TW209254B - Aromatic fabrics and method of making thereof - Google Patents
Aromatic fabrics and method of making thereof Download PDFInfo
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- TW209254B TW209254B TW81108994A TW81108994A TW209254B TW 209254 B TW209254 B TW 209254B TW 81108994 A TW81108994 A TW 81108994A TW 81108994 A TW81108994 A TW 81108994A TW 209254 B TW209254 B TW 209254B
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經濟部中央標準曷8工消費合作社印絮 A6 B6 五、發明説明（1 ) 本發明像有關一種賦予纖維製品逸香之賦香味方法及 逸香纖維製品。 通常為使纖維製品漂逸香味，其所採取之手段有在含 有合成樹脂之印染糊料中直接混入香料，使用其印染纖維 製品之方法，或將含有合成樹脂及香料之分散液直接浸染 於纖維製品之方法。惟經由此等方法所得纖維製品所發散 出之香味，通常僳在初期較為強烈，但很快即被揮發失去 香味，其速度亦很快。而且在保管製品時所散發出之香料 會污染（移香）其他纖維製品，造成許多困擾，在消費階 段亦有經一次洗灌即失去全部香氣成份之缺點。 藉由摩擦等外力被破壊之微囊中包含有香料的内包香 料撤囊僳可藉由破壞徹囊而散發香氣者*包囊被破壊前不 會因揮發而失去香味。 所以如果可以堅牢地粘著固定此類内包香料之微囊於 纖維製品，並且可以長期間因使用該纖維製品而比較固定 地破壞適量之微囊時，則可以長期間比較固定地散發適度 之香氣，保管中亦無移香之問題，而且還可得耐洗濯性優 之纖維製品。 如果採用壓染含有内包香料之微囊及合成樹脂之分散 液於纖維製品之方法時，雖然被粘著固定於纖維製品之微 囊量較少，但所得纖維製品之質地受損之程度亦較小。又 ，依據特公昭53—47440號公報所掲示方法，採用 含多量合成樹脂之印染糊料中混入有内包香料微囊者予以 印染之方法時，雖然可以對纖維製品粘著固定多量之微囊 (請先閲讀背面之注意事項再場寫*.頁) 裝. 訂- 私纸張尺咬迺用中國29家抒举（CNS)甲1規格（21U X 2耵公坌） _ 3 - 經濟部中央標準局8工消费合作社印¾ A6 B6 五、發明説明（2 ) ，但亦提高所得纖維製品質地受損之程度。並且邸使採用 此等任何手段，亦無法獲得長期間可以較固定散發足夠香 味之纖維製品。 本發明像有鑑於以往技術上所具有問題而開發者，其 目的在於提供可以堅牢且多量地粘附内包香料之微囊於纖 維製品，因使用該纖維製品而可以長期間比較固定地破壞 適量之微囊，散發出適度之香氣的賦予香味之方法，以及 提供可以堅牢且多置地粘附内包香料之徹囊，且藉由使用 其纖維製品可以長期且較固定地破痰適置之徹囊以散逸香 氣之逸香纖維製品者。 為達成上述目的，本發明之賦香味的方法傜具備：以 含有氮陽離子化合物之液狀物對纖維製品施予陽離子化處 理之步驟； 為使高分子化合物所成微囊中至少内包有香料之内包 香料微囊粘附於上述纖維製品，以内包香料微囊被分散之 微囊分散液狀物，對於被陽離子化處理之纖維製品施予粘 附包囊處理之步驟；所成者。 又，本發明之逸香纖維製品偽將高分子化合物所成微 囊中至少内包香料之内包香料徹囊，粘附於以含有氮陽離 子化合物之液狀體予以陽離子化處理之纖維製品所成者。 潘mm品 本發明之纖維製品所用纖維可為例如木棉、麻等纖維 素纖雒、羊毛、絲等蛋白纖維、黏液嫘縈纖維等再生纖維 (請先閲讀背面之注意事項再填寫本頁) -裝. 訂. 本纸张尺度逯用f S3家^MCNS)甲4规格Uiu X 297公签） -4 - A6 B6 209如 五、發明説明（3 )Printed by the Central Standards Consumer Industry Cooperative of the Ministry of Economic Affairs A6 B6 V. Description of the invention (1) The present invention relates to a method for imparting fragrance to fiber products and fragrance fiber products. Generally, in order to scent the fragrance of fiber products, the method adopted is to directly mix the fragrance in the printing and dyeing paste containing synthetic resin, use the method of printing and dyeing the fiber product, or directly impregnate the dispersion containing the synthetic resin and fragrance in the fiber Product method. However, the fragrance emitted by the fiber products obtained by these methods is usually strong in the early stage, but it will soon be volatilized and lose the fragrance, and its speed is also very fast. Moreover, the fragrance emitted during the storage of products will contaminate (transfer fragrance) other fiber products, causing many problems. In the consumption stage, it also has the disadvantage of losing all aroma components after one wash and irrigation. The microcapsules that have been broken by friction and other external forces contain the inner encapsulated fragrance of the fragrance. Withdrawing the capsules can release the aroma by destroying the capsules. * The capsules will not lose their fragrance due to volatilization before the capsules are broken. Therefore, if the microcapsules containing such fragrances can be firmly fixed to the fiber products, and the appropriate amount of microcapsules can be destroyed relatively fixedly due to the use of the fiber products for a long period of time, the moderate fragrance can be distributed relatively fixedly for a long period of time. There is no problem of fragrance removal during storage, and fiber products with excellent washing resistance can also be obtained. If the method of pressure dyeing microcapsules containing fragrance encapsulated and synthetic resin in fiber products is used, although the amount of microcapsules adhered and fixed to the fiber products is less, the texture of the resulting fiber products is also damaged to a lesser extent. small. In addition, according to the method disclosed in Japanese Patent Publication No. 53-47440, when a printing and dyeing paste containing a large amount of synthetic resin is mixed with a package of perfumed microcapsules for printing and dyeing, although a large amount of microcapsules can be fixed to the fiber product ( Please read the precautions on the back and then write on the page. *) Binding. Ordering-Private paper ruler bite to use 29 Chinese expressive (CNS) A1 specifications (21U X 2 逵 公 坌) _ 3-Ministry of Economic Affairs Printed by the Bureau of Standards, Industry and Consumer Cooperatives A6 B6 V. Description of the invention (2), but it also increases the degree of damage to the texture of the resulting fiber products. Moreover, the use of any of these methods by Di Di also failed to obtain fiber products that could suffice enough fragrance for a long period of time. The present invention is developed in view of the problems in the prior art, and its purpose is to provide a microcapsule that can firmly adhere a large amount of perfume-encapsulated to a fiber product, and because of the use of the fiber product, a suitable amount can be destroyed relatively fixedly for a long period of time. Microcapsules, a method of imparting fragrance with a moderate fragrance, and providing thorough capsules that can firmly and multiplely adhere the encapsulated fragrance, and by using its fibrous products, it can break the phlegm for a long time and more firmly Those who disperse the fragrance of the fragrance fiber products. In order to achieve the above object, the method for scenting the present invention includes: a step of subjecting a fibrous product to a cationization treatment with a liquid containing a nitrogen-cationic compound; in order to make the microcapsules formed by the polymer compound contain at least a fragrance The perfume-encapsulated microcapsules adhere to the above-mentioned fiber products, and the microcapsule dispersion liquid in which the perfume-encapsulated microcapsules are dispersed is subjected to the step of adhering and encapsulating the fibrous products that have been cationized; In addition, the fragrant fiber product of the present invention pseudo-encapsulates at least the perfume-encapsulated perfume in the microcapsules made of the polymer compound and adheres to the fiber product that is cationized with a liquid containing a nitrogen-cationic compound . Pan mm products The fibers used in the fiber products of the present invention can be regenerated fibers such as cellulose fibers such as kapok, hemp, protein fibers such as wool and silk, mucous rayon fibers (please read the precautions on the back and fill in this page)- Packed. Ordered. This paper size is f S3 ^ MCNS) A 4 specifications Uiu X 297 public signature) -4-A6 B6 209 as five, invention description (3)
(請先面之注意事項再蜞寫本頁W 、醋酯纖維等半合成纖維、聚醛胺鐵雒、聚酯鐵維、聚丙 稀睛继維、聚胺基甲酸乙酯纖維等合成纖維。 本發明之纖維製品可為例如纱、纱條、散毛、織物、 编織物、不織布、使用此等織物、编織物、不織物之衣物 等缝製之·製品等。缝製之製品有例如襯衫、運.動衫、夾克 、牛仔楝、襪子、袋子、帽子等。本發明之纖雒製品不必 用限定為由單一種類纖維所成者。例如纱可為一種或二種 以上選自如上述纖維之纖維所混纺纱，又，織物亦可為交 織二種以上纱之製品。 另外，本發明中所利用纖維製品亦可為預先經染色等 著色者。 訂· 氛陽鼸平化会物 本發明之氮陽離子化合物可為例如以下所示種類。即 ,烷基銨鹽型之化合物、吡啶鹽型化合物、二氣基二醯胺 型化合物、聚胺型化合物、多陽離子型化合物。 氮陽離子化合物之具體例可為如下者。 烷基銨鹽型化合物有例如： 經濟部中央標準局*:工消費合作杜印製 三甲基十八烷基氯化銨、三甲基十六烷基氛化銨、三甲基 月桂基氯化銨、二甲基月桂基氣化銨、月桂基甲基氣化銨 、月桂基二甲基苯甲基氯化銨、烷基苯甲基二甲基氯化銨 、硬脂基苯甲基二甲基氣化銨、及烷基三甲基氣化銨等之 烷基銨鹽型陽離子界面活性劑；2, 3—環氧丙基三甲基 氯化銨；3—氣基一2—羥丙基三甲基氯化銨；以及特開 -5 - 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） 經濟部中央標準局β工消費合作社印製 A6 B6____ 五、發明説明（4 ) 昭52 — 1 55285號公報及特開昭 52 - 1 55286號公報所掲示具有三氮雜苯環之烷基 较鹽化合物等。 吡錠鹽型化合物有例如： 月桂*基氣化吡啶及硬脂醯胺基甲基氣化吡錠等吡錠鹽 型陽離子界面活性劑等。 二氰基二醛胺型化合物有例如： 二氰基醯胺之福馬林縮合物等。 聚胺型化合物有例如： 聚烯聚胺、與胍衍生物之縮合物、聚乙烯亞胺類、及 聚醯胺聚胺類等。 多陽離子型化合物之例有： 如特開昭54—64186號公報所掲示之聚丙烯睛 聚合物等的三级胺聚合物。 如特公昭4 3 — 2 4 3號公報所掲示之二甲胺—表氯 醇縮聚合物。 如特開昭57 — 1 1 2480號公報所掲示之2 —甲 基丙烯氣丙基三甲基銨鹽聚合物。 如特開昭55—76177號公報所掲示之二甲基二 烯丙基氣化銨条聚合物，如特開昭5 1 — 1 1 2987號 公報所掲示之聚表氯醇一三甲胺反應物。 如持開昭57—210083號公報所掲示之1一乙 烯基眯唑之四级化物聚合物。 如特開昭60—9979號公報及特開昭 衣纸張尺及通用中困Β家櫺準（CNS>甲4規格（2iu X 297公釐） -----------------{-----装------#------Μ (請先W讀背面之注意事項再填寫农頁) -6 - A6 B6 五、發明説明（5 ) 6 0 — 9 9 8 0號公報所記載之聚烯聚胺類的環氣化合物 所成四级化物之聚合物。 如特開昭5 7 _ 4 7 3 0 9號公報所記載之丙烯醯胺 及與其可共聚之陽離子性單體的共聚物。 特開昭63 — 234007號公報記載之具有四级銨 鹽基的陽離子性聚合物。 特開昭63-284225號公報記載之胺烷基丙烯 酵胺条聚合物的四级鹽等四级銨鹽型之聚合物。 待開昭56—128382號公報所掲示之如下所示 單體單位所成聚合物^ •Θ (請先閲f面之注意事項再f本買) -—裝.(Please follow the precautions before writing this page W, synthetic fibers such as acetate fiber, semi-synthetic fiber such as acetate fiber, polyacetal iron iron, polyester iron, polypropylene eye, polyurethane fiber, etc. The fiber product of the present invention may be, for example, yarn, sliver, loose hair, fabric, woven fabric, non-woven fabric, products sewed using such fabrics, woven fabrics, non-woven clothing, etc. The sewed products include, for example, shirts , Sports shirts, jackets, denim, socks, bags, hats, etc. The fiber products of the present invention need not be limited to those made of a single type of fiber. For example, the yarn may be one or more than one selected from the above-mentioned fibers The yarn blended with the fiber, and the fabric may be a product in which two or more kinds of yarn are interwoven. In addition, the fiber product used in the present invention may be a colorant that has been dyed in advance. The nitrogen cation compound can be, for example, the following types: namely, alkyl ammonium salt type compounds, pyridine salt type compounds, diaminodiamide type compounds, polyamine type compounds, and polycation type compounds. Specific examples of the substance can be as follows. Examples of alkyl ammonium salt-type compounds include: Central Bureau of Standards of the Ministry of Economic Affairs *: Industrial and Consumer Cooperation Du Printed Trimethyl Octadecyl Ammonium Chloride, Trimethyl Cetyl Amide Ammonium chloride, trimethyl lauryl ammonium chloride, dimethyl lauryl ammonium chloride, lauryl methyl ammonium vapor, lauryl dimethyl benzyl ammonium chloride, alkyl benzyl dimethyl chloride Alkyl ammonium salt-type cationic surfactants such as ammonium chloride, stearyl benzyl dimethyl ammonium vapor, and alkyl trimethyl ammonium vapor; 2,3-epoxypropyl trimethyl chloride Ammonium; 3-amino-2-hydroxypropyltrimethylammonium chloride; and JP-5-This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) Central Bureau of Standards of the Ministry of Economic Affairs A6 B6____ printed by the β-Consumer Cooperative Co., Ltd. V. Description of the invention (4) Zhao 52-1 55285 and JP 525-1155286 show the alkyl salt compounds with triazabenzene rings etc. Pyridine Salt type compounds include, for example, pyridinium salt-type cationic surfactants such as lauryl-based gasified pyridine and stearylaminomethyl gasified pyridine. Examples of cyanodialdehyde compounds are: formalin condensate of dicyanamide; polyamine compounds are, for example, polyene polyamines, condensates with guanidine derivatives, polyethylene imines, and poly Amide polyamines, etc. Examples of polycationic compounds are: Tertiary amine polymers such as the polypropylene eye polymer shown in Japanese Patent Laid-Open No. 54-64186. Such as No. 4 3-2 4 3 The dimethylamine-epichlorohydrin condensate polymer shown in the gazette. As disclosed in Japanese Patent Laid-Open No. 57-1 1 1 2480, the 2-methacrylic gas-propyltrimethylammonium salt polymer. -The dimethyl diallyl gasified ammonium strip polymer shown in JP-A No. 76177, such as the polyepichlorohydrin-trimethylamine reactant shown in JP-A No. 5 1-1 1 2987. For example, the quaternary polymer of 1-vinyl zirconium is shown in the publication No. 57-210083. For example, Japanese Patent Laid-Open No. 60-9979 and Japanese Patent Laid-out Paper Ruler and Universal Standard BB Standard (CNS > A 4 specifications (2iu X 297mm) ------------ ----- {----- 装 ------ # ------ Μ (Please read the precautions on the back before filling in the agricultural page) -6-A6 B6 V. Description of invention ( 5) A polymer of quaternary compounds formed from polyolefin polyamine ring gas compounds described in JP-A-9 9 8 0. Propylene described in JP-A No. 5 7 _ 4 7 3 0 9 Copolymers of amides and cationic monomers copolymerizable therewith. Cationic polymers having quaternary ammonium salt groups as described in Japanese Patent Laid-Open No. 63-234007. Amino alkyl groups described in Japanese Patent Laid-Open No. 63-284225 Polymers of quaternary ammonium salt type, such as quaternary salt of acrylamide polymer. To be shown in the publication No. 56-128382, the polymer formed by the monomer unit shown below ^ • Θ (please read f The precautions will be bought again)--installed.
HzC CHz \Φ/ N / \ k ch3 ch3 訂· n 以下式單體單位所成聚合物（商品名：Sharoll DC 糸列，第一工業製藥公司製），以及 經濟部中央標率局貝工消費合作社印製 等 C Η 2 C Η Η—C Η 2 h2c ch2 \θ/ N / \ R i R 2 夕 π Θ 此等四级銨鹽聚合物與其他乙烯条聚合物所成共聚物 -7 - 本纸張又度逯用中國國家標準（CNS)甲4規格（210 X 297公釐） A6 B6 經濟部中央標準居R工消费合作社印製 五、發明説明（6 ) 此等氮陽離子化合物中，尤以聚胺型化合物、二気基 二醯胺型化合物、以及羼於多陽離子型之四级銨鹽型聚合 物、及四级銨鹽與其他乙烯糸單體所成共聚物在本發明中 持別有效。 含氙陽離孑化合物之?商狀物 含氮陽離子化合物之液狀物有例如含有氮陽離子化合 物之水溶液，及含氮陽離子化合物之印染糊料等。 陽離子化處理 陽離子化處理可以對一部份或全部纖維製品，以例如 浸漬纖維製品於含氮陽離子化合物之水溶液的狀態下進行 ,亦可以霧狀噴塗此類水溶液於纖雒裂品爭以處理，亦可 以印染含有氮陽離子化合物之印染糊料於纖雒製品予以處 理。 莕料 可在本發明中使用之香料有不溶水性或難溶水性之天 然香料及合成香料。此等香料可以任意组合使用，可視其 需要添加可延長香氣赛命之保留劑或改變香氣變調用劑等 補助劑予以使用。藉由組合一種或二種以上之香料及補助 劑而可得鈐蘭、薫衣草、紫羅蘭、玫瑰、茉莉花、康乃馨 、紫丁香、風信子、百合、揠子花、洋茉莉等天然花香氣 ;香蕉、蘋果、鳳梨、樱桃、葡萄等水果香氣；窮香；以 (請先閲讀背面之注意事項再塡寫本頁) 丨裝· 訂· -i 衣紙張又度通《! +國國家標準（CNS)取!規格（210 X 297公坌） -8 - A6 B6 五、發明説明（7 ) 及其他想像性或幻想性之快香。 上述天然香料之例有：如麝香、痤貓香、海狸香、龍 延香等之動動性香料；烯孫、香茅醇、香葉草醇、沈香醇 、檬樣油醛、香茅醛、丁香酚、黃樟油精及薄荷醇等植物 香料；以·及如下之精油等，即，茴香油、釣樟油、松香油 、香茅油、樟腦油、桂皮酮油、茉莉花精油、綠薄荷油、 雪松油、老鸛草油、丁字油、晚香玉油、松節油、橙花醇 油、薄荷油、掌玫油、羅漢松油及迷迭香油等。上述合成 香料則有例如香葉烯、香芹酮、羥基香茅醛、萜品醇、水 合萜二醇、1 一薄荷醇、冰片、樟腦、紫羅酮、及甲基紫 羅酮之類的萜烯条合成香料；以及苯甲醇、/3 -苯基乙醇 、苯基乙醛、肉桂醛、α—戊基肉桂醛、仙客來醛、茴香 醛、茴香腦、/3 —棻酚甲醇、洋茉籾精、乙基香草醛、香 豆靈、水楊酸異戊酯、胺茴酸甲酯、甲基胺茴酸甲酯、香 草醛、甲基香草醛、玫瑰苯酮、醋酸α—苯丙酯、窮香酮 、合成麝香、青葉醇、茉籾酮、7 —十一烷内酯、及 Versalide {1—〔2 — (3 — 乙基一 5，6，7，8 — 四氫基_5，_5, 8, 8 —四甲基）某基〕乙酮}等類 的芳香族及脂環族条合成香料等。 上述保留劑則有例如苯甲酸乙酯、酞酸乙酯、水揚酸 苯甲酯、洋茉籾精、十三烷二酸乙烯酯、菖蒲油、及十氧 雜十六醇等。 上述改變香氣變調劑俗有例如高级脂肪族醛及異丁子 香酚等。 -----------------γ-----裝------.玎------^ (請先閲讀背面之注$項再填寫本買> 經濟部中央襟準爲β工消费合作社印焚 衣纸張又度逄用中因因家抒率（CNS)甲1規恪（210 X 297公釐） _ 9 _ 經濟部中央標準局W工消費合作社印製 A6 B6 五、發明説明（8 ) 肉包番料撤爨 欲在高分子化合物所成微囊中至少内包香料之方法， 可以採用例如以下之方法。 即，·可以使用如上述之香料及補助劑等，以及做為形 成皮膜物質之高分子化合物，並視其需要使用界面活性劑 、保護膠體、pH調整劑、電解質等，依公知之囊化方法 實施，卽可以以分散水条分散液之狀態獲得内包香料微囊 〇 徹囊化之方法可以採用例如界面聚合法、原地聚合法 、液中硬化被覆法等化學上方法；相分離法、凝聚法、界 面析出法等物理化學方法；噴塗乾燥法、氣中懸濁被覆法 、粉床法、真空蒸鍍法等機械上方法等。 又，可以使用此等方法中之一種或二種以上包囊化方 法重覆二次包囊化處理，藉此可以成為複層之微囊。必須 針對撤囊粒徑、膜厚、膜材料進行檢討、適當地調整微囊 之強度使其可以視其用途長期間比較穩定地藉由使用纖維 製品而産生摩擦，可破壞適量之微囊以散發適度之香氣為 最重要。 内包香料之微囊粒徑係以0. 1〜lOOzzm為宜 0. lwm以下時很難破壞微囊、通常之纖維製品用法時 ，例如依服時幾乎無法因穿用衣服之動作而散發香氣，另 一方面，若為1 00 /zm以上時則會因些微之外力而破壊 微囊，在製造成品之工程中香氣會散發殆盡。内包香料微 -10 - (請先閱讀背面之注意事项再填寫本頁) —裝. 訂. 經濟部中央標準局R工消費合作社印製 Α6 Β6 五、發明説明（9 ) 囊之更佳粒徑僳1〜50//m。只要為此範圍，通常可藉 由一般使用纖維製品而較容易破壞微囊更易於發散適度香 氣，製品化工程中不會因撖囊被破壊散發香料。 上述形成皮膜物質，較佳者有例如可形成聚脲皮膜之 多價異氰酸鹽與多價胺，可形成聚醛胺皮膜的多醯氣與多 價胺，可形成聚胺基甲酸乙醋皮膜的多價異氰酸鹽與聚羥 基化合物，可形成聚酯皮膜之多醛氮與聚羥基化合物，可 - · · 形成環氣樹脂皮膜之環氧化合物與多價胺，可形成三聚氡 胺樹脂皮膜之三聚氣胺福馬林預聚物，以及可形成脲樹脂 皮膜之脲福馬林預聚物，及乙基纖維素，聚苯乙烯及聚醋 酸乙烯，及後述之陰離子性高分子化合物，兩性高分子化 合物等。 另外，上述撤囊之皮膜偽以耐熱性優之熱硬化性者為 宜。較佳之上述界面活性劑及保護膠體可使用者有例如陰 離子性界面活性劑，兩性界面活性劑，陰離子性高分子化 合物，兩性高分子化合物等。又，可以併用此等與非離子 界面活性劑。 上述p Η調整劑或電解質可以使用上述包囊化法中通 常被使用者。 本發明中可以直接使用含如上述所得内包香料徹囊之 分散液，亦可以使用在可以保持徹囊分散性之範圍下自該 分散液中除去界面活性劑或保護膠鼸者。另外，亦可以脱 水、乾燥該徹囊之分散液使其一旦成為粉末狀，使用時視 其需要加入界面活性劑或保護膠體分散於液中使用。這時 (請先S讀背面之注意事項再填寫本頁) 丨装. 訂. 本紙張尺度通用中國國家標翠（CNS)甲4現格（210 X 297公;) -11 - 54 54 經濟部中央標準局S工消費合作杜印？* Α6 Β6 五、發明説明（10) 若該微囊之分散性極佳時亦可以不必添加界面活性劑或保 護膠體。構成撤囊皮膜之高分子化合物若為陰離子性或兩 性者，則通常均具有充分之分散性。 上述陰離子性界面活性劑可為例如烷基硫酸酯鹽、院 基苯磺酸·鹽、烷基菓磺酸鹽、烷基硫琥珀酸鹽、烷基二苯 醚二磺酸鹽、烷基磷酸鹽、聚氧乙烯烷基硫酸酯、聚氣乙 稀烷基烯丙基硫酸酯鹽、聚氣乙烯烷基醚硫酸鹽、聚氣乙 嫌烷基苯醚硫酸鹽、聚氣乙烯聚苯乙烯基苯醚硫酸酯、聚 氧乙烯烷基磷酸酯等。 上述陰離子高分子化合物有例如聚丙烯酸、聚一α— 經基丙烯酸及甲基丙烯酸以及此等與其他乙烯条聚合物所 成共聚物、乙烯/馬來酐共聚物、丁烯/馬來酐共聚物、 乙烯醚/馬來酐共聚物、陰離子改質之聚乙烯醇、阿拉伯 橡膠、羧甲基纖維素、羥乙基纖維素、羥丙基纖維素、澱 粉衍生物等。 上述兩性高分子化合物可為例如明膠、酪素等。 上述非離子性界面活性劑則有例如聚氧乙烯烷基醚、 聚氣乙烯烷基烯丙醚及其他聚氣乙烯衍生物、聚氣乙烯♦ 聚氧丙烯塊狀共聚物、花楸釀脂肪酯、聚氣乙烯花楸醇脂 肪酸酯、甘油脂肪酸酯等。 又，内包香料微囊可以賦香味同時賦予色彩於纖維製 品成為由著色劑所著色之物品。著色内包香料微囊時可以 例如在製造之際混入著色劑於形成皮膜物質而予以著色。 上述著色劑可以使用例如不溶性偶氮条、&染料条、 长4氏張又度通用申® 律罕（CNS)甲1現格（210 X 297公坌） -12 - (請先閲讀背面之注意事項再填寫本頁) _裝· 訂- 經濟部t央標準局Λ工消費合作社印製 A6 B6 五、發明説明（11) 驗性染料媒色顔料、酸性染料媒色顔料等各種有機顔料； 欽白、鉻黃、鎘红、氣化鐵、碩黑、群青等無機顔料；直 接染料、酸性顔料、反應性顔料、鹺性顔料等。又，例如 螢光顔料、油溶性染料、分散染料、固溶體型之日光螢光 顔料等亦可使用。 撒釁分散液狀物 微囊分散液狀物可為例如分散内包香料微囊之水条分 散液及分散内包香料撤囊之印染糊料等。 粘附撒蠹處琿 粘附微囊處理可以對一部份或全部继維製品，以浸漬 纖維製品於分散有内包香料徹囊之水分散液的狀態下進行 ,亦可以用噴鍍霧狀之如上述水条分散液纖維製品予以處 理，亦可以用印染分散有内包香料微囊之印染糊料於纖維 製品予以處理。 賦莕味之工稈例 採用本發明之賦香味方法賦香予纖維製品時，可以例 如為以下之方法。 首先精練上述纖維製品，去除漿料或雜質。當然只要 清淨亦可以免去精練。 其次在適當之浸漬用浴中投入對纖維製品為5〜5 0 重量倍之水（浴比1 : 5〜1 : 50),較佳為10〜 ------------------{-----裝------訂------歲 {請先聞讀背面之注意事項再場寫本頁> Ρ氏張;通用中困國家標苹（CNS)甲4规格（2ΐυ X 297 W釐〉 -13 - A6 B6 經濟部中央標準场R工消費合作社印製 五、發明説明（13 30重量倍之水（浴比1 : 10〜1 : 30),在此水中 加入對處理前之纖維製品為〇·1〜20重童％,較佳為 0. 3〜5重量％左右之氮陽離子化合物。對此再添加醋 酸、酒石酸、草酸、蘋果酸等酸，調整p Η值為酸性，為 提高陽離子化合物對纖維製品之滲透性，可視其需要加入 脲、甘油、乙二醇、聚乙二醇、二（乙二醇）等濕潤劑。 其次浸漬上述纖維製品於如上述所得水溶液（含有氮 陽離子化合物液狀物之一例），保持於常溫〜8 0*C左右 溫度5〜30分鐘左右，即可以有效地陽離子化該纖維製 品。 繼而充分冲洗纖維製品，洗去多餘之氪陽離子化合物 或其他添加劑後予以脱水。 其次，在含有被處理纖維製品中，放入對處理前继維 製品為1:5〜1:50,較佳為1:1◦〜1:30之 水，再於其中加入對處理前之纖維製品為0. 1〜50重 量％，較佳係1〜25重量％左右之内包香料徹囊並予以 分散。此内包香料微囊可以做為含内包香料徹囊之分散液 予以加入。 於常溫至9 01C左右處理如上述所得分散液（微囊分 散液狀物之一例）徑5〜3◦分鐘時，被陽離子化之上述 纖維製品中可以完全吸入内包香料微囊。以10〜50重 量％高濃度使用上述内包香料撤囊時，此處理溫度僳以 60〜901C為宜。 藉由此處理，上述内包香料徹囊可以藉由化學上之離 f請先閲讀背面之注意事項再填寫本頁> -裝- 訂· Λ 本紙m々度遇用中國國家#at (CNS) W 4 «埤（211) X 297公f ) -14 - 娌濟部中央標準局R工消費合作社印Κ A6 B6 五、發明説明（13) 子結合及物理上吸附而結合於上述纖維製品，將之脱水、 乾燥而可以使内包香料撤囊堅牢且多置地粘附於餓維裂品 。欲使其更牢固地粘附時，最好在乾燥後再以80〜 1 8 0 *0左右溫度熱處理0 . 5〜1 0分鐘左右。 如此所得之纖維製品偽粘附有大量之内包香料微囊， 並且不會損及纖維製品之感觭，質地柔軟，洗濯堅牢度亦 極優者。 較侔之賦莕味方法 本發明賦香味方法中較佳之實施形態係以不損及纖維 製品質地及感觸之量的粘結劑對於纖維製品施予粘結處一 理之工程。 經此粘結處理工程所得纖維裂品像被強化内包香料微 囊對於纖維製品之粘附，可以更提高其洗濯堅牢度。 上述拈結劑之量僳對該纖維製品以粘結劑固體成份而 言，通常為0. 1〜10重量％左右，較佳係0. 3〜5 重量％。 可使用之粘結劑像例如丙烯酸樹脂、甲基丙烯酸樹脂 、醋酸乙烯樹脂、聚胺基甲酸乙酯樹脂、聚酯樹脂、苯乙 烯丁二烯膠乳、聚烯類樹脂、上述陰離子性高分子化合物 中的聚丙烯酸、甲基丙烯酸、或此等之衍生物或此等與其 他乙烯糸聚合物之共聚物。本發明中係以此等中之丙烯酸 酯樹脂、聚胺基甲酸乙酯樹脂為最佳。 粘結處理偽可在例如浸漬纖維製品於含粘結劑之水溶 ——；--------------γ-----装------訂------Λ (請先聞讀背面之注意事項再填寫本頁} 本紙張尺度過用中國國家標準（CNS)甲4規格（210 X 297公釐） -15 - 經濟部中央標準局R工消费合作社印黎 A6 B6 五、發明説明（14) 液的狀態下進行，亦可噴霧含粘結劑之水溶液於纗維製品 予以處理，亦可以印染含粘結劑之印染糊料於纖維製品予 以處理。 依此實施形態賦香味予纖維製品時，可採用例如以下 之方法。. 賦番味奮例1 以含有氮陽離子化合物之水溶液處理（陽離子化處理 )纖維製品後，藉由浸漬於含上述内包香料撤囊之分散液 中的處理（粘附處理），使該内包香料微囊吸附於纖維裂 品。更在該液中加入對該纖維製品為0.1〜10重量％ 粘結劑固體成份的粘結劑，繼而在常溫至90t：處理1〜 30分鐘（粘结劑處理）後，脱水乾燥之。 _莕昧審例2 以含有氮陽離子化合物之水溶液處理（陽離子化處理 )纖維製品後，藉由浸漬於含上述内包香料微囊之分散液 中的處理（粘附處理），使該内包香料微囊吸附於纖維製 品後，予以脱水。繼而在收容該纖維製品之浴中，再注入 浴比為1:5〜1:50,較佳為1:10〜1:30左 右之水，再加入對該纖維製品為0.1〜10重量％粘結 劑固體成份之粘結劑，於常溫至9 Ot：處理5〜3 0分鐘 (粘結劑處理）後予以脱水乾燥。 (請先聞讀背面之注意事项再場寫本買) _裝- 訂· 衣纸H变逯用中囷西家標;iMCNS)甲1規恪（21U X 297公货） * 16 - 經濟部中央櫺準局W工消费合作社印製 A6 v _B6____ 五、發明説明（15) 賦香味奮例3 以含有氮陽離子化合物之水溶液處理（陽離子化處理 )後，浸漬於含上述内包香料微囊及對纖維製品為〇. 1 〜10重量％粘結劑固體成份之粘结劑，於常溫至90t： 處理5〜· 3 0分鐘（粘附處理及粘結劑處理），予以脱水 、乾燥。 賦呑味奮例4 以含有氮陽離子化合物及對纖維裂品為0.1〜10 重置％粘結劑固體成份之粘结劑的水溶液處理纖維製品（ 第1工程：陽離子化處理及粘結劑處理）後，浸漬於含上 述内包香料微囊之分散液中的處理（第2工程：粘附處理 ),藉此使内包香料微囊吸附於纖維製品。在常溫至90 t：處理1〜3 0分鐘後予以脱水、乾燥。 又，第1工程中還可視其需要加入蘇打灰或氫氣化納 ，以中和氮陽離子化合物。 另外，第1工程中還可以代替氮陽離子化合物與粘結 劑二者，使用不損及纖維製品之質地及感觸之量的屬於氮 陽離子化合物的陽離子性粘結劑。 此類陽離子性粘結劑有例如Voncoat SFC条列（商品 名：醋酸乙烯条或丙烯酸醋糸乳劑：大日本油墨化學工業 公司製）、Yodosol AT条列（商品名：丙烯酸酯糸乳劑： 鐘纺NSC公司製）、CGC条列（商品名：丙烯酸酯条乳劑 :住友化學工業公司製）、特開昭62 — 1 87702號 (請先閲讀背面之注意事项再填寫本頁) .裝. 訂- 本紙張逯用中國囷家桴準（CNS)甲4規恪（21U X 297公釐） -17 - 缦濟部中央標準房R工消费合作社印黎 A6 B6 五、發明説明（16) 公報掲示之陽離子性乳劑、特開昭62— 1 3 1 003號 公報掲示之陽離子性共聚物、特開昭62—201914 號公報掲示之陽離子性聚合物，特開昭 62 — 2632 1 1號公報掲示之陽離子性膠乳等。 以上·較佳之賦香味實例1〜4中，粘結劑偽可吸附於 纖維製品大約與含於液中同程度，即對於纖維裂品為 0. 1〜10重置％程度之拈结劑固體成份，經脱水乾燥 ，即可以堅牢地粘附於該纖維製品。結果可以更提高其摩 擦堅牢度或洗濯堅牢度。這時，粘結劑固體成份若為 0. 1重置％以下時效果不足，10重量％以上時則常會 損及纖維之感觸、質地。 以上説明之本發明賦香味方法中，亦可以為使内包香 料撤囊著色在分散内包香料徹囊之微囊分散液狀物中使其 含有例示之著色劑或熱可逆變色性材料及光可逆變色性材 料等著色劑，使其吸附内包香料徹囊時可以同時吸附此等 著色劑於纖維製品。 藉此在賦香味時，還可以同時實現固定地著色，或因 溫度變化或光照射而引起之可逆性色彩變化等。 熱可逆變色性材料有例如酸顯色性物質、酸性物質及 溶劑之三成份混合物；酸顯色性物質及酸性物質之二成份 混合物；膽甾型液晶；金屬錯鹽等，EP_A-◦ 480 1 62所掲示之材料。 另外，光可逆變色性材料有例如偶氮苯条化合物、硫 截条化合物、雙硫腙金屬錯合物、螺吡喃条化合物、螺噁 本呔張又度通用中®阈家埭準（CNS)甲4 *見恪（21(J X 297公:$ ) -18 - <請先«讀背面之注意事項再填寫本頁) 丨裝_ 訂· 經濟部中央標準爲R工消费合作社印製 A6 B6 五、發明説明（17) 嗪条化合物、亞甲基丁二酐（（fulgide条化合物、二氫 基芘条化合物、螺I*喃条化合物、1、4 2H —噁嗪、 三苯甲烷条化合物、Violoeen条化合物、棻吡喃条化合物 等有機光致變色物質。具體言，可以使用同樣於EP_A 一 04 80 1 62所掲示之材料。本發明中尤以使用螺吡 喃条化合物、螺噁嗪糸化合物、fulgide糸化合物、某吡 喃糸化合物為宜。 另外，還可以先著色纖維製品，然後施予如上述之本 發明賦香味方法。 肉句.番料撒g夕製诰例 其次舉内包香料微囊之製造例，又，以下記載中以「 份」表示「重量份」。 製造例1 在30份保持為40¾之10% (重量/重量）明膠 中，投入1 2份Woody 4319 (合成香料商品名·· Kotobuki香料公司裂）、調整攪拌速度使其乳化成為約 10Wm左右粒徑。繼而在此混合物中加入30份同樣保 持為401C之10% (重量/重董）阿拉伯橡膠，繼缠摟 拌1 ◦分鐘。將128份40t：之水予以混合物中，再滴 下醋酸使pH值為4〜4. 3。其後冷卻此混合物為5¾ ，加入1份30% (重量/重量）福馬林及數滴10% ( 重量/重量）氫氣化鈉，調整pH值為9。其後每分鐘昇 (請先閲讀背面之注意事項再填寫本頁} -丨裝. 訂· 本紙張尺度逯用中國國家標準（CNS)甲·！現格（21ϋ X 2S7公货） -19 - W如 A6 B6 五、發明説明（18) 高1C之速度昇溫至50*0,保持此溫度1小後，放冷， 得到約200份分散有内包香料微囊之分散液。 製造例2 在保持為6 0 TC之3 0 0份3% (重量/重量） EMA3 1 (乙稀一馬來酸共聚物商品名，盂山度公司製 )水溶液中，加入於6 0¾加熱混合之2 0份LEMON 43 14 (合成香料之商品名：K0T0BUKI香料公司製）， 與60份十六醇，調整攪拌速度予以乳化使之成為粒徑5 wm左右。另外於6〇1〇反應30份37% (重量/重量 )甲醛，與1 ◦份三聚氡胺1 ◦分鐘得到三聚氰胺之預聚 物，將其滴入上述乳化液中。滴下後，昇溫液溫為8 ου ，摟拌加熱30分鐘，得420份分散有内包香料微囊之 分散液。 製造例3 绠濟部中央標準局8工消费合作社印製 (請先閲讀背面之注意事項再塡寫本頁> Γ 在300份含有3份Demol N (陰離子界面活性劑 之商品名，花王公司製）之水溶液中，滴入保持為8〇υ 之40份DINP (可塑劑）及30份SumijuleN 75 (脂肪族聚異氟酸酯之商品名，住友Byer Ureathan公司 製）之混合液，調整攪拌速度使之粒徑可為2wm程度。 約15分鐘後提昇溫度為95υ,加熱攪拌2小時，得約 4 0 0份分散有内包香料微囊之分散液。 本纸張又度通用中囤:¾家懌哗（CNS)甲i坭格（21G X 2釕2¾ > - 20 - ο 經濟部中央標準局R工消费合作社印製 ο r;l A6 B6 五、發明説明（19) 製造例4 在196份2%聚乙烯醇中，滴下保持於801C之 3 5份Peppermint 4 2 3 4 (合成香料商品名，Ko t ob-uki香料公司製），5 5份Crystol 3 5 2 (流動石蟠 商品名，.Esso石油公司製），2 0份Epikote 8 2 8( 環氣樹脂商品名，油化Shallepoxy公司製）及2份F卜 ex blue base (酞青商品名，松井色素化學工業公司製） 之混合液，調整掇拌速度使其粒徑為約15 /im。繼而滴 下1 2份Epicure U (硬化劑商品名，油化Shell Epoxy 公司裂），繼續加熱攪拌反應2小時。得到約320份分 散有被著色為藍色之内包香料微囊的分散液。 〔發明之效果〕 依本發明賦香味之方法時，可以不損及纖維製品之質 地與感觭之下，堅牢且多量地粘附内包香料微囊於纖維製 品，洗濯後亦很少自纖維裂品脱落内包香料微囊，保管纖 維製品中亦無移香味之問題。而且該纖維製品還可以因使 用時之摩擦等長期且較固定地破壞適置之微囊，發散適度 之香味。 又，對纖維製品施予粘結劑處理時，可以在不傷及纖 維製品質地及感觸之下強化内包香料微囊粘附於纖維製品 ，纖維製品散發之香味作用亦與未施予粘結劑者相同，可 以長期被維持。 本發明之逸香纖雒製品係可藉由使用時之摩擦，長期 (請先面之注意事項再填寫本頁> _裝· 訂· 本纸張疋度適用中國國家標準（CNS)甲4规格（210 X 297公嫠> -21 - A6 B6 五、發明説明（20) 且較固定地破壊適量之内包香料徹囊散發適置香氣，藉由 洗濯亦很少脱落内包香料撤囊，保管中亦無移香之問題， 並且可以保有纖維製品之極佳質地及感觸。 又，藉由不損及纖維製品質地及感觸之置的粘結劑所 處理者偽可強化粘附包含香料微囊於纖維製品，散發香氣 之作用與未施予粘結劑處理者無異，可被長期維持下去。 以下說明本發明實施例，當然，本發明並不限定於此 者。 實施例1 首先洗練棉襯衫（120份白布）去除漿料或雜質。 其次，在5公升容器中加入2400份水（浴比1 : 2 0 ) 2份，Sanf ix PAC— 7 (四级銨鹽型陽離子性高分 子化合物水溶液商品名，三洋化成工業公司製）及10份 乙二醇。 浸漬上述洗練過之棉襯衫於此水溶液，慢慢提高溫度 至70t：處理1 5分鐘。 經濟邨中央樣準局S工消费合作社印裂 (請先面之注$項再填寫本頁) r 繼而以水充分沖洗襯衫，除去多餘之氮陽離子化合物 或其他添加物後脱水之。 其次在5公升容器中放入被脱水後之襯衫，2400 份水，10份製造例1所得内包香料微囊分散液，25份 Chromicolor aqualite ink fast blue AQ-2 7 (感溫變 色性色素商品名，松井色素化學工業公司製），慢慢提高 液溫，於80C處理15分鐘，結果内包香料微囊被完金 本紙張尺度適用中西西家樣準（CNS>甲4说格（210 X 297公釐） -22 * «濟部中央揉準房R工消费合作社印製 认㈣ A6 B6 五、發明説明（21) 吸附入襯衫。 繼而充分冲洗此襯衫，脱水後自然乾燥，雄而以轉鼓 乾燥於1 4 0 t：熱處理1分鐘。 如此所得襯衫係質地，感觸俱佳，穿用此襯衫慢抱時 可以發散木香，有如在森林中慢抱之感覺。另外，隨體溫 上昇，藍色襯衫變成白色。 實施例2 與實施例 1 一 樣操作使01111*〇1111〇〇1(^&<111&1〖16£&3-t blue AQ-2 7及内色香料微囊吸附於棉襯衫（白棉布 1 2 0份），以水沖洗襯衫並脱水之操作。 繼而將2400份水及12份（固體成份約3. 6份 )Matsuminsole MR-1 0 (丙嫌酸醋条樹脂乳液商品名， 松井色素化學工業公司製）加入收容有襯衫之容器，繼而 慢慢提高溫度，於701C處理15分鐘後，脱水、乾燥襯 衫。 所得襯衫示有與實施例1一樣之功能，感觸與質地均 極佳且不遜於實施例1,並且可提高耐洗濯性。 實施例3 以 2 5 份 Photopia aqualite ink Purple A-Q-R(感 光變色性色素商品名，松井色素化學工業公司製）.代替 Chromicolor aqualite fast blue A-Q-2 7 以外，其他均 與實施例1一樣處理棉襯衫。 (請先面之注$项再填寫拿買) t 丁 本紙張尺度適用中困國家標準（CNS)甲4规格（210 X 297公釐） -23 - 00 00 經濟部中央標準局貝工消費合作社印製 A6 B6 五、發明説明（22) 如此所得襯衫係穿用時亦同樣只要輕度動作即可發出 木香，令穿用者仿如沐浴於森林中，精神清爽。又，出去 室外被照射陽光部份即成深紫色，襯衫之感觸、質地、耐 洗灌性等品質均與實施例1一樣極佳。 賁施例4 首先洗練棉蓮動衣（3 0 0份），除去漿料及雜質。 在1 ◦公升容器中放入6 0 0 0份水，2. 7份Sa-nf ix 7 0 (陽離子性高分子化合物商品名，三羊化成公 司製）及15份乙二醇，浸漬上述蓮動衣於此液中，於 601C處理15分鐘後，充分洗濯蓮動衣，予以脱水。 其次在收容有此運動衣之1◦公升容器中放入 600 ◦份水，加入45份製造例2之内包香料微囊分散 液並使之分散。然後慢慢昇溫此液，處理15分鐘後，充 分沖洗棉蓮動衣，並予脱水。 繼而在收容有此蓮動衣之10公升容器中注入 6000份水，加入30份1^£^&11六？一20(聚胺基甲 酸乙酯乳液商品名，大日本油墨化學工業公司製），慢慢 提昇液溫，於7〇r處理15分鐘後，脱水棉蓮動，方以 自然乾燥充分乾燥。 穿用此蓮動衣作輕度蓮動時可以因摩擦而破壞微囊， 漂逸檸樣香味，蓮動衣之感觸、質地、耐洗濯性均佳。 實施例5 (請先«面之注$項再f本頁) -裝- 訂_ 本紙張適用中國國家標準（CNS)甲4¾格（210 X 297公釐） -24 ~ ,09 ,09 經濟部中兴標準局霣工消费合作社印製 A6 B6 五、發明説明（23) 洗練丙烯睛製襯衫，除去漿料或雜質。 其次在5公升容器中加入2400份水（浴比1 : 20) , 4份SanfiXPAC-7 (四级銨鹽型陽離子性离分 子化合物水溶液商品名，三洋化成公司製），6份1^18-uminsoi.MR-C (丙烯酸酯条樹脂乳液商品名，松井色素化 學工業公司製），浸漬洗練過之襯衫此等混合液中，慢慢 提昇液溫，於70TC處理15分鐘。 繼而以水充分沖洗襯衫，予以脱水。 其次在5公升容器中加入2400份水及10份實施 例4所得内包香料微囊，浸漬脱水過之襯衫。 缓缓提昇此處理液之溫度，於7 Ot：處理15分鐘， 結果此處理傜自藍色變為無色透明，被確認已全部被吸盡 〇 其次，充份沖洗襯衫，脱水後充分乾燥之。 如上述所得襯衫傜感觭及質地均佳，呈藍色，穿用時 隨著軽微動作而可漂逸出清香之荷荷香味，該功能僳經重 覆洗濯亦未消失。 實施例6 在5公升容中放入2400份水（浴比1 : 20), 2份SanfixPAC-7 (四级銨鹽型陽離子型高分子化合物 水溶液商品名，三洋化成公司製）及10份乙二醇。 預先以一般印染油墨，使用網販型印染玫瑰花園案之 聚酯/棉混纺短上衣（120份），將其浸漬於上述水溶 (請先閲讀背面之注意事項45-¾^頁) .丨裝 訂· 本紙張又度逋用r困困家標準（CNS)甲4规格（210 X 297公釐〉 _ 25 - ώ A6 B6 五、發明説明（24) 液中，缓缓提昇溫度，在701C處理15分鐘。 繼而以水沖洗該衣衫去除多餘之氮陽離子化合物或其 他添加物後予以脱水。 其次，在數容有脱水過衣衫之5公升容器中加入 240 0.份水，及20份製造例3所得内包香料微囊分散 液，缓缓提昇溫度，於801C處理15分鐘。 如此所得衣衫僳感觸及質地均佳，穿用時以輕微之動 作或例如坐在沙發上之摩擦等，即可以破壞微囊，漂逸出 玫瑰香氣。功能偽經久重覆洗濯亦不會消失。 比較例1 代替製造例1所得内包香料撤囊分散液，使用含界面 活性劑之1 88份水中乳化1 2份Woody 4 3 1 9所成 1 ◦份乳化液，除此外其他則均與實施例1 一樣處理襯衫 ，此襯衫僳在乾燥工程中香料即岗失殆盡，所剩些微香味 亦洗濯一次即完全消失，失去商品價值。 比較例2 除不使用氮陽離子化合物以外，其他則均與實施例1 一樣處理，所得襯衫像未完全吸附内包香料微囊，所以香 料極微，經數次摩擦即失去香味，失去商品價值。 比較例3 同樣洗練實施例1使用之襯衫，去除糊料或雜質。 本纸張反度適用中國國家標準（CNS)甲4规格（210 X 297公釐） -26 ~ (請先閲iMc面之注意事项再填寫本頁) i裝_ 訂· 經濟部中央標準局R工消费合作杜印製 9 οHzC CHz \ Φ / N / \ k ch3 ch3 Order · n polymer formed by monomer units of the following formula (trade name: Sharoll DC Shitolie, manufactured by First Industrial Pharmaceutical Co., Ltd.), and shellfish consumption of the Central Standardization Bureau of the Ministry of Economic Affairs Co-printed by the cooperative, etc. C Η 2 C Η Η—C Η 2 h2c ch2 \ θ / N / \ R i R 2 evening π Θ The copolymer of these quaternary ammonium salt polymers and other ethylene strip polymers-7- This paper is also printed with Chinese National Standard (CNS) A4 specifications (210 X 297 mm). A6 B6 Printed by the Central Standard of the Ministry of Economic Affairs, R, R, and Consumer Cooperatives 5. Description of the invention (6) Among these nitrogen cation compounds, In particular, polyamine-type compounds, dibenzyldiamide-type compounds, and polycationic quaternary ammonium salt-type polymers, and copolymers of quaternary ammonium salts and other vinyl monomers are included in the present invention Keep it separate. Commercial products containing xenon-cation compounds include liquids containing nitrogen-containing cationic compounds, such as aqueous solutions containing nitrogen-containing cationic compounds, and printing and dyeing pastes containing nitrogen-containing cationic compounds. Cationization treatment Cationization treatment can be carried out on some or all of the fiber products, for example, by immersing the fiber products in an aqueous solution of a nitrogen-containing cationic compound, or spraying such an aqueous solution in the form of a spray on the fiber cracking products for treatment. It can also be used for printing and dyeing pastes containing nitrogen cation compounds on cellulose products. Flavoring materials Flavors that can be used in the present invention include natural flavors and synthetic flavors that are insoluble or insoluble in water. These fragrances can be used in any combination, and supplements such as a retention agent that can prolong the life of the fragrance or an alteration agent for changing the fragrance can be added as needed. By combining one or more than two kinds of fragrances and supplements, natural floral aromas such as konjac, scallion, violet, rose, jasmine, carnation, lilac, hyacinth, lily, sedgeflower, jasmine, etc. can be obtained; The aroma of bananas, apples, pineapples, cherries, grapes and other fruits; poor fragrance; (please read the precautions on the back and then write this page) 丨 installation · order · -i clothing paper again "! + National standard ( CNS) Take! Specifications (210 X 297 gong) -8-A6 B6 Fifth, the description of the invention (7) and other imaginative or fancy fragrance. Examples of the above-mentioned natural fragrances are: dynamic fragrances such as musk, acne fragrance, beaver fragrance, longyan incense, etc .; sunsun, citronellol, geraniol, linalool, lemon-like olealdehyde, citronellal , Eugenol, sassafras olein, menthol and other plant flavors; and the following essential oils, such as fennel oil, camphor oil, rosin oil, citronella oil, camphor oil, cinnamone oil, jasmine essential oil, green Peppermint oil, cedar oil, geranium oil, T-shaped oil, tuberose oil, turpentine oil, neroli oil, peppermint oil, palm rose oil, momordica pine oil, rosemary oil, etc. The above-mentioned synthetic fragrances include, for example, geraniol, carvone, hydroxycitronellal, terpineol, hydrated terpene diol, 1-menthol, borneol, camphor, ionone, and methyl ionone. Terpene strip synthetic fragrance; and benzyl alcohol, / 3-phenylethanol, phenylacetaldehyde, cinnamaldehyde, α-pentylcinnamaldehyde, cyclamen aldehyde, anisaldehyde, anethole, / 3-benzyl alcohol methanol, Jasmine essence, ethyl vanillin, coumarol, isoamyl salicylate, methyl anthranilate, methyl methyl anthranilate, vanillin, methyl vanillin, rosphenone, acetate α- Phenyl propyl ester, fenvalerone, synthetic musk, chlorophyllin, jasmone, 7-undecalactone, and Versalide {1— [2— (3-ethyl ethyl 5,6,7,8—tetrahydro _5, _5, 8, 8-tetramethyl) a group] ethyl ketone} and other aromatic and cycloaliphatic synthetic spices. Examples of the retention agent include ethyl benzoate, ethyl phthalate, benzyl salicylate, jasmine essence, vinyl tridecanedioate, calamus oil, and decaoxahexadecanol. Examples of the above-mentioned aroma-altering agents include higher aliphatic aldehydes and isoeugenol. ----------------- γ ----- installed ------. 玎 ------ ^ (Please read the note $ item on the back before filling in Benbuy> The Central Ministry of Economic Affairs printed and burned paper for the β-Consumer Cooperative Cooperative Society and used it again in the Chinese Inheritance Ratio (CNS) A1 Regulation (210 X 297 mm) _ 9 _ Ministry of Economic Affairs Central Bureau of Standards W A6 B6 printed by the Industrial and Consumer Cooperatives V. Description of the invention (8) The method of removing the meat-packaging material To enclose at least spices in the microcapsules formed by the polymer compound, for example, the following method can be adopted. That is, the above method can be used Perfumes and supplements, as well as polymer compounds used as film-forming substances, and use surfactants, protective colloids, pH adjusters, electrolytes, etc. as required, according to well-known encapsulation methods, which can be dispersed in water The state of the strip dispersion is to obtain perfume-encapsulated microcapsules. The methods of encapsulation can use chemical methods such as interfacial polymerization, in-situ polymerization, liquid hardening coating, etc .; phase separation, coacervation, interface precipitation, etc. Chemical method; spray drying method, air suspension coating method, powder bed method, vacuum evaporation method and other mechanical methods Methods, etc. In addition, one or more of these methods can be used to repeat the second encapsulation process, which can become multi-layer microcapsules. The membrane material is reviewed and the strength of the microcapsules is appropriately adjusted so that it can be used relatively stably for a long period of time through the use of fiber products to generate friction, which can destroy the appropriate amount of microcapsules and emit a moderate fragrance is the most important. The particle size of the microcapsules is preferably 0.1 to lOOzzm. It is difficult to destroy the microcapsules and the usual usage of fiber products when the lwm is below, for example, it can hardly emit fragrance due to the action of wearing clothes on the other hand. ， If it is above 100 / zm, the microcapsules will be broken due to slight external force, and the fragrance will be exhausted in the process of manufacturing the finished product. Including perfume micro-10-(Please read the precautions on the back before filling this page ) — Installed. Ordered. Printed by the Ministry of Economic Affairs, Central Standards Bureau R Industrial and Consumer Cooperatives Α6 Β6 V. Description of the invention (9) The better particle size of the capsule is 1 ~ 50 // m. As long as it is within this range, the general It is easier to use fiber products Damaged microcapsules are more likely to emit a moderate fragrance, and the fragrance will not be broken by the capsules in the production process. The above film-forming substances are preferably polyvalent isocyanates and polyvalent amines that can form polyurea films, Polyamide and polyvalent amine that can form polyaldehyde amine film, polyvalent isocyanate and polyhydroxy compound that can form polycarbamate ethyl acetate film, polyaldehyde nitrogen and polyhydroxy compound that can form polyester film, --· Epoxy compounds and polyvalent amines that form a ring gas resin film, a trimeramine preform polymer that can form a trimer radon resin film, and a urea formalin prepolymer that can form a urea resin film , And ethyl cellulose, polystyrene and polyvinyl acetate, and anionic polymer compounds, amphoteric polymer compounds, etc. described later. In addition, the film withdrawn from the capsule is preferably a thermosetting compound having excellent heat resistance. Preferred users of the above surfactants and protective colloids include, for example, anionic surfactants, amphoteric surfactants, anionic polymer compounds, amphoteric polymer compounds and the like. In addition, these and nonionic surfactants can be used in combination. The above-mentioned pH regulator or electrolyte can be usually used by the user in the above-mentioned encapsulation method. In the present invention, a dispersion liquid containing the encapsulated perfume capsule obtained as described above may be used as it is, or a surfactant or a protective gelatin may be removed from the dispersion liquid within a range that can maintain the capsule dispersibility. In addition, it is also possible to dehydrate and dry the thoroughly dispersed liquid to make it into a powder form, add surfactants or protective colloids to be dispersed in the liquid if necessary after use. At this time (please read the precautions on the back and then fill out this page) 丨 installed. Ordered. This paper standard is universal Chinese National Standard Cui (CNS) A 4 present grid (210 X 297 g;) -11-54 54 Central Ministry of Economic Affairs Standardization Bureau S Industry and Consumer Cooperation Du Yin? * Α6 Β6 5. Description of the invention (10) If the dispersity of the microcapsules is very good, it is not necessary to add surfactants or protective colloids. If the polymer compound constituting the capsule removal membrane is anionic or amphoteric, it usually has sufficient dispersibility. The anionic surfactant may be, for example, an alkyl sulfate ester salt, a benzene sulfonic acid salt, an alkyl fruit sulfonic acid salt, an alkyl sulfur succinate salt, an alkyl diphenyl ether disulfonate, an alkyl phosphoric acid Salt, polyoxyethylene alkyl sulfate, poly gas ethylene alkyl allyl sulfate, poly gas ethylene alkyl ether sulfate, poly gas ethylene alkyl ether sulfate, poly gas ethylene polystyrene Phenyl ether sulfate, polyoxyethylene alkyl phosphate, etc. The above-mentioned anionic polymer compounds include, for example, polyacrylic acid, poly-α-hydroxyacrylic acid, methacrylic acid, and copolymers with other ethylene strip polymers, ethylene / maleic anhydride copolymers, butene / maleic anhydride copolymerization Substances, vinyl ether / maleic anhydride copolymers, anion-modified polyvinyl alcohol, acacia rubber, carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, starch derivatives, etc. The amphoteric polymer compound may be, for example, gelatin, casein, and the like. The above-mentioned nonionic surfactants include, for example, polyoxyethylene alkyl ethers, polygas ethylene alkyl allyl ethers and other poly gas ethylene derivatives, polygas ethylenepolyoxypropylene block copolymers, rowan fat esters 、 Polyethylene ethylene rowanol fatty acid ester, glycerin fatty acid ester, etc. In addition, the fragrance-encapsulated microcapsules can impart fragrance while imparting color to the fiber product to become an object colored by the coloring agent. When coloring the fragrance-encapsulated microcapsules, for example, a coloring agent may be mixed with a film-forming substance at the time of manufacture and colored. The above colorants can be used, for example, insoluble azo strips, & dye strips, long 4 s Zhang Youdu general application ® Lu Han (CNS) A 1 spot (210 X 297 gong) -12-(please read the back (Notes and fill in this page again) _Installation and Ordering-A6 B6 Printed by the Industry and Commerce Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (11) Various organic pigments such as test dye mordant pigments, acid dye mordant pigments; Inorganic pigments such as Qin Bai, Chrome Yellow, Cadmium Red, Vaporized Iron, Shuo Black, Ultramarine; Direct Dyes, Acid Pigments, Reactive Pigments, Rag Pigments, etc. Further, for example, fluorescent pigments, oil-soluble dyes, disperse dyes, solid-solution type fluorescent fluorescent pigments, and the like can also be used. Dispersed dispersion liquid The microcapsule dispersion liquid may be, for example, a dispersion liquid for dispersing perfume-encapsulated microcapsules and a printing and dyeing paste for dispersing perfume-encapsulated microcapsules. Adhesion of micro-capsules at the place of sticking to the codling can be carried out on some or all of the following maintenance products, with impregnated fiber products in the state of dispersing the water dispersion liquid containing the encapsulated fragrance and capsules, or it can be sprayed and sprayed. If the above-mentioned water-strip dispersion fiber products are processed, they can also be processed by printing and dyeing pastes containing dispersed microcapsules on the fiber products. Examples of work stalks for imparting nourishment When using the scenting method of the present invention to impart fragrance to fiber products, the following methods can be exemplified. First refine the above fiber products to remove pulp or impurities. Of course, as long as it is clean, it can also avoid refining. Secondly, put 5 to 50 times the weight of water for fiber products in a suitable bath for dipping (bath ratio 1: 5 to 1: 50), preferably 10 to ------------ ------ {----- 装 ------ booking ------ year-old {please read the notes on the back first and then write this page > Ρ's Zhang; general trapped National Standard Ping (CNS) A 4 specifications (2 1 × X 297 W%) -13-A6 B6 Printed by the Ministry of Economic Affairs, Central Standard Field, R Industry and Consumer Cooperatives 5. Description of invention (13 30 times the weight of water (bath ratio 1: 10 ~ 1: 30), adding nitrogen cation compound to the water before the treatment of the fiber product is 0.1 to 20% by weight, preferably about 0.3 to 5% by weight. To this is further added acetic acid, tartaric acid, oxalic acid , Malic acid and other acids, adjust the p Η value to be acidic, in order to increase the permeability of cationic compounds to fiber products, wetting agents such as urea, glycerin, ethylene glycol, polyethylene glycol, di (ethylene glycol), etc. may be added as needed Secondly, immerse the above-mentioned fiber product in the aqueous solution obtained above (an example of a liquid containing nitrogen cation compound), and keep it at a normal temperature of ~ 80 * C for about 5 ~ 30 minutes, which can effectively cationize the Dimensional products. Then rinse the fiber products thoroughly, wash away excess krypton cationic compounds or other additives, and then dehydrate. Secondly, in the fiber products containing the treated products, put the following dimensional products before treatment: 1: 5 ~ 1: 50, It is preferably 1: 1◦ ~ 1: 30 of water, and then added to the fiber product before treatment is 0. 1 ~ 50% by weight, preferably 1 ~ 25% by weight of the encapsulated perfume thoroughly encapsulated and dispersed This microencapsulated perfume capsule can be added as a dispersion liquid containing a complete capsule of perfume. When the dispersion liquid obtained above is processed at room temperature to about 9 01C (an example of microcapsule dispersion liquid) with a diameter of 5 to 3◦ minutes, The encapsulated fiber products can be completely inhaled into the encapsulated perfume microcapsules. When using the encapsulated perfume at a high concentration of 10 to 50% by weight, the treatment temperature is preferably 60 to 901C. With this treatment, the inner package Spices can be separated by chemical separation. Please read the precautions on the back before filling out this page. -Installation- Order · Λ This paper m々 度 用 用 中国 国家 #at (CNS) W 4 «埤 （211) X 297 公 f) -14-Central Ministry of Education Printed by the Bureau of Industry and Consumer Cooperatives A6 B6 V. Description of the invention (13) Sub-bonding and physical adsorption to bind to the above-mentioned fiber products, dehydration and drying to make the enveloping perfume removed from the capsule firmly and adhere to the hungry dimension Cracked products. If you want to make it more firmly adhered, it is best to heat treatment at a temperature of about 80 ~ 1 8 0 * 0 after drying for about 0.5 ~ 10 minutes. The fiber products so obtained have a large amount of pseudo adhesion It contains fragrance microcapsules, and will not damage the sense of fiber products. It has a soft texture and excellent washing fastness. Lesser enveloping method The preferred embodiment of the present scenting method is a process of applying adhesive treatment to the fiber product with an amount of binder that does not impair the texture and feel of the fiber product. The adhesion of the fibrous cracked product obtained by this bonding process to the reinforced fragrance-encapsulated microcapsules to the fibrous products can further improve the washing fastness. 3〜5 重量 ％。 The amount of the above-mentioned binding agent for the fiber product in terms of the solid content of the binder is usually about 0.1 ~ 10% by weight, preferably 0.3 ~ 5% by weight. Usable binders such as acrylic resins, methacrylic resins, vinyl acetate resins, polyurethane resins, polyester resins, styrene butadiene latexes, polyene resins, the above-mentioned anionic polymer compounds In the polyacrylic acid, methacrylic acid, or derivatives of these or copolymers of these with other vinyl-based polymers. In the present invention, acrylate resins and polyurethane resins among these are most preferred. Bonding treatment can be used for example to impregnate fiber products in water containing binder ———————————————————————— ---- Λ (Please read the precautions on the back and then fill in this page) This paper is used in China National Standard (CNS) A4 specifications (210 X 297 mm) -15-R Engineering, Central Bureau of Standards, Ministry of Economic Affairs Consumer Cooperative Yinli A6 B6 V. Description of the invention (14) It can be carried out in the state of liquid. It can also be sprayed with an aqueous solution containing binders to treat products. It can also be used to print and dye printing pastes containing binders to fiber products. Treatment. When the fragrance is imparted to the fiber product according to this embodiment, for example, the following method can be used .. Example 1 of flavoring after treating the fiber product with an aqueous solution containing a nitrogen cation compound (cationization treatment), by dipping in the product containing the above The treatment (adhesion treatment) in the dispersing liquid of the enveloping perfume containing capsules, so that the microcapsules of enveloping perfume can be adsorbed on the fissures of the fiber. Furthermore, the solid content of the binder of 0.1 to 10% by weight for the fibrous product is added to the liquid Binder, then at normal temperature to 90t: after 1 ~ 30 minutes of treatment (binder treatment), remove Dry it. _Numerous Examination Example 2 After treating the fibrous product with an aqueous solution containing a nitrogen cation compound (cationization treatment), the treatment (adhesion treatment) by immersing in the dispersion liquid containing the above-mentioned fragrance-encapsulated microcapsules was used After the fragrance-encapsulated microcapsules are adsorbed on the fiber product, they are dehydrated. Then, in the bath containing the fiber product, re-inject water with a bath ratio of 1: 5 ~ 1: 50, preferably about 1: 10 ~ 1: 30, Then add a binder with the solid content of 0.1 to 10% by weight of the fiber product at normal temperature to 9 Ot: after 5 to 30 minutes of treatment (binder treatment), dehydrate and dry it. (Please read first The notes on the back will be bought in the next copy) _installed-ordered · clothes and paper H changed to use the Chinese standard of the West; iMCNS) A 1 standard (21U X 297 public goods) * 16-Wong Consumer Cooperative Cooperative of the Central Bureau of Economics of the Ministry of Economic Affairs Printed A6 v _B6____ V. Description of the invention (15) Example 3 of aromatization After treatment with an aqueous solution containing a nitrogen cation compound (cationization treatment), it is immersed in the microcapsule containing the above-mentioned encapsulated fragrance and the fiber product is 0.1 to 10 The binder with the weight percentage of the solid content of the binder, at room temperature to 90t · Processing -5 to 30 minutes (and a binder adhesion treatment process), be dehydrated and dried. Fu Xie Fen Fen Example 4 Treating fiber products with an aqueous solution containing a nitrogen cationic compound and a binder with 0.1% to 10% of the solid content of the cracked fiber (replacement 1: cationization treatment and binder treatment ), Then immersed in the dispersion liquid containing the above-mentioned perfume-encapsulated microcapsules (the second process: adhesion treatment), thereby allowing the perfume-encapsulated microcapsules to be adsorbed on the fiber product. At room temperature to 90 t: dehydrate and dry after 1 to 30 minutes of treatment. In addition, in the first project, soda ash or hydrogen hydride may be added as needed to neutralize the nitrogen cation compounds. In addition, in the first project, instead of both the nitrogen cationic compound and the binder, a cationic binder belonging to the nitrogen cationic compound may be used in an amount that does not impair the texture and feel of the fiber product. Such cationic binders include, for example, the Voncoat SFC line (trade name: vinyl acetate or acrylic vinegar emulsion: manufactured by Dainippon Ink Chemical Industry Co., Ltd.) and the Yodosol AT line (trade name: acrylate emulsion: Zhongfang Manufactured by NSC), CGC (product name: acrylic strip emulsion: manufactured by Sumitomo Chemical Industry Co., Ltd.), Japanese Patent No. 62-1 87702 (please read the precautions on the back before filling in this page). Install. Order- This paper is based on China National Standards (CNS) A4 (21U X 297mm) -17-Manju Central Central Standard House R Industrial and Consumer Cooperative Society Inari A6 B6 V. Description of Invention (16) Cationic emulsion, cationic copolymer shown in Japanese Patent Laid-Open No. 62-1 3 1 003, cationic polymer shown in Japanese Patent Laid-Open No. 62-201914, cationic polymer shown in Japanese Patent Laid-Open No. 62-2632 Latex, etc. 1 ~ 4 above, the preferred endowment fragrance example, the binder can be pseudo-adsorbed in the fiber product about the same level as contained in the liquid, that is, for the fiber cracked product is 0. 1 ~ 10 reset% degree of tackifier solid The ingredients, after dehydration and drying, can be firmly adhered to the fiber product. As a result, the rubbing fastness or washing fastness can be further improved. At this time, if the solid content of the binder is 0.1% or less, the effect is insufficient, and when it is 10% by weight or more, the touch and texture of the fiber are often impaired. In the method for scenting of the present invention described above, the encapsulated fragrance can also be removed and colored in the microcapsule dispersion liquid in which the encapsulated fragrance is dispersed to contain the exemplified coloring agent or thermally reversible color material and optically reversible color. Colorants such as sexual materials, so that when they absorb the fragrance contained in the capsule, they can absorb these colorants at the same time in the fiber products. In this way, when scenting, fixed coloring or reversible color change due to temperature change or light irradiation can be achieved at the same time. Thermally reversible color materials include, for example, a three-component mixture of acid color-developing substance, acidic substance and solvent; a two-component mixture of acid color-developing substance and acidic substance; cholesteric liquid crystal; metal salt, etc., EP_A-◦ 480 1 62 materials shown. In addition, the photoreversible materials include, for example, azobenzene compounds, sulfur-cutting compounds, dithizone metal complexes, spiropyran compounds, spirooxabene and general-purpose medium-threshold (CNS ) A4 * See Ke (21 (JX 297 public: $) -18-< Please «Read the notes on the back and then fill out this page) 丨 Installation_ Order · The central standard of the Ministry of Economic Affairs is A6 printed by R Industry and Consumer Cooperative B6 V. Description of the invention (17) azine strip compound, methylene succinic anhydride ((fulgide strip compound, dihydropyrene strip compound, spiro I * fur strip compound, 1, 4 2H-oxazine, triphenylmethane strip Organic photochromic substances such as compounds, Violoeen strip compounds, and pyroprene strip compounds. Specifically, materials similar to those shown in EP_A- 04 80 1 62 can be used. In the present invention, spiropyran strip compounds and spirooxane compounds are particularly used. It is suitable to use oxazine compound, fulgide compound, and a pyran compound. In addition, it is also possible to color fiber products first, and then to apply the method of flavoring of the present invention as described above. Meat sentence. Example of manufacturing perfume-encapsulated microcapsules "Parts" means "parts by weight." Manufacturing Example 1 Put 30 parts of 10% (weight / weight) gelatin kept at 40¾ into 12 parts of Woody 4319 (synthetic fragrance brand name Kotobuki fragrance company split), Adjust the stirring speed to emulsify it to a particle size of about 10Wm. Then add 30 parts of 10% (weight / weight) Arabic rubber that is also kept at 401C to this mixture, and then wrap it for 1 ◦ minutes. Mix 128 parts of 40t: The water was added to the mixture, and then acetic acid was added dropwise to make the pH value 4 to 4.3. Then the mixture was cooled to 5¾, 1 part of 30% (w / w) formalin and a few drops of 10% (w / w) hydrogen were added Sodium hydroxide, adjust the pH value to 9. After that, it rises every minute (please read the precautions on the back and then fill out this page)-丨 installed. Ordered · The paper standard uses the Chinese National Standard (CNS) A ·! 21ϋ X 2S7 (commercial product) -19-W as A6 B6 V. Description of the invention (18) Increase the temperature at a high 1C to 50 * 0, keep this temperature for 1 hour, let it cool, and obtain about 200 parts of dispersed microencapsulated perfume capsules Dispersion liquid Production Example 2 3% (weight / weight) EMA3 1 (ethylene Maleic acid copolymer trade name, manufactured by Yu Shandu Co., Ltd. is added to 20 parts of LEMON 43 14 (synthetic trade name: KOTOBUKI Perfume Co., Ltd.) of 60 parts and 60 parts of cetyl alcohol, which are heated and mixed at 60 ¾. Adjust the stirring speed to emulsify it to a particle size of about 5 wm. In addition, 30 parts of 37% (weight / weight) formaldehyde was reacted in 6010, and 1 part of trimeric radonamine was used for 1 minute to obtain a melamine prepolymer. Drop it into the above emulsion. After dropping, the temperature of the warming solution was 8 ου, and the mixture was heated for 30 minutes, and 420 parts of the dispersion in which the fragrance-encapsulated microcapsules were dispersed were obtained. Production Example 3 Printed by the 8th Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy (Please read the precautions on the back before writing this page> Γ contains 300 copies of Demol N (trade name of anionic surfactant in 300 copies, Kao Corporation) In the aqueous solution), a mixed solution of 40 parts of DINP (plasticizer) and 30 parts of Sumijule N 75 (trade name of aliphatic polyisofluorate, manufactured by Sumitomo Byer Ureathan) maintained at 8〇υ was added dropwise, and the stirring was adjusted The speed can make the particle size of about 2wm. After about 15 minutes, raise the temperature to 95υ, heat and stir for 2 hours, and get about 400 parts of the dispersion liquid containing the perfumed microcapsules. This paper is also commonly used: ¾ Jia Yijia (CNS) Jiai Nige (21G X 2 Ruthenium 2¾ >-20-ο Printed by the Central Standards Bureau of the Ministry of Economic Affairs, R Industrial and Consumer Cooperatives οr; l A6 B6 V. Invention description (19) Manufacturing Example 4 in In 196 parts of 2% polyvinyl alcohol, 35 parts of Peppermint 4 2 3 4 (synthetic fragrance trade name, manufactured by Kotob-uki fragrance company) kept at 801C were dropped, and 5 5 parts of Crystol 3 5 2 (flowing stone pan product) Name, manufactured by .Esso Petroleum Company), 20 copies of Epikote 8 2 8 (trade name of ring gas resin, Oil Chemical Corporation) System) and 2 parts of F-ex blue base (trade name of Phthalocyanine, manufactured by Matsui Pigment Chemical Industry Co., Ltd.), and the mixing speed is adjusted so that the particle size is about 15 / im. Then, 12 parts of Epicure U (hardening) is dropped The brand name of the agent, Shell Epoxy Co., Ltd. (oily cracking), continued to heat and stir the reaction for 2 hours. About 320 parts of the dispersion liquid containing the encapsulated fragrance microcapsules colored in blue were obtained. [Effect of the Invention] The fragrance according to the present invention In the method, without damaging the texture and sense of the fiber product, the microcapsules containing the encapsulated fragrance can be firmly and abundantly adhered to the fiber product. After washing, the microcapsules containing the fragrance are rarely detached from the fiber cracked product. It also has no problem of shifting the fragrance. Moreover, the fiber product can also damage the microcapsules that are placed in a fixed position for a long period of time due to friction during use, and emit a moderate fragrance. Furthermore, when the fiber product is treated with a binder, it can be Without damaging the texture and feel of the fiber product, it strengthens the adhesion of the encapsulated perfume microcapsules to the fiber product. The fragrance effect of the fiber product is also the same as that of the non-applied binder, and can be maintained for a long time. The invented Yixiang Fiber Luo product can be used for a long time by friction during use (please pay attention to the precautions before filling out this page> _install · order · The paper content is applicable to China National Standard (CNS) A4 specifications (210 X 297 公 嫠 > -21-A6 B6 V. Description of the invention (20) and the amount of the contained fragrance in the capsule is relatively fixed and distributes the proper fragrance, and the fragrance is rarely detached by washing. There is no problem of fragrant fragrance, and it can retain the excellent texture and feel of fiber products. In addition, the binder treated by the binder without compromising the texture and feel of the fiber product can pseudo-strengthen the adhesion of the microcapsules containing the fragrance to the fiber product, and the effect of emitting fragrance is no different from that of the binder treatment. Can be maintained for a long time. The embodiments of the present invention will be described below. Of course, the present invention is not limited thereto. Example 1 A cotton shirt (120 parts of white cloth) was first washed to remove slurry or impurities. Next, add 2400 parts of water (bath ratio 1: 2 0) 2 parts, Sanf ix PAC-7 (trade name of quaternary ammonium salt type cationic polymer compound aqueous solution, manufactured by Sanyo Chemical Industry Co., Ltd.) and 10 in a 5 liter container Parts ethylene glycol. Immerse the washed cotton shirt in this aqueous solution and slowly raise the temperature to 70t: treat for 15 minutes. The Sampling Bureau of the Central Sample Bureau of the Economic Village printed and cracked (please fill in the first item before filling in this page) r Then rinse the shirt thoroughly with water to remove excess nitrogen cation compounds or other additives and then dehydrate it. Next, put the dehydrated shirt, 2400 parts of water, 10 parts of the perfumed microcapsule dispersion containing the obtained Example 1, 25 parts of Chromicolor aqualite ink fast blue AQ-2 7 (trade name of thermochromic pigment) , Manufactured by Matsui Pigment Chemical Industry Co., Ltd.), slowly raise the temperature of the liquid, and treat it at 80C for 15 minutes. As a result, the encapsulated perfume microcapsules are finished on the gold paper standard. ) -22 * «Recognized by the Ministry of Economy, Central Engineering, and Rong Consumer Cooperative Co., Ltd. A6 B6 V. Description of the invention (21) Adsorbed into the shirt. Then rinse the shirt thoroughly, dry naturally after dehydration, and dry it with a drum At 1 4 0 t: heat treatment for 1 minute. The shirt thus obtained is of good texture and feels good. When wearing this shirt, it can emit woody fragrance when holding it slowly, just like holding it slowly in the forest. In addition, as the body temperature rises, the blue shirt It turns to white. Example 2 In the same way as Example 1, 01111 * 〇1111〇〇1 (^ & < 111 & 1 〖16 £ & 3-t blue AQ-2 7 and inner color perfume microcapsules are adsorbed on Cotton shirt (white cotton 1 20 copies), rinse the shirt with water Dehydration operation. Then, add 2400 parts of water and 12 parts (solid content of about 3.6 parts) Matsuminsole MR-1 0 (trade name of acrylic acid vinegar strip resin emulsion, made by Matsui Pigment Chemical Industry Co., Ltd.) into the container containing the shirt , And then slowly increase the temperature, after 15 minutes of treatment at 701C, dehydrate and dry the shirt. The resulting shirt shows the same function as Example 1, the touch and texture are excellent and not inferior to Example 1, and can improve the washing resistance Example 3 25% of Photopia aqualite ink Purple AQR (photosensitive color changeable pigment trade name, manufactured by Matsui Pigment Chemical Industry Co., Ltd.). Except for Chromicolor aqualite fast blue AQ-2 7, all other treatments were the same as in Example 1. (Please fill in the first $ item and then buy to buy) t Dingben paper size is applicable to the national standard (CNS) A4 specifications (210 X 297 mm) -23-00 00 shellfish consumption of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the cooperative A6 B6 V. Description of the invention (22) The shirt obtained in this way can also emit a woody fragrance with only slight movements when worn, making the wearer feel like bathing in the forest and refreshing his spirit. The part of the outdoor where the sunlight is irradiated becomes dark purple, and the qualities of the shirt, such as touch, texture, and washing and irrigation resistance, are as excellent as in Example 1. Ben Shi Example 4 First wash the cotton lotus moving clothes (300 copies), Remove the slurry and impurities. Put 6,000 parts water, 2.7 parts Sa-nf ix 7 0 (trade name of cationic polymer compound, manufactured by Sanyang Chemical Co., Ltd.) and 15 parts B in a 1 liter container Glycol was soaked in the above lotus moving clothes in this solution. After treatment at 601C for 15 minutes, the lotus moving clothes were washed thoroughly and dehydrated. Next, put 600 parts of water in a 1 liter container containing the sportswear, and add 45 parts of the dispersion liquid of microcapsules containing perfume in Manufacturing Example 2 to disperse. Then warm up the solution slowly. After 15 minutes of treatment, fully rinse the cotton lotus moving clothes and dehydrate them. Then infuse 6000 parts of water into the 10 liter container containing the lotus moving clothes, and add 30 parts of 1 ^ £ ^ & 11? One-20 (trade name of polyurethane emulsion, manufactured by Dainippon Ink Chemical Industry Co., Ltd.), slowly raise the temperature of the liquid, and after 15 minutes of treatment at 70 ° C, dehydrate the cotton lotus, and then fully dry it by natural drying. When wearing this lotus jersey for light lotus movement, the microcapsules can be destroyed due to friction and the lemon-like scent can be relaxed. The feel, texture and washability of the lotus jersey are good. Example 5 (please first «face note $ item and then f this page)-Binding-Order _ This paper applies to China National Standard (CNS) A 4¾ grid (210 X 297 mm) -24 ~, 09, 09 Ministry of Economic Affairs A6 B6 printed by Engong Consumer Cooperative of ZTE Standards Bureau 5. Description of invention (23) Wash the shirt made of acrylic eye to remove slurry or impurities. Secondly, add 2400 parts of water (bath ratio 1:20) into a 5 liter container, 4 parts of SanfiXPAC-7 (trade name of quaternary ammonium salt type cationic ionomer aqueous solution, manufactured by Sanyo Chemical Co., Ltd.), 6 parts of 1 ^ 18- uminsoi.MR-C (trade name of acrylic stripe resin emulsion, manufactured by Matsui Pigment Chemical Industry Co., Ltd.), dipped in the mixed liquid of the shirt after washing, slowly raise the temperature of the liquid, and treat at 70TC for 15 minutes. Then rinse the shirt with water and dehydrate it. Next, add 2400 parts of water and 10 parts of the fragrance-encapsulated microcapsules obtained in Example 4 to a 5 liter container to impregnate the dehydrated shirt. Raise the temperature of the treatment solution slowly at 7 Ot: 15 minutes of treatment. As a result, this treatment changed from blue to colorless and transparent, and it was confirmed that it has been completely exhausted. Secondly, rinse the shirt thoroughly and dry it after dehydration. As described above, the shirt obtained has a good sense of texture and texture, and is blue in color. With the slight movement of the wearer, the fragrance of the lotus can be smelted. This function has not disappeared after repeated washing. Example 6 In a 5 liter volume, 2400 parts of water (bath ratio 1:20), 2 parts of SanfixPAC-7 (quaternary ammonium salt type cationic polymer compound aqueous solution trade name, manufactured by Sanyo Chemical Co., Ltd.) and 10 parts of B Diol. Use general printing and dyeing inks in advance, and use the polyester / cotton blended short coat (120 copies) of the online sales printing and dyeing rose garden case, and immerse it in the above water-soluble (please read the notes 45-¾ ^ on the back side). Binding · This paper uses the Standard of the Sleepy Family Standard (CNS) A 4 (210 X 297 mm) _ 25-ώ A6 B6 5. Description of the invention (24) In the liquid, slowly raise the temperature and process at 701C 15 Minutes. Rinse the clothes with water to remove excess nitrogen cation compounds or other additives and then dehydrate. Secondly, add 240 0. parts of water in a 5 liter container with dehydrated clothes, and 20 parts of Production Example 3 The dispersion of perfume microcapsules is included, and the temperature is slowly raised and treated for 15 minutes at 801 C. The texture and texture of the clothes obtained in this way are good, and the microcapsules can be destroyed by slight movements or rubbing while sitting on the sofa. , The fragrance of rose escapes. The functional pseudo-long-term repeated washing will not disappear. Comparative Example 1 Instead of the encapsulated fragrance withdrawing dispersion obtained in Manufacturing Example 1, emulsify 1 2 parts of Woody 4 3 with 1 88 parts of water containing surfactant 1 9 into 1 ◦ servings The chemical solution, except for the others, treated the shirt in the same way as in Example 1. The fragrance of the shirt was lost in the drying process, and the remaining slight fragrance disappeared completely after washing once, and the value of the product was lost. Comparative Example 2 Except Except for the nitrogen cation compound, the other treatment is the same as in Example 1. The resulting shirt does not completely absorb the encased fragrance microcapsules, so the fragrance is extremely slight, and after several rubs, it loses fragrance and loses its commercial value. Comparative Example 3 The same washing example 1. Use the shirt to remove the paste or impurities. This paper is negatively applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) -26 ~ (please read the precautions on the iMc before filling this page) i 装 _ Order · Du Printing Co., Ltd., R-Consumer Cooperation, Central Bureau of Standards, Ministry of Economic Affairs 9 ο
6 6 A B 五、發明説明（25) 趙而在5公升容器中加入2400份水，100份製 造例1所得内包香料微囊分散液，120份“^11!^113〇-1 MR- 10,以2次浸漬2次揑壓方式處理未施予氮陽離 子化處理之上述襯衫。 結果.藉此處理亦無法使内包香料徹囊完全吸附於襯衫 ，所得襯衫之香味甚微，而且感觸粗植，不具商品價值。 其次，對於實施例1 ,比較例1 ,比較例2及比較例 3所得製品，分別比較香味強度漂逸香味功能的持續性， 感觸及質地，以及耐洗濯性，結果示於表1。 表1中〇表示佳，X表示不佳。 .(請先閲尊面之注$項再本頁) 丨裝_6 6 AB V. Description of the invention (25) Zhao Er added 2400 parts of water in a 5 liter container, 100 parts of the dispersion of microcapsules containing encapsulated perfume obtained in Manufacturing Example 1, 120 parts of “^ 11! ^ 113〇-1 MR-10, Treat the above shirt without nitrogen cationization by immersing and squeezing twice. As a result, the treatment cannot fully absorb the contained perfume into the shirt, the fragrance of the resulting shirt is very slight, and it feels rough. No commercial value. Secondly, for the products obtained in Example 1, Comparative Example 1, Comparative Example 2 and Comparative Example 3, the scent strength, the scent function, the continuity of the scent function, the touch and the texture, and the wash resistance were compared, and the results are shown in the table. 1. In Table 1, ○ means good, X means bad. (Please read the note $ item on this page and then this page) 丨 装 _
〔表 1〕 經濟部中央揉準局w工消费合作杜印製 香味強 漂逸香味功 感觸及 耐洗濯性 度 能之持缠性 質地 實施例1 〇 〇 〇 〇 比較例1 X X 〇 X 比較例2 X X 〇 X 比較例3 X X X X 訂- 本紙ίδ·尺度遴用中國國家標準（CNS)甲4规格（210 X 297公釐） _ 27 -〔Table 1〕 The Central Kneading Bureau of the Ministry of Economic Affairs and Industry and Consumer Cooperation Co., Ltd. Printing the strong scent of the fragrance and the entanglement properties of washability and performance. Example 1 Comparative Example 1 XX 〇X Comparative Example 2 XX 〇X Comparative Example 3 XXXX Order-This paper is used for the size selection of China National Standard (CNS) A 4 (210 X 297 mm) _ 27-
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4245685A JPH0693570A (en) | 1992-07-31 | 1992-08-20 | Method for sticking perfume and perfume-releasing fiber product |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW209254B true TW209254B (en) | 1993-07-11 |
Family
ID=51356919
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW81108994A TW209254B (en) | 1992-08-20 | 1992-11-10 | Aromatic fabrics and method of making thereof |
Country Status (1)
| Country | Link |
|---|---|
| TW (1) | TW209254B (en) |
-
1992
- 1992-11-10 TW TW81108994A patent/TW209254B/en active
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