312705 A7 B7 五、發明説明（） ，<^為〇或正數，b/a=0.5〜4.0，c/a=0〜1.0，n/m=0.5 〜2.0〕；及， R - C - L II 0 II) r.f 1ί Y A ψ 拿務· 會餐基〕 經濟部中央標準局負工消费合作杜印¾ 〔式中，L為離去基，R為碳數11〜13之直 Μ下，詳細說明本發明。 本發明中，U)成分之結晶性矽酸鹽必須對於從後述 之漂白活性化劑所生成之有機過酸安定性。本發明所使用 之結晶性矽酸鹽為上述式（I )所示之結晶性矽酸鹽，且具 有100mg CaC03/g Μ上之離子交換容量者或其水和物。離 子交換容量不足100mg CaC03/g之結晶性矽酸鹽幾乎無助 於提高有機過酸之安定性。 前述式（I)中Μ為選自氫原子及遇期表la族之元素中 。週期表la族元素之例如Na、I(等之鹼金屬元素。Μ亦可 使用單一之元素，亦可使用複數之元素。亦即，Ma0成分 亦可爲如Nas0與Ka0之混合物。 Me為選自遇期表之la、lb、Ha、IV a及VI族元素之 中，如此元素之例如Mg、Ca、Zn、Y、Ti、Zr、Fe。本發 明中Me所使用之元素若為上述限定範圍内，無特別限定， MMg、Ca、Fe為佳。Me亦可使用單一元素，亦可使用複數 之元素。亦即，Mem〇n成分亦為如MgO與CaO之混合物。m、 η分別爲n/m成為(h 5〜2.0之正數。n/m為配位於Me-原子之 氧離子數，實質上選自0.5、1.0、1.5、2.0之值。 本發明使用之結晶性矽酸鹽亦可爲水和物。此時，每 {請先閲讀背面之注意事項/填寫本頁) -裝· 訂 線 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 6 經濟部中央揉準局負工消费合作社印裝 312705 A7 B7 五、發明説明（) 一分子之水和量爲〇〜15(換算Hs0之冥耳量）。 於前述式（I )中，b/a為0.5〜4.0 ’以1.0〜1,8為佳 。b/a為不足0.5之結晶性矽酸鹽則耐水性不彰，為超過 4.0之結晶性矽酸鹽則離子交換能低，作為離子交換體之 性能不彰。 前述式（I )中，c/a為0〜1_0, M0.01〜0.8為佳。 c/a爲超過1.0之結晶性矽酸鹽則離子交換能低，作為離子 交換體之性能不彰。 a及b分別為正數，c爲0或正數，但，此等只要b/a及 c/a在前述之範圍内即可，並無特別限定。又，如前述， aM»0為如a’Na»0與a”K,0之混合物時，a為a’ + a”。此對於 c亦相同。 本發明中（a)成分所使用之結晶性矽酸鹽可Μ很容易 依歐洲專利第 550048 號或 Phys· Chem. Glasses., 2_, Ρ. 127〜138 (1966)、Ζ· Kristallogar., ρ· 396〜 404 (1969)所記載之方法調製。該結晶性矽酸鹽，例如為 使a、b、c之各值成為目的之結晶性矽酸鹽，乃以預定之 量秤取原料成分，混合，所得到之混合物通常Μ 300〜500 C、較佳係500〜1000C，更佳係600〜9001燒成而使之 結晶，即可製得。此時，燒成溫度不足300它時，因結晶 化不彰*所得到之結晶性矽酸鹽之耐水性差，此外，若燒 成溫度超過1500¾，結晶性矽酸鹽之粒子會變粗大，所得 到之結晶性矽酸鹽之離子交換能低。燒成時間通常為0.1 〜24小時。如此之燒成可於電氣爐、瓦斯爐等之加熱瀘實 本紙張尺度適用中國國家標準（CNS ) A4规格（210X297公釐） 7 I — — — — — 裝 I I I 訂 I I I I 線 (請先聞讀背面之注$項一V填寫本頁) 一 312705 A7 B7 S03Ni 五、發明説明（) 施。又，燒成後，所得到之結晶性矽酸鹽視需要可粉碎成 預定之粒度。本發明所使用之結晶性矽酸鹽的粒度無特別 限定，但Μ0·01〜ΙΟΟμιπ之範圍内為佳。 本發明之成分的結晶性矽酸鹽亦可使用市售者例 如八牛又卜社製之層狀矽酸鹽（商品名：SKS-6〉。 本發明所使用之（a>成分的結晶性矽酸鹽，必須作爲 (B)成分之漂白活性化劑於水中發生之有機過酸的安定化 劑。本發明組成物含有（a>成分0.1〜20重量％ (M組合物 全重量為基準）、較佳係1〜15重量％、尤Μ 2〜10重量％ 為佳。（a>成分之量不足0.1重量％時，於水中之有機過酸 無安定化效果，即使調配多於20重量％，其安定化效果未 被改善，經濟上不利。 本發明之必須成分即（b)成分係於水中與過氧化氫化 應而產生有機過酸，即以前述式（I)所示之漂白活性化劑 。式（Π〉中之L的離去基之例可舉例Μ下述式U)所示之 基及下述式（IV)所示之基。 dll) 1^ I n 111 II ! ϋ 11 ^ I 線 (請先《讀背面之注$項一/填寫本頁) 一 經濟部中央標準局負工消费合作社印簟 COONa (IV) 户1 <· 「正卞 章制 式（Π)中，R之烷基為直鏈且碳數11〜13者。具有磺 數10M下之烷基乃不安定，且易分解，此外，具有碳數14 以上之烷基者，未顯示所希望之漂白力。 式U>所示之漂白活性化劑之中，尤佳者為Μ下述式 8 本紙張尺度適用中國國家標準（CNS ) A4规格（210X297公釐） Α7 Β7 經濟部中央標準局貝工消費合作社印製 五、發明説明（） (V)所示之化合物：c. |H23 - c - 0 -^〇y_s〇3Na ο 本發明化合物含有（b)成分0.1〜15重量 全。量為基準、較佳係1〜10重量％、尤佳係2〜7重fi%。 (b)成分不足0.1重量％時，無漂白效果，另外，超過15重 量％時，於水中產生之有機過酸會與漂白活性化劑反應， 成為二醯基體，溧白力降低。 (b)成分之漂白活性化劑可於水中與過氧化氫反應而 產生有機過酸。因此，爲了漯白，遇氧化氫為必須的。本 發明中係組合過氧化氫放出體舆漯白活性化劑來使用。 (c>成分之過氧化氫放出體之例如粒狀或粉狀體之過 碳酸鹽、過硼酸鹽、過磷酸鹽、過矽酸鹽，其中，Μ遇碩 酸鹽有效，尤以過碳酸納為有效。 本發明組成物含有過氧化氫放出體1〜20%重量％ (以 組成物全重量為基準），較佳係2〜15重量％。此董不足1 重量％時，無充分之漂白性能，另外，此量即使超過20重 量％，漂白性能並未充分提高。 本發明之必須成分即（d)成分之非離子界面栝性劑具 有於25C中為漿泥或液體之特徽。若使用25 C下為固體之 非離子性界面活性劑，則無法得到優異之漂白力。 本發明有用之非離子界面活性劑如聚氧乙撐烷基醚、 聚氧乙撐烷基苯基_、聚氧乙撐葡萄聚糖脂肪酸酯、聚氧 乙撐山梨糖脂肪酸酯、聚乙二醇脂肪酸醋、聚氧乙播烷基312705 A7 B7 V. Description of the invention (), <^ is 〇 or positive number, b / a = 0.5 ~ 4.0, c / a = 0 ~ 1.0, n / m = 0.5 ~ 2.0]; and, R-C-L II 0 II) rf 1ί YA ψ Naomu · Meeting base] Duin, the consumer cooperation of the Central Standards Bureau of the Ministry of Economic Affairs DU [In the formula, L is the leaving base, and R is the direct number of carbon numbers 11 ~ 13, detailed The invention is illustrated. In the present invention, the crystalline silicate of U) component must be stable to the organic peracid generated from the bleach activator described later. The crystalline silicate used in the present invention is a crystalline silicate represented by the above formula (I) and has an ion exchange capacity of 100 mg CaC03 / g M or its hydrate. Crystalline silicates with an ion exchange capacity of less than 100 mg CaC03 / g can hardly help improve the stability of organic peracids. In the aforementioned formula (I), M is selected from the group consisting of hydrogen atoms and elements from the la group in the encounter table. For example, Na and I (alkali metal elements of the la group elements of the periodic table. M can also use a single element or a plurality of elements. That is, the Ma0 component can also be a mixture of Nas0 and Ka0. Me is selected From the elements of group la, lb, Ha, IV a, and VI of the period table, such elements as Mg, Ca, Zn, Y, Ti, Zr, Fe. The elements used by Me in the present invention are as defined above Within the range, there is no particular limitation, MMg, Ca, Fe are preferred. Me can also use a single element or a plurality of elements. That is, the Mem〇n component is also a mixture of MgO and CaO. M, η are n / m becomes a positive number of (h 5 ~ 2.0. n / m is the number of oxygen ions coordinated to the Me-atom, which is substantially selected from the values of 0.5, 1.0, 1.5, 2.0. The crystalline silicate used in the present invention is also It can be water and things. At this time, every {please read the precautions on the back / fill in this page) -The paper size of the binding and binding book is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 6 Central Ministry of Economy Printed by the quasi-bureau consumer labor cooperative 312705 A7 B7 V. Description of the invention () The amount of water in one molecule is 0 ~ 15 (converted to Hs0 In the above formula (I), b / a is 0.5 ~ 4.0 ', preferably 1.0 ~ 1,8. The crystalline silicate with b / a less than 0.5 is poor in water resistance, exceeding 4.0 crystalline silicates have low ion exchange energy and poor performance as ion exchangers. In the above formula (I), c / a is 0 ~ 1_0, M0.01 ~ 0.8 is better. C / a is more than The crystalline silicate of 1.0 has low ion exchange energy and poor performance as an ion exchanger. A and b are positive numbers, c is 0 or positive number, but as long as b / a and c / a are in the above It can be within the range and is not particularly limited. Also, as mentioned above, when aM »0 is a mixture of a'Na» 0 and a "K, 0, a is a '+ a". This is also the same for c. This In the invention (a), the crystalline silicate used in the component can be easily conformed to European Patent No. 55048 or Phys · Chem. Glasses., 2_, Ρ. 127 ~ 138 (1966), Z · Kristallogar., Ρ · Prepared by the method described in 396 ~ 404 (1969). The crystalline silicate is, for example, a crystalline silicate in which the values of a, b, and c are targeted, and the raw material components are weighed and mixed in a predetermined amount , The resulting mix The material is usually M 300 ~ 500 C, preferably 500 ~ 1000C, more preferably 600 ~ 9001, and it can be prepared by firing it. At this time, when the firing temperature is less than 300, it will not be crystallized * The obtained crystalline silicate has poor water resistance. In addition, if the firing temperature exceeds 1500¾, the particles of the crystalline silicate will become coarse, and the ion exchange energy of the obtained crystalline silicate will be low. The firing time is usually 0.1 to 24 hours. Such firing can be used in heating furnaces such as electric furnaces and gas furnaces. The paper standard is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm). 7 I — — — — — Pack III Order the IIII line (please read beforehand) Note on the back $ item 1V fill in this page) One 312705 A7 B7 S03Ni 5. Description of invention () Implementation. Furthermore, after firing, the obtained crystalline silicate can be pulverized to a predetermined particle size if necessary. The particle size of the crystalline silicate used in the present invention is not particularly limited, but it is preferably in the range of Μ0 · 01〜100μιπ. The crystalline silicate of the component of the present invention can also be a layered silicate (trade name: SKS-6> manufactured by Yaniu Yubu Co., Ltd., which is commercially available. (A > crystallinity of the component used in the present invention Silicate, must be used as the bleach activator of component (B) to stabilize the organic peracid generated in water. The composition of the present invention contains (a> component 0.1 to 20% by weight (based on the total weight of M composition) It is preferably 1 to 15% by weight, especially 2 to 10% by weight. (A> When the amount of the component is less than 0.1% by weight, the organic peracid in water has no stabilizing effect, even if it is more than 20% by weight. The stability effect has not been improved, which is economically disadvantageous. The essential component of the present invention (b) component is to generate organic peracid in response to hydrogen peroxide in water, that is, activated by the bleaching represented by the above formula (I) Examples of the leaving group of L in the formula (Π> can be exemplified by the base represented by the following formula U) and the base represented by the following formula (IV). Dll) 1 ^ I n 111 II! Ϋ 11 ^ I line (please read "Note on the back $ item 1 / fill in this page") 1. Minong COON, Ministry of Economic Affairs, Central Standards Bureau, Consumer Cooperative a (IV) Household 1 < · "In the Zheng Bian Zhang system (Π), the alkyl group of R is a straight chain and the carbon number is 11 to 13. The alkyl group with a sulfonic number of 10M is unstable and easily decomposed, In addition, those with an alkyl group with a carbon number of 14 or more do not show the desired bleaching power. Among the bleach activators shown in formula U >, the preferred one is Μ. The following formula 8 CNS) A4 specification (210X297 mm) Α7 Β7 Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Description of compound () (V) Compound shown: c. | H23-c-0-^ 〇y_s〇3Na ο The compound of the present invention contains (b) component 0.1 to 15% by weight. Based on the amount, preferably 1 to 10% by weight, particularly preferably 2 to 7% fi%. (b) When the component is less than 0.1% by weight, no bleaching In addition, if it exceeds 15% by weight, the organic peracid generated in water will react with the bleach activator to form a diacrylic matrix, and the whitening power will be reduced. (B) The bleach activator of the component can be peroxidized in water Hydrogen reacts to produce organic peracids. Therefore, in order to whiten, it is necessary to meet hydrogen oxide. In the present invention, combined peroxidation It can be used as a whitening activator. (C > Percarbonate, perborate, perphosphate, persilicate of granular or powdery hydrogen peroxide component, such as granular It is effective in the case of sodium salt, especially sodium percarbonate. The composition of the present invention contains hydrogen peroxide emitter 1 ~ 20% by weight (based on the total weight of the composition), preferably 2 ~ 15% by weight. When Dong is less than 1% by weight, there is no sufficient bleaching performance. In addition, even if this amount exceeds 20% by weight, the bleaching performance is not sufficiently improved. The non-ionic interface agent which is an essential component of the present invention (d) component has a special emblem of slurry or liquid in 25C. If a nonionic surfactant which is solid at 25 C is used, excellent bleaching power cannot be obtained. Nonionic surfactants useful in the present invention such as polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl, polyoxyethylene glucan fatty acid ester, polyoxyethylene sorbose fatty acid ester, poly Ethylene glycol fatty acid vinegar, polyoxyethylene alkyl
請先聞讀背面之注$項一/填寫本頁) *裝· -* 線 本紙張尺度適用中國國家橾準（CNS ) Α4规格（210X297公釐） 9 312705 A7 B7 五、發明说明（） 經濟部中央標準局貝工消费合作社印製 胺、甘油脂肪酸酯、高级脂肪酸烷醇醯胺、烷基糖苷、烷 基胺氧化物。 其中，Μ聚氧乙撐烷基K為佳*尤MC1D〜C14之直鏈 或分枝鏈之1级或2级醇之環氧乙烷加成物，且每一分子 平均4〜10莫耳之環氧乙烷加成而成者為佳。 本發明組成物（d)成分含有3〜20重量％ (M組成物全 重量為基準）、較佳係3.5〜10重量％、尤M4〜8重量％爲 佳。此量不足3重量％時，洗淨力低，另外，此量超過20 重量％，水溶液中之非離子界面活性劑撤胞之量會增加， 該撤胞可溶化漂白活性化剤（b)，故溧白力明顯降低。 本發明之（b〉成分乃可與從（c>成分生成之過氧化氫反 應而生成之有機過酸，藉U)成分之結晶性矽酸鹽及（d)成 分之非雛子界面活性劑之存在即使在過渡金屬離子之存在 下亦具優異之安定性。結果，有機過酸可顯示優異之漂白 力。 本發明有關溧白洗淨劑組成物。因此，本發明之組成 物亦可含有任意之洗淨成分。任意之洗淨成分如只要於一 般漂白洗淨劑組成物中用來作為界面活性劑即可，並無特 別限定。本發明中較佳係使用選自Μ下所示之陽離子界面 活性劑及兩性界面活性劑中之一種Μ上的界面活性劑作為 洗淨成分。 陰離子界面活性劑之例，如烷基苯磺酸鹽、烷基醚硫 酸鹽、烷烯醚硫酸鹽、烷基硫酸鹽、烷烯基硫酸麴、α-烯烴磺酸鹽、α-磺脂肪酸鹽、cc-磺脂肪酸酯鹽、烷基醚 請 先 « 面 之 注 裝 頁 訂 線 本紙張尺度遠用中國國家標準（CNS ) A4规格（210X297公釐） 10 A7 B7 五、發明説明（） 羧酸鹽、烷烯基醚羧酸發、胺基酸型界面活性荆、N-酿基 胺基酸型界面活性劑、烷基磷酸酯、烷烯基磷酸酯、烷基 磷酸醋鹽、烷烯基磷酸酯鹽，Μ烷基苯磺酸鹽、烷基醚硫 酸鹽、烷烯基醚硫酸鹽、烷基硫酸鹽及烷烯基硫酸鹽為佳 又，兩性界面活性劑例如磺甜菜驗型界面活性劑、碩 甜菜驗型界面活性劑、羥基磺甜菜驗糸界面活性劑。 本發明之漂白洗淨劑組成物除了必須成分即上述（a) 〜（d)成分及上述洗淨成分外，亦可含有其他成分。其他 成分之例，如：非結晶性之矽酸鹽、碳酸鹽等之鹸劑；芒 硝等之增量劑；結晶性鋁矽酸鹽（沸石）、非結晶性鋁矽酸 鹽、正磷酸鹽、焦磷酸鹽、三聚磷酸鹽、亞硝基之酸鹽 、乙二胺四醏酸鹽、摔樺酸鹽、異掙檬酸鹽等之2價金颶 離子捕捉劑；聚乙烯醇、聚乙烯基吡咯酮、羧甲基鐵維素 、聚丙烯酸鹽等之再污染防止劑（即分散劑 >;蛋白酶、酯 酶、脂肪酶、纖維素酶等之酵素；結塊抑制剤；過氧化物 之安定化劑；氧化防止劑；螢光染料；著藍剤；香料等。 〔實施例〕 經濟部中央標準局貝工消费合作社印製 Μ下，說明構成本發明漂白洗淨劑組成物之各成分的 合成例及實施例。本發明不限於此等實施例。 又，例中之％只要無特別記載乃為重量％基準。 漕白活袢仆.割 > 合成例 ⑴漂白活性化剤（1 )之合成 將預先脫水之Ρ-酚磺酸納l〇〇g (0.40mol)分散於二甲 11 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 312705 A7 B7 五、發明説明（ 經濟部中央橾準局貝工消费合作社印製 基甲醯胺（DMF)中。所得到之混合物Μ機械攪拌器攪拌並 昇至50Ό，然後，Μ 30分鐘滴入氯化月桂酸。滴入終了後 ，於同溫下使Ρ-酚磺酸納與氣化月桂酸反應3小時。在減 壓下<0.5〜lBmHg)、100C下蒸脯反應混合物，蹓去DMF。 Μ丙酮洗淨殘渣，再Μ水/丙酮（1/1，莫耳比）溶劑再結 晶，得到下逑式（i )所示之漂白活性化劑。產率為85%。 ⑵漂白活性化劑（li )之合成 除P-酚磺酸納之脫水物代之Μ P-酚羧酸納之脫水物Μ 外，其餘同於上述溧白活性化劑（1 )之合成方法，得到下 述式（11)所示之漂白活性化薄I。產率為65%。 ⑶漂白活性化劑（m )之合成 除Ρ-酚磺酸納之脫水物代之Mo-酚磺酸納之脫水物Μ 外，其餘同於上述溧白活性化剤（1 )之合成方法，得到下 述式（m)所示之漂白活性化剤。產率為50%。 ⑷漂白栝性化劑（iv)之合成 除了漂白活性化劑之烷基原，使用氯化肉豆蔻酸取代 氯化月桂酸之外，其餘同於上述漂白活性化劑（1〉之合成 方法，得下述式（IV〉所式之漂白活性化剤。產率為75%。 ⑸壬醯氧基苯磺酸鈉之合成 除了漂白活性化劑之烷基原，使用氣化壬酸取代 氯化月桂酸之外，其餘同於上述潇白活性化劑（1 )之合成 方法，得下述式（V〉所式之ρ-壬醢氧基苯磺酸納。產率為 87%。 I----------裝-- (請先閱讀背面之注$項一-Τ填寫本頁) 訂 線 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） 12 A7 B7 五、發明説明（ C | | Η 2 3 — C0 — 0 普 S03Na ( i ) C | | Η 2 3 — C 0 -。普 COONa (i i), 请 先 閱 C 1 1 H 2 3 - C 0 - 0 (iii)；Please read the note $ item 1 on the back / fill in this page) * Package--* The size of the line paper is applicable to China National Standard (CNS) Α4 specification (210X297mm) 9 312705 A7 B7 V. Description of invention () Economy The Ministry of Central Standards Bureau Beigong Consumer Cooperative printed amines, glycerin fatty acid esters, higher fatty acid alkanolamides, alkyl glycosides, and alkylamine oxides. Among them, Μ polyoxyethylene alkyl K is a good * especially MC1D ~ C14 linear or branched chain 1 or 2 alcohol ethylene oxide adducts, and each molecule average 4 to 10 moles Addition of ethylene oxide is preferred. The component (d) of the composition of the present invention contains 3 to 20% by weight (based on the total weight of the M composition), preferably 3.5 to 10% by weight, especially M4 to 8% by weight. When the amount is less than 3% by weight, the cleaning power is low. In addition, if the amount exceeds 20% by weight, the amount of non-ionic surfactant in the aqueous solution will be increased. The removal of the bleaching agent can be dissolved and bleached (b), Therefore, Li Bai's power is significantly reduced. The (b> component of the present invention is an organic peracid that can be reacted with hydrogen peroxide generated from the (c > component, by U) component crystalline silicate and (d) component non-child surfactant There is excellent stability even in the presence of transition metal ions. As a result, organic peracids can show excellent bleaching power. The present invention relates to a whitening detergent composition. Therefore, the composition of the present invention can also contain any The cleaning component. Any optional cleaning component is not particularly limited as long as it is used as a surfactant in a general bleaching detergent composition. In the present invention, it is preferable to use a cation selected from the group consisting of One of the surfactants and amphoteric surfactants is used as the cleaning component on M. Examples of anionic surfactants are alkylbenzene sulfonate, alkyl ether sulfate, alkenyl ether sulfate, alkyl Sulfate, alkyl alkenyl sulfate, α-olefin sulfonate, α-sulfonic acid fatty acid salt, cc-sulfonic acid fatty acid ester salt, alkyl ether, please first National Standard (CNS) A 4 Specifications (210X297mm) 10 A7 B7 5. Description of the invention () Carboxylate, alkenyl ether carboxylic acid, amino acid type surfactant, N-bromo amino acid type surfactant, alkyl Phosphate esters, alkenyl phosphate esters, alkyl phosphate ester salts, alkenyl phosphate ester salts, M alkylbenzene sulfonates, alkyl ether sulfates, alkenyl ether sulfates, alkyl sulfates and alkenes The basic sulfate is better, and amphoteric surfactants such as sulphur beet inspection surfactant, sucrose beet inspection surfactant, hydroxy sulphur sugar beet inspection surfactant. The bleach detergent composition of the present invention except essential components The above components (a) to (d) and the above cleaning components may also contain other components. Examples of other components, such as: non-crystalline silicate, carbonate, etc. emery agent; Glauber salt, etc. extender ; Crystalline aluminosilicate (zeolite), non-crystalline aluminosilicate, orthophosphate, pyrophosphate, tripolyphosphate, nitroso acid salt, ethylenediamine tetraacetate, betulinic acid Salt, isocitrate and other bivalent gold ion trapping agents; polyvinyl alcohol, polyvinylpyrrole Recontamination inhibitors for ketones, carboxymethyl ferrovitamins, polyacrylates, etc. (ie dispersing agents); enzymes such as protease, esterase, lipase, cellulase; caking inhibition; peroxide stability Chemical agents; oxidation inhibitors; fluorescent dyes; blue dyes; spices, etc. [Examples] Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs to illustrate the components of the bleach detergent composition of the present invention Synthesis Examples and Examples. The present invention is not limited to these Examples. In addition, the% in the examples is based on the weight% unless otherwise specified. Cao Baihuoju. Cut> Synthesis Example (1) Bleaching Activation (1) The synthesis will disperse 100g (0.40mol) of pre-dehydrated P-phenolsulfonate in Dimethyl 11. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) 312705 A7 B7 V. Description of invention ( In the printing of carboxamide (DMF) by the Beigong Consumer Cooperative of the Central Bureau of Industry and Commerce. The resulting mixture was stirred with a mechanical stirrer and raised to 50Ό, and then, lauric acid chloride was added dropwise for 30 minutes. After the end of the instillation, sodium p-phenolsulfonate was reacted with vaporized lauric acid at the same temperature for 3 hours. Under reduced pressure < 0.5 ~ 1BmHg), the reaction mixture was steamed at 100C to remove DMF. The residue was washed with M acetone, and then recrystallized with M water / acetone (1/1, molar ratio) solvent to obtain the bleach activator shown by the following formula (i). The yield is 85%. (2) The synthesis of bleach activator (li) is the same as the synthesis method of the above-mentioned Li Bai activator (1) except that the dehydrated product of P-phenolsulfonic acid is replaced by the dehydrated product M of P-phenolcarboxylic acid sodium. To obtain the bleach activated thin I shown by the following formula (11). The yield is 65%. (3) The synthesis of the bleach activator (m) is the same as the synthesis method of the above-mentioned whitening activator (1) except that the dehydrate of P-phenolsulfonate is replaced by the dehydrated M of Mo-phenolsulfonate. A bleach activation agent represented by the following formula (m) is obtained. The yield is 50%. ⑷Synthesis of bleaching agent (iv) Except for the original alkyl of bleach activator, the use of chlorinated myristic acid instead of lauric acid chloride, the rest are the same as the synthesis method of bleach activator (1) Obtain the bleach activation formula represented by the following formula (IV>. The yield is 75%. ⑸Synthesis of sodium nonyloxybenzene sulfonate In addition to the original alkyl of the bleach activator, gasified nonanoic acid is used instead of chlorination Except for lauric acid, the rest is the same as the synthesis method of the above Xiaobai activator (1), to obtain sodium ρ-nonoxyoxybenzenesulfonate of the following formula (V> formula. The yield is 87%. I- --------- installed-- (Please read the note $ item 1 on the back-fill in this page) The paper size of the binding book is applicable to the Chinese National Standard (CNS) Α4 specification (210X297mm) 12 A7 B7 5. Description of the invention (C | | Η 2 3 — C0 — 0 普 S03Na (i) C | | Η 2 3 — C 0-. 普 COONa (ii), please read C 1 1 H 2 3-C 0- 0 (iii);
Na03S， C13H27-C〇-0-(^y-SO3Na (iv： ίι 之 注 l·Na03S, C13H27-C〇-0-(^ y-SO3Na (iv: Note of l
CeHi?— CO—CeHi? — CO—
S03Na 所髮 ji- T m 裝 頁 结晶袢讷敌額：>镅魁 將本發明之結晶性矽酸鹽的調製方法表示如下，但不 限於此等方法。 界面活性剤⑴之調製方法 M b/a值及c/a值表示於表1之值比率，於2號矽酸鈉 <SiO»/Na»0=2.5，水分：60%)中加入氫氧化鈉及無水氫 氧化鈣之混合物（使微量之氫氧化納分散於無水氫氧化鈣 上者），所得到之混合物Μ均混器混合。所得到之混合物 取適量置於白金製硏缽中，在空氣中K 700C燒成1小時， 然後，急速冷却。粉碎所得到之燒成物，Μ形成粒子徑 ΙΟΟμιηΜ下且為表1所示組成之結晶性矽酸鹽。 除了將原料更改爲表1所示者，亦即，依需要，2號 矽酸納代之以矽酸鉀，氫氧化納代之以氫氧化鉀，無水氫 訂 線 經濟部中央揉準局貞工消费合作杜印製 本紙張尺度逋用中鬮國家橾準（CNS ) Α4規格（210X297公釐） 13 _ 五、發明説明（） A7 B7 氧化鈣代之Μ無水氫氧化鎂，又，其等之使用量變更成 b/a及c/a值如示於表1之量，其餘同於上述之方法，調製 結晶性矽酸鹽⑵、⑶及⑸〜⑺。 結晶性矽酸鹽⑷之調製方法，如下。 依結晶性矽酸鹽⑴之調製方法實施至燒成之過程，得 結晶性矽酸鹽。將該結晶性矽酸鹽無水物分散於離子交換 水中，得分散液。所得之分散液放置1小時後，使該分散 液通過0.2μ·之過濾膜進行過濾。過濾膜上之殘渣於ΐοου 下乾燥16小時，形成表1所示组成之結晶性矽酸鹽⑷。 以下述之方法測定所得到之結晶性矽酸鹽⑴〜⑺的離 子交換容量。結果如示於表1中。 <離子交換容量之測定方法> 精秤試料約O.lg，再加入氣化鈣溶液（CaC〇3之濃度為 1%〉50ml。所得到之混合物於251：下攙拌60分鐘，然後， 以5棰C號之濾紙進行過濾。取出濾液10ml，依EDTA滴定法 测定濾紙中之Ca量，從該值算出試料之鈣離子交換量。 請 先 閲 Λ 之 注 奢 裝 訂 線 經濟部中央標準局β：工消费合作社印裝 本紙張尺度適用中困國家揉準（CNS ) Α4规格（210X297公釐） 14 312705 A7 B7 五、發明説明（ 表 結晶性 矽酸鹽 No. MaQ M6m〇 n b/a c/a 離子交換容量 (mgCaC03/g) ⑴ Na»0 CaQ 2 0.2 243 ⑵ Na.O MgO 1 0.2 418 ⑶ K„0 CaO 1 0. 1 450 ⑷ Naa0/H«0 CaO 1 0.5 230 ⑸ Na«0 CaO 1 4.1 85 ⑻ Naa〇 CaO 4.5 0.2 64 ⑺ Na»0 一 2 0 150 潭白洗课割紐成物之讕製方法 請 先 閱 Λ 之 注 裝 經濟部中央樣準局貝工消费合作社印裝 Μ下實施例所使用之溧白洗淨劑組成物的調製方法如 示於下，但，本發明漂白洗淨劑組成物之調製方法並不特 別限定於此等方法。 <方法1 > 使用漂白劑〔成分（b>及（c>成分〕、結晶性矽酸鹽〔 U)成分〕及非離子性界面活性劑〔（d>成分〕Μ外之洗淨 劑成分（洗淨劑組成物之原料〉，調製60%水分量之漿泥。 噴霧乾燥此漿泥。所得到之粒子傾入攪拌型造粒機中，再 加入結晶性矽酸鹽〔U)成分〕。一面噴霧非離子性界面 活性劑〔（d)成分〕一面進行造粒。於所得到之洗淨劑粒 子中加入漂白劑成分〔（b)及（c)〕，混合所得到之混合物 ，調製漂白洗淨劑粉末。 <方法2 > •訂 線 本紙張尺度適用中國國家橾準（CNS ) A4规格（2丨0〆297公釐） 15 _ 1 cr _ A7 B7 五、發明説明（） Μ捏合機乾混漂白劑成分〔（b)及（c)成分〕以外之洗 淨成分，調製洗淨劑粉末。於所得到洗淨劑粉末中加入漂 白劑成分〔（b)及（c)成分〕。混合所得到之混合物，調製 漂白洗淨 實施例1 機過酸之安定化效果的評價 淨釋1^1 經濟部中央橾準局貝工消费合作社印製 於1升燒杯（直徑lien，高15cm〉中，加入水950ml (水 溫2010 將CaCl8調整成170ppm、Cu**離子調整成l〇〇ppb 。於該水中，Μ洗淨劑組成物總量為lg之量加入第2表所 示成分之中的第一成分，然後，加入第3表之添加劑（第 二成分）。攪拌所得到之混合物5分鐘（播拌子：長徑4cb 、短徑lem、旋轉數：lOOrpn)，然後，Μ洗淨劑組成物緦 量爲lg之量將漂白活性化劑（1 )〜（iv)(第三成分〉加入該 混合物中。所得到之混合物攪拌10分鑣後，觸酶0.06g。 所得到之混合物攪拌1分鐘後，加入10%碘化鉀溶液l〇ml 及20%硫酸溶液100ml。MO. IN硫代硫酸納溶液滴定所得 到之混合物。除了將爲調整CaCU成爲170ppm、CuB*離子 成爲100PPb所使用之水更換成離子交換水之外，其餘重覆 相同之操作。依下式求取過酸安定化率。結果如示於表3 中。 使用CaCU為170ppm、Cu**離子為100ppb之水時的滴定量 過酸安定化率----X 1〇〇 使用離子交換水時之滴定量 '---------裝I 請先聞讀背面之注意Ϋ項P填寫本頁 訂 線 本紙張尺度逍用中國國家揉準（CNS ) A4規格（210X297公釐） 16 - A7 B7 五、發明説明（） 表 2 洗淨成分 配合比率 第 LAS-NaKi a〜14) -1 25% AS-Na(C12~ η)·3 596 非離子界面活性劑"3 5% 石鹼（牛脂〉 \°/〇 成 蘇打灰 10¾ 聚丙烯酸鈉 (MW= 8000) 0.5% 分 過碳酸納 10% 芒硝 平衡量 第二成分（結晶性矽酸鹽） 表3所示之量 第三成分（漂白活性化劑） 596 全 部 10096 註〉 *1 :直鍵烷基（C1B〜14)苯磺酸鈉 *2 :烷基（C12〜14)硫酸鈉 *3:聚氧乙撐基烷基醚（烷基之碳數：12〜14 、環氧乙烷平均加成冥耳數在7、25=0下 為液狀） 17 本紙張尺度逍用中國國家標準（CNS ) A4規格（210X297公釐） 經濟部中央梂準局貝工消費合作社印製 312705 A7 B7 五、發明説明（） 表 3 過 酸安定 化率（％) 第二成 分 第三成分（漂白活性化劑）之種類 種 類 配合量 (ί) (11 ) (m) (ίν) 本 結晶性矽酸鹽⑴ 10% 78 88 78 89 結晶性矽酸鹽⑴ \°/〇 67 78 68 88 發 結晶性矽酸鹽⑵ \m 67 67 87 78 明 結晶性矽酸鹽⑵ 1% 56 65 64 62 結晶性矽酸鹽⑶ 10¾ 89 89 78 67 品 結晶性矽酸鹽⑷ 10% 78 67 79 78 結晶性矽酸鹽⑺ 10% 70 78 69 89 結晶性矽酸鹽⑴ 0.01% 13 15 25 21 比 結晶性矽酸鹽⑵ 0.01¾ 12 21 18 19 結晶性矽酸鹽⑶ 0.01¾ 12 11 9 4 結晶性鋁矽酸鈉 (沸石） 10¾ 0 0 0 0 較 結晶性矽酸鹽⑸ 10% 25 25 35 25 結晶性矽酸鹽⑻ 10% 35 20 40 45 矽酸納（JIS2號） (離子交換容量0 mg/g) 10% 35 35 45 40 品 偏矽酸鈉 (離子交換容量0 mg/g) 10% 35 45 35 35 無 10% 0 0 0 0 (請先閲讀背面之注意事項/埃寫本頁) -裝· ,ys 線 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 18 五、發明説明（ A7 B7 經濟部中央揉準局負工消费合作社印製 實施例2 洗淨漂白力之評價 量取造成黃斑原因成分之亞油酸及角鯊烯之混合物 (重量比1/10)以使其在氣仿溶液中之濃度爲10重量％，並 使之溶解於氯仿中。所得到之溶液0.4ml均一地塗布於木 綿布（4 X 4cm)。將所得到之布置入50¾之恒溫槽中，放置 24小時。使用乾燥後之布的b值（表示反射率、黃色之程度 )爲4M上者作為模型黃斑污染布。 以此污染布4片作爲1套，使用表4所示之組成的溧白 洗淨劑組成物依下述條件洗淨。對於原布及洗淨前後之布 (經乾燥劑），测定b值，並Μ下式求取洗淨率。結果如示 於表4〜6中。 洗淨率（％)= (La- U)/ (U- U)x 100 L。：原布之反射率 U:洗淨前污染布之反射率 :洗淨後污染布之反射率 <洗淨條件> 使用4° DH之水，調製洗淨劑組成物濃度為O.lg/Ι升 之洗淨劑水溶液。Μ溫度20¾、旋轉數lOOrpm、洗淨時 間10分鐘之條件，洗淨模型污染布。 請 先 閱 背 之 注 項 裝 頁 •訂 線 本紙張尺度逋用中國國家橾準（CNS ) Α4规格（210x297公釐） -19 A7 B7 五、發明説明（） 經濟部中央橾準局貝工消費合作社印製 表 4 本發明品 比較品 組成物No. (1) (2) (3) (4) (5) (6) 漂 白 洗 淨 劑 組 成 % 25 25 25 25 25 25 AS-Na^^H)** 5 5 5 5 5 5 非離子界面活性劑《3 5 5 5 5 5 5 石鹼（牛脂> 1 1 1 1 1 1 蘇打灰 10 10 10 10 10 10 聚丙烯酸納 (MW= 8000) 1 1 1 1 1 1 沸石（4A型） 10 10 10 10 10 10 芒硝 平衡量 PC(過磺酸鈉） 10 10 10 10 10 10 漂白活性化劑< 1 ) 5 漂白活性化劑（U ) 5 漂白活性化劑（m ) 5 漂白活性化劑（iV) 5 TAED “ 5 壬醯氧基苯磺酸鈉 5 結晶性矽酸鹽⑴ 5 5 5 5 5 5 結晶性矽酸鹽⑵ 結晶性矽酸鹽⑶ 結晶性矽酸鹽⑷ 結晶性矽酸鹽⑺ 矽酸納（JIS2號〉 計 100 100 100 100 100 100 洗淨率 （％) 66 67 68 65 32 45 (請先閲讀背面之注意事項孑螇寫本頁) -裝. 、11 線 本紙張尺度適用中國國家橾準（CNS ) A4規格（210X297公釐） 20 312705 A7 B7 五、發明説明（ 經濟部中央揉準局貝工消費合作社印製 表 5 本發 明 品 比較品 組成物 No. (7) (8) (9) (10) (11) (12) LAS-Na^^H)*1 25 25 25 25 25 25 5 5 5 5 5 5 非離子界面活性劑-3 5 5 5 5 5 5 石鹼（牛脂） 1 1 1 1 1 1 蘇打灰 10 10 10 10 10 10 漂 聚丙烯酸納 (MW= 8000) 1 1 1 1 1 1 白 沸石（4A型） 10 10 10 10 10 10 洗 芒硝 平 衡 量 PC(過碳酸鈉） 10 10 10 10 10 10 淨 漂白活性化劑（i ) 5 5 5 5 5 5 劑 漂白活性化劑（il ) 漂白活性化劑（m〉 組 漂白活性化劑（iV> 成 TAED*4 壬酿氧基苯磺酸鈉 結晶性矽酸鹽⑴ % 結晶性矽酸鹽⑵ 5 結晶性矽酸鹽⑶ 5 結晶性矽酸鹽⑷ 5 結晶性矽酸鹽⑺ 5 矽酸納（JIS2號） 5 計 100 100 100 100 100 100 洗淨率 （％) 65 66 67 71 23 23 請 先 閲 背 * 之 注 裝 訂 線 本紙張尺度適用中國國家梂準（CNS ) A4規格（210X297公釐） 21 - 五、發明説明（) 經濟部中央揉準局貝工消費合作社印製 表 6 本發明品 比較品 組成物 No. (13) (14) (15) (16) (17) (18) LAS-Na^rW1 25 25 25 25 25 25 AS-Na(Cia〜14)*a 5 5 5 5 5 5 非離子界面活性劑"3 5 5 5 5 5 5 石鹸（牛脂） 1 1 1 1 1 1 蘇打灰 10 10 10 10 10 10 漂 聚丙烯酸鈉 (MW= 8000) 1 1 1 1 1 1 白 沸（4A型） 10 10 10 10 10 10 洗 芒硝 平 衡 量 PC(過磺酸鈉） 10 10 10 10 10 10 淨 漂白活性化劑（1 ) 1 0.1 0.01 劑 漂白活性化劑（U ) 漂白活性化劑（m ) 組 漂白活性化劑（iv〉 成 TAED “ 5 壬醢氧基苯磺酸納 5 結晶性矽酸鹽⑴ 5 5 5 5 % 結晶性矽酸鹽⑵ 結晶性矽酸鹽⑶ 5 結晶性矽酸鹽⑷ 5 結晶性矽酸鹽⑺ 5 矽酸納（JIS2號） 5 計 100 100 100 100 100 100 洗淨率 （％〉 67 69 71 23 12 32Ji- T m issued by S03Na. Crystalline enemies: > Americium The preparation method of the crystalline silicate of the present invention is shown below, but it is not limited to these methods. The modulation method of the interface activity (1) The M b / a value and c / a value are shown in the value ratio in Table 1. Add hydrogen to No. 2 sodium silicate < SiO »/ Na» 0 = 2.5, moisture: 60%) A mixture of sodium oxide and anhydrous calcium hydroxide (when a small amount of sodium hydroxide is dispersed on anhydrous calcium hydroxide), the resulting mixture M is mixed with a homomixer. An appropriate amount of the obtained mixture was placed in a platinum bowl, sintered in the air at K 700C for 1 hour, and then rapidly cooled. The obtained fired product was pulverized, and M formed a crystalline silicate having a particle diameter of 100 μm and a composition shown in Table 1. In addition to changing the raw materials to those shown in Table 1, that is, as needed, No. 2 sodium silicate is replaced with potassium silicate, and sodium hydroxide is replaced with potassium hydroxide. Industrial-consumer cooperation to print this paper. The standard of the paper is used in China National Standard (CNS) Α4 specification (210X297 mm) 13 _ V. Description of invention () A7 B7 Calcium-based Mn anhydrous magnesium hydroxide, and others, etc. The amount of use is changed to the amount of b / a and c / a as shown in Table 1, and the rest are the same as the above method, and the crystalline silicates ⑵, ⑶ and ⑸ ~ ⑺ are prepared. The preparation method of crystalline silicate ⑷ is as follows. According to the preparation method of crystalline silicate (1), the crystalline silicate is obtained through the process from firing to firing. The crystalline silicate anhydrous was dispersed in ion exchanged water to obtain a dispersion. After the obtained dispersion liquid was allowed to stand for 1 hour, the dispersion liquid was filtered through a 0.2 µ filter membrane. The residue on the filter membrane was dried under Ιοου for 16 hours to form crystalline silicate ⑷ with the composition shown in Table 1. The ion exchange capacity of the obtained crystalline silicates ⑴ to ⑺ was measured by the following method. The results are shown in Table 1. < Measurement method of ion exchange capacity > The sample of precision scale is about O.lg, then add the vaporized calcium solution (the concentration of CaC〇3 is 1%> 50ml. The resulting mixture is mixed at 251: 60 minutes, then , Filter with 5 ° C filter paper. Take out 10ml of the filtrate, measure the amount of Ca in the filter paper according to EDTA titration method, and calculate the amount of calcium ion exchange of the sample from this value. Please read the central standard of the Ministry of Economy Note Bureau β: The size of the paper printed by the industrial and consumer cooperatives is applicable to the troubled countries (CNS) A4 specifications (210X297 mm) 14 312705 A7 B7 5. Description of the invention (Table crystalline silicate No. MaQ M6m〇nb / ac / a Ion exchange capacity (mgCaC03 / g) ⑴ Na »0 CaQ 2 0.2 243 ⑵ Na.O MgO 1 0.2 418 ⑶ K„ 0 CaO 1 0. 1 450 ⑷ Naa0 / H «0 CaO 1 0.5 230 ⑸ Na« 0 CaO 1 4.1 85 ⑻ Naa〇CaO 4.5 0.2 64 ⑺ Na »0 1 2 0 150 Tan Baixiu class cut the new method of the finished product, please read the note of Λ printed by the Central Sample Bureau of the Ministry of Economic Affairs Printed by the Beigong Consumer Cooperative The preparation method of the whitening detergent composition used in the following examples is as shown below, but The preparation method of the bleach detergent composition of the present invention is not particularly limited to these methods. ≪ Method 1 > Use of bleach [components (b > and (c > components), crystalline silicate [U) component ] And a nonionic surfactant [(d> component] detergent component other than M (raw material of detergent composition), prepare 60% moisture slurry. Spray dry the slurry. The particles obtained Pour into a stirring granulator, then add crystalline silicate [U] component]. While spraying the nonionic surfactant [(d) component], granulate it. In the resulting detergent particles Add the bleaching ingredients [(b) and (c)], mix the resulting mixture to prepare the bleach detergent powder. ≪ Method 2 > • The paper size of the binding book is applicable to China National Standard (CNS) A4 ( 2 丨 0〆297mm) 15 _ 1 cr _ A7 B7 V. Description of the invention () Μ Kneader dry mixing bleaching ingredients ((b) and (c) ingredients) other than washing ingredients, preparing detergent powder . Add bleaching ingredient ((b) and (c) ingredient to the obtained detergent powder 。Mix the resulting mixture to prepare the bleaching and washing example 1 Evaluation of the effect of the stability of the machine overacid Net release 1 ^ 1 Printed in a 1 liter beaker (diameter lien, height 15cm) > In 950ml of water was added (water temperature 2010 adjusted CaCl8 to 170ppm and Cu ** ion to 100 ppb). In this water, the total amount of the M detergent composition is 1 g, and the first component among the components shown in Table 2 is added, and then the additive (second component) in Table 3 is added. Stir the resulting mixture for 5 minutes (boiler: long diameter 4cb, short diameter lem, rotation number: 100rpn), and then, the amount of M detergent composition is lg to bleach the activator (1) ~ ( iv) (Third component> added to the mixture. After stirring the resulting mixture for 10 minutes, 0.06g of catalase. After stirring the obtained mixture for 1 minute, 10ml of 10% potassium iodide solution and 100ml of 20% sulfuric acid solution were added 。 MO. IN sodium thiosulfate solution titration of the resulting mixture. Except that the water used to adjust CaCU to 170ppm and CuB * ion to 100PPb is replaced with ion-exchanged water, the rest of the same operation is repeated. The peracid stabilization rate was obtained. The results are shown in Table 3. Titration peracid stabilization rate when using water with CaCU of 170 ppm and Cu ** ion of 100 ppb ---- X 100 using ion-exchanged water Titration of time '--------- installed I Please read the note on the back first Ϋ Item P fill in this page line book This paper size is easy to use Chinese National Standard (CNS) A4 specification (210X297mm) 16-A7 B7 V. Description of the invention () Table 2 Mixing ratio of cleaning ingredients (LAS-NaKi a ~ 14) -1 25% AS-Na (C12 ~ η) · 3 596 Non-ionic surfactant " 3 5% Petroleum (tallow) \ ° / 〇 成 Sodium ash 10¾ Sodium polyacrylate (MW = 8000) 0.5% Sodium carbonate 10% balance amount Glauber's salt second component (crystalline silicate) The third component (bleach activator) in the amount shown in Table 3 596 All 10096 Note> * 1: straight-chain alkyl (C1B ~ 14) benzene Sodium sulfonate * 2: alkyl (C12 ~ 14) sodium sulfate * 3: polyoxyethylene alkyl ether (the carbon number of alkyl: 12 ~ 14, the average addition number of ethylene oxide is 7, 25 = 0 is liquid) 17 The paper size is free to use the Chinese National Standard (CNS) A4 specification (210X297 mm) Printed 312705 A7 B7 by Beigong Consumer Cooperative of the Central Bureau of Economic Affairs of the Ministry of Economy V. Description of invention () Table 3 Peracid stabilization rate (%) Types of the second component and third component (bleach activator) Blending amount (ί) (11) (m) (ίν) This crystalline silicate ⑴ 10% 78 88 78 89 Crystalline silicate ⑴ \ ° / 〇67 78 68 88 Crystalline silicate ⑵ \ m 67 67 87 78 Bright crystalline silicate ⑵ 1% 56 65 64 62 Crystalline silicate ⑶ 10¾ 89 89 78 67 product crystalline silicate ⑷ 10% 78 67 79 78 crystalline silicate ⑺ 10% 70 78 69 89 crystalline silicate ⑴ 0.01% 13 15 25 21 than crystalline silicate ⑵ 0.01¾ 12 21 18 19 crystalline silicate ⑶ 0.01¾ 12 11 9 4 crystalline sodium aluminosilicate (zeolite) 10¾ 0 0 0 0 more crystalline silicate ⑸ 10% 25 25 35 25 crystalline silicate ⑻ 10% 35 20 40 45 sodium silicate (JIS No. 2) (ion exchange capacity 0 mg / g) 10% 35 35 45 40 sodium metasilicate (ion exchange capacity 0 mg / g) 10% 35 45 35 35 none 10% 0 0 0 0 (please read the precautions on the back / write this page first)-installed, ys line paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) 18 V. Invention description (A7 B7 Printed by the Ministry of Economic Affairs of the Ministry of Economic Affairs of the Ministry of Consumer Cooperatives. Example 2 Evaluation of cleaning and bleaching power A mixture of linoleic acid and squalene (a weight ratio of 1/10) that cause macular degeneration is weighed The concentration in the imitation solution was 10% by weight, and it was dissolved in chloroform. 0.4 ml of the resulting solution was uniformly applied to a cotton cloth (4 X 4 cm). Place the obtained into a thermostat of 50¾ and leave it for 24 hours. Use the b value of the cloth after drying (indicating the degree of reflectance and yellowness) of 4M or higher as the model macular contamination cloth. Using this set of 4 contaminated cloths as a set, a cleaning agent composition of Li Bai with the composition shown in Table 4 was used and washed under the following conditions. For the original cloth and the cloth before and after washing (after desiccant), the b value is measured, and the washing rate is determined by the following formula. The results are shown in Tables 4-6. Cleaning rate (%) = (La-U) / (U-U) x 100 L. : Reflectivity U of original cloth: Reflectivity of contaminated cloth before washing: Reflectivity of contaminated cloth after washing < Cleaning conditions > Using 4 ° DH water, the concentration of detergent composition is adjusted to O.lg / 1 liter of detergent aqueous solution. Wash the model contaminated cloth under the conditions of Μ temperature 20¾, rotation speed 100 rpm, washing time 10 minutes. Please read the back page of the note item first. The paper size of the binding book uses the Chinese National Standard (CNS) Α4 specification (210x297mm) -19 A7 B7 5. Invention description () Ministry of Economic Affairs Central Bureau of Standardization Consumption Cooperative Printed Table 4 Composition of the comparative product of the invention No. (1) (2) (3) (4) (5) (6) Composition of bleach detergent 25% 25 25 25 25 25 25 AS-Na ^^ H ) ** 5 5 5 5 5 5 Non-ionic surfactant "3 5 5 5 5 5 5 Petroleum (tallow> 1 1 1 1 1 1 soda ash 10 10 10 10 10 10 10 sodium polyacrylate (MW = 8000) 1 1 1 1 1 1 Zeolite (Type 4A) 10 10 10 10 10 10 Glauber's salt balance PC (sodium persulfonate) 10 10 10 10 10 10 Bleach activator < 1) 5 Bleach activator (U) 5 Bleach activator (m) 5 bleach activator (iV) 5 TAED "5 sodium nonyloxybenzene sulfonate 5 crystalline silicate ⑴ 5 5 5 5 5 5 crystalline silicate ⑵ crystalline silicate Salt ⑶ crystalline silicate ⑷ crystalline silicate ⑺ sodium silicate (JIS No. 2) total 100 100 100 100 100 100 cleaning rate %) 66 67 68 65 32 45 (please read the precautions on the back to write this page first)-installed., 11 line paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) 20 312705 A7 B7 V. Description of the invention (printed by the Beigong Consumer Cooperative of the Ministry of Economic Affairs of the Ministry of Economic Affairs 5 The composition of the comparative product of the invention No. (7) (8) (9) (10) (11) (12) LAS-Na ^ ^ H) * 1 25 25 25 25 25 25 5 5 5 5 5 5 5 Non-ionic surfactant-3 5 5 5 5 5 5 Petroleum (tallow) 1 1 1 1 1 1 Soda ash 10 10 10 10 10 10 Drift Polyacrylic acid sodium (MW = 8000) 1 1 1 1 1 1 White zeolite (type 4A) 10 10 10 10 10 10 Washing thenardite balance PC (sodium percarbonate) 10 10 10 10 10 10 Net bleach activator (i) 5 5 5 5 5 5 agent bleach activator (il) bleach activator (m> group bleach activator (iV > into TAED * 4 nonyloxybenzene sulfonate crystalline silicate ⑴% crystallinity Silicate ⑵ 5 crystalline silicate ⑶ 5 crystalline silicate ⑷ 5 crystalline silicate ⑺ 5 silicate Nano (JIS No. 2) 5 Total 100 100 100 100 100 100 Washing rate (%) 65 66 67 71 23 23 Please read the note on the back * The paper size is applicable to China National Standards (CNS) A4 specification (210X297 ) 21-V. Description of the invention () Printed by the Beigong Consumer Cooperative of the Central Ministry of Economic Affairs of the Ministry of Economic Affairs 6 The comparative product composition of the invention No. (13) (14) (15) (16) (17) (18 ) LAS-Na ^ rW1 25 25 25 25 25 25 AS-Na (Cia ~ 14) * a 5 5 5 5 5 5 Non-ionic surfactant " 3 5 5 5 5 5 5 Stone Partridge (Tallow) 1 1 1 1 1 1 Soda ash 10 10 10 10 10 10 Bleached sodium polyacrylate (MW = 8000) 1 1 1 1 1 1 White boiling (type 4A) 10 10 10 10 10 10 Balance of washed thenardite PC (sodium persulfate) 10 10 10 10 10 10 Net bleach activator (1) 1 0.1 0.01 agent bleach activator (U) bleach activator (m) group bleach activator (iv> into TAED "5 sodium nonoxyphenoxybenzene sulfonate 5 Crystalline silicate ⑴ 5 5 5 5% Crystalline silicate ⑵ Crystalline silicate ⑶ 5 Crystalline silicate ⑷ 5 Crystalline silicate ⑺ 5 Sodium silicate (JIS No. 2) 5 Total 100 100 100 100 100 100 Cleaning rate (%> 67 69 71 23 12 32
本紙張尺度逋用中國國家標率（CNS ) A4規格（210X297公釐） 22 經濟部中央標準局貝工消費合作社印^ A7 B7 五、發明説明（） 註〉 *1 :直鐽烷基（clg〜14)苯磺酸鈉 *2 :烷基（Cia〜14〉硫酸納 *3 :聚氧乙撐基烷基醚（烷基之磺數：12〜14、環氧 乙烷平均加成冥耳數在7、25P下爲液狀） *4: Ν,Ν,Ν’，Ν’-四乙二胺 實施例3 洗淨漂白力之評價 調製表7〜8所示組成之漂白洗淨劑組成物，Μ同於 實施例2之方法，實施其等洗淨力之評價。結果如示於表 7〜9中。 3 2 本紙張尺度適用中國國家揉準（CNS ) Α4規格（210X297公釐） 312705 經濟部中央揉準局貝工消費合作社印裝 A7 B7___五、發明説明（) 本發明有關一棰漂白洗淨劑組成物。更詳而言之，本 發明有鼷一種用來從缕維除去疏水性之（親油性）污垢，並 漂白缕維之漂白洗淨劑組成物，且含有於水溶液中顯示高 安定性且可產生有機過酸之漂白活性化劑。 自Μ往，即已知氣条漂白劑可非常有效地除去附著於 纗維上之污垢。但，氯糸漂白劑因氧力很強，無法使用於 有色圖案物等之漂白，而且，味道很強。因此，最近廣泛 要求使用無如此缺點之氧条漂白劑。 但，自Μ往所使用之氧条漂白劑即過硼酸鹽、過磺酸 鹽、過磷酸鹽及過矽酸蘧等之無機過氧化物對除去親水性 之污垢（果汁等之屑物）很有效，卻無法充分除去疏水性之 污垢。 因此，很多硏究者乃組合如此之過氧化物及有機過酸 前區體（溧白活化劑），企圖解決上述之問題。 英國專利第836988號及854798號所記載之發明相當於 該技術領域之初期發明。此等文獻中係記載渫白活性化劑 含有乙氧基苯磺酸鈉或酚磺酸鈉之酯類。又，於英國專利 第855735號中係揭示Ν,Ν,Ν’，Ν’-四乙醢基乙二胺（TAED)所 靥之醢基有機醢胺作為漂白活性化劑。此外，最近之專利 例如於歐洲專利第0174132號及0185522號及美國專利第 4412934號及4248928號中亦掲示漂白活性化劑。但，即使 採用此等文獻所記載之漂白活性化劑，對於疏水性之污垢 尤其是内褲之黃斑跡等污垢，氧条漂白劑之漂白力仍難謂 充分。 (請先閱讀背面之注意事項f填寫本頁) •裝· 訂 線· 本紙張尺度逋用中國國家標率（CNS ) A4规格（210X297公釐） 4 312705 A7 B7 五、發明説明（ 其中之一原因在於從漂白活性化劑產生之有機過酸的 安定性仍不彰。溧白活性化劑係於水瑢液中與過氧化氫反 應，而成為比過氧化氫之氧化力還強之有機過酸，此有機 過酸可分解污跡、黃斑之成分。但，有機過酸因其本身之 反應性高，不僅分解很早，亦會被洗濯水中含有撤量之過 度金屬離子（尤其Cu、Fe>分解。亦即，有機過酸在還未有 效作用於污垢而除去之時即已被分解殆盡。 本發明人乃對氧条漂白洗淨劑組成物銳意硏究，結果 ，發現過氧化氫與具有離子交換能之特定結晶性矽酸鹽、 具有特定烷基鏈長之漂白活性化劑及特定非離子界面活性 劑一起組合，則從該溧白话性化劑生成之有機過酸不論過 渡金屬離子是否存在，在水溶液中可顯示高安定性，如此 之組合對疏水性之污垢尤其是内褲之黃斑等的除去非常有 效。 亦即，本發明一種漂白洗淨劑組成物，Μ組成物全重 量為基準，含有〇_1〜20重量％之（a)以下述式（I )所示之 結晶性矽酸鹽且為具有lOOng C|^阁上之離子交換容量 lb)於水中可與過氧化氫 請 先 閱 •is 之 注 裝 頁 訂 線 經濟部中央標準局貝工消费合作社印製 者或其水和物、0.1〜15重量 反應並產生有機過酸之下述式<1>所示之漂白活性化劑、 1〜20重量％之（c)過氧化氫放出體、及3〜20重董％之（d〉 於25C中為漿泥或液體之非離子性界面活性劑： 〔式中，Μ爲氫原子或週期表之la族元素，Me為通期表之 Π a、I b、I a、IV a或\1族元素，a、b、b、η分別爲正數 本紙張尺度適用中國國家揉準（CNS ) Α4規格（210X297公釐） 5 A7 B7 五、發明説明（） 經濟部中央揉準局貝工消费合作社印製 表 7 本 發明 品 比 較 品 組成物 No. (1) (2) (3) (4) (5) (6) LAS-Naai^W1 25 25 25 25 25 25 AS-Na^n*)"2 5 5 5 5 5 5 石鹼（牛脂） 1 1 1 1 1 1 蘇打灰 10 10 10 10 10 10 漂 聚丙烯酸鈉 (MW= 8000) 1 1 1 1 1 1 白 沸石（4A型） 10 10 10 10 10 10 洗 芒硝 平 衡 量 漂白活性化劑（1 ) 5 5 5 5 淨 TAED-3 5 劑 壬酿氧基苯磺酸鈉 PC(過碳酸鈉） 15 15 15 15 15 15 組 結晶性矽酸鹽⑴ 5 5 5 5 5 5 成 結晶性矽酸鹽⑵ 結晶性矽酸鹽⑺ 矽酸鈉（JIS2號） % 非離子界面活性劑⑴ 5 5 非離子界面活性劑⑵ 5 非離子界面活性劑⑶β6 5 非離子界面活性劑⑷-7 5 10 計 100 100 100 100 100 100 洗淨率 （％) 82 85 89 45 38 34 (請先閲讀背面之注意Ϋ項Hv%寫本頁) ’裝· -* 線 本紙張尺度適用中國國家橾準（CNS ) Α4規格（210X297公釐） 24 經濟部中央標準局貝工消費合作社印製 312705 五、發明説明（） 表 8 本 發明 品 比 較 品 組成物 No. (7) (8) (9) (10) (11) (12) LAS-Naai^H)*1 25 25 25 25 25 25 AS-Na(Cia~… 5 5 5 5 5 5 石鹼（牛脂） 1 1 1 1 1 1 蘇打灰 10 10 10 10 10 10 漂 聚丙烯酸納 (MW= 8000) 1 1 1 1 1 1 白 沸石（4A型） 10 10 10 10 10 10 洗 芒硝 平 衡 量 漂白活性化劑（i > 5 5 5 5 5 淨 TAED*3 劑 壬酿氧基苯磺酸鈉 5 PC(過硝酸納） 15 15 15 15 15 15 組 結晶性矽酸鹽⑴ 5 5 成 結晶性矽酸鹽⑵ 5 結晶性矽酸鹽⑺ 5 10 矽酸納（JIS2號〉 5 % 非離子界面活性劑⑴"4 5 5 5 5 B 10 非離子界面活性劑⑵-β 非離子界面活性劑⑶-s 非離子界面活性劑⑷ 計 100 100 100 100 100 100 洗淨率（％) 43 79 87 32 71 89 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 25 經濟部中央橾準局貝工消費合作社印裝 312705 A7 B7 五、發明説明（） 表 9 比較品 組成物 No. (13) (14) (15) (16) 漂 白 洗 淨 劑 組 成 % LAS-Na(Cia〜H)el 25 25 25 25 AS-NaiC!，〜14)"a 5 5 5 5 石鹼（牛脂） 1 1 1 1 蘇打灰 10 10 10 10 聚丙烯酸鈉 (MW= 8000) 1 1 1 1 沸石（4A型） 10 10 10 10 芒硝 平衡衡 漂白活性化劑（1 ) 5 5 TAED-3 士醢氧基苯磺酸納 PC(過磺酸納〉 15 15 15 15 結晶性矽酸鹽⑴ 5 5 結晶性矽酸鹽⑵ 結晶性矽酸鹽⑺ 矽酸納（JIS2號） 非離子界面活性劑⑴〃 1 5 5 5 非離子界面活性劑⑵〃 非離子界面活性劑⑶ 非離子界面活性劑⑷-τ 計 100 100 100 100 洗淨率 （％) 34 34 35 12 本紙張尺度適用中國國家橾準（CNS ) A4規格（210X297公釐） 26 312705 A7 B7 五、發明説明（） 註） :1 :直鏈烷基（cls〜14)苯磺酸鈉 :2 :烷基（Cia~ 14〉硫酸納 3 : N, Ν, Ν’，Ν’ -四乙二胺 :4:聚氧乙撐基烷基醚（烷基之碳數：12〜14、烷基 之平均碳數：13、環氧乙烷平均加成莫耳數在7 25¾下為液狀） :5:聚氧乙撐基烷基醚（烷基之磺數：12〜14、烷基 之平均碳數：13.5、環氧乙烷平均加成冥耳數 在9、251C下為液狀） :6:聚氧乙撐基烷基醚（烷基之碳數：12〜16、烷基 之平均磺數：12.5、環氧乙烷平均加成莫耳數 在6、25¾下為液狀） :7 :聚氧乙撐基烷基醚（烷基之碳數：12〜14、烷基 之平均碳數：13、環氧乙烷平均加成莫耳數在 12、25¾下為固體〉 請 先 閲 面 之 注 % 裝 訂 線 經濟部中央標準局貝工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 27This paper uses the China National Standard (CNS) A4 standard (210X297mm) 22 Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs ^ A7 B7 5. Description of the invention () Note> * 1: Straight alkyl (clg ~ 14) Sodium benzenesulfonate * 2: alkyl (Cia ~ 14> sodium sulfate * 3: polyoxyethylene alkyl ether (sulfon number of alkyl: 12 to 14, average addition of ethylene oxide The number is liquid at 7, 25P) * 4: Ν, Ν, Ν ', Ν'-Tetraethylenediamine Example 3 Evaluation of cleaning and bleaching power Composition of the bleaching detergent composition shown in Tables 7 to 8 In the same way as in Example 2, the evaluation of the equivalent detergency is carried out. The results are shown in Tables 7 to 9. 3 2 The paper size is applicable to China National Standard (CNS) Α4 specification (210X297 mm) 312705 The Ministry of Economic Affairs, Central Bureau of Industry and Commerce, Beigong Consumer Cooperative Printed A7 B7___V. Description of the invention () The present invention relates to the composition of a bleaching detergent. In more detail, the present invention has a kind of It removes hydrophobic (oleophilic) dirt and bleaches the bleaching detergent composition, and is contained in an aqueous solution to show high stability and productivity. Organic peracid bleach activator. From M to the past, it is known that the air strip bleach can very effectively remove the dirt adhering to the dimensional. However, due to the strong oxygen, the chlorite bleach can not be used in colored patterns The bleaching of substances, etc., and the taste is very strong. Therefore, the use of oxygen strip bleach without such shortcomings is widely required recently. However, the oxygen strip bleach used from M is perborate, persulfonate, and superphosphate Inorganic peroxides such as salt and persilicic acid are very effective in removing hydrophilic dirt (debris such as fruit juice), but they cannot sufficiently remove hydrophobic dirt. Therefore, many researchers combine such peroxides And organic peracid precursors (liquid activator) in an attempt to solve the above problems. The inventions described in British Patent Nos. 836988 and 854798 are equivalent to the initial inventions in this technical field. These documents describe the white activity The chemical agent contains esters of sodium ethoxybenzene sulfonate or sodium phenol sulfonate. In addition, British Patent No. 855735 discloses Ν, Ν, Ν ', Ν'-tetraethylethylenediamine (TAED) As a result, the acetoorganoacetamide as Bleach activator. In addition, recent patents such as European Patent Nos. 0174132 and 0185522 and US Patent Nos. 4412934 and 4248928 also show bleach activators. However, even if the bleach activators described in these documents are used It is hard to describe the bleaching power of the oxygen strip bleaching agent for hydrophobic dirt, especially the yellow spots on underwear, etc. (please read the precautions on the back f to fill in this page) • Packing · Threading · This paper The standard uses the Chinese National Standard (CNS) A4 specification (210X297mm) 4 312705 A7 B7 V. Description of the invention (One of the reasons is that the stability of the organic peracid produced from the bleach activator is still poor. Li Bai activator reacts with hydrogen peroxide in water, and becomes an organic peracid that is stronger than hydrogen peroxide. This organic peracid can decompose the components of stains and macula. However, due to its high reactivity, organic peracids not only decompose very early, but will also be decomposed by the removal of excessive metal ions (especially Cu, Fe>) in the wash water. That is, organic peracids have not yet effectively worked on When the dirt is removed, it has been decomposed and exhausted. The inventor has made a serious investigation on the composition of the oxygen strip bleaching detergent, and as a result, it has been found that hydrogen peroxide and a specific crystalline silicate having ion exchange energy have specific If the bleach activator with a long alkyl chain is combined with a specific nonionic surfactant, the organic peracid generated from the vernacular activator can show high stability in aqueous solution regardless of the presence or absence of transition metal ions. The combination is very effective for removing hydrophobic dirt, especially macular, etc. of underpants. That is, the bleaching detergent composition of the present invention contains 0-1 to 20% by weight based on the total weight of the M composition (a ) The crystalline silicate represented by the following formula (I) and having an ion exchange capacity of 100 ng C | ^ on the cabinet lb) Can be used with hydrogen peroxide in water in Printed by the Central Standards Bureau Beigong Consumer Cooperative or its hydrates, 0.1 to 15 weight percent bleach activator as shown in the following formula < 1 > reacting to produce organic peracid, 1 to 20 weight percent (c ) Hydrogen peroxide emitter, and 3 ~ 20% by weight (d> Non-ionic surfactant which is slurry or liquid in 25C: [In the formula, M is hydrogen atom or la group element of the periodic table, Me is the Π a, I b, I a, IV a or \ 1 group element of the general schedule, a, b, b, η are positive numbers. The paper size is applicable to the Chinese National Standard (CNS) Α4 specification (210X297 mm) 5 A7 B7 V. Description of the invention () Printed by the Ministry of Economic Affairs, Central Bureau of Standardization, Pui Kung Consumer Cooperative 7 The composition of the comparative product of the invention No. (1) (2) (3) (4) (5) (6) LAS-Naai ^ W1 25 25 25 25 25 25 AS-Na ^ n *) " 2 5 5 5 5 5 5 trona (tallow) 1 1 1 1 1 1 soda ash 10 10 10 10 10 10 bleached sodium polyacrylate (MW = 8000) 1 1 1 1 1 1 White zeolite (type 4A) 10 10 10 10 10 10 Washing thenardite balance bleach activator (1) 5 5 5 5 Net TAED-3 5 agent nonyloxybenzenesulfonate Sodium PC (sodium percarbonate) 15 15 15 15 15 15 Group crystalline silicate ⑴ 5 5 5 5 5 5 Form crystalline silicate ⑵ crystalline silicate ⑺ Sodium silicate (JIS No. 2)% Non-ionic interface activity Agent ⑴ 5 5 Non-ionic surfactant ⑵ 5 Non-ionic surfactant ⑶β6 5 Non-ionic surfactant ⑷-7 5 10 Total 100 100 100 100 100 100 Cleaning rate (%) 82 85 89 45 38 34 (please first Read the note on the back Ϋ Item Hv% to write this page) 'Package ·-* The size of the line paper is applicable to the Chinese National Standard (CNS) Α4 specifications (210X297 mm) 24 Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 312705 V Description of the invention () Table 8 Composition of the comparative product of the invention No. (7) (8) (9) (10) (11) (12) LAS-Naai ^ H) * 1 25 25 25 25 25 25 AS- Na (Cia ~… 5 5 5 5 5 5 Petroleum (tallow) 1 1 1 1 1 1 1 Soda ash 10 10 10 10 10 10 Bleached polyacrylic acid sodium (MW = 8000) 1 1 1 1 1 1 White zeolite (type 4A ) 10 10 10 10 10 10 Washing thenardite balance bleach activator (i > 5 5 5 5 5 net TAED * 3 agent Sodium nonyloxybenzene sulfonate 5 PC (sodium pernitrate) 15 15 15 15 15 15 Group crystalline silicate ⑴ 5 5 into crystalline silicate ⑵ 5 crystalline silicate ⑺ 5 10 sodium silicate ( JIS No. 2> 5% nonionic surfactant ⑴ " 4 5 5 5 5 B 10 nonionic surfactant ⑵-β nonionic surfactant ⑶-s nonionic surfactant ⑷ Total 100 100 100 100 100 100 Wash Rate (%) 43 79 87 32 71 89 This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 25 Printed by 312705 A7 B7 of Beigong Consumer Cooperative of Central Central Bureau of Economics of the Ministry of Economy V. Description of invention () Table 9 Comparative composition No. (13) (14) (15) (16) Bleach detergent composition% LAS-Na (Cia ~ H) el 25 25 25 25 AS-NaiC !, ~ 14) " a 5 5 5 5 Petroleum (tallow) 1 1 1 1 Soda ash 10 10 10 10 Sodium polyacrylate (MW = 8000) 1 1 1 1 Zeolite (type 4A) 10 10 10 10 Glauber salt balance bleach activator (1) 5 5 TAED-3 Sodium oxybenzene sulfonate PC (sodium persulfonate) 15 15 15 15 Crystallization Silicate ⑴ 5 5 Crystalline silicate ⑵ Crystalline silicate ⑺ Sodium silicate (JIS 2) Nonionic surfactant ⑴〃 1 5 5 5 Nonionic surfactant ⑵〃 Nonionic surfactant ⑶ Non Ionic surfactant ⑷-τ 100 100 100 100 Washing rate (%) 34 34 35 12 This paper scale is applicable to China National Standard (CNS) A4 specification (210X297 mm) 26 312705 A7 B7 V. Description of invention () Note): 1: linear alkyl (cls ~ 14) sodium benzenesulfonate: 2: alkyl (Cia ~ 14> sodium sulfate 3: N, Ν, Ν ', Ν'-tetraethylenediamine: 4: poly Oxyethylene alkyl ether (the carbon number of the alkyl group: 12 ~ 14, the average carbon number of the alkyl group: 13, the average addition mole number of ethylene oxide is liquid under 7 25¾): 5: polyoxy Ethylene alkyl ether (sulfon number of alkyl: 12 ~ 14, average carbon number of alkyl: 13.5, average addition number of ethylene oxide is liquid at 9, 251C): 6: polyoxygen Ethylene alkyl ether (the carbon number of the alkyl group: 12 ~ 16, the average sulfonic number of the alkyl group: 12.5, the average addition mole number of ethylene oxide is liquid under 6, 25¾): 7: polyoxygen Ethylene Alkyl ether (the carbon number of the alkyl group: 12 ~ 14, the average carbon number of the alkyl group: 13, the average addition mole number of ethylene oxide is solid under 12, 25¾) Please read the note first. The size of the paper printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 27