408066 五、發明說明（l) - 本發明係有關一種攜帶型、可控制釋放香味的裝置及其製 作方法。此裝置可貼於衣服或皮膚，亦可做成首飾配帶於 身上’而以受控制的速度持久散發出香味。此裝置除改進 了香水使用上之皮廣刺激性，尚具備易於攜帶' 保存容 易、造型優雅、香味持續與香味強度之可控制等優點。此 裝置亦可固定於周遭環境，如廁所、車内或辦公室，而具 備除臭 '清新空氣甚至提神等功能。從以上介紹可知，本 發明具諸多優點值得實施販售，亦即有產業上利用性。 [發明背景] $統技術中已有許多方法’能於—段時間内保持香味 放。例如，端午節所使用之香包或香囊，乃是將具芳 :植物部分縫入包或囊内。又如，把玫塊精油溶入壤濁； 燃燒時，香味因高熱而散發出丨。近㈣推出室内 freshener) ’則是在固趙蠟塊中含有香油， 中香油因沸點低而揮發釋出。此類產品的缺點 ^製作過程t加入界面活性劑（surfactant) ’且需加入 = 或紫外線吸收劑以增加產品穩定性（如美國專利 J 3’567, 1 1 9 );如此’則因物質間的相互作用，不易保 =味的品質。^國專利(公告號4 493,869)中揭露以微 :i :!T〇Ca 含香精的技術，此方法的缺點則在 ί: Λ不f定性’使製品的保存期短暫。此外，2 專利（公告號4,88U9Q)中揭露—種芳香貼 ^408066 V. Description of the Invention (l)-The present invention relates to a portable device capable of controlling fragrance release and a method for manufacturing the same. This device can be attached to clothes or skin, or it can be made into jewelry and worn on the body 'to emit fragrance at a controlled rate for a long time. In addition to improving the skin irritation of perfume, this device also has the advantages of being easy to carry, easy to store, elegant in shape, scent persistence and controllable scent intensity. This device can also be fixed in the surrounding environment, such as the toilet, car or office, and it has the functions of deodorizing, fresh air and even refreshing. As can be seen from the above description, the present invention has many advantages that are worth implementing for sale, that is, it has industrial applicability. [Background of the Invention] There are many methods in the conventional technology 'which can maintain the fragrance for a period of time. For example, the sachet or sachet used in the Dragon Boat Festival is to sew the fragrant: plant part into the bag or sachet. Another example is to dissolve the rose essential oil into the turbid soil; when burning, the fragrance is emitted by the high heat 丨. Kinki launched an indoor freshener) ’which contains sesame oil in Gu Zhao wax block, and the sesame oil is released due to its low boiling point. Disadvantages of this kind of product ^ Surfactant is added during the manufacturing process 'and it is necessary to add = or UV absorber to increase product stability (such as U.S. Patent J 3'567, 1 1 9); so' there may be The interaction is not easy to maintain = the quality of taste. ^ National Patent (Publication No. 4 493,869) discloses the technology that contains micro: i:! T〇Ca flavor, but the disadvantage of this method is that the shelf life of the product is short. In addition, disclosed in 2 patents (Announcement No. 4,88U9Q)-a kind of aromatic paste ^
—408066 五、發明說明（2)—408066 V. Description of the invention (2)
Patch)的製作技術，其香精是溶 中，藉由香精在聚合物中的緩慢^ σ _〇lyurethane 料& ^ 的鲛慢擴散，而達到控釋香味的 效果。然而，由於香精是在聚合 逐管味的 :問題:⑴聚合反應的殘留反應物應時可加與入香 (3)味黨不Λ定、⑺聚合反應的複雜性增加製程的困難度、 (3)需要多種反應物’使製作成本增加，不利於產業的利 用。我國新型專利C公告號3164〇2)中有一種隨身香貼片 係將含香水之膠囊置於上下層透氣布冑，使用時 把膠囊折斷釋出香水而產生香#。此專利有如下缺點： (1)貼片之造型與大小受到膠囊限制、（2)貼片設計中並未 具控釋香味之結構、（3)折斷的膠囊恐有傷害上下布層之 嫌，使用安全性與結構穩定性或有問題。本發明之目的即 在改進先前技術的諸多缺點，希望提供一種新的控釋香味 裝置’其功能特點為（〇製作方式簡易（2)產品結構穩定 (3 )攜帶容易（4)使用方式多樣化，例如貼於衣物' 貼於皮 膚、放於口袋中、放於鞋内、做成首飾（如香包、手鍊、 項鍊或墜子）使用；亦可將裝置貼、放於周遭環境而使香 味彌漫。 [詳細說明] 本發明的原理，乃利用化學物質溶在高分子膠體時’擴散 速度受到膠體結構牵制而變慢，以故來控制釋放香味。本 發明有如下技術特點：（1)所使用膠體為水膠類高分子物Patch) production technology, the essence is soluble, and the slow diffusion of the essence in the polymer ^ σ _olyurethane material & ^ slow diffusion, to achieve the effect of controlled release fragrance. However, since the essence is tasted one by one during the polymerization: Problem: The residual reactants of the polymerization reaction can be added to the fragrance (3) the taste of the party is uncertain, the complexity of the polymerization reaction increases the difficulty of the process, ( 3) Multiple reactants are needed to increase the production cost, which is not conducive to industrial utilization. In China's new patent C bulletin number 3164402, there is a portable fragrance patch. The capsule containing perfume is placed on the upper and lower breathable cloth, and the capsule is broken to release the perfume when in use. This patent has the following disadvantages: (1) the shape and size of the patch are limited by capsules, (2) the structure of the patch does not have a controlled release fragrance structure, and (3) the broken capsule is likely to hurt the upper and lower fabric layers, Use safety and structural stability may be problematic. The purpose of the present invention is to improve the many shortcomings of the prior art. It is hoped to provide a new controlled release fragrance device. Its functional characteristics are: (0) simple manufacturing method (2) stable product structure (3) easy to carry (4) diversified use methods , Such as sticking to clothing 'sticking to skin, putting in pockets, putting in shoes, making jewelry (such as sachets, bracelets, necklaces or pendants) for use; or putting devices in and around the environment to diffuse the fragrance [Detailed description] The principle of the present invention is to use a chemical substance to dissolve in a polymer colloid, the diffusion rate is slowed down by the colloidal structure, so as to control the release of fragrance. The present invention has the following technical characteristics: (1) used Colloids are hydrocolloid polymers
ΑΛ穩帶螌控制釋放香味的裝置.ptd 第6頁 408066 五、發明說明（3) 質’此類勝體已在保養品、創傷包覆醫材與經皮吸收劑型 中廣泛使用’但尚未應用於香味之控釋；水膠不與香味物 質起化學反應’其穩定性與相容性佳，故適合用來控釋香 味。（2 )製作過程簡便易行，與美國專利（公告號 4’880, 690)相比，其優點在於並不進行聚合反應而直接使 用已完成聚合反應的高分子膠體。為方便攜帶，本裝置係 設計成片狀物’由表層、中間層與底層三個結構所組成。 其中’表層是以透氣性高之不織布、合成皮或動物皮革為 材料；這些材料易切割成各種造型並染上顏色以供成品多 樣化。中間層乃一添加香味物質之高分子膠體，其膠體種 類如水膠（hydrogel)類之聚乙烯醇（p〇lyvinyl alc〇h〇l ; PVA)、聚乙烤 ^^(p〇lyvinylpyrr〇lid〇ne ;PVP)、聚甲 基丙烯酸氫氧基乙酯（p〇lyhydr〇xyaikyl m e t h a c r y 1 a t e )、聚丙晞 II 胺（p 0 1 y a c r y 1 a m 土 廿 e)、聚丙稀 西旨（卩〇173(：]^1&1：〇及曱基纖維素（11141^1(^111^〇56)等。 目刚商業化之水膠產品多為粉末狀，使用時需以水或低分 子量醇類如乙醇、己六醇（s 〇rb i t〇 1 )及甘油類等溶劑溶散 成半流動性之膠體；之後再均勻加入香味物質，包括動、 植物萃取液及化學合成與半合成的各類易揮發香精，此時 便可用塗布刀將膠體塗布於表層之一面，靜置一段時間後 流動性降低而成形，亦即產生近似果凍的外觀。為改變膠 ，硬度，尚可添加賦型劑包括澱粉、二氧化鈦及氫氧化鋁 等增黏性物質。底層的材質需求為具支持性與易於裁切之 特性，可為不織布、合成皮或動物皮革等布、皮類；亦可ΑΛ stable device for controlling the release of fragrance. Ptd page 6 408066 V. Description of the invention (3) Quality 'This kind of body has been widely used in skin care products, wound-covered medical materials and percutaneous absorption dosage forms' but has not yet been applied For the controlled release of fragrance; hydrogel does not react chemically with the fragrance substance. 'It has good stability and compatibility, so it is suitable for controlled release fragrance. (2) The manufacturing process is simple and easy. Compared with the US patent (Publication No. 4'880, 690), it has the advantage of directly using the polymer colloid that has completed the polymerization reaction without performing the polymerization reaction. In order to facilitate carrying, the device is designed as a sheet-like object, which is composed of a surface layer, a middle layer and a bottom layer. Among them, the surface layer is made of non-woven fabric, synthetic leather or animal leather with high air permeability; these materials can be easily cut into various shapes and dyed for the finished product. The middle layer is a polymer colloid with a flavor substance added, and the colloid type is hydrogel-type polyvinyl alcohol (p〇lyvinyl alc〇h〇l; PVA), polyethylene baking ^ (p〇lyvinylpyrr〇lid.) ne; PVP), polyhydroxyethyl methacrylate (polyoldroxyaikyl methacry 1 ate), polyacrylamide II amine (p 0 1 yacry 1 am soil), polypropylene polyether (卩 〇173 ( :] ^ 1 & 1: 0 and fluorenyl cellulose (11141 ^ 1 (^ 111 ^ 〇56), etc. Most of the hydrogel products that have just been commercialized are powdery. When using, water or low molecular weight alcohols such as Solvents such as ethanol, hexabutanol (sorb it〇1), and glycerol dissolve into semi-fluid colloids; after that, scent substances, including animal and plant extracts and chemical and semi-synthetic compounds, are evenly added. Volatile flavor. At this time, the colloid can be coated on one surface of the surface layer with a coating knife. After standing for a period of time, the fluidity is reduced and formed, which results in an approximate jelly appearance. In order to change the gum and hardness, excipients can be added including starch , Titanium dioxide and aluminum hydroxide, etc. Of supportive needs and characteristics of easy cutting, may be non-woven, synthetic leather, cloth or animal, skin type; also
A:\攜帶型控制釋放香味的裝置. 'Η 408066 五、發明說明（4) ::自P?及PET塑膠膜如此可避免香精之滲漏。為了幫助 底層黏著於中間層，尚可先在底層之背面塗上黏膠，再以 :面黏著於中間層。若本裝置以貼片㈣使用，則於底層 盆：感壓膠，烘乾後覆蓋離型·；之後再以背面黏 '?Β 。為使製程更加容易，底層亦可只用雙面膠； 先將雙面膠一面的離型紙撕去，再黏著於中間|。本發明 的香味強度與控釋期時間長短’係由高分子膠體種類之選 :、膠體塗布厚度、香味物質的比例與裝置的面積而決 疋以下列舉實施例，將本發明的結構、製作方法與功能 詳細說明如後： [實施例1 ] 在本實施例中’表層為不織布（thermal bonded，22g/ C πί ) °中間層的高分子膠體為pVp (k = 6〇);中間層的製法 如下：（1)將重量比30% PVP與重量比20%酒精均勻混合、 (2)將重量比40%玫瑰油加入上一步驟之產物並充分混 合、（3)將重量比10%殿粉加入上一步棘之產物並充分混 合、（4)以塗布刀塗抹以上膠體至不織布之一面，其塗抹 厚度0, 5mm、（5)靜置於空氣中3小時使膠體成形。底層為 雙面膠帶；雙面膠帶需先剝離其中一面離型紙，再黏至中 間層。成品可切割為各種造型的貼片，其一片面積約為8 平方公分；使用前將雙面膠另一面離漤紙剝離，即可貼於 衣物。藉由香味物質在高分子膠體的煖慢擴散作用，而維 持釋放玫瑰香味5日以上。A: \ Portable device for controlling the release of fragrance. '408 408066 V. Description of the invention (4) :: From P? And PET plastic film can avoid the leakage of flavor. In order to help the bottom layer adhere to the middle layer, it is still possible to apply adhesive on the back of the bottom layer, and then use the: face to adhere to the middle layer. If the device is used as a patch, then the bottom pot: pressure-sensitive adhesive, cover and release after drying; then stick the ?? B on the back. In order to make the process easier, the bottom layer can only use double-sided tape; the release paper on one side of the double-sided tape is peeled off first, and then stuck in the middle |. The intensity of the fragrance and the length of the controlled release period of the present invention are determined by the type of polymer colloid: the thickness of the colloid coating, the proportion of the fragrance substance and the area of the device. The following examples are given to illustrate the structure and manufacturing method of the present invention. The detailed description of the function is as follows: [Example 1] In this example, the 'surface layer is non-woven (thermal bonded, 22g / C πί) ° The polymer colloid of the intermediate layer is pVp (k = 6〇); the method of manufacturing the intermediate layer As follows: (1) uniformly mix 30% by weight PVP with 20% by weight alcohol, (2) add 40% by weight rose oil to the product of the previous step and mix thoroughly, (3) 10% by weight Add the product from the previous step and mix thoroughly. (4) Apply the above colloid to one side of the non-woven fabric with a coating knife. The application thickness is 0, 5mm. (5) Leave it in air for 3 hours to form the colloid. The bottom layer is double-sided tape; the double-sided tape needs to be peeled off one side of the release paper before sticking to the middle layer. The finished product can be cut into various shapes of patches, with an area of about 8 square centimeters; before use, peel the other side of the double-sided tape away from the paper to apply it to clothing. With the warm and slow diffusion of scent substances in the polymer colloid, it can maintain the release of rose fragrance for more than 5 days.
A:\攜帶型控制釋放香味的裝置.ptd 第8頁 408066 五、發明說明（5) [實施例2 ] 在本實施例中’表層納合成皮。t間層高分子膠 VA，中間層的製法如下：（1)將重量比5〇% pVA與重量 20%水均勻混合、（2)將重量比22%αι香水加入上一步驟 之產物並充分混合、（3)將重量比8%二氧化鈦加入上一步 驟之產物並充分混合、（4)以塗布刀塗抹至合成皮之一 面，塗抹厚度0. 5mm、（5)靜置於空氣中6小時使膠體成 形2底層為不織布（high丨oft，32g/c m2)，先以塗布刀塗 抹一層厚度0. 1 mm的易吸水性感壓膠至不織布底面，於85 分鐘，再把離型膜覆蓋在感壓膠上。最後將上述 黏Λ於中間層，並切割為各種造型貼片，其 其性質不會刺激皮廣 於ί; =7用公/。使用前將離型膜剝離，"貼 、 感壓膠具有吸水特性，於長久貼用後 ’藉由香水物質在高分子膠體的緩慢 擴散作用，而維持釋放 砰取香味於3日以上。 以上所述為本發明之具 依本發明之構想所作之2施例與所運作之技術原理’ * 内，合予陳明。 均等改變，仍應在本發明之範圍A: \ Portable device for controlling the release of fragrance. Ptd page 8 408066 V. Description of the invention (5) [Example 2] In this example, ’the surface layer receives synthetic leather. The interlayer polymer glue VA and the intermediate layer are prepared as follows: (1) uniformly mix 50% by weight pVA with 20% by weight of water; (2) add 22% by weight αα perfume to the product of the previous step and fully Mixing, (3) adding 8% by weight of titanium dioxide to the product of the previous step and thoroughly mixing, (4) applying a coating knife to one side of the synthetic leather, applying a thickness of 0.5mm, (5) standing in the air for 6 hours Make the colloid shape 2 The bottom layer is a non-woven fabric (high 丨 oft, 32g / c m2), first apply a layer of 0.1 mm thick water-absorbing and sexy glue to the bottom surface of the non-woven fabric with a coating knife, and then cover the release film in 85 minutes. Pressure sensitive adhesive. Finally, the above is glued to the middle layer and cut into various modeling patches, whose properties will not irritate the skin wider than ί; = 7 用 公 /. The release film is peeled off before use. "The adhesive and pressure-sensitive adhesive have water-absorbing properties. After long-term application, it can maintain the release by diffusing the perfume substance in the polymer colloid and slam for more than 3 days. What has been described above are the two embodiments of the present invention and the technical principles of operation according to the concept of the present invention. Equal changes should still be within the scope of the invention