TW202402814A - 超高分子量聚合物以及製造與使用其之方法 - Google Patents

超高分子量聚合物以及製造與使用其之方法 Download PDF

Info

Publication number
TW202402814A
TW202402814A TW112116124A TW112116124A TW202402814A TW 202402814 A TW202402814 A TW 202402814A TW 112116124 A TW112116124 A TW 112116124A TW 112116124 A TW112116124 A TW 112116124A TW 202402814 A TW202402814 A TW 202402814A
Authority
TW
Taiwan
Prior art keywords
water
soluble polymer
polymerization
unit
monomer
Prior art date
Application number
TW112116124A
Other languages
English (en)
Chinese (zh)
Inventor
庫倫 L G 戴維森
梅根 洛特
瑞貝卡 歐爾生
迪亞哥 I 佩德羅
華萊士 G 索耶
布倫特 S 薩默林
Original Assignee
美商佛羅里達大學研究基金會公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 美商佛羅里達大學研究基金會公司 filed Critical 美商佛羅里達大學研究基金會公司
Publication of TW202402814A publication Critical patent/TW202402814A/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/52—Amides or imides
    • C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F120/52—Amides or imides
    • C08F120/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F120/52—Amides or imides
    • C08F120/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F120/56—Acrylamide; Methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/32—Polymerisation in water-in-oil emulsions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/56—Acrylamide; Methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/24—Homopolymers or copolymers of amides or imides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/24—Homopolymers or copolymers of amides or imides
    • C08L33/26—Homopolymers or copolymers of acrylamide or methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Medicinal Preparation (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
TW112116124A 2022-04-29 2023-04-28 超高分子量聚合物以及製造與使用其之方法 TW202402814A (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US202263336733P 2022-04-29 2022-04-29
US63/336,733 2022-04-29
US202263368404P 2022-07-14 2022-07-14
US63/368,404 2022-07-14

Publications (1)

Publication Number Publication Date
TW202402814A true TW202402814A (zh) 2024-01-16

Family

ID=88519897

Family Applications (1)

Application Number Title Priority Date Filing Date
TW112116124A TW202402814A (zh) 2022-04-29 2023-04-28 超高分子量聚合物以及製造與使用其之方法

Country Status (11)

Country Link
US (1) US20230357461A1 (enExample)
EP (1) EP4514867A4 (enExample)
JP (1) JP2025515505A (enExample)
KR (1) KR20250033149A (enExample)
CN (1) CN119731223A (enExample)
AU (1) AU2023262591A1 (enExample)
CA (1) CA3251104A1 (enExample)
GB (1) GB2633232A (enExample)
MX (1) MX2024013370A (enExample)
TW (1) TW202402814A (enExample)
WO (1) WO2023212672A2 (enExample)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3088067B1 (fr) * 2018-11-06 2020-11-06 S N F Sa Procede de synthese de polymeres par polymerisation radicalaire controlee en emulsion inverse
WO2025155868A1 (en) * 2024-01-18 2025-07-24 Univeristy Of Florida Research Foundation, Inc. Polymers and methods making and using polymers
AU2025233965A1 (en) * 2024-03-04 2026-07-16 Alcon Inc. Carbamoylphenylboronic acid-containing acrylic monomers and uses thereof
WO2025250734A1 (en) * 2024-05-29 2025-12-04 University Of Florida Research Foundation, Inc. High molecular weight polymers and methods of making the same
CN119144002B (zh) * 2024-09-20 2025-05-30 扬州工业职业技术学院 一种超支化多支链聚醚破乳剂及其制备方法
CN119381051A (zh) * 2024-12-31 2025-01-28 浙江摩克激光智能装备有限公司 一种ltcc用快速紫外光固化导电银浆及其制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040151886A1 (en) * 2000-03-06 2004-08-05 Bobsein Barrett Richard Binder composition
US7832856B2 (en) * 2006-12-20 2010-11-16 Bausch & Lomb Incorporated Coatings and solutions for contact lenses
EP2863892B1 (en) * 2012-06-20 2017-11-08 University Of Waterloo Mucoadhesive nanoparticle delivery system
US11505634B2 (en) * 2017-12-19 2022-11-22 Spcm Sa Method for producing anionic water-soluble polymer on the basis of bioacrylamide and acrylic acid
CN117999081A (zh) * 2021-08-31 2024-05-07 佛罗里达大学研究基金会公司 超高分子量聚合物及其使用方法

Also Published As

Publication number Publication date
WO2023212672A2 (en) 2023-11-02
KR20250033149A (ko) 2025-03-07
AU2023262591A1 (en) 2024-11-21
GB2633232A (en) 2025-03-05
EP4514867A4 (en) 2026-07-29
EP4514867A2 (en) 2025-03-05
JP2025515505A (ja) 2025-05-15
CA3251104A1 (en) 2023-11-02
US20230357461A1 (en) 2023-11-09
GB202415979D0 (en) 2024-12-11
MX2024013370A (es) 2025-02-10
WO2023212672A3 (en) 2023-12-07
CN119731223A (zh) 2025-03-28

Similar Documents

Publication Publication Date Title
US20230357461A1 (en) Ultra-high molecular weight polymers and methods of using the same
Olson et al. Inverse miniemulsion photoiniferter polymerization for the synthesis of ultrahigh molecular weight polymers
d'Agosto et al. RAFT‐mediated polymerization‐induced self‐assembly
Byard et al. Preparation and cross-linking of all-acrylamide diblock copolymer nano-objects via polymerization-induced self-assembly in aqueous solution
An 100th anniversary of macromolecular science viewpoint: achieving ultrahigh molecular weights with reversible deactivation radical polymerization
Yeow et al. Polymerization-induced self-assembly using visible light mediated photoinduced electron transfer–reversible addition–fragmentation chain transfer polymerization
Khan et al. RAFT emulsion polymerization for (multi) block copolymer synthesis: overcoming the constraints of monomer order
Hill et al. Expanding the scope of RAFT polymerization: recent advances and new horizons
Ratcliffe et al. Polymerization-induced self-assembly of all-acrylic diblock copolymers via RAFT dispersion polymerization in alkanes
Lai et al. Functional polymers from novel carboxyl-terminated trithiocarbonates as highly efficient RAFT agents
Lovett et al. A robust cross-linking strategy for block copolymer worms prepared via polymerization-induced self-assembly
Cunningham et al. Poly (glycerol monomethacrylate)–poly (benzyl methacrylate) diblock copolymer nanoparticles via RAFT emulsion polymerization: synthesis, characterization, and interfacial activity
Rieger et al. Surfactant-free RAFT emulsion polymerization using poly (N, N-dimethylacrylamide) trithiocarbonate macromolecular chain transfer agents
Bories-Azeau et al. Facile synthesis of zwitterionic diblock copolymers without protecting group chemistry
Zhang et al. Modular monomers with tunable solubility: synthesis of highly incompatible block copolymer nano-objects via RAFT aqueous dispersion polymerization
Gyorgy et al. RAFT dispersion polymerization of methyl methacrylate in mineral oil: High glass transition temperature of the core-forming block constrains the evolution of copolymer morphology
Quek et al. RAFT Synthesis and aqueous solution behavior of novel pH-and thermo-responsive (co) polymers derived from reactive poly (2-vinyl-4, 4-dimethylazlactone) scaffolds
Zhang et al. Preparation of styrene–maleic anhydride–acrylamide terpolymer particles of uniform size and controlled composition via self-stabilized precipitation polymerization
Rosselgong et al. Core degradable star RAFT polymers: synthesis, polymerization, and degradation studies
Bowman et al. Controlling morphological transitions of polymeric nanoparticles via doubly responsive block copolymers
Wang et al. Dual pH-and light-responsive amphiphilic random copolymer nanomicelles as particulate emulsifiers to stabilize the oil/water interface
Yuan et al. Nonspherical nanoparticles with controlled morphologies via seeded surface-initiated single electron transfer radical polymerization in soap-free emulsion
Huang et al. Synthesis of triblock copolymers via RAFT polymerization and their application as surfactants for crude oil-in-water emulsion
Luo et al. Mechanistic investigation of the position of reversible addition–fragmentation chain transfer (RAFT) groups in heterogeneous RAFT polymerization
RU2276161C2 (ru) Водные композиции, содержащие химический микрогель, ассоциированный с водным полимером