TW338034B - Process for the oxidation of hydrocarbons, alcohols of ketones by heterogeneous catalysis - Google Patents

Process for the oxidation of hydrocarbons, alcohols of ketones by heterogeneous catalysis

Info

Publication number
TW338034B
TW338034B TW085104533A TW85104533A TW338034B TW 338034 B TW338034 B TW 338034B TW 085104533 A TW085104533 A TW 085104533A TW 85104533 A TW85104533 A TW 85104533A TW 338034 B TW338034 B TW 338034B
Authority
TW
Taiwan
Prior art keywords
silicates
oxidation
manganese
bar
liquid phase
Prior art date
Application number
TW085104533A
Other languages
Chinese (zh)
Inventor
Costantini Michel
Fache Etic
Gilbert Laurent
Original Assignee
Rhone Poulenc Fibres
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Fibres filed Critical Rhone Poulenc Fibres
Application granted granted Critical
Publication of TW338034B publication Critical patent/TW338034B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/245—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of keto groups or secondary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C55/00—Saturated compounds having more than one carboxyl group bound to acyclic carbon atoms
    • C07C55/02—Dicarboxylic acids
    • C07C55/14—Adipic acid

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A process of oxidation into carboxylic acid, by molecular oxygen or a gas containing the same, of a hydrocarbon, an alcohol or a ketone, in the liquid phase, in an at least partial solvent of the intended carboxylic acid, in the presence of a heterogeneous catalyst containing at least manganese atoms incorporated in the crystal matrix of a molecular sieve under the temperature of between 50 and 200oC and pressure of between 0.1MPa (10 Bar) and 20MPa (200 bar) and with the liquid phase containing a solvent generally chosen from polar protic solvents and polar aprotic solvents, more particularly from carboxylic acids and esters of 3 to 20 carbon atoms and the crystal containing at least manganese atoms incorporated in the crystal matrix chosen from aluminum silicates, boron silicates, iron silicates and gallium silicates among other metal silicates, SAPOs and Pos, with the total weight of the manganese sive varying between 0.1 to 10 thereof.
TW085104533A 1995-04-07 1996-04-16 Process for the oxidation of hydrocarbons, alcohols of ketones by heterogeneous catalysis TW338034B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9504428A FR2732678B1 (en) 1995-04-07 1995-04-07 OXIDATION PROCESS OF HYDROCARBONS, ALCOHOLS OR KETONES BY HETEROGENIC CATALYSIS

Publications (1)

Publication Number Publication Date
TW338034B true TW338034B (en) 1998-08-11

Family

ID=9478065

Family Applications (1)

Application Number Title Priority Date Filing Date
TW085104533A TW338034B (en) 1995-04-07 1996-04-16 Process for the oxidation of hydrocarbons, alcohols of ketones by heterogeneous catalysis

Country Status (14)

Country Link
EP (1) EP0819110A1 (en)
JP (1) JPH10505867A (en)
KR (1) KR19980703703A (en)
CN (1) CN1183760A (en)
AR (1) AR001504A1 (en)
BR (1) BR9604863A (en)
CA (1) CA2215472A1 (en)
CZ (1) CZ313797A3 (en)
FR (1) FR2732678B1 (en)
MX (1) MX9707721A (en)
PL (1) PL322658A1 (en)
SK (1) SK134097A3 (en)
TW (1) TW338034B (en)
WO (1) WO1996031455A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013204119A1 (en) 2013-03-11 2014-09-11 Ke-Min Lin Window-blind arrangement and associated string guide device

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1142858B1 (en) * 1998-12-22 2005-03-09 Mitsubishi Chemical Corporation Process for producing aliphatic aldehydic acid and/or aliphatic dicarboxylic acid
KR20010101783A (en) * 1999-02-04 2001-11-14 추후보정 Oxidanon of hydrocarbons to acids in the presence of fluoro compounds
FR2791667B1 (en) * 1999-03-30 2002-05-24 Rhone Poulenc Fibres PROCESS FOR THE OXIDATION OF HYDROCARBONS, ALCOHOLS AND / OR KETONES
FR2806079B1 (en) * 2000-03-08 2003-03-14 Rhodia Polyamide Intermediates PROCESS FOR THE OXIDATION OF ACID HYDROCARBONS
FR2806078B1 (en) * 2000-03-08 2004-01-30 Rhodia Polyamide Intermediates PROCESS FOR THE OXIDATION OF ACID HYDROCARBONS
FR2828194B1 (en) * 2001-08-03 2004-03-19 Rhodia Polyamide Intermediates PROCESS FOR THE OXIDATION OF ACID HYDROCARBONS
US7358401B2 (en) 2005-03-31 2008-04-15 Sumitomo Chemical Company, Limited Method for manufacturing cycloalkanol and/or cycloalkanone
JP5136017B2 (en) 2007-11-21 2013-02-06 住友化学株式会社 Process for producing cycloalkanol and / or cycloalkanone
US8212099B2 (en) * 2009-11-05 2012-07-03 Chevron U.S.A. Inc. N-paraffin selective hydroconversion process using borosilicate ZSM-48 molecular sieves
CN102452872B (en) * 2010-10-29 2014-08-20 中国石油化工股份有限公司 Reaction method for catalyzing cyclic ketone by total silicone molecular sieve
CN105646223B (en) * 2014-12-04 2017-12-26 中国科学院大连化学物理研究所 A kind of method that levulic acid catalysis oxidation esterification prepares succinate
CN108863758B (en) * 2018-08-06 2021-10-22 杭州紫乘生物科技有限公司 Method for preparing 5-hexenoic acid
CN112961048B (en) * 2021-02-08 2022-10-18 中国石油大学(华东) Technological method for co-producing K.A. oil and adipic acid by one-step method

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3529020A (en) * 1965-08-16 1970-09-15 Mobil Oil Corp Oxidation processes employing aluminosilicate catalysts and an initiator

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013204119A1 (en) 2013-03-11 2014-09-11 Ke-Min Lin Window-blind arrangement and associated string guide device

Also Published As

Publication number Publication date
CN1183760A (en) 1998-06-03
EP0819110A1 (en) 1998-01-21
WO1996031455A1 (en) 1996-10-10
MX9707721A (en) 1997-12-31
CZ313797A3 (en) 1998-03-18
JPH10505867A (en) 1998-06-09
BR9604863A (en) 1998-05-26
FR2732678B1 (en) 1997-05-23
KR19980703703A (en) 1998-12-05
AR001504A1 (en) 1997-10-22
FR2732678A1 (en) 1996-10-11
PL322658A1 (en) 1998-02-16
CA2215472A1 (en) 1996-10-10
SK134097A3 (en) 1998-02-04

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