294609294609
經濟部中央標準局員工消費合作社印¾ 艮據王要巾請專利範_述之概念，本發明係關於一 種用於况動性及高黏滯性介質的反應器裝置。 斤根據DE 21 00 615，習知有一種用於流動狀態下之物 質’尤其是麟由預聚合物被齡成具高分子量的聚醋之 反應器容器。其係由—個水平放置、一端有入口、而另一 端具有出口的反魅，及—條在反應器内室下方、用來 推進及輸魏動性物質的可旋轉裝置所構成。此裝置係以 、個很微小的間隙’繞著—個走向為反應室長軸方向的轴 旋轉。這個可旋轉的推進及輸送裝置是由—個固定在同轴 軸幹上的承載框所構成的。而一些平板則固定在其四周的 邊上k些平板是一個接著—個的，在旋轉轴的方向上， 以如下的方式傾斜地架起來：在每片平板周圍上，一個且 I相同的直徑，而且位在—個距兩反應室之額面最小距離 處的兩點’它們同時也是位在—條與旋轉軸_之螺旋線 二兩點’並且也是在每片平板上距其額面最近的兩點。 ㈣以這-條假想螺旋線所連触來的點，便稱之為軌跡 *'如此—來，就能將介質從入口輸送至出口。 =這種習知之反絲容财，例如具_性和黏滞性 的早，和預聚合物，是從這個反應室的入口中灌進來，在 反£、器巾移動’在其巾混肖，並通過外如 ί合程序。聚“成的產物讚從出口翻 森中的介質經由各做在其愤轉的平板所料並且^ 上推進。其中，當這些具有黏滞性的介質從旋轉中的平板 上流過去時’會在平板上形成—片產物的_和流層。告 本紙張尺度適用中以祕（ιιοΤΊ^Γ) -6 - .}裝— (碕先閱讀背面之注意事項再填寫本頁} ------------- In « - - I In I — n n n u n 五 發明説明 (2·) A7 B7 經濟部中央標準局員工消費合作社印製 $械的作用介人反應中的介質之時，輸出物質便會形成所 欲的聚合體，而同時剩餘的反應物成份，也將會被汽化蒸 發’而變成廢氣被抽出來。 本發明的基本任務為，將目前的技術所做成的反應器 裝置加以改良，使其能有一個相當簡單、而且穩定性較 佳、旎防止其彎曲變形的結構，以製造具有優良品質的反 應物。 、根據本發明，此項任務係_主射請專利範圍中所 1之特徵及結合其特徵所述之大意而得以解決的。 。、當轉子是由一個連接在軸幹上、而且具有穿孔的空心 圓柱體所構成，而且橫跨在反應室味的方向上之環形元 件被固定在這個轉子上時，_方面可提高穩定度，而另一 万面又能利用具有相應外形和數量的環形元件控制介質 的停留時間。這種具有穿孔的空心圓柱體，因具有很大的 ==力矩，所以抗寶曲的硬度較大，而使其扭曲變形也 是仵特別的小。同時，空心圓柱體上的穿孔也有助於介質 在促進蒸發自由面積的形成下進行攪掉。 根據申請專纖_朗情提㈣措施，還能更進 一步的加以進化和改良。 -旦將環形元件以一個傾斜於旋轉軸的方式設置 ί物產生—麵㈣職，其會局麵對聚合物的融 溶物產生-個較劇烈的攪拌效果。利用傾斜的環形 糊分送錐管裡。這個傾斜角 的選擇万式’是要在整個反應器的長度上，能產生一個 裝 ~~ I— n I n —、1τ— I — ί — n (請先閱讀背面之注意事項再填寫本頁) —Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. According to Wang Yaojin ’s patent application concept, the present invention relates to a reactor device for dynamic and highly viscous media. According to DE 21 00 615, there is known a reactor vessel for substances in a flowing state, especially pre-polymers which are aged from a high molecular weight polyester. It consists of a horizontally placed anti-charm with an inlet at one end and an outlet at the other end, and a rotatable device for advancing and transporting kinetic substances under the inner chamber of the reactor. This device rotates around a very small gap around an axis whose direction is the long axis of the reaction chamber. This rotatable propulsion and conveying device is composed of a bearing frame fixed on the coaxial shaft. Some flat plates are fixed on the sides of the four sides. These flat plates are one after the other. In the direction of the rotation axis, they are slanted up in the following manner: around each flat plate, one and the same diameter, And at two points at the minimum distance from the frontal plane of the two reaction chambers, they are also at the two points of the spiral line with the rotation axis _ and they are also the two points closest to the frontal plane on each plate . (Iv) The point touched by this imaginary spiral is called the trajectory * 'so-then, the medium can be transported from the inlet to the outlet. = This kind of conventional anti-silver property, such as _ sex and viscous early, and pre-polymer, is poured in from the entrance of this reaction chamber, in the anti- £, towel movement 'in the towel mix , And through external procedures. The product formed by the "combination" is expected from the media in the outlet through the inflated plate and pushed forward. Among them, when these viscous media flow past the rotating plate, they will Formed on the flat plate-_ and the flow layer of the product. The paper size is applicable to the Chinese-Israeli (ιιοΤΊ ^ Γ) -6-.} Packing-(Read the precautions on the back before filling this page) ----- -------- In «--I In I — nnnun Five descriptions of inventions (2 ·) A7 B7 Employee's Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs prints the role of $ mechanics in mediating the reaction medium, output The substance will form the desired polymer, and at the same time the remaining reactant components will also be vaporized and evaporated 'into exhaust gas. The basic task of the present invention is to make the current technology into a reactor device It is improved so that it can have a fairly simple structure with better stability and prevent bending and deformation, so as to produce a reactant with excellent quality. According to the present invention, this task is _Main Shot Please Patent The characteristics of 1 and the combination of the characteristics described The general solution was solved. When the rotor is composed of a hollow cylinder connected to the shaft and having a perforation, and the ring element spanning the direction of the reaction chamber is fixed on the rotor, _The aspect can improve the stability, and the other ten thousand faces can use the corresponding shape and number of ring elements to control the residence time of the medium. This hollow cylinder with perforations has a large == moment, so Kangbao The hardness of the curve is large, and its distortion is also particularly small. At the same time, the perforation in the hollow cylinder also helps the medium to be stirred off under the formation of a free area that promotes evaporation. According to the application special fiber_ 朗 情 提 ㈣ Measures can be further evolved and improved. -Once the ring element is set in a way inclined to the axis of rotation, it will produce a face-to-face job, which will face the melt of the polymer. Stirring effect. Use inclined ring-shaped paste to dispense into the conical tube. The choice of this inclination angle is to be able to produce a device in the entire length of the reactor ~~ I— n I n , 1τ- I - ί - n (Please read the back issues of the note and then fill in this page) -
經濟部中央標準局員工消費合作社印製 五、發明説明（3·)義精確的停留時間頻譜。 、環形元件最佳的設置方式是，將環形元件以某種傾斜 的方式來完成的。這種方式是要讓它位在轉子長度上的軌 跡點，能夠形成-條螺旋線。其中，環形元件上的軌跡點 是指那些與外殼兩個額面中的—面，具有最小距離的點。 在每裡，只要環形元件具有一個屬於群組的軌跡點，而這 些軌跡點是落在一條這一類的螺旋線上時，亦同。 以這種配置方式，只要環形元件不致於過分阻礙介質 在軸向上的運動時，便可以達到一個特優的輸送效果。關 於這一點，一方面必須選擇外殼和環形元件外徑間的間 隙，以使旋轉中的環形元件能夠形成一個足以對抗介質流 動的阻力，而這個阻力則又必須比軌跡點的滑動所形成的 推進力要小。另一方面，環形元件和平板上必須設有一些 穿孔，也必須顧及到介質沿著輸送的方向上漸增的黏 性。 一個特別有利的情形是，在輸送的方向上，環形元件 的截面積及/或環形元件的間距及/或空心圓柱體上的 穿孔之大小為逐漸增大的狀況。其中，它也可以是區段式 的，因為基於這種方式，便可以將反應的條件和介質的狀 態即其黏滞性相搭配，而能更精確地控制停留時間頻譜。 對此，還能利用一群組一群組地具有相同裝置角和軌跡點 的環形元件加以支援。這種互相平行，以群組的方式安置 的環形元件，將會使其中的某些區域具有一個較小的軸向 輸送效果，即它將形成一個疊接起來的區域。不同產品的 本紙張尺度適用中國國家樣準（CNS ) A4規格（210x297公釐〉Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. 5. Description of Invention (3 ·) Accurate residence time spectrum. 3. The best way to set the ring element is to complete the ring element in a tilted manner. This method is to make it located at the track point along the length of the rotor, which can form a helix. Among them, the trajectory points on the ring element refer to those points with the smallest distance between the two frontal planes of the shell. In each mile, as long as the ring element has a track point belonging to the group, and these track points fall on a spiral line of this type, the same is true. In this configuration, as long as the ring element does not excessively impede the movement of the medium in the axial direction, an excellent conveying effect can be achieved. In this regard, on the one hand, the gap between the outer diameter of the housing and the ring element must be selected so that the rotating ring element can form a resistance sufficient to resist the flow of the medium, and this resistance must be greater than the advancement caused by the sliding of the track point. Be less forceful. On the other hand, the ring element and the flat plate must be provided with some perforations, and must also take into account the increasing viscosity of the medium in the direction of transport. A particularly advantageous situation is that the cross-sectional area of the ring element and / or the distance between the ring elements and / or the size of the perforations in the hollow cylinder are gradually increasing in the direction of transport. Among them, it can also be segmented, because based on this method, the reaction conditions can be matched with the state of the medium, that is, its viscosity, and the residence time spectrum can be controlled more accurately. For this, it can also be supported by a group of ring elements with the same device angle and track point. Such ring elements that are parallel to each other and arranged in groups will give some areas a smaller axial transport effect, that is, they will form a superimposed area. The paper size of different products is applicable to China National Standards (CNS) A4 specification (210x297mm)
請 先 閱 讀 背 4L 項 再 填袭裝 頁 訂 ..泉 經濟部中央標準局員工消費合作社印製 29^609 A7 B7 五、發明说明（4.) 停留時間模式，可經由這些區域來適應相關的反應動力機 制。 為了要讓這些以群組的方式安置、而且以相同軌跡點 調節成的平板能夠提高其叠接的效果，也可以將它們以如 下述實施例之方式處理：在設置一個三片平板構成的群組 時’中間的平板具有-個較小的、或相對的裝置角，或是 具有-個退縮的軌跡點。這有利於疊接的群組中攪拌的效 果。 這個反應H的結構是可以簡化的，目為在群組和區段 之間有相同的結構情形。 若是在空心圓柱體的内壁四周，另外再固定上一些附 加的環時，則介質或它所形成的泡沐，在抵擒軸向上液流 的把力’以及避免它在轴向上直接流到空心圓柱體内壁的 能力，便會減緩下來4中，泡泳特別容易在反應器的起 始區域中形成。在此區域中有減壓區及主要排氣區，而且 會進行劇烈的反應。 藉由裝置一或多個閘板，可如預期般操縱介質，而且 也可經由此方式達到一個疊接的效果。 更有利的方式為，在高黏滯性的區域中，將環形元件 間的刮刀棒置於介質衆泥中，利用刮刀棒可以避奸板間 形成橋樑及液面過度的傾斜。對於特殊的外形而言例如 犁頭形的，這些刮刀棒也會對介質的攪拌和輸送有所^ 獻。 將其出口做成分送錐管，及在分送錐管前裝置—個問 --------------,π------在 (請先閱讀背面之注意事項再填寫本頁) _·Please read the back 4L item and fill in the binding page .. Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 29 ^ 609 A7 B7 V. Description of the invention (4.) The residence time mode can be adapted to relevant areas through these areas Reaction dynamic mechanism. In order to make these plates arranged in groups and adjusted with the same track point improve the effect of overlapping, they can also be processed as in the following embodiment: When a group consisting of three plates is set During assembly, the middle plate has a smaller, or opposite device angle, or has a retracted trajectory point. This is beneficial to the effect of mixing in the overlapping group. The structure of this reaction H can be simplified, aiming to have the same structural situation between groups and sections. If it is around the inner wall of the hollow cylinder, and some additional rings are fixed, the medium or the bubble formed by it will resist the force of the liquid flow in the axial direction of the capture axis and prevent it from flowing directly to the axial direction The capacity of the inner wall of the hollow cylinder will be slowed down, and bubble swimming is particularly easy to form in the initial region of the reactor. There is a decompression zone and a main exhaust zone in this area, and a violent reaction will occur. By installing one or more shutters, the medium can be manipulated as expected, and a stacking effect can also be achieved in this way. A more advantageous way is to place the scraper bar between the ring elements in the mud of the medium in the area of high viscosity. The scraper bar can avoid the formation of bridges between the plates and excessive tilting of the liquid surface. For special shapes such as plowshares, these scraper bars also contribute to the mixing and conveying of the medium. Take the outlet as a component and send it to the conical tube, and install it in front of the conical tube-a question ------------, π ------ in (please read the notes on the back first Please fill out this page again) _ ·
經濟部中央標準局員工消費合作社印裝 A7 B7 五、發明説明（5.) 板和裝置-個在那裡旋轉的刮刀和攪拌器，使介質能均勻 的輸出液流。其中，這個閘板會讓其介質從一個旋轉運動 中鬆弛下來，而讓形成一個水平的'可測量的水平面，且 其與簍子攪拌器之速率無關。 若要將沈積的液面高度上方之容器表面騰出來，則空 心圓柱體和反應室的偏心設置方式，以及將排氣套管設計 在反應室後方末端的方式，都會有所貢獻。流經的反應物 蒸氣具有清洗的作用，而同時又由於所述之分送錐管將輸 出表面積放大，所以在排氣套管之特別敏感的下緣，就可 以避免產生一個汲取的效果，而且也可以防止粒子被帶走 (霧狀夾帶）。上述的空心圓柱體結構也有利於減少這種 夾帶（霧狀夾帶），因為空心圓柱體的内部區域，並不會 被内部所掉下來的介質薄膜所擋住。這些介質有很多是成 縷的從空心圓柱體的開口中間穿過去，因此有足夠的自由 面將反應蒸氣排除。換句話說，就是速度慢到足以避免產 物被帶走。 其他的措施’則是在外殼的頂端額外的選定目標加 熱，以避免寡聚物之附著，或有不欲的沈積物生成。 圖式中將說明兩個本發明的實施例，而於下述之說明 中做進一步的闡釋。圖式之說明如下： 圖一本發明反應器裝置之一個剖面， 圖二圖一中所使用的閘板裝置之上視圖， 圖二圖一中，設置於環形元件間之棒形刮刀元件之 上視圖， I紙法尺 準（CNS)A4^ ⑺Gx297 公釐) -10- I裝 I I I I I訂 n線 (請先閲讀背面之注意事項再填寫本頁) * . 經濟部中央標準局員工消费合作社印裝 A7 B7 五、發明説明（6.) 圖四圖一中，設置於分送區的底部閘板之上視圖， 圖五本發明第二種反應器裝置的一個剖面， 圖六在圖一及/或圖五中設置的棒形和犁頭形刮 刀之視圖，以及 圖七圖五中，設置於分送區的底部閘板之上視圖。 實施例1 : 圖一所示的反應器，特別適用於流動性的物質。其具 有一個配備著熱覆層2的外殼1。外殼1的縱向上看去 時，有一熱媒體從兩側、由各處經由一條導管3，被引到 熱覆層2裡去的。在整個反應器裝置被加熱的時候，利用 此方式可以防止彎曲變形》在外殼裡面，其中的一端設有 一個用來輸入聚合物的入口 4，而在另一端則有一個用來 輸出聚合物的出口5。外殼1裡面有一個轉子可旋轉地架 在穿過外殼額面的軸幹6,7上》在本實施例中，轉子8的長 軸與外殼1的長軸相比，有略微往下偏移—些（見圖一）， 以便為反應生成的蒸氣，例如乙二醇及乙醒蒸氣或其他的 氣體，在其上方騰出多一點的空間。在外殼丄後方的末 端，從聚合物的輸送方向看去，則設有一截排氣套管21。 轉子8具有一個空心的圓柱體、一個圓柱狀的簍子 9 ’其具有方形的穿孔10，而穿孔間則有縱向和橫向的小 挺Π構成一個栅欄狀的分布或一個柵攔狀的框。基本上， 這種栅欄狀的配置係稱為空心圓柱體9，但是它的形狀和 製作方式則不是本發明的要件。當小徑的結構連貫在一起 時會比較好。從轉子8的全長上看去，帶孔的平板12和輕 本紙張尺度適用中國國家標準（CNS) Α4規格（210χ 297公釐 I I I I 裝— I I —訂 I I 1 I I 泠 (請先閱讀背面之注意事項再填寫本頁} . , * -11- B7 B7 經濟部中央標準局員工消费合作社印製Printed by A7 B7, Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. 5. Description of the invention (5.) Plates and devices-a scraper and agitator rotating there to enable the medium to evenly output the liquid flow. Among them, this ram allows its medium to relax from a rotating motion, and allows a horizontal 'measurable horizontal plane to be formed, which is independent of the speed of the basket mixer. To free up the surface of the container above the level of the deposited liquid, the eccentric setting of the hollow cylinder and the reaction chamber, as well as the way of designing the exhaust sleeve at the rear end of the reaction chamber, will contribute. The reactant vapor flowing through has a cleaning effect, and at the same time, because the distribution cone tube amplifies the output surface area, it can avoid a drawing effect at the particularly sensitive lower edge of the exhaust sleeve, and It can also prevent particles from being taken away (entrained by mist). The above-mentioned hollow cylinder structure also helps to reduce this entrainment (fog entrainment), because the inner area of the hollow cylinder is not blocked by the dielectric film that falls inside. Many of these media are threaded through the opening of the hollow cylinder, so there is enough free surface to remove the reaction vapor. In other words, it is slow enough to avoid the product being taken away. Other measures' are additional heating of selected targets at the top of the enclosure to avoid adhesion of oligomers or undesirable deposits. Two embodiments of the present invention will be illustrated in the drawings, and further explained in the following description. The description of the drawings is as follows: Figure 1 is a cross section of the reactor device of the present invention, Figure 2 is a top view of the shutter device used in Figure 1 and Figure 2 is a bar-shaped scraper element arranged between the ring elements in Figure 1 View, I paper ruler standard (CNS) A4 ^ ⑺Gx297 mm) -10-I installed IIIII set n line (please read the precautions on the back before filling this page) *. Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (6.) In Fig. 4 and Fig. 1, the top view of the bottom shutter installed in the distribution area, Fig. 5 is a cross section of the second reactor device of the present invention, and Fig. 6 is in Fig. 1 and / or Or the view of the rod-shaped and plow-shaped scrapers set in Figure 5, and the view of the upper shutter set at the bottom of the distribution area in Figures 7 and 5. Example 1: The reactor shown in Figure 1 is particularly suitable for fluid materials. It has a housing 1 equipped with a thermal coating 2. When seen in the longitudinal direction of the housing 1, a heat medium is led into the heat cladding layer 2 through a duct 3 from both sides and everywhere. When the entire reactor device is heated, this method can prevent bending deformation》 In the shell, one end of which is provided with an inlet 4 for polymer input, and the other end is used for polymer output Exit 5. Inside the housing 1 there is a rotor rotatably mounted on the shafts 6,7 passing through the front face of the housing. In this embodiment, the long axis of the rotor 8 is slightly offset downwards compared to the long axis of the housing 1— (See Figure 1), in order to make a little more space above the vapors generated by the reaction, such as ethylene glycol and ethyl alcohol vapor or other gases. At the end at the rear of the casing, as viewed from the direction of polymer transport, a section of exhaust sleeve 21 is provided. The rotor 8 has a hollow cylinder, a cylindrical basket 9 'with square perforations 10, and there are vertical and horizontal small holes between the perforations to form a fence-like distribution or a fence-like frame. Basically, this fence-like arrangement is called a hollow cylinder 9, but its shape and manufacturing method are not essential to the present invention. It is better when the structure of the trail is coherent. Viewed from the full length of the rotor 8, the flat plate 12 with holes and light paper size are applicable to the Chinese National Standard (CNS) Α4 specification (210 × 297mm IIII Pack—II—Subscribe II 1 II Ling (please read the notes on the back first Please fill in this page}., * -11- B7 B7 Printed by Employee Consumer Cooperative of Central Bureau of Standards, Ministry of Economic Affairs
，輪13是接連著的固定在空心肺體㈣外表面上或小 徑11上’用來做為輸送和攪拌的元件。纽應室1下方帶 孔勺平板之間#即在聚合物的糊衆所在之處，於兩個前 後排列在-柳;f孔平板12或麟輪13之間，至少都設有 一個閘板設備14,17和棒形的刮刀15。 如圖所示，反應器在其長度上被分成三個不同的區 域’其中，例如獅絲孔平板12或麟輪13之間距，從 -區到另-區彼此都有變彳也就是說，在人口側的環形 平板12的間距要比中間區域為小，而其則又比末端區域為 小。同樣的，在空心圓柱體9上的穿孔12大小，則是逐漸 增大。在整個_平板12的截面上有很多的孔，而在輕線 輪上則有縱向和橫向的輻線。其中，這些孔的大小，亦即 %形平板12上所空出來的截面是由前至後逐漸增大的，而 輕線13的數目也是-區區的遞減。如最後三個輻線輪⑽ 示，它橫向的小輻線較多。在反應器的全長上，這些改變 並不需要-區-區的來進行’而是可以以—個連續的方式 來進行。 從圖中我們可以看出，環形平板12和輻線輪丨3是傾斜 地置於空心圓柱體9的長軸上。其中，裝置角是可變的， 亦即從聚合物的注人到輸出，裝置角將會變得比較小。而 裝置角的大小，則端視被處理的物質而定，例如在0至4。 之間，最好則是位在0.5至2.5。之間，其中，平板或環形 ^板的直徑也是一個影響的因素。圖上所無法看出來的 是，環形平板12或輻線輪13係讓其「軌跡點」落在一條螺 本紙張尺度適用中國國家檩準（CNS) A4規格（210x 297公釐） -12- 經濟部中央標準局員工消費合作社印裝 2^46〇9 at ______^ 五、發明説明（8·) 旋線或是蜗形的線上，而且是一組一組地相互偏移著的。 其中，「軌跡點」就是指位在平板12或是輻線輪13周邊上 的二位置。在所觀察的平板上，它是位在一個距外殼1 額面的最近之處，以及在另一個額面的最遠之處。在這些 平板12和輻線輪13之中，會有一個群組，如許多前後相鄰 的平板，它們具有相同的軌跡點。而從圓周的方向上看過 去，則下-個群組會有—個姆料—個麟來講是偏移 的軌跡點。在前後相鄰的環形平板上，軌跡點之間的角 度’隨著介質在反應器中所欲停留的時間長短而定。平板 12或韓線輪13的裝置角，是可以—組—組或是—區—區的 加以變化。當整個群組旋轉的時候，這個群組附近的介 質，將會有一個一定的比例被輸向前或輸向後。而其餘的 部分則是跑到下-個群組的範圍内。停留時間頻譜也可以 利用這種方式來達成。 這個佔了整個反應室大約1〇·22%容積之被處理的介 質會因為環形平板12或輻線輪13的移動而被拖著跑，並從 中流出來。在空心圓柱體9的穿孔10上，也同時會形成有 助血於反應的絲線和中空的平面。空心圓柱體9的外徑是 截止於反應11的下緣，並略低於介f的液面高度。 在空心圓柱體9的内室中，從縱向上看去，環形平板 I6概間是以固定_關定的，其__方面可以抑制介質 中的氣泡’而另-方面也可以成為介質滴落下來的元件。 在第-區絲，設有-個域二所示_板設備，其 係由一個與空心圓柱體9之長軸呈90。的角，且是置於其 1Ί------ίτ------.4. (請先閱讀背面之注意事項再填寫本頁) ， ·. .The wheels 13 are successively fixed on the outer surface of the hollow lung body (iv) or the small diameter 11 'and are used as conveying and stirring elements. Between the flat plates with holes in the bottom of the button room 1 # That is where the polymer paste is located, it is arranged in front of the two before and after the willow; between the flat plates 12 with f holes or the wheel 13 with at least one shutter Equipment 14, 17 and rod-shaped scraper 15. As shown in the figure, the reactor is divided into three different zones along its length. Among them, for example, the distance between the lion wire plate 12 or the wheel 13 changes from one zone to another zone. That is, The distance between the annular flat plates 12 on the population side is smaller than the middle area, and it is smaller than the end area. Similarly, the size of the hole 12 in the hollow cylinder 9 gradually increases. There are many holes in the entire cross section of the flat plate 12, and there are longitudinal and transverse spokes on the light reel. Among them, the size of these holes, that is, the cross section vacated on the% -shaped flat plate 12 gradually increases from front to back, and the number of light lines 13 also decreases gradually. As shown by the last three spoke wheels, it has more small spokes in the lateral direction. Over the entire length of the reactor, these changes do not need to be made zone by zone, but can be done in a continuous manner. As can be seen from the figure, the annular flat plate 12 and the spoke wheel 3 are placed obliquely on the long axis of the hollow cylinder 9. Among them, the device angle is variable, that is, from the injection of the polymer to the output, the device angle will become relatively small. The size of the device angle depends on the material being processed, for example, 0 to 4. Between, the best is between 0.5 and 2.5. Among them, the diameter of the flat plate or the ring ^ plate is also an influencing factor. What can't be seen on the picture is that the ring-shaped flat plate 12 or the spoke wheel 13 makes its "track point" fall on a spiral paper scale, which is applicable to China National Purlin Standard (CNS) A4 specification (210x 297 mm) -12- Printed 2 ^ 46〇9 at ______ ^ by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (8 ·) The spiral or snail-shaped line is offset from one group to another. The "track point" refers to two positions on the periphery of the flat plate 12 or the spoke wheel 13. On the observed slab, it is located closest to the frontal surface of the housing 1 and farthest to the other frontal surface. Among these flat plates 12 and spoke wheels 13, there will be a group, such as many adjacent flat plates, which have the same track point. Looking at it from the circumferential direction, the next group will have an unexpected track point. On the annular plates adjacent to each other, the angle between the track points depends on the length of time the medium is to stay in the reactor. The device angle of the flat plate 12 or the Korean reel 13 can be changed from group to group or from zone to zone. When the whole group rotates, a certain percentage of the media around this group will be lost forward or backward. The rest is within the scope of the next group. The dwell time spectrum can also be achieved in this way. This processed medium, which occupies about 10 · 22% of the volume of the entire reaction chamber, will be dragged and run out due to the movement of the annular flat plate 12 or the spoke wheel 13 and flow out of it. On the perforation 10 of the hollow cylinder 9, a silk thread and a hollow flat surface which help the blood to react are also formed at the same time. The outer diameter of the hollow cylinder 9 ends at the lower edge of the reaction 11, and is slightly lower than the liquid level of the medium f. In the inner chamber of the hollow cylinder 9, when viewed from the longitudinal direction, the annular flat plate I6 is fixed _ closed, its __ aspect can suppress bubbles in the medium 'and the other aspect can also become the medium dripping Coming components. In the-zone wire, there is a plate device shown in the second zone, which is 90 degrees from the long axis of the hollow cylinder 9. The corner is placed on its 1Ί ------ ίτ ------. 4. (Please read the precautions on the back before filling this page), ·...
Α7 Β7 五、發明説明（9.) 請 先 閲 讀 背 ί 事 項 上的平板17，以及由一片閘板14所組成的。閘板μ是牢牢 地固疋在外殼1上，而且大致是延伸到空心圓柱體9上， 並構成一個圓弧狀。平板Π的外緣具有-些孔22。其中， 閉板的擺設則是要讓外殼1和閘板⑽下緣能構成一個 間隙。而介質將受到這些閘板咖的導引，而這就是用來 控制其停留時間頻譜的另一個方法。 在介質的糊漿中，刮刀棒是如圖三所示固定在外殼工 上的’其係以傾斜偏移之方式安置在旋轉的方向上，而且 浸在介質之中。刮轉ls能用諸止高轉性物質在輕線 輪13之間所形成的橋樑和附著物。除此之外，其也可利用 液流的阻力減緩介質在旋轉的方向上造成斜面的情形。刮 刀棒15在外形上是可以自由選擇的，例如其可以具有圓形 或，線形的截面。然而它也可以以下列方式構成：其可促 進回黏滞性的介質之輸送效果，例如使其傾斜的靠在輸送 的方向上。 經濟部中央標準局員工消費合作社印製 出口5係由-個壓扁的分送錐管構成，因而能夠均勾 的輸出液流。除此之外，一個固定在空心圓柱體9上的攪 棒和刮刀18也對kba分送有所助益。刮刀會和空心圓柱體 9厂起旋轉，而且會同時在外殼丄的額面上刮動並攪拌‘ 免此夕卜’裝置一個末端閘板Η時，就可以改善而均句的 輸出。其形狀是一個圓截弧，並和外殼2相連，且具有許 許多多細小的孔23 (圖四）。末端閘板19是由分送錐管^ 的方向上看過去的。空心圓㈣9是_-個由帶狀=片 所製的星形固定架24將其末端連接在軸幹7上。圖示之Α7 Β7 Fifth, the description of the invention (9.) Please read the flat plate 17 on the back item, and it is composed of a shutter 14. The shutter μ is firmly fixed on the casing 1, and extends substantially to the hollow cylinder 9 and forms a circular arc shape. The outer edge of the tablet Π has some holes 22. Among them, the arrangement of the closing plate is to allow the housing 1 and the lower edge of the shutter ⑽ to form a gap. The medium will be guided by these shutters, and this is another method used to control its residence time spectrum. In the paste of the medium, the scraper bar is fixed to the casing as shown in Fig. 3, which is placed in the direction of rotation in a tilted offset manner, and is immersed in the medium. The scraping ls can stop the bridges and attachments formed between the light reels 13 with highly rotating substances. In addition, it can also use the resistance of the liquid flow to slow down the situation where the medium causes a slope in the direction of rotation. The doctor bar 15 is freely selectable in shape, for example, it may have a circular or linear cross section. However, it can also be constructed in such a way that it can promote the transport effect of the viscous medium, such as making it lean against the transport direction. Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Export 5 is made up of a flattened distribution cone, so that it can uniformly output the liquid flow. In addition to this, a stir bar and scraper 18 fixed to the hollow cylinder 9 also contribute to kba distribution. The squeegee will rotate with the hollow cylinder 9 and at the same time it will scrape and stir at the front face of the shell sock at the same time to improve the output of a uniform sentence when the one end shutter Η of the ‘free this evening’ device is installed. Its shape is a circular truncated arc, which is connected to the housing 2 and has many small holes 23 (Figure 4). The end shutter 19 is viewed from the direction of the distribution cone ^. The hollow circle (9) is a star-shaped fixing frame 24 made of a strip-shaped piece, and its end is connected to the shaft shaft 7. Pictured
本紙張尺度適用中CNS ) Α4規格（、 -14 - 經濟部中央標準局貝工消費合作社印裝 A7 ---_______Β7 五、發明" 一 端閘板19防止介質在末端所形成的傾斜液面。在這種水平 的液面下，以鉛探棒測量輻射線的方式或是以其他的測量 方式測量液面的高度時，便會有較好的結果。 排氣套管21係呈錐狀構造’用以增大排放的面積，但 是卻可以減小因吸附作用而被帶走的粒子。在熱覆層2 中，及其上方的頂點，設有一圈迴管20，其中流著—種熱 媒體，其具有一個比熱覆層2裡的熱媒體還高的高溫。利 用這種方式，可以防止寡聚物形成沈積。 實施例2 : 在圖五所示的反應器，是特別適用於高黏滯性的介 質。其具有一個堪與圖一所示的反應器相比的基本結構， 而不同點則特別在於安裝於轉子上的環形元件1213之形 狀和配置方式，及固定在外殼1内側上的刮刀和閘板。 如同在實施例1中所示的反應器一樣，外殼1也具有 一個熱覆層2。在這一個反應器的裝置中，熱覆層係沿著 反應器的方向分成三個區域。由於介質是從入口 4向著分 送錐管5移動，所以聚合物的凝結也是照著反應器的方向 進行。若是將這個反應器至少分成三個區域29a,2%和 29c ’則在每一個區域中，便可以將這一區中的聚合物調 到一個最佳的溫度。 在反應器上的上方也有一個迴管20，裡面流著熱媒 體’其具有一個比三個加熱區中最高的溫度還要高的溫 度。如此便可以防止寡聚物沈積在反應器的上方。 入口 4、分送錐管5及排氣套管21之結構和配置方式 本紙张尺度適用中國國家標隼（CNS )人4说格（210X 297公釐） -15- ^------1T------.4- (請先閲讀背面之注意事項再填寫本頁) ·. 294609 A7 ---—?_ B7__ 五、發明説明（U.) ~' -- 係與實施例1相同。在外殼i中，轉子8 s可旋轉地架在 軸幹6,7上的，其中，崎於外殼i的長轴而言，轉子8的 旋轉轴依然是略微的向下婦。翻轉子本身也是由一個 芝心圓柱體9賴成’其係糊—個星糊定架24固定於 軸幹7之上，而且也具有一個如同實施例丄的外形。在這 個空心圓柱體上也具有穿孔10，以及位在其間的小徑u， 其中’穿孔的⑤讀面積是沿著介質流動的方向逐漸增 加0 在空心圓柱體9的外表面上或在小徑u上配備一些 環形元件。由於配備了這些環形元件，所以轉子便分成了 二個大致上為等長的區域。在前區中，設置了一個由實施 例1中所習知的搖晃平板12，而且是略微地傾斜於轉子8 的旋轉軸。在反應器的前半段，介質的黏滯性還是很小， 所以在那裡並沒有设置刮刀棒，而是利用一個沒水元件25 劇烈的攪拌介質。 經濟部中央標準局員工消費合作社印裝 (請先閱讀背面之注意事項再填寫本頁) 在轉子的中間區域設有一些水平的輻線環及/或 水平的管狀環32，用來做為環形元件。它們也同樣是略微 傾斜於空心圓柱體9上的轉子之旋轉轴。部分的管狀環32 也有布上鋼絲網，以便能更劇烈的攪拌介質。如圖六所 示，位在其對面，外殼1的内侧上與轉子的旋轉軸相垂直 之處，設有已安裝好的棒形刮刀15,27。其同樣也能改善介 質攪拌的狀況，並且還能避免聚合物在管狀環和輻線環之 間开>成聚合物橋樑。由於管狀環和輕線環係與刮刀棒相傾 斜’所以環並沒有辦法將它所附著的聚合物清理乾淨。 本紙張尺度適用中國國家揉準< CNS ) A4規格（210X297公釐） -16- A7 B7 五、發明説明（12.) 反應器的最後一個部分，係以固定於空心圓柱體9夕卜 表面且垂直於轉子之旋_的#狀環及/或鱗環28做 為環形元件。其作用在於，使這個區域中的介質不致於被 環形元件所推動。因此，在此區域中的刮刀棒，便要做成 一個如圖六所示般的犁頭狀26❶利用這個犁頭狀的刮刀 26，則介免不只會被拌勻，而且還會被輸送往分送錐管5 的方向 ^ 在分送錐管5的正前方備有一支帶有刮刀18的揽 棒’及一片柵狀的輸出閘板19，其係由如圖七所示的空心 圓桿30所構成的。此閘板使介質從一個旋轉運動中鬆弛下 來’並形成一個水平、而且可測量的水平面，而其與轉子 的旋轉速度或推進器的推進速度並無關連。 而在這個反應器的架構中，大約18_22%的反應器容積 被填以介質之時，也證實對濃縮聚合物的均勻度有所幫 助0 1.11 111 訂 I 旅 (請先閱讀背面之注意事項再填寫本頁) ， · _ 經濟部中央樣準局貝工消费合作社印裝 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -17- A7 B7 i5.10.2 4 ..充λ -—β 經濟部中央樣準局員工消費合作社印製 五、發明説明（l3 ) 符號簡單說明 1外殼 23孔 2熱覆層 24星形固定架 3導管 25汲水元件 4入口 26犁頭狀刮刀棒 5分送錐管 27棒形刮刀 6袖幹 28管狀環或輻線環 7軸幹 29加熱區域 8轉子 30空心圓桿 9空心圓柱體 31輻線環 10穿孔 32管狀環 11小徑 12環形平板 13輻線輪 14閘板 15棒形刮刀 16環形平板 17平板 18刮刀 19末端閘板 20迴管 21排氣套管 22孔 I--------： -I------ir------^ (請先閲讀背面之注意事項再填寫本頁) .. 本紙張尺度適用中國國家標準（CNS ) Α4規格（210χγ&公釐This paper standard is applicable to CNS) Α4 specifications (, -14-Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 ---_______ Β7 V. Invention " One end shutter 19 prevents the inclined liquid surface formed by the medium at the end. Under this level of liquid surface, when measuring the height of the liquid surface with a lead probe or other measurement methods, there will be better results. The exhaust sleeve 21 is a cone-shaped structure 'To increase the area of discharge, but it can reduce the particles that are taken away by adsorption. In the hot cladding 2, and the vertex above it, there is a loop 20, in which a kind of heat flows The medium has a higher temperature than the heat medium in the thermal coating 2. In this way, the formation of oligomers can be prevented. Example 2: The reactor shown in Figure 5 is particularly suitable for high viscosity Hysteretic medium. It has a basic structure comparable to the reactor shown in Figure 1, but the difference is in particular the shape and arrangement of the ring element 1213 mounted on the rotor and fixed on the inside of the housing 1 Scraper and ram. Like the reactor shown in Example 1, the casing 1 also has a thermal coating 2. In the device of this reactor, the thermal coating is divided into three regions along the direction of the reactor. Since the medium is Moving from the inlet 4 to the distribution cone 5, the polymer coagulation is also in the direction of the reactor. If the reactor is divided into at least three areas 29a, 2% and 29c 'in each area, then The polymer in this zone can be adjusted to an optimal temperature. There is also a return pipe 20 above the reactor, where the thermal medium flows, which has a temperature higher than the highest temperature in the three heating zones This will prevent oligomers from depositing above the reactor. The structure and configuration of inlet 4, distribution cone 5 and exhaust sleeve 21 This paper standard is applicable to China National Standard Falcon (CNS) Ren 4 said Grid (210X 297mm) -15- ^ ------ 1T ------. 4- (please read the precautions on the back before filling this page) ·. 294609 A7 -----? _ B7__ Fifth, the description of the invention (U.) ~ '-is the same as in Example 1. In the housing i, the rotor can rotate for 8 s Mounted on shafts 6,7, of which, as for the long axis of the housing i, the axis of rotation of the rotor 8 is still slightly downward. The flipper itself is also made up of a Zhixin cylinder 9 Tie paste—A star paste fixation frame 24 is fixed on the shaft stem 7, and also has a shape like the embodiment. The hollow cylinder also has a perforation 10, and a small diameter u in between, where The reading area of the perforation is gradually increased along the direction of the medium flow 0. On the outer surface of the hollow cylinder 9 or on the small diameter u are equipped with some ring elements. Because these ring elements are equipped, the rotor is divided into two roughly The upper area is of equal length. In the front zone, a sway plate 12 as known in Embodiment 1 is provided, and is slightly inclined to the rotation axis of the rotor 8. In the first half of the reactor, the viscosity of the medium is still very small, so there is no scraper bar, but a dry element 25 is used to vigorously stir the medium. Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) There are some horizontal spoke rings and / or horizontal tubular rings 32 in the middle of the rotor, which are used as rings element. They are likewise the axis of rotation of the rotor slightly inclined to the hollow cylinder 9. Part of the tubular ring 32 is also covered with a wire mesh so that the medium can be stirred more vigorously. As shown in Fig. 6, on the opposite side, on the inner side of the housing 1 perpendicular to the rotation axis of the rotor, there are installed rod-shaped scrapers 15,27. It can also improve the condition of media agitation, and can also prevent the polymer from forming a polymer bridge between the tubular ring and the spoke ring. Since the tubular ring and the light wire ring system are inclined to the scraper bar, the ring has no way to clean the polymer to which it is attached. This paper scale is applicable to China National Standards (CNS) A4 specification (210X297mm) -16-A7 B7 5. Description of the invention (12.) The last part of the reactor is fixed on the surface of the hollow cylinder 9 And the # -shaped ring and / or scale ring 28 perpendicular to the rotation of the rotor is used as a ring-shaped element. The effect is to prevent the medium in this area from being pushed by the ring element. Therefore, the scraper bar in this area should be made into a plow-shaped blade 26 as shown in Fig. 6. With this plow-shaped blade 26, it will not only be mixed, but also transported to The direction of the distribution cone 5 ^ In front of the distribution cone 5, there is a rod with a scraper 18 and a grid-shaped output shutter 19, which consists of a hollow round rod as shown in Figure 7 30 constituted. The shutter relaxes the medium from a rotating motion and forms a horizontal, measurable horizontal plane, which is not related to the rotation speed of the rotor or the propulsion speed of the thruster. And in the architecture of this reactor, when about 18_22% of the reactor volume is filled with medium, it also proves to be helpful for the uniformity of the concentrated polymer. 0 1.11 111 Order I Brigade (please read the notes on the back first (Fill in this page) · · _ The paper size of the printed copy of the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) -17- A7 B7 i5.10.2 4 .. λ- —Β Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (l3) Brief description of symbols 1 Shell 23 holes 2 Thermal cladding 24 Star-shaped fixing frame 3 Conduit 25 Water pumping element 4 Entrance 26 Plough-shaped scraper bar 5 dispensing cone tube 27 rod scraper 6 sleeve stem 28 tubular ring or spoke ring 7 shaft stem 29 heating zone 8 rotor 30 hollow round rod 9 hollow cylinder 31 spoke ring 10 perforation 32 tubular ring 11 small diameter 12 annular flat plate 13 spoke wire wheel 14 gate 15 bar scraper 16 annular flat plate 17 flat plate 18 scraper 19 end gate 20 return pipe 21 exhaust casing 22 hole I --------: -I ------ ir ------ ^ (Please read the notes on the back before filling out this page): This paper Scale applicable Chinese National Standard (CNS) Α4 Specification (210χγ & mm