TW302411B - - Google Patents

Description

3〇24U B7 Printed by Beigong Consumer Cooperative of Central Bureau of Standards, Ministry of Economy V. Description of invention (1) 1 1 The present invention relates to a paper coating composition, especially a composition > 1 1 can give excellent print quality to paper And outstanding printing results 〇1 I used here "Paper J broadly covers and includes paper N in a narrow sense and paper please 1 first 1 board 〇 I I read 1 | Apply paper coatings mainly composed of pigments and water-based binders on paper The back side 1 I's finished product and then the necessary steps m such as the coated paper obtained by drying and calendering 9 Note 1 1 has been widely used in commercial prints, magazines, books, etc. due to excellent printing matters 1 re 1 effect and other properties 0 Zhu Yue gradually needs higher quality and develops high-speed printing%. Steps to improve the quality of coated paper. Especially page 1 1 In the lithography industry that dominates various printing technologies, the water wetting effect is taken into account 1 1 Λ Water resistance such as moisture absorption and improvement of anti-foaming performance on the rotary machine 1 Ink Acceptability is an important issue. 〇1 1 To solve the above problems, it is usually to add a wet strengthening 1T 1 agent or a printing quality improver to the paper coating composition including melamine-formaldehyde resin'urea-formaldehyde tree 1 I fat> or polyacrylic See, for example, JP-B-69 -11667 1 1 and JP-B-84- 3 2 5 97 (JP-B refers to Japanese Patent Application for Examination Announcement) ° 1 1 although these are known Wet enhancer or printing quality improver $ shows effective features but still has serious defects or deficiencies in some of the required features f 1 1 can not always meet the practical 0 1 | For example f-based plastic resins such as melamine-formaldehyde resin and urea -Formaldehyde 1 I Resin not only causes the release of formaldehyde on the coating line or white coated paper, but also has no effect on improving the ink acceptance and anti-foaming performance. 1 In addition, when the pH of the coating composition increases » Amino-based plastic resin's 1 I water-improving effect is less significant. Polyamide polyurea-formaldehyde resin can be 1 1 1 -3-1 1 1 The paper size can be used in China National Standard (CNS) A4 specifications (210X297mm) A7 B7 printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (2) The improvement of the effect is not only waterproof, but also ink acceptance and anti-foaming performance. However, the degree of improvement available from this does not necessarily fully meet the recent need for higher-grade coated paper. Therefore, work hard for further improvement. For example, JP-A-92-100997 and JP-A-92-263696 propose improvements (JP-A refers to the Japanese patent application for non-examination announcement). However, there is still a need to further improve performance, and the growing demand for coated paper quality. The purpose of the present invention is to provide a paper coating composition that can provide high quality to coated paper as required, such as higher water resistance, ink receptivity, etc. than those obtained by conventional techniques. After intensive studies, the present inventors have found that a paper coating composition containing a special compound exhibits excellent performance, and thus completed the present invention. The invention provides a paper coating composition comprising: (I) pigment; (Π) water-based adhesive; (I) water-soluble resin, which is made by reacting at least the following components: (a) alkylene diamine or polyalkylene Based polyamines; (b > urea compounds, and (c) compounds selected from aldehydes, epihalogenase and α, 7-dihalo-3- / 3-enzymes; M and (IV) selected from the following compounds: (h) amines, selected from monoamines on C4 or M, diamines on C4 or M, and their salts, (g) quaternary ammonium salts, and (h) obtained from the reaction of dicarboxylic acids and polyamines Polyamide. -4- The size of this paper is compliant with the Chinese National Standard (CNS > A4 specification (210X297mm) ^ · — (Binding 8 (please read the precautions on the back and fill in this page) Central Ministry of Economic Affairs Printed A7 B7 by the Zongong Consumer Cooperative Cooperative. V. Description of the invention (3) According to the present invention, the water-soluble resin (I) can be made by reacting (a) (bXc) with one or more additional compounds. Additional compounds include, for example ( d) Dicarboxylic acid compounds and (e) cycloaliphatic compounds, such as cycloaliphatic amines having at least one active hydrogen, or cycloaliphatic epoxy compounds. As follows: 1 Can be used as the pigment of component (I) of the present invention, which is commonly used in paper coating. Examples of pigments include white inorganic pigments such as kaolin, talc, carbonic acid consumption (grinding or precipitation), aluminum hydroxide, satin White, titanium oxide, etc .; M and white organic synthetic pigments, such as polystyrene, melamine-formaldehyde resin, urea-formaldehyde resin, etc. Can be used alone or in combination of two or M. Organic or inorganic coloring pigments are also available Combined use. The present invention can be used as an aqueous binder of component (I), which is commonly used in paper coating. Examples of pigments include water-soluble binders and aqueous emulsion-type binders. Water-soluble binders include unmodified or modified Quality starch, such as oxidized starch and phosphate esterified starch, polyvinyl yeast, water-soluble protein, such as prion protein and gelatin, M and modified cellulose, such as carboxymethyl levulin. Aqueous emulsion-type adhesive Examples include styrene-butadiene type resin, vinyl acetate type resin, ethylene-vinyl acetate resin, K and methyl methacrylate resin. These water-based adhesives can be used alone, or two or more types can be used The water-soluble resin (Π) in the present invention is composed of at least (a) alkylene diamine or polyalkylene polyamine, (b) urea compound, and (c) selected from the group consisting of aldehydes, epihalogen and alpha , 7-dihalo- / 3-alcohol compound is made by reaction. Water-soluble resin (B) one of the raw materials (a) alkylene diamine or polyalkylene-5- This paper scale is used in Chinese national frame Standard (CNS) A4 specification (210X297mm) --------- (installed-(please read the precautions on the back before filling in this page) Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 5. Description of invention (4) Examples of polyamines, including aliphatic diamines, such as ethylenediamine, propylenediamine, 1,3-propanediamine, and hexamethylenediamine; polyalkylene The base polyamines are, for example, diethylenetriamine, triethylenetetramine, tetraethylenepentamine, iminobispropylenediamine, 3-nitrogen-1,6-diamine and 4,7-diazo Heterodec-1,10-diamine. From an industrial point of view, among them, M diethylenetriamine and triethylenetetramine are preferred. These alkylene diamines and polyalkylene polyamines U) can be used alone or in combination of two or more. It is also an example of a urea compound (b) as a raw material of a water-soluble resin (M) used in the present invention, and includes urea, thiourea, guanidine urea, methylurea, dimethylurea, and the like. From industrial regulations, K urea is better. These urea compounds (I) may be used alone or in combination of two or more. The water-soluble resin (M) used in the present invention is used as the aldehyde of the raw material (c), for example, formaldehyde; alkyl aldehydes such as acetaldehyde and propionaldehyde; glyoxal; M and alkyl dialdehydes such as malondialdehyde and Succinaldehyde. From an industrial point of view, formaldehyde and glyoxal are preferred. These aldehydes can be used alone or in combination of two or more. The water-soluble resin (Μ) used in the present invention is used as the raw material (c) for the surface halogen fermentation, which can be expressed by the following formula:

CH2 -CH (CH2) w X \ / 0 where X represents a halogen atom and V »represents 1, 2 or 3. Preferred examples of epihalohydrin include epichlorohydrin and epibromohydrin. The water-soluble resin (H) used in the present invention is used as the raw material for α-dihalo- / 3-fermentation, which can be expressed by the following formula: -6-The paper size is in the state of the Central Government (CNS) A4 specification (210Χ297 Mm) ------;-, 丨 {install ----- 1--order -------- ^ I (please read the precautions on the back before filling this page) A7 B7 Ministry of Economic Affairs Printed by Beigong Consumer Cooperative of Central Bureau of Standards 5. Description of invention (5) 1 1 CH I 2 -Υ 1 1 1 CH 1 2 -0Η 1 1 1 CH 2 -Z η 1 1 1 where Y and 1 each independently represent halogen Atom 0 α * 7-dihalo-β-yeast 1 The preferred examples include 1, 3-. Chloro-2 -propanase Ί back 1 1 such epihalohydrin and α f-dihalo-β-yeast &gt; Can be used alone 9 Also note 1 | Can be used in combination of two or more. Item 1 can be used to prepare the water-soluble resin (I) aldehyde epihalohydrin and α f-dihalogenated landfill Packed-β-fermentation> Can be used alone> It can also be used in combination of two or M. For example »Page 1 I Can use both aldehyde and epihalogenase while aldehyde and α, 7-dihalo-β-alcohol Also 1 1 can be used at the same time. 〇1 Water-soluble resin (I) is composed of at least (a) Extrude diamine and polyextrin-based poly1 amidine »(b) Urea compound y and (C) White selection contains aldehydes 9 Epihalohydrin reacted with 1 α t -dihalo-β -enzyme to make water-soluble resin (I) can be made by the reaction of 1 I (a) (b) (C) and one or more additional compounds. 1 1 Preferred examples of the compound include (d) a dicarboxylic acid compound * and (e) an alicyclic 11 compound »such as an alicyclic amine * having at least one active hydrogen * or an alicyclic 1 epoxy compound. 1 1 Dicarboxylic acid compound id) is a compound t having a dicarboxyl group or its derivative 1 1 Biological 0 Dicarboxylic acid compound (d) Not only its free acid can be used »1 1 its ester anhydride and other 〇 dicarboxylic acid compound (d) can be aliphatic aromatic 1 U. Or alicyclic compound 〇 dicarboxylic acid compound (d) Example 9 with fat Group 2 1 carboxylic acids • such as succinic acid> glutaric acid adipic acid sebacic acid, maleic acid 1 fumaric acid linoleic acid and other dimer acids; aromatic dicarboxylic acids 9 such as stupid 1 1 1- 7-1 1 1 This paper scale is printed in Chinese National Standard (CNS &gt; A4 size (210X297mm) A7 B7 Printed by Beigong Consumer Cooperative of the Central Standardization Bureau of the Ministry of Economy V. Invention Instructions (6) 1 1 Formic acid • V Isophthalic terephthalic acid, etc.> M and cycloaliphatic dicarboxylic acid 1 1 9 such as tetrahydroterephthalic acid V. Hydrogen terephthalic acid cyclohexane-1,3 1 1 -dicarboxylic acid , Cyclohexane-1, 4--carboxylic acid cyclopentanedicarboxylic acid 3-methyl please 1 first 1 tetrahydroterephthalic acid 4-methyl tetra Hydrogen terephthalic acid 3-methylhydrogen 1 terephthalic acid 4-methyl-hydroterephthalic acid, etc. backside 1 1 ester of dicarboxylic acid (d) »There is, for example, a single with lower alcohol Esters and diesters> Note 1 I and polyesters with glyphosate matters 1 and then 1 If the dicarboxylic acid compound (d) is a lipid rw cyclic compound> Usually use this package C 4 to about C 96 The compound 〇 used as (d) the alicyclic compound has a page 'w »1 1 saturated 鐽 0 in the present invention * If the position f of the unsaturated bond is not mentioned, then 1 1 alicyclic compound is included in any Compound with unsaturated bond at position 〇1 \ If the dicarboxylic acid compound (d) is an alicyclic compound &gt; its anhydride can also be used better than 1 〇Anhydride example contains tetrahydronhydride 9 • Hydrogen m anhydride »3 -Methyltetrahydrom 1 anhydride> 4- A基 .Tetrahydrophthalic anhydride 9 3 -methylhydrogen Sfe anhydride y 4-methyl-hydrogen m 1 I anhydride etc. 〇1 1 1 If the dicarboxylic acid compound (d) is an alicyclic compound »it is best to use 1 1 Polyester with a dicarboxylic acid group * such as the reaction product of a dicarboxylic acid and glyphosate I. The best polyester is an example with a carbamate carboxylic acid group. The glyoxylate contains alkane 1 1 diol t Such as ethylene glycol malonase and succinase &gt; cyclic two enzymes &gt; such as 1 1 cyclopentane and cyclohexane two enzymes »adipic enzyme 9 such as butene two enzymes and octene 1 | yeast &gt; poly Two enzymes V such as diethylene glycol Λ dipropylene zymase diethylene glycol Λ Υ Polyethylene glycol and polysuccinyl diphenol A and ethylene oxide addition compound 1 Hydrogenated biphenol A and ethylene oxide burning Addition compound 〇Polyester with a carboxylic acid group at the molecular terminal 1> It can be obtained by reacting -8 carboxylic acid with ethyl yeast> 1 1 1 1 1 1 paper Also used the Chinese National Standard (CNS &gt; A4 specification (210X29 * 7mm) A7 B7 Printed by the Ministry of Economic Affairs, Central Bureau of Economic Development, Zhengong Consumer Cooperative Co., Ltd. 5. Description of invention (7) 1 1 Use excess carboxyl Acid 0 Dicarboxylic acid compound (d) Can be used alone 1 1 * It can also be used in combination of two or M Ο 1 1 Alicyclic amines with at least one active argon 9 Usually a fat with c &amp;-C 12 please first 1 Cyclic ring »Μ Cyclohexane ring is preferred and has at least-* primary amine or amine extension ° 闻 it 1 The amine group can be directly or through a linking group such as support» Embed in the alicyclic ring,. Examples of alicyclic amines with 1 I on the back have at least ___. Active hydrogen atoms * Contains cyclohexylamine, diattention 1 I Cyclohexylamine 1, 3-diaminocyclohexylamine, 1, 4-diamine Cyclohexane 4,4 'Matter 1 Re 1 -Diamino-3,3'-Dimethyldicyclohexylmethane, 4,4' · Diamino-3,3'4 Nest Pack-Dimethyl 1,2-bis (aminomethyl) ring page 1 I hexane 1,2-bis (aminomethyl) cyclohexylamine 1,4-bis (aminomethyl) ring Hexane 1 1, N-aminopropylcyclohexylamine ·, 1,5-bis (aminoethyl) octahydro-4,7-methylidene 1 \ indene% 2, 6-bis (aminoethyl) octahydrogen -4,7-methylene indene, 2,2-bis (4-amine ring 1 hexanyl) propane, bis (4-aminoxenyl) methane '4,4 1 monooxobis (cyclohexyl 1 amine) 4, 4 »_ Nitrobis (cyclohexylamine), 1, 3, 5 -triaminocyclohexane 1 I, 2, 4 '-diamino-3, 3', 5, 5? — Tetramethyl Radical τη Cyclohexyl methane, 4,4 '1 1 -diamino- 3, 3', 5, 5 »_ tetramethyldicyclohexylmethane, and methylenediamine 1 1 〇 cycloaliphatic amine can be used alone 9 can also Two or more of them are used in combination 0 | The alicyclic epoxy compound 9 used as (e) is usually a compound having a C 4-C 12 1 1 alicyclic ring &gt; preferably a cyclohexane ring &gt; Or an indirect 1 I epoxy group attached to an alicyclic ring. The alicyclic epoxy compound contains cyclohexyl 1 I alkene oxide \ vinylcyclohexene oxide> bis (3,4-epoxycyclohexyl) 1 Ί Adipic acid ester 3, 4-epoxycyclohexane carboxylate 3- (3,4-epoxycyclohexyl 1 yl) ~ 8, 9-epoxy-2,4-dioxaspiro [5, 5] Eleventh house diglycidyl, 1 hydrogen m acid ester 2, 2, bis (4-glycidol oxidized cyclohexyl) -9-propane, etc. 1 1 1 1 1 1 This paper scale is applicable to the Chinese National Standard (CNS) A4 (2 丨 0X297mm) A7 B7 Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Invention Instructions (8) 1 1 Alicyclic Group rw oxygen compounds can be used alone »Two or more kinds can be used together 〇1 1 _ Cyclic amines and alicyclic epoxy compounds can be used in combination 〇1 1 m soluble compound (HI) One of the preferred examples» is (a) Dialkylene diamine or please 1 first 1 polyalkylene polyamine 9 (b) Urea compound> (C) White selection contains aldehydes Λ See 1 Table of halogen fermentation and α —. Halogen-β-fermentation Compounds &gt; If necessary, add the back Λ 1 | (e). The selection contains aliphatic amine M with at least-active hydrogen and lipid XB9. Note on the family 1 I. Cycloaliphatic compounds such as epoxy compounds 9 are obtained by reaction 〇 Matter 1 Re 1 After obtaining the above alkali-soluble compound In the reaction of (Ε) &gt; (a) (b) and (C)% of the actual installation &gt; or (a) (b) (C) and (e) the reaction order is irrelevant &gt; can be explained on the reverse page 1 | One of the application methods is as follows: 1 diamine or polyextenyl polyamine (a) and urea compound (b) * After 1 \ deamination reaction (referred to as reaction under M), followed by selection of aldehyde-containing epihalogenase 1 With α f-dihalo-β-alcohol (C) compound reaction (reaction 1 after 1 reaction is called reaction 2) &gt; if the reaction material also uses alicyclic compound 1 I (e) when 9 in Reaction 1 and / or anti-a * Mt should be 2 when »One or more types of 1 1 (e) can be made to react with other raw materials * ie (a) (b) or (C) 〇1 1 at the time of anti-wish 1 &gt; Add urea compounds (b) 9 and (a) at the same time to anti-I Bter 懕 0. Two-step reaction f can be used. First add one part. The reaction of (b) 9 and (a) 1 1 »Add the rest (b) 9 to remove Ammonia reaction 0 If in reaction 2 If 1 1 is aldehyde as (C) &gt; then it is better to carry out the reaction under acidic conditions. 9 It can also be reacted under 1 I basic conditions and then under acidic conditions. If reaction 2 I Ί is using epihalogen Enzyme and / or α f -dihalo-β -enzyme as (c) &gt; 1 is most likely to react under weakly acidic or test conditions> eg PH5 or Μ 1 I * and Μ PH6- 9 Better 〇 1 1 1 -1 0- 1 1 1 This paper is again suitable for China National Standard (CNS & A4 specifications (210X297 mm) A7 B7 Printed by Beigong Consumer Cooperative, Central Bureau of Standards, Ministry of Economy V. Inventions Explanation (9! 1 1 These reactions can be carried out in a known manner. For example 9 The reaction using (a) (b) (c) 1 1 as a raw material has been contained in JP-A-92-100997 • except (a)) (b) (C) In addition to 1 1, the reaction using (e) as a raw material t is known from JP-A-92-263696 and 1 is first described in 1 JP-A-92-333697. Hong I 1 I 鹸 soluble compound (I) another--the preferred specific example, is U) alkylene diback 1 1 amine or polyalkylene polyamine 9 (b) urea compound (C) selected white contains aldehyde Note 1 IV Compound of epihalogenase and α 1 -dihalo-β-enzyme> (d) Binary carboxyl matters 1 and 1 acid compound> Add (e) alicyclic compound if necessary Install at least-active hydrogen cycloaliphatic amines »M and cycloaliphatic epoxy compounds» Add page 1 I to obtain 〇1 1 in the reaction to obtain the above alkali-soluble compound (I) in the anti-condensate> (a) The order of the reaction between ⑷ 1 \ or (e) is irrelevant. Here is one of the reaction methods. Example 1 Order as follows: 1 order (a) alkylene diamine or polyalkylene polyamine »(b) urea compound and 1 I ( d) Dicarboxylic acid compound ， After deamination reaction and dehydration (K is referred to as reaction 3) 1 1 t produces poly sulfonamide poly P »followed by (C) selection contains aldehydes> epihalohydrin 1 1 and α f-dihalo-β -Alcohol compound reaction (reaction I after reaction 3 Μ should be called reaction 4) &gt; If (e) alicyclic compound is also used as reaction raw material, 1 1 can be used in reaction 3 and / or reaction 4 One or more (e) reacts with other raw materials such as 1 1 (a) (b) (c) 〇1 I Reaction 3 Some of the ways of proceeding are as follows: 1 Ί Add urea compound once (b) Perform the reaction 〇1 Optional addition part (b) Carry out the deamination reaction 9 and then add the rest (b) 9 and then proceed to the 1 1 deamination reaction. Ο 1 1 1 -1 1-1 1 1 The paper size is in accordance with the Chinese National Standard (CNS> A4 specifications ( 210X297mm) 5. Description of the invention (10) Dehydration reaction is carried out between (a) and (d), followed by deamination reaction with (b). Part (b) undergoes a deamination reaction with U), and the resulting compound undergoes a dehydration reaction with (d), followed by a dehydration reaction with the remaining (b). (a) (b) and part (b) are dehydrated and deaminated at the same time, and then deaminated with the rest (b). If aldehyde is used as (c) in reaction 4, it should be carried out under acidic conditions, or it may be carried out under alkaline conditions first, and then under acidic conditions. If epihalogenase and / or α, 7-dihalo- / 3-enzyme is used as (c) in reaction 4, it is advisable to carry out the reaction under weakly acidic or basic conditions, such as pH 5 or Μ, ΗρΗ6- 9 is better. These reactions can be carried out in a known manner. For example, the reaction using (a) (b) (c) (d) as a raw material has been contained in JP-A- 80-3 1 8 37, JP-A-82- 1 6 7 3 1 5, JP-A -87-1 04995, JP-A-87-1 25092, JP-A-87-12 5 093, etc., except for (3) (1)) ((:) (0), for use (as raw materials Reaction, see JP-A-90-216297 and JP-A-90-221498. The paper coating composition of the present invention includes (IV), water-based binder (I) and water-soluble resin (H) in addition to (IV) ) Compounds, selected from the group consisting of (h) Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) Amine, selected from the group consisting of monoamines with C4 or Μ Or diamines on M, and their salts, (g) quaternary ammonium salts, polyglycosamines obtained by reacting M and dicarboxylic acids with polyamines. Amine (h) is selected from the group consisting of C4 or M Monoamines and diamines and their salts. Among them, amines on M (: 5 or M are preferred. (H) Primary, secondary and tertiary amines can be used. Regardless of aliphatic, aromatic, cycloaliphatic and ophthalmic types Any amine can be used. -12- This paper uses the Chinese National Standard (CNS) A4 (210X297mm) A7 B7 Central Ministry of Economic Affairs Printed by the Quasi-Bureau of Consumer Labor Cooperatives 5. Description of the invention (11 1 1 Examples of primary amines include aliphatic monoamines * such as butylamine amylamine \ hexylamine octylamine 1 1 amine isobutylamine 2-ethylhexylamine, etc. * alicyclic Group monoamines, such as cyclohexylamine 1 1 Λ amine methylcyclohexylamine, etc .; and aromatic monoamines> such as stupid amine, toluene please 1 first 1 amine benzylamine, aminoamine phenol, etc. 〇Read I 1 I Examples of amine stretches include monoamines having aliphatic &gt; aromatic or cycloaliphatic groups &gt; M on the back side 1 I and monoamines such as dipropylamine dicyclohexylamine, N-methylcyclohexyl Note 1 I Amine H-Methylaniline, pyrrolidine piperidine, etc. Item 1 V Re 1 Tertiary amines Examples include monoamines with aliphatic, aromatic or alicyclic groups 1 Original M and cyclic monoamines 9 such as triethylamine Dibutylamine Λ Ν, Ν- Methyl n-Prop1 | Amines, Η, Ν-dimethyl rga, Hexamines Η, Η-dimethylaniline, pyridine, etc. 〇1 1 Diamine contains a compound with a diprimary amine group> has a secondary amine Compound 1 f Compound 9 Compound 9 having a di-tertiary amine group and a compound having a diamine group having a substitution number different from each other. Preferred examples of diamines include aromatic diamine esters 1 cyclic diamines and Diamines with cyclic amino groups. Preferred diamines are, for example, lipid and aromatic amines with 1 1 diprimary amino groups 9 such as 1,3-diaminocyclohexane 1 1 isophor m diamine Λ 1. 3-bis (aminomethyl) cyclohexane, bis (4-amino 1 1 rm cyclohexyl) methane, 2,2-bis (4-amino cyclohexyl) propane, methylenediamine, I 4 , 4 '-oxobis (cyclohexylamine), 4,4 1 · Sulfobis (cyclohexylamine) phenylenediamine 1 1% Toluene diamine \ Extened xylene diamine etc. 7 Has the number of amine substitutions Compounds with different 1 1 diamino groups, such as 3-methylaminomethyl-3,5,5imethyl 1 1 cyclohexylamine &gt; 1 -methylamino-3 -aminomethyl-3, 5 , 5-trimethylcyclohexylamine 1-1 Ίaminomethyl-3 -methylaminemethylcyclohexylamine, 1-aminomethyl-3-dimethylamine methyl 1 yl m hexane> 1- Methylamine methyl-3 -dimethylamine methylcyclohexane, 4-1 1 aminopyridine, etc. &gt; Compound 9 having a secondary secondary amino group such as N, N,: A 1 1 -1 3- 1 1 1 This paper scale uses the Chinese National Standard (CNS) A4 (210X297 mm) A7 B7 Printed by the Zhengong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs V. Description of Invention (I2) 1 1 Gisophor m diamine 1, 3-bis (methylaminemethyl) cyclohexane, etc .; Μ and 1 1 compounds with di-tertiary amine groups 9 such as Ν, Ν '-tetramethylisophora di 1 1 amine 1, 3- Bis (dimethylaminomethyl) cyclohexane, etc. 0 / &quot; N Please 1 first 1 (h) The amine can be used as above Inorganic acid salts of amines and diamines and tartaric acid. 0 Reading 1 Inorganic acids are, for example, hydrochloric acid, sulfuric acid, phosphoric acid, etc. Organic acids are, for example, acetic acid 1 Backside 1 I, formic acid% oxalic acid, etc. Note 1 | These The amine can be used alone or in combination of two or more. 0 Matter 1 Re-one organic quaternary ammonium seed (g) Any compound with at least —— quaternary nitrogen can be used 0% This pack (g) Example contains ** quaternary nitrogen connection For compounds with a tetrahydrocarbyl group, on the ring page • S_> 1 1 compounds with quaternary nitrogen 〇 The number of quaternary nitrogen is not limited 9 can be used with a single quaternary nitrogen 1 1 quaternary ammonium salt> with two quaternary nitrogen quaternary ammonium salt, Μ And quaternary ammonium salts with three or M last quarter 1 nitrogen. From an economic point of view or considering feasibility &gt; M single or second quarter m 1 is better to order salt 9 especially M single quaternary ammonium salt is especially good 0 1 there is m quaternary parent salt (g) 9 of which are commonly used in single or second season Ammonium salt, having a quaternary nitrogen 1 I connected to a tetrahydrocarbyl group> wherein at least the dihydrocarbyl group is C 2 -C 3 alkyl 1 1 or alkylene 〇1 1 Μ single quaternary ammonium salt and is connected to all the tetrahydrocarbyl groups of the quaternary nitrogen , 1 can be C 1 -C 3 alkyl <, four hydrocarbon groups can also have two or three Ci ~ C 4 courtyard groups 1 1 9 The remaining one or two are hydrocarbon groups with more carbon atoms 〇1 1 Μ The second quaternary m salt and 9 is connected to the base of the second quaternary nitrogen (hereinafter referred to as the linking group) 1 | The number of carbon atoms is not limited »and the linking group may include an alicyclic or aromatic 1 Ί group. If the linking group is C 1- C ;; alkylene, the hydrocarbon group connected to the quaternary nitrogen instead of 1 group is not limited &gt; only at least one CC Ξ; alkyl is connected to each 1 quaternary nitrogen. If the linking group is C 1 C = &gt; alkylene , Then it is connected to quaternary nitrogen instead of 1 1 1 -1 4- 1 1 1 This paper size is applicable to China National Standard (CNS) A4 specification (210X297mm) V. Description of the invention (13) Printed by the Ministry of Economic Affairs, Central Bureau of Customs, Shellfish Consumer Cooperation. The base of the base is quaternary ammonium, quaternary ammonium, ammonium, ammonium, ammonium, ammonium, ammonium, ammonium, ammonium, ammonium, ammonium, ammonium, ammonium, ammonium, ammonium. The organic acid can be separated from the chlorine by three chemical conversions, each of which is buried in the atmosphere and S '0 0 M? »^ Blt * MM ^ _Ms« The number is connected to the nitrogen S group or, the acid precursor is M, s基基 合 合 »ί Bian, son 0 |. | __ son son ethyl carbon three bases, methyl methylated benzyl nitrogen &quot; Lian Jiyuan ② number. For example, polymethyl ammonium trimethyl trimethyl quaternary carbon si proton root bromide is much more than the original trichemical base-based second agent methyl dichloride. It has more original acid and has a base lipids. The alkyl dibasic group has a harder hexastearyl alkane than the T ^ M carbon carbocyclic ring. For the connection 3, there are CU, multi-family, non-ionized, containing chemical base A, ten hard surface fat, etc. ϋ1_member is more fragrant as chloride. The chlorhexidine-containing triammonium and the second hard decalammonium are combined as clt. There are aromatic acids such as acid, etc., and the base is torus-based ammonium, sub-, and chemical. Ammonium chlorinated ammonium ion ammonium chloride ^ 3 «for the neutron has a diammonium ion group with a salt ionization cationization group, 3 ^ 6! C3, salt or ion. The root is based on the benzyl chloride family of benzyl chloride, the lower C3 but the lower 1-ammonium anion and other acid quaternary chloropropyl 2-trimethyl aryl group in the M1-, 01 to the root of the grass Monoalkenyl group, benzyl benzyl benzyl benzyl group C1 made of non-bicyclic hydrochloric acid, using dimethyl fatty acid as the base bismuth salt compared with cinnyl two W unrestricted group one or lipid ammonium roots as triester The lipid base is called methylethylammonium diyl acceptor base, and the quaternary acid-free bases are the atmosphere, and the hard alkyl is often a dioxane. The upper family form of the tongjiji monoyl linker, the acidic lanthanum ring-like methyl laurel and the cinnamon brown are in contact with hydrocarbons. Carboxylic acid methylammonium, one to three gas month, two month to month hard (please read the precautions on the back and then fill out this page) The paper size is based on the Chinese National Standard (CNS) A4 specification (210X297 mm) A7 B7 economy The Central Bureau of Standards of the Ministry prints for the industrial and consumer cooperatives 5. Description of invention (W) 1 1 The di- or tri-hydrocarbon groups in nitrogen are C 1 C 3 alkyl groups, and the remaining-or 2 are 1 1 C 3-C 24 aliphatic Or aromatic hydrocarbon group> 1 1 The aliphatic hydrocarbon group contains a halogenated group, alkenyl group, cyclic alkyl group, etc. ○ Aromatic please 1 first 1 The hydrocarbon group contains benzyl group, phenethyl group, etc. The preferred compound is quaternary nitrogen »Qiwen 1 The trihydrocarbyl groups attached to nitrogen are methyl or ethyl 1 and the other is C 3 ~ C 24 back 1 1 aliphatic hydrocarbon group, and the particularly preferred compound is quaternary nitrogen 9 of which trihydrocarbyl group Note 1 1 is methyl »And the other is C ί Ϊ-C 12 alkyl &gt; Matter 1 Re 1 Preferred examples of the single quaternary ammonium used in the invention include: octyl trimethyl chloride number 4 decyl trimethyl ammonium chloride, lauryl trimethyl ammonium nitride, etc. Page 1 I Two quarter It salt examples used in the present invention Contains: 1, 3-bis (trimethylammonium ethyl) 1 1 • ma m hexamethylene dichloride, N, N, N ', Η &gt; Ν', Ν »mono-methyl isophorone two number Dibromo 1 ο Η-tallow alkyl-N, Η, N ♦ »Η ', Η« — pentamethyltrimethyl ί? Diammonium dichloride and so on. 1 These organic quaternary ammonium salts (g) can be used alone or in combination of two or more. 1 Polyamine m is obtained from the reaction of dicarboxylic acid ⑴ with polyamine (j). 〇 1 1 The dicarboxylic acid (i) is a compound having a dicarboxylic acid and its derivative. The dicarboxylic acid (i) used as a raw material for the polym amine (h) contains its free acid, its ester, its anhydride, etc. Examples of dicarboxylic acids (i) include the above compounds (d) »namely 1 1 aliphatic ·, aromatic and cycloma dicarboxylic acids» monoesters and diesters of one of the dicarboxylic acids and the lower enzyme 1 1 , An anhydride of one of the dicarboxylic acids »Μ and a polyester made from one of the dicarboxylic acids and 1 1 diacid. Among them, polyesters with free carboxylic acid groups are preferred. Among the polyesters. Polyesters of 20 or below are preferred. 〇1 Dicarboxylic acid ί i) Can be used alone X29 530 &gt; It can also be used in combination of two or more 〇1 I Polyamine (j) Can be used with two Or Μ upper primary amine and / or secondary amine amine »1 1 1 -16- 1 1 1 This paper scale uses the national rubbing rate of China (CNS> A4 specification (210X297 mm) A7 B7 Central Bureau of Standards of the Ministry of Economic Affairs Printed by Beigong Consumer Cooperative V. Description of the invention (is) 1 1 Such as aliphatic amines, as used in the manufacture of water-soluble resins (II) as raw materials for the hospital 1 1 Diamines or polyalkylene polyamines alicyclic polyamines &gt; Aromatic polyamines, etc. Among them, 1 among 1 1 M aliphatic diamines are preferred. These amines can be used monotonously, or two kinds or please use 1 first and more than 1 kinds in combination. Read 1 Read 1 | Alicyclic II The amine can be a compound having an alicyclic ring of about C 5-C 12, and the back surface of M cyclohexane 1 | The ring is preferably a compound of M and a di-primary amine and / or secondary amine group. The amine group can be directly attached to the lipid 1 I Cyclic ring 9 or indirectly connected to the fat via a linking group such as alkylene 1 In addition, the compound used in the ring 0 of the ring group can also be-* Amine group (1) Directly or indirectly 4 This is connected to the cycloaliphatic group 9 The other amine group is an amine alkyl group and is connected to the amine group page S_ ^ 1 | (1) 〇1 1 Examples of alicyclic diamines include diaminocyclohexane, isophorone diamine, 1 bis (aminomethyl) cyclohexanebis (4-aminocyclohexyl) methane &gt; 2,2-bis (4 1 ding-aminocyclohexyl) propane methylenediamine, 4, 4′-oxobis (cyclohexylamine), 1 4,4, -sulfobis (cyclohexylamine) 4,4'-diamino-3,3'-dimethylbicyclo 1 I hexyl methane, 4, 4, -diamino-3,3'-dimethyldicyclohexane, N-amine 1 1 Propylcyclohexylamine 1,5-bis (aminomethyl) octahydro-4,7-methyleneindene 2,6-1 1 Bis (aminomethyl) octahydro-4,7-methyleneindene, 2 , 4 1 · diamino-3, 3 »&gt; 5, 5 '&gt; -κ 1 -tetramethyldioxyhexylmethane 4,4' -diamino-3, 3 ', 5, 5 , -Tetramethyl 1 1 -dicyclohexylmethyl, etc. 〇1 1 Aromatic diamines have at least one aromatic ring »Μ and a compound selected from the group consisting of primary 1 I amine groups and secondary amine groups 〇 aromatic Examples of diamines include dimethyl 1 Ί phenylenediamine, 4, 4 '-diaminodiphenylmethane, 4, 4 »_ — amino-3, 3 t _ 1 dimethyldiphenylmethane N-amine Propylaniline 2,4, -didiamino-3,3 '1 I, 5,5 f monodiamino-3,3 »5,5, -tetramethyldiphenylmethane, etc. c 1 1 1 -17- 1 1 1 This paper is printed in Chinese National Standards (CNS & A4 specifications (210X29 * 7mm) A7 B7 Printed by the Central Bureau of Standards, Ministry of Economy, Tooling and Consumer Cooperatives V. Invention Instructions (16) 1 1 Physical properties of Polyamide (h) 9 such as solubility in aqueous solvents »1 1 Crystallinity ♦ It depends on the (i) dicarboxylic acid used as the raw material of Polyamide (h) and ⑴ 1 1 Polyamine. Therefore, it can be adjusted by choosing raw materials and adding M. Please select 1 first 1 polyacetamide (h) from (i) dicarboxylic acid and (J) polyamine &gt; from 100 to 1 to read 1 I 250 ¾, preferably at 1 30 to 200 ¾, the reaction for 2 to 12 hours, remove the water generated in the reaction, back ij 1 | should be obtained 〇 dicarboxylic acid amount is preferably per mole of polyacetamide Note 1 1 0. 5- 1 mole C reaction can be carried out in the presence or absence of an acid catalyst. 1 and 1 more line »such as hydrochloric acid · &gt; manganic acid phosphoric acid, formic acid, acetic acid and polyacetamide (h) 4 The script is installed at 60% weight In the most aqueous solution, the viscosity at 25 is 20 -1 0 0 0 centipoise 0 pages · »_ ^ 1 1 Viscosity Η 50 -5000 centipoise 1 1 Polyamide (h) Can be used alone * Two kinds Or more than one. 〇1 The ratio of the pigment () in the paper coating composition of the invention to the water-based binder (π &gt; ratio 1 Order &gt; According to the target or use &gt; Determine the same as the conventional paper coating composition 〇1 The water-based binder (I) in the paper coating composition of the present invention (I) »Μ per 100 1 I weight of the most pigment. (]) Use 5 Up to 200 parts by weight is better 9 and &gt; λ 1 0 to 50 1 1 parts by weight is the best 0 Water-soluble resin (I) Μ Per 100 parts by weight of pigment (I) 1 1 Use 0.05-5 parts by weight is better »Μ 0. 1 to 2 parts by weight is better 〇I The amount of the compound (IV) used in the composition of the paper coating of the present invention is as follows 〇 1 1 If the compound (IV) is an amine (h) 9 the amount of M water-soluble resin (I ) Solid 1 The most important ingredient is about 1 to 50% by weight, preferably 9 and M is about 5 to 20% by weight 1 | Better 〇1 If the compound (IV) is polyamide (h) 9 Polyamide amount M Water soluble Resin 1 I (Π) About 1 to 90% by weight of the solid content is preferably 9 and M is about 3 to 1 80 The weight is better 0 1 1 1 -1 8-1 1 1 The size of the paper is based on the Chinese National Standard (CNS) A4 (210X297mm)

Printed by the Ministry of Economic Affairs, Central Bureau of Accreditation and Consumer Cooperatives V. Description of the invention (17) 1 1 At the time of manufacturing the paper coating composition of the present invention »The water-soluble resin (a) and the compound 1 1 (IV) can be pre-mixed> Next Mix with pigment (I &gt; and water-based adhesive (I) 1 1 9 to make a composition »or (I) and (IV) with pigment (I) and water y— \ Please 1 first 1 adhesive (I ) Mix 〇The water-soluble resin (I) and the compound (IV) Wen 1 Whether it is a mixture of (I) and (IV)> or individual 9 and pigment ([) slurry back Sj 1 | or water-based adhesive (E ) Pre-mix »Add additional attention to the resulting mixture 1 I Other ingredients &gt; Can also achieve the effect of the invention 〇 Matters 1 Re 1 If necessary» The paper coating composition of the invention 1 can be improved to contain other I ingredients 9 such as dispersion Agents »Viscosity or fluidity adjustment Agent, defoamer anti-page 1 1 corrosion agent> lubricating m, water-holding agent and colorant y containing dye and colored pigment 1 1 material 0 1 paper coating composition of the present invention can be &gt; λ any known coating means Used for 1 stapling substrate> such as blade coater, air knife coater, N-stalk coater, upper 1 rubber press coater, gate roll coater, and mosaic coater. After coating> The paper 1 I is dried as needed. LW. Dry. If necessary »Coated paper is treated with a super calender, etc. 1 1 1 Surface smoothing 〇 1 1 Since the paper coating composition of the present invention also contains compound (IV), the obtained Coated paper shows improved performance compared to the use of pigment (I) &gt; water-based binder (I) and water-soluble resin 1 1 resin (I) composed of paper coating composition obtained. 1 The present invention refers to the reference example And the embodiments need only be detailed It is known that the present invention 1 I is not limited to this. All percentage parts and ratios are unless otherwise noted. 9 1 All are M. Weight indication. In the reference example, the viscosity and pH are measured at 25. 1 Reference 1 1 1 -1 9- 1 1 1 This paper is printed in Chinese National Standard (CNS> A4 size (210X297 mm). The Central Bureau of Economic Affairs of the Ministry of Economic Affairs, Printed by Aigong Consumer Cooperative A7 B7 V. Description of the invention (18) In the thermometer, reflow In a four-necked flask with a condenser and a stir bar, add 146.2 g (1.0 mol) triethylenetetramine and 30.0 g (0.5 mol) of urea, and the mixture is heated at an internal temperature of 140-160 &lt; 〇 for 3.5 hours. Deamination. Then, 73.1 g (0.5 mol) of adipic acid was added, the internal temperature was maintained at 150-1 60 ° C, and dehydration-acetamide was performed for 5 hours. The internal temperature drops to 1 3 0 υ again, add 120 · .1 g (2.0 mol) of urea, and perform deamination for 2 hours at an internal temperature of 120-130. Then add 270 grams of water to make an aqueous resin solution. To this solution was added 60.9 g (0.75 mol) of 37% formaldehyde in water. The resulting system was adjusted to pH 4-5 with 70JS sulfuric acid, and reacted at an internal temperature of 70C for 4 hours. The reaction system was adjusted to pH 4-5 with an aqueous solution of KOH and reacted at an internal temperature of 70¾ for 4 hours. Then, the obtained aqueous solution of sodium hydroxide M was adjusted to pH 6.5 and concentrated to 50¾ to obtain 675 grams of water-soluble resin aqueous solution with a viscosity of 140 centipoise. Participant_Example 1 In the same device used in Reference Example 1, 58.5 g (0.4 mol) of triethylenetetramine and 12.0 g (0.2 mol) of urea were added, and the mixture was heated at an internal temperature of 120-140¾ for 3 hours, and then removed ammonia. Then, 34.4 g (0.2 mol) of hexahydrophthalic acid was added. At an internal temperature of 1 5 0-1 6 0 t: dehydration-rattinization for 5 hours. Neimai was lowered to 130C again, 48.0 grams (0.8 mole) of urea was added, and deamination was carried out at an internal temperature of 120-13.0 · 10 for 2 hours. After the reaction was completed, the internal temperature dropped to 100 t, and 108 g of water was added to make an aqueous resin solution. To this solution was added 32.4 g (0.4 mol) of 37¾ formaldehyde in water, the resulting system was 70¾

Benzoic acid is adjusted to PH5.I. After the internal temperature rose to 60¾, the reaction system was allowed to react for 5 hours and then cooled. Then, the obtained M285K sodium hydroxide aqueous solution was neutralized to obtain 275 g of a water-soluble resin aqueous solution with a viscosity of 45 centipoise and a pH of -20. The paper size was determined by the National Sleeping Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling out this page). Installed. -I! Printed A7 B7 by the Consumer Labor Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Description of Invention (19) 7.1 with a concentration of 50%. [Shenhuang 1] In the same device used in Reference Example 1, 146.2 g (1.0 mol) of triethylenetetramine and 180.2 g (3.0 mol) of urea were added, and the mixture was heated at an internal temperature of 120-140t: heated for 2 hours, and then removed ammonia. Then, 150 g was added to prepare an aqueous resin solution. To this solution was added 56.8 g (0.7 mol) of 37¾ formaldehyde in water, and the resulting system should be at an internal temperature of 70 ° i for 4 hours. Then adjust the system to 70 »; sulfuric acid was adjusted to p Η 4.0, keeping the internal temperature at 70 C, and the reaction system reacted for 4 hours. Then, the obtained system K aqueous solution of sodium hydroxide was adjusted to pH 7.0 to obtain 515 g of a water-soluble resin aqueous solution with a viscosity of 3 50 centipoise and a concentration of 50 X. Ref .. Example—4._ In a four-necked flask equipped with a dipmeter, 1. 丨 ebig condenser and stir bar, add 142 g (1.0 mol) of 1,3-bis (aminoethyl) cyclohexane Alkane and 73.0 g (0.5 mol) adipic acid were kept at an internal temperature of 150-160 ° C, and dehydration-amidation was carried out for 5 hours. After the reaction was completed, water was added to obtain 3 38 grams of polyamidoamine aqueous solution, with a viscosity of 400 cps and a concentration of 60¾. Reference m In the same device used in Reference Example 4, 170.2 g (1.0 mol) of isophordiol diamine and 50 g (0.5 mol) of succinic anhydride were added, and the internal temperature was maintained at 150-160C for dehydration-ammonification 5 hours. After the reaction was completed, water was added to obtain 357 g of polyacetamide aqueous solution with a viscosity of 450 centipoise and a concentration of 60¾. Part __ Example „6_ In the same device used in Reference Example 4, add 74.2 g (1.0 mol) 1,3-propanediamine, Μ and 83.1 g (0.5 mol) 3-methyl-1,2, 3,6-Tetrahydro-2 1-This paper standard is easy to use China National Standard (CNS &gt; A4 specification (210X297mm) --------- f pack ---- I--order ------ f 1-. (Please read the precautions on the back before filling in this page) A7 B7 Printed by the Central Bureau of Economic Affairs of the Ministry of Economic Affairs Beigong Consumer Cooperative V. Description of invention (2〇) 1 1 m anhydride and 4-Methyl_ 1, 2, 3, 6-tetrahydropeptide anhydride mixture, keep the internal temperature 1 1 150-155¾, dehydration and amination for 5 hours. After the reaction is complete, add 1 1 water to get 247.2 Gram polyamidoamine aqueous solution, 60% concentration. Please 1 first 1 read 1 In the same device used in Reference Example 4, add 116.2 g (1.0 mol) square it 1 I of methylene diamine, Μ And 83.1 g (0.5 mol) of 3-methyl-1, 2, 3, 6-tetrahydro Note 1 | Anhydride and 4-methyl-1,2, 3, 6-tetrahydrophthalic anhydride Mixture, keeping internal temperature matters 1 Then 1 150-155V, dehydration _ amination for 5 hours. After the reaction is completed, add 4 copies of the water to get 31 7 2 grams of polyacetamide aqueous solution, the concentration of 60 ¾ 〇 Page 1 | Sen Huang 1 1 used in Reference Example 4 In the same device, add 103.2g (1.0mol) diethylenetriamine and 73 • 1g (0.5mol) adipic anhydride, keep the internal temperature 150-155 1 9 for dehydration- It is aminated for 5 hours. Then, 152.1 g (1.0 mol 1T 1 ear), 1,2,3,6-tetrahydrogen anhydride and 60.1 g (1.0 mol) ethylenediamine are added, Maintain the internal temperature of 150-1510 in 1 I, and perform dehydration-amidation for 5 hours. After the reaction is completed 1 1 y, add water to get 5 87. 5 g of polybromide aqueous solution, the concentration is 60%. In the same device used, add 60. 1 g (1.0 mol) of ethyl 1 1 diamine and 87.1 g (0.5 mol) of dimethyl adiphydride, and maintain the internal temperature of 110 VI for demethylase 6 hour. After the reaction was completed, water was added to obtain 194.2 g of polyacetate 1 | amine aqueous solution with a concentration of 60% &lt;) 1 Reference 1 In the same device used in Reference Example 4, add 103.2 g (1.0 mol) of 2 1 1 Ethylenediamine, 60 .1 g (1.0 mole) Ethylenediamine and 202.3 g (1.0 mole 1 1 1 -22- 1 1 1 This paper scale uses the Chinese national standard (CNS &gt; A4 size (210X297 mm) A7 B7 printed by the WC Industrial Consumer Cooperative of the Central Bureau of Economics of the Ministry of Economic Affairs 5. Description of the invention (21) Ear) Sebacic acid, keeping the internal temperature 150-1551 ^ for dehydration-acetamide It takes 5 hours. After the reaction is complete, add 549.3 g of polyamidoamine aqueous solution with a concentration of 60¾ °. Refer to Table 1 to prepare the colorants of the formulation (solid-based) shown in Table 1 below: Table 1 (Colorants) Composition Ratio Pigment Ultrawhite 90 70 Parts Carbital 90 2) 30 parts dispersant: Sumirez resin DS-10 3) 0 ·, 2 parts water-based adhesive: SN- 30 7 4) 12 parts Oji Ace A 4 parts Note: (1) Engel Hard Minerals and Chemical in the United States Clay of Division Inc. products. (2) Calcium carbonate manufactured by Fuji Kaolin Company of Japan. (3) Polyacrylic acid type pigment dispersant manufactured by Sumitomo Chemical Company of Japan. (4) Styrene-butadiene latex manufactured by Sumitomo Naugatuck Corporation of Japan. (5) Oxidized powder from Japan Oji National company. The ratios in Table 1 are calculated based on solids content. The paper standard of Shizhiya is suitable for CNS A4 specifications (210X297mm) -------- 1 &lt; 袈 ----- „-order ------ tick (Please read the precautions on the back and then fill out this page) A7 B7 Printed by the Consumer Standardization Cooperative of the Central Standards Bureau of the Ministry of Economy V. Invention Instructions (22) 1 1 In Reference Example 1 2 2 5 g of resin aqueous solution »Add 5 6 grams of cyclohexylamine 1 1 amine, the most fixed containing the latter 9 is tf 5 5 9 9 The viscosity is 138 centigrade 1 1 poise resin solution. The resulting resin solution is added to the coloring material prepared in Reference Example 11 please first 1 * The ratio of the resin solid containing the most pigment is 0.5 to 100 〇Read 1 W Μ Μ back Λ 1 I in the 225 grams of resin aqueous solution obtained in Reference Example 1 &gt; add 22 • 5 grams 1, 3 ~ Note 1 I Bis (aminomethyl) cyclohexane Μ Solid content &gt; The latter is 205K of the former, Matter 1 The viscosity is 135% The resin solution obtained is added to reference i. The color material prepared in Example 1 of the present example. The ratio of resin solid content to pigment is 0. 5 ratio page-^ 1 I 100 α 1 1 real m 1 in the reference example 2 Add 125 g of cyclohexyl 1-ir amine to the obtained 125 g of resin aqueous solution, and fix the resin solution containing 20% of the former, the latter is 20% of the former, and obtain a resin solution with a viscosity of 93 centipoise. The obtained resin solution is added to the reference example 1 1 The colorant 1 I> The ratio of the resin solid content to the most pigment is 0.5 to 100 〇1 1 Shilong _ _ Example _ 4 1 1 in the 145 grams of resin aqueous solution obtained in Reference Example 2, add 3.6 grams of isophorone ketone diamine y M fixed content> The latter is 5¾ 9 of the customer. The obtained viscosity is 44 1 1 centipoise resin solution. 0 The resulting resin solution is added to the color 1 1 material prepared in Reference Example 11. , The ratio of the resin solid containing the most pigment is 0.5 to 100 〇 1 I actual m 1 Reference example 3 The obtained resin aqueous solution and isophorone diamine 9 Individually added 1 The colorant prepared in Reference example 11 »The resin solid content to the pigment ratio is 0. 4 1 I ratio 100 * and different The ratio of Erdidiamine to pigment is 0.1 to 100 〇1 1 1 -24- 1 1 1 The paper size is based on the Chinese National Standard (CNS) A4 specification (210 × 297 mm). Printed by the consumer cooperative A7 B7 V. Description of the invention (23) Actual—In the 172 g aqueous resin solution obtained in Reference Example 3, add 5.2 g of 1,3-bis (aminomethyl) cyclohexane, with a fixed content of M, the latter being 5% of the former, the viscosity of 349 centipoise resin solution. The resulting resin solution was added to the color material prepared in Reference Example 11, and the resin solid content to pigment ratio was 0.5 to 100. In Example 1-2, the paper coating composition prepared in Examples 1 to 6 was added with water and a 10% aqueous sodium hydroxide solution to adjust the total solid content to 60¾ and the pH to about 9.0. The physical properties of the prepared composition were measured according to the following methods. The measured properties are shown in Table 2 below. (1) P Η: Using a glass electrode hydrogen ion densitometer manufactured by Toa D e n p a Industrial Co., Ltd., immediately after the composition was prepared, p Η was measured at 25 ° C. (2) Viscosity: Use the BL-type viscometer manufactured by Tolcyo Keiki, immediately after the composition is made, measure the viscosity at 60 ° pm, at 25 ° C. The prepared composition is 14g with a gold bar / ni2 Single coating rate is applied to one or both sides of fine paper with a basic weight of up to 80g / m2, the paper is immediately dried in 120t: hot air for 30 seconds, and then adjusted to moisture at 65¾ for 16 hours, then, At 60 t: Super calendering twice with a linear pressure of 60 kg / cm to obtain coated paper. The water resistance and ink receptivity of the resulting coated paper were evaluated by the following test methods. The results are shown in Table 2 below. (3) Water resistance (wet picking method): WP): The coated surface is moistened with a water supply roller, and printed with an RI tester (manufactured by Akira Manufacturing Co., Ltd.). Visual peeling (Picking) is measured according to 1 (inferior ) To 5 -25- This paper scale is applicable to China National Standard (CNS) A4 specification (210X297mm)-^ ^ Binding ^ I (please read the notes on the back side and fill in this page first) A7 B7 V. Description of invention (24) (Excellent) Five-level score water resistance. (4) Ink acceptance: (4-1) Method A: coating Dampening water supply roller surface K, using a RI printing tester. Accepting inks visually, according to 1 (poor) to 5 (excellent) rating score of five.,

I (4-2) Method B: Use the R I test machine for printing, and add water to the ink. The ink acceptance is rated on a five-level scale from (inferior) to 5 (excellent). ------.-- "-K 装 -----.-- 種 ------" 1 (please read the notes on the back before filling out this page) Ministry of Economic Affairs Central Standards Bureau Industrial Consumption Printed by the cooperative-26- This paper scale is used in the Chinese National Standard (CNS) A4 specification (210X297mm). V. Description of the invention (25) Resin (Example number) 1 Coating UJUUL:

pH (25 ^) Viscosity (2510) (centipoise) Coated paper: Water resistance: WP method oil acceptable method A method B A7 B7 2 3 4 5 9.2 9.3 9.0 9.2 9.1 9.1 1,820 1,850 1,880 1,790 1,770 1,760 4.0 4.0 4.3 4. .8 4. .0 4.5 4. ------.-- Ί-ί outfit ---- ^-book ------> 1 (Please read the note on the back first Ϋ Item and then fill out this page) Printed by the Ministry of Economic Affairs, Central Bureau of Industry and Commerce, Male Workers' Consumer Cooperative-27 copies of this paper are used in China National Standard (CNS) Α4 specification (210X297mm) Printed by Beigong Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs A7 B7 V. Description of the invention (26) Implemented in 225 grams of resin aqueous solution obtained in Reference Example 1, 5.6 grams of cyclohexyltrimethylammonium chloride was added to obtain a resin solution with a viscosity of 130 centipoise. The resulting resin solution was added to Reference Example 11, and the resin solid content to pigment ratio was 0.5 to 1 to 100,000. In the 225 g aqueous resin solution obtained in Reference Example 1, 45 g of S a η 丨 s ο 1 C ( The 50 lauryl dimethyl benzyl ammonium ammonium hydroxide solution produced by Kao Company) is a resin solution with a viscosity of 1 2 8 centipoise. The obtained resin solution was added to the color material prepared in the reference example, and the ratio of resin solid content to pigment was 0.5 to 100. EXAMPLES Example 1. To the 125 g aqueous resin solution obtained in Reference Example 2 was added 12.5 g of cyclohexyltrimethylammonium chloride to obtain a resin solution having a viscosity of 40 centipoise. The obtained resin solution was added to the color material prepared in Reference Example 11 and the resin solid content to pigment ratio was 0.5 to 10 0.

Implementation of the colorant prepared in Reference Example 11, add the resin aqueous solution obtained in Reference Example, and C 9 aj amine D 8 § Ρ ”Kao Corporation product 75¾ diheptadecyl trimethyl ammonium cyanide solution) The latter has a weight ratio of 5/1 to the former solids, and the total pigment ratio is 0.5 to 100 in terms of solids content. In the 172 g aqueous resin solution obtained in Reference Example 3, 6.9 g of Coatamine D86P was added to obtain a resin aqueous solution having a viscosity of 380 centipoise. Result-28- This paper scale is easy to use Chinese National Standard (CNS &gt; A4 specification (210X297 Gongmai)) --------- Ί '袈 ---- L--Subscribe ------ 1 (Please read the precautions on the back and then fill out this page) A7 B7 printed by the Consumer Labor Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (27) The resin solution is added to the color material made in Reference Example 11 and the resin solid content The pigment ratio is 0.5 to 100. Real m To the 172 grams of resin aqueous solution obtained in Reference Example 3, 10.4 grams of Sanssol C is added to obtain a resin aqueous solution with a viscosity of 330 centipoise. The resulting resin solution is added to the color prepared in Reference Example 11. The ratio of the resin solid content to the pigment is 0.5 to 100 °. Example In the 172 g aqueous resin solution obtained in Reference Example 3, 20.6 g of tetramethyl bromide was added to obtain a resin aqueous solution with a viscosity of 440 centipoise. The resin solution was added to the color material prepared in Reference Example 11, and the ratio of resin solid content to pigment was 0 · 5 to 1 0 0. 172 g of the resin solution obtained in Reference Example 3 on Example 1 was added 20.6 g of n-hexyl trimethyl Ammonium bromide yielded a resin solution with a viscosity of 530 centipoise. The resulting resin solution was added to Reference Example 11 The ratio of the resin solid content to the pigment is 0.5 to 1 0 0 ° m. In the 172 g resin solution obtained in Reference Example 3, add 20.6 g of n-octyltrimethylammonium bromide to obtain a viscosity of 6 1 0 A resin solution in centipoise. The resulting resin solution was added to the color material prepared in Reference Example 11, and the resin solid content to pigment ratio was 0.5 to 10 0.

帄 渄 I In the 172 grams of resin solution obtained in Reference Example 3, add 20.6 grams of Zhengde basic paper size to use the Chinese National Standard (CNS) Α4 specification (210X297 public daughter) ------.-- installed- ------- Subscribe ------ "I (Please read the precautions on the back before filling out this page) A7 B7 printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Invention Instructions (28) Ammonium bromide, a resin solution with a viscosity of 810 centipoise. The resulting resin solution was added to the color material prepared in Reference Example 11, the resin solid content of the pigment tb ^ 0.5 tblOO ° Example _ Example-1-8_ In Reference Example 3 obtained 172 grams of resin solution, add 68.6 grams 30. U, Yuezi Base trimethyl chloride chlorination solution, to obtain a resin solution with a viscosity of 400 centipoise. The resulting resin solution was added to the color material prepared in Reference Example 11, and the resin solid contained the most pigment ratio of 0.5 to 100. EXAMPLES In 172 g of the resin solution obtained in Reference Example 3, 7.3 g of 28. U n-hexadecyltrimethylammonium ammonium chloride solution was added to obtain a resin solution having a viscosity of 690 centipoise. The resulting resin solution was added to the color material prepared in Reference Example 11, and the resin solid contained the most pigment ratio of 0.5 to 10 0. Example 20. In 172 grams of resin solution obtained in Reference Example 3, 32.6 grams of 63. U stearyl trimethyl ammonium ammonium chloride solution was added to obtain a resin solution with a viscosity of 1490 centipoise. The resulting resin solution was added to the color material prepared in Reference Example 11 and the resin solid contained the most pigment ratio of 0.5 to 100.实 _ 姐 _2 丄 The paper coating composition prepared in Examples 8-20 was added with water and 10¾ sodium hydroxide solution to adjust to a total solids content of 60¾ and a pH of about 9.0. The physical properties of the prepared composition were measured according to the method described in Example 7, and the measured properties are listed in Table 3 and Table 4. The resulting composition uses a metal wire rod M 14g / ia2 single coating rate -30- The paper size is easy to use China National Standard (CNS} A4 specification (210X297 mm) I-^ — / binding I (please first Read the precautions on the back and fill out this page) A7 B7 5. Description of the invention (29) Apply to one or both sides of fine paper with a basic weight of 80g / m2. The paper is dried by hot air in 12010 for 30 seconds, at 20¾, Relative humidity 65 ¾ conditioning force pressure line straight and V ο 6 in the back of the paper, the cloth is coated with 6 11 small, part of the water in two cases of 7 cases. According to the table 4 according to the table, and 3 The inks such as oil fruit and knot-resistant water are resisted by the table. The evaluation paper appraisal method is to be tested by the painter (please read the precautions on the back side and then fill out this page). The paper size of the printed papers of the Bureau of Labor and Social Welfare Cooperatives used the Chinese National Standard (CNS) A4 specification (2 丨 0X297mm). 5. Description of the invention (3〇) Resin (Example No.) League 1 can_:

pH (251C) Viscosity (25t :) (cartridge) Coating M: Water resistance: WP method ink acceptance method A method B A7 B7 10 11 12 13 9.2 9.3 9.0 9.2 9.1 9.1 1,830 1,870 1,880 1,810 1,790 1,780 3. 4 . 3.9 4.6 4. 3.8 4.4 4, 4.1 4.7 4.5 4.1 .4 3.8 4.5 4.4 ------,-1 &lt; policy ------ order ------ '_ (please read the back first Please pay attention to this page and then fill out this page) Printed by the Ministry of Economic Affairs, Central Bureau of Accreditation and Printing Co., Ltd. -32- This paper uses the Chinese National Standard (CNS) A4 specification (210X297mm). V. Description of invention (31) Resin (31 Example number) Coating-material UMi—The thing brain 1: pH (25¾) Cobalt hemp (25D) (casket) Coated paper: Water resistance: 14 A7 B7 15 16 17 18 19 20 9.1 9.2 9.1 9.1 9.1 9.1 9 . 810 1,840 1,850 1,870 1,840 1,800 1,880 ΙίΡ method 3.8 4.0 3.8 4.0 3.8 4.3 3.8 Ink acceptance: Method A 3.9 4.0 4.7 4.8 4.7 4.5 4.2 Method B 3.8 4.2 4.6 4.8 4.5 4.4 4.2. 1 ^ Pack „Order ^ I (please first Read the precautions on the back and fill in this page) Printed by Beigong Consumer Cooperative of Central Bureau of Standards of the Ministry of Economic Affairs-33- This paper size is applicable to the Chinese National Standard (CNS) Α4 specification (210Χ 297% -it printed by the Ministry of Economic Affairs Central Standards Bureau Negative Consumers Cooperatives A7 B7 V. Description of invention (32) rm m 225g of resin aqueous solution (H) obtained in Reference Example 1, plus reference example 4. The resulting 9.3 g of polybromide aqueous solution, the amount of polyamidoamine is the most 5% of the solid content of resin (II). The resulting solution K sulfuric acid is adjusted to pH 6.5, add 1.9 g of water to obtain a resin solution containing polyamidoamine 50ίΚ, viscosity 198 centipoise., The resulting resin solution is added to the color material prepared in Reference Example 11, the resin solid contains the most pigment ratio is 0.5 to 100. Actually obtained in Reference Example 2 resin aqueous solution (Μ) , Add the aqueous solution of polyamide obtained in Reference Example 4, poly_amine is the most solid content of resin (I) 5¾. The resulting solution M sulfuric acid is adjusted to P Η 7.0, add water to obtain a resin solution containing polyamide, concentration 50% The viscosity is 100 centipoise. The resulting resin solution is added to the color material prepared in Reference Example 11, and the resin solid content to pigment ratio is 0.5 to 100. Example-Example 14 In the resin aqueous solution (BI) obtained in Reference Example 3, the poly-amine aqueous solution obtained in Reference Example 4 was added, and polyamide was the most solid content of the resin (Μ). The obtained solution M was adjusted to pH 6.8, and water was added to obtain a resin solution containing polyacetamide, with a viscosity of 60 S! And a viscosity of 178 centipoise. The resulting resin solution was added to the color material prepared in Reference Example 11, and the resin solid content to pigment ratio was 0.5 to 100. Real straight U_5 "In the aqueous resin solution (Bl) obtained in Reference Example 1, add the aqueous solution of polyacetamide obtained in Reference Example 4, the maximum content of polyacetamide resin (®) is 20¾. The resulting solution M benzoic acid is adjusted to P Η 6, 7. Add water to obtain a resin solution containing polyamide, with a degree of 50¾ and a viscosity of 230 centipoise. The resulting resin solution is added to --------------------------------- -^ I (Please read the precautions on the back before filling in this page) This paper is printed in China National Standard (CNS) A4 (210X297mm) A7 B7 Printed by the Central Labor Bureau of the Ministry of Economic Affairs V. Description of the invention (33) 1 1 The colorant prepared in Reference Example 11 * The resin solid content to pigment ratio is 0.5 to 1 1 100 〇1 1 Implementation Jin Please 1 first 1 in Reference Example 2 The resulting resin aqueous solution (I ) Inside »Add Reference Example 5 to the obtained Wen 1 polyaqueous amine aqueous solution &gt; Polyamide is the most resin (Π) solid content of 5¾ 〇 back it 1 | The obtained solution M sulfuric acid adjustment Section to PH7. 2 9 Add water to obtain a resin containing polyamidoamine. Note 1 I liquid, 50 degrees * viscosity 167 centipoise. The resulting resin solution is added to the reference item 1 again 1 Examination example 1 1 The colorant prepared * resin The ratio of the solid content to the pigment is 0.5 to 1 0 0 °. The book is written and dismissed. Page 27 | In Reference Example 3, the obtained resin aqueous solution (1) &gt; Add Reference Example 5 to the obtained 1 1 poly_amine aqueous solution polyacetamide The amount is 20¾ 1 of the solid content of the resin (I). The resulting solution is adjusted to P Η 6 with sulfuric acid. 9 9 Add water to obtain a polyamide-containing resin 1 Order solution »Concentration 60%» Viscosity 33 1 centipoise The resulting resin solution is added to 1 Reference Example 1 1 The colorant produced »The ratio of resin solid content to pigment is 0.5 to 1 I 100 0 1 Implementation 1 1 In the resin aqueous solution (m) obtained in Reference Example 3, add the polyproduce produced in Reference Example 4 Amine water Solution> The amount of polyamide is 50% of the solid content of the resin (I) 1 1 The resulting solution M sulfuric acid is adjusted to PH6. 8 »Add water to obtain a polyamide-containing resin 1 1 solution» Concentration 60¾ f Viscosity 342 centipoise obtained The resin solution was added to 1 I. Reference Example 1 1. The colorant prepared by the ratio of 1 »The resin solid content to the pigment ratio was 0.5 to 1 100 〇1 Actual 1 1 to the resin aqueous solution (I) obtained in Reference Example 3 9 Add Reference Example 6 Result 1 1 1 -35- 1 1 1 The size of this paper is far from China National Standard (CNS) A4 (2 丨 0X297mm) at B7 Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of Invention (34 ) 1 1 Aqueous solution of polyamidoamine * The amount of polyamidoamine is 20% of the solid content of the resin (η) 1 1 The resulting solution K acid is adjusted to PH7. 2 9 Add water to obtain the resin containing polyamidoamine 1 1 Solution »Concentration 6 0S; 9 viscosity 346 centipoise. The resulting resin solution is added to 1 First 1 Reference Example 1 1 The colorant obtained »The resin solid content to the pigment ratio is 0.5. The ratio is 0. Read the back S} 1 100 〇1 | Implementation JO O Note 1 1 The resin aqueous solution obtained in Reference Example 3 (I ) Within 9 plus Reference Example 7 Obtained items 1 and then 1 polym amine aqueous solution * The amount of polyamide is 20¾ of the solid content of resin (I) 4 The solution obtained from this script M is adjusted to pH 7 with sulfuric acid. 1 »Add water to obtain polyamidoamine-containing Resin page 1 I solution 9 economic degree 60 ¾, viscosity 340 centipoise 0 The resulting resin solution is added to 1 1 Reference example]] The prepared pigment> The resin solid content to pigment ratio is 0.5 to 1 100 〇1 Example—3 1 1 In the resin aqueous solution (I) obtained in Reference Example 3 * Add 1 I polyamidoamine solution obtained in Reference Example 8> Polyamide It is 20% of the solid content of the resin (I) 1 1 The resulting solution Μ Telluric acid is adjusted to pH 7. 2 Add water to obtain a polyamide-containing resin 1 1 solution * Concentration 60%> Viscosity 372 cps The resulting resin solution is added to Production of Reference Example 1 1 Colorant> The ratio of resin solid content to pigment is 0.5 to 1 1 100 〇1 1 Actual 2 1 | In the resin aqueous solution (B) obtained in Reference Example 3 »Add Reference Example 9 1 Polyamide aqueous solution> Polyamide amount is 20¾ solid content of resin (I) 1 The resulting solution sulfuric acid is adjusted to pH 6. 9 * Add water to obtain polyamide-containing resin 1 Solution 1 Concentration 60% 9 Viscosity 356 centipoise. The resulting resin solution is added to 1 1 1 -36- 1 1 1 This paper size is not printed in China National Standards (CNS) A4 specifications (210X297 mm) A7 B7 Printed by Beigong Consumer Cooperative of Central Bureau of Economic Development, Ministry of Economic Affairs Description (35) 1 1 Reference Example 11 Colorant * The ratio of resin solid content to pigment is 0. 5 to 1 1 100 〇1 I Implementation--Example _13 Please 1 I in the resin aqueous solution (I) obtained in Reference Example 3 9 plus Reference Example 10 to read 1 I read 1 I aqueous solution of polyamine 9 polyimide is the most resin (I) 20¾ solid content back A 1 1 of 1 The resulting solution K sulfuric acid is adjusted to PH7. 2 9 Add water to get the resin containing polyacetamide Note 1 | Solution * 60 ° cycle ♦ Viscosity 342 centipoise. The resulting resin solution is added to item 1 and then 1 Reference Example 11. The colorant 9 is prepared. The resin solid content to pigment ratio is 0.5. The ratio is filled in the book 1 00 〇 Page 1 I Example 1 34 1 1 Reference example 1 The obtained resin aqueous solution * and Reference example 4 The obtained polyacetamide water 1 solution * Individually added to the color material 9 prepared in Reference example 11 where Resin solution 1 1 Order 1 The weight ratio of polyacrylamide solution is 90 to 4 (M solid content is 9 5 to 5) &gt; and the total solid content of resin and polyamide to pigment ratio is 0.5 Better than 100 ° 1 I — Μ Set J 5-1 1 1 Paper coating composition made in Examples 22 to 34 »Add water and 10¾ argon oxygen 1 1 sodium hydroxide aqueous solution« Adjust to a total solids content 60¾ »pH about 9. 0 〇Physical properties of the finished product 9 measured according to the method described in Example 7> measured performance 1 1 shown in Tables 5 and 6 below 〇1 I made the composition using a gold rod 14 g / m 2 PP A--coating rate is applied 1 1 on one or both sides of fine paper with a basic weight of 80 g / m2, paper stand 1 is dried in hot air in 12010 for 30 seconds, then at 20 D, relative Humidity 65¾ 1 After conditioning moisture for 16 hours tm at 60 and a linear pressure of 60kg / cm 2 super 1 1 Calendering twice to get coated paper 〇1 1 1 -37- 1 1 1 This paper is again printed with the Chinese National Standard (CNS) A4 (210X297 mm). The A7 B7 is printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy. V. Invention Instructions (36) The water resistance and ink acceptance of the test were evaluated according to the test method described in Example 7. The results obtained are shown in Tables 5 and 6 below. ~ 3 8 * ------.-- 1U East-(Please read the precautions on the back before filling out this page) Order · This paper size is applicable to China National Standards (CNS) A4 «l grid (210X: 297 mm) A7 B7 printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (37) Xiezhi (Example No.) The composition of the paint is straight [Title 22 23 24 25 26 27 ρΗ (25Ό) 9.2 9.3 9.0 9.2 9.1 9.1 Viscosity (25D) (centipoise) Coated_cloth paper: Water resistance: 1,820 1,790 1,830 1,860 1,800 1,880 WP method ink acceptance: 4.0 4.5 4.3 4.1 4.5 4.4 Method A 3.9 4.5 4.5 4.0 4.5 4.5 Method B 3.7 4.2 4.3 4.1 4.2 4.5 -39- (please read the notes on the back first and then fill in this page) Order · The size of this paper adopts the Chinese National Standard (CNS & A4 specifications (210X297 mm) B7 V. Invention description (38 ) ^ _6_ Resin (Example No.) The paint is combined into one UL: 28 29 30 31 32 33 34 pH (25 ^) 9.1 9.1 9.0 9.2 9.2 9.1 9.3 Viscosity (25t :) (Box) Coated paper: Water resistance: 1,910 1,830 1,880 1,890 1,870 1,850 1,830 WP ink acceptance: 4.2 4.0 4.2 4.0 4.1 4.2 4.0 A 4.7 4.5 4.3 4.2 4.0 4.1 3.8 Method B 4.7 4.3 4.1 4.4 4.2 4.5 3.8 (please read "Precautions on the back side and then fill out this page") 4 ^-This paper is based on China National Standard (CNS) A4 specifications ( 210X297mm) A7 B7 printed by the Beigong Consumer Cooperative of the Central Bureau of Economic Development of the Ministry of Economic Affairs 5. Description of the invention (dipping) Contains the most pigment ratio of 0.5 to 100 to make a paper coating composition. Ratio___Comparative .. Example 1 and Reference Example 2 The resin aqueous solution obtained is added to the color material prepared in Reference Example 11 and the resin solid contains the most suitable A pigment ratio of 0.5 to 100 is used to make a paper coating composition. A comparison of 13 The aqueous resin solution obtained in Reference Example 3 is added to the color material prepared in Reference Example 11, and the resin solid contains the most pigment ratio of 0.5 to 10 0, to make a paper coating composition. TL—I use the color material made in Reference Example 11 as a paper coating formulation, without adding other compounds. It is more expensive than _Long ... 5_ .. The paper coating composition prepared in Comparative Examples 1 to 4 is added with water and 10% aqueous sodium hydroxide solution, adjusted to a total solids content of 60¾ and a pH of about 9.0. The physical properties of the resulting composition were measured as described in Example 7, and the measured properties are shown in Table 7 below. The resulting composition was applied on a single or double side of fine paper with a basic weight of up to 80 g / m2 with a single coating rate of gold wire rod M14g / m2. The paper was immediately dried in hot air at 120 ° C for 30 seconds At 20C, a relative humidity of 65¾ conditioned moisture for 16 hours, and then at 60 t: and linear pressure 60 kg / cm Super-41-This paper scale uses Chinese national standards (CNS} A4 specifications (210X297 mm) ( Please read the precautions on the back before filling out this page) 袈. Order i 30C411 A7 B7 5. Description of the invention (4〇) After calendering twice, the coated paper can be obtained. The water resistance and ink acceptance of the resulting coated paper, according to the implementation Evaluation of the test method described in Example 7. The results obtained are shown in Table 7 below. ------.-- ΊΊ 'Service ----- „-Subscribe ------ A) (Please read the back page first Please pay attention to this page.) The printed paper of the Central Standards Bureau of the Ministry of Economic Affairs is printed in Chinese. The paper size is based on the Chinese National Standard (CNS) A4 specification (2 丨 0X297mm). Fifth, the invention description (4l) resin (implementation Example No.) 1 i The sister waste treatment and treatment J4JL: pH (25¾) 9

Viscosity (250 (centipoise) Water resistance of coated paper: WP method oil acceptance method A method B A7 B7 9.2 9.0 9.1 9.3 1,820 1,860 1,770 1,650 3.5 3. 1.0 3.2 3.3 3.5 1. 丨 3.1 3.0 3.5 I "-. ^ Order. ^. _ (Please read the precautions on the back before filling in this page) Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs _ 4 3 _ This paper size is free to use the Chinese National Standard (CNS &gt; A4 specifications ( 210X297mm) A7 B7 5. Description of the invention (42) The coated paper obtained by using the paper coating composition of the present invention has various excellent properties, such as ink receptivity, water resistance, etc. Although the present invention has been described in detail with reference to specific real cell examples , But those who are good at this knowledge know that, without departing from its spirit and scope, various changes and modifications can be made. ------. I · — ·!-^ Outfit-(please read the back of S first Please pay attention to this page and then fill out this page). Printed by the Ministry of Economic Affairs, Central Standards Bureau, Employee Consumer Cooperatives-44- This paper size is used in China National Standard (CNS) A4 (210X297mm)

Claims (1)

I Announcement J i Scope of Patent Application ^ No. 83105999 "Paper Coating Group 11.2 &gt; From Youchengwu" Patent Case (Amended on November 20, 1985) Patent application scope: 1.-Paper coating composition, including : (I) 100 parts by weight of pigment; (II) 5 to 200 parts by weight of water-based binder; (III) 0.05 to 5 parts by weight of water-soluble resin, obtained from the reaction of the following compounds, (a) alkylene diene Amines or polyalkylene polyamines; (b) urea compounds, and (c) selected from aldehydes, epihalohydrin, and dihalogenated mono / S-alcohols; and (IV) 1 to 90% by weight (for water-soluble The resin (III) in terms of solids content) is selected from the following compounds: (f) amines, selected from monoamines, diamines and salts thereof each having 4 to 12 atoms; (g) having four Compounds with first-grade nitrogen atoms connected to four hydrocarbon groups or compounds with fourth-order nitrogen atoms on the ring, printed with the Central Standard Falcon Bureau Beigong Consumer Cooperative of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) ) Polyamide obtained from the reaction of a dicarboxylic acid compound and a polyamine. 2. If the composition of item 1 of the patent application scope, the water-soluble resin of component (III) is obtained by the reaction of the following compounds (a), (b), (c), (d): -1-this paper Standards apply to China National Standard (CNS) A4 specification (210X297mm) S024 (a) Extension A8 B8 C8 D8 Μ Month 11.2 0 Supplementary application Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (b) Urine (c) mization (d) II 3. If applying for monocarboxylic acid 4. If applying for water dissolution Sexually derived: (a) Stretch (b) Urine (c) Electrification (e.) Ring selection 5. If you apply for water-soluble (e) reverse (a) Stretch (b) Urine (c) Elective alkyldiamine or Polyalkylene polyamines; element compounds, and compounds from aldehydes, epihalohydrin, and α, 7-dihalo-yS-alcohols; and monocarboxylic acid compounds. The composition of item 2 of the patent scope, in which the compound of component (d) is free acid, ester or anhydride. The composition of item 1 of the patent scope, wherein the resin of component (III) is composed of the following compounds U), (b), (c), (e) reacted alkyldiamine or polyalkylene polyamine; Aldehydes, epihalohydrins, and 0 (, 7 compounds; and alicyclic compounds from alicyclic amines and alicyclic gas compounds having at least one active hydrogen atom. The composition of the patent scope item 1 resins consists of the following Compound (a), should be obtained: Alkyldiamine or polyalkylene polyamine; element compound, dihalo- / 3-alcohol (b), (c), (d) , (Please read the precautions on the back before filling in this page) Self-aldehydes, epihalohydrin compounds; -dihalo- / 3 -alcohol The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm ) Remarks in this Yu Yu Ji Ji independence (d) (e) 6. Such as Shen (f) 7 · such as Shen Geshu 8. Such as Shen (g) with 9. If Shen Yu or son, 1 0. Such -A binary money is selected from those who have patented amines with a family of ring gases. They are familiar with patented atoms. Patents have four or four levels, please patent two or four and apply for four-level ammonium A8 B8 C8 D8 Η 3 county level Λ afen. 2 Ο The employee consumption cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs is printed on the fourth-level radon original 11. If the application is designed for (h) poly-acquisition winners. 12. If the application is customary, the binary carboxyl 1 3. If the application specifically covers an alicyclic acid compound, an alicyclic amine having at least one active hydrogen atom, and an alicyclic compound of an alicyclic compound. The composition of scope item 1, wherein compound (IV) is the scope of The composition of item 6, wherein (f) the amine has the composition of item 1 in the range of 5 to 12, wherein the compound (IV) is a compound in which a graded nitrogen atom is connected to four hydrocarbon groups or a compound in a ring radon atom. Scope item 8 The composition of the item, wherein the component (g) is a first-level salt, in which a four-valued hydrocarbon group is connected to the fourth-order nitrogen source to four groups independently of each other (^ -C3 alkyl group. Substances, in which the component (g) is a salt, in which there are three formaldehyde and-* C8 _ (: 12 alkyl linker. The composition of the first item of interest scope, in which the compound (IV) amine can be borrowed binary The carboxylic acid compound reacts with the polyamine to obtain the composition of item 11 of the scope, wherein (h) the polyamic acid compound It is obtained by reacting with alicyclic diamine. The composition of item 11 of the profit range, wherein (h) is obtained by reacting polyamide dicarboxylic acid compound with polyamine. This paper scale is applicable to China National Standard (CNS}) Μ specification (210X297mm) (please read the precautions on the back before filling this page), Luo 14. The composition as claimed in item 11 of the patent scope, in which (h) polyamine is obtained from the reaction of an aromatic dicarboxylic acid compound with a polyamine. 15. The composition as claimed in item 11 of the patent application, in which (h) polyamide is obtained by reacting an aliphatic dicarboxylic acid compound with 4 to 12 atoms with a polyamine. 16. The composition according to item 11 of the patent application scope, wherein the dicarboxylic acid compound used for obtaining (h) polyamide is a free acid, ester or anhydride> '〇❼ 17. If the patent application scope is 1st The composition of the item, in which the compound (IV) is present in the amount of 3 to 80X weight of the solid content of the water-soluble resin (III) (please read the precautions on the back before filling out this page) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy -4- This paper scale is applicable to China National Standard (CNS) A4 specification (210X297mm)