TW375624B - Olefin polymers prepared with substituent indenyl containing metal complexes - Google Patents

Olefin polymers prepared with substituent indenyl containing metal complexes

Info

Publication number
TW375624B
TW375624B TW087106781A TW87106781A TW375624B TW 375624 B TW375624 B TW 375624B TW 087106781 A TW087106781 A TW 087106781A TW 87106781 A TW87106781 A TW 87106781A TW 375624 B TW375624 B TW 375624B
Authority
TW
Taiwan
Prior art keywords
group
substituent
hydrocarbyl
olefin
olefin polymers
Prior art date
Application number
TW087106781A
Other languages
Chinese (zh)
Inventor
Lawrence T Kale
Daniel D Vander Lende
Peter N Nickias
Jasson T Patton
James C Stevens
R Parikh Deepak
J Mangold Debra
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of TW375624B publication Critical patent/TW375624B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Abstract

This invention is directed to an olefin polymer produced by polymerizing at least one alpha-olefin in the presence of a group 4 metal complex comprising an indenyl group substituent in the 2 or 3 position with at least one group selected from hydrocarbyl, perfluoro-substituent hydrocarbyl, silyl, germyl and mixtures thereof, said indenyl group further being covalently bonded to the metal by means of a divalent ligand group, wherein the divalent ligand comprises nitrogen or phosphorus having an aliphatic or alicyclic hydrocarbyl group covalently bonded thereto via a primary or secondary carbon. Preferred olefin polymers of the invention will be characterized as having a high molecular weight, narrow molecular weight distribution, high vinyl content, and a bimodal DSC melting curve or a deconvoluted ATREF or GPC curve which shows at least two distinct narrow peaks. The olefin polymer will have utility in a variety of applications, including but not limited to films, fibers, foams, molded parts, and as components of formulations such as adhesives, sealants, coatings, caulks, and asphalt.
TW087106781A 1997-05-01 1998-05-01 Olefin polymers prepared with substituent indenyl containing metal complexes TW375624B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US4541097P 1997-05-01 1997-05-01
US4534897P 1997-05-01 1997-05-01

Publications (1)

Publication Number Publication Date
TW375624B true TW375624B (en) 1999-12-01

Family

ID=26722669

Family Applications (1)

Application Number Title Priority Date Filing Date
TW087106781A TW375624B (en) 1997-05-01 1998-05-01 Olefin polymers prepared with substituent indenyl containing metal complexes

Country Status (14)

Country Link
EP (1) EP0977787A1 (en)
JP (1) JP2001522399A (en)
KR (1) KR20010020425A (en)
CN (1) CN1112383C (en)
AR (1) AR012645A1 (en)
AU (1) AU742617B2 (en)
BR (1) BR9808704A (en)
CA (1) CA2288893A1 (en)
NO (1) NO995294L (en)
PL (1) PL336594A1 (en)
RU (1) RU2200169C2 (en)
TR (1) TR199902884T2 (en)
TW (1) TW375624B (en)
WO (1) WO1998049211A1 (en)

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ATE495205T1 (en) * 1998-11-02 2011-01-15 Dow Global Technologies Inc SHEER-FLUFFILIZABLE ETHYLENE/ALPHA-OLEFIN/DIENE POLYMERS AND THEIR PRODUCTION
JP5133050B2 (en) * 2004-03-17 2013-01-30 ダウ グローバル テクノロジーズ エルエルシー Catalyst composition comprising a shuttling agent for forming an ethylene multiblock copolymer
US7524911B2 (en) 2004-03-17 2009-04-28 Dow Global Technologies Inc. Adhesive and marking compositions made from interpolymers of ethylene/α-olefins
CA2601248A1 (en) 2005-03-17 2006-09-28 Dow Global Technologies Inc. Fibers made from copolymers of propylene/alpha-olefins
AU2006227348A1 (en) * 2005-03-17 2006-09-28 Dow Global Technologies Inc. Adhesive and marking compositions made from interpolymers of ethylene/alpha-olefins
JP5226973B2 (en) 2007-06-15 2013-07-03 三井化学株式会社 Ethylene-based copolymer, composition containing the copolymer, and use thereof
MY180069A (en) * 2010-03-02 2020-11-20 Dow Global Technologies Llc Ethylene-based polymer compositions
JP5574916B2 (en) * 2010-10-26 2014-08-20 三井化学株式会社 Process for producing olefin polymer
CN104703994B (en) * 2013-09-26 2017-05-10 Lg化学株式会社 Transition metal compound, catalyst composition containing same, and method for preparing polymer by using same
WO2015046930A1 (en) 2013-09-26 2015-04-02 주식회사 엘지화학 Catalytic composition and method for preparing polymer including same
US9376519B2 (en) 2013-09-26 2016-06-28 Lg Chem, Ltd. Transition metal compound, catalytic composition including the same, and method for preparing polymer using the same
JP6355733B2 (en) * 2013-10-30 2018-07-11 エルジー・ケム・リミテッド Olefin resin
BR112016018907B1 (en) * 2014-02-28 2021-07-06 Mitsui Chemicals, Inc method for producing a crosslinked product, laminated molded article, ethylene copolymer (a) and ethylene copolymer composition
CN107107025A (en) 2015-01-06 2017-08-29 Scg化学有限公司 SiO2Layered double-hydroxide microballoon and their preparation method
KR102054466B1 (en) * 2015-12-22 2019-12-11 주식회사 엘지화학 Catalystic composition comprising transition metal compound, and for preparing polymers using the same
GB201608384D0 (en) 2016-05-12 2016-06-29 Scg Chemicals Co Ltd Unsymmetrical metallocene catalysts and uses thereof
CN111902467B (en) 2018-02-05 2022-11-11 埃克森美孚化学专利公司 Processability of LLDPE enhanced by addition of ultra high molecular weight high density polyethylene
WO2020235285A1 (en) * 2019-05-17 2020-11-26 株式会社ブリヂストン Multi-component copolymer, rubber composition, resin composition, tire, and resin product

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL8702902A (en) * 1987-04-06 1988-11-01 Stamicarbon ETHENE COPOLYMER.
JPH0777754B2 (en) * 1987-07-07 1995-08-23 三井石油化学工業株式会社 Stretch wrapping film
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5272236A (en) * 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
IT1254474B (en) * 1992-02-28 1995-09-25 Montecatini Tecnologie Srl PROCESS FOR THE PREPARATION OF ETHYLENE ELASTOMERIC COPOLYMERS
EP0705269B1 (en) * 1993-06-24 1997-01-15 The Dow Chemical Company Titanium(ii) or zirconium(ii) complexes and addition polymerization catalysts therefrom
WO1995014024A1 (en) * 1993-11-18 1995-05-26 Idemitsu Kosan Co., Ltd. Transition metal compound, olefin polymerization catalyst, and process for producing olefin polymer by using said catalyst
US5447895A (en) * 1994-03-10 1995-09-05 Northwestern University Sterically shielded diboron-containing metallocene olefin polymerization catalysts
DE19522013A1 (en) * 1995-06-21 1997-01-02 Hoechst Ag Transition metal compound
PL186283B1 (en) * 1995-10-27 2003-12-31 Dow Chemical Co Metal complexes containing substituted indenyl and method of polymerising olefins

Also Published As

Publication number Publication date
CN1258303A (en) 2000-06-28
AU742617B2 (en) 2002-01-10
AR012645A1 (en) 2000-11-08
JP2001522399A (en) 2001-11-13
AU7173998A (en) 1998-11-24
CA2288893A1 (en) 1998-11-05
CN1112383C (en) 2003-06-25
PL336594A1 (en) 2000-07-03
KR20010020425A (en) 2001-03-15
TR199902884T2 (en) 2000-09-21
BR9808704A (en) 2000-07-11
RU2200169C2 (en) 2003-03-10
EP0977787A1 (en) 2000-02-09
NO995294L (en) 1999-12-29
WO1998049211A1 (en) 1998-11-05
NO995294D0 (en) 1999-10-29

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