TW307830B - - Google Patents

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TW307830B
TW307830B TW83103238A TW83103238A TW307830B TW 307830 B TW307830 B TW 307830B TW 83103238 A TW83103238 A TW 83103238A TW 83103238 A TW83103238 A TW 83103238A TW 307830 B TW307830 B TW 307830B
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Taiwan
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liquid
light
polymer
suspension
particles
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TW83103238A
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Chinese (zh)
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Research Frontiers Inc
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Priority claimed from US07/972,830 external-priority patent/US5463492A/en
Priority claimed from US07/972,826 external-priority patent/US5463491A/en
Priority claimed from US08/059,980 external-priority patent/US5467217A/en
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Publication of TW307830B publication Critical patent/TW307830B/zh

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Description

經濟部中央標準局員工消费合作社印製 A 7 B7 _ 五、發明説明(1 ) 本申請案為间在申請中之美國專利案序號第972,828及 972,830號(二察皆在1992年11月6日雄出申請)的接績部 份,其等内容併入本文KH參考,&其等為間在申鏞中之 美國專利案序豔786.511號(1992年11月1日攞出申_ ’但 現已放索)之接纗部份。 獲1之領域 本發明偽鼷於光闕用之流騮嫌浮液,且更祥鑼言之•係 闞於由紫外光矚射安定液黼騄浮癘及其顏之方法與材料° 窗噩 光閥用於光之讕變巳將近60年。一光鬭可繼述為由隔関 一小段距_之二器壁所形成之光爾菅•其至少有一器壁麴 透明,且此二器鑒具有一般為通明導電塗鼸之電極於其上 。此光爾管含有一 ”光閫臁浮液u,其可為液籲光W _浮液 或含如下文所述之液戆光閥》浮液黴滴之臢。此液《光Μ 嫌浮液包含許多懸浮於液臁懸浮介質之小粒子。無外加電 場時•液憊光閥懸浮液中之粒子里規歉亂布朗 (Brownian)*動,因而一束光通人此光爾管時將遭反射、 穿通或吸收,端視粒子之本質輿钃度及光之飾量而定。當 於光閥之光_懸浮液中豳加一爾壜時•各粒子里對齊且對 許多懸浮液而言•大部份之光可通通光電管。已攞出之光 閥可用於許多目的,包括:例如,字數型顧示器、爾裰顯 示器、窗、鏞、濾光器、滑雪罐回鏞、眼績及同一類可控 制通«光量之裝置等。此外,除上述之禊籲光闕》液之外 ,一種可用於光閥者為包含一聚合物基質之_,該臢具有 本紙張尺度逍用中國國家標準(CNS ) Α4规格(210Χ297公釐) 83. 3.10,000 -----.--α---裝------訂------線| - * 畔 (#先閲讀背面之注意事項再填寫本頁) 經濟部中央樣準局貝工消費合作社印製 307330 A1 _B7 五、發明説明(2 ) 分布於整個此聚合物基質之液鑣錄泮液撇癎,如前述两在 審理中之美鬮専利申鱅察序號第972,826及972,830中所 述者。本專利銳明書中述及之所脔専利及專利申鳙案併入 本文以玆參考。更詳《資料,見下面之-節,棚鼸為”光 閥_ ”。A 7 B7 _ printed by the Employees ’Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. V. Description of the Invention (1) This application is the serial number of the United States Patent Case No. 972,828 and 972,830 (the two inspections were on November 6, 1992 Part of the performance of the male applicants), the contents of which are incorporated into the KH reference of this document, & etc. are in the US Patent Case No. 786.511 (November 1, 1992). It has been released now). The field obtained by the present invention is pseudo-buoyant to the floating liquid used in the light and it is more auspicious. It is the method and material for the floating liquid and its face which are exposed to the stable liquid by ultraviolet light. Light valves have been used in light for nearly 60 years. A light beam can be described as a light wall formed by two walls separated by a small distance_ It has at least one wall that is transparent, and the two walls have electrodes that are generally transparent and conductively coated on it . This Guang'er tube contains a "light" floating liquid u, which can be liquid light W_ floating liquid or containing liquid mildew drops of liquid floating light valve as described below. This liquid "光 Μ is floating The liquid contains many small particles suspended in the liquid suspension medium. When there is no external electric field, the particles in the suspension of the liquid exhausted light valve will be Brownian *, so a beam of light will pass through the light tube. It is reflected, penetrated or absorbed, depending on the nature of the particles and the amount of decoration and the amount of light decoration. When in the light of the light valve _ suspension is added to a sill • Each particle is aligned and for many suspensions Words • Most of the light can pass through the photocell. The light valve that has been used can be used for many purposes, including: for example, word number monitors, Er monitors, windows, yin, filters, ski cans, etc. Eye records and the same kind of devices that can control the flux of light, etc. In addition, in addition to the above-mentioned liquid, the one that can be used for the light valve is a polymer matrix, which has the size of this paper. Use China National Standard (CNS) Α4 specification (210Χ297mm) 83. 3.10,000 -----.-- α --- installed ------ order ---- --Line |-* Bank (#Read the precautions on the back before filling in this page) Printed 307330 A1 _B7 by Beigong Consumer Cooperative of the Central Bureau of Economics of the Ministry of Economic Affairs V. Invention description (2) distributed throughout the polymer matrix The liquid is recorded in the liquid, as described in the aforementioned two patent applications under review, serial numbers 972,826 and 972,830. The patent and patent application cases mentioned in this patent's Ruiming book are incorporated herein For reference. For more details, "Information, see below-section, shed mule is" light valve_ ".

散置1# I 本發明之光閫懸浮液可為任一包含本技藝所知或本發明 之發明者所知、或下文所知光闕用之液態光«鼸浮液微滴 的液臁光«嫌浮液•且可根镰已知之技術_配》於此所用 之"光鬭液戆懸浮液"或"«戆懸浮液”一辭窳指一"液鐮》 浮介賢",其中大部份之小粒子為分載[型。此"液臁騄浮 介霣”包含一或多儸非水性、离電駔性之液牖•其中較佳 之液钃溶有至少一類作為滅少粒子黏聚傾Λ且作為使其保 持分散之聚合安定麵。 如所知•無櫬及有櫬粒子可用於光闢_浮液•如雲母、 金靥、石墨、金屬Α化物、多鹵化物(於先前技藝中有時 稱作全鹵化物)之*酸等。液_鼸浮覼中之粒子可為光 -偏極化,如含鹵素之光偏極化材料,例如多_化物之着 酸_。(於此所用之” «Τ —辭意指如1 969年紐約赛果-# 爾(McGraw-Hi 1 1)鼷害公司,哈氏(Hackh's)化學字典第四 版中所定義之有機含氰籲)。若使用多_化物之驗酸鼸· 螓部位可為如舫面哈氏化學字典定義之奎寧麯。美_専利 案2,178,99β及2,289,712中詳綑指示多_化物之奎寧驗 酸鱷的使用》該粒子可為光-吸收或光 反射型。 一 5 - 本紙張尺度逋用中國國家槺準(CNS > A4规格(210X297公釐) 83. 3. 10,000 — -nn n I 訂 I 線《 (請先閲讀背面之注$項再填寫本頁) 經濟部中央標準局員工消费合作社印製 Α7 Β7 五、發明説明(3 ) 並且,該粒子可為氫化多鹵化物之奎寧__» *如酸性 磓酸二氲辛可尼汀多_化物,如述於美_專利案 4,131,334 «,或光-偏極化之金鼸Β»化物成多_化物· 如澳化嗣或二氯化-蜇五氛鉻鈷碴酸_多鷗化物*如供如 美_專利案1 , 956,867 ,較佳為,此粒子為如縯等述於美 圔専利案第4,877,313及5,002,701號中所述之光-《I槿 化多鹵化物粒子,其於周鼸*»中較先前技藝之多鹵化物 更安定。 理論上,任一類型之可反射、峨收及/或穿«所須可見 光波長之粒子背可用於光閥懸浮液。 光«懸浮液中所用之粒子形狀較佳蘼為”不等軸”*亦即 粒子之形狀或结構為使-位向中粒子攝截之光較另一位向 多。Μ針狀、桿狀、板條吠或薄片肜之粒子為宜。 粒子較佳為腰體大小•亦即粒子之長瑾平均約1微米或 更少。較佳為,大部份粒子之長龜具有小於Μ光波畏之一 半(亦即2000埃或更小)以保持光敢射極低。 任一類於《場或磁場中可定向之懸浮液粒子»磨用*包 括光-敝射及光-吸收粒子。然而•以可睱收镰擊於其上 之可見光的粒子為較佳*因為其具有非常小之光-散射. 且光極化晶艚為特佳且有用,因為其可產生令人愉悅 之視覺外觀。 光-吸收粒子包含許多類型之材料•包括彩色可定向性 顔料及色素,例如拓禰石紅、辱電性之黑成灰色材料,如 石墨或碳黑•如廣泛用於客-主液暴裝置之二色性色素、 -6 - 本紙張尺度適用中國國家梯準(CNS ) Α4規格(210Χ297公釐) 83. 3.10,000 ----;------兹------訂------線I. (請先閲讀背面之注意事項再填寫本頁) 經濟部中央梂準局員工消費合作社印褽 Α7 Β7 五、發明説明(4 ) 光-儀極化材料例如澳化鑭•及多_化物《且特別為多_ 化物例如該等關於先《技藝光閥装置中所述者。 於此所用之”多》化物”一辭係Μ習知之意義使用,且亦 與許多先前技藝之光鬮専利中使用之”__化物”_義 > 例 如,見禰鼷為”腰艚肇浮液及其_程”之美國專利案 1 · 951 · 664 (Μ德(Land))中第1行•其指出之物料為一母 質化合物(可為辕瓖含氰鑛的确酸薩或某些如美_«利 4.270,841號中所述之其他鼸)輿碘或酿化物之反應產物 。該反應產物常稱為多»化物化合物。此類型之粒子詳》 討論於《馨之普通化學期刊、第20卷、第1005-1 016頁 (1950年)刊登的D.A.离狄那(GotHna)及G.P.费爾鼴 (Faer* nan)之”多碘化物之光學性質及结構"。例如,碘硫 酸奎寧為酸性磙酸多_壅寧•且其化式於默克(Merck)索 引第10販(N.J.拉威(Rahway)之默克&公_ >之檷麵"四_ 确酸奎寧”下所得為 4C2〇H24N2〇2,3H2S〇4.2Hi, I 4.6H20。 於更新穎且較佳類型之多釀化物中,母質化合物不須為嬲 類♦例如見於美園專利案第4,87?, 3 13及5,002,701 «。 於此等多_化物化合物中·_裱瓣為形成鐽狀且此化合物 為強偏光_。於此所用之"多鹵化物”一辭籯掏如多碘化物 之化合物•但其中至少某些_化物中之碘為另一鹵索元橐 所取代。 本發明之光閥蘼浮嬤可包括任一先萠提出用於光《中Μ 懸浮粒子之液態懸浮介通常•液鐮鼸浮介質可包含一 或多镅可同時懸浮粒子且溶解任·聚合安定繭(用Μ降低 -7- ; Η 裝 (請先閎讀背面之注$項再填寫本頁) 訂散 置 1 # I The light suspension of the present invention can be any liquid light containing liquid light «elu float droplets known in the art or known to the inventors of the present invention, or known below as light barriers «Suspended liquid • Technology that can be used for root sickle_Matching " Guang 鬭 液 戆 suspended liquid " or "« 戆 suspension liquid " refers to one " liquid sickle "Fujie Ken ", where most of the small particles are part-loaded [type. This " liquid buoyant floating medium "contains one or more non-aqueous, ionotropic liquid tablets. Among them, the preferred liquid dissolves at least One type is the polymerization stabilizing surface that acts as a cohesive decay for the particles and keeps them dispersed. As is known • No 榇 and 榇 particles can be used for photo-buoyant liquids such as mica, gold tantalum, graphite, metal A compounds, polyhalides (sometimes referred to as full halides in the prior art), etc. . The particles in the liquid_float can be light-polarized, such as halogen-containing light-polarized materials, such as poly-chemical acid. (As used herein, the term «Τ—means organic cyanide as defined in the fourth edition of the 1969 New York Saigol- # Seoul (McGraw-Hi 1 1) Harmony Company, Hackh's Chemical Dictionary Appeal). If you use the acid test of poly-chemicals, the larvae can be a quinine song as defined in the Hashi Chemical Dictionary of Fang Mian. The quinine test of the multi-chemical compounds in the detailed instructions of the Mei_Xi case 2,178,99β and 2,289,712 The use of acid crocodile "The particles can be of light-absorption or light-reflective type. 1. 5-This paper scale uses the Chinese National Standards (CNS & A4 specifications (210X297 mm) 83. 3. 10,000 — -nn n I Order line I (Please read the note on the back of the $ item and fill in this page) A7 Β7 printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (3) And, the particles can be quinine of hydrogenated polyhalides __ »* Such as acid dioxin dicinoconitine poly_ compound, as described in the US_Patent Case 4,131,334«, or light-polarized gold bromide »compound into multiple _ compounds · such as Australian Hua Si or Dichloride-sting five-chromium chromium-cobalt ascorbic acid_polyglyphate * as provided by Rumei_Patent Case 1, 956,867, preferably, this particle is described in US The light described in No. 4,877,313 and 5,002,701 in the case of "Xi-I" polyhalide particles, which is more stable in Zhou Zhou * »than polyhalides in the prior art. In theory, any type of reflective, The back of the particles that can receive and / or wear «the required wavelength of visible light can be used in the suspension of light valves. The shape of the particles used in the light« suspension is preferably "unequal axis" * that is, the shape or structure of the particles is such that- The particles in the direction are more intercepted by the light than the other direction. The particles of M needle, rod, slat bark or lamella are suitable. The particles are preferably the size of the waist • That is, the average length of the particles is about 1 Micron or less. Preferably, most of the long turtles with particles have less than half of the M light wave (that is, 2000 angstroms or less) to keep the light emission extremely low. Any type can be oriented in the field or magnetic field Suspension particles »Abrasive * includes light-spraying and light-absorbing particles. However, particles with visible light that can be sickened on it are preferred * because they have very little light-scattering. And light The polarized crystal stern is particularly good and useful because it can produce a pleasing visual appearance. The child contains many types of materials • Including color orientable pigments and pigments, such as topaz red, black and gray materials such as graphite or carbon black • Such as the two-color widely used in passenger-main liquid storm devices Sex pigment, -6-This paper scale is applicable to China National Standards (CNS) Α4 specification (210Χ297mm) 83. 3.10,000 ----; ------ here ------ ---- Line I. (Please read the precautions on the back before filling out this page) Printed by the Central Consumer ’s Bureau of the Ministry of Economic Affairs Employee Consumer Cooperatives Α7 Β7 5. Description of the invention (4) Light-instrument polarizing materials such as Lanthanum • And multi-chemical compounds, and especially multi-chemical compounds such as those described in the first "technical light valve device." The term “多》 化 物” used here is used in the sense of M ’s knowledge, and is also used with the “__ 化 物” _ 义> used in many previous arts, such as the “Luhuazhao”. "Floating liquid and its process" in US Patent Case No. 1 · 951 · 664 (M De (Land)), line 1 • The material indicated is a parent compound (which can be the acid or some of the cyanide ore in the Yuanyuan These are the reaction products of iodine or brews as described in US _ "Lee 4.270,841". This reaction product is often referred to as a polychemical compound. This type of particle details "discusses DA GotHna and GP Faer * nan published in" Journal of General Chemistry, Volume 20, Pages 1005-1016 (1950) " Optical properties and structure of polyiodide. For example, quinine iodosulfate is an acidic polyoxalate. The chemical formula is Merck (Merck) index No. 10 Merck (NJ Rahway) Merck & Public_ > The 椷 面 " Four_Quinic Acid Quinine ”is 4C2〇H24N2〇2, 3H2S〇4.2Hi, I 4.6H20. In a more novel and better type of multi-brewed, the mother The qualitative compound does not need to be a class. For example, see the US Patent No. 4,87 ?, 3 13 and 5,002,701 «. Among these multi-chemical compounds, the _ mounting petal is formed into a shape and the compound is strongly polarized. The term " polyhalide " as used herein refers to a compound like polyiodide, but at least some of the iodine in the compound is replaced by another halogen element. The light valve of the present invention may include Any pre-proposed liquid suspension medium used for light "medium M suspended particles is usually • Liquid sickle floating medium may contain one or more americiums which can simultaneously suspend particles And dissolve Ren · polymerization stable cocoon (use Μ to reduce -7-; Η outfit (please read the note $ item on the back before filling in this page)

線A 本紙張X龙適用中國國家標準(CNS ) Α4规格(210Χ297公釐) 83. 3. 10,000 經濟部中央梯準局負工消費合作社印製 307830_Z_ 五、發明説明(5 ) 粒子黏聚之傾向因而维持粒子聽浮> 之高電阻性、化學情 性液驩。本技藝中所知之液態懸泮介霣於此皆可用,如揭 示於美國専利茱4,247,175號之液態》浮介霣。通常,钃 擇液鑣齄浮介霣或溶解於其中之聚合安定繭之一或二者, Μ維持懸浮粒子於重力平衡中。 於本發明中可用之光Μ騄浮液述於美國専利察 4,407,565號且其基於一具高爾阻性、化學惰性、低分子 曇液態氟碳聚合物之液艨鼸浮介質的使用•該《合物於室 溫具有至少約1 . 5之比重且其姐成朦子之至少約50%為瘺 素原子、至少約60%之鹵素原子為鎮且其餘為籯及/或_ 。較佳之液戆想浮介霣亦包含例如笨三甲酸三烷釀等等之 混溶性高電阻有機液«,以搮供*浮粒f重力平衡且幫肋 分敗液態懸浮介質中之粒子。其他用作涠瘠性离雪瞄有機 液麵之材料為該等於美圏專利莱第4,772,1 03中搨示者· 且有闞液態懸浮材料之细節可參見美國專利案4 , 407,565 號。 若使用足夠量之安定化聚合物,則不併有該由化液«I之 其他類型光闔懸浮液亦可使用,&可維持粒子於重力平衡 〇 另一有用之光閥懸浮液係基於使用非揮發性或最低揮發 性有槲液臑(通常分類為喔化劑)之液態懸浮介質。該"鑒 化劑”液態懸浮介質可包含一或多種可使粒?騄浮且可溶 解聚合安定劑之電胆性、化學情性、較不揮發(高沸點)之 有機液體。例如,當液戆光閥懋浮液之聚合安定_包括固 本紙張尺度適用中國國家橾準(CNS〉Α4规格(210Χ297公釐) 83. 3. 10,000 ----I.--5---Μ------訂------線 ί - (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局貝工消費合作社印装 Α7 Β7 五、發明説明(6 ) 臁聚(2 -甲基)丙烯酸鼸畤,有用之液軀嫌浮介霣包括聚 (2 -甲基)丙烯酸齙之液鼸塑化耀,例如己二釀_、苯甲酸 酯、三乙酸甘油、間笨二甲酸_、苯六甲酸釀、油酸醮 、氣烷烴、苯二甲酸酸、癸二酸_等等。其他固鐮聚合安 定劑之液戆懸浮介質可類似灞自用作該聚合物之塑化麵的 液_。較佳為,苯三甲酸三烷如苯三甲酸三 正-丙 基或三-正-丁基醮及/或己二酸二烷酷如己二酸二-2 -乙基己酯可用作K新戊基(2 -甲基)丙烯醱_之共聚物為基 材的固態聚合安定_之液戆懸浮介質。 當使用此聚合安定劑峙*其可為結合至粒子表面並且溶 於非水性液《或液態懸浮介質液艚中之輩一钃型固齷聚合 物。此外,可能有二或多種充作聚合安定麵糸統之固戆聚 合安定爾。例如,粒子可塗有第一類型之困鐮聚合安定_ (例如硝化繼維素),其可有效攞供一粒子之平面塗_,而 另一或更多其他類型之固態聚合安定_結合或則連間第一 類型固態聚合安定麵並可溶於液鼸黪浮介質中Μ使粒子分 敗及立《保護。 為保挎粒子》浮,液態嫌浮介質較佳亦可钽含如圈態聚 合安定爾,如掲示於1992年3月26日攞出申_之美圈専利 申請菜序號第855,266號及歐洲專利公告案350,354號之 Α-Β類型墉狀共聚物。除此塊狀共聚钧之外’於液戆懸浮 介質中亦可搌供有用之确化繼維素及/或其他固應聚合安 定麵。較佳為使用恰足夠之Α-Β鳙狀聚合物以保持粒子醣 浮,如所知,粒一給定之光閥懸泮液而言,其用量由經驗 -9- 本紙張尺度適用中國國家揉準(CNS ) A4規格(210X297公瘦) 83. 3.10,000 (請先閲讀背面之注^h項再填寫本頁) 訂 -線ί 經濟部中央標準局員工消費合作社印製 S^783Q at ___B7 __ 五、發明説明(7 ) 決定。通常*固態聚合安定繭之IT可為約196 m約309έ · 如5%至約25%,Μ钂量計且Μ光蠲液讎»浮液之擁重為 基準。然而,雖使用固籮聚合安定繭為較佳•但其不需用 於所有情況。事實上,如前述有讕用於光閨顧之專利申讅 菜中所述•可使用液態聚合安定_以增益。 光,.BL騰- 雖然液態光闕《浮液可用作例如光鼷之光變元件* 但具有分布於聚合物基霣之液《光闕嫌浮液微痛之_亦可 能用作光-調變元件。參見美臞專利寒3,257 · 995 、 3,341,274與4,919.521號·Μ &丨992年11月6日间在申 謫中之美_申睛案序號第972,826及972,830號,其等併 入本文Μ玆參考》 因此,癯用於光閾之釀可包含一具有光闕翳浮液微满分 布於基質内之交遵聚合物基質,此光W*浮液包含*浮於 一液態懸浮介霣中之粒子。於無電場旛加至光鬭懸浮液畤 ,此粒子呈現散亂布朗蓮動,而於有電場處加至光閨懸浮 液時圼對麵。 具有光閥懸浮液滴分布於其内之交達聚合物基爾讚可以 缠當之液艚而膨願。此改善所得麟之頻率共据特性,且滅 少光散射》 於本發明之一較佳具艚實嫌例中》交逋聚合物基霣為交 連之聚有機矽烷。 當此膜自一液雄可交壤聚有機矽烷之寡聚合物或聚合物 形成時•較佳為,使液籮可交連聚有檝矽烷之寡聚合物或 -1 0 - I I n 1- n Ί— n ^ 11 I I —訂 1111 線 C (請先閲饋背面之注意事項再填离本頁), 本紙張尺度適用中鬮國家標準(CNS ) A4規格(210X297公釐) 83. 3.10,000 經濟部中央橾準局員工消费合作社印褽 A7 B7 五、發明説明(8 ) 聚合物及一液態光閥_浮液,輿一作為乳化鳎之有櫬矽烷 /有機簞»共聚物乳化,接蕃處理乳化之薄靨以使可交達 聚有檐矽烷之寡聚合物或聚合物交繡,因而形成該 適用作光闥之光調變元件之膜亦可包含-*含有可溶於液 態光閥懸浮液之官能基的已交連聚合物基質。特定言之, 此聚合物基霣可藕由包括該官麄基之液鏞可交缠聚合物乳 化麵而提供。可_由使此光闞懸浮液於一液鏽可交連共聚 物乳化_中之乳化,接著為交缠反應而形成該顏。此禊戆 可交連共聚物乳化劑不僅提供交建之聚合物基質•並且於 形成該縝時作為乳化朗。 此_亦可包含一交*之聚有機矽烷《合物基*·且分布 於經交壤聚合物基材之液態光閾馨浮液可包括一部份或完 全氟化之聚合安定劑,糴Μ大致滅少光閥_之光歉射或 "白霧”。滅少白霧之進-步改善可藉由繅供具芳番基之纆 交連聚有機矽烷聚合物基賨及/或_由Μ—部份或完全鎮 化之有櫬液髓使該__釅而得。於此所用之”氟化”一辭意 指一部份或完全鎮化之材料。Line A This paper X Dragon applies the Chinese National Standard (CNS) Α4 specification (210Χ297 mm) 83. 3. 10,000 Printed by the Ministry of Economic Affairs Central Bureau of Standards and Labor Consultative Cooperative 307830_Z_ V. Description of the invention (5) Tendency of particle cohesion Thus maintaining the high resistivity and chemical sensation of particles listening to float. The liquid suspension pans known in the art can be used here, such as the liquid floating floats disclosed in US Liquid No. 4,247,175. Usually, one of or both of the liquid-selective floatation medium or the cohesive polymer cocoon dissolved in it, M maintains the suspended particles in gravity balance. The light humor floating liquid usable in the present invention is described in U.S. Patent No. 4,407,565 and it is based on the use of a liquid stern floating medium with high resistance, chemically inert, low-molecular-weight liquid fluorocarbon polymer. The compound has a specific gravity of at least about 1.5 at room temperature and at least about 50% of its elder sister is a fistula atom, at least about 60% of the halogen atoms are towns, and the rest are 籯 and / or _. The preferred liquid buoyant float also contains miscible high-resistance organic liquids such as trioxane triben, etc., in order to provide the gravity balance of the floating particles and to help distribute the particles in the liquid suspension medium. Other materials used for the organic liquid surface of the barren detached snow sight are equivalent to those disclosed in U.S. Patent No. 4,772,103. For details of the liquid suspension material, please refer to U.S. Patent No. 4,407,565. If a sufficient amount of stabilizing polymer is used, other types of photo-suspension suspensions without chemical solution «I can also be used. &Amp; can maintain particles in gravity balance. Another useful light valve suspension is based on Use a non-volatile or least volatile liquid suspension medium with mist liquid (usually classified as a sulfonating agent). The " identifying agent " liquid suspension medium may contain one or more organic liquids that can disperse the granules and dissolve the polymeric stabilizers, such as the electro-biliary, chemical, and less volatile (high boiling point) organic liquids. For example, when The stability of the polymerization of the liquid light valve and the floating liquid _ including the size of the solid paper is applicable to the Chinese National Standard (CNS> A4 specifications (210Χ297 mm) 83. 3. 10,000 ---- I .-- 5 --- Μ- ----- book ------ 线 ί-(Please read the precautions on the back before filling in this page) Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Α7 Β7 V. Invention Instructions (6) Ranju (2-Meth) acrylic acid molybdenum, useful liquid bodies such as poly (2-meth) acrylic acid liquid molybdenum plasticizers, such as adipo, benzoate, triacetin, M-dicarboxylic acid, mellitic acid, oleic acid, oleic acid, gas alkanes, phthalic acid, sebacic acid, etc. The liquid suspending medium of other solid sickle polymerization stabilizers can be similar to that used for this polymer. The liquid of the plasticized surface. Preferably, the trioxane of trimellitic acid such as tri-n-propyl or tri-n-butyl benzenetricarboxylic acid and / or the dioxane of adipic acid is like hexane. Di-2-ethylhexyl acid can be used as a liquid polymerization suspension medium for the solid polymerization stabilizer of K neopentyl (2-methyl) acrylamide copolymer. When using this polymerization stabilizer * It can be a metal-type solid polymer bonded to the surface of the particles and dissolved in a non-aqueous liquid or liquid suspension medium. In addition, there may be two or more solid polymer stabilizers that serve as a polymer stabilizer. For example, the particles may be coated with the first type of sleepy polymerization stabilizer (for example, nitrification following vitamins), which can effectively provide a flat coating of a particle, while another or more other types of solid polymerization stabilizers_ Combined or connected, the first type of solid-state polymerization stabilizer can be dissolved in the liquid mucous floating medium, so that the particles can be divided and protected. For the purpose of protecting the particles, the liquid floating medium is preferably also tantalum. Ring-shaped polymerization of Andalil, as shown on March 26, 1992, the application of the _Zomei application No. 855,266 and European Patent Bulletin No. 350,354 type A-B type copolymers. In addition to this block copolymerization 'Junwai' can also be used in liquid suspension medium to provide useful confirmation Vitamins and / or other solid-state polymerization stabilizers. It is preferable to use just enough A-B carp-like polymers to keep the particles floating, as known, for a given light valve suspension, the amount From experience-9- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 male thin) 83. 3.10,000 (please read the note ^ h on the back side and then fill out this page) Printed S ^ 783Q at ___B7 __ by the Bureau of Standards and Staff Consumer Cooperative V. The description of the invention (7) is determined. Usually * The IT of the solid-state polymerization stabilization cocoon can be about 196 m to about 309 ang. 5% to about 25% Moreover, the weight of the liquid is the benchmark of the floating liquid. However, although it is better to use a solid grate to stabilize the cocoon, it does not need to be used in all situations. In fact, as mentioned in the aforementioned patent application for Guanggu Gu • Liquid polymerization can be used to gain stability. Guang, .BL Teng-Although the liquid light-queue "floating liquid can be used as a light-variable element such as the light-emitting element *, but with a liquid distributed on the polymer base", the light-liquid floating liquid may also be used as light- Modulation element. See US Patent Nos. 3,257 · 995, 3,341,274 and 4,919.521 · M & 丨 in the United States in November 6, 992 in the application of Shen Mei_Shen Jing case serial number No. 972,826 and 972,830, which are incorporated herein by reference Therefore, the brew used for the photothreshold may contain a cross-composite polymer matrix with the photo-liquid floating liquid slightly distributed in the matrix, and the light W * floating liquid contains particles floating in a liquid suspension medium. When no electric field is added to the light suspension suspension, the particles show scattered Brownian motion, and when the electric field is added to the light suspension, the particles are opposite. The delivery polymer Kilzan, which has light valve suspended droplets distributed in it, can swell with the liquid stagnation. This improves the frequency coherence characteristics of the resulting lins, and eliminates light scattering. In one of the preferred examples of the present invention, the cross-linked polymer base is a cross-linked polyorganosilane. When the membrane is formed from a liquid male oligopolymer or polymer capable of intersecting polyorganosilane • Preferably, the liquid pan can be crosslinked with an oligopolymer or -1 0-II n 1- n Ί— n ^ 11 II —Order 1111 line C (please read the precautions on the back and then leave this page), the paper size is applicable to China National Standard (CNS) A4 specification (210X297mm) 83. 3.10,000 Printed by the Ministry of Economic Affairs of Central Central Bureau of Employee Consumer Cooperative A7 B7 V. Description of the invention (8) Polymer and a liquid light valve_floating liquid, as one of the emulsified soles, there is a silane / organic scrub »copolymer emulsified The emulsified thin tartium is processed so that the oligomers or polymers that can be delivered with eaves silane are intertwined, so that the film forming the light modulating element suitable for light can also contain-* Contains soluble liquid light valve The crosslinked polymer matrix of the functional groups of the suspension. In particular, the polymer base may be provided by the liquid embedding surface of the liquid noodles including the official base. It can be emulsified by emulsifying the suspension of the photocondensate in a liquid rust-crosslinkable copolymer, followed by the entanglement reaction to form the pigment. This cross-linkable copolymer emulsifier not only provides a cross-linked polymer matrix, but also acts as an emulsifier when forming the macro. This _ may also contain a cross-linked polyorganosilane "composite base *, and the liquid photo-threshold floating liquid distributed on the cross-linked polymer substrate may include a partially or fully fluorinated polymerization stabilizer, Xuan M 細 愛 少 光 光電 _ 光光 射 or " White Mist. &Quot; The further improvement of extinction and white mist can be further improved by supplying a cross-linked polyorganosilane polymer-based scorpion with an aromatic group and / or It is obtained from Μ-partially or completely ballasted liquid medulla. The term "fluorinated" as used herein means a partly or fully ballasted material.

鳖 iJUrMillJ&JiLJL 如於此所用,電磁光光譜之紫外光(fJV>K域包含具有波 長為約100埃至約4,000埃之鏞_的電磁輾射《該UV韉射 具危瞼性•特別對眼瞒,且亦可導致晒傷及可降解許多類 材料。因此,通常相當重要的是祖擄成吸收UV輻射K防止 或減少此類問鼸。 光鬮懸浮液因紫外光轜射•例如鼸光之絮外光囑射*而 *11- 本紙張又度適用中國國家揉準(CNS ) A4规格(210X297公釐) 83. 3. ίΟ,ΟΟΟ . ^ 狀 n 、v't> 矣《 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央橾準局員工消費合作杜印製 A7 B7 _ 五、發明説明(9 ) 易於降解,此對許多材料而言麵實。光鷗_及/或光闢懸 浮液曝«於UV輜射終究可埴成懸泮癘不利之改變’例如黷 色改變及/或於一給定外加鼋壓之對比比率之滅低。因為 光閥之許多應用包含使其中之光鼸及液鼸光Μ鼸浮液曝霣 於uv轎射,故滅低光«懸浮液受該瓤射之降解效應非常重 要。當然,可沈稹一犟或多曆之本技蕕所知之塗顏•其可 吸收或反射遭受任何照射至光閥之丨丨V糴射的光鼸外蟹之紫 外光輻射。Μ該塗黼逋*UV囑射可降低到達光«的光»» 浮液之11V轜射量而因此有利。然而•該塗膜可醢霱饕一欲 «免之相當費用。 紫外光吸收_,有時於本技藝中稱作紫外光安定覿*為 一種可吸收電磁光譜紫外光匾域之糴射雛。有許多巳知類 型之UV吸收繭。二苯甲_為廣泛使用之一類UV暇收_。然 而,其通常於低極性膽肪族液*中之溶解度受隈·而因此 不完全遘用於光閥懸浮液。其他類可臃之UV圾收爾*例如 酚-鑠鍇合物*亦不完全遴用於光醐懸浮液*係因下列因 素所致:低劣之溶解度、於若千情形中有太*之導電度、 或與懸浮粒子相容不佳。 為得到優良ϋν吸收_之優點•又丨翊時親免輿大多數類型 UV安定繭有闞之問鼷,業巳發琨娜作已取代或未取代之 2-(2’-羥基苯基)-苯並三氮唑的此類UV吸收爾與此光鬮_ 浮液搭配為槿佳。(方便起見,此等UV吸收爾於此可構作 ”苯並三氮唑衍生物”。 -12- 藏------訂------線{ (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家揉準(CNS ) Α4規格(2丨0X297公釐) 83. 3.10,000 307830 Μ Β7 五、發明説明(10 ) 液戆或固鼸苯並三氣唑衍生物可於液態光讕赚浮濂製進 前或後溶於液戆光閥聽浮液之液懸懸浮介質中》當此笨並 三氮唑衍生物為高度绲溶之液钃時可特別有利*因為此 UV吸收_然可包含一相當部份之禊钃光闢懸浮隳,而因此 極有效預防或滅少光鼷·浮液之ϋν降解。較佳為·該液態 笨並三氣唑衍生物為非揮發性或籌低揮發性I Μ具有極瓶 之蒸氣壓•若用於光閥_,刖使其保存於_中。 有數種使U.V.安定繭可併人含液满之_的方法。例如· 此U.V.安定麵可溶於用Μ處理此臢且因此辱入此鹏之_麇 爾中。參見美鼷専利申讅蒹序號第972.826 «。或者 U.V.安定麵可於和基霣聚合物滟合铺加入液耀光»赚浮液 。或者U.V.安定麵可與聚合物基霣溷合◊或者U.V.安定_ 可直接併人聚合物基質(例如· KU.V.吸收麵分子取代聚 二甲基矽烷聚合物之若千甲基官能基•或其他基質聚合物 中之其他該取代)。或者U.V.安定爾可纆由U.V.安定_輿 反應單«之衍生化而直接併入安定化之聚合物,且鼸後共 聚合Κ產生安定化聚合物。 包括UV-吸收官能基之犟_(較佳之單黼為笨並三氮唑) 可便於用作(1)液戆懸浮液之安定化聚合物中及/或(2) 於膜形流體鼸浮液中所用基爾聚合物之部份結構的共犟麵 〇 於另一具黼實例中,此安定化聚合物或基爾聚合物含有 可與ϋν-吸收材料反應之反應官雛基•例如笨並三氮_之 衍生物,於其結構中《其具有-·可輿基質聚合物或安定化 -13- (請先閲讀背面之注意事項再填寫本頁) 訂 經濟部中央標準局貝工消費合作社印製 本紙張尺度適用中國國家樣準(CNS > A4规格(210X297公釐〉 83. 3. !〇,〇〇〇 A7 B7 五、發明説明(11) 聚合物中之反應官_基反應且结合之官麄基。 臁注意雷一光《篛阻《嫌乎所有大部份*通它之uv_射 時,此光鬮之價值可大幅提昇,因為其可防让光w 一脚之 工作件免受由光閾另一側醱射之UV緬射(例如_光)的降解 〇 因此本發明_由在光闢懸浮液之隳臁光«»浮介爾中包 含一有效量之固態或液戆笨並三氱唑衍物•而提供一免_ 露於紫外光輻射之安定液態光閥懸浮液β 本發明亦_由在液態光閥懸浮液之聚合安定麵中併入一 有效UV-安定化之最的共聚合犟髑之犟牖(其包括一 U V -暇 收性官能基,例如苯並三氮唑之衍生物),而攆供一免_ 露於紫外光編射之安定的液態光關_浮液。 本發明亦攞供一 UV-安定化_,其I»由使用一有效鼉之 液態苯並三氮唑衍生物作此顏之膨脹繭及/或_由於此膜 之基質聚合物中併入一有效最之共聚合犟位的苯並Ξ氮喃 衍生物,而可用作光閥之光-讕變元件。 本m涟胤銳1 用於本發明之笨並三餛_衍生物包括該等具化式(I )者 (請先閲讀背面之注意事項再填寫本頁) 成!Turtle iJUrMillJ & JiLJL As used herein, the ultraviolet light of the electromagnetic light spectrum (fJV > K domain contains electromagnetic waves with a wavelength of about 100 angstroms to about 4,000 angstroms_ electromagnetic rolling "The UV ray archer is dangerous for the eyelids • Especially Concealed, and can also cause sunburn and degradable many types of materials. Therefore, it is usually very important that Zu Chengcheng absorbs UV radiation K to prevent or reduce such problems. The light suspension is irradiated by ultraviolet light. The light of the light is directed by the light * and * 11- This paper is again suitable for the Chinese National Standard (CNS) A4 specification (210X297 mm) 83. 3. ίΟ, ΟΟΟ. ^ 状 n 、 v't> 韣 《( Please read the precautions on the back before filling out this page) A7 B7 _ printed by the consumer cooperation of the Central Central Bureau of Economic Affairs of the Ministry of Economic Affairs _ V. Invention Instructions (9) It is easy to degrade, which is true for many materials. Guangou_ and / Or light exposure suspension exposure to «UV radiation can eventually lead to unfavorable changes in suspension '' such as black color changes and / or the reduction of the contrast ratio at a given applied pressure. Because of the many applications of light valves Including exposing the light mule and the liquid mule Μ 铸 floating liquid to the uv car, so the low light is extinguished. The degradation effect of the liquid is very important. Of course, it can be painted or known by the skilled arts. It can absorb or reflect any light that is exposed to the light valve. The ultraviolet radiation of the crabs outside the mule. ΜThe coating of UV light can reduce the amount of 11V emission of the light reaching the light «light» »and is therefore beneficial. However, the coating film can be used to avoid« free It is quite expensive. Ultraviolet absorption_, sometimes referred to in the art as ultraviolet stabilization * is a kind of larvae that can absorb the ultraviolet spectrum of the electromagnetic spectrum. There are many known types of UV absorption cocoons. Dibenzone _Is one of the widely used UV leisure collections. However, its solubility in low-polarity cholesteric liquids * is generally affected by Kuma, and therefore it is not completely used in light valve suspensions. Other types of UV waste can be collected. * For example, phenol-halonium sulfonate compounds * are not completely used in the suspension of optical sachets * due to the following factors: poor solubility, too high conductivity in the case of Ruoqian, or incompatibility with suspended particles In order to get the advantages of excellent ϋν absorption _ again 丨 Yi Shi pro-free and most types of UV stable cocoon has a pity Asked, this kind of UV absorption of 2- (2'-hydroxyphenyl) -benzotriazole, which is substituted or unsubstituted by Ye Sifa Kunna, is the best combination of this light and buoyant. For convenience, these UV absorptions can be constructed here as "benzotriazole derivatives". -12- Tibetan ------ order ------ line {(please read the notes on the back first Please fill in this page again) This paper scale is applicable to China National Standard (CNS) Α4 specifications (2 丨 0X297mm) 83. 3.10,000 307830 Μ Β7 V. Description of invention (10) Liquid or solid benzotriazine Derivatives of azole can be dissolved in liquid suspension medium before or after being prepared in liquid light, and can be dissolved in the liquid suspension medium of the light valve and the floating liquid. When the stupid triazole derivative is a highly soluble liquid, it can be It is particularly advantageous * because this UV absorption can contain a considerable part of the suspended light, which is extremely effective in preventing or destroying the degradation of the light and floating liquid. It is preferable that the liquid benzotriazole derivative is non-volatile or has low volatility. It has a vapor pressure of the polar bottle. • If it is used in a light valve, store it in it. There are several ways to make U.V. stable cocoons and people filled with liquid. For example, this U.V. stability surface is soluble in the treatment of this dill with Μ and thus is insulted into this penguin. Please refer to the serial number 972.826 «. Or the U.V. stabilizer can be added to the Yaoguang polymer base to add liquid flares »earn floating liquid. Or the UV stabilizer can be combined with the polymer base ◊ or UV stabilizer _ can be directly incorporated into the polymer matrix (for example, KU.V. The absorption surface molecule replaces the dimethylmethyl functional group of the polydimethylsilane polymer • Or other such substitutions in other matrix polymers). Alternatively, U.V. stability can be directly derivatized into the stabilized polymer by derivation of the U.V. stability_Yu reaction sheet, and post-copolymerization of K can produce a stabilized polymer. Included UV-absorbing functional groups (preferably monofluorocarbons are benzotriazoles) can be conveniently used as (1) stabilizing polymers in liquid suspensions and / or (2) floating in membrane-shaped fluids The common structure of the partial structure of the Kiel polymer used in the liquid. In another example, this stabilized polymer or Kiel polymer contains a reactive base that can react with the ϋν-absorbing material. Derivatives of Pyrogallium_ in its structure "It has-· may be based on matrix polymer or diazepam-13- (please read the precautions on the back before filling out this page). The paper scale printed by the cooperative is applicable to the Chinese national standard (CNS> A4 specification (210X297 mm> 83. 3. 〇〇〇〇〇〇7 A7 B7. V. Description of the invention (11) Reaction officials in the polymer _ based reaction And the combination of the official government. Lao pay attention to Lei Yiguang's "Zhu obstruction" is suspected that most of the * through its uv_ shot, the value of this light can be greatly improved, because it can prevent light w The work piece is protected from the degradation of UV light emitted by the other side of the light threshold (for example, light). Therefore, the present invention is suspended by the light The floating light «» floater contains an effective amount of solid or liquid tribenzazole derivative and provides a free _ stable liquid light valve suspension β exposed to ultraviolet radiation. The invention also _Incorporating a most effective UV-stabilizing copolymerization of the light stabilizer suspension into the polymerization stabilizer surface (which includes a UV-recovery functional group, such as benzotriazole Derivatives), and provide a free _ stable liquid light off exposed to ultraviolet light _ floating liquid. The present invention also provides a UV- stabilized _, which I »by using an effective liquid benzo The triazole derivative is used as the expansion cocoon of this face and / or because the matrix polymer of this film incorporates an effective and most copolymerized benzotriazole derivative, it can be used as a light valve light -Variable components. This mianyin sharp 1 is used in the present invention and includes three derivatives (I) (please read the precautions on the back before filling this page).

、1T 經濟部中央樣率局貝工消費合作社印製1T Printed by Beigong Consumer Cooperative of Central Sample Bureau of Ministry of Economic Affairs

本紙張尺度適用中國國家標準(CNS ) A4規格(2丨0X297公釐) 83. 3. 10,000 經濟部中央標準局貝工消费合作社印製 A7 £7___ 五、發明説明(12 ) ,其中Ri、1^及Ra僩8!丨為鳐、_素戒有機官鑠基。如上所 述•當此苯並三《唑用作共蓽艚時,h或h可為一具有可 聚合雙鍵之有機官能基*較佳為終_之可聚合雙鍵。合瓛 之R a為氫、廉素*較佳為氱、烷基戒烷氧基。興有終纗之 可聚合雙鐽的有櫥官能基較佳可得自丙烯釀戒2-甲基丙烯 酸,或其醮類或釀胺類。 西巴-集巨(Ciba-Geigy)公司販賣用作UV圾收爾之笨並 三氯唑衍生物,其註冊商檮為TINUVIN 。此笨並三欐唑具 有上述化式(I )。例如,於Tinuvin 327中* Ri及Ra各為 第三丁基,且R3為氱。於Tinuvin 3 28中,各R:及h各确 C(CH3)2CH2CH3 基,&Ra 為氫。於 TUuvin 326 中 * 1^為 第三丁基、R2為甲基且R 3為籯。於T i n u v丨η P中,R i與 民3各為籯且R 2為甲基。所有此四種化合物於室溫為固鼸粉 末。雖然所有此四種化合物於某些有櫬液讎中可溶解•但 Tinuvin 328於低極性有檐液_中最易溶解,且因此當溶 解於光閾懸浮液之液皤嫌浮介質中或直接溶解於其本身之 懸浮液中畤,此類化合物為最有用。 液態之苯並三氣唑衍生物亦為已知。例如Tinuvin 38 4 為液《。Tinuvin為化式(I ),其中!U為第三Γ基、R *為 -CH2CH2COOC*H17且R3為氳。懸浮液中UV暖收麵之溶解度 愈大•可安全置入騄浮液而無此物料沉澱雔害之用量愈多 ,且可保護懸浮液而免受U V輻射之效果愈佳。並且*由光 閥中懸浮液所吸收之UV_射愈多,當光閫用作窗子時*此 光閥可防止毯子、傢俱、油漆,等等免受UV糴射之降解更 -15- 本紙張尺度適用中國國家揉準(CMS〉Α4規格(210X297公釐) 83. 3. 10,000 « · Μ —訂 务/ (請先閲讀背面之注意事項再填寫本頁)。 五、發明説明(13 ) hi B7 經濟部中央標準局貝工消費合作社印製 有效。 亦可於液戆懸浮液之聚合安定翮成於光闢麟之基質聚合 物中併入一 UV-吸收化合物,蚁明_改善光闢鼸浮禊對 U V輻射之安定性。 使用如亞利桑那州、凰匯城之海耀爾斯(Her aeus) DSET研究室(Labor at or ies)有限公_販售之名為”陽光酒 試(Suntest) CPS”的UV光灝股僑,對竇例中所述之液艟光 闕懸浮液及膜進行鎩密之IIV澜試 <> 此設備轤出低於800 ΠΒ之總輻射為每平方米400與765瓦之間,且於最大功率 下操作下述試驗。 m^SLL· 使光閥光電管中之液戆光閾懸浮液受DV光澜鼸射605小 時。此懸浮液包含2.5%之期狀物(包含塗覆礴化_維素鼙 合物之吡畊-2,5-二羧酸多_化鈣粒子>、20. 5¾之苯三甲 酸三-n-丁醮、3.1 696之安定化聚合物(其為具有約 3 09, 000之平均分子璗且70個2-甲基丙烯酸烴基乙_之掣 髑犟位的新戊基2 -甲基丙烯酸《/ 2 -甲II丙烯酸煙基乙_ 之A-B塊狀共聚物)、69.84%之哈羅卡朋油(13〗〇〇84<^ Oil) 0.8型(新澤西州、囂肯瞒(Hackensack)之哈羅卡朗 產品販售)及4%之Tinuvin 328 。曝露於UV光# 605小時 後*覼察之顔色或吸收性(a bsorba nee)鵃乎無變化。 使2.07克之具有約150,000分子饞之二烴基終鳙的聚 二甲基矽烷與0 . 0 4克之四丁基正砂酸翻、〇 . 05克之二丁基 16 請· 先 閲 讀·背 項 再 4 寫 本 頁 Μ 訂 線 本紙張尺度適用中國國家梯準(CNS ) Α4规格(210X297公釐〉 83. 3.1〇,〇〇〇 307830_ 五、發明説明(l4 ) 二月桂酸錫、0 . 2克之聚二甲基砂埦/新戊* 2 -甲基丙嫌 _酗之塊狀共聚物乳化麵及0.74¾之粒子灞縐物加熱而结 合、乳化及交連,Μ製得一 此灌鎞物為-黏潲漉_之 液態懸浮液,其包含20%之糊狀物(其包含艙覆_化__ 素聚合物之吡畊-2,5 -二羧酸多嫌化鈣粒、20%之具有 約349,000平均分子量且僅8個2-甲基丙烯醣蠼基乙_單 髓單位的新戊基2 -甲基丙烯酸酯/ 2 -甲基丙烯酸煙基乙_ 之A-B塊狀安定化共聚物、Μ及60%之苯三甲酸三-η-丙 酗之_化液體。以10%1^〇1^丨〇323之3,6-二甲基辛烷溶 液使經交連之議膨脹。將此纆膨礙之臢置於光Μ光爾管中 且曝露於UV光灑中575小時,而膜之顥色®峨收性嫌乎嫵 變化。 霞Jim 可使用Tinuvin 384 、液鼸UV賑收劑取代Tinu*in 328 、固齷而重覆實例]及2 •可得類斛结果》 已知甚多之UV-吸收單體的實例。例如*包含緬取代及 未經取代之苯並三氮唑的可聚合犟艚係揭示於美_專利渠 第 4,528,311 、 4,612,358 、 4.868,251 、 4,785.063 及 經濟部中央標準局員工消費合作社印裝 5,112,912號中。非苯並彐氰唑衍生物之可共聚合單黷癱 UV吸收劑實例陳述於,例如美國専利案第3,1 62,676與 4,304,895號及英圃専利案885,986號<> 該UV-吸收單«(較佳為僅包含·可聚合终蠼聲鏞)可鑤 於併入任一光閥技藝或本發明所揭示之安定化聚合物及/ 或基質聚合物,且具有明鼷改善其所併入之光闢懸浮液的 17 本紙張尺度適用中國國家揉準(CNS ) A4规格(210X297公釐) g3. 3. 1〇.°00 A 7 B7 $07830_ 五、發明説明(15 ) U V吸收性之功效》 亦可》由使用包含一反應官能基之ϋ\Γ-吸收材料興安定 化聚合物或基質聚合物中之缠當反應官雕基反應· κ使該 等UV-吸收官能基接至安定化聚合物或基霣聚合物,而使 UV-吸收材料與安定化或基霣聚合物結合。例如•安定化 或基質聚合物可包含丙烯醱甘油_或2 -甲丙婦酸甘油醮之 官能基。該等官能基可輿例如包含躲綦或其他反應官能基 之苯並三氮唑衍生物的U V -吸收化合物反應。該方法、化 合物及共聚物掲示於美顯專利案第5 ,112. 9 12號。 當然,UV-吸收_之量可Μ霄__定· Μ提供所需之 UV吸收性。於使用液態UV吸收麵之時,其可攞供所有之液 態懸浮介霣,且此可構成大於約70% Κ重鼉計之光闢_浮 液。於光調變元件為膜之形式時,基鬌聚合物及液態光闕 懸浮液各較佳含有U V吸收麵,使潯U V吸收爾之鱅屋Μ光謂 變元件之總重為基準為至少1% *較佳大於約3%。 雖然已舉譖本發明之特定具體實例*但可知本«明並因 此受限•故由任一熟悉此技«者所作之任何修正皆隸麵本 發明之輿實精神及領域。 經濟部中央標準局員工消費合作社印製 本紙張尺度逋用中國鬮家棣準(CNS ) A4规格(210X297公釐) 83. 3. 10,000This paper scale applies the Chinese National Standard (CNS) A4 specification (2 丨 0X297mm) 83. 3. 10,000 Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 £ 7 ___ V. Description of invention (12), of which Ri, 1 ^ And Ra Xu 8! 丨 is a ray, _Sujie organic official sulfonyl group. As mentioned above • When this benzotriazole is used as a co-fungal, h or h may be an organic functional group having a polymerizable double bond * preferably a final polymerizable double bond. The R a of the 瓛 is hydrogen, and L * is preferably 氱, alkyl or alkoxy. It is preferred that the polymerizable bismuth-containing cabinet-like functional group is preferably obtained from propylene or 2-methacrylic acid, or its amides or amines. The Ciba-Geigy company sells the benzotrichloride derivatives used as UV waste collectors and its registrar is TINUVIN. This stupid tripyrazole has the above formula (I). For example, in Tinuvin 327 * Ri and Ra are each the third butyl, and R3 is 氱. In Tinuvin 3 28, each R: and h each confirm C (CH3) 2CH2CH3 group, & Ra is hydrogen. In TUuvin 326 * 1 ^ is a third butyl group, R2 is a methyl group and R 3 is 籯. In T n u v i n P, R i and Min 3 are each Y and R 2 is methyl. All four of these compounds are solid powder at room temperature. Although all of these four compounds are soluble in certain liquids, Tinuvin 328 is most soluble in low-polarity eaves liquids, and therefore when dissolved in the liquid suspension of the optical threshold suspension, it is likely to be in a floating medium or directly Dissolved in its own suspension, these compounds are the most useful. Liquid benzotriazole derivatives are also known. For example, Tinuvin 38 4 is liquid ". Tinuvin is chemical formula (I), among them! U is the third Γ group, R * is -CH2CH2COOC * H17 and R3 is radium. The greater the solubility of the UV warming surface in the suspension. The more the amount of puddle floating liquid that can be safely placed without the precipitation of this material, and the better the effect of protecting the suspension from UV radiation. And * the more UV_ absorbed by the suspension in the light valve, the more the light is used as a window * this light valve can prevent blankets, furniture, paint, etc. from being degraded by UV light. The paper scale is applicable to the Chinese National Standard (CMS> Α4 specification (210X297mm) 83. 3. 10,000 «· Μ-ordering / (please read the precautions on the back and fill in this page). Fifth, the description of the invention (13) hi B7 Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. It can also be stabilized in the polymerization of liquid suspension suspensions and incorporated into a matrix polymer of Guangpirin, which incorporates a UV-absorbing compound. The stability of the ponchos to UV radiation. The use of such as Heraeus DSET laboratory (Labor at or ies) limited company in Arizona, Phoenix _ sold under the name "Sunshine wine test (Suntest ) CPS ”UV photon stocks overseas, conducted a liquid IIV test on the liquid and light suspensions and membranes described in the case of Dou. ≪ > The total radiation emitted by this equipment is less than 800 ΠΒ per square Between 400 and 765 watts, and operate the following test at maximum power. M ^ SLL The liquid suspension of the light threshold was exposed to DV light for 605 hours. This suspension contains 2.5% of the period (including pyrogen-2,5-dicarboxylic acid polypyridinate-coated with sulfonated _weisu compound) _Calcium oxide particles>, 20.5¾ of tri-n-butyric acid trimellitate, 3.1 696 stabilization polymer (which is an average molecular weight of about 3 09, 000 and 70 2-methacrylic acid hydrocarbon groups Neo-pentyl 2-methacrylic acid (B-copolymer of 2-methylmethacrylic acid nicotinyl-B), 69.84% of halocapone oil (13〗 〇〇84 < ^ Oil) Type 0.8 (New Jersey, Hackensack ’s Hakakarang products sold) and 4% Tinuvin 328. Exposure to UV light # 605 hours * Color or absorbency observed (a bsorba nee) is almost unchanged. Make 2.07 grams of polydimethyl silane with approximately 150,000 molecules of dihydrocarbyl terminal bigheads and 0.04 grams of tetrabutyl orthosalicylate, and 0.05 grams of dibutyl 16 please. Read and recite first and then write this page 4. The paper size of the line book is applicable to China National Standard (CNS) Α4 specification (210X297mm) 83.3.1〇, 〇〇〇307830_ V. Description of the invention (l4 ) Tin dilaurate, 0.2 g of polydimethyl satin / neoprene * 2-methylpropyl _ heavy block block copolymer emulsified surface and 0.74¾ particle crepe are heated to combine, emulsify and cross-link , M prepared a liquid suspension of-sticky _ liquid suspension, which contains 20% of the paste (which contains the coating _ __ chemical polymer of pyrogen-2,5-dicarboxyl Acid polycalcium granules, 20% of neopentyl 2-methacrylate / nicoyl 2-methacrylate with an average molecular weight of about 349,000 and only 8 2-methacryloyl ethanoyl_monomedullary units AB block stabilized copolymer of B, M and 60% tri-n-propene tricarboxylic acid liquid. The cross-linked protocol was expanded with 10% solution of 3,6-dimethyloctane 323. This swelling was placed in a light tube and exposed to UV light for 575 hours, and the film's Hao color® acceptability seemed to change. Xia Jim can replace Tinu * in 328 with Tinuvin 384, liquid ray UV collector, and repeat the example] and 2 • Available results >> There are many known examples of UV-absorbing monomers. For example, the polymerizable tungsten containing Burmese substituted and unsubstituted benzotriazoles is disclosed in U.S. Patent No. 4,528,311, 4,612,358, 4.868,251, 4,785.063, and printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs No. 5,112,912 in. Examples of copolymerizable monochrysanthemum UV absorbers that are not benzocyanazole derivatives are described in, for example, U.S. Kerry Case Nos. 3,1 62,676 and 4,304,895 and Yingpu Keli Case No. 885,986 < > «(Preferably contains only • polymerizable final yoke) can be incorporated into any light valve technology or the stabilized polymer and / or matrix polymer disclosed in the present invention, and has the advantages of improving its incorporation The 17 paper scales of Guangpi Suspension are suitable for China National Standard (CNS) A4 (210X297mm) g3. 3. 10.0. ° 00 A 7 B7 $ 07830_ 5. Description of the invention (15) The effect of UV absorption 》 Also》 By using ϋ \ Γ-absorbent materials containing a reactive functional group to stabilize the entanglement in the polymer or matrix polymer, the reaction will be based on the reaction. Κ These UV-absorbing functional groups will be connected to the stabilizer Polymer or base-based polymer, and the UV-absorbing material is combined with the stabilizer or base-based polymer. For example, the stabilizer or matrix polymer may contain the functional groups of propylene glycerin or 2-methylpropionic acid glycerin. Such functional groups may be reacted with UV-absorbing compounds including, for example, benzotriazole derivatives of benzotriazole or other reactive functional groups. This method, compounds and copolymers are shown in US Patent No. 5,112. 9 12. Of course, the amount of UV-absorption can be set to provide the required UV absorption. When the liquid UV absorption surface is used, it can provide all the liquid suspension medium, and this can constitute more than about 70% of the light _ floating liquid. When the light modulating element is in the form of a film, the base polymer and the liquid light-queue suspension preferably each contain a UV absorbing surface, so that the total weight of the UV absorber Miyao light modulating element is at least 1 % * Is preferably greater than about 3%. Although specific examples of the present invention have been cited *, it can be seen that this document is clearly and therefore limited. Therefore, any amendments made by anyone familiar with this technique will reflect the spirit and field of the invention. Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

Claims (1)

^荦83丨0:;238號專利由請案 λ8 3ϋν63〇 88 由文由辑專利範園烙正本(86年2月; 3^ 荦 83 丨 0 :; No. 238 Patent Application Request λ8 3ϋν63〇 88 You Wen You Ji Original copy of the patent Fan Yuan (February 86; 3 經濟部中央標隼局員工消费合作社印製 1 · 一種液態光閥懸浮液,其包含懸浮於一液態懸浮介霣中 之粒子及該液_懸浮介質中之安定丨b聚合物,W避免該 等粒子黏聚,該安定化聚合物包含一jj V -吸收有效量之 茏並三氮唑丨H-吸牧酮*其中該安定化聚合物包含其與 該u v吸收劑之a體盟位共聚合之翬體單位,或該丨j v吸收 劑係藉由伴隨之反應而與該安定化聚合物结合。 2. 根楝申譜專利範圍第1項之懸浮液,其中該u v吸收劑為 一種笼並三氮唑衍生物,其具有可與該聚合安定劑之該 罝體盟位共聚合之基團。 3. 根據申謫專利範圍第1項之懸浮液 > 其中該UV吸收劑為 一$並三氡唑衍生物具有可與該聚台安定劑反骣之基圈 0 4 . 一種適用作為光閥之光調變元件之_ *其包含一聚合物 基質及分布於此聚合物基®中之如申耩專利範圍第1 、 2或3項所請之液態光闕懸浮液之微滴,此聚合物基筲 戎此液態光闊懸浮液戎二者均包含一1丨V -吸牧有效量之 Π V吸收劑。 5. 根據申請專利範則第4項之賴,其中該聚合物基霣包含 其®該IJV吸收劑之簠餺置位共聚合之里體覃泣。 6. 根撺由諝專利範晒荦4項之膜,其中該丨jV吸收劑藕由伴 埔之反應而與該聚合物基S结合。 7 . 根據申請專利範_第5琿之_,其中該丨jV吸收劑為一棰 茏竝三氮唑衍生物*其具有可與該聚合物基筲之該里體 罝泣共聚合之基團。 (請先閔讀背面之注意事項再填寫本頁) 本紙伕尺度適用中國國家梂準(CNS) A4说格ί 210X 297公釐S 3 δ 7ο 7} ABCD 六、申請專利範圍 8. 根據申請專利範圍第7項之膜,其中該UV吸收劑為一苯 並三氮唑衍生物,具有可與聚合物基霄反應之基團。 9. 一種光閥,其具有對立之光霣管器雙,及一介於該等光 電管器壁間之光調變元件.其中之改良為此光調變元件 為申諝專利範圍第1項之液態光閥懸浮液。 10. —種光閥,其具有對立之光電管器1,及一介於該等光 罨管器壁間之光調變元件*其中之改良為此光調變元件 為申諝專利範園第4項之膜。Printed by the Employee Consumer Cooperative of the Central Standard Falcon Bureau of the Ministry of Economic Affairs1. A liquid light valve suspension, which contains particles suspended in a liquid suspension medium and the liquid_stable polymer in the suspension medium, to avoid these Particles agglomerate, the stabilizing polymer contains a jj V -absorption effective amount of benzotriazole 丨 H-sucker ketone * wherein the stabilizing polymer contains its co-polymerization with the a body of the uv absorbent The unit of the body, or the jv absorbent, is combined with the stabilized polymer through the accompanying reaction. 2. Suspension of No. 1 in the patent scope of Neemin Spectrum, wherein the u v absorber is a caged triazole derivative having a group copolymerizable with the gangbit of the polymerization stabilizer. 3. Suspension according to item 1 of the patent scope of the application for application> where the UV absorber is a triazole derivative with a base ring that can be reversed with the polystabilizer 0 4. One suitable for use as a light valve The light modulating element _ * It consists of a polymer matrix and microdroplets of liquid photo-queue suspension distributed in this polymer matrix ® as claimed in item 1, 2 or 3 of the patent application, this polymerization Material-based Sharon This liquid light broad suspension contains both a 1 V-absorbing effective amount of Π V absorbent. 5. According to Item 4 of the Patent Application Regulations, where the polymer-based compound contains its ® IJV absorber, which is co-polymerized in the position-in-place system. 6. The film according to the patent No. 4 of the patent document, in which the JV absorbent lotus root is combined with the polymer base S by the reaction of Banpu. 7. According to the patent application _ 第 5 珲 之 _, in which the 丨 jV absorber is a dibenzotriazole derivative * which has a group which can be copolymerized with the polymer base of the polymer . (Please read the precautions on the back first and then fill out this page) This paper is applicable to China National Standards (CNS) A4 said grid 210X 297mm S 3 δ 7ο 7} ABCD VI. Patent application 8. According to patent application The film of item 7 in the scope, wherein the UV absorber is a benzotriazole derivative having a group reactive with a polymer base. 9. A light valve, which has a pair of opposite phototubes, and a light modulating element interposed between the walls of the photocells. The improvement is that the light modulating element is the liquid state of claim 1 of the patent scope Light valve suspension. 10. A light valve, which has an opposite photoelectric device 1, and a light modulating element between the walls of the light ducts * The improvement of which is the light modulating element is the 4th of the patent patent garden Of the film. 經濟部中央標嗥局員工消費合作社印製 -2- (請务閱讀背面之注意Ϋ項再填寫本頁)Printed by the Employee Consumer Cooperative of the Central Standardization Bureau of the Ministry of Economic Affairs -2- (Please read the note Ϋ on the back and fill out this page) 本紙張尺度逋用中國國家椹準(CNS ) A4洗格(210X297公釐)The size of this paper is washed with Chinese National Standard (CNS) A4 (210X297mm)
TW83103238A 1991-11-01 1994-04-12 TW307830B (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US78651191A 1991-11-01 1991-11-01
US07/972,830 US5463492A (en) 1991-11-01 1992-11-06 Light modulating film of improved clarity for a light valve
US07/972,826 US5463491A (en) 1991-11-01 1992-11-06 Light valve employing a film comprising an encapsulated liquid suspension, and method of making such film
US08/059,980 US5467217A (en) 1991-11-01 1993-05-11 Light valve suspensions and films containing UV absorbers and light valves containing the same

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