經濟部中央標準局員工消費合作社印裝 A7 B7__五、發明説明（） 發明領域 本發明係關於一種浮水印花布之製造方法，更特別的 是，本發明係關於一種遇水會顯現圖案之印花布之製造方 法。 發明背景 求新求變是任何產品在市場上維持不墜的原則，日常 用品，休間用品及衣物更是如此。本發明方法所生產的浮 水印花布在乾燥及濕潤情況能夠圼現不同之圖案，搭配顔 料印花之圖案可造成與眾不同、標新立異之優越感，亦能 顯示布料目前是處於乾燥狀態或濕潤狀態，不僅有利於使 用者分辨其狀態*此特色亦便於判定是否需要烘乾之進一 步處理。 本發明的目的是提供一種浮水印花布之製造方法。 本發明的又一目的是提供一種遇水即顯現浮水印之印 花布的製造方法。 本發明又一目的是提供一種防水加工方法，使布料防 水、保暖。 發明概要 本發明浮氺印花布之製造方法之作業流程主要為浮水 印花湖製作、顔料印花製作、網版製作、機印、定型、水 洗和最終得到成品。視需要，也可以在浮水印花糊製作、 顔料印花製作、網版製作之前進行防水處理，防水處理包 括面底層塗布膠液製作、防水上膠、面層塗布膠液製作、 -4- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） ----------ir— (請先閲讀背面之注意事項再填寫本頁)Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7__V. Description of the Invention (Field of the Invention) The present invention relates to a method for manufacturing a floating printing cloth. More specifically, the present invention relates to a printing that displays a pattern when it encounters water. Manufacturing method of cloth. Background of the Invention The need for innovation and change is the principle of keeping any product on the market, especially daily necessities, rest products and clothing. The floating printing cloth produced by the method of the present invention can show different patterns in dry and wet conditions, and the pattern printed with pigment can cause a distinctive and unique superiority, and can also show that the cloth is currently in a dry or wet state. Not only is it helpful for users to distinguish their status * This feature also makes it easy to determine whether further processing is required for drying. An object of the present invention is to provide a method for manufacturing a floating printing cloth. Yet another object of the present invention is to provide a method for manufacturing a printed fabric that exhibits a watermark when exposed to water. Yet another object of the present invention is to provide a waterproof processing method to make the cloth waterproof and warm. Summary of the Invention The working process of the manufacturing method of floating print fabric of the present invention is mainly the production of floating water, printing lake production, pigment printing production, screen printing, machine printing, shaping, washing and finally obtaining finished products. If necessary, you can also perform water-repellent treatment before the production of floating printing paste, pigment printing, and screen printing. The water-repellent treatment includes the coating of the top and bottom coatings, the waterproof gluing, and the coating of the top coatings. Applicable to China National Standard (CNS) A4 specification (210X 297 mm) ---------- ir— (Please read the notes on the back before filling this page)
'IT 五、發明説明（ 防水上膠、定型等 ㈠製糊配方 A .顔料糊 a.原料糊 .白色顔料糊： A7 B7 4Π 固著劑 UCRAMIN PUD) 0. 1%六偏磷酸鈉 1 . 17¾¾乳化劑（emulsifier VA) 1.5¾乳化劑（emulsifier WV) 8%二乙二醇 5%架橋劑 UCRAFIX MF) 5 %苗一油 3 7 . 3 3 ¾水 1 . 9%合成糊料 UCRACONZ BN)'IT V. Description of the invention (waterproof gluing, styling, etc. paste formulation A. Pigment paste a. Raw material paste. White pigment paste: A7 B7 4Π Fixing agent UCRAMIN PUD) 0.1% sodium hexametaphosphate 1. 17¾¾ Emulsifier VA 1.5 ¾ Emulsifier WV 8% diethylene glycol 5% bridging agent UCRAFIX MF) 5% Miaoyi oil 3 7. 3 3 ¾ water 1. 9% synthetic paste URACONZ BN)
.原料糊 .白色顏料（Pigment DRN 4 0¾ 60¾ ---------ί裝-- (請先閱讀背面之注意事項再填寫本頁) ,1Τ ^• B .浮水印花糊： 經濟部中央梯準局負工消費合作社印製 .原料糊：5%乳化劑、45%水Μ及50¾苗—油。 .揮印糊：9 5 %上述原料糊與5 %撥水劑（F c _ 2 ? 〇 ) 製糊作業： 製糊作業分製備原料糊以及浮水印花湖兩大步驟 中製備原料糊又分為： -5 - 其 本紙張尺度適用中國國家標準（CNS ) A4規格（210><297公釐〉 經濟部中央棣準局員工消費合作社印製 A7 B7五、發明説明（） (a )顔料糊之製備：將上述六偏磷酸納、乳化劑 (emulsifier VA)、乳化劑（emuisifier WV)、二乙二酵 、架橋劑、水K及合成糊料攪拌均勻之後，慢慢將苗一油 加入，此時之攪拌機K 1 5 Q 0至2 Q 0 0 r ρ «I攪拌，待乳化完全後 再加入固著劑，再予K攪拌均勻即可； (b)白色顔料糊之製備：取40¾原料糊，加人60%白顔料 (white DRN)，搜拌均勻； 浮水印花糊之製備包括製備原料糊及機印糊，其中原 料糊之製備為，先將固著劑和六偏磷酸納攪拌均勻之後* 再慢慢將乳化劑（emulsifier VA)加入，待乳化完成即可； 機印糊之製備係取95%上述原料糊加入5%撥水劑（FC- 2 7 0 )， 予K均勻攪拌即可。 ㈡製版 ⑴浮水印花糊所用的網版網目為1 8 G 0 m e s h ;顔料糊所 用的網版網目為1 (3 Q 〇 m e s h。 ⑵使用機台為平版印花機或圓版印花機。 ㈢機印 若為平版印花，其作業條件為：速度為13公尺/分鐘’ 乾燥箱溫度為1 3 Q°C，刮刀長度為 2 · 8公分，版序K浮水 印為前版，顔料為後版。 若為圓版印花，其作業條件為：速度為4 5公尺/分鐘’ 乾燥箱溫度為 130 °C*刮刀與布料之角度為+5° ’版序 -6 - II-------"ί 裝-- (讀先閱讀背面之注意事項再填寫本頁) 訂 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ 297公釐） 經濟部中央榡準局員工消費合作社印製 A7 B7_五、發明説明（） κ浮水印為前版，顔料為後版。 ㈣定型 經過上述程序處理的浮水印花布進行18〇υ X60公尺/分 鐘的不過水定型處理（超餵料為+ 3 % )，該糊配方中的化學試 劑與布纖維產生架橋反應。 ㈤水洗 Μ 8 Ο Ό X 3 (]公尺/分鐘的速率進行水洗，不添加任何試 劑，圓茼乾燥室溫為1201,以完全除去未反應的試劑。 Κ下簡述本發明製造方法所採用之原料： 固著劑（ACRAMIN PDD)為脂肪糸聚酯聚氨基甲酸酯之陰 離子分敗液，適用於低笛一油含量或不含苗一油之情況， 對於伸縮性織物有較佳之伸張度，對於顔料印花是相當合 適的。 乳化分散劑（Emulsifier VA)為聚乙二酵之非離子衍生 物，能促進顔料印花之均勻，降低搓揉之敏感度及増加糊 之摻透力，K及改善糊之流動性，此試劑對電解質、酸、 鹼有較佳的抵抗性。 乳化分散劑（Emulsifier WV)為芳基聚乙二醚之非離 子產物，對顔料印花會增加其糊的流動性，且清洗網版時 易去除，此外，對酸、鹼鹽或硬水亦具抵抗性。 二乙二醇可增加印花糊之滑溜性，減少塞版及提升糊 膜之柔軟度。 架橋劑（A C R A F I X M F )為醚化的三聚氰胺樹脂之無色液 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（2丨0X297公釐） 經濟部中央樣準局員工消費合作社印製 A7 B7__五'發明説明（） 體，其具有多官能基之架橋效果，可改菩濕摩擦及水洗牢 度且具有較佳之流動性。 苗一油（white spirit)為中油苗栗廠生產一號油，多 用於油水乳化之溶劑中。 合成棚料（ACRACONQ BN)為丙烯糸銨鹽之共聚物，具備 優良的抗電解及硬水性，且對印面之色值及艶度，均勻性 ，均有較佳之表現，色糊有較佳之操作性及易洗性，且印 面尖銳性佳。 六偏磷酸納為水質處理劑，可確保用水之品質。 乳化劑（Ρ Ε Ν Ε ϋ )為破壞水、油間之界面張力，可幫助 笛油和水之相互溶解。 撥水劑（FC-270)屬氟素糸陽離子性撥水劑，能提供布 面之撥水撥油效果。 產物遇水出現圖案之原理分為兩種，分述如后： 1.使用撥水劑固著於圖案上之纖維内部，使其具有良 好之撥水效果，當纖維吸水時，此部份不吸水，雄持乾燥 狀態，而其它未經處理之部份則按一般狀況吸水*而圼現 濕潤狀態*故圖案可完整顯現。 2 .圖案内之纖維未經處理，其它部位使用撥水劑固著 於纖維之內部，使其具有良好之撥水效果，當布面之纖維 吸水時 > 除圖案之纖維吸水外•其它因處理具有撥水效果 不吸水而雄持乾烽狀態，而圖案可完整顯現。 ㈥防水處理 -8 - m —1 - - -1— u ml I A^·/ i - (請先閲讀背面之注意事項再填寫本頁) 訂 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） 經濟部中央樣準局員工消費合作社印裝 A7 B7五、發明説明（） 使用機台為上膠塗布機及二連式上膠塗布機。 Μ下簡述防水處理採用的藥劑： 二液型P U樹脂（ϋ U - 2 (Π 5 ):防水塗布加工主劑，具良好 伸長率，抗張力及柔軟度。 一液型Ρ ϋ樹脂（D U - 1 7 5 0 ):防水塗布加工主劑，具良好 伸長率，抗張力及柔軟度。 架橋劑（D C - 7 5 ):接著劑之架橋劑，增加耐熱性，耐化 性*接著性。 硬化促進劑（D A- 9 G Κ ):快速促進硬化型，適用於接著 劑之硬化促進。 手感調整劑（CRISVON ADDITIVE No.5):適用面層之添 加物，可增加滑性防黏，增加反撥性。 丁酮（Μ E K ):稀釋用溶劑。 製備配方： ⑴底層塗布膠疲 ---------ί裝-- (請先閲讀背面之注意事項再填寫本頁) 訂 二液型 PD膠液（DU-2G15) 12.2% 架橋劑（β C - 7 5 ) 3 Λ% 硬化促進劑（D A - 9 G fl) 3.2% 溶劑（Μ E K)t 21.4% 0面層塗布膠液 一疲型 PU膠液（DU-1751]) 70¾ 手感調整劑（CRISVON ADDITIVE Νο·5) 1.5% 溶劑（Μ Ε Κ) 28.5¾ 本紙張尺度適用中國國家標準（CNS ) Α4規格（210 X 297公釐） 經濟部中央標準局員工消费合作社印裝 A7 B7__五、發明説明（） 塑膠作業 ⑴底層塗布膠液之製備 P U膠液（D ϋ - 2 Q 1 5 ) ’溶劑混合攪拌均勻後，慢慢放人架 橋劑（DC-75)，此時攪拌機以1500至2G0QRPM攪拌10分鐘後 ，再慢慢放入硬化促進劑（DA-9QH)，再予Μ攪拌均勻即可 Ο ⑵面層塗布膠液之製備 Ρ ϋ膠液（D U - 1 7 5 Q )，溶劑混合攪拌均勻後*再放入手感 調整劑（CRISVON ADDITIVE No· 5)，此時攪拌機W 1500至 2 0 0 G R P Μ搜拌均勻即可。 上膠塗布 ⑴底層塗布：其作業條件：速度為30公尺/分鐘，溫度為 160 V ° ⑵面層塗布：其作業條件：速度為30公尺/分鐘，溫度為 16 0。。 雖然本發明係Κ其較佳實施例Κ及圖示加Κ說明，應 理解的是實施例僅僅為示範目的，並非用Κ限制本發明。 凡根據前述實施例所作可簡易思及之改變，均屬本發明之 專利範圍，本發明之專利特激將由申請專利範圍界定之。 n , n K- It fn HI I 1.. 1^1 I (請先閲讀背面之注意事項再填寫本頁) 訂 -10- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）Raw Material Paste. White Pigment (Pigment DRN 4 0¾ 60¾ --------- ί Pack-(Please read the precautions on the back before filling out this page), 1T ^ • B. Floating Printing Paste: Ministry of Economic Affairs Printed by the Central Working Group of Consumers' Cooperatives. Raw material paste: 5% emulsifier, 45% water M and 50¾ seedling-oil.. Printing paste: 95% of the above raw material paste and 5% water repellent (F c _ 2? 〇) Paste operations: Paste operations are divided into two steps: preparing raw material paste and floating water printing lake. The raw material paste is divided into: -5-The paper size is applicable to Chinese National Standard (CNS) A4 specification (210 > < 297 mm> Printed by A7 B7, Consumer Cooperatives of the Central Bureau of Standards and Assistance of the Ministry of Economic Affairs 5. Description of the invention () (a) Preparation of pigment paste: Sodium hexametaphosphate, emulsifier VA, emuisifier WV), dioxin, bridging agent, water K and synthetic paste are mixed well, then slowly add Miaoyi oil. At this time, the mixer K 1 5 Q 0 to 2 Q 0 0 r ρ «I stir, wait After the emulsification is complete, add the fixing agent, and then stir evenly with K; (b) Preparation of white pigment paste: take 40¾ raw material paste, add 60% white (White DRN), search and mix well; the preparation of floating printing paste includes the preparation of raw material paste and machine printing paste, in which the preparation of raw material paste is made by first mixing the fixing agent and sodium hexametaphosphate uniformly, and then slowly emulsifying Add the emulsifier VA and wait until the emulsification is completed. For the preparation of machine-printed paste, take 95% of the above raw material paste and add 5% water repellent (FC-2 7 0), and stir evenly with K. The screen mesh used for printing paste is 18 G 0 mesh; the screen mesh used for pigment paste is 1 (3 Q 0 mesh). ⑵ The machine used is a lithographic printing machine or a rotary printing machine. 若 If the machine printing is a lithographic printing , Its operating conditions are: the speed is 13 meters / minute 'drying box temperature is 1 3 Q ° C, the blade length is 2 · 8 cm, the plate order K watermark is the front version, the pigment is the rear version. If it is a round version For printing, the operating conditions are: the speed is 4 5 meters / minute ', the temperature of the drying box is 130 ° C * the angle between the scraper and the cloth is +5 °' version order -6-II ------- " ί Loading-(Read the precautions on the back before filling in this page) The size of the paper used in this edition applies to the Chinese National Standard (CNS) Α4 (210 × 297 mm) A7 B7 printed by the Consumer Cooperatives of the Central Government Bureau of the Ministry of Economic Affairs_V. Description of the invention () The κ watermark is the front version and the pigment is the rear version. 18〇υ X60 meters / minute without water setting treatment (+ 3% for super-feed), the chemical reagent in the paste formula has a bridging reaction with the cloth fiber. ㈤Washing Μ 8 〇 Ό X 3 (] m / min. Water washing was performed without adding any reagents. The drying temperature was 1201 at room temperature to completely remove unreacted reagents. The following is a brief description of the method used in the manufacturing method of the present invention. Raw materials: The fixing agent (ACRAMIN PDD) is an anionic liquid of fatty polyester polyester polyurethane. It is suitable for low flute oil content or no seedling oil content. It has better stretch for stretchable fabrics. It is quite suitable for pigment printing. Emulsifier VA is a non-ionic derivative of polyethylene glycol, which can promote the uniformity of pigment printing, reduce the sensitivity of kneading and the penetration power of kneading, K And improve the fluidity of the paste, this reagent has better resistance to electrolytes, acids, and alkalis. Emulsifier WV is a non-ionic product of aryl polyethylene glycol, which will increase the paste's flow when printing on pigments. It is easy to remove when cleaning the screen, and it is also resistant to acids, alkali salts or hard water. Diethylene glycol can increase the slipperiness of the printing paste, reduce plugging and improve the softness of the paste film. ACRAFIXMF ) Is a colorless liquid of etherified melamine resin (please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 specification (2 丨 0X297 mm) Employees of the Central Bureau of Prospecting and Quarantine of the Ministry of Economic Affairs Cooperative prints A7 B7__ five 'invention description () body, which has a multi-functional bridging effect, can change the wet friction and washing fastness and has better fluidity. Miao Yiyou (white spirit) is the Zhongyou Miaoli Factory Produces No. 1 oil, mostly used in oil-water emulsified solvents. Synthetic shed (ACRACONQ BN) is a copolymer of propylene ammonium salt, which has excellent resistance to electrolysis and hard water, and has a good color value, uniformity, and uniformity on the printed surface. Both have better performance, the color paste has better operability and washability, and the printed surface is sharp. Sodium hexametaphosphate is a water treatment agent, which can ensure the quality of water. Emulsifier (ΡΕΝΝΕΕ) is It destroys the interfacial tension between water and oil, which can help the oil and water dissolve each other. Water-repellent agent (FC-270) is a fluorine 糸 cationic water-repellent agent, which can provide water-repellent oil-repellent effect on the surface of the cloth. Water Appearance The principle is divided into two types, which are described as follows: 1. Use a water-repellent agent to fix the inside of the fiber on the pattern to make it have a good water-repellent effect. When the fiber absorbs water, this part does not absorb water and stays dry. , While the other untreated parts absorb water according to the general situation * and show a wet state *, so the pattern can be completely displayed. 2. The fibers in the pattern are untreated, and other parts are fixed to the inside of the fiber with a water-repellent agent. Make it have good water-repellent effect, when the fiber on the cloth absorbs water> Except the fiber of the pattern absorbs water • Others hold the dry state because the treatment has water-repellent effect and do not absorb water, and the pattern can be completely displayed. ㈥ Waterproof treatment -8-m —1---1— u ml IA ^ · / i-(Please read the precautions on the back before filling in this page) The size of the paper is applicable to China National Standard (CNS) A4 (210 X 297) (%) Printing of A7 B7 by the Consumer Cooperatives of the Central Procurement Bureau of the Ministry of Economic Affairs 5. Description of the invention () The machine is a gluing coater and a two-line gluing coater. The following is a brief description of the chemicals used in waterproof treatment: Two-component PU resin (ϋ U-2 (Π 5): the main agent for waterproof coating processing, with good elongation, tensile strength and softness. One-component P ϋ resin (DU- 1 7 5 0): Main agent for waterproof coating processing, with good elongation, tension resistance and softness. Cross-linking agent (DC-7 5): Cross-linking agent for adhesive, increase heat resistance, chemical resistance * adhesion. Hardening promotion Agent (D A- 9 G KK): fast curing hardening type, suitable for hardening promotion of adhesives. CRISVON ADDITIVE No. 5: Additive for surface layer, can increase slip resistance, increase anti-sticking Methyl ethyl ketone (M EK): solvent for dilution. Preparation formula: ⑴ bottom coating rubber fatigue --------- ί-(Please read the precautions on the back before filling this page) Order two liquids Type PD glue (DU-2G15) 12.2% bridging agent (β C-7 5) 3 Λ% hardening accelerator (DA-9 G fl) 3.2% solvent (M EK) t 21.4% 0 surface coating glue 1 Weak PU glue (DU-1751)) 70¾ Touch modifier (CRISVON ADDITIVE Νο · 5) 1.5% solvent (Μ Ε) 28.5¾ This paper size is applicable to China Standard (CNS) Α4 size (210 X 297 mm) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs A7 B7__V. Description of the invention () Plastic operation: Preparation of the bottom coating glue PU glue (D ϋ-2 Q 1 5) 'After the solvent is mixed and stirred well, put the bridging agent (DC-75) slowly. At this time, the mixer is stirred at 1500 to 2G0QRPM for 10 minutes, and then the hardening accelerator (DA-9QH) is slowly added. Μ can be stirred evenly 〇 ⑵ surface layer coating glue preparation P ϋ glue solution (DU-1 7 5 Q), after the solvent is mixed and stirred evenly * then add the feel adjuster (CRISVON ADDITIVE No · 5), at this time the mixer W 1500 to 2 0 GRP Μ can be searched evenly. Glue coating ⑴ primer coating: its operating conditions: speed of 30 meters / minute, temperature of 160 V ° ⑵ surface coating: its operating conditions: speed of 30 Meters / minute, temperature is 16 0. Although the present invention is described in the preferred embodiment K and the illustration plus K, it should be understood that the embodiment is for exemplary purposes only, and does not limit the present invention with K. According to the foregoing The changes that can be easily considered in the examples belong to the present invention The scope of patents, the patent excitement of the present invention will be defined by the scope of patent application. N, n K- It fn HI I 1 .. 1 ^ 1 I (Please read the precautions on the back before filling this page) Order -10- Paper size applies to China National Standard (CNS) A4 (210X297 mm)