TW202231952A - Method for manufacturing antibacterial melt-blown non-woven fabric - Google Patents

Method for manufacturing antibacterial melt-blown non-woven fabric Download PDF

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TW202231952A
TW202231952A TW110108353A TW110108353A TW202231952A TW 202231952 A TW202231952 A TW 202231952A TW 110108353 A TW110108353 A TW 110108353A TW 110108353 A TW110108353 A TW 110108353A TW 202231952 A TW202231952 A TW 202231952A
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antibacterial
melt
manufacturing
nonwoven fabric
natural
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TW110108353A
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錢建豪
胡宛婷
梁宗德
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台灣科德寶寶翎不織布股份有限公司
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Abstract

The invention provides a method for manufacturing an antibacterial melt-blown non-woven fabric, which includes the following steps. Natural antibacterial powders and polymer materials are melt-blended and granulated to form antibacterial particles. Afterwards, the antibacterial particles are subjected to a melt-blown process, so as to make an antibacterial melt-blown non-woven fabric.

Description

抗菌熔噴不織布的製造方法Manufacturing method of antibacterial meltblown nonwoven fabric

本發明是有關於一種熔噴不織布的製造方法,且特別是有關於一種抗菌熔噴不織布的製造方法。The present invention relates to a manufacturing method of a melt-blown non-woven fabric, and in particular, to a manufacturing method of an antibacterial melt-blown non-woven fabric.

隨著生活水準的提升,人類對於居家環境與個人衛生的要求也越來越提高。近年來,已開發各種具有抗菌功效的商品,且產品的抗菌功能性為業界不斷創新與發展的主要目標。在紡織領域中,不織布突破了傳統的紡織原理,並具有製程短、生產速度快、產量高、成本低、用途廣、原料來源多等優點,在日常生產和生活中有著廣泛的應用。因此,在各種具有抗菌作用的產品中,抗菌熔噴不織布為受到高度重視的商品之一。With the improvement of living standards, people's requirements for home environment and personal hygiene are also increasing. In recent years, various products with antibacterial effects have been developed, and the antibacterial function of products is the main goal of continuous innovation and development in the industry. In the textile field, non-woven fabrics break through the traditional textile principle, and have the advantages of short process, fast production speed, high output, low cost, wide application, and many sources of raw materials, etc., and have a wide range of applications in daily production and life. Therefore, among various products with antibacterial effect, antibacterial meltblown nonwoven is one of the highly valued commodities.

抗菌熔噴不織布的製備過程須使用抗菌劑,抗菌劑主要包括有機抗菌劑、無機抗菌劑及天然抗菌劑三大類。有機抗菌劑的成分以有機酸、酚、醇、酯為主,其殺菌效果顯著,但易使細菌產生抗藥性,並具有嚴重的毒副作用,會對人體產生危害,因此,有機抗菌劑不能用於纖維的功能性處理。無機抗菌劑大多是無機物載銀、鋅、銅離子的複合物,抗菌有效期長,對皮膚刺激性小,但抗菌作用起效較晚。天然抗菌劑主要是從動植物中提取的蛋白類、糖類、油劑類和酚類化合物等天然成分,具有毒副作用低、使用安全等特點。然而,在習知抗菌熔噴不織布的製備過程中,即使使用天然抗菌劑進行加工,以改善有機抗菌劑及無機抗菌劑的缺點,仍具有天然抗菌劑容易脫落而不可水洗的缺點,進而導致抗菌效果受到影響而降低,且因不可水洗而導致使用操作便利性受到限制。The preparation process of antibacterial meltblown nonwovens requires the use of antibacterial agents, which mainly include three categories: organic antibacterial agents, inorganic antibacterial agents and natural antibacterial agents. The ingredients of organic antibacterial agents are mainly organic acids, phenols, alcohols and esters, which have a significant bactericidal effect, but are easy to make bacteria resistant to drugs, and have serious toxic and side effects, which will cause harm to the human body. Therefore, organic antibacterial agents cannot be used. Functional treatment of fibers. Most of the inorganic antibacterial agents are complexes of silver, zinc and copper ions carried by inorganic substances. Natural antibacterial agents are mainly natural ingredients such as proteins, sugars, oils and phenolic compounds extracted from animals and plants, which have the characteristics of low toxicity and side effects and safe use. However, in the preparation process of the conventional antibacterial meltblown nonwoven fabric, even if the natural antibacterial agent is used for processing to improve the shortcomings of the organic antibacterial agent and the inorganic antibacterial agent, the natural antibacterial agent still has the disadvantage that the natural antibacterial agent is easy to fall off and cannot be washed with water, thereby causing antibacterial agents. The effect is affected and reduced, and the convenience of use and operation is limited because it cannot be washed with water.

基於上述,發展出一種抗菌熔噴不織布的製造方法,以改善習知技術中天然抗菌劑容易脫落而不可水洗的缺點,進而提升抗菌效果並增加操作便利性,為目前所需研究的重要課題。Based on the above, a method for manufacturing an antibacterial meltblown nonwoven fabric has been developed to improve the shortcomings of the conventional technology that the natural antibacterial agent is easy to fall off and cannot be washed with water, thereby improving the antibacterial effect and increasing the convenience of operation, which is an important topic currently required for research.

本發明提供一種抗菌熔噴不織布的製造方法,能夠改善習知技術中天然抗菌劑容易脫落而不可水洗的缺點,進而提升抗菌效果並增加操作便利性。The invention provides a method for manufacturing an antibacterial melt-blown nonwoven fabric, which can improve the shortcomings of the conventional technology that the natural antibacterial agent is easy to fall off and cannot be washed with water, thereby improving the antibacterial effect and increasing the convenience of operation.

本發明提供一種抗菌熔噴不織布的製造方法,包括以下步驟。將天然抗菌粉體與高分子材料進行熔融共混造粒製程,以形成抗菌粒子。之後,將抗菌粒子進行熔噴製程,以製成抗菌熔噴不織布。The present invention provides a method for manufacturing an antibacterial meltblown nonwoven fabric, which comprises the following steps. The natural antibacterial powder and polymer materials are melt-blended and granulated to form antibacterial particles. After that, the antibacterial particles are subjected to a melt-blown process to produce an antibacterial melt-blown nonwoven fabric.

在本發明的一實施例中,天然抗菌粉體是由天然植物提煉而成,成分包括肉桂醛。In an embodiment of the present invention, the natural antibacterial powder is extracted from natural plants, and the components include cinnamaldehyde.

在本發明的一實施例中,天然抗菌粉體在溫度200℃至270℃下抗菌功能不會失效。In an embodiment of the present invention, the antibacterial function of the natural antibacterial powder will not fail at a temperature of 200°C to 270°C.

在本發明的一實施例中,天然抗菌粉體的粒徑為40 μm至50 μm。In an embodiment of the present invention, the particle size of the natural antibacterial powder is 40 μm to 50 μm.

在本發明的一實施例中,高分子材料為可熔噴的高分子材料粒子,且高分子材料包括聚乙烯、聚丙烯、聚醯胺或聚氨酯。In an embodiment of the present invention, the polymer material is melt-blown polymer material particles, and the polymer material includes polyethylene, polypropylene, polyamide or polyurethane.

在本發明的一實施例中,在熔融共混造粒製程中,以天然抗菌粉體與高分子材料的總重量計,天然抗菌粉體的添加量為0.5 wt%至10 wt%。In an embodiment of the present invention, in the melt blending and granulation process, based on the total weight of the natural antibacterial powder and the polymer material, the added amount of the natural antibacterial powder is 0.5 wt % to 10 wt %.

在本發明的一實施例中,在熔融共混造粒製程中,螺桿溫度為170℃至200℃,模頭溫度為200℃至210℃。In an embodiment of the present invention, in the melt blending granulation process, the temperature of the screw is 170°C to 200°C, and the temperature of the die head is 200°C to 210°C.

在本發明的一實施例中,在熔噴製程中,螺桿溫度為170℃至230℃,紡孔溫度為230℃至270℃,吐出量為30 kg/hr至60 kg/hr。In an embodiment of the present invention, in the melt blowing process, the screw temperature is 170°C to 230°C, the spinning hole temperature is 230°C to 270°C, and the discharge rate is 30 kg/hr to 60 kg/hr.

在本發明的一實施例中,抗菌粒子的粒徑為2.5 mm至3.5 mm * 2.0 mm至3.0 mm,含水率小於2000 ppm。In an embodiment of the present invention, the particle size of the antibacterial particles is 2.5 mm to 3.5 mm * 2.0 mm to 3.0 mm, and the moisture content is less than 2000 ppm.

在本發明的一實施例中,抗菌熔噴不織布經JIS L1902測試金黃葡萄球菌及肺炎桿菌,所測得的靜菌活性值(Bactereostatic activity value)為2.2 以上;抗菌熔噴不織布經ASTM E2149測試金黃葡萄球菌及肺炎桿菌,細菌減少百分比大於或等於99%。In one embodiment of the present invention, the antibacterial meltblown non-woven fabric is tested by JIS L1902 for Staphylococcus aureus and Bacillus pneumoniae, and the measured Bactereostatic activity value is above 2.2; the antibacterial meltblown nonwoven fabric is tested for golden yellow by ASTM E2149 Staphylococcus and Pneumococcus, the percentage of bacterial reduction is greater than or equal to 99%.

基於上述,本發明提供一種抗菌熔噴不織布的製造方法,其中將天然抗菌粉體與高分子材料進行熔融共混造粒製程,以形成抗菌粒子,再將抗菌粒子進行熔噴製程,以製成抗菌熔噴不織布。如此一來,可使抗菌粉體在抗菌熔噴不織布的表面及內部均勻分布,避免抗菌粉體從抗菌熔噴不織布脫落,因此,能夠改善習知技術中天然抗菌劑容易脫落而不可水洗的缺點,進而提升抗菌效果並增加操作便利性。Based on the above, the present invention provides a method for manufacturing an antibacterial melt-blown nonwoven fabric, wherein the natural antibacterial powder and the polymer material are subjected to a melt-blending granulation process to form antibacterial particles, and then the antibacterial particles are subjected to a melt-blown process to make Antibacterial meltblown nonwoven. In this way, the antibacterial powder can be evenly distributed on the surface and the interior of the antibacterial meltblown non-woven fabric, and the antibacterial powder can be prevented from falling off from the antibacterial meltblown nonwoven fabric. Therefore, the disadvantage of the conventional technology that the natural antibacterial agent is easy to fall off and cannot be washed can be improved. , thereby enhancing the antibacterial effect and increasing the convenience of operation.

以下,將詳細描述本發明的實施例。然而,這些實施例為例示性,且本發明揭露不限於此。Hereinafter, embodiments of the present invention will be described in detail. However, these embodiments are exemplary, and the present disclosure is not limited thereto.

在本文中,由「一數值至另一數值」表示的範圍,是一種避免在說明書中一一列舉該範圍中的所有數值的概要性表示方式。因此,某一特定數值範圍的記載,涵蓋該數值範圍內的任意數值以及由該數值範圍內的任意數值界定出的較小數值範圍,如同在說明書中說明文寫出該任意數值和該較小數值範圍一樣。As used herein, a range represented by "one value to another value" is a general representation that avoids listing all the values in the range in the specification. Accordingly, the recitation of a particular numerical range includes any numerical value within that numerical range as well as a smaller numerical range bounded by any numerical value within that numerical range, as if the arbitrary numerical value and the smaller numerical range were written in the description in the specification The value range is the same.

本發明提供一種抗菌熔噴不織布的製造方法,包括以下步驟。將天然抗菌粉體與高分子材料進行熔融共混造粒製程,以形成抗菌粒子。之後,將抗菌粒子進行熔噴製程,以製成抗菌熔噴不織布。The present invention provides a method for manufacturing an antibacterial meltblown nonwoven fabric, which comprises the following steps. The natural antibacterial powder and polymer materials are melt-blended and granulated to form antibacterial particles. After that, the antibacterial particles are subjected to a melt-blown process to produce an antibacterial melt-blown nonwoven fabric.

在本實施例中,天然抗菌粉體是由天然植物提煉而成,成分可包括肉桂醛,但本發明並不以此為限。天然抗菌粉體在溫度200℃至270℃下抗菌功能不會失效。天然抗菌粉體的粒徑為約40 μm至50 μm,當天然抗菌粉體的粒徑在此範圍內時,可降低後續熔融共混造粒製程中飛散的可能性。In this embodiment, the natural antibacterial powder is extracted from natural plants, and the components may include cinnamaldehyde, but the present invention is not limited to this. The antibacterial function of natural antibacterial powder will not fail under the temperature of 200℃ to 270℃. The particle size of the natural antibacterial powder is about 40 μm to 50 μm. When the particle size of the natural antibacterial powder is within this range, the possibility of scattering in the subsequent melt blending and granulation process can be reduced.

在本實施例中,高分子材料為可熔噴的高分子材料粒子,且高分子材料可包括聚乙烯、聚丙烯、聚醯胺或聚氨酯,但本發明並不以此為限。高分子材料沒有氣味,且高分子材料在230℃的溫度及2.16公斤的負荷下之熔融指數(MI)是在20 g/10min至1600 g/10min範圍內。In this embodiment, the polymer material is melt-blown polymer material particles, and the polymer material may include polyethylene, polypropylene, polyamide or polyurethane, but the present invention is not limited thereto. The polymer material has no odor, and the melt index (MI) of the polymer material at a temperature of 230° C. and a load of 2.16 kg is in the range of 20 g/10min to 1600 g/10min.

在本實施例中,在熔融共混造粒製程中,以天然抗菌粉體與高分子材料的總重量計,天然抗菌粉體的添加量為約0.5 wt%至10 wt%。此外,在熔融共混造粒製程中,螺桿溫度為約170℃至200℃,模頭溫度為約200℃至210℃。In this embodiment, in the melt blending and granulation process, based on the total weight of the natural antibacterial powder and the polymer material, the added amount of the natural antibacterial powder is about 0.5 wt % to 10 wt %. In addition, in the melt blending granulation process, the screw temperature is about 170°C to 200°C, and the die temperature is about 200°C to 210°C.

在本實施例中,關於熔融共混造粒製程所形成的抗菌粒子,在例如是以聚丙烯作為高分子材料的條件下,粒徑為約2.5 mm至3.5 mm * 2.0 mm至3.0 mm,含水率小於2000 ppm。抗菌粒子在170℃的溫度及2.16公斤的負荷下之熔融指數(MI)是在150 g/10min至400 g/10min範圍內,且過濾試驗值為2 bar至4 bar。In this embodiment, regarding the antibacterial particles formed by the melt blending and granulation process, for example, under the condition that polypropylene is used as the polymer material, the particle size is about 2.5 mm to 3.5 mm * 2.0 mm to 3.0 mm, and contains water. rate is less than 2000 ppm. The melt index (MI) of the antimicrobial particles at a temperature of 170°C and a load of 2.16 kg is in the range of 150 g/10min to 400 g/10min, and the filter test value is 2 bar to 4 bar.

在本實施例中,在熔噴製程中,在例如是以聚丙烯作為高分子材料的條件下,螺桿溫度為約170℃至230℃,紡孔溫度為約230℃至270℃,吐出量約為30 kg/hr至60 kg/hr。In this embodiment, in the melt blowing process, under the condition that polypropylene is used as the polymer material, the screw temperature is about 170°C to 230°C, the spinning hole temperature is about 230°C to 270°C, and the discharge rate is about 30 kg/hr to 60 kg/hr.

在本實施例中,關於熔噴製程所製成的抗菌熔噴不織布,拉伸強度縱向(MD)大於或等於7,橫向(CD)大於或等於6。此外,抗菌熔噴不織布經JIS L1902測試金黃葡萄球菌及肺炎桿菌,所測得的靜菌活性值(Bactereostatic activity value)為2.2以上;抗菌熔噴不織布經ASTM E2149測試金黃葡萄球菌及肺炎桿菌,細菌減少百分比大於或等於99%。抗菌熔噴不織布的濾效大於或等於99%(3 μm),且壓差小於20 Pa。In this embodiment, for the antibacterial meltblown nonwoven fabric made by the meltblown process, the tensile strength in the longitudinal direction (MD) is greater than or equal to 7, and the transverse direction (CD) is greater than or equal to 6. In addition, the antibacterial meltblown non-woven fabric was tested by JIS L1902 for Staphylococcus aureus and pneumoniae, and the measured Bactereostatic activity value was above 2.2; the antibacterial meltblown nonwoven fabric was tested by ASTM E2149 for Staphylococcus aureus and pneumoniae, bacteria The percentage reduction is greater than or equal to 99%. The filtration efficiency of the antibacterial meltblown non-woven fabric is greater than or equal to 99% (3 μm), and the pressure difference is less than 20 Pa.

綜上所述,本發明提供一種抗菌熔噴不織布的製造方法,其中將天然抗菌粉體與高分子材料進行熔融共混造粒製程,以形成抗菌粒子,再將抗菌粒子進行熔噴製程,以製成抗菌熔噴不織布。如此一來,可使抗菌粉體在抗菌熔噴不織布的表面及內部均勻分布,避免抗菌粉體從抗菌熔噴不織布脫落,因此,能夠改善習知技術中天然抗菌劑容易脫落而不可水洗的缺點,進而提升抗菌效果並增加操作便利性。此外,本發明的抗菌熔噴不織布經JIS L1902測試金黃葡萄球菌及肺炎桿菌,所測得的靜菌活性值(Bactereostatic activity value)為2.2以上;經ASTM E2149測試金黃葡萄球菌及肺炎桿菌,細菌減少百分比大於或等於99%。因此,可得知本發明的抗菌熔噴不織布具有良好的抗菌效果。To sum up, the present invention provides a method for manufacturing an antibacterial meltblown nonwoven fabric, wherein a natural antibacterial powder and a polymer material are subjected to a melt blending and granulation process to form antibacterial particles, and then the antibacterial particles are subjected to a meltblown process to obtain an antibacterial particle. Made of antibacterial meltblown nonwoven. In this way, the antibacterial powder can be uniformly distributed on the surface and inside of the antibacterial meltblown non-woven fabric, and the antibacterial powder can be prevented from falling off from the antibacterial meltblown nonwoven fabric. Therefore, the disadvantage of the conventional technology that the natural antibacterial agent is easy to fall off and cannot be washed can be improved. , thereby enhancing the antibacterial effect and increasing the convenience of operation. In addition, the antibacterial melt-blown non-woven fabric of the present invention is tested by JIS L1902 for Staphylococcus aureus and Pneumococcus, and the measured Bactereostatic activity value is above 2.2; when tested by ASTM E2149, Staphylococcus aureus and Pneumococcus reduce bacteria. The percentage is greater than or equal to 99%. Therefore, it can be known that the antibacterial meltblown nonwoven fabric of the present invention has a good antibacterial effect.

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Claims (10)

一種抗菌熔噴不織布的製造方法,包括: 將天然抗菌粉體與高分子材料進行熔融共混造粒製程,以形成抗菌粒子;以及 將所述抗菌粒子進行熔噴製程,以製成抗菌熔噴不織布。 A manufacturing method of antibacterial meltblown nonwoven, comprising: The natural antibacterial powder and the polymer material are melt-blended and granulated to form antibacterial particles; and The antibacterial particles are subjected to a melt-blown process to produce an antibacterial melt-blown non-woven fabric. 如請求項1所述之抗菌熔噴不織布的製造方法,其中所述天然抗菌粉體是由天然植物提煉而成,成分包括肉桂醛。The method for manufacturing an antibacterial meltblown nonwoven fabric according to claim 1, wherein the natural antibacterial powder is extracted from natural plants, and the components include cinnamaldehyde. 如請求項1所述之抗菌熔噴不織布的製造方法,其中所述天然抗菌粉體在溫度200℃至270℃下抗菌功能不會失效。The method for manufacturing an antibacterial meltblown nonwoven fabric according to claim 1, wherein the antibacterial function of the natural antibacterial powder will not fail at a temperature of 200°C to 270°C. 如請求項1所述之抗菌熔噴不織布的製造方法,其中所述天然抗菌粉體的粒徑為40 μm至50 μm。The method for producing an antibacterial meltblown nonwoven fabric according to claim 1, wherein the particle size of the natural antibacterial powder is 40 μm to 50 μm. 如請求項1所述之抗菌熔噴不織布的製造方法,其中所述高分子材料為可熔噴的高分子材料粒子,且所述高分子材料包括聚乙烯、聚丙烯、聚醯胺或聚氨酯。The method for manufacturing an antibacterial melt-blown nonwoven fabric according to claim 1, wherein the polymer material is a melt-blown polymer material particle, and the polymer material comprises polyethylene, polypropylene, polyamide or polyurethane. 如請求項1所述之抗菌熔噴不織布的製造方法,其中在所述熔融共混造粒製程中,以所述天然抗菌粉體與所述高分子材料的總重量計,所述天然抗菌粉體的添加量為0.5 wt%至10 wt%。The method for manufacturing an antibacterial meltblown nonwoven fabric according to claim 1, wherein in the melt blending and granulation process, the natural antibacterial powder is based on the total weight of the natural antibacterial powder and the polymer material. The body is added in an amount of 0.5 wt% to 10 wt%. 如請求項1所述之抗菌熔噴不織布的製造方法,其中在所述熔融共混造粒製程中,螺桿溫度為170℃至200℃,模頭溫度為200℃至210℃。The method for manufacturing an antibacterial meltblown nonwoven fabric according to claim 1, wherein in the melt blending and granulation process, the temperature of the screw is 170°C to 200°C, and the temperature of the die is 200°C to 210°C. 如請求項1所述之抗菌熔噴不織布的製造方法,其中在所述熔噴製程中,螺桿溫度為170℃至230℃,紡孔溫度為230℃至270℃,吐出量為30 kg/hr至60 kg/hr。The method for manufacturing an antibacterial meltblown nonwoven fabric according to claim 1, wherein in the meltblown process, the screw temperature is 170°C to 230°C, the spinning hole temperature is 230°C to 270°C, and the discharge rate is 30 kg/hr to 60 kg/hr. 如請求項1所述之抗菌熔噴不織布的製造方法,其中所述抗菌粒子的粒徑為2.5 mm至3.5 mm * 2.0 mm至3.0 mm,含水率小於2000 ppm。The method for manufacturing an antibacterial meltblown nonwoven fabric according to claim 1, wherein the particle size of the antibacterial particles is 2.5 mm to 3.5 mm * 2.0 mm to 3.0 mm, and the moisture content is less than 2000 ppm. 如請求項1所述之抗菌熔噴不織布的製造方法,其中所述抗菌熔噴不織布經JIS L1902測試金黃葡萄球菌及肺炎桿菌,所測得的靜菌活性值(Bactereostatic activity value)為2.2以上;所述抗菌熔噴不織布經ASTM E2149測試金黃葡萄球菌及肺炎桿菌,細菌減少百分比大於或等於99%。The manufacturing method of the antibacterial meltblown non-woven fabric according to claim 1, wherein the antibacterial meltblown nonwoven fabric is tested by JIS L1902 for Staphylococcus aureus and Pneumococcus, and the measured Bactereostatic activity value is above 2.2; The antibacterial meltblown non-woven fabric is tested by ASTM E2149 for Staphylococcus aureus and Pneumococcus, and the bacterial reduction percentage is greater than or equal to 99%.
TW110108353A 2021-02-02 2021-03-09 Method for manufacturing antibacterial melt-blown non-woven fabric TW202231952A (en)

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