TW202401047A - Partition wall for image display device, method for manufacturing same, and image display device including partition wall - Google Patents

Partition wall for image display device, method for manufacturing same, and image display device including partition wall Download PDF

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TW202401047A
TW202401047A TW111122992A TW111122992A TW202401047A TW 202401047 A TW202401047 A TW 202401047A TW 111122992 A TW111122992 A TW 111122992A TW 111122992 A TW111122992 A TW 111122992A TW 202401047 A TW202401047 A TW 202401047A
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partition wall
image display
thickness
display device
line width
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TW111122992A
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Chinese (zh)
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金勳植
金台昆
權寧豎
朴瑟琪
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南韓商東友精細化工有限公司
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Abstract

The present disclosure provides a partition wall for an image display device, the partition wall which satisfies 0.8 ≤ A/B < 1.0 and 0.85 ≤ C/B < 1.0 when the line width at a thickness of 95% from the lowermost end portion of the partition wall is A, the maximum line width at a thickness of 50 to 90% from the lowermost end portion of the partition wall is B, and the line width at a thickness of 10% from the lowermost end portion of the partition wall is C, with respect to the total thickness of the partition wall, a manufacturing method thereof, and an image display device including the partition wall. The partition wall for an image display device according to the present disclosure can be effectively applied to the manufacture of the color conversion pixels through the inkjet process, and the image display device including the partition wall has excellent luminance and maintains high luminance even when observed from the side surface, thereby exhibiting an effect of excellent viewing angle properties.

Description

用於影像顯示裝置的間隔壁、用以製造其的方法與包含間隔壁的影像顯示裝置Partition wall for image display device, method for manufacturing same and image display device including partition wall

本揭露係有關於用於影像顯示裝置(image display device)的間隔壁(partition wall)、用以製造其的方法、以及包含間隔壁的影像顯示裝置。The present disclosure relates to a partition wall for an image display device, a method for manufacturing the same, and an image display device including the partition wall.

傳統的影像顯示設備使用彩色濾光片(color filter)以形成色彩。在這種情況下,當具有白色的背光光源發出的光通過紅色、綠色與藍色濾光片,濾光片吸收特定波長的光且使特定波長的光穿透以顯示所需的色彩。這種穿透光的問題在於,其是透過吸收與穿透來區分的,因此相較於產生光的背光光源有大量損失。Traditional image display devices use color filters to form colors. In this case, when the light emitted by the backlight source with white color passes through the red, green and blue filters, the filters absorb the light of specific wavelengths and allow the light of specific wavelengths to pass through to display the desired color. The problem with this transmitted light is that it is differentiated by absorption and transmission, so there is a lot of loss compared to the backlight source that produced the light.

最近,正在對使用色彩轉換層的影像顯示裝置進行研究。例如,在由色彩轉換層與產生藍光的背光光源組成的顯示器結構中,藍色像素因為使用背光光源的藍色而可完整地使用背光光源產生的光。此外,在色彩轉換層顯示器中顯示紅色至綠色的像素是藉由將藍色轉換為紅色至綠色,因此光損失相較於傳統彩色濾光片使用吸收與穿透方法較小,從而可展現優異的光效率。然而,傳統已知的使用色彩轉換層的影像顯示裝置在亮度與視角特性上仍不夠令人滿意。Recently, research is being conducted on image display devices using color conversion layers. For example, in a display structure composed of a color conversion layer and a backlight source that generates blue light, blue pixels can fully use the light generated by the backlight source because they use the blue color of the backlight source. In addition, the pixels displaying red to green in the color conversion layer display are by converting blue to red to green, so the light loss is smaller compared to the absorption and transmission method of traditional color filters, which can display excellent performance. of light efficiency. However, the brightness and viewing angle characteristics of conventionally known image display devices using color conversion layers are still not satisfactory.

同時,就通常用於製造色彩轉換層的色彩轉換像素的黃光製程(photo process)而言,其益處在於製程是簡單的且可大量生產相同產物,但其問題在於會產生大量廢水且實際使用的材料量小於浪費掉的材料量,使得大部分的材料被丟棄。最近,噴墨製程已應用於色彩轉換像素的製程,其益處在於不會產生廢水且可減少丟棄的材料量。Meanwhile, as for the photo process, which is usually used to manufacture color conversion pixels of the color conversion layer, the advantage is that the process is simple and the same product can be mass-produced, but the problem is that a large amount of wastewater is generated and the actual use The amount of material is less than the amount of material wasted, causing most of the material to be discarded. More recently, inkjet processes have been used to create color-converting pixels, with the benefit of producing no waste water and reducing the amount of discarded material.

進行這種噴墨製程需要間隔壁(partition wall)與墨水。間隔壁作為區分每一用於注入墨水之像素區域的堰(weir)。透過噴嘴以使形成的像素區域填滿墨水。在噴墨製程中,當形成於多個間隔壁之間的像素區域(即孔洞)中的墨水的延展性(spreadability)與溼潤性(wettability)不足,會發生處理時間增加與色彩轉換像素中的缺陷增加的問題。This inkjet process requires partition walls and ink. The partition wall serves as a weir that differentiates each pixel area for ink injection. Fill the pixel area with ink through the nozzle. In the inkjet process, when the spreadability (spreadability) and wettability (wettability) of the ink formed in the pixel areas (i.e., holes) between multiple partition walls are insufficient, processing time will increase and color conversion in the pixels will occur. The problem of increased defects.

與此相關,韓國專利公開號10-2019-0090114揭露具有改善的色彩再現性與光效率之色彩轉換構件、以及包含其的電子裝置,但其並未察覺視角特性不足與透過噴墨製程形成色彩轉換像素的問題。Related to this, Korean Patent Publication No. 10-2019-0090114 discloses a color conversion member with improved color reproducibility and light efficiency, and an electronic device including the same, but it does not notice insufficient viewing angle characteristics and color formation through the inkjet process Problem with converting pixels.

[先前技術文獻][Prior technical literature]

[專利文獻][Patent Document]

(專利文獻1) 韓國專利公開號10-2019-0090114(Patent Document 1) Korean Patent Publication No. 10-2019-0090114

[技術問題][Technical Issue]

本揭露是為了改善上述傳統的技術問題,且本揭露的目的係為提供用於影像顯示裝置的間隔壁,其能夠提升亮度與視角特性。The present disclosure is to improve the above-mentioned traditional technical problems, and the purpose of the present disclosure is to provide a partition wall for an image display device, which can improve brightness and viewing angle characteristics.

本揭露的另一目的係為提供用於影像顯示裝置的間隔壁,其具有由間隔壁定義的多個像素區域中的色彩轉換墨水的延展性與溼潤性優異之特性,從而可有效地應用於用以形成色彩轉換像素的噴墨製程。Another object of the present disclosure is to provide a partition wall for an image display device, which has the characteristics of excellent ductility and wettability of the color conversion ink in a plurality of pixel areas defined by the partition wall, so that it can be effectively used in An inkjet process used to form color-converting pixels.

本揭露的又一目的係為提供用以製造用於影像顯示裝置的間隔壁之方法。Another object of the present disclosure is to provide a method for manufacturing a partition wall for an image display device.

本揭露的又一目的係為提供包含用於影像顯示裝置的間隔壁之影像顯示裝置。Another object of the present disclosure is to provide an image display device including a partition wall for the image display device.

[技術方案][Technical solution]

本揭露提供用於影像顯示裝置的間隔壁,其中相對於間隔壁整體的厚度,間隔壁從最下端算起95%的厚度處的線寬(line width)係為A,間隔壁從最下端算起50%至90%的厚度處的最大線寬係為B,間隔壁從最下端算起10%的厚度處的線寬係為C,間隔壁滿足0.8 A/B < 1.0與0.85 C/B < 1.0。 The present disclosure provides a partition wall for an image display device, wherein relative to the overall thickness of the partition wall, the line width at 95% of the thickness of the partition wall from the bottom end is A, and the line width of the partition wall from the bottom end is A. The maximum line width at 50% to 90% of the thickness is B, the line width at 10% of the thickness of the partition wall from the bottom is C, and the partition wall meets 0.8 A/B < 1.0 and 0.85 C/B < 1.0.

此外,本揭露提供用以製造用於影像顯示裝置之間隔壁的方法,方法包含在基板上形成間隔壁的步驟,其中相對於間隔壁整體的厚度,間隔壁從最下端算起95%的厚度處的線寬係為A,間隔壁從最下端算起50%至90%的厚度處的最大線寬係為B,間隔壁從最下端算起10%的厚度處的線寬係為C,間隔壁滿足0.8 A/B < 1.0與0.85 C/B < 1.0。 In addition, the present disclosure provides a method for manufacturing a partition wall between image display devices. The method includes the step of forming a partition wall on a substrate, wherein 95% of the thickness of the partition wall from the bottom is relative to the overall thickness of the partition wall. The line width at is A, the maximum line width at 50% to 90% of the thickness of the partition wall from the bottom is B, and the line width at 10% of the thickness of the partition from the bottom is C, The partition wall satisfies 0.8 A/B < 1.0 and 0.85 C/B < 1.0.

此外,本揭露提供影像顯示裝置,其包含用於影像顯示裝置的間隔壁。In addition, the present disclosure provides an image display device including a partition wall for the image display device.

[有利功效][Beneficial effects]

根據本揭露的包含用於影像顯示裝置的間隔壁之影像顯示裝置具有優異的亮度且即便從側表面觀察亦可維持高亮度,從而展現優異的視角特性之功效。The image display device including the partition wall for the image display device according to the present disclosure has excellent brightness and can maintain high brightness even when viewed from the side surface, thereby exhibiting the effect of excellent viewing angle characteristics.

此外,本揭露的用於影像顯示裝置的間隔壁的特性在於,由間隔壁定義的多個像素區域中的色彩轉換墨水的延展性與溼潤性優異,從而可有效地應用於透過噴墨製程製造像素部分(pixel portion)。In addition, the characteristic of the partition wall used in the image display device of the present disclosure is that the color conversion ink in the multiple pixel areas defined by the partition wall has excellent ductility and wettability, so that it can be effectively used in manufacturing through the inkjet process. Pixel portion.

此外,透過將根據本揭露之用於影像顯示裝置的間隔壁應用於影像顯示裝置,可提供具有優異的亮度與視角且像素部分沒有缺陷的高品質影像顯示裝置。In addition, by applying the partition wall for an image display device according to the present disclosure to an image display device, a high-quality image display device with excellent brightness and viewing angle and no defects in the pixel portion can be provided.

本揭露提供用於影像顯示裝置的間隔壁,其中相對於間隔壁整體的厚度,間隔壁從最下端算起95%的厚度處的線寬係為A,間隔壁從最下端算起50%至90%的厚度處的最大線寬係為B,間隔壁從最下端算起10%的厚度處的線寬係為C,間隔壁滿足0.8 A/B < 1.0與0.85 C/B < 1.0。 The present disclosure provides a partition wall for an image display device, wherein relative to the overall thickness of the partition wall, the line width at 95% of the thickness of the partition wall from the bottom end is A, and from 50% to 50% of the thickness of the partition wall from the bottom end. The maximum line width at 90% of the thickness is B, the line width at 10% of the thickness of the partition wall from the bottom is C, and the partition wall satisfies 0.8 A/B < 1.0 and 0.85 C/B < 1.0.

此外,本揭露提供用以製造用於影像顯示裝置之間隔壁的方法,方法包含在基板上形成間隔壁的步驟,其中相對於間隔壁整體的厚度,間隔壁從最下端算起95%的厚度處的線寬係為A,間隔壁從最下端算起50%至90%的厚度處的最大線寬係為B,間隔壁從最下端算起10%的厚度處的線寬係為C,間隔壁滿足0.8 A/B < 1.0與0.85 C/B < 1.0。 In addition, the present disclosure provides a method for manufacturing a partition wall between image display devices. The method includes the step of forming a partition wall on a substrate, wherein 95% of the thickness of the partition wall from the bottom is relative to the overall thickness of the partition wall. The line width at is A, the maximum line width at 50% to 90% of the thickness of the partition wall from the bottom is B, and the line width at 10% of the thickness of the partition from the bottom is C, The partition wall satisfies 0.8 A/B < 1.0 and 0.85 C/B < 1.0.

此外,本揭露提供包含用於影像顯示裝置的間隔壁之影像顯示裝置。In addition, the present disclosure provides an image display device including a partition wall for the image display device.

本揭露已透過實驗證實,根據本揭露之用於影像顯示裝置的間隔壁在其形狀滿足上述特定條件時,可提升應用此間隔壁的影像顯示裝置的亮度與視角特性且可有效應用於用以形成色彩轉換像素之噴墨製程。The present disclosure has confirmed through experiments that when the shape of the partition wall for an image display device according to the present disclosure satisfies the above-mentioned specific conditions, the brightness and viewing angle characteristics of the image display device using the partition wall can be improved and can be effectively used to form Inkjet process for color conversion pixels.

通過以下詳細描述的多個實施例並結合附圖,本揭露的多個益處與多個特徵、以及用以實現它們的方法將變得顯而易見。本揭露並不限於以下揭露的多個實施例,而可實施為各種形式。提供多個實施例以使本揭露之揭示內容完善,且使本領域中具有通常知識者充分了解本揭露之範圍。Benefits and features of the present disclosure, as well as methods for realizing them, will become apparent through the following detailed description of the embodiments in conjunction with the accompanying drawings. The present disclosure is not limited to the embodiments disclosed below, but can be implemented in various forms. Various embodiments are provided to complete the disclosure, and to fully understand the scope of the disclosure to those skilled in the art.

用以說明本揭露之多個實施例而揭示於圖式中的形狀、尺寸、比例、角度、數量等係為示例性的,且從而本揭露不限於繪示的態樣。本說明書中相同元件符號代表相同元件。The shapes, sizes, proportions, angles, quantities, etc. disclosed in the drawings for illustrating various embodiments of the disclosure are exemplary, and thus the disclosure is not limited to the illustrated forms. The same component numbers in this specification represent the same components.

在描述本揭露時,若相關的已知功能或構造可能會不必要地混淆本揭露之標的,則其詳細描述將會省略。當本說明書中使用「包含」、「具有」、「組成」等用詞時,除非使用「僅」,否則可以增加其他部件。When describing the present disclosure, if related known functions or structures may unnecessarily obscure the subject matter of the present disclosure, their detailed descriptions will be omitted. When words such as "comprising", "having" and "consisting of" are used in this specification, other components may be added unless "only" is used.

當解釋元件時,在描述位置關係的情況下,例如當兩個部件的位置關係被描述為「上」、「在頂部」、「在底部」、「旁邊」等,除非使用「正好」或「直接」,否則可能有一或更多的其他元件位於這兩個部件之間。When explaining components, in the case of describing the positional relationship, for example, when the positional relationship between two parts is described as "on", "at the top", "at the bottom", "side", etc., unless "just" or "exactly" or " "directly", otherwise there might be one or more other components between the two parts.

本揭露的各實施例的各特徵可部分地或全部地互相結合或組合,且可在技術上以各種方式互鎖與驅動。此外,個別實施例可彼此獨立地實施或可關聯地一起實施。Features of various embodiments of the present disclosure may be partially or fully combined or combined with each other, and may be technically interlocked and driven in various ways. Furthermore, individual embodiments may be implemented independently of each other or may be implemented together in association.

以下將參照圖式描述本揭露的多個具體實施例。然而,附圖係繪示本揭露之較佳實施例,且用以一起搭配本揭露之上述內容以進一步理解本揭露之技術精神。因此,本揭露不應被解釋為僅限於這些圖式描述的態樣。Various specific embodiments of the present disclosure will be described below with reference to the drawings. However, the accompanying drawings illustrate preferred embodiments of the present disclosure and are used together with the above content of the present disclosure to further understand the technical spirit of the present disclosure. Accordingly, the present disclosure should not be construed as being limited to the aspects described in these diagrams.

用於影像顯示裝置的間隔壁Partition walls for image display devices

本揭露提供用於影像顯示裝置的間隔壁。The present disclosure provides partition walls for image display devices.

在影像顯示裝置中,由於每一像素表現一顏色,形成能夠區別每一像素的間隔壁是必要的。在本揭露中,用於影像顯示裝置的間隔壁可形成以定義像素區域,也就是說,圍繞像素區域。In an image display device, since each pixel represents a color, it is necessary to form partition walls that can distinguish each pixel. In the present disclosure, a partition wall for an image display device may be formed to define a pixel area, that is, to surround the pixel area.

像素區域係為表現顏色的像素部分形成的區域,且代表包含紅色、綠色或藍色墨水的著色組成物(coloring composition)與發光材料噴塗或施加的區域,或填充著色組成物的區域。The pixel area is an area formed by a pixel portion that expresses a color, and represents an area where a coloring composition including red, green or blue ink and a luminescent material are sprayed or applied, or an area where the coloring composition is filled.

影像顯示裝置的示例可包含液晶顯示裝置、有機發光二極體、柔性顯示器(flexible display)等等,但本揭露不限於此,本領域中所有已知可應用的顯示裝置均可作為示例。Examples of image display devices may include liquid crystal display devices, organic light emitting diodes, flexible displays, etc., but the disclosure is not limited thereto, and all applicable display devices known in the art may be used as examples.

第1圖是用以說明根據本揭露一實施例之用於影像顯示裝置的間隔壁的形狀之剖面圖。以下將搭配第1圖詳細說明根據本揭露之用於影像顯示裝置的間隔壁的形狀。FIG. 1 is a cross-sectional view illustrating the shape of a partition wall for an image display device according to an embodiment of the present disclosure. The shape of the partition wall used in the image display device according to the present disclosure will be described in detail below with reference to Figure 1 .

第1圖中,D代表從間隔壁的最下端(the lowermost end portion)至最上端(the uppermost end portion)的高度,也就是間隔壁的厚度。間隔壁的厚度(D)沒有特別限制,但可較佳地為8至12微米( m),且更佳為9至11 m。當用於影像顯示裝置的間隔壁滿足上述厚度範圍,其益處在於可進一步提升光效率從而可展現出表現優異的色彩轉換像素。 In Figure 1, D represents the height from the lowermost end portion of the partition wall to the uppermost end portion, that is, the thickness of the partition wall. The thickness (D) of the partition wall is not particularly limited, but may preferably be 8 to 12 microns ( m), and preferably 9 to 11 m. When the partition wall used in the image display device meets the above thickness range, the benefit is that the light efficiency can be further improved and color conversion pixels with excellent performance can be displayed.

在本揭露中,A、B和C表示在間隔壁的特定高度處測量之間隔壁的線寬。更具體地,A代表從間隔壁的最下端算起95%的厚度處的線寬,也就是高度0.95D。B代表從間隔壁的最下端算起50%至90%的厚度處的最大線寬,較佳係為從間隔壁的最下端算起60%至80%的厚度處的最大線寬。C代表從間隔壁的最下端算起10%的厚度處的線寬,也就是高度0.1D。In this disclosure, A, B, and C represent the line widths of the partition walls measured at specific heights of the partition walls. More specifically, A represents the line width at 95% of the thickness from the bottom end of the partition wall, which is a height of 0.95D. B represents the maximum line width at 50% to 90% of the thickness from the bottom end of the partition wall, preferably 60% to 80% of the thickness from the bottom end of the partition wall. C represents the line width at 10% of the thickness from the bottom end of the partition wall, which is a height of 0.1D.

根據本揭露之用於影像顯示裝置的間隔壁可滿足0.8 A/B < 1.0,較佳係為0.85 A/B < 1.0。 The partition wall used in the image display device according to the present disclosure can satisfy 0.8 A/B < 1.0, the best is 0.85 A/B < 1.0.

此外,根據本揭露之用於影像顯示裝置的間隔壁可滿足0.85 C/B < 1.0,較佳係為0.9 C/B < 1.0。 In addition, the partition wall used for the image display device according to the present disclosure can satisfy 0.85 C/B < 1.0, preferably 0.9 C/B < 1.0.

相較於使用A、B和C全都具有相同線寬的間隔壁,當根據本揭露之用於影像顯示裝置的間隔壁滿足以上A/B與C/B的範圍時,可形成表面部分的面積增加的像素區域。因此,可增加從光源入射到像素部分的光的吸收率(absorption rate),以展現優異的亮度,且隨著光從像素部分射出的角度提升,可減少側面亮度降低,以展現優異的視角特性。Compared to using partition walls A, B, and C all having the same line width, when the partition walls for an image display device according to the present disclosure satisfy the above ranges of A/B and C/B, the area of the surface portion can be formed Increased pixel area. Therefore, the absorption rate of light incident from the light source to the pixel portion can be increased to exhibit excellent brightness, and as the angle at which light is emitted from the pixel portion increases, the decrease in side brightness can be reduced to exhibit excellent viewing angle characteristics. .

此外,相較於使用A、B和C全都具有相同線寬的間隔壁,當根據本揭露之用於影像顯示裝置的間隔壁滿足以上A/B與C/B的範圍時,可形成體積增加的像素區域。因此,由於像素區域可容納更多的著色組成物,可藉由光轉換率增加來展現優異的亮度與色彩轉換特性。In addition, compared to using partition walls A, B, and C all having the same line width, when the partition walls used for the image display device according to the present disclosure satisfy the above ranges of A/B and C/B, the volume can be increased. pixel area. Therefore, since the pixel area can accommodate more colored components, it can exhibit excellent brightness and color conversion characteristics by increasing the light conversion rate.

同時,在形成間隔壁的過程中,用以形成間隔壁的組成物中在高溫加熱處理期間昇華的成分可能會落入像素區域中而形成汙染物。這些汙染物中,形成於像素區域的中間部分的汙染物成為抑制製造色彩轉換像素中的色彩轉換墨水的延展性與溼潤性之主因,尤其是透過噴墨製程。當根據本揭露之用於影像顯示裝置的間隔壁滿足以上A/B與C/B的範圍時,可減少形成間隔壁的過程中產生的附著於像素區域之中間部分的汙染物。因此,色彩轉換墨水具有優異的延展性與溼潤性,從而其可有效地應用於透過噴墨製程製造色彩轉換像素。At the same time, during the process of forming the partition walls, components in the composition used to form the partition walls that sublimate during the high-temperature heat treatment may fall into the pixel area and form contaminants. Among these contaminants, contaminants formed in the middle portion of the pixel area become the main cause of inhibiting the ductility and wettability of the color conversion ink used in manufacturing color conversion pixels, especially through the inkjet process. When the partition wall for an image display device according to the present disclosure satisfies the above ranges of A/B and C/B, contaminants attached to the middle portion of the pixel area generated during the formation of the partition wall can be reduced. Therefore, the color conversion ink has excellent ductility and wettability, so that it can be effectively used to manufacture color conversion pixels through the inkjet process.

根據本揭露之用於影像顯示裝置的間隔壁可由用以形成間隔壁的感光性樹脂組成物(photosensitive resin composition)形成。The partition wall used in the image display device according to the present disclosure may be formed of a photosensitive resin composition used to form the partition wall.

用以形成間隔壁的感光性樹脂組成物Photosensitive resin composition for forming partition walls

根據本揭露之用以形成間隔壁的感光性樹脂組成物可包含著色劑(colorant)、鹼溶性樹脂(alkali-soluble resin)、光聚合性化合物(photopolymerizable compound)、光聚合起始劑(photopolymerization initiator)與溶劑,且必要時可更包含添加劑(additive),但本揭露不以此為限。The photosensitive resin composition used to form partition walls according to the present disclosure may include a colorant, an alkali-soluble resin, a photopolymerizable compound, and a photopolymerization initiator. ) and solvents, and may further contain additives if necessary, but the present disclosure is not limited thereto.

著色劑Colorants

根據本揭露之感光性樹脂組成物中的著色劑可包含白色顏料(pigment)。The colorant in the photosensitive resin composition according to the present disclosure may include white pigment.

白色顏料是為了用於影像顯示裝置的間隔壁之反射性,且具體而言可提升間隔壁之反射率(reflectance)。也就是說,白色顏料可藉由反射像素部分產生的光中指向間隔壁方向的光來提升亮度。The white pigment is used to improve the reflectivity of the partition walls of the image display device, and specifically can increase the reflectance of the partition walls. That is to say, the white pigment can improve the brightness by reflecting the light generated by the pixel portion toward the partition wall.

白色顏料較佳可具有150奈米(nm)至300 nm的平均粒徑(average particle diameter);當其平均粒徑小於150 nm時,會發生在380 nm至780 nm的區域(係為可見光區)的反射性減弱的問題;當其平均粒徑超過300 nm時,會發生可分散性(dispersibility)與儲存穩定性惡化的問題。The white pigment preferably has an average particle diameter of 150 nanometers (nm) to 300 nm; when the average particle diameter is less than 150 nm, it will occur in the region of 380 nm to 780 nm (visible light region) ) has the problem of weakened reflectivity; when its average particle size exceeds 300 nm, problems of deterioration in dispersibility and storage stability will occur.

在本揭露中,「平均粒徑」可為數目平均粒徑(number average particle diameter),例如,其可由場發射掃描式電子顯微鏡(field emission-scanning electron microscope; FE-SEM)或穿透式電子顯微鏡(transmission electron microscope; TEM)觀察到的影像得到。具體而言,其可透過從場發射掃描式電子顯微鏡或穿透式電子顯微鏡之觀測影像中提取多個樣品、測量這些樣品的直徑、以及計算算術平均數(arithmetic mean)而得到。In the present disclosure, the "average particle diameter" may be the number average particle diameter, which may be determined by, for example, a field emission-scanning electron microscope (FE-SEM) or a transmission electron microscope. The image observed by a microscope (transmission electron microscope; TEM) is obtained. Specifically, it can be obtained by extracting multiple samples from observation images of a field emission scanning electron microscope or a transmission electron microscope, measuring the diameters of these samples, and calculating an arithmetic mean.

當滿足上述條件,可使用本技術領域中已知的顏料作為白色顏料。在一或多個實施例中,可使用C.I. Pigment White 4、5、6、6:1、7、18、18:1、19、20、22、25、26、27、28、32等,且就反射效率與白度(whiteness)而言,C.I. Pigment White 6或22是較佳的,且C.I. Pigment White 6更佳。When the above conditions are satisfied, pigments known in the art can be used as the white pigment. In one or more embodiments, C.I. Pigment White 4, 5, 6, 6:1, 7, 18, 18:1, 19, 20, 22, 25, 26, 27, 28, 32, etc. may be used, and In terms of reflection efficiency and whiteness, C.I. Pigment White 6 or 22 is better, and C.I. Pigment White 6 is better.

可單獨使用這些白色顏料,或可混合使用這些白色顏料中的兩種或更多種。These white pigments may be used alone, or two or more of these white pigments may be mixed and used.

C.I. Pigment White 6包含的二氧化鈦(Titanium oxide; TiO 2)是廉價的,且由於其折射率(refractive index)高而具有優異的反射率,從而其可作為有效的白色著色劑,並且就白度而言具有金紅石(rutile)結構是較佳的。 CI Pigment White 6 contains titanium dioxide (Titanium oxide; TiO 2 ) which is cheap and has excellent reflectivity due to its high refractive index, making it an effective white colorant and excellent in whiteness. It is better to have a rutile structure.

作為白色顏料的二氧化鈦(TiO 2)可依據需要進行樹脂處理(resin treatment)、使用引入酸基或鹼基的顏料衍生物(pigment derivatives)等的表面處理、以聚合物等在顏料表面上進行的接枝處理(graft treatment)、使用硫酸霧化法等的霧化處理(atomization treatment)、使用有機溶劑或水以移除雜質的清潔處理、或使用離子交換法的離子雜質移除處理等。 Titanium dioxide (TiO 2 ), which is a white pigment, can be subjected to resin treatment (resin treatment), surface treatment using pigment derivatives (pigment derivatives) that introduce acidic or basic groups, etc., or polymers on the surface of the pigment as needed. Graft treatment, atomization treatment using sulfuric acid atomization method, cleaning treatment using organic solvent or water to remove impurities, or ionic impurity removal treatment using ion exchange method, etc.

二氧化鈦(TiO 2)可包含使用選自由氧化矽(silicon oxide; SiO 2)、氧化鋁(aluminum oxide; Al 2O 3)、氧化鋯(zirconium oxide; ZrO 2)與多種有機材料所組成的群組中的一或更多者進行表面處理的二氧化鈦,較佳可包含使用氧化矽(SiO 2)、氧化鋁(Al 2O 3)與氧化鋯(ZrO 2)依序進行表面處理的二氧化鈦,更佳可包含使用有機材料對經表面處理的二氧化鈦(TiO 2)的最外表面進行表面處理而得到的二氧化鈦。有機材料沒有特別限制,只要是藉由低極性單分子層塗布二氧化鈦的表面處理來降低分散二氧化鈦(TiO 2)所需的能量,且可避免二氧化鈦壓縮(compressed)或凝聚(agglomerated)。在一或多個實施例中,硬脂酸(stearic acid)、三甲基丙烷(trimethylpropane; TMP)、季戊四醇(pentaerythritol)等可作為有機材料。 Titanium dioxide (TiO 2 ) may include a group selected from the group consisting of silicon oxide (SiO 2 ), aluminum oxide (Al 2 O 3 ), zirconium oxide (ZrO 2 ) and various organic materials. The titanium dioxide that is surface-treated with one or more of them preferably includes titanium dioxide that is surface-treated with silicon oxide (SiO 2 ), aluminum oxide (Al 2 O 3 ), and zirconium oxide (ZrO 2 ) in sequence, and more preferably Titanium dioxide obtained by surface-treating the outermost surface of surface-treated titanium dioxide (TiO 2 ) using an organic material may be included. The organic material is not particularly limited, as long as the energy required to disperse the titanium dioxide (TiO 2 ) is reduced by surface treatment of low-polarity monolayer-coated titanium dioxide, and the titanium dioxide is prevented from being compressed or agglomerated. In one or more embodiments, stearic acid, trimethylpropane (trimethylpropane; TMP), pentaerythritol, etc. can be used as organic materials.

可提升反射亮度特性,同時藉由如上述經表面處理的二氧化鈦來降低二氧化鈦的光催化活性(photocatalytic activity)。尤其,根據表面處理的較佳實施例,可具有改善可靠度之益處,例如耐熱性、耐化學性等。表面處理可以是藉由包覆(encapsulation)來處理。The reflective brightness characteristics can be improved and the photocatalytic activity of titanium dioxide can be reduced by surface-treated titanium dioxide as mentioned above. In particular, according to preferred embodiments of surface treatment, there may be benefits of improving reliability, such as heat resistance, chemical resistance, etc. Surface treatment can be through encapsulation.

經表面處理的二氧化鈦中包含的二氧化鈦核(core)的量較佳係為重量百分比85%至95%,基於經表面處理的二氧化鈦的總重量。當在上述範圍內處理二氧化鈦核的表面,經表面處理的二氧化鈦核展現出優異的白度與優異的反射亮度。The amount of titanium dioxide core contained in the surface-treated titanium dioxide is preferably 85% to 95% by weight, based on the total weight of the surface-treated titanium dioxide. When the surface of the titanium dioxide core is treated within the above range, the surface-treated titanium dioxide core exhibits excellent whiteness and excellent reflective brightness.

二氧化鈦的市售品的示例可包含杜邦公司(DuPont)的「R-101」、「R-102」、「R-103」、「R-104」、「R-105」、「R-350」、「R-706」、「R-794」、「R-796」、「TS-6200」、「R-900」、「R-902」、「R-902+」、「R-906」、「R-931」、「R-960」和「R-6200」、亨斯邁公司(Huntsman)的「R-FC5」、「TR81」和「TR88」、以及石原產業(ISK)的「CR-57」等。Examples of commercially available titanium dioxide products include "R-101", "R-102", "R-103", "R-104", "R-105", and "R-350" from DuPont , "R-706", "R-794", "R-796", "TS-6200", "R-900", "R-902", "R-902+", "R-906", "R-931", "R-960" and "R-6200", Huntsman's "R-FC5", "TR81" and "TR88", and Ishihara Sangyo (ISK)'s "CR- 57" and so on.

本揭露之著色劑可更包含選自黑色顏料、紅色顏料與橘色顏料中的一或更多者。The colorant of the present disclosure may further include one or more selected from black pigments, red pigments and orange pigments.

可使用本技術領域中已知的顏料作為黑色顏料,在一或多個實施例中可使用内醯胺黑(lactam black)、苝黑(perylene black)、氰黑(cyanine black)、苯胺黑(aniline black)、碳黑(carbon black)、鈦黑(titanium black)等,且可單獨使用這些顏料,或可混合使用這些顏料中的兩種或更多種。As the black pigment, pigments known in the art can be used. In one or more embodiments, lactam black, perylene black, cyanine black, aniline black ( aniline black), carbon black (carbon black), titanium black (titanium black), etc., and these pigments may be used alone, or two or more of these pigments may be mixed and used.

黑色顏料可依據需要使用樹脂進行表面處理。表面處理方法沒有特別限制,例如,可使用具有OH基的化合物、具有COOH基的化合物及/或聚矽氧(silicone)化合物對碳黑的表面進行表面處理。在一實施例中,能夠和聚矽氧烷(polysiloxane)鍵結的基團的示例可表示為(Si-O) n,其可依需要形成標記的主鏈或環、及/或和氧鍵結的矽烷(silane)化合物,包含氫、烷基(alkyl group)、乙烯基(vinyl group)、芳基(aryl group)、烷芳基(alkylaryl group)、芳烷基(aralkyl group)等。 The black pigment can be surface treated with resin as needed. The surface treatment method is not particularly limited. For example, the surface of the carbon black can be surface treated using a compound having an OH group, a compound having a COOH group, and/or a polysilicone compound. In one embodiment, an example of a group that can be bonded to polysiloxane can be expressed as (Si-O) n , which can form a labeled main chain or ring, and/or bond with oxygen as needed. The bonded silane compound includes hydrogen, alkyl group, vinyl group, aryl group, alkylaryl group, aralkyl group, etc.

黑色顏料的市售品的示例可包含三菱公司(Mitsubishi)的「MA77」、「MA7」、「MA8」、「MA11」、「MA100」、「MA100R」、「MA100S」、「MA230」、「MA220」和「MA14」、巴斯夫公司(BASF)的「Paliogen Black L 0086」、「Lumogen Black L 0087」、「Lumogen Black L 0088」、「Sicopal Black L 0095」、「Paliogen Black L 0084」和「Irgaphor Black S 0100CF」等。Examples of commercially available black pigments include Mitsubishi's "MA77", "MA7", "MA8", "MA11", "MA100", "MA100R", "MA100S", "MA230", and "MA220" ” and “MA14”, BASF’s “Paliogen Black L 0086”, “Lumogen Black L 0087”, “Lumogen Black L 0088”, “Sicopal Black L 0095”, “Paliogen Black L 0084” and “Irgaphor Black S 0100CF" etc.

紅色顏料可選自二酮吡咯類(diketopyrrole-based)或二酮吡咯並吡咯類(diketopyrrolopyrrole-based)顏料、蒽醌類(anthraquinone-based)顏料、苝類(perylene-based)顏料與偶氮類(azo-based)顏料中的一或更多者,且具體而言可為選自由C.I. Pigment Red 9、97、81、105、122、123、144、149、150、155、166、168、171、175、176、177、179、180、185、192、202、208、209、214 、215、216、220、222、224、242、254、255、264、269、270和272所組成的群組中的一或更多者,但本揭露對此不特別加以限制。The red pigment may be selected from diketopyrrole-based or diketopyrrolopyrrole-based pigments, anthraquinone-based pigments, perylene-based pigments and azo pigments One or more of (azo-based) pigments, and specifically can be selected from C.I. Pigment Red 9, 97, 81, 105, 122, 123, 144, 149, 150, 155, 166, 168, 171 , 175, 176, 177, 179, 180, 185, 192, 202, 208, 209, 214, 215, 216, 220, 222, 224, 242, 254, 255, 264, 269, 270 and 272 One or more of the group, but this disclosure is not particularly limited to this.

橘色顏料可選自喹啉黃類(quinophthalone-based)顏料、異吲哚啉酮類(isoindolinone-based)顏料與二酮吡咯並吡咯類(diketopyrrolopyrrole-based)顏料中的一或更多者,且具體而言可為選自由C.I. Pigment orange 13、15、31、36、38、40、42、43、51、55、59、61、64、65和71所組成的群組中的一或更多者,但本揭露對此不特別加以限制。The orange pigment may be selected from one or more of quinophthalone-based pigments, isoindolinone-based pigments and diketopyrrolopyrrole-based pigments, And specifically, it can be one or more selected from the group consisting of C.I. Pigment orange 13, 15, 31, 36, 38, 40, 42, 43, 51, 55, 59, 61, 64, 65 and 71 Many, but this disclosure does not specifically limit this.

著色劑的含量可為重量百分比0.5%至30%,較佳可為重量百分比1.0%至20%,基於感光性樹脂組成物中的固體總重量。當著色劑的含量落在上述範圍內,其益處在於可進一步增加對光的光遮蔽性(light-shielding properties)。The content of the colorant may be 0.5% to 30% by weight, preferably 1.0% to 20% by weight, based on the total solid weight of the photosensitive resin composition. When the content of the colorant falls within the above range, the benefit is that the light-shielding properties against light can be further increased.

在本揭露中,感光性樹脂組成物中的固體總重量意指感光性樹脂組成物中除了溶劑以外的其餘成分的總重量。In the present disclosure, the total weight of solids in the photosensitive resin composition means the total weight of the remaining components in the photosensitive resin composition except the solvent.

鹼溶性樹脂alkali soluble resin

鹼溶性樹脂用以藉由塗布顏料粒子來避免感光性樹脂組成物中的顏料粒子溶解於溶劑中,且用以避免顏料粒子之間的凝聚(agglomeration)造成的黏度(viscosity)增加。The alkali-soluble resin is used to prevent the pigment particles in the photosensitive resin composition from dissolving in the solvent by coating the pigment particles, and to avoid an increase in viscosity caused by agglomeration between the pigment particles.

鹼溶性樹脂沒有特別限制,但可包含由以下化學式1所表示的共聚物(copolymer)。The alkali-soluble resin is not particularly limited, but may include a copolymer represented by the following Chemical Formula 1.

[化學式1] [Chemical formula 1]

(在化學式1中,R 1和R 2各自獨立地為氫或甲基(methyl group),且單體a和單體b的莫耳比率(molar ratio)為1:20至20:1。) (In Chemical Formula 1, R 1 and R 2 are each independently hydrogen or a methyl group, and the molar ratio of monomer a and monomer b is 1:20 to 20:1.)

在本揭露中,包含以上化學式1之共聚物(包括環氧基)作為鹼溶性樹脂可提升耐溶劑性(solvent resistance)、儲存穩定性與殘膜率(residual film rate)。In the present disclosure, the copolymer (including epoxy group) of the above Chemical Formula 1 as an alkali-soluble resin can improve solvent resistance, storage stability and residual film rate.

鹼溶性樹脂的重量平均分子量沒有特別限制,但可為3,000至100,000,較佳為3,000至50,000,且更佳為5,000至50,000。The weight average molecular weight of the alkali-soluble resin is not particularly limited, but may be 3,000 to 100,000, preferably 3,000 to 50,000, and more preferably 5,000 to 50,000.

基於固體含量,鹼溶性樹脂具有50至200 mg KOH/g的酸價(acid value),且在上述範圍內可改善顏料的分散穩定性(dispersion stability)。Based on the solid content, the alkali-soluble resin has an acid value of 50 to 200 mg KOH/g, and can improve the dispersion stability of the pigment within the above range.

鹼溶性樹脂可為具有可和由以上化學式1所表示的共聚物共聚合(copolymerizable)的其他單體之共聚物。The alkali-soluble resin may be a copolymer having other monomers copolymerizable with the copolymer represented by Chemical Formula 1 above.

可和化學式1共聚合的鹼溶性樹脂之單體之具體示例可包含:芳香族乙烯基化合物類(aromatic vinyl compounds),例如苯乙烯(styrene)、乙烯基甲苯(vinyltoluene)、 -甲基苯乙烯( -methylstyrene)、對氯苯乙烯(p-chlorostyrene)、鄰甲氧基苯乙烯(o-methoxystyrene)、間甲氧基苯乙烯(m-methoxystyrene)、對甲氧基苯乙烯(p-methoxystyrene)、鄰乙烯基苄基甲基醚(o-vinylbenzylmethylether)、間乙烯基苄基甲基醚(m-vinylbenzylmethylether)、對乙烯基苄基甲基醚(p-vinylbenzylmethylether)、鄰乙烯基苄基縮水甘油醚(o-vinylbenzylglycidylether)、間乙烯基苄基縮水甘油醚(m-vinylbenzylglycidylether)和對乙烯基苄基縮水甘油醚(p-vinylbenzylglycidylether);烷基(甲基)丙烯酸酯類(alkyl(meth)acrylates),例如甲基(甲基)丙烯酸酯(methyl(meth)acrylate)、乙基(甲基)丙烯酸酯(ethyl(meth)acrylate)、n-丙基(甲基)丙烯酸酯(n-propyl(meth)acrylate)、i-丙基(甲基)丙烯酸酯(i-propyl(meth)acrylate)、n-丁基(甲基)丙烯酸酯(n-butyl(meth)acrylate)、i-丁基(甲基)丙烯酸酯(i-butyl(meth)acrylate)、二級丁基(甲基)丙烯酸酯(sec-butyl(meth)acrylate)和t-丁基(甲基)丙烯酸酯(t-butyl(meth)acrylate);脂環(甲基)丙烯酸酯類(alicyclic(meth)acrylates),例如環戊基(甲基)丙烯酸酯(cyclopentyl(meth)acrylate)、環己基(甲基)丙烯酸酯(cyclohexyl(meth)acrylate)、2-甲基環己基(甲基)丙烯酸酯(2-methylcyclohexyl(meth)acrylate)、三環[5.2.1.0(2,6)]癸烷-8-基(甲基)丙烯酸酯(tricyclo[5.2.1.0(2,6)]decan-8-yl (meth)acrylate)、2-二環戊氧基乙基(甲基)丙烯酸酯(2-dicyclopentanyloxyethyl(meth)acrylate)和異冰片(甲基)丙烯酸酯(isobornyl(meth)acrylate);芳基(甲基)丙烯酸酯類(aryl(meth)acrylates),例如苯基(甲基)丙烯酸酯(phenyl(meth)acrylate)和苄基(甲基)丙烯酸酯(benzyl(meth)acrylate);羥烷基(甲基)丙烯酸酯類(hydroxyalkyl(meth)acrylates),例如2-羥乙基(甲基)丙烯酸酯(2-hydroxyethyl(meth)acrylate)和2-羥丙基(甲基)丙烯酸酯(2-hydroxypropyl(meth)acrylate);N取代的順丁烯二醯亞胺化合物類(N-substituted maleimide compounds),例如N-環己基順丁烯二醯亞胺(N-cyclohexylmaleimide)、N-苄基順丁烯二醯亞胺(N-benzylmaleimide)、N-苯基順丁烯二醯亞胺(N-phenylmaleimide)、N-鄰羥基苯基順丁烯二醯亞胺(N-o-hydroxyphenylmaleimide)、N-間羥基苯基順丁烯二醯亞胺(N-m-hydroxyphenylmaleimide)、N-對羥基苯基順丁烯二醯亞胺(N-p-hydroxyphenylmaleimide)、N-鄰甲基苯基順丁烯二醯亞胺(N-o-methylphenylmaleimide)、N-間甲基苯基順丁烯二醯亞胺(N-m-methylphenylmaleimide)、N-對甲基苯基順丁烯二醯亞胺(N-p-methylphenylmaleimide)、N-鄰甲氧基苯基順丁烯二醯亞胺(N-o-methoxyphenylmaleimide)、N-間甲氧基苯基順丁烯二醯亞胺(N-m-methoxyphenylmaleimide)和N-對甲氧基苯基順丁烯二醯亞胺(N-p-methoxyphenylmaleimide);不飽和醯胺化合物類(unsaturated amide compounds),例如(甲基)丙烯醯胺((meth)acrylamide)和N,N-二甲基(甲基)丙烯醯胺(N,N-dimethyl(meth)acrylamide);不飽和氧雜環丁烷化合物類(unsaturated oxetane compounds),例如3-(甲基丙烯醯氧甲基)氧雜環丁烷(3-(methacryloyloxymethyl)oxetane)、3-(甲基丙烯醯氧甲基)-3-乙基氧雜環丁烷(3-(methacryloyloxymethyl)-3-ethyloxetane)、3-(甲基丙烯醯氧甲基)-2-三氟甲基氧雜環丁烷(3-(methacryloyloxymethyl)-2-trifluoromethyloxetane)、3-(甲基丙烯醯氧甲基)-2-苯基氧雜環丁烷(3-(methacryloyloxymethyl)-2-phenyloxetane)、2-(甲基丙烯醯氧甲基)氧雜環丁烷(2-(methacryloyloxymethyl)oxetane)和2-(甲基丙烯醯氧甲基)-4-三氟甲基氧雜環丁烷(2-(methacryloyloxymethyl)-4-trifluoromethyloxetane)等。 Specific examples of the monomer of the alkali-soluble resin copolymerizable with Chemical Formula 1 may include: aromatic vinyl compounds, such as styrene, vinyltoluene, -Methyl styrene ( -methylstyrene), p-chlorostyrene, o-methoxystyrene, m-methoxystyrene, p-methoxystyrene, o-vinylbenzylmethylether (o-vinylbenzylmethylether), m-vinylbenzylmethylether (m-vinylbenzylmethylether), p-vinylbenzylmethylether (p-vinylbenzylmethylether), o-vinylbenzylglycidyl ether (o-vinylbenzylglycidylether), m-vinylbenzylglycidylether (m-vinylbenzylglycidylether) and p-vinylbenzylglycidylether (p-vinylbenzylglycidylether); alkyl (meth)acrylates (alkyl(meth)acrylates) , such as methyl(meth)acrylate, ethyl(meth)acrylate, n-propyl(meth)acrylate )acrylate), i-propyl(meth)acrylate, n-butyl(meth)acrylate, i-butyl(meth)acrylate i-butyl(meth)acrylate), secondary butyl(meth)acrylate(sec-butyl(meth)acrylate) and t-butyl(meth)acrylate(t-butyl(meth)acrylate) ) acrylate); alicyclic (meth) acrylates (alicyclic (meth) acrylates), such as cyclopentyl (meth) acrylate (cyclopentyl (meth) acrylate), cyclohexyl (meth) acrylate (cyclohexyl ( meth)acrylate), 2-methylcyclohexyl(meth)acrylate, tricyclo[5.2.1.0(2,6)]decan-8-yl(meth)acrylic acid Ester (tricyclo[5.2.1.0(2,6)]decan-8-yl (meth)acrylate), 2-dicyclopentanyloxyethyl(meth)acrylate (2-dicyclopentanyloxyethyl(meth)acrylate) and isoester isobornyl(meth)acrylate; aryl(meth)acrylates, such as phenyl(meth)acrylate and benzyl benzyl(meth)acrylate; hydroxyalkyl(meth)acrylates, such as 2-hydroxyethyl(meth)acrylate meth)acrylate) and 2-hydroxypropyl(meth)acrylate; N-substituted maleimide compounds, such as N-cyclic Hexylmaleimide (N-cyclohexylmaleimide), N-benzylmaleimide (N-benzylmaleimide), N-phenylmaleimide (N-phenylmaleimide), N- No-hydroxyphenylmaleimide (No-hydroxyphenylmaleimide), N-m-hydroxyphenylmaleimide (Nm-hydroxyphenylmaleimide), N-p-hydroxyphenylmaleimide ( Np-hydroxyphenylmaleimide), N-o-methylphenylmaleimide (No-methylphenylmaleimide), N-m-methylphenylmaleimide (Nm-methylphenylmaleimide), N-p-methyl Phenylmaleimide (Np-methylphenylmaleimide), N-methoxyphenylmaleimide (No-methoxyphenylmaleimide), N-m-methoxyphenylmaleimide Amine (Nm-methoxyphenylmaleimide) and N-p-methoxyphenylmaleimide (Np-methoxyphenylmaleimide); unsaturated amide compounds, such as (meth)acrylamide (( meth)acrylamide) and N,N-dimethyl(meth)acrylamide (N,N-dimethyl(meth)acrylamide); unsaturated oxetane compounds, such as 3-( Methacryloyloxymethyl)oxetane (3-(methacryloyloxymethyl)oxetane), 3-(methacryloyloxymethyl)-3-ethyloxetane (3-(methacryloyloxymethyl)- 3-ethyloxetane), 3-(methacryloyloxymethyl)-2-trifluoromethyloxetane (3-(methacryloyloxymethyl)-2-trifluoromethyloxetane), 3-(methacryloxymethyl) )-2-phenyloxetane (3-(methacryloyloxymethyl)-2-phenyloxetane), 2-(methacryloyloxymethyl)oxetane (2-(methacryloyloxymethyl)oxetane) and 2- (Methacryloyloxymethyl)-4-trifluoromethyloxetane (2-(methacryloyloxymethyl)-4-trifluoromethyloxetane) and the like.

可各自單獨使用以上舉例說明的化合物,或可混合使用以上舉例說明的化合物中的兩種或更多種。The above-exemplified compounds may each be used alone, or two or more of the above-exemplified compounds may be used in mixture.

本揭露之鹼溶性樹脂可依據需要和本技術領域中常用的各種其他已知的鹼溶性樹脂進一步混合使用。The alkali-soluble resin of the present disclosure can be further mixed with various other known alkali-soluble resins commonly used in this technical field as needed.

鹼溶性樹脂的含量可為重量百分比20%至70%,較佳可為重量百分比30%至60%,基於感光性樹脂組成物中的固體總重量。當鹼溶性樹脂的含量落在上述範圍內,顏料粒子均勻分散,且可避免顏料粒子之間的凝聚,從而具有提升耐溶劑性與儲存穩定性之益處。The content of the alkali-soluble resin may be 20% to 70% by weight, preferably 30% to 60% by weight, based on the total solid weight of the photosensitive resin composition. When the content of the alkali-soluble resin falls within the above range, the pigment particles are evenly dispersed and aggregation between the pigment particles can be avoided, thus having the benefits of improving solvent resistance and storage stability.

光聚合性化合物photopolymerizable compound

光聚合性化合物係為可藉由光和熱來聚合的化合物,可在沒有特別限制下選擇與使用本技術領域中已知的聚合性化合物,只要其可藉由光和熱來聚合,且其具體示例可包含單官能單體(monofunctional monomer)、雙官能單體(bifunctional monomer)、另一多官能單體(polyfunctional monomer)等。The photopolymerizable compound is a compound that can be polymerized by light and heat, and polymerizable compounds known in the art can be selected and used without particular restrictions, as long as they can be polymerized by light and heat, and their Specific examples may include a monofunctional monomer, a bifunctional monomer, another polyfunctional monomer, and the like.

單官能單體、雙官能單體與多官能單體的類型沒有特別限制,且多官能單體的示例可包含三羥甲基丙烷三(甲基)丙烯酸酯(trimethylolpropane tri(meth)acrylate)、乙氧基化三羥甲基丙烷三(甲基)丙烯酸酯(ethoxylated trimethylolpropane tri(meth)acrylate)、丙氧基化三羥甲基丙烷三(甲基)丙烯酸酯)丙烯酸酯(propoxylated trimethylolpropane tri(meth)acrylate)、新戊四醇三(甲基)丙烯酸酯(pentaerythritol tri(meth)acrylate)、新戊四醇四(甲基)丙烯酸酯(pentaerythritol tetra(meth)acrylate)、二新戊四醇三(甲基)丙烯酸酯(dipentaerythritol tri(meth)acrylate)、二新戊四醇五(甲基)丙烯酸酯(dipentaerythritol penta(meth)acrylate)、乙氧基化二新戊四醇六(甲基)丙烯酸酯(ethoxylated dipentaerythritol hexa(meth)acrylate)、丙氧基化二新戊四醇六(甲基)丙烯酸酯(propoxylated dipentaerythritol hexa(meth)acrylate)、二新戊四醇六(甲基)丙烯酸酯(dipentaerythritol hexa(meth)acrylate)等。The types of monofunctional monomers, difunctional monomers and multifunctional monomers are not particularly limited, and examples of multifunctional monomers may include trimethylolpropane tri(meth)acrylate, Ethoxylated trimethylolpropane tri(meth)acrylate, propoxylated trimethylolpropane tri(meth)acrylate meth)acrylate), pentaerythritol tri(meth)acrylate, pentaerythritol tetra(meth)acrylate, dineopenterythritol dipentaerythritol tri(meth)acrylate, dipentaerythritol penta(meth)acrylate, ethoxylated dipentaerythritol hexa(meth)acrylate ) Acrylate (ethoxylated dipentaerythritol hexa(meth)acrylate), propoxylated dipentaerythritol hexa(meth)acrylate (propoxylated dipentaerythritol hexa(meth)acrylate), dipentaerythritol hexa(meth)acrylate Ester (dipentaerythritol hexa(meth)acrylate) etc.

光聚合性化合物的含量可為重量百分比5%至50%,較佳可為重量百分比10%至45%,基於感光性樹脂組成物中的固體總重量。就像素部分的強度或平滑度而言,光聚合性化合物的含量落在上述範圍內是較佳的。The content of the photopolymerizable compound may be 5% to 50% by weight, preferably 10% to 45% by weight, based on the total solid weight of the photosensitive resin composition. In terms of the intensity or smoothness of the pixel portion, it is preferable that the content of the photopolymerizable compound falls within the above range.

光聚合起始劑Photopolymerization initiator

作為光聚合起始劑,可在沒有特別限制下選擇與使用本技術領域已知的光聚合起始劑。光聚合起始劑的示例可包含苯乙酮類(acetophenone-based)化合物、二苯基酮類(benzophenone-based)化合物、三[口井]類(triazine-based)化合物、噻噸酮類(thioxanthone-based)化合物、肟類(oxime-based)化合物、安息香類(benzoin-based)化合物、聯咪唑類(biimidazole-based)化合物等,且光聚合起始劑的市售品的示例可包含汽巴精化公司(Ciba)的「OXE-01」、「OXE-02」和「OXE-03」、巴斯夫公司(BASF)的IRGACURE OXE-03等。As the photopolymerization initiator, photopolymerization initiators known in the art can be selected and used without particular limitations. Examples of photopolymerization initiators may include acetophenone-based compounds, benzophenone-based compounds, triazine-based compounds, thioxanthone-based compounds thioxanthone-based compounds, oxime-based compounds, benzoin-based compounds, biimidazole-based compounds, etc., and examples of commercially available photopolymerization initiators may include steam Ciba's "OXE-01", "OXE-02" and "OXE-03", BASF's IRGACURE OXE-03, etc.

可單獨使用這些光聚合起始劑,或可混合使用這些光聚合起始劑中的兩種或更多種。These photopolymerization initiators may be used alone, or two or more of these photopolymerization initiators may be used in mixture.

光聚合起始劑的含量可為重量百分比0.01%至15%,較佳可為重量百分比0.1%至10%,基於感光性樹脂組成物中的固體總重量。當光聚合起始劑的含量落在上述範圍內,光聚合反應速率恰當,此可較佳地避免總處理時間(process time)增加且可避免光反應導致最終固化膜的物理性質劣化。The content of the photopolymerization initiator may be 0.01% to 15% by weight, preferably 0.1% to 10% by weight, based on the total solid weight in the photosensitive resin composition. When the content of the photopolymerization initiator falls within the above range, the photopolymerization reaction rate is appropriate, which can better avoid an increase in the total processing time and avoid deterioration of the physical properties of the final cured film caused by the photoreaction.

根據本揭露之感光性樹脂組成物除了包含光聚合起始劑之外還可包含光聚合引發助劑(photopolymerization initiation aid)。當光聚合引發助劑和光聚合起始劑一起使用,感光性樹脂組成物變得更加敏感,此可較佳地提升產率。The photosensitive resin composition according to the present disclosure may further include a photopolymerization initiation aid in addition to the photopolymerization initiator. When a photopolymerization initiating assistant and a photopolymerization initiator are used together, the photosensitive resin composition becomes more sensitive, which can better improve the yield.

光聚合引發助劑係為用以促進光聚合性化合物之聚合的化合物,光聚合性化合物之聚合由光聚合起始劑引發,且可使用選自由胺(amines)與羧酸(carboxylic acid)化合物所組成的群組中的一或更多化合物作為光聚合引發助劑。The photopolymerization initiating assistant is a compound used to promote the polymerization of the photopolymerizable compound. The polymerization of the photopolymerizable compound is initiated by the photopolymerization initiator, and a compound selected from amines and carboxylic acid can be used. One or more compounds in the group serve as photopolymerization initiating assistants.

光聚合引發助劑的含量一般可為0.001莫耳(mole)至10莫耳,較佳可為0.01莫耳至5莫耳,基於1莫耳的光聚合起始劑。當光聚合引發助劑的含量落在上述範圍內,透過提升光聚合效率可期待產率的提升效果。The content of the photopolymerization initiating assistant can generally be 0.001 mole to 10 mole, preferably 0.01 mole to 5 mole, based on 1 mole of the photopolymerization initiator. When the content of the photopolymerization initiating assistant falls within the above range, the productivity improvement effect can be expected by increasing the photopolymerization efficiency.

溶劑Solvent

溶劑沒有特別限制,只要其可溶解感光性樹脂組成物中的其他成分,且可使用感光性樹脂組成物的領域中已知的各種有機溶劑。The solvent is not particularly limited as long as it can dissolve other components in the photosensitive resin composition, and various organic solvents known in the field of photosensitive resin compositions can be used.

在一或多個實施例中,溶劑的示例可包含:乙二醇單烷基醚類(ethylene glycol monoalkyl ethers),例如乙二醇單甲基醚(ethylene glycol monomethyl ether)、乙二醇單乙基醚(ethylene glycol monoethyl ether)、乙二醇單丙基醚(ethylene glycol monopropyl ether)和乙二醇單丁基醚(ethylene glycol monobutyl ether);二乙二醇二烷基醚類(diethylene glycol dialkyl ethers),例如二乙二醇二甲基醚(diethylene glycol dimethyl ether)、二乙二醇二乙基醚(diethylene glycol diethyl ether)、二乙二醇二丙基醚(diethylene glycol dipropyl ether)和二乙二醇二丁基醚(diethylene glycol dibutyl ether);乙二醇烷基醚乙酸酯類(ethylene glycol alkyl ether acetates),例如乙酸甲賽璐蘇(methyl cellosolve acetate)和乙酸乙賽璐蘇(ethyl cellosolve acetate);烷基二醇烷基醚乙酸酯類(alkylene glycol alkyl ether acetates),例如丙二醇單甲基醚乙酸酯(propylene glycol monomethyl ether acetate)、丙二醇單乙基醚乙酸酯(propylene glycol monoethyl ether acetate)、丙二醇單丙基醚乙酸酯(propylene glycol monopropyl ether acetate)、甲氧基丁基乙酸酯(methoxybutyl acetate)和甲氧基戊基乙酸酯(methoxypentyl acetate);芳香碳氫化合物類(aromatic hydrocarbons),例如苯(benzene)、甲苯(toluene)、二甲苯(xylene)和均三甲苯(mesitylene);酮類(ketones),例如甲基乙基酮(methyl ethyl ketone)、丙酮(acetone)、甲基戊基酮(methyl amyl ketone)、甲基異丁基酮(methyl isobutyl ketone)和環己酮(cyclohexanone);醇類(alcohols),例如乙醇(ethanol)、丙醇(propanol)、丁醇(butanol)、己醇(hexanol)、環己醇(cyclohexanol)、乙二醇(ethylene glycol)和甘油(glycerin);酯類(esters),例如3-乙氧基丙酸乙酯(ethyl 3-ethoxypropionate)和3-甲氧基丙酸甲酯(methyl 3-methoxypropionate);環狀酯類(cyclic esters),例如 -丁內酯( -butyrolactone)等。 In one or more embodiments, examples of solvents may include: ethylene glycol monoalkyl ethers, such as ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, etc. ethylene glycol monoethyl ether, ethylene glycol monopropyl ether and ethylene glycol monobutyl ether; diethylene glycol dialkyl ethers), such as diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol dipropyl ether and diethylene glycol dimethyl ether. Diethylene glycol dibutyl ether; ethylene glycol alkyl ether acetates, such as methyl cellosolve acetate and ethyl cellosolve acetate); alkylene glycol alkyl ether acetates, such as propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate (propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate, methoxybutyl acetate, and methoxypentyl acetate; aromatic hydrocarbons Aromatic hydrocarbons, such as benzene, toluene, xylene, and mesitylene; ketones, such as methyl ethyl ketone, acetone (acetone), methyl amyl ketone (methyl amyl ketone), methyl isobutyl ketone (methyl isobutyl ketone) and cyclohexanone (cyclohexanone); alcohols (alcohols), such as ethanol (ethanol), propanol (propanol) ), butanol, hexanol, cyclohexanol, ethylene glycol and glycerin; esters, such as ethyl 3-ethoxypropionate (ethyl 3-ethoxypropionate) and methyl 3-methoxypropionate; cyclic esters, such as -Butyrolactone ( -butyrolactone) etc.

就塗布性(coatability)與乾燥性而言,溶劑較佳可為具有100 至200 的沸點的有機溶劑,且更佳可為丙二醇單甲基醚乙酸酯、丙二醇單乙基醚乙酸酯、環己酮、乳酸乙酯(ethyl lactate)、乳酸丁酯(butyl lactate)、3-乙氧基丙酸乙酯、3-甲氧基丙酸甲酯等。 In terms of coatability and drying properties, a solvent with 100% to 200 Organic solvents with a boiling point, and more preferably propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, cyclohexanone, ethyl lactate, butyl lactate, 3 -Ethyl ethoxypropionate, methyl 3-methoxypropionate, etc.

可單獨使用這些溶劑,或可混合使用這些溶劑中的兩種或更多種,且溶劑的含量可為重量百分比60%至90%,較佳可為重量百分比70%至85%,基於感光性樹脂組成物的總重量。當溶劑的含量落在上述範圍內,較佳地可提升使用例如輥塗機(roll coater)、旋轉塗布機(spin coater)、狹縫-旋轉塗布機(slit and spin coater)、狹縫塗布機(slit coater)(模塗機(die coater))等塗布裝置或噴墨來分布溶劑的適用性(applicability)。These solvents may be used alone, or two or more of these solvents may be mixed, and the content of the solvent may be 60% to 90% by weight, preferably 70% to 85% by weight, based on photosensitivity The total weight of the resin composition. When the content of the solvent falls within the above range, it is preferable to use a roll coater, a spin coater, a slit and spin coater, or a slot coater. The applicability of coating devices such as (slit coater) (die coater) or inkjet to distribute the solvent.

添加劑additives

根據本揭露之感光性樹脂組成物必要時還可包含添加劑,且添加劑的種類可依據使用者的需求決定,本揭露對添加劑的種類沒有特別限制。The photosensitive resin composition according to the present disclosure may also contain additives if necessary, and the types of additives can be determined according to the user's needs. The present disclosure does not specifically limit the types of additives.

在一或多個實施例中,可使用選自分散劑(dispersant)、潤溼劑(wetting agent)、矽烷偶合劑(silane coupling agent)和抗凝聚劑(anti-agglomeration agent)中的至少一者。In one or more embodiments, at least one selected from the group consisting of a dispersant, a wetting agent, a silane coupling agent, and an anti-agglomeration agent may be used.

可使用市售的界面活性劑作為分散劑,界面活性劑的示例可包含聚矽氧類界面活性劑(silicone-based surfactant)、氟類界面活性劑(fluorine-based surfactant)、具有氟原子的聚矽氧類界面活性劑、以及其混合物。Commercially available surfactants can be used as dispersants. Examples of surfactants may include silicone-based surfactants, fluorine-based surfactants, polysiloxane surfactants with fluorine atoms, etc. Silicone surfactants, and mixtures thereof.

聚矽氧類界面活性劑的示例可包含具有矽氧烷鍵(siloxane bond)的界面活性劑等。其市售品的示例可包含Toray Silicone公司(Toray Silicone Co., Ltd.)生產的「Toray Silicon DC3PA」、「Toray Silicon SH7PA」、「Toray Silicon DC11PA」、「Toray Silicon SH21PA」、「Toray Silicon SH28PA」、「Toray Silicon 29SHPA」、「Toray Silicon SH30PA」、以及聚醚改質矽氧油「SH8400」、信越矽利光股份有限公司(Shin-Etsu Silicone Co., Ltd.)生產的「KP321」、「KP322」、「KP323」、「KP324」、「KP326」、「KP340」和「KP341」、GE Toshiba Silicon公司(GE Toshiba Silicon Co., Ltd.)生產的「TSF400」、「TSF401」、「TSF410」、「TSF4300」、「TSF4440」、「TSF4445」、「TSF-4446」、「TSF4452」和「TSF4460」等。Examples of polysiloxane-based surfactants may include surfactants having siloxane bonds and the like. Examples of commercially available products include "Toray Silicon DC3PA", "Toray Silicon SH7PA", "Toray Silicon DC11PA", "Toray Silicon SH21PA", and "Toray Silicon SH28PA" produced by Toray Silicone Co., Ltd. ", "Toray Silicon 29SHPA", "Toray Silicon SH30PA", and polyether modified silicone oil "SH8400", "KP321" produced by Shin-Etsu Silicone Co., Ltd., " KP322", "KP323", "KP324", "KP326", "KP340" and "KP341", "TSF400", "TSF401", "TSF410" produced by GE Toshiba Silicon Co., Ltd. , "TSF4300", "TSF4440", "TSF4445", "TSF-4446", "TSF4452" and "TSF4460", etc.

氟類界面活性劑的示例可包含具有氟碳鏈的界面活性劑等。其市售品的示例可包含Sumitomo 3M公司(Sumitomo 3M Co., Ltd.)生產的「Prolinate (產品名) FC430」和「Prolinate FC431」、Dainippon Ink Chemical公司(Dainippon Ink Chemical Co., Ltd.)生產的「Megapack (產品名) F142D」、「Megapack F171」、「Megapack F172」、「Megapack F173」、「Megapack F177」、「Megapack F183」和「Megapack R30」、Shin-Akita Kasei公司(Shin-Akita Kasei Co., Ltd.)生產的「Ftop (產品名) EF301」、「Ftop EF303」、「Ftop EF351」和「Ftop EF352」、旭硝子公司(Asahi Glass Co., Ltd.)生產的「Suffron (產品名) S381」、「Suffron S382」、「Suffron SC101」和「Suffron SC105」、Daikin Fine Chemicals公司(Daikin Fine Chemicals Co., Ltd.)生產的「E5844」、BMChemie公司(BMChemie)生產的「BM-1000」和「BM-1100」(產品名)等。Examples of the fluorine-based surfactant may include surfactants having a fluorocarbon chain and the like. Examples of commercially available products include "Prolinate (product name) FC430" and "Prolinate FC431" produced by Sumitomo 3M Co., Ltd., Dainippon Ink Chemical Co., Ltd. "Megapack (product name) F142D", "Megapack F171", "Megapack F172", "Megapack F173", "Megapack F177", "Megapack F183" and "Megapack R30" are manufactured by Shin-Akita Kasei Corporation (Shin-Akita "Ftop (product name) EF301", "Ftop EF303", "Ftop EF351" and "Ftop EF352" manufactured by Kasei Co., Ltd.), "Suffron (product name) manufactured by Asahi Glass Co., Ltd. Name) S381", "Suffron S382", "Suffron SC101" and "Suffron SC105", "E5844" produced by Daikin Fine Chemicals Co., Ltd., "BM- 1000" and "BM-1100" (product name), etc.

具有氟原子的聚矽氧類界面活性劑的示例可包含具有矽氧烷鍵與氟碳鏈的界面活性劑等。其市售品的示例可包含Dainippon Ink Chemical公司(Dainippon Ink Chemicals Co., Ltd.)生產的「Megapack (產品名) R08」、「Megapack BL20」、「Megapack F475」、「Megapack F477」和「Megapack F443」。Examples of polysiloxane-based surfactants having fluorine atoms may include surfactants having siloxane bonds and fluorocarbon chains, and the like. Examples of commercially available products include "Megapack (product name) R08", "Megapack BL20", "Megapack F475", "Megapack F477" and "Megapack" produced by Dainippon Ink Chemicals Co., Ltd. F443".

作為潤溼劑,可使用甘油(glycerin)、二伸乙甘醇(diethylene glycol)和乙二醇(ethylene glycol),且可單獨使用這些潤溼劑,或可混合使用這些潤溼劑中的兩種或更多種。As the wetting agent, glycerin, diethylene glycol, and ethylene glycol can be used, and these wetting agents can be used alone, or two of these wetting agents can be mixed and used. species or more.

矽烷偶合劑的示例可包含胺丙基三乙氧基矽烷(aminopropyltriethoxysilane)、 -巰丙基三甲氧基矽烷( -mercaptopropyltrimethoxysilane)和 -甲基丙烯醯氧基丙基三甲氧基矽烷( -methacryloxypropyltrimethoxysilane),其市售品的示例可包含Toray-Dow Corning Silicon公司(Toray-Dow Corning Silicon Co., Ltd.)生產的「SH6062」和「SZ6030」、信越矽利光股份有限公司(Shin-Etsu Silicone Co., Ltd.)生產的「KBE903」、「KBM803」和「KBM-9007」等。 Examples of silane coupling agents may include aminopropyltriethoxysilane, -Mercaptopropyltrimethoxysilane( -mercaptopropyltrimethoxysilane) and -Methacryloyloxypropyltrimethoxysilane( -methacryloxypropyltrimethoxysilane), examples of commercially available products include "SH6062" and "SZ6030" produced by Toray-Dow Corning Silicon Co., Ltd., Shin-Etsu Silicone Co., Ltd. "KBE903", "KBM803" and "KBM-9007" produced by Silicone Co., Ltd.).

抗凝聚劑的示例可包含聚丙烯酸鈉(sodium polyacrylate)。Examples of anti-agglomerating agents may include sodium polyacrylate.

本揭露之感光性樹脂組成物可以本技術領域中已知的傳統方法製備,且本揭露對製備方法沒有特別限制。The photosensitive resin composition of the present disclosure can be prepared by conventional methods known in the art, and the present disclosure has no particular limitations on the preparation method.

在本揭露的一實施例中,著色劑先和溶劑混合,且使用球磨機(bead mill)或類似物使其分散。此時,可依需要使用顏料分散劑,且亦可能混合部分或全部的鹼溶性樹脂。將剩餘的鹼溶性樹脂、光聚合性化合物與光聚合起始劑、以及添加劑(依需要添加)加入得到的分散物中之後,可依需求進一步添加額外的溶劑並加至預定濃度,以得到所需的感光性樹脂組成物。In one embodiment of the present disclosure, the colorant is first mixed with a solvent and dispersed using a bead mill or the like. At this time, a pigment dispersant may be used as necessary, and part or all of the alkali-soluble resin may also be mixed. After adding the remaining alkali-soluble resin, photopolymerizable compound, photopolymerization initiator, and additives (added as needed) to the obtained dispersion, additional solvents can be added as needed to a predetermined concentration to obtain the desired The required photosensitive resin composition.

製造用於影像顯示裝置的間隔壁之方法Method for manufacturing partition wall for image display device

此外,本揭露提供用以製造用於影像顯示裝置的間隔壁之方法。In addition, the present disclosure provides methods for manufacturing partition walls for image display devices.

根據本揭露之用以製造用於影像顯示裝置的間隔壁之方法可包含在基板上形成間隔壁的步驟,其中相對於間隔壁整體的厚度,間隔壁從最下端算起95%的厚度處的線寬係為A,間隔壁從最下端算起50%至90%的厚度處的最大線寬係為B,間隔壁從最下端算起10%的厚度處的線寬係為C,間隔壁滿足0.8 A/B < 1.0與0.85 C/B < 1.0。 The method for manufacturing a partition wall for an image display device according to the present disclosure may include a step of forming a partition wall on a substrate, wherein a thickness of 95% of the thickness of the partition wall from a lower end relative to the overall thickness of the partition wall is The line width is A, the maximum line width at 50% to 90% of the thickness of the partition wall from the bottom is B, the line width at 10% of the thickness of the partition from the bottom is C, the partition wall Meet 0.8 A/B < 1.0 and 0.85 C/B < 1.0.

A至C的意義、以及在滿足A/B與C/B之範圍的情況下的技術優點和上述用於影像顯示裝置的間隔壁的敘述內容中提及的那些相同。The meanings of A to C and the technical advantages when the ranges of A/B and C/B are satisfied are the same as those mentioned in the above description of the partition wall for the image display device.

在基板上形成間隔壁的步驟可包含:將感光性樹脂組成物施加於基板上然後進行加熱乾燥(heat drying)的塗布膜形成步驟;以紫外光照射形成的塗布膜的曝光步驟;使顯影劑(developer)接觸曝光的塗布膜以進行顯影的圖案形成步驟;以及使形成的圖案固化的後固化(post-curing)步驟。The step of forming the partition wall on the substrate may include: a coating film forming step of applying a photosensitive resin composition to the substrate and then performing heat drying; an exposing step of the formed coating film by ultraviolet light irradiation; using a developer (developer) A pattern forming step of contacting the exposed coating film for development; and a post-curing step of curing the formed pattern.

首先,將本揭露之感光性樹脂組成物施加於基板上,且然後進行加熱乾燥以移除揮發性成分,例如溶劑等,從而形成平滑塗布膜。First, the photosensitive resin composition of the present disclosure is applied to a substrate, and then heated and dried to remove volatile components, such as solvents, etc., thereby forming a smooth coating film.

可藉由例如旋轉塗布、可撓性塗布法(flexible coating method)、輥塗法、狹縫-旋轉塗布法或狹縫塗布法等塗布方法來進行塗布。在塗布之後,進行加熱乾燥(前烘烤)以使揮發性成分(例如溶劑)揮發。加熱乾燥後的塗布膜的厚度通常約7 m至15 m。此處對加熱乾燥沒有特別限制,但較佳係為在90 至100 之間進行120秒至180秒。當滿足加熱乾燥溫度與時間範圍,其益處在於可輕易製造出滿足A/B和C/B範圍之用於影像顯示裝置的間隔壁。 Coating can be performed by a coating method such as spin coating, flexible coating method, roller coating method, slot-spin coating method or slot coating method. After coating, heat drying (pre-baking) is performed to evaporate volatile components (such as solvents). The thickness of the coating film after heating and drying is usually about 7 m to 15 m. There are no special restrictions on heating and drying here, but it is preferably at 90 to 100 between 120 seconds and 180 seconds. When the heating and drying temperature and time ranges are met, the advantage is that partition walls for image display devices that meet the A/B and C/B ranges can be easily manufactured.

使紫外光通過遮罩照射以此方法得到的塗布膜,以形成目標圖案。照射紫外光時,藉由光聚合起始劑在紫外光照射的位置形成自由基(radicals),並藉由自由基和聚合性化合物反應以進行光固化。此時,較佳可使用例如遮罩對準機(mask aligner)或步進機(stepper)之裝置,以使平行光均勻地照射在整個曝光部分,且可進行遮罩與基板的精確定位。The coating film obtained in this way is irradiated with ultraviolet light through a mask to form a target pattern. When ultraviolet light is irradiated, the photopolymerization initiator forms free radicals (radicals) at the location where the ultraviolet light is irradiated, and the free radicals react with the polymerizable compound to perform photocuring. At this time, it is preferable to use a device such as a mask aligner or a stepper, so that the parallel light can be uniformly illuminated on the entire exposed part, and the mask and the substrate can be accurately positioned.

遮罩圖案可包含用以一體地形成像素部分與間隔壁的第一圖案、以及用以僅形成間隔壁的第二圖案。例如,第一圖案可以一圖案,在此圖案中,將要和間隔壁一體地形成的像素部分區域、以及相鄰間隔壁將要形成的區域一體地形成。The mask pattern may include a first pattern for integrally forming the pixel portion and the partition wall, and a second pattern for forming only the partition wall. For example, the first pattern may be a pattern in which a pixel partial area to be formed integrally with the partition wall and an area where adjacent partition walls are to be formed are integrally formed.

g射線(g-rays)(波長436 nm)、h射線(h-rays)、i射線(i-rays)(波長365 nm)等可用作紫外光。可依需求適當地選擇紫外光輻照度(irradiance),本揭露對此不加以限制。G-rays (wavelength 436 nm), h-rays (h-rays), i-rays (wavelength 365 nm), etc. can be used as ultraviolet light. The ultraviolet irradiance can be appropriately selected according to requirements, and this disclosure is not limited.

可藉由使顯影劑接觸光固化完全的塗布膜以溶解未曝光部分並進行顯影,以形成間隔壁。此處對顯影劑沒有特別限制,只要其為本技術領域中的常用者,但可使用具有1,100 s/m至1,300 s/m的導電度之顯影劑。此外,形成間隔壁的步驟沒有特別限制,但較佳係為藉由在1.0 mpa至1.3 mpa的壓力下噴塗顯影劑來進行。當滿足顯影劑的導電度與壓力範圍,其益處在於可輕易製造出滿足A/B和C/B範圍之用於影像顯示裝置的間隔壁。The partition walls can be formed by contacting the developer with the fully photocured coating film to dissolve the unexposed portions and develop the film. The developer is not particularly limited here as long as it is commonly used in the technical field, but a developer having a conductivity of 1,100 s/m to 1,300 s/m may be used. In addition, the step of forming the partition walls is not particularly limited, but is preferably performed by spraying the developer at a pressure of 1.0 to 1.3 mpa. When the conductivity and pressure range of the developer are met, the advantage is that partition walls for image display devices that meet the A/B and C/B ranges can be easily manufactured.

如此獲得的圖案形狀可通過後固化處理來變硬。此處,後固化步驟通常在150 至250 下進行於5分鐘至35分鐘,但較佳可在200 至220 下進行於30分鐘至35分鐘。當滿足後固化溫度與時間範圍,其益處在於可輕易製造出滿足A/B和C/B範圍之用於影像顯示裝置的間隔壁。 The pattern shape thus obtained can be hardened by a post-curing process. Here, the post-cure step is usually at 150 to 250 The next step is 5 minutes to 35 minutes, but preferably 200 minutes. to 220 Continue for 30 to 35 minutes. When the post-curing temperature and time ranges are met, the advantage is that partition walls for image display devices that meet the A/B and C/B ranges can be easily manufactured.

影像顯示裝置Image display device

此外,本揭露提供包含用於影像顯示裝置的間隔壁之影像顯示裝置。簡而言之,根據本發明的影像顯示裝置可包含由上述用於形成間隔壁的感光性樹脂組成物形成的間隔壁。In addition, the present disclosure provides an image display device including a partition wall for the image display device. In short, the image display device according to the present invention may include partition walls formed of the above-mentioned photosensitive resin composition for forming partition walls.

具體而言,影像顯示裝置除了包含根據本揭露之用於以影像顯示裝置之間隔壁之外還可包含影像顯示裝置中通常包含的其他元件,例如光學膜等,但本揭露不以此為限。Specifically, in addition to the partitions between image display devices according to the present disclosure, the image display device may also include other components commonly included in image display devices, such as optical films, etc., but the disclosure is not limited thereto. .

影像顯示裝置之具體示例可包含多種顯示裝置,例如液晶顯示器(液晶顯示裝置(LCD))、有機電激發光(EL)顯示器(包含有機電激發光顯示裝置、有機發光二極體顯示器和量子點發光二極體顯示器(QLED))、無機發光二極體顯示器、液晶投影機、遊戲顯示裝置、用於行動電話等的可攜式終端之顯示裝置、用於數位相機的顯示裝置、用於汽車導航的顯示裝置等,但本揭露不以此為限。Specific examples of image display devices may include various display devices, such as liquid crystal displays (liquid crystal display devices (LCD)), organic electroluminescent (EL) displays (including organic electroluminescent display devices, organic light emitting diode displays and quantum dots). Light-emitting diode displays (QLED), inorganic light-emitting diode displays, liquid crystal projectors, game display devices, display devices for portable terminals such as mobile phones, display devices for digital cameras, and automobiles Navigation display device, etc., but the present disclosure is not limited to this.

當影像顯示裝置包含根據本揭露之用於影像顯示裝置的間隔壁時,其益處在於可提供具有優異的亮度與視角且在像素部分沒有缺陷之高品質影像顯示裝置。When the image display device includes the partition wall for the image display device according to the present disclosure, the advantage is that a high-quality image display device with excellent brightness and viewing angle and no defects in the pixel portion can be provided.

以下基於多個實施例更加詳細地描述本揭露,但以下揭露的本揭露之實施例僅為說明用途,本揭露之範圍不限於這些實施例。本揭露之範圍由申請專利範圍定義,而且本揭露包含在等同於申請專利範圍中定義之意義與範圍內的所有變化型。此外,除非另有說明,否則在以下實施例和比較例中表示含量的「%」和「份」是基於質量。The present disclosure will be described in more detail below based on multiple embodiments. However, the embodiments of the present disclosure disclosed below are for illustrative purposes only, and the scope of the present disclosure is not limited to these embodiments. The scope of the present disclosure is defined by the claimed scope, and the present disclosure includes all variations within the meaning and scope equivalent to that defined in the claimed claim. In addition, unless otherwise stated, "%" and "part" indicating content in the following examples and comparative examples are based on mass.

實施例Example

製備例:製備感光性樹脂組成物Preparation example: Preparation of photosensitive resin composition

根據下表1描述的成分與含量製備感光性樹脂組成物。The photosensitive resin composition was prepared according to the ingredients and contents described in Table 1 below.

[表1] (單位:重量份) 製備例1 製備例2 製備例3 製備例4 著色劑 A-1 8 7 5 5 A-2 - 1 - - A-3 - - 4 - A-4 - - - 4 鹼溶性樹脂 B 41 41 41 41 光聚合性化合物 C 42 42 41 41 光聚合起始劑 D 8.5 8.5 8.5 8.5 溶劑 E 300 300 300 300 添加劑 F 0.5 0.5 0.5 0.5 A-1:TiO 2(亨斯邁公司生產的TR-88) A-2:碳黑(三菱公司生產的MA100) A-3:C.I. Pigment Orange 64(科萊恩公司(Clariant)生產的PV Fast Orange H2GL) A-4:C.I. Pigment Red 177(巴斯夫公司生產的Cromophtal) B:3,4-epoxytricyclo[5.2.1.0 2,6]decan-9-yl acrylate/methacrylic acid copolymer(莫耳比率 = 60/40,Mw = 7200) C:二季戊四醇六丙烯酸酯(dipentaerythritol hexaacrylate)(日本化學公司(Nippon Chemical Co., Ltd.)生產的KAYARAD DPHA) D:IRGACURE OXE-03(巴斯夫公司生產) E:丙二醇甲醚乙酸酯(propylene glycol monomethyl ether acetate; PGMEA) F:矽烷偶合劑(信越矽利光股份有限公司生產的KBM-9007) [Table 1] (Unit: parts by weight) Preparation Example 1 Preparation Example 2 Preparation Example 3 Preparation Example 4 Colorants A-1 8 7 5 5 A-2 - 1 - - A-3 - - 4 - A-4 - - - 4 alkali soluble resin B 41 41 41 41 photopolymerizable compound C 42 42 41 41 Photopolymerization initiator D 8.5 8.5 8.5 8.5 Solvent E 300 300 300 300 additives F 0.5 0.5 0.5 0.5 A-1: TiO 2 (TR-88 produced by Huntsman Corporation) A-2: Carbon black (MA100 produced by Mitsubishi Corporation) A-3: CI Pigment Orange 64 (PV Fast Orange produced by Clariant) H2GL) A-4: CI Pigment Red 177 (Cromophtal produced by BASF) B: 3,4-epoxytricyclo[5.2.1.0 2,6 ]decan-9-yl acrylate/methacrylic acid copolymer (Molar ratio = 60/40 , Mw = 7200) C: dipentaerythritol hexaacrylate (KAYARAD DPHA produced by Nippon Chemical Co., Ltd.) D: IRGACURE OXE-03 (produced by BASF) E: Propylene glycol methyl ether Acetate (propylene glycol monomethyl ether acetate; PGMEA) F: Silane coupling agent (KBM-9007 produced by Shin-Etsu Silicone Co., Ltd.)

實施例Example 11 :製造間隔壁: Manufacturing partition wall

依序使用中性清潔劑、水與酒精清洗5公分 5公分玻璃基板(康寧公司(Corning Incorporated)),然後使其乾燥。為了形成間隔壁,將製備例1之感光性樹脂組成物旋轉塗布於玻璃基板上且最終膜厚度為10.0 m,在無塵烤箱中以90 前烘烤150秒。在經前烘烤的基板冷卻至室溫後,和石英玻璃光罩的距離設定為50 m,使用曝光機(Topcon公司生產的(Topcon Co., Ltd.) TME-150RSK)以100 mJ/cm 2的曝光量用光照射基板。此時的照射使用來自超高壓水銀燈的反射光。在此情況下,使用具有形成於相同平面上的圖案之光罩。用以形成間隔壁的遮罩的內部具有長方形阻擋部(未曝光部),光傳導部(圖案)具有作為間隔壁的直線相互交叉的形式。在照光後,使用壓力型(press-type)顯影機在1.0 mpa的壓力下噴塗水性顯影劑(導電度1100 s/m)以進行顯影處理,水性顯影劑包含重量百分比0.12%的非離子界面活性劑和重量百分比0.04%的氫氧化鉀。在使用水清洗後,在無塵烤箱中以210 後烘烤30分鐘,以形成間隔壁。 Use neutral detergent, water and alcohol in order to clean 5 cm 5 cm glass substrate (Corning Incorporated) and allowed to dry. In order to form partition walls, the photosensitive resin composition of Preparation Example 1 was spin-coated on a glass substrate with a final film thickness of 10.0 m, in a dust-free oven at 90 Bake for 150 seconds. After the pre-baked substrate is cooled to room temperature, the distance from the quartz glass mask is set to 50 m, using an exposure machine (TME-150RSK produced by Topcon Co., Ltd.) to irradiate the substrate with light at an exposure dose of 100 mJ/cm 2 . The irradiation at this time uses reflected light from an ultrahigh-pressure mercury lamp. In this case, a mask having patterns formed on the same plane is used. The mask for forming partition walls has a rectangular barrier portion (unexposed portion) inside, and the light conductive portion (pattern) has a form in which straight lines as partition walls intersect each other. After illumination, use a pressure-type developing machine to spray a water-based developer (conductivity 1100 s/m) at a pressure of 1.0 MPa for development. The water-based developer contains 0.12% by weight of non-ionic interface activity agent and 0.04% potassium hydroxide by weight. After cleaning with water, place in a dust-free oven at 210 Post-bake for 30 minutes to form dividers.

實施例Example 22 至實施例To the embodiment 1010 與比較例and comparative example 11 至比較例To comparative example 66 :製造間隔壁: Manufacturing partition wall

進行和實施例1相同的步驟以形成間隔壁,不同之處在於用於實施例1的製備例1之感光性樹脂組成物以及個別處理條件根據下表2中的組成物與條件修改。The same steps as in Example 1 were performed to form partition walls, except that the photosensitive resin composition and individual processing conditions used in Preparation Example 1 of Example 1 were modified according to the compositions and conditions in Table 2 below.

[表2] 實施例 比較例 1 2 3 4 5 6 7 8 9 10 1 2 3 4 5 6 感光性樹脂組成物 G-1 G-1 G-1 G-1 G-1 G-1 G-1 G-2 G-3 G-4 G-1 G-1 G-1 G-1 G-1 G-1 前烘烤溫度 ( ) 90 90 95 100 95 93 95 100 95 95 85 85 85 85 85 85 前烘烤時間 (秒) 150 180 180 150 120 165 155 145 135 130 100 100 120 85 90 110 顯影劑導電度 (m/s) 1100 1150 1300 1200 1200 1150 1130 1200 1180 1200 1700 1800 1750 1650 1600 1500 顯影劑壓力 (mpa) 1.0 1.1 1.3 1.1 1.1 1.0 1.3 1.1 1.1 1.1 0.8 0.9 0.8 0.8 0.9 0.9 後烘烤溫度 ( ) 210 220 210 200 220 220 210 200 220 220 240 240 235 240 240 235 後烘烤時間(分) 30 30 30 35 30 30 30 35 30 30 30 30 25 30 30 25 G-1:根據製備例1的感光性樹脂組成物 G-2:根據製備例2的感光性樹脂組成物 G-3:根據製備例3的感光性樹脂組成物 G-4:根據製備例4的感光性樹脂組成物 [Table 2] Example Comparative example 1 2 3 4 5 6 7 8 9 10 1 2 3 4 5 6 Photosensitive resin composition G-1 G-1 G-1 G-1 G-1 G-1 G-1 G-2 G-3 G-4 G-1 G-1 G-1 G-1 G-1 G-1 Pre-baking temperature ( ) 90 90 95 100 95 93 95 100 95 95 85 85 85 85 85 85 Pre-bake time (seconds) 150 180 180 150 120 165 155 145 135 130 100 100 120 85 90 110 Developer conductivity (m/s) 1100 1150 1300 1200 1200 1150 1130 1200 1180 1200 1700 1800 1750 1650 1600 1500 Developer pressure (mpa) 1.0 1.1 1.3 1.1 1.1 1.0 1.3 1.1 1.1 1.1 0.8 0.9 0.8 0.8 0.9 0.9 Post-baking temperature ( ) 210 220 210 200 220 220 210 200 220 220 240 240 235 240 240 235 Post-baking time (minutes) 30 30 30 35 30 30 30 35 30 30 30 30 25 30 30 25 G-1: Photosensitive resin composition based on Preparation Example 1 G-2: Photosensitive resin composition based on Preparation Example 2 G-3: Photosensitive resin composition based on Preparation Example 3 G-4: Based on Preparation Example 4 photosensitive resin composition

實驗例Experimental example

(1) 測量間隔壁的形狀(1) Measure the shape of the partition wall

對於根據實施例1至實施例10與比較例1至比較例6製造的間隔壁,使用FE-SEM設備(Hitachi的Regulus 8240)拍攝間隔壁的形狀,並測量個別間隔壁的厚度(D)與在特定厚度處的線寬(A至C)。結果示於下表3與第2至4圖。For the partition walls manufactured according to Examples 1 to 10 and Comparative Examples 1 to 6, FE-SEM equipment (Regulus 8240 of Hitachi) was used to photograph the shape of the partition walls, and the thickness (D) and thickness of the individual partition walls were measured. Line width at a specific thickness (A to C). The results are shown in Table 3 below and Figures 2 to 4.

線寬A代表從間隔壁的最下端算起95%的厚度處的線寬,線寬B代表從間隔壁的最下端算起50%至90%的厚度處的最大線寬,線寬C代表從間隔壁的最下端算起10%的厚度處的線寬。Line width A represents the line width at 95% of the thickness from the bottom end of the partition wall, line width B represents the maximum line width at 50% to 90% of the thickness from the bottom end of the partition wall, and line width C represents The line width at 10% of the thickness from the bottom of the partition wall.

[表3] 實施例 比較例 1 2 3 4 5 6 7 8 9 10 1 2 3 4 5 6 膜厚度D ( m) 10.2 10.1 10.3 10.2 10.5 10.5 10.3 10.4 10.5 10.5 9.8 10.1 10.2 10.5 11.3 10.5 線寬A ( m) 18.3 18.4 19.7 19.4 18.8 19.4 20.6 21.1 21.1 18.9 17.4 21.8 17.5 17.2 21.8 16.4 線寬B ( m) 22.2 21.6 22.8 22.4 21.3 21.8 22.5 23.1 23.1 20.8 23.1 21.5 21.9 23.1 21.5 21.9 線寬C ( m) 20.4 20.3 20.1 20.5 20.6 20.2 21.8 21.2 21.8 20.2 20.3 15.6 22.3 13.5 12.1 11.3 A/B 0.82 0.85 0.86 0.87 0.88 0.89 0.92 0.91 0.91 0.91 0.75 1.01 0.80 0.74 1.01 0.75 C/B 0.92 0.94 0.88 0.92 0.97 0.93 0.97 0.92 0.94 0.97 0.88 0.73 1.02 0.58 0.56 0.52 [table 3] Example Comparative example 1 2 3 4 5 6 7 8 9 10 1 2 3 4 5 6 Film thickness D ( m) 10.2 10.1 10.3 10.2 10.5 10.5 10.3 10.4 10.5 10.5 9.8 10.1 10.2 10.5 11.3 10.5 Line width A ( m) 18.3 18.4 19.7 19.4 18.8 19.4 20.6 21.1 21.1 18.9 17.4 21.8 17.5 17.2 21.8 16.4 Line width B ( m) 22.2 21.6 22.8 22.4 21.3 21.8 22.5 23.1 23.1 20.8 23.1 21.5 21.9 23.1 21.5 21.9 Line width C ( m) 20.4 20.3 20.1 20.5 20.6 20.2 21.8 21.2 21.8 20.2 20.3 15.6 22.3 13.5 12.1 11.3 A/B 0.82 0.85 0.86 0.87 0.88 0.89 0.92 0.91 0.91 0.91 0.75 1.01 0.80 0.74 1.01 0.75 C/B 0.92 0.94 0.88 0.92 0.97 0.93 0.97 0.92 0.94 0.97 0.88 0.73 1.02 0.58 0.56 0.52

(2) 評估亮度特性(2) Evaluate brightness characteristics

對於根據實施例1至實施例10與比較例1至比較例6的間隔壁,透過噴墨製程將20滴(每滴10皮升(pico-liter))紅色量子點墨水*注入由間隔壁定義的像素區域以形成像素。將功率消耗量30 mW的藍光光源引入像素以發出紅光,接著使用CAS 140CT(Instrument System)測量其亮度值。計算紅光亮度值和藍光光源的亮度值的比例(紅光亮度值/藍光光源的亮度值,%)並示於下表4。For the partition walls according to Examples 1 to 10 and Comparative Examples 1 to 6, 20 drops (10 pico-liters per drop) of red quantum dot ink* were injected into the partition walls defined by the inkjet process. pixel area to form a pixel. A blue light source with a power consumption of 30 mW is introduced into the pixel to emit red light, and then its brightness value is measured using CAS 140CT (Instrument System). The ratio of the red light brightness value to the brightness value of the blue light source (red light brightness value/brightness value of the blue light source, %) was calculated and shown in Table 4 below.

*紅色量子點墨水:紅色量子點墨水組成物包含紅色量子點、散射物質(TiO 2)、光聚合性化合物(DPHA)、以及光聚合起始劑(IRGACURE OXE-03)。 *Red quantum dot ink: The composition of red quantum dot ink contains red quantum dots, scattering material (TiO 2 ), photopolymerizable compound (DPHA), and photopolymerization initiator (IRGACURE OXE-03).

(3) 評估視角特性(3) Evaluate viewing angle characteristics

在影像顯示裝置的性質上,視角是非常重要的評估因素。In terms of the nature of image display devices, viewing angle is a very important evaluation factor.

在本揭露中,對於形成於「(2) 評估亮度特性」中的像素,透過逐漸改變基於前表面的角度(0 )來側量側表面的亮度值,透過檢查測得藍光光源的亮度值的50%時的角度來評估視角特性。結果示於下表4。 In this disclosure, for the pixels formed in "(2) Evaluating brightness characteristics", by gradually changing the angle based on the front surface (0 ) to measure the brightness value of the side surface, and evaluate the viewing angle characteristics by checking the angle at which 50% of the brightness value of the blue light source is measured. The results are shown in Table 4 below.

視角愈大,即便從側表面觀察,亮度也維持愈高。因此,可得到高品質影像顯示裝置。The wider the viewing angle, the higher the brightness remains even when viewed from the side surface. Therefore, a high-quality image display device can be obtained.

(4) 評估噴墨製程特性(4) Evaluate inkjet process characteristics

對於根據實施例1至實施例10與比較例1至比較例6的間隔壁,使用OmniJet 300(UniJet Co., Ltd.)將1滴(10皮升)白色墨水*滴入由間隔壁定義的像素區域,依據以下評估標準與第5圖的標準評估像素區域內的墨水的延展性與溼潤性。結果示於下表4。For the partition walls according to Examples 1 to 10 and Comparative Examples 1 to 6, use OmniJet 300 (UniJet Co., Ltd.) to drop 1 drop (10 picoliters) of white ink* into the space defined by the partition wall For the pixel area, evaluate the ductility and wettability of the ink in the pixel area based on the following evaluation criteria and the criteria in Figure 5. The results are shown in Table 4 below.

*白色墨水:白色墨水組成物包含散射物質(TiO2)、光聚合性化合物(DPHA)、以及光聚合起始劑(IRGACURE OXE-03)。*White ink: The white ink composition contains a scattering substance (TiO2), a photopolymerizable compound (DPHA), and a photopolymerization initiator (IRGACURE OXE-03).

噴墨製程特性的評估標準Evaluation criteria for inkjet process characteristics

:當滴入1滴時,墨水使間隔壁溼潤。 : When 1 drop is added, the ink moistens the partition wall.

:當滴入1滴時,墨水的尺寸為30 m或更大。 : When 1 drop is dropped, the size of the ink is 30 m or larger.

:當滴入1滴時,墨水的尺寸為20 m或更大且小於30 m。 : When 1 drop is dropped, the size of the ink is 20 m or greater and less than 30 m.

:當滴入1滴時,墨水的尺寸為10 m或更大且小於20 m。 : When 1 drop is dropped, the size of the ink is 10 m or greater and less than 20 m.

:當滴入1滴時,墨水的尺寸小於10 m。 : When 1 drop is dropped, the size of the ink is less than 10 m.

[表4] 實施例 比較例 1 2 3 4 5 6 7 8 9 10 1 2 3 4 5 6 亮度評估 (%) 86.5 86.9 84.8 85.9 87.5 88.2 89.2 87.9 91.3 91.8 82.4 81.5 68.4 81.2 83.4 84.5 視角 ( ) 64 68 62 66 68 62 69 58 60 62 48 42 35 55 45 51 噴墨製程特性 [Table 4] Example Comparative example 1 2 3 4 5 6 7 8 9 10 1 2 3 4 5 6 Brightness evaluation(%) 86.5 86.9 84.8 85.9 87.5 88.2 89.2 87.9 91.3 91.8 82.4 81.5 68.4 81.2 83.4 84.5 perspective ( ) 64 68 62 66 68 62 69 58 60 62 48 42 35 55 45 51 Inkjet process characteristics

參照上表4的結果,可證實使用本揭露之實施例1至實施例10的間隔壁(滿足0.8 A/B < 1.0和0.85 C/B < 1.0)形成的像素在亮度、視角與噴墨製程特性上皆展現優異效果。 Referring to the results in Table 4 above, it can be confirmed that using the partition walls of Examples 1 to 10 of the present disclosure (satisfying 0.8 A/B < 1.0 and 0.85 C/B < 1.0), the pixels formed exhibit excellent results in terms of brightness, viewing angle and inkjet process characteristics.

同時,可證實使用不滿足0.8 A/B < 1.0及/或0.85 C/B < 1.0的比較例1至比較例6的間隔壁形成的像素具有降低的亮度、視角與噴墨製程特性,且特別是具有大幅降低的視角與噴墨製程特性。 At the same time, it can be confirmed that the use does not satisfy 0.8 A/B < 1.0 and/or 0.85 The pixels formed by the partition walls of Comparative Examples 1 to 6 with C/B < 1.0 have reduced brightness, viewing angle, and inkjet process characteristics, and particularly have greatly reduced viewing angle and inkjet process characteristics.

A,B,C:線寬 D:厚度 A,B,C: line width D:Thickness

第1圖是用以說明根據本揭露一實施例之用於影像顯示裝置的間隔壁的形狀之剖面圖; 第2圖是根據本揭露之實施例1之用於影像顯示裝置的間隔壁之剖面SEM照片; 第3圖是根據本揭露之比較例2之用於影像顯示裝置的間隔壁之剖面SEM照片; 第4圖是根據本揭露之比較例3之用於影像顯示裝置的間隔壁之剖面SEM照片;及 第5圖係為評估本揭露之實施例中的噴墨特性的評估標準。 Figure 1 is a cross-sectional view illustrating the shape of a partition wall for an image display device according to an embodiment of the present disclosure; Figure 2 is a cross-sectional SEM photograph of a partition wall used in an image display device according to Embodiment 1 of the present disclosure; Figure 3 is a cross-sectional SEM photograph of a partition wall used in an image display device according to Comparative Example 2 of the present disclosure; Figure 4 is a cross-sectional SEM photograph of a partition wall used in an image display device according to Comparative Example 3 of the present disclosure; and Figure 5 is an evaluation standard for evaluating inkjet characteristics in embodiments of the present disclosure.

A,B,C:線寬 A,B,C: line width

D:厚度 D:Thickness

Claims (12)

一種用於影像顯示裝置的間隔壁,其中相對於該間隔壁整體的一厚度,該間隔壁從最下端算起95%的該厚度處的一線寬係為A,該間隔壁從最下端算起50%至90%的該厚度處的一最大線寬係為B,該間隔壁從最下端算起10%的該厚度處的一線寬係為C,該間隔壁滿足0.8 A/B < 1.0與0.85 C/B < 1.0。 A partition wall for an image display device, wherein relative to a thickness of the partition wall as a whole, a line width of 95% of the thickness of the partition wall from the bottom end is A, and the partition wall is A from the bottom end. The maximum line width at 50% to 90% of the thickness is B, the line width of the partition wall at 10% of the thickness from the bottom is C, and the partition wall satisfies 0.8 A/B < 1.0 and 0.85 C/B < 1.0. 如請求項1所述之間隔壁,其中B係為該間隔壁從最下端算起60%至80%的該厚度處的該最大線寬。The partition wall as described in claim 1, wherein B is the maximum line width at 60% to 80% of the thickness of the partition wall from the bottom end. 如請求項1所述之間隔壁,其中該間隔壁形成以定義多個像素區域。The partition wall as described in claim 1, wherein the partition wall is formed to define a plurality of pixel areas. 如請求項1所述之間隔壁,其中該間隔壁的該厚度係為8至12微米( m)。 The partition wall as claimed in claim 1, wherein the thickness of the partition wall is 8 to 12 microns ( m). 如請求項1所述之間隔壁,其中該間隔壁由一感光性樹脂組成物(photosensitive resin composition)形成,該感光性樹脂組成物包含一著色劑(colorant)、一鹼溶性樹脂(alkali-soluble resin)、一光聚合性化合物(photopolymerizable compound)、一光聚合起始劑(photopolymerization initiator)與一溶劑。The partition wall according to claim 1, wherein the partition wall is formed of a photosensitive resin composition, and the photosensitive resin composition includes a colorant, an alkali-soluble resin resin), a photopolymerizable compound, a photopolymerization initiator and a solvent. 如請求項5所述之間隔壁,其中該感光性樹脂組成物包含: 基於該感光性樹脂組成物的一固體總重量, 重量百分比0.5%至30%的該著色劑; 重量百分比20%至70%的該溶性樹脂; 重量百分比5%至50%的該光聚合性化合物;以及 重量百分比0.01%至10%的該光聚合起始劑, 且該感光性樹脂組成物包含: 基於該感光性樹脂組成物的一總重量,重量百分比60%至90%的該溶劑。 The partition wall as described in claim 5, wherein the photosensitive resin composition contains: Based on a total solid weight of the photosensitive resin composition, 0.5% to 30% by weight of the colorant; 20% to 70% by weight of the soluble resin; 5% to 50% by weight of the photopolymerizable compound; and 0.01% to 10% by weight of the photopolymerization initiator, And the photosensitive resin composition includes: Based on the total weight of the photosensitive resin composition, the solvent is 60% to 90% by weight. 一種用以製造用於影像顯示裝置的間隔壁之方法,包含在一基板上形成一間隔壁的一步驟, 其中相對於該間隔壁整體的一厚度,該間隔壁從最下端算起95%的該厚度處的一線寬係為A,該間隔壁從最下端算起50%至90%的該厚度處的一最大線寬係為B,該間隔壁從最下端算起10%的該厚度處的一線寬係為C,該間隔壁滿足0.8 A/B < 1.0與0.85 C/B < 1.0。 A method for manufacturing a partition wall for an image display device, including a step of forming a partition wall on a substrate, wherein 95% of the partition wall from a lower end is formed relative to a thickness of the entire partition wall. The line width at the thickness is A, the maximum line width at 50% to 90% of the thickness of the partition wall from the bottom end is B, and the maximum line width at 10% of the thickness of the partition wall from the bottom end is B The line width of is C, and the partition wall satisfies 0.8 A/B < 1.0 and 0.85 C/B < 1.0. 如請求項7所述之方法,其中形成該間隔壁的該步驟包含: 將一感光性樹脂組成物施加於該基板上然後進行加熱乾燥以形成一塗布膜的一塗布膜形成步驟; 以紫外光照射形成的該塗布膜以使該塗布膜曝光的一曝光步驟; 使一顯影劑(developer)接觸曝光的該塗布膜以進行顯影並形成一圖案的一圖案形成步驟;以及 使形成的該圖案固化的一後固化步驟。 The method of claim 7, wherein the step of forming the partition wall includes: A coating film forming step of applying a photosensitive resin composition to the substrate and then heating and drying to form a coating film; An exposure step of irradiating the formed coating film with ultraviolet light to expose the coating film; A pattern forming step of contacting a developer to the exposed coating film to develop and form a pattern; and A post-curing step to cure the formed pattern. 如請求項8所述之方法,其中該塗布膜形成步驟中的加熱乾燥係在90 至100 之間進行120秒至180秒。 The method according to claim 8, wherein the heating and drying in the coating film forming step is performed at 90 to 100 between 120 seconds and 180 seconds. 如請求項8所述之方法,其中該圖案形成步驟係在1.0 mpa至1.3 mpa的一壓力下噴塗(spraying)具有1,100 s/m至1,300 s/m的一導電度的該顯影劑。The method of claim 8, wherein the pattern forming step is spraying the developer having a conductivity of 1,100 s/m to 1,300 s/m under a pressure of 1.0 mpa to 1.3 mpa. 如請求項8所述之方法,其中該後固化步驟係在200 至220 之間進行30分鐘至35分鐘。 The method of claim 8, wherein the post-curing step is performed at 200 to 220 Do this for 30 to 35 minutes. 一種影像顯示裝置,包含如請求項1所述之間隔壁。An image display device including a partition wall as described in claim 1.
TW111122992A 2022-06-21 2022-06-21 Partition wall for image display device, method for manufacturing same, and image display device including partition wall TW202401047A (en)

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