TW313531B - - Google Patents

Description

Printed by the Central Industry Bureau of the Ministry of Economic Affairs, Labor and Consumer Cooperatives ° 13〇3l A7 _B7__ V. Description of the invention (1) The present invention is generally about a shear mixing device and its use in different manufacturing processes, the present invention is more about a The use of a shear mixing device that generates very small bubbles and a device that supplies gas to a liquid medium. The present invention is particularly applicable to such devices and applications that enhance the mass transfer of reactive gases in chemical or biochemical reactions. Gases such as oxygen. In "Quality of Very Small Bubbles-Optimal Bubble Size for Aeration" Volume 33, pages 1415 to 1423 (1978), M Motarjemi and G. J.  Jameson teaches that bubbles are usually used for mass transfer, especially in the context of dissolved oxygen in water. On page 1422, it suggests that it is necessary to develop a practical new method to produce "a large number of diameters less than 0.  lmni's small bubbles ". In" Bubble in Motion "Trans IChemE Volume 77 Part A, pages 587 to 594 (November 1993), G.  J.  Jaaeson provided an overview of Dr. John Davison's contribution to the study of bubble and gas-liquid two-phase flow hips. On page 592, he discussed the problem of generating small bubbles by reducing the average pore size of the diffusion. This problem includes: the pressure drop of the diffuser and possible hole blockage caused by the presence of solid water in devices such as sewage tanks. On page 593, he discussed bubble mergers and noted the need to apply a force to the bubbles Μ moves it out of the hole very quickly to prevent it from merging. Possible devices for adding this force include: the liquid stream on the hole or the oscillation of the gas skeleton applied to the hole itself or the hole. In the first aspect, the present invention provides a device that can generate bubbles with a diameter of less than 1 mm without simultaneously generating the problems proposed by Jameson due to the reduction of the average hole diameter of the diffuser of the traditional bubble generating device. The device of the present invention includes: the paper The standard is applicable to China National Standard (CNS) Α4 specification (210X297mm) (please read the precautions on the back before filling in this page) 袈.  A7 _B7_ printed by the Employees ’Consumer Cooperative of the Central Prototype Bureau of the Ministry of Economic Affairs 5. Description of the invention (2) At least one conduit carrying the first liquid to be mixed, which has an open first end for receiving the first liquid to be mixed and A sun-closed second end, a hole in the tube is defined in each of the tubes close to the second end of the blue door, after which the liquid received by the open first end flows out of the tube; a mixer The body is generally defined by the conduit and has a closed first end defining a corresponding hole through which each conduit passes. The mixer body further includes a second end, each of which has such a second end The duct defines a shrinkage hole, and corresponds to a constrictor closed by the mixer body and defined between the first end and the second end of the constriction of the mixing body. The hole in each duct is generally positioned to be connected to the relevant specific duct A braided hole; and a second fluid supply conduit connected to a liquid plaque formed in the hollow space surrounded by the mixer, Μ provides a constriction hole above one of the second ends of the mixer body for the second fluid to pass through And the streamer A first flow shear mixed with steamed bread embodiment is provided by the apertures located on the respective shrinkage. The second aspect of the present invention relates to a shear mixing device, which includes: a conduit for providing the first flow to be mixed, and a hole with a value of more than 1 is defined in the length of each conduit; a mixer body, It has a first end and a second end, and defines a hollow space surrounded by the first end and the second end. This space is connected to the liquid supply conduit to form a liquid skull. The first end and the second end have The respective corresponding openings defined by it are used to receive the carrier pipe passing therethrough. In this way, the hole of the first liquid to be mixed provided in the pipe is positioned to form a liquid connection with the hollow space. The third point of the present invention relates to the third related implementation of a shear mixing device. The paper size is applicable to the Chinese National Standard (CNS) Α4 specification (210Χ297 mm) 5 (please read the precautions on the back before filling this page).  Printed and printed S18S31 Α7 Β7 by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy. V. Examples of inventions (3) Examples include a hollow sub-assembly for receiving air liquid, a sub-assembly for generating bubbles, M and S, selectively, The first hand, receiving the gas and the liquid skeletal secondary entanglement system, is dynamically connected with the bubble generating sub-assembly, and forms a liquid connection. As a third embodiment, the receiving gas and liquid lancet subassembly includes: a tilted central conduit with an open inlet end M for receiving liquid hydride and an outlet end entangled with bubbles to form a liquid connection; Μ 和 一 接A gas shell, which is located roughly at the periphery of the central duct and is spaced from the central duct, whereby M defines a channel through which gas rolls through to the bubble-generating sub-assembly * which includes at least one gas pocket for feeding and grazing through it; And through the channel to the bubble generating sub-assembly connected to the receiving gas channel, the gas receiving shell with its one end and the central duct to form a gas-tight mollusk * The mint is closer to the entrance end of the central duct and farther from it Exit end. The air bubble generating sub-assembly in the third shear mixing device must include a gas-tight base plate connected to the outlet end of the central duct and a gas-liquid distribution shell which accommodates and distributes from the receiving gas shell. Gas and liquid with the central duct, and it is in a gas-tight connection with the substrate, and a clad plate, which is sequentially connected to the gas-distributive liquid distribution shell in a gas-tight relationship. The gas liquid distribution shell has a Central, funnel-shaped fluid expansion shell * The shell has a substrate and a cover plate that separate the bubble generation sub-assembly into an upper liquid expansion cavity and a lower gas skull expansion cavity. The funnel-shaped flow expansion cavity has A portion of the central duct near its outlet end is formed into a substantially air-tight hollow stem, and a peripheral extension projecting outwardly from the hollow stem * has a number of holes defined therein and in fluid connection with the gas expansion cavity Many holes that form a streamer connection with the liquid expansion cavity, and the hole and the gas supply liquid. The paper size is applicable to the Chinese National Standard (CNS) Α4 specification (210X297 mm) (please read the back side first Precautions to fill out this page) Buddhist monk's robe · Order οιόούΐ Central Bureau of Ministry of Economic Affairs rub prospective employees consumer cooperatives printed Α7 Β7 V. description of the invention (4) is connected and mixed to form a flow channel transmission ilk Po warm connection. The fluid channels are preferably separated from each other by a flow divider, which is also defined on the outer circumferential extension of the hollow stem. The fourth point of the present invention relates to a method of generating bubbles in the liquid phase, the diameter of the bubbles is less than 0. 1mm, the method includes: a.  When the gas i is introduced into the liquid through the holes in the components or elements separating the gas and the liquid skull, put the gas to a pressure sufficient to form bubbles; b.  M is sufficient to provide a flow rate exceeding the critical Weber number of gas and liquid to flow the liquid through the hole M to produce the desired bubble diameter. Fig. 1 is a first embodiment of the present invention and an axial schematic cross-sectional view of a shear mixing device according to the above-mentioned first viewpoint, Fig. 2 is another embodiment of the present invention and its special feature lies in the above-mentioned second viewpoint Axial schematic cross-sectional view of the shear mixing device, the third circle is an axial schematic cross-sectional view of the third embodiment of the shearing device of the present invention, the fourth garden is the top view of the third group device, the fifth plaque is Table I is a graph of the data shown in Table I. Table I is a list of the oxygen transfer results of the second embodiment. The vertical axis represents KLaae, and the horizontal axis represents the airflow rate represented by M per minute rise (SLM>); It uses traditional shear mixing technology to achieve the rectification or energy loss (expressed in kilopascals) of a predetermined bubble diameter. With reference to the figures, Figures 1, 2 and 3 provide diagrammatic representations of the three item-based devices with the present invention. Figure 4 is another view of the device shown in Figure 3. Different devices are not limited to those shown, the size, location and number of holes ----;-. --- ^ I 装 ------ 訂 ----- 4 Spicy (please read the precautions on the back before filling in this page) This paper size is applicable to China National Standard Falcon (CNS) Α4 specification (210X297mm } 7 01S531 A7 B7 Fifth, the description of the invention (5) is for illustration only and not for limitation. Figure 1 depicts the shear mixing device represented by reference number 10, the device 10 includes a hollow mixing device 11, and one is carried by Μ A pipe 15 to be mixed with liquid, a second fluid supply pipe 20 having a channel 21 and a plunger 25. The mixer body 11 has a first end 12 and a second end 13 away from the first end 12, the mixer body 11 includes The hollow space 30 between the first end 12 and the second end 13 of the nursery, the second end has a hole 14 defined therein, and a proper shape of a mixer body 11 (to facilitate identification, the second fluid supply conduit 20 is ignored) is a Hollow, right-cylindrical, with one end (second end 13) beating, and with a closed hole at the other end (first end 12) relative to the open end, when the mixer is so shaped and there is only one duct 15 , The orifice 14 and the conduit 15 must be coaxial with the mixer's main body * When it has at least two conduits 15, increase the number of orifices 14 The quantity M matches the number of conduits. The plunger 25 is placed in the second end 13 of the mixer plaque 11. When the plunger 25 is so close, it is necessary to define at least one hole or aperture 26 in it, when there is only one conduit At 15 o'clock, it is necessary to set the hole 26 so that it is co-glazed with the axis of the mixed medulla. When there are at least two catheters, each hole 26 is preferably coaxial with the corresponding catheter 15. Printed by the Employees Consumer Cooperative of the Central Ministry of Economic Affairs The conduit 15 has a first end 16 and a second end 17 that is away from the first end 16. The first end 16 is open and is preferably connected to a first fluid source (not shown), and the second end 17 is Closed or covered, M prevents the first fluid from flowing out through this end, the conduit 15 passes through, and is closely placed in the hole 14 of the first end 12 of the mixer body 11, preferably the conduit 15 is formed in the hole 14 in this way Joining, so it can provide a substantial leakproof, better airtight seal 8 around the periphery of the catheter 15 through the hole 14 (please read the precautions on the back before filling this page) The paper wave scale is applicable to China National Standard (CNS) Α4 specifications ( 210X297mm) Printed by the Consumers Cooperative of the Ministry of Central Development and Customs of the Ministry of Tao Α 7 Β7 Fifth, the description of the invention (6) The sealing tube also passes through the hole 26 of the plunger 25. For this reason, the catheter 15 cooperates with the plunger 25 to form a constricted hole 27 in the hollow space 30, the type of which is close to the second At the position of the end 17 is a longitudinal annular space defined by the length of the catheter 15. In this length, the catheter 15 has defined a number of holes 19 therein, and each hole 19 is connected with a braided hole 27, the number and size of the holes 19 The distance and position must be sufficient to provide small bubbles when the fourth aspect of the present invention is operated. The second fluid supply conduit 20 is dynamically connected between the first end 12 and the second end 13 of the oscillating unit 11 In this connection, the channel 21 of the second conduit 20 is connected to the hollow space 30 in a liquid manner. * If necessary, an additional flow feeder on the top of the inclination M can be connected to the mixing skull 11M to provide mixing in a similar manner. The extra fluid (gas or liquid, but preferably liquid) of the body 11 is combined with a gas skeleton (which can be a single gas brew or a mixture of multiple gasses) or multiple gases from one duct 15 or multiple ducts 15. With reference to FIG. 2, a shear mixing device according to the second aspect of the present invention is depicted. It is roughly designated by reference number 40. The device 40 includes a hollow mixing body 41, a carrier tube 50, and a flow channel including a channel 61. Supply catheter 60. The mixer body 41 has a first end 42 and a second end 43 away from the first end 42. The mixer body 41 includes a hollow space 55 between the first end 42 and the second end 43, and the first end 42 has its defined A hole 44, the second end 43 has a hole 45 defined therein, each hole 44 is preferably coaxial with the opposite hole 45, the appropriate shape of the mixer body 41 (to facilitate identification, ignoring the roller feeding tube 60> is one The shape of the hollow cylinder is two holes and two closed holes M and holes 44 and 45. When the mixture is formed in this way, it is preferable to align each tube 50 with the axis of the pair of opposite holes 44 and 45 in a coaxial arrangement. The wave scale is in accordance with the Chinese National Standard (CNS> Α4) (210X 297mm) 9 ------------ installed-- (please read the precautions on the back and fill in this page) Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. A7 B7 V. Description of the invention (7) The catheter 50 has a first end 51 and a second end 52 away from the first end 51. The catheter 50 passes through and is closely placed in the mixer Among the holes 44 and 45 of the snakehead 41, preferably M can provide a substantially leak-proof, preferably airtight perimeter of the conduit 50 that meets the holes 44 and 45 In this way, the ducts 15 of the holes 44 and 45 are close to each other. Since the first end 42 and the second end 43 are separated from each other, the coupling body surrounds the length of the duct 50. In this length, the duct 50 defines many of the holes 54. Each hole 54 is fluidly connected to the hollow space, and the number, size, spacing, and position of the holes 19 must be sufficient to provide small bubbles when operating in accordance with the fourth aspect of the invention. The flow supply duct 60 is connected to the mixer in conjunction At the intermediate point between the first end 42 and the second wire 43 of the body 41, when connected in this way, the channel 61 of the catheter 60 is connected to the hollow space 55 liquid eluent, if necessary, a M can be connected in a similar way An additional fluid supply is connected to the mixing skull 11M to provide additional fluid for the mixing cylinder 11. The first moving roller under pressure can be a gas cylinder such as air or oxygen, connected by a source (not shown) to the first cylinder. The first end 16 of a duct 15 flows into the duct 15 of the hole 10 (shown in the first ffl). It is necessary for the first lotus roller to enter the shrink hole 27 through the hole 19 in the duct 15 21 into the hollow space 30, the hollow space 30 ΜSecond lotus fluid * flow plaque rolls in and rolls through the shrink hole 27, the shrink hole 27 has a cross-sectional area smaller than the hollow space, so that the second lotus fluid when the speed of rolling through the knitting hole 27 is greater than its flow The speed of the passage 21 and the hollow space 30, the first lotus flow flowing through the hole 19 is under a pressure to prevent the second lotus roll body from entering the conduit 15 through the hole 19, when the first lotus flow is gas The second scroll is a liquid crocodile. The pressure must be sufficient to generate bubbles. It is believed that the flow of the second movement roller that rolls through the pores 27 requires the paper standard to apply to the Chinese National Standard (CNS) Α4 specification (210X297 mm) 10 (Please read the notes on the back and then fill in this page) Outfit-Order 313531 Printed by the Ministry of Economic Affairs Central Counseling Bureau Co-operative Consumer Cooperative Α7 Β7 V. Description of Invention (8) Large enough to overcome the gap between gas and liquid Interfacial tension, thereby forcing the bubbles to split into small bubbles, if the two streams are liquid or gas, I believe that the hole 10 facilitates the mixing of the lotus fluid, if the second movement fluid is a liquid and the first lotus fluid flows. For the gas mixed in the liquid, it is believed that the hole 10 can provide a gas mixture The dispersion of mollusc in liquid. As shown in FIG. 2, the hole 40 is suitable for merging the first moving fluid desiring to be liquid and flowing through the perforated duct 50, and the second movement of the channel 61 that is desirably a gas skull and flowing through the fluid supply duct 60. fluid. The specific characteristics of the hole 10 are also suitable for the hole 40. The first lotion fluid flows into the conduit 50 from a source (not shown) by operative connection with the first end 50 of the conduit 50. It is not necessary to change its cross-sectional area, and it is not necessary to change the flow speed of the first flow of the flow through the duct 50. The second motion flow is connected to the liquid supply duct 60 by the liquid, and the source flows into the channel 61. The second flow The stream rolls from the channel 61 into the hollow space 55 »and thereby enters the duct 50 through the hole 54. The second motion flow sickle is under the force of the bubble generated by the foot M and substantially prevents the first lotus fluid from entering the hollow space 55. When the hole 10 is used, the flow of the liquid motion stream must be sufficient to decompose the bubbles generated when the gas lotus moves through the hole and comes into contact with the liquid fluid. In addition, the hole 40 is also suitable for the purpose of the hole 10. The third coil still depicts the third embodiment of the shear mixing device of the present invention, which is generally shown by reference number 100. The hole 100 includes a middle air and a liquid receiving secondary entanglement, and a gas ray generating secondary assembly 140 And a selection handle 190. When the handle 190 is present, it is advantageous to set the hole 100 in a container (not shown), such as a polymerization reactor or a biochemical reactor. The receiving subassembly 110 includes a central duct 111 and a gas receiving shell 120. The paper size is applicable to China National Standard (CNS) Α4 specification (210X297mm) (please read the precautions on the back and fill in this page) Order-11-A7 _____B7_ printed by the Consumer Labor Cooperative of the Central Bureau of Economic Development of the Ministry of Economic Affairs 5. Description of the invention (9), the central duct 111 has an open entrance end 112 and an exit end 113 that catches the entrance end. The air bubble generating sub-assembly 140 is in a rolling connection, and the central duct 111 has a glaze channel 114 suitable for passing liquid. The gas receiving housing 120 is preferably composed of a single structural element, or as shown in the third section * which may include A ring-shaped gas receiving chamber 121 and a urn-shaped gas mullet Fu Yiyi 123. The gas receiving chamber housing 122 has at least one gas defined therein. It is necessary to spiral the inside of the channel 122 to generate gas. Airtight connection of the source (not shown), the gas skull receiving chamber shell 1212 surrounds a gas skull receiving channel 122 to form a fluid flow hollow chamber 124, the annular gas transmission shell 123 must be at least linear with the central duct Partial cooperation M shape A gas from the gas receiving casing 121 is connected to the bubble generating sub-shaped elongated annular space 126, the casing 123 has a first end 125 snagged into the hollow chamber, and a second away from the first end 125 The end 127 > the annular space 126 also forms a cascade with the hollow chamber 124, so that the first lotus liquid (preferably a gas) entering the passage 122 can flow into the hollow chamber 124, and then pass through the annular space 126. The components of the receiving sub-assembly 110 are operatively connected to each other by a fixing device such as welding 115. The gas generating sub-assembly 140 includes a bottom plate 141, a gas pith and a liquid distribution shell bun 150, and a covering plate 180, a bottom plate 141 has a plurality of holes 142 defined therein, and the bottom plate 141 also has an annular ring-sealed housing 146 defined therein which suitably includes a sealing device 146. The sealing device 146 is more suitable for providing the bottom plate 141 and the housing for an O-ring M Between the 150 is a substantially airtight seal, the bottom plate 141 preferably has a hole 149 defined in one of the center or axis, the hole 149 is preferably internally spiraled, so that when the air bubble generates secondary entanglement into 140 and receive secondary The paper wave scale is applicable to the Chinese National Standard Falcon (CNS> Α 4 Specifications (210Χ297mm) 12 1. 1 f II HI 1 ^ 1 (Please read the precautions on the back before filling in this page) The central sample of the Ministry of Economic Affairs is the employee consumer cooperative ’s printed rice 簟 Α7 Β7. V. Description of the invention (10) The assembly as shown in Figure 3 When installed, the end 127 of Yixu 123 can be screwed into the hole 149. During the interlocking engagement, the distribution housing 150 includes an outer wall 141 and a central roller expansion housing 160. The housing 160 must be a funnel with a hollow stem 170 (a tube or hollow that usually extends from the smaller end of the element) Dry hollow cone-shaped element) and the peripheral extension extending outward from the stem 170 towards the cover plate 180. The peripheral extension 161 preferably extends outwardly from its actuating connection to the outer wall 151 by a continuous band welding or other satisfactory joining device *. An internal annular space 171 is defined in the hollow trunk 170. The shape-like space 171 preferably includes a packaging device 172, preferably a zero-shaped cut. When the chief 170 is slidably mounted on the linear portion of the central tube 111 near the second end 113 of the tube 111, it provides a substantially airtight and Liquid-tight seal. The peripheral extension 161 protruding outwardly defines a plurality of holes 162 therein, and the extension 161 also has a plurality of rolling pipes 163 defined therein. Each fluid pipe 163 is connected to the adjacent liquid pipe by a liquid diverter 164 The roads are separated (as shown in Figure 4). The extension 161 further has a plurality of holes 165 defined therein. The holes 165 must meet the fluid diverter 164 (see the fourth circle), and it is preferably internally spiraled. The combination of the operation of 151 and the central fluid expansion shell surrounds a hollow space 143. The hollow space 143 forms a liquid flow with the hole 162, and when the hole 100 is assembled as shown in FIG. 3, it is aligned with a long annular space 126 〇The outer wall 151 needs to terminate in a flange 152, which is separated from the peripheral extension 161 that protrudes outwards. The flange 152 has multiple paper waves defined by it. The Chinese National Standard (CNS) Α4 specifications apply (210X297mm) 13 ------------- 'outfit-(please read the precautions on the back before filling in this page) Order 313531 Α7 Β7 Ministry of Economic Affairs Central Bureau of Accreditation Unemployment Consumer Cooperative Printing 5. Description of the invention (11) Hole 154, hole 154 It is preferably internally spiraled and aligned with the counter hole 142 in the substrate plate 141, and the outer wall 151 is operatively connected to the bottom plate 141 by a suitable fixing device such as «cap 144. The cover plate 180 has defined therein Most of the holes 181, the holes 181 must be aligned with the axis of the inner spiraled hole located in the outer lip 161, it is necessary to fix the cover plate by using M to actuate the holes 181 and 165, such as the nut fixing device 183, The distribution housing 150, the cladding plate 180 must have a central axis fluid diverter 185 defined therein. When the device is assembled as shown in FIG. 3, the diverter 185 must be a pyramid with a bee point protruding forward, and It must be aligned with the axis of the central duct 111. When assembled, the cladding plate 180 and the central rolling body expansion shell 160 define a hollow fluid distribution space 158, and the cladding plate 180 and the expansion shell 160 also circulate the first channel 163, when When the device is assembled as shown in Fig. 3, the distribution space 158 forms a roller body continuity with the roller channel 163 and the central duct 111. When the handle 190 is used, it is installed for the purpose of covering, and the cladding also has a central hole 188 defined therein. Hole 188 is necessary for the interior The helical M is matched with the outer helical handle. Picture 4 shows the top view circle of the distribution plaque. The hole 162 shown is aligned with the rolling channel 163, and the fluid channel 163 is separated by the diverter 164, as appropriate The shape is zigzag. From the source (not shown) through the conduit 111, the hole 100 sends the second lotus fluid (preferably a liquid liquor) into the distribution space 158, enters the flow channel 163, and at the same time, from the source (Not shown) The first moving roller is transmitted through the passage 122, the chamber 124, the annular passage 126, and the hole 100, and then enters to roll through the hole 162 (please read the precautions on the back before filling this page). The size of the printed paper is applicable to the Chinese National Standardization (CNS) Α4 specification (210X297mm). 14 Central Ministry of Economic Affairs, Central Bureau of Customization, Beigong Consumer Cooperation Du Printing Package, A7 _B7_ 5. Description of the invention (12) Out of the room 143, device 10 and The lotus flow stream and device described in 40 are also applicable to the device 100. It is preferable to select the velocity of the moving fluid or the linear (set to volume) roll rate according to the changes of the device 10, 40 and the device 100 or the like. The moving streamer reaches the desired bubble diameter or size. Those who are familiar with this technique can choose appropriate holes and determine satisfactory operating conditions without undue experimentation, and those who are skilled in this technique can determine the holes contained here without undue experimentation or exceeding the spirit of the present invention. Moderate improvement. As depicted in Figures 1, 2 and 3, the holes in the scope of the present invention can be used in many applications, by way of illustration and not limitation, which include the use of oxygen or modified inlet water for biochemical reactors such as wastewater treatment Mass transfer of gas improves the performance of an oxygen-activated polymerization inhibitor at an upper stage of M in the polymerization reaction, and the mixing degree of at least one gaseous eel in M and roughly improves the liquid sump. In the last aspect, the commercially significant application examples of the mixing device of the present invention are: the production of polymerized carbonates in the solution process, or especially in the interfacial process * where the gaseous sulfonic acid derivatives such as chlorides contain The dihydroxy compound of 2,2-bis (4-hydroxyphenyl) propane in a homogeneous solution containing bisphenol-A and phosphorus oxychloride, or in a two-phase system, in which bisphenol-A is dissolved in Or an aqueous solution of suspended organic matrix, or the presence (in the interfacial process) of an organic solvent (such as methine chloride) that can dissolve the polycarbonate oligomer product of the reaction of bisphenol-A and bisphenol-A.  Thing). Including column flow and continuous stirring reactors, different batches and continuous loops and single operation arrangements have been described or known in this technique, as shown in U.S. Patent No. 4. Cases 737,573 and 4,939,230 and the different reference materials contained in them. The paper size is applicable to the Chinese National Standard (CNS) Α4 specification (210X297mm) (Please read the precautions on the back before filling out this page). Packing and Ordering 15 51So31 A7 B7 V. Description of the invention (13) Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. Those skilled in polyester technology can understand that the shear mixing device of the present invention can be appropriately and necessary applied to different methods. Improve the roller body area established therein, and consider the known interface method, in which bubbling of chlorinated chloroform with methine vapor organic solvent will effectively improve the gasification of carbamide to methine gas The dispersion rate of chemical compounds. In further observation, those skilled in the art can know that the device and method of the present invention can be used to reduce the reaction time * By this, for any dynamic fast reaction gas-liquid reaction system with limited mass transfer, it can be reduced The number or size of reactors required to manufacture a predetermined amount of product (relatively reducing the cost of manufacturing the product), or may allow the existing reactors and methods to produce more products. As is well understood, many oxidation or hydrogenation methods are in this category. For example, in the method of manufacturing vinylbenzene hydroperoxide and t-butyl hydrogen-oxygen compound, it is an intermediate of the known commercial method of M, which is used to produce propylene oxide and styrene, M On the one hand, cracking of propylene oxide and t-butyl yeast, which includes significant reaction time (from 1 hour to 4 hours, see Kirk-Othner book of chemical technology, third edition, volume 19, pages 257 to 261 (1982) ) Of "propylene oxide"), and requires multiple reactors. In this regard, t-butyl hydroperoxides are traditionally oxidized by isobutane liquid-phase gas at 10 to 30 percent t-butyl alcohol and 95 to 150 degrees Celsius temperature and 2075 to 5535 kPa pressure at 20 to 30 Percent isobutane conversion and 60 to 80 percent TBHP selectivity, and 20 to 40 percent TBA conversion. The unreversed isobutane and a portion of the TBA produced are separated from the product and recycled back to the hydroperoxide generating reactor, which can be found in the US National Paper Standard (CNS) A4 specification (210X297mm) ) 16 ------- ^ --- {installed ----- ordered (please read the precautions on the back before filling out this page) A7 B7 Printed by Zhengong Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs Description of invention (14) in the case of National Patent No. 4,128,587. In the case of styrene at 140 to 150 degrees Celsius and 30 to 30 psi a (206 to 175 absolute pressure) of air or oxygen, styrene hydroperoxides can be prepared by liquid orange oxidation to form the conversion of hydroperoxides The rate is over 2 to 2.  The reaction time of 5 hours is said to be 10 to 15 percent. This can be seen in U.S. Patent Nos. 3,351,635, 3,459,810 and 4,066,076. Another obvious commercial application is the use of epoxy resin through corresponding ethylenic gas fermentation, such as from allyl chloride to gas methoxypropyl ring, butene oxide through butene gas ethylation, propylene oxide through propylene chloride Ethylene. Therefore, under a wider understanding, the present invention is more effective for the method of manufacturing epoxide, or, as mentioned above, can be more widely applied to other two-phase gas-liquid inversion methods, which can be improved here The mass transfer from gas to liquid leads to certain benefits. Special consideration is given to the manufacture of epoxides of chlorinated yeast mediators, which traditionally use the production of gaseous olefinic enzymes and the subsequent generation of gaseous alcohols and _Jinqi hydroxide in an epoxidation step. In order to form an aqueous salt solution product containing at least one epoxide, the device and method of the present invention (as further explained below) are separately applicable to the gain and improvement of olefin gas alcohol production. In this aspect, the generation of olefinic gas-substituted alcohols is particularly achieved by contacting a low-degree chemical hypochlorous acid (HOC1) solution with at least one unplaned organic compound to produce an aqueous eaves containing at least one ethyl alcohol gas. product. This "unsaturated organic compound may include 2 to about 10 atomic atoms, preferably 2 to 8 atomic atoms * more preferably 2 to 6 sulfonic atoms, and the organic compound may be selected from substituted; ^ unsubstituted olefin groups, It can be linear, branched or circular, preferably linear. Appropriate paper size is applicable to China National Standard (CNS) A4 specification (210X297mm) 17 ^ ϋ · ^^^ 1 al ^ imnn ^ HI HI I ^ nm m · ^ eJ (please read the precautions on the back before filling this page) A7 B7_ Printed by the Beige Consumer Cooperative of the Central Sample Bureau of the Ministry of Economic Affairs V. Description of the invention (15) Alkenes include pentene, propadiene, butadiene Enene, isopropene, allyl alcohol, cinnamyl yeast, acrolein, 2,4,6 tricresyl, allyl acetate, allyl, ethylene, allyl, methallyl Based on helium, propylene, butene, ethylene, styrene, hexene and allyl chloride and the same article and homologues 0 propylene, butene, ethylene, styrene, hexene and allyl ammonia Preferred olefins, propylene, butene, and allyl nitrogen are more preferred, and propylene is the best. The olefin is preferably unsubstituted, but can also be passively substituted. The term "passive" refers to the substitution of ene plaque with any base plaque that does not interfere with the formation of ethylene or oxyoxide. Passive substituents include gas, fluorine, phenyl, and the like. The epoxidation shown here Additional detailed descriptions of the method and phase-locking gas ethylene have been found in commonly assigned US Patent Nos. 5,486,627 and 5,532,389 (which are incorporated by reference as M). Although the preferred examples of the incorporated patent case and this method include low The use of nitride-based aqueous H0C1 solutions will be easily understood by those skilled in the art. This method can also be applied to hypogasite solutions, typically in the presence of nitrogen equivalent * and can also be applied to gases that are partially or completely dissolved in water The use of gas. For a more ideal result, the typical addition is sufficient to provide an organic compound to the low chloride H0C1 whose ear ratio is greater than 0. 8 of organic compounds. In order to ensure the complete reaction of Η 0C1, it is necessary to provide organic compounds in an amount of at least equivalent, preferably to provide the amount of organic compounds encountered in the reactor from 0 to 25% of its ears, and more preferably from 0 to 10% of the ears of organic organic Compound. Recyclable unreacted organic compounds are suspected to be in contact with HOC 1. When the supply of compounds exceeds the requirements of the reaction * A person who is familiar with this technology can fully apply different known methods to recycle the original paper. The standard is applicable to the Chinese National Standard (CNS ) A4 specification (210X297mm) 18 (Please read the precautions on the back before filling in this page) Packing and ordering 〇 " Ψ Ο ^ o ± c〇31 A7 B7 Printed and printed by the Central Bureau of Economics, Ministry of Economic Affairs, Zhengong Consumer Cooperative ;, Description of the invention (16) Reactive organic compounds. Typically, the M concentration is from about 1 to about 10 weight ϋ: the low chloride aqueous H0C1 is used as a feed, preferably from about 2 to 7 weight; H0C1 in M water shall prevail. This provides a good balance between water tank measurement and the suppression of by-product formation. The organic compound can be brought into contact with the HOC 1 by any method sufficient to generate a gaseous alcohol. Typically it introduces the organic compound and HOC1 into the reactor by a method that maximizes the contents of the reactor, preferably, The contact between the H0C1 solution and the organic compound takes place in a ytterbium or semi-continuous reactor. In continuous reactors, such as a continuous tubular reactor, the injection of reactants and the extraction of products occur simultaneously. The example of a semi-continuous reactor is an organic compound that has already been quantified in the reactor. The reactor, after which the HOC1 solution was continuously injected into the reactor * to produce gaseous ethylene products accumulated in the reactor. More preferably, the suspicion occurs under mixing in a continuous reactor, such as a column flow reactor or a backmix reactor. In a column flow reactor, the reactor is injected at one end and the product is withdrawn at the other end, and there is very little internal mixing in the reactor, such as a continuous tubular reactor. In a reverse-mixing reactor, the reactants are dared to mix with the feed materials to produce a uniform product and reactant concentration in the reactor. An example of such a continuous flip reactor is a continuous flow stirred tank reactor (CSTR) . The conditions of temperature, pressure and reaction time are not necessary. Any conditions in which HOC1 reacts with an organic compound can be applied, preferably M30 to 60. (The temperature of the injection of H0C1 melt into the reactor is more preferably about 40 ** C. Conveniently, since the low temperature requires a refrigerator or other cooling, the reaction temperature of the H0C1 / organic compound is at least 40eC. More preferably, The S degree of the reactor is at least 60 ° C, preferably, the temperature is less than 100 ° C, more preferably less than 90 ° C (to prevent the water in the reactor and the paper size from using the Chinese National Standard (CNS) A4 specification (210X297 Mm) (Please read the precautions on the back before filling out this page) Binding _ Order 19 A7 B7 5. Description of the invention (17 vaporization of organic compounds), and the best is less than about 80. (: (To prevent this ffl degree The formation of the by-products.) When a column flow reactor is used to inject olefin gas into the HOC 1 through a vertical H0C1 solution flow tube, the design of the shear mixing device of the present invention is that the surface speed of the liquid snake is at least 15 inches per second (4. 6n / sec), preferably at least 30 hours / second (9. 1m / sec> and less than about 100 inches / second (15. 2n / sec>, preferably less than 50 hours / second (15. 2i »/ sec), the surface velocity of the gas injected into the liquid flow is at least 3 inches / second (0. 9n / sec), preferably at least about 6 inches / second (1. 8 cm / sec), and less than about 30 inches / sec (9.  lm / sec), preferably less than 20 inches / second (6. 1m / SeC), the ratio of liquid surface velocity to gas surface velocity is at least 1. 0, preferably at least 1. 5, and about less than 10, preferably less than about 8. In order to achieve this condition, when the gas skull body is typically larger than the liquid skull volume, the box requires a novel shear mixing device. When multiple devices are used, sufficient space is provided between the devices so that at least 80S :, preferably at least about 90X of organic matter is reacted when additional organic matter is injected into the liquid stream. By removing the liquid from the reactor, passing through a mixing device, and returning it to the recovery line in the reaction vessel, CSTR is used as a reactor to allow the accumulation of higher liquid snails to flow through the shear mixing device. In this operation, the fresh HOC 1 solution is mixed with the recovery stream in front of the novel shear device or injected into the CSTR container via a separate line. Optionally, an additional CSTR container is provided to assist the traditional mixing device that can maintain the uniform distribution of the reactants and products in the container, such as a traditional mechanical stirrer. In the design of the novel shear mixing device in a special configuration, the liquid The surface speed is at least 15 inches per second (4. 6ni / sec) "is preferably at least 30 inches / second (9. 1m / sec) and less than about 100 hours / second (15. 2a / sec), compared with I ------. . . . . . .  _: Ί 丨 ί Installation-(Please read the precautions on the back before filling out this page) The size of the printed paper printed by the Ministry of Economic Affairs of the Ministry of Economic Affairs of the Beigong Consumer Cooperative Society is applicable to the Chinese national standard (〇 ^) 84 specifications (210 to 297 mm) 20 _ on-V. Description of the invention (18 A7 B7 Printed by the Consumer Labor Cooperative of the Central Bureau of Economic Development of the Ministry of Economic Affairs is less than 50 inches / second (15. 2m / sec). The surface velocity of the gas injected into the liquid stream is at least 3 inches / second (0. 9m / sec) * Preferably at least about 6 inches / second (1. 8cn / sec), and less than about 30 inches / sec (9.  lm / sec), preferably less than 20 inches / second (6. lB / seC), the ratio of the surface speed of the liquid waist to the surface speed of the gas is at least 1. 0, preferably at least 1. 5, and about less than 10, preferably less than about 8. Although typically only a novel device is required to meet these conditions, it is understandable that depending on the reactor shape and size of the applied shear mixing device, it is necessary to use additional devices. In the preferred embodiment using CSTR, the CSTR is operated adiabatically, where the column flow reactor is usually operated isothermally. Therefore, the heat of the reactor is effectively removed from the CSTR by a recovery heat exchanger or a reaction jacket. To minimize external heating and cooling on the reactor, the reaction heat is preferably the same as the raw material feed ffl, so , Anti-mash heat increases the feed temperature to the required reaction temperature. "The coincidence of temperature is also a common practice." For example, one of the thermal reactions with propylene and the like can increase the temperature of the ear H0Π feed concentration (about 5% by weight H0C1> about 551). Therefore, if the reaction temperature is about 9 ° C, the feed temperature is preferably 35 ° C. The smaller difference between the feed temperature and the reaction temperature needs to be cooled, and the larger difference needs to be heated. This temperature control is achieved by any device in the conventional technology, such as the mixing in the tube reaction vessel and the reactor Spiral, or heat exchanger in the external recovery line. More conveniently, the pressure is at least about 2 atmospheres (about lOlkPa) is preferably at least 2 atmospheres (202. 6kPa), higher pressure also strengthens the mass transfer of organic compounds and H0C1 solutions * Conveniently, due to the lower K demand reduces the manufacturing cost of the reactor and reduces the energy cost of introducing gas into the reactor, the pressure is about 7-- . --- Γ 丨 装 ------ booking ----- 竦 (please read the precautions on the back before filling in this page) This paper mounting standard is applicable to China National Standard (CNS) A4 specification (210X297mm) 21 A7 B7 Printed by the Industrial and Consumer Cooperative of the Central Bureau of Economics of the Ministry of Economic Affairs V. Description of Invention (19) Less than 150psig (10. 37kPa), preferably about 100Psig (691 kPa). Due to factors such as the reactants used, the reaction temperature, the desired degree of conversion, the ratio of liquid to gas through the shear mixing device of the present invention, the amount of organic compounds encountered, the pressure of the reactor, the ratio of gasified compounds in the H0C1 feed and the concentration of the H0C1 feed, The time required for the production of chloroacetate also varies. A person skilled in the art can determine the time required for the reaction of H0C1 with organic compounds. For example, when using propylene as the organic compound in the CSTR, and under the above optimal conditions, the reaction time can be reduced as small as 2 minutes, preferably As small as 1 minute, conveniently, the reaction time is about less than 10 minutes, and more preferably less than 5 minutes of furnace to minimize the size of the reactor required to produce a predetermined amount of product. The reaction of allyl gasification is higher than that of propylene. Fast, so the pain requires a minimum reaction time, but the reaction of butene or hexene is slower than propylene and requires more time. The conversion rate of H0C1 in the CSTR is advantageously at least about 90 moles 5; and preferably greater than 98 moles 7, so that, when diluted from the reacted H0C1 solution, the degree of H0C1 in the reactor does not exceed 2 Weight 2 »and preferably less than 1 weight 2. The lower conversion rate is as simple as the separation yield of "Propylene Glycol", which is caused by the oxidation of gas-substituted alcohol products such as propylene-based gas-substituted enzymes (MCA) and other undesirable by-products. Advantageously, in The conversion rate in CSTR is about less than 99. 8¾, if possible, a high conversion rate requires a longer residence time, therefore, a larger device to produce a predetermined amount of product. In order to be consistent with the findings and requirements of the Motarjeni and Jaaeson reference materials described in the introduction of the present invention * and consistent with the aforementioned gas-liquid users, according to this, the method of the present invention involves the generation of small bubbles in the liquid, which is preferred I ---;-^ --- f Form ------- IT (please read the notes on the back before filling in this page) This paper is the standard Chinese National Standard (CNS) A4 specification (210X 297 Mm) 22-Ο Ο-V. Description of the invention (20) A7 B7 The Central Consolidation Bureau of the Ministry of Economic Affairs prints a diameter 1 of less than one tenth of a centimeter (Ub), which is in the scope of the invention! The device is particularly suitable for the method of the invention. This method consists of two functions: each function of contacting the gas with the flowing liquid mole. One function is to place the gas under sufficient S force to generate bubbles when the gas is injected into the liquid skeleton, through at least one hole in the component or assembly Isolate the gas from the liquid. Another role is to consider the physical properties of the gas and the liquid plaque. M—the linear rolling speed is sufficient. M provides a critical Huber number that exceeds the desired bubble size. The Weber number allows the flowing stream to pass through the hole. In fact , The flow rate contributes to the splitting of the initially generated bubbles on the holes * This splitting effectively results in the generation of bubbles with a diameter of less than 0 · lnm. Therefore, the method of the present invention can effectively control the bubbles generated in the liquid shovel. It is better to use the devices 10, 40 and 100 and their changes in combination with this method. M, the size of the bubble is controlled by determining the surface area for mass transfer And then manage the mass transfer from gas ram to liquid. The unitless number called Weber's number is used to predict the formation of bubbles between the bubble and the flow of the crocodile. In "Bubble in the Lotus", G.  J.  Jameson refers to D. on page 588  A.  Lewisn and J.  F.  Davi & on's early achievement "Bubble Splitting in Shear Flow" see Trans.  IChemE Vol. 60, pages 283 to 291 (1982), Jaeeson specifies the "critical Weber number" or WecritM used by Lewis and Davidson to describe the force of trying to split or divide a bubble and try to maintain a bubble size-or strong enough to recover the bubble The critical ratio of up to large size-exceeding the critical Weber number will cause the bubble to split. The present invention uses a shear field M to control the size of the bubble. The field is formed by the liquid generated through the hole initially created by the bubble. If the flowing liquid has a sufficient speed, the shear field will be large enough to exceed the Weber number. , And split the spirit. Gas (please read the precautions on the back before filling in this page) Binding · Order-This paper size is applicable to the Chinese National Standard (CNS) Α4 specification (210X297mm) at Β7 5. Description of the invention (21) The division of the body will continue until the size of the bubble formed meets the critical Weber number. The Weber number is defined by the following equation:

We = r * u * * dm / s where r = liquid density u = velocity of liquid in shear field dni = bubble diameter s = interfacial tension between phases The invention can be used for coalescing liquids such as tap water or as The non-coalesced liquid of the seawater produced by some processes and treatment, or depending on factors such as hydrogen bonding, can be a single flow of coalescence or non-coalescing. As used herein, "coalescence" refers to the fact that once bubbles are generated, the bubbles tend to quickly merge into larger bubbles. As used herein, "non-coalescence" means that once bubbles are generated, the bubbles tend to remain as independent bubbles and maintain their size. The single-flow or feed roller is suitable for containing a polymerization inhibitor of wastewater activated by gas, or the gas may be a reactant in a polymerization reaction that requires mass transfer from the gas skeleton to the foot of the skeleton, another embodiment Among them, air mule can be dissolved in liquid mule. In fixed applications, such as the aeration of saline wastewater, the mass transfer of oxygen into the saline wastewater increases the rate of biochemical anti-sleep, in other words, when the mass transfer rate improves, the amount of oxygen used increases by generating more traditional For small bubbles, the method and device of the present invention effectively improve mass transfer. This improvement comes from consuming energy to produce a shear field. This energy consumption is proportional to the pressure drop of the mixing conduit and the square of the liquid velocity. As shown in Figure 6, the papers and standards are applicable to the Chinese National Standard (CNS &gt; M specifications (210X297mm) I ----.--- j- 丨 installation ------ order ----- T line (please read the precautions on the back before filling in this page) 24 A7 B7 of the Beigong Consumer Cooperative Society of the Ministry of Economic Affairs of the Ministry of Economic Affairs A7 B7 V. The description of the invention (22) shows the actual difference in energy consumption to the bubble size The point occurs in the range from about 50 to 70kPa, although as the energy consumption gradually increases, the surface mass of the mass transfer increases, and the cost of the energy child will exceed the benefits obtained by the mass transfer. The energy cost becomes an uneconomical difference The reversal rate will vary with the choice of end use. In other words, when the effectiveness of oxygen-activated polymerization inhibitors is increased, end use will bear greater energy costs than wastewater treatment. The following examples further define, but do not limit Exemplary of invention. Unless otherwise stated, all parts and percentages are by weight. M 1 at 6 inches by 6 inches in cross-sectional area (15.2 by 15.2 cm (cb), 36 inches (91.4 cm) high propylene The method according to the present invention is carried out in a similar way. The aqueous solution of Μ 10X weight NaCl is injected into the tank Medium to 29.7 inches high, the tank has an open top and its temperature is 68 degrees Fahrenheit (20 degrees Celsius (° C)). The two-phase mixing device used in this example is similar to that shown in Figure 1 It is composed of an outer diameter of 3/8 inch (0.9cm> (0D) —closed end stainless steel internal air duct (15), and it has three 1/64 inch when perforated by 120 ° ( 0.04cm) hole, which is 3/8 inches from the closed end. The outer two-phase mixed body is processed from a 3/8 inch (0.9cm) PVC pipe processed to 0.423 inches (1.1cm) inner diameter (ID) Nipple, the rest of the device consists of a 1/2 inch (1.3cm) PVC pipe T-shaped, a stainless steel 1/2 inch (1.3ca) male pipe spiral to 3/8 inch (0.9 cffl) of the tubular connector, which is punctured by a tube that meets a 3/8 inch (0.9cn), M and two values l / 2 (1.3c ·) to 3/8 inch (0.9CH) tube One of the bushings is connected to one of the ends of the T-shaped tube, and the 3/8 inch (0.9 cm) tube is connected to the bushing through a connector, the tube to the tube and the paper size is suitable for t National Standard (CNS) A4 specification (210X297mm) 25 (Please read the notes on the back first (Fill in this page) Binding-Book 5. Invention Instructions (23) A7 B7 The Printed Connector of the Beigong Consumer Cooperative of the Central Bureau of Economics of the Ministry of Economic Affairs is connected to the other tube end of the T-shaped object, and is 3/8 inches (0.9 c ·) The tube is inserted into the first end of the two closures through the connector until the tip of the tube just meets the end of the nipple, leaving the three-tilt 1/64 inch (0.4ca>) hole in the nipple. Using the second bush, place The two-phase mixing device is connected to the 1/2 inch (1.3c ·> mother tube solenoid port at the center of the bottom of the tank, so that the mixer is vertically discharged into the tank and discharged from the March TE-5C-MD centrifugal pump The pipeline is connected to the remaining port of the T-shaped object. The pump suction pipe is connected to the 1/2 (1.3ca) female solenoid port in the corner edge of the bottom of the tank. The Wallace and Tiernan type 5120M12333XXXL Varea-Meter flowmeter is located at the discharge The amount of M in the tube is low. Connect a gas supply tube to a 3/8 inch (0.9cb> tube), and measure the gas roll rate with a Matheson mass roll conveyor with a Matheson multi-flow controller model. The liquid flow rate is 1.75 gallons per minute (GSP) (11X10 · 9 cubic meters per second U3 / cm), and the air flow rate is 1.235 Supper Liter Per Minute (SLM). At this rate, the coffin is filled with small bubbles with a milky, almost opaque appearance. Suspend a 1/8 inch (0.3ca> thick black rubber plate from the top of the tank and extend down into the tank about one and a half feet below the liquid level <0.46a) to position the plate at A few centimeters on the front wall of the trough, a background where bubbles can be observed in the field of the partition can be observed. A video camera with a magnifying glass is used to record the color image of small bubbles in the acrylic plate in the trough and print a 1 Bm on the transparent The grid of the board is cast in the groove, and it can also be monitored to calibrate the display. Use a fine-tuning and fast-forward video recorder to view the recording tape, so that each lens in the recording tape can be analyzed, using a centimeter ruler Measure the bubbles displayed on the lens * This method can also be used to view and display the shadow band head of the 1BB grid. (Please read the precautions on the back before filling in this page). The size of the bound paper is applicable to the Chinese National Standard (CNS) A4 specification (210X297 public daughter) 26 Α7 Β7 V. Description of invention (24)-The grid division of the display , The resulting magnification is about 60 to 1 (measured 1 mm = actual 0.015 4 m pass> 0 in a lens, Μ0 · 047ββ to 0.154a · ten fan, Μ 0. 155 to 0.23lmm four Fan letter and the three range of 0.232 to 0.385 to observe bubbles with a size from 0 to 0.046mm, the smallest bubble that can be measured is 0.0154iib * and the largest bubble observed by the lens is 0.385πηη. Example 2 According to the American Society of Civil Engineering (ASCE) ), In the unsteady state program of clean water designed as a shear mixing device for salty wastewater (standard for measurement of gas transmission in ladle water, American Civil Engineering Association of New York (1984)) and the device shown in No. 2 The oxygen transmission test is performed on the sample, and the comparison between the measured result and a known commercial coarse bubble diffuser is shown in Table I. (Please read the precautions on the back before filling in this page) Pack. Order the Central Ministry of Economic Affairs Bureau Industry Consumer Cooperation. Du Yinmo paper standards Applicable _ National Standard (〇 '«) 8 4 specifications (210 \ 297 mm) 27 318531 A7 B7 V. Description of the invention (25) Test the number of diffusers Lin I table fswfm) Water flow (liters per minute / gallon per Minutes> ki ^ ao (1 / hour) 12 3 4 5 6 7 SAE (1 pound oxygen HP / h) coarse diffuser 1 2 50.9 / 1.7 0 1.6 1.7 shear mixer 22.4 / 0.75 49.2 / 13 3.3 2.6 shear Mixer 38.9 / 1.3 49.2 / 13 5-1 2.5 Shear mixer 50.9 / 1.7 49.2 / 13 6.2 2.5 Shear mixer 53.9 / 1.8 49.2 / 13 6.3 2.5 Efforts to mix 101.8 / 3.4 49.2 / 13 9.7 1.8 Shear mixer 53.9 / 1.8 49.2 / 13 15.4 5.7 (5¾ Weiliang) (Please read the precautions on the back before filling in this page) Printed by Beigong Consumer Cooperative of the Central Rubbing Bureau of the Ministry of Economic Affairs -28-1 SAE = quasi-air exposure efficiency ( 1 pound of oxygen per horsepower per hour) 2 The example of the present invention is to directly compare the shear mixing device with the coarse bubble diffuser, using a ct value (which is defined as the ratio of the k # values of the two measurement systems), in this example In the reference state, the reference standard is: use the coarse bubble diffuser and tap 1 of the tap water, use the tap 1 and 4, in the tap water, α shear mixer (trial 4)

Vkda. CBD (Trial 1> = 3.9 Use Trial 1 and 7, in 5Z brine, a = kLaa. Shear mixer (Trial 7) / kLaa. CBD (Trial 1) = 9.6. In Table I The data shows the effectiveness of the present invention relative to the conventional coarse diffuser. An alpha value greater than one unit (1.0) indicates a more effective mass transfer relative to the shear mixer of the coarse bubble diffuser. It is believed that at least part of the increase in mass transfer column is formed For an increased surface pitch, the increased surface area is greater than the average bubble size of the shear mixer. The typical average bubble size of the coarse bubble diffuser is small. The alpha value of the salt-containing test solution (trial return 7) implies that for a Tap water (The standard of this paper is the Chinese National Standard (CNS) Α4 specification (210X297mm) Α7 Β7 ^ 13531 5. Description of the invention (26) 1) The mass transfer improvement of the coarse bubble diffuser is at least partially caused by the liquid The non-coalescing characteristics of 酦, in other words, once formed, the bubbles are easy to maintain their independence and will not merge or mix with other bubbles. 倒 _2_The introduction of the gas-liquid shear mixer installed in the military process is to eliminate the tenth order reaction The generation of free radical polymer at the t stage before the device In one of the sections, t new gas / liquid shear mixers of the device are used to improve the gas dispersion in the reaction mixer. Except that there is only one hole 54 in the first conduit 50, this shear mixing device is as shown in Figure 2. Shown (device 40), oxygen in the air activates the free radical inhibitor in this system. Before this shear mixer device, the polymer present in the first to tenth stages and about 0.5 cubic feet ( The polymer of 0.014b3) is collected by filtration every eight hours, and the gas / liquid shear mixing device is operated at a flow rate of 11.5 SLM and a solvent rolling speed of 1.0 gallon per minute (6.3 * 10 · 9β3 / sec). The device has a hole diameter of 3/16 inch (0.5 &lt;: »〇, and a hole length of 1 inch (2.5 &lt;: 1»), and the gas skull and the solvent are mixed outside the to-be-decided counter vessel and passed through a tube Enter the shear mixing device located in the reactor. Due to the device of this shear mixer, the K of the polymer in the first seven stages is reduced, and the polymer formation is reduced to 0.025 cubic feet (0.007cb3> every eight hours. The mixer in this example has only one hole for generating bubbles, which can be strengthened by additional holes ， People who are familiar with this technology can definitely determine the number of holes based on their use without extra experience. M 4. Install a 200 gallon container in a gas / liquid shear mixer, the container is made of Μ Free radical polymerization. The degassed water of organic compounds, the size of the paper on the air is not used in China (CNS> A4 specifications (210X297mm) ----.------ f pack-(please Read the precautions on the back and then fill out this page) Ordered by the Central Standards Bureau of the Ministry of Economic Affairs to print the cooperation with the laborers. 5. Description of the invention (27 A7 B7 Oxygen in the printing of the negative work consumer cooperative of the Central Bureau of the Ministry of Economic Affairs. The conventional free radical inhibitors operate gas / liquid shear mixers (such as No. 3 sink) at a flow rate of 4.0 quasi-cubic hourly minute (SCFM) airflow and 50 gallons per minute (0.19n3 / aii〇). Used by> The initial batch of organic monomers contained about 2% by weight of water, and within 12 hours, degassed to 0.0500% M, the degassed state was 80 »nHg absolute pressure and 60. C. The four picking batches degassed by this method did not form any polymer in the gas. Example 5 A vessel with a diameter of 0.6m and a height of 4.57m is filled with a sludge activated sludge produced by an industrial wastewater treatment plant with a height of 4.27. * The total solid floatation (TSS) is 2600iag / L, use Brooks Instruaent Mass Controller (5851 Type I) measured 5SLM nitrogen to purge 0.086m3 of space volume, M 〇.19m3 / h to feed the feed solution and let it stay for 6.3 hours. The feed solution is from the industrial oxidation plant. 70g / LH degree (approximately 7 weight percent) wastewater, the substrate concentration is 150ag / L, using a pore diameter of 0.005η and M Brooks Instrument. Mass Controller (5851 I mode) Lan De's 1.14SLM oxygen state gas exposure system , And let the system stand for 1 hour, MIngold Electronic IncDO sensor / wheel (type 4300) knows that the concentration of dissolved oxygen is lng / L, using Teledyne Analytic Instrunents TAI 322 multi-channel oxygen detection The oxygen output measured by the system is 15.9%, which produces an oxygen transfer efficiency of 233: Here, the oxygen is introduced into the shear mixing device shown in the second circle of the present invention with the original oxygen and all parameters. The oxygen exhaust concentration immediately fell, and the calculated Oxygen transmission efficiency immediately rises. After t shoveling, the transmission efficiency is 50X and the oxygen exhaustion rate is 10.2%. This paper is again applicable to the Chinese National Standard (CNS) A4 (210X297 mm) 30 (please read the back Please pay attention to this page and then fill out this page) 袈-Order the Ministry of Economic Affairs Central Bureau of Industry and Commerce Beigong Consumer Cooperatives to print Α7 Β7 i 'Instructions (28) Thirteen minutes later, the transmission efficiency is 70% and the oxygen concentration is 6.4Z, Fifty-two minutes later, the Fu delivery efficiency was 90¾ and the oxygen exhaust wave was 2.2%, which formed a spike value, and thereafter, the dissolved oxygen quickly rose to a steady state of 5ag / L. Example 6 Leather 8 Vertical installation , And equipped with a vertical baffle and a stirrer with one or two mixers in the cylindrical CSTR Example 6 to 8 and Comparative Examples A and B, Comparative Examples A and B use a value of 5 inches in diameter Cheaineer CD-6 low blender and a 5 inch diameter Lighting A-315 high mixer. Examples 6 to 8 use only a 5 inch diameter Lighting A-315 mixer. In Examples 6 to 8 , Continuously add the aqueous HOC1 solution to the center of the mixer, pump the liquid from the bottom of the CSTR, and pass it through a recovery line The mixing device of the present invention, which is located outside the CSTR and has an internal diameter of 0.295 inches at the inlet port of the container (as shown in Figure 3), sends the liquid back to the CSTR located below the bottom of the mixer, olefin gas It was fed into a mixing device perpendicular to the liquid flow through a 0.295 inch-hour tube with an internal diameter, and the product was continuously recovered through a recovery line to maintain the level of liquid murine in the CSTR. In Comparative Examples A and B, the aqueous H0C1 solution was continuously added near the center of the low mixer, and the dioxirium was continuously added to the low mixer through a 4 inch diameter distribution ring composed of a 1/4 inch diameter pipeline Beneath it, the diffusion cut has holes with a pitch of 1/32 inch uniformly distributed along the ring, and the product is continuously recovered via the bottom pump to maintain the liquid level in the CSTR. Use a novel shear mixing device to produce propylene gas ethanol at a pressure of M50psig, a temperature of 69eC Μ and a stirrer speed of 400 per second to operate the above CSTR, M 2551 b / h will be 5.87 · weight Λ H0C1 solution this paper again Applicable to the Chinese National Standard (CNS) Α4 specification (210X297mm) 1— -... I (please read the precautions on the back before filling in this page)-* 1Τ A7 B7 5. Description of the invention (29) and 2151b / h of water is added to the reactor, and the liquid is recovered at a rate of 32001b / h through the mixer, thereby providing a surface liquid velocity of 3in / sec. To achieve a surface gas velocity of 10ft / sec and a liquid and gas velocity of 3: 1 (M 12.51b / h rate of propylene gas was added through the mixer, M 483Ib / h rate from the bottom of the CSTR continuous recovery of the product, 2 minutes of wok reaction time can provide 98. (UH0C1 conversion rate Μ and The yield is 98.0X propylene gas ethanol (based on propylene). Comparative Example A Production of propylene chloroethanol using a conventional gas distributor M50 psig pressure, 71 ° C temperature M and agitator 560 per second operating the above CSTR , Add 5.65% by weight of H0C1 solution and 631b / h water at 1151b / h Reactor, M added propylene through the loop distributor at a rate of 4.71 b / h, and M 101 b / h recovered the product from the upper part of the reactor. The speed of M 183 lb / h continuously removed the product for 12 minutes. The reaction time can be provided 98.0% 11001 conversion rate and yield 97.5:!; Propylene «ethanol (subject to propylene). Then LZ_ uses a novel shear mixing device to crack butenes" Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Ethanol Economy- ---------- (Install-(Please read the precautions on the back before filling in this page) Set the rate of 8.11 b / h using butene and repeat the procedure of Example 6, the reaction status is 20psU Pressure, temperature of 66 ° C and a single mixer speed of 400 per second, the liquid feed is 5.65 of 1501b / h; the weight of 110 (: 1 solution and 1681b / h of water is 31.910ft / sec The speed of surface gas *, the rate of M 34001 b / h recovers the propylene liquid from the shear mixer, the speed of the surface gas is 11.8% / 36 «:, which provides a liquid to gas rate ratio of 2.7, with 3261b / The rate of h continuously recovers the product from the bottom of the CSTR, and the reaction time of 3 minutes of shovel can provide 99.8:! ^ 0 (: 1 conversion rate and Yield 94.95; Butene Gas This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm) -32 32 A7 ____B7___ 5. Description of the invention (30) Ethanol (M butene shall prevail). hh fg Example B The cracking of butene gas ethanol using a traditional gas distributor uses butene as the feed gas skeleton, and the rate of M4.71b / h is added to the distributor for the procedure of Comparative Example B. The reaction condition is 20 psig Sleeping power, with a mixer speed of 550 rpm, the feed liquid is 4.9 weight 3; and the rate is 95.51b / hr H0C1 solution and 57.51b / h water, M1581b / h successively remove the product, 15 minutes The reaction time can provide a conversion rate of 99.5 ϋίΗΠ and a yield of 94.25: butene gas ethanol (K butene prevails.) Example 8-The use of a novel shear mixing device for the manufacture of hexene ammonia ethyl fermentation using 7.21 b / h The procedure of Example 6 was repeated with hexene instead of propylene. The reaction conditions included a pressure of 3.8 psig, a temperature of 78 ° C and a stirrer speed of 450 rpm, and the feed liquid was a H0C1 solution with a weight of 2.14, a surface speed of 29 ft / sec. , M 30801b / h rate, the liquid is recovered from the anti-hardening device through the mixer, the surface gas speed is 29ft / secM to provide a liquid-gas speed ratio of 1.0, the product is continuously removed at 16611) / {1, 14.4 points sickle The reaction time can provide 1002 HOC1 conversion rate Μ and yield 88.2 2Hexene gas ethanol (M hexene shall prevail.) (Please read the precautions on the back before filling in this page) 袈 · Order the Central Standardization Bureau of the Ministry of Economic Affairs to print this paper for the industrial and consumer cooperatives. The paper standard is applicable to the Chinese National Standard (CNS ) Α4 specifications (210 × 297 mm) _ 3 3 A S1S531 A7 _B7 printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (31) Comparison table of component numbers 10, 40, 100 Device 126, 171 annular space 12, 42 First end 140 Air bubble generation sub-assembly 13, 43 Second end 141 Bottom plate 20 Second flow supply pipe 144 Nut 21, 61 Channel 150 Distributor shell 25 Plunger 151 Outer wall 14, 19, 26, 27, 44 , 45,54 Hole 152 Flange 50 Conduit duct 158 Distribution space 60 Conduit 160 Expanded shell 149 Hole 161 Peripheral extension 111 Central duct 163 Roller channel 112,125 First end 164,185 Diverter 113,127 Second end 170 Hollow stem 120 receiving Yi plaque 172 encapsulation device 122 channel 180 cover plate 123 transfer shell 188 central hole 30,55, 124 hollow chamber 190 handle (please read the precautions on the back before filling in this page) 'installation. The size of the printed paper applies to China National Standard (CNS) A4 specification (210X297mm) 34

Claims (1)

The Ministry of Interest and Economic Affairs of the Ministry of Industry and Information Technology of the Ministry of Industry and Consumers Co-printed Α8 Β8 C8 D8, patent application 1. A shear mixing device, including: at least one conduit carrying a first fluid to be mixed with Μ , Which has an open first end and a closed second end that receive the first plaque to be mixed with M, and has one or more holes defined in each of the conduits close to the closed second end, through which , The fluid received from the open first end flows out of the duct; a mixer body generally defined by the duct or ducts and having a closed first end, the closed first end defining a corresponding hole or Each hole passes through each of the holes, and the mixing body further has a second end, which defines a shrinkage hole having each of the tubes and is opposite to the one enclosed by the mixing fish and by the mixing body Closing the defined hollow space between the first end and the second end, the holes in each of the ducts are generally located in the narrow holes connected to a specific duct; and a second flow eluent supply duct, which is The hollow enclosed by the mixed mule Space connection, using M to provide a second fluid, which meets one or more narrow holes at the second end of the mixer main body and is supplied in the form of a shear force by holes located in the respective narrow holes The top plaque mix. 2. The device as described in item 1 of the patent application scope, wherein the conduit for supplying the first stream to be mixed with Μ is fixed to the corresponding hole in the first end of the «by means of a large leakproof seal Inside. 3. The device as described in item 1 of the patent application scope, wherein the narrow hole connected to a holding guide tube is in the form of a longitudinal annular space, which has the shape of a hollow positive figure column. The size of this paper is easy to use Chinese National Standard (CNS) Α4 ^ grid (210X297mm) (please read the precautions on the back first and then fill out this page) Binding-Order 35 Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Cooperative Consumer Cooperative Α8 Β8 C8 D8 6. Scope of patent application 4. The device as described in item 1 of the scope of patent application, in which the holes close to the closed second end of a specific conduit are isolated from each other. 5. A shear mixing device, comprising: one or more conduits for providing a first roller-headed snakehead to be mixed with M, each of the conduits defining one or more holes extending along the length of the conduit; a mixer body , Having a first end and a second end and defining a substantially enclosed hollow space between the first and second ends, which is in fluid communication with a fluid supply conduit, the first and the first of the mixer body The two ends each have an opening M defined therein, and a duct with a hole passing through it. In this way, the duct providing the first stream to be mixed is in fluid communication with the hollow space. 6. The device as described in item 5 of the patent application, wherein each holed duct forms a substantially leak-proof seal with the corresponding opening in the first and second ends of the mixer body through which the duct passes . 7. The device as described in item 6 of the patent application park, in which the holes in each tube are isolated from each other. 8. A shear mixing device, including a middle air body and flow receiver sub-assembly, a bubble generating sub-assembly, and a selective handle, the air plaque and fluid receiving sub-assembly is in motion with the bubble generating sub-assembly The assembly is connected and forms flow communication. 9. The device as described in item 8 of the patent application, wherein the gas and liquid receiving subassembly includes: an open inlet end for receiving a fluid and an outlet communicating with the bubble generating subassembly The middle tube at the end; and the paper size is applicable to the Chinese National Standard (CMS) Α4 specification (210X297 mm) (please read the precautions on the back and then fill out this page) 袈 · Book 36-313531 A8 B8 C8 D8 VI. Apply for a patent The Ministry of Economy, Central Bureau of Standards, Employee and Consumer Cooperative ^ produces a gas-receiving shell, which is roughly encased in the middle duct and separated from it, thereby defining a passage for gas to flow to the bubble generating sub-assembly, and includes at least A passage through which the gas received by M and the passage through the bubble generating sub-assembly is connected, and the gas-tight receiving shell M has an airtight relationship connecting one end to a point on the central duct that is closer to the entrance end The exit end is relatively high. 10. The device as claimed in item 9 of the patent scope, wherein the bubble generating sub-assembly includes a bottom plate, whose M gas-tight relationship is connected to the intermediate pipe adjacent to the outlet end of tt, one for containing and distributing Separate from the gas-receiving shell and the middle conduit of the gas plume and the gas stream and the flow stream distribution shell, and its M-airtight relationship is connected to the bottom plate, and a cladding is a gas-tight type Connected to the gas and fluid distribution shell in turn, the gas and flow distribution shell has a middle, funnel-shaped fluid expansion shell, the bottom and the cover plate form the secondary formation component of bubbles into an upper flow expansion chamber and a lower «Expansion chamber, the funnel-shaped rolling skull expansion shell has a hollow tube that is sealed in a gas-tight manner over a part of the intermediate tube near the outlet end of the intermediate tube, and a protrusion extending outward from the hollow tube, The peripheral extension portion has a plurality of holes defined therein and communicating with the gas expansion chamber, and a plurality of flow chambers in fluid communication with the expansion chamber of the flow tank, the holes are in communication with the flow skull grooves, Mix with M in general encounter At the gas and fluid Po send key. 11. The device as described in item 10 of the patent application, wherein the roller channels are isolated from each other by fluid distributors, and the fluid distributors are defined to extend outward from the hollow stem and extend peripherally . This paper scale is applicable to China National Standard (CNS) Α4 specifications (210Χ297mm) (please read the notes on the back before filling out this page). Order 37 Printed by the Central Bureau of Standards of the Ministry of Economic Affairs, Co-operative Consumer Cooperative Α8 Β8 C8 D8 々, apply Patent scope 12.-A method for generating bubbles in a fluid, including: a. When introducing gas into the liquid chamber through the holes in the component or element separating the gas and the liquid, place the gas in a sufficient amount to form bubbles Under the pressure; b. The fluid is flowed through the hole at a linear rate of a Weber number that exceeds the critical Weber number of the gas and the flow through the hole, so that a bubble with a diameter of less than 0.1 mm can be generated in the liquid plaque bubble. 13. The method as described in item 12 of the patent application scope, wherein the gas system reacts with the components contained in the stream or a stream. 14. The method as described in item 13 of the patent application scope, wherein the reaction gas is at least one of chlorine, bromine, iodine, oxygen, or an oxygen-containing hydrazine. 15. The method as described in item 14 of the patent application scope, wherein the oxygen-containing gas is air. 16. The method as described in item 12 of the patent application park, in which the gas leech can be mixed with the liquid gas. 17. The method as described in item 16 of the scope of patent application, wherein the liquid molybdenum is methine chloride and the gaseous compound includes sterilized gas. 18. The method as described in item 12 of the patent application scope, wherein the fluid is a non-coalesced flow S. 19_ The method as described in item 18 of the patent application plaque, wherein the non-coalesced flow system is a saline wastewater. 20. The method as described in item 19 of the patent application Fan Xing, wherein the stream system contains a waste water stream and the gas is oxygen, air, or oxygen-enriched air. 21. The method as described in Item 12 of the patent application, in which the mobile stream paper &quot; ^ · applies to the Chinese National Standard (CNS) (210X297mm) (please read the precautions on the back before filling this page ) Order 38 A8 B8 C8 D8 6. The speed of applying for the scope of patent is about at least 20 feet per second. 22. The method as described in item 12 of the scope of the patent application, wherein the roller system comprises a monomer stream of a polymerization inhibitor that can be activated by oxygen, and wherein the gas system contains oxygen or an oxygen-containing gas mixture. 23. The method as described in item 12 of the patent application scope, wherein the roller system is a low-vaporizer aqueous hypochlorous acid solution, an aqueous hyponitrous acid solution or a chemical compound dissolved in water, and the gas contains an unsaturated Organic compounds »When the unsaturated organic substance and one of the liquid are poured under the mixing conditions, a reaction product with an olefinic chlorohydrin product is formed. 24_ The method of claim 23, wherein the unsaturated organic compound is selected from the group consisting of propylene, butylene, and propylene. 25. The method of claim 24, The unsaturated organic compound is propylene or allyl gas. 26. The method according to item 25 of the patent application scope, wherein the unsaturated organic compound is propylene * and the olefinic gas alcohol formed by it is propylene chloroformase. Printed by the Consumer Cooperative of the Central Bureau of Economic Cooperation of the Ministry of Economic Affairs n In ml 1tn «In nn nn ^ 一« ^ — ^ 1 In ^^^ 1 ^^^ 1 ml ^ eJ (Please read the notes on the back before filling this page ) 27. A method for forming air bubbles in a first-class eel, the air bubbles having a diameter of less than about 0.1 mm, the method includes using the device as described in item 1 of the patent application scope to introduce the air dew The flow through the narrow hole of the hole "the formed shear zone" The fluid flows in such a way as to form a pressure drop across the narrow hole of less than about 49,000 Pascals and the gas is sufficient to constitute the conduit and coupling One of the narrow tubes has a pressure drop of less than about 35,000 Pascals. This paper uses the Chinese National Standard (CNS) Α4 specification (210X297 mm) -39-313531 abI C8 D8 —________—- 6. The patent application scope 28. — A method of manufacturing monoolefinic aerosols with Μ By combining unsaturated organic compounds with a rolling low gasification compound, aqueous hypochlorous acid solution in a gas mandarin in a reverse mixing reactor by combining the unsaturated organic compound in the gas mandarin under conditions suitable for the formation of the gaseous alcohol. The improvement includes increasing the mass transfer of the unsaturated organic compound from the gas phase into the fluid secondary acid solution by supplying the unsaturated luxury compound to the fluid secondary gas in the form of small bubbles having an average diameter of less than about 0.1 mm Acid solution. 29. An interface method for producing polysulfonates, in which a dihydroxy compound is reacted with a basic acid derivative in a reaction mixture, and its special feature is that it has both an aqueous phase and an organic phase, in which poly-solic acid The vinegar product is soluble and accumulable, and wherein the sulfonic acid derivative is supplied to the reaction mixture with at least a portion of M as a gas, the improvement comprises M gasifying in the form of small bubbles with an average diameter of less than about 0.1 mm Sulfonic acid derivatives are supplied to this method. (Please read the precautions on the back and then fill out this page) Binding 'Order Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs This paper uses the Chinese National Standard (CNS) Α4 specification (210X297 mm) 40