TW387947B - Electrolyser for production of halogen gases using electrolysis cells having metal reinforcements, and process for the manufacture thereof - Google Patents

Electrolyser for production of halogen gases using electrolysis cells having metal reinforcements, and process for the manufacture thereof Download PDF

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TW387947B
TW387947B TW86113879A TW86113879A TW387947B TW 387947 B TW387947 B TW 387947B TW 86113879 A TW86113879 A TW 86113879A TW 86113879 A TW86113879 A TW 86113879A TW 387947 B TW387947 B TW 387947B
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electrolyzer
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cathode
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TW86113879A
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Thomas Dr Borucinski
Karl-Heinz Dulle
Jurgen Gegner
Martin Wollny
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Krupp Uhde Gmbh
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修正補充' Α7 Β7 、發明説明( ) 圖號說明 1 常用電解器 2 電臓 3,4 半殻 3A,4A 電麵後牆 5 封口 6 隔片(隔膜) 7 接觸帶 8 陽極 8A 縫隙 9 陰極 10 實碰 ιοα,ιοβ 側邊 11 進料 13,14,15 開口或縫隙 16,16, ,16&quot; 焊縫 -^^1 1^ ^—J- an I - - 1— 1—ί I —l·— - - n\t/ ^ m ^^1 ^iv (請先閲讀背面之注意事項再填寫本I) 訂— 經濟部智慧財產局員工消費合作社印製 本紙張尺度逋用中國國家揉準(CNS ) Α4规格(210X297公釐) 經濟部中央搮準局負工消费合作社印製 Α7 Β7 五、發明説明(1 ) 本發明_你於一種從鐮金屬0化物水溶液生産窗素氣 鼸的霣解器,使用若干如板狀之電解槽,並嫌堆叠排列 且通霣達接·各槽供由兩片導霣材料製成之半殼_來加 上外殼,於槽殼之至少一處後艟之外侧附有接*帶;該 槽殼裝有供給霍解槽電流和電解給料之鋇入器,並有轉 出樯霣流和霜解産物之裝置;包含一《槿和一陰極,各 有一基本上為水平之表面,並且以一膈板相互分两,相 互平行排列,並通霣連接經由金羼補強物#接至各檐》 之後艢》 本發明亦鼷供一種》造如此之霣解器之較佳方法,其 中各嶺別霣解檐製自首先接合各值槽鷇之兩Η本》,同 時配置包括陰極、»極和隔板等所有必需之裝置,後者 用金颺補強物予以固定,並将跚極和陰極通霣建接至榷 毅。板狀之電解檐經通霣連接並且並排堆疊排列,在堆 疊中互相繫緊以保持持鑛接觸。 檐電流是經由堆疊中靠外之檐而供至槽之堆疊饑,在 霣流經遇堆疊另《上靠外之槽而放電之前,霣流供以穿 遇榷堆叠體之基本上垂直之方向來被分配至板狀霣解槽 之中央面。當槽霣流被施加至中央面,霣解榴霣流逹到 至少為4ΚΑ/·2 (仟安培/公尺2 &gt;之平均霣流密度。 申請人已知在ΕΡ 0 189 535 Β1之専利中提出一種霣 解器。在此已知之霣解器中,》極與陰棰兩者經由以繫 緊之形式配置之金羼補強物連接於各半後牆》各》 槿和陰極半殼於後方以接觸箝固定,用以確保與相期之 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) (請先閲讀背面之注f項再填窝本頁) -訂 A7 B7 五、發明説明(&gt;) 相同霣解榷接觸》霣流沿接鼸帚經通後艚流入金属補強 _·從此電流由諸金羼接鷗酤(補強物/限極之接»點) 被分配遍及m槿》一旦電流)a通膜η則被陰極接受•使 其猗經繫緊形補強物進入在陰極傈上之後艢•然後在進 入次一霣解檐之前回至接》帶。導霄元件是以黏焊連接 。霣解榷電流收集於焊貼以促成离峰霣流密度· 此已知電解器之一項缺»在於霣流不流遇接觸箝的整 值表面·逭是基於下列事實:雄開繫緊型補強物和供極 後雇藺的金屬連接物之霣流你於單费一酤進入接觸帚· 如帚霣流之表面減少時,霣流流動所霈霣壓,邸所嫌接 觸霣壓,隨之增加,而且因為霈要特別的能量以供霣解 生成物之生産,其痛求隨霣壓而直鎳增加,則生産成本 亦增加β 經濟部中央揉準局貝工消费合作社印製 (請先閲讀背面之注$項再填寫本頁) 此已知之《解器之另一缺鼬在於揮性之顧因,繫緊型 補羧物將後艚輿霣極速接,並非在後鵃與電槿之藺成垂 直之配置,迪成電流通輅之睡長,也促使槽電腰增加· 此外,從繫緊型補強物之霣流且於一單貼進入霣擓,一 方面造成不均的《流分配,另一方面又再增加槽電壓β 在電極上不均勻的霣流分配也迪成霣解質的《耗,结果 霣流效率降低而腠片使用壽命縮短。 本發明之目的在於創作一種霣解器,其箝霣表面僂可 能大,因而防止在僅單獼一酤将霣流饑入霣榷和接鼸帶 以避免不均勻的霣流分配。 根择本發明,在簡介中所描述之霣解器形式供足了此 本紙張尺度逋用中國國家標準(CNS A4«l格(2丨0〆297公釐) 經濟部中央揉率局員工消费合作社印製 Α7 Β7 五、發明説明ο ) 項目的,以設計成固黼片狀形式之金靨補強物,與接《 檐緊接而其邊之离及於後艚和皤極或陰極之高度。 根》本發明構築之霣解器,其實際防止不均勻霄流通 «表面,因為霣流你以整值表面而非經由單獨一黏餵入 霉捶和接《帶,電流的通路因補強片可以垂直設置於各 後牆與霄棰之間而縮短。發明在此説明之具龌例確保所 需檣霣壓逮小於已知之霣解器。 陰極可以製自雄、鈷、嫌或絡或其合金鵰極則製自 鈦、鈮或钽·此等金鼷之合金,或從一種金羼-陶瓷材 料或氣化物- RI瓷材料。此外,這些霣極被《以一種觴 媒活性塗層•故而霣槿較佳為具有厢孔(多孔板,多孔 金鼹,格子裂品或有百頁形鬭口之金饜薄片),使在《 解程序中所形成之氣觼易於在電解槽後進入空間。此項 除氣確保在各霣極間的霣解液儘量減少氣泡,於是能夠 逹到最大的導霣性。 隔板,或稱之為瞑片,是一種離子交換隔臢,通常製 自聚四氬乙烯或其衍生物和全氣乙烯基醚磺酸及/或全 氟乙烯基磺酸的共聚物。隔臃使霣解生成物不致混合且 其對於鐮金藝離子具選擇滲透性,而容許霣流流通。孔 板也可以用作隅板。孔板是一種細孔隔板.防止各氣醱 混合,在陰極與皤極之間産生電解質之接通而允許霣流 流通。 實心板Η形成之金颺補強物可被視為固體表面或可被 投置以醑孔或縫除。 本纸伕尺度適用中國國家梂準(CNS ) Α4规格(2Ι0Χ297公釐) (請先閱讀背面之注意事項再填寫本頁) 訂 A7 B7_ 五、發明说明(冷) 電解器之另一優黏涉及粬入分配轚,透纒陔分配器使 «解霣可以被觸入半殼之中而有最適當之霣解霣供鼴· 此输入分配器較佳為建構成能使半鷇之各節段能典從輪 入分配器中之至少一籲两孔提供新鮮之*解掖,並且在 输入分配器中之各開孔面積之结和小於或等於输入分配 器的横截面稹》 對陽捶和皤極經由一籲導霣的雙重接合被整合地建接 至實心板《較佳之具醭例是將平面行之接觸幣整體用一 導電金鼷的三重接合連至後黼以及實心板之下· 另一遘擇地•也可以對各後艢藉由一金篇導電的雙重 接合整讎連至資心板而設置•接》帚是在後艢以组成焊 接(Bulild-upveld)而形成· 雙重或三重接合之整鼸連接之施行,一方面在實心板 舆後艢之鬨,另一方面在後艢舆接觸箝之两,或在實心 板與《極之冊,免除接縫之需要,此意指槽霣流不再霈 要克愎發生於接縫中之表面霣阻· 經濟部中央揉準局貞工消费合作社印袈 (請先閱讀背面之注意事項再填寫本頁) 整鼸建结之三重接合之另一優顧B經建立•三重接合 使半殼後艚之彎曲刚性有相笛程度之增加•由於在堆璗 中所預置之預應力和槽霣流在電解檜各後躕間的傅輪, (直接傅輪經由於相鄺霣解槽後臁上各接觸帶同時發生) ,接觸箝在預鼴力之彩礬下必須保持水平使霣流可以雄 量於相_接觸指間經較多之表面流邊。三重接合之較离 彎曲剛性将降低堆疊中值別霣解槽两的接觸《阻》 限極半殼是裂自耐鹵素和麵溶液之材料,而陰極半毂 本紙張尺度適用中國國家橾準(CNS ) A4规格(210X297公釐〉 Α7 Β7 五、發明説明(r) 則製自晒齡液之材料· 根據本發明前述霣解器之製法,其一項優異特微在於 實心板形狀之各補強物與在各後鑛和限棰或陰極間之金 屬導_連接是以邇原燒结法或焊接方法産生》 理原燒结法涉及一種接着劑,主要含有一種氣化的物 質,其如NiO,以及一種有機膠合劑β此接箸Μ沿實心板 並沿待結合之元件•例如後»,而予施用,然後兩件被 用螵旋夾绀壓在一起。在有孅_合_硬化後,接著嫌的 氣化成份在邐原氣氛(例如H2,C0等)中被用熱嫌结。 較佳之焊接方法為雷射光焊法。霣射光在垂直於焊接 之方向被極化以減少頂上聯珠(Top bead)與接合苗間之 寬度比率。 一種光學的鏡組可被用以形成笛射光使形成待別之光 束並産生二或多值焦黏,移動速率為可選擇。 另一倕點為雷也光可以利用一播瞄器驅動儀..較佳為 以β電石英以离頻操作以與焊接方向成直角以可選擇之 速率掃瞄》 圖式Hff單翻: 本發明將箱如下之圈解作更样細之銳明: 第1臑在«解器中相鄰電解檜之稱截面, 第2圖為第1圔剖面之剖視圓, 第3 A至3D圖呈實心板狀補強物之各種變化, 第4A至4C圖在接觭帶,槽殼後牖和實心板間各種金屬 三重接合之放大詳画。 用於鹺金属鹵化物水溶液生産豳素氣體之常用霄解器 (1),具有若干值相鄰如板格狀之電解槽(2&gt;堆叠排列而 本紙張尺度適用中國國家梯準(CNS ) Α4规格(210X297公釐) (請先聞讀背面之注$項再填寫本頁) tr' 線 經濟部智慧財產局员工消费合作社印製- 鋰濟部中央樣準局貝工消费合作社印輦 A7 B7_ 五、發明説明(k ) 相互通霣連结〇第1 中兩β如此之霉解槽(2&gt;M嫌顧示 «&gt;各《解榴(2)具有一 β槽《由兩Η附有突錁狀鼷圈之半 殼(3, 4)所组成。一隔片(隔膜)(6)用封口(5)固定於半 毅之間。也可以用其他方法保持隔膜(6)。 若干接觸》(7)以平行跨覆於各«解檐» (2)之後臃 (4Α}之整軀深度。接鷗帶(7)以淨接等方法被附替於 各外殼後艢之外韬,將更詳述於後》逭些接_指建立對 相鄗霣解檐(2)(亦邸並不具有其本身的接》帶之後牆 (3Α&gt;之《性接觴β 在各槽《(3, 之内有一平整表面之鵰極和一平 整表面之陰極(9)緊鄰於隔膜(6),跚極(8)和陰極(9}各 連接至補強物,其呈實心板(10}狀,並對正接觸糟(7) β實心板(10}以其整縝铒邊(i〇A&gt;附於»極(8&gt;或險極 (9)而産生金颺導轚性β為將霣解進料艉入槽中並將霣 解産物轉出,實心板(1〇&gt;從涵篕其整儀《度之攧邊U0A) 向相酆之ϋ邊(10Β&gt;窄縮,且在窄鏞II典接觸糟(7&gt;之离 度相同β因此其Μ邊(10丨)沿接觸帚整鶴离度附著於面 向接觸帚ΓΠ之後艚(3Α/4Α)之反面, 各霣解槽(2)裝有饋入器(11)供霣解産製作用。各電 解槽亦有一装置(未示 &gt;以釋出霣解産物》 各霣極{陽棰(8)和陰極(9))被設計成為可使霣解進料 和放出生成物自由流動或通遇如第2 所示之缝隙(8Α) 或其相似者· ~框件稱為檐框,用於接合若干連鑛之板格 狀《解槽(2)。如板狀之霣解槽是懸於槽框之兩植上髹 -8 - 本紙張尺度適用中國國家揉率(CNS &gt; A4規格(210X297公釐&gt; (請先聞该背面之注f項再填寫本頁) 訂 經濟部中央梯準局貝工消费合作社印*. A7 _. _B7 五、發明説明(7 ) 之間,使其平面垂直於上櫟_。如板格狀之霣解榷(2&gt; 在上板線兩侧有一懸臂支架,使其能夠將其重量轉移於 上樣之上封口。 支架依板格水平之方向董於一水平位置且延伸出突嫌 醑®邊狳之外。該支架下续位在懸掛於框架内之板格狀 之霣解槽上突綠圃匾。 板格狀之霣解槽(2)供懸於槽框有如舾浮夾。於槽框之 内霣解槽如以堆璺安排•其板面像以機械.和鬣氣作接梅。 霣解器之有此結構形狀者,被稱為驗蠱淸迪之霣解器》 在懸璺構造中用已知之張力裝置以並排連结若干霣解 槽(2),霣解槽(2)經由接觭帚(7)霣氣迪接至堆纒構造 中舆其相鄰霣解槽。然後霄池從接觸箝(7)通過半殼, 由寶心板(10)通入陽極(8&gt;。在通遇隔膜(6)之後,霣流 被霣極(9)所接受而從此從實心板(10)通入B —半殼《 ,或更精準進入半殼(3A)之後艄,然後從該飈轉入次檐 之接觸帶(7)。依此方法,藉由將槽霣流由一外侧檐膿餞 入且由另一邊外倒槽體轉出來將槽電流散佈至整傾霣解 堆疊醱。 在第2圈中所代表電解榷之剖面表示一 U形接觸箝(7)附 着於半殼醱槽殼(4)之後臃(4 A)之一部份。在後方與接 («帶(7)對準之實心板(1〇&gt;附著於槽毅後牆(4A),實心板 (10&gt;位於型銷II型接觸帶(7)之中央。在後將參照第4A與 4C圏作更詳細之說明。實心板(1〇)之另一供邊U0A)附著 於隈極(8&gt;,其整籲表面積連结於實心板U〇),而鄰近此 -9 - 本紙張尺度逍用中國國家標準(CNS ) A4氅旛(2ICW M7公釐) (請先閲讀背面之注f項再填寫本頁) 1T--Γ. -^丨· A7 B7 五、發明説明(/) 等匾域之缝隙(8A)容允霣解給料和釋出成品通過。在實 心板(10&gt;舆陰極(9)之間亦設置相同之連接。 如在第3A至3D圈所可見,實心板(10)可以有多種設計。 第3A匾所示代表有實體表面之實心板,惟基於前述理由 兩《線10A與10B長度有所不同。 在第3B_所示之模式代表具有链除(13)之實心板(1〇) 。第3D國中之實心板是根镰第3C園,從铒面覼察實心板 (10)之視,其亦揭I隙,乃由衝片針孔(punching slanted holes)所_構成。 如第2鼷中已示,由於轚流通輅沿其金長像以金羼連 接至槽殼後《(3A/4A)及連接至鹤別霣«(8, 9),在各 轚極(限捶8和陰極9)與槽软後牆(3A/4A)間之連接處提 供最大的檐切面積以供《流流經實心板(10&gt;,此外,由 於實心板(10)代表在槽殼後艢(3A/4A)與《極(8/9)之 間的垂直連通,故霄流通路最短。 鐘濟部中央揉率局貝工消费合作社印製 (請先閲讀背面之注意事項再嗔寫本頁) 實心板連接至霣搐(8/9)並至槽殼之後艢(34/4纟)而 無須借肋於接縫将造成霣流流動額外之表面霣阻之基於 此理,待達結之元件以二重或三重金鼷連接而结合,其 較佳者是利用雷射光焊法産製,不過習用焊法如霣阻熔 焊也適合。採用還原燒結法也可以。焊接也可以逐點施 行以促成热的輪入僂可能小以確保變形最小。其也可能 沿艟別霉解槽的整傾高度焊接,因此接口應達鑛而確保 最適當的霣流分佈並使接觸霣阻減至最小,故而連到檐 霣壓儋可能為最低。 -10 - 本紙張尺度適用中國國家標準(CNS ) A4规格(210X297公釐) 經濟部中央標準局貝工消费合作社印製 A7 B7___ 五、發明説明(9 ) 第4A至4C圓願示各種形式的三重連接所受雷射光焊法 的彩《。各圈中也表示出接觸帶(7),部份槽殼的後艢 (4A)和實心板的《邊。 在第4 A 中所示之形式為一種雷射接頭•笛射源具有 K=0.5的光束值,輻射功率P=2仟瓦·而聚焦組件之 聚焦值F = 10。所生焊縫(16)形成一特殊的鐘p。在頂 腰珠舆接口 B的寬度所生獨特比率為2 . 5。 在第4A圔中的實嫌代表焊鍵(16”,是箪射光以相同 之功率和聚焦值所産生•但用待別离的光束&lt;^Κ=0.8· 此時在頂聯珠舆接口的寬度比率為2.0。然而·此較佳 之比率具有較小的半《變形•意指在實心板(10)舆後麄 (4 Α)間的接口區被減小幾乎約達25%。 在第4Β圖中所示之形式,代表一種以舆第〇圈者相同 之雷射源和聚焦組件所生焊縫之形式,但涉及雷射 光束在垂直於焊接之方向被極化。此導致焊縫被明顯擴 大,此為光束聚焦增大之结果,由Brewster效醮所造成 ,其偽作用於焊縫面上。此焊缝以16”代表。頂聊珠與 接口匾之寬度比率為1.6。此種情形中·焊縫的鼸積大 約輿第4A圈者相同,但接口匾大約增大25%。 在第4C圏中所示焊接頭U6”·)中,在頂_珠與接口匾 寬度比率待別良好。此情形中,接口區比在第4 A鼷之焊 接頭大50%。在此表示焊縫形式U6”’)是用特別光束來 逹成,該光束偽由與第4B鼷中焊接頭所用者相同之雷射 瀝所形成,藉一光學鏡組使其形成産生兩铒焦黏之雷射 -11 - 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) (請先Η讀背面之注意事項再填寫本頁)Correction and supplementation 'Α7 Β7, description of the invention () Description of drawing number 1 Commonly used electrolyzer 2 Electric 臓 3, 4 Half-shell 3A, 4A Electric surface back wall 5 Seal 6 Separator (diaphragm) 7 Contact strip 8 Anode 8A Gap 9 Cathode 10 Real touch ιοα, ιοβ side 11 feed 13,14,15 openings or gaps 16,16, , 16 &quot; weld-^^ 1 1 ^ ^ —J- an I--1— 1—ί I —l · —--N \ t / ^ m ^^ 1 ^ iv (Please read the notes on the back before filling in this I) Order — Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the paper size is printed in China (CNS) ) Α4 size (210X297 mm) Printed by the Central Laboratories Bureau of the Ministry of Economic Affairs, Consumer Cooperative, A7, B7 V. Description of the invention (1) The present invention is a decomposer for the production of window element gas from a solution of sickle metal 0 solution. , Use a number of plate-like electrolytic cells, and are arranged in a stack and accessible. Each tank is made of two shells made of two pieces of conductive material. To add the shell, at least one back of the tank shell. The outer side is equipped with a connection band; the tank shell is equipped with a barium inlet device for supplying the current of the lysing tank and an electrolytic feed, and there is a flow and a frost A device for decomposing the product; including a "hibiscus and a cathode, each having a substantially horizontal surface, and divided into two by a cymbal plate, arranged in parallel with each other, and connected to each eave via the Jin 羼 补强 物 #" After that, the present invention also provides a "better method for making such a disintegrator, in which each ridge type is made from two copies of each value slot firstly", and the configuration includes a cathode, a pole and All necessary devices, such as partitions, are fixed with Jin Yang reinforcements, and the anode and cathode are connected to each other. The plate-shaped electrolytic eaves are connected through a through hole and arranged side by side in a stack, which are fastened to each other in the stack to keep the ore contact. The eaves current is supplied to the stack of stacks through the outer eaves in the stack. Before the current flows through the stack and discharges, the current flows through the substantially vertical direction of the stack.来 distributed to the center of the plate-shaped crimping tank. When the trough flow is applied to the central surface, the dehydration flow is decomposed to an average flow density of at least 4ΚΑ / · 2 (仟 Amps / meter 2 &gt;. The Applicant knows the benefits of EP 0 189 535 Β1 A decomposer is proposed in this. In the known decomposer, "the pole and the yin are connected to each half-rear wall through a gold shim reinforcement arranged in a tie form." Each "hibiscus and cathode half-shell The back is fixed with contact pliers to ensure that the paper size is compatible with the Chinese National Standard (CNS) A4 size (210X297 mm) (please read the note f on the back before filling the page)-order A7 B7 、 Explanation of the invention (&gt;) Identical contact solution "The stream flows along the broom after passing through and flows into the metal to reinforce it. From then on, the current is connected to the gulls by the jewels (reinforcement / limiter connection» point). Throughout "Moon" once the electric current) a through film η is accepted by the cathode • After the warp-tightening reinforcement enters the cathode 傈 on the cathode 然后 and then return to the》 band before entering the next 霣 untie eaves. The guide element is connected by adhesive bonding.霣 Understanding current is collected in the welding paste to promote off-peak flow density. · One of the shortcomings of this known electrolyzer is that the flow does not flow across the entire surface of the contact clamp. 逭 It is based on the following facts: The flow of reinforcements and metal connectors hired after the supply electrode will enter the contact broom at a single cost. If the surface of the broom flow decreases, the current flow will be under pressure, and the suspected contact pressure will follow. Increase, and because it requires special energy for the production of decomposed products, its desire to increase nickel with pressure will increase production costs. Read the note on the back of the page before filling in this page.) This known "Another shortcoming of the resolver is due to the nature of the nature, the tight-type carboxyl compound will be connected to the posterior speed very quickly, not the posterior electricity and electricity The vertical arrangement of the hibiscus and the long sleep time of Dicheng current also promoted the increase of the electric waist of the trough. In addition, from the current of the fastening reinforcement and entering the ridge with a single patch, on the one hand, it caused unevenness. 《Flow distribution, on the other hand, increase the tank voltage β. Non-uniform flow distribution on the electrode Dicheng rainstorm solution Quality "consumption efficiency is decreased flow results rainstorm Cou sheet shortened life. The purpose of the present invention is to create a decomposer whose clamping surface may be large, so as to prevent the flow of entrapment into and interfering with the flow in a single pass to avoid uneven flow distribution. Based on the present invention, the format of the dissolver described in the introduction is sufficient for this paper size, and the Chinese national standard (CNS A4 «1 grid (2 丨 0〆297mm) is used for consumption by the Central Bureau of the Ministry of Economic Affairs Cooperatives printed A7 B7 V. Description of the invention ο) For the project, the gold reinforcements designed in the form of solid slabs are placed next to the eaves and the distance between the edges and the height of the rear pole and the pole or cathode . "Root" The decomposer constructed by the present invention actually prevents uneven flow through the surface, because for the flow, you feed the mold with a whole surface instead of a single stick and connect the "belt, the path of the current can be strengthened by the reinforcement sheet. It is installed vertically between each back wall and Xiaoya and shortened. The specific examples of the invention described here ensure that the required pressure capture is smaller than that of known dissolvers. The cathode can be made of male, cobalt, arsenic, or alloy, or its alloy poles are made of titanium, niobium, or tantalum alloys of these metals, or from a gold alloy-ceramic material or gaseous-RI porcelain material. In addition, these poles are "made with a medium-active coating. Therefore, hibiscus is preferably with porous cells (porous plates, porous gold, lattice cracks, or gold-leaf flakes with louver-shaped openings). << The gas entrapment formed during the solution process easily enters the space behind the electrolytic cell. This degassing ensures that the decomposing solution between the poles minimizes air bubbles, so that maximum conductivity can be achieved. The separator, or diaphragm, is an ion-exchange diaphragm, and is usually made from a copolymer of polytetragonethylene or a derivative thereof and a full gas vinyl ether sulfonic acid and / or a perfluorovinyl sulfonic acid. The barrier prevents the decomposed products from being mixed and is selectively permeable to Sickle art ions, allowing flow to flow. Orifice plates can also be used as fascia plates. Orifice plate is a kind of fine-pore separator. It prevents the mixing of various gas radon, and creates the connection of electrolyte between the cathode and the cathode, allowing flow to flow. Gold reinforcements formed from solid panels can be regarded as solid surfaces or can be placed with countersinks or seams. The size of this paper is applicable to China National Standard (CNS) A4 specification (2Ι0 × 297 mm) (Please read the precautions on the back before filling this page) Order A7 B7_ V. Description of the invention (cold) Another advantage of electrolyzer involves The input distributor, through the distributor, allows the «solution» to be touched into the half-shell and has the most appropriate solution. · This input distributor is preferably constructed to enable each section of the Can provide at least one and two holes in the turn-in distributor to provide a fresh solution, and the sum of the area of each opening in the input distributor is less than or equal to the cross-section of the input distributor. The pole is integrated to the solid board through a double joint called a guide. "The preferred example is to connect the flat contact coins as a whole with a triple bond of a conductive gold wire to the back and the solid board." Another alternative • It can also be set to each backing through a gold-conducting double-joint connection to the center panel. • The broom is formed in the backing to form a bulild-upveld. Double Or triple-joint tidy connection, on the one hand, solid plate On the other hand, the contact between the tongs and the tongs on the other hand, or on the solid board and the book of poles, eliminating the need for seams, which means that the trough flow no longer has to overcome the seams. Impediments in the surface · The seal of Zhengong Consumer Cooperative of the Central Ministry of Economic Affairs of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page). The bending rigidity of the rear shell of the half-shell has an increase in the degree of phase flutes. Due to the pre-stress and groove flow preset in the stack, the Fu wheels between the electrolytic reactors (the direct Fu wheels pass the phase solution The contact strips on the back of the slot occur at the same time). The contact pliers must be kept level under the pre-stressed alum so that the flow can be masculine on the surface with more edges flowing between the contact fingers. The triple-joint rigidity compared with the bending will reduce the contact between the two median stacks. The “resistance” limit half shell is a material that is crack-resistant from halogen and surface solution. The size of the cathode half-hub is applicable to Chinese national standards. CNS) A4 specification (210X297 mm> A7 B7 V. Description of the invention (r) The material made from the aging liquid · According to the method for making the disintegrator of the present invention, one of its outstanding features lies in the reinforcement of the shape of the solid plate The metal-to-metal connection between the rear ore and the thorium or cathode is produced by the 迩 hara sintering method or the welding method. The rihara sintering method involves an adhesive, mainly containing a gasified substance, such as NiO , And an organic adhesive β, which is then applied along the solid plate and along the element to be bonded, such as the back », and then applied, and then the two pieces are pressed together with a screw clamp. After having ___ hardened Then, the suspected vaporized components are thermally sintered in a Horihara atmosphere (such as H2, C0, etc.). The preferred welding method is laser light welding. Radon light is polarized in a direction perpendicular to the welding to reduce overhead Width ratio between top bead and spliced seedlings An optical lens group can be used to form the flute light to form a beam to be separated and generate two or more values of coherent stickiness. The moving speed is selectable. Another point is that Lei Yeguang can use a sight driver .. It is better to use β-electric quartz to operate at an off-frequency to scan at a right angle to the welding direction at a selectable rate. Schematic Hff single turn: The present invention interprets the following circle of the box into more detailed sharpness: 1 臑 The cross section of the adjacent electrolytic 桧 in the «Decomposer», Figure 2 is the cross-section circle of the section 圔 1, and Figures 3 A to 3D show various changes of the solid plate-shaped reinforcement. Figures 4A to 4C are in Enlarged detailed drawing of the triple junction of various metals between the splice belt, the rear shell of the tank shell and the solid plate. A commonly used hydrolyzer (1) for the production of halogen gas from a metal halide aqueous solution, which has several values adjacent to each other, such as a plate-like shape. Electrolytic cell (2 &gt; stacked arrangement and this paper size applies to China National Standard (CNS) A4 size (210X297 mm) (please read the note on the back before filling in this page) tr 'Ministry of Economic Affairs Intellectual Property Bureau Printed by Employee Consumer Cooperatives-Lijiang A7 B7_ 2. Description of the invention (k) The two betas are connected to each other in the same way as in the first paragraph. (2) M suspicion indications &gt; &gt; Each "detoxification (2) has a beta slot" It consists of the half shells (3, 4) of the cymbal loop. A septum (diaphragm) (6) is fixed between the two ends with a seal (5). The diaphragm (6) can also be held by other methods. Several contacts "( 7) The entire body depth of the 臃 (4Α) behind each «Relief Eaves» (2) in parallel straddle. The gull belt (7) is attached to the outer ridge of each shell by means of net connection, etc. Detailed in the following "Some connection_ refers to the establishment of the opposite eaves solution (2) (Yidi does not have its own connection") behind the wall (3Α &gt; "Sexual connection β in each slot" (3, There is a flat-surfaced carved electrode and a flat-surfaced cathode (9) next to the diaphragm (6), the cathode (8) and the cathode (9) are each connected to the reinforcement, which is in the shape of a solid plate (10), and The positive contact β (7) β solid plate (10) with its rounded edges (i0A> attached to the »pole (8) or dangerous pole (9)) generates the Jin Yang conductance β as the solution. The material is poured into the tank and the decomposed product is transferred out. A solid plate (1〇 &gt; The whole instrument "U's edge of the degree U0A" towards the opposite edge (10B &gt; narrow, and the contact angle in the narrow II code (7 &gt; the same degree of separation β so its M edge (10 丨) along the contact broom crane The degree of separation is attached to the opposite side of the 艚 (3A / 4Α) facing the contact broom ΓΠ, and each 霣 dissolution tank (2) is equipped with an feeder (11) for 霣 production. Each electrolytic cell also has a device (not shown &gt; to release the decomposed product). The anodes {yang (8) and cathode (9)) are designed to allow the decomposed feed and release products to flow freely or pass through. In the case of the gap (8A) or the like shown in the second frame, the frame is called an eaves frame, which is used to join a number of continuous ore-like slabs. For example, the plate-shaped crevice is suspended on the two sides of the creel frame. -8-This paper size applies to the Chinese national kneading rate (CNS &gt; A4 size (210X297 mm &gt;) (please listen to the note f on the back first) (Fill in this page again.) Order the seal of the Beige Consumer Cooperative of the Central Government Bureau of the Ministry of Economic Affairs *. A7 _. _B7 V. Description of the invention (7), make the plane perpendicular to the upper oak _. (2) There is a cantilever bracket on both sides of the upper plate line, which enables it to transfer its weight to the top of the sample and seal it. The bracket is in a horizontal position according to the horizontal direction of the plate and extends beyond the edge of the edge. The lower part of the bracket protrudes from the green garden plaque on the plate-shaped relief box suspended in the frame. The plate-shaped relief box (2) is used to suspend in the groove frame like a floating clamp. Inside the groove frame The dissolution tank is arranged as a stack. The plate surface is mechanically connected to the hyena. Those that have this structure and shape are known as the disintegrators for inspection. In the suspension structure A known tension device is used to connect several dissolution tanks (2) side by side, and the dissolution tanks (2) are connected to the stacking structure through a broom (7). . Then Xiaochi passed the contact tongs (7) through the half shell, and passed through the Baoxin plate (10) to the anode (8). After meeting the diaphragm (6), the flow was accepted by the pole (9) and it has been since The core plate (10) enters B—half-shell “, or more precisely after entering the half-shell (3A), and then from this ridge into the contact zone (7) of the second eaves. In this way, by channeling the trough stream It is put in from one outside eaves and turned out from the other side of the inverted trough to spread the slot current to the tilting and destacking stack. The cross section of the electrolytic cell represented in the second circle shows a U-shaped contact pliers (7) attached A part of the 4 (4 A) behind the half-shell 酦 trough shell (4). A solid plate (10) with alignment at the back («belt (7) is attached to the trough rear wall (4A), A solid plate (10 &gt; is located in the center of the type II contact belt (7). It will be described in more detail with reference to 4A and 4C. The other supply side U0A of the solid plate (10)) is attached to the pole (8 &gt;, its entire surface area is connected to the solid board U〇), and adjacent to this -9-This paper size is in accordance with Chinese National Standard (CNS) A4 氅 幡 (2ICW M7 mm) (Please read the note on the back first f) 1T--Γ.-^ 丨 · A7 B7 V. Description of the Invention (/) The gap (8A) in the plaque field allows the feed to be released and the finished product to pass. Between the solid plate (10) and the cathode (9) The same connection is also provided. As can be seen in circles 3A to 3D, the solid plate (10) can have various designs. The plaque shown in 3A represents a solid plate with a solid surface, but for the reasons mentioned above, the length of the two lines 10A and 10B The pattern shown in 3B_ represents the solid plate (10) with chain division (13). The solid plate in the 3D country is the root sickle 3C garden, and the solid plate (10) is inspected from the surface. The view, which also reveals the I gap, is composed of punching slanted holes. As shown in the second paragraph, since the 轚 辂 is connected to the trough shell with a gold 辂 along its golden long image ((3A / 4A) and connected to Tsubetsu 霣 (8, 9),捶 8 and cathode 9) and the soft back wall of the trough (3A / 4A) provide the largest eaves cut area for the flow through the solid plate (10), in addition, since the solid plate (10) represents the The vertical connection between Houyi (3A / 4A) and "Pole (8/9), so the Xiaoluo path is the shortest. Printed by the Shellfish Consumer Cooperative of the Central Rubbing Bureau of Zhongji Ministry (please read the precautions on the back first) (Write this page) The solid plate is connected to the convulsions (8/9) and to the back of the trough shell (34/4 纟) without the need for ribs in the joints. This will cause additional surface obstruction to the flow of the flow. The components of the tie knot are combined by double or triple gold cymbals. The better one is produced by laser welding, but customary welding methods such as thorium resistance welding are also suitable. Reduction sintering can also be used. Welding is also possible It can be implemented point by point to promote the hot wheel entry. It may be small to ensure minimum deformation. It may also be welded along the tilting height of the mold groove, so the interface should be mine to ensure Appropriate flow distribution and minimizing contact resistance, so the pressure connected to the eaves may be the lowest. -10-This paper size applies to China National Standard (CNS) A4 (210X297 mm) Central Bureau of Standards, Ministry of Economic Affairs Printed by Shelley Consumer Cooperatives A7 B7___ V. Description of the Invention (9) The 4A to 4C rounds show the color of the laser welding method for the various types of triple connections. The contact strips (7), parts are also shown in each circle. The rear ridge (4A) of the slot shell and the "edge" of the solid plate. The form shown in Section 4A is a laser connector. The flute source has a beam value of K = 0.5, and the radiant power P = 2 仟 W · And the focus value of the focusing component F = 10. The generated weld (16) forms a special clock p. The unique ratio generated by the width of the top waist bead interface B is 2.5. It is suspected in 4A 圔Represents the welding key (16 ", which is generated by the irradiated light with the same power and focus value. But the beam to be separated is &lt; ^ Κ = 0.8. At this time, the width ratio at the Dingzhuzhuyu interface is 2.0. However, · This better ratio has a smaller half of the "deformation means that the interface area between the solid plate (10) and the rear ridge (4 Α) is reduced. It is about 25%. The form shown in Figure 4B represents a form of welding seam produced by the same laser source and focusing assembly as the 0th circle, but it involves the laser beam in the direction perpendicular to the welding It is polarized. This results in a significant expansion of the weld seam. This is the result of the increased focus of the beam. It is caused by the Brewster effect. Its pseudo effect is on the weld seam. This weld seam is represented by 16 ". Top chat beads and interfaces The width ratio of the plaque is 1.6. In this case, the buildup of the weld is about the same as circle 4A, but the interface plaque is increased by about 25%. In the welding head U6 "·) shown in 4C 圏, in The width ratio of the top_bead to the interface plaque is good. In this case, the interface area is 50% larger than the welded joint at 4 A 鼷. It is shown here that the welding seam form U6 "') is formed by a special light beam, which is pseudo-formed by a laser beam which is the same as that used for the welding head in Section 4B. Scorch Laser-11-This paper size applies to Chinese National Standard (CNS) Α4 size (210X297 mm) (Please read the precautions on the back before filling this page)

4 4 經濟部中央橾準局貝工消费合作社印製 A7 _B7__ 五、發明説明(t。) 光束,傷移約0.5«米•此種形式之焊縫也可以用例如 用波輻為0.5毫米在高頻播嵫聚焦鏡而達成· 在遒些鼸中笼未表示出各項鏔節,霣解槽(2}於其較 低部份具有一《解液入口 解液可以在一單黏或用所 諝輸入分配器鋇入槽中•翰入分配器供以有两口之管子 形式存在於元件中。由於每一半«被連接於後鵃(3A/ 4A)和霣極(8, 9)之間的實心板10所分段,酋兩籲半β (3, 4)裝有一输入分配罌,則能達成適當的濃度分S, 因而被安置於半玟中之输入分配器的畏度相當於半败的 寬度,而且各段經由翰入分配器之至少一嫡聞口得有_ 別之霣解掖供應》在输入分配器中各開口之横截面之和 應小於或等於技管的内截面。4 4 Printed by the Shellfish Consumer Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs, A7 _B7__ V. Description of the invention (t.) Beam, wound displacement of about 0.5 «m • This type of welding seam can also be used, for example, with a wave of 0.5 mm in High-frequency broadcast focusing lens is achieved. In some cases, the cages are not shown. The solution tank (2) has a lower part of the solution solution inlet solution. All of the input distributors are barium into the groove. The Han into the distributor is provided in the form of a two-port pipe in the element. Because each half «is connected between the back 鵃 (3A / 4A) and the 霣 pole (8, 9) Segmented by the solid plate 10, the two halves of β (3, 4) are equipped with an input distribution pill, and the appropriate concentration score S can be achieved. Therefore, the input distributor placed in the half 玟 is equivalent to half the degree of fear The width of the opening and the length of each section can be obtained through at least one opening of the distributor. The sum of the cross-sections of the openings in the input distributor should be less than or equal to the inner section of the technical tube.

如在第1 中所可見,兩值半穀(3, 4)在突錄画圈S 域被鏍栓鎖住〇然後各槽釅式被懸起或被置於槽框内, 在此未予表示•此你利用在突嫌上的支持裝置(未示)而 逹成。霣解器(1}可用單獨一樯構成,或較佳结合若干 鵪《解槽(2&gt;,並排安置於懸掛堆蠱構迪之中•如果若干 儀別的槽被依戀疊原理而臛合在一起•值別的檐必須在 張力裝置封合之前以平行面對正,否則《流從一槽至次 榷的傳輸不可能有效遍及所有的接觸帶(7)。為求被懸 於或置於檐框之中之各槽,能夠並排對正,此等空重 董通常約為210公斤之元件需能輕易被移動。此你藉 設一支架而達成,亦邸此等支持表面位於槽框和槽架 (未示)上而有適合之塗層者β為此目的,位於元件之突 -12- 冬紙張尺度適用中國國家標準(CNS ) Α4規格(2丨ΟΧ 297公釐) (請先閲讀背面之注意事項再填寫本頁) 訂 A7 ____ B7_ 五、發明説明(1,) 鳔框上之支架被襯為合成材料之如PE, PP, PVC, PFA, PEP, E/TFE, PVDF或PTFE,而在稽框上的支特面也以 一種此等合成材料塗覆。合成材料可以簡單被置於一溝 中而黏上焊合或用鳔絲鎖住,以使合成曆能牢固固定。 兩種合成層相互接觸之情形意指在框中各傾別元件可以 輕易移動,使可以用人力並排對正而無須藉助於提吊推 移之裝置。在槽框中各元件之可移動性使其可以藉由蘭 閉蕖力裝置輕易沿後牆整饞匿域安置。此.為均勻分配電 流所必霈。再則也能確保槽舆槽框間的绝綠。 (請先閲讀背面之注意事項再填寫本頁) V ! 經濟部中央揉率局負工消费合作社印製 -13- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 修正補充' Α7 Β7 、發明説明( ) 圖號說明 1 常用電解器 2 電臓 3,4 半殻 3A,4A 電麵後牆 5 封口 6 隔片(隔膜) 7 接觸帶 8 陽極 8A 縫隙 9 陰極 10 實碰 ιοα,ιοβ 側邊 11 進料 13,14,15 開口或縫隙 16,16, ,16&quot; 焊縫 -^^1 1^ ^—J- an I - - 1— 1—ί I —l·— - - n\t/ ^ m ^^1 ^iv (請先閲讀背面之注意事項再填寫本I) 訂— 經濟部智慧財產局員工消費合作社印製 本紙張尺度逋用中國國家揉準(CNS ) Α4规格(210X297公釐)As can be seen in Section 1, the two-valued half-valleys (3, 4) are locked by 镙 bolts in the S field of the recording circle. Then each slot is suspended or placed in the slot frame. Indication • This is done using a support device (not shown) on the suspect. The disintegrator (1) can be composed of a single unit, or a combination of several quake units (2 &gt;), which are placed side by side in the hanging pile structure. • If several units are combined in accordance with the principle of stacking Together • The other eaves must face up in parallel before the tension device is sealed, otherwise the transmission of the stream from one slot to the second cannot be effectively spread across all contact zones (7). In order to be suspended or placed The slots in the eaves frame can be aligned side by side. These empty weight directors usually weigh about 210 kg. The components need to be able to be easily moved. This is achieved by setting up a bracket. These support surfaces are located in the slot frame and A suitable coating on a slot frame (not shown) β For this purpose, located at the protrusion of the element -12- Winter paper size Applies to Chinese National Standard (CNS) Α4 specification (2 丨 〇 × 297 mm) (Please read first Note on the back, please fill out this page) Order A7 ____ B7_ V. Description of the invention (1,) The bracket on the frame is lined with synthetic materials such as PE, PP, PVC, PFA, PEP, E / TFE, PVDF or PTFE And the support surface on the frame is also coated with one of these synthetic materials. The synthetic material can be simple It is placed in a trench and welded or locked with a wire to make the synthetic calendar firmly fixed. The situation where the two synthetic layers are in contact with each other means that the respective tilting elements in the frame can be easily moved, so that human labor can be used. It is aligned side by side without the need to lift and move the device. The mobility of each component in the slot frame allows it to be easily installed along the entire hidden area of the back wall by the blue closure device. This is for the uniform distribution of current It must be. Then you can also ensure the green between the slots. (Please read the precautions on the back before filling out this page.) V! Printed by the Central Consumer Bureau of the Ministry of Economic Affairs, Consumer Cooperatives -13- This paper size Applicable to Chinese National Standard (CNS) A4 specification (210X297mm) Amend and supplement 'Α7 Β7, description of invention () Drawing number description 1 Common electrolyzer 2 Electric cymbal 3, 4 Half-shell 3A, 4A Electric surface rear wall 5 Seal 6 Separator Sheet (diaphragm) 7 Contact strip 8 Anode 8A Gap 9 Cathode 10 Real contact ιοα, ιοβ Side 11 Feed 13,14,15 Opening or gap 16,16, , 16 &quot; Weld seam-^^ 1 1 ^ ^ —J -an I--1— 1—ί I —l · —--n \ t / ^ m ^^ 1 ^ iv (Please read first Note to fill out the back of this I) set - Ministry of Economic Affairs Intellectual Property Office employees consumer cooperatives in this paper printed with the Chinese national scale Bu rub quasi (CNS) Α4 size (210X297 mm)

Claims (1)

公告招 D8 申請專利範圍 第86113879號「使用具金屬補強物之電解槽來製造鹵 素氣體之電解器及其製法」專利案(88年11月修正) A申請專利範圍: 1. 一種用於一個從鹼金屬鹵化物水溶液生產鹵素氣 體之電解器⑴,利用若千如板狀之電解槽⑵並排 安置而堆叠且以電連通,各槽容納於由導電材料 製成的兩片(3, 4)半殻中,在至少一槽殼後牆 (3A,4A)之外側附有接觸帶⑺,該槽殻裝有供應槽 電流和電解進料(11)之饋入器,附有猶出槽電流 和電解生成物之裝置,其包含一陽極⑻和一陰極 ⑼而各有一基本水平表面*並用一隔板⑹互相分 開而且互相平行安置,經過金屬補強物與各別外 殻後牆(3A,4A)以電連通,其特徵在於, 金靥補強物爲實心板(10)之形狀,其係與接觸 帶(7)等高,而其側邊(10A,10B)高至後牆(3A, 4A)和陽極(8)或陰極(9)之全部高度 2 ·如申請專利範圍第1項之電解器,其中實心板(丨〇 ) 具有一實體之表面。 3.如申請專利範圍第1項之電解器,其中實心板(1〇) 設有開口或縫隙(13,14,15)。 4_如申請專利範圍第1項至第3項中任一項之電解 器,其中設置輸入分配器,從此可將電解液饋入 半殻(3,4)之中。 本紙張尺度逍用中國國家梂準(CNS ) Λ4规格(210X297公釐) (請先聞讀背面之注$項再填寫本頁) -、?τ· 經濟部智慧財產局員工消費合作社印製Announced D8 Patent Application No. 86113879 "Electrolyzers for the production of halogen gases using electrolytic tanks with metal reinforcements and its manufacturing method" (Amended in November 88) A. Application scope: 1. An electrolyzer ⑴ for the production of halogen gas using an aqueous solution of an alkali metal halide, which is stacked side by side and electrically connected using a plate-shaped electrolytic tank ⑵, each tank is accommodated in two pieces (3, 4) made of conductive material In the shell, a contact band ⑺ is attached to the outer side of at least one tank shell rear wall (3A, 4A). The tank shell is provided with a feeder for supplying tank current and electrolytic feed (11), and a tank current and Device for electrolytic products, comprising an anode ⑻ and a cathode ⑼ each having a substantially horizontal surface *, separated from each other by a partition ⑹ and placed in parallel to each other, passing through metal reinforcements and the rear walls of the respective enclosures (3A, 4A) It is electrically connected, which is characterized in that the gold reinforcement is in the shape of a solid plate (10), which is the same height as the contact band (7), and its side edges (10A, 10B) are as high as the rear wall (3A, 4A). And the total height of the anode (8) or cathode (9) 2 The electrolyzer of the scope of application for patent No. 1 wherein the solid plate (丨 〇) has a solid surface. 3. The electrolytic device according to item 1 of the patent application scope, wherein the solid plate (10) is provided with an opening or a gap (13, 14, 15). 4_ If the electrolytic device of any one of the items 1 to 3 of the scope of patent application, an input distributor is provided, and the electrolyte can be fed into the half shell (3, 4) from then on. This paper size is in accordance with China National Standards (CNS) Λ4 specification (210X297 mm) (please read the note on the back before filling in this page)-,? Τ · Printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 公告招 D8 申請專利範圍 第86113879號「使用具金屬補強物之電解槽來製造鹵 素氣體之電解器及其製法」專利案(88年11月修正) A申請專利範圍: 1. 一種用於一個從鹼金屬鹵化物水溶液生產鹵素氣 體之電解器⑴,利用若千如板狀之電解槽⑵並排 安置而堆叠且以電連通,各槽容納於由導電材料 製成的兩片(3, 4)半殻中,在至少一槽殼後牆 (3A,4A)之外側附有接觸帶⑺,該槽殻裝有供應槽 電流和電解進料(11)之饋入器,附有猶出槽電流 和電解生成物之裝置,其包含一陽極⑻和一陰極 ⑼而各有一基本水平表面*並用一隔板⑹互相分 開而且互相平行安置,經過金屬補強物與各別外 殻後牆(3A,4A)以電連通,其特徵在於, 金靥補強物爲實心板(10)之形狀,其係與接觸 帶(7)等高,而其側邊(10A,10B)高至後牆(3A, 4A)和陽極(8)或陰極(9)之全部高度 2 ·如申請專利範圍第1項之電解器,其中實心板(丨〇 ) 具有一實體之表面。 3.如申請專利範圍第1項之電解器,其中實心板(1〇) 設有開口或縫隙(13,14,15)。 4_如申請專利範圍第1項至第3項中任一項之電解 器,其中設置輸入分配器,從此可將電解液饋入 半殻(3,4)之中。 本紙張尺度逍用中國國家梂準(CNS ) Λ4规格(210X297公釐) (請先聞讀背面之注$項再填寫本頁) -、?τ· 經濟部智慧財產局員工消費合作社印製 六、申請專利範圍 5. 如申請專利範圍第4項之電解器,其中輸入分配 器被設計成使半殼(3,4)之各節段可以經由輸入 分配器中之至少一個開口而輸入新鮮的電解液, 而且各開口面積之和小於或等於輸入分配器之橫 截面積。 6. 如申請專利範圍第1項至第3 項任一項之電解 器,其中陽極(8)或陰極(9)經一導電之雙重接合 而接至實心板⑽》 7. 如申請專利範圍第4項之電解器,其中陽極(8) 或陰極(9 )經一導電之雙重接合而接至實心板⑽。 8. 如申請專利範圍第5項之電解器,其中陽極(8) 或陰極(9 )經一導電之雙重接合而接至實心板⑽。 9·如申請專利範圍第1項至第3 項任一項之電解 器,其中接觸帶(7),經由一導電的金屬三重接合 整體地連至牆(4A)和實心板(10)之下。 10. 如申請専利範圍第4項之電解器,其中接觸帶 (7) ’經由一導電的金屬三重接合整體地連至牆 (4A)和實心板(10)之下。 經濟部智慧財產局員工消費合作社印製 11. 如申請專利範圍第5項之電解器,其中接觸帶 (7),經由一導電的金屬三重接合整體地連至牆 (4A)和實心板(1〇)之下。 12. 如申請專利範圍第6項之電解器,其中接觸帶 (7) ’經由一導電的金屬三重接合整體地連至牆 -2- 本紙張尺度適用中國國家揉準(CNS ) A4规格(210X297公兼) 六、申請專利範圍 (4A)和實心板(10)之下》 (請先Μ讀背面之注意事項存填寫本S·) 13. 如申請專利範圍第1項至第3項中任一項之電解 器’其中各個後牆(3A)經由一金屬導電的雙重接 合整體地接至實心板(10)。 14. 如申請專利範圍第4項之電解器,其中各個後牆 (3A)經由一金屬導電的雙重接合整體地接至實心 板(10) 〇 15. 如申請專利範圍第5項之電解器,其中各個後牆 (3A)經由一金屬導電的雙重接合整體地接至實心 板(10)。 16. 如申請專利範圍第6項之電解器,其中各個後牆 (3A)經由一金屬導電的雙重接合整體地接至實心 板(10)。 17. 如申請專利範圍第13項之電解器,其中接觸帶(7) 是在後牆(4A)藉組成焊接(build-up welds)來形 成。 . 經濟部智慧財產局貝工消費合作社印製 18·如申請專利範圍第1項至第3項中任一項之電解 器,其中陽極半殼(4)是製自耐鹵素和鹽溶液之 材料。 19. 如申請專利範圍第4項之電解器,其中陽極半殼 (4)是製自耐鹵素和鹽溶液之材料。 20. 如申請專利範圍第5項之電解器,其中陽極半殻 (4)是製自耐鹵素和鹽溶液之材料。 本紙張尺度逋用中國國家橾準(CNS ) Α4規格(210X297公釐) 經濟部智慧財產局員工消费合作社印製Announced D8 Patent Application No. 86113879 "Electrolyzers for the production of halogen gases using electrolytic tanks with metal reinforcements and its manufacturing method" (Amended in November 88) A. Application scope: 1. An electrolyzer ⑴ for the production of halogen gas using an aqueous solution of an alkali metal halide, which is stacked side by side and electrically connected using a plate-shaped electrolytic tank ⑵, each tank is accommodated in two pieces (3, 4) made of conductive material In the shell, a contact band ⑺ is attached to the outer side of at least one tank shell rear wall (3A, 4A). The tank shell is provided with a feeder for supplying tank current and electrolytic feed (11), and a tank current and Device for electrolytic products, comprising an anode ⑻ and a cathode ⑼ each having a substantially horizontal surface *, separated from each other by a partition ⑹ and placed in parallel to each other, passing through metal reinforcements and the rear walls of the respective enclosures (3A, 4A) It is electrically connected, which is characterized in that the gold reinforcement is in the shape of a solid plate (10), which is the same height as the contact band (7), and its side edges (10A, 10B) are as high as the rear wall (3A, 4A). And the total height of the anode (8) or cathode (9) 2 The electrolyzer of the scope of application for patent No. 1 wherein the solid plate (丨 〇) has a solid surface. 3. The electrolytic device according to item 1 of the patent application scope, wherein the solid plate (10) is provided with an opening or a gap (13, 14, 15). 4_ If the electrolytic device of any one of the items 1 to 3 of the scope of patent application, an input distributor is provided, and the electrolyte can be fed into the half shell (3, 4) from then on. This paper size is in accordance with China National Standards (CNS) Λ4 specifications (210X297 mm) (please read the note on the back before filling in this page)-、? τ · Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. The scope of patent application 5. For example, the electrolyzer of item 4 of the scope of patent application, wherein the input distributor is designed so that each section of the half shell (3, 4) can be input through at least one opening in the input distributor. Electrolyte, and the sum of the area of each opening is less than or equal to the cross-sectional area of the input distributor. 6. If the electrolyzer of any one of items 1 to 3 of the scope of patent application, wherein the anode (8) or the cathode (9) is connected to the solid plate through a conductive double joint " The electrolyzer of item 4, wherein the anode (8) or the cathode (9) is connected to the solid plate through a conductive double joint. 8. For the electrolyzer of item 5 of the patent application, wherein the anode (8) or the cathode (9) is connected to the solid plate through a conductive double joint. 9. The electrolyzer according to any one of claims 1 to 3, wherein the contact strip (7) is integrally connected to the wall (4A) and the solid plate (10) via a conductive metal triple junction . 10. For example, apply for the electrolyzer of item 4 of the benefit scope, wherein the contact strip (7) 'is integrally connected to the wall (4A) and the solid plate (10) via a conductive metal triple junction. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 11. If the electrolyzer of item 5 of the patent application scope, the contact strip (7) is integrally connected to the wall (4A) and the solid plate (1) via a conductive metal triple junction 〇). 12. For example, the electrolyzer of the 6th scope of the patent application, in which the contact strip (7) 'is connected to the wall as a whole through a conductive metal triple joint -2- This paper size applies to China National Standard (CNS) A4 (210X297) (Concurrently) 6. The scope of patent application (4A) and the bottom of solid board (10) "(Please read the notes on the back and fill in this S ·) 13. If you apply for any of the items 1 to 3 of the scope of patent application One item of electrolyzer 'wherein each back wall (3A) is integrally connected to a solid plate (10) via a metal conductive double joint. 14. For example, the electrolyzer of the scope of patent application, wherein each back wall (3A) is integrally connected to the solid plate (10) through a metal conductive double joint. 015. For the electrolyzer of the scope of patent application, Each back wall (3A) is integrally connected to the solid plate (10) through a metal conductive double joint. 16. The electrolyzer according to item 6 of the patent application, wherein each back wall (3A) is integrally connected to the solid plate (10) via a metal conductive double joint. 17. The electrolyzer of item 13 of the patent application, wherein the contact strip (7) is formed by build-up welds on the back wall (4A). Printed by the Shelley Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 18. If the electrolyzer of any one of the items 1 to 3 of the scope of patent application, the anode half shell (4) is made of materials resistant to halogen and salt solutions . 19. The electrolyzer as claimed in item 4 of the patent application, wherein the anode half-shell (4) is made of a material resistant to halogen and salt solutions. 20. The electrolytic device according to item 5 of the patent application, wherein the anode half shell (4) is made of a material resistant to halogen and salt solutions. This paper size is printed in China National Standards (CNS) Α4 size (210X297 mm) Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 中陰極半殻(3 )Middle-cathode half-shell (3) 申請專利範圍 ™— 21. 如申請專利範圍第6項之電解器,其中陽極半殼 (4)是製自耐鹵素和鹽溶液之材料。 22. 如申請專利範圍第9項之電解器,其中陽極半殼 (4)是製自耐鹵素和鹽溶液之材料。 23. 如申請專利範圍第13項之電解器,其中陽極半殻 (4)是製自耐鹵素和鹽溶液之材料。 24. 如申請專利範圍第17項之電解器,其中陽極半殼 (4)是製自耐鹵素和鹽溶液之材料。 25. 如申請專利範圍第1項至第3項中任一項之電解 . · 器,其中陰極半殻(3)是製自耐鹸液之材料。 26. 如申請專利範圍第4項之電解器,其中陰極半殻 (3)是製自耐鹸液之材料。 27. 如申請專利範圍第5項之電解器,其中陰極半殻 (3)是製自耐鹼液之材料。 28. 如申請專利範圍第6項之電解器,其中陰極半殻 (3)是製自耐驗液之材料。 29 .如申請專利範圍第9項之電解中陰極半殼(3 ) 是製自耐鹼液之材料。 30.如申請專利範圍第13項之電解 是製自耐鹼液之材料。 输 31. 如申請專利範圍第17項之電解器,其中陰極半殻 (3)是製自耐鹸液之材料。 32. 如申請專利範圍第18項之電解 ί中陰極半殼(3) -4- 本紙張尺度逍用中國國家梯丰(CNS ) Α4规格(210X297公釐) 387947 ABCD 經濟部智慧財產局員工消費合作社印製 六、申請專利範圍 是製自耐鹼液之材料。 33. —種製造如申請專利範圍第1項之電解器之方 法,在其中個別的電解槽首先結合各個外殻之兩 片半殼,配以所有必需之裝置所製成,該等裝置 包括陰極、陽極和隔板,後者用金靥補強物固定, 而且通電連接陽極和陰極至外殻,藉此板狀之各 電解槽經通電連接,且並排安置呈堆疊狀,相互 繫緊於叠中以確保持續地接觸,其特徵在於在實 心板形式之補強物和各個後牆與陽極或陰極間的 金屬導電接合是以還原燒結法或雷射光焊接法之 手段製成,藉由將雷射光焊接法中之雷射光束在 垂直於焊接之方向被極化,以減少頂聯珠與結合區 之間之寬度比率。 34. 如申請專利範圍第33項之方法,其中用光學鏡組 以形成雷射光束使之能夠形成特別光東而產生二 或更多之焦點,位移速率爲可選擇。 35. 如申請專利範圍第33項或第34項之 雷射光以對焊接方向成直角,以可選b之速率使 用以高頻操作之掃瞄器驅動儀,或壓電石英來掃 瞄。 方法,其中 (請先H讀背面之注f項再填寫本頁) 訂· .咴! 本紙張尺度適用中國國家榡準(CNS ) A4规格(210X297公釐)Scope of Patent Application ™ — 21. The electrolyzer according to item 6 of the scope of patent application, in which the anode half shell (4) is made of a material resistant to halogen and salt solutions. 22. The electrolyzer as claimed in item 9 of the patent application, wherein the anode half-shell (4) is made of a material resistant to halogen and salt solutions. 23. The electrolytic device according to item 13 of the patent application, wherein the anode half shell (4) is made of a material resistant to halogen and salt solutions. 24. The electrolytic device according to item 17 of the patent application, wherein the anode half shell (4) is made of a material resistant to halogen and salt solutions. 25. The electrolytic device of any one of the items 1 to 3 of the scope of application for a patent, wherein the cathode half shell (3) is made of a material resistant to rhenium. 26. For example, the electrolyzer of item 4 of the patent application scope, wherein the cathode half shell (3) is made of a material resistant to rhenium. 27. For the electrolyzer of item 5 of the scope of patent application, the cathode half-shell (3) is made of alkali-resistant material. 28. The electrolyzer of item 6 of the patent application, wherein the cathode half-shell (3) is made of a material resistant to the test solution. 29. The cathode half-shell (3) in electrolysis as claimed in item 9 of the scope of patent application is made of a material resistant to alkali. 30. Electrolysis according to item 13 of the scope of the patent application is made of alkali-resistant materials. Loss 31. For example, the electrolyzer of item 17 of the scope of patent application, in which the cathode half shell (3) is made of a material resistant to rhenium. 32. For example, the electrolytic cathode of the 18th in the scope of the patent application (3) -4- The paper size is free to use China National Steps (CNS) Α4 size (210X297 mm) 387947 ABCD Employees of Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the cooperative 6. The scope of patent application is made of materials that are resistant to alkali. 33. A method of manufacturing an electrolyzer such as the one in the scope of patent application, in which an individual electrolytic cell is first made by combining two half-shells of each casing with all necessary devices, including the cathode , The anode and the separator, the latter of which is fixed with a gold reinforcement, and the anode and the cathode are electrically connected to the casing, whereby the plate-shaped electrolytic cells are connected by electricity, and are arranged side by side in a stack shape, which are tied to each other in the stack to Ensuring continuous contact is characterized by the reinforcement in the form of a solid plate and the metal conductive joints between each back wall and the anode or cathode are made by reduction sintering or laser welding, by laser welding The laser beam is polarized in a direction perpendicular to the welding direction to reduce the width ratio between the top beads and the bonding area. 34. For example, the method of claim 33, wherein an optical lens group is used to form a laser beam so that it can form a special light beam to generate two or more focal points, and the displacement rate is selectable. 35. If the laser light in item 33 or 34 of the patent application is applied at right angles to the welding direction, the scanner driver for high-frequency operation or piezoelectric quartz can be scanned at a rate of optional b. Method, which (please read the note f on the back before filling this page). This paper size applies to China National Standard (CNS) A4 (210X297 mm)
TW86113879A 1997-09-24 1997-09-24 Electrolyser for production of halogen gases using electrolysis cells having metal reinforcements, and process for the manufacture thereof TW387947B (en)

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