A6 B6 經濟部中央橾準局员工消费合作社印製 五、發明説明() 本發明係有關一棰金屬熔液改良劑,其能在鑄造用金 靥熔液.中,從去氧(除氣),去除夾雜物,使金靥组織健全 (使均勻),機械性質(抗拉強度,抗折強度及硬度等)諸點 上賦予經改善的性質。 Μ往,在冶金領域,尤指需一旦先將原料金屬成熔融 狀態之後或經加熱再加工之領域中,有一共同之問題點、 乃如氧、気或氫等氣體之混入,或不必要之灰雜物存在, 凝固後之金羼组織變不均勻等。 在縳造之領域中亦有金靥熔液中之氧等氣體之抽除( 一般稱去氧)或使凝固後之金屬组雜健全化尤為重要。以 往在鐵条金屬中,為去氧而加入容易舆氧等結合之碩*矽 ,錮及鋁等類之單體或化合物粉末,而為使金屬组镞能健 全,使用MFe-Si,Ca-Si等為主成分之接種劑。又,在銅 条金属中則加入磷化合物以去除氣體。 本發明的目的,在於提供一種金屬熔液改良劑,其可 一舉解除在鑄造領域中成為長年課題之如上述問題點者。 本發明人,爲逹成上述目的而多次精心硏究之结果, 獲悉如含有由硫化戡粉末與矽石灰粉末之混合物绖加熱處 理所成之處理混合物時*則可在上述鑄造領域中改善各種 性質,终至完成本發明。 (烽先閲讀背而.之注意.事項再填寫i 裝· 訂· -丨線· 衣纸張尺度適用中國困家櫺準(CNS)甲4規格(210 X 297公兌) -3 - 81.9.25,000 〇〇9λ4^ Α6 Β6 經濟部中央標準局β:工消費合作社印製 五、發明説明() 本發明之特擞,在於使用硫化鐵粉末與矽石灰粉末之 混合物經由加熱處理所得之處理混合物一點。雖如此處理 混合物係有效之理由尚不清楚,但單獨使用硫化鐵,單獨 使用矽石灰或僅單純地混合兩者均無上逑效果。 硫化鐵粉末可K硫化鐵(FeaS)也可爲硫化亞鐵(FeS) ,但依價格、購得之難易度斟度時宜採用硫化亞鐵較佳。 至於粉末顆粒·直徑Μ约100〜300網目,宜K約150〜200¾ 目者較佳。 矽石灰者亦稱為Wollastonite之一種鈣、鐵及錳之環 矽酸鹽。在本發明中,其顆粒直徑约為100〜300網目,宜 以約150〜200網目較佳。 硫化鐵粉末與矽石灰粉末之混合比例,應在9〜5 : 1 〜5重董比,如能以8〜6 : 2〜4則更好。在此範圍外時則 有所期的性質越不易得的趨向。加熱處理溫度通常在300 〜750=0如能在450〜650t較宜。太低或太高均可能使反 應越不完全。處理時視欲使用之對象與目的而異,通常多 為1〜10小時,而以3〜5小時較宜。 使用本發明之金饜熔掖改良劑時,會有優異的去氧效 果及健全金屬组織(均質化)效果,而夾雜物亦會減少。如 為金屬熔液改良劑,則除上述處理混合物之外,宜再加入 碳粉末、矽粉末、鋁粉末、氧化矽粉末、氧化鋁粉末、氧 化亞鐵粉末、鐵粉、錳鐵粉末、螢石、磺化矽粉砂 、氯牝納、銅粉、矽戡及氟化納等之一棰或二棰調 和之。所適用對象可為鑄鐵、鋁,鋁合金銅及銅合金等。 (誇先閲讀背面.之注意事項再填寫4 丨裝· 訂· .線. 本纸張尺度適用中國國家標準(CNS〉甲4規格(210 X 297公兌) 4 81.9.25.000 w A6 _B6_ 五、發明説明() (請先閲讀背面-之注意事項再填寫扣κ) 如對象金属爲鏵鐵時,舉一例,上述處理混合物15〜 45% (重量百分率,以下均同)、宜為20〜35%,碳粉7〜 12%,宜為9〜10%,矽粉0.5〜2.0% ,宜爲1.0〜1.5% ,鋁粉0.2〜0.7%,宜為0.4〜0.5%,氧化矽粉2.0〜4.0 %,宜爲2.5〜3.5%,K及氧化鋁粉0.5〜1.2% , )〜1·0%較佳等所成之組合物較適宜。而必要時再配)^ |氧彳b亞1¾粉爲增充_亦可°又’再舉他一例》S如上述 處理混合物15〜45%,如20〜40%更佳,鐵粉20〜40%, 如25〜35%更佳,錳鐵粉4〜10%,如5〜8%更佳,螢 石2〜8%,如4〜6%更佳,磺化矽5〜15% ,如為7 〜13%更佳,及氧化亞鐵5〜20%,如7〜15%更佳等而 成之组合物亦可宜。而在上述混合物以外之成份與上述處 理混合物之配合,尤可莠熔融鐵水之去氧,去除夾雜物Μ 及促使凝固後之金靥组绻之健全化之效果。 如對象金屬為錮或銅合金(例如青銅等)時,舉其一例 ,上述處理混合物15〜45%,如20〜40%更宜,與銅粉lfl 〜30%,如15〜25%更宜,氣化納15〜35%,如20〜30% 更宜,硼砂5〜15%,如7〜12%更宜,矽鐵1〜5 % * 經濟部中央揉準扃貝工消費合作社印製 如2〜4%更宜,錳鐵2〜8%,如,3〜6%更宜,及 氟化納%,如2〜4%更宜等類之组合物亦可。如 使用如此%>良劑時,可增進熔液之流動性,冒頭效果亦 獲得改菩*收縮時之凹孔減少,得改善機械性質、尤以伸 長率為著。 至於,使用對象金屬為鋁或鋁合金時,如其一例,係 本纸張尺度適用中國國家標準(CNS)甲4規格(210 X 297公兌) 5 81.9.25.000 A6 B6 經濟部中央標準局工消費合作社印製 五、發明説明() 上逑處理混合物15〜45%,宜或20〜40%,氣化納20%〜 45%,宜或25〜35%,砸砂1〜10重量%,宜或3〜7% ,氟化鈉·20〜40%及宜或25〜35%而所成組合物較宜。添 加如此改良劑時,可有優異除氣效果,減少鑄造缩孔,改 善機械性質。 作為金属熔液改良劑用時,對於100重量份之金靥熔 液宜為如所含上述處理混合物係20〜35%者則加0. 1〜0.7 重量份,或0.3〜0.5重量份更為佳。如添加過量,雖無害 但不經濟,而過度不足時則有得不到效果之趨向。 金屬熔液改良劑之添加方法可有多種的方法,例如把 改良劑封裝在銷製、銅製及鋁製之筒罐内投進熔液中爲一 簡單方式且可均勻混合。 所能蒱得之熔液,其氣體成份減少夾雜物亦少,並且 改善流動性。凝固後之鑄件金屬组織呈均勻而健全,而機 械性質擾異。 Μ下依據製造例及實施例說明本發明之金屬熔液改良 剤,惟本發明並不只限定於這些實施例。 製造例1 取硫化亞鐵粉末(顆粒度150〜200網目)80重量份與矽 石灰粉末(顆粒度150〜200網目)20重量份充分混合,於 400C加熱4小時而得處理粉末。 實施例1 混合Μ下各粉末,調製成鑲鐵用金屬熔液改良劑。 請先閲讀背面.之注意,事項再填寫>^>,) •裝· 訂_ •線· 中國國家標準(CNS)甲4规格(210 X 297公兌) -6 - 81.9.25,000 £〇3糾 A6 B6 五、發明説明( 製造例1之處理混合物 鐵粉(砂鐵) 錳鐵粉末 螢石粉末 磺化矽粉末 氧化亞鐵粉末 (重置份) 35 32 7 5 10 11 (請先閲讀背面.之注意·事項再填寫i 〇 經濟部中央標準局貝工消費合作社印製 100 為期能有一均匀混合物,粉末顆粒直徑均使在150〜 200網目。 所得改良劑,分取0.3公斤,充《密封在鏑製罐中。 將此裝有改良劑之罐投入鑄鐵(FC30、JISM下同)熔液100 公斤中,五分鐘後取樣,以紅外線吸收法測量溶液中殘留 氧含量,係為31ppm 。而原液中之殘留氧含量之測量值, 係 8 2 Ρ ρ π。 實施例2 將上述製造例1中所調裂成之改良劑0.3公斤充填密 封在網製罐中,投入鑄鐵(FC2 5)之熔液中,十分篾後採樣 製成試片。 Μ此試片之切斷表面使用3%硝酸酒精腐蝕後,藉金 屬顙撤鏡(400倍)觀察,瞭解鑄戡金屬组織之均勻度。 其结果如第1圖所示之素描圖。為便比較,就原液亦 做同樣觀察。其结果為第2圖所示。 良紙張尺度適用中國囿家標準(CNS)甲4规格(210 X 297公兌) 81.9.25,000 經濟部中央櫺準局β:工消費合作社印製 A6 B6 五、發明説明() 又,對各試片的機械性質(拉伸試驗,抗折試驗,硬 度,急冷)測試。其結果如表1所示。試驗方法如下。 (拉伸試驗) 依照JIS Z 2241為之。試片:直徑20公釐(mm)、溫度 :23X: 〇 (硬度) 依照JIS Z 2243爲之。試片:援用拉伸試驗所使用之 試料,在其中心位置测量。 表 1 機械性質. 元液 添加改良劑0.3kg 拉伸強度(kg/mna) 22.8 26.3 抗折試驗 最大荷重(kg) 1005 1025 彎曲(mm) 7.5 9.5 硬度 218 208 急冷 6.2 3.2 實施例3 為評估金属熔液之流動性,把鋳鐵(FC 15〉加熱熔融 至14 501C,投入網罐裝密封之在製造例1所調製成改良劑 0.3公斤。於投入五分鐘後,澆注於第3'圖所示之鋳模》 觀察熔液之到逹位置,有添加改良劑者可到達B酤,相對 ----------------.-----------裝------,订-------線 (請先閲讀背面•之注意•事項再填寫一.K) 一 本纸張尺度適用中國國家橒準(CNS)甲4規格(210 X 297公?〉 8 81.9.25,000 Α6 Β6 五、發明説明() 地未加改良劑者則僅能到達A點而已。 該鐵模,係具有一如第3圖所示之注入口 1於中心, 而其斷面為5am X 7mm之通路2呈螺旋狀延伸。 實施例4 混合下列各粉末調製成銅及銅合金用之金屬熔液改良 如製造例1之處理混合物 35 銅粉 20 氯化納 25 砸砂 9 矽鐵 3 mm 5 氟化鈉 3 100 粉末之顆粒度爲期有一均勻混合物,一律M150〜200 網目。 經濟部中央標準局R工消費合作社印5衣 (价先閲讀背面-之注意事項再填寫i >) 分取所得改良劑0.3公斤,装填於銅製罐子密封。准 此装有改良劑之銅罐投入100公斤(13001 )之青銅(BC6>瑢 液中。於30分鐘後鑄造,作成試片。 此一試片之抗拉強度為26kg/mma,伸長率32%。鋳造 時熔液之流動順暢*所得鑄件表面細緻而優越。 又,為能比較,同樣薄造Μ傳統磷条去氧劑除氣之試 本纸張尺度適用中國國家橒準(CNS)甲4规格(210 X 297公楚) 9 81.9.25,000 A6 B6 五、發明説明() 片,測量其抗拉強度及伸長率结果,分別是23kg/inma及25 %有待改善者。且,其薄件表面殘存有粗糙部分。 實施例5 混合下列各粉末調製鋁或鋁合金用金属熔液改良劑。 (請先閏讀背两之注意.事項再場寫一 >c 丨裝. 經濟部中央標準局R工消費合作社印製 100 爲得一均勻混合物粉末顆粒度一律M150〜200網目。 分取所得之改良劑0.3公斤,裝该在鋁罐中密封之。 將此有改良劑之鋁罐投入100公斤鋁熔液中。於30分鐘後 澆鑄*製作成試片。 將此試片(試片數3個)Μ真空熔融抽出法做質量分忻 (700^:><30分鐘)檢測其殘留氣體。再以顯撤鏡檢査其氣 孔數。將其结果示如表2。又,在表2中亦一併列示未加 改良劑之原液结果。 訂. .線. (重量份) 如製造例1之混合物 35 氯化納 33 硼砂 5 氟化鈉 27 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公兌) - 10 - 81.9.25.000 2〇9设 • Α6 Β6 五、發明説明() 表 2 · 殘留氣體(ppm) 氣孔 Ha CH« Na CO C0a 合計 數量 原液 20.7 0.295 0.025 0.663 0.055 21.7 多 本發明 3.42 0.085 0.005 0.103 0.002 3.62 少 原液 18.3 0.301 0.000 0.472 0.003 19.1 多 本發明 7.01 0.149 0.000 0.274 0.004 7.44 少 原液 19.1 0.303 0.000 0.738 0.071 20.2 多 本發明 5.73 0.129 0.000 0.180 0.018 6.06 中 (請先閲讀背面•之注意事項再塡窝私λ) -裝· 訂- 依據本發明之冶金用處理混合物,可提供一種可Μ去 氧,除去夾雜物及使金屬組雜健全,更而能改菩機械性質 ,而可提供優良铸件。 圃式:> 簡蜇說明 第1圖係示在實施例2所製作之鑄件金屬組鍇顯撤鏡 照片之素描圖。 第2圖為實施例2所作成原液得來之比較用鑄件金屬 组織顯撤鏡照片之素描圖。 第3圖為實施例3中使用之鑄模槪略斷面圖。 '線· 經濟部中央標準局R工消費合作社印製 本纸張尺度適用中國國家標準(CNS)甲4規格(210 X 297公踅) 11 81.9.25,000A6 B6 Printed by the Employees ’Consumer Cooperative of the Central Department of Economic Affairs of the Ministry of Economic Affairs 5. Description of the invention () This invention relates to a batch of metal melt improver, which can be deoxidized (degassed) in the gold melt for casting. , Remove the inclusions, make the gold lute structure sound (even), mechanical properties (tensile strength, flexural strength and hardness, etc.) to give improved properties. In the metallurgical field, especially in the field where the raw metal needs to be melted or heated and then processed, there is a common problem, that is, the mixing of gases such as oxygen, deuterium, or hydrogen, or unnecessary The gray debris exists, and the golden tissue becomes non-uniform after solidification. In the field of binding, there is also the extraction of oxygen and other gases (generally referred to as deoxygenation) from the gold tantalum melt or the consolidation of the solidified metal group. In the past, iron ore metal was added with a monomer or compound powder that is easy to combine with oxygen and other monomers or compounds for deoxidation. In order to make the metal group sound, MFe-Si, Ca- The inoculant of Si and other main components. In addition, phosphorus compounds are added to the copper strip metal to remove the gas. An object of the present invention is to provide a metal melt improver that can solve the problems mentioned above, which have been a long-term problem in the casting field. The present inventors have conducted many studies to achieve the above-mentioned objectives, and learned that if they contain a treatment mixture made of a mixture of sulfide powder and silica-lime powder, they can be improved in the above-mentioned casting field. The nature of the invention is completed. (Feng first read the notes of the back. Matters need to be filled in. I install · order ·-丨 line · clothing paper standards are applicable to China's poor home standard (CNS) A 4 specifications (210 X 297 public exchange) -3-81.9. 25,000 〇〇9λ4 ^ Α6 Β6 Ministry of Economic Affairs Central Standards Bureau β: Printed by the Industrial and Consumer Cooperatives V. Description of the invention () The special feature of the present invention is to use a mixture of iron sulfide powder and silica lime powder through heat treatment Although the reason why the treatment of the mixture is effective is unclear, the use of iron sulfide alone, silica lime alone, or simply mixing the two has no effect. The iron sulfide powder can be iron sulfide (FeaS) or sulfide. Ferrous iron (FeS), but it is better to use ferrous sulfide according to the price and ease of purchase. As for powder particles, the diameter M is about 100 ~ 300 mesh, preferably K is about 150 ~ 200¾ mesh. Silica lime It is also known as Wollastonite, a cyclic silicate of calcium, iron and manganese. In the present invention, the particle diameter is about 100 ~ 300 mesh, preferably about 150 ~ 200 mesh. Iron sulfide powder and silica lime powder The mixing ratio should be within 9 ~ 5: 1 ~ 5 weight ratio, if it can be 8 ~ 6: 2 ~ 4, it is better. Outside this range, it is more difficult to obtain certain properties. The heat treatment temperature is usually 300 ~ 750 = 0 If it can be 450 ~ 650t, it is better. Too low or too high may make the reaction incomplete. The treatment will vary depending on the object and purpose to be used, usually 1 ~ 10 hours, and 3 ~ 5 hours. It is advisable to use the inventive golden nugget improver, which will have excellent deoxidizing effect and improve the metal structure (homogenization) effect, and the inclusions will also be reduced. If it is a metal melt improver, except the above In addition to the treatment mixture, it is advisable to add carbon powder, silicon powder, aluminum powder, silicon oxide powder, aluminum oxide powder, ferrous oxide powder, iron powder, ferromanganese powder, fluorite, sulfonated silica powder sand, chlorpyrene , Copper powder, silica gel, sodium fluoride, etc., one or two of them are reconciled. The applicable objects can be cast iron, aluminum, aluminum alloy copper and copper alloy, etc. (Kua first read the back. Note before filling in 4 丨Binding · Order ·. Line. This paper scale is applicable to the Chinese National Standard (CNS> A 4 specifications (210 X 297 conversion) 4 81.9.25.000 w A6 _B6_ V. Description of invention () (please read the precautions on the back side-then fill in the deduction κ) If the target metal is tungsten iron, for example, the above treatment mixture is 15 ~ 45% (weight percent, below Same)), preferably 20 ~ 35%, carbon powder 7 ~ 12%, preferably 9 ~ 10%, silicon powder 0.5 ~ 2.0%, preferably 1.0 ~ 1.5%, aluminum powder 0.2 ~ 0.7%, preferably 0.4 ~ 0.5%, silica powder 2.0 ~ 4.0%, preferably 2.5 ~ 3.5%, K and alumina powder 0.5 ~ 1.2%,) ~ 1 · 0%, etc., are suitable. (If necessary, re-dispensed) ^ | Oxygen Bah 1¾ powder for augmentation _ can ° ° 'to give him another example》 S as the above treatment mixture 15 ~ 45%, such as 20 ~ 40% better, iron powder 20 ~ 40%, such as 25 to 35% is better, ferromanganese powder 4 to 10%, such as 5 to 8% is better, fluorite 2 to 8%, such as 4 to 6% is better, sulfonated silicon 5 to 15%, A composition of 7 to 13% is more preferable, and ferrous oxide is 5 to 20%, for example, 7 to 15% is better. The combination of the components other than the above-mentioned mixture and the above-mentioned treatment mixture can especially remove oxygen from the molten molten iron, remove the inclusions M, and promote the soundness of the solidified gold scorpion group. If the target metal is a copper or copper alloy (such as bronze, etc.), for example, the above treatment mixture is 15 ~ 45%, such as 20 ~ 40% is more suitable, and copper powder lfl ~ 30%, such as 15 ~ 25% is more suitable , Gasification sodium 15 ~ 35%, such as 20 ~ 30% is more suitable, borax 5 ~ 15%, such as 7 ~ 12% is more suitable, ferrosilicon 1 ~ 5% * Printed by the Central Ministry of Economic Affairs of the Ministry of Economics and Agriculture Cooperative Print Compositions such as 2 to 4% are more suitable, ferromanganese 2 to 8%, such as 3 to 6%, and sodium fluoride%, such as 2 to 4% are more suitable. If such a%> good agent is used, the fluidity of the melt can be improved, and the heading effect can also be improved. The concave holes during shrinkage can be reduced, which can improve the mechanical properties, especially the elongation rate. As for the use of aluminum or aluminum alloys, as an example, the paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 public exchange rate) 5 81.9.25.000 A6 B6 Ministry of Economic Affairs Printed by the cooperative. 5. Description of the invention () The upper treatment mixture is 15 ~ 45%, preferably or 20 ~ 40%, the gasification sodium is 20% ~ 45%, preferably or 25 ~ 35%, and the sand is 1 ~ 10% by weight. Or 3 ~ 7%, sodium fluoride · 20 ~ 40% and preferably or 25 ~ 35% and the composition is more suitable. When adding such modifier, it can have excellent degassing effect, reduce casting shrinkage cavity and improve mechanical properties. When used as a metal melt improver, for 100 parts by weight of gold-tallow melt, it is preferable to add 0.1 to 0.7 parts by weight, or 0.3 to 0.5 parts by weight, if it contains 20 to 35% of the above treatment mixture. good. If it is added excessively, it is harmless but not economical, and if it is excessively insufficient, it tends not to be effective. There are various methods for adding the metal melt modifier. For example, it is a simple way to encapsulate the modifier in pins, copper and aluminum cans and put it into the melt, and it can be mixed uniformly. The available melt has less gas content, less inclusions, and improved fluidity. After solidification, the metal structure of the casting is uniform and sound, but the mechanical properties are disturbed. The following describes the improvement of the molten metal of the present invention based on manufacturing examples and examples, but the present invention is not limited to these examples. Production Example 1 80 parts by weight of ferrous sulfide powder (granularity of 150 to 200 mesh) and 20 parts by weight of silica lime powder (granularity of 150 to 200 mesh) were thoroughly mixed, and heated at 400C for 4 hours to obtain a treated powder. Example 1 Each powder under M was mixed to prepare a molten metal modifier for iron inlays. Please read the notes on the back first, and then fill in the items > ^ >,) • Binding · Order _ • Line · China National Standard (CNS) A 4 specifications (210 X 297 public exchange rate) -6-81.9.25,000 £. 3 Correction A6 B6 V. Description of the invention (Manufacturing Example 1 treatment mixture iron powder (sand iron) Ferromanganese powder fluorite powder sulfonated silicon powder ferrous oxide powder (reset) 35 32 7 5 10 11 (please read first Note on the back. Please fill in i 〇printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 100 for a uniform mixture with a powder particle diameter of 150 to 200 mesh. The obtained improver is divided into 0.3 kg and charged " Sealed in dysprosium canister. Put this canister with modifier into 100 kg of molten iron (FC30, the same below JISM), take samples after five minutes, and measure the residual oxygen content in the solution by infrared absorption method, which is 31 ppm. The measured value of the residual oxygen content in the stock solution is 8 2 ρ ρ π. Example 2 The modifier 0.3 kg split into the above-mentioned manufacturing example 1 was filled and sealed in a net-made tank, and cast iron (FC2 5) In the melt, it was sampled very much to make a test piece. After the cut surface of the test piece was corroded with 3% nitric acid alcohol, the metal mirror was used to remove the mirror (400 times) to observe the uniformity of the cast metal structure. The results are shown in the sketch shown in Figure 1. For comparison , The same observation is made on the stock solution. The result is shown in Figure 2. The good paper size is applicable to the Chinese Standard (CNS) A 4 specification (210 X 297 public exchange rate) 81.9.25,000 Central Ministry of Economic Affairs β: Work Printed by the consumer cooperative A6 B6 V. Description of the invention () In addition, the mechanical properties (tensile test, bending test, hardness, quenching) of each test piece are tested. The results are shown in Table 1. The test methods are as follows. Tensile test) according to JIS Z 2241. Test piece: diameter 20 mm (mm), temperature: 23X: 0 (hardness) according to JIS Z 2243. Test piece: the test material used in the tensile test is used, and Center position measurement. Table 1 Mechanical properties. Element liquid added modifier 0.3kg Tensile strength (kg / mna) 22.8 26.3 Flexural test maximum load (kg) 1005 1025 Bending (mm) 7.5 9.5 Hardness 218 208 Quick cooling 6.2 3.2 Examples 3 To evaluate the fluidity of the molten metal, Melt the iron (FC 15> to 14 501C by heating, put it into a net pot and seal it, and prepare 0.3 kg of improver prepared in Manufacturing Example 1. After five minutes of pouring, pour it into the die shown in Figure 3 '. Observe When the melt reaches the position, if you add the modifier, you can reach the B-bit, relatively ----------------.----------- install --- ---, order ------- line (please read the back • note • matters and fill in one. K) A paper size is applicable to China National Standard (CNS) A 4 specifications (210 X 297 ? > 8 81.9.25,000 Α6 Β6 V. Description of the invention () Those who did not add modifiers can only reach point A. The iron mold has an injection port 1 as shown in Figure 3 at the center, and a passage 2 whose cross section is 5am X 7mm extends spirally. Example 4 Mix the following powders to prepare a molten metal for copper and copper alloys. Improve the treatment mixture as in Manufacturing Example 35. Copper powder 20 Sodium chloride 25 Sanding 9 Ferrosilicon 3 mm 5 Sodium fluoride 3 100 Powder particles There is a homogeneous mixture at a time, all M150 ~ 200 mesh. Printed 5 garments of R Industry and Consumer Cooperatives, Central Bureau of Standards, Ministry of Economic Affairs (price first read the back-notes and then fill in i >) Divided 0.3 kg of the resulting modifier, filled and sealed in copper cans. The copper pot containing the modifier is put into 100 kg (13001) of bronze (BC6) liquid. Cast after 30 minutes to make a test piece. The tensile strength of this test piece is 26 kg / mma and the elongation is 32 %. The flow of the melt is smooth during manufacture * The surface of the resulting casting is fine and superior. Also, for comparison, the test paper of the same thinner traditional phosphor strip deaerator degassing paper size is applicable to China National Standard (CNS) A 4 Specifications (210 X 297 Gongchu) 9 81.9.25,000 A6 B6 5. Description of the invention () piece, the results of measuring its tensile strength and elongation are 23kg / inma and 25% of those to be improved. And, its thin parts Rough parts remain on the surface. Example 5 Mix the following powders to prepare a metal melt modifier for aluminum or aluminum alloys. (Please read the notes on both sides first. Note the matter and write one again> c 丨 Installed. Central Standard of the Ministry of Economic Affairs Printed by Bureau R Industry and Consumer Cooperatives 100 to obtain a uniform mixture of powders with a uniform particle size of M150 ~ 200. Divide 0.3 kg of the resulting modifier and seal it in an aluminum can. Put this aluminum can with modifier into 100 Kg aluminum melt. Cast after 30 minutes * made The test piece (three test pieces) M vacuum fusion extraction method for mass fraction Xin (700 ^: > < 30 minutes) to detect its residual gas. Then with the removal of the mirror to check the number of pores. The results are shown in Table 2. In addition, the results of the stock solution without the modifier are also listed in Table 2. Order ... Line. (Parts by weight) As in the mixture of Production Example 1 35 Sodium chloride 33 Borax 5 Sodium fluoride 27 This paper scale is applicable to the Chinese National Standard (CNS) A4 specifications (210 X 297 conversion)-10-81.9.25.000 2〇9 Design • Α6 Β6 V. Description of invention () Table 2 · Residual gas (ppm) Pore Ha CH «Total amount of Na CO C0a stock solution 20.7 0.295 0.025 0.663 0.055 21.7 More invention 3.42 0.085 0.005 0.103 0.002 3.62 Less stock 18.3 0.301 0.000 0.472 0.003 19.1 More invention 7.01 0.149 0.000 0.274 0.004 7.44 Less stock 19.1 0.303 0.000 0.738 0.071 20.2 More invention 5.73 0.129 0.000 0.180 0.018 6.06 (please read the notes on the back first and then the private λ)-Binding · Ordering-According to the metallurgical treatment mixture of the present invention, it can provide a kind of deoxygenation to remove inclusion It can make the metal group complex and sound, and can improve the mechanical properties of the bodhisattva, and can provide excellent castings. Garden type: > Brief description of sting The first figure is a sketch of a photo of the cast metal set of the cast metal set produced in Example 2. Fig. 2 is a sketch drawing of a photograph showing the removal of the mirror of the metal structure of the cast metal obtained in Example 2 for comparison. FIG. 3 is a schematic cross-sectional view of the mold used in Example 3. FIG. 'Line · Printed by R Industry and Consumer Cooperatives, Central Bureau of Standards, Ministry of Economic Affairs This paper scale is applicable to the Chinese National Standard (CNS) Grade 4 (210 X 297 public) 11 81.9.25,000