Α7 Β7 經濟部中央標準局貝工消費合作社印^Α7 Β7 Printed by Beigong Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs ^
五、發明説明（ 1 ) I 本 發 明 乃 有 關 — 種 由 例 如 顆 粒 或 纖 維 強 化 材 料 之 不 燃 I I h 性 不 連 缠 相 藏 於 例 如 Jrrr Μ 機 可 硬 化 液 態 基 料 之 不 燃 性 連 m • Γ· I 相 所 組 成 之 不 燃 性 複 合 結 構 及 其 製 法 〇 κ I 請 I 以 往 的 複 合 材 料 係 由 —* 或 多 種 例 如 長 絲 增 強 材 料 之 不 先 •閱 I I 連 續 相 埋 藏 於 例 如 可 硬 化 液 態 粘 合 性 基 質 之 連 續 相 所 構/ 背 I 成 者 〇 複 合 材 料 結 構 往 往 是 包 括 由 玻 璃 ) 碩 素 或 其 他 無 之 注 I | 意 I 機 物 所 構 成 之 長 絲 增 強 材 料 作 為 不 連 缠 相，且 包 括 熱 固 性 事 項 I I 有 機 樹 脂 基 質 作 為 連 缠 相 〇 若 加 熱 至 800 T ( 427"C )以 上 再 填 寫 本 I «—J[ t 大 部 分 的 熱 固 性 有 機 基 質 材 料 分 解 1 而 産 生 煙 或 有 頁 I I 毒 氣 體 〇 若 加 熱 至 1 200 °F (6 4 9 ¾ )以上之溫度， 則玻璃 I I I 絲 增 強 材 料 熔 融 〇 主 要 是 基 於 此 等 理 由 1 以 往 含 玻 璃 I I 絲 為 不 連 缠 相 之 複 合 結 構 並 不 適 合 製 造 曝 露 火 焰 之 結 構 I 訂 ,或是製造用於在地面上儲存或輸送可燃液體之槽或管。 I | HFPA (國家防火協會） 第 30條 規 章 有 關 於 可 m 性 液 體 的 I I 儲 存 及 處 理 > 此 規 定 對 於 地 面 上 m ri\\\ 料 儲 槽 及 地 面 上 的 煉 I I 油 管 等 而 言 t 必 須 採 用 銷 或 其 他 不 燃 性 結 構 材 料 〇 FAA ( 」· 聯 邦 航 空 協 )及 D01 (交通部）要 求 飛 機 及 火 車 内 裝 材 料 I 必 須 是 曝 露 於 75 0 °F 399 10 ) 以 上 的 火 災 溫 度 時 不 燃 燒 I I 或 不 産 生 毒 氣 者 〇 地 面 上 的 銅 槽 會 銹 蝕 t 且 受 到 閃 電 Ί 或 維 修 銹 蝕 槽 體 而 不 小 心 處 理 時 » 往 往 發 生 火 災 〇 I I 木 屋 頗 易 著 火 $ 而 普 通 的 塑 膠 及 浸 潰 樹 脂 之 玻 璃 m 維 結 I I 構 曝 露 於 點 火 點 時 則 會 産 生 毒 氣 及 煙 霧 〇 I I 做 為 連 纊 相 之 傳 統 複 合 基 3 質 材 料 通 常 包 含 兩 成 分 % 熱 I I I I I I 本紙張尺度適用中國國家標率（CNS ) Α4洗格（210Χ297公釐） 83. 3. 10,000 經濟部中夬標準局貝工消费合作社印製 A6 B6 五、發明説明（2 ) 固性有機聚合物，它們都是相當昂貴，而a在輸送、儲 存及操作時必須待別小心。若此等有機基質材料為不飽 和聚酯或乙烯酯樹脂，則通常含有高至5 0 %重量的苯乙 烯單體，因此必須作為可燃性液體處理之。苯乙烯單體的蒸發 會産生不尋常的氣味，故工作場所往往必須通風。若所 選的有機基質材料包含環氣樹脂，必須小心以防止操作 員的皮_接觸到或專子呼吸到胺硬化劑材料。此外，前 述類型的傳统複合基質材料需採用待殊溶劑或其他化學 品來清潔相關的工具及容器。 長久以來，認為可溶性矽醉鹽不適合做為長絲增強複 合材料之連缅相；一項理由是可溶性矽酸鹽會腐蝕玻璃， 且藉由脱水而非聚合或化學反應進行固化。固化後之可 溶性矽酸鹽之結合力及層間剪切強力實質上小於大部分 的塑膠及熱固性樹脂。此外，除非經塗層或特殊熱處理 ,固化之可溶件矽酸鹽會慢慢的溶於水中。又有甚者， 若可溶性矽酸鹽物料利用例如徹波爐能量或曝露於150 T (65它）以上之溫度等非常快速的脱水而硬化時，則所 得的複合結構會變成很脆而不能使用。 如今本案申請者發現若藉加人某些金屬氣化物或粘土 以巧質可溶性液態矽酸鹽，則可溶性矽酸鹽會比以往用 來做為長絲增強複合結構之連續相基料之化學品組成物 具有更符合要求的結構及化學持性。 ， 例如未浸漬之編織或未编織之玻璃纖維束，如使用作為配合有可 -4 - 本紙張尺度適用中國國家標準（CNS)甲4規格（210X297公釐） {請先閲讀背面之：!i,意事項再填窝本頁) -裝 •11 A7 B7 經濟部中央樣準局員工消費合作社印製 五、發明説明（3) 1 固 化 液 態 有 機 鈷 合 基 質 而 形 成 複 合 材 料 之 不 連 缠 相 者 » ί I · 加 熱 至 1 300 Τ (704 t： )時， 將 會 熔 融 〇 吾 發 現 若- 某 些 可 溶 - 1 κ 性 液 態 矽 酸 鹽 用 來 浸 漬 及 結 合 玻 璃 m 維 之 長 絲 時 » 即 使 /-N 請 r 1 所 得 複 合 結 構 加 熱 至 玻 璃 m 維 長 絲 之 熔 點 以 上 1 其 仍 然 先 -閱 1 I / 讀 1 是 *=ί=* 兀 整 的 〇 吾 亦 發 現 若 複 合 結 構 之 連 績 相 含 有 藉 加 入 少 背 I 之 1 量 的 某 金 屬 氣 化 物 而 改 質 之 可 溶 性 液 態 矽 酸 鹽 時 t 即 注 意 1 事 1 使若該液態連缠相是例如曝露於215°F (102C)以上之溫 項 再 填 1 Jl 度 中 而 很 快 的 脱 水 硬 化 t 所 得 複 合 結 構 實 質 上 較 難 溶 於 水 寫 本 頁 装 I 〇 1 吾 更 發 現 低 粘 度 可 溶 性 矽 酸 鹽 容 易 浸 漬 及 塗 佈 玻 璃 絲 1 1 或 碩 絲 9 且 可 用 來 製 造 長 絲 纏 繞 之 管 形 複 合 結 構 〇 可 溶 1 I 性 矽 酸 鹽 較 熱 固 性 樹 脂 便 宜 I 無 毒 1 只 需 用 水 即 可 清 潔 1 訂 I 工 具 及 成 形 裝 置 9 環 境 安 全 • 處 理 時 不 污 染 環 境 » 運 輸 1 1 及 操 作 安 全 1 可 容 易 及 安 全 地 儲 存 數 年 » 且 利 用 某 脱 1 水 技 術 t 即 可 容 易 硬 化 〇 就 本 案 串 請 者 所 知 ，巨 X.A. 刖 尚 無 人 1 I 利 用 具 有 所 欲 品 質 之 可 溶 性 矽 酸 鹽 做 為 複 合 結 構 之 不 燃 Λ I 性 連 纊 相 之 實 用 方 法 (其中複合結構亦含不燃性長絲或 1 顆 粒 作 為 不 連 m 相 )〇 1 於 是 * 本 發 明 之 百 的 乃 提 供 一 種 利 用 可 溶 性 液 態 矽 酸 1 1 鹽 為 不 燃 性 複 合 結 構 之 連 缠 相 基 質 材 料 之 經 濟 » 且 有 效 1 1 的 方 法 〇 1 1 本 發 明 之 一 觀 點 傺 • 該 方 法 包 含 混 合 金 靥 氣 化 物 和 可 1 1 溶 性 液 態 矽 酸 鹽 而 形 成 不 燃 -5 性 - 液 態 連 缠 相 * 並 製 備 至 少 1 1 1 1 1 本紙張尺度適用中國國家標準（CNS〉A4说格（210X297公釐） 83. 3.10,000 4 明 説 明 發 五 A6 B6 不亞 之合 成複 組成 所形 粒而 顆相 機缠 $ S 性不 燃於 不漬 或浸 絲相 長鑕 績連 連態 性液 燃該 不使 由 ， 上相 質缅 實連 構 結 合 複 性 燃 不 之 化 i i 硬 得 構 結 亞 合 複 此 燥 乾 後 然 :發 構本 結 另 之 明 在 傺 點 觀 法 方 述 前 由 請 申 合 複 之 得 榡 結 合 複 f材 之緣 中絕 文泡 本發 述材 所板 下 ， 以構 如結 。之 構繞 結缠 可 及 絲 長。 含層 包塗 詞之 1 塗 ”漆 二請先閲讀背面之注意事項再填寫本頁) 示 圓 明 說 單 簡 點 瞜 他 其 之 明 發 本 明 發 本 瞭 明 可 画 附 及 明 說 之 列 C 之下的 由目 及 燃 不 成 構 於 適 -裝 合 捻 根 。數 圖複 線之 時絲構 相長結 續合曲 連捻撓 態根央 液數中 化複向 硬之縱 可相有 於缠置 漬連配 浸不中 當之其 示構示 顯結顯 1 合 2 圖複圖 性 經濟部中央棋準局貝工消费合作社印製 剖 面分線 角 剖部捻 等 構 線 之 分結 捻質 部 頭之基 之 接質有 構 之基漬 結 端有浸 性 兩漬向 燃 鄰浸定 不 相 向周。 之 管 定 圓構 式 合 向 化結 形 複 縱 固頭 管 對 之 及接 合 一 構成成 複 缠 結.，形構 層 連 頭圔於線 多 械 接面用捻 。呈 機 該剖示該 圖乃 乃 乃角顯， 線 3;4 5 等 6 置 絲圖圖圖 .，_ 大圖裝 長面 圖放之 -線一 本紙張尺度逋用中國國家梂準（CNS)甲4规格（210x297公釐） 經濟部中央標準局貝工消费合作社印製 A6 B6 五、發明説明（爻） 添行太發明夕島住掸式：： 吾發現當某些可溶的矽酸鹽和5重量％的氣化鋅粉末 混合，而形成液體組成物，經加熱至250T (120C )脱水， 所得之硬化材料很脆，但實質上較不溶於水。然後斷定 此液體組成物可適用作為多孔珍珠岩或多孔蛭石之粘合 劑，由此可製得耐高溫，不燃性及耐水性複合絶緣材 料。此種絶緣材料已商用為防火門或地面上的複合管及 槽。 吾更發現若含有玻璃長絲之層合板或纱帶（不連纊相） 浸漬可溶性液態矽酸鹽（連缠相），然後以熱風吹其表面 ，則會粘合成不燃性多層複合結構。吾更斷定此結構可 用作為形成長絲缠繞管，壓力容器及槽之構成，用來儲 存或輸送不燃性及可燃性液體或氣體。 吾亦發現某些可溶性液態矽酸鹽具有足夠的低粘度， 故能容易地浸潰連鑲長絲捻線或構成玻璃纖雒緊密鏃物 之長絲。吾更發現此種矽酸鹽可做為吾於1992年2月26 日提出之美國專利申請案838, 463號"雙壁複合管及偶合 結構組件，以及其製法和製造裝置"中所述之複合結構 之連缠相成份。詳而言之，某些低粘度可溶性液態矽酸 鹽為可使前述專利申諳案中所逑的可滲透的複合管環形 結構例如呈現超過l，〇fl〇°F (538 °C)之燃點的溫度具有 本紙張尺度逋用中8國家樣準（CNS1甲4规格（210X297公釐) 乂請先閲請背面之注意事項再填寫本頁) .裝 .訂 經濟部中央標準局貝工消费合作社印製 A7 B7 五、發明説明（） 不燃性的理想基質材料。可溶性矽酸鹽基質亦可配用碩 絲而形成能耐超過2000°F (1076¾)之溫度的不燃性複合 材料。 吾又發現若某些可溶性液態矽酸鹽基質材料在低於 150T (65Ό)溫度下脱水而缓慢硬化時，則其長絲增強 複合結構會保持長絲增強材料之抗張強度的相當部位。 若以可溶性矽酸鹽基質材料組成複合結構，例如1974年 1月8日所獲准之本發明者之美國專利3,784, 44 1號 複合結構”中所述之類型者，則所形成高抗張強度之電 絕緣體，即使在表面産生弧光，亦不會産生”磺徑” (Carbon path)〇 曝露於空氣時，可溶性矽酸鹽液體藉脱水而硬化。吾 發現若添加少量的陶氏矽酮200流體（粘度約10厘史托） 於可溶性液態矽酸鹽中，則可溶性液態矽酸鹽之"儲存 壽命”及”適用期"（P 〇 t 1 i f e )可延長數個月。該矽酮油 之油狀薄膜會浮在主要為可溶性液態矽酸鹽的液態基質 材料的表面，而提供防止空氣透過之屏障。此阻氣層可 抑制脱水及防止硬化矽酸鹽薄膜或皮膜之形成，否則會 改變可溶性液態矽酸鹽的粘度以及長絲潤溼性及浸漬性。 在增強複合結構中採用矽酸鹽糸基質有許多優點，包 含可形成不燃性複合材料，其熔點為玻璃纖維熔點的兩 倍以上；可降低液態基質成本至低於任何以往的熱固性 本紙張尺度適用中國國家標隼（CNS) A4規格（210X297公釐） 83.3.10,000 ----：------f #-- (請先-53讀背面之注意事項再填寫本頁) 訂 % . 經濟部中央標準局貝.工消费合作社印製 A6 B6 五、發明説明（7 ) 樹脂；提供完全無毒的工作環境；簡化任何廢棄液態基 質材料之處理步驟；提供無臭，不污染環境及環境安全 之不燃性基質材料：只需用水即可快速且簡易地清淨基 質施塗器及基質處理裝置；不必混合，只需用單一成分 之基質糸統；以及提供在溫熱的乾空氣下或室溫下即可 硬化之基質。 最廣泛而言，不燃性複合結構之製法包含慘混金屬氧 化物和可溶性液態矽酸鹽而形成不燃性液態連缠相，製 備實質h至少由不燃性連缠長絲或不燃性無機頼粒紺成 之不連缠相，將該不連鑛相浸漬潤溼在液態連缠相中以 形成複合亞結構，然後乾燥此複合亞結構而硬化該連缠 相，形成硬化之不燃性複合結構。該摻混步驟較佳為加 入約1 . Q %至5 % (對連續相重量而言）的金屬氣化物於可 溶性液態矽酸鹽中。加入步驟可包含添加金红石级二氧 化鈦粉末，氣化鋅粉末及/或氣化鐵粉末於可溶性液態 δ夕酸鹽中。可溶性液態矽酸鹽較佳為粘度為約6 0至4 0 0 厘泊，密度為約4 0 . 0至4 2 . 2度”波美（B a u m e ),而ρ Η值為 約]1 · 3者。 適最的高嶺土粘土粉末（例如可溶性液態矽酸鹽重量 份的5 . 0至4 0 . 0 % )可先和一或多種金屬氣化物粉末混合 ，然後才和液態連缠相混合，而得具有所欲粘度及觸# 性之可塗佈之不燃性複合結構或塗層。此種可塗佈之塗 層可利用氧化鐵或其他金屬氣化物之組合而被箸色。高 (請先閲讀背面之注意事項再璜寫本頁) .裝 .訂 -線. 本紙張尺度遑用中國國家榣準<CNS)甲4规格（210X297公釐） 經濟部中央橒準局貝工消费合作社印製 A6 B6 五、發明説明（8 ) 嶺土（ A丨2 () 3 · 2 Η 2 0 )為大部分粘土之主要成分，某些 · 粘土則含有石灰，鹼土，有機物及其他雜質。若和可溶 性液態矽酸鹽混合，則粘土不溶，而是呈膠體溶液之形 式。若可溶性液態矽酸鹽硬化，則含粘土之混合物變硬 ,且因粘土具有可逆_體之性質，故該混合物會具有相 當大的壓縮強度。 前述製備較佳為包含製備一種由含約3 0 %至7 (1 %；(對 複合结構之體積而言）之玻璃絲或碳絲所構成的不連續 相。若使用玻璃絲，則較佳為採用直徑約3至2 5徹米之 Ε玻璃所製成者，並加工成長重比為毎磅重量50至675 媽長的紗。 該乾燥步驟較佳為使複含亞結構曝露於6 5 Τ (丨S ) 至】CTF ( 6 6 °C )之溫度，以加速脫水及連續相的硬化。 曝露步驟乃包括對箸複合亞結構吹熱風，言到適當地固 化。 如前所建議，本法亦包括在具比重低於可溶性液態矽 酸鹽液態連塘相中加人抗硬化劑。在較佳的方法中，該 添加步驟偽在該液體中加人足最的矽酮油，而在液態連 鑛相之表面形成一層不透氣之矽酮油薄膜。較佳之矽鋼 油為粘度約1 0至1 〇 〇厘"史托"（s t 〇 k e >之陶氏2 0 0聚二甲 基矽氧烷矽酬油。 圖1及2說明本發明方法於T：業産品之應用，提供並 捻合複數根長絲線1 〇，以形成不連績相，而且利用液態 -1 0 - {請先閲讀背面之注意事項再填寫本頁) .裝 訂. -線. 本紙張尺度遑用中Η Η家搮準（CNS)甲4规格(210X297公釐） 經濟部中央樣準局貝工消费合作社印製 A6 _B6_ 五、發明説明（9 ) 基質1 1 (連靖相）浸漬在複數根長絲線中之單絲1 2 ,並潤 溼之。圖：）至（5説明本方法尚包含浸過之捻合绵1 3缚於 成形表面而形成第一層1 4。圖6説明乾燥步驟較佳為包 含使浸清過之捻合绵1 3的至少一表而1 5曝露於约1 5 Ο T (6 6 °C )之硬化溫度下；方法之一是利用熱空氣吹風機1 6 對複合結構表而I 5吹出熱風1 7，以加速液態連镰相1 1的 脱水及硬化，形成基質粘合之捻合線1 3。 太方法之權：大應用包含重覆前述的檢合，浸清及潤滢 步驟，以形成浸清過的捨合線1 3之笔二層1 8， ft將第二 層1 8冒放於第一層1 4 h，形成多層複合结構1 9，如_ 3 和圖彳所示。如丨比等圖所示，置放步驟包含將第二層】8 丨遵切方向地冒約於第厣】4 h .使得第--囁和第二層之 線彼此互相夺叉成為雙軸取向。尤伴為該置放步驟包 括使第一層和第二厲之長絲線1 0定向成至少大约互相_ 盲。 :Γ業廬甩性. 本發明之液態組成物乃可用來實質h提高常用玻璃纖 雄及其他合適材料之耐濕性的安全、防火、無毒、無臭 β低粘度之無機連缠相複合基質。本組成物可藕刷子， 轅筒或噴_設備而被應用，且不必通風。其可做為長絲 鑣繞基質，而形成耐火複合管及槽結構。若本液態組成 物配用連缠的或编織的長絲增強材料，刖可用來模塑， 拉擠或做為積層之基質：若配用多孔珍珠岩或蛭石，刖 {請先•閲讀背面之注意事項再填窝本頁) -裝 .訂 .韓. 本紙張尺度遴用中國困家橒準（CNS)甲4规格（210x297公釐） 經濟部t央樣準局貝工消费合作社印製 A6 B6 五、發明説明（10 ) 可做為不燃性W合絶续材料之連缠柑粘合基質；若配用 粘土，岩石或砂之細磨粉末，則可做為可塗佈不燃性防 火複合塗層之可硬化液態基質。 本發明之液態組成物可在標準塑嘐容器中輸送及儲存 。若在1 5 0 °F以下之溫ft器好儲存，刖儲存壽命至少Γ)年 。其可用來製造飛機 眙内無煙防火複合結構，曝露 在火焰下也不會逸出煙或毒氣之内門結構及傢俱。本矜 明之不燃性複合材料不會受到苯乙烯單體，石油液體， 去硬化聚酯及環氣塑膠及例如二氛甲垸之非極性溶劑之 影響。除特定合成發泡絕緣材料外，若預期會連缠地接 觸水、，酸、醇或食品，則本發明之不燃性複合材料必須 用不透水之塗層或結構包覆。 利闬本組成物為基質之複合結構的其他工業應用包含 :當電弧經過結構外表面時，不會産生磺徑、不易碎之 高抗張強度的複合電絕緣體；可耐至少2000T(1093t：) 之溫度而能夠維持結構性能之耐火絕熱結構容器；裝熔 融金屬之鑄模·，及例如用於槍膛，追擊砲，火箭砲及飛 彈發射管，火箭加速箱，固態推進劑之火箭管口等之不 燃性碳纖雒複合材料。 倒丄 Η參照圖】-6，由玻璃絲增強t彳料1 (]所組成之不連缠 相形成各種不燃性複合結構。以由可硬化液態基質1 1所 組成之連缠相浸濱不連缠相。連缠相之組成（重量計）如 -1 2 - 本紙張尺度逋用中國國家標準（CNS)甲4规格（210X297公釐） .....................................................................................裝.......................玎.....................線 {請先閲讀背面之注意事項再填寫本頁) 經濟部中央樣準局貝工消费合作社印製 A6 B6 五、發明説明（*> ) 下： 20.0份粘度100厘泊，密度1.37克/厘米3 (40.0波美} PH11.3之液態可溶性矽酸鹽（PQ公司工業化學 部製，産品名為矽酸納溶液E,商品名"PQ可溶性矽 酸鹽"）， ^ 1.0份金紅石级二氣化鈦粉末（商品名” Tioxide")及 0.02份粘度10厘史托之聚二甲矽氣烷（陶氏康寧公司製 商品名"Dow Corning 200液 在玻璃絲增強材料浸潰於液態基質中後，使複合結構 之表面曝露於相對溼度小於80%,溫度約75T之空氣中 而硬化。此過程之後，1由厚度為0.020至0.080吋（0.5至 2.0毫米）之编織玻璃纖維布製成不燃性複合板。V. Description of the invention (1) I The present invention is related to a kind of non-combustible material consisting of particles or fiber-reinforced materials II. The non-combustible phase is stored in the non-combustible material of the machine-hardenable liquid base material Jrrr Μ m Γ · I The non-combustible composite structure composed of phases and its preparation method κκ I Please I The previous composite materials consisted of-* or a variety of such as filament reinforced materials without precedence. Read II The continuous phase is buried in, for example, a hardenable liquid adhesive matrix Continuous phase structure / back I. The composite material structure is often composed of glass) or other materials. I | Italian I. The filament-reinforced material composed of organic materials as an unentangled phase, and includes thermosetting matters II The organic resin matrix is used as an intertwined phase. If heated to 800 T (427 " C) or more, fill in this I «—J [t Most thermosetting organic matrix The material decomposes 1 and generates smoke or toxic gas. If heated to a temperature above 1 200 ° F (6 4 9 ¾), the glass III wire reinforcement material melts. This is mainly due to these reasons. 1 Previously containing glass II wire Composite structures that are not intertwined are not suitable for making flame-exposed structures, or for making tanks or tubes for storing or transporting flammable liquids on the ground. I | HFPA (National Fire Protection Association) Article 30 regulations on the storage and handling of m liquids II This requirement is required for m ri \\\ material storage tanks on the ground and II oil pipelines on the ground. The use of pins or other non-combustible structural materials. FAA (”· Federal Aviation Association) and D01 (Ministry of Transportation) require that the interior materials of aircraft and trains I must be exposed to fire temperatures above 75 0 ° F 399 10) and do not burn II Or those who do not produce poisonous gas 〇The copper groove on the ground will be corroded and subjected to lightning Ί or maintenance of the corroded groove body and careless handling »There is often a fire 〇II The wooden house is quite susceptible to fire. The ordinary plastic and resin-impregnated glass m When exposed to the ignition point, the dimensional structure II will produce toxic gas and smoke. II The traditional composite-based three-phase material used as a continuous phase usually contains two components%. Heat IIIIII This paper size is applicable to the Chinese national standard (CNS) Α4 wash grid (210 × 297 mm) 83. 3. 10,000 Printed A6 B6 by Beigong Consumer Cooperative of China National Standards Bureau, Ministry of Economic Affairs 5. Description of invention (2) Solid organic polymers, they are quite expensive, and a Be careful when transporting, storing and operating. If these organic matrix materials are unsaturated polyester or vinyl ester resins, they usually contain up to 50% by weight of styrene monomer, so they must be treated as flammable liquids. The evaporation of styrene monomer produces an unusual odor, so the workplace must often be ventilated. If the selected organic matrix material contains a ring gas resin, care must be taken to prevent the operator's skin from contacting or breathing into the amine hardener material. In addition, the traditional composite matrix materials of the aforementioned types require special solvents or other chemicals to clean the related tools and containers. It has long been believed that soluble silicate salts are not suitable as a continuous phase for filament-reinforced composite materials; one reason is that soluble silicates corrode glass and solidify by dehydration rather than polymerization or chemical reactions. The binding strength and interlayer shear strength of the soluble silicate after curing are substantially less than most plastics and thermosetting resins. In addition, unless after coating or special heat treatment, the cured soluble silicate will slowly dissolve in water. What's more, if the soluble silicate material is hardened by very rapid dehydration, such as the energy of a wave oven or exposure to a temperature above 150 T (65 it), the resulting composite structure becomes very brittle and cannot be used . Now applicants in this case have discovered that if some metal vapors or clays are used to make soluble liquid silicates, the soluble silicates will be used as a continuous phase base material for filament-reinforced composite structures. The composition has a more suitable structure and chemical persistence. , Such as unimpregnated woven or unwoven glass fiber bundles, if used as a co-coupling -4-This paper scale is applicable to China National Standard (CNS) A 4 specifications (210X297 mm) {Please read the back of the first :! i, fill in this page again with considerations)-installed • 11 A7 B7 Printed by the Employee Consumer Cooperative of the Central Bureau of Prospects of the Ministry of Economic Affairs V. Description of the invention (3) 1 Solidified liquid organic cobalt matrix to form an unentangled phase of the composite material »Ί I · When heated to 1 300 Τ (704 t:), it will melt. I found that if-some soluble-1 κ liquid silicate is used to impregnate and combine glass m-dimensional filaments» Even if / -N please r 1 the resulting composite structure is heated to the melting point of the glass m-dimensional filament 1 above it is still first-reading 1 I / reading 1 is * = ί = * neat ○ I also found that if the composite structure has a continuous performance The phase contains a soluble liquid that is modified by adding a certain amount of a certain amount of a certain metal vapor When the acid salt is t, pay attention to 1 thing. 1 If the liquid entangled phase is exposed to a temperature term above 215 ° F (102C) and then filled in 1 Jl degree, the dehydration hardens quickly. The resulting composite structure is substantially more difficult. Dissolve in water and write this page I 〇1 I also found that low-viscosity soluble silicate is easy to impregnate and coat glass filament 1 1 or master filament 9 and can be used to make filament-wound tubular composite structures. Soluble 1 I-type silicon Salts are cheaper than thermosetting resins I Non-toxic 1 Can be cleaned only with water 1 Order I Tools and forming equipment 9 Environmental safety • No pollution to the environment during handling »Transportation 1 1 and safe operation 1 Can be stored easily and safely for several years» and use A certain water removal technology t can be easily hardened. As far as the applicants of this case are concerned, Ju XA has no one. I I use soluble silicates with the desired quality as the non-combustible Λ I of the composite structure Practical method for the continuous phase (the composite structure also contains non-combustible filaments or 1 particle as the non-connected m phase). 〇1 * The invention of the 100th is to provide a soluble liquid silicic acid 1 1 salt for non-combustible composite The economics of the intertwined matrix material of the structure »and effective 1 1 method 〇1 1 One of the viewpoints of the present invention ye • This method contains a mixture of gold tar vapor and 1 1 soluble liquid silicate to form a non-combustible-5 Liquid entangled phase * and prepare at least 1 1 1 1 1 The paper size is in accordance with Chinese National Standard (CNS> A4 specification (210X297 mm) 83. 3.10,000 4 Explain clearly and send out A6 B6 inferior composite compound The shape of the camera is entangled with $ S. It is incombustible without stains or long-dip silk. The continuous liquid combustion should not be allowed. The upper phase of the main structure is combined with the repetition of incombustibility. Ii. Combining this dryness comes afterwards: the structuring of the textbook is clear from the point of view of Ye Before the French statement, please apply for the combination of the combination of the f-materials in the margin of the fictional text under the description of the material in this article, in order to form a knot. The structure is twisted and tangled to make the filament length. The first layer of coated words is "painted". Please read the precautions on the back before filling in this page.) Shi Yuanming said the simple list and clarified his other texts. In the following figure, the structure is not suitable for the proper twisting of the twisted root. When the figure is multi-threaded, the structure of the silk is long and continuous, and the twist is twisted. If the stains are not matched properly, the display structure is shown as 1 in 2. The figure is multi-patterned. The Ministry of Economic Affairs Central Bureau of Game Science and Technology Co., Ltd. prints the section line, the angle section, the section twist, and other structure lines. The base of the head is connected with the structure, the base of the base is immersed, the two ends are immersed, and the immersion is adjacent to the immersion. Complex entanglement. The shape of the structure layer is connected to the twisting of the multi-machine interface of the thread. The machine shows the figure is the angle of the line, the line 3; 4 5 and so on. Install the long-form drawing on the line-line of a paper standard using China National Standards (CNS) A 4 specifications (210x297mm) A6 B6 printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (爻) Tian Xingtai invented the Yushima Island Shan style: :: I found that when some soluble silicate and 5 weight % Of the vaporized zinc powder is mixed to form a liquid composition, which is dehydrated by heating to 250T (120C), the resulting hardened material is very brittle, but is substantially less soluble in water. Then it is concluded that this liquid composition can be applied as porous perlite Or porous vermiculite binder, which can produce high temperature, incombustibility and water resistance composite insulation materials. This insulation material has been commercially used as composite pipes and grooves on fire doors or on the ground. I even found that if it contains glass Filament laminate or gauze (unconnected phase) is impregnated with soluble liquid silicate (connected phase), and then blown on the surface with hot air, it will be bonded into a non-combustible multilayer composite structure. I am sure that this structure can be used As the formation of filament winding tube, pressure vessel and tank, it is used to store or transport non-combustible and flammable liquid or gas. I also found that some soluble liquid silicates have sufficient low viscosity, so they can Easily impregnate continuous twisted filament twisted filaments or filaments that constitute a glass fiber slender compact. I also found that this silicate can be used as my US Patent Application 838, 463 filed on February 26, 1992 No. " Double-walled composite pipe and coupling structure components, as well as the entangled phase composition of the composite structure described in its manufacturing method and manufacturing device ". In detail, some low-viscosity soluble liquid silicates can make the aforementioned The permeable composite tube annular structure described in the patent application case, for example, exhibits a temperature exceeding the ignition point of 1, 〇fl〇 ° F (538 ° C), which is in accordance with the national standard of the paper (CNS1 A4 standard) (210X297mm) Please read the precautions on the back and fill in this page first. Binding. Binding A7 B7 printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the invention () Ideal non-combustible matrix material. Soluble silicate matrices can also be combined with silk to form non-combustible composites that can withstand temperatures in excess of 2000 ° F (1076¾). I also found that if some soluble liquid silicate matrix materials are dehydrated and slowly hardened at temperatures below 150T (65Ό), the filament-reinforced composite structure will maintain a considerable portion of the tensile strength of the filament-reinforced material. If a composite structure is composed of a soluble silicate matrix material, such as the type described in US Patent No. 3,784, 44 No. 1 Composite Structure of the inventor, which was granted on January 8, 1974, the high tensile strength is formed The electrical insulator does not produce a "Carbon path" even when arcing on the surface. When exposed to air, the soluble silicate liquid hardens by dehydration. I found that if a small amount of Dow Silicone 200 fluid is added (Viscosity is about 10 centistols) In soluble liquid silicate, the " storage life " and "pot life" (P 〇t 1 ife) of soluble liquid silicate can be extended for several months. The silicone The oily film of oil will float on the surface of the liquid matrix material mainly soluble liquid silicate and provide a barrier against air penetration. This gas barrier layer can inhibit dehydration and prevent the formation of hardened silicate film or film, otherwise Will change the viscosity of soluble liquid silicate and the wettability and impregnability of filaments. The use of silicate matte in the reinforced composite structure has many advantages, including the formation of non-combustible composite materials, which The point is more than twice the melting point of the glass fiber; it can reduce the cost of the liquid substrate to be lower than any previous thermosetting. This paper standard is applicable to the Chinese National Standard Falcon (CNS) A4 specification (210X297 mm) 83.3.10,000 ----:- ---- f #-(please read the notes on the back before -53 and fill in this page) Order%. Central Bureau of Standards of the Ministry of Economic Affairs. A6 B6 printed by the Industrial and Consumer Cooperatives 5. Description of the invention (7) Resin; provided Completely non-toxic working environment; simplify the processing steps of any waste liquid matrix materials; provide non-flammable matrix materials that are odorless, non-polluting and environmentally safe: just use water to quickly and easily clean the matrix applicator and matrix processing device; There is no need to mix, just use a single-component matrix system; and provide a matrix that can be hardened under warm dry air or at room temperature. Most broadly, the method of making non-combustible composite structures includes miscible metal oxides and Soluble liquid silicate to form a non-combustible liquid entangled phase, to prepare an intangible entangled phase at least consisting of incombustible entangled filaments or incombustible inorganic particles, to impregnate the non-inflammable mineral phase In the liquid entangled phase to form a composite substructure, and then the composite substructure is dried to harden the entangled phase to form a hardened incombustible composite structure. The blending step is preferably to add about 1. Q% to 5% ( For the weight of the continuous phase, the metal vapor is in soluble liquid silicate. The adding step may include adding rutile grade titanium dioxide powder, vaporized zinc powder and / or vaporized iron powder in soluble liquid delta silicate. The soluble liquid silicate preferably has a viscosity of about 60 to 400 centipoise, a density of about 40.0 to 42.2 degrees "Baume, and a ρ Η value of about 1 3 of them. The most suitable kaolin clay powder (for example, 5.0 to 40.0% by weight of soluble liquid silicate) can be mixed with one or more metal vaporized powders first, and then mixed with liquid entanglement to obtain Coatable non-combustible composite structure or coating with desired viscosity and touch properties. This coatable coating can be colored by using a combination of iron oxide or other metal vapors. High (please read the precautions on the back before writing this page). Binding. Binding. This paper uses the Chinese National Standard < CNS) Grade 4 (210X297mm) Central Ministry of Economic Affairs Printed by the industrial and consumer cooperatives A6 B6 V. Description of the invention (8) Clay (A 丨 2 () 3 · 2 Η 2 0) is the main component of most clays, and some clays contain lime, alkaline earth, organic matter and others Impurities. If mixed with soluble liquid silicate, the clay is insoluble, but in the form of a colloidal solution. If the soluble liquid silicate hardens, the clay-containing mixture becomes hard, and because the clay has reversible properties, the mixture will have considerable compressive strength. The foregoing preparation preferably includes preparing a discontinuous phase composed of glass filaments or carbon filaments containing about 30% to 7 (1%; (for the volume of the composite structure). If glass filaments are used, it is preferably used It is made of E glass with a diameter of about 3 to 25 cm, and processed into a yarn with a length to weight ratio of 50 to 675 mm per pound. The drying step is preferably to expose the complex substructure to 6 5 Τ (丨 S) to] CTF (6 6 ° C) temperature to accelerate dehydration and continuous phase hardening. The exposure step includes blowing hot air on the composite composite structure of the chopsticks, which is properly cured. As suggested before, this method also Including the addition of anti-hardening agent in the liquid silicate phase with a specific gravity lower than that of soluble liquid silicate. In a preferred method, this addition step pseudo-adds the most human silicone oil in the liquid, while in the liquid A thin film of silicone oil is formed on the surface of the mineral phase. The preferred silicone steel oil has a viscosity of about 10 to 100 centigrade. Dow 2 0 0 polydimethyl methacrylate (st 〇ke >) Silicone silicone oil. Figures 1 and 2 illustrate the application of the method of the present invention to T: industrial products, providing parallel twisting Several filament threads 1 〇 to form a non-continuous performance phase, and the use of liquid-10-(please read the precautions on the back before filling out this page). Binding.-Thread. This paper size is used in the middle Η Η 家 殮Standard (CNS) A4 specification (210X297 mm) A6 _B6_ printed by the Beigong Consumer Cooperative of the Central Prototype Bureau of the Ministry of Economic Affairs V. Description of invention (9) Substrate 1 1 (Lian Jing phase) is immersed in a plurality of filaments Wire 1 2, and wetting it. Figure :) to (5 shows that the method still includes the impregnated twisted cotton 13 bound to the forming surface to form the first layer 14. Figure 6 shows that the drying step preferably includes At least one surface of the soaked twisted cotton 1 3 and 15 is exposed to a hardening temperature of about 1 5 Ο T (6 6 ° C); one of the methods is to use a hot air blower 16 to the composite structure surface I 5 Blow out hot air 1 7 to accelerate the dehydration and hardening of the liquid continuous sickle phase 1 1 to form a matrix-bonded twisted wire 1 3. The right of the method: large applications include repeating the aforementioned inspection, dipping and moistening Steps to form the second layer 18 of the pen of the immersed rounding line 1 3, ft put the second layer 18 on the first layer 14 h to form a multi-layer composite structure 1 9 , As shown in _ 3 and Figure 彳. As shown in the figure, the placement step includes placing the second layer] 8 丨 in the direction of the first round] 4 h. This makes the first-second and second The lines of the layers intersect each other to become biaxially oriented. This is particularly the case where the placing step includes orienting the first layer and the second filament 10 to be at least approximately mutually blind. The liquid composition can be used to substantially improve the safety, fire resistance, non-toxic and odorless β low viscosity inorganic entangled phase composite matrix of commonly used glass fiber and other suitable materials. The composition can be applied with lotus brushes, cowls or spray equipment, and does not require ventilation. It can be used as a matrix of filaments to form a refractory composite tube and groove structure. If the liquid composition is equipped with entangled or braided filament reinforcement materials, it can be used for molding, pultrusion or as a laminated substrate: if it is equipped with porous perlite or vermiculite, please {please read first (Notes on the back and fill in this page)-Binding. Binding. Korea. This paper is based on China ’s poor home standard (CNS) A 4 specifications (210x297 mm). Printed by the Ministry of Economic Affairs of the Ministry of Economic Affairs. System A6 B6 V. Description of the invention (10) Can be used as a non-combustible W-bonded continuous bonding material for citrus bonding; if it is equipped with finely ground powder of clay, rock or sand, it can be coated as non-combustible Hardenable liquid matrix of fire-resistant composite coating. The liquid composition of the present invention can be transported and stored in standard plastic containers. If the temperature ft device below 150 ° F is well stored, the storage life is at least Γ) years. It can be used to manufacture smoke-free fireproof composite structures in airplanes, and internal door structures and furniture that will not emit smoke or poisonous gas when exposed to flames. The non-combustible composite material of the present invention is not affected by styrene monomer, petroleum liquid, de-cured polyester and ring-shaped plastic, and non-polar solvents such as dichloromethane. In addition to certain synthetic foamed insulating materials, if it is expected to be in contact with water, acids, alcohols or foodstuffs, the non-combustible composite material of the present invention must be covered with a water-impermeable coating or structure. The other industrial applications of the composite structure of the Lilu composition as a matrix include: when the arc passes through the outer surface of the structure, a composite electrical insulator with high tensile strength that does not produce a sulfone diameter and is not brittle; can withstand at least 2000T (1093t :) Refractory and heat-insulating structural container capable of maintaining structural performance at the temperature; casting mold containing molten metal; Carbon fiber composites. Refer to the figure below] -6, the non-complex entangled phase composed of glass fiber reinforced t-material 1 (] forms various non-combustible composite structures. The entangled phase composed of hardenable liquid matrix 1 1 is immersed in the water Entangled phases. The composition (weight) of the intertwined phases is -1 2-This paper uses the Chinese National Standard (CNS) A 4 specifications (210X297 mm) .............. .................................................. ..................................................................... ................. Line {Please read the precautions on the back before filling in this page) A6 B6 printed by Beigong Consumer Cooperative of Central Bureau of Standards, Ministry of Economic Affairs * >) Under: 20.0 parts of liquid soluble silicate with a viscosity of 100 centipoise and a density of 1.37 g / cm3 (40.0 Baume) PH11.3 (manufactured by the Industrial Chemistry Department of PQ Corporation, the product name is sodium silicate solution E, Trade name " PQ soluble silicate "), ^ 1.0 part rutile grade titanium dioxide powder (trade name "Tioxide") and 0.02 parts polydimethylsilane (Tow Corning) with a viscosity of 10 centiStokes Company-made trade name " Dow Corning 200 liquid soaked in glass fiber reinforced material After collapsed in the liquid matrix, the surface of the composite structure is exposed to air with a relative humidity of less than 80% and a temperature of about 75T to harden. After this process, 1 is woven from a thickness of 0.020 to 0.080 inches (0.5 to 2.0 mm) Non-combustible composite board made of glass fiber cloth.
例T T 按照圖6所示之步驟製造不燃性管子結構β使連鑲之 玻璃雜維粗纱10由中心抽取式包裝20拉出，經導纱環21 成為乾纱22,然後由導纱環23引入裝有液態基質11之塗 佈鍋24,使纱22進行浸潰。此液態基質和前面例I中所 述者相同。然後使纱22經過塗佈浸潰棒25之下方，纱帶 形成棒26之上方，通過纱帶擠壓棒27及帶寬控制棒28之 下方，將纱帶引導而置於成形表面。纱帶3 0在置於成形 表面前，先通過吹熱風機16,使得纱帶之上表面及下表 面短促地曝露於熱空氣17中，其中吹熱風機之出口溫度 約 450Τ (196.7eC )0 -1 3 - 本紙張尺度逍用中Η Η家標準（CNS)甲4规格（210X297公釐） {請先閲讀背面之注意事項再填寫本頁) -裝 •訂. 經濟部中央榣準局貝工消费合作社印製 A6 B6 五、發明説明（) 纱帶表面溫度不可超過150T (65.6 °C ),以確保液態 基質不會沸騰或太快脱水纱帶30之厚度約fl.t)20吋 (0.5毫米）以10圈纱帶製造約0.2Q时厚的複合圓筒。 經發現採用吹熱風機16脱水並使液態基質組.成物硬化， 則加工後多層複合層合板立即變成足夠硬而能夠自圓筒 形成面移除β 例II丄 由做為不連缠相的多孔珍珠岩和做為液態連缠相之下 列混合物（份數偽以重量計）製造不燃性複合合成發泡複 合結構： 20.0份粘度100厘泊，i度1.37克/厘米3 (40.0波美） PH11.3之可溶性液態矽酸鹽（PQ公司之工業化 學部製，産品名”矽酸納溶液E ,商品名"P Q可溶性 矽酸鹽"），及 1 . 〇份氧化鋅粉末 本例中用作為不燃性合成泡沫絶熱體之較佳形式的多 孔珍珠岩屬"未塗層之粗農業级"。在液態基質中加入乾 燥珍珠岩，利用合適混合器混合，直到具有麵漿糰之稠 度。然後將混合物倒入模具中，並放入爐中加熱至275 T (1 3 5 °C )。在乾燥空氣中加熱到2 5 0 T ( 1 2 1 °C )以上兩小時 後，複合材料之基質硬化而得浸在水中數天也不會溶解 或崩解之不燃性合成發泡結構。 此不燃性絶熱複合材料可用來製造屋瓦，紱灶，水蒸 -1 4 - 本紙張尺度適用中國國家樣準（CNS)甲4规格（21,0X297公釐） .................................................................(.....................裝.......................ΤΓ.....................^ '請先閲讀背面之注意事項再填窝本頁) 經濟部中央標準局貝工消费合作社印製 A6 B6 五、發明説明（Μ ) 氣輸送管，以及使煙锈及空氣調節用之玻璃纗維製導管具 有隔音及防火性能。若用於暖合板或玻璃纖維板之間， 則該絶緣材料可做為防火牆及防火門。Example TT A non-combustible tube structure β is manufactured according to the steps shown in FIG. 6 so that the continuous glass-inlaid roving 10 is pulled out from the center-drawing package 20, becomes a dry yarn 22 through the yarn guide ring 21, and then is introduced by the yarn guide ring 23 The coating pot 24 containing the liquid substrate 11 impregnates the yarn 22. This liquid matrix is the same as described in Example I above. Then, the yarn 22 is passed under the coating impregnation bar 25, the yarn band is formed above the bar 26, and the yarn band is guided under the forming surface by the yarn band squeeze bar 27 and the bandwidth control bar 28 below. Before the yarn belt 30 is placed on the forming surface, the hot air blower 16 is used to make the upper and lower surfaces of the yarn belt exposed to the hot air for a short time. The outlet temperature of the hot air blower is about 450T (196.7eC). -1 3-The size of this paper is easy to use in the Η Η family standard (CNS) A 4 specifications (210X297 mm) (please read the precautions on the back and then fill out this page)-binding • binding. Ministry of Economic Affairs Printed by the industrial and consumer cooperatives A6 B6 V. Description of the invention () The surface temperature of the yarn belt should not exceed 150T (65.6 ° C) to ensure that the liquid matrix will not boil or be too fast. The thickness of the dewatering yarn belt 30 is about fl.t) 20 inches ( 0.5 mm) A composite cylinder with a thickness of about 0.2Q is made with 10 turns of yarn. It was found that the hot air blower 16 was used to dehydrate and harden the liquid matrix. The multilayer composite laminate immediately became sufficiently hard to remove β from the cylindrical forming surface after processing. Example II Porous perlite and the following mixture (parts pseudo-by weight) as a liquid entangled phase are used to make a non-combustible composite synthetic foam composite structure: 20.0 parts viscosity 100 centipoise, i-degree 1.37 g / cm3 (40.0 Baume) PH11.3 soluble liquid silicate (manufactured by the Industrial Chemical Department of PQ Corporation, product name "sodium silicate solution E, trade name " PQ soluble silicate "), and 1.0 part zinc oxide powder in this example It is used as a preferred form of non-combustible synthetic foam insulation. The porous perlite is "uncoated coarse agricultural grade". Add dry perlite to the liquid matrix and mix with a suitable mixer until it has a paste The consistency of the dough. Then pour the mixture into the mold and heat it to 275 T (1 3 5 ° C) in the oven. After heating to 2 5 0 T (1 2 1 ° C) for more than two hours in dry air , The matrix of the composite material is hardened and immersed in water A non-combustible synthetic foam structure that does not dissolve or disintegrate in the sky. This non-combustible heat-insulating composite material can be used to make roof tiles, stoves, and steam -1 4-This paper size is applicable to China National Standards (CNS) A 4 Specifications (21,0X297mm) ................................................... ...................................................... .............. TΓ ............... ^ 'Please read the notes on the back first Matters refilled on this page) A6 B6 printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of Invention (Μ) Gas delivery pipes and glass ducts for smoke rust and air conditioning maintenance have sound insulation and fire resistance If it is used between warm plywood or fiberglass board, the insulation material can be used as a firewall and fire door.
例IV 利用做為不連鑛相之粘土頼粒及做為連缠相之下列混 合物（份數以重量計）製造可漆塗之白色不燃性複合結構 或塗層材料： 14.0份粘度1〇〇厘泊，密度1.37克/厘米3 (40.0波美） PH11.3之可溶性液態矽酸鹽（PQ公司工業化學部 製，産品名"矽酸納溶液E "，商品名為” P Q可溶性 矽酸鹽"）， 1 . 〇份金紅石级二氣化鈦粉末（商品名為"T i ο X i d e ")及 0.02份粘度10厘史托之聚二甲基矽氣烷（陶氏康寧公司 出品之"Dow Corning 200液）。 本複合塗層之不連缠相為200撤米細度之高嶺土（John 181〇6公司製，商品名為1^616 1^32")。在15.02份重 量液態連缠相中加入約4.0份重量乾固不連續相，並充分 混合。然後在各種乾淨木材表面塗上所得的白色液體 組成物做為白色底漆，使得木材表面遇到200(rF的丁烷 火焰也不會引燃。此不燃性複合底漆過熱而會起泡，_ 此能防止木材表面著火。本複合底漆亦可粉刷，而和許 多室内及室外用冰性醇酸樹脂塗料有相容性。 ’ -15- 本紙張尺度適用中國國家標準（CNS)甲4規格（210X297公釐） ...........................N..........·-............................................一..................裝.......................ΤΓ.....................t '請先閲.讀背面之注意事項再填寫本頁) A7 B7 五、發明説明（） 圃示夕簡Μ說明 由下列之說明及附圖可明瞭本發明本發明之其他優點 及目的。 圖1顯示當浸漬於可硬化液態連續相時，適於構成不燃 性複合结構之不連績相之複數根捻合長絲線圖。 圖2顯示其中配置有縱向中央撓曲結構之複數根捻合 長絲線圖。 画3乃呈多層複合管形式之不燃性結構之部分等角剖 面圖； 圖4乃機械連缠一對複合管相鄰兩端之接頭結構剖面 圖； 圖5乃該接頭結構之縱向定向浸漬有基質之捻線部分 放大等角剖面圖； _6顯示用於形成及固化圓周定向浸潰有基質之捻線 之裝置，該捻線構成接頭結構。 (請先閱讀背面之注意事項再填寫本頁) 訂 經濟部中央標準局貝工消费合作社印製 -16 - 本紙張尺度逋用中國國家標率（CNS ) Α4現格（210X297公釐） 83.3.10,000 經濟部中央標準局貝工消费合作社印裝 A7 B7五、發明説明（) 圖式主要符號說明 10 :長絲線 1 1 :液態基質 1 2 :各別單絲 13 :浸過之捻合線 14 :第一層 1 5 :浸.過之捻合線表面 16 :熱空氣吹風機 17 :熱風 1 8 :第二層 19 :多層複合結構 20:中心抽取式包裝 21 , 23 :導纱環 22 :乾纱 24 :塗佈鍋 25 :塗佈浸漬棒 26 :纱帶形成棒 27 :纱帶擠壓棒 28 :纱帶寬控制棒 3 0 ··纱帶 (請先閲讀背面之注意事項再填寫本頁) .装. 訂 -17 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 83. 3.10,000Example IV The use of clay particles as non-contiguous mineral phases and the following mixture (parts by weight) as interlaced phases to produce paintable white non-combustible composite structures or coating materials: 14.0 parts viscosity 100. Centipoise, density 1.37 g / cm3 (40.0 Baume) PH11.3 soluble liquid silicate (manufactured by PQ Corporation, Department of Industrial Chemistry, product name " sodium silicate solution E ", trade name "PQ soluble silicon Acid salt "), 1.0 part of rutile grade titanium dioxide powder (trade name " T i ο X ide ") and 0.02 part of polydimethylsilazane (ceramic "Dow Corning 200 liquid" produced by Corning Co., Ltd. The non-contiguous phase of the composite coating is kaolin with a fineness of 200 meters (made by John 181〇6, trade name 1 ^ 616 1 ^ 32 "). Add about 4.0 parts by weight of dry solid discontinuous phase to 15.02 parts by weight of liquid entangled phase, and mix well. Then apply the resulting white liquid composition on various clean wood surfaces as a white primer, making the wood surface encounter 200 (The rF butane flame will not ignite. This non-combustible composite primer will overheat and will Foam, _ This can prevent the wood surface from catching fire. The composite primer can also be painted, and is compatible with many indoor and outdoor ice-based alkyd resin coatings. -15- This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210X297 mm) ........................... N ...............- .. ..........................................One....... ........... pretend .......................... TΓ .............. ....... t 'Please read first. Read the precautions on the back and then fill out this page) A7 B7 V. Description of the invention () Brief description of the garden description The following description and drawings can illustrate the present invention Other advantages and purposes. Figure 1 shows a diagram of a plurality of twisted filaments suitable for forming a non-combustible phase of an incombustible composite structure when immersed in a hardenable liquid continuous phase. Figure 2 shows a longitudinal central flex Drawing of multiple twisted filaments of the structure. Drawing 3 is a partial isometric cross-sectional view of a non-combustible structure in the form of a multi-layer composite tube; Figure 4 is a cross-sectional view of the structure of the joint of the adjacent ends of a pair of composite tubes mechanically wrapped; 5 is the longitudinal orientation of the joint structure impregnated with a matrix Enlarged isometric cross-sectional view of the twisted part; _6 shows a device for forming and curing a circumferentially oriented impregnated matrix twisted wire, which constitutes a joint structure. (Please read the precautions on the back before filling this page) Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the People's Republic of China -16-This paper standard uses the Chinese National Standard Rate (CNS) A4 format (210X297 mm) 83.3.10,000 Printed by the Beige Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs A7 B7 5 Description of the invention () Explanation of the main symbols in the drawing 10: filament yarn 1 1: liquid matrix 1 2: individual filaments 13: impregnated twisted wire 14: first layer 15: impregnated. Twisted twisted wire surface 16: hot air blower 17: hot air 18: second layer 19: multi-layer composite structure 20: center-pullable packaging 21, 23: yarn guide ring 22: dry yarn 24: coating pot 25: coating dipping rod 26: yarn Tape forming bar 27: Yarn band extrusion bar 28: Yarn band control bar 3 0 · Yarn band (please read the precautions on the back before filling in this page). Packing. Order-17-This paper size applies to Chinese national standards ( CNS) A4 specification (210X297mm) 83. 3.10,000