A7 B7 293078 五、發明説明（i) (請先閲讀背面之注意事項再填寫本頁) 本發明偽有關於利用超臨界流體處理廢棄物之糸統及 方法，持別是有關於利用超臨界流體當作溶劑與廢棄物預 先混合或混合溶解有機廢窠物再利用焚化裝置焚化混合之 有機廢棄物的条統及方法。 經濟部中央標隼局員工消費合作社印製 傳統上，有機廢棄物的處理法就是燃燒，在一値燃燒 塔中，將空氣或氣氣打入與燃料及廢棄物混合，再加以燃 燒，高溫燃燒之下，有機化合物中的元素就會與氧元素進 行化合，即所謂氣化作用，而失去原來的分子結構，並消 滅其毒性，舉一値簡單的例子，多氣聯苯是常見的液態有 機廢料，其最大的用途便是用在電力變壓器中作為絕緣物 ，多氣聯苯若進入人體，對身體的危害将會非常大；但是 ，多氣聯苯的組成元素卻只有硪，氫，氣三種而已。以高 溫焚化法，理論上可以將多氣聯苯完全分解為二氣化硪， 水，及氛酸根類，這些分子都没有像多氣聪苯一般的毒性 ，都可以被排放到自然界中，但是，傳統的焚化法經常由 於燃燒不完全，未能將化學廢料完全分解而造成有毒廢料 的殘留，甚至在燃燒反應中新生成他種有毒化學分子。這 些反應不完全的燃燒，大抵上可以分為兩種原因··第一是 燃燒過程中氣氣供應不足或氣氣未能均勻分配以致反應不 I 完全；其二是燃燒溫度過低造成少量廢棄物未能充分被氣 化。 此外，對於有毒之固態廢棄物來說，有毒物質通常僅 是附著於固態廢棄物之表面或其内部孔洞中，傳統之焚化 法將整傾固體廢棄物燃燒焚化，處理時間之效率及成本上 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（2 ) 並不經濟。 再者，傳统的燃燒方式是讓燃料及廢棄物分別抵達燃 燒器後才進行混合.因此燃燒氣體與廢棄物混合均勻程度 受制於蓮送管線在燃燒器出口的大小及形狀，以致燃燒效 1 率不佳。 從物質的三相圖中（第1圖），可察覺固體受熱時， 當溫度到逹熔點，分子開始自由移動，而形成液體狀態。 如果逝續升高溫度加熱，分子所具有的動能增強，其具有 的能量漸能脱離液驩表面的束缚而蒸發，蒸氣壓隨溫度而 10 增高。當溫度到達沸點時，其蒸氣壓與外界的大氣壓力相 同，便開始汽化成氣態。但是物質在溫度、壓力雄缠增高 達某一點時，稱此點為臨界點（critical point),此時氣 態和液態合而為一，不論如何加大壓力和提髙溫度都無法 回到氣態或液態，此相區我們稱為超臨界狀態（Supercr ία t ica 1 Flu id Reg ion),處於此相匾的物質稱為臨界流體 (Supercritical Fluid),此流體的物理性質介於氣態和 液態之間。它的低黏度和高擴散能力近似於氣體，當裝谋 此種流體之容器擴充時，流體將有如氣體般快速佔滿整個 空間；此流體的密度近似於液體，分子間的引力與液體相 20 近，故有如液體般具有相當的溶解能力。由於以上特殊的 性質，超臨界流體被應用於當萃取的工具。 本紙張尺度逋用中國國家橾準（CNS ) Α4規格（210Χ 297公釐） (請先閲讀背面之注意事項再填寫本頁) 裟··A7 B7 293078 V. Description of the invention (i) (Please read the precautions on the back before filling in this page) This invention is about the system and method of using supercritical fluid to treat waste, especially about using supercritical fluid It is used as a system and method for premixing or dissolving organic waste residues in solvent and waste, and incineration of mixed organic waste by incinerator. Printed by the Employee Consumer Cooperative of the Central Standard Falcon Bureau of the Ministry of Economic Affairs Traditionally, the treatment method of organic waste is combustion. In a combustion tower, air or gas is injected into the fuel and waste, mixed, and then burned, burning at high temperature Below, the elements in organic compounds will combine with the element of oxygen, so-called gasification, and lose the original molecular structure and eliminate its toxicity. To give a simple example, polygas biphenyl is a common liquid organic The biggest use of waste materials is to use it as an insulator in power transformers. If gaseous biphenyl enters the human body, it will be very harmful to the body; however, the constituent elements of gaseous biphenyl are only Na, hydrogen, gas Only three. The high-temperature incineration method can theoretically decompose the gaseous biphenyl into two gasification, water, and chlorate. These molecules are not as toxic as the gaseous benzene, and can be discharged into the nature, but The traditional incineration method often results in the residue of toxic waste due to incomplete combustion and failure to completely decompose the chemical waste, and even generates other kinds of toxic chemical molecules in the combustion reaction. The incomplete combustion of these reactions can be roughly divided into two reasons. The first is that the gas supply is insufficient or the gas is not evenly distributed during the combustion process so that the reaction is not complete; the second is that the combustion temperature is too low, resulting in a small amount of waste The matter was not fully vaporized. In addition, for toxic solid waste, toxic substances are usually only attached to the surface of the solid waste or the internal holes, the traditional incineration method will burn the incineration of solid waste, the efficiency and cost The paper standard applies the Chinese National Standard (CNS) A4 specification (210X297 mm) A7 B7 printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. The invention description (2) is not economical. In addition, the traditional combustion method is to allow the fuel and waste to be mixed after reaching the burner. Therefore, the uniformity of the combustion gas and waste is limited by the size and shape of the lotus delivery line at the burner outlet, so that the combustion efficiency is 1%. Not good. From the three-phase diagram of the substance (Picture 1), it can be seen that when the solid is heated, when the temperature reaches the melting point, the molecules start to move freely and form a liquid state. If the temperature is continuously increased and heated, the kinetic energy of the molecule will increase, and the energy it has can gradually evaporate from the shackles of the liquid surface, and the vapor pressure will increase with temperature. When the temperature reaches the boiling point, its vapor pressure is the same as the outside atmospheric pressure, and it begins to vaporize into a gaseous state. However, when the temperature and pressure of the material increase to a certain point, this point is called the critical point. At this time, the gas and liquid are combined into one. No matter how you increase the pressure and raise the temperature, you cannot return to the gas or Liquid state, this phase area is called supercritical state (Supercr ία t ica 1 Flu id Reg ion), the material in this phase is called supercritical fluid, and the physical properties of this fluid are between gas and liquid state . Its low viscosity and high diffusion capacity are similar to gas. When the container for this fluid is expanded, the fluid will fill up the entire space as quickly as the gas; the density of this fluid is similar to that of liquid, and the attraction between molecules and liquid phase is 20 Recently, it has considerable dissolving ability like liquid. Due to the above special properties, supercritical fluids are used as extraction tools. This paper uses the Chinese National Standard (CNS) Α4 specification (210Χ 297mm) (Please read the precautions on the back before filling this page) 裟 ··
、1T 203078 五、發明説明（3 ) ♦超臨界流體的物理性質 密度 黏度 擴散傜數 (g ml'1) (泊） (cni S-1) 氣體 10-3 0.5-3.5 ( X 10--) 0.01-1.0 超臨 界 0.2-0.9 0.2-1.0 ( X 10-3) 3.3-0.1(X 10--) 流 體 液體 0.8-1.0 0.3-2.4 ( X 10-2) 0.5-2.0 ( X 10_s) (請先閲讀背面之注意事項再填寫本頁) 衮'、 1T 203078 V. Description of the invention (3) ♦ Physical properties of supercritical fluid Density, viscosity and diffusion number (g ml'1) (poise) (cni S-1) Gas 10-3 0.5-3.5 (X 10--) 0.01-1.0 Supercritical 0.2-0.9 0.2-1.0 (X 10-3) 3.3-0.1 (X 10--) Fluid liquid 0.8-1.0 0.3-2.4 (X 10-2) 0.5-2.0 (X 10_s) (please first Read the precautions on the back and then fill out this page) 衮 '
、1T 經濟部中央標率局員工消費合作杜印«. 針對以上之缺失，本發明之目的乃是要提供一種處理 L5 廢棄物、待別是化學、翳療、和有害事業廢棄物之集統與 方法，藉由此方法氣氣可均勻分配至菝棄物並與廢棄物在 抵逹燃燒器前就充分混合，使燃燒效率提升，燃燒溫度降 低，而且用來處理固態廢棄物時能將有毒物質自固態廢棄 物先行清洗出，單獼焚毅有毒物質，節省處理成本及時間 20 〇 上述本發明之目的乃藉由將廢棄物與超臨界流體預先 混合再送至之燃燒器中燃燒而達成。 亦即，本發明乃利用超臨界流體當作溶劑與廢棄物混 合或混合溶解，再將此超臨界流體；廢棄物混合物噴送入 -5 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） A7 B7 五、發明説明（4 ) —燃燒器中進行焚化。 本發明利用超臨界流體處理化學廢棄物進行焚化銷毀 ，具有以下的優點： (請先閱讀背面之注意事項再填寫本頁) 第一，超臨界流體對於有機分子可以有很好的溶解性 ' ，所以，選擇適當的超臨界流饈可以對欲被溶解的有機廢 棄物達到極佳的溶解及混合的效果。第二，若使用超流體 氣作為上述的超臨界流體溶劑，則被溶解到超臨界流體氣 中的廢棄物將可以被棰大量的氧分子所均勻包圍，在進行 焚化燃燒反應時上述的廢棄物將可以均勻且完全地被氣化 10 而消滅。第三，對於固態廢棄物的處理，使用超臨界流體 可以將上述的固態廢棄物中真正欲消滅的有棄物質具蘧擇 性地清洗出來，單獨焚毀有毒的物質，節省處理成本及時 間。第四，本發明的方法可以有效地將廢棄物在進入燃燒 器之前就均勻地與燃料或助燃物混合，不受管線在燃燒器 15 出口的大小形狀限制，提昇燃燒的效率，節省燃料成本。 經濟部中央標隼局員工消費合作社印製 第五，廢棄物極有可能在與超臨界狀態的燃料或助燃物就 先進行氣化反應，這是許多超臨界流體的持殊性質，如此 更可提高燃燒效率。第六，超臨界流體具有極佳的擴散性 (diffusivity),將廢棄物送入燃燒器時可有效帶動廢棄 20 物的分佈，達到均勻燃燒的效果。 為使本發明之目的、特擞及優黏更清楚，以下配合圖 式及實施例對本發明作詳細的說明。 第1圖為物質之三相圖； 第2圖為本發明之利用超臨界流髏處理廢棄物之糸統 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） A 7 B7 經濟部中央橾隼局員工消費合作杜印製 五 、發明説明 ( 5 ) 1 I 之 — 較 佳 實 施 例 示 意 圖 Ο 1 1 1 本 發 明 之 基 本 設 計 包 括 至 少 一 超 臨 界 流 體 供 m 裝 置 用 1 1 來 將 進 料 之 流 體 超 臨 界 化 並 提 供 超 臨 界 流 體 9 一 廢 棄 物 貯 1 I 請 1 1 存 及 混 合 裝 置 用 來 貯 存 及 混 合 送 入 之 廢 棄 物 及 超 臨 界 流 體 先 閱 1 I i 以 及 一 焚 化 裝 置 其 具 有 燃 燒 器 及 氣 體 源 用 以 供 應 燃 料 氣 讀 背 1 1 I 體 或 助 燃 氣 體 至 噴 射 燃 燒 器 〇 之 注 1 I 意 依 照 本 發 明 之 超 臨 界 流 體 供 應 裝 置 包 括 有 加 熱 器 壓 事 項 I 再4 1 _ .1 缩 機 以 及 氣 體 源 • 氣 體 源 可 依 需 要 供 應 大 氣 或 瓶 裝 氣 體 〇 填 寫 衣 瓶 裝 氣 體 可 為 燃 料 氣 體 如 氫 氣 > 一 氣 化 磺 天 然 氣 及 其 尽 頁 1 L0 他 烷 類 氣 體 肋 燃 氣 體 如 氣 氣 及 大 氣 t 或 不 可 燃 氣 體 如 二 1 1 氣 化 硪 » 二 者 皆 可 被 超 臨 界 化 後 做 為 載 體 氣 體 Ο 要 被 超 臨 1 1 界 化 之 氣 體 送 至 壓 縮 機 壓 縮 並 經 加 熱 器 加 熱 成 超 臨 界 流 體 1 訂 * 例 如 二 氣 化 m 在 攝 氏 31 .3度 及 72 .9大 氣 壓 下 就 形 成 超 臨 1 1 界 流 體 〇 1 1 15 依 照 本 發 明 可 依 需 要 m 擇 燃 料 氣 體 、 不 可 燃 氣 體 或 助 1 1 燃 氣 體 作 為 超 臨 界 流 體 » 亦 可 同 時 使 用 二 種 以 上 之 超 臨 界 流 體 參 例 如 使 用 超 臨 界 流 體 氣 對 某 些 極 性 強 的 有 機 廢 棄 物 Γ | 不 能 完 全 溶 解 1 此 時 就 可 m 擇 具 有 極 性 之 超 臨 界 流 體 作 為 1 1 載 醱 1 如 超 臨 界 流 體 Hz 0 並 與 超 臨 界 流 體 氣 混 合 來 逹 到 溶 1 1 20 解 及 混 合 廢 棄 物 之 效 果 〇 又 如 對 於 非 棰 性 之 菝 棄 物 9 則 可 1 1 使 用 二 氧 化 碩 超 臨 界 流 體 作 為 載 體 並 與 超 臨 界 流 體 氣 混 合 1 1 I 來 達 成 溶 解 及 混 合 廢 棄 物 之 效 果 〇 1 1 依 照 本 發 明 之 廢 棄 物 貯 存 及 m 合 裝 置 包 括 有 一 流 體 廢 1 1 棄 物 貯 存 槽 及 混 合 槽 〇 流體 7 - 廢 棄 物 先 貯 存 在 貯 存 槽 中 再 1 1 1 1 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇X：297公釐） 293078 A7 B7 五、發明説明（6 ) 送入混合槽與超臨界流體混合並被超臨界流醱攥帶進入焚 化裝置之噴射燃燒器中。如果要處理的是固態菝棄物，則 本發明之廢棄物貯存及混合裝置可包括一固態廢棄物貯存 槽及一研磨裝置。貯存在貯存槽中之固態廢棄物先經研磨 » 裝置研磨成碎K、細粒或粉末，送入混合槽中與超臨界流 體混合，超臨界流體將其表面及内層孔洞中之有毒物質洗 出，送入焚化裝置之噴射燒射器中進行燃燒。 以下藉由參考第1圖之較佳實施例再詳細說明本發明 之利用超臨界流體處理廢棄物条統之基本結構。如第1圖 0 所示，本發明之廢棄物處理条統包括超臨界流皤供應裝置 10,廢棄物貯存及混合裝置20及焚化装置30。 超臨界流體供應裝置10包括一超臨界流膿供應裝置本 醱11,其為一貯槽，一壓縮機12用來將氣體源13送來之氣 體壓縮逹到超臨界狀態，及一加熱器14,用以調控氣體達 15 到超臨界狀態，並預先調整臨超界流體的溫度以利其進入 經濟部中央標隼局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 廢棄物貯存及混合裝置20,進行與廢棄物之混合萃取動作 。氣體源包括一瓶裝氣體源131及大氣氣體源132。瓶裝氣 體可依箱要供應肋燃氣體1311,燃料氣體1312或不可燃氣 體1313。大氣氣體源132可依箱要供應肋燃氣體（空氣） 20 〇 廢棄物貯存及混合裝置20包括一廢棄物混合槽21用來 容纳廢棄物及送入之超臨界流體，流體廢棄物貯存槽22, 研磨裝置23及固態廢棄物貯存槽24。廢棄物混合槽21蓮包 含了兩値控制閥211, 212用以分別控制超臨界流體之進入 -8 -本紙張尺度適用令國國家標準（CNS ) A4規格（210X297公釐） A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明 ( 7 ) | 及 超 臨界 流 體 與 廢 棄 物 之混 合 物 的 送 出 f m 此 調 節 混 合 槽 I 21之 内壓 及 廢 棄 物 之 洗 出和 流 放 動 作 〇 流 體 廢 棄 物 221 ( 1 1 | 包 括 氣體 和 液 體 ) 先 進 入流 體 廢 棄 物 貯 存 槽 22再 經 由 泵 浦 1 I 請 1 1 222送至混合槽21並由控制閥223控 制 〇 當 混 合 槽 21因 超 臨 先 閱 1 | it 1 I 1 界 流 體進 入 而 内 壓 提 高 時， 控 制 閥 223可 蘭 閉 以 防 止 超 瞌 背 1 I 界 流 體及 廢 棄 物 的 混 合 物之 回 流 » 固 態 廢 棄 物 2 4 1則 先 進 冬 意 1 1 入 固 態廢 棄 物 貯 存 槽 24之中 經 研 磨 裝 置 23研 磨 粉 碎 送 入 混 事 項 I 合 槽 21中 〇 當 超 臨 界 流 體與 廢 棄 物 <=fs* 兀 金 混 合 後 « 閥 212 打 再 填 寫 本 1 r 開 9 混合 物 送 入 焚 化 裝 置3β進 行 燃 燒 〇 頁 1 1 '0 焚化 裝 置 30包 括 一 燃燒 裝 置 31 t 例 如 一 噴 射 燃 燒 器 » 1 1 及 一 氣體 源 32 〇 氣 體 源 32包 括 瓶 裝 氣 體 源 321 及 大 氣 氣 腥 1 1 源 322 , 瓶 裝 氣 體 源 321包 括 助 燃 氣 3211 如 氣 1 及 燃 料 氣 1 訂 體 3212 , 如 氫 〇 例 如 以 氫氣 作 燃 燒 氣 體 時 > 氫 氣 經 細 管 孔 1 1 噴 入 燃燒 室 中 • 當 超 臨 界流 體 攜 帶 液 態 化 學 廢 棄 物 進 人 上 1 1 I 5 述 燃 燒室 時 ， 點 火 讓 氫 、氧 進 行 燃 燒 反 應 〇 在 此 燃 燒 反 應 1 1 中 溫 度可 達 到 非 常 高 1 因而 被 超 臨 界 流 體 所 包 圍 的 化 學 廢 棄 物 可被 均 勻 且 » *-» 兀 金 的 燃燒 達 到 完 全 銷 毅 廢 棄 物 之 百 的 〇 1 1 由以 上 實 施 例 可 知 ，本 發 明 先 使 助 燃 氣 體 ( 氣 氣 ) 1 燃 料 氣體 或 非 燃 性 氣 體 或配 合 使 用 二 者 以 上 成 超 臨 界 流 體 1 1 ：!0 , 再 溶解 廢 棄 物 並 與 廢 棄物 混 合 後 » 再 送 入 焚 化 裝 置 焚 化 1 1 之 糸 統與 方 法 不 但 氣 氣可 均 勻 分 配 至 廢 棄 物 使 燃 燒 效 率 1 1 提 高 .燃 燒 溫 度 降 低 » 對於 有 毒 之 固 態 廢 棄 物 還 可 先 將 有 1 1 毒 物 質清 洗 出 來 參 而 且 構造 簡 單 • 使 用 容 易 1 因 此 極 適 合 1 1 裂 作 成為 小 型 燃 燒 機 » 增加 .9 _ 其 實 用 性 〇 1 1 1 1 本紙張尺度適用中國國家標準（CNS〉A4規格（210 X 297公釐） A7 B7 五、發明説明（8 ) 此外本發明所提供的超臨界流塍燃燒法不只適用於化 學廢棄物的處理，更可以使用於具有生物傳染性危險的發 療菝棄物或含劇毒物質之有害事業廢棄物的銷毅，用途甚 廣。 i 雖然本發明已以較佳實施例掲露如上，然其並非用以 限定本發明，任何熟習此項技S者，在不脫離本發明之精 神和範圍内，當可作些許之更動與潤飾，因此本發明之保 護範圔當視後附之申誚專利範圍所界定者為準。 L0 ft 1^^1. ^^^1 ^^^1 l^n In —-^^1 ml nf^i TJ J^i J (請先閲讀背面之注意事項再填寫本頁) 5 11, 1T Ministry of Economic Affairs, Central Standardization Bureau, employee consumption cooperation Du Yin «. In view of the above deficiencies, the purpose of the present invention is to provide a comprehensive treatment of L5 waste, especially chemical, turbid, and hazardous business waste And method, by this method gas can be evenly distributed to Smilax waste and fully mixed with the waste before reaching the burner, so that the combustion efficiency is improved, the combustion temperature is reduced, and when used to treat solid waste, it can be toxic The material is first washed out from the solid waste, and the single toxic substance is toxic, saving processing cost and time. The purpose of the present invention described above is achieved by pre-mixing the waste with the supercritical fluid and sending it to the burner for combustion. That is, the present invention uses supercritical fluid as a solvent to mix or dissolve with waste, and then dissolve the supercritical fluid; the waste mixture is sprayed into -5-This paper scale is applicable to China National Standard (CNS) A4 specification ( 210X297mm) A7 B7 V. Description of the invention (4)-Incineration in the burner. The present invention uses supercritical fluid to treat chemical waste for incineration and destruction, and has the following advantages: (please read the precautions on the back before filling this page) First, supercritical fluid can have good solubility for organic molecules. Therefore, selecting the appropriate supercritical fluid can achieve excellent dissolution and mixing of the organic waste to be dissolved. Second, if superfluid gas is used as the above-mentioned supercritical fluid solvent, the waste dissolved in the supercritical fluid gas can be evenly surrounded by a large amount of oxygen molecules. Will be uniformly and completely vaporized 10 and eliminated. Third, for the treatment of solid wastes, the use of supercritical fluids can selectively wash out the above-mentioned solid wastes that are truly intended to be eliminated, and incinerate toxic substances separately, saving disposal costs and time. Fourth, the method of the present invention can effectively mix the waste with fuel or combustion aid evenly before entering the burner, and is not limited by the size and shape of the pipeline at the outlet of the burner 15 to improve the efficiency of combustion and save fuel costs. Printed by the Ministry of Economy ’s Central Standard Falcon Bureau ’s Employee Consumer Cooperatives. Fifth, it is highly likely that waste will undergo gasification reactions with supercritical fuels or combustibles first. Improve combustion efficiency. Sixth, the supercritical fluid has excellent diffusivity. When the waste is sent to the burner, it can effectively drive the distribution of the waste 20 and achieve the effect of uniform combustion. In order to make the purpose, features and superiority of the present invention clearer, the following describes the present invention in detail with reference to the drawings and examples. Figure 1 is the three-phase diagram of the material; Figure 2 is the system of the present invention for the treatment of waste by supercritical flow. The paper standard is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm) A 7 B7 Economy Ministry of Central Falcon Bureau employee consumption cooperation Du Printed 5. Description of the invention (5) 1 I-the schematic diagram of the preferred embodiment Ο 1 1 1 The basic design of the present invention includes at least one supercritical fluid for the m device 1 1 The feed fluid is supercritical and provides supercritical fluid. 9 A waste storage 1 I please 1 1 storage and mixing device used to store and mix the incoming waste and supercritical fluid. 1 I i and an incinerator With burner and gas source for supplying fuel gas reading back 1 1 I body or combustion-supporting gas to injection burner. Note 1 I means supercritical flow according to the invention The body supply device includes heater pressure items, and then 4 1 _ .1 compressor and gas source. • The gas source can supply the atmosphere or bottled gas as required. Fill in the bottled bottle. The gas can be fuel gas such as hydrogen gas. Exhaust page 1 L0 Other gas ribs gas such as gas and atmosphere t or non-combustible gas such as 2 1 1 Gasification sieve »Both can be supercriticalized as carrier gas Ο To be super pro 1 1 The boundary gas is sent to the compressor for compression and heated by the heater to form a supercritical fluid. 1 * For example, the second gasification m will form a super-precision fluid at 11.3 degrees Celsius and 72.9 atmospheres. According to the present invention, fuel gas, non-combustible gas or auxiliary fuel gas can be selected as the supercritical fluid as required. Critical fluid parameters such as the use of supercritical fluid gas for certain highly polar organic wastes Γ | can not be completely dissolved 1 At this time, you can choose a polar supercritical fluid as 1 1 loaded with 1 such as supercritical fluid Hz 0 and The supercritical fluid gas is mixed to dissolve 1 1 20 to dissolve and mix the effects of waste. Also for non-smiling Smilax waste 9 can be used. 1 1 Use supercritical fluid dioxide as a carrier and mix with the supercritical fluid gas Mix 1 1 I to achieve the effect of dissolving and mixing waste. 0 1 The waste storage and mixing device according to the present invention includes a fluid waste 1 1 waste storage tank and mixing tank. Fluid 7-waste is stored in storage first 1 1 1 1 in the tank. The size of this paper is in accordance with the Chinese National Standard (CNS) A4 (21〇X: 297 mm) 293078 A7 B7 5. Description of the invention (6) It is fed into the mixing tank and mixed with the supercritical fluid and is super critical Po grip into the incinerator with the burner apparatus of the injector. If the solid Smilax waste is to be processed, the waste storage and mixing device of the present invention may include a solid waste storage tank and a grinding device. The solid waste stored in the storage tank is first ground by grinding »The device is ground into crushed K, fine particles or powder, and sent into the mixing tank to be mixed with the supercritical fluid. The supercritical fluid will wash out the toxic substances on the surface and the inner pores , Sent to the jet burner of the incinerator for combustion. The basic structure of the waste treatment system using supercritical fluid of the present invention will be described in detail below by referring to the preferred embodiment of FIG. 1. As shown in FIG. 1, the waste treatment system of the present invention includes a supercritical fluid supply device 10, a waste storage and mixing device 20, and an incineration device 30. The supercritical fluid supply device 10 includes a supercritical fluid supply device main unit 11, which is a storage tank, a compressor 12 for compressing the gas sent from the gas source 13 to a supercritical state, and a heater 14, It is used to regulate the gas from 15 to supercritical state, and pre-adjust the temperature of the super-superfluid fluid to facilitate it to be printed by the Employee Consumer Cooperative of the Central Standard Falcon Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) Waste The storage and mixing device 20 performs a mixed extraction operation with waste. The gas source includes a bottled gas source 131 and an atmospheric gas source 132. Bottled gas can be supplied with ribbed gas 1311, fuel gas 1312 or non-combustible gas 1313 according to the tank. The atmospheric gas source 132 can supply the ribbed gas (air) according to the tank 20 〇The waste storage and mixing device 20 includes a waste mixing tank 21 for accommodating the waste and the supercritical fluid fed in, and the fluid waste storage tank 22 , Grinding device 23 and solid waste storage tank 24. The waste mixing tank 21 contains two control valves 211, 212 to control the entry of supercritical fluids separately -8-This paper size is applicable to the national standard (CNS) A4 specification (210X297 mm) A7 B7 Central Ministry of Economic Affairs Printed by the Bureau of Standards and Employee Consumer Cooperative V. Description of the invention (7) | and the delivery of the mixture of supercritical fluid and waste fm This adjusts the internal pressure of the mixing tank I 21 and the washing and discharge of waste. Fluid waste 221 (1 1 | Including gas and liquid) First enter the fluid waste storage tank 22 and then send it to the mixing tank 21 via the pump 1 I 1 1 222 to be controlled by the control valve 223. When the mixing tank 21 is due to exceed the first reading 1 | When it 1 I 1 fluid enters and the internal pressure increases, the control valve 223 can be closed to prevent the backflow of the mixture of 1 I fluid and waste »Solid waste 2 4 1 Advanced Winter 1 1 Enter solid Grinded in the waste storage tank 24 The device 23 is grinded and crushed and fed into the mixing tank I. When the supercritical fluid is mixed with the waste < = fs * metal, the valve 212 is opened and filled in again. 1 r Open 9 The mixture is sent to the incinerator 3β for combustion. Page 1 1 '0 The incinerator 30 includes a combustion device 31 t such as a jet burner »1 1 and a gas source 32. The gas source 32 includes a bottled gas source 321 and atmospheric gaseous source 1 1 322, and the bottled gas source 321 includes Combustion gas 3211 such as gas 1 and fuel gas 1 are customized 3212, such as hydrogen. For example, when hydrogen is used as the combustion gas> Hydrogen is injected into the combustion chamber through the thin tube hole 1 1 • When the supercritical fluid carries liquid chemical waste into people 1 1 I 5 When the combustion chamber is described, ignition allows hydrogen and oxygen to undergo a combustion reaction. In this combustion reaction 1 1 the temperature can reach very high 1 so that the chemical waste surrounded by supercritical fluid can be uniform and »*-» Burning Achieving 100% of the total sales of waste. From the above examples, it can be seen that the present invention first makes the combustion-supporting gas (gas gas) 1 fuel gas or non-combustible gas or use both or more into a supercritical fluid 1 1:! 0, after re-dissolving the waste and mixing with the waste »then sent to the incinerator for incineration 1 1 The system and method not only can the gas be evenly distributed to the waste so that the combustion efficiency is increased 1 1 The combustion temperature is reduced» For toxic solid waste It can also be cleaned with 1 1 toxic substances first and its structure is simple • easy to use 1 so it is very suitable for 1 1 split into small burners »increased. 9 _ its practicality 〇 1 1 1 1 This paper size is suitable for Chinese countries Standard (CNS> A4 specification (210 X 297 mm) A7 B7 V. Description of the invention (8) In addition, the supercritical fluid combustion method provided by the present invention is not only applicable to the treatment of chemical waste, but also can be used for biological infections Sexual danger Smilax disposable hair treatment or hazardous industrial waste containing Yi pin of toxic substances, uses a wide range. i Although the present invention has been exposed as above with preferred embodiments, it is not intended to limit the present invention. Anyone who is familiar with this technology can make some changes and modifications without departing from the spirit and scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the scope defined in the attached patent application. L0 ft 1 ^^ 1. ^^^ 1 ^^^ 1 l ^ n In —- ^^ 1 ml nf ^ i TJ J ^ i J (Please read the precautions on the back before filling this page) 5 11
J 經濟部中央標隼局員工消費合作杜印製J Produced by the Central Standard Falcon Bureau of the Ministry of Economic Affairs Employee Consumer Cooperation
0 IX 本紐尺度適用中國國家揉率（CNS ) A4⑺U7公釐）0 IX The New Zealand scale applies to China ’s national rubbing rate (CNS) A4⑺U7mm)