TW210992B - - Google Patents

Description

Λ (i 15 6 210992 V. Description of the invention) This invention relates to the technology for recovering organic liquids and petroleum-related products from water bodies, soil, water flow, ship stern, and solid surfaces such as garages and factory floors, sales decks and similar solid surfaces, These petroleum products include crude oil and refined petroleum distillates. Many methods have been proposed for the treatment of petroleum-related pollutants. Many materials have been proposed for use as oil spill absorbers, including a large amount of straw , Clay, silica or Kieselguhr particles. At the same time, it has also been proposed to use foamed polymer materials such as porous polystyrene particles and porous polyethylene wool, or solid inorganic fillers Other additives are used together. US Patent No. 3, 518, 183 discloses the use of a mono-area large-area monovinyl aromatic conjugated diene block copolymer (Monoinyl arene-Conjugated diene block copolymer) and oil traces on the water In contact with oil spills, draw oil into the block copolymer, and then separate the block copolymer filled with oil from the water. The polymer can be combined with the ring-shaped tubular net surrounding the pit platform in the sea; it can also be combined with railings and embankments to prevent oil traces from drifting into the port or along part of the coastline. US Patent No. 4,941,978 discloses the use of a styrene A granular elastic composition of k-shaped copolymer and ethylene / butene copolymer elastomer to treat oil spills on water. The present invention relates to the use of a pelletized thermoplastic elastomer block copolymer to recover from soil and water The technology of oil and other liquid contaminants. One of the concepts of the present invention relates to a method for removing organic liquid contaminants from an aqueous solution mixed with the contaminated particles, which includes passing the solution through a standard paper Happy to use a Η family "Bi (CNS) T4 regulations (2 丨 0X297; ¢)-4-81. 6. 10,000 sheets (H) Please read the back to the urgent matters first, then fill in this page π Line Ministry of Economics Biyang Purification Bureau Beigong Xiaotuo Cooperation Du Yin 3i Λ 6 η 6 2109G2 Fifth, invention description () (please read the precautions Sun fills in this page first) contact area, this area contains a Removal of granular thermoplastic bombs A fixed bed formed by a block copolymer. The thermoplastic elastomer block copolymer includes a linear double block copolymer, a triple block copolymer, or a branched double block copolymer. In addition, the pelletized thermoplastic elastic block The copolymer includes a monovinyl aromatic polymer block bonded to an elastic conjugated diene polymer block, or a monovinyl aromatic polymer block bonded to an elastic monovalent polymer block. After the solution passes through the fixed bed formed by the particulate block copolymer, the water stream can be recovered from the contact area with substantially no contaminants. If necessary, the solution can be subjected to one or more ozone, ultraviolet radiation and active sulfonation treatments and / Or through an air stripping tower. The elastic polymer block and / or monovinyl aromatic polymer block can be partially or completely hydrogenated. The thermoplastic elastic copolymer preferably comprises a polystyrene-polybutylene-polystyrene block copolymer or a polystyrene-ethylene / butylene copolymer-polystyrene block copolymer. The Ministry of Economic Affairs, Central Standards Bureau, Beigong Consumer Co., Ltd. cooperated with Du Printing. In addition, it has been found from monovinyl aromatic-conjugated diene block copolymers, monovinyl aromatic-monoene block copolymers and these blocks If the thermoplastic rubber selected from the group consisting of hydrogenated derivatives of the copolymer is coated with a small amount of hydrophobic silica, it can greatly reduce the amount of oil absorbed and the amount of polymer required. According to the present invention, the sulfohydrogen compound educt is brought into contact with the composition of the present invention to encase the hydrogen compound. If the spillage is crude oil from water or refined petroleum product spillage, the composition of the present invention will entrap the oil and then float on the surface of the water, they can be easily scooped and recovered. If the spillage is on a solid surface, such as a garage floor, the composition of the present invention will cover the spilled liquid so that they can easily be used on paper scales in China National Standard (CNS) TM specifications (210x297 (Public *) 5 81. 6. 10,000 sheets (H) Λ Γ. Η 6 210d9j V. Description of the invention () Except that, at most, only a little effusion will be left. The present invention also relates to a method for removing organic liquid contaminants from mud. The method includes the step of combining soil contaminated with organic liquid with one of the above-mentioned thermoplastic elastic block copolymers. Secondly, the soil contaminated with the organic liquid and the thermoplastic elastic copolymer are mixed to form a homogeneous mixture of the thermoplastic elastic copolymer and the soil contaminated with the organic liquid. After this homogeneous mixture is mixed with water again, organic contaminants encapsulated by the copolymer can be recovered from this homogeneous mixture, and contaminant-free soil can be recovered from the remaining mixture. One of the viewpoints of the present invention is that the contaminated soil is preferably washed with water under pressure, and then the water extract is processed according to the above procedure, that is, the contaminated liquid passes through a thermoplastic dusty block containing granular particles The contact area of the fixed bed formed by the copolymer. If necessary, after recovery from the homogeneous mixture, the organic liquid contaminants encapsulated by the copolymer can be dissolved in organic solvents such as petroleum spirits, gasoline, diesel, or new crude oil to form an organic liquid contaminant-elastic polymerization Oil-petroleum liquid composition, the liquid composition obtained here can be used as fuel for stoves, engines, etc. Moreover, usually, the soil contaminated with organic liquid is excavated first, and then the contaminated soil is mixed with the thermoplastic block copolymer. The present invention also relates to a method for recovering an organic liquid film from a solid surface, the steps of which are to first uniformly spread the aforementioned thermoplastic elastic block copolymer on the organic liquid film, and then recover the copolymer covering the organic liquid from the solid surface . Generally, the amount of block copolymer required per gallon of organic liquid is about 0.1 lb to 1 lb, depending on the surface area of the spill, the viscosity of the organic liquid, and the length of time the organic liquid is attached to the surface of the object. For example, the larger the surface area, the more organic (please read the precautions before writing on this page). Install-Line-51 copies of the paper standard used by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. CNS) Τ4 specifications (210X297; ¢) 6 81. β · 10,000 sheets— (H) 21099 ^ V. Description of invention () The higher the viscosity of the liquid and the longer the organic liquid stays on the surface of the object, the more it needs Polymer to encapsulate these organic liquids. Another aspect of the present invention relates to a method of using a hydrogen compound fluid recovered from water; and the hydrogen compound is a thermoplastic elastomeric block copolymer of K described above, which is first wrapped and then recovered. The steps of this method include dissolving a stream of nitrile compound wrapped in thermoplastic rubber in a solvent such as petroleum spirits, gasoline, diesel oil, crude oil, etc. to form a roll of thermoplastic rubber-sulfohydrogen compound-petroleum liquid composition. The liquid compound can be used as fuel for stoves, engines, etc. Therefore, this method also includes the step of burning the thermoplastic rubber-hydrogen compound-petroleum liquid composition in a furnace. In the dissolving step, it is preferable to heat the solvent to increase the dissolution of the hydrocarbon fluid covered by the thermoplastic rubber in the solvent. The Ministry of Economic Affairs, the Central Bureau of Sassafras and the Bureau of Industry and Fisheries cooperated with Du Yin ¾. The present invention also relates to a method of removing organic liquid contaminants in the soil, in which the soil contaminated with organic matter is first mixed with water to the bottom, M The organic liquid contaminants are extracted from the soil and a soil / liquid mixture is obtained. This mud / liquid mixture is then filtered to obtain cleaned mud and a filtrate containing organic liquid contaminants. Next, the filtrate is passed through a contact area containing a fixed bed formed of one of the above-mentioned particulate thermoplastic elastomeric block copolymers, and a substantially contaminant-free water stream is recovered from this joint area. The invention also relates to a method for preventing organic pollutants in underground fuel tanks from leaking into the soil under the tanks. The steps of this method include mixing the first amount of soil with one of the above-mentioned thermoplastic elastic block copolymers to form a soil / block copolymer mixture. The soil / block copolymer mixture is used in this paper scale. Sample standard (CNS) Ή specification (2) 0X297; ¢)-1-81. 6. 10,000 sheets (H) Λ Γ »It 6 210992 V. Description of invention () (please read the back to the notes # item Write this page) Place at the bottom of the excavated mud cave, and then place the underground fuel tank on these mud / block copolymer mixture, and then fill the cave with the second amount of mud ». The soil / block copolymer mixture will absorb any fluid that leaks out of the fuel tank and infiltrates, thus preventing the fluid from seeping into the soil. The present invention also relates to a method for preventing organic contaminants leaking or overflowing from the well source from penetrating into the soil near the well source. This method first mixes the soil of the first number S with one of the above-mentioned thermoplastic elastic block copolymers to form a tilting soil / block copolymer mixture, and then places the soil / block copolymer mixture on the ground near the well source on. This soil / bulk copolymer mixture will absorb organic contaminants leaking or escaping from the well source, thus preventing the organic contaminants from seeping into the soil around the well source. Figure 1 is an overview of a stern filter system. This system is equipped with a parallel copolymer processing unit, which contains thermoplastic elastomer block copolymer particles according to the present invention, and the water flowing therethrough is removed by Μ Contained hydrocarbon contaminants; the Ministry of Economic Affairs, the central standard and the Beigong Consumer Goods Cooperation Du Yin 51. Figure 2 is a flow chart of a combined morphology processing system, this system includes a copolymer processing unit, a value Air stripping tower unit, an ozone treatment unit, an ultraviolet irradiation treatment unit and an activated carbon treatment unit; Figure 3 is a flow chart showing the steps of a method for recovering organic liquid from mud according to the present invention; Figure 4 is a cross-sectional view of an underground fuel tank placed above the soil / bulk copolymer mixture; Μ and Figure 5 are a paper-scale edge of the paper surrounded by an annular soil / bulk copolymer mixture. Ping (CNS) T4 specifications (2) 0 × 297; ΙΗ 8 81. 6. 10,000 sheets (Η) AG It 6 210993 V. Description of invention () A perspective view of the source of the oil production well. (Please read first Pay attention to Xiang Sunxian wrote a wooden page) The compositions used in the present invention include a thermoplastic elastic copolymer. The thermoplastic elastic copolymer used in the practice of the present invention includes a block having at least one monovinyl aromatic polymer bonded to another conjugated two The vinyl aromatic monomer of the vinylene polymer block and the block copolymer segment of the conjugated diene, or the vinyl aromatic monomer having at least one monovinylaromatic polymer block bonded to another single polymer Block polymer fragments of bulk and monoene monomers, and hydrogenated derivatives of these block copolymers. Each polymer block or block fragment can contain one hundred or more individual Monomer 〇〇— Zaowu α The Ministry of Economic Affairs Standard and the Beigong Pricing Cooperative Printed 5i. In detail, the block copolymer used in the present invention is a thermoplastic elastic linear two-block, three-block or branched (radial > Diblock copolymers, which contain monovinyl aromatic polymer blocks bonded to elastic conjugated diene or elastic monoene polymer blocks, M and hydrogenated derivatives including these polymer blocks. The general structure of the linear block copolymer can be linear A-B-A three-block form, radial or branched A-B two-block form, and linear A-B two-block form. In these molecular formulas Among them, "Α" represents a monovinyl aromatic polymer block, which can be partially or completely hydrogenated; and "Β" represents a univalent conjugated diene, hydrogenated diene, monoene or hydrogenated monoene polymer The three-block structure of ABA uses elastic polymer block B as an intermediate block and polymer block A as a terminal block. Radial or branched AB block copolymer contains many A polymer blocks , They are combined together at their first ends to form a common center. These A polymer blocks include various paper-based Xiaoyaozhongbi (CNS) that extend radially outward from the common center M in different directions. T < 1 regulation (2) 0X297 and 9-81. 6. ίο, 000 sheets (Η) Λ (5 Η 6 2109 & 2 V. Description of the invention) The second end. Each second end is connected to a slap B polymer block, which usually extends radially outward from the common center M. Monovinyl aromatic polymer blocks contain elemental polymer or copolymer blocks. At the same time, most of them contain a monovinyl aromatic monoeel as the main polymerizable unit. Conjugated diene and hydrogenated diene polymer blocks and monoene and hydrogenated monoene polymer blocks can be in the form of elementary polymers or copolymers; the main feature is that their structure can make them have the characteristics of elastic polymerization properties . These blocks "A" and "B" can be partially or completely argonized. If the hydrogenation is only partial, it is best to allow block "B", the conjugated diene polymer block, to be hydrogenated to improve their oxidation resistance. Therefore, these polymers may contain unhydrogenated, partially hydrogenated, or fully hydrogenated polymer blocks. The monovinyl aromatic monomers that can be used to form the thermoplastic elastic block copolymer of the present invention include styrene, ct-methylstyrene, and cycloalkylstyrene. These monomers can be combined with each other in the form of polymers or copolymers or form a block "A" with a small amount of conjugated diene. The conjugated diene that can be used to form block WB "or as a minor component in block" A "preferably includes conjugated diene containing 4 to 8 nitrile atoms per molecule, especially butadiene And isoprene. As for the monoene which can form the block "B" with M, it is best to contain 2 to 8-value sulfon atoms, among which ethylene, propylene and butene are more suitable. At present, the preferred "B" The block contains copolymers of ethylene / propylene and ethylene / butene. Representative thermoplastic elastomer block copolymers with configurations of polystyrene-polybutadiene-polystyrene, polystyrene-polyisoprene Ethylene-polystyrene, ffc scale of this paper, the Chinese national standard (〇 milk) 174 specifications (2) 0 father 297 public release) (please read the back-to-be-attentive matters # 锅 写 木 页) Duyang 5i 81. 6_ 10,000 sheets (H) Λ 0 Η 6 2109δ2 of the Yangtze Standard Bureau Beigong Xiaotuo Co., Ltd. 5. Description of invention () and polystyrene-poly (ethylene / butylene) -polystyrene A-B -A triblock copolymer; polystyrene-polybutadiene and polystyrene-polyisoprene radial or branched A-B diblock copolymer; M and polystyrene -Polybutadiene, polystyrene-poly (ethylene / propylene) and polystyrene-poly (ethylene / butene) linear A-B diblock copolymers. The currently preferred thermoplastic elastic block copolymer is poly Styrene-polybutadiene-polystyrene and polystyrene-poly (ethylene / butene) -polystyrene linear A-B-A triblock copolymer. The best thermoplastic rubber used in the present invention It is currently supplied by Micro Environmenal Corporation of Grand Rapids, Michigan under the trade name of PS 3200 and PS 3400. PS 3200 products include a polystyrene-polybutadiene-polystyrene block copolymer, The PS 3400 product contains a polystyrene-poly (ethylene / butylene) -polystyrene block copolymer. The most ideal material supplied by this manufacturer is a kind of revocation sold in the form of M small nine or powder Particulate matter. Currently, the powder form is preferred because its smaller nine-form material provides greater absorption and / or adsorption ("envelopment" > surface area. These thermoplastic elastomers (rubber > block copolymerization The fineness modulus of the particles is preferably between 100 and 300 microns Among them, 180 to 220 meters is the most ideal. In some cases, it is necessary to uniformly coat a small amount of hydrophobic silica on the surface of the thermoplastic elastomer copolymer particles to increase its fluidity and ability to absorb hydrocarbons. Patent and Technical literature has disclosed hydrophobic silica additives that can be used, and these additives are also readily available from many manufacturers. Hydrophobic silicas can generally include any compound containing silica, such as silica, silica gel, platy silica Algae soil and other forms of hydrophobic silicon pombenite used in paper size for a happy use a Η family standard (CN5) Ή specification (210X297 g *) (please read the precautions 4 before writing this page ) Installed. Line <. Printed by the employee consumption cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 81. 6. 10, 〇〇〇 Zhang (Η) Λ (ί Η Γ > 2109G3 V. Description of the invention). The best silica is the hydrophobic amorphous fumigation marketed by Degussa Company, Futian, New Jersey under the commercial name of Aerosil R-972, R-972V, R-974, R-974V and R-976. Black silica. The amount of hydrophobic silica used may be 0.1 to 2.5 weight percent (wt%), preferably 0.5 weight percent, depending on the weight of the thermoplastic elastic block copolymer. The hydrophobic silica can be quickly combined with the thermoplastic elastomer block copolymer by any conventional mixing method, so that the surface of the block copolymer is provided with a uniform hydrophobic silica coating. The amount of treated block copolymer to be used is determined by the thickness of the oil film to be absorbed, the time required to economically recover the contaminated oil, the agitation of the water body to be degreased when treating the oil trace in the water, and Similar physical factors. When the spill contains a film no thicker than 0.5 inches, it is best to use 3 to 7 pounds of pelletized block copolymer for each gallon of spill. The time required for the block copolymer to entrap the oil will vary with temperature, the degree of perturbation, the ratio of liquid extract to the block copolymer, the viscosity of the liquid, and the surface of the block copolymer used. Printed by Beigongxiao, Co-operative Society, Ministry of Economic Affairs, Ministry of Economic Affairs ¾ The outer layer of the block copolymer of the present invention is a bulk copolymer withdrawal agent, and within a few seconds after the liquid spill is exposed, the hydrocarbon will soon be removed. Compound exudates are covered. The time required to remove spills not exceeding half an inch is usually calculated in minutes. However, the larger range of spills, such as those caused by shallow tearing of oil tankers, is more time-consuming to remove, because the continuous exposure time of the surface of the fresh entrainment agent will depend on the volume of the exudates and their expanded area. In general, when treating the exudate with the capsules of the present invention, it is best to start within about 4 hours of the occurrence of eruption. It is not difficult to understand that when using the composition of the present invention, it is extremely large to handle 81. 610, 000 sheets (H) of this paper »Standards and Standards (88) 〒 4 specifications (210 father 297 g *) Λ (i It 6 21099-5 Fifth, the description of the invention), the overflow of the M needs to be treated once. Surprisingly, the block copolymer even after a small amount of hydrophobic silica treatment (such as 0.1 ~ 2.5 volume percent), can also increase the removal capacity, its removal volume improvement, from about 3 times the volume of the bulk copolymer processing oil to increase to about 4 times the volume of the bulk copolymer processing volume In addition, the time for using the treated block copolymer to entrap the spilled oil is about 25% less than the time for using the untreated polymer to absorb the spilled oil. The treated block copolymer substantially completely removes the spilled liquid. Encased in the body, and the surface of the block copolymer sachet is generally kept dry and non-toxic. Therefore, it will be convenient for some methods, such as gathering with a rake, moving a bar or net, etc., along the surface of the choppy water or similar Collect and seal block copolymer on the surface Liquid. If the spillage is on a solid surface such as a steel deck, wooden deck, concrete floor, etc., you can use a broom or similar to remove the copolymer containing the liquid. There are many ways to complete the removal of the composition of the present invention. The application of liquid spillage. It is better to spread the composition more evenly on the contaminated area or on the part of the area to be treated. The composition of the present invention can be removed or other methods Spread on the surface of the spilled liquid and / or in the spilled liquid. This can be done in a variety of ways. Liquid spills on concrete floors or similar surfaces can be spread by manual spreading or other methods of spreading the composition of the invention On the other hand, M recovers these debris. The smaller debris on the water surface can be sprayed, blown, or withdrawn from the boat to the surface of the spill and treated. For larger spills, This paper may be required "for standard use in the national aqua standard (CN5) Grade 4 (210X297): (please read the back and forth precautions # 项 筠 ^ -page) installation · line · Ministry of Economic Affairs Quasi-bureaucrat Printed by Zuoshe 81. 6. l〇, 〇〇〇ft (Η) Λ Γ. II 6 21090 ^ 5. Description of the invention () Several ships are used. In the case of a large area contaminated by oil, it can be traditional The aircraft smells radium solids to the surface of the oil traces. These spills will be trapped, thus preventing their continued diffusion, and then use a fence that allows water to flow, which is contained in a porous mesh cover The decapsulation agent of the present invention prevents & outgoing objects from reaching the coastline and beaches. These barriers allow water to pass through its structure, but it will entrap the oil passing through the mesh covering, making it impossible for the oil to pass. The composition can also be used to clean the abdomen water tank. The decapsulation agent of the invention can be directly withdrawn into the abdomen water tank, or a pillow with a closed mesh cloth filled with the porous aeration agent mixture of the invention or Stern bag to remove pollution. The present invention also relates to a treatment method for removing contaminants in organic liquids, in particular, hydrogen compounds dispersed or carried in water streams such as chemical treatment liquid streams. In this treatment method, a stream of water contaminated with organic liquid is allowed to flow directly through a fixed bed of thermoplastic elastomer copolymer absorbent particles. This type of water stream to be treated contains organic liquid contaminants such as fuel, methyl ethyl ether, toluene, ethylbenzene, xylene and benzene, M and even Jinlong like iron. For example, in Figure 1, it is a treatment system for removing organic liquid contaminants carried in the stern of the ship. This system includes a copolymer processing unit 11 which includes a downstream of two parallel copolymer absorbent beds 12 and 14 The stern pump 10 is connected to it by an appropriate pipeline. The contaminated organic liquid flow can be pumped from the stern 18 or other container containing the sloping liquid to make it flow through a stern outlet pipe 16, and then guided by a three-way valve 24 to flow through a value treatment unit The tube 20 or the processing unit enters the tube 22. Pressure 81. 6. 10,000 sheets (Η) (please read the cautionary notes of the Sun Sun crucible ¾. Wood pages). Binding. Order _ The Ministry of Economic Affairs Standards and the A Industrial Consumer Cooperation Cooperative Print 51 Λ fi ΗΓ) gl. 9i ^ V. Description of the invention () Table 23 can measure the pressure of the contaminated organic liquid in the outlet pipe 16 of the stern. (Please read the general notes first and then write the wooden page) When the three-way valve 24 directs the contaminated fluid into the treatment unit and enters the pipe 20, this contaminated fluid can be drawn by the stern pump 10 A fixed-bed copolymer absorbent bed 12 composed of massive copolymer particles. The treated aqueous solution flowing out from the copolymer absorbent bed 12 is substantially free of contaminants, it flows through the outlet pipe 26 of a unit, and then is introduced into the container inlet pipe 30 by a three-way valve 28. The pressure gauge 32 can measure the pressure of the treated liquid flowing into the tube 30 through the container. Finally, the abdomen pump 10 pumps the treatment liquid from the container into the tube 30 into a treatment liquid container 34 or back into the abdomen 18. Just like the conventional practice of liquid treatment systems including parallel multi-value processing units, the copolymer absorbent bed 14 remains ready for use as long as the first copolymer absorbent bed 12 carries the copolymer particles in its fixed layer When regenerating, you can go online to replace the lotus. The amount of bulk copolymer bladder particles (absorbent) filled in each of the copolymer absorbent beds 12 and 14 must be sufficient to enclose about 2 1/2 quarts of liquid organic contaminants. By pressure gauge 23 and the pressure difference measured by the pressure gauge 32 represent the bed 12 through the copolymer absorbent

I The pressure from the Ministry of Economic Affairs and the standard printed by the A Co-operative Cooperative Society has been reduced. When the pressure drop across the copolymer absorbent bed 12 is equivalent to entrapment of approximately 2 quarts of contaminants, an appropriate warning is generated, at which point the operator can allow the second copolymer absorbent bed 14 to replace the lotus. , And the fixed bed particles in the first value copolymer absorbent bed 12 are regenerated. By turning the three-way valve 24, the second copolymer absorbent bed 14 can be used as a clematis. After that, the contaminated organic liquid will flow through the treatment unit into the pipe 22 instead of the treatment unit into the pipe 20. The treated liquid flowing out of the copolymer absorbent bed 14 will enter the outlet pipe 36. The three-way valve 28 should be converted to allow the treatment liquid flowing through the outlet pipe 36 to be introduced to 81. 6. 10, 000 sheets (H). This paper size is used in the BB Home Sample (CNS) T4 regulation ( (210x297 male dragon) 210902_Λβ_ V. Description of the invention () The container enters the tube 30. After several months of construction of this aft filter system, no pollutants will remain in the environment. However, if the fixed bed particles in the copolymer absorbent bed used are not regenerated in a timely manner, the fixed bed will only continue to apply iron to the pressure of the treated fluid in the vessel inlet pipe 30, and cannot maintain the proper pumping time of the stern pump 10. At this time, the cavitation pump 10 will cause a large cavitation phenomenon. The Ministry of Economic Affairs Standard ^ ΕΞζ Gongxiaozhong Cooperative printed the first test data to indicate that the value of the copolymer processing unit 11 as shown in Figure 1 can be arranged in series, which will result in continuous high pollution Removal effect. Alternatively, referring to FIG. 2, another combination can be seen, which includes one or more copolymer processing units 11, one or more air stripping unit 40, one or more ozone treatment units 42, one or The multi-value ultraviolet irradiation treatment unit 44M and the one- or multi-value active treatment unit 46, which are arranged in series with M, use M to remove pollutants entering the water stream 48 and produce a non-polluting outlet water stream 50. Of course, a combination rule does not necessarily include all these units, it can be any combination of these units. For example, the ozone treatment unit 42 is more suitable for use when killing bacteria entering the water stream 48 or removing gold jelly in the water stream. The ultraviolet irradiation treatment unit 44 is also suitable for killing bacteria. The decision to use a series of polymer absorbent units or some form of combination system will depend on the nature of the pollutants, the degree of removal required, and the cost of the associated components. For example, to treat a water stream that is mainly contaminated with lower volatile compounds such as xylene, from a technical and economic point of view, polymer treatment alone is good. If you use a combination type system to deal with gasoline-contaminated water flow, then use 81. 6. 10,000ft (Η) (please read the back to the precautions # hard to write this page) This paper scale is used in the BB family standard ( CNS) 〒4 gauge (210x297 public goods) Λ ίϊ Π 6 Printed by the Ministry of Economic Affairs, Central Bureau of Industry and Commerce, A Industrial and Consumer Goods Cooperative V. Description of the invention () Before using a unit of air stripping tower, firstly copolymerize The material treatment unit pre-treating the water stream may remove a large amount of benzene and toluene, as well as substantially all lower volatile compounds such as xylene. This will reduce the A load of the processing tower containing the active master and increase the life of the activated carbon. In this way, since the cost of active sulphur can be greatly reduced, this combined treatment method can result in a lower overall treatment cost. In addition, in the treatment systems currently used commercially, activated carbon treatment units are generally used. Because the active processing unit constitutes an approved filter medium. However, the active bed must be regenerated almost every day, adding considerable cost. When a copolymer treatment unit and an active sulfonation treatment unit are connected in series and placed in front of the active nitrate treatment unit, the active base in the active master treatment unit needs to be regenerated approximately every 1 to 2 weeks. Using this combination treatment system, the copolymer in the copolymer processing unit needs to be regenerated approximately every 3 to 4 days, and the cost of regeneration is lower than that of the activated carbon bed. The present invention also relates to a method of using a sulfohydrogen compound fluid that is encapsulated in a thermoplastic rubber block copolymer and recovered from water. This method is to dissolve the fluid of the compound of haze which is covered by thermoplastic rubber in a solvent such as petroleum spirit, gasoline, diesel oil and crude oil, to form a thermoplastic rubber-hydrogen compound suitable for use as fuel for furnaces, engines, etc. Fluid-petroleum liquid composition. In other words, in this dissolution step, the thermoplastic rubber will also be dissolved by the solvent. This thermoplastic rubber-hydrogen compound fluid-petroleum liquid composition can then be burned in a fire or used as a fuel in an engine. In the process of dissolution, it is best to heat the solvent to promote the dissolution of the sulfohydrogen compound fluid covered by the thermoplastic rubber in the solvent. (Please read the back-to-back precautions for Sun Xiang to write this page) Binding and Strapping-This paper standard is used in a Η family sample standard (CHS) specifications (210X297 public; ¢) _ _ 81. 6. 10,000 sheets ( H) Λ ίί Η 6 2109 ^ 2 V. Description of the invention () The present invention also relates to two methods for recovering organic liquid, especially hydrogen compounds, that have penetrated into the soil. Please refer to Figure 3. In the first method, the soil contaminated by the debris is first excavated and put into a mixer such as a belt mixer. Secondly, one of the aforementioned bulk copolymer decapsulation agents M and the contaminated soil in the mixture is added to the mixer in a weight ratio of approximately 1:10 to 1: 1, preferably 1: 1. In addition, it is advisable to add some fresh hydrogen compounds to the soil in the mixer and the decontamination agent to activate the pollutants of the organic liquid. Third, the contaminated soil and the block copolymer are encapsulated in the mixer for a time period sufficient for the block copolymer to adsorb and / or absorb the contaminants. The mixing time can be from 30 seconds to 2 hours or longer, currently preferably 1 to 10 minutes; the length of the mixing time will depend on the nature of the pollutant and the time the pollutant is in the soil. Then the homogeneous mixture of the soil and the copolymer coated with contaminants is put into a storage tank, and the copolymer covered with contaminants becomes powdery or large agglomerates, which will be copolymerized depending on the block used It depends on the thing. Fourthly, the homogeneous mixture is mixed with water to leaching the pollutants and water enclosed by the copolymer from the soil. The clumps of encapsulated pollutants will float to the surface of the water, and these pollutant blocks will be removed by M grabbing. The remaining water and soil are almost free of organic liquid pollutants. When recovering these contaminated blocks from the water, it is best to use a net from 1/8 inch to 1 hour. Then the water and mud are filtered to obtain substantially dry mud and separation water, both of which do not contain organic pollutants. These organic liquid contaminants encapsulated by the copolymer will be installed in the subsequent steps (please read the counter-product's "#quotation" page #) at this time. Printed by the price cooperative, the paper standard is used in the FFL family standard (CNS) T4 specification (210X297) 18 81. 6. 10,000 sheets 〇〇Λ 6 Η 6 2l〇9G ^ V. Invention description () The value of economic use. For example, the contaminant mass surrounded by the block copolymer can be liquefied in solvents such as petroleum spirits, gasoline, diesel, or crude oil. The organic pollutant-elastic polymer-organic solvent liquid composition produced after dissolution can be used as a fuel source for industrial fire engines and engines. Alternatively, the copolymer solids that enclose the pollutants can also be used as solid fuels. In the second method of recovering the organic liquid infiltrated into the soil, the soil contaminated by the spillage is first excavated, and then mixed with the water in the mixer or other mixing device, and then Μ is leached from the soil Filter out contaminants. Secondly, the mixture is filtered to obtain washing soil and a filter solution for spreading or spreading organic liquid. The filtrate is then passed through a fixed bed of thermoplastic elastomeric copolymer absorbent particles such as the copolymer processing unit 11 shown in the first section to remove organic contaminants from the water stream. If necessary, according to the first method described above, the washed soil can be treated with M to remove contaminants in the soil. The present invention also relates to the use of the thermoplastic elastomer block copolymer to treat liquid eel spills on solid surfaces such as net decks, wooden decks, and concrete floors. The treatment method is to manually disperse the bulk copolymer decapsulation agent on the surface of the exudate by manual withdrawal or other methods. As for determining the amount of the block copolymer required, it will depend in part on the thickness of the organic liquid film to be absorbed and / or absorbed and the time required for economical collection of the liquid. When the liquid spill contains a film no thicker than about 0.5 inches, the amount of block copolymer used is preferably between 0.1 and 1 pound for each gallon of spill. The time required for the block copolymer to encase the organic liquid will vary with temperature, the ratio of the organic liquid to the block copolymer, and the size of the organic liquid on this paper. The CNS TM specifications (2). : Ϊ) (please read the back-end precautions # fill out this page) installed-printed by the Zhenyang Consumer Cooperative Society, Bureau of Standards, Ministry of Economic Affairs 51 81. 6. 10,000 sheets (Η) 2109 ^ -3 Λ G Η 6 5. Description of the invention () The viscosity, the surface area of the block copolymer used, and the time the organic liquid remains in the soil or on the deck surface vary. The block copolymer encapsulant comes into contact with liquid spills and soon begins to contain liquid hydrocarbon spills within seconds. The time required to clean the decanter with a thickness not more than half a hour; usually calculated in M minutes. These organic liquids or petroleum-related liquids are almost completely covered by the block copolymer, and the surface of the block copolymer capsules is kept almost dry (non-oily), non-sticky and non-toxic. This helps collect organic liquid and block copolymers, such as gathering with a rake and sweeping with a broom. Referring to FIG. 4, the present invention also relates to a method for preventing organic pollutants from seeping into the soil underneath an underground fuel tank. In this method, a soil / block copolymer mixture 60 is produced by thoroughly mixing the first amount of soil with the aforementioned block copolymer. Next, this soil / block copolymer mixture 60 is placed at the bottom of the hole 62 excavated in the soil 63. Then, a subterranean fuel tank 64 is properly placed on the earth / block copolymer mixture 60, and then the second amount of earth 66 is filled into the hole 62. Printed by the Ministry of Economic Affairs and printed by the Employee Consumer Cooperative (please read back and forth: ¾¾ Matters and then write this page) If the organic fluid 68 leaks from the underground fuel tank 64, they may penetrate down through the second volume The soil 66 is absorbed and / or adsorbed by the block copolymer in the soil / block copolymer mixture 60. If necessary, the soil / block copolymer mixture 60 can be placed directly under the sill 64, and any organic liquid leaking from the tank 64 will be directly incorporated into the soil / block copolymer mixture 60. Therefore, this method can prevent the organic liquid 68 in the underground fuel tank 64 from seeping into the soil 63 underneath. The size of this paper is not the same as the iMCNS (4〗 0χ2ί) 7 Gong «)-20-81. 6. 1〇, 〇〇〇 sheets (Η) Λ 6 η 6 2109 ^ 2 5 2. Description of the invention () (Please read the notes on the contrary to Sun Xiang to write this page) Similarly, referring to FIG. 5, the present invention also relates to a method for preventing leakage or leakage from the wellhead 72 of Yiyou oil well 70 The method of infiltrating the organic pollutants into the soil around the well source 72. In this method, the well source 72 is surrounded by the ring 74 composed of the aforementioned soil / bulk copolymer mixture. The oil and other organic contaminants leaked or spilled from the wellhead 72 of the oil well 70 can be returned to the pasture, because the bulk copolymer in the soil / bulk copolymer mixture will leak out or overflow from the wellhead 72 Absorb and / or adsorb pollutants. This is to prevent any such contaminants from seeping into the soil near the well source 72. If necessary, the area near the wellhead 72 can be dug to the desired depth and then filled with the soil / block copolymer mixture. In other words, the ring 74 formed from the soil / bulk copolymer mixture can be any desired depth. Now the following examples will further illustrate the present invention: Example 1: Pingyang Standard Bureau, Ministry of Economic Affairs β Gongxiao " Cooperative Du Printing Co., Ltd., a single fixed bed absorption tower with a diameter of 0.5, into a powder with a volume of about 100 ml PS 3200 absorbent (a block copolymer sold by Micro Environmental Corporation of Grand Rapids, Michigan, USA) to a depth of about 30 inches. Then the water contaminated with gasoline (containing about 0.6 grams of AM0C0 silver grade unleaded gasoline per liter of solution) Μ 12 bed volumes (BV) per hour through the absorption tower, where the bed volume is defined A volume equal to the volume of the block copolymer in the absorption tower (ie, 100 ml). Therefore, the feed rate is 1.2 liters / hour. According to EPA method 602 (V0A), after measuring the absorption tower after 1 2/3, 3 1/3, 6 2/3, 10 and 13 1/3 hours, the components in the sewage stream flowing out of it are removed. Percentage (for oranges for untreated water flow), and use 81. 6. 10.000 sheets (Η) of the size of this paper in the standard a Η home rubbing (CNS) T4 specification (210X297; ft) 2i〇9 ^^ V. Description of the invention () The results are listed in the table below: Λ 6 Π 6% ingredients remove contaminants 1 2/3 hours 3 1/3 hours 6 2/3 hours 10 hours 13 1/3 hours MTB (Methyl 3 31.6 59.6 33.0 41.6 13.4 grade butyl ether) Benzene 99.4 93.1 76.9 81.4 79.0 Toluene 100.0 100.0 99.5 96.6 91.7 Ethylbenzene 100.0 100.0 100.0 100.0 100.0 Xylene 100.0 100.0 100.0 100.0 100.0 (Please read the precautions before writing this page) Economy The Ministry of Health, People's Liberation, and Employee Counsel Cooperatives printed as expected, and the more volatile components like benzene and toluene passed through the absorption tower faster. During the test, there was no indication of any increase in pressure drop across the absorption tower. In addition, no melting or “melting” of the block copolymer was found (the interaction between gasoline and the block copolymer is different from absorption and / or adsorption). Therefore, the physical reaction of the absorbent is similar to that observed in other absorption-type absorption tower systems. Fenli 2: The process of Example 1 was repeated, but M PS 3400 absorbent (a block copolymer sold by Micro Environment Corporation of Grand Rapids, Michigan, USA) replaced the PS 3200 absorbent in the absorption tower. However, the standard of this paper is to use the China Rent B Standard (CNS) Grade A specification (210x297 g; ft) 81. 6.) 0,000 sheets (Η) Λ 6 Η 6 5. Description of the invention () Preliminary test of the outflow of sewage Since the volatile organic compounds (benzene, toluene, ethylbenzene, and xylene) were compared with the experiment using PS 3200 in Example 1, they passed the absorption tower quite quickly, and the M test ended after 3 3/1 hours . After 1 2/3 and 3 1/3 hours of the absorption tower, the measured percentage removal of components in the outflow sewage (relative to the untreated water flow) are listed in the table below. From the results, it can be seen that the PS 3200 absorbent used in Example 1 is more effective than the PS 3400. (Please read the back and the precautions ## to write this page) The Ministry of Economic Affairs, Bureau of Standards, Beigong Consumer Cooperatives Cooperative 3i Contaminant% component removal 1 2/3 hours 3 1/3 hours MTBE 19.0 78.8 Benzene 84.5 83.6 Toluene 93.8 94.0 Ethylbenzene 97.1 97.5 Xylene 96.7 97.1 Example 3: To determine the efficiency of PS 3200 and PS 3400 in a single-stage group contact system to remove gasoline from water, each block copolymer was determined first The ultimate adsorption and / or absorption performance. Since it is found that these block copolymers will tend to melt or melt after being exposed to the concentrated gasoline solution, so the binding-binding-line · 51c scale of this paper uses the Chinese HJ standard (CNS) T4 specification (210x297 : B :) 81. 6. 10,000 sheets (Η) fj Λ (5 Π 6 V. Description of the invention (use the following procedure to determine the ultimate performance: U) Add a specific amount of gasoline to the excess polymer to make it Can act for several hours; (b) Remove the block copolymer that reacts with gasoline to melt or melt, and then weigh the unreacted block copolymer; and (c) Subtract the total weight of the block copolymer The weight of the unreacted block copolymer can determine the weight of the reacted (melted or melted) block copolymer. The results of the performance test are as follows: The polymerization performance of the material gasoline (gasoline (gram) (gram)) Objects (grams> / polymers (grams>) (please read the precautions on the first page to write this page) Pack-PS 3200 PS 3400 5. 5. 4 4, 1.04 1.25 Line-Ministry of Economic Affairs Standard The Bureau of β-Work Consumer Cooperation cooperates to print the PS 3400 material for a specific absorbed dose The amount of gasoline absorbed is more than the PS 3200 material. During the test, it was found that the PS 3400 material seems to have a greater "melting" degree than the PS 3200 material. This is for the excellent performance of the PS 3200 in the absorption tower type method. Some explanations are provided; in this type of method, the absorbent is not moved, and it is hoped that the melting will be minimized to avoid possible absorption bed blockage or liquid passage. After determining the ultimate performance of the absorbent, after absorption Between the agent and the contaminated water, a single-stage, grouped isothermal, contact treatment process is carried out. The steps are as follows: the paper scale is used in 8 or 8 揳 樳 計 (〇 肊) 言 4 specifications (2 丨 0> < 297 Male dragon) 81. 6. 10,000 sheets (H) Λ 6 Η 6 V. Description of invention () The following are: First, M Amoco silver-grade unleaded gasoline contaminates the distilled water, placing two liters of the resulting contaminated aqueous solution in two containers respectively ; In each bow container, the concentration is 0.6 grams of gasoline per liter of solution. Second, the first dose of absorbent (powder>, which is equivalent to the amount of 100% adsorption efficiency required to recover all gasoline (For PS 320 0 absorbent, the calculated amount is 0.6 g / L), add to the first two liter solution, and then add the second dose of absorbent equal to twice the first dose to the second two liter solution Then each sample is mixed in a rotating drum for about 16 hours. After the mixing is completed, the sample water is taken out from each container separately, and then the "BETX" ("benzene, toluene, Ethylbenzene, xylene ") pollutants. The percentage of its component removal is shown as follows:% component removal (please read the back-end notes # fill out this page) to install. Order · Line < Ministry of Economic Affairs, Bureau of Standards, Employee Consumer Cooperative Printed Pollutant Polymer The first dose (0.6 g / L) The second dose of polymer (1_2 g / L) Benzene 27.8 33.6 Toluene 46.5 50.4 Ethylbenzene 62.8 66.4 Xylene 65.5 68.5 This paper uses the Chinese National Standard (CNS) Ή specifications ( (210x297 male dragon) 81. 6. 10,000 sheets (Η) Printed by the Central Bureau of Economic Affairs of the Ministry of Economic Affairs " Cooperative printed 2l099 ^^; Fifth, the invention description () Endeavour Example 4: Repeat Example 3 Treatment process, but replace the PS 3200 absorbent with PS 3400 absorbent. At the same time, add the first dose of absorbent equivalent to the amount required for M100% adsorption efficiency to recover all gasoline (for PS 3400 absorbent, the calculated amount is 0.5 g / L), add the first value to gasoline contamination In two liters of aqueous solution. A second dose of absorbent equal to twice the first dose was added to the second two-liter aqueous solution contaminated with gasoline. After the sample is mixed, remove the container from the mixing drum and analyze the removal of contaminants. The percentage of its component removal is shown as follows: A 6 Π 6 (please read back to the precautions before writing this page)% component removal equipment-the first dose of pollutant polymer (0.5 g / L) Polymerization The second dose of the substance (1.0 g / L) Benzene 20.8 24.2 Toluene 37.4 43.2 Ethylbenzene 54.9 60.7 Xylene 58.2 63.4 When checking the effectiveness of the absorbent in the single-stage group contact method in Examples 3 and 4, PS can be found Both the 3200 and PS 3400 absorbents remove part of the gasoline component, of which PS 3200 is more effective. Secondly, the experimental results show that doubling the dose of the absorbent does not significantly increase the size of the paper. The use of the rent-free home-like standard (CNS) T4 specification (210X297 public A) 26 81. 6 ·〗 0,000 sheets (H ) Λ 6 η 6 21090 ^ V. Description of invention () (Please read the precautions before writing this page) Add the removal effect of gasoline pollutants. Third, it is obvious that the single-stage grouping method of Example 3 and Example 4 can not remove the gasoline component in the aqueous solution as well as the absorption tower contact method of Example 1 and Example 2. Example H: Μ-a modified 55-gallon cylinder with inlet and whisker distribution mains Expand the process of Example 1. The absorption tower can be filled with approximately 50 gallons of PS 3200 absorbent (about 140 pounds). The expanded flow rate (based on the 12 BV / hr rate tested in Example 1) is approximately 10 gallons / minute. The expected pressure drop through the absorption tower will be less than 3 psig. Jian Li: Spill half a cup of unleaded gasoline on the ground of the garage, and then remove a block copolymer microcapsule (PS 3400) on the surface of the extract. In about 15 seconds, the leached gasoline was enveloped by the copolymer. Example 7: The process of Example 6 was repeated, but 10-W30 engine oil was used instead of unleaded gasoline, and roughly similar experimental results were obtained. Example 8: The Ministry of Economic Affairs Standard ^ β 工 消 貀 Cooperative Seal 51 Mix 100 g of uncontaminated soil (IR approved) with 10 g of No. 2 diesel oil to produce a sample of contaminated soil. Then 10 grams of PS 3200 absorbent was mixed with the contaminated soil sample for 30 minutes to produce a homogeneous composition. The homogenized composition was mixed with 1 liter of deionized water for two hours, and the homogenized composition was leached in water. When the leaching step is completed, the enclosed pollutant blocks will rise to the surface of the water, which can be skimmed on the surface with a net to remove these pollutant blocks. Then filter the remaining samples, and then use 81,000 sheets of paper. ⑻ The standard size of the Chinese paper (CNS) Τ4 specifications (210X297) is used for the standard paper size u- Λ 6 H6 Central Bureau of Economic Development The employee ’s cooperative prints 5. The description of the invention (a gas chromatograph with a fid detector properly analyzes the volatile organic pollutants (benzene, toluene, ethylbenzene, and xylene) in the filter fluid. The liquid does not contain any measurable volatile organic pollutants. Therefore, the content of volatile organic pollutants has not been employed lOppb (10 parts per billion). Example 9: Repeat the process of Example 8, but the polluted The mixing time of the soil sample and the absorbent was extended from 30 minutes to two hours, and the same results were obtained. Example 1 0: 20 gallons of topsoil contaminated with 2 gallons of unleaded gasoline were sent to a belt mixer, and then Approximately 3 gallons of the encapsulating agent used in Example 1 were mixed with contaminated topsoil to produce a substantially homogeneous composition, which was placed in a 100-gallon storage tank. An additional 50-gallon tap water was used to homogenize this Composition mix When the enclosed contaminants float to the surface of the storage tank * Use a leaf rake to skim them off, and then test the water and soil left in question and find that they will generally be free of unleaded gasoline. Example 11: In this experiment, seawater was placed in a glass container, and then a sufficient amount of Kuwait to form a half-inch thick film on the surface of the water was poured onto the seawater. The solid hydrophobic silica (Aerosil R 974 ) The treated block copolymer (Kraton G-1650) is spread on the surface of the crude oil, forming a thickness of about 1/8 inch, and then stirred to make it into the crude oil film. In less than 1 minute, the present invention The block copolymer composition completely encapsulates the crude oil, forming a dry solid floating on the surface of the seawater. Because of the appearance of this dry solid, all paper sizes are freely used by China B Jiabiao (CNS) T4 regulation (210X297 male dragon) ) 81. 6. 10, 000 sheets (H) (please read the precautions before filling in this page) installed · Central Standard of the Ministry of Economic Affairs and printed by Beigong Consumer Cooperation Λ 6 Π 6 V. Inventions Description () does not contain oil stains, so it is easy to go from the sea surface After removing dry solids, seawater becomes clear without crude oil remaining. Using the untreated Kraton G-1650 block copolymer to process the above-mentioned Kuwait crude oil film, it takes about 1-1 / 2 minutes to wrap up the crude oil Scrap. Case 1 2: Repeat the process of Example Π, but use fresh water instead of seawater to obtain approximately the same results. Yin Li 1 3: Repeat the process of Example 12, but use unleaded gasoline instead of Kuwaiti crude oil to obtain roughly The same result. Case U: Repeat the process of Example 12, but using a 10-W-30 lubricant instead of Kuwait crude oil, the experimental results are roughly the same, and the water treated with the encapsulating agent of the present invention is completely free of Pollutants. Example 15: Repeat the process of Example 12, but replace the Kuwait crude oil with the following pollutants: diesel, heptane, sealing oil, transformer oil, JP-5 jet engine fuel, hydraulic oil, and transmission oil. In each experiment, roughly the same results were obtained, and the water was also substantially free of sulfohydrogen compound contaminants. In all experiments, the time required to encase the hydrogenated compound with the composition of the present invention was 25% faster than with the untreated composition. Example 1 fi: A 32-foot-long ship equipped with two inboard diesel engines and having 20 to 30 gallons of stern slots, with a circumference of about 4 hours and a length of about 48 inches, and built example 11 This paper size is used in China. Home standard (CN5) f4 specifications (2) 0X297 male dragon) 81. 6 · 10, 000 sheets (H) (please read back to the precautions # fill out this page) installation · line. Λ 6 Β 6 Printed by the Ministry of Economic Affairs, Standards of the Ministry of Economic Affairs, Co., Ltd., Pyongyang Co., Ltd. 10 points-V. Invention description () The stern pouch of the composition of the present invention used in pollution treatment. The stern pouch is effective before replacing Μ Remove 2 quarts of contaminated oil. In use, the stern bag can make the water in the stern substantially free of oil contaminants. Window Example 17: The surface of a small inland lake is covered with diesel oil traces about 1/4 inch thick Covering an area of 1/4 acres, in order to protect the lake shore from oil pollution, a barrage that allows water to pass through was used, in which each leaning wooden member filled the composition of the present invention used in Example 11, and the The wood is placed between the lake shore and the oil track. First, use a small boat to spray the book used in Example 11 on the edge of the oil track towards the lake shore The composition of the invention is then sprayed around the oil trace from the edge of the oil trace towards the center. The amount of the composition used to treat the pollution is approximately 20% of the calculated overflow weight. Within four hours The oil pollution is almost completely covered. Then use a 1 / 8-inch net to catch the oil-encrusted fragments in the water. The recovered fragments are dissolved in petroleum spirit to form a liquid diesel-rubber petroleum essence composition. Then This composition is filled into a 55-gallon mesh cylinder, which can be used as fuel for industrial water heaters. Example 18: In this example, a stern pump equipped with a parallel filter cylinder and appropriate piping and valves, First use one of the filters to remove pollutants in the abdomen water, and the second filter is on standby at any time. When the first filter is being renovated, it can replace the clematis. Each filter cartridge The amount of the decapsulation agent of the present invention used in the filled example 11 is sufficient to enclose about 2-1/2 quart of hydrocarbon contaminants. When the pressure drop through the filter is equivalent to entrap about 2 quarts Of contaminants The system will produce an appropriate value (please read the precautions before writing this page). Binding-Order-This paper is used in the middle of the paper (CNS) Ή specifications (210x297 public 81. 6. 10, 〇〇〇 Zhang (Η) The Ministry of Economic Affairs of the Central Committee of the Ministry of Economics and Fisheries C5 Workers' Co-op Cooperative Printing V. Description of Invention () Warning, at this time, you can use the second filter to replace, and then clean the first filter If the filter is not replaced in time, the filter will continue to function until the pressure drop makes the stern pump stop automatically and stop working. This stern pump has passed the system for about 6 months, so that the pollutants in the environment can be roughly Therefore, the present invention provides a high-efficiency method for recovering organic liquid or petroleum liquid from mud, water flow and solid surfaces. The block copolymers used in these methods can quickly absorb and / or adsorb the decanted organic liquid or petroleum-related liquid. After these organic liquids or petroleum-related liquids have been absorbed and / or adsorbed, the block copolymers encapsulating the organic liquids can be easily recovered, leaving at most the amount of decanted organic liquids or petroleum-related liquids. The recovered copolymer containing the recovered organic liquid can be used as solid fuel again, or it can be dissolved in each liquid fuel to form a fuel oil, which can avoid expensive landfill or cleaning problems. In addition, because the organic liquid is surrounded by the copolymer, it will increase the combustion temperature of the organic liquid (lower its ignition point). Table 10. Stern pump 11. Copolymer processing unit 12. Copolymer absorbent bed 14. Copolymer absorbent bed 16. Vessel outlet tube 18. Vessel 20. Handling unit inlet tube 22. Handling unit inlet tube (please read the precautions first and write this page) Packing-This paper standard is easy to use in a S family sample (CNS ) Τ4 specifications (210X297 public) 81. 6. 10,000 sheets (H) A 6 Π 6 5. Description of the invention () 23 · Pressure gauge 24. Three-way valve 26. Processing unit outlet pipe 28. Three-way valve 30. Container Inlet pipe 32. Pressure gauge 34. Treatment liquid container 36. Barrel outlet pipe 40. Air stripping tower 42. Ozone treatment unit 44. Ultraviolet radiation treatment unit 46. Active master treatment unit 48. Inlet water flow 50. Outlet water flow 60. Soil / Block copolymer mixture 62. Excavated hole 63. Surrounding soil 64. Underground fuel tank Printed by the Central Bureau of Economics, Ministry of Economic Affairs, Beigong & Cooperative (please read the back-end notes # 塡 写 此 页) 66. The second amount of soil 68. Organic fluid 70. Oil well 72. Well source 74. Ring body The paper size is easy to use China B standard (CNS) T4 specification (210X25) 7 male; «:) 81. 6. 10,000 sheets (H)

Claims (1)

I patch j HG 109 2 7 7 7 7 AB c D Printed by R Industry and Consumer Cooperatives, Central Bureau of Standards, Ministry of Economic Affairs VI. Patent Application No. 81104607 Patent Application Amendment of Patent Scope Amendment Date: June 82, 1 A method of contaminating organic liquids, comprising passing the aqueous solution through a contact area, the contact area containing at least one of a thermoplastic thermoplastic linear bi-block copolymer, a tri-block copolymer or a branched bi-block copolymer The formed fixed bed, and the pelletized thermoplastic elastomeric block copolymer contains at least one monovinylarene polymer block combined with an extruded conjugated diene polymer block, or one with an elastic monoene polymer Block-bonded monovinyl aromatic polymer block; M and a substantially contaminant-free water stream recovered from the contact area. 2. A method for removing contaminants of organic liquid from the soil * includes: at least one type of thermoplastic elastomer linear bi-block copolymer, tri-block copolymer, or branched two-block copolymer in the soil contaminated with organic liquid The copolymer is combined, and the pelletized thermoplastic elastic block copolymer contains a monovinyl aromatic polymer block combined with an elastic conjugated diene polymer block, or a monoethylene combined with an elastic monoene polymer block Based aromatic polymer block; mixing the soil contaminated with organic liquid with the thermoplastic elastic block copolymer to form a homogeneous mixture of the thermoplastic elastic block copolymer and the soil contaminated with organic liquid; mixing the homogeneous mixture Mix with water; recover the organic liquid B dyestuff enclosed by the block copolymer from the homogeneous mixture; and this paper is again applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm> — — 1J * -1——！ * Pack — 11 — I order ----- ^ " (please read the notes on the back and then write this page) 7 7 7 7 AB c D 、 Patent application difficulties from the rest In the mixture Grazing non-polluting soil 3. A method for recovering organic liquid film from a bow liquid or solid surface, which includes: will include a linear bi-block copolymer, tri-block copolymer, or branched bi-block copolymer The finely divided particulate thermoplastic elastomeric block copolymer is evenly dispersed on the organic liquid film, and the withdrawn thermoplastic elastomeric block copolymer contains a monovinyl aromatic polymer combined with a block copolymer of a co-coated diene diene Block, or a monovinyl aromatic polymer block combined with an elastic monoene polymer block; wherein the block copolymer is evenly coated with a layer of hydrophobic silica, and the amount of silica used is copolymerized in the thermoplastic block Within the range of 0.1 to 2.5 weight percent of the weight of the substance t Let the block copolymer encapsulate the contaminated oil; Μ and recover the block copolymer encapsulating the organic liquid from the surface of the liquid or solid. 4. Remove from the soil in a row The method for organic pollutants includes: mixing the soil contaminated with organic matter with water, and then leaching the organic liquid contaminants from the soil and obtaining a soil / liquid mixture « Filtering the soil / liquid mixture to obtain washed soil and a filtrate containing the contaminants of the organic liquid; passing the filtrate through a copolymer containing at least one thermoplastic elastomer linear bi-block copolymer, tri-block copolymer, or The contact area of a fixed bed formed by the branched double block copolymer, the size of the thermoplastic paper withdrawn from this sheet is in accordance with the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm> {Please read the note on the back Matters will be written on this page.) Installation and printing. Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy. 6. Patent Application Group A7 B7 C7 D7 A block copolymer of at least one polyimide and elastic conjugated diene. A monovinyl aromatic polymer block combined with a mass, or a monovinyl aromatic polymer block combined with an elastic monoene polymer block; M and a substantially pollution-free water stream recovered from the contact area. 5. A method to prevent organic pollutants from leaking from a coffin or pipe containing contaminants into the soil under or around the tank or pipe, including: mixing a certain amount of soil with a granular thermoplastic Dust linear bi-block copolymers, tri-block copolymers, or branched bi-block copolymers are mixed to form a soil / block copolymer mixture. The particulate thermoplastic elastomer block copolymer contains at least one conjugate with elasticity Monovinyl aromatic polymer blocks combined with diene polymer blocks, or monovinyl aromatic polymer blocks combined with elastic monoene polymer blocks; M and the earth / block copolymer mixture is placed in The perimeter or underneath of the tank or tube is underground. 6. According to the method described in item 5 of the patent application scope, it also includes the step of recovering the mixture of soil and copolymer from the ground contaminated with organic matter; The steps of printing and separating the copolymer containing contaminants from the soil. 7. The method according to any one of claims 1 to 6, wherein the elastic polymer block is at least partially hydrogenated. 8. According to the method described in any one of the items 1 to 6 of the patent application scope, this paper is again applicable to the Chinese Kjia Standard (CNS) A 4 specifications (210 X 297 public goods) 35 A7 B7 C7 D7 Ministry of Economic Affairs Printed and patented by the 8th Industrial Cooperative Cooperative of the Central Bureau of Standards, where the monovinyl aromatic polymer block is at least partially hydrogenated. 9. The method according to any one of claims 1 to 6, wherein the thermoplastic elastic block copolymer comprises a polystyrene-polybutadiene-polystyrene block copolymer. 10. The method according to any one of claims 1 to 6, wherein the thermoplastic elastomer block copolymer comprises a polystyrene-ethylene / butylene copolymer-polystyrene block copolymer Thing. 11. The method according to any one of items 1 to 6 of the patent application scope, further comprising dissolving the organic liquid pollutant enclosed by the block copolymer in an organic solvent to form an organic liquid pollutant -The copolymer liquid skull composition can be used as fuel for stoves, engines, etc. 12. The method according to item 11 of the patent application scope, wherein the organic solvent is selected from the group consisting of petroleum spirits, diesel oil, crude oil, and gasoline. 13. The method according to item 3 of the patent application scope, wherein the amount of the block copolymer used is approximately in the range of 0.1 to 1 pound for each gallon of organic liquid. 14. According to the method described in item 1 of the patent application scope, it also includes the step of treating the solution with ozone. 15. According to the method described in item 1 of the patent application scope, it also includes the step of treating the solution with ultraviolet radiation. 16. According to the method described in item 1 of the patent scope of application, the step of treating the solution with speech carbon is also included. (Please follow the precautions before writing this page on the wall)-Binding · Ordering. 7.4. This paper scale is applicable to China's B standard (CNS > A 4 specifications (210 X 297 Gong ®> A7 B7 C7 D7_ Sixth, apply for a patent Fan Yuan 17. According to the method described in item 1 of the scope of patent application, it also includes the step of passing the solution through an air stripper. ---------------- 1- · 1 ----- 装 ------ # (泉 (Please read the precautions on the back before writing this page) The paper standard printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm >