TW379238B - Polysiloxane copolymers from Michael adduct reactions - Google Patents

Description

No. 86117226 Patent Application Chinese Manual Revised Page (October 87)

V. Description of the invention (2)

Ο «CH2 = C-C-0-.I R

-Q η Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economics, where R is H or CH3, n = 1 and Q is an organic group, and the reaction of the eight and six is preferably performed in a solvent. In particular, the present invention provides silicone-containing copolymers, such as: a silicone monodiol polymer, a second ketone monomer polymer, and a stilbene monoaryl polymer. These 1 polymers are made from the Michael addition reaction, using amine-functional polysiloxanes and acrylates with organic groups (such as polyether, alkyl, or aryl). The polysiloxane (A) of the present invention has the formula R3Si0 (SiR20) xSiR3 or (ii) (SiR2〇) Z-, wherein the average X of X is from 0 to 1000 z, and at least 3 R are each selected from a hydroxyl group, Alkoxy, trifluoropropyl, alkyl with 4 to 4 carbon atoms, phenyl, and amine functional groups, and at least one R on the polysiloxane is an amine functional group. These linear or cyclic polymers may be zeolite or zeolite. Rhenium has a viscosity ranging from 5 to 50,000 square millimeters per second (cs), and its molecular weight is from 300 to 25,000. x 値 can be from 0 to 1000, the preferred range is 0 to 500, and the best range is 0 to 100. Z is any integer greater than or equal to 3. -5- This paper size applies to China National Standard (CNS) Α4 specification (2 丨 0 × 297 male t) ---------— *-(Please read the precautions on the back before filling this page)

, 1T A7 A7 Printed by the Consumer Cooperatives of the Central Government Bureau of the Ministry of Economic Affairs

V. Description of the invention (1) The present invention relates to a polyoxygenated polymer produced by a Michael addition reaction between a polyoxymethylene fired containing an amine functional group and acrylic acid vinegar having a hydrocarbon group-containing group. Eight et have already cooked the use of # 麦可 加 反应 'but its use is restricted in ketone chemistry (the use is limited. It is now found that using this chemical method, the functionality is formed by the amine m-oxygenation and the propionate acid functional group. Non-functional siloxane reaction to produce functional or non-functional siloxane method. Relative to the 10,000, ethyl ethyl SiH addition reaction, our proposed reaction does not require additional catalyst, and the final copolymer The stoichiometric ratio is easily based on the amine and acetic acid molmol ratio. The #oxane copolymer 'can be prepared without the need for a catalyst and the siloxane copolymer can be formed because the adduct is completely formed. The present invention is a composition prepared by the reaction of (A) and (B), wherein (a) is at least one polysiloxane selected from (i) R3SiO (SiR2〇) xSiR3 or ⑻ (〒 _z— 丨 Wherein, the average 値 of X is from 0 to 1000 z 値 at least 3 R is selected from the group consisting of a radical, an alkoxy group, an oxo group, an alkyl group having a fluorene atom, a phenyl group, and an amine functional group And at least one of the polysiloxanes is an amine functional group; and (B) at least one acrylate having the following formula The standard applies to the National Standard of China (CNS) A4 specification (2 丨 0 X 297 mm) --------- "Install I-C $ Read .f side notes • Identification Matters Fill this page}- Revision • I- -I — i I i ____I ___ —LING ------------ Chinese Version of the Chinese Manual for Patent Application No. 861Π226 Amendment Page (October 87)

Invention Description (

〇 • II CH2 = C-C-〇 I R n

Q, R'H or CH3 'n-1 and q is an organic group. This acrylate group (B) is monofunctional (when V is equal to 1). Specific examples of the acrylate used in the practice of the present invention are Li 7 __. Abstract: Glycol ethylene glycol monoacrylate, polypropylene glycol monopropionate, tetrafluoropropylpropionate, methoxy ( Ethyloxy) Ethylpropionate. Q 疋 does not interfere with any organic groups in the Michael addition reaction between the reactive amines of the polyoxymethylene (A) and the propionate group (β). (Please read the precautions on the reverse side before filling out this page),-° Γ Printed on the paper by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. The paper size applies to the Chinese National Standard (CNS) Α4 specification (210 × 297 mm) Patent Application No. 86117226 Case Chinese Manual Revision Sheet (October 87)

V. Description of the invention (2)

Ο «CH2 = C-C-0-.I R

-Q η Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economics, where R is H or CH3, n = 1 and Q is an organic group, and the reaction of the eight and six is preferably performed in a solvent. In particular, the present invention provides silicone-containing copolymers, such as: a silicone monodiol polymer, a second ketone monomer polymer, and a stilbene monoaryl polymer. These 1 polymers are made from the Michael addition reaction, using amine-functional polysiloxanes and acrylates with organic groups (such as polyether, alkyl, or aryl). The polysiloxane (A) of the present invention has the formula R3Si0 (SiR20) xSiR3 or (ii) (SiR2〇) Z-, wherein the average X of X is from 0 to 1000 z, and at least 3 R are each selected from a hydroxyl group, Alkoxy, trifluoropropyl, alkyl with 4 to 4 carbon atoms, phenyl, and amine functional groups, and at least one R on the polysiloxane is an amine functional group. These linear or cyclic polymers may be zeolite or zeolite. Rhenium has a viscosity ranging from 5 to 50,000 square millimeters per second (cs), and its molecular weight is from 300 to 25,000. x 値 can be from 0 to 1000, the preferred range is 0 to 500, and the best range is 0 to 100. Z is any integer greater than or equal to 3. -5- This paper size applies to China National Standard (CNS) Α4 specification (2 丨 0 × 297 male t) ---------— *-(Please read the precautions on the back before filling this page)

, 1T Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs! «7 5〇 < ί No. 86 丨 17226 Patent Application 1 at * 〇 'Chinese Manual Correction Page (October 87) Β1 V. Description of Invention ( 7) (ii)-(CH2) y (OCH2CH2) aOR, ^ (m)-(CH2) y (OCH2CH2) a (OCH2CHCH3) bOR ·, (iv)-(CH2) y [OCH2CH (CH2CH3)] cOR ' , (V)-(CH2) y (OCH2CHCH3) b [OCH2CH (CH2CH3)] cOR ', (vi)-(CH2) y (OCH2CH2) a [OCH2CH (CH2CH3)] cOR', and (vii)-(CH2 ) y (OCH2CHCH3) b〇R '? where R' is a hydrogen atom, an amyl group having 1 to 4 carbon atoms, an aryl group having 6 to 12 carbon atoms' an arane having at least 6 carbon atoms Base; or fluorenyl, the integer y is 2-20; a is 1-120; b is 1-50; and c is Bu 50. Typical polyethers include-(CH2CH20) 8H,-(CH2CH20) 12H,-(CH2CH20) 8CH3,-(CH2CH20) 12CH3,-(CH2CH20) 8C (0) CH3,-(CH2CH2O) 20H,-(CH2CH (CH2CH3) ) O) 10CH3,-(CH2CHCH30) 5C (0) CH3 or a mixture thereof. The molar ratio of NH to propionate is usually from 1000 to 0.001. Most of the copolymers described here are prepared without the aid of solvents. However, when a solvent is used, the solvent is preferably selected in consideration of the solubility of the final product. Typical solvents are aliphatic, aromatic, alcohol or water. The composition we have proposed can also include fillers and fillers, often using enhanced and enhanced types. This filler is present in an amount as high as 200 parts by weight of the copolymer. Typical fillers include silica, alumina, aluminum hydroxide, diatomaceous earth, magnesium hydroxide, ground quartz, mica, carbonic acid dance, clay, barium sulfate, and oxygen-10- This paper size applies to Chinese national standards (CNS) A4 specification (210X297mm) -------- 4 Pack -------- Order-: ---- ~ ^ (Please read the precautions of Rainbow before filling this page) 5. Description of the invention (3 A7 B7 For the purpose of the present invention, this amine functional group is bonded to at least one silicon atom of polyammonoxane (A) via a sand-carbon bond, preferably killed by the following formula:

rV Ν · R2

N r1 R3 · (I) k Economy A Standard Employee Consumer Corporation Formula (I), R1 is a monovalent group, each selected from a hydrogen atom, an alkyl group with Iii 8 carbon atoms (such as methyl, ethyl Radicals, propyl, isobutyl, hexyl, octyl, decyl, dodecyl and tetradecyl); substituted radicals with .1 to 18 carbon atoms (eg 3-chloro Propyl or 3,3,3-trihydropropyl); aryl groups with 6 to 16 carbon atoms (such as: phenyl or #yl); substituted aryl groups with 6 to 30 carbon atoms (Such as: chloro.phenyl, chlorotolyl, and dioxylene.), Arylalkyl groups with 7 to 9 carbon atoms (such as ..., fluorenyl, phenethyl, and% phenylpropyl) And alkylaryl groups with 7 to 16 carbon atoms (such as: tolyl, diphenyl, ethylphenyl and propyltolyl). According to the invention, at least one R1 group in formula VII is a hydrogen atom. Other ... groups are preferably fluorenyl. Similarly, in formula (2), R2 is a divalent hydrocarbon group having 2 to 6 carbon atoms (for example, ethylene, propyl, butyl, and hexyl). Ethyl is preferred. 'K is 0, 1 or 2 ^ R3 is a divalent organic linking group that separates at least one carbon atom between the nitrogen of formula (I) and the stone of polystilbene oxide (A). This group contains at least one carbon atom. Benfenmin does not limit other properties as long as it is chemically stable (ie, does not react with it) and does not interfere with component (B) when it encounters a hydrolyzable alkoxy group. -6-propionic acid functionality and component (A) -6 This paper size applies to Chinese National Standard (CNS) A4 size (210X297 mm) ~ 1 pack — (Please read the back of the ** 的 NoteMore Matters # -fill in This page) Order one by one ~~ I --- .I .1 II · Revised page of Chinese specification of Patent Application No. 86117226 (October 1987) 5. Description of the invention (9) L33 millimolar) 8.5 Ml vial. This solution was stirred for 1 hour with a magnetic dispenser and a search bar. The final substance is a misty 'white liquid with a viscosity in m of 1660 mPa s (cp). Example 2 MD3D " M + PEG 400 Me3Si〇 (SiMe20) 3 (NH2CH2CH2NHCH2CH (CH3) CH2)

MeSiOhSiMedl (0.1 g, 10.0 mmol) and polyethylene glycol 400-acrylic acid vinegar (10.25 g, 20.0 mmol) were weighed into 18.5.ml vials. This solution was stirred with a magnetic stirrer and a stir bar for 1 hour. The final substance was a transparent, yellow liquid with a viscosity of 925 mPa_s (cp) at 23 ° C. Example 4 M, D1f) D% M '+ PPG 400 Me3SiO (SiMe2O) 10 {NH2CH2CH2NHCH2CH (CH3) CH2) 1 \ ^ 5 丨 〇} 25 丨 1 ^ 3 (8.55 g, 5.00 mmol) and polypropylene glycol 400-acrylate (7.25 g, 20.0 mmol) was weighed into a 18.5 ml vial. This solution was stirred with a magnetic stirrer and a stirrer for 1 hour. The final substance is a transparent liquid with a viscosity of 752 mPa.s (cp) at 23 ° C. Example 5 MDsM'M + PEG 2000 Me3SiO (SiMe20) 3 (NH2CH2CH2NHCH2CH (CH3) CH2)

MeSiO} | SiMe3 (10.16 g, 10.00 mmol) and polyethylene glycol 2000-acrylate (26.97 g, 10.0 mmol) were weighed into 18.5 ml vials. This solution ^ Binding ----- 1 (Please read the notes on the back cylinder first and then fill out this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs -12- This paper applies the Chinese National Standard (CNS) A4 Specifications (2 丨 0X297 mm) A7 B7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (4 The reaction between amine functionalities is sufficient. The preferred R3 is selected from propyl, butyl and butyl Isobutyl. Examples of specific amine-containing groups include -CH2CH2CH2NH2, -CH2CH2CH2N (H) CH2CH2NH2, -CH2CH2CH2N (H) CH2CH2N (H) CH2CH2NH2 '-CH2CH2CH2CH2NH2, -CH2CH2CH2CH2CH2CH2CH2CH2CH2CH2N CH2CH2NMe2, -CH2CH2CH2N (H) Et, -CH2CH (CH3) CH2N (H) CH2CH2NH2, and -CH2CH (CH3) CH2NH2, where Me and Et are methyl and ethyl, respectively, and the same applies hereinafter. Polysiloxanes ( A) Manufactured from methods known in the art. For example, they are derived from alkoxysilanes (e.g. methyltrimethoxysilane, tetraethoxysilane, tetramethoxysilane, dimethyldioxane Silane or phenyltrimethoxysilane) and amine-functional alkoxysilane The polyorganosiloxanes whose amines and alkyl groups are statistically distributed on different silicon atoms should be obtained. This process can be performed continuously or simultaneously to change the distribution of amines and alkoxy groups. In addition, by using siloxane redistribution Catalysts (such as: alkali metal hydroxides or silanol esters), with additional organosiloxane units to balance the above polymers, different structures can be made. Cells can be made by using cyclic diorganopolysiloxanes The mixture of amine, alkylalkylalkoxysilane, and optionally used alkoxyalkane is reacted to obtain the statistical distribution of alkoxy, alkyl, and amine groups by such an equilibrium procedure. The polysiloxane of the present invention Alkane (A) and at least one propionate of the formula (b) The paper size of the combined table applies to the Chinese National Standard (CNS) A4 (210 X 297 round) n · II— III-nnn-nnnn T (please first Read the notes on the back Φ and fill in this page again) Printed Chinese Manual of Patent Application No. 86117226 by the Ministry of Economic Affairs of the Central Government Bureau of Consumers' Correction Sheet (September S7) V. Description of the Invention (17) Acrylate (3.72 Grams, 20.0 milligrams Ear) was weighed into a 185 mL vial. This solution was stirred in a magnetic stirrer and stir for 1 hour. The final material is transparent, low-viscosity fluid.

Example 24 M " D10M " + TFPMA will be (NH2CH2CH2NHCH2CH (CH3) CH2) Me2SiO (SiMe2- (CH2CH2CH2NHCH2CH2NH2) (10.41 g, lo.o millimoles) and 2,2,3,3 -tetrafluoropropyl acrylate ( 3.72 g, 20.0 mmol) were weighed into a 18.5 ml vial. This solution was stirred with a magnetic stirrer and a stirrer for 1 hour. The final substance was a transparent low viscosity fluid. Comparative Example 1 MD96D " 2M + TMPTA Me3Si (SiMe20) 96 ((NH2CH2CH2NHCH3CH (CH3) CH2)

MeSiOh-SiMe3 (10.0 g) and trimethylolpropane triacrylate (SartomerTM 351) (1.0 g) were weighed into 18.5 ml vials. This solution was stirred for 2 minutes (until homogeneous) 'and poured into a weighing pan to a thickness of 3.35 mm (132 mils). The time required for the material to form a cured surface (S0T or surface coverage time) and the time required for complete gelation (fully cured) on the sample were recorded. The results were 105 minutes and 180 minutes, respectively. The Shore hardness of the obtained glue was measured on a Shore " 00 " hardness tester, and its 値 was 45.

L Dagger Comparative Example 2 MD96D " 2M + HDDA Me3SiO (SiMe2〇) 96 ((NH2CH2CH2NHCH3CH (CH3) CH2)

MeSi0} 2-SiMe3 (10.0 g) and hexanediol diacrylate (Sartomer ™ 238) (1.0 g) were weighed into 18.5 ml vials. This solution was stirred for 2 minutes (until homogeneous) 'and poured into an aluminum weighing pan to a thickness of 3.05 mm (120 mils). Record the time required for this material to form a cured surface on the sample (s0T or surface-covered -20- This paper + National Standard (CNS) A4 specification (210X297 mm) '~ --- I' Λ 1 Order ---(Please read the notes on the back * and fill in this page) Revised page of Chinese Manual for Patent Application No. 861Π226 (October 1987)

Invention Description (

〇 • II CH2 = C-C-〇 I R n

Q, R'H or CH3 'n-1 and q is an organic group. This acrylate group (B) is monofunctional (when V is equal to 1). Specific examples of the acrylate used in the practice of the present invention are Li 7 __. Abstract: Glycol ethylene glycol monoacrylate, polypropylene glycol monopropionate, tetrafluoropropylpropionate, methoxy ( Ethyloxy) Ethylpropionate. Q 疋 does not interfere with any organic groups in the Michael addition reaction between the reactive amines of the polyoxymethylene (A) and the propionate group (β). (Please read the precautions on the reverse side before filling out this page),-° Γ Printed on the paper by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. The paper size applies to the Chinese National Standard (CNS) Α4 specification (210 × 297 mm) Patent Application No. 86117226 Revised page of the Chinese manual for the case (October 87) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. The description of the invention (18) time) and the time required for complete gelation (fully cured), the results are 24 hours and 48 hours. The Shore hardness of the resulting glue was measured on a Shore, 〇 " hardness tester, and its 値 was 3. Comparative Example 3 MD96D " 2M + PETA Me3Si (SiMe20) 96 {(NH2CH2CH2NHCH3CH (CH3) CH2) MeSiO} 2-SiMe3 (10.0 g) and dipentaerythritol pentaacrylate (SartomerTM399) (1.0 g) were weighed into a 18.5 ml vial . This solution was stirred for 2 minutes (until it was homogeneous) and poured into an aluminum weighing pan to a thickness of 3.05 mm (120 in ears). The time required for the material to form a cured surface (SOT or surface coverage time) and the time required for complete gelation (complete curing) on the sample were recorded. The results were 75 minutes and 105 minutes, respectively. The Shore hardness of the obtained glue was measured on a Shore " 00 " hardness tester and its 値 was 35. Comparative Example 4 MD96D " 2M + urethane acrylate Me3Si (SiMe20) 96 {(NH2CH2CH2NHCH3CH (CH3) CH2) MeSiOL-SiMe3 (10.0 g) and a hexafunctional aromatic with an acrylated polyol diluent Urethane acrylate (UCB Radcure Ebecryl® resin 220) (1.0 g) was weighed into a 18.5 ml vial. The solution was stirred for 2 minutes (until homogeneous) and poured into an aluminum weighing pan to a thickness of 3 ::! Mm (122 mils). Record the time required for the material to form a cured surface (SOT or surface coverage time) and the time required for complete gelation (complete curing) on the sample. The results are 30 minutes and 60 minutes, respectively. The% 01 ^ hardness of the obtained glue measured at the Shore " 00 "durometer soil, the hardness of which is 4 0. Up to Comparative Example 5 MDq &D; D, M + TMPTA + Diatomite Me3Si (SiMe20) 96 {(NH2CH2CH2NHCH3CH (CH3 ) CH2) -21-(Please read the notes on the back before filling this page) Binding. Order-This paper size is applicable to China Family Standard (CMS) A4 specification (210X 297 mm) Cooperative printed A7 ________ B7____ 5. Description of the invention (6) Typical Q groups include polyether, aliphatic, aromatic and cycloaliphatic hydrocarbon groups. This fluorene group is functional and reactive or non-functional and Non-reactive. For example, Q may be a monovalent hydrocarbon group, such as: a morpho group having 1 to 100 carbon atoms, including methyl, ethyl, propyl 'isopropyl, butyl, pentyl, iso Pentyl, neopentyl, hexyl, octyl, dodecyl, hexadecyl, 3-methylheptyl, 6-butyl octadecyl, tertiary butyl, tridecyl And 2,2-diethylpentyl; alkenyl, such as: vinyl, allyl, hexenyl, butenyl, 3-octyl ryl, 4,9-octadecadiene Pentyl and 4-nonenyl; alkynyl, such as: propynyl, heptynyl, butynyl, and decynyl; alkenyl block groups such as 1-penten-3-ynyl or 2 -Ethyl-1-butene-3-alkynyl; cycloaliphatic radicals' such as: cyclohexyl, 2,4-dimethylcyclopentyl, cyclohexenyl, bicyclo [3, ι, 〇] Hexyl, tricyclononenyl, spiro [4,5] decyl, monospiro [4,1,4,2] -1-tridecylenyl, decathelenyl, 2,3-dihydroindenyl and 1,2,3,4-tetrahydrofluorenyl; aryl groups such as phenyl, tolyl, xylyl, 3-ethylphenyl, biphenyl, fluorenyl, anthryl, and pentacene , 3,4-methylethylphenyl, 9,9-difluorenyl and 4-m-bitriphenyl; and aralkyls, such as 2-phenyloctyl, 3-fluorenyl-2- ( 4-isopropylphenyl) heptyl, fluorenyl, .2-ethylfluorenyl, 2-ethyl-p-cumyl, diphenylmethyl, 4,5-diphenylpentyl, 2 _Phenylaceton and 2_Phenylpropyl. In addition, 'Q is an identical or different group containing oxyethyl, oxypropyl, oxybutyl or a combination thereof. Representative q Is a polyether selected from: (i)-(CH2) y (OCH2CH2) a (OCH2CHCH3) b [〇CH2CH (CH2CH3 )] c〇R ', -9- This paper size is applicable to China National Standard (CNS) A4 specification (210x297 mm) "Packing -------- Order -------- ^ ^ (Please read the back Note the Yuan matters and fill in this page again) S6117226 Patent Application Chinese Specification Revised Page (S7 October 8 Milk 丨 B7 You V. Invention Description (19

MeSiOh-SiMe3 (10.0 g) and trimethylolpropane triacrylate

Saitomer 351) (1.0 g) and 3.5 g of CeliteTMFP-3 filler were weighed into 18.5 ml vials. Stir this solution; mix for 2 minutes (until homogeneous) and pour into a weighing pan to a thickness of 4_3 mm (170 mils). Record the time required for the material to form a solidified surface (SOT or surface coverage time) and the time required for complete gelation (complete curing) on the sample. The results are 100 minutes and 140 minutes, respectively. The hardness of the 51Oth generation of the obtained glue was measured on a Shore " 00 " hardness tester, and its 値 was 83. Comparative Example 6 MDwD'VM + ΗΓ > ηΛ Me3Si (SiMe20) 96 {(NH2CH2CH2NHCH3CH (CH3) CH2) MeSiO} -SiMe3 (10.0 g) and Hexanediol Dipropionate (SartolinTM238) (2.0 g) were weighed Into a 18.5 ml vial. This solution was stirred for 2 minutes (until uniform) 'and poured into an aluminum weighing pan to a thickness of 3.8 mm (150 mils). Record the time required for the material to form a cured surface (SOT or surface coverage time) and the time required for complete gelation (complete curing) on the sample. The crusts are 48 hours and 48-72 hours, respectively. The Shore hardness of the obtained glue was measured on a Shore " 00 " hard gauge, and its 値 was less than 1, which was a sticky glue. in mn tmv m · tm · 1 nn nil--........》 eJ ^ i ^ n— f-—I (please read the precautions of s' before filling this page) Central Ministry of Economic Affairs Printed by the Bureau of Standards Consumer Cooperatives 22- This paper size applies to the Chinese National Standard (CNS) A4 (210X 297 mm) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs! «7 5〇 < ί No. 86 丨 17226 Patent application 1 at * 〇 'Chinese specification amendment page (October 1987) B1 V. Description of invention (7) (ii)-(CH2) y (OCH2CH2) aOR, ^ (m)-(CH2) y ( OCH2CH2) a (OCH2CHCH3) bOR ·, (iv)-(CH2) y [OCH2CH (CH2CH3)] cOR ', (v)-(CH2) y (OCH2CHCH3) b [OCH2CH (CH2CH3)] cOR', (vi) -(CH2) y (OCH2CH2) a [OCH2CH (CH2CH3)] cOR ', and (vii)-(CH2) y (OCH2CHCH3) b〇R'? Where R 'is a hydrogen atom and has 1 to 4 carbon atoms An aryl group having 6 to 12 carbon atoms, an aralkyl group having at least 6 carbon atoms; or an amidino group, the integer y is 2-20; a is 1-120; b is 1-50 And c is Bu 50. Typical polyethers include-(CH2CH20) 8H,-(CH2CH20) 12H,-(CH2CH20) 8CH3,-(CH2CH20) 12CH3,-(CH2CH20) 8C (0) CH3,-(CH2CH2O) 20H,-(CH2CH (CH2CH3) ) O) 10CH3,-(CH2CHCH30) 5C (0) CH3 or a mixture thereof. The molar ratio of NH to propionate is usually from 1000 to 0.001. Most of the copolymers described here are prepared without the aid of solvents. However, when a solvent is used, the solvent is preferably selected in consideration of the solubility of the final product. Typical solvents are aliphatic, aromatic, alcohol or water. The composition we have proposed can also include fillers and fillers, often using enhanced and enhanced types. This filler is present in an amount as high as 200 parts by weight of the copolymer. Typical fillers include silica, alumina, aluminum hydroxide, diatomaceous earth, magnesium hydroxide, ground quartz, mica, carbonic acid dance, clay, barium sulfate, and oxygen. (CNS) A4 specification (210X297mm) -------- 4 Pack -------- Order-: ---- ~ ^ (Please read the precautions of Rainbow before filling this page) A7 __B7_____ 5. Description of the invention u) Zinc, iron oxide and talc. Various pigments (such as carbon black or titanium dioxide) can also be added as fillers. Commonly used are fused or precipitated silica and colloidal silica. The precipitated surface-treated calcium carbonate is used as a semi-reinforcing filler, and the ground calcium carbonate (treated or untreated) is used as a supplemental filler. The composition of the present invention is used as a foaming accelerator, an anti-caking agent, a waterproofing agent, an antifouling agent, an anti-foaming agent, a surfactant, a fiber treating agent, a protective coating, and a slip aid. In the following examples, the so-called "polyethylene glycol 400-acrylate" represents an acrylated polyether whose structure is CH2 = CHC (0) 0 (C2H40) 8H (Mw = 512_6); the so-called " "Polypropylene glycol 400-propionate" represents an acrylated polyether whose structure is CH2 = CHC (0) 0 (C3H60) 5H (Mw = 362.5); the so-called "polyethylene glycol 540-acrylate" Represents an acrylated polyether whose structure is CHfCHC ^ COCKC ^ KUC ^ nCHs (Mw = 541); the so-called "polyethylene glycol 1000-acrylate" represents its structure is CH2 = CHC (O) O (C2H4O ) 20H (Mw = 952) acrylated polyether; the so-called " polyethylene glycol 2000-acrylate " represents that its structure is CH2 = CHC (0) 0 (C2H40) 43H (Mw = 1964) Acrylated polyether. Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the note on the back before filling this page) The viscosity in the example is at 23 ° C. Use Brookfield Digital Viscometer, Model DC-II, with No. 3 shaft at 60 rp_m The equipment used was determined from Brookfield Engineering Laboratories, Stoughton, MA. Example 1M'DmM '+ PEG 400 will (NH2CH2CH2CH2) Me2SiO (SiMe20) t93SiMe2 (CH2CH2CH2NH2) (19.43 g, 1.33 mmol) and polyethylene glycol. 400—Acrylic (0.57g, -11-This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X 297mm>) No. 86117226 Patent Application Chinese Specification Correction Page (October 87)) V. Invention Note (9) L33 millimoles is weighed into a 8.5 ml vial. This solution is stirred for 1 hour with a magnetic dispenser and a searcher. The final substance is a misty 'white liquid whose viscosity in m is 1660 mPa s (cp). Example 2 MD3D " M + PEG 400 Me3Si〇 (SiMe20) 3 {NH2CH2CH2NHCH2CH (CH3) CH2)

MeSiOhSiMedl (0.1 g, 10.0 mmol) and polyethylene glycol 400-acrylic acid vinegar (10.25 g, 20.0 mmol) were weighed into 18.5.ml vials. This solution was stirred with a magnetic stirrer and a stir bar for 1 hour. The final substance was a transparent, yellow liquid with a viscosity of 925 mPa_s (cp) at 23 ° C. Example 4 M, D1f) D% M '+ PPG 400 Me3SiO (SiMe2O) 10 {NH2CH2CH2NHCH2CH (CH3) CH2) 1 \ ^ 5 丨 〇} 25 丨 1 ^ 3 (8.55 g, 5.00 mmol) and polypropylene glycol 400-acrylate (7.25 g, 20.0 mmol) was weighed into a 18.5 ml vial. This solution was stirred with a magnetic stirrer and a stirrer for 1 hour. The final substance is a transparent liquid with a viscosity of 752 mPa.s (cp) at 23 ° C. Example 5 MDsM'M + PEG 2000 Me3SiO (SiMe20) 3 (NH2CH2CH2NHCH2CH (CH3) CH2)

MeSiO} | SiMe3 (10.16 g, 10.00 mmol) and polyethylene glycol 2000-acrylate (26.97 g, 10.0 mmol) were weighed into 18.5 ml vials. This solution ^ Binding ----- 1 (Please read the notes on the back cylinder first and then fill out this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs -12- This paper applies the Chinese National Standard (CNS) A4 Specifications (2 丨 0X297 mm) A7 --___ B7_ printed by the Consumer Cooperatives of the Central Associated Bureau of the Ministry of Economic Affairs 5. Description of the invention (10); stir with a magnetic stirrer and stirrer for 1 hour at night. The final material is soil at room temperature. Duplicate 1MD100D'M + PPG 400 Me3SiO (SiMe2O) 100 {NH2CH2CH2CH2) MeSiO}, SiMe3 (17.12 g, 2.23 mmol) and polypropylene glycol 400-acrylate (2.18 g, 6.14 mmol) Weigh into a 18.5 ml vial. This solution was stirred with a magnetic stirrer and a stirrer for 1 hour. The final substance was a misty liquid with a viscosity of 6810 mPa.s (cp) at 23eC. f Example 7 M'D10M '+ PPG 400 + PEG 400 (NΗ2 (: Η2 (: Η2ΝΗ <: Η20: Η ((: Η3) (: Η2) Μ @ ίΟ (5ίΜε2Ο) 10 3 ^^ 2 ((: 112 (: 112 (: 1 ^: ^ 11 <: 112 (: 1121 ^ 112) (6.76 g, 6.49 mmol) and polypropylene glycol 400-acrylate (2.34 g, 6.46 mmol) and polyethylene Diol 400-propionate (3.31 g, 6.46 mmol) was weighed into a 18.5 ml vial. This solution was stirred with a magnetic stirrer and stirrer for 1 hour. The final substance was a transparent liquid with a viscosity of 23 ° C It is 1660 mPa.s (cp). Example 8 MDiooM + PPG 400 + PEG 400 MesSiCKSiMeAhooKNi ^ CE ^ Ci ^ CHdMeSiOhSiMe; (5.00 g, 0.645 mmol), polypropylene glycol 400—acrylate (2.16 g, 5.97 Mmol) and polyethylene glycol 400-acrylate (3.06 g, 5.98 mmol) were weighed into 18.5 ml vials. This solution was stirred with a magnetic stirrer and stirrer for 1 hour. The final substance was a transparent liquid, which was The viscosity at 23 ° C is 1580 mPa.s (cp) 0 Example 9 D% + PPG 400 will be (OSiMeCH2CHMeCH2NH (CH2) 2NH2) 4 (6.96 g, 10 millimolar) -13- This paper is for China Standard (CNS) A4 Grid (210X297 mm) H ---: 11 1: iinn -inn an-. Ding 1 I..: ______ I. (0¾, v '口 一 I (Please read the note on the back of the issue # -fill in (This page) Printed A7 by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs _____B7 V. Description of the invention (11) ~ —— Yiwa Polypropylene Glycol 400-propionate (3.62 g, 10 mmol) weighed into a 18 5 ml vial The solution was stirred with a magnetic stirrer and a stirrer for 1 hour. The final substance was a transparent fluid with a viscosity of 7530 mpa.s (cp) at 23 ° C. Example 10 Ethoxylated nonylphenol propionate ^ (NH2CH2CH2NHCH2CH (CH3) CH2) Me2SiO (SiMe2O) 10

SiMe2 (CH2CH2CH2NHCH2CH2NH2) (10_4 g, 10 mmol) and ethoxylated nonylphenol acrylate (ch2 = chc (o) oc9h19c6h4oc2h5) (4.5 g, 10.0 mmol) were weighed into 18.5 ml vials. This solution was stirred with a magnetic stirrer and stirrer for 1 hour. The final substance was a transparent fluid, with a viscosity of 23 ° (3) which was 116〇111? &Amp; .5 (^). (NH2CH2CH2NHCH2CH (CH3) CH2) Me2SiO (SiMe2O) 10 SiMe2 (CH2CH2CH2NHCH2CH2NH2) (7 g, 6.72 millimeter Mol) and ethoxylated nonylphenol propionate (ch2 = chc (o) oc9h19c6h4oc2h5) (6.6 g '14.67 mmol) were weighed into a 18.5 ml vial. This solution was stirred with a magnetic stirrer and stirrer 1 The final substance is a transparent fluid with a viscosity of 1240 mPa.s (cp) at 23 ° C. Example 1 13 Thirteen-Carbonyl Acetylpropionate (NH2CH2CH2NHCH2CH (CH3) CH2) Me2SiO (SiMe2O) 10 511 ^ 2 ((: 112 (: 112 (: 11 " 11 (: 112 (: 1121 ^ 2) (10.49 g, 10.07 mmol)) and tridecyl acrylate (CH2 $ HC (0) 0 ( CH2) 12CH3) (2.5 g, 9.84 mmol) was weighed into an 8.5 ml vial. This solution was stirred with a magnetic stirrer and stirrer for 1 hour. The final substance was a transparent fluid with a viscosity of 220 mPa at 23 ° C .s (cp). Put (NH2CH2CH2NHCH2CH (CH3) CH2) Me2SiO (SiMe2O) 10 -14- This paper size applies to China National Standard (CNS) 8-4 (2 丨 0 X 297 mm) C Please read the first Note for this page, please fill in this page) Order A7 B7 V. Description of invention (12)

SiMe2 (CH2CH2CH2NHCH2CH2NH2) (10.49 g, 10.07 mmol) and tridecyl acrylate (CH2 = CHC (0) 0 (CH2) 12CH3) (5.00 g '19.7 mmol) are weighed into 18.5 ml vials in. This solution was stirred with a magnetic stirrer and a stirrer for 1 hour. The final substance is a transparent fluid with a viscosity of 200 mPa.s (cp) at 23 ° C. Example 1 2 Caprolactam acrylate (NH2CH2CH2NHCH2CH (CH3) CH2) Me2SiO (SiMe2〇) I0 51 62 ((: 112 (^ 2 (^ 2; ^ 11〇12 (: 11 to 112) (8.00 g , 7.68 mmol) and caprolactam propionate (ch2 = chc (o) o (ch2) 2 (oc (o) (ch2) 5o)) 2h (5 _ 2 3 g, 15 _ 2 mol ) Weigh 18.5 ml I into the bottle. This solution was stirred with a magnetic stirrer and stirrer for 1 hour. The final substance was a transparent fluid with a viscosity of 200 mPa. S (cp) at 23 C. Example 1 3 Lauryl Propionate (NH2CH2CH2NHCH2CH (CH3) CH2) Me2SiO (SiMe2O) 10 SiMe2 (CH2CH2CH2NHCH2CH2NH2) (8.00 g, 7.68 mmol) and lauryl acrylate (CH2 = CHC (0) 0 (CH2) uCH3) (1.85 G, 7.70 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs ----------- '' pack-- (Please read the precautions on the back before filling this page} Millimoles) Weigh 18.5 ml In a vial. This solution was stirred with a magnetic stirrer and a stirrer for 1 hour. The final substance was a transparent fluid with a viscosity of 190 mPa.s (cp) at 23 ° C. (NH2CH2CH2NHCH2CH (CH3) CH2) Me2SiO (SiMe2 〇) 10 SiMe2 (CH2CH2CH2NHCH2CH2NH2) (7.00 g, 6.72 mmol) And lauryl acrylate (3.23 g, 13.45 mmol) were weighed into an 8.5 ml vial. This solution was stirred with a magnetic stirrer and stirrer for 1 hour. The final substance was a transparent fluid with a viscosity of 150 at 23 ° C mPa.s (cp). -15- This paper size applies to the Chinese National Standard (CNS) A4 (210X297 mm). 5. Description of the invention (13 A7 B7 Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (NH2CH2CH2NHCH2CH ( CH3) CH2) Me2SiO (SiMe2〇) 10 SiMe2 (CH2CH2CH2NHCH2CH2NH2) (7.00 g, 6.72 mmol) and lauryl acrylate (6.46 g, 26.92 mmol) are weighed into a 18.5 ml vial. This solution is magnetically stirred Stir with a stirrer for 1 hour. The final substance is a transparent fluid with a viscosity of 60 mPa.s (cp) at 23C. (NH2CH2CH2NHCH2CH (CH3) CH2) Me2SiO (SiMe2〇) 10 SiMe2 (CH2CH2CH2NHCH2CH2NH2) (6 g, 5.76 Millimoles) and lauryl acrylate (8.31 g, 34.63 millimoles) were weighed into 18.5 ml vials. This solution was stirred with a magnetic stirrer and a stirrer for 1 hour. The final substance is a transparent fluid with a viscosity of 210 mPa.s (cp) at 23 ° C. f ίΗ 1 4 MD3D " M + PEG 400 Me3SiO (SiMe20) 3 {(NH2CH2CH2NHCH2CH (CH3) CH2) MeSiOhSiMes (5.60 g, 5.51 mmol) and polyethylene glycol 400-propylene 1¾ • vinegar (5.40 g '10.54 Millimoles) were weighed into 18.5 ml vials. This solution was stirred for 1 hour with a magnetic stirrer and a stirrer. The final substance is a transparent yellow liquid 'whose viscosity at 23C is 760 mPa.s (cp). Example 1 5 MD, nD ", M Me3SiO (SiMe2O) 10 {(NH2CH2CH2NHCH2CH (CH3) CH2) -MeSiO} 2SiMe3 (9.00 g '7.19 mmol,) and polyethylene glycol 400-acrylate (3.89 g, 7.9 Millimoles) were weighed into 18.5 ml vials. This solution was stirred with a magnetic stirrer and stirrer for 1 hour. The final substance was a transparent liquid with a viscosity of 381 mPa.s (cp) at 23 ° C. -16- This paper size is in accordance with Chinese National Standard (CNS) A4 specifications (210X297 mm (please read the notes on the back before filling out this page). Binding j Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 _____B7 V. Description of the invention (14) Me3SiO (SiMe2O) 10 {(NH2CH2CH2NHCH2CH (CH3) CH2) ^^ 8 丨 〇} to 3 (6.94 g, 5.54 mmol) and polyethylene glycol 400-propionate ( 6_00 grams, 11.09 millimoles) were weighed into 18_ 5 ml vials. The solution was stirred with a magnetic stirrer and stirrer for 1 hour. The final substance was a turbid liquid whose viscosity at 23 C was 651 mPa.s (cp). Me3SiO (SiMe2O) 10 {(NH2CH2CH2NHCH2CH (CH3) CH2) -1 ^ 8 丨 〇} with 1 ^ 3 (4.15 g, 3.31 mmol) and polyethylene glycol 400-propionate (8.0 g , 15.62 mmol) into a 18.5 ml vial. The solution was stirred with a magnetic stirrer and a stirrer for 1 h! The final substance was a transparent liquid with a viscosity of 551 mPa.s (cp) at 23 C. f 1 6 M " Di〇M " + PEG 400 will be (NH2CH2CH2NHCH2CH (CH3) CH2) Me2SiO (SiMe2O) 10 SiMe2 (CH2CH2CH2NHCH2CH2NH2) (5.78 g, 5.55 mmol) and polypropylene 400—Acrylic ester (6-00 g, 16.57 mmol) was weighed into a 18.5 ml vial. This solution was stirred with a magnetic stirrer and a stirrer for one hour. The final substance was a transparent liquid with a viscosity of 1310 mPa at 23 ° C .s (cp). t ίΗ 1 7 MD10〇DnM + PEG 400 Me3SiO (SiMe2O) 100 {(NH2CH2CH2NHCH2CH (CH3) CH2) -MeSiOhSiMes (14.35 g, 1.85 mmol) and polyethylene glycol 400-acrylate (1.00 g, 1.85 mmol) was weighed into a 18.5 ml vial. This solution was stirred with a magnetic stirrer and a stirrer for 1 hour. The final substance was a turbid liquid. The __-17-_ Housekeeping (CNS) 纟 4 Secrets (21GX297mm) '~~' ~~~ I --------- 'Binding-^ ---- J.. (Please read the notes on the back first (Fill in this page again) Printed by A7 B7, Shellfish Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs 5. Description of the invention (15) The viscosity at 23 C is 190 mPa.s (cp). Example 1 8 MDinnD 丨 M + PEG 2000 Me3SiO (SiMe2〇) 1 () 0 {(NH2CH2CH2CH2) MeSiO} 1SiMe3 (7.69 g, 1.0 mmol) and polyethylene glycol 2 000-acrylate (2.70 g, 1 _〇〇mol) were weighed in 18.5 Ml vial. This solution was stirred with a magnetic stirrer and a stirrer for 1 hour. The final substance is a solid wax. Weigh Me3SiO (SiMe2O) 100 {[[NH2CH2CH2CH2) MeSiO} 1SiMe3 (7.69 g, 1.0 mmol) and polyethylene glycol 2000—acrylate (ι · 84 g, 0.88 mmol) into a 18.5 ml vial . This solution was stirred with a magnetic stirrer and sandalwood for 1 hour. The final substance is a solid wax. Example 1 9 MDmnDf'M + PEG 2000, PEG 1000 will be MejiCKSiMeAh. . Milk H2CH2CH2NHCH2CH (CH3) CH2)

MeSiOhSiMe ^ M grams, 1.0 millimoles), polyethylene glycol 2000-acrylate (2.70 grams, 1.0 millimoles) were weighed into 18.5 ml vials. This solution was stirred with a magnetic stirrer and a stirrer for 1 hour. The final material was solid. Weigh Me3SiO (SiMe2O) 100 {(^ H2CH2CH2NHCH2CH (CH3) CH2) -MeSiO} 3SiMe3 (7.75 g, 1.0 mmol) and polyethylene glycol 1000-propionate (1.84 g, 1.0 mmol) into 18.5 ml vial. This solution was stirred with a magnetic stirrer and a stirrer for 1 hour. The final substance is solid wax. T iH 2 0 MDjoD '^ M + PEG 2000 and PEG 1000 Me3SiO (SiMe2O) 10 {(NH2CH2CH2NHCH2CH (CH3) CH2) -MeSiO} 2SiMe3 (2-50 grams, 2.00 millimoles) and polyethylene Diol 2000-acrylate (5.40 g · '2.00 mmol) was weighed into a 18.5 ml vial. This solution was stirred for 1 hour with a magnetic stirrer and a stirrer. The final substance is a solid state domain. ----------- 「Install ------ Order ------ ^ (Please read-# 面 之 fit 意 事 # 'Fill in this page) -18-

Printed by A7 _____B7 of the Central Bureau of Standards, Ministry of Economic Affairs, B7 V. Invention Description (16) Me3SiO (SiMe2O) 10 {(NH2CH2CH2NHCH2CH (CH3) CH2) _ 1 ^ 8 丨 〇} 2811 ^ 3 (3.50 g, 2_80 milli Mol) and polyethylene glycol 1000-propionate (5.15 g, 2.8 mmol) were weighed into 18.5 ml vials. This solution was stirred with a magnetic stirrer and a stirrer for 1 hour. The final substance is a solid wax. Example 21 lyrDmlvT + PEG 2000 (NH2CH2CH2NHCH2CH (CH3) CH2) Me2SiO (SiMe 〇) 10 SiMe2 (CH2CH2CH2NHCH2CH2NH2) (2.5 g, 2.40 mmol) and polyethylene glycol 2000-acrylate (6.19 g, 2.30 mmol Mol) into a 18.5 ml vial. This solution was stirred with a magnetic stirrer and a stirrer for 1 hour. The final substance is a solid wax. Weigh (NH2CH2CH2NHCH2CH (CH3) CH2) Me2SiO (SiMe 〇) 10 SiMe2 (CH2CH2CH2NHCH2CH2NH2) (3.0 g, 2.88 mmol) and polyethylene glycol 2000-acrylate (5.06 g, 1.88 mmol) into a 18.5 ml vial in. This solution was stirred with a magnetic stirrer and a stirrer for 1 hour. The final substance is a solid snail ^. Example 2 2 MD3D " iM + TFPMA Me3Si (SiMe20) 3 {(NH2CH2CH2NHCH3CH (CH3) CH2)] ^ 31〇} 1811 ^ 3 (10.16 g, 10.0 mmol) and 2,2,3,3-tetrafluoro Propyl acrylate (1:86 g, 10.0 mmol) was weighed into a 18.5 ml vial. This solution was stirred with a magnetic stirrer and a stirrer for 1 hour. The final substance is a transparent, low viscosity fluid. Example 2 3 MD10D " 2M + TFPMA Me3Si (SiMe2O) 10 {(NH2CH2CH2NHCH3CH (CH3) CH2) MeSiO} 2 SiMe3 (12_51 g, 10.0 mmol) and 2,2,3,3-tetrafluoropropyl-19 -This paper size is suitable for wealth management (CNS) A4 specification (2 丨 GX297 mm) ~ --------- 『-Packing ------ Order --- ^ ---- J .VJC (please read the note on the back to fill in this page). The printed version of the Chinese manual for the patent application No. 86117226 printed by the Employees' Cooperatives of the Central Government Bureau of the Ministry of Economic Affairs (October S7) 5. Description of the invention (17 ) Acrylate (3.72 g, 20.0 mmol) was weighed into 18 5 ml vials. This solution was stirred with a magnetic stirrer and a stirrer for 1 hour. The final substance is a transparent, low viscosity fluid.

Example 24 M " D10M " + TFPMA will be (NH2CH2CH2NHCH2CH (CH3) CH2) Me2SiO (SiMe2- (CH2CH2CH2NHCH2CH2NH2) (10.41 g, lo.o millimoles) and 2,2,3,3 -tetrafluoropropyl acrylate ( 3.72 g, 20.0 mmol) were weighed into a 18.5 ml vial. This solution was stirred with a magnetic stirrer and a stirrer for 1 hour. The final substance was a transparent low viscosity fluid. Comparative Example 1 MD96D " 2M + TMPTA Me3Si (SiMe20) 96 ((NH2CH2CH2NHCH3CH (CH3) CH2)

MeSiOh-SiMe3 (10.0 g) and trimethylolpropane triacrylate (SartomerTM 351) (1.0 g) were weighed into 18.5 ml vials. This solution was stirred for 2 minutes (until homogeneous) 'and poured into a weighing pan to a thickness of 3.35 mm (132 mils). The time required for the material to form a cured surface (S0T or surface coverage time) and the time required for complete gelation (fully cured) on the sample were recorded. The results were 105 minutes and 180 minutes, respectively. The Shore hardness of the obtained glue was measured on a Shore " 00 " hardness tester, and its 値 was 45.

L Dagger Comparative Example 2 MD96D " 2M + HDDA Me3SiO (SiMe2〇) 96 ((NH2CH2CH2NHCH3CH (CH3) CH2)

MeSi0} 2-SiMe3 (10.0 g) and hexanediol diacrylate (Sartomer ™ 238) (1.0 g) were weighed into 18.5 ml vials. This solution was stirred for 2 minutes (until homogeneous) 'and poured into an aluminum weighing pan to a thickness of 3.05 mm (120 mils). Record the time required for this material to form a cured surface on the sample (s0T or surface-covered -20- This paper + National Standard (CNS) A4 specification (210X297 mm) '~ --- I' Λ 1 Order ---(Please read the notes on the back *. Please fill in this page) Revised page of the Chinese specification of Patent Application No. 86117226 (October 87) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 18) time) and the time required for complete gelation (fully cured), the results are 24 hours and 48 hours respectively. The Shore hardness of the resulting glue was measured on a Shore, 〇 " hardness tester, and its 値 was 3. Comparative Example 3 MD96D " 2M + PETA Me3Si (SiMe20) 96 {(NH2CH2CH2NHCH3CH (CH3) CH2) MeSiO} 2-SiMe3 (10.0 g) and dipentaerythritol pentaacrylate (SartomerTM399) (1.0 g) were weighed into a 18.5 ml vial . This solution was stirred for 2 minutes (until it was homogeneous) and poured into an aluminum weighing pan to a thickness of 3.05 mm (120 in ears). The time required for the material to form a cured surface (SOT or surface coverage time) and the time required for complete gelation (complete curing) on the sample were recorded. The results were 75 minutes and 105 minutes, respectively. The Shore hardness of the obtained glue was measured on a Shore " 00 " hardness tester and its 値 was 35. Comparative Example 4 MD96D " 2M + urethane acrylate Me3Si (SiMe20) 96 {(NH2CH2CH2NHCH3CH (CH3) CH2) MeSiOL-SiMe3 (10.0 g) and a hexafunctional aromatic with an acrylated polyol diluent Urethane acrylate (UCB Radcure Ebecryl® resin 220) (1.0 g) was weighed into a 18.5 ml vial. The solution was stirred for 2 minutes (until homogeneous) and poured into an aluminum weighing pan to a thickness of 3 ::! Mm (122 mils). Record the time required for the material to form a cured surface (SOT or surface coverage time) and the time required for complete gelation (complete curing) on the sample. The results are 30 minutes and 60 minutes, respectively. The% 01 ^ hardness of the obtained glue measured at the Shore " 00 "durometer soil, the hardness of which is 4 0. Up to Comparative Example 5 MDq &D; D, M + TMPTA + Diatomite Me3Si (SiMe20) 96 {(NH2CH2CH2NHCH3CH (CH3 ) CH2) -21-(Please read the precautions on the back before filling out this page) Binding. Order-This paper size is applicable to the Chinese family standard (CMS) A4 specification (210X 297 mm) No. S6117226 Chinese patent application Revised page (S7 October 8 milk B7 special fifth, invention description (19

MeSiOh-SiMe3 (10.0 g) and trimethylolpropane triacrylate

Saitomer 351) (1.0 g) and 3.5 g of CeliteTMFP-3 filler were weighed into 18.5 ml vials. Stir this solution; mix for 2 minutes (until homogeneous) and pour into a weighing pan to a thickness of 4_3 mm (170 mils). Record the time required for the material to form a solidified surface (SOT or surface coverage time) and the time required for complete gelation (complete curing) on the sample. The results are 100 minutes and 140 minutes, respectively. The hardness of the 51Oth generation of the obtained glue was measured on a Shore " 00 " hardness tester, and its 値 was 83. Comparative Example 6 MDwD'VM + ΗΓ > ηΛ Me3Si (SiMe20) 96 {(NH2CH2CH2NHCH3CH (CH3) CH2) MeSiO} -SiMe3 (10.0 g) and Hexanediol Dipropionate (SartolinTM238) (2.0 g) were weighed Into a 18.5 ml vial. This solution was stirred for 2 minutes (until uniform) 'and poured into an aluminum weighing pan to a thickness of 3.8 mm (150 mils). Record the time required for the material to form a cured surface (SOT or surface coverage time) and the time required for complete gelation (complete curing) on the sample. The crusts are 48 hours and 48-72 hours, respectively. The Shore hardness of the obtained glue was measured on a Shore " 00 " hard gauge, and its 値 was less than 1, which was a sticky glue. in mn tmv m · tm · 1 nn nil--........》 eJ ^ i ^ n— f-—I (please read the precautions of s' before filling this page) Central Ministry of Economic Affairs Printed by Staff Bureau of Standards Bureau 22- This paper size applies to China National Standard (CNS) A4 (210X 297 mm)

Claims (1)

Patent Application No. 86117226 A8 Chinese Patent Application Amendment (February 88) Stomach 6. Scope of patent application: Top. 1. A composition 'comprising the reaction product (A) of (A) and (B) is at least one polysiloxane, selected from among (i) R3SiO (SiR2〇) xSiR3 or ( ii) (SiR20) rj where the average value is from 1 to 250 and at least 3 R are selected from alkyl and amine functional groups with 4 to 4 carbon atoms, and at least one R on the polysiloxane is amine functional And (B) at least one acrylate of the formula X 2 〇CH2 = CC-0- R -Q η printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs where 'R is Η or CH3, η = 1 and Q is a monovalent hydrocarbon group, or an identical or dissimilar group containing oxetyl, oxetyl, oxetyl, or a combination thereof. 2. The composition according to item 1 of the scope of patent application, wherein the composition further comprises a solvent, and the solvent is selected from the group consisting of water, alcohols, and aliphatic or aromatic solvents. 3. The composition according to item 1 of the scope of patent application, wherein Q is selected from the group consisting of: (i)-(CH2) y (〇CH2CH2) a (〇CH2CHCH3) b [OCH2CH (CH2CH3)] c. R '> (ii)-(CH2) y (〇CH2CH2) aOR', this paper size applies to China National Standard (CNS) A4 specification (21 OX297 mm) II-= ---- 1 I n I order ~~ Send · (Please read the precautions on the back before filling out this page-No. 86117226 Patent Application A8 Chinese Patent Application Amendment (February 88) Stomach 6. Scope of patent application: Top. 1. A composition 'comprising the reaction product (A) of (A) and (B) is at least one polysiloxane, selected from among (i) R3SiO (SiR2〇) xSiR3 or ( ii) (SiR20) rj where the average value is from 1 to 250 and at least 3 R are selected from alkyl and amine functional groups with 4 to 4 carbon atoms, and at least one R on the polysiloxane is amine functional And (B) at least one acrylate of the formula X 2 〇CH2 = CC-0- R -Q η printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs where 'R is Η or CH3, η = 1 and Q is a monovalent hydrocarbon group, or an identical or dissimilar group containing oxetyl, oxetyl, oxetyl, or a combination thereof. 2. The composition according to item 1 of the scope of patent application, wherein the composition further comprises a solvent, and the solvent is selected from the group consisting of water, alcohols, and aliphatic or aromatic solvents. 3. The composition according to item 1 of the scope of patent application, wherein Q is selected from the group consisting of: (i)-(CH2) y (〇CH2CH2) a (〇CH2CHCH3) b [OCH2CH (CH2CH3)] c. R '> (ii)-(CH2) y (〇CH2CH2) aOR', this paper size applies to China National Standard (CNS) A4 specification (21 OX297 mm) II-= ---- 1 I n I order ~~ Send · (Please read the precautions on the back before filling out this page-printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Αδ ν rj '*' Β8 Ο ί J ιώ Ο Ο C8. D8 VI. Patent Application Scope (in )-(CH2) y (OCH2CH2) a (OCH2CHCH3) b〇R '! (Iv)-(CH2) y [OCH2CH (CH2CH3)] cOR' '(vHCH2) y (OCH2CHCH3) b [OCH2CH (CH2CH3)) cOR ', (Vi)-(CH2) y (OCH2CH2) a [OCH2CH (CH2CH3)] cOR', and (vii)-(CH2) y (OCH2CHCH3) bOR ', where R' is a hydrogen atom, having 1 to An alkyl group of 4 carbon atoms, an aromatic group of 6 to 12 carbon atoms, and the integer y is 2-20; a is 1-120; b is .1-50; and c is 1-50. 4. According to The composition in the scope of patent application item 1, wherein the amine functional group is selected from the group consisting of--(i) -CH2CH2CH2NH2, (ii) -CH2CH2CH2N (H) CH2CH2NH2, (iii) -CH2CH2 CH2N (H) CH2CH2N (H) CH2CH2NH2 '(iv) _CH2CH2CH2CH2NH2, (v) -CH2CH2CH2CH2CH2NH2' (vi) -CH2CH2CH2N (H) Me, (vii) -CH2CH2CH2CH2N (H) CH2CH2NMe2, (vm) -CH2CH2N (Ix) -CH2CH (CH3) CH2N (H) CH2CH2NH2 and (x) -CH2CH (CH3) CH2NH2, where Me stands for methyl group and Et stands for ethyl group. -2- This paper standard applies to Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before filling in this tile) Order