TW379251B - Cleaning and disinfecting compositions with electriolytic disinfecting booster - Google Patents

Description

A7 B7 Five 'Invention Description G) Invention Fan Yuan Fayue is a mild acidic amine oxide cleaner containing a fourth-grade disinfectant. BACKGROUND OF THE INVENTION It is known to use amine oxide surfactants in cleaning compositions. Amine oxides are often used as co-surfactants to assist and maintain foams formed in the 'name' compositions for washing, shampooing and dishwashing. Amine oxides have been used in hard surface cleaners, such as acid bath cleaners or lower p, dishwashers with sorbent softener (pH 4 to 6 9) and selected non-acidic (medium To alkaline) cleaners for hard surfaces. Among non-acid hard surface cleaners, amine oxide cleaner surfactants are essentially nonionic (PKa between about 4 and about). These non-ionic amine oxides provide good cleaning properties and leave little or no visible residue on hard surfaces when dry. U.S. Patent No. 5,435,935, issued to Kupneski on July 25, 1955, discloses the use of quaternary ammonium compounds' in lye hard surface cleaning compositions, which is incorporated herein by reference. Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). Non-acid hard surface cleaners containing amine oxides will stain or fade the surface of ethylene (polyvinyl chloride). The dyed color is a pale yellow to dark brown that fades from vinyl. Dyeing may also occur on waxed vinyl surfaces where the sacrifices are thin or peeled off, so the range where the amine oxide can directly contact ethylene. A mildly acidic hard surface cleaner composition is disclosed in Wierenga's co-trial and co-assigned US Patent Application No. 08 / 412,622 (P & G 4980R), which contains With quaternary ammonium disinfectant-4-This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) Description of the invention (2 Quats and amine oxide interface printed by the Consumer Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs Active agent. However, the composition which is acidic pH itself is incompatible with the quaternary ammonium disinfectant, so that the disinfectant loses its ability to disinfect. Therefore, the object of the present invention is to provide a cleaning composition for hard surfaces.和 ΛΠ · Japanese-style amine oxide cleaner surfactant, with its disinfection and cleaning, without any acetamidine staining or minimizing it. Another object of the invention is to provide a disinfectant that will not be cleaned. This composition leaves visible residues on the surface. Another object of the present invention is to provide a method for cleaning the vinyl surface using this composition. SUMMARY OF THE INVENTION The composition of the present invention provides A better combination of cleaning, disinfection and upper screw and floor polishing than this technical composition. The preferred composition is a mild surface cleaning composition for hard surfaces, which contains: amine oxide cleaner; b) Level 4 disinfectant (quat); c) acidifier; and d) effective amount of electrolyte disinfection promoter. The preferred composition is prepared for use with a p 从 from 3 to less than 7 and an amine oxide cleaner from 40 pm to about 12,500 ρριη and a grade 4 from about 50 ppm to about ^ 00 ppm As the disinfectant, a fourth-level disinfectant with at least 500ρρπ1 is preferred. The present invention also discloses a concentrated hard surface cleaning composition. The concentrated composition is formulated as it is or diluted with water carrier to a ratio of 1: 1 to 1: 600. 5- This paper is from China National Standard (CNS) Α4 size (210 × 297 public director) (please read first Note on the back then fill out this page} 鬅--Μβ

L. Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, Yinzhen A7 --- B7_ ___ V. Description of Invention (3). The preferred ratio is from 丨: 丨 to 丨: 6 〇 by volume or weight, more preferably from 1:20 to 1: 300, and most preferably from 1:30 to 1: 260. When these concentrated compositions are mixed with a predetermined amount of water to provide a ready-to-use composition, the concentrated composition of the present invention contains preferably from about 0.5 to about 40 parts of the amine oxide cleaner, ranging from 1 to 30 Is more preferred, and is best from i to 25 parts; preferably from about t to about 25 parts of a fourth-level disinfectant, more preferably from 1 to 20 parts, and most preferably from 2 to 16 parts; effective amount of An acidulant (having less than about 602 pKa), preferably from 0.05 to 10 parts, more preferably from 0.5 to 5 parts; and an effective amount of an electrolyte disinfection accelerator, having from 0.05 to 12 parts Good, more preferably from 0.2 to 8 parts, and most preferably from 0.2 to 2 parts. The preferred specific gravity of the concentrated liquid of the present invention is from 0.9 to 1.1. The composition includes sufficient acidifying agent to protonate at least about 0% of the amine oxidizing substance, and also provides a diluent composition having about 11 to about 3 to 7, preferably from 4 to 6 cars. These liquid hard surface cleaning and disinfecting compositions have excellent disinfection and cleaning properties. It has wax safety. It can also be a group without flushing. Thing. As the composition dries, it does not leave visible residues on the hard surface. A method for disinfecting and cleaning the surface of acetamidine using the liquid composition is also disclosed. It is also disclosed that TF is a preferred concentrated composition, which can easily obtain a mild acidic diluent composition by adding an aqueous liquid. The invention also provides a non-liquid formulation of a derivatizable liquid composition. Non-liquid formulations are basically liquid compositions that reduce the amount of water carrier liquid (e.g., gels) or no water carrier liquid (e.g., granules) at all. In terms of method, the present invention relates to a method for disinfecting and cleaning an ethylene surface using the liquid composition herein. According to the method of this method, the liquid composition is suitable for B-6. This paper size is suitable for financial standards (CNS) A4 specification (2ι〇 × 297). --- Order ------ (Please read the precautions on the back before filling this page) V. Description of the invention (4 A7 B7 Consumer cooperation of the Central Standards Bureau of the Ministry of Economic Affairs Du printed the surface of the radon and wipe it with a porous material Detailed description of the invention The mild acidic dilution and concentration liquid composition of the present invention comprises: "amine oxide cleaner surfactant" 2) acidifying agent "3) fourth grade disinfectant, 4) Electrolyte disinfection promotes 5) water carrier liquid. Diluted or undiluted liquid composition can be used to clean hard surfaces. Diluted is better because it does not require rinsing. If a concentrated composition is used on a hard surface, rinsing is Necessary. In order to disinfect hard surfaces, the product must provide at least 500 to 600 ppm of quaternary ammonium disinfectant. In order to achieve safe sanitary measures, the product must provide at least 50 ppm of quaternary ammonium disinfectant to A reduction of 100 ppm is preferred. A preferred concentration of the invention The composition comprises: about 1 to 25 parts of an amine oxide surfactant; about 2 to 16 parts of a quaternary ammonium gasification; about 1-3 parts of EDTA is selected as needed; about 0.2 to 2 parts of phosphoric acid; About 02 to 2 parts of potassium vaporization and the remainder is water. The pH is preferably adjusted from 3 to 6 with HC 1 or phosphoric acid or a mixture thereof. The liquid composition of the present invention can be used as a floor, wall or toilet. Non-rinsing type hard surface cleaners. It has been found that non-acid liquid mother compounds and cleaning compositions containing amine oxides can contaminate the surface of acetamidine. However, the liquid composition of the present invention is extremely low or free of any ethylene contamination. In addition, the liquid composition has excellent disinfection and cleaning characteristics, and when dried, it will leave little or no visible residue. The ppm described herein is the weight of the liquid composition ready for use. Weight ppm and volume ppm are about the same, because the concentrated composition of the present invention has a specific gravity of about 1. Some of the concentrated composition has a slightly changed specific gravity, but (please read the precautions on the back before filling this page).

* 1T " This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) > Printed by A7, Consumer Cooperation of Employees, Central Standards Bureau, Ministry of Economic Affairs ------------- B7____ 5. The description of the invention (5) still belongs to the scope of the present invention under the present disclosure. The weight of the concentrate is based on the weight, but when the liquid detergent is provided directly after dilution, the PP m by weight can be used to reflect the dilution Degree. "Electrolyte disinfection promoter" as used herein refers to any electrolyte chemical that can increase the disinfection effectiveness of the composition of the present invention. "Moderately acidic" as used herein means greater than about 3.0 to less than PH of 70%. All pH values used herein are measured in a 25t (77T) aqueous system. 2. "Ethylene" as used herein refers to materials or surfaces containing polyacetylene. These materials or surfaces May be waxed or unwaxed. X "Non-liquid" as used herein refers to particles, powders that can be diluted with the aqueous carrier liquid described below to produce the mild acidic hard surface cleaning composition of the present invention Or gel formulation. "The" liquid composition "as used herein means the hard-free surface cleaning and disinfecting composition of the mild acidic solution Ha of the present invention or an aqueous dilution thereof. All parts, percentages used according to the present invention , Ppm and ratio are based on the weight of the composition, and it is assumed that the material has 100% activity, unless it is specified. ~ The following is a detailed description of the product and method of the present invention. Emulsion cleaning Agent Interfacial Active Sword Composition The composition contains amine oxide cleaning surfactants typically having a pKa of from about 4 to about 6. According to the description below, there are at least about 0 to about 100 amine oxides in the composition. The species must be in a cationic or protonated form. 0 The preferred liquid concentrate composition contains from about 0.5 to about 40 parts of amine oxide. This paper is sized to the Chinese National Standard (CNS) A4 (210X297). Packing- ------ Order 丨 ----- ^ ball (please read the precautions on the back before filling this page) The Central Bureau of Standards of the Ministry of Economic Affairs, Shellfish Consumer Cooperative Du printed A7 B7 V. Description of the invention (6) Cleaning Surfactant 'It is preferably from W to about 30 parts, more preferably from W to about 25 parts, and most preferably from 2 to 6 parts. Dilute the concentrated liquid to provide a ready-to-use preferred composition of the present invention. Amine oxidation It is preferred to have a chemical formula of rr, r " n0, wherein R is a substituted or unsubstituted alkyl or alkenyl group including from about 8 to about 30 carbon atoms, and from about 8 to about 18 carbons Atoms are preferred. The R, and R, groups each include a substituted or unsubstituted alkyl or alkenyl group of from about 1 to about 18 carbon atoms, preferably from about! To about 4 carbon atoms. . R, and r " are more preferably methyl groups, and examples thereof include dodecyldimethylamine oxide, tetradecyldimethylamine oxide, cetyldimethylamine oxide, Octadecyl dimethylamine oxide and coconut alkyl difluorenylamine oxide. Amine oxide cleaner surfactants can be prepared by known and familiar methods. One method is the oxidation of tertiary amines, as described in U.S. Patent Application No. 3,223,647 and British Patent Application No. 437,566. Generally speaking, the tertiary amine is prepared by controlling the oxidation of the corresponding tertiary amine. Examples of amine oxide detergent surfactants suitable for use in the composition include dodecyldimethylamine oxide, tridecyldimethylamine oxide, tetradecyldimethylamine oxidation Compounds, pentadecyldimethylamine oxide, octadecyldimethylamine oxide, dodecyldiethylamine oxide, tetradecyldiethylamine oxide, hexadecyl Diethylamine oxide, octadecyldiethylamine oxide, dodecyldipropylamine oxide, tetradecyldipropylamine oxide, cetyldipropylamine oxide Octadecyldipropylamine oxide, dodecyldibutylamine oxide, tetradecyldibutylamine oxide, hexadecyldibutylamine oxide, octadecyldibutylamine oxide Butyl amine oxide, dodecyl methyl ethyl amine oxide, tetradecyl ethyl propyl amine oxide, ten-9- This paper size is applicable to Chinese bacteria (CNS) A4 specification (210X297 (Mm) -------- i Pack-(Please read the notes on the back before filling this page) Order-J line printed by the Shell Standard Consumer Cooperative of the Ministry of Economic Affairs A7 B 7 V. Description of the invention (7) ττ alkylpropylbutylamine oxide and octadecylmethylbutylamine oxide. It is also possible to use an amine oxide cleaner surfactant prepared from the oxidation of a tertiary amine prepared from a mixed alcohol derived from coconut oil. From an economic point of view, these are the preferred coconut alkylamine oxides, because for the purposes of the present invention, it is not necessary to separate the mixed alcohol fraction into pure components to obtain the pure chain length fraction of the amine oxide. . Quaternary Ammonium Sword The composition includes water-soluble quaternary ammonium disinfectant and other shellfish with disinfectant properties. The important mother-in-law is quaternary: compound. Examples of suitable fourth-stage disinfection bombs 1 include dioctyl, octyldecyl, and didecyldimethylammonium chloride; N-alkyl (C12 to C18) dimethylammonium chloride and N-alkane ((: 12 to (: 18) dimethylethylbenzyl ammonium chloride and mixtures thereof, etc. These are used herein as disinfectants with a p Η of 3 to 6 is preferred. Four-stage according to the disinfectant and electrolyte The combination of accelerators provides excellent disinfection properties and / or negative effects, especially similar to the negative effects of prior art compositions on cleaning and / or contamination. Quaternary ammonium disinfectants have 50 to i 5 The amount of 〇〇ppm 'is targeted at a use concentration of about 60 ± 100ppm, and different quaternary ammonium disinfectant doses are used according to the target disinfection organism. Suitable quaternary ammonium disinfectants are disclosed in 195 5 U.S. Patent No. 5,435,935, issued to Cooper Nessie on July 25, 2015, is hereby incorporated by reference in its entirety. Acidifying Agents It has been found that the use of specific acidifying agents in liquid compositions can reduce or eliminate amine oxidation Substances contaminate the surface of ethylene. These acidifiers are used to make liquid compositions Protonation or cationic amine oxidation has also been found-10- This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) ~ J II (Please read the precautions on the back first (Fill in this page again.) Consumption cooperation between employees of the Central Bureau of Standards, Ministry of Economic Affairs, Du printed A7 B7. 5. Description of invention (8) The material can be reduced (ie, 10% protonation) or eliminated (ie, 90%-100%). Protonation) contamination, thus increasing the life of the surface of the second lady. The concentrated composition herein preferably contains from 0.5 to 10 parts of an acidulant, more preferably from 0.2 to 5 parts, and from 0.5 to 5 parts. 2 parts is best, the acidifying agent has at least one p K a value of less than about 6 p K a, more preferably less than about 5.0, and more preferably from about 3.0 to about 5.0. The pKa of the amine oxide should be less than the p Ka value of the selected amine oxide, preferably less than about 1 to 2. The acidifying agent provides protonation of the amine oxide in the composition. The acidifying agent may comprise a member selected from organic acids, Acids of inorganic acids or mixtures thereof. Preferred inorganic acids are hci, hno3, H3P04, HC103 and mixtures thereof. The preferred organic acids are sulfurized succinic acid, methanesulfonic acid, glycerol phosphate, ethylenediamine tetraacetic acid (EDTA), diethylenetriaminepentaacetic acid (H5DTPA), maleic acid, malonic acid, Salicylic acid, tartaric acid, fumaric acid, citric acid, o-g too acid, malic acid, itaconic acid, lactic acid, ascorbic acid, 2,2-dimethylsuccinic acid, succinic acid, benzoic acid and propionic acid But is not limited thereto. The acidifying agent is more preferably selected from the group consisting of thiobutanoic acid, citric acid, salicylic acid, phosphoric acid 'nitric acid, hydrogen acid, peroxy acid, grass, maleic acid, o-g too acid, and Its mixture. The best are scale acid, hydrogen acid, nitric acid, peroxyacid, thiosuccinic acid and mixtures thereof. The liquid composition of the present invention includes sufficient acidulant to establish a ρη value of the composition between about 30 and less than 7.0, preferably between about 4.0 and about 6.0, and between about 4 · Better between 0 and about 5.5. The use of a liquid amine oxide composition having a ρ η of less than about 3.0 on a hard surface may damage the waxed surface, and when ρ 以上 of more than 7.0 is used, it may cause excessive contamination of the ethylene surface. The liquid composition of the present invention must also include sufficient acidifying agent to make the composition have -11 · This paper size towel making country g] household materials (CNS) A4 specifications (21GX297 public magic III II Pack — II order — 1 · ^ ( (Please read the notes on the back before filling out this page)

Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs :::: 10% protonation of amine oxidized substances at a ratio between about 50% to about 100% = [^^ 9 ()% to 1 () ( )%. A cationic amine oxide having four levels of radicals is used according to the " f dagger " formula used herein. Response

RR'R " N- ^ 〇 + H + ^ RR'R " N + 〇H means the conversion of a non-ionic amine oxide into a cationic amine oxide by protonation. $ To achieve the necessary composition pH & amine oxidation material protonation, the preferred acid, agent concentration (ie in the preferred liquid composition) is typically between about 0.05 parts by weight of the liquid composition Between about 0 and about 0 parts, more typically between about 0.01 and about 7 parts t. The acid concentration will be based on the p Ka of the amine oxide, the strength (pKa and concentration) of the selected acidifier, the target pH of the composition, the mole percentage of the amine oxide, and the relative acidity of the acid source and other materials in the composition / Alkaline. Since inorganic acids tend to have a lower pKa than organic acids, it is easier to obtain the target pΗ value with inorganic acids. Inorganic acids can be combined with weaker organic acids to make it easier to reach the target ρ Η value. The hard surface can be cleaned with a liquid composition in a diluted or undiluted form. The disinfectant composition must be registered as an insecticide in ΕρΑ, so it must be registered for disinfection. Before use, the composition is typically diluted with an aqueous liquid. Upon dilution, the composition contains from about 40 pm to about 2,500 ppm of the amine oxide detergent surfactant, preferably from about 0.001 pm to about 2800 pm . Regardless of the dilution or undilution, the liquid composition used on a hard surface must have the necessary composition ρ and protonation of the amine oxidizing species described herein. -12- This paper size is applicable to Chinese National Standard (CNS) Α4 specification (210X297 mm) -------- 1 Packing -------- Order ------ J Xian (Please read the back first Note: Please fill in this page again) A7 B7 printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (10) The necessary pH value of the composition is maintained by the amine oxide component. Amine oxide detergent surfactants generally have a suitable buffering capacity within the range of ρ η described herein. Even when diluted with tap water, the normal amine oxide component can maintain the pH of the composition below 7.0. If necessary, additional buffers can be added to help maintain acidity. These buffers are selected as needed. The ethylene contamination described in this paper comes from the dehydrochlorinaUon effect on the surface of the polyethylene gas. A salty non-acidic amine oxide composition will accelerate this degassing hydrogenation reaction. The accelerated dehydrogenation effect is represented by the following reaction formula:-(CH2-CHC1K + RR'RN ^ 0->-(CH = CH) x- (CH2-CHCl) -n.x + (RR, R " N + OH Cr) x Polychlorinated ethyleneamine oxide Polyethylene gas dehydrogen chloride (typical color) (yellow-brown) Polyethylene gas dehydrogenated has a yellow to brown color, depending on the degree of chlorine removal It depends. The non-ionic amine oxide in the non-acid liquid hard surface cleaner can accelerate this degassing hydrogenation reaction. Protonation of the amine oxidation material to the level described in this article and maintaining the acidic environment will significantly reduce The rate of dehydrochlorination and the reduction or elimination of acetamidine pollution. In the liquid composition herein, the protonated amine oxide is unlikely to trigger the dehydrochlorination reaction, thus ending the pollution. When the mild acid-liquid amine oxide composition of the present invention is used on an acetic stele, it will cause little or no pollution.] Binding jA (Please read the precautions on the back before filling this page) -13 A7 B7 5. Description of the invention („)

Table I Ethylene tile pollution composition of product diluted with liquid amine oxide composition, p-dimethylamine oxide (ppm) acidifying agent acidifying agent pKa acidifying agent concentration (ppm) composition pH pollution A 700 No No No 8.0 Severe ~ " B 700 h3po4 2.12 7.12 12.32 100 4.6 No C 700 HCl Very Low 110 4.7 Mild " D 700 hno3 Very Low 200 4.7 No-E 700 Maleic Acid 2.00 6.26 150 4.7 No — '— F 700 Oxalic acid 1.19 4.21 140 4.7 Mild G 700 Ortho-phthalic acid 3.10 5.27 250 4.6 Mild Η 700 Tartaric acid 3.02 4.54 230 4.6 S5 ~~~~' ~~~~ I 700 Oxalic acid 3.06 4.74 5.40 200 4.6 J 700 Malic acid 3.40 5.05 200 4.6 Light K 700 Succinic acid 4.19 5.57 200 4.8 Light ϊ '' '— L 1 TOO Acetic acid 4.76 4.54 230 4.9 Each composition includes 600 ppm of (didecyldimethylammonium chloride) surface activity Agent 1 (please read the precautions on the back before filling this page). It is printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. In order to transfer the data summarized in Table I, 'the following method will be used. But it is equivalent to normal Long-term ethyl contamination under the condition. According to this method, rinse the white vinyl flooring with warm tap water / 7 and then rinse it with isopropanol twice before allowing it to air dry.% 1 ml of each A composition A_L was applied to individual areas of the tile, and the finished tile was left at room temperature for one hour, then it was placed at 60.00 (14〇 卞), -14-A7 B7 12 Description of the invention (1 hour '4 5 minutes. Remove the tiles from the oven and allow them to cool to room temperature. Rinse the cooled stele with tap water and visually inspect the treated area on each tile.晞 Contamination. Divide the degree of pollution into "no" (no color change), "mild" (very slight, but discoloration can be noticed) ,, moderate, (yellow change), or "severe" (brown) Variation). Each composition A_L is a liquid concentrate at a dilution of 1: 128, which has a pH of 4.5. After dilution, 'each composition (B_L) painted on a stele has a value between about 45 and PH between 5.0. Every diluted composition is therefore Of water, coconut dimethyl amine oxides, quaternary ammonium disinfectants and specific composition of an acidifying agent. Composition A is a control product. It has a pH of about 80. Therefore, essentially 100% of the amine oxide surfactant is in a non-ionic form. This composition (A) causes severe pollution. Compositions B-J are mild acidic amine oxide compositions in which 90 to 100% of the amine oxide species are protonated with an acidifying agent having a p Ka value of less than about 30. Compositions B-L caused little or no ethylene contamination. Composition K & L contains a weaker acid (pKa value greater than about 30), which causes only moderate soil pollution. However, note that all mildly acidic compositions (B_L) cause lower contamination than composition a, which has a higher ρ η (8.0) and therefore has less than 10% amine oxidation The substance is in cationic form. Protonation of cargo poisons on ρ Η and Α Ο It has been found that protonated amine oxides under acidic conditions can limit the sterilization effectiveness of quaternary ammonium disinfectants against Gram-positive bacteria (staphylococci). Without being bound by theory, salted shellfish amine oxide (cation) and quaternary ammonium (cation) disinfectants compete for binding sites on the cell wall. Quaternary ammonium disinfectant is a bactericide, because it (please read the precautions on the back before filling this page). • Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. A7 ________B7___ V. Description of the Invention (13) The integrity of the cell wall is destroyed by disrupting the interaction between membrane proteins and lipids. Because the cell surface is normally negatively charged, it helps attract and bind quaternary ammonium (positively charged) disinfectants. Since the protonated amine oxide (AOH +) is also a cation, the quaternary ammonium disinfectant and AO Η + will compete for the same binding site. A 0 FT has little or no intrinsic bactericidal activity, so the overall disinfection effectiveness of the mixture will be significantly reduced (refer to Table 丨). Formulations M-Q in Table II are based on the formulations described in Comparative Example 4. There is no E D T A or K C 1 in the formulation μ-Q. N-Q pΗ is adjusted by adding phosphoric acid.

Table II ρ Η / amine oxide / protonated amine oxide / quaternary ammonium disinfection efficacy test # Solution pH% AOH% AOH + Results of disinfection efficacy 1 Μ 8.0 100 0 0/10 (pass) 7.0 7.0 0 〇 / 1 〇 (Pass) 0 6.0 97 3 2 / 1〇 (Fail) P 5.0 76 24 6/10 (Fail) Q 4.0 24 76 10/10 (Fail) The Environmental Protection Agency (EP Α) uses AO AC to apply the dilution method to measure disinfection剂 efficacy. In the child test, the test tube carrier was first inoculated with the target bacteria (in this example, Staphylococcus aureus) and then treated with the test product. After a fixed period of culture, live bacteria on the vector were evaluated. Results are stated in terms of number of growing tubes / total number of inoculated tubes. The data in Table 丨 is a screening test because only 10 test tubes are inoculated. 〇 / 1〇 results represent no bacteria growth in 10 test tubes (pass); ι〇 / ι〇 results represent bacteria growth in all 10 test tubes (failed in the screening test- 16- This paper size applies to Chinese national standards (CNS > Λ4 specifications (------- I II IIII | Approval for ordering f ice (please read the precautions on the back before filling this page)) Central Bureau of Standards, Ministry of Economic Affairs Printed by employees 'consumer cooperatives A7 B7 V. Invention Description (I4) In the test' any bacterial growth is considered a failure. In order to register the formulation as a disinfectant, 60 carriers must be inoculated and must not be in more than 丨 test tubes Bacterial growth was found. Although not limited by theory, we believe that protonated amine oxide (AOH +) is not a bactericide because it may or may not pass through the cell wall (because of its chemical structure), or the pH between cells (& gt 7) Rapidly deprotonate amine oxides and render them ineffective. Electrolyte Disinfection Accelerators The compounds of the present invention include an effective amount of an electrolyte disinfection accelerant, which contains a metal test or alkaline earth metal salt ' _ From I selected from, nitrate, sulphate and perchlorate salts preferably selected from:. Licl, LiBr,

LiN03, NaCl, NaBr, Nal, KC1, KBr, KI, KN〇3, KC104,

CaCl2, BaCl2, Na2S04, MgS04 and mixtures thereof. The boosting amount in the concentrate is from 0.05 to 12 parts, preferably 0.2 to 8 parts. A lower amount is better. The booster in the ready-to-use composition is preferably from 5 p pm to 500 ppm, and more preferably from 25 ppm to 300 ppm. Electrolyte disinfection promoters significantly increase the disinfection effectiveness of the composition. Accelerators are better with strong electrolytes, especially KC1 and NaCl. Water Carrier Liquid The compositions herein are used in liquid form on hard surfaces. Therefore, the previous components are blended with the water carrier liquid. The choice of water carrier liquid is not important. It must be safe and chemically compatible with the components of the composition. It should be either neutral or acidic 'to reduce the amount of acidification required. The water carrier liquid can contain solvents commonly used in hard surface cleaning compositions. -17- This paper size applies to China National Standard (CNS) A4 specifications (210X297 mm) -------- One 'pack' --- ---- Order 丨 ----- (Please read the notes on the back before filling this page) A7 B7 V. Description of the invention (15) Fee 1. These solvents must be compatible with the components of the composition and must be chemically stable at the mildly acidic pH of the composition. It should also have good film-forming / residue characteristics. For example, a solvent for hard surface cleaners is described in US Patent Application No. 5,108,660 issued to Michael, 1 992, which is incorporated herein by reference. The water carrier liquid is preferably water or a miscible mixture of alcohol and water. Water-alcohol mixtures are preferred because alcohols can help disperse and dissolve amine oxides and other materials in the composition. Moreover, the viscosity of the composition can be adjusted using alcohol. The alcohol is preferably a C 2 -C 4 alcohol. Most preferred is ethanol. The water carrier liquid is most preferably water or a water-ethanol mixture containing from about 0 to 50 parts of ethanol. Non-Liquid Formulation The present invention also includes a non-liquid composition to which an aqueous carrier liquid is added to easily obtain a mild acid-based hard surface cleaning composition. The non-liquid composition may be granular, powdery, or gelatinous, preferably granular. Non-liquid compositions generally include higher doses of the composition components described herein, in addition to the water carrier. Non-liquid compositions also contain acidifying agents as described herein, with organic acidifying agents being preferred. The non-liquid composition includes a sufficient amount of acid to provide a ratio of pH and protonation of the amine oxidizing species within the range of the mild acid composition described herein when diluted with an aqueous carrier liquid. The non-liquid gel composition includes a reduced amount of an aqueous carrier liquid. The non-liquid particulate composition does not substantially include any aqueous carrier liquid. Regardless of the form, before forming the cleaning composition for hard surfaces of the mild acid solution of the present invention, the paper size is -18 · This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 × 297 mm) Please read the back δ Please fill in this page for the matters of interest. Binding A7 B7 printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the invention (16 Add the water carrier liquid to the liquid composition. Please read the precautions in the back 1 before filling. 5 Packing The composition of the present invention may optionally include auxiliary substances that increase cleaning and aesthetics. In addition to amine oxide surfactants, the composition may optionally include non-interfering (auxiliary surfactants. Adding auxiliary surfactants may Produces cleansing activity. A wide variety of organic water-soluble surfactants can be used as needed. The choice of auxiliary surfactants is based on the user's needs for the intended use of the composition and the commercial availability of the surfactant. The composition can Includes any nonionic and both commonly used in liquid hard surface cleaning compositions Ionic / amphoteric surfactants. Examples of compatible co-surfactants for use in compositions are shown below. The use of "alkyl" indicates a hydrocarbon group (having a chain length from about c 8 to C 2 2 ) Of these surfactants, which are generally considered to be cleaners. Examples of suitable non-ionic surfactants include polyethoxy sorbitol esters, fatty ammonium and di-ethanol ammonium, c8 -c22 ethoxy esters and mixed coconut ethoxy esters containing 1 to 30 ethoxy esters. Employees of the Central Bureau of Standards, Ministry of Economic Affairs, Consumer Co-operation, Du Printed Suitable Zwitterionic Surfactants Betaine and thiobetaine and similar compounds, such as (: 8 to (: 18 amino propane sulfonate and cs to c! 8 ammonium propionate). It is usually impossible to provide a sufficient amount of anionic interface Active agents provide cleaning benefits. Anionic (negatively charged) surfactants can be combined with cationic (positively charged) disinfectants quaternary ammonium and / or AOH + to form insoluble precipitates. However, small amounts of anionic surfactants ( < 5 %) Adjust physical properties (such as specific gravity and stickiness-19 paper rule Chinese National Standard (CNS) & specifications (210X297 mm)) Employees ’cooperation with the Central Standards Bureau of the Ministry of Economic Affairs Printed A7 B7 5. Description of the invention (17) Degrees) without sinking in the fourth grade of a disinfectant or A Η Η +. For most purposes, it is better to use an anionic substance in acid form to reduce the auxiliary substances required for acidifying the composition. Particularly preferred anionic surfactants in this context are linear alkylbenzene sulfonates and alkyl ether sulfates having the general formula AE x S Ο #, where A = C10-C22 alkyl 'E is ethylene oxide And where χ is an integer from 0 to 30; C, 0-C, 4-alkenesulfonate and mixtures thereof. Other optional additives may be used in the composition to increase aesthetic and / or cleaning performance ' such as fragrances, whiteners, enzymes, and colorants. Detergent builders can also be used in the composition. These builders are particularly useful when using co-surfactants or co-surfactants, and they are even more useful when the composition is diluted with special hard tap water (eg, more than 12 grams) before use . Detergent builders hide calcium and magnesium hardness ions that may be combined with auxiliary surfactants or co-surfactants in other ways and reduce their effectiveness. Detergent builders can be used in the composition at a concentration of from about 30 parts to about 10 parts. Basic builder materials are generally not useful in the present invention because they may not be effective under acidic conditions. Relatively 'these optional builder materials ^ β contains acidic or neutral integrators and includes, for example, water-soluble polyisoacids (eg, polymers and copolymers of acrylic acid and maleic acid), polysulfonic acids, amines Stubborn foam inhibitors such as polyacetic acid are particularly useful in compositions. In the hard surface cleaner compositions herein, the amine oxide component promotes the formation and persistence of undesired secondary refractory bubbles. Therefore, the composition should preferably contain a sufficient amount of succinate inhibitors to avoid excessive amounts of paper iSF Chinese National Standards (CNS > Cleverly (------) during use of the composition on hard surfaces. --One pack ------ Order -------- (Please read the notes on the back y before filling this page) 20- Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (18)-Refractory foaming inhibitors. Refractory foaming inhibitors are particularly suitable for preparing compositions that do not require rinsing.: 乂 Known and familiar methods can provide refractory foaming inhibitors. Refractory foaming inhibitors can be based on their Choose in the formulation ability of the composition and the residual characteristics of the composition, etc. The head solid foam inhibitor must be chemically compatible with the components in the composition, and it must have an effect in the pH range described herein: And should not leave visible residue on the cleaned surface. Low foam co-surfactants can be used as stubborn foam inhibitors to mediate the head solid foam properties in the composition. Between about 1 The cosurfactant concentration is usually from 3 to about 3 parts. Yes. Examples of co-surfactants suitable for use herein include block copolymers (eg, pironic® and Tetronic (S, both from BASF) and alkylation (eg, ethoxylation). / Propoxylated) Primary and secondary% (for example, 'Tergit〇i® from Union Carbide; Poly_Tergent® from Orin (01m) Company.) The inhibitor preferably contains a silicone-based substance. The bright substances are effective stubborn foam inhibitors at very low temperatures. The composition preferably contains from about 0.01 to about 0.50 parts of silicone. The stubborn foam inhibitor of the ingredients, more preferably contains from about 0.01 to about 0.3 parts. At these low concentrations, the stubborn foam inhibitor based on silicone is less likely to interfere with the composition of group e. Performance. An example of a stubborn heart / terminal inhibitor with stone ketone as the main ingredient suitable for this composition is Dowcrning®. These 4 can be known and familiar methods as needed, but better A stubborn foam inhibitor based on stone ketone is incorporated into the composition. Benefits 21-j Binding- ---- f · ^ (Please read the notes on the back before filling out this page) This paper size · (2Ί0 〆297mm) Printed by the Consumer Cooperatives of the Central Procurement Bureau of the Ministry of Economic Affairs A7 ---! Z___ V. Description of the invention (19) In addition to the aforementioned reduction of acetamidine contamination, the composition also has excellent cleaning and disinfection characteristics' and will leave little or no visible residue on the hard surface when dried. Available The composition of the present invention cleans and disinfects toilets, etc., as well as hard surfaces. It has been found that these compositions, whether used in flush or non-rinsing applications, leave little or no visible residue on the hard surface. It also has surprising waxy compatibility. According to the above description, at least about 10% of the amine oxide in the composition is a cation. However, on drying, the cationic surfactant tends to form crystalline salts, thus forming a cloud-like residue. However, this situation does not occur when the composition of the present invention is applied to a hard surface (rinsing or non-rinsing application). It has also been found that the composition exhibits excellent de-particulate and greasy soil-removal properties. This is surprising because hard surface cleaners for acidic liquids typically do not clean particulate or greasy dirt on hard surfaces in general as compared to non-acid hard surface cleaners. Most acidic hard surface cleaners are used in the chamber to remove hard water contamination. The composition provides excellent detergency properties, and, unlike current products in the art, leaves little or no visible residue on the cleaned surface to the extent that there is little or no significant damage. Detergents for hard surfaces typically have good or good detergency properties or good residual properties (for example, 'It does not leave visible residues on the cleaned surface), but not both. The compositions herein provide these desired properties simultaneously in a single product. Therefore, the composition is the only one suitable for cleaning, for example, heavily soiled. Bright surfaces' such as waxed vinyl flooring. -22 · [The paper standard is applicable to the Zhongguanjia Standard (CNS) M (21GX297)] ----- (Please read the precautions on the back before filling out this page). -'Β A7 B7 Central Ministry of Economic Affairs Printed by Standards Bureau Consumer Cooperatives V. Description of Invention (20) The user has stated the invention in detail regarding the composition's viewpoint. The present invention also includes a method for cleaning and disinfecting the surface of acetamidine (waxed or unwaxed). The benefits of using the composition on vinyl surfaces have been described above. The second method comprises using a mild acidic liquid composition on the surface of ethylene, or, preferably, using a water diluent thereof. Next, it is wiped with a porous material f, such as a 'cloth or mop, and allowed to dry. In the preferred method, the mild acidic composition is first diluted with an aqueous liquid (preferably tap water). The diluted composition has a pH between about 30 and less than 7.0, preferably between about 4.0 and about 60, and contains from about = 0 ppm to about 12,5 00 ppm of the above-mentioned amine oxide detergent surfactants, preferably from about 100 ppm to about 2800 ppm, and having a quartile / disinfectant of about 600 ppm. At least about 10% of the amine oxide in the diluted composition is crusted, preferably from about 50% to about 100%, and more preferably from about 90% to about 100%. The diluted composition is then applied to the surface of the vinyl, wiped (with a porous material), and allowed to dry. In a preferred method (refer to the examples herein), the mild acidic concentrated composition of the present invention is first diluted with an aqueous liquid (preferably tap water). The concentrated composition contains from 0.05 to 10 parts of an acidulant to protonate the amine oxidizing species and provide the required pΗ. The diluted composition has a pH of between about 30 and 70, preferably between about 4.0 and about 6.0, and contains from about 40 to 1) 111 to about 12,500 ppm of the amine oxide described above. The detergent surfactant is preferably from about 200 ppm to about 2000 ppm, more preferably from about 400 ppm to about 1000 ppm, and has a quaternary ammonium disinfectant of about 600 ppm. Dilution-23- This paper size applies Chinese National Standard (CNS) A4 specification (210X297mm) III Binding-Bookbinding-(Please read the notes on the back before filling this page) Α7 Β7 V. Description of the invention (21) At least about 10% of the amine oxide in the composition is protonated, and may be from about 50% to about 100%, more preferably from about 90% to about 100%. A preferred composition contains 15 to 500 ppm of a strong electrolyte, such as KC1. The diluted composition is then applied to the surface of ethylene, wiped (with a porous material), and allowed to dry. Examples The following examples illustrate, but are not limited to, the compositions of the present invention. Example 1 was prepared without mixing the ingredients in a particular order to form a concentrated group of people. The concentrated composition was diluted with tap water in a volume dilution standard of 1: 128 and tested for cleanliness and disinfection. The diluted composition of Example 1 was effective against both Gram-positive and negative organisms. The p Η of the concentrated composition is 4.5. The ρ Η of the diluted composition is about 4.5 to 5. Example 1 -------- / Crack— (Please read the precautions on the back before filling in this page} * 11 Employees ’Cooperative Cooperative of China ’s Standards Bureau, Ministry of Economic Affairs, Indamine Oxide, 9.00 quaternary ammonium + 7.68 h4edta 2.00 Phosphoric acid 1.11 Ethanol a 0.96 Potassium chloride 0.95 Maleic acid a 0.56 Poly-tergent CS-1 LP * 0.50 Fragrance 0.40 Na5DTPAa 0.17 Silicone solid (DC DSE) 0.0064 1 竦 -24- This paper size applies to Chinese national standards (CNS ) Α4 specification (210 × 297 mm) A7 B7 22 h2o2 water, color & other 5. Description of the invention (0.04 76.55 1 0 0.00% + coconut dimethylamine oxide + didecyldimethylammonium chloride * ethoxylate The by-products of the base and propoxylated surfactant a raw materials are calculated by multiplying the number of components by 10,000 + 128 to calculate the volume ppm of the dilute composition ready for use in this example. Some of the compositions of this example 1 are better The variant comprises about 8 to 10 parts of an amine oxide surfactant; about 6 to 8 parts of a quaternary ammonium vapor; about i to 3 parts of EDTA; about 0.5 to 2 parts of phosphoric acid; about 〇 or 丨 25 parts of potassium gasification and the rest of the water. Adjust p H with H C1 or phosphoric acid or a mixture thereof All variables will kill Gram-positive and Gram-negative organisms. Example 2 Compares Example 1 except that the acid EDTA is replaced with more acid (for example, 'with more phosphoric acid). The composition will be thoroughly cleaned, but Does not disinfect Gram-negative organisms, but is effective against Gram-positive organisms. Comparative Example 3 Compares to Example 1, except that chlorination is not used. The composition is thoroughly cleaned, but does not have a Gram-positive organism. Efficacy. Λ, Comparative Example 4 This male example is the same as Comparative Example 3, but does not use E d Τ Α. Comparative Example 4 is for Gram-positive organisms or Gram-negative organisms when p Η is lower than 7. Zhang Zhang Shijicaiguanjiayi one binding --- ^ (Please read the notes on the back before filling out this page) Printed by the Staff Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs Ⅴ 5. Description of Invention (23) No effect (refer to Table II) A7 B7--Order 1 · ^ (Please read the precautions on the back before filling out this page) Printed by the Staff Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economy 26- This paper size applies to Chinese national standards (C NS) A4 size (210X 297 mm)

Claims (1)

Six, apply for patent Fan Yuan 1. A liquid cleaning and disinfecting composition comprising: from 40 parts per million (ppm) to 1,500 ppm of an amine oxide cleaner; and from quat of ammonium disinfectant (quat) from 50 ppm to 1500 ppm ); An electrolyte disinfection promoter from 15 ppm to 500 ppm; an aqueous carrier and an effective amount of an acidifying agent so that the cleaning composition has an acidic pΗ value from 3 to less than 7; wherein the electrolyte disinfection promoter is An alkali metal or alkaline earth metal salt; wherein the amine oxide has the formula RR_R " NO 'wherein R contains from 8 to 30 carbon atoms, and R' and R " each contain 1 to 18 carbon atoms; and the acidifying agent system therein Selected from hci, hno3, H3P04, HC103, sulfosuccinic acid, methanesulfonic acid, glycerol phosphate, ethylenediamine tetraacetic acid (edta), diethylenetriaminepentaacetic acid (Η 5 DT PA), Maleic acid, malonic acid, salicylic acid, tartaric acid, fumaric acid, citric acid, ortho-gj; acid, gualic acid, itaconic acid, lactic acid, ascorbic acid, 2,2-dimethylsuccinic acid , Succinic acid, benzoic acid, propionic acid and mixtures thereof. 2. The composition according to item 1 of the scope of patent application, wherein the electrolyte disinfection accelerator is selected from the group consisting of LiCl, LiBr, LiN03, NaCl, NaBr, Nal, KC1, KBr, KI, KNO3, KC104, CaCl2, BaCl2, Na2S04, MgS04 and their mixtures. The composition according to item 1 of the scope of patent application, wherein the electrolyte disinfection promoter is selected from the group consisting of NaCl, NaBr, Nal, KC1, KBr, KI, and mixtures thereof; and wherein the electrolyte disinfection promoter The content is from 25 to 300 ppm; wherein the acidifying agent is selected from the group consisting of ethylene diamine tetraacetic acid (EDTA), maleic acid, scaly acid, dioctyl succinic acid, nitric acid, hydrochloric acid, The group consisting of peroxyacid, o-phthalic acid and mixtures thereof; and 27-of this paper music standard is applicable to the Zhongguan Family Standard (CNS) Α4 · (21 () > < 297 public, please read the back first. Note for re-binding printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs Six, apply for patent Fan Yuan 1. A liquid cleaning and disinfecting composition comprising: from 40 parts per million (ppm) to 1,500 ppm of an amine oxide cleaner; and from quat of ammonium disinfectant (quat) from 50 ppm to 1500 ppm ); An electrolyte disinfection promoter from 15 ppm to 500 ppm; an aqueous carrier and an effective amount of an acidifying agent so that the cleaning composition has an acidic pΗ value from 3 to less than 7; wherein the electrolyte disinfection promoter is An alkali metal or alkaline earth metal salt; wherein the amine oxide has the formula RR_R " NO 'wherein R contains from 8 to 30 carbon atoms, and R' and R " each contain 1 to 18 carbon atoms; and the acidifying agent system therein Selected from hci, hno3, H3P04, HC103, sulfosuccinic acid, methanesulfonic acid, glycerol phosphate, ethylenediamine tetraacetic acid (edta), diethylenetriaminepentaacetic acid (Η 5 DT PA), Maleic acid, malonic acid, salicylic acid, tartaric acid, fumaric acid, citric acid, ortho-gj; acid, gualic acid, itaconic acid, lactic acid, ascorbic acid, 2,2-dimethylsuccinic acid , Succinic acid, benzoic acid, propionic acid and mixtures thereof. 2. The composition according to item 1 of the scope of patent application, wherein the electrolyte disinfection accelerator is selected from the group consisting of LiCl, LiBr, LiN03, NaCl, NaBr, Nal, KC1, KBr, KI, KNO3, KC104, CaCl2, BaCl2, Na2S04, MgS04 and their mixtures. The composition according to item 1 of the scope of patent application, wherein the electrolyte disinfection promoter is selected from the group consisting of NaCl, NaBr, Nal, KC1, KBr, KI, and mixtures thereof; and wherein the electrolyte disinfection promoter The content is from 25 to 300 ppm; wherein the acidifying agent is selected from the group consisting of ethylene diamine tetraacetic acid (EDTA), maleic acid, scaly acid, dioctyl succinic acid, nitric acid, hydrochloric acid, The group consisting of peroxyacid, o-phthalic acid and mixtures thereof; and 27-of this paper music standard is applicable to the Zhongguan Family Standard (CNS) Α4 · (21 () > < 297 public, please read the back first. Attention: Rebinding VO 2-* · " 0 ABCD printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 6. The scope of patent application The content of the quaternary ammonium disinfectant is at least 500 ppm, and the pH value is To 5. 4. The composition according to item 1, 2, or 3 of the scope of the patent application, wherein the acidifying agent is selected from the group consisting of ethylene diamine tetraacetic acid (EDTA), peroxyacid and dioctyl sulfonate butane, diacid Group consisting of KC1 and its mixture; and Wherein the amine oxide cleaner has the formula RR'R "NO ', where R contains from 8 to 18 carbon atoms, and R, and R " each contain 1 to 4 carbon atoms. 5_ According to the scope of the patent application 1' 2 Or a composition of 3, wherein the cleaning composition contains an amine oxide cleaner from 100 to 2800 ppm; wherein the p 液体 value of the liquid composition is from 4 to 6, and from 90% To 100% of the amine oxide cleaner is protonated; and wherein the content of the quaternary ammonium disinfectant is at least 50 ppm 'and wherein the composition contains a foam suppression sword; wherein the quaternary disinfectant is Selected from the group consisting of dioctyl, octyldecyl and didecyldimethylammonium chloride, N-alkyl ((: 12 to (: 18) dimethylammonium chloride and N-carbyl (Cu to C18) A group consisting of dimethylethylphosphonium ammonium gaseous substance and its mixture. 6. The composition according to item 5 of the scope of patent application, wherein the quaternary ammonium disinfectant is monodecyl monomethyl chloride. Economy The Ministry of Central People's Republic of China Standards Bureau Employees' Consumer Cooperatives India Fan 7. The composition according to item 5 of the scope of patent application, wherein the cleaning composition contains Amine oxide cleaners from 2000 ppm to 2000 ppm, and the content of the four-stage bell-disinfectant bombs are at least 600 ppm to 100 ppm. 8.-A kind for cleaning and sanitation or A method for disinfecting the surface of the second wife, the method includes the following steps: -28- This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297). Scope a) Apply a ready-to-use liquid cleaning group & item according to patent scope i of the towel onto the surface of ethylene, and then b) wipe the liquid cleaning composition on the surface of ethylene with a porous material and make The ethylene surface was dry. 9. The method according to item 8 of Shenyan Patent, wherein the liquid cleaning composition has a pH value between 4 and 6, an acidifying agent having a value less than 40pK & and 9% in the liquid cleaning composition. % To 100% of the amine oxide cleaner is protonated; and wherein the amine oxide cleaner has the formula RR, R " NO, where R contains from 8 to 18 carbon atoms, and R, and R, • Each contains 1 to 4 carbon atoms. 10. A concentrated hard surface cleaning composition comprising: a) from 0.5 to 40 parts of an amine oxide cleaner based on the weight of the concentrated composition; b) from 1 to 3 Quaternary ammonium disinfectant; c) electrolyte disinfection promoter from 0.05 to 2 parts; d) an effective amount of an aqueous carrier liquid; and e) acidifier from 0.05 to 10 parts; The electrolyte disinfection accelerator is an alkali metal or alkaline earth selected from the group consisting of LiCl, LiBr, LiN03, NaCl, NaBr, Nal, KC1, KBr, KI, KN03, KC104, CaCl2, BaCl2, Na2S04, MgS04 and mixtures thereof. A metal salt; wherein the amine oxide has the formula RR, R ,, NO, wherein R contains from 8 to 30 carbon atoms, and R 'and R " each contain 1 to 18 carbon atoms; and the acidifying agent system therein Selected from HC1, HN03, H3P04, HC103, sulfosuccinic acid, methanesulfonic acid, glycerol phosphate, ethylenediamine tetraacetic acid (ED TA), diethylenetriaminepentaacetic acid (H 5 D TP A), maleic acid, malonic acid, salicylic acid, tartaric acid, fumaric acid, citric acid, o-phthalic acid, malic acid, itaconic acid, lactic acid, anti- -29- This paper size is based on the Chinese national standard (CNS > A4 size (210X297mm) f Please read the precautions on the back before filling out this page} 2. The scope of the patent application: Ascorbyl 2,2-methylsuccinic acid, succinic acid, benzoic acid, propionic acid and mixtures thereof. The pH value of its t liquid composition is between; f less than 10% of the amine oxide cleaner is protonated; and wherein the acidifying agent may include at least m to 4 parts of ethylenediaminetetraacetic acid (EDTA) based on the weight of the concentrated composition. The material is diluted with water at a ratio of 1: 1 to 1: 600. 11. The concentrated hard surface cleaning composition according to item 1G of the patent application, which contains from 4 to 16 parts of the four Grade ammonium disinfectant; wherein the concentrated composition is diluted from 20 to 1: 300 by volume of water. 12. Cleansing group for concentrated hard surfaces according to item No. Material, wherein the concentrated hard surface cleaning composition comprises: σ, a) from 1 to 25 parts The amine oxide cleaner; b) from 4 to 16 parts of quaternary chloride; c) 1 to 3 parts of ethylene diamine tetraacetic acid (EdTa) as needed. D) from 0 to 25 parts to 2.0 Parts of phosphoric acid; e) potassium carbide from 0,2 to 2 parts; f) the rest is water; and wherein the concentrated cleaning composition uses water in the concentrate, ^ yj ^ counts 1:30 to 1: 260 When diluted in the proportion, it will provide + cleansing and disinfecting composition for Han only. 13. A concentrated hard surface main object according to item 10 of the scope of the patent application, wherein the concentrated hard surface cleaning composition contains β-Kang combination a) from 8 to 10 parts of the amine oxide cleaner B) Four-level gasification press from 6 to 8 parts; -30- This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) 1 pack ----- 1T ----- -1 (Please read the back. 疋 Note before filling out this page) 25ί Α8 Β8 C8 D8 VI. Patent application scope c) From 1 to 3 parts of ethylenediamine tetraacetic acid (EDTA); d) From 0.5 to 1.2 parts of phosphoric acid E) from 0.5 to 1.25 parts of the potassium chloride; f) the balance is water; and wherein the concentrated cleaning composition is a dilute composition diluted with water 1: 1 2 8 for immediate use. To mention (please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs -31 This paper size applies to China National Standard (CNS) A4 (210X297 mm)