TW392059B - Process and apparatus for evaporating liquid oxygen - Google Patents

Process and apparatus for evaporating liquid oxygen Download PDF

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Publication number
TW392059B
TW392059B TW88101277A TW88101277A TW392059B TW 392059 B TW392059 B TW 392059B TW 88101277 A TW88101277 A TW 88101277A TW 88101277 A TW88101277 A TW 88101277A TW 392059 B TW392059 B TW 392059B
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Taiwan
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evaporator
flushing
liquid
oxygen
auxiliary
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TW88101277A
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Chinese (zh)
Inventor
Franz Habicht
Gerhard Pompl
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Linde Ag
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Description

A7 B7 五、發明説明(,) 發明説明 本發明俗關於一種蒸發液態氧的方法及其在以空氣之 低溫分餾製造氣之方法中之用途。 在本申請案中,氣表示具有高於相對空氣之氣含量之 仟何混合物,例如,至少70S:,較佳為至少98¾。(在本申 請案中,所有之百分比表示莫耳量,除非明確地另有指 示。)其特別包括不純氣,及工業级純氣與具有99.99X 或以上之純度之高純度氣。對於許多應用,需要在使用 前藉由在主蒸發器中以使用熱載體之間接熱交換蒸發之 ,而將存在之液態氧轉化成氣醱形式。 此型蒸發特別發生於、氣態氣藉低溫精餾之製造,其中 氣産物在精餾管柱底部以液態狀態發生,因為其比氮與 氬較不揮發性。為了使精皤管柱得到氣體形式之産物及 産生升起之蒸氣,以液態狀態發生之氧必須在主蒸發器 中類似地蒸發。在此最廣為流傳為古典Linde雙管柱法, 其中主蒸發器配置於低壓管柱之底部及以來自壓力管柱 頂部之冷凝氣操作(參見Hausen/Linde之Tiefteaperat-111'16(^11〗11[低溫工程],第2版,在第284頁之第4.1.2 之部份)。在此情形中之主蒸發器如冷凝器-蒸發器操作 及經常稱為主冷凝器。其亦藉一或更多値如循環或降膜 蒸發器而操作之熱交換區而實行。 本發明亦關於其他之雙管柱方法,例如,其中主蒸發 器以空氣操作,及具有三或更多個氮-氧分離^客Ιϋ法 。氮-氣分離精餾管柱之下游可流„接„製造其他空氣成份之 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) (請先閲讀背面之注意事項再ί本頁) -裝_ 訂. 經濟部智慧財產局員工消費合作社印製 經濟部中央橾準局貝工消費合作社印製 A7 _B7___ 五、發明説明(> ) 装置,特別是貴簠氣體•例如,氣製造。 如果液態《完全或本霣上完全蒸發•較少之揮發性雄 霣,例如,如(:02或》<20 ·在蒸發器中累積,即使逭些_ 霣在被蒸發之氣(或被分籲之空氣)中僅以非常低之濃度 存在(然而.早期令人擄心之乙炔在以吸附預備鈍化之 空氣分鐳設備中不再是問臛)° 一些逭些較不揮發性物 質,例如,C〇2或4〇·可如固體沈濺及必須偶而移除, 以《免主蒸發器中热交換器通路之砠塞。為了移除埴些 分離之固*,全艚設備必須鼸機。在大型空氣分籲設備 中,例如,其表示二至五日之停止作莱。 為了降低較不揮發性成份之累稹,習憒上連績地成偁 而自主蒸發器取出一些沖洙流形式之液體,及丢索此流 。較不揮發性成份隴此沖洙體積一起在保持液戆狀態之 中氣中累積,使其在主蒸發器中之濺度受限。在从吸附 預備纯化之空氣分鏞設備中,沖洗體積習慣上為引入蒸 發器之液態氧纗量之0.02至0.04X。對於精餾之空氣«化 上流,因為巳使用分子篩吸收器取代先前使用之返復式 热交換器(Revex)或再生器,由於可燃性較不揮發性成份 在此型氧蒸發器(主蒸發器)中之累檐引起之間題已降低 至此型沖洗流足以防止有害濃度之烴而不需要額外拥量 之程度(參見 Hausen/Linde之 Tieftenperaturtechnik[ 低湛工程],第2版,在第312與313頁之第4.5.1.5部份)。 本發明之目的為增加主蒸發器蒸發液態氧之可用性, 及特別地,儘可能地防止對操作之中斷。 -4 - 本紙張尺度適用中國固家標準(〇阳)八4規格(2丨0父2-97公釐厂、 ------^----------—訂 (請先閱讀背面之注意事項再填寫本頁) A7 B7 經濟部智慧財產局員工消費合作杜印製 五、發明説明( ) 1 1 此 S 的 由 Φ 請 專 利 範 圍 第 1 項 之 特 點 完 成 〇 其 中 $ 白 1 主 m 發 器 取 出 之 (第- -)沖洗流送至 主 蒸 發 器 分 離 配 置 之 1 輔 肋 蒸 發 器 〇 在 此 輔 肋 蒸 發 器 9 大 部 份 之 第 一 沖 洗 流 蒸 請 1 1 I 發 及 因 此 可 製 造 成 氣 産 物 或 中 間 産 物 氣 産 生 〇 其 次 > 白 先 閲 1 讀 1 1 輔 肋 蒸 發 器 取 出 第 二 冲 洗 流 及 丢 棄 〇 (在由液態氧製造 背 面 I 之 1 氪 及 /或氙之待別情形中, 需要進- •步作業。 )第 - 冲 洗 注 意 1 流 連 缠 地 由 主 蒸 發 器 送 至 輔 肋 蒸 發 器 9 而 第 二 沖 洗 流 可 事 項 1 I 1 連 纊 地 或 分 批 取 出 〇 f 本 裝 在 本 發 明 中 ,可自主蒸發器取出如第- -沖洗流之相當大 頁 1 量 之 液 體 5 使 得 可 排 出 所 有 之 較 不 揮 發 性 成 份 及 其 在 主 1 1 蒸 發 器 中 之 濃 度 可 保 持 低 〇 特 別 地 * 在 主 蒸 發 器 中 不 發 1 I 生 固 體 沈 積 Ο 然 而 此 大 體 積 之 沖 洗 液 體 並 非 兀 全 流 失 1 , 因 為 __‘ 些 第 一 沖 洗 流 在 輔 肋 蒸 發 器 中 蒸 發 及 以 氣 體 形 1 丁 1 式 取 出 〇 由 輔 助 蒸 發 器 取 出 僅 習 慣 上 如 第 — 冲 洗 流 之 沖 1 I 洗 體 積 9 例 如 引 入 主 蒸 發 器 之 液 態 氣 量 之 0 - 02至 0 . 5% 1 1 9 較 佳 為 0 . 0 2至 0 . 2%〇 (在分批取出第二沖洗流之情形, 1 1 百 分 tb 指 時 間 平 均 〇 )其餘之第- -沖洗流在辅助蒸發器 線 | 中 蒸 發 及 可 如 氣 態 氧 産 物 而 利 用 Ο 1 1 使 用 本 發 明 可 密 集 地 沖 洗 主 蒸 發 器 9 使 得 可 能 造 成 固 1 | 體 沈 積 之 較 不 揮 發 性 成 份 之 含 量 保 持 極 低 Ο 較 不 揮 發 性 1 I 成 份 完 全 送 至 輔 肋 蒸 發 器 及 經 第 二 沖 洗 流 與 偶 而 操 作 之 1 1 加 熱操作去除 〇 1 I 固 體 沈 積 因 此 僅 發 生 在 輔 肋 蒸 發 器 中 , 而 非 主 蒸 發 器 1 1 0 然 而 9 輔 肋 蒸 發 器 可 藉 加 熱 5- 遠 tb 主 蒸 發 器 簡 αο 早 地 清 除 1 1 1 1 1 1 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明( 4* ) 1 1 固 髓 〇 為 此 g 的 正 常 操 作 偁 而 被 加 热 搡 作 中 斷 在 加 1 1 I 热 搡 作 中 » 與 主 蒸 發 器 分 離 之 輔 肋 蒸 發 器 無 液 tt 白 主 蒸 1 1 發 器 送 至 m 肋 蒸 發 器 中 0 同 時 • _ 肋 蒸 發 器 升 至 顯 著 地 /·—S 請 1 1 比 其 在 正 常 操 作 高 » 例 如 至 少 20K , 較佳為20至50Κ之 閲 背 1 溫 度 之 溫 度 〇 主 蒸 發 器 及 其 所 安 裝 之 設 備 之 操 作 在 此 方 之 法 中 不 需 要 中 斷 〇 由 於 主 蒸 發 器 之 強 烈 沖 洗 f 其 不 再 需 ί 1 事 1 要 加 熱 Μ 去 除 固 體 〇 項 再 1 I 如 果 在 正 常 操 作 中 白 主 蒸 發 器 取 出 之 第 沖 洗 流 之 量 % % I 裝 為 引 入 主 蒸 發 器 中 之 液 態 氣 ft 之 至 少 IX ,較佳為至少30Χ 頁 s_ 1 | » 及 /或最多103ί ► * 較 佳 為 最 多 5X * 其 為 方 便 的 〇 1 I 本 發 明 進 一 步 有 闢 依 照 申 請 専 利 範 _ 第 1或2項 之 方 法 1 1 在 依 照 申 講 專 利 範 園 第 6 項 之 對 應 裝 置 中 f 依 照 申 請 専 1 訂 ί 1 利 範 麵 第 3 項 之 空 氣 低 溫. 分 餾 方 法 之 使 用 9 特 別 是 Μ 吸 附 空 氣 預 先 純 化 之 空 氣 分 皤 法 及 設 備 參 例 如 在 分 子 曄 1 上 〇 此 型 之 方 法 與 設 備 用 於 存 在 於 大 量 空 氣 中 之 氧 氣 1 I 及 /或其他氣體之製造。 1 線 1 此 外 « 本 發 明 係 鼷 於 依照 申 請 專 利 胳專第 4 或 5 項 之 蒸 發 液 態 氧 之 裝 置 〇 1 I 本 發 明 及 本 發 明 之 其 他 细 節 在 Μ 下 參 考 示 於 圓 式 中 之 1 1 例 示 具 體 實 施 例 而 更 詳 细 地 解 釋 〇 在 圖 式 中 : 1 1 第 1 圈 顬 示 具 有 包 括 一 匾 之 主 蒸 發 器 之 第 一 例 示 具 體 1 | 實 施 例,及 1 1 第 2 ΙΒΙ 89 顯 示 具 有 包 括 多 區 之 主 蒸 發 器 之 第 二 例 示 具 Η 1 I 實 施 例 〇 - 5 - 1 1 1 1 1 本紙張尺度適用中國國家標準(CNS ) A4規格(210乂297公釐〉 A7 B7 五、發明説明(r ) (請先閲讀背面之注意事項再^^€本頁) 第1圔顯示用於空氣低溫分餾之雙管柱之一部份,即 ,壓力管柱1之頂部及低壓管柱2之底部。主蒸發器3 用以蒸發自低壓管柱2之最低質量轉移部份流出之液態 氣最低質量轉移部份在围式中示為板4,但是其亦可 為安排之充填物)。自低壓管柱經線路9取出氣態氣産 物。 主蒸發器可配置於雙管柱内-如第1團所示,特別是 在低壓管柱之底部。或者,其可如雙管柱外部之分離組 件而設置或整合至與雙管柱分離之另一傾組件中,例如 ,甲烷排出管柱中,如DE4332870A1或DE2055099A專利 所示。經配置於主蒸發器3之較低匾域之線路5,第一冲 洗流連鑛地取出及引入輔助蒸發器6中《第二沖洗流7由 輔肋蒸發器6之較低區域連鑲地或分枇取出,而蒸發之 氧8回到低壓管柱。或者,蒸氣8可由低壓管柱送至氧 産物線路9中或至另一裝置中,例如,依照DE4332870A1 或DE2055099 A專利之甲烷棑出管柱之較低區域中。 經濟部智慧財產局員工消費合作社印製 用於主蒸發器之間接加熱之熱載體10為來自臛力管柱1 上部之氮。在主蒸發器中冷凝之氮11在兩偏管柱回流而 使用。輔肋蒸發器6類似地以來自壓力管柱之氮或以空 氣作為熱載體12,而在正常操作中加熱。冷凝之熱載體 經線路13取出及進料至一或更多個精餾管柱中。 在特定時間間隔,例如,三至十二倨月,較佳為約六 傾月,有藉由封閉在第一沖洗線路5中之閥14而由正常 操作成為加熱操作之切換。熱載體12之進料亦封閉。而 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) S92Q59_b7_ 五、發明説明(& ) 的300K之热空氣經線路15進行至輔肋蒸發器6之液態分 鏞室中及經媒路16再度去除。加热相包含闞閉,淸空, 加熟,再冷卻與起動及持鑛,例如,10至24小時,較佳 為約20小時。 如果第一沖洗流5在其引入鞴肋蒸發器6之前通過裝 置19M去除較不揮發性成份,例如,藉吸附,其為有利 的,但是在本發明之內容中並非必要的。 第2鼷之例示具體實施例異於第1画在於主蒸發器由 多匾3a,3b形成。例如,在作為來自壓力管柱1之氣態氮 進料10之中央管同心圔地配置匾3a,3b。明顧地,此例示 具《實施例亦可裝有去除較不揮發性成份之裝置(第1鼸 之 19)。 ——In n n I---1- - —-I I (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐;ί A7 B7 392059 五、發明説明(7 ) 參考符號說明 3......主蒸發器 5 ......第一沖洗線路 6 ......輔肋蒸發器 7 ......第二沖洗線路 8 ......氣體產物烺路 15,16..加热裝置 9 ......產物線路 (請先閲讀背面之注意事項再填寫本頁) 装·A7 B7 V. Description of the invention (,) Description of the invention The present invention relates to a method for evaporating liquid oxygen and its use in a method for producing gas by low-temperature fractionation of air. In the present application, gas means any mixture having a gas content higher than that of relative air, for example, at least 70S :, preferably at least 98¾. (In this application, all percentages are expressed as moles, unless explicitly indicated otherwise.) They specifically include impure gases, and industrial grade pure gases and high-purity gases with a purity of 99.99X or more. For many applications, it is necessary to convert the existing liquid oxygen into a tritium form by using a heat exchanger to evaporate the heat carrier in the main evaporator before use. This type of evaporation occurs especially when the gaseous gas is produced by cryogenic rectification, where the gaseous product occurs in a liquid state at the bottom of the distillation column, because it is less volatile than nitrogen and argon. In order to obtain the product in gaseous form from the refined column and to produce a rising vapor, the oxygen generated in the liquid state must be similarly evaporated in the main evaporator. The most popular here is the classical Linde double-column method, in which the main evaporator is located at the bottom of the low-pressure string and is operated with condensate from the top of the pressure string (see Tiefteaperat-111'16 (^ 11 by Hausen / Linde) 〖11 [Cryogenic Engineering], 2nd edition, section 4.1.2 on page 284). The main evaporator in this case is a condenser-evaporator operation and is often called the main condenser. It is also Implemented by one or more heat exchange zones that operate as a circulating or falling film evaporator. The invention also pertains to other two-column methods, for example, where the main evaporator is operated with air and has three or more Nitrogen-oxygen separation method ^ Customer I. The downstream of the nitrogen-gas separation rectification column can be connected to the other paper components to make this paper. The size of the paper applies to the Chinese National Standard (CNS) Α4 specification (210 × 297 mm) (Please read first (Notes on the back of this page are again on this page)-Assembling and ordering. Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by the Consumer Cooperative of the Ministry of Economic Affairs, printed by the Central Bureau of Quarantine Bureau of the Ministry of Economic Affairs, and printed by the Shellfish Consumer Cooperative. Noble gas • For example, gas manufacturing. If the liquid “completely or completely evaporates on the plate” • less volatile males, for example, such as (: 02 or) < 20 • accumulated in the evaporator, even if some _ 霣 is being evaporated in the gas (or being It only exists in very low concentrations in the air) (However, the early worrying acetylene was no longer a problem in air radium equipment that was prepared to be passivated by adsorption) ° Some of the less volatile substances, For example, C02 or 40 · can be removed as solids and must be removed occasionally to avoid clogging of the heat exchanger path in the main evaporator. In order to remove some separated solids *, the entire equipment must be In large-scale air distribution equipment, for example, it means to stop working for two to five days. In order to reduce the accumulation of less volatile components, Xi's success has been achieved and autonomous evaporators have taken out some flushes. The liquid in the form of a stream, and the stream is lost. The less volatile components, together with the flushing volume, accumulate in the gas while maintaining the state of the liquid, making its splash in the main evaporator limited. In purified air decanting equipment, the flushing volume is customarily used to introduce evaporation The liquid oxygen content of the device is 0.02 to 0.04X. For the rectified air, it is high, because it uses a molecular sieve absorber instead of the previously used Revex or regenerator, which is less volatile due to its flammability The problem caused by the accumulation of components in this type of oxygen evaporator (main evaporator) has been reduced to the extent that this type of flushing flow is sufficient to prevent harmful concentrations of hydrocarbons without the need for additional capacity (see Tieftenperaturtechnik of Hausen / Linde [ Engineering], 2nd edition, section 4.5.1.5 on pages 312 and 313). The object of the present invention is to increase the availability of liquid oxygen from the main evaporator and, in particular, to prevent interruption of operation as much as possible. -4-This paper size is applicable to China Gujia standard (〇 阳) 8 4 specifications (2 丨 0 father 2-97 mm factory, ------ ^ ------------ order ( Please read the notes on the back before filling in this page) A7 B7 Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperation Du V. Invention Description () 1 1 This S is completed by Φ Please complete the features of item 1 of the patent scope, of which $ White 1 main m hair heater takes out the (first--) flushing stream and sends it to the main evaporator separate configuration 1 auxiliary rib evaporator. Here the auxiliary rib evaporator 9 most of the first flushing stream steam 1 1 I And therefore can be produced as a gas product or an intermediate product gas. Secondly> White first read 1 Read 1 1 The secondary ribbed evaporator takes out the second flushing stream and discards it (at the back of I made from liquid oxygen 1) and / or In other cases of Xenon, you need to proceed-• step operation.) Section-Flushing Note 1 from the main evaporator to the auxiliary rib evaporator 9 and the second Washable items 1 I 1 Take out continuously or in batches. 0f This is installed in the present invention, and can take out a considerable amount of liquid such as page 1 of the flushing flow by the autonomous evaporator 5 so that all the less Volatile components and their concentration in the main 1 1 evaporator can be kept low. Especially * no 1 solid deposits occur in the main evaporator. However, this large volume of flushing liquid does not completely lose 1 because __ '' Some of the first flushing streams are evaporated in the auxiliary rib evaporator and taken out in a gas form 1 to 1. The removal from the auxiliary evaporator is only customary as the first-flushing stream 1 I wash volume 9 such as the liquid introduced into the main evaporator 0-02 to 0.5% of air volume 1 1 9 is preferably 0.2 to 0.2% 0 (in the case of taking out the second flushing flow in batches, 1 1% tb means time average 0) the rest Section--Flushing flow in auxiliary evaporator line | Medium evaporation and can be used as gaseous oxygen products 〇 1 1 The main evaporator 9 can be rinsed intensively using the present invention so that the content of less volatile components that may cause solid deposits is kept very low 〇 less volatile 1 I The components are completely sent to the auxiliary rib evaporator and are occasionally operated by the second flushing stream. 1 1 The heating operation is removed. 1 I solid deposits therefore occur only in the auxiliary rib evaporator, not the main evaporator. 1 1 0 However 9 auxiliary ribs Evaporator can be heated by 5- far tb Main evaporator Jan αο Cleared early 1 1 1 1 1 1 This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) A7 B7 Employee Consumer Cooperatives, Central Standards Bureau, Ministry of Economic Affairs Printed 5. Description of the invention (4 *) 1 1 solid medicament 〇 normal operation for this g is heated and interrupted during the addition of 1 1 I hot operation »auxiliary rib evaporator separated from the main evaporator is liquid-free tt white Steam 1 1 send to m ribbed evaporator 0 at the same time • _ ribbed evaporator rises significantly / · —S Please 1 1 higher than it is in normal operation »For example at least 20K, preferably 20 to 50K 1 The temperature of the temperature. The operation of the main evaporator and its installed equipment does not need to be interrupted in this way. Because of the intense flushing of the main evaporator, it is no longer needed. 1 The matter 1 must be heated to remove solids. 1 I If the amount of the first flushing flow taken out by the white main evaporator in normal operation%% I is filled with at least IX of the liquid gas ft introduced into the main evaporator, preferably at least 30 × pages s_ 1 | »and / or at most 103ί ► * It is preferably at most 5X * It is convenient 〇1 I The present invention further develops the method according to the application of the application _ item 1 or 2 1 1 in the corresponding device according to item 6 of the patent application park According to Shen Please order 1 for the low temperature of air in item 3 of the Lifan surface. The use of fractionation methods 9 especially the air purification method and equipment parameters of M adsorption air purification in advance. For example, the molecular method 1 is used for this method and equipment. Production of oxygen 1 I and / or other gases present in large amounts of air. 1 线 1 In addition «The present invention is based on a device for evaporating liquid oxygen according to item 4 or 5 of the patent application. 0 1 I The present invention and other details of the present invention are shown below in the circular form 1 1 Exemplifying a specific embodiment and explaining it in more detail. 0 In the drawing: 1 1 The first circle shows a first exemplary embodiment with a main evaporator including a plaque 1 | embodiment, and 1 1 second 2 ΙΒΙ 89 shows having The second example of the main evaporator including multiple zones is Η 1 I Example 〇-5-1 1 1 1 1 This paper size is applicable to China National Standard (CNS) A4 specifications (210 乂 297 mm> A7 B7 V. Invention Explanation (r) (Please read the notes on the back before ^^ € this page) Section 1 第 shows a part of the double-column used for low-temperature fractionation of air, that is, the top of the pressure column 1 and the low-pressure column 2 The bottom. The main evaporator 3 is used to evaporate the liquid flowing from the lowest mass transfer part of the low-pressure pipe column 2. The minimum mass transfer part of the gas is shown as plate 4 in the enclosure, but it can also be the filling of the arrangement). Take out the gaseous gas products from the low-pressure pipe string through line 9. The main evaporator can be located in a double-tube string-as shown in the first block, especially at the bottom of the low-pressure tube string. Alternatively, it may be provided as a separate component outside the double-column column or integrated into another tilted component separated from the double-column column, for example, methane is discharged into the column, as shown in DE4332870A1 or DE2055099A patent. Via the line 5 arranged in the lower plaque area of the main evaporator 3, the first flushing stream is taken out of the mine and introduced into the auxiliary evaporator 6. Tiller out, and the evaporated oxygen 8 returns to the low-pressure column. Alternatively, the vapor 8 may be sent from the low pressure string to the oxygen product line 9 or to another device, for example, the lower area of the methane decanting string according to DE4332870A1 or DE2055099 A patent. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the heat carrier 10 used for indirect heating of the main evaporator is nitrogen from the upper part of the power pipe column 1. The condensed nitrogen 11 in the main evaporator is used for refluxing in the two-column columns. The co-boiler evaporator 6 similarly uses nitrogen from a pressure pipe string or air as a heat carrier 12 and is heated in normal operation. The condensed heat carrier is removed via line 13 and fed into one or more rectification columns. At certain time intervals, for example, three to twelve months, preferably about six declining months, there is a switch from normal operation to heating operation by closing the valve 14 in the first flushing line 5. The feed to the heat carrier 12 is also closed. And this paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) S92Q59_b7_ V. 300K hot air of the invention description (&) through line 15 to the liquid separation chamber of the auxiliary rib evaporator 6 and the Media path 16 is removed again. The heating phase comprises closing, emptying, ripening, cooling and starting and holding, for example, 10 to 24 hours, preferably about 20 hours. It is advantageous if the first flushing stream 5 removes less volatile components by means of the device 19M before it is introduced into the ribbed evaporator 6, for example by adsorption, but it is not necessary in the context of the present invention. The second embodiment is different from the first embodiment in that the main evaporator is formed of multiple plaques 3a, 3b. For example, the plaques 3a, 3b are arranged concentrically in a central pipe as a gaseous nitrogen feed 10 from a pressure pipe string 1. Obviously, this example shows that "the embodiment can also be equipped with a device for removing less volatile components (1st to 19th). ——In nn I --- 1--—-II (Please read the notes on the back before filling this page) The paper size printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs applies the Chinese National Standard (CNS) A4 specification ( 210X297 mm; ί A7 B7 392059 V. Description of the invention (7) Reference symbol description 3 ... Main evaporator 5 ... First flushing circuit 6 ... Auxiliary rib evaporator 7 ...... Second flushing line 8 ...... Gas product line 15,16. Heating device 9 ...... Product line (Please read the precautions on the back before filling this page ) Loading ·

、1T 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐)、 1T Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm)

Claims (1)

經濟部智慧財產局員工消費合作社印製 A8 B8 392059_m_ 六、申請專利範圍 1. 一種蒸發液態氧的方法,其中在正常操作中 液態氣引入主蒸發器(3)中及在此部份地蒸發, 從主蒸發器(3)移除液態狀態之第一沖洗流(5), 第一沖洗流(5)在輔助蒸發器(6)部份地蒸發及 自輔肋蒸發器(6)取出液態狀態之第二沖洗檢(7), 其中,在此方法中,正常操作藉加熱操作中斷,及在 加熱操作中 無液體(5>自主蒸發器(3)送至輔肋蒸發器(6)中及 輔肋蒸發器(6)升至顯著地高於其在正常操作之溫度 之溫度。 2. 如申請專利範圍第1項之方法,其中在正常操作中 ,從主蒸發器(3)取出之第一沖洗流(5)之量為引入主 蒸發器(3)中之液態氧量之至少U,較佳為至少3J;,及 /或最多1 0 χ,較佳為最多5 U 3. 如申請專利範圍第1或2項之方法,在一種在精餾条 統中以低溫分餾製造氧之方法之使用,其具有壓力管 柱⑴及及低壓管柱⑵以蒸發來自低壓管柱⑵之液態氣, 在主蒸發器⑶及輔助蒸發器⑹産生之至少一些蒸氣⑻ 被引入低壓管柱⑵中及/或被取出成為氣態氧産物⑼。 4. 一種蒸發液態氧的裝置,其具有 主蒸發器⑶, 輔肋蒸發器⑹, 將液態氧引入主蒸發器中之裝置, 第一沖洗線路⑸,用於自主蒸發器⑶取出第一液態 -1 0 - 本紙張X·度適用中國國家標準(CNS ) Α4说格(210Χ297公釐)— --------裝-------訂------^--泉 ~ · (請先閲讀背面之注意事項再1^5?本頁) A8 B8 C8 D8 沖洗流 第二 態沖洗 氣體 加熱 5 .如申請 洗流⑸ 至少1 5! 5X之量 6 .如申請 氣之裝 ⑴及低 連接至 發器⑶ 7 .如申請 發器⑹ 柱⑵或 392059 申請專利範圍 ,及將第一沖洗流引入輔肋蒸發器《6)中, 沖洗線路⑺,用於自輔肋蒸發器(6)取出第二液 流, 産物線路(8),用於自輔肋蒸發器取出蒸氣,及 裝置(15 ,16),其可連接輔肋蒸發器⑹。 專利範圍第4項之裝置,其具有設定第一沖 在正常操作為引入主蒸發器⑶中之液態氣量之 ,較佳為至少3X,及/或最多ιοχ,較佳為最多 之控屬裝置。 專利範圍第4或5項之裝置,在低溫分皤製造 置之使用,其具有精餾条統,其具有壓力管柱 壓管柱⑵,將液態氧引入主蒸發器⑶中之裝置 低壓管柱⑵及具有氧産物線路(9.8)以自主蒸 及/或輔肋器⑹取出氣態氧産物之裝置。 專利範圍之裝置,其具有用於自輔助蒸 取出蒸氣之物線路⑻,其連接至低壓管 連接至與低壓連接之産物線路⑼。 (請先閲讀背面之注意事項再本頁) 經濟部智慧財產局員工消費合作社印製 11 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐)Printed by A8 B8 392059_m_ of the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperatives 6. Scope of Patent Application 1. A method of evaporating liquid oxygen, in which liquid gas is introduced into the main evaporator (3) and partially evaporated in normal operation, The first flushing stream (5) in the liquid state is removed from the main evaporator (3), and the first flushing stream (5) is partially evaporated in the auxiliary evaporator (6) and taken out of the liquid state from the auxiliary rib evaporator (6) The second flushing inspection (7), wherein, in this method, the normal operation is interrupted by the heating operation, and there is no liquid in the heating operation (5 > the autonomous evaporator (3) is sent to the auxiliary rib evaporator (6) and The co-boiler evaporator (6) rises to a temperature significantly higher than its temperature in normal operation. 2. The method of item 1 in the scope of the patent application, wherein in normal operation, the second evaporator is removed from the main evaporator (3). The amount of a flushing stream (5) is at least U, preferably at least 3J, of the amount of liquid oxygen introduced into the main evaporator (3); and / or at most 10 χ, preferably at most 5 U 3. if applied Method 1 or 2 in patent scope, manufactured in a rectification system by cryogenic fractionation The use of the oxygen method, which has a pressure column ⑴ and a low pressure pipe string 蒸发 to evaporate liquid gas from the low pressure pipe string ,, and at least some of the vapor ⑹ generated in the main evaporator ⑶ and the auxiliary evaporator ⑹ is introduced into the low pressure pipe string ⑵ and / or taken out as a gaseous oxygen product 4. 4. A device for evaporating liquid oxygen, which has a main evaporator ⑶, a ribbed evaporator ⑹, a device for introducing liquid oxygen into the main evaporator, a first flushing circuit ⑸, used for autonomous evaporator ⑶ to take out the first liquid -1 0-The X degree of this paper applies the Chinese National Standard (CNS) Α4 grid (210 × 297 mm) — -------- installation ---- --- Order ------ ^-Spring ~ (Please read the precautions on the back and then 1 ^ 5? This page) A8 B8 C8 D8 Flushing flow The second state of flushing gas heating 5. If applying for flushing flow ⑸ Amount of at least 15! 5X 6. If applying for gas installation and low connection to the hair dryer ⑶ 7. If applying for hair dryer ⑹ pillar ⑵ or 392059 for patent scope, and introducing the first flushing stream into the auxiliary rib evaporator " In 6), the flushing line ⑺ is used to take out the second liquid stream from the auxiliary rib evaporator (6), and the product line ( 8) for taking out steam from the auxiliary rib evaporator, and a device (15, 16) which can be connected to the auxiliary rib evaporator ⑹. The device of the fourth scope of the patent has a control device for setting the first flush in the normal operation to the amount of liquid gas introduced into the main evaporator ⑶, preferably at least 3X, and / or at most ιοχ, and most preferably at most. The device in the patent scope No. 4 or 5 is used in the low-temperature decantation production. It has a rectification system, which has a pressure column and a pressure column. It introduces liquid oxygen into the main evaporator. ⑵ and a device with an oxygen product line (9.8) to take out gaseous oxygen products by autonomous steaming and / or auxiliary ribs. The device covered by the patent has a line ⑻ for extracting steam from the auxiliary steam, which is connected to a low-pressure pipe and a product line 连接 connected to the low-pressure. (Please read the cautions on the back before printing this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 11 This paper size applies to China National Standard (CNS) A4 (210X 297 mm)
TW88101277A 1999-01-28 1999-01-28 Process and apparatus for evaporating liquid oxygen TW392059B (en)

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