經濟部中央標準局IS：工消f合作社印製 五、發明説明（l) 本發明是有關一'種不含氣化棚，可纺成纖維之玻璃組 合物；亦有關一種在纺絲機頭内將本發明組合物紡成絲的 方法，該紡絲機頭像由一種合金製成，此合金材料偽經過 機械合金處理或氣化物分散強化處理過。本發明亦有關玻 璃纖維絶緣材，係由本發明組合物所産製而得者。 已知玻璃組合物可用在以離心纺絲機頭將玻璃纖維化 的技術上。組合物内常慘混氧化硼，俾提供溫度/黏度特 性，使得玻璃可在足夠低溫下，自由通過離心紡絲機頭壁 之孔口，以防過度腐触與侵触紡絲機頭。使用氣化硼産生 一問題是：硼具揮發性，會從玻璃馆槽逸出而引起污染問 題。此外，硼易冷凝於再生器上，因而使再生器積垢，並 使再生器無法用於改進燃燒燃料的玻璃燦槽（fuel fired glass melting tank)之熱效率 〇 GB 2 041 910提議減少或消除氧化硼，結果導致液相 線溫度以及氣化錯或氣化银之含量升高。氣化硼含量降低 的組合物實際上根本無法藉先前紡絲技術，於工業基礎上 予以纖維化。有人提議一種採用新式紡絲機頭形狀的技術 ，但實際上，當以習知合金製成此種紡絲機頭時，，纺絲機 頭的腐触程度高，令人無法接受。同時，依此專利案之玻 璃組合物其耐久性又太低。 美國第4 402 767號專利提出一種新親紡絲機頭之製 造方法，結合溫熱加工、退火與熱形成等過程，生産以機 械方式合金化的合金或以氣化物分散強化的合金。此種紡 (請先閲讀背面之注意事項再填寫本頁) 冬紙張尺羊遑用中困國家標準(CNS)T4^/2K)x297公 Λ 6η 6 五、發明説明（2) 絲機頭據稱對箱化玻璃的侵独具有絶佳的抗性，而且可方§ 高速1315 C之高溫下生産玻璃纖雜和礦物滅:該專利說明 書中並未述及製造玻璃纖維之任何細節:， 問題在於要找出不含硼的玻璃組合物，其除了具有戸月: 需要的耐久性以外，同時又須可用在如美國專利第4 402 767號所述之高溫纺絲機頭。玻璃不含氣化硼雖然會使其 在水液中的耐久性變差，但吾等已鑑定出某一範圍之組合 物具有令人滿意的耐久性。 根據本發明，一種不含氣化硼，可紡成纖維之玻璃組 合物包含下列各成分，以重量百分率（vrt-%)表示：Printed by the Central Bureau of Standards of the Ministry of Economic Affairs: Printed by the Gongxiao F Cooperative V. Description of the invention (l) The present invention relates to a glass composition that does not contain a gasification shed and can be spun into fibers; The method of spinning the composition of the present invention into silk, the spinning machine head is made of an alloy, and this alloy material is pseudo-processed by mechanical alloy treatment or gasification dispersion strengthening treatment. The present invention also relates to glass fiber insulating materials, which are produced from the composition of the present invention. It is known that the glass composition can be used for the technique of fiberizing glass with a centrifugal spinning head. Boron oxide is often miscible in the composition to provide temperature / viscosity characteristics so that the glass can pass freely through the orifice of the centrifugal spinning head wall at a sufficiently low temperature to prevent excessive corrosion and invasion of the spinning head. One problem with the use of vaporized boron is that boron is volatile and will escape from the glass pavilion and cause pollution problems. In addition, boron easily condenses on the regenerator, thus fouling the regenerator and making the regenerator unusable for improving the thermal efficiency of the fuel fired glass melting tank. GB 2 041 910 proposes to reduce or eliminate oxidation Boron results in an increase in the liquidus temperature and the content of vaporization error or vaporized silver. The composition with a reduced boron content cannot actually be fiberized on an industrial basis with previous spinning technology. Someone has proposed a technique that uses the shape of a new spinning head, but in fact, when such a spinning head is made of a conventional alloy, the degree of corrosion of the spinning head is unacceptably high. At the same time, the durability of the glass composition according to this patent is too low. U.S. Patent No. 4 402 767 proposes a method of manufacturing a new spinning head, which combines warm processing, annealing and thermal forming processes to produce an alloy alloyed mechanically or an alloy strengthened by gasification dispersion. This type of spinning (please read the precautions on the back before filling in this page) National Standard (CNS) T4 ^ / 2K for the winter paper ruler (XS) T4 ^ / 2K) x297 public Λ 6η 6 Fifth, the invention description (2) silk head data It is said that it has excellent resistance to the invasion of boxed glass, and it can produce glass fiber and minerals at a high temperature of 1315 C. The patent specification does not mention any details of manufacturing glass fiber: the problem lies in To find a boron-free glass composition, in addition to the durability required, it must also be used in high-temperature spinning heads as described in US Patent No. 4 402 767. Although the glass does not contain vaporized boron, although its durability in water is deteriorated, we have identified a range of compositions with satisfactory durability. According to the present invention, a glass composition that does not contain vaporized boron and can be spun into fibers contains the following components, expressed in weight percent (vrt-%):
Si〇2 66-73 A 1 2 0 3 0.8-5 R a 0 ^ Na 2〇 + Ka 0 14-17.5 CaO 6.5-12 Si〇2 + A 1 a 0 a 69-74 (請先閲讀背面之注意事項再填寫本頁) 裝· 經濟部中央標準局员工消t合作社印製 此種玻璃在高達約1200°C之溫度時具有1000泊（poise)或 以下之黏度，且液相線至少比黏度1000泊時的溫度低130 °C 〇 此組合物也可含有：〇-2%Fe3〇3 ; 0-5%Mg〇 ; 0-0.6 %S0：3。全部皆以wt-%表示。 各組成分的含量以在下列所示之範圍内為較佳，以wt —%表示： SiOa 67-72.4 本紙張尺A逍用中國S家«準(CNS)甲4規格(210X297公龙) 五、發明説明（3 ) Λ 6 13 6 經濟部中央標準局工消#合作社印製 A1 2〇3 1-4 Ra〇 14.5-17 Ka〇 0.5-2 Naa〇 13.5-16.5 CaO 7-11.2 Fe = 03 0.1-2.5 MgO 0.2-4.4 Si〇a + AUOa 70-73.7 而其中，各組成分之含量以在下列所示之範圍内為最 佳，以wt-9^表示： si〇a 67-70 A1 =〇3 2-4 NasO 14-15.5 Ka〇 0.5-1.5 ΜεΟ 3-4.5 CaO 7-8.5 Fe2〇3 0.3-2 S〇3 0-0.3 SlOa + AlaOa 70-72 Ha3〇 + K2〇 15-16.5 為獾致低液相線溫度 ，需要高量的Na2〇,不過MgO的 較佳狹窄含量範圍，使Na 2〇的需要最減至最低，因而提供 最佳耐久性，同時將液相線維持於tblOOO泊黏度溫度至少 (請先閲讀背面之注意事項再填寫本頁) 裝· -線· 本紙張尺度逍用中國國家標毕(CNS)T4規格(210><297公放) t 、r ·\ Λ 6 Ιϊ 6 經濟部中央楳準局员工消費合作社印製 五、發明説明（4 ) 低160°C之溫度；比1170°C為低 謹以下列實例1 -28以說明本發明之内容。實例中SO 3 、及Fe2〇3之低含量係以最低值記錄。事實上，這些化 合物的含置很低，如同原料中的雜質，對玻璃纖維的性質 並無顯著影馨。實例及耐久性試驗細節列於表1。須注意 ，實例18不在本發明之範圍内，因其氣化ig含量低，使得 耐久性不足。 目前並沒有國際測試標準以評估某種玻璃是否適用於 玻璃纖維絶緣用途上。目前大多採用ISO 719實驗室用品 試驗，原因在於此試驗提供玻璃水液耐久性與耐候性一値 有用的指標。在此試驗中，2g玻璃粒以蒸踏水在98 °C的溫 度下處理60分鐘，然後把宰出來的齡用0.01M HC1滴定。 耐久性係以每克玻璃翠出之齡量來表示，其中驗係由中和 所需酸量計算而得的。玻璃滅之相關等級為：ISO第3级-62至264x/g驗/g ;第4級-265至620 wg/g。玻璃滅 屬於第3級者較佳；但因絶緣性能為玻璃與樹脂粘合劑二 者之函數，且已有粘合劑可供用於較高度釋放性的玻璃， 故良好的第4級玻璃滅也可接受。評級為第3級者偽屬良好 ，而第4級者可以接受，但不如第3级好。 (請先閲讀背面之注意事項再填寫本頁) 裝· 訂.·線. 本紙張尺度逍用中《國家標毕(CNS)甲4規格(210父297公釐） Γ·3 ό <L* 2 66 ΛΒ 五、發明説明（5) 表1 經濟部中央標準局员工消f合作社印製 實例 1 2 3 4 5 6 7 8 Si〇2 70 69 68 67 70 69 67 67 A1 2〇3 1 2 3 4 3 3 3 3 S 1 0 2 *" A 1 2 0 3 71 71 71 71 73 72 70 70 F〇2〇3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 CaO 8 8 8 8 8 8 8 9 MgO 4 4 4 4 4 4 4 4 Na = 0 15.5 15.5 15.5 15.5 13.5 14.5 16.5 15.5 K=0 1 1 1 1 1 1 1 1 R=0 16.5 16.5 16.5 16.5 14.5 15.5 17.5 16.5 SO 3 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Tlog3 1146 1150 1155 1159 1191 1173 1136 1142 液相線 952 964 982 1002 1012 1002 980 1018 UgRaO/g 307 270 260 248 186 251 406 285 等级 4 4 3 3 3 3 4 4 (請先閱讀背而之注意事項再填窝本頁) 裝- 線· 本紙5艮尺度遑用中S S家標準(CNS)甲4規格(210X297公釐)Si〇2 66-73 A 1 2 0 3 0.8-5 R a 0 ^ Na 2〇 + Ka 0 14-17.5 CaO 6.5-12 Si〇2 + A 1 a 0 a 69-74 (Please read the notes on the back first Please fill in this page for details.) The glass printed by the Ministry of Economic Affairs Central Standards Bureau ’s employees ’cooperatives has a viscosity of 1000 poise or less at a temperature of up to about 1200 ° C, and the liquidus has a viscosity of at least 1000 The temperature at 130 ° C is 130 ° C lower. The composition may also contain: 0-2% Fe3〇3; 0-5% Mg〇; 0-0.6% S0: 3. All are expressed in wt-%. The content of each component is preferably within the range shown below, expressed in wt-%: SiOa 67-72.4 The paper ruler A Xiao uses the Chinese S home «quasi (CNS) A 4 specifications (210X297 male dragon) V 2. Description of the invention (3) Λ 6 13 6 Printed by the Central Standards Bureau of the Ministry of Economy #Cooperatives A1 2〇3 1-4 Ra〇14.5-17 Ka〇0.5-2 Naa〇13.5-16.5 CaO 7-11.2 Fe = 03 0.1-2.5 MgO 0.2-4.4 Si〇a + AUOa 70-73.7 and among them, the content of each component is best in the range shown below, expressed as wt-9 ^: si〇a 67-70 A1 = 〇3 2-4 NasO 14-15.5 Ka〇0.5-1.5 ΜεΟ 3-4.5 CaO 7-8.5 Fe2〇3 0.3-2 S〇3 0-0.3 SlOa + AlaOa 70-72 Ha3〇 + K2〇15-16.5 is a badger To lower the liquidus temperature, a high amount of Na2〇 is required, but the preferably narrow range of MgO content minimizes the need for Na2〇 and thus provides the best durability while maintaining the liquidus at tblOOO. Viscosity temperature is at least (please read the precautions on the back before filling in this page) Install · -Line · This paper scale is free to use China National Standard (CNS) T4 specifications (210 > < 297 public release) t 、 r · \ Λ 6 Ιϊ 6 warp Printed by the Employee Consumer Cooperative of the Central Department of Economics, Ministry of Economic Affairs 5. Description of the invention (4) The temperature is 160 ° C lower; it is lower than 1170 ° C. The following examples 1-28 are used to illustrate the content of the invention. In the examples, the low content of SO 3 and Fe 2 O 3 is recorded at the lowest value. In fact, the content of these compounds is very low, just like the impurities in the raw materials, it has no significant impact on the properties of glass fibers. Examples and details of durability tests are listed in Table 1. It should be noted that Example 18 is not within the scope of the present invention, and its low gasification ig content makes the durability insufficient. There is currently no international test standard to assess whether a glass is suitable for fiberglass insulation applications. At present, most of the ISO 719 laboratory supplies tests are used because this test provides a useful indicator of the durability and weather resistance of glass water. In this test, 2 g of glass pellets were treated with distilled water at a temperature of 98 ° C for 60 minutes, and then the slaughtered age was titrated with 0.01 M HC1. Durability is expressed in terms of age per gram of glass, where the test is calculated from the amount of acid required for neutralization. The relevant levels of glass extinction are: ISO level 3 -62 to 264x / g inspection / g; level 4 -265 to 620 wg / g. Glass extinction belongs to the third level; however, because the insulation performance is a function of both glass and resin adhesives, and existing adhesives are available for glass with a higher degree of release, the good level 4 glass extinction Also acceptable. Those with a rating of 3 are pseudo-good, while those with a rating of 4 are acceptable, but not as good as those with a rating of 3. (Please read the precautions on the back before filling in this page) Binding · Ordering · Line. This paper is used in "National Standard (CNS) A 4 specifications (210 father 297 mm) Γ · 3 ό < L * 2 66 ΛΒ V. Description of the invention (5) Table 1 Example of printing by the Employees ’Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 1 2 3 4 5 6 7 8 Si〇2 70 69 68 67 70 69 67 67 A1 2〇3 1 2 3 4 3 3 3 3 S 1 0 2 * " A 1 2 0 3 71 71 71 71 73 72 70 70 F〇2〇3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 CaO 8 8 8 8 8 8 8 9 MgO 4 4 4 4 4 4 4 4 Na = 0 15.5 15.5 15.5 15.5 13.5 14.5 16.5 15.5 K = 0 1 1 1 1 1 1 1 1 R = 0 16.5 16.5 16.5 16.5 14.5 15.5 17.5 16.5 SO 3 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Tlog3 1146 1150 1155 1159 1191 1173 1136 1142 Liquidus 952 964 982 1002 1012 1002 980 1018 UgRaO / g 307 270 260 248 186 251 406 285 Level 4 4 3 3 3 3 4 4 (Please read the notes before you read (Filling this page) Packing-Line · This paper is 5 gram size and is used in SS home standard (CNS) A 4 specifications (210X297 mm)
66 AB 五、發明説明（厶） 表1 經 濟 部 屮 央 標 準 局 工 消 费 合 作 社 印 % 實例 9 10 11 12 13 14 15 16 Si〇a 69 68.5 69 68 72.4 70 68 68 A 1 2〇3 3 3 3 3 1.3 3 4 3 Si〇2+Al2〇3 72 71.5 72 71 73.7 73 72 71 Fe2〇3 0.3 0.3 0.3 1.3 0.1 0.3 0.3 1.9 CaO 7 8 7.5 7.5 11.2 8.3 7.5 8 MgO 4 4 4 4 0.2 3.9 3.5 3.9 Ha2〇 15.5 15 15 15 14 13.5 15.5 14 K2〇 1 1 1 I 0.5 0.9 1 1 r2〇 16.5 16 16 16 14.5 14.4 16.5 15 SO 3 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Tlog3 1166 1163 1169 1163 1170 1195 1158 1170 液相線 950 990 966 1000 1018 1018 996 1026 UgRaO/g 298 258 259 253 286 231 256 195 等級 4 3 3 4 4 3 3 (請先閱讀背面之注意事項再塡寫本頁) 裝- 訂 線- Λ1 i 2 66 Λ° 五、發明説明（7 ) 表1 經濟部中央標準局员工消费合作杜印製 實例 17 18 19 20 21 22 23 24 Si〇2 68.5 71 68 69 68 67 66 66 A 1 2〇3 3 0 3 3 3 3 3 4 Si〇2+Al2〇3 71.5 71 71 72 71 70 69 70 F02〇3 0.3 0.3 0.3 0.3 1.3 2.3 3.3 2.5 CaO 7.6 8 8 7.5 7.5 7.5 7.5 7.8 MsO 4.4 4 4 4 4 4 4 3 Na=0 15 15.5 15.5 15 15 15 15 15.5 K2〇 1 1 1 1 1 1 1 1 r2〇 16 16.5 16.5 16 16 16 16 16.5 SO 3 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Tlog3 1165 1142 1154 1170 1164 1157 1150 1155 液相線 r 1006 940 981 974 994 1002 1024 1010 UgRaO/g 251 474 251 259 253 236 239 240 等級 3 4 3 3 3 3 3 3 (請先閲讀背而之注意事項再填窝本頁) 裝‘ 線- 本紙張尺度逍用中困B家標毕(CNS)甲4規格（210X297公A) Λ 6 Β 6 五、發明説明（S) 表1 經濟部中央標準局貝工消费合作杜印製 實例 25 26 27 28 si〇2 66 70 69.5 70.5 A1 2〇3 4 2 2 3 S 10 2 +Δ1 2 0 3 70 72 71.5 73.5 Fes〇3 2.5 0.5 0.5 0.3 CaO 6.8 8.5 8.5 8 Ms〇 4 4 4 4 Na2〇 15 14.5 14 13 K=0 1.5 0.5 1.5 1 r2〇 16.5 15 15.5 14 S〇3 0.2 0 0 0.2 Tlog3 1164 1166 1165 液相線 1014 1006 1005 UgRaO/K 206 261 229 186 等級 3 3 3 3 (請先閲讀背面之注意事項再填寫本頁) 裝· •：訂·. 線· 私紙》尺度边用中囷困家標準（CNS)甲4規格（210X297公；¢)66 AB V. Description of Invention (厶) Table 1 Printed by the Industrial and Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy Example 9 10 11 12 13 14 15 16 Si〇a 69 68.5 69 68 72.4 70 68 68 A 1 2〇3 3 3 3 3 1.3 3 4 3 Si〇2 + Al2〇3 72 71.5 72 71 73.7 73 72 71 Fe2〇3 0.3 0.3 0.3 1.3 0.1 0.3 0.3 1.9 CaO 7 8 7.5 7.5 11.2 8.3 7.5 8 MgO 4 4 4 4 0.2 3.9 3.5 3.9 Ha2 〇15.5 15 15 15 14 13.5 15.5 14 K2〇1 1 1 I 0.5 0.9 1 1 r2〇16.5 16 16 16 14.5 14.4 16.5 15 SO 3 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Tlog3 1166 1163 1169 1163 1170 1195 1158 1170 liquid phase Line 950 990 966 1000 1018 1018 996 1026 UgRaO / g 298 258 259 253 286 231 256 195 Level 4 3 3 4 4 3 3 (please read the precautions on the back before writing this page) Binding-Strapping-Λ1 i 2 66 Λ ° V. Description of the invention (7) Table 1 Example of du printing for consumer cooperation of the Central Bureau of Standards of the Ministry of Economy 17 18 19 20 21 22 23 24 Si〇2 68.5 71 68 69 68 67 66 66 A 1 2〇3 3 0 3 3 3 3 3 4 Si〇2 + Al2〇3 71.5 71 71 72 71 70 69 70 F02〇3 0.3 0.3 0.3 0.3 1.3 2.3 3.3 2.5 CaO 7.6 8 8 7.5 7.5 7.5 7.5 7.8 MsO 4.4 4 4 4 4 4 4 4 3 Na = 0 15 15.5 15.5 15 15 15 15 15.5 K2〇1 1 1 1 1 1 1 1 r2〇16 16.5 16.5 16 16 16 16 16.5 SO 3 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Tlog3 1165 1142 1154 1170 1164 1157 1150 1155 Liquidus r 1006 940 981 974 994 1002 1024 1010 UgRaO / g 251 474 251 259 253 236 239 240 Level 3 4 3 3 3 3 3 3 (please read the back first Please pay attention to this matter and fill in this page.) Installed-Line-This paper is for the purpose of easy use and trapping. B Home Standard (CNS) A 4 specifications (210X297 public A) Λ 6 Β 6 V. Description of Invention (S) Table 1 Ministry of Economy Example of du printing by the Central Standards Bureau's Beigong Consumer Cooperation 25 26 27 28 si〇2 66 70 69.5 70.5 A1 2〇3 4 2 2 3 S 10 2 + Δ1 2 0 3 70 72 71.5 73.5 Fes〇3 2.5 0.5 0.5 0.3 CaO 6.8 8.5 8.5 8 Ms〇4 4 4 4 Na2〇15 14.5 14 13 K = 0 1.5 0.5 1.5 1 r2〇16.5 15 15.5 14 S〇3 0.2 0 0 0.2 Tlog3 1164 1166 1165 liquidus 1014 1006 1005 UgRaO / K 206 261 229 186 Level 3 3 3 3 (please read the precautions on the back before filling in this page) Pack · •: Order ·. Line · Private Paper "Standards for the middle-aged sleepy family (C NS) A 4 specifications (210X297 g; ¢)