TW322408B - - Google Patents

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TW322408B
TW322408B TW084113671A TW84113671A TW322408B TW 322408 B TW322408 B TW 322408B TW 084113671 A TW084113671 A TW 084113671A TW 84113671 A TW84113671 A TW 84113671A TW 322408 B TW322408 B TW 322408B
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Taiwan
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acid
aromatic
polyurea
item
urethane
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TW084113671A
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Chinese (zh)
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Ihara Chemical Ind Co
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    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B1/00Constructional features of ropes or cables
    • D07B1/16Ropes or cables with an enveloping sheathing or inlays of rubber or plastics

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  • Ropes Or Cables (AREA)
  • Mechanical Means For Catching Fish (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Description

經濟部中央橾準局貝工消費合作社印製 322408 Α7 Β7 五、發明説明(/ ) 本發明係有闞遠洋漁業或沿岸漁業所用的延钃漁法用 鑭索。 (先行技術) 自古Μ來,延钃漁法的規横較為大,而使用於适洋贿 漁法用的延索,有時達至100〜150 k·,而在沿岸漁 業使用100 k·者也不烯奇。 做為此種延钃漁法用繩索,以往均使用維尼龍,特多 龍,尼籯等維維或在IV索上配置具有羽毛纖維的两索,或 將瀝育含侵於钃索上的延钃漁法用钃索。 然而,上述先行例的維尼龍等維維或配置钃維絲的钃 索,將幹绷以播緬機加Μ揚钃時,幹钃經常擦至船»或揚 _檐而在操作中受損,或钧到多數鮪魚等較大魚Μ負荷高 於播钃檐時,產生甚大的磨耗而幹》會切賺等問鼷。為了 解決此種問豔,亦被用含侵瀝青的延钃漁法用緬索,但瀝 青經常滲出而粘着之故作業上有許多問題,且做為延_漁 法用颺索,其射磨耗性也嫌有不夠。 延繩漁法用钃索自身之性狀,為了順利Μ揚I«機加Μ 櫬颺後捲回於狭窄的甲板上,被要求有柔软性且復原力為 弱。因此,由上述的製造法所得的高強度緬索,在播钃後 捲回於甲板上時,颺索雞成為輪瑁狀而繩索經常打结,實 雞用做在狭窄甲板上所作業的延_漁法用钃索。 (本發明《要) 本發明之目的係解決Μ往所用糴索的各種問鼷,而提 供一種具有優異作乘性及射磨耗性的延钃漁法用典索。 本紙張尺度適用中國國家揉準(CNS ) Α4規格(210X297公釐) (請先閲讀背面之注意事項再4'爲本頁) 裝· ’訂 322408 Α7 Β7 五、發明説明(L) 亦即,本發明延糴漁法用钃索之特微,乃如下述(1) 項至(7)項所述。 (1) 為了賦予射磨性及柔軟而弱復原力於钃索,將硬化時 之硬度為蕭氏470〜D80之合成樹胞,含浸於钃索, 而該合成樹脂,係邐自聚尿素(尿烷)榭脂及聚尿烷樹 B6者。 (2) 上述聚尿素(尿烷)樹脂係由下示一般式(1)所代表之 胺化合物或由該胺化合物及芳香族聚肢所成的胺成分 ,與將異睛酸釀與多元酵加Μ反應所得的末纗具有異 睛酸醮基的預聚物及由聚異睛酸_所成的異睛酸_成 分,加Μ反應而成的聚尿索(尿烷)彌性«者。 (請先聞讀背面之注意事項再填寫,本頁), ”裝-Printed by Beigong Consumer Cooperative of Central Central Bureau of Economic Affairs 322408 Α7 Β7 V. Description of the invention (/) The present invention is a lanthanum cable for the Yantian fishing method used by Kan Yuanyang Fisheries or coastal fisheries. (Prior technology) Since ancient times, the regulations of the Yanyang Fishing Law are relatively large, and the Yansuo used in the foreign bribery fishing method sometimes reaches 100 to 150 k ·, and those who use 100 k · in coastal fisheries are not Enqi. As this kind of rope for fishing method of Yanyan, in the past, vinylon, Tedron, Niwei and other Weiwei were used or two cables with feather fibers were arranged on the IV cable, or the extension of the extension cable on the cable was included. The fishing method uses a strontium cable. However, when the above-mentioned precedents, such as vinylon and other dimensions, or the cords equipped with tritons, dry stems are added to the Burma machine with Μ 扬 钃, the dry ions are often rubbed to the ship »or yang_ eaves and damaged in operation. Or, when the load of most large tuna and other large fish is higher than that of the sowed eaves, there will be a lot of wear and dry "will be asked. In order to solve this kind of problem, it has also been used the Yanso fishing method with intruding bitumen, but the asphalt often oozes and sticks. There are many problems in the operation, and as Yan_fishing method Yansuo, its jet wearability is also Not enough. The longline fishing method uses the properties of the scorpion itself. In order to smooth it and roll it back on a narrow deck, it is required to have flexibility and weak resilience. Therefore, when the high-strength Burmese rope obtained by the above-mentioned manufacturing method is rolled back on the deck after sowing, the yanshen chicken becomes wheel-shaped and the rope is often knotted. The real chicken is used as an extension for working on narrow decks. _The fishing method uses scorpion. (The main point of the present invention) The purpose of the present invention is to solve the various problems of the Mian cable used, and to provide a code for Yanyan fishing method with excellent operating performance and jet wearability. The size of this paper is applicable to China National Standard (CNS) Α4 specifications (210X297mm) (please read the notes on the back first and then 4 'for this page). Packing and ordering 322408 Α7 Β7 V. Description of invention (L) that is, The special features of the thorium used in the Yanbian fishing method of the present invention are as described in the following items (1) to (7). (1) In order to impart abrasiveness, softness, and weak resilience to the cord, synthetic tree cells with a hardness of 470 to D80 during hardening are impregnated with cord, and the synthetic resin is derived from polyurea ( Urethane) resin and polyurethane B6. (2) The above polyurea (urethane) resin is composed of the amine compound represented by the general formula (1) shown below or the amine component formed by the amine compound and the aromatic polymer, and the isobaric acid brewing and multi-enzyme The prepolymer with an isocyanate group obtained from the addition of M reaction and the isocyanic acid component formed by polyisocyanic acid_, the polyurea (urethane) produced by the addition of M reaction . (Please read the precautions on the back before filling in, this page), ”Pack-

,ΤΓ 經濟部中央橾準局貝工消費合作社印製 (式中,Α為氧原子或含有亞氟基且可含有平均分子量200 以上之不飽和结合的聚烷攆,聚烷撐醚或聚烷撐聚醣。· 為1〜3的整數,η為2〜4的整數,X為平均值而代表0 〜0 · 4的數)。 (3)又,上述芳香族聚胺,係使用選自二氨基二苯基甲烷 糸的芳香族二胺,含有氣原子或疏黄原子的芳番族二 胺,氨基苯酸《系的芳香族二肢,甲苯二胺系的芳香 族二胺,二《基二苯基丙烷系的芳香族二胺,及芳香 本紙張尺度逋用中國國家揉準(CNS > Α4規格(210Χ297公釐〉 經濟部中央揉準局貝工消费合作社印製 A7 _B7_ 五、發明説明(3) 族四胺之1種或其Μ上者。 (4)上逑合成樹脂之含浸作業,係使用Μ隋性有機溶朗作 為1〜5flX溶液或分敗液的合成樹腰所實施者。 (5>上述U)所述之合成樹脂,得使用聚尿素(尿烷)彌性 體。 (6)上述陏性有機溶劑,得使用選自脂肪族嗣,芳番族碳 化氫,非霣子性極性溶劑及脂肪酸醣之1種成其Μ上 者0 (7 )上逑合成樹脂之含侵作業,得在常溫下加Μ資施。 茲,對本發明的延繩漁法用姆索詳细說明如下。 先,對本發明之延鑭漁法用《I索所用的钃索及合成樹 脂加以說明。 本發明的延钃漁法用糴索,係將合成樹脂含浸於颺索 而成,而在本發明中可用的颺索為包括一般延钃漁法用繩 索的天然繼维或合成纖维的钃索。 具鱺而言,天然纖維之»索例,可舉馬尼拉麻或劍麻 的钃索。合成纖維的钃索例,可舉,聚乙烯基,聚胺醣, 聚醮等的钃索,及此等合成纖維與芳香族聚釀胺纖維等之 高強度纖雄的禊合钃维的钃索。 在本發明可使用的合成樹胞,係硬化時具有蕭氏硬度 Α70〜D80,較宜為Α80〜D60的範函内者。合成樹脂的硬 度較Α70低時,射磨耗性不足,但合成樹胞的硬度較D80 高者,則钃索表面會變成醣弱而引起剝落或钃索整變成 無柔软性而造成降低作業性而不宜。 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) (請先閲讀背面之注意事項再填寫,本頁)· :裝· *tr 322408 at Β7 五、發明説明() 在上述硬度範圃內,可簡便達成且由容易調製,及容 易調整硬度,以及可製成具有強性者等覼點而言,聚尿素 (尿烷)樹胞及聚尿烷樹脂,較為宜。 其中,聚尿素(尿烷)樹腊為常溫硬化性,且異Μ酸_ 成分中之異睛酸酗基,比水分及氫氧化基較先與氟基相反 應Μ形成尿素结合,而甚難產生二氧化破瓦斯之故,特為 宜。 Μ下,使用於本發明之延钃漁法用钃索的代表性合成 樹脂,以聚尿素(尿烷)榭脂加以說明。 聚尿素(尿烷)樹脂,係將胺成分與異睛酸醣成分加以 反應者。該胺成分,係由下示一般式(1)所代表之胺化合 物或由一般式(1>所代表的肢化合物及芳香族聚胺所成者。 (請先閲讀背面之注$項再填$頁)· 裝·, ΤΓ Printed by the Beigong Consumer Cooperative of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs (where A is an oxygen atom or a fluorinated group and may contain an unsaturated bonded polyalkylene oxide, polyalkylene ether or polyalkylene with an average molecular weight of 200 or more Polyglycan. · Is an integer of 1 ~ 3, η is an integer of 2 ~ 4, X is an average value and represents a number of 0 ~ 0 · 4). (3) In addition, the above-mentioned aromatic polyamine is an aromatic diamine selected from diaminodiphenylmethane, an aromatic diamine containing a gas atom or a yellow atom, and an aminobenzoic acid-based aromatic Limbs, toluene diamine-based aromatic diamines, bis-diphenylpropane-based aromatic diamines, and aromatic paper standards are calibrated in China (CNS> Α4 specifications (210Χ297mm> Economy A7 _B7_ printed by Beigong Consumer Cooperative of the Ministry of Central Affairs and Customs. V. Description of invention (3) One type of family tetraamine or its M. (4) The impregnation operation of the upper synthetic resin is based on the use of Μ Sui organic solvent Lang is implemented as a synthetic tree waist of 1 ~ 5flX solution or split solution. (5> The synthetic resin described in U) above can be obtained by using polyurea (urethane) dense body. (6) The above-mentioned organic solvent , You can use one selected from the group consisting of aliphatic heirs, aromatic hydrocarbons, non-enzymatic polar solvents and fatty acid sugars to form the infiltrating operation of the above synthetic resin 0 (7), which can be added at room temperature M Zi Shi. Here, the long-line fishing method of the present invention is described in detail with Musuo as follows. First, the extension of the present invention The fishing method is described with "Gonzoline and synthetic resin used in I cable. The Yanchong fishing method of the present invention is made by impregnating the synthetic resin with yanso, and the yanso that can be used in the present invention includes general yano The natural secondary dimension of the rope for fishing method or the cord of synthetic fiber. As for gu, the natural fiber can be exemplified by manila or sisal. The synthetic fiber can be exemplified by polyethylene. Bases, polyamine sugars, polycarbohydrates, etc., and these synthetic fibers and aromatic polybromoamine fibers, etc., high-strength fibrous conjugated metal-dimensional trisodium. In the present invention can be used in synthetic tree cells, When the system is hardened, it has a Shore hardness of A70 ~ D80, preferably within the range of A80 ~ D60. When the hardness of the synthetic resin is lower than that of A70, the abrasion resistance is insufficient, but the hardness of the synthetic tree cell is higher than that of D80. The surface of the cable will become weak and cause flaking or the cord will become non-flexible, which is not suitable for reducing the workability. This paper scale is applicable to the Chinese National Standard (CNS) Α4 specification (210Χ297 mm) (please read the notes on the back first Fill in again, this page):: installed * * tr 3224 08 at Β7 V. Description of the invention () In the above hardness range, it can be easily achieved and is easy to adjust, and the hardness can be easily adjusted, and can be made into strong points, such as polyurea (urethane) tree Cellular and polyurethane resins are more suitable. Among them, polyurea (urethane) wax is hardening at room temperature, and the isocyanic acid in the component of isothioic acid_ is more prevalent than fluorine and water based hydroxide groups. On the contrary, M should form a urea combination, and it is very difficult to produce broken gas dioxide, which is particularly suitable. Under M, the representative synthetic resin of the thorium used in the Yantian fishing method of the present invention is polyurea (urethane). The fat is described. Polyurea (urethane) resin is a compound that reacts an amine component with an isanoic acid sugar component. The amine component is an amine compound represented by the general formula (1) shown below or a general formula (1> gt ; Represented by the limb compound and aromatic polyamine. (Please read the note $ item on the back and then fill in the $ page) · Pack ·

、tT, TT

由上示一般式(1)所代表的化合物,則可例舉聚乙二 - « 經濟部中央揉準局貝工消費合作社印製 酵雙(4-第基苯酸醮),聚乙二酵雙(2-氨基苯酸_>,聚乙 二薄雙(3-氨基苯酸隹),聚四甲二酵雙(4-鑲基苯酸ft), 聚四甲二酵雙(2-氨基苯酸_),聚丙二酵雙(2-«基苯酸 ,聚(氧化乙烯-氧化丙烯)二醉雙(4-氨基苯酸_ ),聚 氧化丁二酵雙(4-氨基苯酸酗),聚四甲二醇雙(3,5-二鎮 基笨酸聚丙烯醚甘油三(4-鑲基苯酸醮),聚丙烯難 本紙張尺度適用中國國家揉準(CNS ) A4規格(210X297公釐) ______B7_ 五、發明説明() 季戊四酵四個(4-氨基笨酸B6),聚氧化乙烯雙(4-氨基苯 鼸胺),聚氧化丙烯雙(3,5-二氨基苯釀胺)等。 此種化合物,其中心部之聚烷攆含有部丨上式(1)中 之A]的平均分子量,為200以上的範園内者。 又,芳番族聚胺,可在其芳香環引進氛原子,烷基, 三氣甲基,烷氧碳基等任意的替代基。 此種芳香族聚胺之例,可舉4,4’-甲叉雙氨苯,4,4’-甲叉雙(2-氯氨笨),4,4’-甲叉雙(2,3-二氯氨苯>(1^0灰)1) 經濟部中夬揉準局貝工消费合作社印裝 (請先閲讀背面之注意事項再填寫,本頁)· ,4,4’-甲叉雙(2,5-二氛氨笨),4,4’·甲叉雙(2-甲基氨 苯),4,4,-甲叉雙(2-乙基氬笨),4,4,-甲叉雙(2-異丙基 氰苯),4,4’-甲叉雙(2,6-二甲基氨笨),4,4,-甲叉雙(2 ,6-二乙基氨苯),4,4’-甲叉雙(2-乙基-6-甲基氬苯),4, 4’-甲叉螫(2-氣-6-甲基氨苯),4,4’-甲叉雙(2-氯-6-乙 基氩苯),4,4’-甲叉雙(3-氣-2,6-二乙基氤笨),4,4,-甲 叉雙(2-三氟甲基氨苯),4,4’-甲叉燮(2-甲氧基羰基鑲苯) 等之二氨基二苯基甲烷糸的芳番族二胺;4,4’-二氛基苯 基醚,4,4’-二氨基-3,3’-二氢二苯基醚,4,4’-二氨基二 苯基磺釀,4,4’-二氨基-3,3*-二氣二苯基確釀,雙(4-氨 基苯氧基苯基 > 磺釀,1,2-雙(2-氰基苯基硫代)乙烷,雙 [2-(2-氨基苯基碓代)乙基]對苯二酸酗等之含有氣原子成 硫黄原子的芳番族二胺;1,3-丙烷二酵(4-«基苯酸_), 1,4-丁烷二酵雙(4-氨基苯酸醮),二乙二酵雙(4-氨基笨 酸_),三乙二酵雙(4-氟基苯酸醮),4-氯-3,5-二氨基苯 酸異丙烯,4-氣-3,5-二氟基笨酸異丁烯等的氨基苯酸醮 -8 - 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 經濟部中央揉準局貝工消费合作社印簟 A7 _B7_ 五、發明説明() 糸芳香族二胺;2,4-甲苯二胺,2,6-甲苯二胺,3,5-二乙 基-2,4-甲苯二胺,3,5-二乙基-2,6-甲苯二胺,3,5-二甲 基疏代-2,4-甲苯二胺,3,5-二甲基疏代-2,6-甲苯二胺等 之甲苯二胺糸的芳香族二胺;2,2-雙(4-氟基苯基)丙烷, 2,2-雙(4-氨基-3-甲基苯基)丙烷,2,2-雙(4-氨基-3-乙 基苯基、丙烷,2,2-雙(4-氛基-3-異丙烯苯基)丙烷,2, 2-雙(4-氨基-3,5-二甲基苯基)丙烷,2,2-雙(4-箱基-3, 5-二乙基苯基)丙烷,2,2-雙(4-氟基-3,5-二異丙烯苯基) 丙烷,2,2-雙(4-«基-3-乙基-5-甲基苯基)丙烷等之二 氨基二笨基丙烷糸的芳番族二胺;3,3’,4,4’-四氣基二苯 基醚,3,3’,4,4’-四氣基二苯基等的芳番族四胺等。 此種芳番族聚胺可單獨使用或2種Μ上併用之。 該芳香族聚胺的比例,依所需要之物理性霣及作樂性 等而不同,但所用胺成分[前示一般式(1)所代表之胺化 合物或一般式(1)所示的胺及芳香族聚胺之混合物]中, 通常為0〜50盧量X,宜為0〜30重量!ϋ,更宜為0〜15重 ft X 〇 該異睛酸_成分,係將聚異睛酸醣與多元酵加以反應 而得的末纗具有異_駿_基的預聚物及聚異臃酸_所成者。 聚異睛酸酷之例,可舉六甲叉二異睛酸醮(HMDI), 2, 2,4-三甲基六甲叉二異睛酸_, 1,3,6-六甲叉三異睛酸醮 ,環己烷二異睛酸_,2,4-二苯乙烯異_酸_(2,4-101), 2,6-二笨乙烯二異 _酸_(2,6-101>, 2,4-TDI 與 2,6-101的混合物,2,4-二苯乙烯二異_酸_之2量臁,苯二 本紙張尺度適用中國國家揉準(CMS ) A4規格(210X297公釐) (請先閲讀背面之注意事項再填寫本頁)·The compound represented by the general formula (1) shown above can be exemplified by polyethylene glycol «Enzyme Bis (4-diphenylbenzoic acid) printed by the Beigong Consumer Cooperative of the Central Ministry of Economic Affairs of the Ministry of Economic Affairs Bis (2-aminobenzoic acid_>, polyethylene dithion bis (3-aminobenzoic acid cymbals), polytetramethylene diacid bis (4-aminobenzoic acid ft), polytetramethylene diacid bis (2- Aminobenzoic acid _), Polypropylene bis (2- «ylbenzoic acid, Poly (ethylene oxide-propylene oxide) bis (4-aminobenzoic acid_)), Polyoxygenated succinyl bis (4-aminobenzoic acid Alcohol), polytetramethylene glycol bis (3,5-dibenzyl stearic acid polypropylene ether glycerol tris (4-inlaidin benzoic acid)), polypropylene hard copy paper size applicable to China National Standard (CNS) A4 specifications (210X297mm) ______B7_ V. Description of the invention () Four pentaerythritol four (4-aminosuccinic acid B6), polyoxyethylene bis (4-aminoaniline), polyoxypropylene bis (3,5-di (Aminobenzylamine) etc. This compound, the polyalkane in the center of which contains the average molecular weight of A] in the above formula (1), is within the range of 200 or more. Also, aromatic polyamines, Atom atoms can be introduced in its aromatic ring Alkyl groups, trimethylol groups, alkoxy carbon groups, and other optional groups. Examples of such aromatic polyamines include 4,4'-methylenebisaminobenzene, 4,4'-methylenebis (2 -Chloramphetamine), 4,4'-Methylene bis (2,3-dichloroaminobenzene > (1 ^ 0 ash) 1) Printed by the Ministry of Economic Affairs, Central Bureau of Industry and Commerce, Beigong Consumer Cooperative (please read first The notes on the back will be filled out again, this page) ·, 4,4'-methylene bis (2,5-dihydrochloride), 4,4 '· methylene bis (2-methylaminobenzene), 4, 4, -methylene bis (2-ethyl argon), 4,4, -methylene bis (2-isopropylcyanobenzene), 4,4'-methylene bis (2,6-dimethylamine Stupid), 4,4, -methylene bis (2,6-diethylaminobenzene), 4,4'-methylene bis (2-ethyl-6-methylhydrobenzene), 4, 4'- Methylene sting (2-gas-6-methylaminobenzene), 4,4'-methylene bis (2-chloro-6-ethylhydrobenzene), 4,4'-methylene bis (3-gas- 2,6-diethyl thiophene), 4,4, -methylene bis (2-trifluoromethylaminobenzene), 4,4'-methylene bis (2-methoxycarbonyl inlaid benzene), etc. Aromatic diamine of diaminodiphenylmethane; 4,4'-diaminophenyl ether, 4,4'-diamino-3,3'-dihydrodiphenyl ether, 4,4 ' -Diamine Diphenyl sulfonate, 4,4'-diamino-3,3 * -difluorodiphenyl, bis (4-aminophenoxyphenyl) sulfo, 1,2-bis (2 -Cyanophenylthio) ethane, bis [2- (2-aminophenylsulfonyl) ethyl] terephthalic acid and other aromatic diamines containing gas atoms to sulfur atoms; 1,3 -Propane diacid fermentation (4- «ylbenzoic acid_), 1,4-butane diacid bis (4-aminobenzoic acid), diethylene diacid bis (4-aminobenzoic acid_), triethylene diacid Aminobenzoic acid bis (4-fluoro-3,5-diaminobenzoic acid), 4-chloro-3,5-diaminobenzoic acid isopropene, 4-gas-3,5-difluoroisobutylene isobutene, etc.-this The paper scale is in accordance with the Chinese National Standard (CNS) A4 specification (210X297mm). The Ministry of Economic Affairs, Central Bureau of Standardization, Beigong Consumer Cooperatives, Indo A7 _B7_ V. Description of invention () Shito aromatic diamine; 2,4-toluenediamine, 2,6-Toluenediamine, 3,5-Diethyl-2,4-Toluenediamine, 3,5-Diethyl-2,6-Toluenediamine, 3,5-Dimethylsulfo- Aromatic diamines of toluenediamine such as 2,4-toluenediamine, 3,5-dimethylsulfo-2,6-toluenediamine; 2,2-bis (4-fluorophenyl) Propane, 2,2-bis (4-amino-3-methylbenzene Group) propane, 2,2-bis (4-amino-3-ethylphenyl, propane, 2,2-bis (4-amino-3-isopropenylphenyl) propane, 2,2-bis (4 -Amino-3,5-dimethylphenyl) propane, 2,2-bis (4-boxyl-3,5-diethylphenyl) propane, 2,2-bis (4-fluoro-3 , 5-diisopropenylphenyl) propane, 2,2-bis (4- «yl-3-ethyl-5-methylphenyl) propane and other diaminodibenzyl propane ; 3,3 ', 4,4'-tetraaminodiphenyl ether, 3,3', 4,4'-tetraaminodiphenyl, etc. Such aromatic polyamines can be used alone or in combination with two kinds of M. The ratio of the aromatic polyamine varies according to the physical properties and performance required, but the amine component used [the amine compound represented by the general formula (1) or the amine represented by the general formula (1) and Aromatic Polyamine Mixture], usually 0 to 50 Lu X, preferably 0 to 30 weight! ϋ, more preferably 0 ~ 15 weight ft X 〇The isocyanic acid_ component is a prepolymer with poly_jun_ group and polyisocyanate which is obtained by reacting polyisocyanic acid sugar with polyvalent enzyme Acid Examples of polyisophthalic acid are cool, such as hexamethylene diisocyanate (HMDI), 2, 2,4-trimethylhexamethylene diisocyanate_, 1,3,6-hexamethylene triisocyanate醮, cyclohexane diisocyanic acid_, 2,4-distyryl iso_acid_ (2,4-101), 2,6-dibenzylethylene diiso_acid_ (2,6-101>, A mixture of 2,4-TDI and 2,6-101, 2,4-stilbene diiso-acid, the amount of 2, the benzene two paper size is applicable to the Chinese national standard (CMS) A4 specification (210X297 mm ) (Please read the precautions on the back before filling this page) ·

經濟部中央標準局貝工消费合作社印装 A7 __B7_ 五、發明説明() , 甲基二異臃酸酗(χρί),僱苯二甲基二異臃酸_(MXDI), 四甲基笨二甲基二異請酸酗,B-苯基二異睛酸4,4’-雙苯基二異睛酸醮,二苯基醚-4,4’-二異睛酸醱,3,3*-二甲苯-4,4’-二異_酸_ (TODI),二甲氧笨基二異睛酸_ (0灰01),4,4’-二苯基甲烷二異臃黢*(»101),液狀“1, 3, 3’-二甲基-4,4’-二苯基甲烷二異睛酸_,1-5-奈二異 _酸_(〇1),三苯基甲烷三異睛酸_(TTI)等在聚尿烷 彌性臞之製造一般所使用的任意聚異睛酸_。 又,做為預聚物,在上述聚異睛酸_中,將由一般式 Ηπ-Α...(2)所表示的多元_,Μ所定量反應而得的兩末 蟠具有異睛酸_基之反應生成物亦可用之。 製備該聚尿素(尿烷)樹脂時的胺成分與異請酸ft成分 之比例,則異睛酸釀基(-NCO)與氨基(-NH2)之莫耳比 (-NC0/-NH2),為通常0.9〜1.5之範園,較宜為1.0〜1.3 之範園就可。 如此所得的聚尿索(尿烷)樹脂,可容易調整為蕭氐 硬度A7 0 K上,D80 Μ下的硬度。又所得的聚尿素(尿烷) 樹脂,一般具有弹性,而含浸於钃索時可充份發揮其性能 之故,癯用於本發明延钃漁法用钃索。 製備上述聚尿素(尿烷)樹脂時,通常是不需要但亦可 用催化劑。做為此種催化耀,宜為可容易溶解於胺成分[ 由前述一般式(1)所代表之胺化合物或該胺化合物與芳香 族聚胺的混合物】者。 此種催化鑲之例,可舉三乙烯二胺,三乙基肢,三丙 -10- 本紙張尺度逋用中國國家梂準(CNS ) 210X297公釐) :---„-------C ii (請先閲讀背面之注$項再填寫於頁) 訂- A7 B7_ 五、發明说明() 基胺,三丁基胺,六甲叉四胺,N-烷基觸啉,N-五甲基二 乙烯三胺,N-六甲基三乙烯三胺,Ν,Ν-二乙基苯胺,N,H-二甲基竽胺,Ν,Ν-二甲基十二胺,二甲胺口啶,》,投-二甲基9嗦,Ν,Ν,Ν’,ΙΤ-四甲叉乙基二胺,》,1),》1’,>1’-四 甲基丙烷二胺,1(),1»’,1}’-四甲基-1,3-丁烷二胺,(1,1),『 ,Ν’-四甲基六甲叉二胺,U,N,N’,Ν’-五甲基二乙烯三胺, 三(二甲基氨基甲基)酚,Ν,Ν’,IT-三(二烷基氟基烷#) 六氫-S-三氪雜苯,1,8-二氪雜環-【5,4,0]-十一碳烯(DBU) ,1,8-二氪雜瓖-[5,4,0]-十一碳烯甲基甲亞确酸銨,等 之第三級胺類及含氰雑化合物等。 又,可使用其他之有拥金羼催化繭,如路易斯酸催化 劑,四-η-丁基錫,三-η-丁基錫釀酸釀,三-η-丁基鋦醱 酸醣,η-丁基錫三氣化物,三甲基錫《氣化物,二甲基錫 二氣化物,二丁基錫二月桂酸二丁基錫二-2-乙基己 酸_,亞鍚辛酸釀等之有檐錫化合物,乙釀丙酮鋅络臞, 經濟部中央梯準局貝工消费合作社印装 (請先聞讀背面之注$項再填寫本頁) 乙釀丙嗣鋁络艚,乙釀丙嗣鈷络艚等之乙鼸丙酮金蹰络髖 ,環烷酸铅,癸酸鉛,環烷酸鈷等之環烷酸金颺鼸,笨基 水銀釀酸_,笨基水銀油酸鹽,苯基水銀辛酸Κ,苯基水 銀奈酸等的有機水銀化合物,辛酸鉛,奈酸鉛等的有 櫬鉛化合物,有拥薩醮之Ml性金屬鹽及有機騮化合物,碳 數2〜12之羧酸練性鹽(釀酸鉀,丙酸鉀,2-乙基己酸鉀, 苯酸納等),碳數13以上之羧酸的金钃_(辛酸納,亞油 酸鉀等),笨酸納赛羧酸Μ外之弱酸_金羼臁等Mt性物質, 甲氣納,笮基三甲基銨氳氧化物,氫化納及氬化钾等鹹金 -11- 本紙張尺度適用中國_家揉準(CNS > A4规格(210X297公釐) 322408 Α7 Β7 五、發明説明() 臈氩化物等強_性物霣,水橇醛與鉀之螯合化合物所代表 的螯合化合物或輔助催化劑(酚類,環氧化物,烷基碳化 物)等。 催化麯可軍獨使用成2種以上併用之#。 使用催化_時,其使用量為100重董份之上述胺成分 [一般式(1)所示的化合物或一般式(1)所示的胺化合物 與芳香族聚胺之混合物〗中佔0.0 1〜5簠量份,較宜為 0 . 05〜3里量份。 又,上述一般式(1)所示的胺化合物,係將一般式 Hn-A...(2>所示的多元酵化合物或末蟠含有氟基多元酵 化合物與η等量之0-, -或P-硝基苯鼸氣,在脫鹽酸繭 之存在下,加以反應而得的硝基化合物,Κ一般方法加以 «原,或一般式(2)所示的多元酵化合物或末斓含有氨基 多元酵化合物,與η等量之靛紅酸脫水物加Κ反應而得。 次,對製造本發明之延»漁法用«索的合成樹脂之含 浸,說明之。 經濟部中央揉準局貝工消费合作社印製 (請先閲讀背面之注意事項再填名本頁)· 使用於製造本發明之延鑷漁法用钃索的合成樹脂,係 Μ陏性有機溶_加以溶解或分散為IX〜5 0Χ溶液,較宜為 10Χ〜4〇χ溶液或分散液者,含侵於钃索。 睹性有機溶爾,可使用脂肪族鼷而可例舉,丙釅,甲 基乙基鬭,二乙基酮,甲基丙基鼷等。又,芳番族碳化氫 也可使用,而可例舉甲苯,二甲苯,乙基苯等。再者,亦 可使用非霣子性極性溶繭,而可例舉二甲基甲釀胺,二甲 基乙釀胺,二甲基亞》等。其他亦可用脂肪酸釀,而可例 -12- 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) 經濟部中央標準局負工消費合作社印装 A7 > B7_ 五、發明説明() 舉_酸乙基_,醵酸甲基_,賂酸甲基K等。 上述溶爾可軍猜使用或二種以上混合使用之。 製備本發明之延繩漁法用繩索所用的合成樹脂溶液或 分散液,以聚尿素(尿烷)樹限為例說明時,例如(1)先準 備晴性有機溶劑,而將上述胺成分及異臃酸_成分一邊攪 拌一邊各別添加,或(2)上述胺成分及異聃酸_成分各別 溶解於陳性有機溶_,而當使用時始將各溶液加以混合, 等可使用任一方法。 次,將合成樹胞含浸於«索Μ製造本發明之延》漁法 用钃索之方法,Μ使用聚尿素(尿烷)樹胞為例說明時,可 舉例如[1】將钃索浸漬於注滿上述聚尿素(尿烷)樹脂之溶 液或分散液的貯槽內,經通所定時間(依條件例如1〜5分 鐘)後拉上«索,去除多餘之聚尿素(尿烷)樹脂Κ獲得延 緬漁法用鑷索的方法(鑲括製造法),或[2]使緬索自始端 Μ所定時間(依條件例如1〜5分鐘)通逢於注滿之聚尿素 (尿烷)樹脂溶液或分數液的貯檐内,然後捲取»索的方法 (連鑛製進法)等。 當製造本發明之延1«漁法用钃索時,將合成樹脂含浸 於»索的合成樹脂含浸量,會大大影響於延嫌漁法用«索 之附磨耗性Μ及整顦性狀。 含浸量,可由钃索與含浸聚尿素(尿烷)樹脂之重置比 所表示的含浸率而代表,亦即,該含浸率則由下示計算式 所求得。 -13- 本紙珉尺度適用中國鬮家椹準(CNS ) A4規格(21〇Χ25>7公釐) (請先閲讀背面之注意事項再填寫,本頁r .装· A7 ____B7_ 五、發明説明() ~ 含浸率=----1 合成樹脂含浸前之每單位長度《索的重量 為了達成本發明目的之較宜含浸率,依所用合成樹脂 或典索之種類,繩索之粗度,Μ及其目的之作槊性等條件 而不同,但例如使用聚尿素(尿烷)樹脂之合成樹脂,維尼 觼钃索(4β·Φ)時,其癯當含浸率為〇.〇1〜0.5,較宜為 0.05〜0.3的範園内。 又,在製造本發明之延_漁法用钃索時,可適當添加 可塑劑,各種填料,氧化防止爾,紫外繚吸收_,著色防 止爾,吸水分解防止謂,防徽_,阻嫌;»,著色_,增量 繭等。 (本發明效果) 本發明之延颺漁法用«索,其射磨耗性甚優異之故, 可長期間使用之。又纗索整體的性狀,可維持比以往所用 的钃索同等或其Μ上的柔軟性,而可容易保持彎曲狀態或 輪環狀。然而,不會如同Κ往之延》漁法用綳索滲出瀝青 或粘着,而作為延》漁法用繩索實具有優異的作業性。 (實施例) 經濟部中央標準局貝工消費合作社印製 :----^-------〇-- (請先閱讀背面之注意事項再填寫私頁) Μ下,就實施例及比較例更具«說明本發明,但本發 明並不受此等實梅例的限制。 寅睢例1 J-- 做為1«索,使用市賣之維尼龍«索(克拉麗公司Μ 4βι -14- 本紙張度適用中國國家標準(CNS > A4规格(210X297公釐) A 7 B7 五、發明説明() … Φ),而將聚尿素彌性體使用{愛里斯馬-1000 [伊哈拉化 學工莱公司製之聚四甲二酵雙(4 -氨基苯酸)]與液狀MDI 者} Μ總括製造法(溶劑;甲基乙基調,聚尿素彌性體之 灞度;3(U,處理時間,3分鐘)含浸後,乾嫌製得緬索A (含浸率0 . 21)。 將所得級索A, Μ下述方法評估其射磨耗性,作業性 ,及鑭索性狀。其結果,表示於(表1)。 [耐磨耗性】 Ο附磨耗性試驗 使用下示試驗櫬及條件,澜定_索至切斷為止的衝程 數。其结果,表示於(表1)。 試驗機種類:绷索磨耗試驗械 磨耗子 :菱目型硬霣處理,150ββ徑#24 (100 Γ . ρ · ·) 銜程數 :50銜程/每分鐘(作動寬25cm) 回轉數 :25轉/每分鐘 荷 重 :7公斤 [作菜性]' 經濟部中央梂準局貝工消費合作社印製 (請先Η讀背面之注意ί項再填寫4頁) Ο滲出及粘着 Μ手握持钃索,査霣際作業時有否滲出或粘着。其结 果,表示於(表1) [1«索性狀] 〇颺索之柔軟·性及復原力 Μ兩手握持長度1〜2β的鑭索,使之撓曲,延直,縮 -15- 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) A7 B7 s 22408 五、發明説明( 小,成輪環狀等,由.實際作業延钃漁法的漁船員(漁師)A7 __B7_ Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs V. Description of the invention (), Methyl diisoxanoic acid (χρί), Employ xylylene diisoxanoic acid_ (MXDI), Tetramethyl stupid Methyl diisocyanate, B-phenyl diisocyanate 4,4'-bisphenyl diisocyanate, diphenyl ether-4,4'-diisocyanate, 3,3 * -Xylene-4,4'-diiso_acid_ (TODI), dimethoxybenzyl diisocyanate_ (0ash01), 4,4'-diphenylmethane diisophosphonium * (» 101), liquid "1, 3, 3'-dimethyl-4,4'-diphenylmethane diisoxanoic acid_, 1-5-naphthalenediiso_acid_ (〇1), triphenyl Methane triisocyanic acid_ (TTI), etc. Any polyisocyanic acid generally used in the manufacture of polyurethane hydrazone. Also, as a prepolymer, in the above polyisocyanic acid_, the general formula The reaction product of the polyhydric _ represented by Ηπ-Α ... (2) and the quantitative reaction of the two endossines with the isocyanic acid_ group can also be used. When preparing the polyurea (urethane) resin The ratio of amine component to isotonic acid ft component, the molar ratio (-NC0 / -NH2) of isanoic acid base (-NCO) to amino group (-NH2) is usually 0.9 ~ 1.5, which is better Is 1. A range of 0 to 1.3 is sufficient. The polyurea (urethane) resin obtained in this way can be easily adjusted to a hardness of A7 0 K and a hardness of D80 M. The polyurea (urethane) resin obtained, Generally, it is elastic and can fully exert its properties when impregnated with strontium chloride. So it is used in the strontium for the method of the present invention. When preparing the above polyurea (urethane) resin, it is usually not needed but a catalyst can also be used . As this kind of catalytic flares, it is preferable to be easily soluble in the amine component [the amine compound represented by the general formula (1) or a mixture of the amine compound and the aromatic polyamine]. Examples of such catalytic setting, Examples include triethylenediamine, triethyllimb, and tripropylene-10-This paper uses the Chinese National Standard (CNS) 210X297mm): --- „------- C ii (please first Read the note $ item on the back and fill in the page) Order-A7 B7_ V. Description of the invention () Basic amine, tributylamine, hexamethylenetetramine, N-alkylcholine, N-pentamethyldiethylenetriamine , N-hexamethyltriethylenetriamine, N, N-diethylaniline, N, H-dimethyldiamine, N, N-dimethyldodecylamine, dimethylamine , ", Cast-dimethyl 9 嗦, Ν, Ν, Ν ', ΙΤ-tetramethylidene diamine,", 1), "1', > 1'-tetramethylpropane diamine, 1 (), 1 »', 1}'-tetramethyl-1,3-butanediamine, (1,1),", N'-tetramethylhexamethylenediamine, U, N, N ', Ν'-pentamethyldiethylenetriamine, tris (dimethylaminomethyl) phenol, Ν, Ν ', IT-tris (dialkylfluoroalkane #) hexahydro-S-trikrylbenzene, 1 , 8-Di-Krypton Heterocycle- [5,4,0] -undecene (DBU), 1,8-Di-Krypton- [5,4,0] -Undecenyl Methylene Ammonium acid, tertiary amines and cyanogen-containing compounds, etc. In addition, other catalysts can be used, such as Lewis acid catalysts, tetra-η-butyl tin, tri-η-butyl tin fermented sour, tri-η-butyl limonate sugar, η-butyl tin tri-gasified compounds , Trimethyltin "gasification, dimethyltin digasification, dibutyltin dilaurate dibutyltin di-2-ethylhexanoic acid_, ethidium bromide and other eaves tin compounds, ethyl acetone zinc complex Printed by the Beigong Consumer Cooperative of the Central Bureau of Economics and Trade of the Ministry of Economic Affairs (please read the $ item on the back and then fill in this page) Aluminium acetone of A-branched aluminum, acetone gold of A-coated aluminum, etc. Naphthenic acid, lead naphthenate, lead decanoate, cobalt naphthenate and other naphthenic acid gold Yangmu, stupid mercury _, stupid mercury oleate, phenyl mercury octanoic acid K, phenyl mercury naphthalene Organic mercury compounds such as acids, lead compounds such as lead octoate and lead naphthalate, Ml-type metal salts and organic prosthetic compounds with carbon dioxide, and carboxylic acid salts with 2 to 12 carbon atoms (potassium fermentate, Potassium propionate, potassium 2-ethylhexanoate, sodium benzoate, etc.), gold metal _ (carbonate of sodium octoate, potassium linoleate, etc.) of carbonic acid with 13 or more carbonic acid, Nasal Weak acid other than acid M_Mt-type substances such as Jin Yishao, Methane, sodium trimethylammonium oxide, sodium hydride and potassium hydride and other salty gold-11- This paper size is suitable for China CNS > A4 specification (210X297mm) 322408 Α7 Β7 5. Description of the invention () Chelating compounds or auxiliary catalysts (phenols) represented by chelating compounds such as hydrocarbaldehyde and potassium, strong compounds such as argon compounds , Epoxides, alkyl carbides), etc .. Catalytic Qu Kejun can be used alone as two or more types of #. When using catalytic, its use is 100% of the above amine components [general formula (1) The compound shown or the mixture of the amine compound and aromatic polyamine represented by the general formula (1) accounts for 0.01 to 5 parts by weight, preferably 0.05 to 3 parts by weight. In addition, the general formula ( 1) The amine compound represented by the general formula Hn-A ... (2> The multi-enzyme compound represented by Hn-A contains a fluorine-based multi-enzyme compound equal to η of 0-,-or P-nitro Phenol gas, a nitro compound obtained by reacting in the presence of dehydrochloric acid cocoon, is added to the original method of K, or as shown in general formula (2) The multi-enzyme compound or molybdenum-containing amino multi-enzyme compound is obtained by reacting an equal amount of η with the isatinic acid dehydrated product and adding K. Second, the impregnation of the synthetic resin used in the production of the fishing method used in the present invention will be explained. Printed by the Beigong Consumer Cooperative of the Ministry of Economic Affairs of the Ministry of Economic Affairs (please read the precautions on the back and then fill in this page) · The synthetic resin used for the manufacture of the thorium used in the extension of the fishing method of the present invention is an organic solvent _ It is dissolved or dispersed into IX ~ 50X solution, preferably 10X ~ 4OX solution or dispersion, which contains intrusion of trontium. Visible organic dissolution, can be used as an aliphatic fatty alcohol can be exemplified, propanol, Methyl ethyl sulfonate, diethyl ketone, methyl propyl ether, etc. In addition, aromatic hydrocarbons can also be used, and toluene, xylene, ethylbenzene, etc. can be exemplified. In addition, non-dice-like polar cocoon dissolution can also be used, and dimethyl methylamine, dimethyl ethylamine, dimethyl sulfoxide, etc. can be exemplified. Others can also be brewed with fatty acids, for example -12- This paper scale is applicable to the Chinese National Standard (CNS) Α4 specification (210X297 mm) Printed by the Ministry of Economic Affairs Central Standards Bureau Negative Consumer Cooperative A7 > B7_ V. Description of invention () Examples include acid ethyl, acid methyl, acid methyl K and the like. The above-mentioned RC can be used by military guessing or a mixture of two or more. When preparing the synthetic resin solution or dispersion used in the longline fishing method rope of the present invention, taking polyurea (urethane) limits as an example, for example (1) first prepare a clear organic solvent, and combine the above amine components and The oxalic acid_components are added separately while stirring, or (2) the above amine components and isoxanoic acid_components are separately dissolved in the organic solvent, and when used, the solutions are mixed, and any one can be used, etc. method. Secondly, the method of impregnating synthetic tree cells with sorrel for fishing method of «Suo M to make the extension of the present invention ''. When M uses polyurea (urethane) tree cells as an example, for example, [1] impregnating the wire with strontium Fill the storage tank filled with the solution or dispersion of the above polyurea (urethane) resin, and after a predetermined time (1 to 5 minutes according to conditions), pull on the cable to remove excess polyurea (urethane) resin K The method of using tweezers (inlaid manufacturing method) for the fishing method of the Myanmar-Burma, or [2] allowing the Burmese cable to meet the filled polyurea (urethane) resin solution for a predetermined time (depending on conditions such as 1 to 5 minutes) from the beginning Or in the storage eaves of fractional liquid, and then take up the method of »request (the method of continuous ore making) and so on. When manufacturing Yan 1 «Copper for fishing method '' of the present invention, the amount of synthetic resin impregnated with« Copper »for the fishing method will greatly affect the abrasion resistance M and the traits of the fishing line. The impregnation amount can be represented by the impregnation rate expressed by the replacement ratio of the cordoprene to the impregnated polyurea (urethane) resin, that is, the impregnation rate can be obtained by the calculation formula shown below. -13- The size of this paper is applicable to China National Standard (CNS) A4 specification (21〇Χ25> 7mm) (please read the precautions on the back before filling in, this page r. Installed · A7 ____B7_ V. Description of invention ( ) ~ Impregnation rate = ---- 1 per unit length before impregnation of synthetic resin "The weight of the cable is better for the purpose of costing the invention. The impregnation rate depends on the type of synthetic resin or code used, the thickness of the rope, Μ and The purpose is different depending on conditions such as properties, but for example, when using synthetic resin of polyurea (urethane) resin, Vinyxine (4β · Φ), its impregnation rate is 0.01 ~ 0.5, which is It should be within the range of 0.05 ~ 0.3. In addition, in the manufacture of the extension method of the present invention, plasticizers, various fillers, oxidation prevention, ultraviolet absorption, coloration prevention, and water absorption decomposition prevention can be appropriately added. , Anti emblem _, anti-suspicion; », coloring _, incremental cocoon, etc. (Effect of the present invention) The yan cable used for the extension of the fishing method of the present invention, because of its excellent abrasion resistance, can be used for a long period of time. The overall properties of the cable can be maintained at the same level or the same It is flexible and can be easily maintained in a curved state or a ring shape. However, it does not ooze asphalt or stick like 線 遠》 綳 緳 用 緳 線, but it has excellent workability as a Yan》 歲 極 法 的 绳. (Example ) Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs: ---- ^ ------- 〇-- (please read the precautions on the back before filling in the private page) Under Μ, the examples and comparative examples More «illustrates the present invention, but the present invention is not limited by these real examples. Yin Sui example 1 J-as 1« cable, using commercially available vinyl nylon «cable (Clari Μ 4βι -14 -This paper size is applicable to the Chinese National Standard (CNS> A4 specification (210X297 mm) A 7 B7 V. Description of invention ()… Φ), and the polyurea body is used {爱里斯马 -1000 [伊哈拉Polytetramethylene bis (4-aminobenzoic acid) manufactured by Chemical Engineering Co., Ltd.] and liquid MDI} umbral manufacturing method (solvent; methyl ethyl tune, polyurea endometrium; 3 (U , Treatment time, 3 minutes) After impregnation, dry to prepare Burmese A (impregnation rate of 0.21). The obtained grade A, Μ The following method to evaluate the jet wear , Workability, and lanthanum cable properties. The results are shown in (Table 1). [Abrasion resistance] Ο Abrasion resistance test The following test conditions and conditions are used, and the number of strokes until the cutting is completed. The results are shown in (Table 1). Type of testing machine: sling abrasion test Mechanical abrasion: diamond-shaped hard-butter treatment, 150ββ diameter # 24 (100 Γ. Ρ ··) Number of ranks: 50 ranks / each Minutes (Actual width 25cm) Number of revolutions: 25 revolutions per minute Load: 7 kg [Working] [Printed by the Central Bureau of Economic Affairs of the Ministry of Economic Affairs of Beigong Consumer Cooperative (please read the notes on the back and fill in 4 pages ) Ο Exuding and sticking Μ hands holding the cable, check if there is any oozing or sticking during the operation. The results are shown in (Table 1) [1 «Cable Properties] 〇The softness, flexibility and resilience of the yan cable. Hold the lanthanum cable with a length of 1 ~ 2β in both hands to make it flex, straighten, and shrink The paper scale is applicable to the Chinese National Standard (CNS) Α4 specification (210X297 mm) A7 B7 s 22408 V. Description of the invention (small, ring-shaped, etc., by the actual operation of the fisherman (fisherman) in the fishing method

人(XI〜X5),對於柔軟性 用钃索(细索E)做為基準 表示於(表1)。 (柔軟性) 〇:柔軟性比«索E △:柔軟性比颺索E X :柔软性比钃索E 復原力,Μ往所用的延«漁法 由下述標準評估之。其结果, 較高 同程度 較低 請 先 閲 讀 背 面 之 注For humans (XI ~ X5), with regard to flexibility, it is shown in (Table 1) using sorrel (fine cable E) as a reference. (Softness) ○: Softness ratio «Copper E △: Softness ratio Jansso E X: Softness ratio Chongsuo E Resilience, the extension method used by« Fishing method '' was evaluated by the following criteria. As a result, higher, lower level, please read the back note first

I (復原力) Ο : Δ : 頁 經濟部中央揉準局貝工消费合作社印装 復原力比糴索Ε較弱 復原力與钃索Ε同程度 X:復原力比钃索Ε較強 再着,綜合性判斷射磨耗性,作業性,柔软性,復原 力等,仍Μ以往所用之延_漁法用繩索(钃索Ε)做為基準 ,將各期索做為延緬漁法用繩索時之遴合性,由下述檷準 接受判斷。其结果,一併表示於(表1)。 (做為延娵漁法用_索的逋合性) Ο :比钃索Ε更合遘 △:逋合性與钃索Ε同程度 X:缠合性比钃索Ε較低 又,使用於含浸的樹脂,另使之硬化而所得的硬度, 做為「硬度J 一併記載於(表1)。 - 實胨例2 使用聚尿素彌性體[使用氫氧化基價20 K0H*g/g,胺 -16 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 經濟部中央橾準局負工消費合作社印製 A7 B7 五、發明説明() — 價75 KOHag/g之聚四甲二酵雙(4-氨基苯酸)與液狀MDI 所製造者]Μ替代聚尿素彌性體外,如同實施例1實施以 獲得《索Β (含浸率0.20)。所得雜索Β,如同實施例1加 Μ評估。其结果,表示於(表1)。 實施例3 使用聚尿素彈性《[使用愛里斯馬-1000與基胺(伊哈 拉化學工業公司製芳香族聚胺),調整為重量比90:10的 胺成分及液狀MDI所製造者]外,如同實施例1賨施,Μ 獲得》索C (含浸率0.23)。所得《索C,如同實施例1加 Μ評估。其结果,表示於(表1)。 ’ 實施例4 做為_索,使用以凱布拉雄維作為芯料的市賣之钃索 (4·βΦ), Μ如同實施例1的聚尿素彌性體,經由總括製 造法加Μ含浸後,乾煉Μ製得延钃漁法用Μ索D (含浸率 0.19)。所得鑭索D,如同實施例1加Μ評估。其结果,表 示於(表1)。 比較例1 使用瀝青(商品名:克比克得,東洋有櫬公司製)Κ 替代實施例1的聚尿素彌性體外,如同實雎例1實施以獲 得钃索Ε (含浸率0.20)。所得钃索Ε,如同實施例1加以 評估。其结果,表示於(表1)。 比較例2 使用將愛里斯馬-1 0 0 0與4, 4’-甲叉雙(2-氣笨胺)的 簠量比調製為20:80的胺成分,及將2,2,2’,2’ -四甲基二 -1 7- 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) (請先閱讀背面之注$項再填寫4頁)I (Resilience) Ο: Δ: The printed resilience of the Beigong Consumer Cooperative of the Central Ministry of Economic Affairs of the Ministry of Economic Affairs is weaker than that of Esso E. The resilience is the same as that of Esso X: the resilience is stronger than that of Esso , Comprehensive judgment of jet abrasion, workability, flexibility, resilience, etc., still used in the past _ fishing method rope (Gordon Ε) as a reference, when each period is used as a rope for Yan Myanmar fishing method The suitability is judged by the standard below. The results are also shown in (Table 1). (It is used for the fishing method of Yanbo fishing method. _ Cable's compatibility) Ο: More compatible than trisoline △: Compliance is the same degree as trisoline X: The entanglement is lower than that of trisoline, and it is used for impregnation The hardness obtained by hardening the resin is described as "Hardness J" in (Table 1).-Peptone Example 2 Polyurea dense body is used [Hydroxide base price 20 K0H * g / g, Amine-16 This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm). The A7 B7 is printed by the Consumer Service Cooperative of the Central Bureau of Economics and Trade of the Ministry of Economic Affairs. 5. Description of the invention ()-Polytetramethyl A of 75 KOHag / g The two enzymes bis (4-aminobenzoic acid) and liquid MDI are manufactured] M instead of polyurea in vitro, implemented as in Example 1 to obtain "Copper B (impregnation rate 0.20). 1 plus M evaluation. The results are shown in (Table 1). Example 3 Using polyurea elasticity "[using Arisma-1000 and base amines (aromatic polyamines made by Ihara Chemical Industry Co., Ltd.), adjusted to weight The ratio of 90:10 amine component and liquid MDI was manufactured], as in Example 1 賨 施, Μ obtained "C (impregnation rate 0.23). C, as in Example 1 plus M evaluation. The results are shown in (Table 1). 'Example 4 As the _ cable, the use of Kebra Xiongwei as the core material of commercially available tin (4 · βΦ) , M is the same as the polyurea dense body of Example 1, after adding M impregnation through the manufacturing method, and dry-melting M to obtain Yan Dang fishing method M cable D (impregnation rate 0.19). The obtained lanthanum cable D, as in Example 1 plus Evaluation of M. The results are shown in (Table 1). Comparative Example 1 Asphalt (trade name: Kebic, manufactured by Toyo Yuki Co.) was used instead of polyurea in vitro of Example 1 as in Example 1 It was carried out to obtain thosoline E (impregnation rate 0.20). The obtained thosoline E was evaluated as in Example 1. The results are shown in (Table 1). Comparative Example 2 Arisma -1 0 0 0 and 4, 4'-Methylene bis (2-pyridylamine) is prepared with an amine content ratio of 20:80, and 2,2,2 ', 2'-tetramethyldi-1 7- China National Standard (CNS) Α4 specification (210X297mm) (Please read the note $ item on the back and fill in 4 pages)

323408 A7 B7 五、發明説明() :’ 甲苯二異睛酸酿與六.甲基二異睛酸_環狀三聚物與3-異睛 酸醮甲基-3,5,5-三甲基環己基異瞬酸酯環狀三聚物之重 量比調製為26:26:78的異聃酸_成分而製得的聚尿素彈 性體,Μ替代實施例1之聚尿素彌性體外,如同實施例1 實胨而獲得延糴漁法用两索F (含浸率0.20)。所得緬索F ,如同實施例1加Μ評估。其结果,表示於(表1)。 (請先閲讀背面之注意事項再填寫本頁) -訂 經濟部中央標準局貝工消費合作社印裝 •ΊΙ. -18- 本紙張Λ度適用中國國家揉準(CNS )八姑1格(210Χ297公釐) 322408 B7 五、發明説明() (表1 ) 經濟部中央標準局貝工消費合作社印裝 張 紙 本 實施例 號碼 (期索) 硬度 酎磨耗性 (衝程數) 作業性 纈索 性狀 滲出 粘着 評估人 柔軟性 復原力 遘合性 XI 〇 〇 〇 實胨例1 蕭氐 X2 〇 〇 〇 (钃索A) A95 20380 無 無 X3 〇 〇 〇 X4 〇 〇 〇 X5 〇 〇 〇 XI 〇 〇 〇 實施例2 蕭氏 X2 〇 〇 〇 (» 索 B) A90 17680 無 無 X3 〇 〇 〇 X4 〇 〇 〇 X5 〇 〇 〇 XI 〇 〇 〇 實雎例3 蕭氐 X2 〇 〇 〇 (钃索C) D58 20214 無 無 X3 〇 〇 〇 X4 〇 〇 〇 X5 〇 〇 〇 XI 〇 〇 〇 實施例4 蕭氏 X2 〇 Δ 〇 (» 索 D) A95 21560 無 無 X3 〇 〇 〇 X4 〇 〇 〇 X5 〇 〇 〇 XI — — 一 比較例1 X2 一 — — (獮索E) 4970 有 有 X3 — — — X4 — ~ — X5 一 — — XI X X X 比較例2 簫氐 X2 X X X (蠲索F) D90 18153 無 無 X3 X X X X4 X X X X5 X X X . -19- (請先閲讀背面之注意事項再填寫本頁) ^^1 , *-'β τ. 家 國 國 中 用 適 準323408 A7 B7 V. Description of the invention (): 'Toluene diisoxanoic acid and hexamethyl diisoxanoic acid_cyclic terpolymer and 3-isoxanoic acid methyl-3,5,5-trimethyl The polyurea elastomer prepared by adjusting the weight ratio of the base cyclohexyl isotonic acid ester cyclic trimer to 26:26:78 is iso-acid_ component, M replaces the polyurea of Example 1 in vitro, as Example 1 Two pouches F (impregnation rate 0.20) for Yan Peng fishing method were obtained by peptone harvesting. The resulting Burmese F was evaluated as in Example 1 plus M. The results are shown in (Table 1). (Please read the precautions on the back and then fill out this page) -Order printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs • ΊΙ. -18- This paper is suitable for the Chinese national standard (CNS) Bagu 1 grid (210Χ297 Mm) 322408 B7 V. Description of the invention () (Table 1) Printed sheets of paper printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Example number (period) Hardness wearability (number of strokes) Operational valsor effusion Adhesion Evaluation Human Soft Resilience Compatibility XI 〇〇〇 Peptone Example 1 Xiao Di X2 〇〇〇 (Torso A) A95 20380 None X3 〇〇〇X4 〇〇〇X5 〇〇〇 XI 〇〇〇 implementation Example 2 Xiao's X2 〇〇〇 (»cable B) A90 17680 no X3 〇〇〇X4 〇〇〇X5 〇〇〇XI XI 〇〇〇 real example Example 3 Xiao Di X2 〇〇〇 (Thorax C) D58 20214 No No X3 〇〇〇X4 〇〇〇X5 〇〇〇XI 〇〇〇 Example 4 Xiao's X2 〇Δ 〇 (»cable D) A95 21560 No No X3 〇〇〇X4 〇〇 〇X5 〇〇〇XI--a comparative example 1 X2--(Xiao cable E) 4970 there is X3---X4-~-X5 one-XI XXX Comparative Example 2 Xiao Xiao X2 XXX (Ranso F) D90 18153 None None X3 XXX X4 XXX X5 XXX. -19- (please read the precautions on the back before filling this page) ^^ 1, *-'β τ. Appropriate for home country and country use

CC

AA

釐 公 7 29 XCentimeters 7 29 X

Claims (1)

妓24〇8 Α8 Β8 C8 D8 修正明· ίο. μ 本等λ ί爾補充 气 申請專利範圍 1 · 一種具有優異__性且柔軟而钃復原力之延I«漁 法用繩索,乃將砸化時之硬度為蕭氏A70〜D80的麵自聚 尿素(尿烷)樹胞及聚尿烷樹含浸於钃索者》 2· 如申鱅《利範_第1項所述的籤钃漁法用繩索, 其中,該聚尿素(尿烷)樹胞,係由下示一般式所代表的胺 Λ合物或由該胺化合物及芳香族聚胺所成的胺成分,輿聚 異睛酸醮及多元酵加Μ反應而得的在末纗具有興臃酸釀基 的預聚_及由聚異晴酸酗所成的輿睛酸釀成分,加Κ反應 而得的聚尿素(尿烷)玀性黼者 m ^^1 Hr In h 1 1^1 I ..... I (請先閲讀背面之注$項再填寫本頁)Prostitute 24〇8 Α8 Β8 C8 D8 Amendment · ίο. Μ Ben et al. Λ ell supplementary gas application patent scope 1 · An extension with excellent __ nature and softness and resilience I «fishing rope, it will be smashed The surface hardness is A70 ~ D80 of Shaw's, which is impregnated with polyurea (urethane) tree cells and polyurethane tree impregnated with cadmium. 2 · For example, the rope for signing the fishing method mentioned in "Lee Fan _ Item 1" , Where the polyurea (urethane) tree cell is an amine compound represented by the general formula shown below or an amine component composed of the amine compound and an aromatic polyamine, and polyisocyanate and polyvalent Fermentation plus M reaction results in a prepolymer with a glutamic acid base at the end _ and polyacrylic acid brewing ingredients made from polyisocyanic acid, and polyurea (urethane) obtained by adding K reaction Sex attacker m ^^ 1 Hr In h 1 1 ^ 1 I ..... I (please read the note $ item on the back before filling this page) 經濟部中央標準局男工消費合作社印裝 (式中,Α為氧原子成含有亞胺基且可含有平均分子量200 Μ上之不鉋和结合聚烷撐,聚烷撐醚或聚烷撐聚酶。為 1〜3的S數,11為2〜4的整數,又為平均值而代表0〜 0 · 4的數)。 3. 如申請專利範園第2項所述的蘊钃漁法用糴索, 其中,該芳番族胺係雄自二«基二苯基甲烷糸的芳番族二 胺,含有氧原子或疏黄原子的芳香族二胺,鑲基笨酸醮糸 表紙張尺度逍用中國國家梂準(CNS > Α4規格(210X297公釐) 322408 Α8 Β8 C8 D8 六、申請專利範固 芳香族二胺,甲苯二胺糸的芳番族二胺,二氬基二苯基丙 烷糸的芳香族二胺,及芳番族四胺之1種或其以上者。 4. 如申講«利範圈第1項所述的延钃漁法用蠲索, 其中,該含浸係使用以«性有機溶Μ作1〜50X »液或分 散液的合成樹脂而實雎者。 5. 如申請專利範第4項所述的延钃漁法用緬索, 其中,該合成樹胞係使用聚尿素(尿烷 >彈性臞所資施者。 6. 如申請專利範園第4項所述的延钃漁,*用钃索, 其中,該晴性有機溶麇係使用胞肪族嗣,芳香族磺化氩, 非質子性極性溶繭,及脂肪酸醣的1種或其以上者。 7. 如申請専利範醒第1項所述的延鼸漁法用繩索, 其中,該含沒作業係在常灌下所資豳者。 (請先閲讀背面之注意事項再填寫本頁) 装· 訂· 經濟部中央揲準局貝工消費合作社印褽 lh. 本紙張尺度適用中國國家標準(CNS ) Α4规格(21〇χ297公釐)Printed by the Male Industry Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (where, A is an oxygen atom containing a polyimide, polyalkylene ether or polyalkylene polymer containing an imine group and an average molecular weight of 200 μM. Enzymes are S numbers from 1 to 3, 11 is an integer from 2 to 4, and it is an average value representing 0 to 0 · 4). 3. As described in item 2 of the patent application garden, the scorpion for fishing method in Yunding, wherein the aromatic amine is an aromatic diamine derived from diphenylmethane, which contains an oxygen atom or Aromatic diamine of yellow atom, tartaric acid tartaric acid table paper scale used in Chinese national standards (CNS > A4 specifications (210X297 mm) 322408 Α8 Β8 C8 D8 六 、 Apply for patent Fanguo aromatic diamine, One or more of aromatic diamines of toluene diamine Shito, aromatic diamines of dihydrodiphenylpropane Shito, and aromatic tetraamines 4. If applying for «Lifan Circle Item 1 The paniculata for Yanzhu fishing method, wherein the impregnation system uses synthetic resin with «sexual organic solution M as 1 ~ 50X» liquid or dispersion. 5. As described in item 4 of the patent application The Yanyan fishing method uses Burmese cable, in which the synthetic tree cell line uses polyurea (urethane > elasticity). 6. As for the Yanfan fishing described in item 4 of the patent application park, * use tin Among them, the clear organic dissolving system uses one type of aliphatic heir, aromatic sulfonated argon, aprotic polar cocoon, and fatty acid sugar The above. 7. For the application of the rope for Yanlu fishing method as described in Item 1 of the Fanli Xing, in which the contained operation is funded by the regular irrigation. (Please read the precautions on the back before filling in this Page) Binding · Order · Printed by the Beigong Consumer Cooperative of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs. This paper size is applicable to the Chinese National Standard (CNS) Α4 specification (21〇297 mm)
TW084113671A 1994-12-22 1995-12-21 TW322408B (en)

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