 2 3 3 6 362 0 0 1 1 l· 100 50 P02 0’5 6 32 0 0 0 0 0,5 2 0.5 0_1 1 1 2 100 S0,1 訂 1.0 0.50.1 0Λ1 1 1 2 3 厶 5 6 222 0 0 0 0 100 50 °.3 1.5 2 0.5 0」0.1 1 1 1 2 2 2 3 5 β 0 0 0 0 2 0.5 〇.1 0.1 1 1 2 2 3 3 办 6 3S 0 2 3 3 100 100 50 50 0.5 0.5 0*^ 線 經濟部中央標準局员工消費合作社印製 267 0 0 0 1 2 0.50.10,1 1 2 3 5 -效今J l· 100 50 〇,1 0.5 2 0.50.1 0.1 1 2 3 3 厶 5 6 300 0 0 1 1 l· 100 50 0.1 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ 297公嫠) 406156 Λ7 B7 五、發明説明) 陴翠強筘蜱1-叟 Geere^^^^^ 0今錐 10、v舔 20今路40、v 瘅 60今淼 90冷浓 會濟一 >萍 才势2Λ寐 舍沙3沖灕1. The paper scale of 1T line is applicable to China National Standards (CNS) A4 specification (2 丨 〇297mm) 408i5〇Λ7 B7 V. Description of the invention Phenol anti-gasification agent 〇. Sample table 6 ----;- --- ^ ------ ΪΓ ------, ii (Please read the note on the back-F4 to write this page) Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy -37- Applicable to China National Standard (CNS) A4 specification (2IOX 297 feet) 408156 A7 B7 V. Description of the invention Gv) pvnητκρnSH Two nSH-? · NASIH Aga3i7PLr 7 Edge 丨 l ·! Geer9 stupid ^ sound body poor dream department 20 Today it-, v 诲 60 Jin Lu § Xi Miao 100 ^ 120 120 Leng Hai 160 Jin Lu 1- 1-Jiji 3 Ice 寐 浼 7 > 漭 2 0.5 0.10.1 1 2 2 3 3 6 362 0 0 0 0 100 500.1 0.5 (Please read the precautions on the back to write this page). Install '2 0.5 0,1 0- 1 1 2 2 3 3 6 362 0 0 1 1 l 100 50 P02 0'5 6 32 0 0 0 0 0,5 2 0.5 0_1 1 1 2 100 S0,1 Order 1.0 0.50.1 0Λ1 1 1 2 3 厶 5 6 222 0 0 0 0 100 50 °. 3 1.5 2 0.5 0 `` 0.1 1 1 1 2 2 2 3 5 β 0 0 0 0 2 0.5 〇.1 0.1 1 1 2 2 3 3 Office 6 3S 0 2 3 3 100 100 50 50 0.5 0.5 0 * ^ Ministry of Economic Affairs Printed by the Central Standards Bureau's Consumer Cooperatives 267 0 0 0 1 2 0.50.10, 1 1 2 3 5-Jeng 100 J 50 100, 1 0.5 2 0.50.1 0.1 1 2 3 3 厶 5 6 300 0 0 1 1 l · 100 50 0.1 This paper size applies to the Chinese National Standard (CNS) Α4 size (210 × 297 mm) 406156 Λ7 B7 V. Description of the invention) 陴 翠 强 筘 tick 1- 叟 Geere ^^^^^ 0 今 cone 10, v licks 20, Jin Lu 40, v 瘅 60, Jin Miao 90, Leng Nong Hui Ji Yi> Ping Cai Shi 2 Λ 寐 Sha Sha 3

1.00,1 0.5 °1 1 2 仁 5 6 181 0 1 2 2 1.00.1 0.50,1 1 办 4 5 5 6 121 0 2 2 3 1.00.1 0.50.1 1 3 办 5 5 6 127 0 1 2 2 尸5 1.0 °.1 0.S 0_1 1 3 3 么 5 6 127 0 0 °5 3 5 6 126 0 0 1 1 °_1 0J 0*: ··0 1 2 2 3 3 205 0 1 2 2 0.5 ,5 -5 '0 0_1 0- 1.0 0·^ 0,5 G.1 1 2 6 185 0 1 2 2 經濟部中央標準局員工消費合作社印製 0.5 2 r 〇 〇.一 P5 °,1 1 厶 5 5 6 121 0 2,5 1_00.1 0- °,1 1 5 5 ω 108 0 1 2 2 2 °.5 1 _°0.1 0.50,1 1 2 3 5 6 157 0 3 3 3 °51.00,1 0.5 ° 1 1 2 Ren 5 6 181 0 1 2 2 1.00.1 0.50,1 1 Office 4 5 5 6 121 0 2 2 3 1.00.1 0.50.1 1 3 Office 5 5 6 127 0 1 2 2 Corpse 5 1.0 ° .1 0.S 0_1 1 3 3 Mod 5 6 127 0 0 ° 5 3 5 6 126 0 0 1 1 ° _1 0J 0 *: ·· 0 1 2 2 3 3 205 0 1 2 2 0.5, 5 -5 '0 0_1 0- 1.0 0 · ^ 0,5 G.1 1 2 6 185 0 1 2 2 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 0.5 2 r 〇〇.1 P5 °, 1 1 厶 5 5 6 121 0 2,5 1_00.1 0- °, 1 1 5 5 ω 108 0 1 2 2 2 °. 5 1 _ ° 0.1 0.50,1 1 2 3 5 6 157 0 3 3 3 ° 5

tb萍今J ---------^衣------iT------線 (請先閱讀背面之注意事項真4寫本頁) 本紙張尺度適用中國國家標隼{ CNS ) A4规格(210 X 297公釐) 4〇δ:56 Λ7 Β7 五、發明説明(於) 經濟部中央標準局員工消費合作社印裝 (實例U到17 1 '比較例7和8 ) 下列組成 物使用加熱於 150 t1捏合滾茼揑合7分鐘以 製餚一種具有 0 . 5毫米厚度 之板 片。從板片 製備測試片 並 且測量他們的 最初著色,在G e e r氏烤箱中的耐熱性,熱 安 定性·和體積電阻率。结果 如表 7所示。 (摻合) 重量份 聚氯乙烯樹脂 (聚合度 =1 G50) 100 酞酸二辛酷 50 試樣 表7 表 7 實 例 比較 例 13 14 15 16 17 7 8 Alkainizer 4 1.4 0.6 1.4 1.4 1.4 2.0 CSH-1 0.6 1.4 0.6 0.6 0.6 2.0 硬脂酸鋅 0.4 0.4 0.4 雙酚A 0.1 0.1 二苄醯基甲烷 0.05 最初著色 3 3 1 1 1 4 4 在Geer氏烤箱中 的耐熱性(分鐘) 100 100 100 100 100 10D 140 "40- (讀先閲讀背面之注意事項異从寫本頁) 本紙張尺度適用中國國家標準ί CNS ) Α4规格(hOXM7公釐) 刪156 經濟部中央標準局員工消費合作·杜印策 A7 B7五、發明説明(巧) 熱安定性(分鐘) 87 52 1 34 1 97 2 0 6 82 3 1 體積電砠率 (ΧΙΟ13 Ω-公分) 6.42 8.9 1 7.7 0 5.83 5.0 3 3.10 10.48 (實例18到2 0,比較例9和U) 下列組成物使用加熱於1 5 0 C捏合滾茼捏合7分鐘以 製餚一種具有0.5毫米厚度之板片。從板片製備測試片並 且測量他們的最初著色,在Geer氏烤箱中的附熱性*熱安 定性,和體攢電阻率。结果如表8所示。 (摻合) 聚氯乙烯樹脂(聚合度=1050) 鈦酸二辛酯 硬脂酸鋅 雙酚A 二苄醯基甲烷 Alkaraizer 4 試樣 表 8 實 例 18 19 20 CSH-1 0.3 0.5 1.0 -41- 本紙張尺度適用中國國家樣準(CNS ) A4規格(210X297公釐) 重量份 100 50 表8 比較例 9 10 11 12 ---------t------1T------^ (谙先閱讀背面之注意事項/ &寫本頁) 408156 A7 —__________B7五、發明説明(4_D ) 經濟部中央標準扃員工消費合作社印聚 硬矽鈣石 0.5 CSH-2 0.5 CSH-3 0.5 最初著色 1 1 1 2 2 1 3 在Geer氏烤箱中 的耐熱性(分鐘) 140 160 180 < 100 100 140 140 熱安定性(分鐘) 299 312 350 264 265 275 268 體積電阻率 (xlO1 3 Ω -公分} 4.1 4.6 6.0 (實例2 1到25,比較例13和14) 1.5 2.0 3,4 2.4 下列組成物使用加熱於1 50 °C捏合滾筒捏合7分鐘以 製備一種具有0.5毫米厚度之板Η。 從板片製備測試片並 且測量他們在G e e r氏烤箱中的耐熱性 電阻率。结果如表9所示。 ,熱安定性,和體積 (摻合) 重量份 聚氯乙烯樹脂(聚合度=1050) 1 0 0 酞酸二辛酯 50 硬脂酸鋅 雙酚A 二苄醯基甲烷 CSH- 1 -4 2- 本紙張尺度適用中國國家梯準(CNS ) A4規格(2I0X297公t > ---------^------tr------.^ (請先閲讀背面之注項#蜞寫本頁) 經濟部中央榇準局員工消費合作社印製 408156 Λ7 B7 、發明説明(4*/ ) 試樣 表 9 表9 實 例 比較 例 21 22 23 24 25 13 14 Alkamizer-4 1. 0 2.0 3.0 Alkainizer-1 2.0 DHT-4 2.0 硬脂酸鈣 1.0 在Geer氏烤箱中 的耐熱性(分鐘) 100 160 180< 120 140 10 20 熱安定性(分鐘) 278 312 493 330 337 11 30 體積電姐率 (xlQ1 3 Ώ-公分) 4.2 4.6 4.7 5.3 5.0 0.3 1.3 * Alkamizer-4:鋅改質之水滑石(由 Kyowa Kagaku Kogyo 公司製造) * DHT-4:水滑石(由 Kyowa Kagaku Kogyo 公司製造} * Alkamizer-l:水滑石(由 Kyowa Kagaku Kogyo公司製造) (實例2 6到2 9,比較洌1 5和1 6 ) 下列組成物使用加熱於1 5 0 °C捏合滾茼捏合7分鐘K 製備一種具有0.5毫米厚度之板片。從板片製備測試片並 -43- 本紙張尺度適用中國固家標準(cNS)Α4規格(210x297公梦-) ---------^------,π------線 (請先閣讀背面之注意事項异填寫本頁)tb 萍 今 J --------- ^ 衣 ------ iT ------ line (please read the precautions on the back first and write this page) This paper size applies to Chinese national standard隼 {CNS) A4 specification (210 X 297 mm) 4〇δ: 56 Λ7 B7 V. Description of the invention (in) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (Examples U to 17 1 'Comparative Examples 7 and 8) The following composition was kneaded for 7 minutes using a kneading roll at 150 t1 to prepare a plate having a thickness of 0.5 mm. Test pieces were prepared from the plates and their initial coloring, heat resistance, thermal stability, and volume resistivity in a Geer oven were measured. The results are shown in Table 7. (Blended) parts by weight of polyvinyl chloride resin (polymerization degree = 1 G50) 100 dioctyl phthalate 50 Sample Table 7 Table 7 Examples Comparative Example 13 14 15 16 17 7 8 Alkainizer 4 1.4 0.6 1.4 1.4 1.4 2.0 CSH- 1 0.6 1.4 0.6 0.6 0.6 2.0 Zinc stearate 0.4 0.4 0.4 Bisphenol A 0.1 0.1 Dibenzylmethylmethane 0.05 Initial coloring 3 3 1 1 1 4 4 Heat resistance in Geer's oven (minutes) 100 100 100 100 100 10D 140 " 40- (Notes on the first page of the first page are different from the ones on this page) The paper size is applicable to the Chinese national standard (CNS) Α4 size (hOXM7 mm) Delete 156 Employees ’cooperation and cooperation with the Central Standards Bureau Policy A7 B7 V. Description of the invention (cleverness) Thermal stability (minutes) 87 52 1 34 1 97 2 0 6 82 3 1 Volume rate (× ΙΟ13 Ω-cm) 6.42 8.9 1 7.7 0 5.83 5.0 3 3.10 10.48 (Example 18 to 20, Comparative Examples 9 and U) The following composition was kneaded for 7 minutes using a kneading roll kneading heated at 150 C to prepare a plate having a thickness of 0.5 mm. Test pieces were prepared from the plates and their initial coloration, heat resistance * heat stability in a Geer's oven, and volume resistivity were measured. The results are shown in Table 8. (Blend) Polyvinyl chloride resin (degree of polymerization = 1050) Dioctyl titanate zinc stearate bisphenol A dibenzylfluorenylmethane Alkaraizer 4 Sample Table 8 Example 18 19 20 CSH-1 0.3 0.5 1.0 -41- This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) 100 parts by weight Table 8 Comparative Example 9 10 11 12 --------- t ------ 1T --- --- ^ (谙 Please read the notes on the back / & write this page) 408156 A7 —__________ B7 V. Description of the invention (4_D) Central Standards of the Ministry of Economy 扃 Employee Consumer Cooperative Printed Polyxonite 0.5 CSH-2 0.5 CSH -3 0.5 Initial coloring 1 1 1 2 2 1 3 Heat resistance in Geer's oven (minutes) 140 160 180 < 100 100 140 140 Thermal stability (minutes) 299 312 350 264 265 275 268 Volume resistivity (xlO1 3 Ω-cm} 4.1 4.6 6.0 (Examples 2 to 25, Comparative Examples 13 and 14) 1.5 2.0 3, 4 2.4 The following composition was kneaded using a kneading roller heated at 1 50 ° C for 7 minutes to prepare a material having a thickness of 0.5 mm Plate Η. Test pieces were prepared from the plates and their heat resistance resistivity in a Geer's oven was measured. The results are shown in Table 9. , Thermal stability, and volume (blended) parts by weight of polyvinyl chloride resin (degree of polymerization = 1050) 1 0 0 dioctyl phthalate 50 zinc stearate bisphenol A dibenzyl fluorenylmethane CSH- 1 -4 2 -This paper size is applicable to China National Standard (CNS) A4 (2I0X297 male t > --------- ^ ------ tr ------. ^ (Please read the back first Note item # 蜞 写 本) Printed by the Consumer Cooperatives of the Central Bureau of Quasi-Economic Bureau of the Ministry of Economic Affairs 408156 Λ7 B7, Invention Description (4 * /) Sample Table 9 Table 9 Examples Comparative Examples 21 22 23 24 25 13 14 Alkamizer-4 1. 0 2.0 3.0 Alkainizer-1 2.0 DHT-4 2.0 Calcium stearate 1.0 Heat resistance in Geer's oven (minutes) 100 160 180 < 120 140 10 20 Thermal stability (minutes) 278 312 493 330 337 11 30 Volume rate (xlQ1 3 Ώ-cm) 4.2 4.6 4.7 5.3 5.0 0.3 1.3 * Alkamizer-4: zinc modified hydrotalcite (manufactured by Kyowa Kagaku Kogyo) * DHT-4: hydrotalcite (by Kyowa Kagaku Kogyo) Manufacturing} * Alkamizer-l: Hydrotalcite (manufactured by Kyowa Kagaku Kogyo) (Example 2 6 to 29, comparison 洌 1 5 and 1 6) The following composition was kneaded by heating at 150 ° C for 7 minutes K to prepare a plate having a thickness of 0.5 mm. Preparation of test strips from plates and -43- This paper size is applicable to the Chinese solid standard (cNS) Α4 specification (210x297 public dream-) --------- ^ ------, π --- --- line (please read the notes on the back first and fill in this page)

il i绅-¾ (fc們在(i e e r氏烤箱中的|彳熱性,熱安定性,和體槓 電姐率。结果妨表10所示。 ί撥合) 重量份 聚氯乙烯樹脂ί聚含度=1ϋ50) 100 鈦酸二辛酯 50 硬脂酸薛 〇. s 雙酚A 0.1 二苄藤基甲烷 0.1 Alkamizer 4 0 . 5 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 試捺 表10 表 10 實 m 比較 例 n 〇 L C η ·τ ώ I n λ “0 2S 15 16 CASH 1.5 e\ Γι u . u p IT -J 1 ΐ τ> ; ·Λ / 1 . 1 \ 1.5 3.0 ^ r it ο έ η - π ^ 1 4 ι \ L υ ϋ ^ £ "γ υ i - r \ i. . ί ; 1.5 CSH-0+ Oi-p (1:1) 1.5 在G e e r氐烤箱中 t 0 U ' 的詗5 ΐ刀鐵; 140 1 ii n iuU \2'ύ ISO 100 1ϋ0 熱安定性(分鐘) 192 2SG 158 238 in 12(3 體積電阪峯 -4 4- 本紙張尺度適用中國國家標準(CNS)A4規格(210x2.97公釐) * — I J I I I I 訂------I--線 經濟部中央標準局貝工消費合作社印策 重量份 100 50 0 . 5 0.1 0.01 1.0 表11 408156 Λ7 ___ B7_ 五、發明説明( (xiOi3 Ω·公分)6.3 6.9 6.2 6.7 4.5 4.0 * C S Η 1到3 + D i - ρ : c S H 1到3和二異戊四醇的簡簞混合物 (實例3 0到3 2,比較的實施洌1 7 ) 合成簧例2的二異戊四酵K甘露醇取代Μ獲得經乾燥 研磨且混合之细扮末鈣一矽石複合物粒子(CASH-M),其Μ 多元醇塗覆。同樣地,合成實例2的二異戊四醇以二異戊 四醇己二酸酯取代以獲得經乾燥研磨且混合之细粉末鈣一 矽石複合物粒子(C A SH-S),其Μ多元酵塗覆。 下列姐成物使用加熱於150 C捏合滾简捏合7分鐘Μ 製備一種具有0.5毫米厚度之板片。從板片製備測試片並 且測量他們在G e e r氏烤箱中的耐熱性*熱安定性,和體槙 電阻率。结果如表11所示。 (摻合) 聚氯乙烯樹腊(聚合度=1W0) 酞酸二辛酯 硬脂酸鋅il iGen-¾ (fc are in (ieer's oven | thermal stability, thermal stability, and body weight e-sister rate. The results can be shown in Table 10.) Dial-in weight parts of polyvinyl chloride resin Degree = 1ϋ50) 100 dioctyl titanate 50 stearate stearate s Bisphenol A 0.1 dibenzyl methane 0.1 Alkamizer 4 0.5 (Please read the notes on the back before filling this page) Intellectual Property of the Ministry of Economic Affairs Printed by the Consumer Cooperatives of the Bureau of the People's Republic of China. Table 10 Table 10 Real m Comparative Example n 〇LC η · τ FREE I n λ "0 2S 15 16 CASH 1.5 e \ Γ u. Up IT -J 1 ΐ τ >; · Λ / 1. 1 \ 1.5 3.0 ^ r it ο έ η-π ^ 1 4 ι \ L υ ϋ ^ £ " γ υ i-r \ i.. Ί; 1.5 CSH-0 + Oi-p (1: 1) 1.5 詗 5 ΐ 刀 铁 at t 0 U 'in a Geer 氐 oven; 140 1 ii n iuU \ 2'ύ ISO 100 1ϋ0 Thermal stability (minutes) 192 2SG 158 238 in 12 (3 volume electric Sakamine-4 4- This paper size applies to China National Standard (CNS) A4 (210x2.97 mm) * — Ordered by IJIIII ----I-line printed by the Central Bureau of Standards of the Ministry of Economy 00 50 0. 5 0.1 0.01 1.0 Table 11 408156 Λ7 ___ B7_ V. Description of the invention ((xiOi3 Ω · cm) 6.3 6.9 6.2 6.7 4.5 4.0 * CS Η 1 to 3 + D i-ρ: c SH 1 to 3 and 2 A simple mixture of isopentaerythritol (Examples 30 to 32, comparative implementation 洌 17) Synthesis of diisopentaerythritol K 2 mannitol from Example 2 to replace Μ to obtain dry and ground finely mixed calcium- Silica composite particles (CASH-M), which are coated with M polyols. Similarly, the diisopentaerythritol of Synthesis Example 2 was replaced with diisopentaerythritol adipate to obtain a dry-milled and mixed fine Powdered calcium-silica composite particles (CA SH-S), which are coated with MU polyenzyme. The following products were prepared by heating and kneading at 150 C for 7 minutes. A plate having a thickness of 0.5 mm was prepared. From the plate Test pieces were prepared and their heat resistance, thermal stability, and volumetric resistivity in a Geer's oven were measured. The results are shown in Table 11. (Blended) Polyvinyl chloride wax (degree of polymerization = 1W0) dioctyl phthalate zinc stearate

雙酚A 二苄醯基甲烷 Alkaraizer 4 試樣 -45- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公漤) ---------^------tT------ (請先聞讀背面之注$項-?%寫本頁) 4081^6 A7 B7 正 五、發明說明(一) 表 例 1 3 2 比 較 例 17 在i; e e r 烤箱中 卢;;«4; ItL· f r\_ itit \ aj [fj熟「丨土、分嫂) 140 14G 140 i n 4 U 熟女疋〗:± ΐ万理J 220 205 21ο ss ££ ^f?r Pa T*r 題損电fci ; (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 (U 1 2 Ώ -公分) 5 ‘ 2 8 . 7 5.1 5.0 (筈例3 3到3 δ,比較的晋葩飼i 8 ) 下列组成韧使苗加熱於1 5 β °C捏合滾茼捏合7分鐘以 製痛一種具有d.5毫米厚度之板片。從板片製備測試片並 且剷量皑們在Geer氐烤箱中的酎熱性,熱安定倥,和體積 電阻率。结果如表12所示。 (接合) 重量份 氯化Μ乙烯樹脂ί ;Π %的氯含量) 100 鈦酸二辛酯 50 硬脂酸鋅 0.4 -4Η- Λ f K ^ SI I ί I 1^1 n I- 本紙張尺度適用中國國家標準(CNS)A4規格(210 x 297公.¾ ) 40815ο A7 B7 五、發明說明U<) 雙骼A 二ΐ嬙基甲烷 經濟部智慧財產局員工消費合作社印製 .0 試樣 表U 主 1 f'l i c 例 比 較 例 33 34 3 5 3 8 1 η i 0 CASH 1 . ϋ i . 0 1 /λ ri r* L 4 U l) * 0 Z . G AIkaiizer-4 1 η i . u i.4 M i z u k a I a c i . 0 片納鋁石 l. 0 在Gi?ei'氏烤箱中 140- 的嗣熱性(分鐘) 140 160 1 60 30 60 熱安定性(分鐘) 102 105 S3 10G 88 體積電駔革 (X 1 (] 1 3 Ώ -公分) 24 . 1 Ο J> 1 i CO . ί 5 · G 3,5 4.5 * i z uka i ac :鋰 -鋁複合 物氫氧化 物的碳酸鹽 (由Η i z u s a w a K a g a k u Κ 〇 g y 〇公司製造) * n訥鋁石:鈉-鋁複合锪M氧化物的碳酸鹽(由Hizusawa R a g a k u K 〇 g y 〇公司製造) -47 - 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁) ro5 丄 8 ο4 A7B7Bisphenol A dibenzylfluorenylmethane Alkaraizer 4 sample-45- This paper size applies to China National Standard (CNS) A4 specification (210X297 cm) --------- ^ ------ tT- ----- (Please read the note on the back-first, write this page) 4081 ^ 6 A7 B7 Fifth, the description of the invention (a) Table Example 1 3 2 Comparative Example 17 in the i; eer oven ; «4; ItL · fr \ _ itit \ aj [fj cooked" 丨 soil, tiller) 140 14G 140 in 4 U MILF 疋〗: ± ΐWanli J 220 205 21ο ss ££ ^ f? R Pa T * r title damage electricity fci; (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (U 1 2 Ώ-cm) 5 '2 8. 7 5.1 5.0 (Example 3 3 to 3 δ, compared to Jin 葩 feed i 8) The following composition toughens the seedlings to heat at 15 β ° C kneading roll kneading for 7 minutes to make a plate with a thickness of d.5 mm. Test from plate And measure the thermal resistance, thermal stability, and volume resistivity in a Geer 氐 oven. The results are shown in Table 12. (Joint) parts by weight of chlorinated vinyl chloride resin; Π% chlorine content) 100 Dioctyl titanate 50 zinc stearate 0.4 -4Η- Λ f K ^ SI I ί I 1 ^ 1 n I- This paper size is applicable to China National Standard (CNS) A4 specification (210 x 297 male. ¾) 40815ο A7 B7 V. Description of the invention U <) Double-bone A Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economics of Dimethylmethane. 0 Sample table U Master 1 f'l ic Example Comparative Example 33 34 3 5 3 8 1 η i 0 CASH 1. Ϋ i. 0 1 / λ ri r * L 4 U l) * 0 Z. G AIkaiizer-4 1 η i. u i. 4 M izuka I aci. 0 pieces of nano-alumite l. 0 140 140- in Gi? ei ''s oven Thermal property (minutes) 140 160 1 60 30 60 Thermal stability (minutes) 102 105 S3 10G 88 Volume electric leather (X 1 (] 1 3 Ώ-cm) 24. 1 〇 J > 1 i CO. Ί 5 · G 3,5 4.5 * iz uka i ac: Carbonate of lithium-aluminum complex hydroxide (manufactured by Η izusawa Kagaku KK 〇 〇 〇) * n bauxite: Carbonic acid of sodium-aluminum composite 锪 M oxide Salt (manufactured by Hizusawa Ragaku K 〇gy 〇) -47-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the back first (Please fill in this page again if necessary) ro5 丄 8 ο4 A7B7

明說 明發 五 细/一 之及得 像物獲 圖合便 射ifcM 繞 0 , 線酸用 射尿使 X 氰 合 和異組 物與物 成且化 組,氧 定 出 S 特選饬 有鈣合 具酸複 , 矽鋁 明從 I 發係鹼 本鈣或 據酸石 抠矽滑 晶7K 结或 良 優 Λ 性 C 化栩 老成 抗組 溫锪 低 合 良聚 改氯 著含 顯之 、 色 性著 定初 安最 熱止 良防 改及 著¾ 顯緣 有絕 ^兵 電 稽的 尿使 氰合 異 組。 與物色 旦化著 氧初 成氬最 形韧免 酵合遊 元複和 多鋁性 和 I 定 鈣鹸安 酸或熱 矽 石 白IX; 晶潢改 结水步 遛或一 從/進 物及許 合ti允 複合其 當 化 , 酷時 酸.¾ (請先閲讀背面之;i意事項再填寫本頁) ---I--—訂 ----I--1_ 線 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS)A4規格(210 * 297公釐)Make it clear that you can get five details / one to get the image, then you can shoot ifcM around 0, use the acid to urinate to make X cyanide and the heterogeneous compound and the material and form the group. The oxygen is selected. With acid complex, silicoaluminium from I hair series basic calcium or silicon acid crystals from 7K knot or good Λ sex C ageing into the resistance group temperature and low polycondensation with chlorine, with significant, color Ding Chuan's hottest Zhiliang prevention reform and writing ¾ The obvious reason is that the urine of the soldiers makes the cyanide different groups. With the appearance of oxygen, the initial formation of argon is the most flexible, non-fermentative, non-aluminium compound, polyaluminum, and calcium, acetic acid, or hot silica white IX; Heti allows you to combine it with the right time, sour and sour. ¾ (Please read the back; please fill in this page before i) --- I --- Order ---- I--1_ Intellectual Property Bureau, Ministry of Economic Affairs The paper size printed by the employee consumer cooperative is applicable to the Chinese National Standard (CNS) A4 specification (210 * 297 mm)

Claims (1)

公告本 08.56 刮饺正 C8 年月Sd_1 laiL 六、申請專利範圍 經濟部眢慧时產局員工消費合作社印製 .•一 ϋ用P含氣聚合轉之安定劑,包括(a ) —種具育κ下 々5i迤式ί 1 )表7T、之化學組或构, Γ a 0 - a S1 ί) 2 · η Η 2 0 ' ‘ * ( 1) 其中χ為不小於0.5之數目,和 η為不大於2.5之數目, 旦在3 · G i到 3 . ϋ8埃的間隔*在2 . 78到2 . 82埃的間隔和 ].〖U到KS4埃的間隔具有X射線繞射圖像的细结晶矽酸 鈣,和(3 )異Μ尿酸醏化合物,其中成分(B )之含量為4至 重量份,每IdQ重量份之或分(Α)。 .一種闬於含氯聚合朝之安定劑,包括(A) —種具有K下 列通式(1)表示之化學S咸物, CaO* xSi〇2 · πίΐ2 〇 · (1) 其中χ為不小於0 . 5之數目,和 η為不大於2.5之數目, 旦^3.()1到3^8埃的間隔,在2.73到2.82埃的閭隔和 1.81到1.S4埃的間隔具有X射線繞射圖像的细结晶矽酸 鈣,(Β)異氰尿酸酯化合物和(C)水滑石或驗一鋁複合物 ,異氰尿酸酯化合鞠U ) Κ 0 . 5至5 ί),每UI0重量份之成 分U)和(C)的缌數約重量比存在,及成分(C)之含量為 i; S . 7 M S ί) 0重量份,每ί 0 ϋ重量份之成分(A )。 .根據串請專利範圍第i項之用於含氯聚合锪之安定劑, 其中異Μ尿酸酯化合物(B )為參(羥烷基)異氟尿酸酯。 .袒據电請專利範圍Μ 2項之用於含氯聚合物之安定劑, (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標率(CNS>A4*1格(210Χ297公嫠) 公告本 08.56 刮饺正 C8 年月Sd_1 laiL 六、申請專利範圍 經濟部眢慧时產局員工消費合作社印製 .•一 ϋ用P含氣聚合轉之安定劑,包括(a ) —種具育κ下 々5i迤式ί 1 )表7T、之化學組或构, Γ a 0 - a S1 ί) 2 · η Η 2 0 ' ‘ * ( 1) 其中χ為不小於0.5之數目,和 η為不大於2.5之數目, 旦在3 · G i到 3 . ϋ8埃的間隔*在2 . 78到2 . 82埃的間隔和 ].〖U到KS4埃的間隔具有X射線繞射圖像的细结晶矽酸 鈣,和(3 )異Μ尿酸醏化合物,其中成分(B )之含量為4至 重量份,每IdQ重量份之或分(Α)。 .一種闬於含氯聚合朝之安定劑,包括(A) —種具有K下 列通式(1)表示之化學S咸物, CaO* xSi〇2 · πίΐ2 〇 · (1) 其中χ為不小於0 . 5之數目,和 η為不大於2.5之數目, 旦^3.()1到3^8埃的間隔,在2.73到2.82埃的閭隔和 1.81到1.S4埃的間隔具有X射線繞射圖像的细结晶矽酸 鈣,(Β)異氰尿酸酯化合物和(C)水滑石或驗一鋁複合物 ,異氰尿酸酯化合鞠U ) Κ 0 . 5至5 ί),每UI0重量份之成 分U)和(C)的缌數約重量比存在,及成分(C)之含量為 i; S . 7 M S ί) 0重量份,每ί 0 ϋ重量份之成分(A )。 .根據串請專利範圍第i項之用於含氯聚合锪之安定劑, 其中異Μ尿酸酯化合物(B )為參(羥烷基)異氟尿酸酯。 .袒據电請專利範圍Μ 2項之用於含氯聚合物之安定劑, (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標率(CNS>A4*1格(210Χ297公嫠) 經濟部智慧时4局員工消費合作社印製 六、申請專利範圍 其中異氯尿酸酯(b合物(B)為參(羥烷基)異氟尿酸酷:: 5.—種用於含氛聚合锪之安定劑,包括(ΰ) 一種具有K下 列通式U )表示之化學組成物, C a 0 * X S 10 2 * π Η z 〇 , , (2 } 其中:<為3.5至2.ϋ之數目,和 η 兩-V'大於ΐ ΰ之戴曰 » 且在:】.ίΠ到:;.ϋ 3埃的間隔,在2 . 7 8到2 . S 2埃的間隔和 1.Si到1.8 4埃的間隔具有X射線鏡射圖像的细结晶钞酸 耗* W ( C)水滑石或驗一|§複合窃Μ氧化物 '其φ或份· (C)之含量為33.3Μ567重量份,每iGO重量份之成分(D) 0 S .椹據电請專利範第1項之周於含氮聚合樹之安定劑, 其中部结晶矽酸鈣(Α)為一種複合锪(Ε),其包含在20: 8 ϋ到8 G : 2 ϋ的重量比之细结晶矽酸鈣U )和多元酵。 7.裉據串請專利範園第1項之芾於含氛聚合物之安定劑* 其中迪结晶矽酸鈣U)具有不小於1.73之Κ下列式(3)定 義Ζ層合不對稱惶Us)的指數< ί 5 = t a π Θ 2 / ΐ a π 0 i · * - ( 3 ) 其中S ,為在3 . 0 i到3 . 0 S埃的間隔之X射線繞射蜂垂直 線和窄角之逄的切線所成之角•和為在上述之峰和 廣角之邊的切線所成之角。 3 .棍據串請專利範圍第1項之用於含氛聚合物之安定劑, 其中细结晶矽酸鈣(A )具有6 ϋ到2㈣公尺2 /克的比表面 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家榡準(CNS > Α4说格(2丨0X297公釐) 408156 A8 B8 C8 D8 申請專利範圍 經濟部智慧財走局員工消費合作社印製 槙,不小於ϋ . 5毫升/克之多孔體積,5 ί)到2 5 G *升/ Π) ϋ兒之吸油量,和ϋ . 1到1 ϋ it微米的平均粒子罝涇: 3 .根據串請專利範圍第6項之兩於含氯聚合物之安定飼* 其中细结晶矽酸鈣(A)祐多元醇的複合物(E)係籍®濕式 一戎乾式™研磨缌结晶矽酸鈣和多元酵甜獲得& ii).棍據申請專利範圍16項之周於含氯聚合锪之安定劏, 其中多元醇為異戊西醇或二異戍四醇。 il.揋據Φ請專利範圍第2項之甩於含氯聚合锪之安定劑, 其中進一步包含(p) 5到73重量份之高鈒脂肪酸鋅,每 ΠΙΟ重量份之成分(A)和(C)缥數。 U ·裉據串謓專利範圍第2項之茁於含氯聚合锪之安定_, 其中進一步包含(G) 1到50重量份之鼢類型抗氧劑,每 Ιδϋ重量份之成分(Α)和U)缌數。 U .银據串請專莉範圍第2項之甩於含氯聚合锪之安定剖, 其中氺滑石為鋅改質之水滑石。 U .椹據串請專利範圍第2項之周於含Μ聚合锪之安定劑, 其中進一步包含U) ϋ . 5到3G重量份之召-二酮或厶基 酸酯,每1DG重量份成分(Α)和(C)的德數。 15 .裉據串請專利範圍第2項之用於含氯聚合物之安定劑, 鹼一鋁複合物1氧化韧的鹽為鋰一鋁複合物1氧化物的 «酸Η。 19,梠撺审請專利範圍第2項之甩於含氧聚合物之安定劑, 其中鹼一鋁複含物氫氯化物的鹽為納一鋁複合物愿氧it (請先閱讀背面之注意事項再填寫本I ) 本紙張足度逋用中國國家標率(CNS > A4洗格(210X297公釐} 408156 Λ8 B8 C8 08 六、申請專利範圍 拘的η .納鋁石型碳酸鹽- 17.裙逋申諳專利範圍第5項之闬於含氛聚合物之安定劑, 其中繃结晶矽酸鈣(D)為一複合锪(S)<其包含2G: SO到 3Π : 21)重量比的细结晶矽酸鈣(A)和多元酵。 13.根據申請專利範圍第5項之用於含氯聚合物之安定劑, 其中10结晶矽酸鈣(D)具有不小於1.75之KT列式(3)定 義之層合不對稱性(i s )的指數* [s = t a η Θ 2 / ian θ ι · * * (3] 其中Θ i為在3 · G1到3 . G S埃的間隔之X射線繞射峰垂直 線和窄角之逢的切線所成之角,和Θ 2為在上逑之峰和 廣角之邊的切媒所成之角。 U .棍據Φ請專利範園第5項之用於含氯聚合锪之安定劑, 其中细结晶矽酸鈣ί δ )具有6 0到2 0 0公尺2 /克的比表面 積,不小於0,3 ·毫升/克之多孔體積,513到2 5 ί]毫升/ Ιϋί)克之趿油量,和0.1到U0微老的平均粒子直涇: 2 Π .棍據串請專利範園第項之甭於含氯聚合物之安定劑, 其中堀结晶矽酸H (D)軺多元醇的複含物(E)係藉由濕式 一戎乾式-研磨题结晶矽酸鈣和多元醇而獲得:= 2 .1 .棍據串請專利範圍第17項之甬於含氯聚合物之安定劑, 其中多元醇為異戊四醇或二異戊四酵。 2 2 .根據申請專利範圍第5項之用於含氯聚合物之安定劑, 其中進一步包含U) 5到7 0重量份高级脂肪酸鋅,每U) 0 St;分之成分(D)和(C)缌數。 -4 _ ----------士水------訂-------良 {請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產苟gi工消費合作钍印製 本紙張尺度逋用中國國家樣準(CNS > ( 21〇X2r?公釐) 408156 as Β8 C8 D8 ______ 六、申請專利範圍 (請先W讀背面之注意事項再填寫本頁) 2 3 .裉據申請專利範圍第5項之用於含填聚合韵之安定劑’ 其中進一步包含(G ) 1到5 (3重量份之酚類型抗氧劑f每 ii)G重量份之成分(D)和(C)缌數。 2 4 .根據串請專利範圔第5項之闬於含氛聚合物之安定劑’ 其中水滑石為鋅改質之水滑石。 2 5 ,裉據串請專利範園第5項之用於含氮聚合物之安定剪I ’ 其中進一步S含U) Q . 5到3 (3重量份之召-二酮或召-酮基 酸詣s每100重量份成分(D)和(C)的缌數a 2 δ .椹據串請專利範圍第5項之用於含氛聚合锪之安定劑* 鹼一鋁複合锪氫氣化物的體為鋰一鋁複合物氫氧化物的 硬酸鹽。 27.根據申請專利範圍第5項之用於含氛聚合物之安定劑, 鹼-鋁複合物氫氧化物的鹽為鈉一鋁複合物氫氯化物的 片鈉鋁石型碳酸鹽。 23.—種安定含氛聚合锪組合锪,钽括(Α)具有G. 2到1U重量 汾之一種Μ下列通式(1)表示之化學組成物, CaO· x〇i〇2 · nHa 0 · (1) 經濟部智慧財產局員工消費合作社印製 其中χ為不小於〇 . 5之數目,和 η為不大於2 · 5之數目* 且在3 . 0 1到3 . G 3埃的間隔,在2 . 7 3到2 . S 2埃的間隔和 1 . 8 1到1 · S 4埃的間隔具有X射線鏡射圈像的细结晶矽酸 鈣,或一種複合物(Ε),其具有多元酵,(b)q.〇1至3重 曼份之異氰尿酸酯化合物’及/或(〇〇·ι至1〇重量份之 紙浪纽適用中國國家標率(°ls >Α4胁(2丨0X297公釐} 經濟部智慧財產局8工消費合作社印製 A8408156 骂D8、申請專利範圍 永滑石或鹼—鋁氫氧化物的鹽,每u 〇重量份之含m聚 合窃: ZS.棍撻串請專利範圍第2S項之含氛聚合物組合韧,其中異 鼠尿酸_化合物U)為參(羥烷基)異氯尿酸酿。 3 ίΐ .裉據串請專利範圍第2 8項之含氯聚合物組合韧,其中含 it聚合物為氯乙烯樹脂,和成分(c)為水滑石。 3 i .根據串請專利範圍第2 S項之含氯聚合物組合锪,其中含 氛聚合物為氛化氯乙烯樹脂,及成分(C)為鹼-鋁複合 窃氳氧化物之鹽。 3 2 ·棍據申請專利範圍第2 S項之含氯聚合物組合韧,其中進 一步包含(F) 5到7Q重量份高级肪酸鋅,每1〇〇重量汾 之含氯聚合锪。 33 .裉據串諸專利範圍第28項之含氯聚合锪组合物,其中進 —步包含(S)O.Qi到5.G重量份之酚類型抗氧劑*每1G0 Μ量份之含氛聚合物= 3 4 .根據串請專利範圍第2 S項之含氯聚合锪組合物,其中水 滑石為鋅改質之水滑石= 3 3 .根據串讅專利範圍第2 S項之含氯聚合韧组合锪,其中其 中進一步包含(Η ) 0 . 31到5 . 0重量份之/3 -二嗣或;5 -嗣基 酸酯*每1 0 β重量份之含Μ聚合物。 (請先閲讀背面之注意事項再填寫本頁) -8 - 本紙張尺度適用中國國家標準(CNS > Α4規格(210Χ29"?公釐)Announcement 08.56 Scrape dumplings are Cd Sd_1 laiL in C8. 6. Application for patents. Printed by the Consumer Cooperatives of the Ministry of Economic Affairs of the Huihui Industry Bureau. • One stabilizer using P gas polymerization, including (a) —species breeding κ 下 々 5i 迤 式 ί 1) Table 7T, the chemical group or structure, Γ a 0-a S1 Γ) 2 · η Η 2 0 '' * (1) where χ is a number not less than 0.5, and η is The number is not greater than 2.5. The interval between 3 · G i to 3. ϋ 8 Angstroms * between 2. 78 to 2. 82 Angstroms and the interval between U. and KS4 Angstroms has a fine X-ray diffraction image. Crystalline calcium silicate, and (3) isoM urate compound, wherein the content of component (B) is 4 to parts by weight, or (A) per part by weight of IdQ. A stabilizer for chlorine-containing polymerization, including (A)-a chemical salt of K having the following general formula (1), CaO * xSi〇2 · πίΐ2 〇 · (1) where χ is not less than The number of 0.5, and η is a number not greater than 2.5, with X-rays at intervals of 1 to 3 ^ 8 angstroms, 2.73 to 2.82 angstroms, and 1.81 to 1.S4 angstroms Diffraction image of fine crystalline calcium silicate, (B) isocyanurate compound and (C) hydrotalcite or aluminum complex, isocyanurate compound Ju U) K 0. 5 to 5 ί) S, 7 MS ί) 0 parts by weight, 0 ϋ parts by weight of each component ( A). The stabilizer for chlorine-containing polymer fluorene according to item i of the patent claim, wherein the isoM urate compound (B) is ginsyl (hydroxyalkyl) isofluorourate. . According to the electricity, please apply for stabilizers for chlorinated polymers in the scope of patent M2, (please read the precautions on the back before filling this page) This paper size is applicable to China's national standard (CNS > A4 * 1 grid ( 210 × 297 gong) Announcement 08.56 Scraping dumplings are Cd Sd_1 laiL in C8. 6. Application for patents. Printed by the Consumers' Cooperatives of the Ministry of Economic Affairs, Huihui Industry Bureau. • A stabilizer used for P gas polymerization, including (a) — Species with κ 下 々 5i 迤 式 ί 1) Table 7T, the chemical group or structure, Γ a 0-a S1 ί) 2 · η Η 2 0 '' * (1) where χ is a number not less than 0.5 , And η are numbers not greater than 2.5, once at an interval of 3. · G i to 3. ϋ 8 Angstroms * at an interval of 2. 78 to 2. 82 Angstroms and]]. [U to KS4 Angstroms have X-ray diffraction Image of finely crystalline calcium silicate, and (3) an isoamidine urate compound, wherein the content of component (B) is 4 to parts by weight, or (A) per part by weight of IdQ. A stabilizer for chlorine-containing polymerization, including (A)-a chemical salt of K having the following general formula (1), CaO * xSi〇2 · πίΐ2 〇 · (1) where χ is not less than The number of 0.5, and η is a number not greater than 2.5, with X-rays at intervals of 1 to 3 ^ 8 angstroms, 2.73 to 2.82 angstroms, and 1.81 to 1.S4 angstroms Diffraction image of fine crystalline calcium silicate, (B) isocyanurate compound and (C) hydrotalcite or aluminum complex, isocyanurate compound Ju U) K 0. 5 to 5 ί) S, 7 MS ί) 0 parts by weight, 0 ϋ parts by weight of each component ( A). The stabilizer for chlorine-containing polymer fluorene according to item i of the patent claim, wherein the isoM urate compound (B) is ginsyl (hydroxyalkyl) isofluorourate. . According to the electricity, please apply for stabilizers for chlorinated polymers in the scope of patent M2, (please read the precautions on the back before filling this page) This paper size is applicable to China's national standard (CNS > A4 * 1 grid ( 210 × 297 public address) Printed by the Consumer Affairs Cooperative of the 4th Bureau of the Ministry of Economic Affairs. 6. Scope of patent application. Among them, isochlorouric acid ester (b compound (B) is ginsyl (hydroxyalkyl) isofluorouric acid): 5.—species Stabilizers for atmospheric polymerization of fluorene, including (i) a chemical composition having the following general formula U), C a 0 * XS 10 2 * π Η z 〇,, (2} where: < 3.5 to 2. The number of ϋ, and η two -V 'are greater than ΐ ΰ 的 戴戴 »and in:]. ΊΠ to:;. Ϋ 3 Angstrom intervals, between 2.78 to 2. S 2 Angstrom intervals And 1.Si to 1.8 4 Angstroms with X-ray spectroscopic images of fine crystalline banknotes, acid consumption * W (C) hydrotalcite or test | § compound stealing M oxide 'its φ or parts · (C) of The content is 33.3M567 parts by weight, the component (D) 0 S per iGO parts by weight. According to the patent application, the stabilizer of the nitrogen-containing polymer tree is described in Item 1. The middle crystal calcium silicate (A) is a kind of Compound 锪 (Ε) It contains 20: 8 ϋ to 8 G: 2 ϋ in a weight ratio of fine crystalline calcium silicate U) and polyenzyme. 7. According to the patent, please refer to item 1 of the patent garden for stabilizers containing aromatic polymers. * Where Di crystal calcium silicate U) has an index of not less than 1.73 and the following formula (3) defines the z-layer asymmetry 惶 Us) < ί 5 = ta π Θ 2 / ΐ a π 0 i · *-( 3) where S is the angle formed by the vertical line of the X-ray diffraction bee and the tangent of the narrow-angle ridge at the interval of 3.0 i to 3.0 S angstroms The angle formed by the tangent. 3. According to the patent application, the stabilizer for atmosphere-containing polymers, the fine crystal calcium silicate (A) has a specific surface of 6 ϋ to 2 ㈣ m 2 / g (please read the back Note: Please fill in this page again.) This paper size is applicable to China National Standard (CNS > Α4 grid (2 丨 0X297 mm) 408156 A8 B8 C8 D8. Patent application scope. Not less than 多孔. Porous volume of 5 ml / g, 5 ί) to 2 5 G * liters / Π) oil absorption of ϋ, and ϋ. 1 to 1 ϋ average particle size of it 罝 泾: 3. Patent according to string Stabilization of chlorinated polymers in range 6 * Among which fine crystalline calcium silicate (A) polyhydric alcohol complex (E) series ® Wet Yijong Dry ™ ground crystalline calcium silicate and polyvalent Obtained fermented sweets & ii). According to the patent application scope of the 16 weeks in the stability of chlorine-containing polymer hydrazone, where the polyhydric alcohol is isopentyl alcohol or diisotriol. il. According to Φ, please refer to the stabilizer of chlorine-containing polymerized fluorene according to item 2 of the patent, which further contains (p) 5 to 73 parts by weight of high-fat fatty acid zinc, and each (10) parts by weight of ingredients (A) and ( C) Number. U. The stability of the chlorine-containing polymer according to item 2 of the patent scope, which further contains (G) 1 to 50 parts by weight of a type 鼢 antioxidant, per δ ϋ parts by weight of the component (A) and U) The number. U.Silver string please ask the stability profile of the second item in the range of chlorine-containing polymer rhenium, where talc is zinc-modified hydrotalcite. U. 椹 According to the scope of the patent, please refer to the stabilizer of M polymer 锪, which further contains U) ϋ. 5 to 3G parts by weight of di-diketone or fluorenyl ester, per 1DG by weight of ingredients Virtues of (A) and (C). 15. According to the patent application of the stabilizer for chlorine-containing polymers, the alkali-aluminum complex 1 oxidized salt is lithium-aluminum complex 1 oxide. 19. Please review the stabilizer of oxygen-containing polymer in item 2 of the patent scope, in which the salt of alkali-aluminum complex hydrochloride is nano-aluminum complex and oxygen (Please read the note on the back first) Please fill in this item again. I) This paper is fully compliant with the Chinese National Standard (CNS > A4 Washing (210X297 mm) 408156 Λ8 B8 C8 08. VI. The scope of patent application is limited to η.Nanolite type carbonate-17 The stabilizer in the patent application item No. 5 is a stabilizer for an atmosphere-containing polymer, wherein the crystalline calcium silicate (D) is a compound (S) < it contains 2G: SO to 3Π: 21). Ratio of fine crystalline calcium silicate (A) and polyzyme. 13. Stabilizer for chlorine-containing polymers according to item 5 of the scope of patent application, where 10 crystalline calcium silicate (D) has a KT column of not less than 1.75 The exponent of laminated asymmetry (is) defined by equation (3) * [s = ta η Θ 2 / ian θ · · * * (3) where Θ i is the interval between 3 · G1 and 3. GS Angstroms The angle formed by the vertical line of the X-ray diffraction peak and the tangent line at the narrow angle, and Θ 2 is the angle formed by the tangent medium on the peak of the upper edge and the edge of the wide angle. 5 stabilizers for chlorine-containing polymerized rhenium, wherein the fine crystalline calcium silicate δ) has a specific surface area of 60 to 200 m 2 / g, and a porous volume of not less than 0.3 ml / g, 513 to 2 5 liters per milliliter per liter of oil, and the average particle size of 0.1 to U0 micro-olds: 2 Π. According to the patent, please refer to the patent for the stabilizer of chlorinated polymers, Among them, the crystalline silicate H (D) 轺 polyol complex (E) is obtained by wet-drying-grinding crystalline calcium silicate and polyol: = 2.1. The stabilizer of scope item 17 is a stabilizer for a chlorinated polymer, wherein the polyhydric alcohol is isopentaerythritol or diisopentaerythritol. 2 2. The stabilizer for a chlorine-containing polymer according to item 5 of the scope of the patent application, which further contains U) 5 to 70 parts by weight of a higher fatty acid zinc per U) 0 St; fractions (D) and ( C) Number. -4 _ ---------- Shishui ------ Order ------- Good {Please read the notes on the back before filling this page) Ministry of Economic Affairs Intellectual Property Consumption cooperation: The paper size of this paper is printed in China (CNS > (21〇2r? Mm) 408156 as Β8 C8 D8 ______ VI. Patent application scope (please read the precautions on the back before filling this page) ) 2 3. The stabilizer for filling polymer rhyme according to item 5 of the scope of the patent application, which further contains (G) 1 to 5 (3 parts by weight of phenol type antioxidant f per ii) parts by weight of G The number of ingredients (D) and (C). 2 4. According to Article 5 of the patent application, the stabilizer of the polymer containing the atmosphere is' the hydrotalcite is a zinc-modified hydrotalcite. 2 5, according to Please refer to the patent No. 5 of the patent No. 5 for the nitrogen-containing polymer stable shear I 'wherein further S contains U) Q. 5 to 3 (3 parts by weight of the call-dione or call-keto acid s per 100 The weight ratios of components (D) and (C) are a 2 δ. According to the patent, the stabilizer for atmospheric polymerization containing the fifth item of the scope of the patent is required. * The base-aluminum composite / hydrogenated body is lithium-aluminum. Complex hydroxides of stearates. 27. According to the stabilizer for an atmosphere-containing polymer according to item 5 of the scope of the patent application, the salt of the alkali-aluminum complex hydroxide is a sodium-aluminum complex hydrochloride flake-type bauxite-type carbonate. 23. -A stable combination of atmospheric polymer, 锪, tantalum (A) has a chemical composition represented by the following general formula (1), with a weight of 2 to 1 U, and CaO · x〇i〇2 · nHa 0 · ( 1) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs where χ is a number not less than 0.5, and η is a number not more than 2.5 *, and at intervals of 3.01 to 3. G 3 Angstroms, in 2. 7 3 to 2. S 2 angstrom interval and 1.8 1 to 1 · S 4 angstrom interval Fine crystalline calcium silicate with X-ray mirror ring image, or a complex (E), which has multiple elements Fermentation, (b) q.〇1 to 3 parts by weight of isocyanurate compound 'and / or (00 · ι to 10 parts by weight of paper langur) applicable Chinese national standard (° ls > Α4 (2 丨 0X297mm) Printed by A8408156, D8, Patent Application Scope Permanent Talc or Alkali-Aluminum Hydroxide Salt, 8% by weight of m polymer Joint theft: ZS. Stick tart skewers, patented item 2S of the aromatic polymer combination tough, in which isorubic acid _ compound U) is ginseng (hydroxyalkyl) isochlorouric acid. 3 3. The combination of chlorine-containing polymers in the range of item 28 is tough, in which the polymer containing it is vinyl chloride resin and the component (c) is hydrotalcite. 3 i. The chlorine-containing polymer combination according to item 2 S of the patent application, wherein the atmosphere polymer is an atmosphere vinyl chloride resin, and the component (C) is a salt of an alkali-aluminum complex pirate oxide. 3 2 · The chlorine-containing polymer combination toughness according to item 2 S of the scope of patent application, which further contains (F) 5 to 7Q parts by weight of high-grade zinc fatty acid, per 100 parts by weight of chlorine-containing polymer fluorene. 33. The chlorine-containing polymeric samarium composition according to item 28 of the patent range, further comprising (S) O.Qi to 5.G parts by weight of a phenol-type antioxidant * per 1G0 M Aromatic polymer = 3 4. Chlorine-containing polymer rhenium composition according to item 2 S of the patent scope, wherein the hydrotalcite is zinc modified hydrotalcite = 3 3. Chlorine content according to item 2 S of the scope of patent Polymeric tough combination 锪, which further comprises (i) 0.31 to 5.0 parts by weight of / 3-dioxo or 5-fluorenyl ester * per 10 β parts by weight of the M-containing polymer. (Please read the precautions on the back before filling this page) -8-This paper size applies to Chinese national standards (CNS > Α4 size (210 × 29 "? mm)
TW87109452A 1998-04-21 1998-06-15 Stabilizer for chlorine-containing polymers and chlorine-containing polymer composition TW408156B (en)

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JP4516650B2 (en) * 2000-01-21 2010-08-04 水澤化学工業株式会社 Stabilizer composition for chlorine-containing polymer
DE102004028821A1 (en) * 2004-06-15 2006-01-12 Baerlocher Gmbh Stabilizer composition for colored halogen-containing thermoplastic resin compositions
US8598259B2 (en) 2008-10-09 2013-12-03 Adeka Corporation Vinyl chloride resin composition for transparent product, and transparent molded product produced by molding the composition
JP6136964B2 (en) * 2014-02-05 2017-05-31 日立金属株式会社 Vinyl chloride resin composition, insulated wire using the same, and method for producing insulated wire

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US5648413A (en) * 1995-02-01 1997-07-15 Mizusawa Industrial Chemicals, Inc. Stabilizer for chlorine-containing polymers, process for the preparation thereof and chlorine-containing polymer composition

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