TW391971B - Floor, wall or ceiling covering - Google Patents

Description

Printed by the Central Government Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives A7 B7 V. Description of the Invention (1) Field of the Invention The present invention relates to floor, wall or ceiling coverings. The invention is particularly concerned with floor, wall or ceiling coverings made of one or more polymer layers. BACKGROUND OF THE INVENTION Materials used as floor and wall coverings need to have different properties, which are sometimes incompatible. One of the important properties of materials for floor and wall coverings is that they have good suitability for uneven or contoured surfaces so that the material can be effectively applied to floors and walls. Materials for floor coatings are particularly important as good Anti-wear, anti-abrasion, anti-scratch and anti-indentation and good indentation recovery to reduce visible scratches and indentations in furniture and rolling objects. Floor and wall covering materials can also contain high levels of general fillers to produce floor and wall coverings over a wide range of hardness. The desired hardness of the flooring material varies widely where the floor is used, for example, the type of room in which a public or private building or floor covering is used. The desired hardness of the flooring material also varies widely depending on its covering pattern, for example, it is based on endless flakes or porcelain-like forms. 0 It is known that the floor covering is based on polyvinyl chloride (PVC). PVC-based materials have many desirable properties, such as good filler acceptance, flexibility, and scratch resistance. However, in recent years, attention has been focused on the disadvantages of PVC as a reference floor, such as its radon content, which forms gasified argon when burned. As a result, those skilled in the art have been working to find alternatives to PVC-based flooring, pickled walls or ceiling coverings. German patent application DE-A-43 24 127 discusses a variety of PVC-free local paper sizes, using the Chinese National Standard (CNS) A4 (210X297 mm) (please read the note on the back before filling in this Page) -tr 4 Printed A7 B7 by the Central Oak Quasi-Bureau Consumer Cooperative of Zhongji Ministry. 5. Description of the Invention (2) Advantages and Disadvantages of Board Coverings. "It discusses the flooring based on ethylene / vinyl acetate copolymer." The covering is not expensive and can be used in a wide range of applications, but its residual content of vinyl acetoacetate comonomer and its relatively low thermal stability require special care when preparing floor coverings. Floor coverings based on low density ethylene / butene or ethylene / 1-octene copolymers are also mentioned. It is mentioned that these copolymers can be highly filled in order to control the flexibility and hardness of the floor. On the other hand, it mentions that it is difficult to provide the lacquer or final layer of these copolymers to improve the resistance to abrasion, because Insufficient adhesion between olefin copolymer and lacquer or final layer. In order to solve these problems, DE-A-43 24 127 proposes a multilayer synthetic board with at least one layer containing an ethylene / acrylate copolymer. Unfortunately, the ethylene / acrylate copolymer is too viscous in the preparation method and provides low Abrasion resistance. WO 96/04419 discloses a sheet-like material suitable for floor coverings' which comprises a polyalkylene resin intimately mixed with at least one filler-containing additive. PolyHyun resin has a relatively narrow molecular weight distribution (M3KO) and a small amount of long chain branches. It is prepared by a single-site catalytic polymerization of at least one linear, branched or cyclic olefin having 2 to 20 carbon atoms. Of it. This sheet material has good properties such as excellent abrasion resistance and high mechanical strength. However, the deformation recovery and scratch resistance of sheet materials are generally not very good. Obviously, there is no material that can fully meet the required and desired properties of a wide range of floor and wall coverings, which depends on how and where the floor, wall or ceiling covering is used and Normally incompatible. Therefore, the “desired nature” is to give priority to the desire of the floor and wall covering to finally make this paper standard applicable to the Chinese National Standard (CNS) M specification (210X297 mm) 11—-1: -I! 1 *-I • Min-I-II ----- Ding ^ Product I (please read the precautions on f-plane and fill in this page) Α7 Β7 V. Description of the invention (3) The materials are selected. In order to increase the variability of materials and material properties suitable for flooring, wall and ceiling coverings, the high-end coating can provide flooring, marinated walls and ceiling coverings based on other polymers used in unconventional techniques. It is particularly desirable to provide floor, wall and ceiling coverings with a good balance of the desired properties, especially the flexibility and suitability for uneven or contoured surfaces in order to effectively coat the floor, wall or ceiling with sufficient scratch resistance "Insufficient indentation resistance, indentation recovery and / or sufficient abrasion resistance" Summary of the invention In one aspect, the present invention relates to a floor, siding, or ceiling covering, which comprises one or more by making one or more Prepared by polymerizing olefin monomers with one or more vinylidene aromatic monomers and / or one or more hindered aliphatic or cycloaliphatic vinylidene monomers and optionally with other polymerizable ethylene unsaturated monomers Substantially random inner polymers. On the other hand, the present invention is related to the use of the above-mentioned substantially random internal preparation of floor, wall or ceiling coverings. Detailed description of the invention Invention of the Central Ministry of Economic Affairs, Central Bureau of Work, Zhengong Consumer Cooperative, India --1 (please read ^: Notes on the surface before filling out this page) The term "floor covering" as used herein means objects whose length and width are substantially greater than their thickness, such as sheets, Porcelain monument or plate-shaped, which can be used to cover at least a part of the floor and which is adhered by static pressure or a fixing agent such as an adhesive system. "Substantially greater than" generally means at least 10 times larger ', preferably at least 50 times larger, more preferably at least 100 times larger. As used herein, "pancreatic wall covering" or "ceiling covering," Means that the above-mentioned objects (such as sheet, tile, or plate) can cover the size of this paper. Applicable to China National Standard (CNS) A4 (210X297 mm) 6 5. Description of the Invention (At least a part of a wall or ceiling, and it is attached to the wall or ceiling by a fixing agent (such as an adhesive system, nails or screws). "Inner polymer" as used herein refers to a A polymer in which at least two different monomers are polymerized to form the inner polymer. As used herein, a "copolymer" refers to a polymer in which at least two different monomers are polymerized to form the copolymer. The polymer used in the present invention Polymers include, but are not limited to, substantially random polymers consisting of one or more (X-olefins and one or more vinyl aryl monomers and / or one or more sterically hindered aliphatic or cycloaliphatic monomers, And optionally with others Random interpolymers prepared from ethylenically unsaturated monomers. Suitable alpha-smoky monomers include, for example, alpha-olefin monomers containing 2 to about 20 carbon atoms, with carbon atoms ranging from 2 to about 12 More preferably, 2 to about 8. The best such single vessels include ethylene, propylene, butylene, 4-methylpentane, 1-hexene and 1-octene. The better monomers are Ethylene or a combination of ethylene and c2ra-olefins. These _a-olefins do not contain a structure having an aryl group. Suitable ethylene-based aryl groups that can be used to prepare the filled polymer composition of the present invention include, for example, compounds having the following chemical formulas: ·

At

I (CH2) n R > — C = C (R2) 2 where R1 is selected from the group consisting of hydrogen and alkyl having 1 to about 4 carbons, preferably argon or methyl; each R2 is selected from Including argon and alkyl groups having 1 to about 4 carbons, preferably hydrogen or methyl; Ar is phenyl or substituted with 1 to 5 substituents selected from the group including halogen, CV4 alkyl, and Cm Aryl; and η (please read the note on the back of the page and fill in this page) Ordering paper 佚 Standards applicable 1 | National standard (〇 阳) 8 4 specifications (2 丨 〇 \ 297 mm) Ministry of Economic Affairs Printed by the Central Consumers ’Cooperative Consumer Association A7 B7 V. Description of the invention (5) is 0 to about 4, preferably 0 to about 2, and 0 is the best. Examples of single vinylidene aromatic single gifts include phenylethyl Diluted, vinyltoluene, α-methylstyrene tertiary butyl styrene, gas benzene diluent (including all isomers of these compounds), etc. Particularly suitable for this monomer include styrene and lower Alkyl or its halogenated derivative. Preferred monomers include styrene, alpha-methylstyrene, lower alkyl (Crc4), or phenyl ring substituted derivatives of phenylene, such as, for example, ortho, Meta and counter Ethyl styrene, ring substituted styrene, para-ethyl toluene or mixtures thereof, etc., preferably aromatic monovinylidene monomer is styrene. '' Hindered aliphatic or cycloaliphatic vinylidene The term "basic monomer" refers to an addition polymerizable vinylidene monomer relative to the chemical formula of the following formula: A * R1 — C = C (R2) 2 i where A1 is a stereobulk of up to 20 carbon atoms Or cycloaliphatic substituents, R1 is selected from hydrogen and alkyl groups containing 1 to about 4 carbon atoms, preferably argon or methyl; each rrR2 is selected from argon and contains 1 to about 4 carbon atoms, respectively The alkyl group is preferably argon or methyl; in addition, R1 and A1 may form a ring system together. The term "stereo-bulking" means that the monomer supporting this substituent generally cannot pass the Ziegler Natta The polymerization catalyst is addition-polymerized at a rate comparable to the ethylene polymerization reaction. Alpha-olefin monomers (such as propylene, butene-1, hexene) containing 2 to about 20 carbon atoms and having a linear aliphatic structure -1 and octene-1) are not considered to be hindered aliphatic monomers. It is preferred that the hindered aliphatic or cycloaliphatic vinylidene compounds have a supported ethylene unsaturation in between. The carbon atom is a tertiary or quaternary substituted monomer. Examples of such substituents include cyclic aliphatic groups (such as cyclohexyl, cyclohexenyl, cyclooctenyl) or their alkyl or aryl groups This paper size applies to Chinese National Standard (CNS) A4 specification (210 × 297 mm) (please read the notes on the back before filling out this page). V. Description of invention (6 A7 B7 Printed by Zhengong Consumer Cooperative, Central Standards Bureau, Ministry of Economic Affairs Packaging derivatives, tertiary butyl, 1101 and 1) 〇11 ^ 1, etc. The best hindered aliphatic or cycloaliphatic vinylidene compounds are cyclohexene and various isobutylene substituted cyclohexene. Derivatives of base ring and 5-ethylidene-2-norbornyl poem. Particularly suitable are 1-, 3-, and 4-vinylcyclohexene. The inner polymers used in the present invention for one or more alpha-olefins and one or more monoethylenically aromatic single vessels and / or one or more hindered aliphatic or cycloaliphatic vinylidene monomers are substantially free of Regulatory polymer. These inner polymers usually contain from about 0.5 to about 65 ', preferably from about 1 to about 55, more preferably from about 2 to about 50, most preferably from about 20 to about 50, especially from about 30 to about 50. At least one vinylidene aromatic monomer and / or hindered aliphatic or cycloaliphatic vinylidene monomer, and about 35 to about 99.5 ', preferably about 45 to about 99, more preferably about 50 to about 98 Preferably, it is about 50 to about 80 ′, especially about 50 to about 70, and at least one mole% of the aliphatic α-dilute hydrocarbon having 2 to about 20 carbon atoms. Other selectively polymerizable ethylene unsaturated monomers include stretched cyclic olefins, such as norbornyl and CrC10 alkyl or C6-C10 aryl substituted JJ block bornene 'inner polymers. Examples are ethylene / styrene / Borneol is thin. Number average molecular weight (Mn) of the inner polymer-generally greater than about 5,000, preferably from about 20,000 to about 1,000, 000, more preferably from about 5000 to about 5000 〇. Melt Index Iζ (according to ASTMD 1238 procedure A, condition E)-generally 0.01 to about 50 g / 10 minutes', preferably about 0.00 to about 20 g / 10 minutes, more preferably about 0.1 to about 10 g / 10 minutes, preferably about 0.5 to about 5 g / 10 minutes. The glass transition temperature (Tg) of the inner polymer is preferably about -40 ° C to about + 35 ° C, and preferably about 0 °. C to about + 30 ° C ', more preferably about + 10 ° C to about + 25eC, which is measured based on differential mechanical scanning (OMS). The density of the inner polymer is preferably about 0.95.

The paper size of the I-page edition is applicable to the Chinese National Standard (CNS) A4 (210X297 mm). Printed by A7 ———--B7 by the Bayer Consumer Cooperation Department of the Central Elevator Bureau of the Ministry of Interest. V. Description of the Invention (7) To about 1.11 g / cm3, more preferably about ο.% To about 105 g / cm3, most preferably about 0.97 to about 1.03 g / cm3. Particularly preferred within the α-thin smoke / ethylene ethylene aromatic The polymer contains from about 30 to about 50 mole% of at least one copolyvinylidene aromatic monomer and from about 15c to about 25c

Tg. Polymerization and removal of unreacted monomers at a temperature higher than the temperature of the individual polymerization reaction of each individual can result in the formation of some homopolymer polymerization products formed by free radical polymerization. For example, when a substantially random inner polymer is prepared, a content of a random vinylene aromatic homopolymer can be formed because of the homopolymerization of the vinylene aromatic monomer at an elevated temperature. If desired, the vinylidene aromatic homopolymer can be separated from the inner polymer by extraction techniques, such as an extraction technique using a non-solvent for the internal polymer or the vinylene aromatic homopolymer to selectively precipitate from solution. For the purposes of the present invention, it is preferred to have less than 15 weights based on the total weight of the inner polymer of the vinylene aromatic homopolymer. 0/0 A substantially random inner polymer can be obtained by typical grafting, argon Polymerization can be easily vulcanized or gasified to provide functionalized derivatives according to established techniques, as modified by reactions known by chemical, functionalization, or other conventional techniques. Substantially random interpolymers can be filed in U.S. Application Serial No. 07 / 545,403 (July 3, 1911 (corresponding to EP-A-0,416,815), James C. Stevens et al.), And U.S. Application 08 Case No. / 469,828 (June 6, 1995) 'and other cases are hereby incorporated for reference. The preferred operating conditions for these polymerizations are pressures from atmospheric pressure to 3,000 atmospheres and temperatures from -30 ° C to 200 ° C. (CNS) Na (2 丨 0Χ297Ί (Please read the $ on the back and fill in this page)

10 A7 B7 printed by Zhengong Consumer Cooperative, Central Bureau of the Ministry of Economic Affairs __ V. Description of the invention (8) Suitable catalysts and preparation methods for the preparation of substantially random internal polymers are described in US Application No. 07 / 545,403 (1990, July 7 Filed on March 3, corresponding to EP-A-416,815); US application serial number 547,718 (July 3, 1990, corresponding to £? -In -468,651); US application 07 / 702,475 (May 1991 20th application, corresponding to EP-A-514,828); US application 07 / 876,268 (filed on May 1, 1992, corresponding to EP-A-520,732); US application serial number 884,966 (1992, 5 Filed on May 15, corresponding to WO 93/23412); US Patent No. 5,374,696 (filed on January 21, 1993); US application number 34,434 (filed on March 19, 1993, corresponding to WO No. 94/01647); U.S. Application No. 08 / 241,523 (filed on May 12, 1994, corresponding to WO 94/06834 and EP 0,705,269); and U.S. Patent No. 5,055,438; No. 5,057,475; No. 5,096,867; No. 5,064,802; No. 5,132,380; and No. 5,189,192; No. 5,321,106, 5,347,0 No. 24; No. 5,350,723; No. 5,374,69_6; No. 5,399,635; No. 5,460,993 ^ Han and No. 5,556,928. All patent cases and applications are incorporated herein for reference. The substantially random α-olefin / vinylidene aromatic inner polymer can also be used by John G. Bradfute et al. (WR Grace & Co.) in WO 95/32095; RB Pannell (Exxon Chemical Patents, Inc. ) Were prepared as described in WO 94/00500; and Plastics Technology (page 25, September 1992), which are hereby incorporated by reference. Also suitable is a substantially random inner polymer system comprising at least one quaternary group of alpha-olefin / vinylaromatic / vinylaromatic / alphaolefin, which is disclosed in the US special paper standard applicable to the Chinese national standard (CNS ) Α4 specification (210X297 mm) (please read the note on the back before filling in this page) Order 11 Zhongji Ministry Central Bureau Procurement Bureau Consumer Work Cooperatives Seal A7 B7 V. Description of Invention (9) 08 / 708,809, filed on September 4, 1996, Fancis J. Timmer et al. These inner polymers contain extra signals that are stronger than 3 times the peak-to-peak noise. These signals appear in the chemical shift range of 43.75 to 44.25 ppm and 38.0 to 38.5 ppm. In particular, the main peaks were observed at 44.1, 43.9, and 38.2 ppm. Proton test NMR experiments indicate that the signal in the range of 43.75 to 44.25 ppm chemical shift is methine break and the signal in the range of 38.0 to 38.5 ppm is methylene break. In order to determine the 13 NMR chemical shift of the inner polymer, the following procedures and conditions were used: 5 to 10% by weight of the polymer solution in 50% of the existing in 1,2,4-trifluorobenzene Prepared from a mixture of 1,1,2,2-tetrachloroethane-d2 and 50 cross product of 0/0 0.10 mole tris (acetamidoacetone) chromium. NMR spectrum is at 130 ° C using inverse Gate decoupling sequence (90 ° C pulse width and pulse delay of 5 seconds or more). The spectral indication is the isolated methylene signal of the polymer distributed at 30,000 ppm. I am convinced that these M signals are due to the involvement of two head-to-tail vinyl aromatics and at least one alpha-olefin insertion, for example, the ethylene / styrene / styrene / ethylene quadruple 'of which the benzene of the quadruple Ethylene monomer insertion occurs in a 1 > 2 (head-to-tail) manner. Those skilled in this art will understand that for quaternions containing vinyl aromatic monomers that are not acetophenone and α-olefins that are not ethylene, ethylene / vinyl aromatic monomer / ethyl aromatic monomer / ethyl Dilute quaternions produce similar carbon NMR peaks, but with slightly different chemical shifts. These interpolymers are prepared by performing a polymerization reaction at a temperature of about -30 ° C to about 250 ° C in the presence of a catalyst as shown below. | Paper 1 ^ (CNS) into 4 threats (210X297 mm) from Shicai Guanjia " (Please read the precautions on the back before filling this page), order -12-A7 B7 V. Description of the invention (10 C „MR, where: each Cp is in each case a substituted cyclopentadienyl group bound to π with a π-bond; E is C or Si; M is a Group IV metal, preferably zr or Hf, Most preferred is Zr; each R is in each case η, hydrocarbyl, silane, or hydrosilyl, each containing up to about 30 (preferably 1 to 20, more preferably 1 to about 10) ) Carbon or silicon atom; each R ′ is in each case fluorene, halo, hydrocarbyl, hydrocarbyloxy, silylhydrocarbyl, hydrosilyl, each containing up to about 30 (preferably 1 to about 20, More preferably, from 1 to about 10) carbon or carbon atoms, or two R1 groups together may be Cuic hydrocarbyl substituted ι, 3-butadiene; m is 1 or 2; and optionally (but preferably) Is present in an activated co-catalyst such as' tris (pentafluorophenyl) boron or methylalumoxazole. In particular, suitable substituted cyclopentadienyl groups include those exemplified by the following chemical formulas: Note% ί Order Central Ministry of Economic Affairs 揲 扃 揲; Industrial and Consumer Cooperative Seal «. Each R in each case is Η, hydrocarbyl, silane hydrocarbyl or 蛵 silyl ', which contains up to 30 (preferably 1 to about 20) , Preferably about 10) carbon or silicon atoms, or two r groups which together form a divalent derivative of these groups. Preferably, R is in each case individually (including all appropriate isomers) Material) hydrogen, methyl, ethyl, propyl, butyl, pentyl, hexyl, benzyl, phenyl or silane or (where appropriate) two of these r groups combine to form a fused ring system, such as indene Base, fluorenyl, tetra-indenyl, tetra- or octa-arsenyl. Private paper sizes are applicable to China National Standards (CNS) A4 (210 × 297 public shame 13 · _____B7 V. Description of the invention (u) Particularly good catalysts include, For example, racemic- (dimethylsilyldiyl (2-methyl-4-phenylindenyl) hammerdi-C1-4alkyl, racemic- (dimethylsilyldiyl (2-methyl Phenyl-4-phenylbenzyl)) fluorene di-C1-4 alkoxide, or any combination thereof, etc. Further methods for the preparation of the inner polymer of the present invention have been described in the literature. Longo Gr assi (Makromol. Chem. 191, pages 2387 to 2396 [1990]) and D 'Anniello et al. (Journal of Applied Polymer Science, vol. 58, pages 1701 to 1706 [1995]) report the use of methylaluminum A 6-ene-styrene copolymer was prepared by using a catalyst system based on azole (MAO) and cyclopentadienyl titanium trigas (CpTiCl3) as the main catalyst system. Xn and Lin (Polymer Preprints, Am. Chem. Soc ·, Div. Polym. Chem ·) Vol. 35, 686, 687 [1994]) have reported the use of \ 1Lu 0: 1/11 (: 14 jaws (1 (: 13 / Into 811) 3 catalyzes the production of random copolymers of styrene and propylene. Lu et al. (Journal of Applied Polymer Science 'p. 53, p. 1453 to 1460 [1994]) have described the use of Tii Copolymerization of ethyl benzene and styrene with l4 / NdCl3 / MgCl2 / Al (Et) 3 catalyst. Sernetz and Mulhaupt (Macromol. Chem. Physo, Vol. 197, pp. 1071 to 1083, 1997) have described the polymerization reaction. Conditions for copolymerization of styrene and ethylene using Me2Si (Me4Cp) (N-third-butyl) TiCl2 / methylalumoxazole Ziegler-Natta catalyst. Alpha-olefin / ethyl aromatic monomer The preparation of inner polymers such as propylene / styrene and butene / styrene is described in U.S. Patent No. 5,244,996 (Mitsui Petrochemical Industries Ltd.). All the methods disclosed above for preparing the inner polymer components are described in This is incorporated for reference. The floor, wall or ceiling covering of the present invention preferably contains about 5 paper sizes. Standard (CNS) A4 size (210X297 mm) 14 A7 B7 Printed by the Central Government Bureau of the Ministry of Economic Affairs of the Ministry of Liji, Printed by the Shellfish Consumer Cooperation, V. Description of the invention (12 to about 100%, more preferably about 10 to about 100% , Preferably about 40 to about 98 / 〇, a substantially random inner polymer (which is based on the total weight of the floor, siding or ceiling covering) "The floor, wall or ceiling of the present invention is in addition to the above The substantially random inner polymer may contain one or more other polymers. If present, the amount is generally up to about 90%, preferably about 5 to about 80%, more preferably about 15 to about 60%, It is preferably about 20 to about 50% (which is based on the total weight of the floor, wall, or ceiling covering). The floor, wall, or ceiling of the present invention may be single-layered or multi-layered. On a single-layered floor, wall, or In ceiling coverings, these additional optional polymers are blended with the above-mentioned substantially random inner polymers. In multilayer flooring, wall or ceiling coverings, these additional optional polymers may be included in the substantially random inner polymer. The same or different layers of the internal polymer. Preferred additional optional polymer is monoethylene Aromatic polymers or copolymers of styrene-styrene dilute segments. The best additional selective polymers are aliphatic α-olefins having 2 to 20 carbon atoms or α- containing 2 to about 20 carbon atoms and containing polar groups. Homopolymers or inner polymers of olefins β Suitable monoethylene aromatic polymers include one or more monoethylene aromatic monomers homopolymers or inner polymers or one or more monovinylidene aromatic monomers Endopolymers that are both non-aliphatic a-olefins and can be polymerized with one or more mononuclears. Suitable monovinylidene aromatic monofluorene is represented by the following chemical formula:

Ar

I wherein R1 and Ar have the meanings shown in the above Chemical Formula I. Exemplary Single Asian Winter Paper "Ruler and Jiaming Mingzuan Standard (CNS) A4 Specification (21〇 > < 297mm) ----------; Clothing-(Please read t (Notes on the back, please fill out this page) Order 15.

Description of the invention (13) Dilute aromatic monoamidines of the above chemical formula 1_, especially benzene has been diluted. Examples of suitable non-monohexylene diaromatic monosynthetic co-polymerization reactions include 'e.g.' C4_c < i conjugated diene, especially butadiene or isoprene, N_phenyl horse Lebenimine Propylamine, Ethyl Acetate, and Nitrile Singles such as' Ethyl Acetate and Methyl Propionate, Ethyl Acetate and Mono- and Difunctional Antacids and Their Derivatives, such as Boxes, and In the case of bifunctional acids' acids, such as acrylic acid, acrylic acid or methacrylic acid ai ', such as' n-butyl acrylic acid, and methyl methyl acrylic acid box, maleic acid Liver and so on. In some cases, it is also desirable to copolymerize a crosslinked monomer (e.g., divinylbenzene) into a monovinylidene aromatic polymer. The polymer formed by the monovinylidene aromatic monomer and other internally polymerizable comonomers preferably contains (internally polymerizes) at least 50% by weight (preferably at least 90% by weight) of one or more kinds of Vinyl aromatic monofluorene. Note

I t Binding Printed by the Central Lie Chuan Majestic Consumer Cooperative of the Ministry of Economic Affairs *. The styrenic block polymer can also be used as an additional optional polymer in the floor, wall or ceiling covering of the present invention. As used herein, the term "block" refers to an elastomer β formed from a block having at least one hard polymer unit and at least one block from a single rubber unit. However, the term is not intended to include thermoelasticity. Ethylene inner polymer (which is generally a random polymer). The preferred block copolymers contain hard segments of a benzene-hex type polymer combined with saturated or unsaturated rubber monomer segments. The structure of the block copolymer used in the present invention is not critical and may be linear or radial, diblock or triblock, or any combination thereof. The unsaturated block copolymers suitable include those represented by the following formula: ABR -(-BA) n or paper (Wu Si_Gu State Standards (CNS) Congxiu (2 丨 0 > < 297 public product) 16 A7 B7 V. Description of the invention (14)

Ax- (BA-) y-BA where each A is a polymer block containing a monovinylidene aromatic monomer, preferably styrene, and each B is a polymer segment containing a total of two dilute monomers , Preferably diisocyanate or dibutylene, and optionally, monoethene aromatic, preferably styrene; R is a residual polyfunctional coupling agent, η is 1 to about An integer of 5; X is 0 or 1; and y is a number from 0 to about 4. Printed by the Central Government Bureau of the Ministry of Economic Affairs, Shelley Consumer Cooperative (please read the notes on the back before filling in this X). The method for preparing these copolymers is known in the industry. Β is used to prepare unsaturated rubber sheets «Unit Proper catalysis of useful block copolymers includes effect-based catalysts, especially lithium-based lithium. U.S. Patent No. 3,595,942 describes a suitable method for argonizing block copolymers with unsaturated rubber monomer units to form block copolymers with saturated rubber monomer units. The polymer structure is determined by its polymerization method. . For example, a linear polymer is formed by sequentially introducing a desired rubber into a reaction vessel sequentially when using these initiators as a base or di-chain 1,2-diphenylene, etc., or by vibrating the second stage. The segment copolymer is formed by coupling with a difunctional coupling agent. On the other hand, the branched structure can be obtained using an appropriate coupling agent having the functionalities related to a block co-ship with three or more units of unsaturated rubber. Couplings can be multifunctional coupling agents (such as bis-alkanes or olefins and divinylbenzene) and certain polar compounds (such as' esters made from silicon, siloxane, or mono-argon carboxylic acids) Work of it. The presence of any coupling residues in the polymer can be ignored due to the proper description of the block copolymer that forms part of the composition of the invention. Suitable block copolymers having unsaturated rubber monomer units include, but are not limited to, styrene-butadiene (SB), styrene-isoprene (SI), styrene-butadiene-benzyl Hexene (SBS), phenhexene-isoprene-styrene This paper uses Chinese National Standard (CNS) A4 * t (210X297 mm) 17 A 7 ___ B7 V. Description of the invention (15 ) (SIS), α-methylstyrene butadiene-α-methylstyrene, and ^ -methylbenzyl ethylene-isoprene-α-methylstyrene. The styrene portion of the block copolymer is preferably a polymer or inner polymer of styrene and its analogs and homologues, including α-methylstyrene and ring-substituted styrene, especially ring-methylated Styrene. Styrene is preferably styrene and α-methylstyrene. Particularly preferred is styrene β. Block copolymers with unsaturated rubber monomer units may contain homopolymers of butadiene or isoprene. Or a copolymer of one or two of these dienes and a small amount of styrene monofluorene. Preferred block copolymers having saturated rubber monomer units include at least one styrene unit segment and at least one ethylene · butene or ethylene-propylene copolymer segment. Preferred examples of such block copolymers having saturated rubber monomer units include styrene / ethylene-butene copolymer, styrene / ethylene · propylene copolymer, styrene / ethylene · butene / styrene (SEBS ) Copolymers, styrene / ethylene_propylene / styrene (S_gPS) copolymers, and the like. — ▼

It is printed by the Central Bureau of Standards of the Ministry of Economic Affairs of the People ’s Republic of China, and it ’s printed on f 碕 4 '. Please fill in this page before filling in this page. The reaction product of an aluminum alkyl compound with nickel or a cobalt carboxylate or alkoxide under conditions that substantially completely hydrogenate at least 80% of the aliphatic double bonds while argonizing not more than about 25% of the styrene aromatic double bonds. "Catalyst action" The preferred block copolymer is one in which at least 99% of the aliphatic double bonds are argonized and at least 5% of the aromatic double bonds are argonized. "The proportion of styrene blocks is usually block copolymers. Between 8 and 65% by weight of the total weight. Preferably, the block copolymer contains 10 to 35% by weight of a styrene block segment and 90 to 65% by weight of a rubber monomer block segment. This paper size is applicable to China National Standards (CNS) A4 specifications (210 × 297 mm) 18 _B7 5. Description of the invention (16) Based on the total weight of the block copolymer. The average molecular weight of the individual blocks can vary within certain limits. In most cases, the styrene blocks and segments have a number average molecular weight of about 5,000 to about 125,000, preferably about 7,000 to about 60,000. It has a number average molecular range of about 10,000 to about 300,000, preferably about 30,000 to about 150,000. Block copolymers typically have a total flat field molecular weight ranging from about 25,000 to about 250,000, and preferably from about 35,000 to about 200,000. Furthermore, various block copolymers suitable for use in the present invention can be grafted with a small amount of functional groups (e.g., maleic anhydride) and modified by any method known in the art. The block copolymers used in the present invention are commercially available, for example, Shell

Chemical Company's trademarks are KRATON ™ and Dexco Polymers' trademarks are provided by VECTOR ™. The Central Government Bureau of the Ministry of Economic Affairs of the Central Bureau of Shellfish Consumer Cooperatives has a better selection of I. Selective polymers are aliphatic α having 2 to about 20 (more than 2 to about 18 ′, more preferably 2 to about 12) carbon atoms. -Olefins or homo- or inner polymers of alpha-olefins having 2 to about 20 (preferably 2 to about 18 ', more preferably 2 to about 12) carbon atoms and containing polar groups. Suitable aliphatic α-olefin monomers that introduce polar groups into the polymer include, for example, ethylene unsaturated fluorene (such as acrylonitrile, fluorene propylene fluorene, ethylene propylene fluorene, etc.); ethylene non-planar and acid anhydrides (such as male Acid anhydride); ethylene unsaturated cesium and cannamine (such as acrylamide, methacrylamide, etc.) "ethylene unsaturated carboxylic acids (mono- and difunctional groups) (such as acrylic acid and methacrylic acid, etc.); ethylene unsaturated carboxylic acid Acid esters (especially lower, for example, CQ alkyl esters), (example 19 printed by the Central Government Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperative, printed A7 ------ B7 V. Description of the invention (17) "- -For example, methyl methyl acrylic acid, ethyl acrylic acid, ethyl ethyl acrylic acid tank, n-butyl acrylic acid vinegar or methyl acrylic acid ethylhexyl acrylic acid, etc.), B Dilute and diene kanimides (such as N-alkyl or N-aryl maleimide (such as N-phenylmaleimide, etc.). Preferred univalents containing polar groups are preferred. Acid, 6-acetylacetic acid®, maleic acid, and acrylonitrile. It can be contained in the polymer by aliphatic alpha · dilute hydrocarbons. Preferably, the polymer is a gasified polyethylene (CPE) or a polygas. The preferred dilute hydrocarbon polymer for use in the present invention is the deer family (containing ring difficulties with 2 to 18 broken atoms) ) Xinchi's homopolymer or inner polymer ^ Suitable examples are homopolymers of ethylene or acrylic 'and two or more α-thin smoke unimaginable inner polymers. Other polymers are 6 为 and _ Or more other interpolymers of α-olefins having 3 to 8 carbon atoms. Preferred single vessels include butene, 4-methyl-1-pentene, 1.hexene, and octene. The olefin polymer may contain (in addition to the α-olefin) one or more non-aromatic monomers that can be polymerized therewith. This additional cohesive single vessel contains, for example, c4_c2. Diene, preferably butylene Or 5-vinylidene-2-norbornene. Olefin polymers are further characterized by their degree of long or short chain branching and their distribution. One type of olefin polymer is usually used by high pressure polymerization methods using traditional long chain branching. Made from a free-radical initiator formed from low-density polymerized olefins (LDPE). The LDPE used in this composition typically has a density of less than 0.94 g / cc (ASTM D 792) and 0.01 To 100% solubility index (preferably oj to 50 g / 10 minutes) (which is determined by ASTM test method D 1238, condition I). The other is a linear olefin polymer without long chain branching, such as The size of the traditional linear paper is applicable to the Chinese National Standard (CNS) A4 (210X297 mm) ^^ 1 · 1 ^ 1 ^^ 1 1 ^ 1 ^^ 1 n 1 ^ 1 n Is smm HI m 1 ^ 1 • * / Ivi (Please read the notes on the back of Zhu Qi and fill in this page again. J -20-Printed by the Central Laboratories of the Ministry of Economic Affairs, Shellfish Consumer Cooperative, A 7 B7. V. Description of the invention (18) Low density polyethylene polymer (not uniform LLDPE) or linear high-density polyethylene polymer (HDPE) is made using a Ziegler polymerization method (eg, US Patent No. 4,076,698, Anderson et al.) And is sometimes referred to as a heterogeneous polymer. HDPE is mainly composed of long linear polyethylene chains. HDPE used in this composition usually has a density of at least 0.94 g / cc (measured by ASTM test method D 1505) and a melt index (ASTM-1238, condition I) of a range of 0.01 to 100, preferably 0_1 to 50 g / 10 minutes. The non-uniform LLDPE used in the composition generally has a density (ASTMD 792) of 0.85 to 0.94 g / cc and a melt index (ASTM-1238, condition I) ranging from 0.01 to 100 ', preferably 0.1 to 50 g / 10 minutes. Preferably, LLDPE is an inner polymer of ethylene and one or more other α-olefins having 3 to 18 carbon atoms (more preferably 3 to 8 carbon atoms). A preferred co-monomer includes 1-butene, 4-methyl-1-pentene, 1-hexene and 1-octene. The other is a nasal branch or a homogeneous polymer (a homogeneous LLDPEX polymer does not contain long chain branches and only has branches derived from monomers (if it has more than two carbon atoms). The homopolymer contains a U.S. patent The producer (Elston) described in case No. 3,645,992 and the producer using a single-site catalyst in a reactor having a relatively high olefin concentration (as described in US Pat. Nos. 5,026,798 and 5,055,438 (€ 31 ^ 11)) .Homogeneous branching / homopolymer is a polymer in which the co-monomers are randomly distributed in the known inner polymer molecule and the inner polymer molecule has a similar ethylene / comonomer ratio in the inner polymer. "Uniform LLDPE used in this composition —Generally has a density of 0.85 to 0.94 g / cc (ASTM D 792) and a range of melting index (ASTM-1238, condition I) This paper size is applicable to China National Kneading (CNS) A4 specification (210X297 mm) --- ------- ^ 4—. »: (Please read the precautionary notes before filling out this page) Dingqi 21 A7 B7 Printed by Zhengong Consumer Cooperative, Central Standards Bureau, Ministry of Economic Affairs ) Is 0.01 to 100, and preferably 0.1 to 50 g / 10 minutes. Preferably, LLDPE is ethylene and a Or more interpolymers having 3 to 18 carbon atoms (preferably 3 to 8 carbon atoms) formed from other alpha-homing hydrocarbons. Preferred comonomers include 丨 · butene, 4-methyl-1 -Pentene, 1-hexene and i-octene β Furthermore, there is a class of substantially linear olefin polymers (SLOP) which can be advantageously used for component (B) of the blends of the invention. These polymers It has processing properties similar to LDPE, except for strength and flexibility. Similar to traditional homopolymers, the substantially linear ethylene / α-olefin inner polymer has only a single melting peak. In contrast, traditional Ziegler polymerization is not The homogeneous linear ethylene / α · olefin inner polymer has two or more melting peaks (determined using a differential scanning calorimeter). Substantially linear olefin polymers are disclosed in U.S. Patent Nos. 5,380,810; 5,272,236 and 5,278,272, These are incorporated herein by reference. SLOP densities measured in accordance with ASTM D-792 are generally 0.85 g / cc to 0.97 g / cc ′ compared to 0.85 g / cc to 0.955 g / cc, and in particular g / cc to 0.92 g / cc 〇SLOP melt index (according to ASTMD-1238, conditions 190 ° C / 2.16 kg (also known as 12))-generally 0.01 grams for 80 minutes To loooo g / 10 minutes, preferably 0.01 g / 10 minutes to 100 g / 10 minutes, especially minutes to 10 g / 10 minutes. Furthermore, it also includes ultra-low molecular weight ethylene polymers and ethylene / α-olefin inner polymer, which is described in WO Patent Application No. 97/01181, entitled "Ultra-low Molecular Weight Polymer", filed on January 22, 1997, which is incorporated herein by reference. These ethylene / 〇; -olefin interpolymers have 12 fused paper sizes and are applicable to China National Standards (CNS) A4 (210X297 mm) (please read the note $ on the back before filling this page) Benz · Order 22 A7 B7 Printed by the MIC Industrial and Consumer Cooperation Department of the Central Rubbing Bureau of the Ministry of Economic Affairs. 5. Description of the invention (20) The melt index is greater than 1,000, or the number average molecular weight (Mn) is less than 110,000. With 2 to about 20 carbons A more preferred homopolymer or inner polymer of the atom and the aliphatic α-olefin optionally containing a polar group is a homopolymer of ethylene; a homopolymer of propylene, at least the other of which contains 4 to about 8 carbon atoms Copolymers of alpha olefins; propylene and at least other copolymers of α-dilute hydrocarbons containing 4 to about 8 carbon atoms; ethoxylates at least one acrylic acid, ethyl acetate, maleic anhydride, or propylene Copolymers of dilute nitriles; acrylic copolymers of at least one acrylic acid, vinyl acetate, maleic anhydride or acrylonitrile; and ethylene, propylene, and dilute dimers, especially LDPE , HDPE, uneven and uniform LLDPE, SLOP, polypropylene (ρρ), special isotactic polypropylene and rubberized polypropylene Ethylene-propylene copolymer or the (EP), or ethylene _ 6 hexenyl acetate copolymer, or an ethylene-acrylic acid copolymer, or any combination thereof. Particularly preferred are the above-mentioned substantially random interpolymers containing about 5 to about 99% (preferably about 10 to about 95%, more preferably about 20 to about 80¾) and about 95 to about 1 ° / 〇 ( It is preferably about 0 to about 5 ° / ° ′, more preferably about 80 to about 20%) of two or more of the above-mentioned aliphatic α-olefins having 2 to about 20 carbon atoms or having 2 to about 20 Blends made from homopolymers or internal polymers of carbon atoms and polar olefin-containing olefins are based on the total weight of the blend. Floor, wall or ceiling coverings prepared from or containing this blend have been found to exhibit surprisingly good abrasion resistance as an upper layer. In a preferred aspect of the present invention, the blend contains about 50 to about 99% (preferably about 60 to about 95% 'more preferably about 70 to about 90%) of the above-mentioned substantially random inner polymer and about 1 to about 50% (preferably about 5 to about 40%, most preferably about 10 to about 30%) one or more of the above-mentioned aliphatic α-cloth paper having 2 to about 20 carbon atoms National ladder ^ 7 (CNS) from the threat (21 () > < 297) and m I — I! I— I — I-I i-I _ ^, r (Please read the notes on t (Fill in this page again) 23 A7 B7 V. Description of the invention (21) Olefins or homopolymers or inner polymers of α · dilute hydrocarbons with 2 to about 20 carbon atoms and containing polar groups, which are based on the total amount of the blend. Weight as the basis. Floor, wall or ceiling coverings containing this blend generally exhibit good indentation resistance and excellent scratch resistance at high loads. Furthermore, floors, walls or ceilings containing this blend Ceiling coverings generally exhibit good corrosion resistance. The floor, wall or ceiling covering of the present invention may contain fillers. If present, the amount is generally up to about 95%, preferably about 10 to about 90%, More preferably about 30 To about 85%, it is based on the total weight of the floor, wall or ceiling covering. The preferred amount of filler is generally changed according to the desired rigidity and application mode of the floor, wall or ceiling covering. Floor, The wall or ceiling sheet is preferably free of filler. However, if it contains a filler, the thickness of the filler is preferably about 10 to about 70%, more preferably about 15 to about 50%. The total weight is the basis. The floor porcelain monument, wall tile or ceiling porcelain monument should preferably contain about 50 to about 95%, more preferably JlJO to about 90%, more preferably about 70 to Approximately 90% of the filler is based on the weight of the floor, wall or ceiling covering. The dilute hydrocarbon / ethylene-bound interpolymer surprisingly demonstrates the high compatibility of different fillers. Useful fillers include organic and inorganic Fillers, such as wood, wood fillers, such as wood powder or wood fiber, paper fiber, corn-like, grass cutting, cotton, carbon black or graphite , Fiberglass, marble ash, cement ash, clay, feldspar, hair stone or Glass, black dream stone, oxidized oxide, oxidized oxide, barium sulfate, dream acid, dream acid angle, titanium dioxide, thorium titanate, glass microspheres or chalk. Among these fillers, sulfuric acid-based paper- -------------- IT (Please _ read the face-free precautions before filling out this page) 24 V. Description of the invention (22 A7 B7 Printed by the Offshore Consumer Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs Stupid, talc, broken stone, barium sulfate, hair stone / glass, glass woven alumina and titanium dioxide and mixtures thereof are preferred. As used herein, "a mixture containing different fillers. The term flooring, wall or Preferred ceiling coverings are compounds that are substantially free of element I, such as, for example, polyethylene gas, polyethylene gas, or flame retardants containing element. The term "compounds which are substantially free of dentin" means that the general content of i-containing compounds is not more than about 10%, preferably not more than 5%, more preferably not more than about 2%, and the best More than about 1%, based on the total weight of the floor, wall or ceiling covering. Most preferably, the floor, tent wall or sky It »board cover of the present invention does not contain any measurable amount of a halogen-containing compound. The floor, siding, or ceiling coverings of the present invention may contain one or more additives, for example, antioxidants, such as' blocked or arsenic acid; light stabilizers, such as, hindered amines; plasticizers, such as, two Octylphthalic acid or epoxidized soybean oil mash thickeners, such as known hydrocarbon thickeners; Yuru, polyethylene glycol; processing aids, such as stearic acid or its metal salt; cross-linking Agents such as peroxides or silanes; toners or pigments in amounts that do not interfere with the good fit, scratch resistance and / or scratch resistance of the floor, wall or ceiling covering of the present invention to uneven or contoured surfaces and / Or indentation recovery. Additives can be used with functional equivalents known to those skilled in the art, generally containing up to 30% by weight, preferably about 0.01 to about 5%, more preferably about 0.02 to about 1% by weight , Wall or ceiling covering weight. The floor, siding or ceiling coverings of the present invention generally have a thickness of

I Side-by-side paper size Quick-use Chinese National Standard (CNS) A4 size (210X297 mm) 25 Printed by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs A 7 B7 V. Description of the invention (23) About 0.025mm to about 25mm, It is preferably about 0.1 mm to about 10 mme. The floor coating preferably has a thickness of about 1 mm to about 10 mm, more preferably about 1 mm to about 5 mm, and most preferably about 1.5 mm to about 4 mm. The wall covering preferably has a thickness of about 0.1 to about 3 mm, more preferably about 0.5 to about 2 mm, and most preferably about 0.5 to about 1.5 mm. 〇 In a preferred embodiment of the present invention, the floor, wall or The ceiling covering is a single layer structure containing the above-mentioned substantially random inner polymer and selective additives. The thickness of the single layer structure is preferably about 0 025 nmi to about 15 mm, and more preferably about 1.5 mm to about 4 mm. In another embodiment of the present invention, the floor, wall or ceiling covering contains at least two layers, wherein at least one layer (A) contains one or more of the aforementioned substantially random inner polymers. The layer (A) generally contains about 5% to about 100%, preferably about 25 ° /. To about 100%, more preferably about 40% to about loo%, and most preferably about 800/0 to about 100%. The above-mentioned random inner polymer is based on the total weight of layer (A) As a benchmark. Layer (A) may contain one or more additional optional polymers and other optional additives, such as fillers (as described above, if the layer contains additional optional polymers, the above conjugates are more If β is present, its content is generally from 0% to about 80%, preferably from 0% to about 60%, and more preferably from about 20% to about 60%, which is the total of layer (A). Weight is the basis. The thickness of the layer (A) is preferably from about 0.25 mm to about 2 mm, preferably from about 0.060 mm to about 1 mm, and more preferably from about o.imm to about 1 mm. Layer (A) May represent the top, bottom, and / or bottom of the floor, wall, or ceiling covering of the present invention. Regardless of whether layer (A) is the top, cross, or bottom 'its modified floor, wall, or ceiling covering material The paper size of the wall applies the Chinese National Standard (CNS) A4 specification (210 >: 297 mm) (please read the precautions on the back before filling in this X) Α7 Β7 V. Applicability of invention description (24) 'It can be applied more easily and can make floor, lintel or ceiling coverings Keep flat on the floor or pickled wall. Furthermore, the layer generally provides good indentation resistance to multi-layer structures, regardless of whether layer (A) represents the top layer, the body layer or the bottom layer. The better layer (A) represents the top layer It provides excellent scratch resistance of a multilayer structure. ”Preferably, the floor, wall or ceiling covering of the present invention contains the above-mentioned layer (A) and one or more additional polymeric layers (B). Preferred polymers are the aforementioned monovinylidene aromatic polymers, styrenic block copolymers, or more preferably 'aliphatic alpha-olefins having 2 to about 20 carbon atoms or having 2 to about 20 carbon atoms And a homopolymer or inner polymer of an olefin containing a polar group. In addition, the 'layer (B) may contain one or more of the above-mentioned substantially random inner polymers, wherein the vinylidene monomer in the inner polymer in the' layer (B) The average molecular content of the rhenium component is different from that of the single molecule of the vinylidene component in the inner polymer in the layer (A). The layer contains (J). The layer (B) generally contains about 5% to about 10%. The above polymer is about 15% to about 100%, more preferably about 40% to about 90%, and most preferably about 60% to 80%. Based on the total weight of layer (B). Layer (B) may contain one or more additional optional polymers and / or one or more other optional additives, such as fillers (as described above). If present The content of the filler is generally about 10% to about 90%, preferably 10% to 75%, and more preferably about 30% to about 50 ° /. It is based on the total weight of the layer (B). The thickness ratio between the layer (A) and the layer (B) is preferably about 0.000 :: 1 to about 10: 1, more preferably 0.1: 1 to about 5: 1, and most preferably about 0.2: 1. To about 5: 1 This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X297 mm) ----------- 'Clothing —.-' (≪ Please read the note on the back of $ Please fill out this page again), ΤΓ 27 V. Description of the invention (25 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs The floor, wall or ceiling covering of the present invention may contain one or more outer buccal layers, which are floor, It is common in wall or ceiling coverings, such as one or more adhesive layers and / or one or more decorative layers. The decorative layer can be placed on top of layer (A), however, it is preferably placed between layer (A) and layer (B). The above-mentioned substantially random interpolymers can be combined with selective additives, and the floor and wall coverings of the present invention can be treated by any suitable method known in the art, including, for example, Banbury mixing, chemical compounding, rolling Grinding, calendering, compression grinding, injection molding and / or sheet extrusion. The useful temperature of the substantially random inner polymer of the inventive floor, wall, and ceiling coverings is mixed with the treatment and the selective additives, and the useful temperature is generally about 100 ° C to about 300 ° C, and more preferably about 120 ° C. 〇 to about 250 eC, more preferably about 140 eC to about 20 (TC »The floor, marinated wall or ceiling covering of the present invention may be foamed or may contain one or more foamed layers. In particular, the above-mentioned substantially no Layers of gauge internal polymers and / or one or more of the above additional polymer layers, if present, may be foamed. One-the foaming «layer may be formed by extrusion or by an expandable or foamable layer Particles, moldable foam particles, or pellets that can be formed by expanding and / or agglomerating and fusing these particles to form a sheet. "The foam structure can be prepared by traditional extrusion foaming methods. The structure is generally prepared by heating the polymer material to form a plasticized or molten polymer material, incorporating a known foaming agent to form a foamable gel, and pressing the gel to form a foamed hydrazone product. The polymer material is heated to its glass transition temperature or melting point or higher before mixing with the blowing agent. The blowing agent can be added or known by methods known in the industry, such as extruder, mixer or blender. Mixed paper sizes are applicable to China Solid Standard (CNS) A4 (210X29 7mm) (Please read the note f on the back before filling this page) Γ va 28 Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 _ _B7____ 5. Description of the invention (26) Into the molten polymer material " The foaming agent is fused with the fused polymer material under a sufficient pressure to avoid substantial expansion of the molten polymer material and uniformly disperse the foaming agent. Optionally, the nucleating agent may be used before plasticizing or melting. Incorporated into polymer melt or dry blended with polymer materials. Foamable gels are typically cooled to lower temperatures to achieve the best physical properties of the foam structure. The gel then passes through Deformed chess pieces are extruded or conveyed to a reduced or lower pressure area to form a foaming structure. The mold may have nozzles that are substantially rectangular to prepare a sheet of the desired width and height. In addition, the mold may have several nozzles To prepare polymer strands, which can be cut into beads. The lower pressure areas are those below the pressure at which the foamable gel is maintained before being extruded through the mold. The lower pressure may be superatmospheric or subatmospheric (Vacuum), but more It is at atmospheric pressure. The foam structure can also be formed into foam beads suitable for molding. To prepare this foam bead, individual resin particles (such as granular resin ingots) are suspended in a liquid state. In the medium, it is more qualitatively insoluble, such as water; due to the autoclave or other pressurized volume, when the pressure and temperature are increased, the foaming agent is introduced into the liquid medium to make it foam. Meanwhile; rapid injection into the atmospheric pressure or decompression zone to expand to form foam beads. This method has been taught in US Patent Nos. 4,379,859 and 4,464,484, which are incorporated herein by reference. The foam beads may then Molding is by any method known in the industry, such as injecting foam beads into a mold, compressing the mold to press the foam beads, and such as heating the beads with steam to coalesce and weld the beads to form an object. Optionally, before it is injected into the mold, Zhuzhu can apply China® home kneading rate (CNS) (21GX297 mm) with air or Shizuku when increasing the pressure ~ (Please read the precautions on the back before filling in this PAGE} Order 29 Printed by the Central Ministry of Economic Affairs of the Central Ministry of Health and Welfare Bureau Co., Ltd. Printed A7 _iz__ Five 'Invention Description (27) Other foaming agents are impregnated. Furthermore, the beads can be heated before injection. Then, the beads Sheets can be molded by suitable molding methods known in the industry. Some methods are taught in U.S. Patent Nos. 3,504,068 and 3,953,558. Various additives can be added to the structure of the foaming vessel, such as stability control agents, Nucleating agents, inorganic fillers, colorants, antioxidants, acid scavengers, UV absorbers, flame retardants, processing aids or extrusion aids. Some additives have been described in detail above. Particularly preferred are floor sheets Floor monuments, wall tablets and wall monuments β It can be used in private and public buildings. It can also be used for covering floors outside buildings, such as balconies and flat roofs. Flooring, walls and especially ceiling coverings of the invention Can also be used as a sound attenuating material • The floor, wall or ceiling covering of the present invention can also be used in geological areas, such as caves or tunnels, instead of PVD. The floor, wall or ceiling covering of the present invention has several properties that make it It depends in particular on the desired end purpose. Depending on the selected type and content of the substantially random and selective additives, the floor, wall or ceiling covering of the present invention has some or all properties such as good resistance Indentation, indentation recovery, good flexibility and adaptability on contours or uneven surfaces, good scratch resistance and / or good abrasion resistance β Furthermore, the floor, wall or ceiling of the present invention The covering may be a compound that is substantially free of molybdenum. Furthermore, when a filler is included in a floor, wall, or ceiling covering, a coupling agent is generally not required. Surprisingly, the floor, wall, or ceiling covering of the present invention (It contains the above-mentioned substantially random inner polymer) Generally, it can contain 70 heavy paper tBIB furniture standard (CNS) Α4 secret (210X297 mm) --- -30--------- --Water ------ 1T r * ( Please complete the note on wt # 1r first and then fill out this page) Printed by A7 _________ B7 of the Central Standards Bureau of the Ministry of Economic Affairs Ⅴ. Description of the invention (28) Filler content of% or more, in many cases, even 80% by weight or more, and typically up to 95% by weight, without the need for a coupling agent, and still exhibit good filler retention and good solid state properties. This is unexpected because many of the above-mentioned f Random inner polymers are mostly unfunctionalized. General adhesives (such as acrylic or styrene / butadiene based adhesives) can be used to fix floor, wall or ceiling coverings to the floor , Wall or ceiling. Adhesion promoting engraving (such as corona surface oxidation or flame treatment or acrylic primer) is generally not required in combination with these adhesives. The following example is used to illustrate the present invention. These examples are not intended to limit the scope of the invention and are not intended to be interpreted as such. The content is the number of heavy directors or the percentage of heavy directors (unless otherwise indicated). The properties of the tested polymers and compounds are determined by the following test procedures: A) Test methods for all examples Melt Index (MI) is determined by ASTM D-123% 1979), condition E (190 ° C; 2.16 kg ) Determine it. The hardness is measured according to DIN 53505 using hardness testers for A and D. B) Box. Test method of Example 1 to 34. pat. ¾ strong; t, secant die and extension, and use ASTM D038, type C to determine. • In response to disease tests, ASTM F 142-93 (Flexible Flooring-McBurney) This paper is sized for China National Standard (CNS) A4 (210X297 mm) 1 n I n ϋ ϋ IIIIII ———. Order > · / u ... (please read the precautions before reading this page, and then fill out this page) 31 Printed by the Central Ministry of Economic Affairs, the Bureau of Industrial and Consumer Cooperatives, A7 _____B7___ V. Description of the Invention (29) Standard Test Method for Indentation Testing) and Improved Testing used. In the improved test, a load of 140 pieces (64 kg) was applied via a 4.5 mm diameter cylindrical foot. The load was applied for 10 minutes and the initial indentation was measured. The residual indentation was measured after 60 minutes. For the improvement test, the indentation is reported as a percentage of the initial sheet thickness. For the residual indentation, if the cylindrical indentation is sufficient to permanently cut and damage the surface, the sample is rated as "Fail". The I1IOOL system uses a device 90. The Erichson Universal Scratch Tester for the -180 diameter stylus is done. A load of 0.1 to 10n was applied to this stylus' and the resulting loss width was measured at 30 days using a Perthen Surface Profiler. Scratch width and depth are expressed in micrometers》

Taber abrasion is tested according to ASTM F-510. The flexural modulus is measured using ASTM D790-95A. "C) The method of Example 35 to 83. DIN abrasion is determined according to DTN 53516, which is measured at 10N. Tonke bends hard to snuggle DTN 53121 at a temperature of 22 ° C. ^ No relaxation time shown in Tables 7 to 9. The final resistance was tested against Zhang Qiangqiang and Zhengxiancunnon 埴 DIN 53504, and the sample S2 was tested at a cross speed of 50mm / min. The "roller 后" was measured by passing a 50-mm diameter roller loaded with 25 liters of mass at a frequency of 21 weeks / minute on a 26cm X 2cm floor sheet. The creep was measured at 20,000 weeks (16 hours) and after 8 hours of recovery "" Fuyao and argon are measured in accordance with ISO 8295 for those who use floor cleaning cloths. This paper size applies the Chinese National Standard (CNS) Α4 specification (2 丨 〇 < 297 mm) — ^ 1 · I--II-III — 1 II r 4 « Please fill in this page again for details) 32 V. Description of invention (30) A7 B7 The central government of the Ministry of Economic Affairs and the Shellfisher Consumer Cooperative Co., Ltd. printed the scratch depth, depending on the brake supply and the inspection limit by imposing 1N and Measured with a triangle knife for loads between 14N. The visual scratch level indicates the load at which scratches can be seen. Inspection limits indicate scratches that can be felt by the fingers. Indentation resistance (i.e., the first indentation after 150 minutes of shrinkage, the last indentation after 150 minutes of relaxation time, and percent recovery) are measured in accordance with DIN 51955. Compression set is measured at 23eC according to DIN 53517 after relaxation time at 504+. Preparation of Yi Jiao / Mo Yi Yi Cohesive J ^ ESI-l, ESI-2, ESI-4, ESI-5, ESI-6 and ESI-7 Reactor Description The single reactor used is 6 plus (22.7 liters) , Oil jacket, autoclave continuous stirred tank reactor (CSTR). A magnetically coupled agitator with lightning strike A_320 provides mixing. The reactor was filled with 475 psig (3,275 kPa) operating fluid «. Operational flow = done inside bottom and top outside. The heat transfer oil is circulated through the reactor to remove some reaction heat. After flowing out of the reactor, a micro-flow flow meter was configured to measure flow and solution density. All lines at the reactor outlet were traced and isolated with 50 psi (344.7 kPa) vapor. Ethylbenzene solvent was supplied to the small plant at 30 psig (207 kPa). The feed to the reactor was measured with a microkinetic mass flow meter. The variable-speed diaphragm pump controls the feed rate. At the solvent pump discharge side flow was used to provide a flush of catalyst injection line (1 lb / hr (0.45 kg / hr) and reactor agitator (0.75 lb / hr (ο.% Kg / hr). These flows Read first note measured by differential pressure flow meter

I Binding This paper size is in accordance with China National Standard (CNS) A4 specification (210X297). _B7________ V. Description of the invention (31) Manually controlled by micro-fluid needle valve. Unhindered benzene-6ene monoblock was supplied to a small plant at 30 psig (207 kPa). The feed to the reactor was measured using a microkinetic mass flow meter. Variable speed film pump controls the feed rate. The styrene stream was mixed with the remaining solvent stream. Ethylene was supplied to small plants at 600 psig (4,137 kPa). Ethylene flow was measured with a micro-movement mass flow meter before the flow-controlled research valve. The Bruce Flow Controller / Controller is used to transport argon into the ethylene stream at the outlet of the ethylene control valve. The ethylene / hydrogen mixture is mixed with the solvent / styrene stream on a peripheral surface. When entering the reactor, the temperature of the solvent / single unit was reduced to about 5 ° C with an exchanger with -5 ° C ethyl acetate on the jacket. This stream enters the bottom of the reactor. The three-component catalyst system and its solvent flushes also enter the reactor at the bottom, but through different outlets of the non-monomer stream. "To prepare Esn, ESI-2 and ESI-4, ESI-5, ESI-6, and ESI- 7, (Third butylamido) dimethyl (tetramethylcyclopentadienyl) silane titanium (11) 1,3-pentadiene is used as a titanium catalyst, and modified methylaluminum oxide Azole (type 3A (MMAO-3A, commercially available from Akzo) was used as the second catalyst component. The boron catalyst used was tris (pentafluorophenyl) boron to make ESI-1 and ESI-2) or bis-argon. Tallow alkylmethylammonium tetrakis (pentafluorophenyl) borate (used to prepare ESI-4, ESI-5, ESI-6 and ESI-7). To prepare ESI-1, the boron cocatalyst has a molar ratio between titanium catalyst of 3: 1, and the molar ratio between MMAO and titanium catalyst is 8: 1. To prepare ESI-2 and ESI-4, the molar ratio between the boron cocatalyst and the titanium catalyst was 2: 1, and the molar ratio between the MMAO-3A and the catalyst was 5: 1. To prepare ESI-5, ESI-6 and ESI-7, the molar ratio between the boron cocatalyst and the titanium catalyst is 1.25: 1 'and the molar ratio between the MMAO-3A and the titanium catalyst is 12: 1. The production of catalyst components has been carried out in an inert atmosphere box. Diluted components This paper is again applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 34 A7 ____B7 _ V. Description of the invention (32) is placed in a nitrogen-filled cylinder and injected into the catalyst operation tank in the processing area . From these operation tanks, the catalyst was pressurized by a piston pump, and the flow rate was measured by a micro-mass flow meter. Before entering the reactor through a single injection line, these fluids are mixed with each other and mixed with a catalyst flush solvent. Printed by the Central Economic and Technical Bureau of the Ministry of Economic Affairs of the People's Republic of China, I—II—I! 'Yi Yiyi IIII —-Order t. V., (Please read 1 ^-面 的 面 $$ Item before filling in this Page> After measuring the solution density with a micro-motion flowmeter, add a catalyst inhibitor (water mixed with solvent) to the container product to stop the polymerization reaction. Other polymer additives can be added with the catalyst inhibitor. Static mixer on the pipeline Dispersion of catalyst inhibitors and additives in the reactor effluent is provided. This stream then enters the post-reaction heater, which provides additional energy for solvent removal and flash evaporation. This flash evaporation is generated after the effluent is heated out of the reactor At the reactor pressure control valve, the pressure was reduced from an absolute pressure of 475 psig (3,275 kPa) to about 250 mm. This flash polymer entered the hot oil jacketed exhauster. About 85% of the volatiles came from the exhauster. The polymer is removed. The volatile matter leaves from the top of the exhauster. The stream is concentrated by the ethione jacketed exchanger and enters the vacuum pump aspirator, and it is discharged to the ethylene glycol jacketed solvent and the styrene / ethylene container. Solvent and styrene from bottom of container Removed and ethylene is removed from the top. The ethylene flow is measured with a micro-mass flow meter and the composition is analyzed. The measured ethylene discharged and the gas cross dissolved in the solvent / styrene flow can be used to calculate the ethylene conversion. In the exhaust The separated polymer is pumped to the ZSK-30 exhaust vacuum extruder by a gear pump. The dry polymer flows out of the extruder in a single strand. When passing through a water bath, the strand is cooled. Excess water is blown out by air from this strand And this strand is cut into granules with a strand cutter. The monomer content and polymerization conditions are provided in Table 1A, and the polymerized polymers of ESI-1 to ESI-8 are provided in Table 1C. The paper dimensions apply to Chinese national standards ( CNS) A4 specification (210X297 mm) 35 A7 B7 V. Description of the invention (33) Table 1A Reactor concentration solution # 1 stream B i Greek stream hydrogen stream styrene stream Ethylene reactor conversion rate: eC _ 碡 / 小 域Kg / h * / hour kg / small_ SCCM small-kg, small 崦% ESI-1 62.1 10.4 4.72 1.2 0.54 20.0 12.0 5.45 77.7 ESI-2 84.3 17.6 7.99 1.9 0.86 27.6 20.6 9.35 75.6 ESZ-4 76.0 16.4 7.44 1.2 0.54 7.0 10.0 4.54 90.5 ESI-5 64 .8 14.0 6.35 1.2 0.54 0.0 20.0 9.08 87.3 ESI-6 68.7 Ϊ1.0 4.99 1.4 0.64 6.0 23.0 10.4 4 86.4 ESI-7 109.7 12.0 5.44 2.3 1.04 2.7 13.0 5.9 84.3 I --------- ί '^ .------ IT (please read the 1r-side precautions before filling out this page) Printed by the Central Ministry of Economic Affairs, Zhengong Consumer Cooperative, to prepare ESI-3 polymer Prepare in 400 (1514 liters) stirred semi-continuous batch reactors. The reaction mixture consisted of approximately 250 gallons (946 liters) of styrene and a reagent containing cyclohexane (85% by weight) and isopropane (15% by weight). Upon addition, the solvent, styrene and ethylene were purified to remove water and oxygen. The suppressor in styrene was also removed. The inert material was removed by stripping the vessel with ethylene. The container is pressurized with ethylene to the curing point. Argon was added to control molecular weight. The temperature in the container is controlled by changing the temperature of the jacket water on the container at the curing point β before the polymerization reaction. The container is heated to the desired operating temperature, and the catalyst component, namely (third butyl amidino) dimethyl ( Tetramethyl · S_cyclopentadienyl) silyl dimethyl titanium (IV) catalyst, CAS # 135072-62-7, tris (pentafluorobenzene paper size), China National Standard (CNS) A4 specification ( 210x297 male dust) 36 Α7 Β7 V. Description of the invention (34) base) boron, CAS # 001109-15-5, modified methylalumoxazole 3A type, CAS # 146905-79-5, its flow is controlled, Add each to the dissolver based on the ratio of 1/3/5 Mol. After the start, the polymerization is treated with the ethylene supplied to the reactor, which is necessary for maintaining the pressure in the vessel. In some cases, argon was added to the reactor head to maintain a mole ratio related to the ethylenic degree. At the end of the operation, the catalyst flow was stopped, ethylene was removed from the reactor, approximately 1000 ppm of Irganox 111 1010 antioxidant was added to the solution, and the polymer solution was isolated. The polymer formed is isolated from the solution by steam stripping in the vessel. In the case of steam stripping materials, additional considerations are necessary in devices such as extruders in order to reduce residual moisture and any unreacted benzohexene. (Please read the notes on the back before filling this page) Order The monomer content and polymerization conditions are provided in Table 1B. Table 1B. Samples are prepared under load and then loaded with styrene. Pressure and temperature are added ^ h2 Operating time Polymers in solution. Pounds kg-lbs kg Psig KPa ° C Gram hours ESI-3 252 114 1320 600 40 276 60 23 6.5 18.0 Ministry of Economy The Central Government Bureau of Standards and Printing Co., Ltd. printed M prepared ethylene / jasmine ethylene copolymer ESI-8 and ESI-8 by dry blending at 80 weight. /. The ethylene / styrene inner polymer ESI-5 and 20 wt / o 6ene / phenhexene inner polymer ESI-6 were prepared. This paper is based on the Chinese National Standard (CNS) A4 specification (2 丨 0 parent 297 mm) 37 B7 V. Description of the invention (35 Table 1C Inner polymer Tg Melt index Total styrene ethyl roasting% (MMR) B Styrene (NMR) in dilute / styrene inner polymer ° C g / 10 min Mole% by weight Mole% by weight ESI-1 na * 2.0 30.3 60.0 na * na * ESI-2 na * 30.0 32.0 62.0 10.3 28.4 ESI-3 25 1.8 46.1 74.8 43.4 72.7 ES: C-4 17 2.2 41.3 70.9 40.2 70.0 ESX-5 25 2.4 49.1 77.0 44.9 73.8 ES1C-6 14 1.3 46.1 74.8 37.0 67.1 ESI-7 -18 4.0 22.5 50.2 13.9 35.9 ESI-8 24 1.3 47.7 76.0 42.6 72.0 Please _ read back-note above

I t Not analyzed. Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperative. The paper dimensions are applicable to the Chinese National Standard (CNS) A4 (210X297 mm). 38 V. Description of the Invention (36) 笫 2 Table: Used in the example Product name abbreviations for other material densities Melting index (g / 10 cents pounds) igm / cc, ITP-2 0.902 AFFINITY ™ DSH 1500.00 (hexene-1-octene copolymer) 1.0 ITP-3 0.871 AFFINITY SM 8400 (ethylene- 1-octene copolymer) 30.0 ITP-4 0.902 AFFINITY SM 1300 (ethylene-1 · octene copolymer) 30.0 VP 8770 0.885 AFFINITY ™ VP 8770 (ethylene-1-octene copolymer) 1.0 LD 150 0.921 Low density polymer Ethylene 0.25 HD 53050E high density polyethylene 0.952 15 = 0.3 HD 35060E high density polyethylene 0.952 0.29 PE-g-MAH Dow XU-60769.04 2.5 0.955 (maleic anhydride grafted polyethylene, of which 1.0% of maleic acid) CaCo3 Pfizer ATF-40 (Gritted Limestone, and Silk Mesh) Oil SHELLFLEX ™ 371 This paper size applies to China National Standard (CNS) A4 (210X297 mm) 39 B7 V. Description of the Invention (37) Examples 1 to 33 Examples 1 to 33, sheet It said system near by the following steps of: (Read precautions to fill out the back of the page) mixing bowl; 2) roll milling, and 3) compression molded sheets. Use the Haake mixer equipped with Rheomix 3000. All components of the blend were added to the mixer and the slewing wheel was at 190. (: Operate at 40 rpm for 10 to 15 minutes. The material is poured out of Haake and fed to a 6-inch diameter X 12-inch wide Farrel two-roll mill (the surface temperature is set to 175.0 °). 〇 ° C after winding or 540 ° before winding.

Pasadena Hydranlics Incorporated (PHI) Ink Condenser Compressed Chess is made into 3 · 175ιηη thick X 101 · 6ιηπι X 101 · 6πιπι thin plate. Compression is in a preheating mode of 205 ° C and operates for 3 minutes at minimum pressure, and increases to a maximum of 15 tons for 2 minutes. The sheet was removed by heating and cooled at 15 tons for 3 minutes. The properties of the compression-molded sheet are measured as described above. Tables 3, 4 and 5 show examples 1 to 31 and comparative examples 32 and 33 according to the present invention (not in the range of this month, but not customary). The composition and physical properties of Chipan) are 0% filling, 60% filling and 85% filling formula, respectively. This paper size applies to the Chinese national standard (CNS > M specification (210X297mm) 40 A7 B7 V. Description of the invention (38) Printing by the Central Samples Bureau of the Ministry of Economic Affairs, Consumer Cooperatives Hardness-Shore A Hardness-Shore D Elongation at break (%) · Pull modulus (MPa) (MP sentence 2% secant amount (MPa) Ρί Niang-1 e ITP-2 ITP-1 〇-ϋ! ^. _. 二 Ί l !!! i _: _: __ ESI-1 CaC03 contention; abnormal II l. 65.6; 19.4 776 20.44 5.79 7.97 ij 100 o III 96.8 61.6 304 138.6 13.61 13.61; 'i.! .i;; * l; 100 oj l '· L_ ”88.6 38.8 382 8.94 8.01 10.01 I o σ > Μ 435 20.20 3.79 9.62 I ΙΟ! ° j;! :: l |. L · got to st 295 140.3 23.50 13.10 I ° IIIJI 1 ixo I! I! Ul w. 96.6 54.8 318 144.8 ... 35.62 12.69 JII i 1 >.: V 3 o II m U 86.2 35.8 450 47.83 16.64 9.03 III g I i I 丨 '丨. I igo 78.8 36.6 476 12.02 11.75 8.13 S i' ; M 'r' o 1 p .; i refute—grass (girl reads 1r-face precautions before filling out this page) Order • In m 1 ^ 1 This paper size is not used China National Standard (CNS) A4 specification (210X297 mm) 41 A7 B7 V. Description of invention (39 t

I Printed by the Shellfish Consumer Cooperative of the Central Government Bureau of the Ministry of Economic Affairs

Taber (111) 5/100 rev) Scratch depth (Hui Mi) 蛊: Gold ζ ?. S; 3 1.!: I. Residual indentation WkgC%) Mark ^ 641¾ (% of thickness) «mark -14kg-10 minutes (mil) hemp 1 now. S Γ- ~ ► r »ve} ψ- ί« h 1 Q * «« S αι s SJ .i: J * — *) 1.86 1.63 (Ο 〇 > Cl 00 μ l :: S 1.08 〇 »〇3: \ .σ > ο ο» Ή} 0.28 —η:. Cn 3 u _ i 3.24 1.28 η 00 j _ i: 1 Μ ΟΙ Κ) -m 2.78 IO σ > /, Bu: οι σ > Μ i 2.16 Π !: 珲.:;! 〇 < D entangled We 1.78 〇 *,! f Ο Κ > ro GO i .meaning! ^ n--- -1---- ^^ 1 -I — ^ 1 --- AI-B ^ — · I— 1 ^ 1 > I (Notes for reading the t surface before filling this page) This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) 42 A7 B7 V. Description of Invention (40) Examples 1 to 8 of Table 3 illustrate floor, wall or ceiling coverings containing the above-mentioned substantially random inner polymer Has well-balanced properties such as low flexibility modulus (which means high flexibility), sufficient resistance to indentations and scratches, and The PVC material of Comparative Example 34 has improved scratch resistance. The products of Examples 1 to 8 are used as unfilled uniform floor coverings or as individual layers in non-uniform structures. In addition, the amazing scratch resistance of ethylene / styrene inner polymers (which have at least about 60% by weight, about 30 mole% of polystyrene), as in the third example, makes these materials suitable as The wear layer or surface layer β of the floor covering of the present invention (please read the precautions on the back before filling in this card) 丨 Department. ≪ τ The printed paper of the Ministry of Economic Affairs Central Central Standards Bureau Real Industrial Consumer Cooperative Society is applicable to China CNS Α4 Specification (210X297mm) 43 V. Description of the Invention (41) Detailed Xiangti 2i * i 〔

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(Please read the precautions on the back before filling in this page) The size of the paper used in this edition applies to the Chinese National Standard (CNS) A4 specification (210 × 297 mm) 44 A7 B7 V. Description of the invention (42 Central Government Bureau of Ministry of Economic Affairs, Consumer Cooperative) Printed Η1 * 金 I 1 " qJT 洚 £ H 谇 s' itch WI i -1 :): i. 丨: i # m 漭 1 3 1 hemp 1 I * 1 丨 s Μ 1 N— * 1 m Μ 1 ”: W, 1 〇σ» 〇a _4i σ > S μ BU Γ C »< 〇Ν > S π zd. j 4i Ol 00 5 ° 00 < Λ φ 'Ν) 00 00 three rp i \ -λ in 2 a »ν, Λ ** * ·: ϊ · 1 • A s .1,. 1 a1: 1»-si 〇 »b > s ο 1 (D '(Σ', 1 triple tt VU ^ aaa > M_ Ol C3 00 Of 阙 bkikJ Heart 1 w Ι-``々i'.h VV'1 O) o σ > Γ °; ί Λ1 1. 厶 丨 1! •. · 1 Ol; «CO go _ m 〇 > eo 00 S riF " s i1 f-: O μ Μ love SSn Bu He ία i ·, Ί— Ol s 3 i, τ σ > ΰ _ ._ ... i): one, ί Ά · Ι J t ..:-• to S s' • s; 00 μ 〇% is) to ^ s | * v | OL · μ • Jk _ 面 f # (Please read the precautions on the back before filling in this ) 袈 · The size of the paper is applicable to China National Standards (CNS) A4 specification (210 × 297). 45 A7 ---------- V. Description of the invention (43) Examples 9 to 18 show that no additives or polymerization are required. Coupling agents to achieve good filler retention and solidity. The products of Examples 9 to 18 can be used as filled uniform floor coverings or as individual layers in non-uniform structures. The products of Examples 9 to 18 are particularly suitable for floor sheet products. --------- t ^ ------ Order (read it ', read the t-side note f, then fill out this page) Printed by the Consumer Affairs Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Paper is also * · Applicable to China National Standard (CNS) Α4 size (210X297 mm) _ -46-

AB V. Description of the invention (44) Printed hardness of the Central Laboratories of the Ministry of Economic Affairs, Consumer Cooperatives, Hardness-Elongation rate at the fracture of Shore D (%) Flexibility (MPa > 2% Secant chessboard volume (MPa) Tension Contact (MPa) Properties: PE-g-MAH ITP «4 1TP-3 γ ESI-4 ESI-3 ESI-2 CaC03 Composition •% by weight BS] ^ JS & M. E-Γ 3 2 * 45 mL · ββ 6.50 I 1 CB CO (II 0.1 $ 1701 2 ΟΙ 1 ^ 1 • i OI S 00 〇 »« 〇§ ΙΟ a 11.10 01 t 0 »'Φ 〇» 0 »s 4.26 < a: 丨: 09 (A : Tablet,-'~ 0 »2103 οι 〇 > (D sb;.: 11!' 13.5 Oft C» 2.05 _ 1209 Ο 69 〇 > 8.41 bi .-¾ 10.5 ω | OI 〇 > OI < 91 660 282 6.06 -4 OI Bu: ': 1 ..i' '1' · M 'Γ: * N | at 00 〇 ». Tkm i _ 0.65 1709 757 13_ cn!' 丨 j :! • i! In S圏 cn < 〇g -a 4.42 ba: H • 'Ί i I bi oa Γ— 〇 »〇» < α 〇 »1531 〇» o 9.61 < n'! 1; {r1 OB 1 09 *… " , 〇 > 〇 > 〇277 225 s CD ht ω 〇 »f, -ί this 3.65 1101 Φ mJk \ _ k I In L: 1 ', j 13.5 0 »< 11 select! ί 00 0.05 2277« 2.26 I!! < 13.5 09 (91 .- r' OI ΟΙ 0 01 5.77: OI! 1 13.5 00 ·. VV .. »[-. · 'Γ \:! 丨, 2728 1012 11.83 I bi 13.5' · _ :: .. 丨 | !. 00 Ol ----------. 装-.. 〆 (Please read the precautions on side f before filling in this page) The paper size is applicable to the Chinese National Standard (CNS) A4 (210X297 mm) 47 A7B7 V. Description of the invention (45 nt = > ^ Ministry of Economic Affairs Printed by the Central Standard Cockleshell Consumer Cooperative

A σο ^ ο ο η S im Hai · s £ S '¥ kf * Sea this arrives I > > s g 戚 g 2 | 名 麻 ί Νμ »1 W 麻 ψ ν» * f 1— »today. S Μ > [Ν 厶 ce o ff «Η» Μ s 1 S 0 »ο» 90 S ^ 4 s «λ to jjl CO < 〇s ο < 〇〇 ΟΙ s« Jk l · »0» Ol s ί.? -k: • k, .cb '::. 2 Φ &< 〇1 • a PI CO »〇s • *. Ιό,;» »» 00 OB s 1 < 〇Φ CO Ol b > < n ci: t Οι ί = I one / CO s _ t 00 < D s .'t 0 > r «D ο» o CO 00 5E m 3. < n 1 * 〇 > (0! J '〇QB: ； J., 5 »cn < 〇09 i 00 b > 〇» • Λ s • i £: * 00 (〇 φ < D secret order ss 1' "!I; 1 · ' < 〇φ 0 »〇» m H c 〇 > aib!! ·; ΰ 0 »HH Wai 09 JO < 〇u • ·! · (II 〇Ι μ 00 I s CJ 糸 s": b bi 〇 > Private Φ 1 00 e > (O os 9 mm i 2 0 »VBH Ol < l > (O -A o mX d > ΟΙ 00 σι s R Agriculture · The size of the paper used by the Chinese National Standards (CNS) A 4 specifications (210X297 mm) 48 Description of the invention (46) The sheets of Examples 19 to 31 have relatively high scratch resistance compared to the sheets of Comparative Examples 32 to 33. They have at least about 60% by weight (about 3 〇mol%) " The amazing scratch resistance of styrene-based ethylene / styrene internal polymers (such as Examples 20, 21, and 23) polymerized in T makes this material particularly suitable for flooring Structures · Examples 19 to 29 illustrate that no additives or polymer coupling agents are needed to achieve good filler retention and solidity. The sheet of Example 21 shows an amazing combination of flexibility and indentation resistance and can be used for floor monument products. It has good assemblability and good adaptability to uneven and contoured surfaces. The products of Examples 19 to 29 can be used as filled uniform floor coverings or as individual layers in non-uniform structures. The products of Examples 19 to 29 are particularly suitable for floor tile structures. Comparative Example 34 The properties of a flexible PVC material, which is commercially available from Amstrong under the trademark “Imperial” and has a thickness of 3.175 mm, were measured as shown in Examples 1 to 33. The flexural modulus is 696Mpa (100,760 psi), with a load of 14 kg and an indentation of 1 mil (254 microns) at 1 minute, a load of 14 kg and an indentation of 10 minutes at 12 mils (305 microns), The initial indentation at a load of 64 kg is 11% of the total thickness, and the residual indentation at a load of 64 kg is 4% of the total thickness. Taber Modu is 40mg / 100rev. All floor, wall or ceiling coverings according to Examples 1 to 25 and 27 to 30 of the present invention

Taber abrasion shows that compared with the comparative PVC material, it is a lot of lower abrasion (Taber abrasion of Examples 26 and 31 has not been tested). A7 B7 Five Ministry of Economy _ Printed and Invented by the Central Working Group of Shellfish Consumer Cooperative (47 Example 35 144 In Examples 38 to 42, 2mm thick sheets were prepared according to the following methods. • Use steel covered with Teflon ™ material And 28cmx 28cm X 0.2cm frame. The powder or granules of the appropriate polymer are filled in the mold. The mass of the polymer filled in the frame is the hip area of the mold (ie, 156 8cm3) X polymer density + 10% The mold is sealed with a steel plate and added at an elevated temperature. In Comparative Example 38, the material of layer B) (as described below) was 190. (: The temperature is pre-pressed at 6 bar mechanical pressure for 6 minutes and 100 bar mechanical pressure for 5 minutes. During the period of 3 minutes and 15 seconds (minimum) to 4 minutes and 12 seconds (maximum), the mold is subjected to 150 eC. Cool to 95 ° C. In Examples 39 to 42, at a temperature of 175 ° C, the ESI material was preloaded at a mechanical pressure of 8 bar for 5 minutes, and pre-pressed at a mechanical pressure of 200 bar for 3 minutes. The mold was set Between the water-cooled steel bottom plate and the top plate, and cooled to room temperature (within 5 minutes-one in Examples 35 to 37, multilayer sheets were prepared, which consisted of the following:-the thickness was below 0.5 mm The layer (A) prepared by the ESI listed in Table 7; and-the layer B) with a thickness of 1.5mm is made of 49% Affinity ™ EG8150 polyolefin plastic 27 ° /. HDPE 53050E, 10% LDPE 150 (All can be purchased from The Dow Chemical Company) and a blend of 14% of Lupolen UHM201 (available from BASF). 1.5mm thick sheet made of layer B) (Examples 35 to 37) Or prepared by ESI (Examples 43 and 44) as described above for Examples 38 to 42. The size of the thin paper applies to the Chinese National Standard (CNS) Λ4 specification (210X297 mm) (please read the note f on the back before filling this page) Order 50 A7 ____B7 V. Description of the invention (48) The sheet is not on the steel sheet Plus what to warm up. In the case of layer B), the dough sheet is heated to 160 ° C to 170 ° C, and in the case of ESI, it is heated to 12Oec to 1300c. In the case where the ESI film of 0.5 mm thickness is pressed on the preheating sheet to the 5 mm layer b), the pressure is 5 minutes at 3 bar and 3 minutes at 10 bar. In the case of a 5mm ESI layer, the force is 1 minute at 3 bar and 丨 minute at 15 bar. The resulting multilayer sheet was cooled to room temperature within 5 minutes. The compositions of the single-layer and multilayer sheets of Examples 35 to 37 and Examples 39 to 44 and Comparative Example 38 are shown in Table 6. i-fitting-(< first read the ^ side of the precautions before filling in this book 1) printed by the shelling consumer cooperatives of the Central Rubbing Bureau of the Ministry of Economic Affairs «. ft:-on paper suitable for the staircase official 97 2 51 A7 B7 V. Invention Note (49) Printed by the Shellfish Consumer Cooperative of the Central Bureau of the Ministry of Economic Affairs

—_I I i IIII, III ——Order.-,, ν (t read the notes on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) 52 5. Description of the invention (50) Table A7 B7 Table 6 illustrates the flooring, marinated wall or ceiling covering of the present invention containing the above-mentioned substantially random inner polymer compared to the sheet of Comparative Example 38 (which contains a blend of polyethylene), Has a low Franke vocal flexural hardness β Furthermore, the floor, wall or ceiling covering of the present invention reaches a very low hardness value after a very short time. Amazingly, the Franke of the multilayer sheets of Examples 35 to 37 has a flexural hardness The Franke bending hardness of individual layers that are much lower than the comparative thickness is expected by the benchmark, although the ESI layer is 25% of the total sheet thickness. Examples 39, 41, and 45 to 83 In Examples 45 to 56 and 59 to 83 2mm thick flakes were prepared as in Examples 38 to 42. The thickness of the PVC floor material of Comparative Example 57 was 2 mm. It is a high-performance PVC floor and contains 30% by weight of filler. It is available from the trade name Tarkett £ 111 丨 1161 ^. The thickness of the paraffin flooring material of Comparative Example 58 is 2 mm. »It is a paraffin parquet flooring material based on Affinity ™ polystyrene, polypropylene, and polyethylene. It corresponds to a brand name available from It is a flooring material for Tarkett SuperNova, but it does not contain a polyurethane coating ^-(Please read the precautions for the noodles before filling out this page)-* Printed by the Ministry of Economy The usability of the sheet mounted as a floor covering was tested. The composition of the flakes and their physical properties are shown in Tables 7 to 9. This paper is again applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 53

AB 5. Description of the invention (si) Printed by the Central Consumer Bureau of the Ministry of Economic Affairs, Consumers Cooperative, S, (t »5 seconds) S" t articles 2 seconds "Franke * bending hardness seconds) Din Modu (mm3): density ( g / cm3) Hardness-Shore D (t = 15) Hardness-Shore D (t = 3) Properties: Polyolefin floor PVC \ ac o (II o π ITP-2 ESI-5 Composition-wt% i 1 SrK !! * >. • 'ί ο »4 〇 > 20.1 290 1.018 2 s • A o 20.0 69.0» 〇0.996 cn ΟΙ s 2S.8 40.1 64.4 mX 09 0.986 at C * A? 2, 1 29.3 34.0 50.2 00 (0 0.965 S 丨. SS Γ, Γ ::,-7 Γ,.! 36.7 39.7 50.6 〇 > 0.939 ts; I rm 〇 € · »c · γ '] ϋ j 39.0 43.0 47.6 0.927 t S Ε ^ ι3 35.7 35.1 37.0 0.905 Ί! ifo I 一 < D 00 1.009 Ol σ > 〇 >! g-i mJk K) 00 1.000 αι s' 〇 * 0 · > 〇 > 1 105 0.986 οι V% to s S 38BS -λ 0.978 ο 〇 > 〇% to 〇 > C · »〇i CA 0.969 ο» 00 2 o 1 154 0.958 σ > 100 霪 32.1 42.6 «η ig 100 l ::: i 32.4 36.2 38.6 J u σ > 100 • i H Draw n II---IIIJ! — —I— ------: I, ^ T «fc (No need to read the notes on the back before filling this page) This Paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 54 A7 B7 V. Description of invention (52) Printed by the Central Labor Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives • β ^ S. 2 series. Original indentation pressure Camphor change (%): W Han Dong% Visual scratch rating (N) 5N Depth of loss (// m) Thin η Rolling creep (% > Elongation (%) Final tensile strength: s "T» eo seconds) S, "t * 20 seconds) Si (t * 10 seconds) fi 〇0.023 0.381 22Λ > 14 〇 <» 1.25 0.01 mL ·; 16.1 < * »β» σι Ok T * 1 279 20.5 C »12.4 _I 16.0. * 1. 1 314 22.1 13 * 2 18.7 20.5 358 21.4 17.2 22.1 24.2;: ^ i ο 00 00« ο 19.4 27.2 28.6 31.1 T'l 664 29.6 29.4 32.5 37.8 i 0.06 638 36.6 30.9 33.7 36.2 _ 274 22.4 Art sasii 265 20.5 Surface_ 287 18.7 旮; 417 20.6 i 796 23.8 i 00 〇 > 37.8 0.02 10.1 22.8 27.5 30.6 es 1 OI -λ 51.2 225 00 io 30.1 32.8 33 * 8 Yantu 铖 7_ / mmn 1 ^ 1 iAm ^ ϋ ^, T * * / · (Please _ first Read the notes on the t side and then fill out this page) This paper size applies the Chinese National Standard (CNS) Α4 specification (210 × 297 mm) 55

AB V. Description of the invention (53) Printing S, (t »5 seconds) S, (t: 2 seconds) iFranke bending hardness s_ {t = o seconds): Din Mo surname (mm3) Density (g / cm *) τ σ '? 5 Hardness-Shore D (t = 3) Properties. HD3S〇6〇E_ HD530S0E ITP-2 ESl-7 ESI-6' Thin · w | 11.4 12.9 12.9 -λ 0.963 〇 · * 〇19.7 17.8 20.5 -AS 0.953 sg S 21.4 20.7 22.5 Οι 0.960 o 00 c »c * Φ 25.1 26.5 27.8 ο 0.933 ogsr: j 31.3 30.4 32.3 M 0.922 * I Φ c ·» c · » : U ·! &Quot;,: >-'j 33.0 35.7 35.6 C0 0.913 us 35.7 35.1 37.0 £ 0.905, | 100 — 117 0.967 〇 > to js garden 1 0.969 units CJ o! 5!! 103.1 113.7 127.1 S 0.965 oS g S sr ^ -.'-. T5,: ί '孖:' 一 ”ί 0.960 s (A 〇CJ CJ — r§; 0.955 s U * to g I II! ^ ≪ 7 · 0.958! ~ · I s 100 I around 80.3 89.0 99.3 0.956 丨 containing I-- · Ol: 0 g, · τ S Note 'i Γ. 1 3 weeks ·; * j > 〇I 5: < 71 OI 1.007 I 100 MB. 1 ···· ^^ a ··· ^ ^ anBIM iwaa 〇ΒΤ ^ J-4,-* (Please read the precautions on t-plane before filling out this page) This paper size applies China National Standard (CNS) A4 specification (210X297 mm) 56

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7 B V. Description of the invention (+ 54) Printed by the Central Consumer Bureau of the Ministry of Economic Affairs, Consumer Work Cooperative, 13 Instrument 3 Final Margin 丨 Compression Variation Test Limitation (N > Visual Scratch Rating (N > S Pants S. Denier) Department of Stupidity 1 Family η 9 Qi 丨 ♦ 3. Final tensile strength s ^ tseo seconds) S, (t »20 seconds) | s, (t = io seconds) 1_% LJ 0.007 0.323 28.8 > 14 • A 10.6 OI ίο 0.32 434 21.0 10.6 10.9 11.5 — 546 29.7 15.7 18.3 18.8 σι • a 31.5 17.7 19.9 20.4 582 31.7 23.6 23.4 24.5 " ϊι '" ^ ·, ι r ·' vi 608 34.5 28.2 27.3 29.8 S · 'Ά ..... J 630 36.9 30.5 31.1 32.7 ^ s- '1 _ 0.06 638 36.6 30.9 33.7 35.2 519 25.4 I 1 534 25.3 I i § 23.0 78.4 90,9 94.6 Γ ^ Ί' © 1 f. • mT '·. I; ^ 2j 655 23.6 I m drawing 742 25.6 | I; 1! I i 58iB • 69.7 71.1 75.7 0 »0.054 0.416 50.1 > 14 CJ 13.6 ΙΟ ο» 0.26 250 19.1 〇〇1 (Please read the notes on the back before filling in this Page)-: 1- * This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) -57

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7 B V. Explanation of the invention (5?) Central Bureau of Standards, Ministry of Economic Affairs β; printed by the Industrial and Consumer Cooperatives “《5 seconds] S, (t» 2 seconds) tranke hip flexion degree s_ (t * o seconds) σ day I Density (g / cp3) Hardness-Shore D (t = 15) Hardness-Shore D (t = 3), LD150 VP 8770 ESI-8 ESI-7 ESI-5 Composition-Heavy Dong ° / 〇11.4 12.9 12.9 • X (0 0.963 100 21.7 23., 23J .. 0.923 ΙΛ Μ s S 18.0 18.6 19.3 0.911 Μ O < * »1 18.2 20.1 19.8 0.907 〇 S s R 16.0 16.1 16.3 £ 0.887 100 1 32.7 37.0 39.8 0.944 with g S Figure UI 0.935 Ci 〇 »o Drawing 0 0.929 S g 1 0.919 100 Negotiation φ -4 〇 > 20.1 § 1.018 2 S« λ o B 34.5 42.7 66.1 119 0.978 S g I 100 0.951 I u Negotiation • 0.937 s _ 00 OI 〇 »11.7 266 1.013 including • A 〇16.1 18.3 27 · 5« λ CO 0.957 g S _ (Please read the notes on the back and fill in this page)

、 1T This paper size is applicable to Chinese National Standard (CNS) Α4 size (210X297 mm) 58 17 9 1 93

AB \ — / 56 / fv Explanatory note issued. Tt * i Printed by the Central Consumer Bureau of the Ministry of Economic Affairs and the Consumer Cooperatives * 3 Detailed book " i " ϊ § ¥ S% b Angold δ Dan thin, clan carving 3ί Έ _ 1 1 ω ω II s I 1 1 Φ II 〇I ω u • Jk 0 3 V 1 1 1 `` Two: .1 L __— '' SP 〇〇1 »0» V Private 〇A σι > 〇ο Μ Privileged 〇0 0 »_ 1 P * _! Ii bt i 1 * · 2 οι ▲ < D 09 < D jO l ·» σ > which «λ mX 〇CO β > ο» < n ίο • A 0 »Ol 00 cn b · • ο δ 〇 > 〇 > οι ω 00 £ 0 cn -A cn Ol ·., / Cn« ο «Jb 5〇〇 to iO bo ω (O ω o .-. _ t. ^; ο s < η ο 〇 > CO i 1 ----- j βι ο 00 0!! iii? 7Γ71:. code macro 〇〇〇ΪΛ 2 K3 V 〇〇 »• a ο ο ΟΙ cn i 〇0 »1 \ t« · BB M _ • A β > '«λ 00 σ >: b» im 1 Λ WBBr »〇S • X 00! I! I ω (Ο ία • A ro • to ΓΓΓίΙ i, vi v ~ j .. _ JS 〇〇S 〇 »IT« I Γ ~ ί κ > i σ > 1 < D i ^ ΙΛ • Private C9 lo U 〇 >! Οι ο 1 ^ I CJ 〇 > 00 < n mA cn ro io CJ b > r- ·-\ 铖 9 > — I —-nn ^ ln ^ ^ 11 4 r /, (please read the precautions on the r side first and then fill out this page) The paper size of the paper is applicable to the Chinese National Standard (CNS) A4 specification (210X297 (Mm) 59 A7 B7 V. Description of the invention (57) Comparison a) Examples 39 to 45 to 50, b) Examples 39 to 51 to 56, c) Examples 41, 59 to 63 and 50, and d) Examples 41, 64 From 68 to 60, it is confirmed that the above-mentioned substantially random inner polymer and an aliphatic o: -olefin homopolymer or inner polymer having 2 to about 20 carbon atoms is a blend, preferably a blend The abrasion measurements of the individual components are as expected on the basis and have very low abrasion. Examples 45, 59, and 64 illustrate 20% polyolefins, which are sufficient to reduce the abrasion of the blend to 2/3 or less compared to the abrasion of the ethylene / styrene interpolymer alone in Examples 39 to 41. When the ethylene / styrene inner polymer was blended with HDPE, as shown in Examples 51 to 55 and 64 to 68, the abrasion of the blend was even lower than that of each individual component in Examples 39, 41 and Comparative Example 56. Of abrasion. This evidence is confirmed by comparing a) Examples 41 and 71 to 74, b) Examples 41 and 75 to 78, and c) Examples 39 and 79 to 81. Comparative Examples 39, 41, 70, 82 and Examples 57 and 58 illustrate that, compared with the known floor coverings, the floor covering of the present invention has excellent scratch resistance.

Hi I In I I-- V ，, / :, (Please read the precautions on f-page before filling out this page) Order printed by the Central Ministry of Economic Affairs, Bureau of Work and Consumer Cooperatives. The paper size applies to Chinese national standards (CNS ) A4 size (210X297mm) 60

Claims (1)

Members are kindly requested to state clearly that this 炱 /.χοΓ.·-ι is followed by the change of the original substance printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, which is printed by 3919 ^ 1. Amendment This amendment date: November 88 1. A floor, wall or ceiling covering that contains one or more substantially random endomers that are made by one or more alpha Prepared by polymerizing one or more ethylene monomers and / or one or more hindered aliphatic or cycloaliphatic vinylene monomers and optionally adding other polymerizable ethylene unsaturated monomers, the one or The plurality of inner polymers include one or more α-olefin monomers from 45 to 99 mol% which are internalized, and from 1 to 55 mol. /. One or more vinylidene aromatic monomers and / or one or more hindered aliphatic or cycloaliphatic vinylidene monomers and optionally other polymerizable ethylenically unsaturated monomers 2. such as the floor of the scope of patent application A pancreatic wall or ceiling covering, wherein the one or more inner polymers contain one or more alpha-dilute hydrocarbon monomers of 50 to 98 mol%, and one or more of 50 to mol% Vinylidene aromatic monomers and / or one or more hindered aliphatic or cycloaliphatic vinylidene monomers and optionally other polymerizable ethylene unsaturated monomers 3. If the floor, wall or Ceiling covering, wherein the one or more substantially random inner polymers contain one or more quaternary sequences, and these sequences are determined by C13 NMR spectroscopy of α_feline / vinylidene aromatic monomer / Composed of ethylene aromatic monofluorene / α-olefin inserts, where the quaternary monofluorene insertion is uniquely produced in a 1,2 (head-to-tail) manner. (Please read the notes on the back before filling out this page). -Line This paper ruler ^^ 〒 Guan Jia Standard (CNSM4 specification (210 X 297 mm) Members are kindly requested to state clearly that this 炱 /.χοΓ.·-ι is changed by Κί Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 3919 ^ 1 VI. Application for Patent Application 'Wai No. 86112688 Patent Reexamination Application for Amendment of Patent Scope Amendment Date: November 88 1. A floor, wall or ceiling covering that contains one or more substantially random cohesion The inner polymer is composed of one or more α-dilute hydrocarbon monomers and one or more ethylene diene monomers and / or one or more hindered aliphatic or cycloaliphatic vinylidene monomers and a selective addition agent. It is prepared by polymerizing other polymerizable ethylenically unsaturated monomers. The one or more inner polymers include one or more α-olefin monomers from 45 to 99 mol% that are internally polymerized, and from 1 To 55 Mol. One or more vinylidene aromatic monomers and / or one or more hindered aliphatic or cycloaliphatic vinylidene monomers and optionally other polymerizable ethylene unsaturated monomers Floor, pancreatic or ceiling covering in item 1 of the patent Wherein the one or more inner polymers contain 50 to 98 mole% of one or more α-dilute hydrocarbon monomers, and 2 to 50 mole% of one or more vinylene aromatic monomers and / Or one or more hindered aliphatic or cycloaliphatic vinylidene monomers and optionally other polymerizable ethylene unsaturated monomers 3. If a floor, wall or ceiling covering in the scope of the patent application, the one The one or more substantially random inner polymers contain one or more quaternary sequences, which are determined by α_woman hydrocarbon / vinylidene aromatic monomer / vinylidene aromatic monomer / α -Composed of olefin inserts, in which the unitary insertion of the quaternion is uniquely generated in a 1,2 (head-to-tail) manner. (Please read the precautions on the back before filling this page). -Line This paper ruler ^^ 〒guanjia standard (CNSM4 specification (210 X 297 mm) Printed by Shelley Consumer Cooperative, Intellectual Property Bureau, Ministry of Economic Affairs, 391971 b | C8 ---- ~ ______ A floor, wall or ceiling covering according to item 1, wherein the one or more substantially random inner polymers contain one or more α-olefin monomers of 50 to 80 mol% internally polymerized, and 20 to 50 mol % One or more vinylene aromatic monomers and / or one or more hindered aliphatic or cycloaliphatic vinylene monomers, and optionally other polymerizable ethylene monomer unsaturated monomers. The floor, wall or ceiling covering of item 1 contains up to 95% of filler based on the total weight of the floor, wall or ceiling covering. 6. If the floor, wall or ceiling covering of item 5 of the patent application It is in the shape of a tombstone and contains a filler of 50 to 95/0 based on the weight of the floor tile. 7. If the floor, wall or ceiling covering of item 1 of the patent application scope, the one or more Substantially random inner polymer 5 to 100% based on the total weight of the floor, wall or ceiling covering »8. If the floor, wall or ceiling covering of item 1 of the patent application scope contains the total weight of the floor, wall or ceiling covering Up to 90% of one or more polymers other than the substantially random inner polymer based on the benchmark 9. If the floor, wall or ceiling covering of item 1 of the patent application covers 5 to 99% of the one or more A substantially random inner polymer and 95 to 1% by weight of one or more aliphatic α-olefins having 2 to 20 carbon atoms or homopolymers of α-olefins having 2 to 20 carbon atoms and containing a polar group Or an inner polymer blend, which is based on the total paper size of the blend and is applicable to National Standards (CNS) A4 (210 X 297 public love) ---------------- (please read the precautions of the mouth first, then fill in this page) order.--Line A8B8C8D8 391971 VI. The weight of the patent application range is based on the weight . 10. If the floor, wall or ceiling covering of item 9 of the patent application scope comprises 5 to 99% of the one or more substantially random inner polymers and 95 to 1% by weight of one or more polymers selected from the group consisting of Blends consisting of: homopolymers of ethylene; copolymers of propylene homopolymers, ethylene and at least one other olefin containing 4 to 8 carbon atoms; propylene and at least one containing 4 to 8 Copolymers of other olefins with carbon atoms; copolymers of ethylene with at least one propionic acid, vinyl acetate, maleic anhydride or acrylic acid; propylene with at least one acrylic acid, vinyl acetate, horse Copolymers made from maleic anhydride or acrylonitrile; and terpolymers of ethylene, propylene and diene. 11. If the floor, wall or ceiling covering of item 1 of the patent application contains at least two layers', at least one layer (A) contains the one or more substantially random inner polymers. 12. For example, the floor, wall or ceiling covering of item π of the application scope, wherein the thickness of the layer (A) is 25 / zm to 2mm. 13. If the floor, wall or ceiling covering of item 11 of the patent application 'wherein the layer (A) contains 25 to 100% of the substantially random inner polymer, this is based on the total weight of the layer (A) as The benchmark counts. 14. The floor, wall or ceiling covering of item 11 of the scope of patent application, which contains the layer (A) and one or more additional polymer layers (B). 15. For example, the floor, wall or ceiling covering of item 14 of the patent application group, wherein the thickness ratio between the layer (A) and the layer (B) is 0.01: 1 to 10: 1. 16. If the floor covering, marinated wall or ceiling covering of item 14 of the scope of patent application is applied — — — — — X ------- Order ------- I-line / M09. (Please read first Note on the back, please fill out this page)