TW202333539A - Optical system and method for a radiation source - Google Patents

Optical system and method for a radiation source Download PDF

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TW202333539A
TW202333539A TW111147930A TW111147930A TW202333539A TW 202333539 A TW202333539 A TW 202333539A TW 111147930 A TW111147930 A TW 111147930A TW 111147930 A TW111147930 A TW 111147930A TW 202333539 A TW202333539 A TW 202333539A
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laser pulse
optical
optical component
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laser
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安德瑞 瑟吉維奇 特奇科夫
艾莉珊卓 馬修思 史崔肯
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荷蘭商Asml荷蘭公司
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Abstract

An optical system for directing first and second laser pulses along an optical axis to a target to generate extreme ultraviolet radiation from said target. The optical system comprises a first optical component configured to redistribute a first laser pulse to form a shaped laser pulse having a hollow region. The optical system comprise a second optical component configured to focus the shaped laser pulse toward the target. The optical system comprises a third optical component configured to focus a second laser pulse toward the target within the hollow region of the shaped laser pulse. The first, second and third optical components are coaxially arranged on the optical axis.

Description

光學系統及用於輻射源之方法Optical systems and methods for radiation sources

本發明係關於一種光學系統及用於一輻射源之方法,特別而言係關於一種用於沿著一光軸將該第一雷射脈衝及該第二雷射脈衝導向至一目標以自該目標產生極紫外線輻射之光學系統。該光學系統適合於用作一EUV輻射源及/或一微影系統的部分。The present invention relates to an optical system and a method for a radiation source, and in particular to a method for directing the first laser pulse and the second laser pulse along an optical axis to a target from the Optical systems that target the production of extreme ultraviolet radiation. The optical system is suitable for use as an EUV radiation source and/or as part of a lithography system.

微影設備為經建構以將所要之圖案施加至基板上之機器。微影設備可用於(例如)積體電路(IC)之製造中。微影設備可(例如)將圖案化裝置(例如,光罩)處之圖案投影至提供於基板上之輻射敏感材料(抗蝕劑)層上。Lithography equipment is a machine constructed to apply a desired pattern to a substrate. Lithography equipment may be used, for example, in the manufacture of integrated circuits (ICs). A lithography apparatus may, for example, project a pattern at a patterning device (eg, a photomask) onto a layer of radiation-sensitive material (resist) provided on a substrate.

為了將圖案投影於基板上,微影設備可使用電磁輻射。此輻射之波長判定可形成於基板上之特徵的最小大小。相比於使用例如具有193 nm之波長之輻射的微影設備,使用具有介於4至20 nm範圍內之波長(例如6.7 nm或13.5 nm)的極紫外(extreme ultraviolet;EUV)輻射之微影設備可用於在基板上形成較小特徵。To project patterns onto substrates, lithography equipment may use electromagnetic radiation. The wavelength of this radiation determines the minimum size of features that can be formed on the substrate. Compared to lithography equipment that uses radiation with a wavelength of, for example, 193 nm, lithography that uses extreme ultraviolet (EUV) radiation with a wavelength in the range of 4 to 20 nm, such as 6.7 nm or 13.5 nm. Equipment can be used to form smaller features on substrates.

可用以產生EUV輻射之一個系統為涉及使用雷射來經由雷射射束將能量沈積於燃料材料中的雷射產生電漿(LPP)系統。雷射能量至燃料材料中的沈積產生電漿。在電子藉由電漿之離子去激發及與離子再結合期間,自電漿發射包括EUV輻射。One system that can be used to generate EUV radiation is a laser-produced plasma (LPP) system that involves the use of lasers to deposit energy into the fuel material via a laser beam. The deposition of laser energy into the fuel material creates a plasma. During the deexcitation of electrons by and recombination with ions of the plasma, emission from the plasma includes EUV radiation.

WO2012069898揭示一種LPP系統,該LPP系統使用兩個雷射射束,即主脈衝雷射射束及預脈衝雷射射束以自燃料材料產生EUV輻射。射束塑形單元設置於主脈衝雷射射束之束路徑上,從而將主脈衝雷射射束變換至中空雷射射束中。第一聚焦光學元件設置於射束塑形裝置的下游從而聚焦中空雷射射束。提供第二聚焦光學元件,該第二聚焦光學元件聚焦預脈衝雷射射束,使得預脈衝雷射射束及中空主脈衝雷射射束朝向燃料材料在相同方向上行進。主脈衝雷射射束之射束塑形及預脈衝雷射射束的聚焦在不同的垂直光軸上出現。WO2012069898 discloses an LPP system that uses two laser beams, namely a main pulse laser beam and a pre-pulse laser beam, to generate EUV radiation from fuel materials. The beam shaping unit is disposed on the beam path of the main pulse laser beam, thereby transforming the main pulse laser beam into the hollow laser beam. The first focusing optical element is disposed downstream of the beam shaping device to focus the hollow laser beam. A second focusing optical element is provided which focuses the pre-pulse laser beam such that the pre-pulse laser beam and the hollow main pulse laser beam travel in the same direction towards the fuel material. Beam shaping of the main pulse laser beam and focusing of the pre-pulse laser beam occur on different vertical optical axes.

本發明之一目標為提供一種改良自一LPP系統產生EUV輻射的光學系統。It is an object of the present invention to provide an improved optical system for generating EUV radiation from an LPP system.

根據本發明之一第一態樣,提供一種用於沿著一光軸將第一雷射脈衝及第二雷射脈衝導向至一目標以自該目標產生極紫外線輻射之光學系統。該光學系統包含:一第一光學組件,其經組態以使該第一雷射脈衝重新分佈以形成具有一中空區之一塑形雷射脈衝;及一第二光學組件,其經組態以使該塑形雷射脈衝朝向該目標聚焦。該光學系統包含一第三光學組件,其經組態以在該塑形雷射脈衝之該中空區內使該第二雷射脈衝朝向該目標聚焦,其中該第一光學組件、該第二光學組件及該第三光學組件共軸配置於該光軸上。According to a first aspect of the invention, an optical system is provided for directing a first laser pulse and a second laser pulse to a target along an optical axis to generate extreme ultraviolet radiation from the target. The optical system includes: a first optical component configured to redistribute the first laser pulse to form a shaped laser pulse having a hollow region; and a second optical component configured to focus the shaping laser pulse toward the target. The optical system includes a third optical component configured to focus the second laser pulse toward the target within the hollow region of the shaped laser pulse, wherein the first optical component, the second optical component The component and the third optical component are coaxially arranged on the optical axis.

相較於使第一雷射脈衝重新塑形且沿著不同軸線使該第二雷射脈衝聚焦的光學系統,本發明之光學系統有利地受益於增大的轉化效率。轉化效率之增大係至少部分歸因於在經塑形之第一雷射脈衝與聚焦之第二雷射脈衝之間的可忽略(或零)角度、經塑形之第一雷射脈衝與該光學系統之光軸之間的可忽略(或零)角度,及經聚焦之第二雷射脈衝與該光學系統之光軸之間的可忽略(或零)角度。此外,轉化效率經進一步改良,此係因為第一雷射脈衝及第二雷射脈衝的數值孔徑相較於已知光學系統增大。此外,轉化效率進一步經改良,此係因為第一脈衝及第二脈衝共用同一平面。The optical system of the present invention advantageously benefits from increased conversion efficiency compared to an optical system that reshapes the first laser pulse and focuses the second laser pulse along a different axis. The increase in conversion efficiency is due, at least in part, to the negligible (or zero) angle between the shaped first laser pulse and the focused second laser pulse, the relationship between the shaped first laser pulse and the focused second laser pulse. A negligible (or zero) angle between the optical axes of the optical system, and a negligible (or zero) angle between the focused second laser pulse and the optical axis of the optical system. Furthermore, the conversion efficiency is further improved due to the increased numerical aperture of the first laser pulse and the second laser pulse compared to known optical systems. In addition, the conversion efficiency is further improved because the first pulse and the second pulse share the same plane.

相較於第一雷射脈衝及第二雷射脈衝沿著光軸佔據相同區的已知光學系統,根據本發明之該光學系統有利地受益於包括於其中之光學組件上的減小之熱負荷(及對光學組件之損害的關聯風險)。此係因為第一雷射脈衝及第二雷射脈衝可與不同光學元件及/或光學元件之不同部分相互作用而非與相同光學元件之相同部分相互作用。此外,相較於允許第一雷射脈衝及第二雷射脈衝沿著光軸佔據相同區的已知光學系統,本文中揭示之光學系統的光學效率增大,此係因為不同光學組件(例如,不同光學元件及/或相同光學元件之不同部分)可經定製以與第一雷射脈衝及第二雷射脈衝相互作用(其可包含不同特性,例如波長、功率等)。Compared to known optical systems in which the first laser pulse and the second laser pulse occupy the same area along the optical axis, the optical system according to the invention advantageously benefits from reduced heat on the optical components included therein. load (and associated risk of damage to optical components). This is because the first laser pulse and the second laser pulse may interact with different optical elements and/or different parts of optical elements rather than with the same part of the same optical element. Furthermore, compared to known optical systems that allow the first laser pulse and the second laser pulse to occupy the same area along the optical axis, the optical efficiency of the optical system disclosed herein is increased due to different optical components, such as , different optical elements and/or different portions of the same optical element) can be customized to interact with the first laser pulse and the second laser pulse (which can include different characteristics, such as wavelength, power, etc.).

相較於用於已知EUV輻射源中的已知光學系統,根據本發明之光學系統有利地受益於目標處第一雷射脈衝及第二雷射脈衝之空間輪廓的增大之穩定性及再現性。此係因為相較於用於已知EUV輻射源中的已知光學系統,共軸配置使得能夠更均勻地在目標處分佈第一雷射脈衝及第二雷射脈衝的空間輪廓。此外,重新分佈第一雷射脈衝之空間輪廓確保第一雷射脈衝的能量保持而非至少部分丟失。此外,光學組件之共軸配置提供包含易於修理及/或更換光學組件的緊湊設計。Compared to known optical systems used in known EUV radiation sources, the optical system according to the invention advantageously benefits from an increased stability of the spatial profile of the first and second laser pulses at the target and Reproducibility. This is because the coaxial configuration enables a more uniform distribution of the spatial profile of the first and second laser pulses at the target compared to known optical systems used in known EUV radiation sources. Furthermore, redistributing the spatial profile of the first laser pulse ensures that the energy of the first laser pulse is maintained rather than at least partially lost. Additionally, the coaxial configuration of the optical components provides a compact design that includes easy repair and/or replacement of the optical components.

詞語「第一」及「第二」及類似者僅用以識別不同特徵,且並不指明時間或空間次序。在第二雷射脈衝入射於目標上後,第一雷射脈衝可入射於目標上。The words "first" and "second" and the like are used only to identify different features and do not indicate a temporal or spatial order. After the second laser pulse is incident on the target, the first laser pulse can be incident on the target.

複數個光學組件可包含反射光學組件。複數個光學組件可包含透射光學組件。The plurality of optical components may include reflective optical components. The plurality of optical components may include transmissive optical components.

第一雷射脈衝及第二雷射脈衝可包含不同波長。The first laser pulse and the second laser pulse may include different wavelengths.

目標可為一燃料小滴(例如,錫)。The target may be a fuel droplet (eg, tin).

第二雷射脈衝可經組態以改變目標的形狀。舉例而言,第二雷射脈衝可經組態以將目標自小液滴形狀改變成餅乾形狀。The second laser pulse can be configured to change the shape of the target. For example, the second laser pulse can be configured to change the target from a droplet shape to a cookie shape.

第二雷射脈衝可包含大約1030 nm的波長。The second laser pulse may contain a wavelength of approximately 1030 nm.

第一雷射脈衝可經組態以使得目標發射極紫外線輻射。舉例而言,第一雷射脈衝可將目標轉換成發射極紫外線輻射的電漿。The first laser pulse may be configured so that the target emits extreme ultraviolet radiation. For example, a first laser pulse can convert the target into a plasma that emits extreme ultraviolet radiation.

第一雷射脈衝可包含約10.6 µm的波長。The first laser pulse may contain a wavelength of approximately 10.6 µm.

該第一光學組件及該第三光學組件可定位於一單一光學元件之不同表面上。The first optical component and the third optical component can be positioned on different surfaces of a single optical element.

此配置相較於已知光學系統有利地減小光學元件的數目,藉此減小成本及複雜度,同時相較於已知光學系統簡化修理及替換。This configuration advantageously reduces the number of optical elements compared to known optical systems, thereby reducing cost and complexity, while simplifying repair and replacement compared to known optical systems.

第一光學組件可形成於單一光學元件的前側上。第三光學組件可形成於單一光學元件的背側上。The first optical component may be formed on the front side of the single optical element. The third optical component can be formed on the backside of the single optical element.

該光學系統可包含一輻射收集器,其經組態以接收由目標發射之極紫外線輻射。輻射收集器可包含共軸配置於光軸上的孔徑。第二光學組件及第三光學組件可經組態以通過孔徑使經塑形且第二雷射脈衝聚焦。The optical system may include a radiation collector configured to receive extreme ultraviolet radiation emitted by the target. The radiation collector may include apertures coaxially disposed on the optical axis. The second optical component and the third optical component may be configured to shape and focus the second laser pulse through the aperture.

相較於具有沿著不同軸線形成塑形且第二雷射脈衝及/或離軸定位收集器孔徑的已知光學系統,具有與塑形且第二雷射脈衝及目標共軸的收集器孔徑有利地增大光學系統的轉化效率(當產生EUV輻射時)。Compared to known optical systems with a shaped and second laser pulse and/or off-axis positioned collector aperture along different axes, having a collector aperture coaxial with the shaped and second laser pulse and the target Advantageously, the conversion efficiency of the optical system (when generating EUV radiation) is increased.

第二光學組件可經組態以僅與塑形雷射脈衝相互作用。第三光學組件可經組態以僅與第二雷射脈衝相互作用。The second optical component can be configured to interact only with the shaping laser pulses. The third optical component can be configured to interact only with the second laser pulse.

此配置有利地使得光學組件能夠經定製為第一及第二脈衝的不同特性(例如,波長)。This configuration advantageously enables the optical components to be tailored to the different characteristics (eg, wavelength) of the first and second pulses.

第二光學組件可包含共軸配置於光軸上的開口。The second optical component may include openings coaxially disposed on the optical axis.

此配置有利地提供相較於與已知光學系統更緊湊的系統。This configuration advantageously provides a more compact system compared to known optical systems.

第三光學組件可經組態以在該塑形雷射脈衝之該中空區內使一第三雷射脈衝沿著光軸聚焦至該目標。該第三雷射脈衝可包含不同於第一雷射脈衝及第二雷射脈衝的波長。A third optical component may be configured to focus a third laser pulse along an optical axis to the target within the hollow region of the shaped laser pulse. The third laser pulse may include a different wavelength than the first laser pulse and the second laser pulse.

在第一雷射脈衝之後且在第二雷射脈衝之前,第三雷射脈衝可入射於目標上。After the first laser pulse and before the second laser pulse, a third laser pulse may be incident on the target.

第三雷射脈衝可經組態以製備用於接收第二雷射脈衝的目標。舉例而言,第三雷射脈衝可經組態以在製備中使目標霧化(亦即,類似於氣態狀態,將餅乾小液滴轉換為許多小粒子)從而接收第一雷射脈衝用於產生EUV輻射。第三雷射脈衝可用來增大第一雷射脈衝由目標的吸收。The third laser pulse may be configured to prepare the target for receiving the second laser pulse. For example, the third laser pulse may be configured to atomize the target in preparation (i.e., convert the cookie droplets into many small particles, similar to a gaseous state) to receive the first laser pulse for EUV radiation is generated. The third laser pulse may be used to increase absorption of the first laser pulse by the target.

第三雷射脈衝可具有大約1064 nm的波長。The third laser pulse may have a wavelength of approximately 1064 nm.

根據本發明之第二態樣,提供一種包含第一態樣之光學系統的極紫外線輻射源。According to a second aspect of the present invention, an extreme ultraviolet radiation source comprising an optical system of the first aspect is provided.

根據本發明之一第三態樣,提供一種包含第二態樣之極紫外線輻射源的蝕刻系統。According to a third aspect of the present invention, an etching system including an extreme ultraviolet radiation source of the second aspect is provided.

根據本發明之一第四態樣,提供一種沿著光軸將第一雷射脈衝及第二雷射脈衝導向至目標以自該目標產生極紫外線輻射之方法。該方法包含:使用第一光學組件以使該第一雷射脈衝重新分佈以形成具有一中空區之一塑形雷射脈衝;及使用第二光學組件以使該塑形雷射脈衝朝向該目標聚焦。該方法進一步包含使用一第三光學組件以在該塑形雷射脈衝之該中空區內使該第二雷射脈衝朝向該目標聚焦。該方法亦包含在該光軸上共軸配置該第一光學組件、該第二光學組件及該第三光學組件。According to a fourth aspect of the invention, a method of directing a first laser pulse and a second laser pulse to a target along an optical axis to generate extreme ultraviolet radiation from the target is provided. The method includes: using a first optical component to redistribute the first laser pulse to form a shaped laser pulse having a hollow region; and using a second optical component to direct the shaped laser pulse towards the target focus. The method further includes using a third optical component to focus the second laser pulse toward the target within the hollow region of the shaped laser pulse. The method also includes arranging the first optical component, the second optical component and the third optical component coaxially on the optical axis.

第一雷射脈衝及第二雷射脈衝可包含不同波長之輻射。The first laser pulse and the second laser pulse may include radiation of different wavelengths.

方法可包含在一單一光學元件之不同表面上定位該第一光學組件及該第三光學組件。The method may include positioning the first optical component and the third optical component on different surfaces of a single optical element.

該方法可包含在該單一光學元件之前側上定位該第一光學組件及在該單一光學元件之一背側上定位該第三光學組件。The method may include positioning the first optical component on a front side of the single optical element and positioning the third optical component on a back side of the single optical element.

該方法可包含使用輻射收集器來接收由目標發射之極紫外線輻射。該方法可包含在該光軸上共軸配置該輻射收集器之一孔徑。該方法可包含使用第二光學組件及第三光學組件來通過孔徑使該塑形且第二雷射脈衝聚焦。The method may include using a radiation collector to receive extreme ultraviolet radiation emitted by the target. The method may include arranging an aperture of the radiation collector coaxially on the optical axis. The method may include using a second optical component and a third optical component to shape and focus the second laser pulse through an aperture.

該方法可包含使用第二光學組件來僅與塑形雷射脈衝相互作用。該方法可包含使用該第三光學組件來僅與第二雷射脈衝相互作用。該方法可包含在該第二光學組件中設置一開口及在該光軸上共軸配置該開口。該方法可包含使用第三光學組件以在該塑形脈衝之該中空區內使一第三雷射脈衝沿著光軸聚焦至該目標。該第三雷射脈衝可包含不同於第一雷射脈衝及第二雷射脈衝的波長。The method may include using a second optical component to interact only with the shaping laser pulse. The method may include using the third optical component to interact only with the second laser pulse. The method may include providing an opening in the second optical component and arranging the opening coaxially on the optical axis. The method may include using a third optical component to focus a third laser pulse along an optical axis to the target within the hollow region of the shaped pulse. The third laser pulse may include a different wavelength than the first laser pulse and the second laser pulse.

根據本發明之一第五態樣,提供一種將圖案化輻射射束投影至基板上之方法,其包含使用第四態樣的方法來產生極紫外線輻射。According to a fifth aspect of the present invention, a method of projecting a patterned radiation beam onto a substrate is provided, which includes using the method of the fourth aspect to generate extreme ultraviolet radiation.

圖1繪示包含輻射源SO及微影設備LA之微影系統。輻射源SO經組態以產生EUV輻射射束B及將EUV輻射射束B供應至微影設備LA。微影設備LA包含照明系統IL、經組態以支撐圖案化裝置MA (例如,光罩)之支撐結構MT、投影系統PS,及經組態以支撐基板W之基板台WT。Figure 1 illustrates a lithography system including a radiation source SO and a lithography apparatus LA. Radiation source SO is configured to generate EUV radiation beam B and supply EUV radiation beam B to lithography apparatus LA. Lithography apparatus LA includes an illumination system IL, a support structure MT configured to support a patterning device MA (eg, a photomask), a projection system PS, and a substrate table WT configured to support a substrate W.

照明系統IL經組態以在EUV輻射射束B入射於圖案化裝置MA上之前調節EUV輻射射束B。另外,照明系統IL可包括琢面化場鏡面裝置10及琢面化光瞳鏡面裝置11。琢面化場鏡面裝置10及琢面化光瞳鏡面裝置11共同提供具有所需橫截面形狀及所需強度分佈之EUV輻射射束B。作為琢面化場鏡面裝置10及琢面化光瞳鏡面裝置11之補充或替代,照明系統IL亦可包括其他鏡面或裝置。The illumination system IL is configured to condition the EUV radiation beam B before the EUV radiation beam B is incident on the patterning device MA. In addition, the illumination system IL may include a faceted field mirror device 10 and a faceted pupil mirror device 11 . The faceted field mirror device 10 and the faceted pupil mirror device 11 together provide an EUV radiation beam B having a desired cross-sectional shape and a desired intensity distribution. As a supplement or alternative to the faceted field mirror device 10 and the faceted pupil mirror device 11 , the illumination system IL may also include other mirrors or devices.

在如此調節之後,EUV輻射射束B與圖案化裝置MA相互作用。由於此相互作用,產生經圖案化EUV輻射射束B'。投影系統PS經組態以將經圖案化EUV輻射射束B'投射至基板W上。出於彼目的,投影系統PS可包含經組態以將經圖案化EUV輻射射束B'投射至由基板台WT固持之基板W上的複數個鏡面13、14。投影系統PS可將減小因數應用於經圖案化EUV輻射射束B',因此形成具有小於圖案化裝置MA上之對應特徵之特徵的影像。舉例而言,可應用縮減因數4或8。儘管在圖1中將投影系統PS說明為僅具有兩個鏡面13、14,但投影系統PS可包括不同數目個鏡面(例如,六個或八個鏡面)。After such conditioning, the EUV radiation beam B interacts with the patterning device MA. Due to this interaction, a patterned EUV radiation beam B' is generated. Projection system PS is configured to project patterned EUV radiation beam B' onto substrate W. For this purpose, the projection system PS may comprise a plurality of mirrors 13, 14 configured to project the patterned EUV radiation beam B' onto the substrate W held by the substrate table WT. Projection system PS can apply a reduction factor to patterned EUV radiation beam B', thereby forming an image with features that are smaller than corresponding features on patterning device MA. For example, a reduction factor of 4 or 8 may be applied. Although projection system PS is illustrated in Figure 1 as having only two mirrors 13, 14, projection system PS may include a different number of mirrors (eg, six or eight mirrors).

基板W可包括先前形成之圖案。在此狀況下,微影設備LA使由經圖案化EUV輻射射束B'形成之影像與先前形成於基板W上之圖案對準。The substrate W may include previously formed patterns. In this case, lithography apparatus LA aligns the image formed by the patterned EUV radiation beam B' with the pattern previously formed on the substrate W.

可在輻射源SO中、在照明系統IL中及/或在投影系統PS中提供相對真空,亦即,處於充分地低於大氣壓之壓力下的少量氣體(例如,氫氣)。A relative vacuum, ie, a small amount of gas (eg, hydrogen) at a pressure well below atmospheric pressure, may be provided in the radiation source SO, in the illumination system IL, and/or in the projection system PS.

圖1中所繪示之輻射源SO屬於例如可稱作雷射產生電漿(LPP)源之類型。可包括例如CO 2雷射之雷射系統1經配置以經由具有不同波長之兩個或兩個以上雷射脈衝2沈積能量至諸如錫(Sn)的燃料中,該燃料自(例如)燃料發射器3提供。儘管在以下描述中提及錫,但可使用任何合適燃料。燃料可例如呈液體形式,且可例如係金屬或合金。燃料發射器3可包含噴嘴,該噴嘴經組態以沿著朝向電漿形成區4之軌跡而導向例如呈小液滴之形式的錫。雷射脈衝2在電漿形成區4處入射於錫上。雷射能量至錫中之沈積在電漿形成區4處產生錫電漿7。在電子藉由電漿之離子去激發及與離子之再結合期間,自電漿7發射包括EUV輻射之輻射。 The radiation source SO shown in Figure 1 is of a type that may be called a laser produced plasma (LPP) source, for example. A laser system 1 , which may include, for example, a CO2 laser, is configured to deposit energy via two or more laser pulses 2 of different wavelengths into a fuel, such as tin (Sn), emitted from, for example Provided by Device 3. Although tin is mentioned in the following description, any suitable fuel may be used. The fuel may, for example, be in liquid form, and may be, for example, a metal or alloy. The fuel injector 3 may comprise a nozzle configured to direct tin, for example in the form of small droplets, along a trajectory towards the plasma formation zone 4 . The laser pulse 2 is incident on the tin at the plasma formation zone 4. Deposition of laser energy into tin generates tin plasma 7 at the plasma formation area 4 . During the deexcitation of electrons by the ions of the plasma and their recombination with the ions, radiation including EUV radiation is emitted from the plasma 7 .

微影設備LA包含光學系統100,光學系統100用於沿著光軸將雷射脈衝2導向至電漿形成區4處之錫以產生EUV輻射。光學系統100之實例更詳細地繪示於圖2中。可被用作微影設備LA之部分的替代性光學系統400的實例詳細繪示於圖4中。光學系統100或替代性光學系統400可被視為用於產生EUV輻射之輻射源SO的部分。The lithography apparatus LA contains an optical system 100 for directing the laser pulse 2 along the optical axis to the tin at the plasma formation region 4 to generate EUV radiation. An example of optical system 100 is shown in greater detail in FIG. 2 . An example of an alternative optical system 400 that may be used as part of a lithography apparatus LA is shown in detail in FIG. 4 . Optical system 100 or alternative optical system 400 may be considered as part of a radiation source SO for generating EUV radiation.

由收集器5收集且聚焦來自電漿之EUV輻射。收集器5包含例如近正入射輻射收集器5 (有時更通常地稱為正入射輻射收集器)。收集器5可具有經配置以反射EUV輻射(例如,具有諸如13.5 nm之所要波長之EVU輻射)之多層鏡面結構。收集器5可具有橢球形組態,該橢球形組態具有兩個焦點。如下文所論述,該等焦點中之第一者可處於電漿形成區4處,且該等焦點中之第二者可處於中間焦點6。收集器5可包含孔徑20,雷射脈衝2行進通過孔徑20以到達電漿形成區4。EUV radiation from the plasma is collected and focused by collector 5 . The collector 5 includes, for example, a near normal incidence radiation collector 5 (sometimes more commonly referred to as a normal incidence radiation collector). Collector 5 may have a multilayer mirror structure configured to reflect EUV radiation (eg, EVU radiation having a desired wavelength, such as 13.5 nm). The collector 5 may have an ellipsoidal configuration with two foci. As discussed below, a first of the foci may be at plasma formation zone 4 and a second of the foci may be at intermediate foci 6 . The collector 5 may comprise an aperture 20 through which the laser pulse 2 travels to reach the plasma formation zone 4 .

雷射系統1可在空間上與輻射源SO分隔。在此狀況下,雷射脈衝2可憑藉射束遞送系統(圖中未示)自雷射系統1傳遞至輻射源SO,該射束遞送系統包含例如合適導向鏡及/或射束擴展器及/或其他光學件。雷射系統1、輻射源SO及射束遞送系統可共同地認為係輻射系統。The laser system 1 may be spatially separated from the radiation source SO. In this case, the laser pulse 2 can be delivered from the laser system 1 to the radiation source SO by means of a beam delivery system (not shown), which beam delivery system includes, for example, suitable guide mirrors and/or beam expanders and /or other optical parts. The laser system 1, the radiation source SO and the beam delivery system may collectively be considered to be radiation systems.

由收集器5反射之輻射形成EUV輻射射束B。EUV輻射射束B聚焦於中間焦點6處,以在存在於電漿形成區4處之電漿之中間焦點6處形成影像。中間焦點6處之影像充當用於照射系統IL之虛擬輻射源。輻射源SO經配置,使得中間焦點6位於輻射源SO之圍封結構9中之開口8處或附近。The radiation reflected by collector 5 forms EUV radiation beam B. The EUV radiation beam B is focused at the intermediate focus 6 to form an image at the intermediate focus 6 of the plasma present in the plasma formation region 4 . The image at intermediate focus 6 serves as a virtual radiation source for illuminating system IL. The radiation source SO is configured such that the intermediate focus 6 is located at or near the opening 8 in the enclosure 9 of the radiation source SO.

圖2示意性地描繪光學系統100之截面側視圖,該光學系統100用於沿著光軸130將第一雷射脈衝110及第二雷射脈衝120導向至目標(圖中未示)以自該目標產生EUV輻射。目標可為存在於電漿形成方位4,諸如圖1中所繪示之一個電漿形成方位處的燃料(例如,錫)小液滴。光學系統100包含第一光學組件140,其經組態以使第一雷射脈衝110重新分佈以形成具有中空區155的塑形雷射脈衝150。在圖1之實例中,第一光學組件140包含具有凸起反射表面之軸錐體鏡面,第一雷射脈衝110入射於該凸起反射表面上。凸形表面可包含離軸拋物線。在圖1之實例中,第一光學組件140通常為圓錐體。第一光學組件140可採用其他形狀。凸面圓錐反射表面之頂點共軸配置於光軸130上。第一光學組件140空間重新分佈第一雷射脈衝110的能量。第一光學組件140之軸錐體鏡面藉由在不同方向上反射第一雷射脈衝110之不同部分來空間重新分佈第一雷射脈衝110的能量以形成塑形雷射脈衝150。在圖2之實例中,塑形雷射脈衝150採用具有環形橫截面之中空錐體的形式(其實例如沿著光軸130所見繪示於圖3中)。將瞭解,塑形雷射脈衝150可採用包含中空區之其他形狀的形式。2 schematically depicts a cross-sectional side view of an optical system 100 for directing a first laser pulse 110 and a second laser pulse 120 along an optical axis 130 to a target (not shown) for self-direction. The target generates EUV radiation. The target may be a droplet of fuel (eg, tin) present at a plasma formation orientation 4, such as the one depicted in FIG. 1 . Optical system 100 includes a first optical component 140 configured to redistribute first laser pulse 110 to form a shaped laser pulse 150 having a hollow region 155 . In the example of FIG. 1 , the first optical component 140 includes an axicon mirror with a convex reflective surface on which the first laser pulse 110 is incident. Convex surfaces can contain off-axis parabolas. In the example of FIG. 1, the first optical component 140 is generally a cone. The first optical component 140 may take other shapes. The apex of the convex conical reflective surface is coaxially disposed on the optical axis 130 . The first optical component 140 spatially redistributes the energy of the first laser pulse 110 . The axicon mirror of the first optical component 140 spatially redistributes the energy of the first laser pulse 110 by reflecting different parts of the first laser pulse 110 in different directions to form a shaped laser pulse 150 . In the example of Figure 2, the shaping laser pulse 150 takes the form of a hollow cone with an annular cross-section (an example of which is shown in Figure 3 as seen along the optical axis 130). It will be appreciated that the shaped laser pulse 150 may take the form of other shapes including hollow areas.

在圖2之實例中,光學系統100可包含以上段落中所描述的特徵。另外,塑形雷射脈衝亦可理解為塑形射束脈衝或塑形射束。在額外實施例中,第一光學組件140可為圓錐、球體、非球體或具有自由形式。In the example of Figure 2, optical system 100 may include the features described in the preceding paragraphs. In addition, shaping laser pulse can also be understood as shaping beam pulse or shaping beam. In additional embodiments, the first optical component 140 may be a cone, a sphere, an aspheric or have a free form.

光學系統100包含第二光學組件160,其經組態以使塑形雷射脈衝150朝向目標聚焦。在圖2之實例中,第二光學組件160包含具有凹入反射表面的聚焦鏡面,該塑形雷射脈衝150入射於該凹入反射表面上。第一光學組件140形成塑形雷射脈衝150且經由第一雷射脈衝110之反射朝向第二光學元件160的凹入反射表面導向塑形雷射脈衝150。第二光學組件160之凹入反射表面反射塑形雷射脈衝150且朝向目標聚焦塑形雷射脈衝150(例如,在電漿形成方位4,諸如繪示於圖1中之電漿形成方位處的燃料小液滴)。第二光學組件160包含共軸配置於光軸130上的開口190。即,第二光學組件160之開口190的中心共軸配置於光軸130上。因此,第二光學元件160之凹入反射表面採用包圍光軸130的凹入環面之形式。開口190在圖2中藉由虛線繪示。第一雷射脈衝110沿著光軸130通過孔徑190傳播以到達第一光學組件140。Optical system 100 includes a second optical component 160 configured to focus shaping laser pulse 150 toward a target. In the example of FIG. 2 , the second optical component 160 includes a focusing mirror having a concave reflective surface upon which the shaping laser pulse 150 is incident. The first optical component 140 forms the shaping laser pulse 150 and directs the shaping laser pulse 150 towards the concave reflective surface of the second optical component 160 via reflection of the first laser pulse 110 . The concave reflective surface of the second optical component 160 reflects the shaping laser pulse 150 and focuses the shaping laser pulse 150 toward the target (e.g., at the plasma formation orientation 4, such as that illustrated in FIG. 1 small droplets of fuel). The second optical component 160 includes an opening 190 coaxially arranged on the optical axis 130 . That is, the center of the opening 190 of the second optical component 160 is coaxially disposed on the optical axis 130 . Therefore, the concave reflective surface of the second optical element 160 takes the form of a concave torus surrounding the optical axis 130 . Opening 190 is shown in Figure 2 by dashed lines. The first laser pulse 110 propagates through the aperture 190 along the optical axis 130 to reach the first optical component 140 .

光學系統100包含一第三光學組件170,其經組態以在塑形雷射脈衝150之中空區155內使第二雷射脈衝120朝向該目標聚焦。即,第三光學組件170沿著光軸130將第二雷射脈衝120導向且聚焦至目標,使得第二雷射脈衝120在塑形雷射脈衝150之中空區155內傳播。第二雷射脈衝120之環形橫截面在塑形雷射脈衝150之環形橫截面的內圓內巢套(其實例如沿著光軸130可見繪示於圖3中)。在圖2之實例中,第三光學組件170包含具有凹入反射表面的聚焦鏡面,第二雷射脈衝120入射於該凹入反射表面上。第一光學組件140、第二光學組件160及第三光學組件170共軸配置於光軸130上,且因此關於彼此及目標共軸配置(例如,圖1之電漿形成方位4)。Optical system 100 includes a third optical component 170 configured to focus second laser pulse 120 toward the target within hollow region 155 of shaped laser pulse 150 . That is, the third optical component 170 guides and focuses the second laser pulse 120 to the target along the optical axis 130 so that the second laser pulse 120 propagates within the hollow region 155 of the shaped laser pulse 150 . The annular cross-section of the second laser pulse 120 is nested within the inner circle of the annular cross-section of the shaping laser pulse 150 (an example of which can be seen along the optical axis 130 as shown in FIG. 3 ). In the example of FIG. 2 , the third optical component 170 includes a focusing mirror having a concave reflective surface upon which the second laser pulse 120 is incident. The first optical component 140 , the second optical component 160 and the third optical component 170 are coaxially disposed on the optical axis 130 and therefore are coaxially disposed with respect to each other and the target (eg, plasma formation orientation 4 of FIG. 1 ).

有利地,第一光學組件140、第二光學組件160及第三光學組件170之共軸配置允許雷射脈衝110、120 (或雷射射束)共軸指向電漿形成區方位4且與目標相互作用,即使在目標稍微離軸的狀況下。Advantageously, the coaxial configuration of the first optical component 140 , the second optical component 160 and the third optical component 170 allows the laser pulses 110 , 120 (or laser beams) to be directed coaxially to the plasma formation zone orientation 4 and to the target. Interaction, even when the target is slightly off-axis.

在另一實施例中,第三光學組件170包含具有凹入反射表面或平坦表面的聚焦鏡面,第二雷射脈衝120入射於該聚焦鏡面上。在第三光學組件170包含具有平坦表面的鏡面之實施例中,光學系統100進一步包含定位於上游的額外聚焦系統(圖中未繪示),該額外聚焦系統經組態以使該第二雷射脈衝120聚焦。In another embodiment, the third optical component 170 includes a focusing mirror having a concave reflective surface or a flat surface, and the second laser pulse 120 is incident on the focusing mirror. In embodiments in which the third optical component 170 includes a mirror with a flat surface, the optical system 100 further includes an additional focusing system (not shown) located upstream and configured such that the second radar The emission pulse 120 is focused.

在圖2之實例中,第一光學組件140及第三光學組件170位於單一光學元件180的不同表面上。第一光學組件140形成於單一光學元件180之面向第一雷射脈衝的前側上,且第三光學組件170形成於單一光學元件180之面向目標的背側上。即,第一光學組件140之軸錐體鏡面的凸面圓錐形表面定位於單一光學元件180的前側上,且第三光學組件170之聚焦鏡面的凹入反射表面定位於單一光學元件180的背側上。此配置有利地促成光學系統100的緊湊性。In the example of FIG. 2 , the first optical component 140 and the third optical component 170 are located on different surfaces of a single optical element 180 . The first optical component 140 is formed on the front side of the single optical element 180 facing the first laser pulse, and the third optical component 170 is formed on the back side of the single optical element 180 facing the target. That is, the convex conical surface of the axicon mirror of the first optical component 140 is positioned on the front side of the single optical element 180 , and the concave reflective surface of the focusing mirror of the third optical component 170 is positioned on the back side of the single optical element 180 superior. This configuration advantageously contributes to the compactness of optical system 100.

第一光學組件140經組態以僅與第一雷射脈衝110相互作用。第二光學組件160經組態以僅與塑形雷射脈衝150相互作用。第三光學組件170經組態以僅與第二雷射脈衝120相互作用。此情形有利地允許每一光學組件140、160、170經定製以與其各別雷射脈衝110、120相互作用。舉例而言,第一雷射脈衝110且因此塑形雷射脈衝150可具有約10.6 µm的波長。第一雷射脈衝110可為CO2雷射脈衝(即,由二氧化碳雷射產生)。第一光學組件140及第二光學組件160可因此具體而言經設計為對於約10.6 µm的波長為儘可能反射性的。舉例而言,第一光學組件140及/或第二光學組件160可包含諸如銅、碳化矽、矽、塗佈鋼等的反射塗層材料。作為另一個實例,第二雷射脈衝120可具有約1030 nm或1064 nm的波長。第二雷射脈衝120可為以固態雷射,諸如YAG雷射產生的脈衝。第三光學組件170可因此具體而言經設計為對於約1030 nm或1064 nm的波長儘可能為反射性的。舉例而言,第三光學組件170可包含反射塗佈材料,諸如銀、金等。相較於使用單一光學元件與兩個雷射脈衝相互作用的已知光學系統,將不同光學組件140、160、170致力於不同雷射脈衝110、120亦有利地減小光學組件過度加熱的風險,且藉此變形或受到損害。The first optical component 140 is configured to interact only with the first laser pulse 110 . The second optical component 160 is configured to interact only with the shaping laser pulse 150 . The third optical component 170 is configured to interact only with the second laser pulse 120 . This advantageously allows each optical component 140, 160, 170 to be customized to interact with its respective laser pulse 110, 120. For example, the first laser pulse 110 and thus the shaping laser pulse 150 may have a wavelength of approximately 10.6 μm. The first laser pulse 110 may be a CO2 laser pulse (ie, generated by a carbon dioxide laser). The first optical component 140 and the second optical component 160 may therefore be designed in particular to be as reflective as possible for a wavelength of approximately 10.6 μm. For example, the first optical component 140 and/or the second optical component 160 may include a reflective coating material such as copper, silicon carbide, silicon, coated steel, or the like. As another example, second laser pulse 120 may have a wavelength of approximately 1030 nm or 1064 nm. The second laser pulse 120 may be a pulse generated by a solid-state laser, such as a YAG laser. The third optical component 170 can thus be designed in particular to be as reflective as possible for wavelengths of approximately 1030 nm or 1064 nm. For example, the third optical component 170 may include a reflective coating material such as silver, gold, or the like. Dedicating different optical components 140, 160, 170 to different laser pulses 110, 120 also advantageously reduces the risk of overheating of the optical components compared to known optical systems that use a single optical element to interact with two laser pulses. , and thereby be deformed or damaged.

另外,本發明之光學系統有利地使得塗層選擇程序更容易,從而允許將熟知塗層用於每一雷射脈衝或雷射射束。Additionally, the optical system of the present invention advantageously facilitates the coating selection process, allowing well-known coatings to be used for each laser pulse or laser beam.

雖然圖2僅繪示第一雷射脈衝110及第二雷射脈衝120,但光學系統100可將另一雷射脈衝導向至目標。舉例而言,第三光學組件170可經組態以在塑形雷射脈衝150之中空區155內使第三雷射脈衝(圖中未示)沿著光軸130聚焦至目標。第一雷射脈衝、第二雷射脈衝及第三雷射脈衝沿著光軸130之相對定位的實例自透視圖繪示於圖3中。Although FIG. 2 only shows the first laser pulse 110 and the second laser pulse 120, the optical system 100 can guide another laser pulse to the target. For example, third optical component 170 may be configured to focus a third laser pulse (not shown) along optical axis 130 to a target within hollow region 155 of shaped laser pulse 150 . An example of the relative positioning of the first, second, and third laser pulses along the optical axis 130 is illustrated in FIG. 3 from a perspective view.

圖3示意性地描繪圖1之輻射收集器的孔徑20之正視圖。輻射收集器之孔徑20共軸配置於光軸130上。因此,輻射收集器之孔徑20關於第一光學組件140、第二光學組件160及第三光學組件170及目標共軸對準(例如,圖1之電漿形成方位4)。圖3中繪示之視圖可被視為沿著光軸130的數值孔徑視圖。即,由不同雷射脈衝120、150、200佔據之空間可對應於由該等雷射脈衝佔據的不同入射角度。第二脈衝120具有定中心於光軸130上的圓形橫截面形狀。第三雷射脈衝200亦具有定中心於光軸130上的圓形橫截面形狀。第三雷射脈衝200之直徑大於第二雷射脈衝120的直徑。塑形雷射脈衝150具有定中心於光軸130上的環形橫截面形狀。塑形雷射脈衝150之中空區155具有定中心於光軸130上的環形橫截面形狀。第二雷射脈衝120及第三雷射脈衝200定位於塑形雷射射束150的中空區155內。Figure 3 schematically depicts a front view of the aperture 20 of the radiation collector of Figure 1 . The aperture 20 of the radiation collector is coaxially arranged on the optical axis 130 . Thus, the aperture 20 of the radiation collector is coaxially aligned with respect to the first optical component 140 , the second optical component 160 , and the third optical component 170 and the target (eg, plasma formation orientation 4 of FIG. 1 ). The view depicted in FIG. 3 can be viewed as a numerical aperture view along the optical axis 130 . That is, the space occupied by different laser pulses 120, 150, 200 may correspond to different angles of incidence occupied by the laser pulses. The second pulse 120 has a circular cross-sectional shape centered on the optical axis 130 . The third laser pulse 200 also has a circular cross-sectional shape centered on the optical axis 130 . The diameter of the third laser pulse 200 is larger than the diameter of the second laser pulse 120 . Shaping laser pulse 150 has an annular cross-sectional shape centered on optical axis 130 . The hollow region 155 of the shaping laser pulse 150 has an annular cross-sectional shape centered on the optical axis 130 . The second laser pulse 120 and the third laser pulse 200 are positioned within the hollow region 155 of the shaped laser beam 150 .

第二光學組件(圖3中未繪示)經組態以通過孔徑20且朝向目標使塑形雷射脈衝150聚焦。第三光學組件(圖3中未繪示)經組態以通過孔徑20且朝向目標使第二雷射脈衝120聚焦。在沿著光軸130朝向目標傳播時,塑形雷射脈衝150並不佔據與第二雷射脈衝120及第三雷射脈衝200相同的空間,而第三雷射脈衝200之部分佔據與第二雷射脈衝120相同的空間。然而,每一雷射脈衝120、150、200朝向目標聚焦,且因此可入射於目標之同一部分上。A second optical component (not shown in Figure 3) is configured to focus the shaping laser pulse 150 through the aperture 20 and toward the target. A third optical component (not shown in Figure 3) is configured to focus the second laser pulse 120 through the aperture 20 and toward the target. When propagating toward the target along the optical axis 130, the shaping laser pulse 150 does not occupy the same space as the second laser pulse 120 and the third laser pulse 200, but part of the third laser pulse 200 occupies the same space as the second laser pulse 120 and the third laser pulse 200. Two laser pulses 120 in the same space. However, each laser pulse 120, 150, 200 is focused towards the target and therefore may be incident on the same part of the target.

在另一實施例中,雷射脈衝120及200可在第三光學組件170上緊接於彼此定位。因此,第三光學組件170經組態以使該等脈衝聚焦,即使其置放於該第三光學組件170的不同區域中。此情形意謂,第二雷射脈衝120及第三雷射脈衝200靠近於軸線。因此,關於光軸130的角度相比於目前技術的其他配置經減小,此情形又有利地增大極紫外線輻射源SO的轉化效率。In another embodiment, laser pulses 120 and 200 may be positioned immediately adjacent to each other on third optical component 170 . Therefore, the third optical component 170 is configured to focus the pulses even if they are placed in different areas of the third optical component 170 . This situation means that the second laser pulse 120 and the third laser pulse 200 are close to the axis. Therefore, the angle with respect to the optical axis 130 is reduced compared to other configurations of the state of the art, which in turn advantageously increases the conversion efficiency of the extreme ultraviolet radiation source SO.

將瞭解,每一雷射脈衝120、150、200沿著光軸130行進,且在不同時間到達目標。圖3的視圖同時繪示所有三個雷射脈衝以便為易於理解展現雷射脈衝120、150、200的相對位置。It will be appreciated that each laser pulse 120, 150, 200 travels along the optical axis 130 and reaches the target at a different time. The view of Figure 3 depicts all three laser pulses simultaneously to demonstrate the relative positions of laser pulses 120, 150, 200 for ease of understanding.

每一雷射脈衝包含用於以不同方式與目標相互作用的一或多個不同特性(例如,波長、電力、形狀等)。第二雷射脈衝120可首先到達目標。第二雷射脈衝120可經組態以改變目標的形狀。舉例而言,第二雷射脈衝120可經組態以使目標自小液滴形狀改變至扁平圓形,或「餅乾」形狀。第二雷射脈衝120可包含大約1030 nm或約1064 nm的波長。第二雷射脈衝120可藉由任何適合的雷射,諸如固態雷射、半導體雷射等中的一或多者來產生。Each laser pulse contains one or more different characteristics (eg, wavelength, power, shape, etc.) for interacting with the target in a different manner. The second laser pulse 120 may reach the target first. The second laser pulse 120 can be configured to change the shape of the target. For example, the second laser pulse 120 may be configured to cause the target to change from a small droplet shape to a flat circular, or "cookie" shape. The second laser pulse 120 may include a wavelength of approximately 1030 nm or approximately 1064 nm. The second laser pulse 120 may be generated by any suitable laser, such as one or more of a solid-state laser, a semiconductor laser, and the like.

第三雷射脈衝200可第二個到達目標。即,在第二雷射脈衝120之後且在第一雷射脈衝110之前,第三雷射脈衝200可入射於目標上。第三雷射脈衝200可經組態以製備用於接收第一雷射脈衝110的目標。舉例而言,第三雷射脈衝200可經組態以在製備中使目標霧化(亦即,類似於氣態狀態,將餅乾小液滴轉換為許多小粒子)從而接收第一雷射脈衝110用於產生EUV輻射。第三雷射脈衝200可用來增大第一雷射脈衝110由目標的吸收。第三雷射脈衝200可具有大約1064 nm的波長。第三雷射脈衝200可藉由任何適合的雷射,諸如固態雷射、半導體雷射等中的一或多者來產生。單一雷射可用以產生第二雷射脈衝120及第三雷射脈衝200。The third laser pulse 200 may reach the target second. That is, after the second laser pulse 120 and before the first laser pulse 110, the third laser pulse 200 may be incident on the target. The third laser pulse 200 may be configured to prepare the target for receiving the first laser pulse 110 . For example, the third laser pulse 200 may be configured to atomize the target in preparation (ie, convert cookie droplets into many small particles similar to a gaseous state) to receive the first laser pulse 110 Used to generate EUV radiation. The third laser pulse 200 may be used to increase absorption of the first laser pulse 110 by the target. The third laser pulse 200 may have a wavelength of approximately 1064 nm. The third laser pulse 200 may be generated by any suitable laser, such as one or more of a solid-state laser, a semiconductor laser, and the like. A single laser can be used to generate the second laser pulse 120 and the third laser pulse 200 .

應理解,霧化目標的另一定義可正使目標變稀薄。It should be understood that another definition of atomizing a target could be thinning the target.

第一雷射脈衝110可最後到達目標。即,在第二雷射脈衝120且在第三雷射脈衝200之後,第一雷射脈衝110可入射於目標上。第一雷射脈衝110可經組態以使得目標發射EUV輻射。舉例而言,第一雷射脈衝110可將目標轉換成發射EUV輻射的電漿。第一雷射脈衝110可包含約10.6 µm的波長。第一雷射脈衝110可藉由任何適合中之一或多者的雷射,諸如CO 2雷射來產生。 The first laser pulse 110 may reach the target last. That is, after the second laser pulse 120 and after the third laser pulse 200, the first laser pulse 110 may be incident on the target. The first laser pulse 110 may be configured to cause the target to emit EUV radiation. For example, the first laser pulse 110 may convert the target into a plasma that emits EUV radiation. The first laser pulse 110 may include a wavelength of approximately 10.6 µm. The first laser pulse 110 may be generated by any suitable one or more lasers, such as a CO2 laser.

如先前參看圖1所描述,收集器5反射之輻射形成EUV輻射射束B。EUV輻射射束B聚焦於中間焦點6處,以在存在於電漿形成區4處之電漿之中間焦點6處形成影像。中間焦點6處之影像充當用於照射系統IL之虛擬輻射源。相較於已知光學系統,雷射脈衝120、150、200之共軸配置(例如,如圖3中所繪示)歸因於雷射脈衝120、150、200與光軸130之間的角度偏移的減小提供多個優勢。As previously described with reference to Figure 1, the radiation reflected by collector 5 forms beam B of EUV radiation. The EUV radiation beam B is focused at the intermediate focus 6 to form an image at the intermediate focus 6 of the plasma present in the plasma formation region 4 . The image at intermediate focus 6 serves as a virtual radiation source for illuminating system IL. In contrast to known optical systems, the coaxial configuration of the laser pulses 120, 150, 200 (eg, as shown in Figure 3) is due to the angle between the laser pulses 120, 150, 200 and the optical axis 130 The reduction in offset provides several advantages.

先前段落之實例可適用於具有高數值孔徑NA光學件的微影系統。對於EUV微影系統,關於高NA,應理解為具有高於0.33,例如0.55之NA的系統。高NA光學件產生該等光學件的較短有效焦距。雷射脈衝120、150、200之共軸配置(例如,如圖3中所繪示)為高NA系統提供額外優勢:射束聚焦位置對輸入射束傾斜度的較低靈敏度。眾所周知的是,此傾斜度可歸因於雷射抖動而引起。因此,本發明之光學系統有利地產生高NA EUV微影系統的更穩定EUV輻射劑量。The examples of the previous paragraphs are applicable to lithography systems with high numerical aperture NA optics. For EUV lithography systems, by high NA is understood to be systems with an NA higher than 0.33, for example 0.55. High NA optics yield a shorter effective focal length for these optics. A coaxial configuration of laser pulses 120, 150, 200 (eg, as shown in Figure 3) provides an additional advantage for high NA systems: lower sensitivity of the beam focus position to input beam tilt. It is known that this tilt can be attributed to laser jitter. Therefore, the optical system of the present invention advantageously produces more stable EUV radiation doses for high NA EUV lithography systems.

相較於已知光學系統,雷射脈衝120、150、200之共軸配置減小目標上第一雷射脈衝110之入射角與目標上第二雷射脈衝120之入射角之間的角度。此情形有利地改良輻射源SO及/或包含光學系統100之微影設備LA的效率,此係因為較小EUV輻射在目標處及/或遠場中(即,在微影設備LA之照明系統IS及/或投影系統PS)失去。目標上第一雷射脈衝110之入射角與目標上第二雷射脈衝120之入射角之間的角度可實質上為零。Compared to known optical systems, the coaxial arrangement of laser pulses 120, 150, 200 reduces the angle between the angle of incidence of the first laser pulse 110 on the target and the angle of incidence of the second laser pulse 120 on the target. This situation advantageously improves the efficiency of the radiation source SO and/or the lithography apparatus LA including the optical system 100 since less EUV radiation is present at the target and/or in the far field (ie, in the illumination system of the lithography apparatus LA IS and/or projection system PS) is lost. The angle between the angle of incidence of the first laser pulse 110 on the target and the angle of incidence of the second laser pulse 120 on the target may be substantially zero.

相較於已知光學系統,雷射脈衝120、150、200之共軸配置減小目標處第一雷射脈衝110之入射角與光軸130之間的角度,輻射收集器之孔徑20定中心於該光軸130上。此情形有利地改良輻射源SO及/或包含光學系統100之微影設備LA的效率,此係因為較小EUV輻射經由EUV輻射在遠場中之傾斜度失去(即,在微影設備LA的照明系統IS及/或投影系統PS中)。此外,EUV輻射在中間焦點6處之失去歸因於電漿在中間焦點處的影像(亦即,照明系統IS的虛擬輻射源)並未傾斜而被減小。目標處第一雷射脈衝110之入射角與光軸130之間的角度可實質上為零,輻射收集器之孔徑20定中心於該光軸130上。Compared to known optical systems, the coaxial configuration of laser pulses 120, 150, 200 reduces the angle between the angle of incidence of the first laser pulse 110 at the target and the optical axis 130, centering the aperture 20 of the radiation collector on the optical axis 130. This situation advantageously improves the efficiency of the radiation source SO and/or the lithography apparatus LA containing the optical system 100 since less EUV radiation is lost via the inclination of the EUV radiation in the far field (i.e. in the lithography apparatus LA lighting system IS and/or projection system PS). Furthermore, the loss of EUV radiation at the intermediate focus 6 is reduced due to the fact that the image of the plasma at the intermediate focus (ie, the virtual radiation source of the illumination system IS) is not tilted. The angle between the angle of incidence of the first laser pulse 110 at the target and the optical axis 130 on which the aperture 20 of the radiation collector is centered can be substantially zero.

相較於已知光學系統,雷射脈衝120、150、200之共軸配置增大可用於雷射脈衝110、120、200的數值孔徑。增大可用於雷射脈衝110、120、200之數值孔徑有利地減低光學像差的存在,此情形又可減小EUV輻射的失去及/或減小在光學系統100及/或微影設備LA中發生的非所要背向反射的強度。增大可用於雷射脈衝110、120、200之數值孔徑亦有利地減小第三雷射脈衝200在目標處的限值,此情形又可改良EUV輻射產生的效率。The coaxial configuration of laser pulses 120, 150, 200 increases the numerical aperture available for laser pulses 110, 120, 200 compared to known optical systems. Increasing the numerical aperture available for the laser pulses 110, 120, 200 advantageously reduces the presence of optical aberrations, which in turn reduces the loss of EUV radiation and/or reduces the interference in the optical system 100 and/or the lithography apparatus LA. The intensity of undesired back reflections that occur in Increasing the numerical aperture available for laser pulses 110, 120, 200 also advantageously reduces the limit of the third laser pulse 200 at the target, which in turn improves the efficiency of EUV radiation generation.

雷射脈衝120、150、200之共軸配置有利地增大極紫外線輻射源SO的轉化效率。The coaxial configuration of the laser pulses 120, 150, 200 advantageously increases the conversion efficiency of the extreme ultraviolet radiation source SO.

雷射脈衝120、150、200之共軸配置有利地增大入射於目標上之第一雷射脈衝110之射束輪廓的穩定性及再現性,此情形在併入光學系統100時又改良EUV產生及微影印刷的效率及穩定性。The coaxial configuration of the laser pulses 120, 150, 200 advantageously increases the stability and reproducibility of the beam profile of the first laser pulse 110 incident on the target, which improves EUV when incorporated into the optical system 100 The efficiency and stability of production and lithography printing.

圖2之光學系統為包含反射組件之光學系統的實例。亦可使用包含其他光學組件,例如透射光學組件的緊湊之共軸光學系統。The optical system of Figure 2 is an example of an optical system including a reflective component. Compact coaxial optical systems containing other optical components, such as transmission optics, may also be used.

圖4示意性地描繪根據本發明之一實施例的包含透射性光學組件之替代性光學系統400的橫截面側視圖。如同圖2之光學系統100的狀況一般,替代性光學系統400適合於沿著光軸130將第一雷射脈衝110及第二雷射脈衝120導向至目標(例如,圖1中所繪示之電漿形成區4的燃料小液滴)以自該目標產生EUV輻射。替代性光學系統400包含第一光學組件440,其經組態以使第一雷射脈衝110重新分佈以形成具有中空區155的塑形雷射脈衝150。在圖4之實例中,第一光學組件440包含第一光學元件441及第二光學元件442。第一光學元件441包含射束擴展器,其經組態以將第一雷射脈衝110轉換為發散射束。第二光學元件442包含軸錐體透鏡,其經組態以自第一光學元件441接收第一雷射脈衝110且空間重新分佈第一雷射脈衝110的能量。第二光學元件442之軸錐體透鏡藉由在不同方向上透射第一雷射脈衝110的不同部分而空間上重新分佈第一雷射脈衝110的能量以形成具有中空區155的塑形雷射脈衝450。Figure 4 schematically depicts a cross-sectional side view of an alternative optical system 400 including a transmissive optical component in accordance with one embodiment of the present invention. As with optical system 100 of Figure 2, alternative optical system 400 is adapted to direct first laser pulse 110 and second laser pulse 120 along optical axis 130 to a target (eg, as shown in Figure 1 The plasma forms fuel droplets in zone 4) to generate EUV radiation from the target. The alternative optical system 400 includes a first optical component 440 configured to redistribute the first laser pulse 110 to form a shaped laser pulse 150 having a hollow region 155 . In the example of FIG. 4 , the first optical component 440 includes a first optical element 441 and a second optical element 442 . The first optical element 441 includes a beam expander configured to convert the first laser pulse 110 into a divergent beam. The second optical element 442 includes an axicon lens configured to receive the first laser pulse 110 from the first optical element 441 and spatially redistribute the energy of the first laser pulse 110 . The axicon lens of the second optical element 442 spatially redistributes the energy of the first laser pulse 110 by transmitting different portions of the first laser pulse 110 in different directions to form a shaped laser with a hollow region 155 Pulse 450.

替代性光學系統400包含經組態以使塑形雷射脈衝150朝向目標聚焦的第二光學組件460。在圖4之實例中,第二光學組件460包含第三光學元件461及第四光學元件462。第三光學元件461包含經組態以使塑形雷射脈衝150準直的準直器。第四光學元件462包含透鏡,其經組態以自第三光學元件461接收塑形雷射脈衝150,且使塑形雷射脈衝150朝向目標(圖中未示)沿著光軸130聚焦。The alternative optical system 400 includes a second optical component 460 configured to focus the shaping laser pulse 150 toward a target. In the example of FIG. 4 , the second optical component 460 includes a third optical element 461 and a fourth optical element 462 . The third optical element 461 includes a collimator configured to collimate the shaping laser pulse 150 . The fourth optical element 462 includes a lens configured to receive the shaping laser pulse 150 from the third optical element 461 and focus the shaping laser pulse 150 along the optical axis 130 toward a target (not shown).

替代性光學系統400包含一第三光學組件470,其經組態以在塑形雷射脈衝450之中空區455內使第二雷射脈衝120朝向該目標聚焦。在圖4之實例中,第三光學組件470包含透鏡,其經組態以在塑形雷射脈衝450之中空區455內使第二雷射脈衝120朝向目標沿著光軸130聚焦。第一光學組件440、第二光學組件460及第三光學組件470共軸配置於光軸130上。The alternative optical system 400 includes a third optical component 470 configured to focus the second laser pulse 120 toward the target within the hollow region 455 of the shaped laser pulse 450 . In the example of FIG. 4 , the third optical component 470 includes a lens configured to focus the second laser pulse 120 toward the target along the optical axis 130 within the hollow region 455 of the shaped laser pulse 450 . The first optical component 440 , the second optical component 460 and the third optical component 470 are coaxially arranged on the optical axis 130 .

在另一實施例中,第三光學元件可為開口或孔徑。在該實施例中,額外光學元件可位於上游,該額外光學元件經組態以使第二雷射脈衝120聚焦。In another embodiment, the third optical element may be an opening or aperture. In this embodiment, additional optical elements may be located upstream configured to focus the second laser pulse 120 .

不管包含透射性組件而非反射組件,替代性光學系統400調節雷射脈衝110、120以達成與圖2之光學系統100相同的結果(即,繪示於圖3中之雷射脈衝110、150、200的共軸配置)。替代性光學系統400可包含經組態以接收由目標發射之EUV輻射的輻射收集器(圖中未示),且輻射收集器可包含共軸配置於光軸130上的孔徑。第二光學組件460及第三光學組件470可經組態以通過輻射收集器之孔徑使塑形雷射脈衝150及第二雷射脈衝120聚焦。第二光學組件460包含共軸配置於光軸130上的開口490。第三光學組件470可經組態以在塑形雷射脈衝450之中空區455內使第三雷射脈衝(圖中未示)沿著光軸130聚焦至目標。第三雷射脈衝可包含不同於第一雷射脈衝110及第二雷射脈衝120的波長(例如,第三雷射脈衝可為繪示於圖3中的第三雷射脈衝200)。Regardless of including transmissive components rather than reflective components, the alternative optical system 400 modulates the laser pulses 110 , 120 to achieve the same results as the optical system 100 of FIG. 2 (i.e., the laser pulses 110 , 150 depicted in FIG. 3 , 200 coaxial configuration). Alternative optical system 400 may include a radiation collector (not shown) configured to receive EUV radiation emitted by the target, and the radiation collector may include an aperture disposed coaxially on optical axis 130 . The second optical component 460 and the third optical component 470 may be configured to focus the shaped laser pulse 150 and the second laser pulse 120 through the aperture of the radiation collector. The second optical component 460 includes an opening 490 coaxially arranged on the optical axis 130 . The third optical component 470 may be configured to focus a third laser pulse (not shown) along the optical axis 130 to the target within the hollow region 455 of the shaped laser pulse 450 . The third laser pulse may include a different wavelength than the first laser pulse 110 and the second laser pulse 120 (eg, the third laser pulse may be the third laser pulse 200 illustrated in FIG. 3 ).

第一光學組件440經組態以僅與第一雷射脈衝110相互作用。第二光學組件460經組態以僅與塑形雷射脈衝150相互作用。第三光學組件470經組態以僅與第二雷射脈衝120相互作用。此情形有利地允許每一光學組件440、460、470經定製以與其各別雷射脈衝110、120相互作用。舉例而言,第一雷射脈衝110且因此塑形雷射脈衝150可具有約10.6 µm的波長。第一光學組件440及第二光學組件460可因此經具體設計為對於約10.6 µm的波長儘可能為透射性的。舉例而言,第一光學組件140及/或第二光學組件160可包含諸如ZnSe的材料。作為另一個實例,第二雷射脈衝120可具有約1030 nm或約1064 nm的波長。第三光學組件470可因此具體而言經設計為對於約1030 nm或約1064 nm的波長儘可能為反射性的。舉例而言,第三光學組件170可包含材料,諸如石英、熔融矽石、BK7等。相較於使用單一光學元件與兩個雷射脈衝相互作用的已知光學系統,將不同光學組件440、460、470致力於不同雷射脈衝110、120亦有利地減小光學組件過度加熱的風險,且藉此防止變形或受到損害。The first optical component 440 is configured to interact only with the first laser pulse 110 . The second optical component 460 is configured to interact only with the shaping laser pulse 150 . The third optical component 470 is configured to interact only with the second laser pulse 120 . This advantageously allows each optical component 440, 460, 470 to be customized to interact with its respective laser pulse 110, 120. For example, the first laser pulse 110 and thus the shaping laser pulse 150 may have a wavelength of approximately 10.6 μm. The first optical component 440 and the second optical component 460 may therefore be specifically designed to be as transmissive as possible for a wavelength of approximately 10.6 μm. For example, the first optical component 140 and/or the second optical component 160 may include a material such as ZnSe. As another example, second laser pulse 120 may have a wavelength of about 1030 nm or about 1064 nm. The third optical component 470 may therefore be designed in particular to be as reflective as possible for wavelengths of about 1030 nm or about 1064 nm. For example, the third optical component 170 may include materials such as quartz, fused silica, BK7, etc. Dedicating different optical components 440, 460, 470 to different laser pulses 110, 120 also advantageously reduces the risk of overheating of the optical components compared to known optical systems that use a single optical element to interact with two laser pulses. , and thereby prevent deformation or damage.

圖5繪示根據本發明之一實施例的沿著光軸將第一雷射脈衝及第二雷射脈衝導向至目標以自該目標產生極紫外線輻射之方法的流程圖。將瞭解,使用措詞「第一步驟」、「第二步驟」等並不指示步驟之時間次序,且確切而言僅用以區分方法的步驟。舉例而言,第二步驟602可在第一步驟601之前執行。如上文所解釋,應瞭解,各種脈衝並未同時入射於目標上。方法之第一步驟601包含使用第一光學組件以使一第一雷射脈衝重新分佈以形成具有中空區之塑形雷射脈衝。方法之第二步驟602包含使用第二光學組件來朝向目標聚焦塑形雷射脈衝。方法之第三步驟603包含使用第三光學組件以在塑形雷射脈衝之中空區內使第二雷射脈衝朝向目標聚焦。方法之第四步驟604包含在光軸上共軸配置第一光學組件、第二光學組件及第三光學組件。將瞭解,圖2之光學系統100或圖4之替代性光學系統400可用以執行圖5的方法。5 illustrates a flowchart of a method of directing a first laser pulse and a second laser pulse along an optical axis to a target to generate extreme ultraviolet radiation from the target, according to one embodiment of the present invention. It will be understood that use of the terms "first step," "second step," etc. does not indicate a temporal order of steps, but rather is used only to distinguish steps of a method. For example, the second step 602 may be performed before the first step 601. As explained above, it should be understood that the various pulses are not incident on the target simultaneously. The first step 601 of the method includes using a first optical component to redistribute a first laser pulse to form a shaped laser pulse with a hollow region. The second step 602 of the method includes using a second optical component to focus the shaped laser pulse toward the target. The third step 603 of the method includes using a third optical component to focus the second laser pulse toward the target within the hollow region of the shaped laser pulse. The fourth step 604 of the method includes arranging the first optical component, the second optical component and the third optical component coaxially on the optical axis. It will be appreciated that the optical system 100 of FIG. 2 or the alternative optical system 400 of FIG. 4 may be used to perform the method of FIG. 5 .

方法可包含將第一光學組件及第三光學組件定位於單一光學元件(例如,圖2中繪示之單一光學元件180)之不同表面上的可選步驟。方法可包含將第一光學組件定位於單一光學元件之前側上的可選步驟。方法可包含將第三光學組件定位於單一光學元件之背側上的可選步驟。The method may include the optional step of positioning the first optical component and the third optical component on different surfaces of a single optical element (eg, single optical element 180 illustrated in Figure 2). The method may include the optional step of positioning the first optical component on the front side of the single optical element. The method may include the optional step of positioning a third optical component on the backside of the single optical element.

方法可包含使用輻射收集器以接收由目標發射之極紫外線輻射(例如,圖1中所繪示的輻射收集器5)之可選步驟。方法可包含在光軸上共軸配置輻射收集器之孔徑(例如,圖3中繪示之孔徑20)的可選步驟。The method may include the optional step of using a radiation collector to receive extreme ultraviolet radiation emitted by the target (eg, radiation collector 5 illustrated in Figure 1). The method may include the optional step of arranging the aperture of the radiation collector (eg, aperture 20 illustrated in Figure 3) coaxially on the optical axis.

方法可包含使用第二光學組件及第三光學組件來通過孔徑聚焦塑形雷射脈衝及第二雷射脈衝(例如,如由圖2或圖4之光學系統執行的繪示於圖3中之共軸配置)的可選步驟。The method may include using the second optical component and the third optical component to focus the shaping of the laser pulse and the second laser pulse through the aperture (e.g., as shown in FIG. 3 as performed by the optical system of FIG. 2 or FIG. 4 Optional step for coaxial configuration).

方法可包含使用第一光學組件以僅與第一雷射脈衝相互作用的可選步驟。方法可包含使用第二光學組件以僅與塑形雷射脈衝相互作用的可選步驟。方法可包含使用第三光學組件以僅與第二雷射脈衝相互作用的可選步驟。此等可選步驟中之每一者由例如圖2及圖4之光學系統來表明。The method may include the optional step of using the first optical component to interact only with the first laser pulse. The method may include the optional step of using a second optical component to interact only with the shaping laser pulse. The method may include the optional step of using a third optical component to interact only with the second laser pulse. Each of these optional steps is illustrated by optical systems such as Figures 2 and 4.

方法可包含在第二光學組件中設置開口的可選步驟。方法可包含在光軸上共軸配置開口的可選步驟。此等可選步驟中之每一者由例如圖2及圖4之光學系統來表明。The method may include the optional step of providing an opening in the second optical component. The method may include the optional step of arranging the openings coaxially on the optical axis. Each of these optional steps is illustrated by optical systems such as Figures 2 and 4.

方法可包含使用第三光學組件以在塑形脈衝之中空區內使一第三雷射脈衝沿著光軸聚焦至目標的可選步驟。該第三雷射脈衝可包含不同於第一雷射脈衝及第二雷射脈衝的波長。此等可選步驟中之每一者由例如如由圖2 (或圖4)之光學系統執行的圖3之共軸配置表明。The method may include the optional step of using a third optical component to focus a third laser pulse along the optical axis to the target within the hollow region of the shaped pulse. The third laser pulse may include a different wavelength than the first laser pulse and the second laser pulse. Each of these optional steps is illustrated by, for example, the coaxial configuration of Figure 3 as performed by the optical system of Figure 2 (or Figure 4).

一種將圖案化輻射射束投影至基板上之方法可包含使用圖5之方法,及其任一可選步驟以產生極紫外線輻射(例如,如由形成圖1之微影設備LA之部分的光學系統100所繪示)。A method of projecting a patterned radiation beam onto a substrate may include using the method of Figure 5, along with any optional steps to generate extreme ultraviolet radiation (e.g., as provided by the optics forming part of the lithography apparatus LA of Figure 1 System 100 is shown).

儘管可在本文中特定地參考微影設備在IC製造中之使用,但應理解,本文中所描述之微影設備可具有其他應用。可能的其他應用包括製造整合式光學系統、用於磁疇記憶體之導引及偵測、平板顯示器、液晶顯示器(LCD)、薄膜磁頭,等等。Although specific reference may be made herein to the use of lithography equipment in IC fabrication, it will be understood that the lithography equipment described herein may have other applications. Possible other applications include the manufacture of integrated optical systems, guidance and detection for magnetic domain memories, flat panel displays, liquid crystal displays (LCDs), thin film magnetic heads, etc.

儘管可在本文中特定地參考在微影設備之上下文中的本發明之實施例,但本發明之實施例可用於其他設備。本發明之實施例可形成以下各者的部分:光罩檢測設備、度量衡設備,或者量測或處理諸如晶圓(或其他基板)或光罩(或其他圖案化裝置)之物件之任何設備。此等設備可通常被稱作微影工具。此微影工具可使用真空條件或環境(非真空)條件。Although specific reference may be made herein to embodiments of the invention in the context of lithography equipment, embodiments of the invention may be used in other equipment. Embodiments of the present invention may form part of a reticle inspection equipment, a metrology equipment, or any equipment that measures or processes items such as wafers (or other substrates) or reticles (or other patterned devices). Such equipment may generally be referred to as lithography tools. This lithography tool can be used under vacuum conditions or ambient (non-vacuum) conditions.

在上下文允許之情況下,可以硬體、韌體、軟體或其任何組合實施本發明之實施例。舉例而言,本發明之實施例可使用包含電腦可讀指令之電腦程式來實施,該等電腦可讀指令經組態以使得電腦進行根據本發明的方法。本發明的實施例可包括攜載該電腦程式的電腦可讀媒體。作為另一個實例,本發明的實施例可使用電腦設備來實施,該電腦設備包含儲存處理器可讀指令的記憶體及經配置以讀取且執行儲存於該記憶體中之指令的處理器。該等處理器可讀指令包含經配置以控制電腦進行根據本發明之實施例之方法的指令。本發明之實施例亦可被實施為儲存於機器可讀媒體上之指令,該等指令可由一或多個處理器讀取及執行。機器可讀媒體可包括用於儲存或傳輸呈可由機器(例如,計算裝置)讀取之形式之資訊的任何機構。舉例而言,機器可讀媒體可包括:唯讀記憶體(ROM);隨機存取記憶體(random access memory;RAM);磁性儲存媒體;光學儲存媒體;快閃記憶體裝置;電學、光學、聲學或其他形式之傳播信號(例如,載波、紅外信號、數位信號等)及其他。另外,韌體、軟件、常式、指令可在本文中被描述為執行某些動作。然而,應瞭解,此等描述僅僅為方便起見,且此等動作事實上係由計算裝置、處理器、控制器或執行韌體、軟體、常式、指令等等之其他裝置產生;且如此進行可引起致動器或其他裝置與實體世界交互。Where the context permits, embodiments of the invention may be implemented in hardware, firmware, software, or any combination thereof. For example, embodiments of the invention may be implemented using a computer program comprising computer readable instructions configured to cause a computer to perform methods according to the invention. Embodiments of the invention may include computer-readable media carrying the computer program. As another example, embodiments of the invention may be implemented using a computer device that includes a memory storing processor-readable instructions and a processor configured to read and execute the instructions stored in the memory. The processor-readable instructions include instructions configured to control the computer to perform methods according to embodiments of the invention. Embodiments of the invention may also be implemented as instructions stored on a machine-readable medium, which instructions may be read and executed by one or more processors. Machine-readable media may include any mechanism for storing or transmitting information in a form readable by a machine (eg, a computing device). For example, machine-readable media may include: read-only memory (ROM); random access memory (RAM); magnetic storage media; optical storage media; flash memory devices; electrical, optical, Acoustic or other forms of propagated signals (such as carrier waves, infrared signals, digital signals, etc.) and others. In addition, firmware, software, routines, and instructions may be described herein as performing certain actions. However, it should be understood that such descriptions are for convenience only and that such actions are in fact produced by a computing device, processor, controller or other device executing firmware, software, routines, instructions, etc.; and so Performing can cause an actuator or other device to interact with the physical world.

雖然上文已描述本發明之特定實施例,但將瞭解,可以與所描述之方式不同的其他方式來實踐本發明。以上描述意欲為說明性,而非限制性的。因此,對於熟習此項技術者將顯而易見的是,可在不偏離下文所闡明之條項之範疇的情況下對所描述之本發明進行修改。 1.     一種用於沿著一光軸將第一雷射脈衝及第二雷射脈衝導向至一目標以自該目標產生極紫外線輻射之光學系統,其包含: 一第一光學組件,其經組態以使該第一雷射脈衝重新分佈以形成具有一中空區之一塑形雷射脈衝; 一第二光學組件,其經組態以使該塑形雷射脈衝朝向該目標聚焦;及, 一第三光學組件,其經組態以在該塑形雷射脈衝之該中空區內使該第二雷射脈衝朝向該目標聚焦,其中該第一光學組件、該第二光學組件及該第三光學組件共軸配置於該光軸上。 2.     如條項1之光學系統,其中該第一雷射脈衝及該第二雷射脈衝包含不同波長。 3.     如條項1或條項2之光學系統,其中該第一光學組件及該第三光學組件位於一單一光學元件之不同表面上。 4.     如條項3之光學系統,其中該第一光學組件形成於該單一光學元件之一前側上,且該第三光學組件形成於該單一光學元件之一背側上。 5.     如任一前述條項之光學系統,其包含經組態以接收由該目標發射之極紫外線輻射的一輻射收集器,其中該輻射收集器包含共軸配置於該光軸上之一孔徑,且其中該第二光學組件及該第三光學組件經組態以通過該孔徑使該塑形且第二雷射脈衝聚焦。 6.     如任一前述條項之光學系統,其中該第二光學組件經組態以僅與塑形雷射脈衝相互作用,且該第三光學組件經組態以僅與該第二雷射脈衝相互作用。 7.     如任一前述條項之光學系統,其中該第二光學組件包含共軸配置於該光軸上之一開口。 8.     如任一前述條項之光學系統,其中該第三光學組件經組態以在該塑形雷射脈衝之中空區內使一第三雷射脈衝沿著該光軸聚焦至該目標,其中該第三雷射脈衝包含不同於該第一雷射脈衝及第二雷射脈衝的波長。 9.     一種極紫外線輻射源,其包含如條項1至8中任一項之光學系統。 10.   一種微影系統,其包含條項9之極紫外線輻射源。 11.    一種沿著一光軸將第一雷射脈衝及第二雷射脈衝導向至一目標以自該目標產生極紫外線輻射之方法,其包含: 使用一第一光學組件以使該第一雷射脈衝重新分佈以形成具有一中空區之一塑形雷射脈衝; 使用一第二光學組件以使該塑形雷射脈衝朝向該目標聚焦; 使用一第三光學組件以在該塑形雷射脈衝之該中空區內使該第二雷射脈衝朝向該目標聚焦;及, 在該光軸上共軸配置該第一光學組件、該第二光學組件及該第三光學組件。 12.   如條項11之方法,其中該第一雷射脈衝及該第二雷射脈衝包含不同波長之輻射。 13.   如條項11或條項12之方法,其包含在一單一光學元件之不同表面上定位該第一光學組件及該第三光學組件。 14.   如條項13之方法,其包含: 將該第一光學組件定位於該單一光學元件之一前側上;及, 將該第三光學組件定位於該單一光學元件之一背側上。 15.   如條項11至14中任一項之方法,其包含: 使用一輻射收集器來接收由該目標發射之極紫外線輻射; 在該光軸上共軸配置該輻射收集器之一孔徑;及, 使用該第二光學組件及該第三光學組件來通過該孔徑使該塑形雷射脈衝及該第二雷射脈衝聚焦。 16.   如條項11至15中任一項之方法,其包含: 使用該第二光學組件以僅與該塑形雷射脈衝相互作用;及, 使用該第三光學組件以僅與該第二雷射脈衝相互作用。 17.   如條項11至16中任一項之方法,其包含: 在該第二光學組件中提供一開口;及, 在該光軸上共軸配置該開口。 18.   如條項11至17中任一項之方法,其包含使用該第三光學組件以在該塑形脈衝之該中空區內使一第三雷射脈衝沿著該光軸聚焦至該目標,其中該第三雷射脈衝包含不同於該第一雷射脈衝及該第二雷射脈衝的一波長。 19.   一種將一圖案化輻射射束投影至一基板上之方法,其包含使用如條項11至18中任一項之方法以產生極紫外線輻射。 20.   一種包含電腦可讀指令的電腦程式,該等電腦可讀指令經組態以使得一電腦進行如條項11至19中任一項之方法。 21.   一種電腦可讀媒體,其攜載如條項20之電腦程式。 22.   一種電腦設備,其包含: 一記憶體,其儲存處理器可讀指令;及 一處理器,其經配置以讀取及執行儲存於該記憶體中之指令; 其中該等處理器可讀指令包含指令,該等指令經配置以控制電腦進行如條項11至19中任一項之方法。 While specific embodiments of the invention have been described above, it will be understood that the invention may be practiced otherwise than as described. The above description is intended to be illustrative and not restrictive. Accordingly, it will be apparent to those skilled in the art that modifications can be made in the invention described without departing from the scope of the terms set forth below. 1. An optical system for directing a first laser pulse and a second laser pulse to a target along an optical axis to generate extreme ultraviolet radiation from the target, comprising: a first optical component configured to redistribute the first laser pulse to form a shaped laser pulse having a hollow region; a second optical component configured to focus the shaping laser pulse toward the target; and, a third optical component configured to focus the second laser pulse toward the target within the hollow region of the shaped laser pulse, wherein the first optical component, the second optical component and the third optical component The three optical components are coaxially arranged on the optical axis. 2. The optical system of item 1, wherein the first laser pulse and the second laser pulse contain different wavelengths. 3. The optical system of Item 1 or Item 2, wherein the first optical component and the third optical component are located on different surfaces of a single optical element. 4. The optical system of clause 3, wherein the first optical component is formed on a front side of the single optical element, and the third optical component is formed on a back side of the single optical element. 5. The optical system of any of the preceding clauses, which includes a radiation collector configured to receive extreme ultraviolet radiation emitted by the target, wherein the radiation collector includes an aperture coaxially disposed on the optical axis , and wherein the second optical component and the third optical component are configured to shape and focus the second laser pulse through the aperture. 6. The optical system of any of the preceding clauses, wherein the second optical component is configured to interact only with the shaping laser pulse, and the third optical component is configured to interact only with the second laser pulse interaction. 7. The optical system of any of the preceding items, wherein the second optical component includes an opening coaxially arranged on the optical axis. 8. If the optical system of any of the preceding clauses, wherein the third optical component is configured to focus a third laser pulse along the optical axis to the target within the hollow region of the shaping laser pulse, The third laser pulse includes a wavelength different from the first laser pulse and the second laser pulse. 9. An extreme ultraviolet radiation source comprising an optical system as in any one of items 1 to 8. 10. A lithography system including the extreme ultraviolet radiation source of clause 9. 11. A method of directing a first laser pulse and a second laser pulse to a target along an optical axis to generate extreme ultraviolet radiation from the target, comprising: using a first optical component to redistribute the first laser pulse to form a shaped laser pulse having a hollow region; using a second optical component to focus the shaping laser pulse toward the target; using a third optical component to focus the second laser pulse toward the target within the hollow region of the shaped laser pulse; and, The first optical component, the second optical component and the third optical component are coaxially arranged on the optical axis. 12. The method of item 11, wherein the first laser pulse and the second laser pulse contain radiation of different wavelengths. 13. The method of Item 11 or Item 12, which includes positioning the first optical component and the third optical component on different surfaces of a single optical element. 14. The method of item 13 includes: Positioning the first optical component on a front side of the single optical element; and, Position the third optical component on one of the backsides of the single optical element. 15. The method of any one of items 11 to 14 includes: using a radiation collector to receive extreme ultraviolet radiation emitted by the target; An aperture of the radiation collector is disposed coaxially on the optical axis; and, The second optical component and the third optical component are used to focus the shaping laser pulse and the second laser pulse through the aperture. 16. The method of any one of items 11 to 15 includes: Use the second optical component to interact only with the shaping laser pulse; and, The third optical component is used to interact only with the second laser pulse. 17. The method of any one of items 11 to 16 includes: providing an opening in the second optical component; and, The opening is arranged coaxially on the optical axis. 18. The method of any one of clauses 11 to 17, comprising using the third optical component to focus a third laser pulse along the optical axis to the target within the hollow region of the shaping pulse , wherein the third laser pulse includes a wavelength different from the first laser pulse and the second laser pulse. 19. A method of projecting a patterned radiation beam onto a substrate, comprising using the method of any one of clauses 11 to 18 to generate extreme ultraviolet radiation. 20. A computer program containing computer-readable instructions configured to cause a computer to perform any of the methods of clauses 11 to 19. 21. A computer-readable medium carrying a computer program as specified in clause 20. 22. A computer device containing: a memory storing instructions readable by the processor; and a processor configured to read and execute instructions stored in the memory; The processor-readable instructions include instructions configured to control the computer to perform any of the methods of clauses 11 to 19.

1:雷射系統 2:雷射脈衝 3:燃料發射器 4:電漿形成區/電漿形成方位 5:收集器 6:中間焦點 7:錫電漿 8:開口 9:圍封結構 10:琢面化場鏡面裝置 11:琢面化光瞳鏡面裝置 13:鏡面 14:鏡面 20:孔徑 100:光學系統 110:第一雷射脈衝 120:第二雷射脈衝 130:光軸 140:第一光學組件 150:塑形雷射脈衝 155:中空區 160:第二光學組件 170:第三光學組件 180:單一光學元件 190:開口 200:第三雷射脈衝 400:替代性光學系統 440:第一光學組件 441:第一光學元件 442:第二光學元件 450:塑形雷射脈衝 455:中空區 460:第二光學組件 461:第三光學元件 462:第四光學元件 470:第三光學組件 490:開口 601:第一步驟 602:第二步驟 603:第三步驟 B:EUV輻射射束 B':經圖案化EUV輻射射束 IL:照明系統 IS:照明系統 LA:微影設備 MA:圖案化裝置 MT:支撐結構 PS:投影系統 SO:輻射源 W:基板 WT:基板台 1:Laser system 2:Laser pulse 3:Fuel Launcher 4: Plasma formation area/plasma formation direction 5: Collector 6: Middle focus 7: Tin plasma 8: Open your mouth 9: Enclosed structure 10: Faceted field mirror device 11: Faceted pupil mirror device 13:Mirror 14:Mirror 20:Aperture 100:Optical system 110: First laser pulse 120: Second laser pulse 130:Optical axis 140: First optical component 150: Shaping Laser Pulse 155: Hollow area 160: Second optical component 170:Third optical component 180:Single optical element 190:Open your mouth 200: The third laser pulse 400:Alternative optical systems 440: First optical component 441:First optical element 442: Second optical element 450:Shaping Laser Pulse 455: Hollow area 460: Second optical component 461:Third optical element 462: The fourth optical element 470:Third optical component 490:Open your mouth 601:First step 602:Second step 603:The third step B: EUV radiation beam B': Patterned EUV radiation beam IL: lighting system IS: lighting system LA: Lithography equipment MA: Patterned installation MT: support structure PS:Projection system SO: Radiation source W: substrate WT: substrate table

現將參看隨附示意性圖式而僅藉助於實例來描述本發明之實施例,其中: -  圖1描繪根據本發明之一實施例的微影系統,該微影系統包含微影設備、輻射源及光學系統。 -  圖2示意性地描繪根據本發明之一實施例的光學系統之截面側視圖,該光學系統用於沿著光軸將第一雷射脈衝及第二雷射脈衝導向至目標以自該目標產生EUV輻射。 -  圖3示意性地描繪輻射收集器之孔徑的正視圖,該輻射收集器形成圖1之微影系統的部分。 -  圖4示意性地描繪根據本發明之實施例的包含透射性光學組件之替代性光學系統的橫截面側視圖。 -  圖5繪示根據本發明之一實施例的沿著光軸將第一雷射脈衝及第二雷射脈衝導向至目標以自該目標產生極紫外線輻射之方法的流程圖。 Embodiments of the invention will now be described by way of example only with reference to the accompanying schematic drawings, in which: - Figure 1 depicts a lithography system according to one embodiment of the present invention. The lithography system includes a lithography equipment, a radiation source and an optical system. - Figure 2 schematically depicts a cross-sectional side view of an optical system for directing a first laser pulse and a second laser pulse along an optical axis to a target for removal from the target, according to an embodiment of the invention EUV radiation is generated. - Figure 3 schematically depicts a front view of the aperture of a radiation collector forming part of the lithography system of Figure 1. - Figure 4 schematically depicts a cross-sectional side view of an alternative optical system including a transmissive optical component according to an embodiment of the invention. - Figure 5 illustrates a flow chart of a method of directing a first laser pulse and a second laser pulse along an optical axis to a target to generate extreme ultraviolet radiation from the target, according to one embodiment of the present invention.

100:光學系統 100:Optical system

110:第一雷射脈衝 110: First laser pulse

120:第二雷射脈衝 120: Second laser pulse

130:光軸 130:Optical axis

140:第一光學組件 140: First optical component

150:塑形雷射脈衝 150: Shaping Laser Pulse

155:中空區 155: Hollow area

160:第二光學組件 160: Second optical component

170:第三光學組件 170:Third optical component

180:單一光學元件 180:Single optical element

190:開口 190:Open your mouth

Claims (15)

一種用於沿著一光軸將第一雷射脈衝及第二雷射脈衝導向至一目標以自該目標產生極紫外線輻射之光學系統,其包含: 一第一光學組件,其經組態以使該第一雷射脈衝重新分佈以形成具有一中空區之一塑形雷射脈衝; 一第二光學組件,其經組態以使該塑形雷射脈衝朝向該目標聚焦;及, 一第三光學組件,其經組態以在該塑形雷射脈衝之該中空區內使朝向該目標聚焦,其中該第一光學組件、該第二光學組件及該第三光學組件共軸配置於該光軸上。 An optical system for directing first and second laser pulses to a target along an optical axis to generate extreme ultraviolet radiation from the target, comprising: a first optical component configured to redistribute the first laser pulse to form a shaped laser pulse having a hollow region; a second optical component configured to focus the shaping laser pulse toward the target; and, a third optical component configured to focus toward the target within the hollow region of the shaped laser pulse, wherein the first optical component, the second optical component and the third optical component are coaxially disposed on the optical axis. 如請求項1之光學系統,其中該第一雷射脈衝及該第二雷射脈衝包含不同波長。The optical system of claim 1, wherein the first laser pulse and the second laser pulse include different wavelengths. 如請求項1或請求項2之光學系統,其中該第一光學組件及該第三光學組件位於一單一光學元件之不同表面上。The optical system of claim 1 or claim 2, wherein the first optical component and the third optical component are located on different surfaces of a single optical element. 如請求項3之光學系統,其中該第一光學組件形成於該單一光學元件之一前側上,且該第三光學組件形成於該單一光學元件之一背側上。The optical system of claim 3, wherein the first optical component is formed on a front side of the single optical element, and the third optical component is formed on a back side of the single optical element. 如請求項1至2中任一項之光學系統,其包含一輻射收集器,該輻射收集器經組態以接收由該目標發射之極紫外線輻射,其中該輻射收集器包含共軸配置於該光軸上之一孔徑,且其中該第二光學組件及該第三光學組件經組態以通過該孔徑使該塑形雷射脈衝及該第二雷射脈衝聚焦。The optical system of any one of claims 1 to 2, which includes a radiation collector configured to receive extreme ultraviolet radiation emitted by the target, wherein the radiation collector includes a coaxial arrangement on the An aperture on the optical axis, and wherein the second optical component and the third optical component are configured to focus the shaping laser pulse and the second laser pulse through the aperture. 如請求項1至2中任一項之光學系統,其中該第二光學組件經組態以僅與該塑形雷射脈衝相互作用,且該第三光學組件經組態以僅與該第二雷射脈衝相互作用。The optical system of any one of claims 1 to 2, wherein the second optical component is configured to interact only with the shaping laser pulse, and the third optical component is configured to interact only with the second Laser pulse interaction. 如請求項1至2中任一項之光學系統,其中該第二光學組件包含共軸配置於該光軸上之一開口。The optical system of any one of claims 1 to 2, wherein the second optical component includes an opening coaxially arranged on the optical axis. 如請求項1至2中任一項之光學系統,其中該第三光學組件經組態以在該塑形雷射脈衝之該中空區內使一第三雷射脈衝沿著該光軸聚焦至該目標,其中該第三雷射脈衝包含不同於該第一雷射脈衝及該第二雷射脈衝的一波長。The optical system of any one of claims 1 to 2, wherein the third optical component is configured to focus a third laser pulse along the optical axis within the hollow region of the shaped laser pulse. The target, wherein the third laser pulse includes a wavelength different from the first laser pulse and the second laser pulse. 一種極紫外線輻射源,其包含如請求項1至8中任一項之光學系統。An extreme ultraviolet radiation source comprising an optical system according to any one of claims 1 to 8. 一種微影系統,其包含如請求項9之極紫外線輻射源。A lithography system including the extreme ultraviolet radiation source of claim 9. 一種沿著一光軸將第一雷射脈衝及第二雷射脈衝導向至一目標以自該目標產生極紫外線輻射之方法,其包含: 使用一第一光學組件以使該第一雷射脈衝重新分佈以形成具有一中空區之一塑形雷射脈衝; 使用一第二光學組件以使該塑形雷射脈衝朝向該目標聚焦; 使用一第三光學組件以在該塑形雷射脈衝之該中空區內使該第二雷射脈衝朝向該目標聚焦;及, 在該光軸上共軸配置該第一光學組件、該第二光學組件及該第三光學組件。 A method of directing a first laser pulse and a second laser pulse to a target along an optical axis to generate extreme ultraviolet radiation from the target, comprising: using a first optical component to redistribute the first laser pulse to form a shaped laser pulse having a hollow region; using a second optical component to focus the shaping laser pulse toward the target; using a third optical component to focus the second laser pulse toward the target within the hollow region of the shaped laser pulse; and, The first optical component, the second optical component and the third optical component are coaxially arranged on the optical axis. 如請求項11之方法,其中該第一雷射脈衝及該第二雷射脈衝包含不同波長之輻射, 且/或該方法包含在一單一光學元件之不同表面上定位該第一光學組件及該第三光學組件, 且視情況在該單一光學元件之一前側上定位該第一光學組件及在該單一光學元件之一背側上定位該第三光學組件。 The method of claim 11, wherein the first laser pulse and the second laser pulse comprise radiation of different wavelengths, and/or the method includes positioning the first optical component and the third optical component on different surfaces of a single optical component, And optionally position the first optical component on a front side of the single optical element and position the third optical component on a back side of the single optical element. 如請求項11至12中任一項之方法,其包含: 使用一輻射收集器來接收由該目標發射之極紫外線輻射; 在該光軸上共軸配置該輻射收集器之一孔徑;及, 使用該第二光學組件及該第三光學組件來通過該孔徑使該塑形雷射脈衝及該第二雷射脈衝聚焦。 If the method of any one of items 11 to 12 is requested, it includes: using a radiation collector to receive extreme ultraviolet radiation emitted by the target; An aperture of the radiation collector is disposed coaxially on the optical axis; and, The second optical component and the third optical component are used to focus the shaping laser pulse and the second laser pulse through the aperture. 如請求項11至12中任一項之方法,其包含: 使用該第二光學組件以僅與該塑形雷射脈衝相互作用;及, 使用該第三光學組件以僅與該第二雷射脈衝相互作用, 及/或在該第二光學組件中設置一開口及在該光軸上共軸配置該開口, 及/或使用該第三光學組件以在該塑形脈衝之該中空區內使一第三雷射脈衝沿著該光軸聚焦至該目標,其中該第三雷射脈衝包含不同於該第一雷射脈衝及該第二雷射脈衝的一波長。 If the method of any one of items 11 to 12 is requested, it includes: Use the second optical component to interact only with the shaping laser pulse; and, using the third optical component to interact only with the second laser pulse, and/or an opening is provided in the second optical component and the opening is arranged coaxially on the optical axis, and/or using the third optical component to focus a third laser pulse along the optical axis to the target within the hollow region of the shaping pulse, wherein the third laser pulse contains a component different from that of the first A wavelength of the laser pulse and the second laser pulse. 一種將一圖案化輻射射束投影至一基板上之方法,其包含使用如請求項11至14中任一項之方法以產生極紫外線輻射。A method of projecting a patterned radiation beam onto a substrate, comprising using the method of any one of claims 11 to 14 to generate extreme ultraviolet radiation.
TW111147930A 2022-01-31 2022-12-14 Optical system and method for a radiation source TW202333539A (en)

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