TW202348860A - Elastic thermal insulation composite material characterized by having good elasticity, thermal insulation property and durability - Google Patents

Elastic thermal insulation composite material characterized by having good elasticity, thermal insulation property and durability Download PDF

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TW202348860A
TW202348860A TW111132966A TW111132966A TW202348860A TW 202348860 A TW202348860 A TW 202348860A TW 111132966 A TW111132966 A TW 111132966A TW 111132966 A TW111132966 A TW 111132966A TW 202348860 A TW202348860 A TW 202348860A
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Taiwan
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thermal insulation
elastic
composite material
melt
fiber
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TW111132966A
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Chinese (zh)
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簡榮富
彭忠山
邱秉瑜
鍾楷智
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新麗企業股份有限公司
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Priority to PCT/IB2022/061133 priority Critical patent/WO2023242627A1/en
Publication of TW202348860A publication Critical patent/TW202348860A/en

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Abstract

This invention provides the elastic thermal insulation composite material with good elasticity, thermal insulation property and durability. The elastic thermal insulation composite material includes a thermal insulation cotton layer and a melt-blown layer; the thermal insulation cotton layer has the unit weight ranging from 20 gsm to 300 gsm and contains thermal insulation fibers; and the melt-blown layer is located on the thermal insulation cotton layer, has the unit weight ranging from 15 gsm to 100 gsm, and contains melt-blown elastic fibers. Wherein, one part of the thermal insulation fibers and one part of the melt-blown elastic fibers are linked with each other at the interface of the thermal insulation cotton layer and the melt-blown layer. The melt-blown elastic fiber is made of raw or recycled polymer elastic material selected from a group consisting of thermoplastic polyurethane, thermoplastic polyester elastomer, polytrimethylene terephthalate and combinations thereof, and the diameter of the melt-blown elastic fiber is 0.1 [mu]m to 35 [mu]m.

Description

彈性保溫複合材料Elastic insulation composite material

本發明係關於一種彈性保溫複合材料,特別是關於一種具有良好拉伸彈性及壓縮回復率、保溫性及耐久性的彈性保溫複合材料。The present invention relates to an elastic thermal insulation composite material, in particular to an elastic thermal insulation composite material with good tensile elasticity, compression recovery rate, thermal insulation and durability.

目前市售的填充式織物,通常是先將表布和裡布依照版型剪出裁片,之後在各個裁片上依照預定版型車縫出複數個填充格,並在填充格內填充兼具輕盈、保溫特性的羽絨,最後再將填充了羽絨的裁片組裝成最後的成品。然而,羽絨的取得有人道問題的疑慮,因此,目前已開發多種人造纖維製造保溫棉材來替代羽絨,製造填充式織物。Currently on the market for padded fabrics, the surface fabric and lining fabric are usually cut into pieces according to the pattern, and then a plurality of filling grids are sewn on each piece according to the predetermined pattern, and the filling grids are filled with both. Down is lightweight and has thermal insulation properties, and finally the down-filled pieces are assembled into the final product. However, there are doubts about humane issues in obtaining down. Therefore, a variety of man-made fibers have been developed to make insulation cotton materials to replace down and make filled fabrics.

傳統的保溫棉材常以人造纖維編織成網,之後依照所需規格堆疊增厚而製得,這類保溫棉材可與表布和裡布一起車縫裁剪,便於加工。然而,保溫棉材的結構較為鬆散,欠缺彈性,雖然可混入膠或低熔點纖維進一步固型,甚至透過三維纖維或彈性纖維的比例調配製得具有一定拉伸彈性的彈性保溫棉材,但其結構上的強度仍有不足。因此,使用傳統保溫棉材所製成的保暖用衣料品或日用品的耐久性(如尺寸安定性)較差,水洗後容易變形,且保溫棉材的纖維可能會從表布、裡布的縫隙和車縫的針孔中跑出來(此現象俗稱跑毛)。因此,在長時間使用之後,填充於表布、裡布之間的保溫棉材的纖維量可能會因此逐漸減少。Traditional thermal insulation cotton materials are often made of man-made fibers woven into a mesh, which are then stacked and thickened according to the required specifications. This type of thermal insulation cotton material can be sewn and cut together with the surface fabric and lining fabric for easy processing. However, the structure of thermal insulation cotton is relatively loose and lacks elasticity. Although glue or low-melting point fibers can be mixed to further solidify the shape, elastic thermal insulation cotton with a certain stretch elasticity can even be produced through the proportion of three-dimensional fibers or elastic fibers, but its The structural strength is still insufficient. Therefore, thermal insulation clothing or daily necessities made of traditional thermal insulation cotton materials have poor durability (such as dimensional stability) and are easily deformed after washing, and the fibers of the thermal insulation cotton materials may come from the gaps and gaps in the surface and lining fabrics. The hair comes out of the sewing needle holes (this phenomenon is commonly known as hair loss). Therefore, after long-term use, the fiber content of the insulation cotton filled between the surface fabric and the lining fabric may gradually decrease.

此外,傳統保溫棉材的保溫特性與厚度有關,要達到一定的保溫值,往往也具有一定的厚度,較為厚重,不利於收納與摺疊攜帶。以目前市售產品來說,保溫棉材有的能作到輕薄,有的具有拉伸彈性,有的則具有高保溫值的特性等,但很難兼具各項優點於單一產品上。In addition, the thermal insulation characteristics of traditional thermal insulation cotton materials are related to thickness. To achieve a certain thermal insulation value, they often have a certain thickness, which is relatively heavy and is not conducive to storage, folding and carrying. Looking at the products currently on the market, some thermal insulation cotton materials can be made thin and light, some have stretch elasticity, and some have high thermal insulation value characteristics, etc. However, it is difficult to combine all the advantages in a single product.

由上可知,使用傳統保溫棉材製成的填充式織物,一般不具有拉伸彈性,且回復效果不佳,若要同時具有高保溫值之特性則織物會較為厚重,且耐久性不足。因此,實有需要開發一種具有輕薄性,且同時能兼具良好拉伸彈性、保溫效果及耐久性的彈性保溫複合材料,來改善目前市售保溫棉材的缺點,用以製備更加輕薄便攜、耐水洗的填充式織物。It can be seen from the above that filled fabrics made of traditional thermal insulation cotton materials generally do not have stretch elasticity and have poor recovery effects. If they want to have high thermal insulation value at the same time, the fabric will be thicker and less durable. Therefore, there is a real need to develop an elastic insulation composite material that is light and thin and has good tensile elasticity, insulation effect and durability to improve the shortcomings of currently commercially available insulation cotton materials and to produce thinner, lighter, more portable, and more durable insulation materials. Washable padded fabric.

有鑑於前述現有技術的不足之處,本發明的其中一目的係提供一種彈性保溫複合材料,其具有良好的保溫性,可降低填充式織物的重量及厚度,達到輕量化的效果;且具有良好的拉伸彈性及壓縮回復率,方便摺疊收納:此外更具有優異的耐久性、耐摩擦性,且於水洗後不易跑毛或縮水。In view of the above-mentioned shortcomings of the prior art, one of the purposes of the present invention is to provide an elastic thermal insulation composite material that has good thermal insulation properties and can reduce the weight and thickness of the filled fabric to achieve a lightweight effect; and has good thermal insulation properties. Excellent tensile elasticity and compression recovery rate, convenient for folding and storage: In addition, it has excellent durability and friction resistance, and is not easy to lint or shrink after washing.

為達上述目的,本發明係提供一種彈性保溫複合材料,其包含:一保溫棉層,其單位重量為20 克/平方公尺(grams per square meter,gsm)至300 gsm,且其包含一保溫纖維;以及一熔噴層,位於該保溫棉層之上,其單位重量為15 gsm至100 gsm,且其包含一熔噴彈性纖維;其中在該保溫棉層及該熔噴層之交界面,該保溫纖維的一部分及該熔噴彈性纖維的一部分相互連結,該熔噴彈性纖維之材料係為一原生或回收之高分子彈性材料,該高分子彈性材料選自由熱塑性聚氨酯(thermoplastic polyurethane,TPU)、熱塑性聚酯彈性體(thermoplastic polyester elastomer,TPEE)、聚對苯二甲酸丙二酯(polytrimethylene terephthalate,PTT)及其組合所組成的群組,且該熔噴彈性纖維之直徑為0.1微米(micrometer,μm)至35 μm。In order to achieve the above purpose, the present invention provides an elastic thermal insulation composite material, which includes: an insulation cotton layer, the unit weight of which is 20 grams per square meter (gsm) to 300 gsm, and which includes an insulation cotton layer. Fiber; and a melt-blown layer, located on the thermal insulation cotton layer, with a unit weight of 15 gsm to 100 gsm, and containing a melt-blown elastic fiber; wherein at the interface between the thermal insulation cotton layer and the melt-blown layer, A part of the insulation fiber and a part of the melt-blown elastic fiber are connected to each other. The material of the melt-blown elastic fiber is a virgin or recycled polymer elastic material. The polymer elastic material is selected from thermoplastic polyurethane (TPU). , a group consisting of thermoplastic polyester elastomer (TPEE), polytrimethylene terephthalate (PTT) and combinations thereof, and the diameter of the melt-blown elastic fiber is 0.1 micrometer , μm) to 35 μm.

在一些具體實施例中,該保溫棉層之單位重量為20 gsm至300 gsm、或25 gsm至250 gsm、或30 gsm至200 gsm、或35 gsm至150 gsm、或40 gsm至120 gsm、或45 gsm至100 gsm、或50 gsm至80 gsm、或55 gsm至60 gsm。In some specific embodiments, the unit weight of the thermal insulation cotton layer is 20 gsm to 300 gsm, or 25 gsm to 250 gsm, or 30 gsm to 200 gsm, or 35 gsm to 150 gsm, or 40 gsm to 120 gsm, or 45 gsm to 100 gsm, or 50 gsm to 80 gsm, or 55 gsm to 60 gsm.

在一些具體實施例中,該保溫纖維之材料係為一原生或回收之纖維材料,該纖維材料係選自由聚對苯二甲酸乙二酯(polyethylene terephthalate,PET)、聚對苯二甲酸丙二酯(polytrimethylene terephthalate,PTT)及其組合所組成的群組。In some specific embodiments, the material of the insulation fiber is a virgin or recycled fiber material, and the fiber material is selected from polyethylene terephthalate (PET), polypropylene terephthalate A group consisting of polytrimethylene terephthalate (PTT) and its combinations.

在一些具體實施例中,該保溫棉層是先將該保溫纖維經梳理機梳理、成型機交叉舖疊而成的纖維疊層,再將該纖維疊層經由針軋、水刺等方式進行交絡、藉由樹脂噴塗、及/或藉由該保溫纖維本身材料中的低融點纖維在烘箱熱處理後形成的結構體。In some specific embodiments, the thermal insulation cotton layer is a fiber laminate formed by first combing the thermal insulation fibers through a carding machine and cross-laying them with a forming machine, and then interlacing the fiber laminates through needle rolling, spunlace, etc. , a structure formed by resin spraying, and/or by oven heat treatment of low melting point fibers in the insulation fiber material itself.

在一些具體實施例中,該高分子彈性材料中包含一熱塑性聚氨酯,且該熱塑性聚氨酯的熔點範圍為150°C至190°C、或160°C至180°C、或170°C至180°C。在一些具體實施例中,該高分子彈性材料中包含一熱塑性聚氨酯,且該熱塑性聚酯彈性體的熔點範圍為210°C至240°C、或220°C至230°C。在一些具體實施例中,該高分子彈性材料中包含一熱塑性聚氨酯,且該聚對苯二甲酸丙二酯的熔點範圍為245°C至265°C、或255°C至260°C。In some embodiments, the polymer elastic material includes a thermoplastic polyurethane, and the melting point of the thermoplastic polyurethane ranges from 150°C to 190°C, or from 160°C to 180°C, or from 170°C to 180°C. C. In some embodiments, the polymer elastic material includes a thermoplastic polyurethane, and the melting point of the thermoplastic polyester elastomer ranges from 210°C to 240°C, or from 220°C to 230°C. In some embodiments, the polymer elastic material includes a thermoplastic polyurethane, and the melting point of the polytrimethylene terephthalate ranges from 245°C to 265°C, or from 255°C to 260°C.

在一些具體實施例中,該高分子彈性材料的熔噴溫度為150°C以上,或為160°C以上,或為170°C以上,或為180°C以上,或為190°C以上,或為200°C以上,或為210°C以上,或為220°C以上,或為230°C以上,或為240°C以上,或為250°C以上,或為260°C以上,或為265°C以上。In some specific embodiments, the melt-blown temperature of the polymer elastic material is above 150°C, or above 160°C, or above 170°C, or above 180°C, or above 190°C, Or above 200°C, or above 210°C, or above 220°C, or above 230°C, or above 240°C, or above 250°C, or above 260°C, or is above 265°C.

在一些具體實施例中,該熔噴層之單位重量為15 gsm至100 gsm、或20 gsm至90 gsm、或25 gsm至80 gsm、或30 gsm至70 gsm、或35 gsm至60 gsm、或40 gsm至55 gsm、或45 gsm至50 gsm。In some specific embodiments, the unit weight of the meltblown layer is 15 gsm to 100 gsm, or 20 gsm to 90 gsm, or 25 gsm to 80 gsm, or 30 gsm to 70 gsm, or 35 gsm to 60 gsm, or 40 gsm to 55 gsm, or 45 gsm to 50 gsm.

在一些具體實施例中,係藉由將該熔噴彈性纖維之材料透過配備有熔噴模頭的擠壓機熔融噴射,得出該熔噴彈性纖維,並將該保溫棉層輸送至該熔噴模頭下方,使該熔噴彈性纖維在該保溫棉層之上形成,而形成該熔噴層;因此,在該保溫棉層及該熔噴層之交界面,該熔噴彈性纖維的一部分會與該保溫纖維的一部分相互連結。在一些具體實施例中,該熔噴彈性纖維的一部分與該保溫纖維的一部分係藉由該熔噴彈性纖維於熔噴後與該保溫纖維接觸而相互黏連。In some specific embodiments, the melt-blown elastic fiber is obtained by melt-spraying the material of the melt-blown elastic fiber through an extruder equipped with a melt-blown die, and the insulation cotton layer is transported to the melt-blown elastic fiber. Under the spray die, the melt-blown elastic fiber is formed on the insulation cotton layer to form the melt-blown layer; therefore, at the interface between the insulation cotton layer and the melt-blown layer, a part of the melt-blown elastic fiber Will be interconnected with part of the insulation fiber. In some embodiments, a portion of the melt-blown elastic fiber and a portion of the insulation fiber are adhered to each other by contacting the melt-blown elastic fiber with the insulation fiber after melt-blown.

在一些具體實施例中,該熔噴彈性纖維之直徑為0.1 μm至35 μm、或0.2 μm至30 μm、或0.5 μm至25 μm、或1 μm至20 μm、或1.5 μm至25 μm、或2 μm至20 μm、或2.5 μm至15 μm、或3 μm至10 μm、或3.5 μm至5 μm。In some specific embodiments, the diameter of the melt-blown elastic fiber is 0.1 μm to 35 μm, or 0.2 μm to 30 μm, or 0.5 μm to 25 μm, or 1 μm to 20 μm, or 1.5 μm to 25 μm, or 2 μm to 20 μm, or 2.5 μm to 15 μm, or 3 μm to 10 μm, or 3.5 μm to 5 μm.

在本案說明書中,「原生」一詞係指該項材料先前並未製成任何產品,為原始材料。在本案說明書中,「回收」一詞係指該項材料是經工業生產之產品的下腳料或經資源回收得到的材料,並非原始材料。以最常見的回收聚酯材料為例,目前可製成纖維之再生聚酯材料的主要來源有兩類,一類為消費前(pre-consumer)和消費後(post-consumer)的聚酯紡織品;另一類為消費後的寶特瓶(PET瓶),這類聚酯材料回收後經過物理方法或化學方法再製成環保的再生纖維材料。In the description of this case, the word "virgin" means that the material has not been made into any products before and is a raw material. In the description of this case, the word "recycled" means that the material is the scraps of industrially produced products or the material obtained through resource recycling, and is not the original material. Taking the most common recycled polyester material as an example, there are currently two main sources of recycled polyester materials that can be made into fibers. One is pre-consumer and post-consumer polyester textiles; The other type is post-consumer PET bottles. This type of polyester material is recycled and made into environmentally friendly recycled fiber materials through physical or chemical methods.

在一些具體實施例中,本案之彈性保溫複合材料所包含的再生成分含量為20%以上(≥20%),符合GRS認證標準。在一些具體實施例中,本案之彈性保溫複合材料所包含的再生成分含量為30%以上(≥30%),或35%以上(≥35%)。In some specific embodiments, the elastic insulation composite material in this case contains a recycled component content of more than 20% (≥20%), which complies with GRS certification standards. In some specific embodiments, the elastic insulation composite material of this case contains a recycled component content of more than 30% (≥30%), or more than 35% (≥35%).

在一些具體實施例中,該保溫纖維之細度為0.8丹尼數 (Denier,D)至15 D、或1.0 D至10 D、或1.2 D至8 D、或1.4 D至6 D、或1.6 D至4 D、或1.8 D至3 D、或2.0 D至2.5 D。在一些具體實施例中,該保溫纖維之直徑為8 μm至150 μm、或10 μm至100 μm、或12 μm至80 μm、或14 μm至60 μm、或16 μm至40 μm、或18 μm至30 μm、或20 μm至25 μm。In some specific embodiments, the fineness of the thermal insulation fiber is 0.8 Denier (D) to 15 D, or 1.0 D to 10 D, or 1.2 D to 8 D, or 1.4 D to 6 D, or 1.6 D to 4 D, or 1.8 D to 3 D, or 2.0 D to 2.5 D. In some specific embodiments, the diameter of the insulation fiber is 8 μm to 150 μm, or 10 μm to 100 μm, or 12 μm to 80 μm, or 14 μm to 60 μm, or 16 μm to 40 μm, or 18 μm. to 30 μm, or 20 μm to 25 μm.

在一些具體實施例中,該保溫棉層可同時包含不同細度的保溫纖維。在一些具體實施例中,該不同細度的保溫纖維可為相同材料或不同材料。In some specific embodiments, the thermal insulation cotton layer may simultaneously contain thermal insulation fibers of different finenesses. In some specific embodiments, the insulation fibers of different finenesses may be the same material or different materials.

在一些具體實施例中,該保溫棉層進一步包含膠、低熔點纖維、或其組合。In some specific embodiments, the thermal insulation cotton layer further includes glue, low melting point fiber, or a combination thereof.

在一些具體實施例中,該低熔點纖維之材料為一雙組份纖維,該雙組份纖維之材料可為原生或回收之材料,包含聚乙烯(polyethylene,PE)、聚丙烯、聚對苯二甲酸乙二酯、聚對苯二甲酸乙二酯共聚物(PET copolymer,coPET)或其他類似聚合物。在一些具體實施例中,該雙組份纖維之材料包含兩種選自由聚乙烯、聚丙烯、聚對苯二甲酸乙二酯、聚對苯二甲酸乙二酯共聚物(PET copolymer,coPET)及其他類似聚合物所組成之群組的聚合物。在一些具體實施例中,該雙組份纖維為聚乙烯/聚對苯二甲酸乙二酯(PE/PET),聚對苯二甲酸乙二酯/聚對苯二甲酸乙二酯共聚物(PET/coPET),聚乙烯/聚丙烯(PE/PP),及其類似聚合物組合。在一些具體實施例中,聚對苯二甲酸乙二酯共聚物為PET與二羧酸的共聚酯,該二羧酸可選自脂肪族二羧酸和和芳香族二羧酸;其中該脂肪族二羧酸可為草酸、丙二酸、琥珀酸、己二酸等;該芳香族二羧酸可為間苯二甲酸、磺化間苯二酸(sulfoisophthalic acid)等。In some embodiments, the material of the low melting point fiber is a bicomponent fiber. The material of the bicomponent fiber can be a virgin or recycled material, including polyethylene (PE), polypropylene, and polyparaphenylene. Ethylene dicarboxylate, polyethylene terephthalate copolymer (PET copolymer, coPET) or other similar polymers. In some embodiments, the bicomponent fiber material includes two materials selected from the group consisting of polyethylene, polypropylene, polyethylene terephthalate, and polyethylene terephthalate copolymer (PET copolymer, coPET). and other similar polymers. In some specific embodiments, the bicomponent fiber is polyethylene/polyethylene terephthalate (PE/PET), polyethylene terephthalate/polyethylene terephthalate copolymer ( PET/coPET), polyethylene/polypropylene (PE/PP), and similar polymer combinations. In some specific embodiments, the polyethylene terephthalate copolymer is a copolyester of PET and dicarboxylic acid, and the dicarboxylic acid can be selected from aliphatic dicarboxylic acid and aromatic dicarboxylic acid; wherein the The aliphatic dicarboxylic acid can be oxalic acid, malonic acid, succinic acid, adipic acid, etc.; the aromatic dicarboxylic acid can be isophthalic acid, sulfoisophthalic acid, etc.

在一些具體實施例中,該低熔點纖維之材料的熔點範圍為110°C至170°C、或125°C至160°C、或140°C至150°C。In some specific embodiments, the melting point of the low-melting fiber material ranges from 110°C to 170°C, or from 125°C to 160°C, or from 140°C to 150°C.

在一些具體實施例中,該膠之材料係為水性壓克力樹脂或水性聚氨酯樹脂。在一些具體實施例中,該水性壓克力樹脂或水性聚氨酯樹脂之固成分為30%至50%。In some specific embodiments, the material of the glue is water-based acrylic resin or water-based polyurethane resin. In some specific embodiments, the solid content of the water-based acrylic resin or water-based polyurethane resin is 30% to 50%.

在一些具體實施例中,該彈性保溫複合材料之厚度為0.40公分(centimeter,cm)至2.8 cm、或0.60 cm至2.6 cm、或0.80 cm至2.4 cm、或1.0 cm至2.2 cm、或1.2 cm至2.0 cm、或1.4 cm至1.8 cm、或1.4 cm至1.6 cm。In some specific embodiments, the thickness of the elastic thermal insulation composite material is 0.40 centimeter (cm) to 2.8 cm, or 0.60 cm to 2.6 cm, or 0.80 cm to 2.4 cm, or 1.0 cm to 2.2 cm, or 1.2 cm to 2.0 cm, or 1.4 cm to 1.8 cm, or 1.4 cm to 1.6 cm.

在一些具體實施例中,該彈性保溫複合材料之保溫值/厚度為1.50克羅/公分 (CLO/cm)以上、或1.60 CLO/cm以上、或1.70 CLO/cm以上、或1.80 CLO/cm以上、或1.90 CLO/cm以上。前述保溫值係根據標準方法ASTM D1518測得。In some specific embodiments, the thermal insulation value/thickness of the elastic thermal insulation composite material is above 1.50 CLO/cm (CLO/cm), or above 1.60 CLO/cm, or above 1.70 CLO/cm, or above 1.80 CLO/cm , or above 1.90 CLO/cm. The aforementioned insulation values are measured according to standard method ASTM D1518.

在一些具體實施例中,該彈性保溫複合材料之根據標準方法ASTM D4770進行測試後,其測試結果為5級,顯示耐水洗性最佳。In some specific embodiments, after the elastic insulation composite material was tested according to the standard method ASTM D4770, the test result was level 5, indicating the best water washing resistance.

在一些具體實施例中,該彈性保溫複合材料根據標準方法ASTM D4770進行測試後,其測試結果為5級,顯示水洗後跑毛情況最少。In some specific embodiments, after the elastic insulation composite material was tested according to the standard method ASTM D4770, the test result was level 5, showing that the lint loss after washing was minimal.

在一些具體實施例中,該彈性保溫複合材料在水洗10次後,其縱向的水洗縮率為1.5%以下、或為1.0%以下、或為0.5%以下、或為0.2%以下。在一些具體實施例中,該彈性保溫複合材料在水洗10次後,其橫向的水洗縮率為2.5%以下、或為1.5%以下、或為0.5%以下、或為0.2%以下。前述水洗縮率係根據標準方法ASTM D4770測得。在本發明中,縱向(machine direction,MD)係為該保溫複合材捲對捲機械傳動的方向,橫向(cross direction,CD)則為與該縱向水平垂直90°的方向。In some specific embodiments, after being washed 10 times, the elastic thermal insulation composite material has a longitudinal washing shrinkage of less than 1.5%, or less than 1.0%, or less than 0.5%, or less than 0.2%. In some specific embodiments, after being washed 10 times, the elastic thermal insulation composite material has a transverse washing shrinkage of less than 2.5%, or less than 1.5%, or less than 0.5%, or less than 0.2%. The aforementioned washing shrinkage is measured according to the standard method ASTM D4770. In the present invention, the machine direction (MD) is the direction in which the thermal insulation composite material is rolled to roll mechanically, and the cross direction (CD) is the direction 90° perpendicular to the machine direction.

在一些具體實施例中,該彈性保溫複合材料之壓縮回復率為80%以上、或82%以上、或85%以上。前述壓縮回復率係根據標準方法ASTM D6571-01測得。In some specific embodiments, the elastic thermal insulation composite material has a compression recovery rate of more than 80%, or more than 82%, or more than 85%. The aforementioned compression recovery rate is measured according to the standard method ASTM D6571-01.

在一些具體實施例中,該彈性保溫複合材料之縱向的拉伸彈性為15%以上,且其橫向的拉伸彈性為20%以上。前述拉伸彈性係根據標準方法ASTM D2594測得。In some specific embodiments, the longitudinal tensile elasticity of the elastic thermal insulation composite material is more than 15%, and the transverse tensile elasticity is more than 20%. The aforementioned tensile elasticity is measured according to standard method ASTM D2594.

在一些具體實施例中,該彈性保溫複合材料之熔噴層的耐摩擦性可達10000轉以上無破損。前述彈性保溫複合材料之熔噴層的耐摩擦性係根據標準方法ASTM D4966-98進行馬丁代爾耐磨測試(Martindale Abrasion Test)而測得。In some specific embodiments, the friction resistance of the melt-blown layer of the elastic insulation composite material can reach more than 10,000 revolutions without damage. The friction resistance of the melt-blown layer of the elastic insulation composite material was measured by conducting the Martindale Abrasion Test according to the standard method ASTM D4966-98.

本發明之的彈性保溫複合材料可應用於各種填充式織物,例如衣料品、圍巾、棉被等。The elastic thermal insulation composite material of the present invention can be applied to various filled fabrics, such as clothing, scarves, quilts, etc.

透過下列詳細的實施方式及後附圖式的說明後,本發明的目的、優點及技術特徵當至為顯明。The objectives, advantages and technical features of the present invention will become apparent through the following detailed description of the embodiments and the accompanying drawings.

本發明之彈性保溫複合材料的製備Preparation of elastic thermal insulation composite materials of the present invention

如圖1及圖2所示,本發明之彈性保溫複合材料1包含一保溫棉層10及一熔噴層20,該保溫棉層10之單位重量為20 gsm至300 gsm,且其包含一保溫纖維11;該熔噴層20位於該保溫棉層10之上,且其單位重量為15 gsm至100 gsm,且其包含一熔噴彈性纖維21;其中在該保溫棉層10及該熔噴層20的交界面,該保溫纖維11的一部分及該熔噴彈性纖維21的一部分相互連結,且該熔噴彈性纖維21之材料係為一原生或回收之高分子彈性材料,該高分子彈性材料選自由熱塑性聚氨酯、熱塑性聚酯彈性體、聚對苯二甲酸丙二酯及其組合所組成的群組,且該熔噴彈性纖維之直徑為0.1 μm至35 μm。其中該熔噴彈性纖維21兩端或中段的空心圓係表示一熔噴彈性纖維21與另一熔噴彈性纖維21或一保溫纖維11的接點。As shown in Figures 1 and 2, the elastic thermal insulation composite material 1 of the present invention includes a thermal insulation cotton layer 10 and a melt-blown layer 20. The unit weight of the thermal insulation cotton layer 10 is 20 gsm to 300 gsm, and it includes a thermal insulation cotton layer 10. Fiber 11; the melt-blown layer 20 is located on the thermal insulation cotton layer 10, and its unit weight is 15 gsm to 100 gsm, and it contains a melt-blown elastic fiber 21; wherein the thermal insulation cotton layer 10 and the melt-blown layer At the interface 20, a part of the insulation fiber 11 and a part of the melt-blown elastic fiber 21 are connected to each other, and the material of the melt-blown elastic fiber 21 is a virgin or recycled polymer elastic material. The polymer elastic material is selected A group consisting of free thermoplastic polyurethane, thermoplastic polyester elastomer, polytrimethylene terephthalate and combinations thereof, and the diameter of the melt-blown elastic fiber is 0.1 μm to 35 μm. The hollow circles at both ends or in the middle of the melt-blown elastic fiber 21 represent the contact points between one melt-blown elastic fiber 21 and another melt-blown elastic fiber 21 or an insulation fiber 11 .

如圖3A所示,位於該保溫棉層10及該熔噴層20之交界面的部份該保溫纖維11及部分該熔噴彈性纖維21相互連結,其中該熔噴彈性纖維21兩端或中段的空心圓係表示一熔噴彈性纖維21與另一熔噴彈性纖維21或一保溫纖維11的接點。另如圖3B所示,位於該保溫棉層10及該熔噴層20之交界面的部份該保溫纖維11及部分該熔噴彈性纖維21相互連結並產生彈性,其中該熔噴彈性纖維21兩端的空心圓係表示一熔噴彈性纖維21與一保溫纖維11的接點,而波浪形雙箭頭係顯示該等熔噴彈性纖維21在該等保溫纖維11之間產生的彈性方向。As shown in Figure 3A, part of the insulation fiber 11 and part of the melt-blown elastic fiber 21 located at the interface of the insulation cotton layer 10 and the melt-blown layer 20 are connected to each other, where the two ends or middle section of the melt-blown elastic fiber 21 The hollow circle represents the contact point between one melt-blown elastic fiber 21 and another melt-blown elastic fiber 21 or an insulation fiber 11 . As shown in FIG. 3B , part of the insulation fiber 11 and part of the melt-blown elastic fiber 21 located at the interface of the insulation cotton layer 10 and the melt-blown layer 20 are connected to each other and generate elasticity, wherein the melt-blown elastic fiber 21 The hollow circles at both ends represent the contact points between a melt-blown elastic fiber 21 and an insulation fiber 11 , and the wavy double arrows indicate the elastic direction of the melt-blown elastic fibers 21 between the insulation fibers 11 .

如圖4所示,使用一熔噴設備100並以熱塑性聚氨酯來製備一位於該保溫棉層10上的熔噴層20。該熔噴設備100包含一擠壓機110、一輸送帶120及一負壓裝置130;該擠壓機110包含一熔噴模頭111;且該熔噴模頭111包含一原料出口112及兩個熱風出口113。As shown in FIG. 4 , a melt-blown equipment 100 is used to prepare a melt-blown layer 20 on the thermal insulation cotton layer 10 using thermoplastic polyurethane. The melt-blown equipment 100 includes an extruder 110, a conveyor belt 120 and a negative pressure device 130; the extruder 110 includes a melt-blown die head 111; and the melt-blown die head 111 includes a raw material outlet 112 and two 113 hot air outlets.

首先提供一保溫棉層10,其單位面積重量為40 gsm,該保溫棉層10包含30%至35%的3 D * 51 mm的再生PET纖維、30%至40%的1.2 D * 38 mm的再生PET纖維、10%至15%的2 D * 51 mm的低熔點纖維、以及15%至25%的水性壓克力樹脂。之後將熱塑性聚氨酯透過配備有熔噴模頭111的擠壓機110進行熔噴,熔噴溫度為150°C以上。其中該熱塑性聚氨酯從原料出口112噴出,得出直徑為0.1 μm至15 μm的熔噴彈性纖維21。將該保溫棉層10透過輸送帶120輸送至熔噴模頭111下方(空心實線箭頭顯示輸送帶方向),使熱塑性聚氨酯之熔噴彈性纖維21在該保溫棉層10上形成,並在該兩個熱風出口113出來的熱風、該負壓裝置130的負壓(空心虛線箭頭顯示負壓方向)輔助下,在該保溫棉層10上方形成一熔噴層20,其中一部分該熔噴彈性纖維21與位於該保溫棉層10表面之一部分該保溫纖維11相互黏連,而使該熔噴層20與該保溫棉層10緊密貼合,冷卻收捲後,即得出本發明之彈性保溫複合材料1,其中該熔噴層20的單位面積重量為40 gsm。Firstly, an insulation cotton layer 10 is provided with a unit area weight of 40 gsm. The insulation cotton layer 10 contains 30% to 35% of 3 D * 51 mm recycled PET fiber and 30% to 40% of 1.2 D * 38 mm. Recycled PET fiber, 10% to 15% 2 D * 51 mm low melting point fiber, and 15% to 25% water-based acrylic resin. The thermoplastic polyurethane is then melt-blown through an extruder 110 equipped with a melt-blown die 111, and the melt-blown temperature is above 150°C. The thermoplastic polyurethane is ejected from the raw material outlet 112 to obtain melt-blown elastic fiber 21 with a diameter of 0.1 μm to 15 μm. The thermal insulation cotton layer 10 is transported to the bottom of the melt-blown die head 111 through the conveyor belt 120 (the hollow solid arrow shows the direction of the conveyor belt), so that the melt-blown elastic fibers 21 of thermoplastic polyurethane are formed on the thermal insulation cotton layer 10, and on the With the help of the hot air from the two hot air outlets 113 and the negative pressure of the negative pressure device 130 (the hollow dotted arrow shows the negative pressure direction), a melt-blown layer 20 is formed above the insulation cotton layer 10, in which a part of the melt-blown elastic fiber 21 and the thermal insulation fiber 11 located on a part of the surface of the thermal insulation cotton layer 10 are mutually adhered to each other, so that the melt-blown layer 20 and the thermal insulation cotton layer 10 are closely adhered to each other. After cooling and rolling, the elastic thermal insulation composite of the present invention is obtained. Material 1, wherein the meltblown layer 20 has a weight per unit area of 40 gsm.

本發明之彈性保溫複合材料的特性Characteristics of the elastic thermal insulation composite material of the present invention

使用本發明之彈性保溫複合材料作為實施例1,其中保溫棉層之單位面積重量為40 gsm,熔噴層之單位面積重量為40 gsm,總單位面積重量為80 gsm。使用前述保溫棉層的材料但單位面積重量為80 gsm的保溫棉作為比較例1,相同材料但單位面積重量為40 gsm的保溫棉作為比較例2。The elastic thermal insulation composite material of the present invention is used as Example 1, in which the unit area weight of the insulation cotton layer is 40 gsm, the unit area weight of the melt-blown layer is 40 gsm, and the total unit area weight is 80 gsm. The insulation cotton made of the aforementioned insulation cotton layer but with a unit area weight of 80 gsm was used as Comparative Example 1, and the insulation cotton of the same material but with a unit area weight of 40 gsm was used as Comparative Example 2.

另外亦使用彈性保溫棉進行比較。所用的彈性保溫棉包含66%至54%的3 D * 51 mm的再生PET纖維、14%至16%的2 D * 51 mm的再生PET纖維、以及20%至30%的水性壓克力樹脂。分別使用單位面積重量為80 gsm、40 gsm的彈性保溫棉作為比較例3、4。In addition, elastic insulation cotton was used for comparison. The elastic insulation cotton used contains 66% to 54% 3 D * 51 mm recycled PET fiber, 14% to 16% 2 D * 51 mm recycled PET fiber, and 20% to 30% water-based acrylic resin . Elastic insulation cotton with a weight per unit area of 80 gsm and 40 gsm was used as Comparative Examples 3 and 4 respectively.

依照以下標準方法,測試實施例1及比較例1至4的各項性質。 1. 單位面積重量:根據標準方法ASTM D3776進行測試。 2. 厚度:根據Invista Method進行測試。 3. 保溫值:根據標準方法ASTM D1518進行測試,所得數值為克羅值(CLO value),單位即為克羅(CLO)。 4. 耐水洗性:根據標準方法ASTM D4770進行測試。測試結果分為5級,其中5級(Level 5)顯示耐水洗性最佳。 5. 水洗後跑毛情況:根據標準方法ASTM D4770進行測試。測試結果分為5級,其中5級顯示水洗後跑毛情況最少。 6. 水洗縮率:根據標準方法ASTM D4770進行測試。 7. 壓縮回復率:根據標準方法ASTM D6571-01進行測試。 8. 彈性:根據標準方法ASTM D2594進行測試。 9. 耐摩擦性:根據標準方法ASTM D4966-98進行馬丁代爾耐磨測試,其中膜材類經過超過5000轉的測試後無破損時判定為耐摩擦性優良。 According to the following standard methods, various properties of Example 1 and Comparative Examples 1 to 4 were tested. 1. Weight per unit area: Tested according to standard method ASTM D3776. 2. Thickness: Tested according to Invista Method. 3. Insulation value: Tested according to the standard method ASTM D1518, the value obtained is the CLO value, and the unit is CLO. 4. Washing resistance: Tested according to standard method ASTM D4770. The test results are divided into 5 levels, among which level 5 (Level 5) shows the best washability. 5. Flint loss after washing: Tested according to standard method ASTM D4770. The test results are divided into 5 levels, of which level 5 shows the least lint after washing. 6. Washing shrinkage: tested according to standard method ASTM D4770. 7. Compression recovery rate: Tested according to standard method ASTM D6571-01. 8. Resilience: Tested according to standard method ASTM D2594. 9. Friction resistance: The Martindale abrasion resistance test is performed according to the standard method ASTM D4966-98. The membrane material is judged to have excellent friction resistance when there is no damage after more than 5,000 revolutions of testing.

以上各項測試結果係列於下表1。The above test results are listed in Table 1 below.

表1   實施例1 比較例1 比較例2 比較例3 比較例4 材料 熔噴層 保溫棉 保溫棉 彈性保溫棉 彈性保溫棉 保溫棉層 總單位面積重量 (gsm) 80 80 40 80 40 厚度 (cm) 0.65 1.38 0.86 1.66 0.79 保溫值 (CLO) 1.27 1.94 0.98 1.24 0.63 保溫值/厚度 (CLO/cm) 1.95 1.4 1.14 0.75 0.79 耐水洗性 水洗5次 5級 4級 4級 4級 4級 水洗10次 5級 4級 4級 4級 4級 跑毛 (水洗3次) 5級 5級 5級 5級 5級 水洗縮率 (%) 方向 MD CD MD CD MD CD MD CD MD CD 水洗5次 0 0 2 3 3 4 11 14 12 13 水洗10次 0 0 2 3 3 4 13 14.8 14 21 壓縮回復率 (%) 85 76 69 75 68.9 彈性 (%) 方向 MD CD MD CD MD CD MD CD MD CD 數值 20 30 0 0 0 0 7 15 10 25 耐摩擦性 >10000轉無破損 (熔噴層) N/A N/A N/A N/A Table 1 Example 1 Comparative example 1 Comparative example 2 Comparative example 3 Comparative example 4 Material Meltblown layer thermal insulation cotton thermal insulation cotton Elastic insulation cotton Elastic insulation cotton insulation cotton layer Total unit area weight (gsm) 80 80 40 80 40 Thickness(cm) 0.65 1.38 0.86 1.66 0.79 Thermal insulation value (CLO) 1.27 1.94 0.98 1.24 0.63 Insulation value/thickness (CLO/cm) 1.95 1.4 1.14 0.75 0.79 Washability Wash 5 times Level 5 Level 4 Level 4 Level 4 Level 4 Wash 10 times Level 5 Level 4 Level 4 Level 4 Level 4 Hair loss (washed 3 times) Level 5 Level 5 Level 5 Level 5 Level 5 Washing shrinkage (%) direction MD CD MD CD MD CD MD CD MD CD Wash 5 times 0 0 2 3 3 4 11 14 12 13 Wash 10 times 0 0 2 3 3 4 13 14.8 14 twenty one Compression recovery rate (%) 85 76 69 75 68.9 Elasticity(%) direction MD CD MD CD MD CD MD CD MD CD numerical value 20 30 0 0 0 0 7 15 10 25 Friction resistance >10000 revolutions without damage (melt blown layer) N/A N/A N/A N/A

實施例1之彈性保溫複合材料具有較高的單位厚度保溫值(保溫值/厚度),因此,以同樣厚度的保溫材料來說,本發明之彈性保溫複合材料的保溫值明顯高於傳統保溫棉和彈性保溫棉,故可達到使填充式織物更為輕薄的效果。而以相同的材質來說,厚度較薄的材料,其單位厚度保溫值也會跟著降低。另以實施例1和比較例3來說,在相同總單位面積重量的條件下,實施例1加入了熔噴層後,其單位厚度較比較例3減少了約60%,但單位厚度保溫值提升了約2.6倍,達到了輕薄保暖的效果。The elastic thermal insulation composite material of Example 1 has a higher thermal insulation value per unit thickness (insulation value/thickness). Therefore, for thermal insulation materials of the same thickness, the thermal insulation value of the elastic thermal insulation composite material of the present invention is significantly higher than that of traditional thermal insulation cotton. and elastic insulation cotton, so it can achieve the effect of making the filled fabric lighter and thinner. For the same material, a thinner material will have a lower thermal insulation value per unit thickness. Taking Example 1 and Comparative Example 3 as an example, under the same total unit area weight, after the melt-blown layer was added to Example 1, its unit thickness was reduced by about 60% compared to Comparative Example 3, but the thermal insulation value of the unit thickness It has been improved by about 2.6 times, achieving the effect of being light and warm.

經水洗測試後,實施例1之彈性保溫複合材料的耐水洗性為最佳的5級,不易跑毛,且尺寸不會因為多次水洗而變小,更為耐用,耐久性更佳。傳統保溫棉和彈性保溫棉的耐水洗性稍遜,但水洗縮率明顯較高。相對之下,實施例1之彈性保溫複合材料在水洗10次後也不會縮水,更加容易清潔保養。After the water washing test, the water washing resistance of the elastic insulation composite material of Example 1 is the best level 5, it is not easy to lint, and the size will not become smaller due to multiple water washings. It is more durable and has better durability. Traditional thermal insulation cotton and elastic thermal insulation cotton are slightly less resistant to washing, but their washing shrinkage is significantly higher. In contrast, the elastic insulation composite material of Example 1 will not shrink even after being washed 10 times, making it easier to clean and maintain.

實施例1之彈性保溫複合材料的壓縮回復率高達85%,且縱向與橫向的彈性也都優於傳統彈性保溫棉。因此,在摺疊或壓縮收納後,更容易回復原狀,保持原有的蓬鬆度,在長久使用後仍能維持保溫值。The compression recovery rate of the elastic thermal insulation composite material of Example 1 is as high as 85%, and the longitudinal and transverse elasticity is also better than that of traditional elastic thermal insulation cotton. Therefore, after being folded or compressed for storage, it is easier to return to its original shape, maintain its original fluffiness, and maintain its thermal insulation value after long-term use.

此外,以馬丁代爾耐磨進行測試,發現實施例1之彈性保溫複合材料的熔噴層具有優良的耐摩擦性,使該彈性保溫複合材料在使用上更具耐久性。In addition, the Martindale abrasion resistance test showed that the melt-blown layer of the elastic insulation composite material of Example 1 has excellent friction resistance, making the elastic insulation composite material more durable in use.

由上可知,本發明之彈性保溫複合材料具有良好彈性及保溫性的彈性保溫複合材料,其具有優異的耐久性,於水洗後不易跑毛或縮水、且具良好耐摩擦性、壓縮回復率和彈性,應用層面更為廣泛。It can be seen from the above that the elastic thermal insulation composite material of the present invention has good elasticity and thermal insulation properties. It has excellent durability, is not easy to lint or shrink after washing, and has good friction resistance, compression recovery rate and Flexibility, wider application level.

1:彈性保溫複合材料 10:保溫棉層 11:保溫纖維 20:熔噴層 21:熔噴彈性纖維 100:熔噴設備 110:擠壓機 111:熔噴模頭 112:原料出口 113:熱風出口 120:輸送帶 130:負壓裝置 1: Elastic insulation composite material 10: Insulation cotton layer 11: Insulation fiber 20: Melt blown layer 21:Melt-blown elastic fiber 100: Melt blown equipment 110:Extruder 111: Meltblown die head 112:Export of raw materials 113:Hot air outlet 120: Conveyor belt 130: Negative pressure device

圖1為本發明之彈性保溫複合材料的示意圖。 圖2為圖1當中保溫棉層及熔噴層之交界面的放大圖。 圖3A為本發明之彈性保溫複合材料中保溫棉層及熔噴層之交界面的保溫纖維及熔噴彈性纖維相互連結的示意圖。 圖3B為本發明之彈性保溫複合材料中保溫棉層及熔噴層之交界面的保溫纖維及熔噴彈性纖維相互連結並產生彈性的示意圖。 圖4為透過熔噴設備製備本發明之彈性保溫複合材料的示意圖。 Figure 1 is a schematic diagram of the elastic thermal insulation composite material of the present invention. Figure 2 is an enlarged view of the interface between the thermal insulation cotton layer and the melt-blown layer in Figure 1. 3A is a schematic diagram of the interconnection of the insulation fibers and the melt-blown elastic fibers at the interface between the insulation cotton layer and the melt-blown layer in the elastic insulation composite material of the present invention. 3B is a schematic diagram showing that the insulation fibers and melt-blown elastic fibers at the interface between the insulation cotton layer and the melt-blown layer in the elastic insulation composite material of the present invention are interconnected and generate elasticity. Figure 4 is a schematic diagram of preparing the elastic thermal insulation composite material of the present invention through melt-blown equipment.

1:彈性保溫複合材料 1: Elastic insulation composite material

10:保溫棉層 10: Insulation cotton layer

20:熔噴層 20: Melt blown layer

Claims (10)

一種彈性保溫複合材料,其包含: 一保溫棉層,其單位重量為20 gsm至300 gsm,且其包含一保溫纖維;以及 一熔噴層,位於該保溫棉層之上,其單位重量為15 gsm至100 gsm,且其包含一熔噴彈性纖維; 其中在該保溫棉層及該熔噴層的交界面,該保溫纖維的一部分及該熔噴彈性纖維的一部分相互連結,該熔噴彈性纖維之材料係為一原生或回收之高分子彈性材料,該高分子彈性材料選自由熱塑性聚氨酯、熱塑性聚酯彈性體、聚對苯二甲酸丙二酯及其組合所組成的群組,且該熔噴彈性纖維之直徑為0.1 μm至35 μm。 An elastic thermal insulation composite material containing: An insulation cotton layer with a unit weight of 20 gsm to 300 gsm and containing an insulation fiber; and A melt-blown layer, located on the thermal insulation cotton layer, has a unit weight of 15 gsm to 100 gsm and contains a melt-blown elastic fiber; Wherein, at the interface between the insulation cotton layer and the melt-blown layer, a part of the insulation fiber and a part of the melt-blown elastic fiber are connected to each other, and the material of the melt-blown elastic fiber is a virgin or recycled polymer elastic material. The polymer elastic material is selected from the group consisting of thermoplastic polyurethane, thermoplastic polyester elastomer, polytrimethylene terephthalate and combinations thereof, and the diameter of the melt-blown elastic fiber is 0.1 μm to 35 μm. 如請求項1所述之彈性保溫複合材料,其中該保溫棉層包含一保溫纖維,且該保溫纖維之材料係為一原生或回收之纖維材料,該纖維材料選自由聚對苯二甲酸乙二酯、聚對苯二甲酸丙二酯及其組合所組成的群組。The elastic thermal insulation composite material as described in claim 1, wherein the thermal insulation cotton layer includes an thermal insulation fiber, and the material of the thermal insulation fiber is a virgin or recycled fiber material, and the fiber material is selected from polyethylene terephthalate. ester, polytrimethylene terephthalate and their combinations. 如請求項2所述之彈性保溫複合材料,其中該保溫棉層進一步包含膠、低熔點纖維、或其組合。The elastic thermal insulation composite material according to claim 2, wherein the thermal insulation cotton layer further contains glue, low melting point fiber, or a combination thereof. 如請求項3所述之彈性保溫複合材料,其中該低熔點纖維的熔點為110°C至170°C。The elastic thermal insulation composite material according to claim 3, wherein the melting point of the low melting point fiber is 110°C to 170°C. 如請求項3所述之彈性保溫複合材料,其中該膠之材料係為水性壓克力樹脂或水性聚氨酯樹脂。The elastic thermal insulation composite material according to claim 3, wherein the material of the glue is water-based acrylic resin or water-based polyurethane resin. 如請求項1所述之彈性保溫複合材料,在該高分子彈性材料中,該熱塑性聚氨酯的熔點範圍為150°C至190°C;該熱塑性聚酯彈性體的熔點範圍為210°C至240°C;且該聚對苯二甲酸丙二酯的熔點範圍為245°C至265°C。As for the elastic thermal insulation composite material described in claim 1, in the polymer elastic material, the melting point of the thermoplastic polyurethane ranges from 150°C to 190°C; the melting point range of the thermoplastic polyester elastomer ranges from 210°C to 240°C. °C; and the melting point range of the polytrimethylene terephthalate is 245°C to 265°C. 如請求項1所述之彈性保溫複合材料,其中該彈性保溫複合材料之保溫值/厚度為1.50 CLO/cm以上。The elastic thermal insulation composite material as described in claim 1, wherein the thermal insulation value/thickness of the elastic thermal insulation composite material is more than 1.50 CLO/cm. 如請求項1所述之彈性保溫複合材料,其中該彈性保溫複合材料之縱向的水洗縮率為1.5%以下,且其橫向的水洗縮率為2.5%以下。The elastic thermal insulation composite material as described in claim 1, wherein the longitudinal washing shrinkage of the elastic thermal insulation composite material is less than 1.5%, and the transverse washing shrinkage of the elastic thermal insulation composite material is less than 2.5%. 如請求項1所述之彈性保溫複合材料,其中該彈性保溫複合材料之壓縮回復率為80%以上。The elastic thermal insulation composite material as described in claim 1, wherein the compression recovery rate of the elastic thermal insulation composite material is more than 80%. 如請求項1所述之彈性保溫複合材料,其中該彈性保溫複合材料之縱向的彈性為15%以上,且其橫向的彈性為20%以上。The elastic thermal insulation composite material as described in claim 1, wherein the elasticity of the elastic thermal insulation composite material in the longitudinal direction is more than 15%, and the elasticity in the transverse direction is more than 20%.
TW111132966A 2022-06-14 2022-08-31 Elastic thermal insulation composite material characterized by having good elasticity, thermal insulation property and durability TW202348860A (en)

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