B7 五、發明説明（1 ) 本發明係關於一種使用於滚筒之釋離劑之改良滾筒釋離 性質之方法。尤其本發明係關於一種使用於造紙中類似加 壓滾筒之滾筒釋離劑，及改良此類滾筒釋離性質之方法。 .ο装. 订 在許多技術方法中，如薄膜，網狀織物等之連磧材料係 在滾筒上通過。取決於環境（溫度，壓力，濕度含量等）， 該連續材料多少黏附於滾筒，所以需要某種釋離力以將連 續材料從滚筒移除。因而常以釋離劑處理此類滾筒以降低 該釋離力並促進連續材料從滾简移除。此類釋離劑之組成 廣泛不同，取決於通過滾筒上之連續材料本質，滾筒之材 料及表面狀態和操作環境。一般而言，此類用劑包括釋離 活性劑，經常亦稱爲潤滑劑。此類用劑經常以純態或乳液 形式使用。 .4 在連續材料通過滾筒上之時常涉及的一個問題在於沉積 形成於滾简表面上，其源自連續材料之成份或污染物。此 類沉積對於滾筒效能有不利影響，最後爲了能夠清潔滾筒 停止操作。爲了避免該清潔或至少提高此清潔中止便使用 沉積預防劑，其組成取決於特定操作，但大部份包括一聚 合物質》 經濟部令夬梂準局員工消费合作社印褽 因爲已知之釋離劑和沉積預防劑常不完全令人滿意，本 發明之目的係提供一種使用於滚筒之改良釋離劑和一種使 用該用劑改良滾筒釋離性質之方法。本發明之目的更在於 改良用以預防滾筒上沉積之物質效力。 因此本發明係關於一種使用於造紙中類似加壓滾筒之滾 筒釋離劑，其包括一種或多種釋離活性組份及視需要之傳 — -4- &張尺度適用中國國家標準（CNS) A4規格（210X297公;Ϊ1 M濟部中夹揉準局Λ工消费合作社印製 第85111949號專利申請案 A7 中文説明書修正頁(86年12月） B7 afllli · niiiwn I I - . » . · · . 五、發明税明（2 ) | ； ...— . —.................— 統添加劑，該釋離劑特徵在於其爲乳液形式》 此外本發明係關於一種改良類似造紙加壓滾筒之滚筒釋 離性質之方法，特徵在於以水稀釋根據本發明之釋離劑破 壞該微乳液，及將該稀釋微乳液應用於滚筒。 從以下發明詳述及申請專利範团，本發明之較佳具體實 施例和優點將顯而易見。 而本發明通常可應用於各種其上通過連續材料之滚筒， 本發明特別適用於造紙廠，因此以下將特別參考造紙和其 中涉及之特定問題敘述本發明。 關於造紙滾筒，尤指加壓滾筒已知之釋離劑或潤滑劑係 油類，非水溶性界面活性劑，非水溶性聚合物和蠟，其係 應用於滚筒（例如以噴霧），於本發明中亦是有用的。而這 些釋離活性物質中一些能夠使用純態，爲了易於應用及在 滚筒上較良好分佈，與使用純態相較之下結合所需之活性 物質量較小，其大部份以乳液（巨乳液）形式使用。然而， 咸知這些用劑遭遇大量有機沉積之問題，且不能夠預防有 機沉積。 現意外發現以此問題能夠被克服或至少相當地降低，倘 若釋離劑係微乳液形式，在應用於滾筒前才以水稀釋。微 乳液係含有大小低於1 OOnm粒子之透明分散液，大部份包 括油性组份，界面活性劑，共界面活性劑和水。有些時候 該油性組份和共界面活性劑能夠相同。微乳液經常羌低黏 度·。個別组份係以使得至少在室溫形成安定液態單相系統 之量存在。微乳液之適當組份及製備以及微乳液性質係已 5- 本紙張尺度適用中國困家標準（CNS ) A4規格（210X297公釐） ο 裝1T-^ 0^ - - (請先s讀背面之注$項再填寫本霣) 第85111949號專利申請案 中文説明書修正頁(86年12月> 五、發明説明（3 A7 —V_JL7 明^2·12補充 知並於文獻中多方面敘述（例如見1983年馬瑟狄克公司 (Marcel Dekker，Inc.)之乳液技術百科全書（Encyclopedia 〇f Emulsion Technology) ; 1989 年約輪韋利桑司公司（John Wiley & Sons，_Inc.)米爾領 J.羅森（Milton J. Rosen)所著之界 面活性劑和界面現象（Surfactants and Interfacial Phenomena);和1988年馬瑟狄克公司界面活性劑科學系列 (Surfactant Science Series)第 30册，M.跑立爾（Bourrel)和 R.S.雪勒特（Schlechter)所著之••微乳液及相關系統-配方， 溶解和物理性質（{^01：061111|181〇113311<1代1316<1578161115-For-mulation，solvency and physical properties)") β 不受限於理論，咸相信根據本發明之改良處根據之事實 在於當稀釋區乳液形式之已知釋離劑時，含釋離活性成份 之乳液滴並未物理變化，相反地，當稀釋時微乳液恰安定 ，且當稀釋時變爲混濁，即釋離活性成份自溶液釋離》換 言之，稀釋巨乳液主要提高連續相的量但保留安定度，因 而乳液滴在滾筒表面上沉積之趨勢較不受影響。相反地， 稀釋時在微乳液中發展之粒子沉積於滾筒表面上之趨勢遠 較大。因此，需要微乳液稀釋時之不安定性以得到本發明 之優點。 稀釋時在微乳液中得到活性成份之粒子大小較小，或者 較佳大於對應巨乳液之粒子大小。粒子越大越難以保持安 定，但釋離效能越佳》將稀釋時粒子大小小於微乳液之巨 乳液保持安定（6個月有效期限）是困難的。因此，需要以 添加適當安定劑將此巨乳液充份安定化，其表示該油性组 -6- 本紙张Α度適用中國國家標芈（CNS ) Α4規格（210X297公釐） 11 ir· -~ (請先《讀背«之注袭項再.填寫本頁) 經濟部中夫標率局負工消费合作社印*. 補充 第8511丨949號專利申請案 中文說明書修正頁(88年9月） 五、發明説明（4 ) 份具有停留於水相之強趨勢。所以再次失去其官能（見以 上）。相反地微乳液容許6個月安.定有效期限，且僅當消費 者使用時，即稀釋時才變得不安定。倘若稀釋微乳液粒子 太大（例如15 0微米或更大），則降低之表面覆蓋力與改 良之釋離不再抵銷，因為不存在足夠粒子以覆蓋滾筒表面（ 對照實例4)。因而通常較佳該微乳液組成係當稀釋時得到 之粒子大小介於10至15〇微米之間，較佳為2〇至1〇〇微米（ 科爾特計數器（Coulter Counter)，見實例4)。 更發現根據本發明之釋離劑提供沉積預防，倘若添加已 知作為沉積抑制劑之水溶性聚合物。例如氰胍—甲醛縮合 物特別適當^ EP 0 599 440 A1中對於適當之聚合物有更明 白之概論，將該揭示併入本文供參考。 除釋離活性組份和沉積預防組份外，根據本發明之釋離 劑能夠包括傳統添加劑，如酸，清潔界面活性劑，鹽等， 條件為該添加劑對於乳液安定釋離活性與沉積預防組份之 效力無不利影響。 經濟部中央樣準局貝工消费合作社印製 在改良類似造紙加壓滾筒之滾筒釋離性質之方法中，微 乳液釋離劑係以水稀釋破壞微乳液，其後將稀釋微乳液應 用於滚筒。實務上應用濃度經常介於01至重量比之 間，〇_2至1_〇%重量比之間較佳，即該微乳液係以水稀釋 至此一程度’使得真正應用於滾筒之组合物包括〇1至15 %重量比原始微乳液，〇 2至1. 〇〇/。重量比較佳。 根據本發明之一替代具體實施倒，亦可能製備一種釋離 劑’其包括上述除水之外所有組份。個別組份之存在量使 本紙張从適用Tllil家標準（CNS > Mg-(加謂公瘦了 A7 B7B7 V. Description of the invention (1) The present invention relates to a method for improving the release property of a roller using a release agent for a roller. In particular, the present invention relates to a roller release agent similar to a pressure roller used in papermaking, and a method for improving the release properties of such a roller. In many technical methods, flail materials such as films, mesh fabrics, etc. are passed on rollers. Depending on the environment (temperature, pressure, humidity content, etc.), how much the continuous material adheres to the drum, so some release force is needed to remove the continuous material from the drum. Such drums are often treated with a release agent to reduce this release force and facilitate the removal of continuous material from the roll. The composition of such release agents varies widely, depending on the nature of the continuous material passing through the drum, the material and surface condition of the drum, and the operating environment. Generally, such agents include release actives, often also referred to as lubricants. Such agents are often used in pure form or as emulsions. .4 A problem often involved when continuous material is passed over the drum is that deposits are formed on the rolled surface and originate from components or contaminants of the continuous material. Such deposits have a detrimental effect on the performance of the rollers, and in the end stop operation in order to be able to clean the rollers. In order to avoid the cleaning or at least improve the cleaning interruption, a deposition preventive agent is used, whose composition depends on the specific operation, but most of it includes a polymer substance. And deposition prevention agents are often not completely satisfactory, and the object of the present invention is to provide an improved release agent for use in a roller and a method for improving the release property of a roller using the agent. The object of the present invention is to improve the effectiveness of the substance for preventing the deposit on the drum. Therefore, the present invention relates to a roller release agent similar to a pressurized roller used in papermaking, which includes one or more release active components and a transmission as needed — -4- & Zhang scale is applicable to Chinese National Standards (CNS) A4 specifications (210X297 male; Ϊ1 M printed by the Ministry of Economic Affairs of the Central Bureau of Industrial and Commercial Cooperation Co., Ltd. printed No. 85111949 patent application A7 Chinese manual revision page (December 86) B7 afllli · niiiwn II-. ». · · · V. Invention tax declaration (2) |; ... —. — .. — — system additive, the release agent is characterized by its emulsion form. The present invention relates to a method for improving the release properties of a roller similar to a paper-making pressurized roller, which is characterized by diluting the release agent according to the present invention with water to destroy the microemulsion, and applying the diluted microemulsion to the roller. When referring to the patent application group, the preferred embodiments and advantages of the present invention will be obvious. The present invention can generally be applied to a variety of cylinders through which continuous materials pass. The present invention is particularly suitable for paper mills, so the following will make special reference to papermaking And the specifics involved The problem is described in the present invention. Regarding papermaking rollers, especially pressurized rollers, known release agents or lubricants are oils, water-insoluble surfactants, water-insoluble polymers and waxes, which are applied to rollers (such as spray ), Which is also useful in the present invention. Some of these release active substances can be used in the pure state. For ease of application and better distribution on the drum, the mass of active substance required in combination with the use of the pure state. Smaller, most of them are used in the form of emulsion (macroemulsion). However, it is known that these agents suffer from a large amount of organic deposition and cannot prevent organic deposition. It has been unexpectedly found that this problem can be overcome or at least considerably equivalent. Reduce, if the release agent is in the form of microemulsion, it is diluted with water before being applied to the roller. The microemulsion is a transparent dispersion containing particles less than 100 nm in size, most of which include oily components, surfactants, and co-interfaces Active agent and water. Sometimes the oily component and co-surfactant can be the same. Microemulsions are often low viscosity. Individual components are formed so that they form at least at room temperature The amount of stable liquid single-phase system exists. The proper composition and preparation of the microemulsion and the nature of the microemulsion have already been 5- This paper size is applicable to China Standards (CNS) A4 (210X297 mm) ο 1T- ^ 0 ^ --(Please read the note $ on the reverse side and fill in this note) No. 85111949 Patent Application Chinese Specification Revision Page (December 86 > V. Description of Invention (3 A7 —V_JL7 Ming ^ 2 · 12 Supplement Know and describe in many aspects in the literature (see, for example, Encyclopedia 〇f Emulsion Technology, Marcel Dekker, Inc., 1983; John Wiley, 1989 & Sons, Inc.) Surfactants and Interfacial Phenomena by Milton J. Rosen; and Surfactant Scientific Series of Surfactants, 1988 Science Series) Volume 30, by M. Bourrel and RS Schlechter • Microemulsions and related systems-formulations, dissolution and physical properties ({^ 01: 061111 | 181〇113311 < 1st generation 1316 < 1578161115-For-mulation solvency and physical properties) ") β is not limited to theory, but it is believed that the improvement according to the present invention is based on the fact that when a known release agent in the form of a dilution zone emulsion is used, the emulsion drops containing the release active ingredient are not Physical changes. On the contrary, the microemulsion is stable when diluted, and becomes turbid when diluted, that is, the active ingredient is released from the solution. In other words, the dilute macroemulsion mainly increases the amount of continuous phase but retains stability, so the emulsion The tendency of drops to deposit on the surface of the drum is less affected. In contrast, particles developed in the microemulsion at the time of dilution have a much greater tendency to deposit on the surface of the drum. Therefore, the instability of microemulsion dilution is required to obtain the advantages of the present invention. The particle size of the active ingredient obtained in the microemulsion upon dilution is smaller, or preferably larger than the particle size of the corresponding macroemulsion. The larger the particles, the more difficult it is to maintain stability, but the better the release efficiency. It is difficult to maintain stability (6 months expiration date) for a giant emulsion with a particle size smaller than that of a microemulsion when diluted. Therefore, it is necessary to fully stabilize this macroemulsion with the addition of appropriate stabilizers, which indicates that the oily group-6- this paper A degree is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 11 ir ·-~ ( Please read the note of “Reading Back” first. Fill out this page) Printed by the Chinese Ministry of Economic Affairs and the Bureau of Labor Standards and Consumer Cooperatives *. Supplementary page of the Chinese manual for Patent Application No. 8511 丨 949 (September 88) 5 (4) The invention has a strong tendency to stay in the water phase. So it loses its function again (see above). Conversely, microemulsions allow a stable shelf life of 6 months and become unstable only when used by the consumer, i.e. when diluted. If the diluted microemulsion particles are too large (e.g. 150 microns or larger), the reduced surface coverage and improved release are no longer offset because there are not enough particles to cover the surface of the roller (Comparative Example 4). Therefore, it is generally preferred that the particle size of the microemulsion composition when diluted is between 10 and 150 microns, preferably between 20 and 100 microns (Coulter Counter, see Example 4) . It has further been found that the release agent according to the present invention provides deposition prevention if a water-soluble polymer known as a deposition inhibitor is added. For example, cyanoguanidine-formaldehyde condensates are particularly suitable ^ EP 0 599 440 A1 has a clearer overview of suitable polymers, the disclosure of which is incorporated herein by reference. In addition to the release active component and the deposition prevention component, the release agent according to the present invention can include traditional additives such as acids, cleaning surfactants, salts, etc., provided that the additive is effective for emulsion stable release activity and deposition prevention group. No adverse effect on the effectiveness of the share. Printed in the method of improving the release properties of rollers similar to paper pressurized rollers by the Central Bureau of Prototype and Boiler Consumer Cooperative of the Ministry of Economic Affairs. . In practice, the application concentration is often between 01 and weight ratio, and preferably between _2 and 1_0% by weight. That is, the microemulsion is diluted to this extent with water. 〇1 to 15% by weight of the original microemulsion, 〇2 to 1. 〇〇 /. Better weight. According to an alternative embodiment of the present invention, it is also possible to prepare a release agent ' which includes all of the above components except water. The amount of individual components makes this paper suitable for the Tllil family standard (CNS > Mg- (plus weight) A7 B7
第85111949號專利申請案 中文説明書修正頁(86年12月) 五、發明说明（5 ) 得當添加水時形成一微乳液。換言之，此本發明之具嫌實 施例係關於一種"濃縮物"或"潛在微乳液"，即當添加適當 水時能夠形成一微乳液。因爲實務上係添加過量水（見以上 )，在此本發明之具體實施例中，微乳液態恰爲一中間物， 爲了釋離該釋離活性成份立即破壞微乳液。理所當然，爲 了眞正形成微乳液並存在一有限時間，水能夠逐步添加（當 釋離劑輸送至滾筒時添加二或多次水）。 以下實例係根據本發明之原理説明本發明，但不以任何 方式限制本發明，除申請範圍中所指之外。所有份數及百 夯比係重量比除非另外指出。 圈式簡單説明： B1顯示各種乳液及水溶液之釋離力對釋離劑濃度（於綠 色花崗石上測量之釋離力）。 闽2顯示各種釋離劑之自滚筒移除紙之紙張寬度。釋離劑 係敘於第9至12頁之實例3中。 實例1 以測定取決於稀釋程度所需之釋離力，研究微乳液，巨 乳液，含陽離子聚合物之水溶液和含陰離子聚合物之水溶 液形式之釋離劑薄張釋離β在此測試中將一剛製備之潮濕 手抄薄張加壓於樣品滾筒材料上，直到得到4〇%均句度 (40〇/。纖維和60%水）之薄張’其黏附於樣品滾筒材料表面。 其後測量從樣品滚筒材料剝離紙所需之力。 結果示於囷！，其中濃度1〇〇%表示未稀釋釋離劑，而滚 度表示包括99.9%重量比水和〇.1%重量比原始未稀釋 --------0¾.------..IT--------ow^ 一 -. (請先Η讀背面之注$項再，填寫本κ ) 經濟部中夬標率局貝工消费合作社印製 8 - A7 B7Patent Application No. 85111949 Chinese Version Correction Sheet (December 86) V. Description of the Invention (5) A microemulsion is formed when water is added. In other words, this suspected embodiment of the present invention relates to a " concentrate " or " potential microemulsion ", i.e., a microemulsion can be formed when appropriate water is added. In practice, an excessive amount of water is added (see above). In the specific embodiment of the present invention, the microemulsion state is just an intermediate, and the microemulsion is immediately destroyed in order to release the released active ingredient. As a matter of course, in order to form microemulsions and exist for a limited time, water can be added gradually (adding two or more times when the release agent is delivered to the drum). The following examples illustrate the invention according to its principles, but do not limit the invention in any way, except as indicated in the scope of the application. All parts and percentages are weight ratios unless otherwise specified. Brief description of the ring type: B1 shows the release force of various emulsions and aqueous solutions on the release agent concentration (release force measured on green granite). Min 2 shows the paper width of various release agents for removing paper from the roller. The release agent is described in Example 3 on pages 9 to 12. Example 1 To determine the release force required depending on the degree of dilution, study the release agents in the form of microemulsions, macroemulsions, aqueous solutions containing cationic polymers and aqueous solutions containing anionic polymers. A freshly prepared wet sheet was pressed onto the sample roll material until a sheet of 40% average pitch (40% fiber and 60% water) was obtained, which adhered to the surface of the sample roll material. Thereafter, the force required to peel the paper from the sample cylinder material was measured. The results are shown in 囷! , Where the concentration of 100% indicates the undiluted release agent, and the roll degree indicates that it includes 99.9% by weight of water and 0.1% by weight of the original undiluted -------- 0¾ .-------- ..IT -------- ow ^ I-. (Please read the note on the back before filling in this κ) Printed by the Shellfish Consumer Cooperative of the Bureau of Standards and Technology of the Ministry of Economic Affairs 8-A7 B7
第85111949號專利申請案 中文説明書修正頁(86年12月） 五、發明説明（） 釋離劑之组合物。 巨乳液由20%重量比調整動物油，7.5%重量比二種非離 子界面活性劑之混合物和72.5%重量比水組成。微乳液由 8.7%重量比調整動物油，11.1%重量比陽離子聚合物， 13.7%重量比2-丁氧基乙醇，17.2%重量比非離子界面活性 (請先《讀背面之注f項再填寫本頁> 經濟部中夬樣準局貝工消费合作社印製 8a- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ΑΤ Β7 五、發明説明（6 ) 劑，1 ·3%陽離子界面活性劑和48%水組成。陽離予聚合物 之水溶液由2.5%重量比陽離子聚合物，5%重量比非離子 界面活性劑，0.02%重量比磷酸和92.48%重量比水組成。 陰離子聚合、物之水溶液由5%重量比陰離聚合物，1 〇%重量 比陰離子聚合物50%水溶液和85%水組成。 從圖1能夠看到釋離效能隨稀釋巨乳液成比例降低。藉 著稀釋微乳液，相較於100%微乳液，10%微乳液之釋離效 能提高。進一步稀釋達約1%時，其效能保持相當固定。因 此少量油在微乳液中效能較大量相同油配方於巨乳液中佳 〇 實例2 進行實驗室和研究釋離測試，比較根據本發明之微乳液 與傳統水溶液及巨乳液形式產品。實驗室釋離測試如實例 1中所述般進行。在研究釋離測試中，係將產品經由喷霧 棒應用於加壓滾筒上。以公分表示測量來自滚筒之紙釋離 點。結果如下表。 {請先«'贫背如之注f項再填寫本頁) 訂 a. 經濟部t央棣车局貝工消費合作社印製 測試產品 於2000 ppm之實驗測試 薄張釋雜力(牛頓/公尺） 於8000 ppm之研究測試 釋離點(公分） 空白（水） 1.80±0.10 0 陽離子水溶液I 1.73 土 0.02 0.5 陽離承水溶液II 1.47 土 0.02 0.4 非離子巨乳液 1.21 ±〇.〇4 0.8 陽離子微乳液 1.08±0.04 1.5 -9 - 紙張尺度逋用中國國家揉準（CNS ) Α4規格（210X297公釐 經濟部中央標準局員工消费合作社印製 A7- B7 五、發明説明（7 ) 陽離子水溶液I係一商業用產品，用20〇/〇重量比陽離子聚 合物，5%重量比非離子界面活性劑，5%重量比磷酸和7〇% 重量比水組成。陽離子水溶液π係與實例i中所使用相同之 產品°非離子巨乳液係由20%重量比調整動物油，7.5%重 量比二種非離子界面活性劑之混合物，1 0%重量比陽離子 界面活性劑，2.23%重量比磷酸和69.27%重量比水組成。 根據本發明之陽離子微乳液係由8%重量比調整動物油， 2%重量比陽離子聚合物，19%重量比非離子界面活性劑， 19%2-丁氧基乙醇和52〇/〇重量比水組成。 測試結果顯示根據本發明之微乳液產生最低釋離力，因 而同意其提供最高釋離點。 實例3 在另一研究中測試三種不同微乳液，並與傳統水溶液和 巨乳液形式產品比較。在此測試中測定來自加墨滾筒之紙 張寬度。紙張寬度随著從滾筒移除紙所需之釋離力提高而 減低。紙張越寬，所需釋雜力越小。研究測試之結果示於 圏2中。 產7306係一商業產品’爲陽離子聚合物水溶液，由 17.0%重量比第一陽離子聚合物，2%重量比第二陽離子聚 合物，0.5%重量比陽離子界面活性劑，5%重量比鱗酸及 75%重量比水組成。產品27·5係一巨乳液，由19 9%重量比 調整動物油’ 2.49%重量比非離子界面活性劑（乙氧基化笼 麻油，HLB 15) ’ 4.98%重量比另一非離子界面活性劑（乙 氧基化脂肪酸，HLB5)。1%重量比雙（2、羥乙基）油酸胺， C請先«请背*-之注$項再填寫本頁) 柒.Patent Application No. 85111949 Amendment Sheet of Chinese Manual (December 86) 5. Description of Invention () Composition of release agent. The macroemulsion is composed of 20% by weight adjusted animal oil, 7.5% by weight of a mixture of two non-ionic surfactants, and 72.5% by weight of water. The microemulsion is adjusted from 8.7% by weight animal oil, 11.1% by weight cationic polymer, 13.7% by weight 2-butoxyethanol, 17.2% by weight non-ionic interface activity (please read "Note f on the back side before filling in this Page > Printed by the China Bureau of Standards and Quarantine, Shellfish Consumer Cooperatives, 8a- This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) ΑΒΒ7 V. Description of the invention (6) Agent, 1.3% Cationic surfactant and 48% water. The aqueous solution of the cationic polymer is composed of 2.5% by weight cationic polymer, 5% by weight non-ionic surfactant, 0.02% by weight phosphoric acid and 92.48% by weight water. Anion The aqueous solution of polymer is composed of 5% by weight anion polymer, 10% by weight anion polymer 50% water solution and 85% water. From Figure 1, we can see that the release efficiency decreases in proportion to the diluted macroemulsion. Compared with 100% microemulsion, the release efficiency of 10% microemulsion is improved. Compared with 100% microemulsion, the release efficiency of 10% microemulsion is improved. When it is further diluted to about 1%, its efficiency remains quite fixed. In the giant emulsion 〇Example 2 A laboratory and research release test was performed to compare the microemulsion according to the present invention with traditional aqueous and macroemulsion form products. The laboratory release test was performed as described in Example 1. In the research release test, the system The product is applied to a pressure roller via a spray stick. The paper release point from the roller is measured in centimeters. The results are shown in the table below. {Please «'poor back as noted in item f before filling out this page) Order a. Economy Department of Yangyang Automobile Bureau, Shelley Consumer Cooperative Co., Ltd. Printed and tested products at 2000 ppm. Experimental test sheet release force (Newton / meter) Research test release point (cm) at 8000 ppm Blank (water) 1.80 ± 0.10 0 Cationic aqueous solution I 1.73 soil 0.02 0.5 Anion bearing aqueous solution II 1.47 soil 0.02 0.4 non-ionic macroemulsion 1.21 ± 〇.〇4 0.8 cationic microemulsion 1.08 ± 0.04 1.5 -9-Paper size: China National Standard (CNS) Α4 Specifications (210X297 mm printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7- B7 V. Description of the invention (7) Cationic aqueous solution I is a commercial product, using 20/0 weight ratio cationic polymer, 5% weight ratio Non-ionic surfactant, consisting of 5% by weight phosphoric acid and 70% by weight water. Cationic aqueous solution π is the same product used in Example i. Nonionic macroemulsion is adjusted by 20% by weight animal oil, 7.5% by weight It is composed of a mixture of two non-ionic surfactants, 10% by weight cationic surfactant, 2.23% by weight phosphoric acid and 69.27% by weight water. The cationic microemulsion according to the present invention is adjusted by 8% by weight animal oil, It is composed of 2% by weight cationic polymer, 19% by weight non-ionic surfactant, 19% 2-butoxyethanol and 52/0 by weight water. The test results show that the microemulsion according to the present invention produces the lowest release force, and it is agreed that it provides the highest release point. Example 3 In another study, three different microemulsions were tested and compared with products in the form of traditional aqueous and macroemulsion products. In this test, the width of the paper from the inking roller is determined. The paper width decreases as the release force required to remove the paper from the roller increases. The wider the paper, the less force is required to release it. The results of the research test are shown in 圏 2. A 7306 series commercial product is a cationic polymer aqueous solution, consisting of 17.0% by weight of the first cationic polymer, 2% by weight of the second cationic polymer, 0.5% by weight of the cationic surfactant, and 5% by weight of the scale acid and 75% by weight of water. Product 27 · 5 is a giant emulsion, adjusted from 19 9% by weight animal oil '2.49% by weight non-ionic surfactant (ethoxylated cage hemp oil, HLB 15)' 4.98% by weight to another non-ionic surfactant (Ethoxylated fatty acids, HLB5). 1% by weight of bis (2, hydroxyethyl) oleic acid amine, C please «Please memorize the * in the note before filling this page) 柒.
IQ -10- 經濟部中央標隼局負工消费合作社印製 ΛΤ B7 五、發明説明（8 ) 0.5°/。重量比二烷基（c8_Ci〇)二甲基氣化銨，5.1%重量比磷 跋（85%)和66.03%重量比水組成。產品27-1至27-4係具以下 組成之微乳液。 27-1 : 8%重量比調整動物油，2%重量比雙氰醢胺-甲醛缩 合物（50¾水溶液），20%重量比乙氧基化（3EO) C!3-聛肪醇’ 16.8%重量比三乙二醇單丁基醚，2%重量 比一燒基（C8-C 1〇)二甲基氣化按，〇.〇40/〇重量比鱗酸 (85%)和51.16%重量比水。 27-2 : 7°/。重量比調整動物油，2%重量比雙氰醯胺-甲醛縮 合物，20%重量比乙氧基化（3EO) C丨3-脂肪醇， 16.8%重量比三乙二醇單丁基醚，2%重量比二烷基 (CVC 1〇)二甲基氣化銨，〇.〇4〇/〇重量比磷酸（85%)，1% 重量比異石蠟和51· 16%重量比水。 27-3 : 2.01%重量比調整動物油，1.99%重量比雙氰醯胺·甲 醛縮合物，19.92%重量比乙氧基化（3£0)(：丨3-脂肪醇 ’ 13.94%重量比三乙二醇單丁基醚，3 78%重量比二 虎基（C.do)·一甲基氣化按’ 0.02%重量比鱗酸（85%) 和60.34%重量比水。 27-4 : 8%重量比調整動物油，2%重量比陽離子聚合物， 19%重量比2-丁氧基乙醇，19%重量比乙氧基化c9-Cn酵和52 %重量比水。 示於圈2中之測試結果清楚地說明根據本發明之微乳液 產生較低紙張收縮，表示由於較低釋離力，較易從滾筒移 除。 -11 - Q 讀先«-會背&-之注意事項再填寫本瓦) 本纸張尺度適用中國國家揉準（CNS ) 格（210X297公釐） B7 五、發明説明（9 ) 實例4 如上所解釋，當似水稀釋時微乳液必需是不安定以便有 最佳效能。不安定乳液之效能較安定者佳。其後將由滴從 水"喷出"，並更強力吸收於滾筒表面上。當稀釋時，微乳 液更必需提供足夠粒子以覆蓋滾筒表面。然而，藉著以水 稀釋並測量以稀釋得到混濁組合物之粒子大小，能夠輕易 地測定微乳液之最佳組成。 藉著將微乳液稀釋至0.2%之濃度，即添加99.8%重量比 水，得到下表中摘錄之測試結果（測試條件見實例1)。使用 科爾特計數器LS 130測定粒子大小。將得到粒子大小分布 (體積务佈）極大値作爲粒子大小。 (·請先：k1*·背面之注意事項再填寫本頁) •ο裝 經濟部中央標準局貝工消費合作社印製 微乳液所含成份 釋離力 評估 (空白=1_90牛頓/公尺） 8% 油 Χ/0%Α 1.51 稀釋時清澈/無粒子 8% 油 X/1%A 1.11 稀釋時混濁 8%油X/20%疏水性界面活性 0.88 稀釋時混濁/ 劑/3%A 12微米粒子大小 6.7% 油+1.3% 油 Y 0.82 稀釋時混濁/ 20%疏水性界面活性劑/3%A 32微米粒子大小 4% 油 X+4% 油 Y 0.84 稀釋時混濁/ 20%疏水性界面活性劑/3%A 116微米粒子大小 8%油Y 0.91 稀釋時混濁/ 20%疏水性界面活性劑/3°/〇A 153微米粒子大小 訂 -12- 本紙張尺度適用中國國家標準（CNS > A4規格（210X297公釐） A3- B7 384330 五、發明説明（1〇 ) 上表中油X係調整動物油，油Y係異石蠟油，疏水性界 面活性劑係乙氧基化（3EO) C13-脂肪酵，A爲二烷基（C8-cio)二甲基氣化銨。 從上表摘錄之結果能夠看到，第一微乳液太安定，因而 不能釋離油粒子。因此當稀釋時保持清澈，並產生較高釋 離力》第三，四，五和六微乳液僅油性組份之組成不同。 能夠看到測得最低釋離力爲第四微乳液，其提供3 2微米之 粒子大小。 請· 先 M- 讀- 背 it. 之 注IQ -10- Printed by the Consumers ’Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs ΛΤ B7 V. Description of the invention (8) 0.5 ° /. The weight ratio of dialkyl (c8_Ci0) dimethyl ammonium vapor, 5.1% by weight phosphorus phosphate (85%) and 66.03% by weight water. Products 27-1 to 27-4 are microemulsions with the following composition. 27-1: 8% weight ratio adjusted animal oil, 2% weight ratio dicyanofluoride-formaldehyde condensate (50¾ aqueous solution), 20% weight ratio ethoxylated (3EO) C! 3-aliphatic alcohol '16.8% weight Than triethylene glycol monobutyl ether, 2% by weight mono- (C8-C 10) dimethyl gasification ratio, 0.040 / 〇 by weight scale acid (85%) and 51.16% by weight ratio water. 27-2: 7 ° /. Weight ratio adjustment animal oil, 2% by weight dicyanamide-formaldehyde condensate, 20% by weight ethoxylated (3EO) C 丨 3-fatty alcohol, 16.8% by weight triethylene glycol monobutyl ether, 2 % By weight dialkyl (CVC 10) dimethyl ammonium gasification, 0.04 / 0 by weight phosphoric acid (85%), 1% by weight isoparaffin, and 51.16% by weight water. 27-3: 2.01% weight ratio adjusted animal oil, 1.99% weight ratio dicyandiamide · formaldehyde condensate, 19.92% weight ratio ethoxylated (3 £ 0) (: 丨 3-fatty alcohol '13.94% weight ratio three Ethylene glycol monobutyl ether, 3 78% by weight of dioxoyl (C.do) · monomethyl gasified by '0.02% by weight of phosphonic acid (85%) and 60.34% by weight of water. 27-4: 8% by weight adjusted animal oil, 2% by weight cationic polymer, 19% by weight 2-butoxyethanol, 19% by weight ethoxylated c9-Cn yeast and 52% by weight water. Shown in circle 2 The test results clearly show that the microemulsion according to the present invention produces lower paper shrinkage, which indicates that it is easier to remove from the roller due to lower release force. -11-Q Read «-Will Back &-Cautions again (Fill this tile) The paper size is applicable to the Chinese National Standards (CNS) grid (210X297 mm) B7 V. Description of the invention (9) Example 4 As explained above, the microemulsion must be unstable when diluted like water, so as to have the best Good performance. Unstable emulsion is more effective than stable ones. After that, it will be “dropped out” from the water and absorbed more strongly on the surface of the drum. When diluted, the microemulsion must more than provide enough particles to cover the surface of the drum. However, the optimum composition of the microemulsion can be easily determined by diluting with water and measuring the particle size of the cloudy composition obtained by the dilution. By diluting the microemulsion to a concentration of 0.2%, that is, adding 99.8% by weight of water, the test results excerpted from the table below are obtained (see Example 1 for the test conditions). Particle size was determined using a Colt counter LS 130. The maximum particle size distribution (volume distribution) is taken as the particle size. (· Please first: k1 * · Notes on the back before filling out this page) • Evaluation of the release force of the ingredients contained in the microemulsion printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (blank = 1_90 Newton / meter) 8 % Oil X / 0% Α 1.51 Clear / particle free when diluted 8% Oil X / 1% A 1.11 Cloudiness when diluted 8% Oil X / 20% Hydrophobic Interfacial activity 0.88 Cloudiness / agent at dilution / 3% A 12 micron particles Size 6.7% oil + 1.3% oil Y 0.82 turbidity when diluted / 20% hydrophobic surfactant / 3% A 32 micron particle size 4% oil X + 4% oil Y 0.84 turbidity when diluted / 20% hydrophobic surfactant / 3% A 116 micron particle size 8% oil Y 0.91 Cloudiness when diluted / 20% hydrophobic surfactant / 3 ° / 〇A 153 micron particle size order -12- This paper size applies to Chinese national standards (CNS > A4 Specifications (210X297 mm) A3- B7 384330 V. Description of the invention (10) In the table above, Oil X is an adjusted animal oil, Oil Y is an isoparaffin oil, and a hydrophobic surfactant is ethoxylated (3EO). C13-lipase , A is dialkyl (C8-cio) dimethyl ammonium gas. From the results of the above table, we can see that the first microemulsion is too stable Therefore, the oil particles cannot be released. Therefore, it remains clear when diluted and produces a high release force. The third, fourth, fifth, and sixth microemulsions differ only in the composition of the oily components. It can be seen that the lowest release force measured is The fourth microemulsion, which provides a particle size of 3 2 microns. Please · M- Read-back it. Note
I 旁 訂 ό 經濟部中央橾準局貝工消费合作社印製 -13- 本纸張又度適用中國國家標準（CNS ) Α4規格（210x297公釐）Next to I. Printed by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs -13- This paper is again applicable to the Chinese National Standard (CNS) Α4 specification (210x297 mm)