A7 B7 五、發明説明（ 發明之範圍 本發明係關於包括通氣裝置之容器。 請 先 閲 讀 背 δ 之 注 意 I r I裝 頁 發明之背景 響應封閉容器内壓力與周圍壓力間之壓力差之容器變形 問題爲包裝工業中熟知者。此種容器變形在某些容器材料 如某些塑膠或金屬爲不可復原性。薄壁部份撓性容器對此 一問題特別敏感。 訂 有可導致上述容器内部與外方間壓力差之多次因數。例 如，容器内盛物可爲化學不穩定性，或可遭受與可能存在 於容器頭部空間中氣體反應，或在某些特定情況下，可與 容器材料本身發生反應。涉及液態内盛物之任何化學反應 物可導致產生氣體，因而容器中產生過度壓力，或由於吸 收任何頭部空間氣體而導致容器中壓力不足。 線 容器内壓力與周圍大氣壓力間之壓力差亦可在容器之裝 填及密封過程中溫度與輸送及貯存過程中外方溫度明顯不 同時發生。另一可能性爲容器裝填時周圍壓力與在不同地 理位置之另一周圍壓力之不同可導致差力差。 經濟部中央標準局員工消費合作社印製 以往技藝提出利用避免容器内外間壓力差之閥系統之數 種解決方法。所提出之方法亦涉及容許容器内產生之壓力 藉使氣體逸出而釋出之各種通氣蓋。例如，FR-A-2 259 026， US-4 136 796及DE-A-2 509 258揭示包括覆蓋至外方孔之可 滲透氣體隔膜之自動通氣封閉容器。隔膜爲不滲透液體 但可滲透氣體之材料製成。因此，容器可包括釋出氣體 至外方而不損失不滲漏性之孔。另一例爲EP-A-593 840，揭 -4 - 本紙乐尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（2 ) 示包容產生壓力之液體之容器，容器爲包括微通道網路 之熱塑材料製成。此微通道網路可滲透氣體但不滲透液 體。 經發現如果液態產品接觸此等隔膜或微通道末端時，隔 膜可損失至少部份可滲透氣體性。具體言之，包含懸浮 於液態產品中固體粒子如碳酸鹽、過碳酸鹽及/或過硼酸 鹽之液態產品，可不完全排離隔膜回應容器内。反之， 經發現隔膜之微孔被自液體沉澱之此等固體粒子堵塞。 此一情況下，可發生容器喪失通氣能力。喪失通氣能力 導致可使容器變形之容器内部與外方間之壓力差。 裝滿之容器在輸送過程中被擾動時，產品潑濺於隔膜上 之情況可導致產品與隔膜間之接觸。經發現輸送過程中 正常發生之潑賤是足以完全間斷容器之通氣能力。產品 可接觸隔膜之另一種方式爲容器倒置貯放。經進一步發 現他種通氣系統例如閥亦可具有相同缺點。 如前文所述，影響隔膜通氣能力之一重要參數爲接觸隔 膜之產品可沉澱出懸浮在產品中之若干固體粒子。因此 ，本發明之一目的爲提供包容含有固體粒子之液態產品 之一種容器，容器藉通氣裝置使產品通氣，因而實際減 少固體粒自液態產品至通氣裝置上之沉澱作用。 發明之概要 本發明提供包容液態產品之容器。容器藉通氣裝置使液 態產品通氣。當容器内壓力異於周圍壓力時，通氣裝置容 許氣體在容器外方與内部之間通過。通氣裝置可滲透氣體 -5- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） ---------批衣---^---^11------.線 (請先閱讀背面之注意事項£.^寫本頁) 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（3 ) 但不滲透液態產品。液態產品含有選自碳酸鹽，過碳酸鹽 ，過硼酸鹽及上述各物之混合物之固體粒子。固體粒子之 粒度不大於400 a m。 圖式之簡單説明 圖la、lb及lc爲根據本發明之包括通氣裝置之容器之不同 具體實例之側示斷面圖（部份顯示）。 圖2a至2c顯示量計根據本發明之與液態產品接觸之通氣 裝置之通氣能力之氣泡點試驗方法之順序。 發明之詳細説明 圖la至lc顯示一容器之一部份。本發明中''容器”一詞 涵蓋能包容液態產品之任何中空本體，及一封閉容器之 任何其他部份。此等其他部份可爲可取除式與容器接合 及容許封閉及開啓容器之一封閉件，例如一帽或蓋。較 佳者，封閉件以不滲漏方式接合容器。封閉件可爲旋置 或卡合式。此外，容器之封閉件可爲轉動頂部，推拉或 轉動帽式封閉件。 圖la爲一容器之側視斷面圖，容器（10)(僅部份顯示）包 括中空本體（11)。中空本體包括邊壁（18)及底壁（未示於圖 la)。容器亦包括封閉容器之頂壁（17)。中空本體能包容任 何液態產品。較佳者，中空本體具有可響應發生於容器 内與周圍壓力之壓力差而變形之撓性程度。本發明亦包 括例如薄塑膠材料製成之袋。容器之適宜形狀可包括圓 筒形，斜縮圓筒形、橢圓形、正方形、長方形或扁平橢 圓形。 -6 - 本紙張尺度適用中國國家標準（CMS ) Α4規格（210 X 297公釐） ----------批衣------Γ.π------^ (請先閲讀背面之注意事項3 寫本頁) -ΓΧ ______________________ 五、發明説明（4 A7 B7 經濟部中央標準局員工消費合作社印製 本發明之較佳具體實例中，容器（10)包括一嘴。較佳者 ，容器爲塑膠、金屬、紙、或此等材料组合之層、層疊 物或共擠製物製成。材料亦可再循環。容器及其零件之 較佳材料包括塑膠如聚乙晞（高或低密度），聚氣乙烯， 聚酯，聚對苯二醇乙二醇（=PET )，可擠製PET，聚丙烯， 聚碳酸酯及尼龍。此等塑膠可單獨或合併成共擠製物， 各層或層合物而使用。 另一基本特點，容器（10)包括通氣裝置。通氣裝置能平 衡容器内壓力與外方大氣壓力。因此，通氣裝置能避免 容器内過高壓力或過低壓力。通氣裝置容許所包容之產 品釋出之氣體自容器内逸出至容器外，或空氣自容器外進 入容器内。通氣裝置在容器處於直立位置時，位於所包容 產品之水平面上方的容器上方部份。氣體導致累積於容器 上方區域之過高或過低壓力。因此，便利氣體通至外方或 内方。 較佳者，通氣裝置包括至少一孔（21)及一隔膜（22)。孔連 接容器之内部與外方。具體言之，孔（21)容許氣體自容器 内部通至外方，或自外方至内方，使容器内壓力保持與 外方大氣壓力相同，或處於至少低於發生明顯容器變形 之壓力。孔可位於頂壁或側壁。另一種較佳選擇，孔爲 容器中空本體（11)之一分立部份之一部份，此分立部份能 固著或接合於中空本體上，例如一封閉件。孔之尺度應 適於氣體通過。 隔膜（22)覆蓋孔，及位於中空本體（11)之内盛物與在中空 請 先 閱 背 面 之 注 意 事 項 r I裝 頁 線 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（5 ) 本體（11)内部或外方之孔（21)之間。隔膜不滲透液體但可 滲透氣體。因此，隔膜能提供不滲透液體之遮斷層，同 時容許氣體通過。較佳者，隔膜可在容器内外間達5 χA7 B7 V. Description of the invention (Scope of the invention The present invention relates to a container including a ventilating device. Please read the note on the back of δ. I r I Background of the invention of the page mounting invention The container deforms in response to the pressure difference between the pressure in the closed container and the surrounding pressure The problem is well known in the packaging industry. This kind of container deformation is irreversible in some container materials, such as certain plastics or metals. Thin-walled flexible containers are particularly sensitive to this problem. Multiple factors of the pressure difference between the external parties. For example, the contents of the container may be chemically unstable, or may be subject to reaction with gases that may be in the head space of the container, or in certain specific cases, may interact with the container material The reaction itself occurs. Any chemical reactant involving the liquid contents can cause gas generation, resulting in excessive pressure in the container, or insufficient pressure in the container due to absorption of any headspace gas. The pressure between the line container pressure and the surrounding atmospheric pressure The pressure difference can also be obvious in the temperature during the filling and sealing of the container and the outside temperature during the transportation and storage. Simultaneous. Another possibility is that the difference between the ambient pressure when the container is filled and another ambient pressure in a different geographic location can cause a difference in force. Several solutions to poor valve systems. The proposed method also involves various vent caps that allow the pressure generated in the container to be released by gas escape. For example, FR-A-2 259 026, US-4 136 796 And DE-A-2 509 258 discloses an automatic vented closed container including a gas-permeable membrane covering an outer hole. The membrane is made of a liquid-impermeable but gas-permeable material. Therefore, the container may include a gas released to the outside Square without loss of non-leakage holes. Another example is EP-A-593 840, Jie-4-This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) Employees' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Printed A7 B7 V. Description of the invention (2) Shows a container containing a pressure-generating liquid. The container is made of a thermoplastic material including a microchannel network. This microchannel network is permeable to gas but not Permeate liquid. It has been found that if a liquid product contacts these membranes or the end of a microchannel, the membrane can lose at least part of its gas permeability. Specifically, it includes solid particles such as carbonates, percarbonates, and / Or the liquid product of perborate may not be completely discharged from the diaphragm to respond to the container. On the contrary, it is found that the micropores of the diaphragm are blocked by these solid particles precipitated from the liquid. In this case, the container may lose its ventilation capacity. Loss of ventilation The capacity causes the pressure difference between the inside and outside of the container that can deform the container. When a filled container is disturbed during transportation, the product splashes on the diaphragm can cause contact between the product and the diaphragm. The transportation process was found to be The splash that occurs normally in the medium is sufficient to completely interrupt the ventilation capacity of the container. Another way the product can reach the septum is to store the container upside down. It was further discovered that other ventilation systems, such as valves, can also have the same disadvantages. As mentioned earlier, one of the important parameters that affects the membrane's ventilating ability is that the product contacting the membrane can precipitate out some solid particles suspended in the product. Therefore, it is an object of the present invention to provide a container for containing a liquid product containing solid particles. The container is vented by a ventilating device, thereby actually reducing the precipitation of solid particles from the liquid product to the venting device. SUMMARY OF THE INVENTION The present invention provides a container for containing a liquid product. The container is vented to the liquid product by a venting device. When the pressure inside the container is different from the surrounding pressure, the venting device allows gas to pass between the outside and inside of the container. Ventilation device can permeate gas-5- This paper size is applicable to China National Standard (CNS) A4 specification (210X 297 mm) --------- batch clothes --- ^ --- ^ 11 ---- -. Line (please read the notes on the back of this page. £. ^ Write this page) A7 B7 printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (3) but impermeable to liquid products. The liquid product contains solid particles selected from the group consisting of carbonate, percarbonate, perborate, and mixtures of the foregoing. The particle size of the solid particles is not more than 400 a m. Brief Description of the Drawings Figures la, lb and lc are side sectional views (partially shown) of different specific examples of a container including a ventilation device according to the present invention. Figures 2a to 2c show the sequence of the bubble point test method for the ventilation capacity of a gas meter in contact with a liquid product in accordance with the present invention. Detailed description of the invention Figures 1a to 1c show a part of a container. The term "container" in the present invention encompasses any hollow body capable of containing a liquid product, and any other part of a closed container. These other parts may be one of the removable types that engage the container and allow the container to be closed and opened. A closure, such as a cap or lid. Preferably, the closure engages the container in a leak-proof manner. The closure can be a swivel or snap-on type. In addition, the closure of the container can be a rotating top, a push-pull or a rotating cap-type closure Figure la is a side cross-sectional view of a container. The container (10) (only partially shown) includes a hollow body (11). The hollow body includes a side wall (18) and a bottom wall (not shown in Figure la). The container also includes the top wall (17) of the closed container. The hollow body can contain any liquid product. Preferably, the hollow body has a degree of flexibility that can deform in response to a pressure difference occurring between the container and the surrounding pressure. The invention also includes For example, a bag made of a thin plastic material. Suitable shapes for the container may include cylindrical, tapered cylindrical, oval, square, rectangular, or flat oval. -6-This paper size applies to Chinese national standards (CMS ) Α4 size (210 X 297 mm) ---------- batch of clothes ------ Γ.π ------ ^ (Please read the note on the back first 3 Write this page ) -ΓΧ ______________________ 5. Description of the invention (4 A7 B7 The preferred embodiment of the present invention printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, the container (10) includes a mouth. Preferably, the container is plastic, metal, paper , Or layers, laminates or coextrusions of these material combinations. Materials can also be recycled. Preferred materials for containers and their parts include plastics such as polyethylene (high or low density), polyethylene gas, Polyester, polyethylene terephthalate (= PET), can be extruded PET, polypropylene, polycarbonate and nylon. These plastics can be used alone or combined into co-extruded products, each layer or laminate Another basic feature is that the container (10) includes a ventilation device. The ventilation device can balance the pressure inside the container with the external atmospheric pressure. Therefore, the ventilation device can avoid excessively high or low pressure in the container. The ventilation device allows the contained products The released gas escapes from the container to the outside of the container, or air enters the container from the outside of the container. Inside. When the container is in the upright position, the part above the container above the level of the contained product. Gas causes excessive or low pressure to accumulate in the area above the container. Therefore, it is convenient for the gas to pass to the outside or inside. Preferably, the ventilation device includes at least one hole (21) and a diaphragm (22). The hole connects the inside and the outside of the container. Specifically, the hole (21) allows gas to pass from the inside of the container to the outside, or from From the outside to the inside, keep the pressure inside the container the same as the external atmospheric pressure, or at least lower than the pressure at which significant container deformation occurs. The hole can be located on the top wall or the side wall. Another preferred option is the hollow body of the container ( 11) A part of a discrete part that can be fixed or joined to a hollow body, such as a closure. The size of the holes should be suitable for gas passage. The diaphragm (22) covers the hole, and the contents inside the hollow body (11) and the hollow. Please read the precautions on the back first. I Binding line This paper size applies to China National Standard (CNS) A4 size (210 X 297 mm) (%) A7 B7 printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (5) Inside or outside the hole (21) of the body (11). The diaphragm is impermeable to liquids but permeable to gases. Therefore, the diaphragm can provide a liquid-impermeable barrier while allowing gas to pass through. Better, the diaphragm can reach 5 χ between the inside and outside of the container
Pa(500 mbar)壓力差，更佳壓力差不滲透液體 。隔膜可爲一平面形表面，至少粗視時如此。隔膜亦可 包含可滲透氣體但不滲透流體之微通道網路，如Ep_A_593 840所説明。隔膜粗現可爲波浪形，如-曲折表面，此—例 中隔膜由與水平方向成不同斜度之數互相連接表面構成。 較佳者，隔膜（22)爲能製成可用以覆蓋孔（21)之薄層之任 何材料製成。隔膜必須可響應小溫度差而滲透氣流。較 佳者，隔膜應容許低達5 X 1〇4 pa (5〇 mbar)及更佳者5 X丨〇3 pa (5 mbar)壓力差之氣體流動。隔膜厚度爲選擇事項，但較佳 者在0.2 mm至2mm範圍。隔膜基本上能包括可製成薄層之 薄層之任何材料’例如具有微孔之塑膠、低或金屬。隔 膜足較佳材料包括微孔性塑膠膜。隔膜微孔尺度應容許 氣體在低壓力差通過’及同時提供高不滲透液體性。較 佳者，微孔在O·1 " m至5 " m範圍，更佳者〇.2；u m至1 " m之 間。隔膜宜爲圓形。但其他形狀如長方形、三角形或其 他形狀亦可用於容器或帽’以改善容器或帽本身之美觀 性0 此一用途之較佳微孔性塑膠膜爲： -不織塑膠膜，尤其Du Pont Company以品名TYVEK出售之 不織紡合聚乙烯膜材料，其中TYVEK, Style 1〇經氟碳化 合物處理而具有高不滲透流體性。 本紙張尺度適用中國國家標準（CNS > A4規格（210X297公釐） ：-------装----——h訂------痒 f請先閑讀背面之注意事項* 冩本艽) ___C. ;;::, 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（6 ) -Gelman Sciences Company, 600, South Wagner Road, Ann Arbor, Ml 48106，US以品名VERSAPOR出售之經疏水性氟單體物 後處理之不織支持物（尼龍或PET)上鑄製之丙烯共聚 物。 隔膜（22)之微孔膜材料可加處理減少其表面能，及因此 改良膜材料之不滲透流體性。當容器（10)包容包含表面作 用劑成分之產品時，尤其必須降低膜材料之表面能而改 善其不滲透性。較佳者，膜材料之比面能（surfactant surface energy)應低於含表面作用劑產品者，以達成對產品内盛物 之實質上完整不滲透性。較佳者，隔膜（22)具有對向容器 内液態產品之較液態產品更具疏水性之至少一表面。 涉及以微比例固定氟碳化合物於膜材料表面之氟碳化合 物處理爲提供減少表面能處理之一例。氟碳化合物處理 減少隔膜之微孔膜材料對液態產品内盛物之沾濕作用之 敏感性。例如，可用於根據本發明之氟碳化合物一 種氟碳化合物材料爲3M Company以品名SCOTCHBAN出售者 。然而，用以處理根據本發明之隔膜之微孔膜材料時， 氟碳化合物處理應不損及隔膜之氣體滲透性。 根據本發明，隔膜（22)可用保持其不滲透液體性及可滲 透氣體性之任何方法在内盛物與孔（21)之間加於中空本體 (11)之内部或外方。因此，施加裝置可包括使用膠粘劑， 或熱密合隔膜於環繞孔之區域上，或機械裝置如夾定或 熱衝壓，或在模製容器時嵌置隔膜。如前文所述，所採 用之施加裝置應不明顯減低隔膜之通氣能力。基於此一 -9- 本紙張尺度適用中國國家標準（CNS ) A4規格（2丨0>< 297公釐） II.-------裝---·--訂------線 If (請先閲讀背面之注意事項〆；寫本頁) -___________ 五 、發明説明（ 7 A7 B7 經濟部中央標準局員工消費合作社印製 原因’較佳者，所使用之任何膠粘劑亦可滲透氣體或不 填塞隔膜微孔。 如同在審查程序中之EP_A_{) 706 954所説明，隔膜（22)亦可 配置於一外套中。尺度可用於根據本發明之容器或帽之 外套爲 GVS，Via Roma 50, 40069, Zola Predosa (BO)，Italy 商業性出 售者。極佳具體實例中，外套之製造及配置隔膜（22)於外 套中能藉"嵌置模塑作業”達成，其中： •將一隔膜片送入一裝置，隔膜片係自一捲隔膜材料以 有利方式送入； •在裝置自片切下至少一隔膜，及置於將在其中 套之模具中； -然後’以固定隔膜於外套中之方式大致環繞隔 外套。”大致環繞"係指完成後，此步驟應產生 隔膜之外套。隔膜之二表面可接觸空氣，但隔 舍保持於外套中。 外套亦可藉將隔膜(22)熱密合，超音波密合或膠 套内而製成。此外，外套可藉將隔膜機械方式固 定在一起之二分立件之間而製成。 根據本發明之液態產品具有懸浮固體特性。液態 爲水成或非水成。非水成液態產品中，水量應不 液態產品重量計之約5 %，更佳者小於重量計約1 子液態產品在商業性銷售狀況下及使用產品時將 定相。此外，含粒子液態產品將較具粘性。通常 品粘度將爲約 0.3 Pa . s (300 cps)至 5 Pa . s (5000 q)s )之範 形成外 膜模製 配置有 膜被緊 钻於外 定於夾Pa (500 mbar) pressure difference, better pressure difference is impermeable to liquid. The diaphragm may have a flat surface, at least when viewed grossly. The membrane may also contain a network of microchannels that are permeable to gases but not permeable to fluids, as described in Ep_A_593 840. The diaphragm can be rough, such as-zigzag surface. In this example, the diaphragm is composed of surfaces connected to each other at different slopes from the horizontal direction. Preferably, the diaphragm (22) is made of any material that can be made into a thin layer that can be used to cover the hole (21). The diaphragm must be permeable to the air flow in response to small temperature differences. Better, the diaphragm should allow gas flow down to a pressure difference of 5 X 104 Pa (50 mbar) and more preferably 5 X 10 Pa (5 mbar). The thickness of the diaphragm is optional, but it is preferably in the range of 0.2 mm to 2 mm. The separator can basically include any material that can be made into a thin layer ', such as plastic, low or metal with microporosity. The preferred material for the diaphragm foot includes a microporous plastic film. The micropore size of the diaphragm should allow gas to pass through at a low pressure differential and at the same time provide high liquid impermeability. Preferably, the micropores are in the range of 0.1 m to 5 m, and more preferably 0.2 m to 1 m. The diaphragm should be round. But other shapes such as rectangles, triangles or other shapes can also be used in containers or caps to improve the aesthetics of the container or cap itself. The preferred microporous plastic film for this purpose is:-Non-woven plastic film, especially Du Pont Company Non-woven spun polyethylene film material sold under the trade name TYVEK. Among them, TYVEK, Style 1 is treated with fluorocarbon and has high fluid-impermeable properties. This paper size applies to Chinese National Standards (CNS > A4 size (210X297 mm): ------- installation -------- h-order ------ itching please read the note on the back first Matters * 冩 本 艽) ___C. ;; ::, printed by A7 B7, Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of Invention (6)-Gelman Sciences Company, 600, South Wagner Road, Ann Arbor, Ml 48106, US A propylene copolymer cast on a non-woven support (nylon or PET) after treated with a hydrophobic fluorine monomer sold under the name VERSAPOR. The microporous membrane material of the membrane (22) can be treated to reduce its surface energy, and thus improve the fluid impermeability of the membrane material. When the container (10) contains a product containing a surface-active ingredient, it is particularly necessary to reduce the surface energy of the film material to improve its impermeability. Preferably, the specific surface energy of the membrane material should be lower than that of a product containing a surfactant to achieve substantially complete impermeability to the contents of the product. Preferably, the diaphragm (22) has at least one surface of the liquid product in the opposing container which is more hydrophobic than the liquid product. One example of a treatment that provides a reduction in surface energy is a fluorocarbon compound treatment that involves fixing a fluorocarbon compound to the surface of a film material in a micro-scale. Fluorocarbon treatment reduces the sensitivity of the membrane's microporous membrane material to the wetting of liquid contents. For example, a fluorocarbon material that can be used in accordance with the present invention is a fluorocarbon material sold by 3M Company under the trade name SCOTCHBAN. However, when treating a microporous membrane material of a separator according to the present invention, the fluorocarbon treatment should not impair the gas permeability of the separator. According to the present invention, the diaphragm (22) can be added to the inside or outside of the hollow body (11) between the inner container and the hole (21) by any method that maintains its liquid-impermeable and gas-permeable properties. Therefore, the application means may include the use of an adhesive, or heat-sealing the diaphragm over the area surrounding the hole, or mechanical means such as clamping or hot stamping, or embedding the diaphragm when molding the container. As mentioned earlier, the application device used should not significantly reduce the venting capacity of the diaphragm. Based on this -9- this paper size applies Chinese National Standard (CNS) A4 specifications (2 丨 0 > < 297 mm) II .------------------- --Line If (please read the precautions on the back first; write this page) -___________ V. Description of the invention (7 A7 B7 Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economics' Better printing, any adhesives used are also Gas permeable or non-filled diaphragm pores. As described in EP_A_ {) 706 954 in the review process, the diaphragm (22) can also be arranged in a jacket. Scales A jacket or container that can be used in accordance with the present invention is GVS, Via Roma 50, 40069, Zola Predosa (BO), Italy, a commercial seller. In an excellent specific example, the manufacture and configuration of the outer membrane (22) in the outer shell can be achieved by " embedding molding operation ", in which: • a diaphragm is fed into a device, and the diaphragm is made from a roll of diaphragm material Feed it in an advantageous manner; • Cut at least one diaphragm from the piece of the device, and place it in a mold that will be placed in it;-then 'around the diaphragm casing in a manner that fixes the diaphragm in the casing. " After the finger is completed, this step should produce a diaphragm sheath. Both surfaces of the diaphragm can be exposed to air, but the compartment is held in the jacket. The outer jacket can also be made by heat-sealing the diaphragm (22), supersonic sealing or inside a rubber sleeve. In addition, the jacket may be made by mechanically securing the diaphragm between two discrete pieces. The liquid product according to the invention has the characteristics of suspended solids. Liquid is either aqueous or non-aqueous. In non-aqueous liquid products, the amount of water should not be about 5% by weight of the liquid product, and more preferably less than about 1 weight of the liquid product. It will be phased under commercial sales conditions and when the product is used. In addition, liquid products containing particles will be more viscous. Usually the viscosity of the product will be in the range of about 0.3 Pa. S (300 cps) to 5 Pa. S (5000 q) s.
請 先 閲 讀 背 之 注 意 事 項 本 頁 -10 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ------ 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（8 ) 佳者約0.5 Pa . s (500 cps)至3 Pa . s (3000 cps )。爲達成本發明之 目的，粘度係在約20°C溫度以採用50 rpm RV #5心軸之布魯 克菲德枯度計（Brookfield Viscometer)量計。 當所包容之液態產品每觸隔膜（22)時，通氣裝置之通氣 性能可被實質上減低。且體言之，此一情況在液態產品 含有懸浮於其中之固體粒子時發生。根據本發明之固體 粒子選自碳酸鹽，過碳酸鹽，過硼.酸鹽及上述各物之混合 物。如前文所説明，隔膜爲通氣裝置之最曝露於所包容產品 之部份。容器内產品與隔膜間之接觸主要可由於輸送過程中 攪動容器所致之潑濺而發生，本説明中使用之"潑濺係指容 器内液體被攪動時，液態物質與一表面之非連，短暫接觸。 所包容之液態產品潑濺情況主要在攪動容器可能性較高之輸 * 送過程中發生。 經發現含有懸浮固體粒子之液態產品接觸隔膜(22)時，隔 膜可失去其氣體滲透性。根據本發明之懸浮於液態產品 中之固體粒子可自產品沉澱及沉積於隔膜上。此一情況 下，隔膜或其部份可被自液態產品沉澱出之固體粒子覆 蓋，亦即隔膜之通氣性能由於部份隔膜被自液體沉澱出 後未排離隔膜之根據本發明之固體粒子堵塞而減低。結 果，容器之通氣能力減小或喪失。 所包容液態產品與隔膜（22)間接觸主要在輸送容器過程 中發生。容器被擾動時，液態產品潑濺至容器内隔膜上 ，經發現輸送過程中一般發生之潑濺是足以完全遮斷容 器之通氣能力。產品可接觸隔膜之另一情況爲倒立貯放 -11 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） I:-------裝---'--^-訂------線—ί (請先閱讀背面之注意事項Η :寫本頁) --f、 __________ 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） A7 ~~----- B7 五、發明説明（9 ) '— - 容器時。進一步發現他種通氣系統例如閥亦可具有相同 缺點。 自隔膜除去潑濺產品之一種可能方法爲刮削潑濺有產品 之隔膜表面。經發現自隔膜表面刮除潑濺產品後，恢復 <隔膜通氣能力足以防止明顯容器變形。表面刮削可用 例如鏟形式是裝置達成。然而，解決本發明問題之此種 方法具有二主要缺點。第一，刮削作用必須由使用者用 手進行而不適宜’或藉複雜且成本高之容器内機械式活 動装置進行。第二，自隔膜刮削潑濺產品之動作可能傷 及隔膜’尤其隔膜之不滲透液體性易於因刮削而喪失。 第二’如果隔膜之表面微孔内部阻塞，刮削作用亦無效。 同在審查程序中之國際專利申請案PCT/US 96/01610提供具 有包括保護裝置之通氣裝置之容器。保護裝置保護通氣 裝置不遭受潑濺產品，例如具有配置於產品與通氣裝置 間之壁。國際專利申請案PCT/US 96/01610中説明之保護裝 置之全部具體實例引述於本説明供參考。 另一種方式，同在審查程序中之歐洲專利申請案 95104281.1提供其中無任何通氣裝置刮削作用之潑濺產品 自動排離通氣裝置之容器。此方法包括將通氣裝置定位 於與支持容器於直立位置之平面成一斜度或垂直平面中 ，如圖lb所示，另一種方式，裝置包括連接於通氣裝置 並伸出之排出裝置（23)，如圖lc所示。排出裝置亦可與支 持容器於直立位置之平面成一斜度或成直交。前述審查 中之國際及歐洲專利申請案能用於根據本發明之容器， -12- *--- . ^ 裝 訂 線 (請先閎讀背面之注意事項1^;寫本頁} 五、發明説明（10 ) A7 B7 經濟部中央標準局員工消費合作社印製 以防止通氣裝置之通氣能力減低。上述歐洲專利申請案 95104281.1説明之排出裝置之具體實例引述於本説明中供參 考。 經發現通氣能力損失係視懸浮固體粒子自液態產品沉澱 於隔膜而減低通氣能力之趨向而定。決定懸浮固體粒子 自液態產品沉澱之留向之主要因數爲固體粒子之最大粒 度。如果懸浮於液態產品中固體粒子之最大粒度大於400 μιη時，固體粒子在潑濺產品排回至容器内之前自液態產 品沉澱於隔膜上。自液態產品沉澱之固體粒子可堵塞隔 膜而減低隔膜本身之通氣能力。 如果懸浮於液態產品中固體粒子之最大粒度小於約400 μιη時，固體粒子多半保持懸浮於液態產品中，直至液態 產品被排回至容器内。因此，根據本發明，懸浮於液態 產品中之固體粒子之最大粒度小於約400 μιη，較佳者小於 約200 μπι，更佳者小於約150 μπι，最佳者小於約100 μιη。爲 獲致減小最大粒度之固體粒子，此等固體粒子可經篩分 及/或予以研磨，然後，將根據本發明之減小最大粒度之 固體粒子加至液態產品。 · 上述各次以下述各實例顯示。下文中，"微量物”爲組 成或產品中選用成分，如水、穩定劑、钮合劑（Chelating agent)基清除劑、表面作用劑、潔白活化劑、組合劑、污 垢懸浮劑（soil suspenders)、染料轉移劑、容劑、增亮劑、香 料、泡沫抑制劑、染料、及上述各物之合併物。 -13- 本纸張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 請 先 閱 背 i 事 項 本衣 頁 訂 線 五、發明説明（η ) A7 B7 實例I及11 成 偷 實例I 實例II 重量百分 重量百分 C12-14烷基乙氧基(3X)硫酸鈉 18.3 18.3 C12-14烷基葡萄糖醯胺 8.1 8.1 C12-14醇羥乙基鹽 16.8 16.8 丁氧基丙氧基丙醇 14.3 14.3 四分之一聚羥氧基化乙撑二胺氣鹽 2 2 祝基二乙基棒樣酸鹽 10.4 10.4 碳酸鈉 8.0 8.0 過碳酸鹽 10.0 0.0 過硼酸鹽 0.0 10.0 微量物 12.1 12.1 碳酸鈉，過碳酸鹽及過硼酸鹽均爲液態產品中懸浮固體 成分。實例I中約1.5%碳酸鈉固體粒子及約1.5 %過碳酸鹽 固體粒子具有大於400 " m之最大粒度。實例II中約1.5 %碳 酸鈉固體粒子及約1.5 %過硼酸鹽固體粒子具有大於400 a m之最大粒度。 I J 裝 訂 0 (請先閱讀背面之注意事項本頁) 經濟部中央標隼局員工消費合作社印製 -14- 本纸張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 經濟部中央標準局員工消费合作社印製 A7 B7 五、發明説明（12 )Please read the note on the back page-10-This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) ------ Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Note (8) The best is about 0.5 Pa.s (500 cps) to 3 Pa.s (3000 cps). For the purposes of this invention, the viscosity is measured at a temperature of about 20 ° C using a Brookfield Viscometer using a 50 rpm RV # 5 mandrel. When the contained liquid product touches the diaphragm (22), the ventilation performance of the ventilation device can be substantially reduced. And, to put it in a nutshell, this happens when the liquid product contains solid particles suspended in it. The solid particles according to the present invention are selected from the group consisting of carbonates, percarbonates, perborates, acid salts and mixtures of the foregoing. As explained earlier, the diaphragm is the most exposed part of the ventilation device to the contained product. The contact between the product in the container and the diaphragm can mainly occur due to splashes caused by agitating the container during transportation. The "spatter" used in this description refers to the non-connection of the liquid substance to a surface when the liquid in the container is agitated. , Brief contact. The containment of liquid product spills occurs mainly during the transfer process, which is more likely to agitate the container. It has been found that when a liquid product containing suspended solid particles comes in contact with the diaphragm (22), the diaphragm can lose its gas permeability. The solid particles suspended in a liquid product according to the present invention can be precipitated from the product and deposited on a membrane. In this case, the diaphragm or a part thereof may be covered by solid particles precipitated from the liquid product, that is, the ventilation performance of the diaphragm is due to the clogging of a part of the diaphragm by the solid particles according to the present invention that do not leave the diaphragm after precipitation from the liquid And reduced. As a result, the ventilation capacity of the container is reduced or lost. The contact between the contained liquid product and the diaphragm (22) occurs mainly during the transportation of the container. When the container is disturbed, the liquid product splashes on the inner diaphragm of the container. It is found that the splash that generally occurs during transportation is sufficient to completely block the ventilation capacity of the container. Another situation where the product can contact the diaphragm is storage upside down-11-This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) I: ------- install ---'-- ^- Order ------ line--ί (please read the notes on the back Η: write this page) --f 、 __________ Printed on paper standards of the China National Standards Administration (CNS) A4 Specifications (210X297 mm) A7 ~~ ----- B7 V. Description of the invention (9) '--When the container. It was further found that other ventilation systems, such as valves, have the same disadvantages. One possible method of removing spattered products from the membrane is to scrape the surface of the membrane with the product spattered. It was found that after the splattered product was scraped off the surface of the diaphragm, the recovery of the diaphragm's ventilation capacity was sufficient to prevent significant container deformation. Surface scraping can be achieved, for example, with a device in the form of a shovel. However, this method of solving the problems of the present invention has two main disadvantages. First, the scraping action must be performed by the user's hands, which is unsuitable 'or by a complicated and expensive mechanical movement device in the container. Secondly, the action of scraping the spattered product from the diaphragm may damage the diaphragm ', especially the liquid-impermeable property of the diaphragm, which is easily lost by the shaving. Second, if the micropores on the surface of the diaphragm are blocked, the scraping effect is also ineffective. The international patent application PCT / US 96/01610, which is also in the examination process, provides a container with a ventilation device including a protective device. The protective device protects the ventilation device from splashing products, for example, having a wall disposed between the product and the ventilation device. All specific examples of protection devices described in the international patent application PCT / US 96/01610 are cited in this description for reference. Alternatively, European Patent Application No. 95104281.1, which is also in the examination process, provides a container in which the spattered product without any scraping effect of the venting device is automatically discharged from the venting device. The method includes positioning the ventilating device in an inclined or vertical plane with a plane supporting the container in an upright position, as shown in FIG. 1b. In another way, the device includes a venting device (23) connected to the venting device and extending, As shown in Figure lc. The discharge device may also be inclined or orthogonal to the plane supporting the container in the upright position. The aforementioned international and European patent applications under review can be used for containers according to the present invention, -12- * ---. ^ Gutter (please read the notes on the back 1 ^; write this page} 5. Description of the invention (10) A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs to prevent a decrease in the ventilation capacity of the ventilation device. Specific examples of the discharge device described in the aforementioned European Patent Application 95104281.1 are cited in this description for reference. It was found that the loss of ventilation capacity It depends on the tendency of the suspended solid particles to precipitate from the liquid product in the diaphragm and reduce the ventilation capacity. The main factor that determines the retention direction of the suspended solid particles from the liquid product is the maximum particle size of the solid particles. If the suspended solid particles in the liquid product When the maximum particle size is greater than 400 μιη, solid particles settle on the diaphragm from the liquid product before the splashed product is discharged back into the container. The solid particles precipitated from the liquid product can block the diaphragm and reduce the breathability of the diaphragm itself. If suspended in the liquid product When the maximum size of the solid particles is less than about 400 μm, most of the solid particles remain suspended in the liquid. Until the liquid product is returned to the container. Therefore, according to the present invention, the maximum particle size of the solid particles suspended in the liquid product is less than about 400 μm, preferably less than about 200 μm, and more preferably less than about 150 μπι, preferably less than about 100 μιη. In order to obtain solid particles with reduced maximum particle size, these solid particles can be sieved and / or ground, and then the solid particles with reduced maximum particle size according to the present invention are added to Liquid products. · The above examples are shown by the following examples. In the following, "trace" is the composition or selected ingredients in the product, such as water, stabilizer, chelating agent-based scavenger, surfactant, and whitening activation. Agents, combination agents, soil suspenders, dye transfer agents, bulking agents, brighteners, fragrances, foam inhibitors, dyes, and combinations of the above. -13- This paper is applicable to China Standard (CNS) A4 specification (210X297 mm) Please read back i. Binding of this page. 5. Description of the invention (η) A7 B7 Example I and 11 Stolen Example I Example II Weight percent C12-14 alkyl ethoxy (3X) sodium sulfate 18.3 18.3 C12-14 alkyl glucosamine 8.1 8.1 C12-14 alcohol hydroxyethyl salt 16.8 16.8 Butoxypropoxypropanol 14.3 14.3 One quarter polyhydroxyoxylated ethylenediamine gas salt 2 2 Benzyl diethyl rodate 10.4 10.4 Sodium carbonate 8.0 8.0 Percarbonate 10.0 0.0 Perborate 0.0 10.0 Traces 12.1 12.1 Sodium carbonate Percarbonate and perborate are suspended solids in liquid products. In Example I, about 1.5% of the sodium carbonate solid particles and about 1.5% of the percarbonate solid particles have a maximum particle size of more than 400 m. About 1.5% of sodium carbonate solid particles and about 1.5% of perborate solid particles in Example II had a maximum particle size of greater than 400 a m. IJ Binding 0 (Please read the note on the back page first) Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs -14- This paper size applies to China National Standard (CNS) A4 (210X 297 mm) Central Printed by the Consumer Bureau of Standards Bureau A7 B7 V. Invention Description (12)
實例ΙΠ及IV 成 份 實例III 實例IV 重量百分 重量百分 三聚嶙酸納 25 25 碎酸納 5 5 羧曱基纖維素 1 1 二氧化献 1 1 乙二胺四醋酸 1 1 聚乙二醇(分子量200) 40 40 醇羥基鹽 10 10 過硼酸鈉 10 0.0 過碳酸鈉 0.0 10 碳酸鈉 5 5 微量物 2 2 實例III之液態產品中懸浮固體成份之碳酸鈉及過硼酸鹽 之最大粒度經過篩獲得200 " m與400 " m間之最大粒度分 配。實例IV之碳酸鈉及過碳酸鹽小於100 v m。 下文説明用以量計上述各具體實例之液態產品後之隔膜 通氣能力之試驗。如圖2a至2c所示，Versapor® V800R之一隔 膜封閉圓柱形管（41)之開敞端部。隔膜包括對向圓柱形管 内部之内表面（42)，相反之外表面（43)完全位於圓柱形管 外。用液態產品（44)重複潑濺隔膜，使液態產品留在内表 -15- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 訂 線 (請先閲讀背面之注意事項本頁) 399022五、發明説明（u ) A7 B7 經濟部中央標準局員工消費合作社印製 面上經1分鐘。然後，倒轉内表面向下，任所潑濺之液態 產品排離隔膜經24小時。最後，24小時排離後，用氣泡 點方法量計通氣壓力。 上述”氣泡點方法"包括下列步驟： -在封閉圓柱形管（41)之開敞端部之隔膜外表面（43)上放 置一薄層水； -以每分鐘100 mbar速率增加管中壓力； -記錄發生氣泡通過隔膜時之壓力。所檢測之壓力爲上 述通氣壓力。 將氣泡點方法量計之壓力與通氣裝置之通氣能力相關 聯。所量計之壓力愈高，通氣能力愈低。反之，所量計 之壓力愈低，通氣能力愈高。 下表顯示實例I至IV之液態產品之通氣能力量計結果。 實例 I > 200 mbar 實例 II > 200 mbar 實例 III 30-60 mbar 實例 IV 30-60 mbar 自上表可明瞭，包含最大粒度大於400 a m之固體粒子之 實例I及II之液態產品顯示實質上減底之通氣能力。然而 ，根據本發明減小固體粒子之最大粒度時，如實例III及 IV，充分保持隔膜之通氣能力。 -16 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 請 先 閲 讀 背 之 注 項 r I裝 頁 訂 線Examples III and IV Ingredients Example III Example IV Weight percent by weight Sodium trimeric sodium 25 25 Sodium tricarboxylic acid 5 5 Carboxyl cellulose 1 1 Dioxin 1 1 Ethylenediamine tetraacetic acid 1 1 Polyethylene glycol (Molecular weight 200) 40 40 Alcoholic hydroxy salt 10 10 Sodium perborate 10 0.0 Sodium percarbonate 0.0 10 Sodium carbonate 5 5 Traces 2 2 The maximum particle size of sodium carbonate and perborate suspended solids in the liquid product of Example III were sieved Get the largest granularity allocation between 200 " m and 400 " m. The sodium carbonate and percarbonate of Example IV are less than 100 v m. The following is a test of the air permeability of the diaphragm after measuring the liquid products of the above specific examples. As shown in Figures 2a to 2c, a diaphragm of Versapor® V800R closes the open end of the cylindrical tube (41). The diaphragm includes an inner surface (42) facing the inside of the cylindrical tube, and an opposite outer surface (43) located entirely outside the cylindrical tube. The liquid product (44) is repeatedly splashed on the diaphragm to keep the liquid product inside. Table-15- This paper size applies to China National Standard (CNS) A4 (210X297 mm). Threading (Please read the precautions on the back page first) ) 399022 V. Description of the invention (u) A7 B7 Printed on the surface of the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy for 1 minute. Then, invert the inner surface downward, and let the liquid product splashed out of the diaphragm for 24 hours. Finally, after 24 hours of venting, the bubble pressure method was used to measure the ventilation pressure. The above "bubble point method" includes the following steps:-placing a thin layer of water on the outer surface (43) of the diaphragm at the open end of the closed cylindrical tube (41);-increasing the pressure in the tube at a rate of 100 mbar per minute -Record the pressure when the bubble passes through the diaphragm. The detected pressure is the above-mentioned ventilation pressure. The pressure of the bubble point meter is related to the ventilation capacity of the ventilation device. The higher the measured pressure, the lower the ventilation capacity. Conversely, the lower the gauge pressure, the higher the ventilation capacity. The following table shows the results of the ventilation capacity meter for liquid products of Examples I to IV. Example I > 200 mbar Example II > 200 mbar Example III 30-60 mbar Example IV 30-60 mbar As can be seen from the table above, the liquid products of Examples I and II containing solid particles with a maximum particle size greater than 400 am show a substantially reduced bottoming capacity. However, the maximum particle size of solid particles is reduced according to the present invention At the time, such as examples III and IV, fully maintain the diaphragm's ventilation capacity. -16-This paper size is applicable to China National Standard (CNS) A4 specifications (210X 297 mm) Please read the note at the back first r I Binding