TW202413035A - Manufacturing method of polarizing plate with phase difference layer - Google Patents

Manufacturing method of polarizing plate with phase difference layer Download PDF

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TW202413035A
TW202413035A TW112114631A TW112114631A TW202413035A TW 202413035 A TW202413035 A TW 202413035A TW 112114631 A TW112114631 A TW 112114631A TW 112114631 A TW112114631 A TW 112114631A TW 202413035 A TW202413035 A TW 202413035A
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phase difference
polarizing plate
difference layer
slow axis
manufacturing
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田中卓哉
麻野井祥明
伊崎章典
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日商日東電工股份有限公司
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本發明提供一種可有效率地製造附相位差層之偏光板之方法,該附相位差層之偏光板其偏光件之吸收軸方向及相位差層之慢軸方向經極精密地控制。本發明實施形態之附相位差層之偏光板之製造方法,包含以下步驟:將在長條方向上具有慢軸之相位差薄膜之胚料捲材,一邊校正胚料捲材之寬度方向上慢軸相對於長條方向之偏移一邊沖裁成預定尺寸,獲得在長邊方向上具有慢軸之單片相位差層中間體;將在長條方向上具有吸收軸之偏光板之胚料捲材沖裁成與相位差層中間體相同尺寸,獲得在相對於長邊方向呈45°方向上具有吸收軸之單片偏光板中間體;以使相位差層中間體與偏光板中間體之外緣一致之方式將其等貼合,獲得偏光板之吸收軸與相位差層之慢軸所成角度為45°的附相位差層之偏光板中間體;以及,沖裁附相位差層之偏光板中間體,獲得在長邊方向上具有吸收軸之預定尺寸之附相位差層之偏光板片。The present invention provides a method for efficiently manufacturing a polarizing plate with a phase difference layer, wherein the absorption axis direction of the polarizer and the slow axis direction of the phase difference layer of the polarizing plate with a phase difference layer are extremely precisely controlled. The manufacturing method of the polarizing plate with a phase difference layer of the embodiment of the present invention comprises the following steps: a blank roll of a phase difference film having a slow axis in the long direction is punched into a predetermined size while correcting the offset of the slow axis in the width direction of the blank roll relative to the long direction, thereby obtaining a single-piece phase difference layer intermediate having a slow axis in the long direction; a blank roll of a polarizing plate having an absorption axis in the long direction is punched into the same size as the phase difference layer intermediate, A single polarizing plate intermediate having an absorption axis at 45° relative to the long side direction is obtained; a phase difference layer intermediate is bonded to a polarizing plate intermediate in such a way that the outer edges thereof are aligned, thereby obtaining a polarizing plate intermediate with a phase difference layer, wherein the angle between the absorption axis of the polarizing plate and the slow axis of the phase difference layer is 45°; and, the polarizing plate intermediate with a phase difference layer is punched to obtain a polarizing plate sheet with a phase difference layer of a predetermined size having an absorption axis in the long side direction.

Description

附相位差層之偏光板之製造方法Manufacturing method of polarizing plate with phase difference layer

本發明係關於一種附相位差層之偏光板之製造方法。The present invention relates to a method for manufacturing a polarizing plate with a phase difference layer.

以液晶顯示裝置及電致發光(EL)顯示裝置(例如有機EL顯示裝置、無機EL顯示裝置)為代表之影像顯示裝置急速普及。就影像顯示裝置而言,為了實現影像顯示、及/或提高該影像顯示之性能,廣泛使用包含偏光板與相位差薄膜(相位差層)之附相位差層之偏光板。又,近年來,正在開發影像顯示裝置之新用途。所述用途之一例可舉虛擬實境(VR)護目鏡。將附相位差層之偏光板應用於VR護目鏡時,其尺寸顯著地小於習知用途。結果,於習知用途中未成為問題之偏光件之吸收軸及/或相位差層之慢軸之軸偏移卻成為實質性問題。 先前技術文獻 專利文獻 Image display devices represented by liquid crystal display devices and electroluminescent (EL) display devices (such as organic EL display devices and inorganic EL display devices) are rapidly becoming popular. In order to realize image display and/or improve the performance of the image display, polarizing plates with phase difference layers, which include polarizing plates and phase difference films (phase difference layers), are widely used in image display devices. In addition, in recent years, new uses of image display devices are being developed. One example of such uses is virtual reality (VR) goggles. When polarizing plates with phase difference layers are applied to VR goggles, their size is significantly smaller than that of conventional uses. As a result, the axial offset of the absorption axis of the polarizer and/or the slow axis of the phase difference layer, which is not a problem in conventional uses, becomes a substantial problem. Prior art literature Patent literature

專利文獻1:日本專利特開2013-182162號公報Patent document 1: Japanese Patent Publication No. 2013-182162

發明欲解決之課題 本發明是為了解決上述課題而作成者,其主要目的在於提供一種可有效率地製造附相位差層之偏光板之方法,該附相位差層之偏光板其偏光件之吸收軸方向及相位差層之慢軸方向經極精密地控制。 Problem to be solved by the invention This invention is made to solve the above-mentioned problem. Its main purpose is to provide a method for efficiently manufacturing a polarizing plate with a phase difference layer, in which the absorption axis direction of the polarizer and the slow axis direction of the phase difference layer are extremely precisely controlled.

用以解決課題之手段 本發明實施形態之附相位差層之偏光板之製造方法,包含以下步驟:將在長條方向上具有慢軸之相位差薄膜之胚料捲材(original roll),一邊校正該胚料捲材之寬度方向上該慢軸相對於長條方向之偏移一邊沖裁成預定尺寸,獲得在長邊方向上具有慢軸之單片相位差層中間體;將在長條方向上具有吸收軸之偏光板之胚料捲材沖裁成與該相位差層中間體相同尺寸,獲得在相對於長邊方向呈45°方向上具有吸收軸之單片偏光板中間體;以使該相位差層中間體與該偏光板中間體之外緣一致之方式將其等貼合,獲得偏光板之吸收軸與相位差層之慢軸所成角度為45°的附相位差層之偏光板中間體;以及,沖裁該附相位差層之偏光板中間體,獲得在長邊方向上具有吸收軸之預定尺寸之附相位差層之偏光板片。 在一實施形態中,上述製造方法從上述相位差薄膜之胚料捲材在寬度方向上獲得3片~16片之上述相位差層中間體。 在一實施形態中,上述相位差層中間體及上述偏光板中間體為短邊75mm~310mm之矩形。 在一實施形態中,上述附相位差層之偏光板片為長邊10mm~70mm及短邊10mm~70mm之矩形。 Means for solving the problem The manufacturing method of the polarizing plate with phase difference layer in the embodiment of the present invention comprises the following steps: a blank roll of phase difference film having a slow axis in the longitudinal direction is punched into a predetermined size while correcting the deviation of the slow axis in the width direction of the blank roll relative to the longitudinal direction, thereby obtaining a single phase difference layer intermediate having a slow axis in the longitudinal direction; a blank roll of polarizing plate having an absorption axis in the longitudinal direction is punched into the same size as the phase difference layer intermediate, thereby obtaining a single phase difference layer intermediate having an absorption axis in a direction at 45° relative to the longitudinal direction. a polarizing plate intermediate; laminating the phase difference layer intermediate and the polarizing plate intermediate in such a way that the outer edges thereof are aligned, thereby obtaining a polarizing plate intermediate with a phase difference layer, wherein the angle between the absorption axis of the polarizing plate and the slow axis of the phase difference layer is 45°; and punching the polarizing plate intermediate with a phase difference layer, thereby obtaining a polarizing plate sheet with a phase difference layer having a predetermined size of absorption axis in the long side direction. In one embodiment, the manufacturing method obtains 3 to 16 phase difference layer intermediates in the width direction from the blank roll of the phase difference film. In one embodiment, the phase difference layer intermediate and the polarizing plate intermediate are rectangular with a short side of 75 mm to 310 mm. In one embodiment, the polarizing plate with phase difference layer is a rectangle with a long side of 10mm~70mm and a short side of 10mm~70mm.

發明效果 根據本發明實施形態,可實現可有效率地製造附相位差層之偏光板之方法,該附相位差層之偏光板其偏光件之吸收軸方向及相位差層之慢軸方向經極精密地控制。 Effect of the invention According to the implementation form of the present invention, a method for efficiently manufacturing a polarizing plate with a phase difference layer can be realized, wherein the absorption axis direction of the polarizer and the slow axis direction of the phase difference layer of the polarizing plate with a phase difference layer are extremely precisely controlled.

以下,參照圖式來說明本發明實施形態,惟本發明不受該等實施形態限定。又,圖式均為示意性表示,並非正確地描繪實際狀態之圖。Hereinafter, the embodiments of the present invention will be described with reference to the drawings, but the present invention is not limited to the embodiments. In addition, the drawings are schematic representations and do not accurately depict actual conditions.

A.附相位差層之偏光板之製造方法的概略 本發明實施形態之附相位差層之偏光板之製造方法,包含以下步驟:將在長條方向上具有慢軸之相位差薄膜之胚料捲材,一邊校正該胚料捲材之寬度方向上該慢軸相對於長條方向之偏移一邊沖裁成預定尺寸,獲得在長邊方向上具有慢軸之單片相位差層中間體(方便起見,稱為相位差層中間體製作步驟);將在長條方向上具有吸收軸之偏光板之胚料捲材沖裁成與該相位差層中間體相同尺寸,獲得在相對於長邊方向呈45°方向上具有吸收軸之單片偏光板中間體(方便起見,稱為偏光板中間體製作步驟);以使該相位差層中間體與該偏光板中間體之外緣一致之方式將其等貼合,獲得偏光板之吸收軸與相位差層之慢軸所成角度為45°的附相位差層之偏光板中間體(方便起見,稱為附相位差層之偏光板中間體製作步驟);以及,沖裁該附相位差層之偏光板中間體,獲得在長邊方向上具有吸收軸之預定尺寸之附相位差層之偏光板片(方便起見,稱為最終步驟)。以下,具體說明各步驟。另外,本說明書中「偏光板之吸收軸」之記載意指偏光板中所含之偏光件之吸收軸。 A. Overview of the manufacturing method of the polarizing plate with phase difference layer The manufacturing method of the polarizing plate with phase difference layer of the embodiment of the present invention comprises the following steps: a blank roll of a phase difference film having a slow axis in the longitudinal direction is punched into a predetermined size while correcting the deviation of the slow axis in the width direction of the blank roll relative to the longitudinal direction to obtain a single-piece phase difference layer intermediate having a slow axis in the longitudinal direction (for convenience, referred to as the phase difference layer intermediate manufacturing step); a blank roll of a polarizing plate having an absorption axis in the longitudinal direction is punched into the same size as the phase difference layer intermediate to obtain a single-piece phase difference layer intermediate having a slow axis in the longitudinal direction at a 45° angle relative to the longitudinal direction. A single polarizing plate intermediate with an absorption axis (for convenience, referred to as a polarizing plate intermediate manufacturing step); the phase difference layer intermediate and the polarizing plate intermediate are bonded together in such a way that the outer edges thereof are aligned, thereby obtaining a polarizing plate intermediate with a phase difference layer whose absorption axis of the polarizing plate and the slow axis of the phase difference layer form an angle of 45° (for convenience, referred to as a polarizing plate intermediate with a phase difference layer manufacturing step); and, the polarizing plate intermediate with a phase difference layer is punched to obtain a polarizing plate sheet with a phase difference layer of a predetermined size having an absorption axis in the long side direction (for convenience, referred to as a final step). Each step is described in detail below. In addition, the description of "absorption axis of polarizing plate" in this manual refers to the absorption axis of the polarizer contained in the polarizing plate.

B.相位差層中間體製作步驟 圖1(a)及圖1(b)係說明相位差層中間體製作步驟的概略圖。首先,如圖1(a)所示,準備相位差薄膜之胚料捲材。相位差薄膜代表上為樹脂薄膜之延伸薄膜,在捲材之長條方向上具有慢軸。構成相位差薄膜之樹脂的代表例可列舉:聚碳酸酯系樹脂、聚酯碳酸酯系樹脂、聚酯系樹脂、聚乙烯縮醛系樹脂、聚芳酯系樹脂、環狀烯烴系樹脂、纖維素系樹脂、聚乙烯醇系樹脂、聚醯胺系樹脂、聚醯亞胺系樹脂、聚醚系樹脂、聚苯乙烯系樹脂、丙烯酸系樹脂等。 B. Phase difference layer intermediate production steps Figure 1(a) and Figure 1(b) are schematic diagrams illustrating the phase difference layer intermediate production steps. First, as shown in Figure 1(a), a phase difference film stock roll is prepared. The phase difference film is typically a stretched film of a resin film having a slow axis in the long strip direction of the roll. Representative examples of resins constituting phase difference films include: polycarbonate resins, polyester carbonate resins, polyester resins, polyvinyl acetal resins, polyarylate resins, cyclic olefin resins, cellulose resins, polyvinyl alcohol resins, polyamide resins, polyimide resins, polyether resins, polystyrene resins, acrylic resins, etc.

相位差薄膜之光學特性可因應目的適當地設定。相位差薄膜因具有慢軸,顯示出nx>ny之關係。相位差薄膜代表上顯示出nx>ny≧nz之折射率特性。相位差薄膜代表上可作為λ/4板發揮功能。相位差薄膜之面內相位差Re(550)宜為100nm~200nm,較宜為110nm~180nm,更宜為130nm~150nm。因相位差薄膜係作為λ/4板發揮功能,以使相位差薄膜之慢軸與偏光件之吸收軸代表上為45°之角度之方式積層相位差薄膜與偏光件(偏光板),藉此可獲得具有優異抗反射功能之附相位差層之偏光板(圓偏光板)。在此,「Re(λ)」係23℃下以波長λnm之光測定之面內相位差。因此,「Re(550)」係23℃下以波長550nm之光測定之面內相位差。Re(λ)係在將層(薄膜)之厚度設定為d(nm)時,藉由式:Re(λ)=(nx-ny)×d求算。The optical properties of the phase difference film can be appropriately set according to the purpose. The phase difference film has a slow axis, and shows the relationship of nx>ny. The phase difference film typically shows the refractive index characteristics of nx>ny≧nz. The phase difference film can typically function as a λ/4 plate. The in-plane phase difference Re(550) of the phase difference film is preferably 100nm~200nm, more preferably 110nm~180nm, and more preferably 130nm~150nm. Because the phase difference film functions as a λ/4 plate, the phase difference film and the polarizer (polarizer) are layered in such a way that the slow axis of the phase difference film and the absorption axis of the polarizer are typically at an angle of 45°, thereby obtaining a polarizer (circular polarizer) with a phase difference layer having excellent anti-reflection function. Here, "Re(λ)" is the in-plane phase difference measured at 23°C with light of wavelength λnm. Therefore, "Re(550)" is the in-plane phase difference measured at 23°C with light of wavelength 550nm. Re(λ) is calculated by the formula: Re(λ)=(nx-ny)×d when the thickness of the layer (film) is set to d(nm).

相位差薄膜可顯示相位差值隨測定光之波長變大之逆色散波長特性,亦可顯示相位差值隨測定光之波長變小之正波長色散特性,又可顯示相位差值幾乎不隨測定光之波長變化之平坦之波長色散特性。The phase difference film can show the reverse dispersion wavelength characteristic that the phase difference value increases with the wavelength of the measured light, the positive wavelength dispersion characteristic that the phase difference value decreases with the wavelength of the measured light, and the flat wavelength dispersion characteristic that the phase difference value hardly changes with the wavelength of the measured light.

相位差薄膜之厚度可設定成可最適當地作為λ/4板發揮功能。換言之,厚度可設定成可獲得上述所期望之面內相位差。具體而言,厚度宜為70μm以下,15μm~60μm為佳。The thickness of the phase difference film can be set to be able to optimally function as a λ/4 plate. In other words, the thickness can be set to obtain the above-mentioned desired in-plane phase difference. Specifically, the thickness is preferably less than 70 μm, preferably 15 μm to 60 μm.

如圖1(a)所示,相位差薄膜代表上於胚料捲材10中在寬度方向上具有軸偏移。更詳而言之,相位差薄膜之慢軸S之方向於捲材之寬度方向端部大多會相對於捲材之長條方向偏移預定角度。該軸偏移代表上於中央部實質上並未顯現,越靠近寬度方向端部就變得越大。寬度方向端部之軸偏移可隨著捲材之寬度變化。例如寬度為1000mm~1500mm左右之捲材中,寬度方向端部之軸偏移可為例如1°~3°。製作大型(例如TV用)附相位差層之偏光板時,所述軸偏移實質上並未成為問題。這是因為藉由改善以附相位差層之偏光板整體計之色彩不均或視角依存性,軸偏移之問題就不會表面化或嚴重化。另一方面,本發明人等新發現於製作非常小型(例如VR護目鏡用:20mm×30mm左右之尺寸)之附相位差層之偏光板時,會因所述軸偏移導致每個最終製品之特性變異大到無法容許。此外,本發明人等為了解決該課題反覆修正錯誤後之結果,發現相較於偏光件之吸收軸之軸偏移,相位差薄膜之慢軸之軸偏移對該課題的影響更大,藉由採用可適當地解除相位差薄膜之慢軸之軸偏移的製程就能解決該課題,從而完成本發明。即,本發明實施形態係可解決迄今尚未認知到的新課題者,且其效果為無法預期之優異效果。As shown in FIG1(a), the phase difference film typically has an axial offset in the width direction in the stock roll 10. In more detail, the direction of the slow axis S of the phase difference film is offset by a predetermined angle relative to the long direction of the roll at the end of the width direction of the roll. The axial offset is typically not substantially apparent in the central portion, and becomes larger as it approaches the end in the width direction. The axial offset at the end in the width direction may vary with the width of the roll. For example, in a roll with a width of about 1000 mm to 1500 mm, the axial offset at the end in the width direction may be, for example, 1° to 3°. When manufacturing large-scale (e.g., TV-use) polarizing plates with phase difference layers, the axial offset does not substantially become a problem. This is because by improving the color unevenness or viewing angle dependence of the polarizing plate with a phase difference layer as a whole, the problem of axial offset will not surface or become serious. On the other hand, the inventors of the present invention have newly discovered that when manufacturing a very small polarizing plate with a phase difference layer (for example, for VR goggles: a size of about 20mm×30mm), the characteristics of each final product will vary greatly to an unacceptable degree due to the axial offset. In addition, the inventors of the present invention have repeatedly corrected errors in order to solve this problem and found that the axial offset of the slow axis of the phase difference film has a greater impact on the problem than the axial offset of the absorption axis of the polarizer. The problem can be solved by adopting a process that can appropriately eliminate the axial offset of the slow axis of the phase difference film, thereby completing the present invention. That is, the embodiments of the present invention can solve new problems that have not been recognized so far, and the effects thereof are unexpectedly excellent.

於本發明實施形態中,如圖1(a)所示,一邊校正胚料捲材10之寬度方向上慢軸S相對於長條方向之偏移一邊沖裁成預定尺寸,從而如圖1(b)所示,獲得在長邊方向上具有慢軸S之單片(代表上為矩形之)相位差層中間體12。更詳而言之如下所述。首先,偵檢胚料捲材10中慢軸S之軸偏移。作為軸偏移之偵檢方法,可採用任意適當之手段。例如可利用Axometrics公司製之「AxoScan」測定軸角度來偵檢軸偏移。偵檢出軸偏移時,根據偵檢出之資訊來調整沖裁刀之方向,再以調整方向後之沖裁刀沖裁胚料捲材之預定處。結果如圖1(b)所示,無論胚料捲材之沖裁位置為何,均可獲得在長邊方向上具有慢軸S(即慢軸方向經精密地控制)、且每個中間體各自之慢軸方向之變異非常小(實質上無變異)之相位差層中間體12。於製作相位差層中間體時校正胚料捲材中慢軸之軸偏移,實質地解除相位差層中間體中每個中間體各自之慢軸方向之變異,藉此於製作後述附相位差層之偏光板中間體及附相位差層之偏光板片(作為最終製品之附相位差層之偏光板)時之軸方向控制便會變得極簡便且容易。In the embodiment of the present invention, as shown in FIG1(a), the offset of the slow axis S in the width direction of the blank coil 10 relative to the longitudinal direction is corrected while the blank coil 10 is punched into a predetermined size, thereby obtaining a single-piece (rectangular in representation) phase difference layer intermediate 12 having a slow axis S in the longitudinal direction as shown in FIG1(b). More details are as follows. First, the axial offset of the slow axis S in the blank coil 10 is detected. As a method for detecting the axial offset, any appropriate means can be used. For example, the "AxoScan" manufactured by Axometrics can be used to measure the axial angle to detect the axial offset. When the axis offset is detected, the direction of the punching knife is adjusted according to the detected information, and then the punching knife with the adjusted direction is used to punch the predetermined position of the blank roll. The result is shown in Figure 1(b). Regardless of the punching position of the blank roll, a phase difference layer intermediate 12 with a slow axis S in the long side direction (i.e., the slow axis direction is precisely controlled) and very small (substantially no) variation in the slow axis direction of each intermediate can be obtained. When manufacturing the phase difference layer intermediate, the axial deviation of the slow axis in the stock roll is corrected, which substantially eliminates the variation of the slow axis direction of each intermediate in the phase difference layer intermediate. This makes the axial direction control during the manufacturing of the polarizing plate intermediate with phase difference layer and the polarizing plate sheet with phase difference layer (the polarizing plate with phase difference layer as the final product) described later become extremely simple and easy.

圖1(a)中顯示了從胚料捲材在寬度方向上沖裁3片相位差層中間體之例,惟於本發明實施形態中,代表上可從胚料捲材在寬度方向上沖裁例如3片~16片、或例如5片~6片之相位差層中間體。若為所述構成,便可獲得製造效率優異、胚料捲材之廢棄少、且適當地校正過胚料捲材之軸偏移之相位差層中間體。此時,所獲得之相位差層中間體可為例如短邊75mm~310mm左右之矩形、或例如長邊250mm~350mm及短邊150mm~250mm左右之矩形。FIG. 1( a) shows an example of punching 3 phase difference layer intermediates from a stock roll in the width direction. However, in the embodiment of the present invention, for example, 3 to 16 or 5 to 6 phase difference layer intermediates can be punched from a stock roll in the width direction. If the above structure is adopted, a phase difference layer intermediate with excellent manufacturing efficiency, less waste of stock rolls, and properly corrected axial offset of the stock roll can be obtained. At this time, the obtained phase difference layer intermediate can be, for example, a rectangle with a short side of about 75 mm to 310 mm, or a rectangle with a long side of about 250 mm to 350 mm and a short side of about 150 mm to 250 mm.

關於相位差層中間體之沖裁,可一邊校正軸偏移一邊1片1片地進行沖裁;亦可在寬度方向之1列上調整預定數量之沖裁刀各自之方向,以該1列為單位地進行沖裁。Regarding the punching of the phase difference layer intermediate, the punching can be performed one by one while correcting the axis deviation; or the directions of a predetermined number of punching knives can be adjusted on one row in the width direction, and the punching can be performed in units of the one row.

C.偏光板中間體製作步驟 另外,如圖2(a)所示,準備偏光板之胚料捲材20。偏光板代表上係具有偏光件與設於偏光件之至少其中一側之保護薄膜。作為偏光件,可採用任意適當之偏光件。形成偏光件之樹脂薄膜可為單層樹脂薄膜,亦可使用二層以上之積層體來製作。由單層樹脂薄膜構成之偏光件的具體例,可列舉:利用碘或二色性染料等二色性物質對聚乙烯醇(PVA)系樹脂薄膜、部分縮甲醛化PVA系樹脂薄膜、乙烯・乙酸乙烯酯共聚物系部分皂化薄膜等親水性高分子薄膜施行染色處理及延伸處理而成者;PVA之脫水處理物或聚氯乙烯之脫鹽酸處理物等多烯系定向薄膜等。宜使用以碘將PVA系樹脂薄膜染色並進行單軸延伸所獲得之偏光件,因其光學特性優異。上述利用碘進行之染色,係藉由例如將PVA系樹脂薄膜浸漬於碘水溶液中來進行。上述單軸延伸之延伸倍率宜為3~7倍。延伸可在染色處理後進行,亦可一邊染色一邊進行。又,亦可延伸後再染色。可視需要,對PVA系樹脂薄膜施行膨潤處理、交聯處理、洗淨處理、乾燥處理等。例如,藉由在染色前將PVA系樹脂薄膜浸漬於水中進行水洗,不僅可洗淨PVA系樹脂薄膜表面之污垢或抗黏結劑,還可使PVA系樹脂薄膜膨潤,從而防止染色不均等情況。 C. Polarizing plate intermediate manufacturing step In addition, as shown in FIG. 2(a), a polarizing plate blank roll 20 is prepared. The polarizing plate generally has a polarizing element and a protective film disposed on at least one side of the polarizing element. As the polarizing element, any appropriate polarizing element can be used. The resin film forming the polarizing element can be a single-layer resin film, or a laminate of two or more layers can be used for manufacturing. Specific examples of polarizers composed of a single layer of resin film include: polyvinyl alcohol (PVA) resin film, partially formalized PVA resin film, ethylene-vinyl acetate copolymer partially saponified film and other hydrophilic polymer films dyed and stretched using dichroic substances such as iodine or dichroic dyes; polyene oriented films such as dehydrated PVA or dehydrogenated polyvinyl chloride. It is preferable to use a polarizer obtained by dyeing a PVA resin film with iodine and uniaxially stretching it because of its excellent optical properties. The dyeing with iodine is performed by, for example, immersing the PVA resin film in an iodine aqueous solution. The stretching ratio of the uniaxial stretching is preferably 3 to 7 times. Stretching can be performed after dyeing or while dyeing. In addition, it can be stretched before dyeing. If necessary, the PVA resin film can be subjected to swelling treatment, crosslinking treatment, cleaning treatment, drying treatment, etc. For example, by immersing the PVA resin film in water and washing it before dyeing, not only can the dirt or anti-adhesive agent on the surface of the PVA resin film be washed away, but the PVA resin film can also be swollen, thereby preventing uneven dyeing.

作為使用積層體而獲得之偏光件的具體例可舉使用樹脂基材與積層在該樹脂基材之PVA系樹脂層(PVA系樹脂薄膜)之積層體、或者是使用樹脂基材與塗佈形成於該樹脂基材之PVA系樹脂層之積層體而獲得之偏光件。使用樹脂基材與塗佈形成於該樹脂基材之PVA系樹脂層之積層體而獲得之偏光件,例如可藉由以下步驟來製作:將PVA系樹脂溶液塗佈於樹脂基材並使其乾燥而於樹脂基材上形成PVA系樹脂層,從而獲得樹脂基材與PVA系樹脂層之積層體;及,將該積層體延伸及染色,以將PVA系樹脂層製成偏光件。於本實施形態中延伸代表上包含使積層體浸漬於硼酸水溶液中來延伸。並且視需要,延伸可進一步包含於硼酸水溶液中進行延伸前將積層體在高溫(例如95℃以上)下進行空中延伸。所獲得之樹脂基材/偏光件之積層體可直接使用(即,可將樹脂基材作為偏光件之保護層),亦可從樹脂基材/偏光件之積層體剝離樹脂基材並於該剝離面積層符合目的之任意適當之保護層來使用。所述偏光件之製造方法之詳細內容記載於例如日本專利特開2012-73580號公報、日本專利第6470455號中。該等專利文獻之記載內容作為參考援引於本說明書中。Specific examples of polarizers obtained using a laminate include a laminate using a resin substrate and a PVA-based resin layer (PVA-based resin film) laminated on the resin substrate, or a laminate using a resin substrate and a PVA-based resin layer coated on the resin substrate. A polarizer obtained by using a laminate of a resin substrate and a PVA-based resin layer coated on the resin substrate can be produced, for example, by the following steps: a PVA-based resin solution is coated on the resin substrate and dried to form a PVA-based resin layer on the resin substrate, thereby obtaining a laminate of the resin substrate and the PVA-based resin layer; and the laminate is stretched and dyed to make the PVA-based resin layer into a polarizer. In this embodiment, stretching typically includes immersing the laminate in a boric acid aqueous solution for stretching. And if necessary, stretching can further include stretching the laminate in the air at a high temperature (e.g., above 95° C.) before stretching in the boric acid aqueous solution. The obtained resin substrate/polarizer laminate can be used directly (i.e., the resin substrate can be used as a protective layer of the polarizer), or the resin substrate can be peeled off from the resin substrate/polarizer laminate and any appropriate protective layer that meets the purpose can be used on the peeled off area layer. The details of the manufacturing method of the polarizer are described in, for example, Japanese Patent Publication No. 2012-73580 and Japanese Patent No. 6470455. The contents of these patent documents are cited in this specification as a reference.

保護薄膜係以可作為偏光件之保護薄膜使用之任意適當之薄膜構成。作為成為該薄膜之主成分材料的具體例,可列舉:三醋酸纖維素(TAC)等纖維素系樹脂;或聚酯系、聚乙烯醇系、聚碳酸酯系、聚醯胺系、聚醯亞胺系、聚醚碸系、聚碸系、聚苯乙烯系、聚降莰烯系、聚烯烴系、環狀烯烴系、(甲基)丙烯酸系及乙酸酯系等透明樹脂等。又,亦可列舉(甲基)丙烯酸系、胺甲酸酯系、(甲基)丙烯酸胺甲酸酯系、環氧系、聚矽氧系等熱硬化型樹脂或紫外線硬化型樹脂等。其他還可舉例如:矽氧烷系聚合物等玻璃質系聚合物。又,亦可使用日本專利特開2001-343529號公報(WO01/37007)中記載之聚合物薄膜。作為該薄膜之材料,例如可使用含有於側鏈具有經取代或未經取代之醯亞胺基之熱塑性樹脂、及於側鏈具有經取代或未經取代之苯基以及腈基之熱塑性樹脂的樹脂組合物,可舉例如:具有由異丁烯與N-甲基順丁烯二醯亞胺所構成之交替共聚物、及丙烯腈・苯乙烯共聚物的樹脂組成物。該聚合物薄膜可為例如上述樹脂組成物之擠製成形物。可使用TAC、(甲基)丙烯酸系樹脂、環狀烯烴系樹脂較佳。The protective film is made of any appropriate film that can be used as a protective film for polarizers. Specific examples of the main component material of the film include: cellulose resins such as triacetate cellulose (TAC); or transparent resins such as polyester, polyvinyl alcohol, polycarbonate, polyamide, polyimide, polyether sulfone, polysulfone, polystyrene, polynorbornene, polyolefin, cyclic olefin, (meth)acrylic acid, and acetate. In addition, thermosetting resins or ultraviolet curing resins such as (meth)acrylic acid, urethane, (meth)acrylic urethane, epoxy, and polysilicone can also be listed. Other examples include glassy polymers such as siloxane polymers. In addition, the polymer film described in Japanese Patent Publication No. 2001-343529 (WO01/37007) can also be used. As the material of the film, for example, a resin composition containing a thermoplastic resin having a substituted or unsubstituted amide group in the side chain and a thermoplastic resin having a substituted or unsubstituted phenyl group and a nitrile group in the side chain can be used, for example: a resin composition having an alternating copolymer composed of isobutylene and N-methyl cis-butylene diimide and an acrylonitrile-styrene copolymer. The polymer film can be, for example, an extruded product of the above resin composition. TAC, (meth) acrylic resin, and cyclic olefin resin can be used preferably.

如圖2(a)所示,偏光板代表上於胚料捲材20中實質上在寬度方向上不具有軸偏移。更詳而言之,因材料、光學特性、製造方法等,偏光件其吸收軸A之方向在遍及胚料捲材之寬度方向整體都顯現成與胚料捲材之長條方向實質上平行之方向。即,偏光件之吸收軸之寬度方向之軸偏移實質上並不存在,或者即便存在,其相對於相位差薄膜之慢軸之軸偏移來說也是非常小。因此,從偏光板之胚料捲材20製作偏光板中間體22時,不需一邊校正軸偏移一邊進行沖裁。結果,於本發明實施形態中,例如藉由使用格子狀之沖裁刀,如圖2(b)所示,可以整批地沖裁複數個偏光板中間體。於圖示例中,藉由朝相對於胚料捲材之長條方向呈45°方向進行沖裁,即可如圖2(c)所示,獲得在相對於長邊方向呈45°方向上具有吸收軸A之單片(代表上為矩形之)偏光板中間體22。藉由如此整批地沖裁複數個偏光板中間體,即可實現優異之製造效率。此外,若朝斜方向(相對於胚料捲材之長條方向呈預定角度之方向)1片1片地沖裁,即便於胚料捲材中不存在軸偏移仍會有每片經沖裁之中間體發生軸方向之變異的情況,而藉由整批地進行沖裁即可避免如此問題。即,可獲得吸收軸方向經精密地控制、且每個中間體各自之吸收軸方向之變異非常小(實質上無變異)之偏光板中間體22。另外,本技術領域中具有通常知識者應明瞭沖裁之角度(相對於胚料捲材之長條方向之角度)除了45°以外亦可因應目的適當地設定。該角度相當於附相位差層之偏光板中偏光件之吸收軸與相位差層之慢軸所成之角度。As shown in FIG. 2( a ), the polarizing plate representative has substantially no axial offset in the width direction in the stock roll 20. In more detail, due to the material, optical properties, manufacturing method, etc., the direction of the absorption axis A of the polarizer appears to be substantially parallel to the long strip direction of the stock roll throughout the width direction of the stock roll. That is, the axial offset of the absorption axis of the polarizer in the width direction does not substantially exist, or even if it exists, it is very small relative to the axial offset of the slow axis of the phase difference film. Therefore, when making the polarizing plate intermediate 22 from the polarizing plate stock roll 20, it is not necessary to perform punching while correcting the axial offset. As a result, in the embodiment of the present invention, for example, by using a grid-shaped punching knife, as shown in FIG2(b), a plurality of polarizing plate intermediates can be punched out in batches. In the example shown in the figure, by punching out in a direction of 45° relative to the long strip direction of the blank roll, a single (representatively rectangular) polarizing plate intermediate 22 having an absorption axis A in a direction of 45° relative to the long side direction can be obtained as shown in FIG2(c). By punching out a plurality of polarizing plate intermediates in batches in this way, excellent manufacturing efficiency can be achieved. Furthermore, if the sheets are punched out one by one in an oblique direction (a direction at a predetermined angle relative to the long strip direction of the stock roll), even if there is no axial deviation in the stock roll, there will still be a situation where the axial direction of each punched intermediate varies. However, such a problem can be avoided by punching out in batches. That is, the polarizing plate intermediate 22 can be obtained, in which the absorption axis direction is precisely controlled and the variation of the absorption axis direction of each intermediate is very small (substantially no variation). In addition, those with ordinary knowledge in the art should understand that the punching angle (the angle relative to the long strip direction of the stock roll) can be set appropriately according to the purpose in addition to 45°. This angle is equivalent to the angle formed by the absorption axis of the polarizer in the polarizing plate with a phase difference layer and the slow axis of the phase difference layer.

如上述之斜方向之沖裁代表上可藉由如下方式進行:偵檢胚料捲材之寬度方向之邊緣,並根據偵檢出之資訊來調整沖裁刀之方向,再以調整方向後之沖裁刀進行沖裁。The above-mentioned oblique punching can be performed in the following way: detect the edge of the blank coil in the width direction, adjust the direction of the punching knife according to the detected information, and then perform punching with the adjusted punching knife.

被沖裁之偏光板中間體之尺寸代表上與相位差層中間體之尺寸相同。因此,所獲得之偏光板中間體可為例如短邊75mm~310mm左右之矩形、或例如長邊250mm~350mm及短邊150mm~250mm左右之矩形。若為所述構成,如後述,附相位差層之偏光板中間體之製作係簡便容易,並且,附相位差層之偏光板中間體中偏光件之吸收軸與相位差層(相位差薄膜)之慢軸之角度控制係容易。The size of the punched polarizing plate intermediate is typically the same as the size of the phase difference layer intermediate. Therefore, the obtained polarizing plate intermediate can be, for example, a rectangle with a short side of about 75mm to 310mm, or a rectangle with a long side of about 250mm to 350mm and a short side of about 150mm to 250mm. If it is the above structure, as described later, the preparation of the polarizing plate intermediate with a phase difference layer is simple and easy, and the angle control of the absorption axis of the polarizer and the slow axis of the phase difference layer (phase difference film) in the polarizing plate intermediate with a phase difference layer is easy.

D.附相位差層之偏光板中間體製作步驟 接著,如圖3(a)所示,將依上述B項記載之方式獲得之相位差層中間體12與依上述C項記載之方式獲得之偏光板中間體22加以貼合,獲得附相位差層之偏光板中間體。相位差層中間體與偏光板中間體代表上係以使各自之外緣一致之方式貼合。如上述,相位差層中間體及偏光板中間體皆為軸方向經精密地控制,並且,每個中間體各自之軸方向之變異非常小,故藉由以使各自之外緣一致之方式貼合,不需進行精密及/或精細之操作,即可良好地控制附相位差層之偏光板中間體中偏光件之吸收軸與相位差層之慢軸之角度。此外,所述操作簡便容易乃自不待言,故附相位差層之偏光板中間體之製作本身亦簡便容易。如此進行,可獲得相位差層在長邊方向上具有慢軸、且偏光件之吸收軸與相位差層之慢軸所成角度為45°的附相位差層之偏光板中間體。 D. Preparation steps of polarizing plate intermediate with phase difference layer Next, as shown in FIG3(a), the phase difference layer intermediate 12 obtained in the manner described in item B above and the polarizing plate intermediate 22 obtained in the manner described in item C above are bonded together to obtain the polarizing plate intermediate with phase difference layer. The phase difference layer intermediate and the polarizing plate intermediate are typically bonded together in such a manner that their outer edges are aligned. As mentioned above, the phase difference layer intermediate and the polarizing plate intermediate are both precisely controlled in the axial direction, and the variation in the axial direction of each intermediate is very small. Therefore, by laminating them in a way that their outer edges are consistent, the angle between the absorption axis of the polarizer and the slow axis of the phase difference layer in the polarizing plate intermediate with phase difference layer can be well controlled without precise and/or delicate operations. In addition, it goes without saying that the operation is simple and easy, so the preparation of the polarizing plate intermediate with phase difference layer is also simple and easy. In this way, a phase difference layer with a slow axis in the long side direction and an angle of 45° between the absorption axis of the polarizer and the slow axis of the phase difference layer can be obtained.

E.最終步驟 接著,如圖3(b)及圖3(c)所示,沖裁依上述D項記載之方式獲得之附相位差層之偏光板中間體30,獲得附相位差層之偏光板片(作為最終製品之附相位差層之偏光板)32。沖裁代表上係朝相對於附相位差層之偏光板中間體之長邊方向呈45°方向進行。結果,如圖3(c)所示,可獲得偏光件在長邊方向上具有吸收軸、且偏光件之吸收軸與相位差層之慢軸所成角度為45°的附相位差層之偏光板片(作為最終製品之附相位差層之偏光板)。如上述,於附相位差層之偏光板中間體中,偏光件之吸收軸與相位差層之慢軸之角度業經良好地控制。因此,從附相位差層之偏光板中間體30製作附相位差層之偏光板片32時,不需一邊校正軸偏移一邊進行沖裁。結果,於本發明實施形態中,例如藉由使用格子狀之沖裁刀,如圖3(b)所示,可以整批地沖裁複數個附相位差層之偏光板片。藉由如此整批地沖裁複數個附相位差層之偏光板片,即可實現優異之製造效率。此外,若朝斜方向(相對於附相位差層之偏光板中間體之長邊方向呈預定角度之方向)1片1片地沖裁,即便於附相位差層之偏光板中間體中不存在軸偏移仍會有每片經沖裁之最終製品發生軸方向之變異的情況,而藉由整批地進行沖裁即可避免如此問題。即,可獲得吸收軸方向及慢軸方向經精密地控制、且每個製品各自之吸收軸方向及慢軸方向之變異非常小(實質上無變異)之附相位差層之偏光板片32。 E. Final step Next, as shown in FIG3(b) and FIG3(c), the polarizing plate intermediate 30 with a phase difference layer obtained in the manner described in item D above is punched to obtain a polarizing plate sheet with a phase difference layer (a polarizing plate with a phase difference layer as a final product) 32. Punching is performed at a direction of 45° relative to the long side direction of the polarizing plate intermediate with a phase difference layer. As a result, as shown in FIG3(c), a polarizing plate sheet with a phase difference layer (a polarizing plate with a phase difference layer as a final product) can be obtained, in which the polarizer has an absorption axis in the long side direction and the angle between the absorption axis of the polarizer and the slow axis of the phase difference layer is 45°. As described above, in the polarizing plate intermediate with a phase difference layer, the angle between the absorption axis of the polarizer and the slow axis of the phase difference layer has been well controlled. Therefore, when the polarizing plate sheet 32 with a phase difference layer is produced from the polarizing plate intermediate with a phase difference layer 30, it is not necessary to perform punching while correcting the axis offset. As a result, in an embodiment of the present invention, for example, by using a grid-shaped punching knife, as shown in FIG. 3(b), a plurality of polarizing plate sheets with a phase difference layer can be punched out in batches. By punching out a plurality of polarizing plate sheets with a phase difference layer in this way, excellent manufacturing efficiency can be achieved. In addition, if the sheets are punched out one by one in an oblique direction (a direction at a predetermined angle relative to the long side direction of the polarizing plate intermediate with a phase difference layer), even if there is no axial offset in the polarizing plate intermediate with a phase difference layer, there will still be variations in the axial direction of each punched final product. Such a problem can be avoided by punching out in batches. That is, the polarizing plate sheet 32 with a phase difference layer can be obtained, the absorption axis direction and the slow axis direction of each product are precisely controlled, and the variations in the absorption axis direction and the slow axis direction of each product are very small (substantially no variations).

如上述之斜方向之沖裁代表上可藉由如下方式進行:偵檢附相位差層之偏光板中間體之邊緣,並根據偵檢出之資訊來調整沖裁刀之方向,再以調整方向後之沖裁刀進行沖裁。宜偵檢附相位差層之偏光板中間體之長邊及短邊2個邊緣。若為所述構成,便可進行更精密之沖裁。The above-mentioned oblique punching can be performed in the following manner: the edge of the polarizing plate intermediate body with the phase difference layer attached is detected, and the direction of the punching knife is adjusted according to the detected information, and then the punching knife with the adjusted direction is used for punching. It is preferable to detect the long side and the short side of the polarizing plate intermediate body with the phase difference layer attached. If it is the above-mentioned structure, more precise punching can be performed.

如以上地進行,可獲得附相位差層之偏光板片(作為最終製品之附相位差層之偏光板)32。所獲得之附相位差層之偏光板片可為例如長邊10mm~70mm及短邊10mm~70mm左右、或例如長邊20mm~40mm及短邊10mm~30mm左右,更詳而言之為長邊30mm及短邊20mm左右之矩形。所述附相位差層之偏光板片可作為例如VR護目鏡用之圓偏光板使用。As described above, a polarizing plate with a phase difference layer (a polarizing plate with a phase difference layer as a final product) 32 can be obtained. The obtained polarizing plate with a phase difference layer can be, for example, a rectangle with a long side of 10 mm to 70 mm and a short side of 10 mm to 70 mm, or a rectangle with a long side of 20 mm to 40 mm and a short side of 10 mm to 30 mm, or more specifically, a rectangle with a long side of 30 mm and a short side of 20 mm. The polarizing plate with a phase difference layer can be used as a circular polarizing plate for VR goggles, for example.

根據本發明實施形態,藉由採用與習知完全不同之製程,可有效率地製造偏光件之吸收軸方向及相位差層之慢軸方向經極精密地控制之附相位差層之偏光板。於非常小型之附相位差層之偏光板之製造中該效果尤為顯著。具體而言如下所述。於習知之製造方法中,代表上是從相位差薄膜之胚料捲材朝相對於胚料捲材之長條方向呈傾斜之方向(例如45°方向)沖裁相位差薄膜,並從偏光板之胚料捲材朝胚料捲材之長條方向沖裁偏光板。這是因為只要如此進行良率就會變高,並且,習知尺寸之附相位差層之偏光板中相位差層(相位差薄膜)之軸偏移問題不會變嚴重。另一方面,於製作非常小型(例如VR護目鏡用:20mm×30mm左右之尺寸)之附相位差層之偏光板時,若為如上述之製造方法,會有每個最終製品之特性變異大到無法容許的情況。根據本發明實施形態,係從相位差薄膜之胚料捲材一邊校正軸偏移一邊沖裁相位差薄膜,並且,從偏光板之胚料捲材朝相對於胚料捲材之長條方向呈傾斜之方向(例如45°方向)沖裁偏光板,藉此,即使最後製作出非常小型之附相位差層之偏光板,仍可獲得偏光件之吸收軸方向及相位差層之慢軸方向經極精密地控制之附相位差層之偏光板。此時,胚料捲材之廢棄部分雖較習知製造方法多,但無法容許之最終製品之數量壓倒性地變少,故有整體上之良率變高的情況。或者,即便是整體上之良率變小的情況,但不破壞最終製品(例如VR護目鏡)也無法檢測附相位差層之偏光板之軸偏移,故以最終製品之品質保證而言還是有用的。According to the implementation form of the present invention, by adopting a process completely different from the known process, a polarizing plate with a phase difference layer in which the absorption axis direction of the polarizer and the slow axis direction of the phase difference layer are extremely precisely controlled can be efficiently manufactured. This effect is particularly significant in the manufacture of very small polarizing plates with phase difference layers. Specifically, it is described as follows. In the known manufacturing method, the phase difference film is typically punched out from the blank roll of the phase difference film in a direction inclined relative to the long strip direction of the blank roll (for example, a 45° direction), and the polarizing plate is punched out from the blank roll of the polarizing plate in the long strip direction of the blank roll. This is because the yield rate will be high if this is done, and the axial offset problem of the phase difference layer (phase difference film) in the polarizing plate with phase difference layer of known size will not become serious. On the other hand, when manufacturing a very small polarizing plate with phase difference layer (for example, for VR goggles: a size of about 20mm×30mm), if the manufacturing method as described above is used, there will be a situation where the characteristics of each final product vary greatly to an unacceptable degree. According to the embodiment of the present invention, the phase difference film is punched out from the blank roll of the phase difference film while correcting the axis deviation, and the polarizing plate is punched out from the blank roll of the polarizing plate in a direction inclined relative to the long strip direction of the blank roll (for example, a 45° direction), thereby, even if a very small polarizing plate with a phase difference layer is finally produced, the absorption axis direction of the polarizer and the slow axis direction of the phase difference layer can still be obtained. At this time, although the waste part of the blank roll is more than the conventional manufacturing method, the number of unacceptable final products is overwhelmingly reduced, so the overall yield rate is increased. Alternatively, even if the overall yield rate decreases, the axis offset of the polarizing plate with a phase difference layer cannot be detected without destroying the final product (such as VR goggles), so it is still useful in terms of quality assurance of the final product.

產業上之可利用性 本發明實施形態之製造方法適用於製造附相位差層之偏光板,尤其,可適用於製造非常小型(例如VR護目鏡用)之附相位差層之偏光板。 Industrial Applicability The manufacturing method of the embodiment of the present invention is applicable to the manufacture of polarizing plates with phase difference layers, and in particular, is applicable to the manufacture of very small polarizing plates with phase difference layers (for example, for VR goggles).

10:相位差薄膜之胚料捲材 12:相位差層中間體 20:偏光板之胚料捲材 22:偏光板中間體 30:附相位差層之偏光板中間體 32:附相位差層之偏光板片(作為最終製品之附相位差層之偏光板) A:吸收軸 S:慢軸 10: Stock roll of phase difference film 12: Phase difference layer intermediate 20: Stock roll of polarizing plate 22: Polarizing plate intermediate 30: Polarizing plate intermediate with phase difference layer 32: Polarizing plate with phase difference layer (polarizing plate with phase difference layer as the final product) A: Absorption axis S: Slow axis

圖1(a)及圖1(b)為概略圖,係說明本發明實施形態之附相位差層之偏光板之製造方法中獲得相位差層中間體之製程。 圖2(a)~圖2(c)為概略圖,係說明本發明實施形態之附相位差層之偏光板之製造方法中獲得偏光板中間體之製程。 圖3(a)~圖3(c)為概略圖,係說明本發明實施形態之附相位差層之偏光板之製造方法中獲得為最終製品的附相位差層之偏光板片之製程。 Figures 1(a) and 1(b) are schematic diagrams illustrating the process of obtaining a phase difference layer intermediate in the method for manufacturing a polarizing plate with a phase difference layer in the embodiment of the present invention. Figures 2(a) to 2(c) are schematic diagrams illustrating the process of obtaining a polarizing plate intermediate in the method for manufacturing a polarizing plate with a phase difference layer in the embodiment of the present invention. Figures 3(a) to 3(c) are schematic diagrams illustrating the process of obtaining a polarizing plate sheet with a phase difference layer as a final product in the method for manufacturing a polarizing plate with a phase difference layer in the embodiment of the present invention.

10:相位差薄膜之胚料捲材 10: Phase difference film blank roll

12:相位差層中間體 12: Phase difference layer intermediate

S:慢軸 S: Slow axis

Claims (4)

一種附相位差層之偏光板之製造方法,包含以下步驟: 將在長條方向上具有慢軸之相位差薄膜之胚料捲材,一邊校正該胚料捲材之寬度方向上該慢軸相對於長條方向之偏移一邊沖裁成預定尺寸,獲得在長邊方向上具有慢軸之單片相位差層中間體; 將在長條方向上具有吸收軸之偏光板之胚料捲材沖裁成與該相位差層中間體相同尺寸,獲得在相對於長邊方向呈45°方向上具有吸收軸之單片偏光板中間體; 以使該相位差層中間體與該偏光板中間體之外緣一致之方式將其等貼合,獲得偏光板之吸收軸與相位差層之慢軸所成角度為45°的附相位差層之偏光板中間體;以及, 沖裁該附相位差層之偏光板中間體,獲得在長邊方向上具有吸收軸之預定尺寸之附相位差層之偏光板片。 A method for manufacturing a polarizing plate with a phase difference layer comprises the following steps: A blank roll of a phase difference film having a slow axis in the longitudinal direction is punched into a predetermined size while correcting the offset of the slow axis in the width direction of the blank roll relative to the longitudinal direction, thereby obtaining a single phase difference layer intermediate having a slow axis in the longitudinal direction; A blank roll of a polarizing plate having an absorption axis in the longitudinal direction is punched into the same size as the phase difference layer intermediate, thereby obtaining a single polarizing plate intermediate having an absorption axis in a direction of 45° relative to the longitudinal direction; The phase difference layer intermediate and the polarizing plate intermediate are bonded together in such a way that their outer edges are aligned, thereby obtaining a phase difference layer-attached polarizing plate intermediate in which the absorption axis of the polarizing plate and the slow axis of the phase difference layer form an angle of 45°; and, The phase difference layer-attached polarizing plate intermediate is punched to obtain a phase difference layer-attached polarizing plate sheet having a predetermined size of absorption axis in the long side direction. 如請求項1之製造方法,其從前述相位差薄膜之胚料捲材在寬度方向上獲得3片~16片之前述相位差層中間體。In the manufacturing method of claim 1, 3 to 16 pieces of the aforementioned phase difference layer intermediates are obtained in the width direction from the aforementioned phase difference film blank roll. 如請求項1或2之製造方法,其中前述相位差層中間體及前述偏光板中間體為短邊75mm~310mm之矩形。The manufacturing method of claim 1 or 2, wherein the phase difference layer intermediate and the polarizing plate intermediate are rectangular with a short side of 75 mm to 310 mm. 如請求項3之製造方法,其中前述附相位差層之偏光板片為長邊10mm~70mm及短邊10mm~70mm之矩形。As in the manufacturing method of claim 3, wherein the polarizing plate with a phase difference layer is a rectangle with a long side of 10 mm to 70 mm and a short side of 10 mm to 70 mm.
TW112114631A 2022-05-26 2023-04-19 Manufacturing method of polarizing plate with phase difference layer TW202413035A (en)

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