TW386087B - Amphipathic compound having succinic acid skeleton - Google Patents

Claims (1)

ο Scope of patent application Α8 Β8 C8 D8 Β7.12. 2 3 This amendment 1. An amphiphilic compound having a succinic acid backbone, and is represented by any one of the following formulae (1) to (4): c / 3M J ^ / c1o Η Ι tlx ) 1 c R o CH, C H2C 'w, c1〇c, b—o O (3) CMHUO 2 CHnc 2 = · H [\ c1ο c \ I Η i RI \ C / C1ο R ii ⑷ ο cuuo ri2 eye π3 where lying means one A straight or branched fluorene saturated hydrocarbon group having 6 to 30 carbon atoms, or a straight fluorinated or branched chain unsaturated hydrocarbon group containing at least one and 12. Or K. unsaturated difluorene and having 6 to 30 carbon atoms ; 1 and 2 each represent a hydrogen atom or a methyl group; R represents a straight or branched fluorene saturated hydrocarbon group having 2 to 6 carbon atoms; M represents a hydrogen atom, an alkali metal, or an ammonium group; and X Represents NΗ or N- (CH2-CH = CH2). 2. A kind of amphiphilic compound, which has a succinic acid backbone, and is represented by any of the following formulas (5) to (6): (Please read the precautions on the back before filling this page) Central Standards of the Ministry of Economic Affairs H2C—CH. D = CC = 0 l I? Ya \ / ^ CH (CH2CH20) mH IB, \ CH-CH2] = CC === 0 (CH2CH20) mH, CH, CH, CH , (5) (δ) where Ri represents a straight or branched 鐽 saturated hydrocarbon group having 6 to 30 carbon atoms, or a unsaturated double bond containing at least one and 12 or Μ and having this paper standard applicable to China National Standard (CNS) A4 Specification (210X297mm) -1 ο Scope of Patent Application A8 B8 C8 D8 Β7.12. 2 3 This amendment 1. An amphiphilic compound having a succinic acid backbone, and is represented by any one of the following formulae (1) to (4): c / 3M J ^ / c1o Η Ι tlx ) 1 c R o CH, C H2C 'w, c1〇c, b—o O (3) CMHUO 2 CHnc 2 = · H [\ c1ο c \ I Η i RI \ C / C1ο R ii ⑷ ο cuuo ri2 eye π3 where lying means one A straight or branched fluorene saturated hydrocarbon group having 6 to 30 carbon atoms, or a straight fluorinated or branched chain unsaturated hydrocarbon group containing at least one and 12. Or K. unsaturated difluorene and having 6 to 30 carbon atoms ; 1 and 2 each represent a hydrogen atom or a methyl group; R represents a straight or branched fluorene saturated hydrocarbon group having 2 to 6 carbon atoms; M represents a hydrogen atom, an alkali metal, or an ammonium group; and X Represents NΗ or N- (CH2-CH = CH2). 2. A kind of amphiphilic compound, which has a succinic acid backbone, and is represented by any of the following formulas (5) to (6): (Please read the precautions on the back before filling this page) Central Standards of the Ministry of Economic Affairs H2C—CH. D = CC = 0 l I? Ya \ / ^ CH (CH2CH20) mH IB, \ CH-CH2] = CC === 0 (CH2CH20) mH, CH, CH, CH , (5) (δ) where Ri represents a straight or branched 鐽 saturated hydrocarbon group having 6 to 30 carbon atoms, or a unsaturated double bond containing at least one and 12 or Μ and having this paper standard applicable to China National Standard (CNS) A4 specification (210X297 mm) -1 A8 B8 C8 D8 6. Patent applications for straight or branched chain unsaturated hydrocarbon groups of 6 to 30 carbon atoms; 卩 2 and 1 ~ 3 each represent a hydrogen atom Or methyl; I represents a straight or branched chain saturated hydrocarbon group having 2 to 6 carbon atoms; Y represents NH, H- (CH2-CH = CH2), or 0; and m represents an integer from 1 to 100. 3 . As the amphipathic compound of item 1 of the patent application scope, wherein R 1 is represented by any one of the following formulae (9) to (13): Rs- CH = CH- CH- Rs i (9) where R5 & RS each Represents a hydrogen atom, or a straight alkyl or alkenyl group with (^ to ": 23, provided that the carbon number range of R5 + Rs2 is 3 to 27; (Please read the precautions on the back before filling in this (Page) CHj CHj CH3 -CH2-C = C-CH * fCH2-CH) ^ CH2_CH2 Η (10) CK3 ch3 or CH2 CHa (-CH2-C-c-〇Η- (· 〇Η2-〇Η) -η〇 Η2-έΗ 2 Hz (11) where n is an integer from 0 to 6; CHj. CH3 CHa -CH2-C = * CH-fC 'CH ^ C -CH3 CH3 CH3 printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. (12 ) BX CHZ CHj CH3 -ch2-c-chtC'ch2) 7 ^ ~ ch3 CHj CHi (13) where p represents an integer from 0 to 6. 4. If the amphiphilic compound in item 2 of the patent application scope is represented by the following formula (9) to (13): R 5- CH = CH- CH- R 6 where R t is (9) This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) 6. Application The scope of the patents each represents a hydrogen atom, or a linear alkyl or alkenyl group having (^ to (: 23), provided that the carbon number of R 5 + R s ranges from 3 to 27; ch3 ch3 ch5 ch3 CH2 ^ CHj ch3 -CH2-C = g—CH + CH + 2-CH} ~ nCH2-CH2 or CHj-έ-C_CH * fCH2-CH) ~ CHz-CH2 Η H2 n. .0. ) (11) CH2 'CHj CH3 -CHrC -CH-f C -CH ^ C-CH, CHj CH3 (13) (Please read the notes on the back before filling out this page) where n represents an integer from 0 to 6; ch3 ch3 · CH3 —CHj-C—CH " fC 'CH2} rC —CHj. or CHa CHa (12)-where p is an integer from 0 to 6. 5. An amphipathic compound having phthalic acid or tetrahydrophthalic acid, hexahydrophthalic acid, norbornene dicarboxylic acid, and ice drop represented by the following formulae (14) to (15) Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs G > represents 0, 〇, 〇W where each represents a hydrogen atom or a methyl group; R3 represents a linear or branched saturated hydrocarbon group having 2 to 6 carbon atoms. Represents a hydrogen atom or a methyl group; M represents a hydrogen atom, an alkali metal or an ammonium group; and X represents ΝΗ or the size of the paper is applicable to Chinese National Standard (CNS) A4 specifications (210X297 mm) A8 B8 C8 D8 々, scope of patent application N- (CH2-CH = CH2) 〇6. A polymer compound having an amphipathic property of a succinic acid backbone represented by any one of formulas (18) to (21) by 0.1 to 90.0% by weight The compound or a mixed compound thereof is obtained by copolymerizing 10.0 to 99.0% by weight of a copolymerizable $ ethylenically unsaturated compound. Hzc cl o =, b1Y οL 一, -CH \ C 丨 Ya- / Μ SM \ c 1οR one one ο H2C ο 2 c—c cIc Μ • c10 b1ο ο ο H2 R—ο ST (20 cnuo Γ, £ c \-Η 4, C / CL (21 ο R——ο cuno R3 (Please read the note on the back page first) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs where R t represents a group with 6 to 30 carbon atoms A straight or branched chain saturated hydrocarbon group, or a straight or branched chain unsaturated hydrocarbon group containing at least one and 12 or less unsaturated difluorenes and having 6 to 30 carbon atoms; each of!? 2 and 卩 3 Represents a hydrogen atom or a methyl group; R represents a straight or branched chain saturated hydrocarbon group having 2 to 6 carbon atoms; M represents a hydrogen atom, an alkali metal or an ammonium group; and Υ represents ΗΗ, N- (CH2- CH = CH2) or 0.7. A water-soluble or dispersible amphiphilic polymeric compound, which is represented by the formula (18) to (21) A compound represented by any one formula or a mixture thereof is copolymerized with 10.0 to 99.9% by weight of a hydrophilic ethylene fluorene unsaturated compound. 8 — Paper-making additive, which contains the water-soluble or dispersible amphiphilic polymer compound as the active ingredient as described in item 7 of the scope of the patent application. This paper uses the Chinese National Standard (CNS) A4 (210 X 297) (Mm)-~~ 4 ~-A8 B8 C8 D8 VI. Application for patent scope 9. A polymer compound which uses 0.1 to 9 0. 0 weight as described in item 2 of the scope of patent application I 0. A kind of water-soluble or dispersible amphiphilic media obtained by copolymerizing a compound represented by any one of formulas (5) to (6) or a mixture thereof with 10.0 to 99.9% by weight of a copolymerizable ethylenically unsaturated compound. 0 to 90.0% by weight of a compound represented by any one of formulas (5) to (6) described in item 2 of the patent application range or a mixture thereof with 0.1 to 90.0% by weight % By weight of the hydrophilic ethylenically unsaturated compound #polymerized. II. A reactive interfacial activator, wherein any one of the formulae (5) to (6), any one of the formulae (18) to (21) or the formula (14) ) To (15): (Please read the precautions on the back before copying this ) • means Xin · Order · C 2 Η d1ο __ ο / CH, C ο Y CHL / 20) m Η 2C (CH ^ 2 billion · &Quot; (5) \ iy (5 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs where R i represents a straight or branched 鐽 saturated hydrocarbon group having 6 to 30 carbon atoms, or a group containing at least one and 1 2 Unsaturated double bond under M or M and a straight or branched 鐽 unsaturated hydrocarbon group having 6 to 30 carbon atoms; 1 to 2 and 1 ^ 3 each represent a hydrogen atom or a methyl group; R4 represents a group having 2 to 6 Straight or branched chain saturated hydrocarbon groups of one carbon atom; M represents a hydrogen atom, an alkali metal or an ammonium group; Υ represents NH, H- (CH2-CH = CH2) or 0; and m represents an integer from 1 to 100; Paper size applies Chinese National Standard (CNS) A4 specification (210 /: 297 Gongao) 5 Patent application scope H2C—CH / \ 〇 = cc = l I OM Y, CH-CH, /. \ O = cc: • II o CH, II (18) (19) A8 B8 C8 D8 Hf = clOM onuc • · I, /: 0B-〇Γ-一 r / 〔/: H \ clo XL 5 / Μ t \ c / c1ο R Η ο (20 c «nuo R3 ti / (21 cn» o * Z CH = C H3 where h represents a straight or branched chain saturated hydrocarbon group having 6 to 30 carbon atoms, or one containing at least one and 12 or K Unsaturated difluorene with 6 to 30 carbons Straight or branched 鐽 unsaturated hydrocarbon groups; 1-2 and 卩 3 each represent a hydrogen atom or a methyl group; R4 represents a straight or * branched 鐽 saturated hydrocarbon group having 2 to 6 carbon atoms; M represents a · Ammonia atom, alkali metal or ammonium group; Y means ΝΗ, Ν- (CH2-CH = CH2) or 0; printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 87 and 1 ^ each represent a hydrogen atom or a methyl group; R3 represents a straight or branched chain saturated hydrocarbon group having 2 to 6 carbon atoms; R1D and Ru each represent a hydrogen atom or a methyl group; M represents a hydrogen atom, Alkali metal or ammonium group; and X represents NH or N- (CH2-CH = CH2). 1 2. —A kind of water-dispersible resin composition, which is prepared by inserting 0.1 to 20 paper rule ~~ 6 ~-(Please read the precautions on the back before filling this page) A8 B8 C8 D8 VI. Application scope of patent The weight percent of the reactive interface activator described in item 11 of the scope of patent application and 80 to 99.9 weight: ¾ ethylene fluorinated unsaturated compound is obtained by emulsion polymerization. 13. A polymer interfacial activator, which is prepared by combining 0.1 to 50% by weight of a reactive interfacial activation surface as described in item 11 of the patent application range and 50 to 99.9% by weight of a hydrophilic ethylenic unsaturated Compounds are copolymerized. ^ 14. A kind of water-dispersible resin composition, which is in the presence of 1 to 99% by weight of a macromolecular interfacial activator as described in item 13 of the scope of the patent application, and 99 to 9% by weight of an ethylene-based polymer. Unsaturated compounds are obtained by emulsion polymerization. 15. A method for manufacturing an amphiphilic polymeric compound, characterized in that, by using a reactive interfacial activator as described in item 11 of the scope of the patent application, it is hydrophilic with an aqueous medium in the presence of a colloidal agent. Non-unsaturated unsaturated copolymerization copolymerization. 16. The method for producing an amphiphilic polymer compound according to item 15 of the scope of patent application, wherein 0.1 to 90% by weight of the reactive interfacial activating agent as described in item 15 of the scope of patent application is Moore polymer t-side activator 0.1 to 10 Molar colloidal agent is copolymerized with 10 to 99.9 weight loyal hydrophilic non-ionic ethylene fluorene unsaturated compound in the presence of an aqueous medium. Printed bags for employees' cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) 1 7. For the method of manufacturing amphiphilic median polymer compounds in the scope of patent application No. 16 The morphing agent comprises at least one selected from the group consisting of inorganic acids, organic acids, inorganic bases and organic bases. 18. A method for manufacturing an amphiphilic high molecular compound, characterized in that, by using a reactive interfacial active agent having at least one fluorene group in the molecule, it is hydrophilic in an aqueous medium in the presence of a colloidal agent. Copolymerization of nonionic ethylene fluorene unsaturated compounds. This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) A8 B8 C8 D8 388087 Application for patent scope 19. For example, for the method of manufacturing amphiphilic median polymer compound in the patent application No. 18, of which 10 to 99.9% by weight of a hydrophilic nonionic ethylenically unsaturated compound in the presence of 0.1 to 10 moles of colloidal agent per mole of polymer interface activator and 0.1 to 90% by weight of the molecule having at least one carboxyl group in the molecule The reactive interfacial activator is copolymerized in an aqueous medium. 20. The method for manufacturing an amphiphilic polymer compound according to item 19 of the scope of patent application, wherein the colloidalizing agent comprises at least one selected from the group consisting of inorganic acids, organic acids, inorganic bases and organic bases. (Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs This paper applies the Chinese National Standard (CNS) Α4 specification (210X297 mm) 8-Q _