TW202302494A - Moisture control and anti-slip volcanic rock plate and its preparation method - Google Patents

Moisture control and anti-slip volcanic rock plate and its preparation method Download PDF

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TW202302494A
TW202302494A TW111114594A TW111114594A TW202302494A TW 202302494 A TW202302494 A TW 202302494A TW 111114594 A TW111114594 A TW 111114594A TW 111114594 A TW111114594 A TW 111114594A TW 202302494 A TW202302494 A TW 202302494A
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volcanic rock
weight
parts
slip
humidity
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牛紅武
牛志遠
牛慧
牛志杰
葛東方
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牛紅武
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/10Lime cements or magnesium oxide cements
    • C04B28/12Hydraulic lime
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/52Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/14Minerals of vulcanic origin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2092Resistance against biological degradation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/52Sound-insulating materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Building Environments (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

A moisture control and anti-slip volcanic rock plate and its preparation method, which includes the following components by weight: volcanic rock aggregate 65~85, lime 40~55, fiber material 28~35 and additive 3~15, through the rational use of the volcanic rocks and organic combination with other components, the performances of moisture control, skid prevention, mildew prevention, heat insulation, noise reduction are effectively improved, and the structural strength is better than other similar products, the cost of products is low, synchronously, the preparation process only needs to be slightly modified in the existing process, the production investment is low, which not only creates a new use of volcanic rock, but also can bring a new self-purification cycle to the environment, so as to meet the requirements of green environmental protection and people’s growing needs of natural ecology, and play a positive role in reducing carbon emissions.

Description

調濕防滑火山岩板材及其製備方法Moisture-adjusting anti-slip volcanic rock plate and preparation method thereof

本發明涉及家裝材料技術領域,特別涉及一種調濕防滑火山岩板材及其製備方法。The invention relates to the technical field of home decoration materials, in particular to a moisture-adjusting anti-slip volcanic rock plate and a preparation method thereof.

在日常生活中,由於浴室、廚房等地需要經常性的用水,因此通常地面濕度較大,經常會發生老人、兒童滑倒事件,目前一般通過在地面上鋪防滑墊解決上述問題,由於防滑墊通常由橡膠材料製成,而橡膠材料不具有吸濕的能力,因此無法對浴室、廚房等地的濕度進行調節,在高濕度的條件下,防滑墊易滋生細菌而出現黴變,影響防滑墊的使用。In daily life, because bathrooms, kitchens and other places need frequent water, the ground humidity is usually high, and elderly people and children often slip and fall. At present, the above problems are generally solved by laying anti-slip mats on the ground. Usually made of rubber materials, and rubber materials do not have the ability to absorb moisture, so it is impossible to adjust the humidity in bathrooms, kitchens and other places. Under high humidity conditions, anti-slip mats are prone to bacteria and mildew, affecting anti-slip mats usage of.

為解決上述技術問題,本發明提供了一種調濕防滑火山岩板材及其製備方法,具有防滑、吸濕調濕、減少黴變的優點。In order to solve the above technical problems, the present invention provides a moisture-regulating anti-slip volcanic rock plate and a preparation method thereof, which have the advantages of anti-skid, moisture-absorbing and humidity-regulating, and mildew-reducing.

為達到上述目的,本發明的技術方案如下:To achieve the above object, the technical scheme of the present invention is as follows:

一種調濕防滑火山岩板材,按重量份計包括如下組分:A moisture-adjusting anti-slip volcanic rock plate, comprising the following components in parts by weight:

火山岩骨料65-85重量份、石灰40-55重量份、纖維材料28-35重量份、添加劑3-15重量份。65-85 parts by weight of volcanic rock aggregate, 40-55 parts by weight of lime, 28-35 parts by weight of fiber material, and 3-15 parts by weight of additives.

作為本發明的一種較佳實施例,所述火山岩骨料的粒徑為80目以上。As a preferred embodiment of the present invention, the particle size of the volcanic rock aggregate is above 80 mesh.

作為本發明的一種較佳實施例,所述纖維材料為木質纖維、玻璃纖維、聚苯纖維、碳酸鋁銨纖維、聚丙烯纖維和石棉礦物纖維中的其中一種或者多種混合。As a preferred embodiment of the present invention, the fiber material is one or more mixtures of wood fiber, glass fiber, polyphenylene fiber, ammonium aluminum carbonate fiber, polypropylene fiber and asbestos mineral fiber.

作為本發明的一種較佳實施例,所述添加劑包括黏合劑、穩定劑、防黴劑和阻燃劑中的其中一種或者多種。As a preferred embodiment of the present invention, the additive includes one or more of an adhesive, a stabilizer, an antifungal agent and a flame retardant.

作為本發明的一種較佳實施例,所述黏合劑選自石膏、磷酸鹽和水溶性聚乙烯醇中的其中一種或者多種。As a preferred embodiment of the present invention, the binder is selected from one or more of gypsum, phosphate and water-soluble polyvinyl alcohol.

作為本發明的一種較佳實施例,所述穩定劑選自三鹽基硫酸鉛、二鹽基硬脂酸鉛、硬脂酸鋅和硬脂酸鈣中的其中一種或者多種。As a preferred embodiment of the present invention, the stabilizer is selected from one or more of tribasic lead sulfate, dibasic lead stearate, zinc stearate and calcium stearate.

作為本發明的一種較佳實施例,所述防黴劑選自廣譜抗菌防黴劑、有機銅鹽、有機錫鹽、苯酚類、咪唑類、吡啶類、噻唑類、氯酚類、季銨鹽衍生物和有機酸鹽中的其中一種或者多種。As a preferred embodiment of the present invention, the antifungal agent is selected from broad-spectrum antibacterial and antifungal agents, organic copper salts, organic tin salts, phenols, imidazoles, pyridines, thiazoles, chlorophenols, quaternary ammonium One or more of salt derivatives and organic acid salts.

作為本發明的一種較佳實施例,所述阻燃劑選自MCA阻燃劑、聚氯乙烯阻燃劑、過氯乙烯阻燃劑和酚醛樹脂阻燃劑中的其中一種或者多種。As a preferred embodiment of the present invention, the flame retardant is selected from one or more of MCA flame retardants, polyvinyl chloride flame retardants, perchlorethylene flame retardants and phenolic resin flame retardants.

另一方面,本發明還提供一種製備上述任一技術方案所述的調濕防滑火山岩板材的方法,包括:On the other hand, the present invention also provides a method for preparing the humidity-adjusting non-slip volcanic rock plate described in any of the above technical solutions, comprising:

按重量份計分別取火山岩骨料65-85重量份、石灰40-55重量份、纖維材料28-35重量份、添加劑3-15重量份作為原材料備用;Take 65-85 parts by weight of volcanic rock aggregate, 40-55 parts by weight of lime, 28-35 parts by weight of fiber material and 3-15 parts by weight of additives as raw materials in parts by weight;

將各原材料研磨至80目以上後充分混合攪拌製得混合原料;Grinding each raw material to more than 80 meshes and then fully mixing and stirring to obtain a mixed raw material;

將混合原料通過流漿法或者抄取法工藝製備成板材胚體後,將板材胚體送入蒸壓釜中進行固化處理,以最終製得板材產品。After the mixed raw materials are prepared into a sheet blank by the slurry flow method or the scissoring method, the sheet blank is sent into an autoclave for curing treatment, so as to finally obtain a sheet product.

作為本發明的一種較佳實施例,通過蒸壓釜進行固化處理時具體為:於1-10Mpa飽和蒸氣壓下,恆壓處理12-24小時。As a preferred embodiment of the present invention, when the curing treatment is carried out in an autoclave, it is specifically: under the saturated vapor pressure of 1-10 Mpa, constant pressure treatment for 12-24 hours.

綜上所述,本發明具有如下有益效果:In summary, the present invention has the following beneficial effects:

本發明實施例通過提供一種調濕防滑火山岩板材及其製備方法,通過對火山岩的合理利用,與其他組分進行有機結合,有效地提高了產品的調濕、防滑、防黴、隔熱、降噪等性能,且結構強度優於其他同類產品,產品的成本較低,滿足大範圍使用的需求;同時,產品的製備工藝只需在現有工藝上略作部分修改即可,生產投入較低,既創造了火山岩的新用途,又能夠給環境帶來新的自我淨化迴圈,符合綠色環保的要求,滿足人們日益增長的自然生態的需求,對減少碳排放起到了積極作用。The embodiments of the present invention provide a moisture-regulating anti-slip volcanic rock plate and its preparation method, and through rational utilization of volcanic rock and organic combination with other components, the humidity-regulating, anti-slip, mildew-proof, heat insulation, and heat-reducing properties of the product are effectively improved. Noise and other performance, and the structural strength is better than other similar products, the cost of the product is low, to meet the needs of a wide range of use; at the same time, the preparation process of the product only needs to be slightly modified on the existing process, and the production investment is low. It not only creates a new use of volcanic rock, but also brings a new self-purification cycle to the environment, meets the requirements of green environmental protection, meets people's growing needs for natural ecology, and plays a positive role in reducing carbon emissions.

下面對本發明實施例中的技術方案進行清楚、完整地描述,顯然,所描述的實施例僅僅是本發明一部分實施例,而不是全部的實施例。基於本發明中的實施例,本領域通常知識者在沒有作出創造性勞動前提下所獲得的所有其他實施例,都屬於本發明保護的範圍。The following clearly and completely describes the technical solutions in the embodiments of the present invention. Obviously, the described embodiments are only some of the embodiments of the present invention, but not all of them. Based on the embodiments of the present invention, all other embodiments obtained by those skilled in the art without creative efforts fall within the protection scope of the present invention.

實施例一Embodiment one

一種調濕防滑火山岩板材,按重量份計包括如下組分:火山岩骨料65-85重量份、石灰40-55重量份、纖維材料28-35重量份、添加劑3-15重量份。A moisture-adjusting anti-slip volcanic rock plate comprises the following components in parts by weight: 65-85 parts by weight of volcanic rock aggregate, 40-55 parts by weight of lime, 28-35 parts by weight of fiber material, and 3-15 parts by weight of additives.

火山岩又稱噴出岩,屬於岩漿岩的一類,是火山作用時噴出的岩漿冷凝、成岩、壓實等作用形成的岩石,與沉積岩在行程條件、發育環境、分佈規律等方面有很大差異。火山岩性能優越,除具有普通石材的一般特點外,還具有自身獨特功能。火山岩石材具有抗風化、耐酸鹼、無放射性等特性;天然的孔狀具有隔音降噪的效果,有利於聽覺環境;獨特的"呼吸"功能易吸收和揮發,能夠調節空氣濕度,改善生態環境;其色澤的古樸在自然的強光下可以有效避免眩目,有益於改善視覺環境。這些種種獨特優點,可以滿足當今時代人們在建築裝修上追求古樸自然、崇尚綠色環保的新時尚。Volcanic rocks, also known as extrusive rocks, belong to the category of igneous rocks. They are rocks formed by the condensation, diagenesis, and compaction of magma ejected during volcanic activity. They are quite different from sedimentary rocks in terms of travel conditions, development environment, and distribution rules. The performance of volcanic rock is superior, in addition to the general characteristics of ordinary stone, it also has its own unique functions. Volcanic rock has the characteristics of weather resistance, acid and alkali resistance, and no radioactivity; the natural pore shape has the effect of sound insulation and noise reduction, which is beneficial to the auditory environment; the unique "breathing" function is easy to absorb and volatilize, and can adjust air humidity and improve the ecological environment ; Its simple and unsophisticated color can effectively avoid dazzling under natural strong light, and is beneficial to improve the visual environment. These various unique advantages can meet the new fashion of people pursuing simplicity and nature and advocating green environmental protection in architectural decoration in this era.

火山岩獨具的天然孔洞,是目前所有建材中唯一的天然吸音材料,火山岩源於火山熔岩噴發後冷凝而生成,因產生於絕對高溫而具有明顯的吸光阻熱功能,火山岩的天然孔洞,使其具備獨特的呼吸功能及優良的吸濕調濕能力,且火山岩中具有三十餘種對人體健康有益的微量元素,對關節炎、風濕痛及各種皮膚病等,都具有較好的療效及保健功能。The unique natural pores of volcanic rock are the only natural sound-absorbing materials among all building materials at present. Volcanic rock is formed by condensation after volcanic lava erupts. It has unique respiratory function and excellent moisture absorption and humidity control ability, and there are more than 30 kinds of trace elements beneficial to human health in volcanic rocks, which have good curative effect and health care for arthritis, rheumatic pain and various skin diseases, etc. Function.

本實施例中,火山岩骨料的粒徑為80目以上,或者在加工時將火山岩骨料研磨至80目以上,優選採用200目以上粒徑的火山岩骨料。In this embodiment, the particle size of the volcanic rock aggregate is above 80 mesh, or the volcanic rock aggregate is ground to above 80 mesh during processing, preferably using a volcanic rock aggregate with a particle size of above 200 mesh.

石灰可以為生石灰和熟石灰,具有較強的鹼性。Lime can be quicklime and slaked lime, which has strong alkalinity.

在使用過程中作為膠凝材料,在常溫下與矽藻土或矽質材料中的活性氧化矽反應,生成水硬性的產物,保證了產品的正常成型。凡是以碳酸鈣為主要成分的天然岩石,如石灰岩、白雲質石灰岩等,都可以用來生產石灰,因此原料分佈較廣,且生產工藝簡單,極大地降低了製品的成本投入。As a gelling material during use, it reacts with diatomaceous earth or active silicon oxide in silicon materials at room temperature to form a hydraulic product, which ensures the normal molding of the product. All natural rocks with calcium carbonate as the main component, such as limestone, dolomitic limestone, etc., can be used to produce lime, so the distribution of raw materials is wide, and the production process is simple, which greatly reduces the cost of products.

本實施例中,纖維材料為木質纖維、玻璃纖維、聚苯纖維、碳酸鋁銨纖維、聚丙烯纖維和石棉礦物纖維中的其中一種或者多種混合,添加劑包括黏合劑、穩定劑、防黴劑和阻燃劑中的其中一種或者多種。In this embodiment, the fiber material is a mixture of one or more of wood fiber, glass fiber, polyphenylene fiber, aluminum ammonium carbonate fiber, polypropylene fiber and asbestos mineral fiber, and the additives include binders, stabilizers, antifungal agents and One or more of the flame retardants.

其中,黏合劑選自石膏、磷酸鹽和水溶性聚乙烯醇中的其中一種或者多種,黏合劑用於對產品進行黏合凝固,提高產品的結合強度;穩定劑選自三鹽基硫酸鉛、二鹽基硬脂酸鉛、硬脂酸鋅和硬脂酸鈣中的其中一種或者多種,穩定劑用於對提高產品成型後的穩定性;防黴劑選自廣譜抗菌防黴劑、有機銅鹽、有機錫鹽、苯酚類、咪唑類、吡啶類、噻唑類、氯酚類、季銨鹽衍生物和有機酸鹽中的其中一種或者多種,防黴劑用於減少產品整體黴變的可能;阻燃劑選自MCA阻燃劑、聚氯乙烯阻燃劑、過氯乙烯阻燃劑和酚醛樹脂阻燃劑中的其中一種或者多種,阻燃劑用於提高產品整體的阻燃性能;在一些實施例中,還可以在產品中添加活性炭、蒙脫石、光觸媒等材料,從而提高產品整體的除臭防黴性能。Among them, the binder is selected from one or more of gypsum, phosphate and water-soluble polyvinyl alcohol, and the binder is used to bond and solidify the product to improve the bonding strength of the product; the stabilizer is selected from tribasic lead sulfate, di One or more of lead stearate, zinc stearate and calcium stearate, the stabilizer is used to improve the stability of the product after molding; the antifungal agent is selected from broad-spectrum antibacterial and antifungal agents, organic copper Salt, organotin salts, phenols, imidazoles, pyridines, thiazoles, chlorophenols, quaternary ammonium salt derivatives and organic acid salts, and antifungal agents are used to reduce the possibility of mildew on the whole product The flame retardant is selected from one or more of MCA flame retardants, polyvinyl chloride flame retardants, perchlorethylene flame retardants and phenolic resin flame retardants, and the flame retardants are used to improve the overall flame retardant performance of the product; In some embodiments, activated carbon, montmorillonite, photocatalyst and other materials can also be added to the product, so as to improve the overall deodorizing and anti-mildew performance of the product.

相應的,本發明還提供一種製備上述技術方案所述的調濕防滑火山岩板材的方法,包括:Correspondingly, the present invention also provides a method for preparing the humidity-adjusting anti-slip volcanic rock plate described in the above technical solution, including:

步驟一、按重量份計分別取火山岩骨料65-85重量份、石灰40-55重量份、纖維材料28-35重量份、添加劑3-15重量份作為原材料備用;Step 1. Take 65-85 parts by weight of volcanic rock aggregate, 40-55 parts by weight of lime, 28-35 parts by weight of fiber material, and 3-15 parts by weight of additives as raw materials in parts by weight;

步驟二、將各原材料通過研磨設備研磨至800目以上後充分混合攪拌製得混合原料,優選研磨至80目以上,在攪拌過程中可能根據需求加入適量的水,形成漿料,以便於後續製板過程的進行,同時,混合攪拌完成後,根據加工工藝的需要,可將混合原料置於溫度為15-25℃、濕度為60-95%的環境中靜置10-15天;Step 2. Grind each raw material through a grinding device to a mesh size of 800 or more, and then mix and stir to obtain a mixed raw material, preferably grinding to a mesh size of 80 or more. During the stirring process, an appropriate amount of water may be added to form a slurry for subsequent preparation. At the same time, after the mixing and stirring is completed, according to the needs of the processing technology, the mixed raw materials can be placed in an environment with a temperature of 15-25 ° C and a humidity of 60-95% for 10-15 days;

步驟三、將混合原料通過流漿法或者抄取法工藝製備成板材胚體後,將板材胚體送入蒸壓釜中進行固化處理,以最終製得板材產品,其中,通過蒸壓釜進行固化處理時具體為:於1-10Mpa飽和蒸氣壓下,恆壓處理12-24小時;通常,在固化完成後還可根據加工需要對板材進行烘乾處理,如利用烘乾機將板材水分烘乾至10wt%以下,烘乾完成後對板材進行打磨、拋光、切割、雕刻等工藝,製得相應尺寸規格和圖案的板材產品。Step 3. After the mixed raw materials are prepared into a sheet blank by a flow method or a copying method, the sheet blank is sent into an autoclave for curing treatment, so as to finally obtain a sheet product, wherein the curing is performed through an autoclave The specific treatment is: under the saturated vapor pressure of 1-10Mpa, constant pressure treatment for 12-24 hours; usually, after the curing is completed, the board can also be dried according to the processing needs, such as using a dryer to dry the water of the board to less than 10 wt%, after the drying is completed, the plates are polished, polished, cut, engraved and other processes to obtain plate products with corresponding sizes, specifications and patterns.

通過對火山岩的合理利用,與其他組分進行有機結合,有效地提高了產品的調濕、防滑、防黴、隔熱、降噪等性能,且結構強度優於其他同類產品,產品的成本較低,滿足大範圍使用的需求;同時,產品的製備工藝只需在現有工藝上略作部分修改即可,生產投入較低,既創造了火山岩的新用途,又能夠給環境帶來新的自我淨化迴圈,符合綠色環保的要求,滿足人們日益增長的自然生態的需求,對減少碳排放起到了積極作用。Through the rational use of volcanic rock and organic combination with other components, the performance of humidity control, anti-skid, mildew resistance, heat insulation, noise reduction and other properties of the product is effectively improved, and the structural strength is better than other similar products, and the cost of the product is lower. low to meet the needs of a wide range of use; at the same time, the preparation process of the product only needs to be slightly modified on the existing process, and the production investment is low, which not only creates new uses for volcanic rocks, but also brings new self to the environment The purification cycle meets the requirements of green environmental protection, meets people's growing needs for natural ecology, and plays a positive role in reducing carbon emissions.

實施例二Embodiment two

一種調濕防滑火山岩板材,按重量份計包括如下組分:火山岩骨料65重量份、石灰40重量份、纖維材料28重量份、添加劑3重量份。A moisture-adjusting anti-slip volcanic rock plate comprises the following components in parts by weight: 65 parts by weight of volcanic rock aggregate, 40 parts by weight of lime, 28 parts by weight of fiber material and 3 parts by weight of additives.

本實施例中,纖維材料選用木質纖維,木質纖維是天然可再生木材經過加工得到的有機絮狀纖維物質,具有無毒、無味、無污染和無放射性的特性。由於木質纖維結構的毛細管作用,將系統內部的水分迅速的傳輸到漿料表面和介面,可使內部的水分均勻分佈明顯減少結皮現象。並且木質纖維可以使製品的黏結強度和表面強度明顯提高,在製品的乾燥過程中張力的減小起到明顯的抗裂作用,保證了製品在使用過程中品質的保證。木質纖維不溶於水、弱鹼和鹼性溶液,有效的提高了系統抗腐蝕性。木質纖維在原料的加工過程中可以有效的保證混合原料的製作過程中均勻的保持原狀並減少系統的收縮和膨脹,大大提高了製品的精度需求,保證了成品標準。In this embodiment, the fiber material is selected from wood fiber, which is an organic floc fiber material obtained by processing natural renewable wood, and has the characteristics of non-toxic, tasteless, pollution-free and non-radioactive. Due to the capillary action of the wood fiber structure, the moisture inside the system is quickly transferred to the surface and interface of the slurry, which can make the internal moisture evenly distributed and significantly reduce the skinning phenomenon. Moreover, wood fiber can significantly improve the bonding strength and surface strength of the product, and the reduction of tension during the drying process of the product plays an obvious anti-cracking effect, ensuring the quality of the product during use. Wood fiber is insoluble in water, weak alkali and alkaline solution, which effectively improves the corrosion resistance of the system. During the processing of raw materials, wood fiber can effectively ensure that the mixed raw materials are uniformly maintained in the original state and reduce the shrinkage and expansion of the system, which greatly improves the precision requirements of the products and ensures the finished product standards.

添加劑包括黏合劑、穩定劑、防黴劑和阻燃劑,其中,黏合劑選用石膏,穩定劑選用三鹽基硫酸鉛,防黴劑選自廣譜抗菌防黴劑,阻燃劑選用MCA阻燃劑。Additives include adhesives, stabilizers, antifungal agents and flame retardants, wherein the adhesive is selected from gypsum, the stabilizer is selected from tribasic lead sulfate, the antifungal agent is selected from broad-spectrum antibacterial and antifungal agents, and the flame retardant is selected from MCA retardants. Fuel.

相應的,本發明的調濕防滑火山岩板材的製備方法包括:Correspondingly, the preparation method of the humidity-adjusting non-slip volcanic rock plate of the present invention comprises:

步驟一、按重量份計分別取火山岩骨料65重量份、石灰40重量份、纖維材料28重量份、添加劑3重量份作為原材料備用;Step 1, taking 65 parts by weight of volcanic rock aggregate, 40 parts by weight of lime, 28 parts by weight of fiber material and 3 parts by weight of additives as raw materials in parts by weight;

步驟二、將各原材料通過研磨設備研磨至200目以上後充分混合攪拌製得混合原料,優選研磨至80目以上,在攪拌過程中可能根據需求加入適量的水,形成漿料,以便於後續製板過程的進行,同時,混合攪拌完成後,根據加工工藝的需要,可將混合原料置於溫度為20℃、濕度為80%的環境中靜置10天;Step 2. Grind each raw material through a grinding device to a mesh size of 200 or more, and mix and stir to obtain a mixed raw material, preferably grinding to a mesh size of 80 or more. During the stirring process, an appropriate amount of water may be added to form a slurry for subsequent preparation. At the same time, after the mixing and stirring are completed, according to the needs of the processing technology, the mixed raw materials can be placed in an environment with a temperature of 20 ° C and a humidity of 80% for 10 days;

步驟三、將混合原料通過流漿法或者抄取法工藝製備成板材胚體後,將板材胚體送入蒸壓釜中進行固化處理,以最終製得板材產品,其中,通過蒸壓釜進行固化處理時具體為:於7Mpa飽和蒸氣壓下,恆壓處理16小時;通常,在固化完成後還可根據加工需要對板材進行烘乾處理,如利用烘乾機將板材水分烘乾至10wt%以下,烘乾完成後對板材進行打磨、拋光、切割、雕刻等工藝,製得相應尺寸規格和圖案的板材產品。Step 3. After the mixed raw materials are prepared into a sheet blank by a flow method or a copying method, the sheet blank is sent into an autoclave for curing treatment, so as to finally obtain a sheet product, wherein the curing is performed through an autoclave The specific treatment is: under the saturated vapor pressure of 7Mpa, constant pressure treatment for 16 hours; usually, after the curing is completed, the board can be dried according to the processing needs, such as using a dryer to dry the water content of the board to below 10wt% After the drying is completed, the plates are polished, polished, cut, engraved and other processes to obtain plate products with corresponding sizes and patterns.

實施例三Embodiment three

一種調濕防滑火山岩板材,按重量份計包括如下組分:火山岩骨料85重量份、石灰55重量份、纖維材料35重量份、添加劑15重量份。A moisture-adjusting anti-slip volcanic rock plate comprises the following components in parts by weight: 85 parts by weight of volcanic rock aggregate, 55 parts by weight of lime, 35 parts by weight of fiber material and 15 parts by weight of additives.

本實施例中,纖維材料選用木質纖維,添加劑包括黏合劑、穩定劑、防黴劑和阻燃劑,其中,黏合劑選用磷酸鹽,穩定劑選用二鹽基硬脂酸鉛,防黴劑選用廣譜抗菌防黴劑,阻燃劑選用聚氯乙烯阻燃劑。In this embodiment, the fiber material is selected from wood fiber, and the additives include adhesives, stabilizers, anti-mold agents and flame retardants, wherein the adhesive is selected from phosphate, the stabilizer is selected from dibasic lead stearate, and the anti-mold agent is selected from Broad-spectrum antibacterial and antifungal agent, flame retardant is polyvinyl chloride flame retardant.

相應的,本發明的調濕防滑火山岩板材的製備方法包括:Correspondingly, the preparation method of the humidity-adjusting non-slip volcanic rock plate of the present invention comprises:

步驟一、按重量份計分別取火山岩骨料85重量份、石灰55重量份、纖維材料35重量份、添加劑15重量份作為原材料備用;Step 1. Take 85 parts by weight of volcanic rock aggregate, 55 parts by weight of lime, 35 parts by weight of fiber material and 15 parts by weight of additives as raw materials in parts by weight;

步驟二、將各原材料通過研磨設備研磨至200目以上後充分混合攪拌製得混合原料,優選研磨至80目以上,在攪拌過程中可能根據需求加入適量的水,形成漿料,以便於後續製板過程的進行,同時,混合攪拌完成後,根據加工工藝的需要,可將混合原料置於溫度為22℃、濕度為80%的環境中靜置12天;Step 2. Grind each raw material through a grinding device to a mesh size of 200 or more, and mix and stir to obtain a mixed raw material, preferably grinding to a mesh size of 80 or more. During the stirring process, an appropriate amount of water may be added to form a slurry for subsequent preparation. At the same time, after the mixing and stirring are completed, according to the needs of the processing technology, the mixed raw materials can be placed in an environment with a temperature of 22 ° C and a humidity of 80% for 12 days;

步驟三、將混合原料通過流漿法或者抄取法工藝製備成板材胚體後,將板材胚體送入蒸壓釜中進行固化處理,以最終製得板材產品,其中,通過蒸壓釜進行固化處理時具體為:於8Mpa飽和蒸氣壓下,恆壓處理18小時;通常,在固化完成後還可根據加工需要對板材進行烘乾處理,如利用烘乾機將板材水分烘乾至10wt%以下,烘乾完成後對板材進行打磨、拋光、切割、雕刻等工藝,製得相應尺寸規格和圖案的板材產品。Step 3. After the mixed raw materials are prepared into a sheet blank by a flow method or a copying method, the sheet blank is sent into an autoclave for curing treatment, so as to finally obtain a sheet product, wherein the curing is performed through an autoclave The specific treatment is: under the saturated vapor pressure of 8Mpa, constant pressure treatment for 18 hours; usually, after the curing is completed, the board can be dried according to the processing needs, such as using a dryer to dry the water content of the board to below 10wt% After the drying is completed, the plates are polished, polished, cut, engraved and other processes to obtain plate products with corresponding sizes and patterns.

實施例四Embodiment four

一種調濕防滑火山岩板材,按重量份計包括如下組分:火山岩骨料75重量份、石灰50重量份、纖維材料32重量份、添加劑10重量份。A moisture-adjusting anti-slip volcanic rock plate comprises the following components in parts by weight: 75 parts by weight of volcanic rock aggregate, 50 parts by weight of lime, 32 parts by weight of fiber material and 10 parts by weight of additives.

本實施例中,纖維材料為石棉礦物纖維,添加劑包括黏合劑、穩定劑、防黴劑和阻燃劑中,其中,黏合劑選用水溶性聚乙烯醇,穩定劑選用硬脂酸鋅,防黴劑選用有機錫鹽,阻燃劑選用酚醛樹脂阻燃劑。In this embodiment, the fiber material is asbestos mineral fiber, and the additives include binders, stabilizers, anti-mold agents and flame retardants, wherein the binder is selected from water-soluble polyvinyl alcohol, and the stabilizer is selected from zinc stearate to prevent mildew. The organic tin salt is selected as the agent, and the phenolic resin flame retardant is selected as the flame retardant.

相應的,本發明的調濕防滑火山岩板材的製備方法包括:Correspondingly, the preparation method of the humidity-adjusting non-slip volcanic rock plate of the present invention comprises:

步驟一、按重量份計分別取火山岩骨料75重量份、石灰50重量份、纖維材料32重量份、添加劑10重量份作為原材料備用;Step 1, taking 75 parts by weight of volcanic rock aggregate, 50 parts by weight of lime, 32 parts by weight of fiber material and 10 parts by weight of additives as raw materials for subsequent use in parts by weight;

步驟二、將各原材料通過研磨設備研磨至200目以上後充分混合攪拌製得混合原料,優選研磨至80目以上,在攪拌過程中可能根據需求加入適量的水,形成漿料,以便於後續製板過程的進行,同時,混合攪拌完成後,根據加工工藝的需要,可將混合原料置於溫度為25℃、濕度為95%的環境中靜置15天;Step 2. Grind each raw material through a grinding device to a mesh size of 200 or more, and mix and stir to obtain a mixed raw material, preferably grinding to a mesh size of 80 or more. During the stirring process, an appropriate amount of water may be added to form a slurry for subsequent preparation. At the same time, after the mixing and stirring are completed, according to the needs of the processing technology, the mixed raw materials can be placed in an environment with a temperature of 25 ° C and a humidity of 95% for 15 days;

步驟三、將混合原料通過流漿法或者抄取法工藝製備成板材胚體後,將板材胚體送入蒸壓釜中進行固化處理,以最終製得板材產品,其中,通過蒸壓釜進行固化處理時具體為:於10Mpa飽和蒸氣壓下,恆壓處理24小時;通常,在固化完成後還可根據加工需要對板材進行烘乾處理,如利用烘乾機將板材水分烘乾至10wt%以下,烘乾完成後對板材進行打磨、拋光、切割、雕刻等工藝,製得相應尺寸規格和圖案的板材產品。Step 3. After the mixed raw materials are prepared into a sheet blank by a flow method or a copying method, the sheet blank is sent into an autoclave for curing treatment, so as to finally obtain a sheet product, wherein the curing is performed through an autoclave The specific treatment is: under the saturated vapor pressure of 10Mpa, constant pressure treatment for 24 hours; usually, after the curing is completed, the board can be dried according to the processing needs, such as using a dryer to dry the water content of the board to below 10wt% After the drying is completed, the plates are polished, polished, cut, engraved and other processes to obtain plate products with corresponding sizes and patterns.

實施例二至實施例四所製得的板材製品的防滑係數、降噪係數和吸水率檢測結果如下表所示:   防滑係數 降噪係數(NRC) 吸水率(%) 實施例二 0.75 0.30 20 實施例三 0.76 0.31 23 實施例四 0.78 0.33 25 The anti-slip coefficient, noise reduction coefficient and water absorption test results of the plate products prepared in Embodiment 2 to Embodiment 4 are shown in the following table: Anti-slip coefficient Noise Reduction Coefficient (NRC) Water absorption (%) Embodiment two 0.75 0.30 20 Embodiment Three 0.76 0.31 twenty three Embodiment four 0.78 0.33 25

上述防滑係數為板材表面的防滑係數,降噪係數為在250、500、1000、2000HZ頻率下測得的吸聲係數的平均值,吸水率為板材吸收水分的能力,本實驗的測量為將板材浸泡在蒸餾水中,於25℃環境中,浸泡1分鐘後增加的品質與原品質相比的百分率。由上表資料可知隨著火山岩的配比的升高,防滑係數、降噪係數和吸水率也逐漸升高。The above-mentioned anti-skid coefficient is the anti-skid coefficient of the surface of the board, the noise reduction coefficient is the average value of the sound absorption coefficient measured at frequencies of 250, 500, 1000, and 2000HZ, and the water absorption rate is the ability of the board to absorb moisture. The measurement in this experiment is the board Soaked in distilled water, at 25 ℃, the percentage of the increased quality compared with the original quality after soaking for 1 minute. It can be seen from the data in the above table that with the increase of the ratio of volcanic rock, the anti-skid coefficient, noise reduction coefficient and water absorption rate also gradually increase.

對所公開的實施例的上述說明,使本領域具有通常知識者能夠實現或使用本發明。對這些實施例的多種修改對本領域具有通常知識者來說將是顯而易見的,本文中所定義的一般原理可以在不脫離本發明的精神或範圍的情況下,在其它實施例中實現。因此,本發明將不會被限制於本文所示的這些實施例,而是要符合與本文所公開的原理和新穎特點相一致的最寬的範圍。The above description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the general principles defined herein may be implemented in other embodiments without departing from the spirit or scope of the invention. Therefore, the present invention will not be limited to the embodiments shown herein, but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.

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無。none.

Claims (10)

一種調濕防滑火山岩板材,按重量份計包括如下組分: 火山岩骨料65-85重量份、石灰40-55重量份、纖維材料28-35重量份、添加劑3-15重量份。 A moisture-adjusting anti-slip volcanic rock plate, comprising the following components in parts by weight: 65-85 parts by weight of volcanic rock aggregate, 40-55 parts by weight of lime, 28-35 parts by weight of fiber material, and 3-15 parts by weight of additives. 如請求項1所述的調濕防滑火山岩板材,其中,所述火山岩骨料的粒徑為80目以上。The humidity-adjusting non-slip volcanic rock plate according to claim 1, wherein the particle size of the volcanic rock aggregate is above 80 mesh. 如請求項1或2所述的調濕防滑火山岩板材,其中,所述纖維材料為木質纖維、玻璃纖維、聚苯纖維、碳酸鋁銨纖維、聚丙烯纖維和石棉礦物纖維中的其中一種或者多種混合。The humidity-adjusting anti-slip volcanic rock plate as claimed in claim 1 or 2, wherein the fiber material is one or more of wood fiber, glass fiber, polyphenylene fiber, aluminum ammonium carbonate fiber, polypropylene fiber and asbestos mineral fiber mix. 如請求項1或2所述的調濕防滑火山岩板材,其中,所述添加劑包括黏合劑、穩定劑、防黴劑和阻燃劑中的其中一種或者多種。The humidity-adjusting anti-skid volcanic rock plate according to claim 1 or 2, wherein the additives include one or more of adhesives, stabilizers, anti-fungal agents and flame retardants. 如請求項4所述的調濕防滑火山岩板材,其中,所述黏合劑選自石膏、磷酸鹽和水溶性聚乙烯醇中的其中一種或者多種。The humidity-adjusting non-slip volcanic rock plate according to claim 4, wherein the binder is selected from one or more of gypsum, phosphate and water-soluble polyvinyl alcohol. 如請求項4所述的調濕防滑火山岩板材,其中,所述穩定劑選自三鹽基硫酸鉛、二鹽基硬脂酸鉛、硬脂酸鋅和硬脂酸鈣中的其中一種或者多種。The humidity-adjusting anti-slip volcanic rock plate as claimed in claim 4, wherein the stabilizer is selected from one or more of tribasic lead sulfate, dibasic lead stearate, zinc stearate and calcium stearate . 如請求項4所述的調濕防滑火山岩板材,其中,所述防黴劑選自廣譜抗菌防黴劑、有機銅鹽、有機錫鹽、苯酚類、咪唑類、吡啶類、噻唑類、氯酚類、季銨鹽衍生物和有機酸鹽中的其中一種或者多種。The humidity-adjusting anti-slip volcanic rock plate as claimed in item 4, wherein the antifungal agent is selected from broad-spectrum antibacterial and antifungal agents, organic copper salts, organic tin salts, phenols, imidazoles, pyridines, thiazoles, chlorine One or more of phenols, quaternary ammonium salt derivatives and organic acid salts. 如請求項4所述的調濕防滑火山岩板材,其中,所述阻燃劑選自MCA阻燃劑、聚氯乙烯阻燃劑、過氯乙烯阻燃劑和酚醛樹脂阻燃劑中的其中一種或者多種。The humidity-adjusting anti-slip volcanic rock plate as claimed in claim 4, wherein the flame retardant is selected from one of MCA flame retardants, polyvinyl chloride flame retardants, perchlorethylene flame retardants and phenolic resin flame retardants or multiple. 一種製備如請求項1-8中任一項所述的調濕防滑火山岩板材的方法,包括: 步驟一,按重量份計分別取火山岩骨料65-85重量份、石灰40-55重量份、纖維材料28-35重量份、添加劑3-15重量份作為原材料備用; 步驟二,將各原材料研磨至80目以上後充分混合攪拌製得混合原料; 步驟三,將混合原料通過流漿法或者抄取法工藝製備成板材胚體後,將板材胚體送入蒸壓釜中進行固化處理,以最終製得板材產品。 A method for preparing the humidity-adjusting non-slip volcanic rock plate as described in any one of claim items 1-8, comprising: Step 1, taking 65-85 parts by weight of volcanic rock aggregate, 40-55 parts by weight of lime, 28-35 parts by weight of fiber material, and 3-15 parts by weight of additives as raw materials in parts by weight; Step 2: Grinding each raw material to more than 80 meshes and then fully mixing and stirring to obtain a mixed raw material; Step 3: After the mixed raw materials are prepared into a board blank by a flow-flow method or a scissoring method, the board blank is sent into an autoclave for curing treatment, so as to finally obtain a board product. 如請求項9所述的製備調濕防滑火山岩板材的方法,其中,通過蒸壓釜進行固化處理時具體為:於1-10Mpa飽和蒸氣壓下,恆壓處理12-24小時。The method for preparing the humidity-adjusting non-slip volcanic rock plate as described in Claim 9, wherein the curing treatment by an autoclave is specifically: under the saturated vapor pressure of 1-10Mpa, constant pressure treatment for 12-24 hours.
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