B7 五、發明説明（1 ) 本發明是一種陰極射線管之螢光幕製法及其結構，尤 指一種利用微細礙粉(Carbon Powder)與其他粗粉粒去構成 螢光幕的色激光隔離。 5 ο 昔知的陰極射線管登幕構造如圖1所示，具有—破璃 (1) ’内面並間差塗佈厚度小於1 um ,直徑在〇 2〜〇 4um間 的微碳粉黑化基底(2)，以隔離設置在各黑化基底(2)間的螢 光區(4)，每一螢光區(4)内有多數排列整齊的螢光點(3)，以 傳導紅、藍、綠等三種或三種以上的色光，上方並延伸一 可覆蓋螢光區(4)與黑化基底(2)的金屬膜(5)，譬如是鋁膜， 以使陰極激射的電子光束(6)進入螢光區(4)時擁有良好的襯 底，避免反射的散逸。 構成上述黑化基底(2)的微碳粉事實上並不能在玻璃（υ 上堆出足夠的厚度，以隔離螢光區(4)。其原因在於螢光幕 進行洪烤時’會讓碳粉的表層碎裂或硬化脱落。以致於由 5 n 陰極激發的電子束在穿過金屬膜(5)後到達螢光區(4)前，會 因隔離不良而形成相鄰螢光區(4)之間的不同色激光電子束 交越混光，造成色彩的失眞及投射亮度的改變，使螢光幕 的發光品質下降。 經濟$央橾準局貝工消費合作社印裝 本發明即在解決上述問題，其目的爲： 一、提供一種不產生相鄰螢光區之色干擾及投射干擾 的陰極射線管螢光幕製法及其結構。 一、 &供一種可以完全隔離相鄰螢光區的隔離區製 法。 二、 提供一種供堆疊隔離區的物質。 _____ -2- 本紙張尺度相巾賴家縣（CNS)A4il#(2I〇x297y^ ) - 5 ο 5 11 經濟央樣準局員工消費合作杜印裝 五、發明説明（2 A7 B7 上述目的的達成，係在供形成螢光幕的玻璃上，以間 差方式塗佈夠高的聚乙烯醇(PVA)，並使各聚乙烯醇間及兩 側，形成一更高的微碳粉和袓粉粒混合物隔離區，藉由硝 酸(HNO3)分解該間差佈設之聚乙烯醇並用水沖去；塗佈螢 光體（Phosphor)及聚乙烯醇的混合物在已消去之聚乙烯醇 區域，曝光去掉混合物中的聚乙烯醇並留下螢光體所形成 的多數色螢光點螢光區，用水清洗未曝光區域並在螢光區 上方塗佈平坦漆使之與隔離區的頂緣齊平，鍍上金屬膜使 成爲陰極射線管的良好襯底，以高溫烘烤該襯底所涵蓋的 區域’俾形成隔離良好的螢光幕。 本案的進一步説明，係配合圖2〜圖9進行。 (圖式簡單説明） 圖1係昔知螢光幕構造的側面剖視圖。 圖2〜圖8係本案陰極射線管之螢光幕製法進行步驟側 面剖視圖，其中： 圖2是本案在玻璃内面，間差佈設多數陣列的聚乙 醇。 /碲 圖3係在各聚乙稀醇之間塗佈以形成隔離區。 圖4係消去各陣列的聚乙烯醇。 圖5係在消去聚乙烯醇的區域佈設螢光體與聚乙烯醇 混合物。 圖6係實施光罩處理，使螢光體與聚乙烯醇設置區只 留下多數螢光體所構成的螢光點及螢光區。 圖7係在各螢光區上方塗佈與隔離區頂緣齊平的平蛔 (請先閲讀背面之注意事項再填寫本頁} -3- 本紙張尺度_ t國國家標準（CNS ) Α4· (2“297公& 5 ο 11 5 '=* 經濟央樣準局員工消费合作社印製 五 A7 B7 漆。 圖8係在平坦漆上方形成金屬膜 圖9係圖3中A-A的放大示意圖 (圖中元件代號） 1—玻璃 4-_螢光區 7—聚乙稀醇 10--隔離區 2—黑化基底 5 —金屬膜 8—螢光體 11--微碳粉 3--螢光點 6—電子束 9--平坦漆 12--粗粉粒 括 如圖@ 8 p/fv ’本發明陰軸線管之螢光幕製法包 a.選取可供製成勞光幕的玻璃⑴譬如是平板或陰極射 線管使其置於工作區上； b_依測算結果在玻璃（1)的内面間差塗佈聚乙埽醇(7)， 如圖2所不，&瘦约在1〇um，並使該間差塗佈的聚乙烯醇 (7)間及兩側可供塗佈； c. 塗佈直徑〇·2〜〇.4um的微碳粉（n)及直徑4 〜5um的組 粉粒（12)譬如是三氧化二鋁(Ai2〇3)、氧化鈦(Ti〇2)之混合物 在上述聚乙烯醇(7)間及其兩側，使形成如第3圖所示之隔 離區（10)’該混合物形態如第9圖局部所示，其高度在l〇um 左右； d. 硝酸(HN〇3)分解前述間差塗佈的聚乙缔醇(7)，如圖4 所不， e.水沖上述硝酸分解後的聚乙烯醇(7)，參見圖4 ; f·如圖5所示，塗佈螢光體(8)以及聚乙烯醇之混合物在 4- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） m HI l·—— In ι· I nn I ^11 m fn w-6 (讀先閱讀背面之注意事項再填寫本頁) 5B7 V. Description of the invention (1) The present invention is a method for manufacturing a fluorescent screen of a cathode ray tube and its structure, especially a color laser isolation using a fine carbon powder and other coarse powder particles to form a fluorescent screen. 5 ο The structure of the known cathode ray tube curtain is shown in Figure 1. It has-broken glass (1) 'inner surface and the difference between the coating thickness is less than 1 um, and the diameter of the micro-carbon powder between 〇2 ~ 〇4um is blackened. The substrate (2) to isolate the fluorescent areas (4) arranged between the blackened substrates (2), and each fluorescent area (4) has a plurality of aligned fluorescent spots (3) in order to conduct red, Three or more colored lights such as blue and green, and a metal film (5), such as an aluminum film, covering the fluorescent area (4) and the blackened substrate (2) is extended above and above, so that the electron beam excited by the cathode (6) Have a good substrate when entering the fluorescent area (4), to avoid the dissipation of reflection. The micro-carbon powder constituting the above-mentioned blackened substrate (2) cannot actually pile up a sufficient thickness on the glass (υ) to isolate the fluorescent area (4). The reason is that when the fluorescent screen is flooded, it will cause carbon The surface of the powder is chipped or hardened and peeled off, so that the electron beam excited by the 5 n cathode passes through the metal film (5) and reaches the fluorescent area (4) before forming an adjacent fluorescent area (4) due to poor isolation. The different colors of the laser electron beams between different colors cross the mixed light, causing the loss of color and the change in the projection brightness, which reduces the luminous quality of the screen. Economy The purpose of solving the above problems is as follows: 1. To provide a method and a structure for manufacturing a cathode ray tube screen that does not generate color interference and projection interference of adjacent fluorescent regions. 1. To provide a method that can completely isolate adjacent fluorescent light. The method of manufacturing the isolation zone of the district. 2. Provide a substance for stacking the isolation zone. _____ -2- This paper size photo paper Laijia County (CNS) A4il # (2I〇x297y ^)-5 ο 5 11 Economic Central Bureau Employee Consumption Cooperation Du Yinzhuang V. Invention Description (2 A7 B7 It is tied on the glass for forming the screen, and it is coated with high enough polyvinyl alcohol (PVA) in a stepwise manner, and each polyvinyl alcohol and the two sides form a higher micro-carbon powder and powder. The granular mixture isolation area is decomposed by nitric acid (HNO3) and the polyvinyl alcohol disposed by the gap is washed away with water; the mixture of phosphor and polyvinyl alcohol is coated on the area of the eliminated polyvinyl alcohol, and removed by exposure The polyvinyl alcohol in the mixture leaves the majority of the fluorescent dots formed by the phosphor. Wash the unexposed area with water and apply a flat paint over the fluorescent area to make it flush with the top edge of the isolation area. The metal film is coated to make a good substrate for a cathode ray tube, and the area covered by the substrate is baked at a high temperature to form a well-isolated fluorescent screen. Further explanation of this case is performed in conjunction with FIGS. 2 to 9. Brief description of the figure) Figure 1 is a side cross-sectional view of a known fluorescent screen structure. Figure 2 to Figure 8 are side cross-sectional views of the steps of the method for manufacturing a cathode ray tube in the present case. Polyethanol for most arrays / Tellurium 3 is coated between each polyvinyl alcohol to form an isolation zone. Figure 4 is the elimination of polyvinyl alcohol of each array. Figure 5 is the mixture of phosphor and polyvinyl alcohol in the area where polyvinyl alcohol is removed. Figure 6 The masking process is implemented so that the phosphor and polyvinyl alcohol installation area only leaves the fluorescent dots and fluorescent areas composed of most phosphors. Figure 7 is the top edge of the coating and isolation area above each fluorescent area. Qi Ping's flat 蛔 (Please read the notes on the back before filling in this page} -3- This paper size_ National Standard of China (CNS) Α4 · (2 "297 公 & 5 ο 11 5 '= * Economic Central Sample A5 B7 lacquer was printed by the Consumer Cooperative of the Bureau of Standards. Figure 8 is a metal film formed on a flat paint. Figure 9 is an enlarged schematic diagram of AA in Figure 3 (component code in the figure). 1—Glass 4-_Fluorescent area 7— Polyvinyl alcohol 10--Isolated area 2--Blackened substrate 5--Metal film 8--Fluorescent body 11--Micro carbon powder 3--Fluorescent dot 6--Electron beam 9--Flat paint 12--Coarse powder particles Including Figure @ 8 p / fv 'The manufacturing method of the fluorescent screen of the negative axis tube of the present invention a. Select the glass which can be made into a labor light curtain, such as a flat plate or a cathode ray tube to put it into work B_ According to the calculation results, the difference between the inner surface of glass (1) and the application of polyethylene glycol (7), as shown in Figure 2, & thin about 10um, and make the difference coated poly Vinyl alcohol (7) can be applied between and on both sides; c. Coating micro-carbon powder (n) with a diameter of 0.2 to 0.4um and group powder particles (12) with a diameter of 4 to 5um, such as dioxide The mixture of aluminum (Ai203) and titanium oxide (Ti〇2) is between the above-mentioned polyvinyl alcohol (7) and on both sides thereof, so that an isolation zone (10) as shown in FIG. 3 is formed. Partially shown in Fig. 9, its height is about 10um; d. Nitric acid (HN03) decomposes the aforementioned difference-coated polyvinyl alcohol (7), as shown in Fig. 4. After the polyvinyl alcohol (7), see Figure 4; f · As shown in Figure 5, the mixture of coated phosphor (8) and polyvinyl alcohol is in accordance with the Chinese National Standard (CNS) A4 specification at 4-paper size (210X297mm) m HI l · —— In ι · I nn I ^ 11 m fn w-6 (Read the precautions on the back before filling this page) 5
5 IX 經濟央標準局貝工消費合作社印製 A7 ---—-B7 五、發明説明（4 ) ' ~~ 上述消去聚乙稀醇(7)的區域中，該被塗佈的營光體⑻包括 可用以發紅光的稀土類螢光體，和可用以發藍光的硫化 鋅，及可用以發綠光的硫化辞； g.曝光，譬如是光罩上述螢光體（8)及聚乙烯醇混合 物，以消去聚乙烯醇並形成多數螢光點聚隼之螢光區(4); h·水沖未曝光區，得如圖6所示； 1.塗佈平坦漆(9)在上述螢光區（4)上方並使之與上 步 驟C所形成的隔離區（1〇)頂緣齊平，如圖7所示； j. 鍍上金屬膜(5)譬如是〇 Nojum的鋁膜在上述平坦 漆(9)與隔離區⑽的上方(供形成覆蓋），如圖8所示，俾構 成陰極射線管之良好反射性金屬襯底(111扣31 back)，其並連 接於陰極射線管的陽極，使陰極所激發的電子束（6)在投射 至螢光區(4)時不會反射散逸； k. 高溫譬如是400 eC〜500烘烤上述金屬膜所含括 的區域，使平坦漆(9)及聚乙烯醇(PVA)燃燒掉。 上述方法製得的陰極射線管螢光幕，基本構造包括— 玻璃（1) ’主要供形成螢光幕；數螢光區(4)，間差分佈在上 述玻璃（1)内面，各螢光區(4)並形成三種以上的色勞光點(3) 傳導排列；數隔離區（10)，包圍並完全隔絶上述之數勞光區 (4); 一平坦漆(9)層，封閉上述數螢光區(4)使之與上述隔離 區（10)齊平，以及一金屬膜(5)’徒覆在上述隔離區（10)與上 述平坦漆(9)之上，供形成良好的陰極射線管投射觀底，'並 連接至陰極射線管的陽極，避免陰極發射之電子束(4)在投 射至螢光區(4)時產生反射。 -5- 本紙伕尺度適用中國國家標(（CNS (2丨οχ297公釐） ^ ~~~--- I- n In · — 1 nn In In . nn n I 、lOJI In In /ϊ^ (請先閲讀背面之注意事項再填寫本頁} A7 B7 五、發明説明（5 ) 由於上述隔離區與螢光區等高，所以可在陰極電子束 投射的斜方向造成擴散時的遮蔽，防止相鄰的螢光區被不 同色激光的侵入而混合失眞，並防止亮度的突增或突減， 使色彩投射更準確、亮度控制更精準，因此具有產業利用 價値而提出如后的申請專利範圍，該專利範圍的請求，非 用以限制本案將來在法律上的權利主張，特此聲明。 (請先閲讀背面之注意事項再填寫本頁) 訂 經濟部中央標準局員工消費合作社印製 -6- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）5 IX A7 printed by the Shellfish Consumer Cooperative of the Central Bureau of Economic Standards ------ B7 V. Description of the invention (4) '~~ In the above area where the polyvinyl alcohol (7) is eliminated, the coated camper body ⑻ includes rare-earth phosphors that can emit red light, zinc sulfide that can emit blue light, and sulfur sulfide that can emit green light; g. Exposure, such as a mask for the above-mentioned phosphor (8) and polymer Vinyl alcohol mixture to eliminate the polyvinyl alcohol and form the fluorescent area of most fluorescent dots (4); h. Water unexposed area, as shown in Figure 6; 1. Apply a flat paint (9) on Above the fluorescent region (4) and flush with the top edge of the isolation region (10) formed in the step C, as shown in FIG. 7; j. Coated with a metal film (5), such as 0Nojum aluminum The film is above the flat paint (9) and the isolation region ⑽ (for forming a cover). As shown in FIG. 8, 8 constitutes a good reflective metal substrate (111 buckle 31 back) of the cathode ray tube, and is connected to the cathode The anode of the ray tube, so that the electron beam (6) excited by the cathode will not reflect and dissipate when projected onto the fluorescent area (4); k. High temperature, such as 400 eC ~ 500 Area, the flat paint (9) and polyvinyl alcohol (PVA) are burned off. The basic structure of the cathode-ray tube fluorescent screen prepared by the above method includes:-glass (1) 'is mainly used to form a fluorescent screen; a number of fluorescent regions (4) are arranged on the inner surface of the glass (1), and each fluorescent Area (4) and forming three or more colored light spots (3) conductive arrangement; a number of isolation areas (10), surrounding and completely isolating the above-mentioned several light areas (4); a flat lacquer (9) layer, closing the above Count the fluorescent area (4) so that it is flush with the above-mentioned isolation area (10), and a metal film (5) 'is overlaid on the above-mentioned isolation area (10) and the above-mentioned flat paint (9) for forming a good The cathode ray tube projects the bottom view, and is connected to the anode of the cathode ray tube to avoid reflection of the electron beam (4) emitted by the cathode when projected onto the fluorescent area (4). -5- The standard of this paper is Chinese national standard ((CNS (2 丨 οχ297mm) ^ ~~~ --- I- n In · — 1 nn In In. Nn n I, lOJI In In / ϊ ^ (Please Read the precautions on the back before filling in this page} A7 B7 V. Description of the invention (5) Since the above-mentioned isolation zone is equal to the fluorescent zone, it can be shielded during diffusion in the oblique direction of the cathode electron beam projection to prevent adjacent The fluorescent area is mixed and lost by the invasion of different colored lasers, and prevents the sudden increase or decrease of brightness, so that the color projection is more accurate and the brightness control is more precise. Therefore, it has the scope of patent application as mentioned below. This patent claim is not intended to limit the future legal claims in this case. (Please read the precautions on the back before filling out this page.) Ordered by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Paper size applies to China National Standard (CNS) A4 (210X297 mm)