TW375601B - Toluene disproportionation process containing over 90% single-pass para-xylene and a toluene conversion of at least 15% using a molecular sieve catalyst - Google Patents

Toluene disproportionation process containing over 90% single-pass para-xylene and a toluene conversion of at least 15% using a molecular sieve catalyst

Info

Publication number
TW375601B
TW375601B TW082102633A TW82102633A TW375601B TW 375601 B TW375601 B TW 375601B TW 082102633 A TW082102633 A TW 082102633A TW 82102633 A TW82102633 A TW 82102633A TW 375601 B TW375601 B TW 375601B
Authority
TW
Taiwan
Prior art keywords
toluene
para
xylene
pass
molecular sieve
Prior art date
Application number
TW082102633A
Other languages
Chinese (zh)
Inventor
Clarence Dayton Chang
Paul Gerhard Rodewald Jr
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/939,752 external-priority patent/US5321183A/en
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Application granted granted Critical
Publication of TW375601B publication Critical patent/TW375601B/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

In a process for the selective disproportionation of toluene to para-xylene, single-pass para-xylene product levels of over 90% coupled with a toluene conversion of at least 15% are achieved using a molecular sieve catalyst treated with a silicon-containing compound prior to and/or during at least part of the disproportionation process.
TW082102633A 1992-03-12 1993-04-09 Toluene disproportionation process containing over 90% single-pass para-xylene and a toluene conversion of at least 15% using a molecular sieve catalyst TW375601B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US85010492A 1992-03-12 1992-03-12
US85010592A 1992-03-12 1992-03-12
US07/939,752 US5321183A (en) 1992-03-12 1992-09-02 Process for the regioselective conversion of aromatics to para-disubstituted benzenes

Publications (1)

Publication Number Publication Date
TW375601B true TW375601B (en) 1999-12-01

Family

ID=60654506

Family Applications (1)

Application Number Title Priority Date Filing Date
TW082102633A TW375601B (en) 1992-03-12 1993-04-09 Toluene disproportionation process containing over 90% single-pass para-xylene and a toluene conversion of at least 15% using a molecular sieve catalyst

Country Status (2)

Country Link
KR (2) KR100277544B1 (en)
TW (1) TW375601B (en)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4090981A (en) * 1976-09-23 1978-05-23 Mobile Oil Corporation Catalyst for selective production of para dialkyl substituted benzenes
US4950835A (en) * 1989-10-24 1990-08-21 Taiwan Styrene Monomer Corporation Novel silicon-modified catalyst Si/HZSM-5, it's preparation, and a process for synthesizing high purity p-dialkyl benzene from monoalkyl benzene by using said catalyst

Also Published As

Publication number Publication date
KR950700119A (en) 1995-01-16
KR100277545B1 (en) 2001-01-15
KR100277544B1 (en) 2001-01-15
KR950700227A (en) 1995-01-16

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