TW302411B - - Google Patents

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TW302411B
TW302411B TW83105999A TW83105999A TW302411B TW 302411 B TW302411 B TW 302411B TW 83105999 A TW83105999 A TW 83105999A TW 83105999 A TW83105999 A TW 83105999A TW 302411 B TW302411 B TW 302411B
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Taiwan
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compound
resin
composition
item
water
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TW83105999A
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Chinese (zh)
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Sumitomo Electric Industries
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3〇24U B7 經濟部中央標準局貝工消费合作社印製 五、發明説明( 1 ) 1 1 本 發 明 係 關 於 一 種 紙 塗 料 組 成 物 尤 指 一 種 組 成 物 > 1 1 可 對 紙 賦 予 優 異 的 印 刷 品 質 和 傑 出 的 印 刷 结 果 〇 1 I 此處所用「紙 J 廣 義 涵 蓋 並 包 含 狹 義 之 紙 Μ 及 紙 請 1 先 1 板 〇 閱 I 讀 1 | 在 紙 上 施 加 主 要 由 顔 料 和 水 性 黏 合 劑 組 成 的 紙 塗 料 組 背 面 1 I 之 成 物 再 接 績 必 要 步 m 諸 如 乾 燥 和 砑 光 所 得 塗 佈 紙 9 注 意 1 1 已 廣 用 於 商 業 印 刷 品 、 雜 誌 Λ 書 等 因 具 有 優 異 的 印 刷 事 項 1 再 1 效 果 等 性 能 0 隨 著 曰 漸 需 要 較 高 品 質 和 開 發 高 速 印 刷 % 本 裝 技 術 壙 不 斷 努 力 進 —* 步 改 善 塗 佈 紙 的 品 質 〇 特 別 是 頁 1 1 在 主 宰 各 種 印 刷 技 術 的 平 版 印 刷 業 為 顧 及 水 潤 濕 效 果 1 1 Λ 吸 濕 等 防 水 性 Μ 及 在 輪 轉 機 上 的 防 起 泡 性 能 改 善 1 油 墨 接 受 性 乃 成 重 要 課 題 〇 1 1 為 解 決 上 述 問 題 通 常 是 於 紙 塗 料 組 成 物 添 加 濕 增 強 1T 1 劑 或 印 刷 品 質 改 良 劑 包 含 蜜 胺 -甲醛樹脂 '脲- 甲 醛 樹 1 I 脂 > 或聚醮胺聚脲 -甲醛樹脂 參見例如J P - B - 69 -11667 1 1 和 JP -Β -84- 3 2 5 97 (JP -B指 審 査 公 告 的 曰 本 專 利 申 請 案 )° 1 1 雖 然 此 等 習 知 濕 增 強 劑 或 印 刷 品 質 改 良 劑 $ 顯 示 有 效 特 徵 但 在 部 份 所 需 特 徵 方 面 仍 各 有 嚴 重 缺 陷 或 不 足 f 1 1 無 法 始 终 滿 足 實 用 0 1 | 例 如 f基塑料樹脂 諸 如 蜜 胺 -甲醛樹脂和尿素- 甲 醛 1 I 樹 脂 不 但 造 成 在 塗 佈 生 產 線 或 白 所 得 塗 佈 紙 釋 出 甲 醛 1 ^ 重 9 而 且 對 改 善 油 墨 接 受 性 和 防 起 泡 性 能 實 質 上 沒 有 效 1 果 〇 此 外 當 塗 佈 組 成 物 的 pH上 升 » 胺 基 塑 料 樹 脂 的 防 1 I 水 改 善 效 果 則 愈 不 顯 著 〇 聚醢胺聚脲 -甲醛樹脂, 可有 1 1 1 -3 - 1 1 1 本紙張尺度逍用中國國家揉準(CNS ) A4规格(210X297公釐) 經濟部中央標準局貝工消費合作社印製 A7 B7 五、發明説明(2 ) 效改善不但防水性,而且油墨接受性和防起泡性能。然 而,由此可得的改進程度,不一定能充分應付最近需要 較高级塗佈紙。因此,為進一步改進而努力。例如, JP-A-92-100997和 JP-A-92-263696倡議改良(JP-A指非 審査公告的日本專利申請案)。惟仍需進一步增進效能, Μ符塗佈紙品質的日增需要。 本發明之目的,在於提供紙塗料組成物,可符需要, 對塗佈紙賦予較高品質,諸如較習知技術所得為高之防 水性、油墨接受性等。 本發明人等經潛心研究,结果發現含特殊化合物之紙 塗料組成物,顯示優異之性能,因而完成本發明。 本發明提供一種紙塗料組成物,包括: (I )顔料; (Π )水性黏合劑; (I)水溶性樹脂,係由至少下列成份反應製成: (a)伸烷二胺或聚伸烷基聚胺; (b >尿素化合物,和 (c)選自醛類、表鹵酵和α ,7 -二鹵代-/3 -酵之 化合物;Μ及 (IV )選自下列之化合物: (h)胺,選自C4或Μ上之單胺,C4或Μ上之 二胺,及其鹽, (g) 有櫬季銨鹽,和 (h) 二元羧酸和聚胺反應而得之聚醢胺。 -4- 本紙張尺度逍用中國國家揉準(CNS > A4规格(210X297公釐) ^ ·—( 裝 訂 八 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央揉準局貞工消費合作社印製 A7 B7 五、發明説明(3 ) 按照本發明,水溶性樹脂(I )可由(a)(bXc)和一種或 多種額外化合物反應製成。額外化合物有例如(d)二元 羧酸化合物和(e)脂環族化合物,諸如具有至少一活性氫 之脂環族胺,或脂環族環氧化合物。 本發明茲詳述如下。 1 可用做本發明成份(I)的顔料,係紙塗佈所常用者。 顔料例包含白色無機顔料,諸如高嶺土、滑石、碳酸耗 (磨粉或沉析)、氫氧化鋁、缎光白、氧化钛等;Μ及白 色有機合成顔料,諸如聚苯乙烯、蜜胺-甲醛樹脂、尿 素-甲醛樹脂等。可單獨使用,亦可二種或Μ上合用。 有機或無機著色顔料亦可合併使用。 本發明可用做成份(I)的水性黏合劑,係紙塗佈所常 用者。顔料例包含水溶性黏合劑和水性乳化液型黏合劑 。水溶性黏合射例包含未改質或改質之澱粉,諸如氧化殺 粉和磷酸鹽酯化澱粉,聚乙烯酵,水溶性蛋白質,諸如 骼朊和明膠,Μ及改質纖維素,諸如羧甲基缴維素。水 性乳化液型黏合劑例包含苯乙烯-丁二烯型樹脂,乙酸 乙烯酯型樹脂,乙烯-乙酸乙烯酯樹脂,Κ及異丁烯酸 甲酯樹脂。此等水性黏合劑可單獨使用,亦可二種或以 上併用。 本發明中水溶性樹脂(Π)是由至少(a)伸烷二胺或聚 伸烷基聚胺,(b)尿素化合物,和(c)選自包含醛類、 表鹵酵和α,7 -二鹵代-/3 -醇之化合物反應製成。 水溶性樹脂(Β)原料之一的(a)伸烷二胺或聚伸烷基 -5- 本紙張尺度逍用中國國家梂準(CNS ) A4规格(210X297公釐) ---------( 裝-- (請先聞讀背面之注意事項再填寫本頁) 訂 經濟部中央標準局貝工消费合作社印製 A7 B7 五、發明説明(4 ) 聚胺例,包含脂肪族二胺類,諸如伸乙二胺、伸丙二胺 、:1,3 -丙二胺、和六亞甲二胺;聚伸烷基聚胺有諸如二 伸乙三胺、三伸乙四胺、四伸乙五胺、亞胺基雙丙二胺 、3-氮雑己-1,6_二胺和4,7-二氮雜癸-1,10-二胺。 從工業觀點言,其中Μ二伸乙三胺和三伸乙四胺為佳。 此等伸烷二胺和聚伸烷基聚胺U)可單獨使用,亦可二 種或Μ上併用。 亦為本發明所用水溶性樹脂(Μ )原料之尿素化合物 (b)例,包含尿素、硫脲、胍脲、甲脲、二甲脲等。從 工業規點言,K尿素為佳。此等尿素化合物(I)可單獨 使用,亦可二種或Μ上併用。 本發明所用水溶性樹脂(Μ)用做原料(c)之醛,有例 如甲醛;烷基醛類,諸如乙醛和丙醛;乙二醛;Μ及烷 基二醛,諸如丙二醛和丁二醛。從工業觀點言,以甲醛 和乙二醛為佳。此等醛類可單獨使用,亦可二種或Μ上 併用。 本發明所用水溶性樹脂(Μ)用做原料(c)之表鹵酵, 可Μ下式表示:3〇24U B7 Printed by Beigong Consumer Cooperative of Central Bureau of Standards, Ministry of Economy V. Description of invention (1) 1 1 The present invention relates to a paper coating composition, especially a composition > 1 1 can give excellent print quality to paper And outstanding printing results 〇1 I used here "Paper J broadly covers and includes paper N in a narrow sense and paper please 1 first 1 board 〇 I I read 1 | Apply paper coatings mainly composed of pigments and water-based binders on paper The back side 1 I's finished product and then the necessary steps m such as the coated paper obtained by drying and calendering 9 Note 1 1 has been widely used in commercial prints, magazines, books, etc. due to excellent printing matters 1 re 1 effect and other properties 0 Zhu Yue gradually needs higher quality and develops high-speed printing%. Steps to improve the quality of coated paper. Especially page 1 1 In the lithography industry that dominates various printing technologies, the water wetting effect is taken into account 1 1 Λ Water resistance such as moisture absorption and improvement of anti-foaming performance on the rotary machine 1 Ink Acceptability is an important issue. 〇1 1 To solve the above problems, it is usually to add a wet strengthening 1T 1 agent or a printing quality improver to the paper coating composition including melamine-formaldehyde resin'urea-formaldehyde tree 1 I fat> or polyacrylic See, for example, JP-B-69 -11667 1 1 and JP-B-84- 3 2 5 97 (JP-B refers to Japanese Patent Application for Examination Announcement) ° 1 1 although these are known Wet enhancer or printing quality improver $ shows effective features but still has serious defects or deficiencies in some of the required features f 1 1 can not always meet the practical 0 1 | For example f-based plastic resins such as melamine-formaldehyde resin and urea -Formaldehyde 1 I Resin not only causes the release of formaldehyde on the coating line or white coated paper, but also has no effect on improving the ink acceptance and anti-foaming performance. 1 In addition, when the pH of the coating composition increases » Amino-based plastic resin's 1 I water-improving effect is less significant. Polyamide polyurea-formaldehyde resin can be 1 1 1 -3-1 1 1 The paper size can be used in China National Standard (CNS) A4 specifications (210X297mm) A7 B7 printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (2) The improvement of the effect is not only waterproof, but also ink acceptance and anti-foaming performance. However, the degree of improvement available from this does not necessarily fully meet the recent need for higher-grade coated paper. Therefore, work hard for further improvement. For example, JP-A-92-100997 and JP-A-92-263696 propose improvements (JP-A refers to the Japanese patent application for non-examination announcement). However, there is still a need to further improve performance, and the growing demand for coated paper quality. The purpose of the present invention is to provide a paper coating composition that can provide high quality to coated paper as required, such as higher water resistance, ink receptivity, etc. than those obtained by conventional techniques. After intensive studies, the present inventors have found that a paper coating composition containing a special compound exhibits excellent performance, and thus completed the present invention. The invention provides a paper coating composition comprising: (I) pigment; (Π) water-based adhesive; (I) water-soluble resin, which is made by reacting at least the following components: (a) alkylene diamine or polyalkylene Based polyamines; (b > urea compounds, and (c) compounds selected from aldehydes, epihalogenase and α, 7-dihalo-3- / 3-enzymes; M and (IV) selected from the following compounds: (h) amines, selected from monoamines on C4 or M, diamines on C4 or M, and their salts, (g) quaternary ammonium salts, and (h) obtained from the reaction of dicarboxylic acids and polyamines Polyamide. -4- The size of this paper is compliant with the Chinese National Standard (CNS > A4 specification (210X297mm) ^ · — (Binding 8 (please read the precautions on the back and fill in this page) Central Ministry of Economic Affairs Printed A7 B7 by the Zongong Consumer Cooperative Cooperative. V. Description of the invention (3) According to the present invention, the water-soluble resin (I) can be made by reacting (a) (bXc) with one or more additional compounds. Additional compounds include, for example ( d) Dicarboxylic acid compounds and (e) cycloaliphatic compounds, such as cycloaliphatic amines having at least one active hydrogen, or cycloaliphatic epoxy compounds. As follows: 1 Can be used as the pigment of component (I) of the present invention, which is commonly used in paper coating. Examples of pigments include white inorganic pigments such as kaolin, talc, carbonic acid consumption (grinding or precipitation), aluminum hydroxide, satin White, titanium oxide, etc .; M and white organic synthetic pigments, such as polystyrene, melamine-formaldehyde resin, urea-formaldehyde resin, etc. Can be used alone or in combination of two or M. Organic or inorganic coloring pigments are also available Combined use. The present invention can be used as an aqueous binder of component (I), which is commonly used in paper coating. Examples of pigments include water-soluble binders and aqueous emulsion-type binders. Water-soluble binders include unmodified or modified Quality starch, such as oxidized starch and phosphate esterified starch, polyvinyl yeast, water-soluble protein, such as prion protein and gelatin, M and modified cellulose, such as carboxymethyl levulin. Aqueous emulsion-type adhesive Examples include styrene-butadiene type resin, vinyl acetate type resin, ethylene-vinyl acetate resin, K and methyl methacrylate resin. These water-based adhesives can be used alone, or two or more types can be used The water-soluble resin (Π) in the present invention is composed of at least (a) alkylene diamine or polyalkylene polyamine, (b) urea compound, and (c) selected from the group consisting of aldehydes, epihalogen and alpha , 7-dihalo- / 3-alcohol compound is made by reaction. Water-soluble resin (B) one of the raw materials (a) alkylene diamine or polyalkylene-5- This paper scale is used in Chinese national frame Standard (CNS) A4 specification (210X297mm) --------- (installed-(please read the precautions on the back before filling in this page) Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 5. Description of invention (4) Examples of polyamines, including aliphatic diamines, such as ethylenediamine, propylenediamine, 1,3-propanediamine, and hexamethylenediamine; polyalkylene The base polyamines are, for example, diethylenetriamine, triethylenetetramine, tetraethylenepentamine, iminobispropylenediamine, 3-nitrogen-1,6-diamine and 4,7-diazo Heterodec-1,10-diamine. From an industrial point of view, among them, M diethylenetriamine and triethylenetetramine are preferred. These alkylene diamines and polyalkylene polyamines U) can be used alone or in combination of two or more. It is also an example of a urea compound (b) as a raw material of a water-soluble resin (M) used in the present invention, and includes urea, thiourea, guanidine urea, methylurea, dimethylurea, and the like. From industrial regulations, K urea is better. These urea compounds (I) may be used alone or in combination of two or more. The water-soluble resin (M) used in the present invention is used as the aldehyde of the raw material (c), for example, formaldehyde; alkyl aldehydes such as acetaldehyde and propionaldehyde; glyoxal; M and alkyl dialdehydes such as malondialdehyde and Succinaldehyde. From an industrial point of view, formaldehyde and glyoxal are preferred. These aldehydes can be used alone or in combination of two or more. The water-soluble resin (Μ) used in the present invention is used as the raw material (c) for the surface halogen fermentation, which can be expressed by the following formula:

CH2 -CH(CH2 )w X \ / 0 其中X代表鹵素原子,V»代表1 , 2或3 。表鹵醇較佳 例包含表氯酵和表溴醇。 本發明所用水溶性樹脂(H)用做原料的α -二鹵代 -/3-酵,可Μ下式表示: -6 - 本紙張尺度逋用中困國家揉準(CNS ) Α4规格(210Χ297公釐) ------;--、丨{裝-----1--訂------^ I (請先閲讀背面之注意事項再填寫本頁) A7 B7 經濟部中央標準局貝工消費合作社印製 五、發明説明 (5 ) 1 1 CH I 2 -Υ 1 1 1 CH 1 2 -0Η 1 1 1 CH 2 -Ζ η 1 1 1 其 中 Y 和 1 各 單 獨 代 表 鹵 素 原 子 0 α * 7 - 二 鹵 代 -β - 酵 聞 1 較 佳 例 包 含 1 , 3- . 氯 -2 -丙酵 Ί 背 面 1 1 之 此 等 表 鹵 醇 和 α f - 二 鹵 代 -β - 酵 &gt; 可 單 獨 使 用 9 亦 注 意 1 | 可 二 種 或 以 上 併 用 〇 事 項 1 再 用 來 製 得 水 溶 性 樹 脂 (I ) 的 醛 表 鹵 醇 和 α f - 二 鹵 填 窝 本 裝 代 -β - 酵 &gt; 可 單 獨 使 用 &gt; 亦 可 二 種 或 Μ 上 併 用 〇 例 如 » 頁 1 I 可 同 時 使 用 醛 和 表 鹵 酵 赘 而 醛 和 α ,7 - 二 鹵 代 -β - 醇 亦 1 1 可 同 時 使 用 〇 1 水 溶 性 樹 脂 (I ) 是 由 至 少 (a ) 伸 烧 二 胺 和 聚 伸 院 基 聚 1 訂 胺 » (b ) 尿 素 化 合 物 y 和 (C ) 選 白 包 含 醛 類 9 表 鹵 醇 和 1 α t - 二 鹵 代 -β - 酵 反 應 製 成 〇 水 溶 性 樹 脂 (I ) 可 由 1 I (a )(b) (C )和- -種或多種額外化合物反應製成 、額外化 1 1 合 物 的 較 佳 例 包 含 (d) 二 元 羧 酸 化 合 物 * 和 (e) 脂 環 族 1 1 化 合 物 » 諸 如 具 有 至 少 一 活 性 氫 之 脂 環 族 胺 * 或 脂 環 族 1 環 氧 化 合 物 〇 1 1 二 元 羧 酸 化 合 物 id) 為 具 有 二 羧 基 之 化 合 物 t 或 其 衍 1 1 生 物 0 二 元 羧 酸 化 合 物 (d) 不 但 可 用 其 游 離 酸 » 亦 可 用 1 1 其 酯 酐 等 〇 二 元 羧 酸 化 合 物 (d) 可 為 脂 肪 族 芳 香 族 1 U . 或 脂 環 族 化 合 物 〇 二 元 羧 酸 化 合 物 (d) 例 9 有 脂 肪 族 二 1 羧 酸 • 諸 如 丁 二 酸 &gt; 戊 二 酸 己 二 酸 癸 二 酸 、 馬 來 酸 1 富 馬 酸 亞 油 酸 等 二 聚 酸 ; 芳 香 族 二 羧 酸 9 諸 如 笨 二 1 1 1 -7 - 1 1 1 本紙張尺度逋用中國國家揉準(CNS &gt; A4规格(210X297公釐) A7 B7 經濟部中央揉準局貝工消费合作社印製 五、發明説明 (6) 1 1 甲 酸 •V 異 苯 二 甲 酸 對 苯 二 甲 酸 等 &gt; Μ 及 脂 環 族 二 羧 酸 1 1 9 諸 如 四 氫 對 苯 二 甲 酸 V . 氫 對 苯 二 甲 酸 環 己 烷 -1 ,3 1 1 -二羧酸、 環己烷- 1 , 4- - 羧 酸 環 戊 院 二 羧 酸 3- 甲 基 請 1 先 1 四 氫 對 苯 二 甲 酸 4- 甲 基 四 氫 對 苯 二 甲 酸 3- 甲 基 氫 聞 讀 1 對 苯 二 甲 酸 4- 甲 基 - 氫 對 苯 二 甲 酸 等 〇 背 面 1 1 之 二 元 羧 酸 (d) 之 酯 » 有 例 如 與 低 级 醇 之 單 酯 和 二 酯 &gt; 注 意 1 I 以 及 與 乙 二 酵 之 多 元 酯 〇 事 項 1 、 再 1 若 二 元 羧 酸 化 合 物 (d) 為 脂 rw 環 族 化 合 物 &gt; 通 常 使 用 本 裝 C 4至約C 96 之 化 合 物 〇 用 做 (d) 的 脂 環 族 化 合 物 具 有 不 頁 'w» 1 1 飽 和 鐽 0 在 本 發 明 書 中 * 若 未 提 及 不 飽 和 鍵 的 位 置 f 則 1 1 脂 環 族 化 合 物 包 含 在 任 何 位 置 有 不 飽 和 鍵 的 化 合 物 〇 1 \ 若 二 元 羧 酸 化 合 物 (d) 為 脂 環 族 化 合 物 &gt; 其 酐 亦 可 較 1 訂 佳 使 用 〇 酐 例 包 含 四 氫 能 酐 9 • 氫 m 酐 » 3 - 甲 基 四 氫 m 1 酐 &gt; 4- 甲 基 .四 氫 酞 酐 9 3 - 甲 基 氫 Sfe 酐 y 4- 甲 基 - 氫 m 1 I 酐 等 〇 1 1 1 若 二 元 羧 酸 化 合 物 (d) 為 脂 環 族 化 合 物 » 則 最 好 使 用 1 1 具 有 二 羧 酸 基 之 聚 酯 * 諸 如 二 元 羧 酸 與 乙 二 酵 之 反 應 生 I 成 物 〇 特 佳 聚 酯 係 具 有 游 雔 羧 酸 基 〇 乙 二 酵 之 例 包 含 烷 1 1 二 醇 t 諸 如 乙 二 醇 丙 二 酵 和 丁 二 酵 &gt; 環 二 酵 &gt; 諸 如 1 1 環 戊 二 酵 和 環 己 二 酵 » 烯 二 酵 9 諸 如 丁 烯 二 酵 和 辛 烯 二 1 | 酵 &gt; 聚 二 酵 V 諸 如 二 乙 二 酵 Λ 二 丙 二 酵 二 乙 二 酵 Λ Ί 聚 乙 二 醇 和 聚 丁 二 酵 聯 酚 A 與 環 氧 乙 之 加 成 化 合 物 1 加 氫 聯 酚 A 與 環 氧 乙 烧 之 加 成 化 合 物 〇 在 分 子 鐽 末 端 1 具 有 羧 酸 基 之 聚 酯 &gt; 可 由 -8 元 羧 酸 與 乙 酵 反 應 而 得 &gt; 1 1 1 1 1 1 本紙張又度逋用中國國家棣準(CNS &gt; A4规格(210X29*7公釐) A7 B7 經濟部中央揉準局貞工消費合作社印製 五、發明説明 (7 ) 1 1 使 用 莫 爾 過 量 的 羧 酸 0 二 元 羧 酸 化 合 物 (d) 可 單 獨 使用 1 1 * 亦 可 二 種 或 Μ 上 併 用 Ο 1 1 至 少 有 一 活 性 氬 之 脂 環 胺 9 通 常 為 具 有 c &amp; - C 12之脂 請 1 先 1 環 族 環 » Μ 環 己 烷 環 為 佳 並 至 少 有 —* 伯 胺 或 伸 胺 基° 聞 it 1 胺 基 可 直 接 或 透 過 撐 等 連 接 基 » 埋 接 於 脂 環 族 環、 。具 背 面 1 I 之 有 至 少 ___. 活 性 氫 原 子 的 脂 環 族 胺 之 例 * 包 含 環 己 胺 、二 注 意 1 I 環 己 胺 1 , 3 - 二 胺 基 環 己 胺 、 1 , 4- 二 胺 基 環 己 烷 4,4' 事 項 1 再 1 -二胺基- 3 , 3 ' -二甲基二環己基甲烷、 4 ,4 ’ · 二 胺 基 -3,3' 4 窝 本 裝 -二甲基雙環己烷 異佛爾嗣二胺 1 ,3 -雙(胺 甲 基 )環 頁 1 I 己 烧 1 , 2- 雙 (胺甲基) 環 己 院 1 , 4- 雙 (胺甲基) 環 己烷 1 1 、 N - 胺 丙 基 環 己 基 胺 ·、 1 , 5- 雙 (胺乙基)八 氫 -4 ,7 -甲撐 1 \ 茚 % 2 , 6- 雙 (胺乙基)八 氫 -4 ,7 -甲撐茚、 2 ,2 -雙( 4- 胺環 1 訂 己 基 )丙烷、 雙(4- 胺 瑁 己 基 )甲烷' 4 ,4 1 一 氧 代 雙 (環己 1 基 胺 ) 4 ,4 » _ 硝 代 雙 (環己基胺) 、 1 , 3 , 5 - 三 胺 基 環 己烷 1 I 、 2, 4 ' -二胺基- 3 , 3 ' ,5 ,5 ?— 四 甲 基 二 τη 環 己 基 甲 烷 、 4,4' 1 1 -二胺基- 3 , 3 ' ,5 ,5 » _ 四 甲 基 二 環 己 基 甲 烷 、 及 甲 二胺 1 1 〇 脂 環 族 胺 可 單 獨 使 用 9 亦 可 二 種 或 多 種 併 用 0 | 用 做 (e ) 的 脂 環 族 環 氧 化 合 物 9 通 常 為 具 有 C 4 — C 12 1 1 脂 環 族 環 的 化 合 物 &gt; 最 好 是 環 己 烷 環 &gt; 並 有 直 接 或 間接 1 I 連 接 至 脂 環 族 環 的 環 氧 基 Ο 脂 環 族 環 氧 化 合 物 包 含 環己 1 I 烯 氧 化 物 \ 乙 烯 基 環 己 烯 氧 化 物 &gt; 雙 (3 ,4 -環氧環己基) 1 Ί 己 二 酸 酯 3 , 4- 環 氧 環 己 烷 羧 酸 酯 3- (3 ,4 -環氧環己 1 基 )~ 8 , 9- 環 氧 -2 ,4 -二噁螺[5 , 5]十 一 院 二 縮 水 甘 油、 1 氫 m 酸 酯 2 , 2- 雙 (4 -縮水甘油氧化環己基) -9 - 丙 烷 等。 1 1 1 1 1 1 本紙張尺度適用中國國家揉準(CNS ) A4规格(2丨0X297公釐} A7 B7 經濟部中央標準局貝工消費合作社印製 五、發明説明 (8 ) 1 1 脂 環 族 rw 壊 氧 化 合 物 可 單 獨 使 用 » 亦 可 二 種 或 多 種 併 用 〇 1 1 _ 環 族 胺 和 脂 環 族 環 氧 化 合 物 可 合 併 使 用 〇 1 1 m 溶 性 化 合 物 (HI ) 較 佳 例 之 一 » 是 由 (a ) 伸 燒 二 胺 或 請 1 先 1 聚 伸 烷 基 聚 胺 9 (b) 尿 素 化 合 物 &gt; (C) 選 白 包 含 醛 類 Λ 閲 1 表 鹵 酵 和 α — . 鹵 代 -β - 酵 之 化 合 物 &gt; 視 需 要 加 上 背 Λ 1 | 之 (e ) 選 白 包 含 具 有 至 少 —- 活 性 氫 的 脂 肪 族 胺 Μ 及 脂 XB9 埸 族 注 意 1 I 環 氧 化 合 物 等 脂 環 族 化 合 物 9 反 應 而 得 者 〇 事 項 1 再 1 在 獲 得 上 述 鹼 溶 性 化 合 物 (Ε ) 的 反 應 中 &gt; (a ) ( b ) 和 (C) % 本 裝 &gt; 或 (a )( b) (C )和( e ) 的反應順序無關緊要 &gt;可說明反 頁 1 | 應 方 式 之 一 例 如 下 : 1 伸 二 胺 或 聚 伸 基 聚 胺 (a ) 和 尿 素 化 合 物 (b) * 經 1 \ 脫 氨 反 應 (M下稱反應) , 接 著 與 選 白 包 含 醛 類 表 鹵 酵 1 訂 和 α f - 二 鹵 代 -β - 醇 (C ) 的 化 合. 物 反 應 (反應1 以後 1 的 反 應 稱 為 反 應 2 ) &gt;若反應原料也使用脂環族化合物 1 I (e ) 時 9 在 反 應 1 和 / 或 反 a*Mt 應 2 時 » 可 令 一 種 或 多 種 1 1 (e ) 與 其 他 原 料 * 即 (a )(b) 或 (C ) 反 應 〇 1 1 在 反 愿 1 時 &gt; 可 一 次 添 加 尿 素 化 合 物 (b) 9 與 (a ) 反 I Bter 懕 0 可 採 用 二 步 驟 反 應 f 首 先 添 加 一 部 .份 (b) 9 與 (a ) 1 1 反 應 » 再 加 其 餘 (b) 9 進 行 脫 氨 反 應 0 若 在 反 應 2 中 使 1 1 用 醛 做 為 (C) &gt; 則 宜 在 酸 性 條 件 下 進 行 反 應 9 亦 可 先 在 1 I 鹼 性 條 件 下 反 應 接 著 在 酸 性 條 件 下 進 行 〇 若 在 反 應 2 I Ί 中 是 使 用 表 鹵 酵 和 / 或 α f - 二 鹵 代 -β - 酵 做 為 (c) &gt; 1 則 最 奸 在 弱 酸 性 或 驗 性 條 件 下 進 行 反 應 &gt; 例 如 PH5 或 Μ 1 I 上 * 而 Μ PH6- 9 更 佳 〇 1 1 1 -1 0- 1 1 1 本纸張又度適用中國國家揉準(CNS &gt; A4规格(210X297公釐) A7 B7 經濟部中央標準局貝工消費合作社印製 五、發明説明 (9 ! 1 1 此 等 反 應 可 按 照 已 知 方 式 進 行 〇 例 如 9 使 用 (a) (b) (c) 1 1 為 原 料 的 反 應 已 載 於 JP -A -92- 100997 • 而 除 (a )(b) (C) 1 1 外 , 還 用 (e) 做 為 原 料 的 反 應 t 已 知 JP -A -92- 263696和 請 1 先 1 JP -A -92- 333697所 述 〇 閎 I 1 I 鹸溶性化合物( I )另- -較佳具體例, 係由U) 伸烷二 背 1 1 之 胺 或 聚 伸 烷 基 聚 胺 9 (b) 尿 素 化 合 物 (C ) 選 白 包 含 醛 注 意 1 I V 表 鹵 酵 和 α 1 - 二 鹵 代 -β - 酵 之 化 合 物 &gt; (d) 二 元 羧 事 項 1 再 1 酸 化 合 物 &gt; 必 要 時 加 (e) 脂 環 族 化 合 物 選 白 包 含 具 有 寫 本 裝 至 少 —- 活 性 氫 的 脂 環 族 胺 » Μ 及 脂 環 族 環 氧 化 合 物 » 加 頁 1 I 以 反 應 而 得 〇 1 1 在 獲 得 上 述 鹼 溶 性 化 合 物 (I ) 的 反 懕 中 &gt; (a)至⑷ 1 \ 或 (e) 間 的 反 應 順 序 無 關 緊 要 〇 茲 說 明 反 應 方 式 之 一 例 1 訂 如 下 1 令 (a ) 伸 烷 二 胺 或 聚 伸 烧 基 聚 胺 » (b) 尿 素 化 合 物 和 1 I (d) 二 元 羧 酸 化 合 物 , 經 脫 氨 反 應 和 脫 水 (K下稱反應3) 1 1 t 產 生 聚 騙 胺 聚 P » 接 著 與 (C ) 選 白 包 含 醛 類 &gt; 表 鹵 醇 1 1 和 α f - 二 鹵 代 -β - 醇 的 化 合 物 反 應 (反應3 Μ後的反 I 應 稱 為 反 應 4 ) &gt;若反應原料亦用(e ) 脂環族化合物, 1 1 則 在 反 應 3 和 / 或 反 應 4 中 , 可 令 一 種 或 多 種 (e) 與 1 1 (a )(b) (c ) 等 其 他 原 料 反 應 〇 1 I 反 應 3 進 行 方 式 之 一 些 例 如 下 : 1 Ί 一 次 添 加 尿 素 化 合 物 (b) 進 行 反 應 〇 1 選 添 加 部 份 (b) 進 行 脫 氨 反 應 9 再 加 其 餘 (b) 9 又 進 1 1 行 脫 氨 反 應 Ο 1 1 1 -1 1 - 1 1 1 本紙張尺度逋用中國國家揉準(CNS &gt; A4规格(210X297公釐) 五、發明説明(10 ) 在(a)和(d)之間進行脫水反應,接著與(b)進行脫 氨反應。 部份(b)經與U)進行脫氨反應,所得化合物再與 (d)進行脫水反應,接著與其餘(b)進行脫水反應。 (a)(b)和部份(b)同時經脫水和脫氨,再與其餘(b) 進行脫氨。 若在反應4中使用醛做為(c),則宜在酸性條件下進 行反應,亦可先在鹼性條件下反應,再在酸性條件下進 行。若反應4中使用表鹵酵和/或α, 7-二鹵代- /3-酵 做為(c ),刖宜在弱酸性或鹼性條件下進行反應,例如 ρΗ5或Μ上,ΜρΗ6-9更佳。 此等反應可按已知方式進行。例如,使用(a)(b)(c) (d) 為原料之反應,已載於JP-A- 80 - 3 1 8 37, JP-A-82- 1 6 7 3 1 5, JP-A-87 - 1 04995, JP - A - 87 - 1 25092, J P - A-87 - 12 5 093等,而除(3)(1))((:)(0)外,遒用(以為原料的反 應,見於 JP-A-90-216297和 JP-A-90-221498。 本發明紙塗料組成物除顔料(I),水性黏合劑(I)和 水溶性樹脂(H)外,又包括(IV)化合物,選自包含(h) 經濟部中央標準局貝工消費合作社印製 (請先聞讀背面之注意事項再填寫本頁) 胺,選自包含具有C4或Μ上之單胺,具有C4或Μ上之 二胺,及其鹽,(g)有櫬季銨鹽,Μ及二元羧酸與聚胺 反應而得之聚醣胺。 胺(h)係選自包含具有C4或Μ上的單胺和二胺及其 鹽。其中Μ (:5或Μ上之胺為佳。(h)胺可用伯胺、仲 胺和叔胺。無論脂肪族、芳香族、脂環族和瑁型胺均可。 -12- 本紙張尺度逋用中國國家橾準(CNS ) A4规格(210X297公釐) A7 B7 經濟部中央揉準局負工消費合作社印製 五、發明説明(11 1 1 伯 胺 例 包 含 脂 肪 族 單 胺 * 諸 如 丁 胺 戊胺 \ 己 胺 辛 1 1 胺 異 丁 胺 2- 乙 基 己 胺 等 * 脂 環 族 單 胺, 諸 如 環 己 胺 1 1 Λ 胺 甲 基 環 己 胺 等 ; 及 芳 香 族 單 胺 &gt; 諸如 笨 胺 、 甲 苯 請 1 先 1 胺 苄 胺 、 胺 間 胺 基 酚 等 〇 閱 I 1 I 伸 胺 例 包 含 具 有 脂 肪 族 &gt; 芳 香 族 或 脂 環族 基 之 單 胺 &gt; 背 面 1 I 之 Μ 及 瑁 型單 胺 &gt; 諸 如 二 丙 胺 二 環 己 胺、 Ν - 甲 基 環 己 注 意 1 I 胺 Η - 甲 基 苯 胺 、 吡 咯 烷 哌 啶 等 〇 事 項 1 V 再 1 叔 胺 例 包 含 具 有 脂 肪 族 、 芳 香 族 或 脂 環族 基 之 單 胺 1 本 裝 Μ 及 環 型 單 胺 9 諸 如 三 乙 胺 二 丁 胺 Λ Ν , Ν - 二 甲 基 正 丙 頁 1 | 胺 、 Η , Ν - 二 甲 基 rga 壊 己 胺 Η , Η- 二 甲 基 苯 胺、 吡 啶 等 〇 1 1 二 胺 包 含 具 有 二 伯 胺 基 之 化 合 物 &gt; 具 有二 仲 胺 基 之 化 1 f 合 物 9 具 有 二 叔 胺 基 之 化 合 物 9 Η 及 具 有取代 數 彼 此 不 1 訂 同 的 二 胺 基 之 化 合 物 〇 較 佳 二 胺 例 包 含 芳香 族 二 胺 脂 1 環 族 二 胺 和 具 有 環 型 胺 基 之 二 胺 〇 較 佳 二胺 有 例 如 具 有 1 1 二 伯 胺 基 之 脂 昉 族 和 芳 香 族 胺 9 諸 如 1 , 3-二 胺 基 環 己 烷 1 1 異 佛 爾 m 二 胺 Λ 1 . 3 - 雙 (胺甲基)環 己 烧、 雙 (4 -胺基 1 1 rm 環 己 基 )甲烷、 2 ,2 -雙( 4- 胺 基 環 己 基 )丙烷、 甲二胺、 I 4, 4 ' -氧代雙(環 己 胺 )、 4,4 1 · 磺 代 雙 (環己胺)伸 苯 二 胺 1 1 % 伸 甲 苯 二 胺 \ 伸 二 甲 苯 二 胺 等 7 具 有 胺基 取 代 數 不 同 1 1 的 二 胺 基 之 化 合 物 , 諸 如 3- 甲 基 胺 甲 基 -3,5 ,5 i甲基 1 1 環 己 胺 ·&gt; 1 - 甲 胺 基 -3 -胺甲基- 3 , 5 , 5- 三 甲基 環 己 胺 1 - 1 Ί 胺 甲 基 -3 -甲基胺甲基環己胺、 1 -胺甲基-3- 二 甲 基 胺 甲 1 基 m 己 烷 &gt; 1 - 甲 基 胺 甲 基 -3 -二甲基胺甲基環己烷、 4 - 1 1 胺 基 吡 啶 等 &gt; 具 有 二 仲 胺 基 之 化 合 物 9 諸如 Ν , Ν , :甲 1 1 -1 3- 1 1 1 本紙張尺度逋用中國國家橾準(CNS ) A4规格(210X297公釐) A7 B7 經濟部中央標準局貞工消費合作社印製 五、發明説明(I2 ) 1 1 基 異 佛 爾 m 二 胺 1 , 3- 雙 (甲基胺甲基)環 己烷 等; Μ 及 1 1 具 有 二 叔 胺 基 之 化 合 物 9 諸 如 Ν , Ν ' -四甲基異佛爾詷二 1 1 胺 1 , 3- 雙 (二甲基胺甲基)環 己 院 等 〇 /&quot;N 請 1 先 1 (h) 胺 可 用 上 述 單 胺 和 二 胺 之 無 機 酸 鹽 和有 櫬酸 盥 0 閱 1 無 機 酸 有 例 如 鹽 酸 、 硫 酸 Λ 磷 酸 等 〇 有 機 酸有 例如 乙 酸 1 背 面 1 I 之 、 甲 酸 % 乙 二 酸 等 〇 注 意 1 | 此 等 胺 可 單 獨 使 用 亦 可 二 種 或 多 種 併 用0 事 項 1 再 1 一 有 機 季 銨 播 (g) 可 用 具 有 至 少 —— 季 氮 的 任何 化合 物 0 % 本 裝 (g) 例 包 含 具 有 —** 季 氮 連 接 於 四 烴 基 之 化 合物 ,在 環 上 頁 •S_&gt; 1 1 有 季 氮 之 化 合 物 〇 季 氮 數 不 受 限 9 可 用 具 有一 季氮 的 單 1 1 季 銨 鹽 &gt; 具 有 二 季 氮 之 二 季 銨 鹽 , Μ 及 具 有三 或Μ 上 季 1 氮 之 季 銨 鹽 〇 從 經 濟 觀 點 或 顧 及 可 行 性 &gt; Μ單 或二 季 m 1 訂 鹽 為 佳 9 尤 Μ 單 季 銨 鹽 為 特 佳 0 1 有 m 季 親 鹽 (g) 當 中 9 常 用 單 或 二 季 銨 鹽, 具有 季 氮 1 I 連 接 於 四 烴 基 &gt; 其 中 有 至 少 二 烴 基 分 別 為 C 2 - C 3烷基 1 1 或 烷 撐 〇 1 1 Μ 單 季 銨 鹽 而 連 接 至 季 氮 的 全 部 四 烴基 ,可 分 別 1 為 C 一 C 3烷基&lt; 、四個烴基亦可有二或三個Ci ~ C 4 院 基 1 1 9 剰 餘 一 或 二 個 為 碳 數 較 多 之 烴 基 〇 1 1 Μ 二 季 m 鹽 而 9 連 接 於 二 季 氮 之 基 (Μ下稱連接基) 1 | 的 碳 原 子 數 不 受 限 制 » 而 連 接 基 可 包 含 脂 環族 或芳 香 族 1 Ί 基 〇 若 連 接 基 為 C 1 - C ; ;烷撐, 則連接於季氮而非連接 1 基 之 烴 基 不 受 限 制 &gt; 惟 至 少 有 一 C C Ξ ;烷基連接於各 1 季 氮 〇 若 連 接 基 為 C 1 C = &gt;烷撐, 則連接於季氮而非連 1 1 1 -1 4- 1 1 1 本纸張尺度適用中國國家揉準(CNS ) A4规格(210X297公釐) 五、發明説明(13 ) 經濟部中央橾準局貝工消費合作杜印製 。 的»接 脂 根離, 季銨.,基基、、.,如、銨 接 基基季連^0 g^w¥ 申»® 豸Itsib連 烴自纟卩。可 機酸離 數氯按如三化化较,化氛 中 接 各 的埋於而S’ 0 0 M?»^blt*MM^_Ms« 數卩接氮S基 或,酸 原甲M,s 基基氯合»ί卞 , 子0|.|_的® 子子乙 碳三基物、甲甲基化苄基 氮 &quot;連 季 原 ② 數的。離離如 多基甲合銨三三甲之基甲 季 碳si子子基根溴例 較己三化化基基二劑甲二 有 多 ㈢®原原之酸,有 有、基的氛脂烷基性二基 具 較 t^M 碳碳環機子子 具銨甲劑基硬六脂活基烷。為 接 3 埋 有 CU多多族無離離 含化基性甲、十硬面脂四等物 具ϋ1_員較較香為氯根。包氯己活三銨、二界硬十銨合 為員clt 有有芳可如酸等,基環面基化銨、子,、化化 ^ 別’二 具具有,例機子例甲、界己氛化銨離銨銨氯佳 ^ 3«為中具子有有離鹽二銨子基基氛化陽化化基較 ,3^6!C3,鹽或離子。根按基化離乙甲基氯族氛氛苄 , 下C3惟1-下銨基陰離等酸季丙氯陽2-三甲基香基基基中 M1-,01以季族之根子草單烯基族、基二甲芳苄苄甲當 基C1制非個二環鹽酸離,用二甲肪较桂基二為基基二鹽 W非限基一或脂銨機根子所如三脂化月脂基稱甲乙基銨 二基受接基單,季無酸離明諸基為氛、硬烷常二 二烷季 的接不連烴述基成,磷根發,己稱基銨基七通基基櫊單 基連基若的上族形子 ,酸本镧環般甲化桂十及桂脂棕在 接若烴。基 肪 離子甲 銨、一三氣月雙M月硬、 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度逋用中國國家揉準(CNS ) A4规格(210X297公釐) A7 B7 經濟部中央標準局爲工消费合作社印製 五、發明説明(W) 1 1 於 氮 的 二 或 三烴 基 分 別 為 C 1 C 3烷基, 其餘- -或二為 1 1 C 3 - C 24脂肪族或芳香族烴基 &gt; 1 1 脂 肪 族 烴 基包 含 焼 基 % 烯 基 有 環 之 烷 基 等 〇 芳 香 族 請 1 先 1 烴 基 包 含 苄 基、 苯 乙 基 等 〇 較 佳 化 合 物 為 具 有 季 氮 » 其 聞 1 中 連 接 於 氮 的三 烴 基 分 別 為 甲 基 或 乙 基 1 另 一 為 C 3 ~ C 24 背 面 1 I 之 脂 肪 族 烴 基 ,而 特 佳 之 化 合 物 為 具 有 季 氮 9 其 中 三 烴 基 注 意 1 1 為 甲 基 » 而 另一 為 C ί Ϊ - C 12烷基 &gt; 事 項 1 再 1 本 發 明 所 用單 季 銨 較 佳 例 包 含 : 辛 基 三 甲 基 氯 化 数 4 窝 本 裝 癸 基 三 甲 基氯 化 銨 月 桂 基 三 甲 基 氮 化 銨 等 〇 頁 1 I 本 發 明 所 用二 季 It 鹽 例 包 含 : 1, 3- 雙 (三甲基銨乙基) 1 1 •ma m 己 二 氯 、N, N , N ' ,Η ♦ &gt; Ν ' ,Ν » 一 - 甲基異佛爾酮 二 数 二 溴 1 ο Η - 牛 油 烷 基-N ,Η ,N ♦ » Η ' ,Η « — 五 甲 基 三 甲 ί? 二 銨 二 氯 等。 1 訂 此 等 有 機 季銨 鹽 (g ) 可 單 獨 使 用 y 亦 可 二 種 或 多 種 併 1 用 〇 1 I 聚 醢 胺 m是 由 二 元 羧 酸 ⑴ 與 聚 胺 (j ) 反 應 而 得 〇 1 1 二 元 羧 酸 (i ) 為 具 有 二 羧 酸 之 化 合 物 及 其 衍 生 物 〇 可 1 1 用 做 聚 m 胺 (h) 原 料 的 二 元 羧 酸 (i ) 包 含 其 游 離 酸 其 I 酯 其 酐 等 〇 二 元 羧 酸 (i ) 例 包 含 上 述 (d) 化 合 物 » 即 1 1 脂 肪 族 ·、 芳 番族 和 脂 ma 環 族 二 羧 酸 » 二 羧 酸 之 一 與 低 級 酵 1 1 之 單 酯 和 二 酯, 二 羧 酸 之 一 的 酐 » Μ 及 由 二 羧 酸 之 一 與 1 1 二 酵 製 成 的 聚酯 〇 其 中 Μ 具 有 游 離 羧 酸 基 的 聚 酯 為 佳 〇 1 聚 酯 當 中 » Κ聚合度在20或以下的聚酯 為 佳 〇 1 二 元 羧 酸 ί i ) 可 單 X29 530 使 用 &gt; 亦 可 二 種 或 多 種 併 用 〇 1 I 聚 胺 (j) 可用 具 有 二 或 Μ 上 伯 胺 和 / 或 仲 胺 基 之 胺 » 1 1 1 -16- 1 1 1 本紙張尺度逋用中國國家揉率(CNS &gt; A4规格(210X297公釐) A7 B7 經濟部中央標準局貝工消费合作社印製 五、發明説明(is ) 1 1 諸 如 脂 肪 族 胺 一 如 製 造 水溶 性 樹 脂 (II )用 做 原 料 之 院 1 1 二 胺 或 聚 伸 烧 基 聚 胺 Λ 脂 環族 聚 胺 &gt; 芳 香族 聚 胺 等 〇 其 1 1 中 Μ 脂 塌 族 二 胺 為 佳 〇 此 等胺 可 單 调 使 用, 亦 可 二 種 或 請 1 先 1 多 種 併 用 〇 閱 I 讀 1 | 脂 環 族 二 胺 可 用 具 有 約 C 5 - C 12脂環族環, Μ環己烷 背 面 1 | 之 環 為 佳 Μ 及 二 伯 胺 和 / 或仲 胺 基 之 化 合物 〇 胺 基 可 直 注 意 1 I 接 連 接 於 脂 環 族 環 9 或 經 烷撐 等 連 接 基 ,間 接 連 接 於 脂 事 項 1 再 1 環 族 之 環 〇 所 用 化 合 物 亦 可其 中 —* 胺 基 (1 ) 直 接 或 間 接 4 窝 本 裝 連 接 於 脂 環 族 之 瑁 9 另 胺基 為 胺 烷 基 並連 接 於 胺 基 頁 S_^ 1 | (1 ) 〇 1 1 脂 環 族 二 胺 之 例 包 含 二 胺基 環 己 燒 、 異佛 爾 酮 二 胺 、 1 雙 (胺甲基)環 己 燒 雙 (4 -胺基環己基)甲烷 ·&gt; 2, 2- 雙 (4 1 訂 -胺基環己基)丙 烷 甲 二 胺、 4 , 4 ' -氧代雙(環 己 胺 )、 1 4, 4, -磺代雙(環 己 胺 ) 4 ,4 '- 二 胺 基 -3 ,3 '- 二 甲 基 二 環 1 I 己 基 甲 烷 、 4 , 4, -二胺基- 3,3' -二甲基二環己烷、 Ν -胺 1 1 丙 基 環 己 胺 1 , 5 - 雙 (胺甲基)八 氬 -4 ,7 -甲撐茚 2 ,6 - 1 1 雙 (胺甲基) 八 氫 -4 ,7 -甲撐茚、 2 ,4 1 · 二 胺基 -3 ,3 » &gt; 5 , 5 ' &gt;-κ 1 -四甲基二瑁己基甲烷 4 ,4 '- 二 胺 基 -3 ,3 ', 5, 5 , -四甲 1 1 基 二 環 己 基 甲 等 〇 1 1 芳 香 族 二 胺 係 具 有 至 少 一芳 香 族 環 » Μ及 選 自 包 含 伯 1 I 胺 基 和 仲 胺 基 之 二 胺 基 的 化合 物 〇 芳 香 族二 胺 例 有 二 甲 1 Ί 苯 二 胺 、 4 , 4 ' -二胺基二苯基甲烷, 4 ,4 » _ — 胺 基 -3 ,3 t _ 1 二 甲 基 二 苯 基 甲 烷 Ν- 胺 丙基 苯 胺 2 , 4,-二 二胺基- 3 , 3 ' 1 I ,5 ,5 f 一 二 胺 基 -3 ,3 » 5, 5 , -四甲基二苯基甲烷等c 1 1 1 -17- 1 1 1 本紙張尺度逋用中國國家橾準(CNS &gt; A4规格(210X29*7公釐) A7 B7 經濟部中央標準局具工消费合作社印製 五、發明説明 (16 ) 1 1 聚 醮 胺 (h) 的 物 理 性 能 9 諸 如 對 水 性 溶 劑 的 溶 解 度 » 1 1 结 晶 性 ♦ 均視 用 做 聚 醢 胺 (h) 原 料 的 (i ) 二 元 羧 酸 和 ⑴ 1 1 聚 胺 而 異 。因 此 » 可 藉 選 擇 原 料 加 Μ 調 節 〇 請 1 先 1 聚 醢 胺 (h) 可 由 (i ) 二 元 羧 酸 與 (J ) 聚 胺 &gt; 在 100至 閲 I 讀 1 I 250 ¾ , 最好在1 30 至 200 ¾ , 反應2 至1 2小時, 除去反、 背 ij 1 | 之 應 中 產 生 的水 份 而 得 〇 二 元 羧 酸 量 最 好 為 每 莫 耳 聚 醢 胺 注 意 1 1 之 0 . 5- 1莫耳C 反應可在酸性觸媒存在下或不存在下進 事 項 1 再 1 行 » 諸 如 鹽酸 ·&gt; 碕 酸 磷 酸 、 甲 酸 乙 酸 〇 聚 醢 胺 (h) 4 寫 本 裝 在 60% 重 最的 水 溶 液 內 , 25 時 黏 度 為 20 -1 0 0 0厘泊 0 頁 ·»_^ 1 1 黏 度 Η 50 -5000厘泊特佳 1 1 聚 藤 胺 (h) 可 單 獨 使 用 * 亦 可 二 種 或 多 種 併 用 〇 1 本 發 明 紙塗 料 組 成 物 中 顔 料 ( ) 量 對 水 性 黏 合 劑 (π&gt;之比 1 訂 &gt; 依 照 標 的或 用 途 &gt; 確 定 與 習 用 紙 塗 料 組 成 物 相 同 〇 1 本 發 明 紙塗 料 組 成 物 中 所 含 水 性 黏 合 劑 (I ) » Μ 每 100 1 I 份 重 最 顔 料.(] ) 使 用 5 至 200 份 重 量 為 佳 9 而 &gt;λ 1 0 至 50 1 1 份 重 最 更 佳0 水 溶 性 樹 脂 (I ) Μ 每 100 份 重 量 顔 料 ( I ) 1 1 使 用 0 . 05 -5份 重 量 為 佳 » 而 Μ 0 . 1至2份 重 量 更 佳 〇 I 本 發 明 紙塗 料 組 成 份 内 使 用 化 合 物 (IV ) 量 如 下 〇 1 1 若 化 合 物(IV ) 為 胺 (h) 9 其 量 Μ 水 溶 性 樹 脂 (I ) 固 體 1 成 份 重 最 的約 1 至 50 重 最 % 為 佳 9 而 Μ 約 5 至 20 重 量 % 1 | 更 佳 〇 1 若 化 合 物(IV ) 為 聚 醯 胺 (h) 9 聚 醢 胺 量 Μ 水 溶 性 樹 脂 1 I (Π ) 固 體 成份 重 量 的 約 1 至 90 重 量 % 為 佳 9 而 Μ 約 3 至 1 80 重 量 更 佳0 1 1 1 -1 8 - 1 1 1 本紙張尺度逋用中國國家揉準(CNS ) A4规格(210X297公釐)CH2 -CH (CH2) w X \ / 0 where X represents a halogen atom and V »represents 1, 2 or 3. Preferred examples of epihalohydrin include epichlorohydrin and epibromohydrin. The water-soluble resin (H) used in the present invention is used as the raw material for α-dihalo- / 3-fermentation, which can be expressed by the following formula: -6-The paper size is in the state of the Central Government (CNS) A4 specification (210Χ297 Mm) ------;-, 丨 {install ----- 1--order -------- ^ I (please read the precautions on the back before filling this page) A7 B7 Ministry of Economic Affairs Printed by Beigong Consumer Cooperative of Central Bureau of Standards 5. Description of invention (5) 1 1 CH I 2 -Υ 1 1 1 CH 1 2 -0Η 1 1 1 CH 2 -Z η 1 1 1 where Y and 1 each independently represent halogen Atom 0 α * 7-dihalo-β-yeast 1 The preferred examples include 1, 3-. Chloro-2 -propanase Ί back 1 1 such epihalohydrin and α f-dihalo-β-yeast &gt; Can be used alone 9 Also note 1 | Can be used in combination of two or more. Item 1 can be used to prepare the water-soluble resin (I) aldehyde epihalohydrin and α f-dihalogenated landfill Packed-β-fermentation> Can be used alone> It can also be used in combination of two or M. For example »Page 1 I Can use both aldehyde and epihalogenase while aldehyde and α, 7-dihalo-β-alcohol Also 1 1 can be used at the same time. 〇1 Water-soluble resin (I) is composed of at least (a) Extrude diamine and polyextrin-based poly1 amidine »(b) Urea compound y and (C) White selection contains aldehydes 9 Epihalohydrin reacted with 1 α t -dihalo-β -enzyme to make water-soluble resin (I) can be made by the reaction of 1 I (a) (b) (C) and one or more additional compounds. 1 1 Preferred examples of the compound include (d) a dicarboxylic acid compound * and (e) an alicyclic 11 compound »such as an alicyclic amine * having at least one active hydrogen * or an alicyclic 1 epoxy compound. 1 1 Dicarboxylic acid compound id) is a compound t having a dicarboxyl group or its derivative 1 1 Biological 0 Dicarboxylic acid compound (d) Not only its free acid can be used »1 1 its ester anhydride and other 〇 dicarboxylic acid compound (d) can be aliphatic aromatic 1 U. Or alicyclic compound 〇 dicarboxylic acid compound (d) Example 9 with fat Group 2 1 carboxylic acids • such as succinic acid> glutaric acid adipic acid sebacic acid, maleic acid 1 fumaric acid linoleic acid and other dimer acids; aromatic dicarboxylic acids 9 such as stupid 1 1 1- 7-1 1 1 This paper scale is printed in Chinese National Standard (CNS &gt; A4 size (210X297mm) A7 B7 Printed by Beigong Consumer Cooperative of the Central Standardization Bureau of the Ministry of Economy V. Invention Instructions (6) 1 1 Formic acid • V Isophthalic terephthalic acid, etc.> M and cycloaliphatic dicarboxylic acid 1 1 9 such as tetrahydroterephthalic acid V. Hydrogen terephthalic acid cyclohexane-1,3 1 1 -dicarboxylic acid , Cyclohexane-1, 4--carboxylic acid cyclopentanedicarboxylic acid 3-methyl please 1 first 1 tetrahydroterephthalic acid 4-methyl tetra Hydrogen terephthalic acid 3-methylhydrogen 1 terephthalic acid 4-methyl-hydroterephthalic acid, etc. backside 1 1 ester of dicarboxylic acid (d) »There is, for example, a single with lower alcohol Esters and diesters> Note 1 I and polyesters with glyphosate matters 1 and then 1 If the dicarboxylic acid compound (d) is a lipid rw cyclic compound> Usually use this package C 4 to about C 96 The compound 〇 used as (d) the alicyclic compound has a page 'w »1 1 saturated 鐽 0 in the present invention * If the position f of the unsaturated bond is not mentioned, then 1 1 alicyclic compound is included in any Compound with unsaturated bond at position 〇1 \ If the dicarboxylic acid compound (d) is an alicyclic compound &gt; its anhydride can also be used better than 1 〇Anhydride example contains tetrahydronhydride 9 • Hydrogen m anhydride »3 -Methyltetrahydrom 1 anhydride> 4- A基 .Tetrahydrophthalic anhydride 9 3 -methylhydrogen Sfe anhydride y 4-methyl-hydrogen m 1 I anhydride etc. 〇1 1 1 If the dicarboxylic acid compound (d) is an alicyclic compound »it is best to use 1 1 Polyester with a dicarboxylic acid group * such as the reaction product of a dicarboxylic acid and glyphosate I. The best polyester is an example with a carbamate carboxylic acid group. The glyoxylate contains alkane 1 1 diol t Such as ethylene glycol malonase and succinase &gt; cyclic two enzymes &gt; such as 1 1 cyclopentane and cyclohexane two enzymes »adipic enzyme 9 such as butene two enzymes and octene 1 | yeast &gt; poly Two enzymes V such as diethylene glycol Λ dipropylene zymase diethylene glycol Λ Υ Polyethylene glycol and polysuccinyl diphenol A and ethylene oxide addition compound 1 Hydrogenated biphenol A and ethylene oxide burning Addition compound 〇Polyester with a carboxylic acid group at the molecular terminal 1> It can be obtained by reacting -8 carboxylic acid with ethyl yeast> 1 1 1 1 1 1 paper Also used the Chinese National Standard (CNS &gt; A4 specification (210X29 * 7mm) A7 B7 Printed by the Ministry of Economic Affairs, Central Bureau of Economic Development, Zhengong Consumer Cooperative Co., Ltd. 5. Description of invention (7) 1 1 Use excess carboxyl Acid 0 Dicarboxylic acid compound (d) Can be used alone 1 1 * It can also be used in combination of two or M Ο 1 1 Alicyclic amines with at least one active argon 9 Usually a fat with c &amp;-C 12 please first 1 Cyclic ring »Μ Cyclohexane ring is preferred and has at least-* primary amine or amine extension ° 闻 it 1 The amine group can be directly or through a linking group such as support» Embed in the alicyclic ring,. Examples of alicyclic amines with 1 I on the back have at least ___. Active hydrogen atoms * Contains cyclohexylamine, diattention 1 I Cyclohexylamine 1, 3-diaminocyclohexylamine, 1, 4-diamine Cyclohexane 4,4 'Matter 1 Re 1 -Diamino-3,3'-Dimethyldicyclohexylmethane, 4,4' · Diamino-3,3'4 Nest Pack-Dimethyl 1,2-bis (aminomethyl) ring page 1 I hexane 1,2-bis (aminomethyl) cyclohexylamine 1,4-bis (aminomethyl) ring Hexane 1 1, N-aminopropylcyclohexylamine ·, 1,5-bis (aminoethyl) octahydro-4,7-methylidene 1 \ indene% 2, 6-bis (aminoethyl) octahydrogen -4,7-methylene indene, 2,2-bis (4-amine ring 1 hexanyl) propane, bis (4-aminoxenyl) methane '4,4 1 monooxobis (cyclohexyl 1 amine) 4, 4 »_ Nitrobis (cyclohexylamine), 1, 3, 5 -triaminocyclohexane 1 I, 2, 4 '-diamino-3, 3', 5, 5? — Tetramethyl Radical τη Cyclohexyl methane, 4,4 '1 1 -diamino- 3, 3', 5, 5 »_ tetramethyldicyclohexylmethane, and methylenediamine 1 1 〇 cycloaliphatic amine can be used alone 9 can also Two or more of them are used in combination 0 | The alicyclic epoxy compound 9 used as (e) is usually a compound having a C 4-C 12 1 1 alicyclic ring &gt; preferably a cyclohexane ring &gt; Or an indirect 1 I epoxy group attached to an alicyclic ring. The alicyclic epoxy compound contains cyclohexyl 1 I alkene oxide \ vinylcyclohexene oxide> bis (3,4-epoxycyclohexyl) 1 Ί Adipic acid ester 3, 4-epoxycyclohexane carboxylate 3- (3,4-epoxycyclohexyl 1 yl) ~ 8, 9-epoxy-2,4-dioxaspiro [5, 5] Eleventh house diglycidyl, 1 hydrogen m acid ester 2, 2, bis (4-glycidol oxidized cyclohexyl) -9-propane, etc. 1 1 1 1 1 1 This paper scale is applicable to the Chinese National Standard (CNS) A4 (2 丨 0X297mm) A7 B7 Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Invention Instructions (8) 1 1 Alicyclic Group rw oxygen compounds can be used alone »Two or more kinds can be used together 〇1 1 _ Cyclic amines and alicyclic epoxy compounds can be used in combination 〇1 1 m soluble compound (HI) One of the preferred examples» is (a) Dialkylene diamine or please 1 first 1 polyalkylene polyamine 9 (b) Urea compound> (C) White selection contains aldehydes Λ See 1 Table of halogen fermentation and α —. Halogen-β-fermentation Compounds &gt; If necessary, add the back Λ 1 | (e). The selection contains aliphatic amine M with at least-active hydrogen and lipid XB9. Note on the family 1 I. Cycloaliphatic compounds such as epoxy compounds 9 are obtained by reaction 〇 Matter 1 Re 1 After obtaining the above alkali-soluble compound In the reaction of (Ε) &gt; (a) (b) and (C)% of the actual installation &gt; or (a) (b) (C) and (e) the reaction order is irrelevant &gt; can be explained on the reverse page 1 | One of the application methods is as follows: 1 diamine or polyextenyl polyamine (a) and urea compound (b) * After 1 \ deamination reaction (referred to as reaction under M), followed by selection of aldehyde-containing epihalogenase 1 With α f-dihalo-β-alcohol (C) compound reaction (reaction 1 after 1 reaction is called reaction 2) &gt; if the reaction material also uses alicyclic compound 1 I (e) when 9 in Reaction 1 and / or anti-a * Mt should be 2 when »One or more types of 1 1 (e) can be made to react with other raw materials * ie (a) (b) or (C) 〇1 1 at the time of anti-wish 1 &gt; Add urea compounds (b) 9 and (a) at the same time to anti-I Bter 懕 0. Two-step reaction f can be used. First add one part. The reaction of (b) 9 and (a) 1 1 »Add the rest (b) 9 to remove Ammonia reaction 0 If in reaction 2 If 1 1 is aldehyde as (C) &gt; then it is better to carry out the reaction under acidic conditions. 9 It can also be reacted under 1 I basic conditions and then under acidic conditions. If reaction 2 I Ί is using epihalogen Enzyme and / or α f -dihalo-β -enzyme as (c) &gt; 1 is most likely to react under weakly acidic or test conditions> eg PH5 or Μ 1 I * and Μ PH6- 9 Better 〇 1 1 1 -1 0- 1 1 1 This paper is again suitable for China National Standard (CNS & A4 specifications (210X297 mm) A7 B7 Printed by Beigong Consumer Cooperative, Central Bureau of Standards, Ministry of Economy V. Inventions Explanation (9! 1 1 These reactions can be carried out in a known manner. For example 9 The reaction using (a) (b) (c) 1 1 as a raw material has been contained in JP-A-92-100997 • except (a)) (b) (C) In addition to 1 1, the reaction using (e) as a raw material t is known from JP-A-92-263696 and 1 is first described in 1 JP-A-92-333697. Hong I 1 I 鹸 soluble compound (I) another--the preferred specific example, is U) alkylene diback 1 1 amine or polyalkylene polyamine 9 (b) urea compound (C) selected white contains aldehyde Note 1 IV Compound of epihalogenase and α 1 -dihalo-β-enzyme> (d) Binary carboxyl matters 1 and 1 acid compound> Add (e) alicyclic compound if necessary Install at least-active hydrogen cycloaliphatic amines »M and cycloaliphatic epoxy compounds» Add page 1 I to obtain 〇1 1 in the reaction to obtain the above alkali-soluble compound (I) in the anti-condensate> (a) The order of the reaction between ⑷ 1 \ or (e) is irrelevant. Here is one of the reaction methods. Example 1 Order as follows: 1 order (a) alkylene diamine or polyalkylene polyamine »(b) urea compound and 1 I ( d) Dicarboxylic acid compound , After deamination reaction and dehydration (K is referred to as reaction 3) 1 1 t produces poly sulfonamide poly P »followed by (C) selection contains aldehydes> epihalohydrin 1 1 and α f-dihalo-β -Alcohol compound reaction (reaction I after reaction 3 Μ should be called reaction 4) &gt; If (e) alicyclic compound is also used as reaction raw material, 1 1 can be used in reaction 3 and / or reaction 4 One or more (e) reacts with other raw materials such as 1 1 (a) (b) (c) 〇1 I Reaction 3 Some of the ways of proceeding are as follows: 1 Ί Add urea compound once (b) Perform the reaction 〇1 Optional addition part (b) Carry out the deamination reaction 9 and then add the rest (b) 9 and then proceed to the 1 1 deamination reaction. Ο 1 1 1 -1 1-1 1 1 The paper size is in accordance with the Chinese National Standard (CNS> A4 specifications ( 210X297mm) 5. Description of the invention (10) Dehydration reaction is carried out between (a) and (d), followed by deamination reaction with (b). Part (b) undergoes a deamination reaction with U), and the resulting compound undergoes a dehydration reaction with (d), followed by a dehydration reaction with the remaining (b). (a) (b) and part (b) are dehydrated and deaminated at the same time, and then deaminated with the rest (b). If aldehyde is used as (c) in reaction 4, it should be carried out under acidic conditions, or it may be carried out under alkaline conditions first, and then under acidic conditions. If epihalogenase and / or α, 7-dihalo- / 3-enzyme is used as (c) in reaction 4, it is advisable to carry out the reaction under weakly acidic or basic conditions, such as pH 5 or Μ, ΗρΗ6- 9 is better. These reactions can be carried out in a known manner. For example, the reaction using (a) (b) (c) (d) as a raw material has been contained in JP-A- 80-3 1 8 37, JP-A-82- 1 6 7 3 1 5, JP-A -87-1 04995, JP-A-87-1 25092, JP-A-87-12 5 093, etc., except for (3) (1)) ((:) (0), for use (as raw materials Reaction, see JP-A-90-216297 and JP-A-90-221498. The paper coating composition of the present invention includes (IV), water-based binder (I) and water-soluble resin (H) in addition to (IV) ) Compounds, selected from the group consisting of (h) Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) Amine, selected from the group consisting of monoamines with C4 or Μ Or diamines on M, and their salts, (g) quaternary ammonium salts, polyglycosamines obtained by reacting M and dicarboxylic acids with polyamines. Amine (h) is selected from the group consisting of C4 or M Monoamines and diamines and their salts. Among them, amines on M (: 5 or M are preferred. (H) Primary, secondary and tertiary amines can be used. Regardless of aliphatic, aromatic, cycloaliphatic and ophthalmic types Any amine can be used. -12- This paper uses the Chinese National Standard (CNS) A4 (210X297mm) A7 B7 Central Ministry of Economic Affairs Printed by the Quasi-Bureau of Consumer Labor Cooperatives 5. Description of the invention (11 1 1 Examples of primary amines include aliphatic monoamines * such as butylamine amylamine \ hexylamine octylamine 1 1 amine isobutylamine 2-ethylhexylamine, etc. * alicyclic Group monoamines, such as cyclohexylamine 1 1 Λ amine methylcyclohexylamine, etc .; and aromatic monoamines> such as stupid amine, toluene please 1 first 1 amine benzylamine, aminoamine phenol, etc. 〇Read I 1 I Examples of amine stretches include monoamines having aliphatic &gt; aromatic or cycloaliphatic groups &gt; M on the back side 1 I and monoamines such as dipropylamine dicyclohexylamine, N-methylcyclohexyl Note 1 I Amine H-Methylaniline, pyrrolidine piperidine, etc. Item 1 V Re 1 Tertiary amines Examples include monoamines with aliphatic, aromatic or alicyclic groups 1 Original M and cyclic monoamines 9 such as triethylamine Dibutylamine Λ Ν, Ν- Methyl n-Prop1 | Amines, Η, Ν-dimethyl rga, Hexamines Η, Η-dimethylaniline, pyridine, etc. 〇1 1 Diamine contains a compound with a diprimary amine group> has a secondary amine Compound 1 f Compound 9 Compound 9 having a di-tertiary amine group and a compound having a diamine group having a substitution number different from each other. Preferred examples of diamines include aromatic diamine esters 1 cyclic diamines and Diamines with cyclic amino groups. Preferred diamines are, for example, lipid and aromatic amines with 1 1 diprimary amino groups 9 such as 1,3-diaminocyclohexane 1 1 isophor m diamine Λ 1. 3-bis (aminomethyl) cyclohexane, bis (4-amino 1 1 rm cyclohexyl) methane, 2,2-bis (4-amino cyclohexyl) propane, methylenediamine, I 4 , 4 '-oxobis (cyclohexylamine), 4,4 1 · Sulfobis (cyclohexylamine) phenylenediamine 1 1% Toluene diamine \ Extened xylene diamine etc. 7 Has the number of amine substitutions Compounds with different 1 1 diamino groups, such as 3-methylaminomethyl-3,5,5imethyl 1 1 cyclohexylamine &gt; 1 -methylamino-3 -aminomethyl-3, 5 , 5-trimethylcyclohexylamine 1-1 Ίaminomethyl-3 -methylaminemethylcyclohexylamine, 1-aminomethyl-3-dimethylamine methyl 1 yl m hexane> 1- Methylamine methyl-3 -dimethylamine methylcyclohexane, 4-1 1 aminopyridine, etc. &gt; Compound 9 having a secondary secondary amino group such as N, N,: A 1 1 -1 3- 1 1 1 This paper scale uses the Chinese National Standard (CNS) A4 (210X297 mm) A7 B7 Printed by the Zhengong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs V. Description of Invention (I2) 1 1 Gisophor m diamine 1, 3-bis (methylaminemethyl) cyclohexane, etc .; Μ and 1 1 compounds with di-tertiary amine groups 9 such as Ν, Ν '-tetramethylisophora di 1 1 amine 1, 3- Bis (dimethylaminomethyl) cyclohexane, etc. 0 / &quot; N Please 1 first 1 (h) The amine can be used as above Inorganic acid salts of amines and diamines and tartaric acid. 0 Reading 1 Inorganic acids are, for example, hydrochloric acid, sulfuric acid, phosphoric acid, etc. Organic acids are, for example, acetic acid 1 Backside 1 I, formic acid% oxalic acid, etc. Note 1 | These The amine can be used alone or in combination of two or more. 0 Matter 1 Re-one organic quaternary ammonium seed (g) Any compound with at least —— quaternary nitrogen can be used 0% This pack (g) Example contains ** quaternary nitrogen connection For compounds with a tetrahydrocarbyl group, on the ring page • S_> 1 1 compounds with quaternary nitrogen 〇 The number of quaternary nitrogen is not limited 9 can be used with a single quaternary nitrogen 1 1 quaternary ammonium salt> with two quaternary nitrogen quaternary ammonium salt, Μ And quaternary ammonium salts with three or M last quarter 1 nitrogen. From an economic point of view or considering feasibility &gt; M single or second quarter m 1 is better to order salt 9 especially M single quaternary ammonium salt is especially good 0 1 there is m quaternary parent salt (g) 9 of which are commonly used in single or second season Ammonium salt, having a quaternary nitrogen 1 I connected to a tetrahydrocarbyl group> wherein at least the dihydrocarbyl group is C 2 -C 3 alkyl 1 1 or alkylene 〇1 1 Μ single quaternary ammonium salt and is connected to all the tetrahydrocarbyl groups of the quaternary nitrogen , 1 can be C 1 -C 3 alkyl <, four hydrocarbon groups can also have two or three Ci ~ C 4 courtyard groups 1 1 9 The remaining one or two are hydrocarbon groups with more carbon atoms 〇1 1 Μ The second quaternary m salt and 9 is connected to the base of the second quaternary nitrogen (hereinafter referred to as the linking group) 1 | The number of carbon atoms is not limited »and the linking group may include an alicyclic or aromatic 1 Ί group. If the linking group is C 1- C ;; alkylene, the hydrocarbon group connected to the quaternary nitrogen instead of 1 group is not limited &gt; only at least one CC Ξ; alkyl is connected to each 1 quaternary nitrogen. If the linking group is C 1 C = &gt; alkylene , Then it is connected to quaternary nitrogen instead of 1 1 1 -1 4- 1 1 1 This paper size is applicable to China National Standard (CNS) A4 specification (210X297mm) V. Description of the invention (13) Printed by the Ministry of Economic Affairs, Central Bureau of Customs, Shellfish Consumer Cooperation. The base of the base is quaternary ammonium, quaternary ammonium, ammonium, ammonium, ammonium, ammonium, ammonium, ammonium, ammonium, ammonium, ammonium, ammonium, ammonium, ammonium, ammonium. The organic acid can be separated from the chlorine by three chemical conversions, each of which is buried in the atmosphere and S '0 0 M? »^ Blt * MM ^ _Ms« The number is connected to the nitrogen S group or, the acid precursor is M, s基基 合 合 »ί Bian, son 0 |. | __ son son ethyl carbon three bases, methyl methylated benzyl nitrogen &quot; Lian Jiyuan ② number. For example, polymethyl ammonium trimethyl trimethyl quaternary carbon si proton root bromide is much more than the original trichemical base-based second agent methyl dichloride. It has more original acid and has a base lipids. The alkyl dibasic group has a harder hexastearyl alkane than the T ^ M carbon carbocyclic ring. For the connection 3, there are CU, multi-family, non-ionized, containing chemical base A, ten hard surface fat, etc. ϋ1_member is more fragrant as chloride. The chlorhexidine-containing triammonium and the second hard decalammonium are combined as clt. There are aromatic acids such as acid, etc., and the base is torus-based ammonium, sub-, and chemical. Ammonium chlorinated ammonium ion ammonium chloride ^ 3 «for the neutron has a diammonium ion group with a salt ionization cationization group, 3 ^ 6! C3, salt or ion. The root is based on the benzyl chloride family of benzyl chloride, the lower C3 but the lower 1-ammonium anion and other acid quaternary chloropropyl 2-trimethyl aryl group in the M1-, 01 to the root of the grass Monoalkenyl group, benzyl benzyl benzyl benzyl group C1 made of non-bicyclic hydrochloric acid, using dimethyl fatty acid as the base bismuth salt compared with cinnyl two W unrestricted group one or lipid ammonium roots as triester The lipid base is called methylethylammonium diyl acceptor base, and the quaternary acid-free bases are the atmosphere, and the hard alkyl is often a dioxane. The upper family form of the tongjiji monoyl linker, the acidic lanthanum ring-like methyl laurel and the cinnamon brown are in contact with hydrocarbons. Carboxylic acid methylammonium, one to three gas month, two month to month hard (please read the precautions on the back and then fill out this page) The paper size is based on the Chinese National Standard (CNS) A4 specification (210X297 mm) A7 B7 economy The Central Bureau of Standards of the Ministry prints for the industrial and consumer cooperatives 5. Description of invention (W) 1 1 The di- or tri-hydrocarbon groups in nitrogen are C 1 C 3 alkyl groups, and the remaining-or 2 are 1 1 C 3-C 24 aliphatic Or aromatic hydrocarbon group> 1 1 The aliphatic hydrocarbon group contains a halogenated group, alkenyl group, cyclic alkyl group, etc. ○ Aromatic please 1 first 1 The hydrocarbon group contains benzyl group, phenethyl group, etc. The preferred compound is quaternary nitrogen »Qiwen 1 The trihydrocarbyl groups attached to nitrogen are methyl or ethyl 1 and the other is C 3 ~ C 24 back 1 1 aliphatic hydrocarbon group, and the particularly preferred compound is quaternary nitrogen 9 of which trihydrocarbyl group Note 1 1 is methyl »And the other is C ί Ϊ-C 12 alkyl &gt; Matter 1 Re 1 Preferred examples of the single quaternary ammonium used in the invention include: octyl trimethyl chloride number 4 decyl trimethyl ammonium chloride, lauryl trimethyl ammonium nitride, etc. Page 1 I Two quarter It salt examples used in the present invention Contains: 1, 3-bis (trimethylammonium ethyl) 1 1 • ma m hexamethylene dichloride, N, N, N ', Η &gt; Ν', Ν »mono-methyl isophorone two number Dibromo 1 ο Η-tallow alkyl-N, Η, N ♦ »Η ', Η« — pentamethyltrimethyl ί? Diammonium dichloride and so on. 1 These organic quaternary ammonium salts (g) can be used alone or in combination of two or more. 1 Polyamine m is obtained from the reaction of dicarboxylic acid ⑴ with polyamine (j). 〇 1 1 The dicarboxylic acid (i) is a compound having a dicarboxylic acid and its derivative. The dicarboxylic acid (i) used as a raw material for the polym amine (h) contains its free acid, its ester, its anhydride, etc. Examples of dicarboxylic acids (i) include the above compounds (d) »namely 1 1 aliphatic ·, aromatic and cycloma dicarboxylic acids» monoesters and diesters of one of the dicarboxylic acids and the lower enzyme 1 1 , An anhydride of one of the dicarboxylic acids »Μ and a polyester made from one of the dicarboxylic acids and 1 1 diacid. Among them, polyesters with free carboxylic acid groups are preferred. Among the polyesters. Polyesters of 20 or below are preferred. 〇1 Dicarboxylic acid ί i) Can be used alone X29 530 &gt; It can also be used in combination of two or more 〇1 I Polyamine (j) Can be used with two Or Μ upper primary amine and / or secondary amine amine »1 1 1 -16- 1 1 1 This paper scale uses the national rubbing rate of China (CNS> A4 specification (210X297 mm) A7 B7 Central Bureau of Standards of the Ministry of Economic Affairs Printed by Beigong Consumer Cooperative V. Description of the invention (is) 1 1 Such as aliphatic amines, as used in the manufacture of water-soluble resins (II) as raw materials for the hospital 1 1 Diamines or polyalkylene polyamines alicyclic polyamines &gt; Aromatic polyamines, etc. Among them, 1 among 1 1 M aliphatic diamines are preferred. These amines can be used monotonously, or two kinds or please use 1 first and more than 1 kinds in combination. Read 1 Read 1 | Alicyclic II The amine can be a compound having an alicyclic ring of about C 5-C 12, and the back surface of M cyclohexane 1 | The ring is preferably a compound of M and a di-primary amine and / or secondary amine group. The amine group can be directly attached to the lipid 1 I Cyclic ring 9 or indirectly connected to the fat via a linking group such as alkylene 1 In addition, the compound used in the ring 0 of the ring group can also be-* Amine group (1) Directly or indirectly 4 This is connected to the cycloaliphatic group 9 The other amine group is an amine alkyl group and is connected to the amine group page S_ ^ 1 | (1) 〇1 1 Examples of alicyclic diamines include diaminocyclohexane, isophorone diamine, 1 bis (aminomethyl) cyclohexanebis (4-aminocyclohexyl) methane &gt; 2,2-bis (4 1 ding-aminocyclohexyl) propane methylenediamine, 4, 4′-oxobis (cyclohexylamine), 1 4,4, -sulfobis (cyclohexylamine) 4,4'-diamino-3,3'-dimethylbicyclo 1 I hexyl methane, 4, 4, -diamino-3,3'-dimethyldicyclohexane, N-amine 1 1 Propylcyclohexylamine 1,5-bis (aminomethyl) octahydro-4,7-methyleneindene 2,6-1 1 Bis (aminomethyl) octahydro-4,7-methyleneindene, 2 , 4 1 · diamino-3, 3 »&gt; 5, 5 '&gt; -κ 1 -tetramethyldioxyhexylmethane 4,4' -diamino-3, 3 ', 5, 5 , -Tetramethyl 1 1 -dicyclohexylmethyl, etc. 〇1 1 Aromatic diamines have at least one aromatic ring »Μ and a compound selected from the group consisting of primary 1 I amine groups and secondary amine groups 〇 aromatic Examples of diamines include dimethyl 1 Ί phenylenediamine, 4, 4 '-diaminodiphenylmethane, 4, 4 »_ — amino-3, 3 t _ 1 dimethyldiphenylmethane N-amine Propylaniline 2,4, -didiamino-3,3 '1 I, 5,5 f monodiamino-3,3 »5,5, -tetramethyldiphenylmethane, etc. c 1 1 1 -17- 1 1 1 This paper is printed in Chinese National Standards (CNS & A4 specifications (210X29 * 7mm) A7 B7 Printed by the Central Bureau of Standards, Ministry of Economy, Tooling and Consumer Cooperatives V. Invention Instructions (16) 1 1 Physical properties of Polyamide (h) 9 such as solubility in aqueous solvents »1 1 Crystallinity ♦ It depends on the (i) dicarboxylic acid used as the raw material of Polyamide (h) and ⑴ 1 1 Polyamine. Therefore, it can be adjusted by choosing raw materials and adding M. Please select 1 first 1 polyacetamide (h) from (i) dicarboxylic acid and (J) polyamine &gt; from 100 to 1 to read 1 I 250 ¾, preferably at 1 30 to 200 ¾, the reaction for 2 to 12 hours, remove the water generated in the reaction, back ij 1 | should be obtained 〇 dicarboxylic acid amount is preferably per mole of polyacetamide Note 1 1 0. 5- 1 mole C reaction can be carried out in the presence or absence of an acid catalyst. 1 and 1 more line »such as hydrochloric acid · &gt; manganic acid phosphoric acid, formic acid, acetic acid and polyacetamide (h) 4 The script is installed at 60% weight In the most aqueous solution, the viscosity at 25 is 20 -1 0 0 0 centipoise 0 pages · »_ ^ 1 1 Viscosity Η 50 -5000 centipoise 1 1 Polyamide (h) Can be used alone * Two kinds Or more than one. 〇1 The ratio of the pigment () in the paper coating composition of the invention to the water-based binder (π &gt; ratio 1 Order &gt; According to the target or use &gt; Determine the same as the conventional paper coating composition 〇1 The water-based binder (I) in the paper coating composition of the present invention (I) »Μ per 100 1 I weight of the most pigment. (]) Use 5 Up to 200 parts by weight is better 9 and &gt; λ 1 0 to 50 1 1 parts by weight is the best 0 Water-soluble resin (I) Μ Per 100 parts by weight of pigment (I) 1 1 Use 0.05-5 parts by weight is better »Μ 0. 1 to 2 parts by weight is better 〇I The amount of the compound (IV) used in the composition of the paper coating of the present invention is as follows 〇 1 1 If the compound (IV) is an amine (h) 9 the amount of M water-soluble resin (I ) Solid 1 The most important ingredient is about 1 to 50% by weight, preferably 9 and M is about 5 to 20% by weight 1 | Better 〇1 If the compound (IV) is polyamide (h) 9 Polyamide amount M Water soluble Resin 1 I (Π) About 1 to 90% by weight of the solid content is preferably 9 and M is about 3 to 1 80 The weight is better 0 1 1 1 -1 8-1 1 1 The size of the paper is based on the Chinese National Standard (CNS) A4 (210X297mm)

經濟部中央揉準局負工消费合作社印褽 五、發明説明(17 ) 1 1 本 發 明 紙 塗 料 組 成 物 製 造 時 » 水 溶 性 樹 脂 (a )和 化 合 1 1 物 (IV )可 預 先 混 合 &gt; 接 著 與 顔 料 (I &gt;和 水 性 黏 合 劑 (I ) 1 1 混 合 9 製 成 組 成 物 » 或 (I )和 (IV )分 別 與 顔 料 (I )和 水 y—\ 請 1 先 1 性 黏 合 劑 (I )混 合 〇 將 水 溶 性 樹 脂 (I )和 化 合 物 (IV ) 聞 1 不 論 是 (I )和 (IV )的混合物 &gt; 或 個 別 9 與 顔 料 ( [)漿液 背 Sj 1 | 之 或 水 性 黏 合 劑 (E )預先混合物 » 再 於 所 得 混 合 物 添 加 其 注 意 1 I 他 成 份 &gt; 亦 可 達 成 本 發 明 效 果 〇 事 項 1 再 1 如 有 需 要 » 本 發 明 紙 塗 料 組 成 物 1 可 進 步 含 有 其 他 I 本 裝 成 份 9 諸 如 分 散 劑 » 黏 度 或 流 動 性 調 節 劑 、 消 泡 劑 防 頁 1 1 腐 劑 &gt; 潤 滑 m 、 持 水 劑 和 著 色 劑 y 包 含 染 料 和 有 色 顔 1 1 料 0 1 本 發 明 紙 塗 料 組 成 物 可 &gt;λ 任 何 已 知 塗 佈 手 段 懕 用 於 1 訂 紙 基 材 &gt; 諸 如 刮 刀 塗 佈 器 氣 刀 塗 佈 器 N 稈 塗 佈 器 、 上 1 膠 壓 機 塗 佈 器 閘 輥 塗 佈 器 和 鑲 造 塗 佈 器 〇 塗 佈 後 &gt; 紙 1 I 視 需 要 經 乾 .LW. 燥 〇 如 有 需 要 » 塗 佈 紙 利 用 超 级 砑 光 機 等 做 1 1 1 表 面 光 滑 處 理 〇 1 1 由 於 本 發 明 紙 塗 料 組 成 物 又 含 有 化 合 物 (IV ), 所 得 塗 佈 紙 顯 示 較 使 用 顔 料 (I ) &gt; 水 性 黏 合 劑 (I )和 水 溶 性 樹 1 1 脂 (I )組 成 的 紙 塗 料 組 成 物 所 得 塗 佈 紙 有 改 善 性 能 〇 1 1 本 發 明 茲 參 見 參 考 例 和 實 施 例 詳 述 之 惟 須 知 本 發 明 1 I 不 限 於 此 〇 所 有 百 分 比 份 量 和 比 率 除 另 有 註 明 外 9 1 均 Μ 重 量 表 示 〇 在 參 考 例 如 實 施 例 中 黏 度 和 pH均 在 25 1 測 量 〇 1 參 1 1 1 -1 9- 1 1 1 本紙張尺度逋用中國國家橾準(CNS &gt; A4规格(210X297公釐) 經濟部中央梂準局貝工消費合作社印裝 A7 B7 五、發明説明(18 ) 於裝於溫度計、回流冷凝器和撹拌棒的四口燒瓶內, 加料146.2克Π.0莫耳)三伸乙四胺和30.0克(0.5莫耳) 尿素,混合物在140-160&lt;〇的内溫加熱3.5小時,遂行脫 氨。然後,加73.1克(0.5莫耳)己二酸,維持内溫150-1 6 0 C,進行脫水-醢胺化5小時。内溫再降至1 3 0 υ, 加120·. 1克(2.0莫耳)尿素,在内溫120-130&quot;〇進行脫氨2 小時。然後加水270克,製成樹脂水溶液。於此溶液添 加60.9克(0.75莫耳)的37%甲醛水溶液。所得系統用70JS 硫酸調節至ΡΗ4-5,在內溫70C反應4小時。反應系統 Κ氫氧化訥水溶液調節至ΡΗ4-5,且在内溫70¾反應4 小時。然後,所得糸統Μ氫氧化納水溶液調至P Η 6 . 5 , 濃縮50¾ ,得675克水溶性樹脂水溶液,黏度140厘泊。 參者_例1 在參考例1所用同樣装置中,加料58.5克(0.4莫耳) 三伸乙四胺和12.0克(0.2莫耳)尿素,混合物在内溫120 -140¾加熱3小時,遂行脫氨。然後,加34.4克(0.2莫 耳)六氫酞酸。在内溫1 5 0 - 1 6 0 t:進行脫水-藤胺化5小 時。內湄再降至130C,加48.0克(0.8莫耳)尿素,在内 溫120-13〇·1〇進行脫氨2小時。反應完成後,內溫降至 1 0 0 t ,加1 0 8克水,製成樹脂水溶液。於此溶液加 32.4克(0.4莫耳)的37¾甲醛水溶液,所得系統以70¾Printed by the Ministry of Economic Affairs, Central Bureau of Accreditation and Consumer Cooperatives V. Description of the invention (17) 1 1 At the time of manufacturing the paper coating composition of the present invention »The water-soluble resin (a) and the compound 1 1 (IV) can be pre-mixed> Next Mix with pigment (I &gt; and water-based adhesive (I) 1 1 9 to make a composition »or (I) and (IV) with pigment (I) and water y— \ Please 1 first 1 adhesive (I ) Mix 〇The water-soluble resin (I) and the compound (IV) Wen 1 Whether it is a mixture of (I) and (IV)> or individual 9 and pigment ([) slurry back Sj 1 | or water-based adhesive (E ) Pre-mix »Add additional attention to the resulting mixture 1 I Other ingredients &gt; Can also achieve the effect of the invention 〇 Matters 1 Re 1 If necessary» The paper coating composition of the invention 1 can be improved to contain other I ingredients 9 such as dispersion Agents »Viscosity or fluidity adjustment Agent, defoamer anti-page 1 1 corrosion agent> lubricating m, water-holding agent and colorant y containing dye and colored pigment 1 1 material 0 1 paper coating composition of the present invention can be &gt; λ any known coating means Used for 1 stapling substrate> such as blade coater, air knife coater, N-stalk coater, upper 1 rubber press coater, gate roll coater, and mosaic coater. After coating> The paper 1 I is dried as needed. LW. Dry. If necessary »Coated paper is treated with a super calender, etc. 1 1 1 Surface smoothing 〇 1 1 Since the paper coating composition of the present invention also contains compound (IV), the obtained Coated paper shows improved performance compared to the use of pigment (I) &gt; water-based binder (I) and water-soluble resin 1 1 resin (I) composed of paper coating composition obtained. 1 The present invention refers to the reference example And the embodiments need only be detailed It is known that the present invention 1 I is not limited to this. All percentage parts and ratios are unless otherwise noted. 9 1 All are M. Weight indication. In the reference example, the viscosity and pH are measured at 25. 1 Reference 1 1 1 -1 9- 1 1 1 This paper is printed in Chinese National Standard (CNS> A4 size (210X297 mm). The Central Bureau of Economic Affairs of the Ministry of Economic Affairs, Printed by Aigong Consumer Cooperative A7 B7 V. Description of the invention (18) In the thermometer, reflow In a four-necked flask with a condenser and a stir bar, add 146.2 g (1.0 mol) triethylenetetramine and 30.0 g (0.5 mol) of urea, and the mixture is heated at an internal temperature of 140-160 &lt; 〇 for 3.5 hours. Deamination. Then, 73.1 g (0.5 mol) of adipic acid was added, the internal temperature was maintained at 150-1 60 ° C, and dehydration-acetamide was performed for 5 hours. The internal temperature drops to 1 3 0 υ again, add 120 · .1 g (2.0 mol) of urea, and perform deamination for 2 hours at an internal temperature of 120-130. Then add 270 grams of water to make an aqueous resin solution. To this solution was added 60.9 g (0.75 mol) of 37% formaldehyde in water. The resulting system was adjusted to pH 4-5 with 70JS sulfuric acid, and reacted at an internal temperature of 70C for 4 hours. The reaction system was adjusted to pH 4-5 with an aqueous solution of KOH and reacted at an internal temperature of 70¾ for 4 hours. Then, the obtained aqueous solution of sodium hydroxide M was adjusted to pH 6.5 and concentrated to 50¾ to obtain 675 grams of water-soluble resin aqueous solution with a viscosity of 140 centipoise. Participant_Example 1 In the same device used in Reference Example 1, 58.5 g (0.4 mol) of triethylenetetramine and 12.0 g (0.2 mol) of urea were added, and the mixture was heated at an internal temperature of 120-140¾ for 3 hours, and then removed ammonia. Then, 34.4 g (0.2 mol) of hexahydrophthalic acid was added. At an internal temperature of 1 5 0-1 6 0 t: dehydration-rattinization for 5 hours. Neimai was lowered to 130C again, 48.0 grams (0.8 mole) of urea was added, and deamination was carried out at an internal temperature of 120-13.0 · 10 for 2 hours. After the reaction was completed, the internal temperature dropped to 100 t, and 108 g of water was added to make an aqueous resin solution. To this solution was added 32.4 g (0.4 mol) of 37¾ formaldehyde in water, the resulting system was 70¾

碕酸調至PH5.I。内溫升至60¾後,令反應系統反應5 小時,再冷卻。然後,所得糸統Μ285Κ氫氧化納水溶液 中和,得275克水溶性樹脂水溶液,黏度45厘泊,pH -20 - 本紙張尺度逋用中困國家揉準(CNS ) A4规格(210X297公釐) (請先閲讀背面之注意事項再填寫本頁) 裝. -i ! 經濟部中央標準局負工消费合作社印製 A7 B7 五、發明説明(19 ) 7 . 1而濃度50% 。 參皇1】 在參考例1所用同樣裝置內,加料146.2克(1.0莫耳) 三伸乙四胺和180.2克(3.0莫耳)尿素,混合物在内溫120 -140t:加熱2小時,遂行脫氨。然後,加150克,製成 樹脂水溶液。於此溶液加56.8克(0.7莫耳)37¾甲醛水 溶液,令所得条統在内溫7〇υ i應4小時。再將糸統用70»; 硫酸調至p Η 4 . 0 ,保持內溫7 0 C,令反應糸統反應4小 時。然後,所得系統Κ氫氧化納水溶液調節至ΡΗ7.0, 得5 1 5克水溶性樹脂水溶液,黏度3 5 0厘泊,濃度5 0 X。 參..例—4._ 在設有潙度計、1.丨e b i g冷凝器和攪拌棒的四口燒瓶 內,加料142克(1.0莫耳)1,3 -雙(胺乙基)環己烷和73.0 克(〇 . 5莫耳)己二酸,保持内溫1 5 0 - 1 6 0 °C ,進行脫水-醢胺化5小時。反應完成後,加水而得3 3 8克聚醯胺水 溶液,黏度400匣泊,濃度60¾ 。 參m 在參考例4所用同樣裝置中,加料170.2克(1.0莫耳) 異佛爾嗣二胺和50克(0.5莫耳)丁二酐,保持內溫150-160C,進行脫水-醸胺化5小時。反應完成後,加水而 得357克聚醢胺水溶液,黏度450厘泊,濃度60¾ 。 參座__例„6_ 於參考例4所用同樣裝置中,加74.2克(1.0莫耳)1,3 -丙二胺,Μ及83.1克(0.5莫耳)3-甲基-1,2, 3,6-四氫 -2 1 - 本纸張尺度逍用中國國家橾準(CNS &gt; A4规格(210X297公釐) ---------f 裝----I--訂------f 1 -. (請先閱讀背面之注意事項再填寫本頁) A7 B7 經濟部中央揉準局貝工消費合作社印製 五、發明説明(2〇 ) 1 1 m 酐 和 4-甲 基 _ 1 , 2, 3 , 6-四氫肽 酐的混 合物, 保持内 溫 1 1 150- 155¾ , 進行脫 水 酿 胺 化5 小 時。 反應完成後, 加 1 1 水 而 得 247 . 2克聚醸 胺 水溶液, 濃度60% 。 請 1 先 1 參 閲 讀 1 在 參 考例 4 所用同樣裝 置 中, 加 116 .2克(1 .0莫耳 )方 背 it 1 I 之 亞 甲 二 胺, Μ 及83 . 1克(0 .5 莫耳)3 -甲 基-1 , 2 ,3,6-四氫 注 意 1 | 酐 和 4 -甲 基 -1,2, 3 , 6-四氫酞 酐之混 合物, 保持内 溫 事 項 1 再 1 150- 155V , 進行脫 水 _ _ 胺 化5 小 時。 反應完成後, 加 4 寫 本 袈 水 得 31 7 . 2克聚醮胺 水 溶液, 濃 度60¾ 〇 頁 1 | 參 皇 1 1 在 參 考例 4 所用同樣裝 置 中, 加 103 .2克(1 .0莫耳 )二 1 \ 伸 乙 三 胺和 73 • 1 克(0. 5莫 耳 )己 二酐, 保持内 溫 150- 155 1 9 進 行脫 水 -醢胺 化 5小時。 然後, 加 152. 1 克(1 . 0莫 1T 1 耳 )1 ,2 ,3,6 -四氫敢 酐 和60 . 1克 (1 . 0莫 耳)乙二胺,保持 1 I 内 溫 度 150- 15510 , 進 行脫水-醢胺 化5 小時。 反應完成 1 1 後 y 加 水得 5 87 . 5 克 聚 釀胺水溶 液, 濃 度60% 〇 1 參 -考 例上 在 參 考例 4 所用同樣裝 置 中, 加 60 . 1 克(1 · 0莫耳) 乙 1 1 二 胺 和 87.1 克 (〇 . 5莫耳)己二酐 二甲酯 ,保持 内溫11 0 V I 進 行 脫 甲酵 6 小時。 反應 完 成後, 加水得194 .2克聚 醢 1 | 胺 水 溶 液, 濃 度60% &lt; ) 1 參ϋΐ丄 1 在 參 考例 4 所用同樣裝 置 中, 加 103 .2克(1 .0莫耳 )二 1 1 伸 乙 二 胺, 60 .1克( 1 · 0莫 耳 )伸 乙二胺 和 202 . 3克(1 . 0莫 1 1 1 -22- 1 1 1 本紙張尺度逋用中國國家標牟(CNS &gt; A4規格(210X297公釐) 經濟部中央揉準局WC工消费合作社印製 A7 B7 五、發明説明(21 ) 耳)癸二酸,保持内溫150-1551^進行脫水-醢胺化5小 時。反應完成後,加水得549.3克聚醢胺水溶液,濃度 60¾ ° 參ϋΐ丄 製備下表1所示配方(固體基)的色料: 表1 (色料) 成份 比率 顔 料 Ultrawhite 90 70 份 Carbital 90 2) 30 份 分 散 劑: Sumirez 樹脂 DS-10 3) 0 · ,2份 水 性 黏合劑: SN- 30 7 4) 12 份 Oji Ace A 4 份 註:(1)美國 Engel Hard Minerals和 Chemical Division Inc.製品之黏土。 (2) 日本富士高嶺土公司製品之碳酸鈣。 (3) 日本住友化學公司製品之聚丙烯酸型顔料分散 劑。 (4) 日本住友Naugatuck公司製品之苯乙烯-丁二烯 乳膠。 (5) 日本Oji National公司製品之氧化暇粉。 表1内比率係按固體含量計算。 實直崖丄 本紙張尺度適用中困國家揉準(CNS ) A4规格(210X297公釐) --------1&lt; 袈-----„--訂------蜱 | (請先閱讀背面之注意事項再填寫本頁) A7 B7 經濟部中央標準局員工消费合作社印製 五、發明説明(22) 1 1 在參 考 例 1 所得2 2 5 克 樹 脂 水 溶 液 內 » 加 5 . 6 克 環 己 1 1 胺 ,Μ 固 定 含 最 言 後 者 9 為 t.f. 刖 者 的 5¾ 9 得 黏 度 為 138 厘 1 1 泊 樹脂 溶 液 〇 所 得 樹 脂 溶 液 添 加 於 參 考 例 11製 成 的 色 料 請 1 先 1 * 樹脂 固 體 含 最 對 顔 料 之 比 為 0 . 5 比 100 〇 閱 讀 1 W Μ Μ 背 Λ 1 I 之 在參 考 例 1 所 得225 克 樹 脂 水 溶 液 内 &gt; 加 22 • 5克 1 , 3 ~ 注 意 1 I 雙 (胺甲基)環 己 烷 Μ 固 體 含 量 &gt; 後 者 為 前 者 的 205K , 事 項 1 再 得 黏度 135 厘 泊 的 樹 脂 溶 液 〇 所 得 樹 脂 溶 液 添 加 於 參 考 i 本 袈 例 1 1製 成 的 色 料 ♦ 樹 脂 固 體 含 量 對 顔 料 之 比 為 0 . 5 比 頁 -—^ 1 I 100 α 1 1 實m 1 在參 考 例 2 所 得 125 克 樹 脂 水 溶 液 內 » 加 12 .5克 環 己 1 -i-r 胺 ,Μ 固 定 含 最 言 t 後 者 為 前 者 的 20% , 得黏度93厘泊 1 的 樹脂 溶 液 〇 所 得 樹 脂 溶 液 添 加 於 參 考 例 1 1製 成 的 色 料 1 I &gt; 樹脂 固 髑 含 最 對 顏 料 之 比 為 0 . 5 比 100 〇 1 1 實龙_ _例_4 1 1 在參 考 例 2 所 得 145 克 樹 脂 水 溶 液 内 , 加 3 . 6 克 異 佛 产 爾 酮二 胺 y Μ 固 定 含 量 言 &gt; 後 者 為 刖 者 的 5¾ 9 得 黏 度 44 1 1 厘 泊樹 脂 溶 液 0 所 得 樹 脂 溶 液 添 加 於 參 考 例 11製 成 的 色 1 1 料 ,樹 脂 固 體 含 最 對 顔 料 之 比 為 0 . 5 比 100 〇 1 I 實m 1 參考 例 3 所 得 樹 脂 水 溶 液 和 異 佛 爾 酮 二 胺 9 個 別 添 加 1 於 參考 例 11製 成 的 色 料 » 樹 脂 固 體 含 量 對 顔 料 比 為 0 . 4 1 I 比 100 * 而 異 佛 爾 嗣 二 胺 對 顔 料 比 為 0 . 1 比 100 〇 1 1 1 -24- 1 1 1 本紙張尺度逋用中國國家橾準(CNS ) A4规格(210Χ297公釐) 經濟部中央揉準局貝工消費合作社印製 A7 B7 五、發明説明(23 ) 實— 在參考例3所得172克樹脂水溶液内,加5.2克1,3-雙(胺甲基)環己烷,Μ固定含量言,後者為前者的5%, 得黏度349厘泊樹脂溶液。所得樹脂溶液添加於參考例 11製成的色料,樹脂固體含量對顔料比為0.5比100 。 實1例—2 , 實施例1至6製成的紙塗料組成物,加水和1 0 %氫氧 化納水溶液,調至總固體含量60¾ , pH約9.0 。所製成 組成物的物理性能,按下述方法測量,測得性能如下表 2所示。 (1 ) P Η :使用T 〇 a D e n p a工業公司製玻璃電極氫離子 濃度計,在組成物製成後立即於2 5 °C測量p Η 。 (2 )黏度:使用..Tolcyo Keiki公司製BL型黏度計,在 組成物製成後立即Μ 6 0「p m,在2 5 °C測量黏度。 製成的組成物用金臑線棒以14g/ni2單次塗佈速率施 加於具有基本重最為80g/m2之细紙單面或兩面上,紙 立刻在120t:熱空氣内乾烽30秒,再於濕度65¾ 調理水份16小時,然後,在60t:和直線壓力60kg/cm超 级砑光二次,得塗佈紙。 所得塗佈紙的抗水性和油墨接受性,偽按下述試驗方 法評估。所得结果如下表2所示。 (3)抗水性(濕式剌落法(wet picking method) : WP) :塗佈表面以供水輥潤溻,利用RI試驗機(Akira製造公 司製品)印刷。目測剝落性(P i c k i n g ),按照1 (劣)至5 -25- 本紙張尺度適用中國國家橾準(CNS ) A4规格(210X297公釐) - ^ ^ 裝 訂 ^ I (請先《讀背面之注意事項再填寫本頁) A7 B7 五、發明説明(24 ) (優)的五等级評分抗水性。 (4)油墨接受性: (4-1)方法A:塗佈表面K供水輥潤濕,利用RI試驗機 印刷。目測油墨接受性,按照1 (劣)至5 (優)的五等级 評分。 、Benzoic acid is adjusted to PH5.I. After the internal temperature rose to 60¾, the reaction system was allowed to react for 5 hours and then cooled. Then, the obtained M285K sodium hydroxide aqueous solution was neutralized to obtain 275 g of a water-soluble resin aqueous solution with a viscosity of 45 centipoise and a pH of -20. The paper size was determined by the National Sleeping Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling out this page). Installed. -I! Printed A7 B7 by the Consumer Labor Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Description of Invention (19) 7.1 with a concentration of 50%. [Shenhuang 1] In the same device used in Reference Example 1, 146.2 g (1.0 mol) of triethylenetetramine and 180.2 g (3.0 mol) of urea were added, and the mixture was heated at an internal temperature of 120-140t: heated for 2 hours, and then removed ammonia. Then, 150 g was added to prepare an aqueous resin solution. To this solution was added 56.8 g (0.7 mol) of 37¾ formaldehyde in water, and the resulting system should be at an internal temperature of 70 ° i for 4 hours. Then adjust the system to 70 »; sulfuric acid was adjusted to p Η 4.0, keeping the internal temperature at 70 C, and the reaction system reacted for 4 hours. Then, the obtained system K aqueous solution of sodium hydroxide was adjusted to pH 7.0 to obtain 515 g of a water-soluble resin aqueous solution with a viscosity of 3 50 centipoise and a concentration of 50 X. Ref .. Example—4._ In a four-necked flask equipped with a dipmeter, 1. 丨 ebig condenser and stir bar, add 142 g (1.0 mol) of 1,3-bis (aminoethyl) cyclohexane Alkane and 73.0 g (0.5 mol) adipic acid were kept at an internal temperature of 150-160 ° C, and dehydration-amidation was carried out for 5 hours. After the reaction was completed, water was added to obtain 3 38 grams of polyamidoamine aqueous solution, with a viscosity of 400 cps and a concentration of 60¾. Reference m In the same device used in Reference Example 4, 170.2 g (1.0 mol) of isophordiol diamine and 50 g (0.5 mol) of succinic anhydride were added, and the internal temperature was maintained at 150-160C for dehydration-ammonification 5 hours. After the reaction was completed, water was added to obtain 357 g of polyacetamide aqueous solution with a viscosity of 450 centipoise and a concentration of 60¾. Part __ Example „6_ In the same device used in Reference Example 4, add 74.2 g (1.0 mol) 1,3-propanediamine, Μ and 83.1 g (0.5 mol) 3-methyl-1,2, 3,6-Tetrahydro-2 1-This paper standard is easy to use China National Standard (CNS &gt; A4 specification (210X297mm) --------- f pack ---- I--order ------ f 1-. (Please read the precautions on the back before filling in this page) A7 B7 Printed by the Central Bureau of Economic Affairs of the Ministry of Economic Affairs Beigong Consumer Cooperative V. Description of invention (2〇) 1 1 m anhydride and 4-Methyl_ 1, 2, 3, 6-tetrahydropeptide anhydride mixture, keep the internal temperature 1 1 150-155¾, dehydration and amination for 5 hours. After the reaction is complete, add 1 1 water to get 247.2 Gram polyamidoamine aqueous solution, 60% concentration. Please 1 first 1 read 1 In the same device used in Reference Example 4, add 116.2 g (1.0 mol) square it 1 I of methylene diamine, Μ And 83.1 g (0.5 mol) of 3-methyl-1, 2, 3, 6-tetrahydro Note 1 | Anhydride and 4-methyl-1,2, 3, 6-tetrahydrophthalic anhydride Mixture, keeping internal temperature matters 1 Then 1 150-155V, dehydration _ amination for 5 hours. After the reaction is completed, add 4 copies of the water to get 31 7 2 grams of polyacetamide aqueous solution, the concentration of 60 ¾ 〇 Page 1 | Sen Huang 1 1 used in Reference Example 4 In the same device, add 103.2g (1.0mol) diethylenetriamine and 73 • 1g (0.5mol) adipic anhydride, keep the internal temperature 150-155 1 9 for dehydration- It is aminated for 5 hours. Then, 152.1 g (1.0 mol 1T 1 ear), 1,2,3,6-tetrahydrogen anhydride and 60.1 g (1.0 mol) ethylenediamine are added, Maintain the internal temperature of 150-1510 in 1 I, and perform dehydration-amidation for 5 hours. After the reaction is completed 1 1 y, add water to get 5 87. 5 g of polybromide aqueous solution, the concentration is 60%. In the same device used, add 60. 1 g (1.0 mol) of ethyl 1 1 diamine and 87.1 g (0.5 mol) of dimethyl adiphydride, and maintain the internal temperature of 110 VI for demethylase 6 hour. After the reaction was completed, water was added to obtain 194.2 g of polyacetate 1 | amine aqueous solution with a concentration of 60% &lt;) 1 Reference 1 In the same device used in Reference Example 4, add 103.2 g (1.0 mol) of 2 1 1 Ethylenediamine, 60 .1 g (1.0 mole) Ethylenediamine and 202.3 g (1.0 mole 1 1 1 -22- 1 1 1 This paper scale uses the Chinese national standard (CNS &gt; A4 size (210X297 mm) A7 B7 printed by the WC Industrial Consumer Cooperative of the Central Bureau of Economics of the Ministry of Economic Affairs 5. Description of the invention (21) Ear) Sebacic acid, keeping the internal temperature 150-1551 ^ for dehydration-acetamide It takes 5 hours. After the reaction is complete, add 549.3 g of polyamidoamine aqueous solution with a concentration of 60¾ °. Refer to Table 1 to prepare the colorants of the formulation (solid-based) shown in Table 1 below: Table 1 (Colorants) Composition Ratio Pigment Ultrawhite 90 70 Parts Carbital 90 2) 30 parts dispersant: Sumirez resin DS-10 3) 0 ·, 2 parts water-based adhesive: SN- 30 7 4) 12 parts Oji Ace A 4 parts Note: (1) Engel Hard Minerals and Chemical in the United States Clay of Division Inc. products. (2) Calcium carbonate manufactured by Fuji Kaolin Company of Japan. (3) Polyacrylic acid type pigment dispersant manufactured by Sumitomo Chemical Company of Japan. (4) Styrene-butadiene latex manufactured by Sumitomo Naugatuck Corporation of Japan. (5) Oxidized powder from Japan Oji National company. The ratios in Table 1 are calculated based on solids content. The paper standard of Shizhiya is suitable for CNS A4 specifications (210X297mm) -------- 1 &lt; 袈 ----- „-order ------ tick (Please read the precautions on the back and then fill out this page) A7 B7 Printed by the Consumer Standardization Cooperative of the Central Standards Bureau of the Ministry of Economy V. Invention Instructions (22) 1 1 In Reference Example 1 2 2 5 g of resin aqueous solution »Add 5 6 grams of cyclohexylamine 1 1 amine, the most fixed containing the latter 9 is tf 5 5 9 9 The viscosity is 138 centigrade 1 1 poise resin solution. The resulting resin solution is added to the coloring material prepared in Reference Example 11 please first 1 * The ratio of the resin solid containing the most pigment is 0.5 to 100 〇Read 1 W Μ Μ back Λ 1 I in the 225 grams of resin aqueous solution obtained in Reference Example 1 &gt; add 22 • 5 grams 1, 3 ~ Note 1 I Bis (aminomethyl) cyclohexane Μ Solid content &gt; The latter is 205K of the former, Matter 1 The viscosity is 135% The resin solution obtained is added to reference i. The color material prepared in Example 1 of the present example. The ratio of resin solid content to pigment is 0. 5 ratio page-^ 1 I 100 α 1 1 real m 1 in the reference example 2 Add 125 g of cyclohexyl 1-ir amine to the obtained 125 g of resin aqueous solution, and fix the resin solution containing 20% of the former, the latter is 20% of the former, and obtain a resin solution with a viscosity of 93 centipoise. The obtained resin solution is added to the reference example 1 1 The colorant 1 I> The ratio of the resin solid content to the most pigment is 0.5 to 100 〇1 1 Shilong _ _ Example _ 4 1 1 in the 145 grams of resin aqueous solution obtained in Reference Example 2, add 3.6 grams of isophorone ketone diamine y M fixed content> The latter is 5¾ 9 of the customer. The obtained viscosity is 44 1 1 centipoise resin solution. 0 The resulting resin solution is added to the color 1 1 material prepared in Reference Example 11. , The ratio of the resin solid containing the most pigment is 0.5 to 100 〇 1 I actual m 1 Reference example 3 The obtained resin aqueous solution and isophorone diamine 9 Individually added 1 The colorant prepared in Reference example 11 »The resin solid content to the pigment ratio is 0. 4 1 I ratio 100 * and different The ratio of Erdidiamine to pigment is 0.1 to 100 〇1 1 1 -24- 1 1 1 The paper size is based on the Chinese National Standard (CNS) A4 specification (210 × 297 mm). Printed by the consumer cooperative A7 B7 V. Description of the invention (23) Actual—In the 172 g aqueous resin solution obtained in Reference Example 3, add 5.2 g of 1,3-bis (aminomethyl) cyclohexane, with a fixed content of M, the latter being 5% of the former, the viscosity of 349 centipoise resin solution. The resulting resin solution was added to the color material prepared in Reference Example 11, and the resin solid content to pigment ratio was 0.5 to 100. In Example 1-2, the paper coating composition prepared in Examples 1 to 6 was added with water and a 10% aqueous sodium hydroxide solution to adjust the total solid content to 60¾ and the pH to about 9.0. The physical properties of the prepared composition were measured according to the following methods. The measured properties are shown in Table 2 below. (1) P Η: Using a glass electrode hydrogen ion densitometer manufactured by Toa D e n p a Industrial Co., Ltd., immediately after the composition was prepared, p Η was measured at 25 ° C. (2) Viscosity: Use the BL-type viscometer manufactured by Tolcyo Keiki, immediately after the composition is made, measure the viscosity at 60 ° pm, at 25 ° C. The prepared composition is 14g with a gold bar / ni2 Single coating rate is applied to one or both sides of fine paper with a basic weight of up to 80g / m2, the paper is immediately dried in 120t: hot air for 30 seconds, and then adjusted to moisture at 65¾ for 16 hours, then, At 60 t: Super calendering twice with a linear pressure of 60 kg / cm to obtain coated paper. The water resistance and ink receptivity of the resulting coated paper were evaluated by the following test methods. The results are shown in Table 2 below. (3) Water resistance (wet picking method): WP): The coated surface is moistened with a water supply roller, and printed with an RI tester (manufactured by Akira Manufacturing Co., Ltd.). Visual peeling (Picking) is measured according to 1 (inferior ) To 5 -25- This paper scale is applicable to China National Standard (CNS) A4 specification (210X297mm)-^ ^ Binding ^ I (please read the notes on the back side and fill in this page first) A7 B7 V. Description of invention (24) (Excellent) Five-level score water resistance. (4) Ink acceptance: (4-1) Method A: coating Dampening water supply roller surface K, using a RI printing tester. Accepting inks visually, according to 1 (poor) to 5 (excellent) rating score of five.,

I (4 - 2 )方法B :利用R I試驗機進行印刷,同時於油墨內 加水。油墨接受性按照(劣)至5 (優)五等级評分。 ------.--「-K装-----.--訂------《 1 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局工消費合作社印製 -26- 本紙張尺度逍用中國國家揉準(CNS ) A4规格(210X297公釐) 五、發明説明(25 ) 樹脂(實施例號) 1 塗物UJUUL:I (4-2) Method B: Use the R I test machine for printing, and add water to the ink. The ink acceptance is rated on a five-level scale from (inferior) to 5 (excellent). ------.-- "-K 装 -----.-- 種 ------" 1 (please read the notes on the back before filling out this page) Ministry of Economic Affairs Central Standards Bureau Industrial Consumption Printed by the cooperative-26- This paper scale is used in the Chinese National Standard (CNS) A4 specification (210X297mm). V. Description of the invention (25) Resin (Example number) 1 Coating UJUUL:

pH (25^ ) 黏度(2510 ) (厘泊) 塗佈紙: 抗水性: WP法 油畢接受性 方法A 方法B A7 B7 2 3 4 5 9.2 9.3 9.0 9.2 9.1 9.1 1,820 1,850 1,880 1,790 1,770 1,760 4.0 4.0 4.3 4. .8 4. .0 4.5 4. ------.--Ί-ί 裝----^--訂------&gt; 1 (請先閲讀背面之注意Ϋ項再填寫本頁) 經濟部中央橾準局男工消费合作社印製 -27 本紙張尺度逍用中國國家棣準(CNS ) Α4规格(210X297公釐) 經濟部中央標準局貝工消费合作社印製 A7 B7 五、發明説明(26 ) 實施 在參考例1所得225克樹脂水溶液內,添加5.6克環 己基三甲基氯化銨,得黏度130厘泊之樹脂溶液。所得 樹脂溶液添加於參考例11,樹脂固體含量對顔料比為 0 · 5 比 1 0 0 〇 實施蓋』 在參考例1所得225克樹脂水溶液內,添加45克 S a η丨s ο 1 C (花王公司製品之5 0 月桂基二甲基苄基氛化 銨溶液),得黏度1 2 8厘泊之樹脂溶液。所得樹脂溶液 添加於參考例製成的色料,樹脂固體含量對顔料比為 0 · 5 比 1 0 0 。 實施.例丄〇 在參考例2所得1 2 5克樹脂水溶液内,添加1 2 . 5克環 己基三甲基氛化銨,得黏度40厘泊的樹脂溶液。所得樹 脂溶液添加於參考例1 1製成的色料,樹脂固體含量對顔 料比為0 . 5比1 0 0 。pH (25 ^) Viscosity (2510) (centipoise) Coated paper: Water resistance: WP method oil acceptable method A method B A7 B7 2 3 4 5 9.2 9.3 9.0 9.2 9.1 9.1 1,820 1,850 1,880 1,790 1,770 1,760 4.0 4.0 4.3 4. .8 4. .0 4.5 4. ------.-- Ί-ί outfit ---- ^-book ------> 1 (Please read the note on the back first Ϋ Item and then fill out this page) Printed by the Ministry of Economic Affairs, Central Bureau of Industry and Commerce, Male Workers' Consumer Cooperative-27 copies of this paper are used in China National Standard (CNS) Α4 specification (210X297mm) Printed by Beigong Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs A7 B7 V. Description of the invention (26) Implemented in 225 grams of resin aqueous solution obtained in Reference Example 1, 5.6 grams of cyclohexyltrimethylammonium chloride was added to obtain a resin solution with a viscosity of 130 centipoise. The resulting resin solution was added to Reference Example 11, and the resin solid content to pigment ratio was 0.5 to 1 to 100,000. In the 225 g aqueous resin solution obtained in Reference Example 1, 45 g of S a η 丨 s ο 1 C ( The 50 lauryl dimethyl benzyl ammonium ammonium hydroxide solution produced by Kao Company) is a resin solution with a viscosity of 1 2 8 centipoise. The obtained resin solution was added to the color material prepared in the reference example, and the ratio of resin solid content to pigment was 0.5 to 100. EXAMPLES Example 1. To the 125 g aqueous resin solution obtained in Reference Example 2 was added 12.5 g of cyclohexyltrimethylammonium chloride to obtain a resin solution having a viscosity of 40 centipoise. The obtained resin solution was added to the color material prepared in Reference Example 11 and the resin solid content to pigment ratio was 0.5 to 10 0.

實施盤丄L 在參考例11製成的色料,分別添加參考例所得樹脂水 溶液,和C 9 aj a m i n e D 8 § Ρ」花王公司製品之75¾雙十七 烷基三甲基氛化銨溶液),後者對前者固體含的重量比 為5 / 1 ,全部對顔料比就固體含量言為0 . 5比1 0 0 。 實m 在參考例3所得172克樹脂水溶液内,添加6.9克 Coatamine D86P,得黏度380厘泊之樹脂水溶液。所得 -28- 本紙張尺度逍用中國國家揉準(CNS &gt; A4规格(210X297公嫠) ---------Ί' 袈----L--訂------1 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局負工消費合作社印裂 A7 B7 五、發明説明(27 ) 樹脂溶液添加於參考例11製成的色料,樹脂固體含量對 顏料比為0.5比100 。 實m 在參考例3所得172克樹脂水溶液内,添加10.4克 San丨sol C,得黏度330厘泊之樹脂水溶液。所得樹脂 溶液添加於參考例11製成的色料,樹脂固體含量對顏料 比為0 . 5 比1 0 0 ° 實施例 在參考例3所得172克樹脂水溶液內,添加20.6克四 甲基溴化_ ,得黏度440厘泊之樹脂水溶液。所得樹脂 溶液添加於參考例11製成的色料,樹脂固體含量對顔料 比為0 · 5 比1 0 0 。 實施麗1上 在參考例3所得172克樹脂溶液,添加20.6克正己基 三甲基溴化銨,得黏度5 3 0厘泊的樹脂溶液。所得樹脂 溶液添加於參考例11製成的色料,樹脂固體含量對顔料 比為0 . 5 比1 0 0 ° 實m. 在參考例3所得172克樹脂溶液,添加20.6克正辛基 三甲基溴化銨,得黏度6 1 0厘泊的樹脂溶液。所得樹脂 溶液添加於參考例11製成的色料,樹脂固體含量對顔料 比為0 . 5比1 0 0 。Implementation of the colorant prepared in Reference Example 11, add the resin aqueous solution obtained in Reference Example, and C 9 aj amine D 8 § Ρ ”Kao Corporation product 75¾ diheptadecyl trimethyl ammonium cyanide solution) The latter has a weight ratio of 5/1 to the former solids, and the total pigment ratio is 0.5 to 100 in terms of solids content. In the 172 g aqueous resin solution obtained in Reference Example 3, 6.9 g of Coatamine D86P was added to obtain a resin aqueous solution having a viscosity of 380 centipoise. Result-28- This paper scale is easy to use Chinese National Standard (CNS &gt; A4 specification (210X297 Gongmai)) --------- Ί '袈 ---- L--Subscribe ------ 1 (Please read the precautions on the back and then fill out this page) A7 B7 printed by the Consumer Labor Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (27) The resin solution is added to the color material made in Reference Example 11 and the resin solid content The pigment ratio is 0.5 to 100. Real m To the 172 grams of resin aqueous solution obtained in Reference Example 3, 10.4 grams of Sanssol C is added to obtain a resin aqueous solution with a viscosity of 330 centipoise. The resulting resin solution is added to the color prepared in Reference Example 11. The ratio of the resin solid content to the pigment is 0.5 to 100 °. Example In the 172 g aqueous resin solution obtained in Reference Example 3, 20.6 g of tetramethyl bromide was added to obtain a resin aqueous solution with a viscosity of 440 centipoise. The resin solution was added to the color material prepared in Reference Example 11, and the ratio of resin solid content to pigment was 0 · 5 to 1 0 0. 172 g of the resin solution obtained in Reference Example 3 on Example 1 was added 20.6 g of n-hexyl trimethyl Ammonium bromide yielded a resin solution with a viscosity of 530 centipoise. The resulting resin solution was added to Reference Example 11 The ratio of the resin solid content to the pigment is 0.5 to 1 0 0 ° m. In the 172 g resin solution obtained in Reference Example 3, add 20.6 g of n-octyltrimethylammonium bromide to obtain a viscosity of 6 1 0 A resin solution in centipoise. The resulting resin solution was added to the color material prepared in Reference Example 11, and the resin solid content to pigment ratio was 0.5 to 10 0.

實U丄』I 在參考例3所得172克樹脂溶液,添加20.6克正癸基 本纸張尺度逋用中國國家標準(CNS ) Α4规格(210X297公嫠) ------.--裝--------訂------《I (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消费合作社印製 A7 B7 五、發明説明(28 ) 三甲基溴化銨,得黏度810厘泊的樹脂溶液。所得樹脂 溶液添加於參考例11製成的色料,樹脂固體含量對顔料 tb^0.5 tblOO ° 實施_例—1—8_ 在參考例3所得172克樹脂溶液,添加68.6克30. U、 月梓基三甲基氯化较溶液,得黏度400厘泊的樹脂溶液 。所得樹脂溶液添加於參考例11製成的色料,樹脂固體 含最對顔料比為0.5比100 。 實施例 在參考例3所得1 7 2克樹脂溶液,添加7 3 . 3克2 8 . U 正十六烷基三甲基氛化銨溶液,得黏度690厘泊的樹脂 溶液。所得樹脂溶液添加於參考例1 1製成的色料,樹脂 固體含最對顔料比為0 . 5比1 0 0 。 實施例.20 在參考例3所得172克樹脂溶液,添加32.6克63. U 硬脂基三甲基氛化銨溶液,得黏度1490厘泊的樹脂溶液 。所得樹脂溶液添加於參考例1 1製成的色料,樹脂固體 含最對顔料比為0.5比100 。 實_姐_2丄 實施例8-20製成的紙塗料組成物,加水和10¾氫氧化 納溶液,調節至總固體含量60¾和pH約9.0 。製成的組 成物物理性能,按照實施例7所述方法測量,測得性能 列於表3和表4 。 製成的組成物使用金屬線棒M 14g/ia2單次塗佈速率 -30- 本紙張尺度逍用中國國家揉準(CNS } A4规格(210X297公釐) I - ^ — / 裝 訂 I (請先閱讀背面之注意事項再填寫本頁) A7 B7 五、發明説明(29 ) 施加於具基本重量為80g/m2之细紙單面或雙面上,紙 經12010熱空氣乾燥30秒,在20¾、相對濕度65¾調理 力 壓 線 直 和 V ο 6 在 後 〇 然紙 ,佈 時塗 小得 6 11 , 份次 水二 光 砑 鈒 超 所 7 例 。 施示 實所 照 4 按表 ,和 性 3 受表 接下 墨如 油果 和结 性得 水所 抗。 的估 紙評 佈法 塗方 得驗 所試 述 (請先《讀背面之注意事項再填寫本頁) 袈 訂 經濟部中央揉準局只工消費合作社印装 本紙張尺度遑用中國國家橾率(CNS ) A4规格(2丨0X297公釐) 五、發明説明(3〇 ) 樹脂(實施例號) 8 塗料姐成_物之姐盟1能_:帄 渄 I In the 172 grams of resin solution obtained in Reference Example 3, add 20.6 grams of Zhengde basic paper size to use the Chinese National Standard (CNS) Α4 specification (210X297 public daughter) ------.-- installed- ------- Subscribe ------ "I (Please read the precautions on the back before filling out this page) A7 B7 printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Invention Instructions (28) Ammonium bromide, a resin solution with a viscosity of 810 centipoise. The resulting resin solution was added to the color material prepared in Reference Example 11, the resin solid content of the pigment tb ^ 0.5 tblOO ° Example _ Example-1-8_ In Reference Example 3 obtained 172 grams of resin solution, add 68.6 grams 30. U, Yuezi Base trimethyl chloride chlorination solution, to obtain a resin solution with a viscosity of 400 centipoise. The resulting resin solution was added to the color material prepared in Reference Example 11, and the resin solid contained the most pigment ratio of 0.5 to 100. EXAMPLES In 172 g of the resin solution obtained in Reference Example 3, 7.3 g of 28. U n-hexadecyltrimethylammonium ammonium chloride solution was added to obtain a resin solution having a viscosity of 690 centipoise. The resulting resin solution was added to the color material prepared in Reference Example 11, and the resin solid contained the most pigment ratio of 0.5 to 10 0. Example 20. In 172 grams of resin solution obtained in Reference Example 3, 32.6 grams of 63. U stearyl trimethyl ammonium ammonium chloride solution was added to obtain a resin solution with a viscosity of 1490 centipoise. The resulting resin solution was added to the color material prepared in Reference Example 11 and the resin solid contained the most pigment ratio of 0.5 to 100.实 _ 姐 _2 丄 The paper coating composition prepared in Examples 8-20 was added with water and 10¾ sodium hydroxide solution to adjust to a total solids content of 60¾ and a pH of about 9.0. The physical properties of the prepared composition were measured according to the method described in Example 7, and the measured properties are listed in Table 3 and Table 4. The resulting composition uses a metal wire rod M 14g / ia2 single coating rate -30- The paper size is easy to use China National Standard (CNS} A4 specification (210X297 mm) I-^ — / binding I (please first Read the precautions on the back and fill out this page) A7 B7 5. Description of the invention (29) Apply to one or both sides of fine paper with a basic weight of 80g / m2. The paper is dried by hot air in 12010 for 30 seconds, at 20¾, Relative humidity 65 ¾ conditioning force pressure line straight and V ο 6 in the back of the paper, the cloth is coated with 6 11 small, part of the water in two cases of 7 cases. According to the table 4 according to the table, and 3 The inks such as oil fruit and knot-resistant water are resisted by the table. The evaluation paper appraisal method is to be tested by the painter (please read the precautions on the back side and then fill out this page). The paper size of the printed papers of the Bureau of Labor and Social Welfare Cooperatives used the Chinese National Standard (CNS) A4 specification (2 丨 0X297mm). 5. Description of the invention (3〇) Resin (Example No.) League 1 can_:

pH (251C ) 黏度(25t:) (匣泊) 塗佈Μ : 抗水性: WP法 油墨接受性 方法A 方法B A7 B7 10 11 12 13 9.2 9.3 9.0 9.2 9.1 9.1 1,830 1,870 1,880 1,810 1,790 1,780 3. 4. 3.9 4.6 4. 3.8 4.4 4, 4.1 4.7 4.5 4.1 .4 3.8 4.5 4.4 ------,--1&lt; 策------订------' _ (請先閲讀背面之注意事項再填寫本頁) 經濟部中央揉準局貝工消费合作社印製 -32- 本紙張尺度逋用中國國家標準(CNS ) A4规格(210X297公釐) 五、發明説明(31 ) 樹脂(實施例號) 塗-料UMi—之物腦1: pH (25¾ ) 鈷麻(25D ) (匣泊) 塗佈紙: 抗水性: 14 A7 B7 15 16 17 18 19 20 9.1 9.2 9.1 9.1 9.1 9.1 9. 810 1,840 1,850 1,870 1,840 1,800 1,880 ΙίΡ法 3.8 4.0 3.8 4.0 3.8 4.3 3.8 油墨接受性: 方法A 3.9 4.0 4.7 4.8 4.7 4.5 4.2 方法B 3.8 4.2 4.6 4.8 4.5 4.4 4.2 . 1 ^ 裝 „ 訂 ^ I (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局貝工消費合作社印製 -33- 本紙張尺度適用中國國家橾準(CNS ) Α4规格(210Χ 297%-it 經濟部中央標準局負工消费合作社印製 A7 B7 五、發明説明(32 ) 實m 於參考例1所得225克樹脂水溶液(H)內,加參考例 4所得9.3克聚釀胺水溶液,聚醢胺量為樹脂(II)固體 含最的5%。所得溶液K硫酸調節至PH6.5 ,加1.9克水 ,得含聚醯胺的樹脂溶液,濃度50ίΚ ,黏度198厘泊。、 所得樹脂溶液添加於參考例11製得的色料,樹脂固體含 最對顔料比為0 . 5比1 0 0 。 實 於參考例2所得樹脂水溶液(Μ)內,加參考例4所得 聚醢胺水溶液,聚_胺最為樹脂(I)固體含量的5¾。所 得溶液Μ硫酸調節至P Η 7 . 0 ,加水得含聚醢胺的樹脂溶 液,濃度5 0 % ,黏度1 0 0厘泊。所得樹脂溶液添加於參 考例11製得的色料,樹脂固體含量對顔料比為0.5比100。 實施—例14 於參考例3所得樹脂水溶液(ΒΙ )內,加參考例4所得 聚_胺水溶液,聚醯胺最為樹脂(Μ)固體含量的5¾。所 得溶液Μ碕酸調節至PH6.8 ,加水得含聚醢胺的樹脂溶 液,澹度6 0 S!,黏度1 7 8厘泊。所得樹脂溶液添加於參 考例11製得的色料,樹脂固體含量對顔料比為0.5比100。 實直U_5„ 於參考例1所得樹脂水溶液(Bl )内,加參考例4所得 聚醢胺水溶液,聚醮胺最為樹脂(®)固體含量的20¾。 所得溶液Μ碕酸調節至P Η 6 , 7 ,加水得含聚醯胺的樹脂 溶液,漘度50¾ ,黏度230厘泊。所得樹脂溶液添加於 ---------裝-----„--IX------^ I (請先閏讀背面之注意事項再填寫本頁) 本紙張尺度逋用中國國家揉準(CNS ) A4规格(210X297公釐} A7 B7 經濟部中央橾準局負工消費合作社印製 五、發明説明(33) 1 1 參考 例 11製得 的 色 料 * 樹 脂 固 體 含 量 對 顔 料 比 為 0 . 5 比 1 1 100 〇 1 1 實施Jin 請 1 先 1 於 參 考例 2 所 得 樹 脂 水 溶 液 ( I ) 内 » 加 參 考 例 5 所 得 聞 1 聚醜 胺 水溶 液 &gt; 聚 醢 胺 最 為 樹 脂 (Π ) 固 體 含 量 的 5¾ 〇 所 背 it 1 | 之 J 得溶 液 Μ硫 酸 調 節 至 PH7 . 2 9 加 水 得 含 聚 醯 胺 的 樹 脂 溶 注 意 1 I 液, 漘 度50¾ * 黏 度 167 厘 泊 〇 所 得 樹 脂 溶 液 添 加 於 參 事 項 1 再 1 考例 1 1製得 的 色 料 * 樹 脂 固 體 含 量 對 顔 料 比 為 〇. 5 比 1 0 0 ° 寫 本 袈 實撤视27 頁 1 | 於 參 考例 3 所 得 樹 脂 水 溶 液 ( 1 ) 內 &gt; 加 參 考 例 5 所 得 1 1 聚_ 胺 水溶 液 聚 醢 胺 量 為 樹 脂 (I ) 固 體 含 量 的20¾ 1 所得 溶 液以 硫 酸 調 節 至 P Η 6 . 9 9 加 水 得 含 聚 醯 胺 的 樹 脂 1 訂 溶液 » 濃度60% » 黏 度 33 1 厘 泊 〇 所 得 樹 脂 溶 液 添 加 於 1 參考 例 1 1製 得 的 色 料 » 樹 脂 固 體 含 量 對 顔 料 比 為 0 . 5 比 1 I 100 0 1 實施 1 1 於 參 考例 3 所 得 樹 脂 水 溶 液 ( m ) 内 , 加 參 考 例 4 所 得 产 聚醃 胺 水溶 液 &gt; 聚 醯 胺 量 為 樹 脂 (I ) 固 體 含 量 的 50% 1 1 所得 溶 液Μ 硫 酸 調 節 至 ΡΗ6 . 8 » 加 水 得 含 聚 醯 胺 的 樹 脂 1 1 溶液 » 濃度60¾ f 黏 度342 厘 泊 〇 所 得 樹 脂 溶 液 添 加 於 1 I 參考 例 1 1製得 的 色 料 » 樹 脂 固 體 含 量 對 顔 料 比 為 0 . 5 比 1 100 〇 1 實 1 1 於 參 考例 3 所 得 樹 脂 水 溶 液 ( I ) 内 9 加 參 考 例 6 所 得 1 1 1 -35- 1 1 1 本紙張尺度遠用中國國家標率(CNS ) A4规格(2丨0X297公釐) at B7 經濟部中央標準局貝工消费合作社印製 五、發明説明(34 ) 1 1 聚 醮 胺 水 溶 液 * 聚 讎 胺 量 為 樹 脂 (η ) 固 體 含 量 的2 0% 1 1 所 得 溶 液 K 碕 酸 調 節 至 PH7 . 2 9 加 水 得 含 聚 醯 胺 的 樹 脂 1 1 溶 液 » 濃 度 6 0S; 9 黏 度 346 厘 泊 〇 所 得 樹 脂 溶 液 添 加 於 請 1 先 1 參 考 例 1 1製 得 的 色 料 » 樹 脂 固 體 含 量 對 顔 料 比 為 0 . 5 比 聞 讀 背 S} 1 100 〇 1 | 之 實施JO O 注 意 1 1 於 參 考 例 3 所 得 樹 脂 水 溶 液 (I ) 内 9 加 參 考 例 7 所 得 事 項 1 再 1 聚 m 胺 水 溶 液 * 聚 醯 胺 量 為 樹 脂 (I ) 固 體 含 量 的20¾ 4 寫 本 袈 所 得 溶 液 Μ 硫 酸 調 節 至 PH7 . 1 » 加 水 得 含 聚 醯 胺 的 樹 脂 頁 1 I 溶 液 9 濟度60¾ , 黏 度340 厘 泊 0 所 得 樹 脂 溶 液 添 加 於 1 1 參 考 例 ]]製 得 的 色 料 &gt; 樹 脂 固 體 含 量 對 顔 料 比 為 0 . 5 比 1 100 〇 1 訂 實 施 例—3 1 1 於 參 考 例 3 所 得 樹 脂 水 溶 液 (I ) 内 * 加 參 考 例 8 所 得 1 I 聚 醮 胺 水 溶 液 &gt; 聚 醯 胺 最 為 樹 脂 (I ) 固 體 含 量 的 20% 1 1 所 得 溶 液 Μ 碲 酸 調 節 至 PH7 . 2 加 水 得 含 聚 醯 胺 的 樹 脂 1 1 溶 液 * 濃 度6 0% &gt; 黏度372 厘 泊 〇 所 得 樹 脂 溶 液 添 加 於 产 參 考 例 1 1製 得 的 色 料 &gt; 樹 脂 固 體 含 量 對 顔 料 比 為 0 . 5 比 1 1 100 〇 1 1 實 2 1 | 於 參 考 例 3 所 得 樹 脂 水 溶 液 (B ) 内 » 加 參 考 例 9 所 得 1 聚 醯 胺 水 溶 液 &gt; 聚 醯 胺 量 為 樹 脂 (I ) 固 體 含 量 的20¾ 1 所 得 溶 液 硫 酸 調 節 至 pH6 . 9 * 加 水 得 含 聚 醯 胺 的 樹 脂 1 溶 液 1 濃 度60% 9 黏 度 356 厘 泊 〇 所 得 樹 脂 溶 液 添 加 於 1 1 1 -36- 1 1 1 本紙張尺度遑用中國國家梯準(CNS ) A4规格(210X297公釐) A7 B7 經濟部中央揉準局貝工消费合作社印製 五、發明説明 (35 ) 1 1 參 考 例 11 製 得 的 色 料 * 樹 脂 固 體 含 量 對 顔 料 比 為 0 . 5 比 1 1 100 〇 1 I 實 施- —例_13 請 1 I 於 參 考 例 3 所 得 樹 脂 水 溶 液 (I ) 内 9 加 參 考 例 10所 得 先 閱 1 I 讀 1 I 聚 醜 胺 水 溶 液 9 聚 醮 胺 最 為 樹 脂 (I ) 固 體 含 量 的 20¾ 背 A 1 1 之 1 所 得 溶 液 Κ 硫 酸 調 節 至 PH7 . 2 9 加 水 得 含 聚 醢 胺 的 樹 脂 注 意 1 | 溶 液 * 循 度 60¾ ♦ 黏 度 342 厘 泊 〇 所 得 樹 脂 溶 液 添 加 於 事 項 1 再 1 參 考 例 11 製 得 的 色 料 9 樹 脂 固 體 含 量 對 顔 料 比 為 0 . 5 比 填 寫 本 1 00 〇 頁 1 I 實 施一例 34 1 1 參 考 例 1 所 得 樹 脂 水 溶 液 * 和 參 考 例 4 所 得 聚 醢 胺 水 1 溶 液 * 個 別 添 加 於 參 考 例 11 製 成 的 色 料 9 其 中 樹 脂 溶 液 1 1 訂 1 對 聚 醜 胺 溶 液 的 重 最 比 為 90 比 4 (Μ固體含量言為9 5比5 ) &gt; 而 樹 脂 和 聚 醯 胺 的 總 固 體 含 量 對 色 料 比 為 0 . 5 比 100° 1 I 實— Μ 置J 5一 1 1 實 施 例 22 至 34製 成 的 紙 塗 料 組 成 物 » 加 水 和 10¾ 氬 氧 1 1 化 納 水 溶 液 « 調 至 總 固 體 含 量 60¾ » pH約 9 . 0 〇 製 成 姐 终 成 物 的 物 理 性 能 9 按 實 施 例 7 所 述 方 法 測 量 &gt; 測 得 性 能 1 1 如 下 表 5 和 表 6 所 示 〇 1 I 製 成 組 成 物 使 用 金 鼷 媒 棒 14 g / m 2 PP 甲 — -塗佈速率施 1 1 加 於 具 基 本 重 量 為 80 g / m2之细紙單面或雙面上, 紙立 1 即 在 12010熱空氣内乾燥30秒, 再於20 D , 相對濕度65¾ 1 調 理 水 份 1 6小 時 t m 後 在 60 和 直 線 壓 力 60kg / C m超级 1 1 砑 光 二 次 , 得 塗 佈 紙 〇 1 1 1 -37- 1 1 1 本紙張又度逋用中國國家橾準(CNS ) A4规格(210X297公釐) 經濟部中央標準局貝工消費合作社印製 A7 B7 五、發明説明(36 ) 所得塗佈紙的抗水性和油墨接受性,按照實施例7所 述試驗方法評估。所得结果如下表5和表6所示。 ~ 3 8 * ------.--1U 東-- (請先閲讀背面之注意事項再填寫本頁) 訂· 本紙張尺度適用中國國家梂準(CNS ) A4«l格(210X:297公釐) 經濟部中央標準局貝工消费合作社印製 A7 B7 五、發明説明(37 ) 榭脂(實施例號) 塗料組成直之Ιί[題 22 23 24 25 26 27 ρΗ(25Ό ) 9.2 9.3 9.0 9.2 9.1 9.1 黏度(25D) (厘泊) 塗_佈紙: 抗水性: 1,820 1,790 1,830 1,860 1,800 1,880 WP法 油墨接受性: 4.0 4.5 4.3 4.1 4.5 4.4 方法A 3.9 4.5 4.5 4.0 4.5 4.5 方法B 3.7 4.2 4.3 4.1 4.2 4.5 -39- (請先W讀背面之注意ί項再填寫本頁) 訂· 本紙張尺度逋用中國國家橾準(CNS &gt; A4规格(210X297公釐) B7 五、發明説明(38 ) ^_6_ 樹脂(實施例號) 塗料姐成並之1理UL: 28 29 30 31 32 33 34 pH (25^ ) 9.1 9.1 9.0 9.2 9.2 9.1 9.3 黏度(25t:) (匣泊) 塗佈紙: 抗水性: 1,910 1,830 1,880 1,890 1,870 1,850 1,830 WP法 油墨接受性: 4.2 4.0 4.2 4.0 4.1 4.2 4.0 方法A 4.7 4.5 4.3 4.2 4.0 4.1 3.8 方法B 4.7 4.3 4.1 4.4 4.2 4.5 3.8 (請先《讀背面之注意事項再填寫本頁) 4^- 本纸張尺度逋用中國國家揉準(CNS ) A4规格(210X297公釐) 經濟部中央揉準局貝工消費合作社印製 A7 B7 五、發明説明(沾) tt—較1丄 參考例1所得樹脂水溶液,添加於參考例11所製成色 料,樹脂固體含最對顔料比為0.5比100 ,製成紙塗料 組成物。 比_ _較..例1 、 參考例2所得樹脂水溶液,添加於參考例1 1所製成色 料,樹脂固體含最對顔料比為0.5比100 ,製成紙塗料 組成物。 比一較13 參考例3所得樹脂水溶液,添加於參考例11所製成色 料,樹脂固體含最對顔料比為0 . 5比1 0 0 ,製成紙塗料 組成物。 tL—較抱 使用參考例11製成的色料,做為紙塗料驵成物,不加 其他化合物。 比_龙...貴_5.. 比較例1至4製成的紙塗料組成物,加水和10%氫氧 化納水溶液,調至總固體含量60¾ , pH約9.0 。製成組 成物的物理性能,按實施例7所述方法測量,測得性能 如下表7所示。 製成的組成物用金鼷線棒M14g/m2單次塗佈速率施 加於具基本重最為80g/m2之细紙單面或雙面上,紙立 即在12〇υ熱空氣内乾燥30秒,在20C,相對濕度65¾ 調理水份1 6小時,然後在6 0 t:和直線壓力6 0 k g / c m超级 -41 - 本紙張尺度逍用中國國家標準(CNS } A4规格(210X297公釐) (請先閲讀背面之注意事項再填寫本頁) 袈. 訂 i 30C411 A7 B7 五、發明説明(4〇 ) 砑光二次,得塗佈紙。 所得塗佈紙的抗水性和油墨接受性,按照實施例7所 述試驗方法評估。所得结果如下表7所示。 ------.—ΊΊ‘ 务-----„--訂------A ) (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局負工消费合作社印装 本纸張尺度逋用中國國家梂準(CNS ) A4规格(2丨0X297公釐) 五、發明説明(4l ) 樹脂(實施例號) 1 i料姐废盥之並理J4JL: pH (25¾ ) 9pH (251C) Viscosity (25t :) (cartridge) Coating M: Water resistance: WP method ink acceptance method A method B A7 B7 10 11 12 13 9.2 9.3 9.0 9.2 9.1 9.1 1,830 1,870 1,880 1,810 1,790 1,780 3. 4 . 3.9 4.6 4. 3.8 4.4 4, 4.1 4.7 4.5 4.1 .4 3.8 4.5 4.4 ------,-1 &lt; policy ------ order ------ '_ (please read the back first Please pay attention to this page and then fill out this page) Printed by the Ministry of Economic Affairs, Central Bureau of Accreditation and Printing Co., Ltd. -32- This paper uses the Chinese National Standard (CNS) A4 specification (210X297mm). V. Description of invention (31) Resin (31 Example number) Coating-material UMi—The thing brain 1: pH (25¾) Cobalt hemp (25D) (casket) Coated paper: Water resistance: 14 A7 B7 15 16 17 18 19 20 9.1 9.2 9.1 9.1 9.1 9.1 9 . 810 1,840 1,850 1,870 1,840 1,800 1,880 ΙίΡ method 3.8 4.0 3.8 4.0 3.8 4.3 3.8 Ink acceptance: Method A 3.9 4.0 4.7 4.8 4.7 4.5 4.2 Method B 3.8 4.2 4.6 4.8 4.5 4.4 4.2. 1 ^ Pack „Order ^ I (please first Read the precautions on the back and fill in this page) Printed by Beigong Consumer Cooperative of Central Bureau of Standards of the Ministry of Economic Affairs-33- This paper size is applicable to the Chinese National Standard (CNS) Α4 specification (210Χ 297% -it printed by the Ministry of Economic Affairs Central Standards Bureau Negative Consumers Cooperatives A7 B7 V. Description of invention (32) rm m 225g of resin aqueous solution (H) obtained in Reference Example 1, plus reference example 4. The resulting 9.3 g of polybromide aqueous solution, the amount of polyamidoamine is the most 5% of the solid content of resin (II). The resulting solution K sulfuric acid is adjusted to pH 6.5, add 1.9 g of water to obtain a resin solution containing polyamidoamine 50ίΚ, viscosity 198 centipoise., The resulting resin solution is added to the color material prepared in Reference Example 11, the resin solid contains the most pigment ratio is 0.5 to 100. Actually obtained in Reference Example 2 resin aqueous solution (Μ) , Add the aqueous solution of polyamide obtained in Reference Example 4, poly_amine is the most solid content of resin (I) 5¾. The resulting solution M sulfuric acid is adjusted to P Η 7.0, add water to obtain a resin solution containing polyamide, concentration 50% The viscosity is 100 centipoise. The resulting resin solution is added to the color material prepared in Reference Example 11, and the resin solid content to pigment ratio is 0.5 to 100. Example-Example 14 In the resin aqueous solution (BI) obtained in Reference Example 3, the poly-amine aqueous solution obtained in Reference Example 4 was added, and polyamide was the most solid content of the resin (Μ). The obtained solution M was adjusted to pH 6.8, and water was added to obtain a resin solution containing polyacetamide, with a viscosity of 60 S! And a viscosity of 178 centipoise. The resulting resin solution was added to the color material prepared in Reference Example 11, and the resin solid content to pigment ratio was 0.5 to 100. Real straight U_5 "In the aqueous resin solution (Bl) obtained in Reference Example 1, add the aqueous solution of polyacetamide obtained in Reference Example 4, the maximum content of polyacetamide resin (®) is 20¾. The resulting solution M benzoic acid is adjusted to P Η 6, 7. Add water to obtain a resin solution containing polyamide, with a degree of 50¾ and a viscosity of 230 centipoise. The resulting resin solution is added to --------------------------------- -^ I (Please read the precautions on the back before filling in this page) This paper is printed in China National Standard (CNS) A4 (210X297mm) A7 B7 Printed by the Central Labor Bureau of the Ministry of Economic Affairs V. Description of the invention (33) 1 1 The colorant prepared in Reference Example 11 * The resin solid content to pigment ratio is 0.5 to 1 1 100 〇1 1 Implementation Jin Please 1 first 1 in Reference Example 2 The resulting resin aqueous solution (I ) Inside »Add Reference Example 5 to the obtained Wen 1 polyaqueous amine aqueous solution &gt; Polyamide is the most resin (Π) solid content of 5¾ 〇 back it 1 | The obtained solution M sulfuric acid adjustment Section to PH7. 2 9 Add water to obtain a resin containing polyamidoamine. Note 1 I liquid, 50 degrees * viscosity 167 centipoise. The resulting resin solution is added to the reference item 1 again 1 Examination example 1 1 The colorant prepared * resin The ratio of the solid content to the pigment is 0.5 to 1 0 0 °. The book is written and dismissed. Page 27 | In Reference Example 3, the obtained resin aqueous solution (1) &gt; Add Reference Example 5 to the obtained 1 1 poly_amine aqueous solution polyacetamide The amount is 20¾ 1 of the solid content of the resin (I). The resulting solution is adjusted to P Η 6 with sulfuric acid. 9 9 Add water to obtain a polyamide-containing resin 1 Order solution »Concentration 60%» Viscosity 33 1 centipoise The resulting resin solution is added to 1 Reference Example 1 1 The colorant produced »The ratio of resin solid content to pigment is 0.5 to 1 I 100 0 1 Implementation 1 1 In the resin aqueous solution (m) obtained in Reference Example 3, add the polyproduce produced in Reference Example 4 Amine water Solution> The amount of polyamide is 50% of the solid content of the resin (I) 1 1 The resulting solution M sulfuric acid is adjusted to PH6. 8 »Add water to obtain a polyamide-containing resin 1 1 solution» Concentration 60¾ f Viscosity 342 centipoise obtained The resin solution was added to 1 I. Reference Example 1 1. The colorant prepared by the ratio of 1 »The resin solid content to the pigment ratio was 0.5 to 1 100 〇1 Actual 1 1 to the resin aqueous solution (I) obtained in Reference Example 3 9 Add Reference Example 6 Result 1 1 1 -35- 1 1 1 The size of this paper is far from China National Standard (CNS) A4 (2 丨 0X297mm) at B7 Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of Invention (34 ) 1 1 Aqueous solution of polyamidoamine * The amount of polyamidoamine is 20% of the solid content of the resin (η) 1 1 The resulting solution K acid is adjusted to PH7. 2 9 Add water to obtain the resin containing polyamidoamine 1 1 Solution »Concentration 6 0S; 9 viscosity 346 centipoise. The resulting resin solution is added to 1 First 1 Reference Example 1 1 The colorant obtained »The resin solid content to the pigment ratio is 0.5. The ratio is 0. Read the back S} 1 100 〇1 | Implementation JO O Note 1 1 The resin aqueous solution obtained in Reference Example 3 (I ) Within 9 plus Reference Example 7 Obtained items 1 and then 1 polym amine aqueous solution * The amount of polyamide is 20¾ of the solid content of resin (I) 4 The solution obtained from this script M is adjusted to pH 7 with sulfuric acid. 1 »Add water to obtain polyamidoamine-containing Resin page 1 I solution 9 economic degree 60 ¾, viscosity 340 centipoise 0 The resulting resin solution is added to 1 1 Reference example]] The prepared pigment> The resin solid content to pigment ratio is 0.5 to 1 100 〇1 Example—3 1 1 In the resin aqueous solution (I) obtained in Reference Example 3 * Add 1 I polyamidoamine solution obtained in Reference Example 8> Polyamide It is 20% of the solid content of the resin (I) 1 1 The resulting solution Μ Telluric acid is adjusted to pH 7. 2 Add water to obtain a polyamide-containing resin 1 1 solution * Concentration 60%> Viscosity 372 cps The resulting resin solution is added to Production of Reference Example 1 1 Colorant> The ratio of resin solid content to pigment is 0.5 to 1 1 100 〇1 1 Actual 2 1 | In the resin aqueous solution (B) obtained in Reference Example 3 »Add Reference Example 9 1 Polyamide aqueous solution> Polyamide amount is 20¾ solid content of resin (I) 1 The resulting solution sulfuric acid is adjusted to pH 6. 9 * Add water to obtain polyamide-containing resin 1 Solution 1 Concentration 60% 9 Viscosity 356 centipoise. The resulting resin solution is added to 1 1 1 -36- 1 1 1 This paper size is not printed in China National Standards (CNS) A4 specifications (210X297 mm) A7 B7 Printed by Beigong Consumer Cooperative of Central Bureau of Economic Development, Ministry of Economic Affairs Description (35) 1 1 Reference Example 11 Colorant * The ratio of resin solid content to pigment is 0. 5 to 1 1 100 〇1 I Implementation--Example _13 Please 1 I in the resin aqueous solution (I) obtained in Reference Example 3 9 plus Reference Example 10 to read 1 I read 1 I aqueous solution of polyamine 9 polyimide is the most resin (I) 20¾ solid content back A 1 1 of 1 The resulting solution K sulfuric acid is adjusted to PH7. 2 9 Add water to get the resin containing polyacetamide Note 1 | Solution * 60 ° cycle ♦ Viscosity 342 centipoise. The resulting resin solution is added to item 1 and then 1 Reference Example 11. The colorant 9 is prepared. The resin solid content to pigment ratio is 0.5. The ratio is filled in the book 1 00 〇 Page 1 I Example 1 34 1 1 Reference example 1 The obtained resin aqueous solution * and Reference example 4 The obtained polyacetamide water 1 solution * Individually added to the color material 9 prepared in Reference example 11 where Resin solution 1 1 Order 1 The weight ratio of polyacrylamide solution is 90 to 4 (M solid content is 9 5 to 5) &gt; and the total solid content of resin and polyamide to pigment ratio is 0.5 Better than 100 ° 1 I — Μ Set J 5-1 1 1 Paper coating composition made in Examples 22 to 34 »Add water and 10¾ argon oxygen 1 1 sodium hydroxide aqueous solution« Adjust to a total solids content 60¾ »pH about 9. 0 〇Physical properties of the finished product 9 measured according to the method described in Example 7> measured performance 1 1 shown in Tables 5 and 6 below 〇1 I made the composition using a gold rod 14 g / m 2 PP A--coating rate is applied 1 1 on one or both sides of fine paper with a basic weight of 80 g / m2, paper stand 1 is dried in hot air in 12010 for 30 seconds, then at 20 D, relative Humidity 65¾ 1 After conditioning moisture for 16 hours tm at 60 and a linear pressure of 60kg / cm 2 super 1 1 Calendering twice to get coated paper 〇1 1 1 -37- 1 1 1 This paper is again printed with the Chinese National Standard (CNS) A4 (210X297 mm). The A7 B7 is printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy. V. Invention Instructions (36) The water resistance and ink acceptance of the test were evaluated according to the test method described in Example 7. The results obtained are shown in Tables 5 and 6 below. ~ 3 8 * ------.-- 1U East-(Please read the precautions on the back before filling out this page) Order · This paper size is applicable to China National Standards (CNS) A4 «l grid (210X: 297 mm) A7 B7 printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (37) Xiezhi (Example No.) The composition of the paint is straight [Title 22 23 24 25 26 27 ρΗ (25Ό) 9.2 9.3 9.0 9.2 9.1 9.1 Viscosity (25D) (centipoise) Coated_cloth paper: Water resistance: 1,820 1,790 1,830 1,860 1,800 1,880 WP method ink acceptance: 4.0 4.5 4.3 4.1 4.5 4.4 Method A 3.9 4.5 4.5 4.0 4.5 4.5 Method B 3.7 4.2 4.3 4.1 4.2 4.5 -39- (please read the notes on the back first and then fill in this page) Order · The size of this paper adopts the Chinese National Standard (CNS & A4 specifications (210X297 mm) B7 V. Invention description (38 ) ^ _6_ Resin (Example No.) The paint is combined into one UL: 28 29 30 31 32 33 34 pH (25 ^) 9.1 9.1 9.0 9.2 9.2 9.1 9.3 Viscosity (25t :) (Box) Coated paper: Water resistance: 1,910 1,830 1,880 1,890 1,870 1,850 1,830 WP ink acceptance: 4.2 4.0 4.2 4.0 4.1 4.2 4.0 A 4.7 4.5 4.3 4.2 4.0 4.1 3.8 Method B 4.7 4.3 4.1 4.4 4.2 4.5 3.8 (please read "Precautions on the back side and then fill out this page") 4 ^-This paper is based on China National Standard (CNS) A4 specifications ( 210X297mm) A7 B7 printed by the Beigong Consumer Cooperative of the Central Bureau of Economic Development of the Ministry of Economic Affairs 5. Description of the invention (dipping) Contains the most pigment ratio of 0.5 to 100 to make a paper coating composition. Ratio___Comparative .. Example 1 and Reference Example 2 The resin aqueous solution obtained is added to the color material prepared in Reference Example 11 and the resin solid contains the most suitable A pigment ratio of 0.5 to 100 is used to make a paper coating composition. A comparison of 13 The aqueous resin solution obtained in Reference Example 3 is added to the color material prepared in Reference Example 11, and the resin solid contains the most pigment ratio of 0.5 to 10 0, to make a paper coating composition. TL—I use the color material made in Reference Example 11 as a paper coating formulation, without adding other compounds. It is more expensive than _Long ... 5_ .. The paper coating composition prepared in Comparative Examples 1 to 4 is added with water and 10% aqueous sodium hydroxide solution, adjusted to a total solids content of 60¾ and a pH of about 9.0. The physical properties of the resulting composition were measured as described in Example 7, and the measured properties are shown in Table 7 below. The resulting composition was applied on a single or double side of fine paper with a basic weight of up to 80 g / m2 with a single coating rate of gold wire rod M14g / m2. The paper was immediately dried in hot air at 120 ° C for 30 seconds At 20C, a relative humidity of 65¾ conditioned moisture for 16 hours, and then at 60 t: and linear pressure 60 kg / cm Super-41-This paper scale uses Chinese national standards (CNS} A4 specifications (210X297 mm) ( Please read the precautions on the back before filling out this page) 袈. Order i 30C411 A7 B7 5. Description of the invention (4〇) After calendering twice, the coated paper can be obtained. The water resistance and ink acceptance of the resulting coated paper, according to the implementation Evaluation of the test method described in Example 7. The results obtained are shown in Table 7 below. ------.-- ΊΊ 'Service ----- „-Subscribe ------ A) (Please read the back page first Please pay attention to this page.) The printed paper of the Central Standards Bureau of the Ministry of Economic Affairs is printed in Chinese. The paper size is based on the Chinese National Standard (CNS) A4 specification (2 丨 0X297mm). Fifth, the invention description (4l) resin (implementation Example No.) 1 i The sister waste treatment and treatment J4JL: pH (25¾) 9

黏度(250 (厘泊) 塗佈紙 抗水性: WP法 油學接受性 方法A 方法B A7 B7 9.2 9.0 9.1 9.3 1,820 1,860 1,770 1,650 3.5 3. 1.0 3.2 3.3 3.5 1.丨 3.1 3.0 3.5 I」 - . ^ 訂.^. _ (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局貝工消费合作社印製 _ 4 3 _ 本紙張尺度逍用中國國家椹準(CNS &gt; A4规格(210X297公釐) A7 B7 五、發明説明(42 ) 使用本發明紙塗料組成物所得塗佈紙,具有各種優異 性能,諸如油墨接受性、抗水性等。 雖然本發明已參照特定實胞例詳述,惟精於此道之士 均知,在不悖其精神及範圍,可加以各種變化和修飾。 ------.I·—·!--^ 裝-- (請先S讀背面之注意事項再填寫本頁) 訂 經濟部中央標準局員工消费合作社印製 -44- 本紙張尺度逍用中國國家揉準(CNS ) A4规格(210X297公釐)Viscosity (250 (centipoise) Water resistance of coated paper: WP method oil acceptance method A method B A7 B7 9.2 9.0 9.1 9.3 1,820 1,860 1,770 1,650 3.5 3. 1.0 3.2 3.3 3.5 1. 丨 3.1 3.0 3.5 I "-. ^ Order. ^. _ (Please read the precautions on the back before filling in this page) Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs _ 4 3 _ This paper size is free to use the Chinese National Standard (CNS &gt; A4 specifications ( 210X297mm) A7 B7 5. Description of the invention (42) The coated paper obtained by using the paper coating composition of the present invention has various excellent properties, such as ink receptivity, water resistance, etc. Although the present invention has been described in detail with reference to specific real cell examples , But those who are good at this knowledge know that, without departing from its spirit and scope, various changes and modifications can be made. ------. I · — ·!-^ Outfit-(please read the back of S first Please pay attention to this page and then fill out this page). Printed by the Ministry of Economic Affairs, Central Standards Bureau, Employee Consumer Cooperatives-44- This paper size is used in China National Standard (CNS) A4 (210X297mm)

Claims (1)

I公告本J i 申請專利範圍 ^ 第83105999號「紙塗料組 11.2 &gt; 从尤 成物」專利案 (85年11月20日修正) 巧申請專利範圍: 1. —種紙塗料組成物,包括: . (I) 100份重量顔料; (II) 5至200份重量水性粘合劑; (III) 0.05至5份重量水溶性樹脂,係由下述化合物反 應而得, (a)伸烷二胺或聚伸烷基聚胺; (b )尿素化合物,和 (c)選自醛類、表鹵醇和二鹵代一 /S -醇 ;以及 (I V ) 1至9 0重量% (對於水溶性樹脂(I I I)固體含'量而 言)選自下列之化合物: (f) 胺類,僳選自各具4値至12個碩原子之單胺、 二胺及其鹽; (g) 具有四级氮原子連接於四個烴基之化合物或 在環上具有四级氮原子之化合物,和 經濟部中央標隼局貝工消費合作社印装 (請先閲讀背面之注意事項再填寫本頁) (h) 由二元羧酸化合物和聚胺反應而得之聚醯胺 者。 2. 如申請專利範圍第1項之組成物,其中成份(III)之 水溶性樹脂係由下列化合物(a )、( b )、( c )、( d )反應 而得: -1 - 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) S024I Announcement J i Scope of Patent Application ^ No. 83105999 "Paper Coating Group 11.2 &gt; From Youchengwu" Patent Case (Amended on November 20, 1985) Patent application scope: 1.-Paper coating composition, including : (I) 100 parts by weight of pigment; (II) 5 to 200 parts by weight of water-based binder; (III) 0.05 to 5 parts by weight of water-soluble resin, obtained from the reaction of the following compounds, (a) alkylene diene Amines or polyalkylene polyamines; (b) urea compounds, and (c) selected from aldehydes, epihalohydrin, and dihalogenated mono / S-alcohols; and (IV) 1 to 90% by weight (for water-soluble The resin (III) in terms of solids content) is selected from the following compounds: (f) amines, selected from monoamines, diamines and salts thereof each having 4 to 12 atoms; (g) having four Compounds with first-grade nitrogen atoms connected to four hydrocarbon groups or compounds with fourth-order nitrogen atoms on the ring, printed with the Central Standard Falcon Bureau Beigong Consumer Cooperative of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) ) Polyamide obtained from the reaction of a dicarboxylic acid compound and a polyamine. 2. If the composition of item 1 of the patent application scope, the water-soluble resin of component (III) is obtained by the reaction of the following compounds (a), (b), (c), (d): -1-this paper Standards apply to China National Standard (CNS) A4 specification (210X297mm) S024 (a) 伸 A8 B8 C8 D8 Μ 月 11.2 0 補充 申請莩 經濟部中央標準局員工消費合作社印製 (b) 尿 (c) m 化 (d) 二 3 .如申請 元羧酸 4 .如申請 水溶性 而得: (a )伸 (b) 尿 (c) 選 化 (e.)選 環 5 .如申請 水溶性 (e) 反 (a) 伸 (b) 尿 (c) 選 化 烷二胺或聚伸烷基聚胺; 素化合物,和 自醛類、表鹵醇和α,7 -二鹵代—yS -醇之 合物;以及 元羧酸化合物。 專利範圍第2項之組成物,其中成份(d)之二 化合物為游離酸、酯或酸酐者。 專利範圍第1項之組成物,其中成份(III)之 樹脂傺由下列化合物U)、(b)、(c)、(e)反應 烷二胺或聚伸烷基聚胺; 素化合物, 自醛類、表鹵醇和0(,7 合物;以及 自具有至少一活性氫原子之脂環族胺和脂環族 氣化合物之脂環族化合物。 專利範圍第1項之組成物 樹脂俗由下列化合物(a)、 應而得: 烷二胺或聚伸烷基聚胺; 素化合物, 二鹵代- /3-醇之 其中成份(II I)之(b)、 (c)、 (d)、 (請先閲讀背面之注意事項再填寫本頁) 自醛類、表鹵醇和 合物; -二鹵代-/3 -醇之 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 备告本 中餘專繼獨· (d) (e) 6 .如申 (f ) 7 ·如申 個碩 8 .如申 (g) 上具 9 .如申 値或 子, 1 0 .如 —個 二元錢 選自具 族環氣 請專利 胺者。 諳專利 原子。 請專利 具有四 有四级 請專利 二個四 有二個 申請專 四级銨 A8 B8 C8 D8 Η 3縣平Λ afen. 2 Ο 經濟部中央標準局員工消費合作社印装 於四级氡原 11 .如申請專 為(h)聚醯 得者。 12 .如申請專 俗由二元羧 1 3 .如申請專 傷由脂環族 酸化合物,以及 有至少一活性氫原子之脂環族胺,及脂環 化合物之脂環族化合物。 範圍第1項之組成物,其中化合物(IV)為 範圍第6項之組成物,其中(f)胺有5至12 範圍第1項之組成物,其中化合物(IV)為 级氮原子連接於四個烴基之化合物或在環 氡原子之化合物。 範圍第8項之組成物,其中成份(g)為一 级较鹽,其中有四値烴基連接於四级氮原 至四個基團彼此獨立為(^ -C3烷基者。 利範圍第9項之組成物,其中成份(g)為 鹽,其中有三個甲棊和-*C8 _(:12烷基連接 子者。 利範圍第1項之組成物,其中化合物(IV ) 胺,係可藉二元羧酸化合物與聚胺反應而 利範圍第11項之組成物,其中(h)聚醯胺 酸化合物與脂環族二胺反應而得者。 利範圍第11項之組成物,其中(h)聚醯胺 二元羧酸化合物與聚胺反應而得者。 本紙張尺度適用中國國家標準(CNS } Μ規格(210X297公釐) (請先閲讀背面之注意事項再填寫本頁) 、罗(a) Extension A8 B8 C8 D8 Μ Month 11.2 0 Supplementary application Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (b) Urine (c) mization (d) II 3. If applying for monocarboxylic acid 4. If applying for water dissolution Sexually derived: (a) Stretch (b) Urine (c) Electrification (e.) Ring selection 5. If you apply for water-soluble (e) reverse (a) Stretch (b) Urine (c) Elective alkyldiamine or Polyalkylene polyamines; element compounds, and compounds from aldehydes, epihalohydrin, and α, 7-dihalo-yS-alcohols; and monocarboxylic acid compounds. The composition of item 2 of the patent scope, in which the compound of component (d) is free acid, ester or anhydride. The composition of item 1 of the patent scope, wherein the resin of component (III) is composed of the following compounds U), (b), (c), (e) reacted alkyldiamine or polyalkylene polyamine; Aldehydes, epihalohydrins, and 0 (, 7 compounds; and alicyclic compounds from alicyclic amines and alicyclic gas compounds having at least one active hydrogen atom. The composition of the patent scope item 1 resins consists of the following Compound (a), should be obtained: Alkyldiamine or polyalkylene polyamine; element compound, dihalo- / 3-alcohol (b), (c), (d) , (Please read the precautions on the back before filling in this page) Self-aldehydes, epihalohydrin compounds; -dihalo- / 3 -alcohol The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm ) Remarks in this Yu Yu Ji Ji independence (d) (e) 6. Such as Shen (f) 7 · such as Shen Geshu 8. Such as Shen (g) with 9. If Shen Yu or son, 1 0. Such -A binary money is selected from those who have patented amines with a family of ring gases. They are familiar with patented atoms. Patents have four or four levels, please patent two or four and apply for four-level ammonium A8 B8 C8 D8 Η 3 county level Λ afen. 2 Ο The employee consumption cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs is printed on the fourth-level radon original 11. If the application is designed for (h) poly-acquisition winners. 12. If the application is customary, the binary carboxyl 1 3. If the application specifically covers an alicyclic acid compound, an alicyclic amine having at least one active hydrogen atom, and an alicyclic compound of an alicyclic compound. The composition of scope item 1, wherein compound (IV) is the scope of The composition of item 6, wherein (f) the amine has the composition of item 1 in the range of 5 to 12, wherein the compound (IV) is a compound in which a graded nitrogen atom is connected to four hydrocarbon groups or a compound in a ring radon atom. Scope item 8 The composition of the item, wherein the component (g) is a first-level salt, in which a four-valued hydrocarbon group is connected to the fourth-order nitrogen source to four groups independently of each other (^ -C3 alkyl group. Substances, in which the component (g) is a salt, in which there are three formaldehyde and-* C8 _ (: 12 alkyl linker. The composition of the first item of interest scope, in which the compound (IV) amine can be borrowed binary The carboxylic acid compound reacts with the polyamine to obtain the composition of item 11 of the scope, wherein (h) the polyamic acid compound It is obtained by reacting with alicyclic diamine. The composition of item 11 of the profit range, wherein (h) is obtained by reacting polyamide dicarboxylic acid compound with polyamine. This paper scale is applicable to China National Standard (CNS}) Μ specification (210X297mm) (please read the precautions on the back before filling this page), Luo 14.如申請專利範圍第11項之組成物,其中(h)聚.醒胺 俗由芳香族二元羧酸化合物與聚胺反應而得者。 15. 如申請專利範圍第11項之組成物,其中(h)聚醯胺 像由4至12個碩原子的脂肪族二元羧酸化合物與聚胺反 應而得者。 16. 如申請專利範圍第11項之組成物,其中供獲得(h) 聚醯胺所用之二元羧酸化合物為游離酸、酯或酸酐者 &gt; ' 〇 ❼ 17. 如申請專利範圍第1項之組成物,其中化合物(IV) 存在量為水溶性樹脂(III)固體含量之3至80X重量者 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印聚 -4- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐)14. The composition as claimed in item 11 of the patent scope, in which (h) polyamine is obtained from the reaction of an aromatic dicarboxylic acid compound with a polyamine. 15. The composition as claimed in item 11 of the patent application, in which (h) polyamide is obtained by reacting an aliphatic dicarboxylic acid compound with 4 to 12 atoms with a polyamine. 16. The composition according to item 11 of the patent application scope, wherein the dicarboxylic acid compound used for obtaining (h) polyamide is a free acid, ester or anhydride> '〇❼ 17. If the patent application scope is 1st The composition of the item, in which the compound (IV) is present in the amount of 3 to 80X weight of the solid content of the water-soluble resin (III) (please read the precautions on the back before filling out this page) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy -4- This paper scale is applicable to China National Standard (CNS) A4 specification (210X297mm)
TW83105999A 1993-07-16 1994-07-01 TW302411B (en)

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