TW202228554A - Brush molded body, and toothbrush - Google Patents
Brush molded body, and toothbrush Download PDFInfo
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- TW202228554A TW202228554A TW110148035A TW110148035A TW202228554A TW 202228554 A TW202228554 A TW 202228554A TW 110148035 A TW110148035 A TW 110148035A TW 110148035 A TW110148035 A TW 110148035A TW 202228554 A TW202228554 A TW 202228554A
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- bristle
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- filaments
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- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B5/00—Brush bodies; Handles integral with brushware
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- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B9/00—Arrangements of the bristles in the brush body
- A46B9/02—Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups
- A46B9/04—Arranged like in or for toothbrushes
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- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
- A46D1/02—Bristles details
- A46D1/0207—Bristles characterised by the choice of material, e.g. metal
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
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- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B2200/00—Brushes characterized by their functions, uses or applications
- A46B2200/10—For human or animal care
- A46B2200/1066—Toothbrush for cleaning the teeth or dentures
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Abstract
Description
本發明是有關於一種刷毛成形體以及牙刷。 本申請案基於2020年12月24日在日本提出申請的日本專利特願2020-214798號而主張優先權,且將其內容引用於本申請案中。 The present invention relates to a bristle molded body and a toothbrush. This application claims priority based on Japanese Patent Application No. 2020-214798 for which it applied in Japan on December 24, 2020, and the content is used in this application.
已提出有一種僅利用射出成形機來製造牙刷的一體成形牙刷(例如,專利文獻1)。一體成形牙刷由於將細絲與刷頭基座部(或刷頭部)一體地成形,因此不需要細絲的材料採購及植毛機,具有可較植毛牙刷更廉價地製造的優點。There has been proposed an integrally formed toothbrush in which a toothbrush is manufactured only by an injection molding machine (for example, Patent Document 1). Since the filaments are integrally formed with the brush head base (or the brush head), the integrally formed toothbrush does not require material procurement of the filaments and a hair planting machine, and has the advantage that it can be manufactured at a lower cost than a bristle toothbrush.
作為刷掃用的一體成形牙刷,提出有將具有細絲及插入孔的刷頭部(刷毛成形體)、及於一端設置有插入部的柄部分開成形,並使兩者嵌合,藉此提供一體成形牙刷(例如,專利文獻2、專利文獻3)。專利文獻2、專利文獻3中記載的牙刷可由使用者來更換刷頭部,因此期待僅將刷頭部廢棄而可重覆使用柄等省資源化。As an integrally-molded toothbrush for brushing, it has been proposed to separate a brush head (molded bristle body) having a filament and an insertion hole, and a shank portion provided with an insertion portion at one end, and to fit the two together. An integrally formed toothbrush is provided (for example, Patent Document 2, Patent Document 3). Since the toothbrush described in Patent Document 2 and Patent Document 3 can be replaced by a user, the brush head is only discarded, and resource saving such as a handle that can be reused is expected.
由於所述刷頭部由單一的樹脂材料成形,因此於提高牙刷的使用感、外觀性(設計性)的方面存在極限。 專利文獻4中公開了一種技術,即:使用配置有另成形的柄部的模具,對包含不同的多種樹脂組成物的細絲進行嵌入成形。 [現有技術文獻] [專利文獻] Since the brush head is formed of a single resin material, there is a limit in improving the usability and appearance (design) of the toothbrush. Patent Document 4 discloses a technique of insert-molding filaments containing a plurality of different resin compositions by using a mold provided with a separately molded shank. [Prior Art Literature] [Patent Literature]
[專利文獻1]日本專利實開昭61-207233號公報 [專利文獻2]中國實用新型第204561298號說明書 [專利文獻3]中國專利申請公開第107041792號說明書 [專利文獻4]中國實用新型第205214577號說明書 [Patent Document 1] Japanese Patent Application Laid-Open No. 61-207233 [Patent Document 2] Chinese Utility Model No. 204561298 Specification [Patent Document 3] Chinese Patent Application Publication No. 107041792 Specification [Patent Document 4] Chinese Utility Model No. 205214577 Specification
[發明所欲解決之課題] 然而,於專利文獻4所記載的牙刷中,設置有劃分多種顏色的細絲的壁,因此於壁的部分無法配置細絲而形成空間。因此,存在如下問題:難以以規則連續的輪廓配置細絲,插入口腔內的刷頭部的溫柔的觸感受損。 [The problem to be solved by the invention] However, in the toothbrush of patent document 4, since the wall which divides the filament of a plurality of colors is provided, the filament cannot be arrange|positioned in the part of a wall, and a space is formed. Therefore, there is a problem that it is difficult to arrange the filaments in a regular continuous contour, and the gentle touch of the brush head inserted into the oral cavity is impaired.
本發明是考慮到以上方面而成者,其目的在於提供一種具有溫柔的觸感且可提高牙刷的使用感、外觀性的刷毛成形體以及牙刷。 [解決課題之手段] The present invention was made in consideration of the above points, and an object thereof is to provide a bristle molded body and a toothbrush which have a soft touch and can improve the usability and appearance of the toothbrush. [Means of Solving Problems]
根據本發明的第一形態,提供一種刷毛成形體,其特徵在於,具有由軟質樹脂形成的刷頭基座部、及自位於所述刷頭基座部的厚度方向的正面側的支撐面突出的多根細絲,所述刷頭基座部具有沿與所述厚度方向正交的長度方向延伸並向該長度方向的其中一側開口的嵌合孔,且所述刷毛成形體包括預成形體以及基座本體成形體,所述預成形體具有包含所述多根細絲的至少一部分的細絲群、及支撐所述細絲群的基部並且位於較所述嵌合孔更靠所述正面側且形成所述刷頭基座部的一部分的支撐座部,且至少一部分由第一樹脂組成物成形,所述基座本體成形體具有所述刷頭基座部與所述多根細絲中的所述預成形體以外的部位,且由與所述第一樹脂組成物不同的第二樹脂組成物成形,所述預成形體與所述基座本體成形體為一體成形的成形體。According to a first aspect of the present invention, there is provided a bristle molded body having a brush head base portion formed of a soft resin, and a support surface protruding from a support surface located on the front side in the thickness direction of the brush head base portion a plurality of filaments, the brush head base portion has a fitting hole extending along a longitudinal direction orthogonal to the thickness direction and opening to one side of the longitudinal direction, and the brush bristle forming body includes a preform A body and a base body formed body, the preform has a filament group including at least a part of the plurality of filaments, and a base that supports the filament group and is located closer to the fitting hole than the fitting hole. A support seat part on the front side and forming a part of the brush head base part, at least a part of which is formed from a first resin composition, and the base body molded body has the brush head base part and the plurality of thin strips. A molded body in which the portion other than the preform in the yarn is molded from a second resin composition different from the first resin composition, and the preform and the base body molded body are integrally molded .
另外,於所述本發明的一形態的刷毛成形體中,其特徵在於,所述多根細絲的一部分構成由所述第一樹脂組成物成形的所述細絲群,所述多根細絲中的所述細絲群以外的所述細絲構成利用所述第二樹脂組成物與所述刷頭基座部一體地成形的所述基座本體成形體。In addition, in the bristle molded body according to one aspect of the present invention, a part of the plurality of filaments constitutes the filament group formed from the first resin composition, and the plurality of filaments are characterized in that The filaments other than the filament group among the filaments constitute the base body molded body integrally molded with the brush head base portion by the second resin composition.
另外,於所述本發明的一形態的刷毛成形體中,其特徵在於,於與所述刷頭基座部的所述長度方向正交的剖面上,若將所述支撐座部的剖面面積設為S1,將所述嵌合孔內部的位於所述正面側的面與所述支撐面之間的區域的剖面面積設為S,則由S1/S表示的值於設有所述嵌合孔的整個區域中為0.6以下。In addition, in the bristle molded body according to one aspect of the present invention, in a cross-section perpendicular to the longitudinal direction of the brush head base portion, when the cross-sectional area of the support seat portion is S1 is assumed, and the cross-sectional area of the region between the surface on the front side and the support surface inside the fitting hole is denoted by S, the value represented by S1/S is the value in which the fitting hole is provided. It is 0.6 or less in the whole area of a hole.
另外,於所述本發明的一形態的刷毛成形體中,其特徵在於,於與所述長度方向正交的剖面上,若將所述嵌合孔的剖面面積設為SV,將所述刷頭基座部的剖面面積設為SW,則由SV/(SW-S1)表示的值於設有所述嵌合孔的整個區域中為0.5以下。In addition, in the brush bristle molded body according to one aspect of the present invention, in a cross-section perpendicular to the longitudinal direction, the brush Assuming that the cross-sectional area of the head base portion is SW, the value represented by SV/(SW-S1) is 0.5 or less in the entire region in which the fitting hole is provided.
另外,於所述本發明的一形態的刷毛成形體中,其特徵在於,若將自所述厚度方向的正面側觀察的所述刷頭基座部的面積設為P,將自所述厚度方向的正面側觀察的所述支撐座部的面積設為P1,則由P1/P表示的值為0.1以上且0.5以下。Moreover, in the bristle molded body of one aspect of the present invention, when the area of the brush head base portion viewed from the front side in the thickness direction is defined as P, the thickness from the When the area of the said support seat part seen from the front side of a direction is set to P1, the value represented by P1/P is 0.1 or more and 0.5 or less.
另外,於所述本發明的一形態的刷毛成形體中,其特徵在於,自所述細絲的基端至在所述厚度方向上與正面側為相反側的所述刷頭基座部的背面為止的最大距離為2.0 mm以上且4.5 mm以下。In addition, in the bristle molded body according to one aspect of the present invention, a distance from the base end of the filament to the brush head base portion on the opposite side to the front side in the thickness direction is characterized in that The maximum distance to the back is 2.0 mm or more and 4.5 mm or less.
另外,於所述本發明的一形態的刷毛成形體中,其特徵在於,若將自所述細絲的基端至所述刷頭基座部的背面為止的最大距離設為T,將所述支撐座部的所述厚度方向的厚度設為t1,則由t1/T表示的值為0.5以下。In addition, in the bristle molded body according to one aspect of the present invention, if the maximum distance from the proximal end of the filament to the back surface of the brush head base portion is T, the Assuming that the thickness in the thickness direction of the support seat portion is t1, the value represented by t1/T is 0.5 or less.
另外,於所述本發明的一形態的刷毛成形體中,其特徵在於,若將所述支撐座部的所述背面側的面與所述嵌合孔內部的所述正面側的面的距離設為t2,則由t1/(t1+t2)表示的值為0.2以上且0.8以下。Further, in the bristle molded body according to one aspect of the present invention, when the distance between the surface on the back side of the support seat portion and the surface on the front side inside the fitting hole is As t2, the value represented by t1/(t1+t2) is 0.2 or more and 0.8 or less.
另外,於所述本發明的一形態的刷毛成形體中,其特徵在於,若將所述細絲群中的所述細絲的根數設為FM,將所述支撐座部與所述基座本體成形體黏接的面積設為Q1(mm 2),則由FM/Q1表示的值為1.0(根/mm 2)以下。 In addition, in the bristle molded body according to one aspect of the present invention, if the number of the filaments in the filament group is FM, the support seat and the base are When the area where the seat body molded body is bonded is set to Q1 (mm 2 ), the value represented by FM/Q1 is 1.0 (pieces/mm 2 ) or less.
另外,於所述本發明的一形態的刷毛成形體中,其特徵在於,於所述支撐座部與所述基座本體成形體的黏接界面設有凹凸結構。In addition, in the bristle molded body according to one aspect of the present invention, a concavo-convex structure is provided at the bonding interface between the support seat portion and the base body molded body.
另外,於所述本發明的一形態的刷毛成形體中,其特徵在於,若將所述長度方向的所述刷頭基座部的最大長度設為L1,將所述長度方向的所述嵌合孔的最大長度設為L2,則由L2/L1表示的值為0.30以上且0.70以下。In addition, in the bristle molded body according to one aspect of the present invention, if the maximum length of the brush head base portion in the longitudinal direction is L1, the fitting in the longitudinal direction is set to L1. Assuming that the maximum length of the closing hole is L2, the value represented by L2/L1 is 0.30 or more and 0.70 or less.
另外,於所述本發明的一形態的刷毛成形體中,其特徵在於,所述預成形體具有所述多根細絲的全部。Moreover, in the brush bristle molding of one aspect of the present invention, the preform has all of the plurality of filaments.
另外,於所述本發明的一形態的刷毛成形體中,其特徵在於,所述預成形體具有:所述細絲群及所述支撐座部,由所述第一樹脂組成物成形;以及第二支撐座部,由與所述第一樹脂組成物及所述第二樹脂組成物不同的第三樹脂組成物成形,支撐第二細絲群及所述第二細絲群的基部。In addition, in the bristle molded body according to one aspect of the present invention, the preform is characterized in that the preform has the filament group and the support seat portion, and is molded from the first resin composition; and The second support seat is formed of a third resin composition different from the first resin composition and the second resin composition, and supports the second filament group and the base of the second filament group.
另外,於所述本發明的一形態的刷毛成形體中,其特徵在於,所述軟質樹脂為聚胺基甲酸酯。Moreover, in the bristle molding of one aspect of the said invention, the said soft resin is a polyurethane, It is characterized by the above-mentioned.
根據本發明的第二形態,提供一種牙刷,其特徵在於包括:本發明的第一形態的刷毛成形體、以及由硬質樹脂形成且具有對所述刷毛成形體的所述嵌合孔裝卸自如的嵌合突部的柄體。According to a second aspect of the present invention, there is provided a toothbrush comprising: the bristle molded body according to the first aspect of the present invention; The handle body of the fitting protrusion.
根據本發明的第三形態,提供一種牙刷,其特徵在於包括:本發明的第一形態的刷毛成形體、以及具有嵌合於所述刷毛成形體的所述嵌合孔的嵌合突部,所述刷毛成形體與所述柄體為一體成形的成形體。 [發明的效果] According to a third aspect of the present invention, there is provided a toothbrush comprising: the bristle molded body of the first aspect of the present invention; The bristle forming body and the handle body are integrally formed forming bodies. [Effect of invention]
於本發明中,提供一種具有溫柔的觸感且可提高牙刷的使用感、外觀性的刷毛成形體以及牙刷。In the present invention, there is provided a bristle molded body and a toothbrush which have a soft touch and can improve the usability and appearance of the toothbrush.
以下,參照圖1至圖18說明本發明的刷毛成形體以及牙刷的實施方式。於本實施方式中,使用刷毛成形體裝卸自如地設置於柄體上的牙刷的例子進行說明。Hereinafter, embodiments of the formed bristle body and the toothbrush of the present invention will be described with reference to FIGS. 1 to 18 . In this embodiment, the example of the toothbrush in which the bristle molding body is detachably provided in the handle body is demonstrated.
再者,以下的實施方式表示本發明的一形態,並不限定本發明,可於本發明的技術思想的範圍內任意地進行變更。另外,於以下的圖式中,為了容易理解各結構,使各結構中的比例尺或數量等與實際的結構不同。In addition, the following embodiment shows one form of this invention, It does not limit this invention, It can change arbitrarily within the range of the technical idea of this invention. In addition, in the following drawings, in order to make it easy to understand each structure, the scale, the number, etc. in each structure are made to differ from an actual structure.
圖1是本實施方式的刷毛成形體20以及牙刷1的正面圖。圖2是刷毛成形體20以及牙刷1的側面圖。牙刷1包括棒狀的柄體10、及刷毛成形體20。柄體10與刷毛成形體20是分開的構件。刷毛成形體20可裝卸自如地安裝於(插入)柄體10。刷毛成形體20由軟質樹脂形成。柄體10由硬質樹脂形成。FIG. 1 : is a front view of the
再者,本實施方式中的正面是指刷毛成形體20的支撐面21a(詳細情況將後述)的法線方向即厚度方向(以下,僅稱為厚度方向)之中,後述的細絲23突出之側(圖2中的上側)。於刷毛成形體20的厚度方向上,將與正面側相反的一側適宜稱為背面側。另外,柄體10的長度方向,即相對於刷毛成形體20插入柄體10的方向(以下,僅稱為插入方向)與所述法線方向正交。於長度方向上,將相對於刷毛成形體20安裝柄體10的一側稱為後端側,將與後端側相反的一側適宜稱為前端側。另外,與所述法線方向及插入方向正交的方向是刷毛成形體20的寬度方向(以下,僅稱為寬度方向)。In addition, the front surface in this embodiment means that the
[刷毛成形體20的第一實施方式]
圖3是刷毛成形體20的正面圖。圖4是圖3中的A-A剖面圖。如圖3及圖4所示,刷毛成形體20包括正面觀察形狀為大致矩形形狀的刷頭基座部21、及設置於刷頭基座部21的正面的多根細絲23。
[First embodiment of the bristle molded body 20]
FIG. 3 is a front view of the bristle molded
作為構成刷毛成形體20的軟質樹脂,可使用各種彈性體,但較佳為聚胺基甲酸酯。
聚胺基甲酸酯與苯乙烯系或聚酯系等的其他彈性體相比,存在拉伸強度高的傾向,因此藉由將聚胺基甲酸酯用於軟質樹脂,即便成為薄壁,亦可確保機械強度,從而可抑制柄體10與嵌合孔22的嵌合時及牙刷1的使用時的破損。
As the soft resin constituting the bristle molded
於聚胺基甲酸酯中,調配0.01 wt%~1.0 wt%(質量%)的C10以上的飽和/不飽和烴、高級醇、脂肪酸醯胺、脂肪酸酯、低分子量聚乙烯、聚乙二醇(Polyethylene glycol,PEG)、脂肪酸金屬鹽、長鏈脂肪酸、脂肪酸甘油、液體石蠟、聚矽氧中的任一種或者將該些複合而調配,以作為潤滑劑、脫模劑發揮功能。In polyurethane, 0.01 wt % to 1.0 wt % (mass %) of saturated/unsaturated hydrocarbons above C10, higher alcohols, fatty acid amides, fatty acid esters, low molecular weight polyethylene, polyethylene di Any of alcohol (Polyethylene glycol, PEG), fatty acid metal salt, long-chain fatty acid, fatty acid glycerol, liquid paraffin, polysiloxane, or a combination of these, can function as a lubricant and a mold release agent.
另外,聚胺基甲酸酯與所述其他彈性體相比,可選擇的硬度的範圍廣,可對應於刷毛成形體20的厚度,選擇考慮了其使用性(例如,刷毛成形體前端的彎曲)的樹脂硬度。作為聚胺基甲酸酯的硬度,較佳為蕭氏(shore)90A以上且蕭氏70D以下。
於聚胺基甲酸酯的硬度較蕭氏90A更軟的情況下,當以薄壁來形成時變得容易變形,因此嵌合變弱,於牙刷1的使用時刷毛成形體20變得容易脫落。於聚胺基甲酸酯的硬度較蕭氏70D更硬的情況下,存在如下的可能性:於刷頭基座部21的背面已傾斜的情況下,當前端撞上了口腔組織時產生疼痛。藉由將聚胺基甲酸酯的硬度設為蕭氏90A以上且蕭氏70D以下,可抑制於牙刷1的使用時刷毛成形體20脫落、或刷頭基座部21的前端撞上時產生疼痛。
In addition, compared with the other elastomers described above, polyurethane can select a wider range of hardness, and can be selected according to the thickness of the bristle molded
另外,作為聚胺基甲酸酯,就確保耐水性與抗菌性的觀點而言,較佳為使用醚系聚胺基甲酸酯。In addition, as the polyurethane, it is preferable to use an ether-based polyurethane from the viewpoint of securing water resistance and antibacterial properties.
細絲23為自位於刷頭基座部21的厚度方向的正面側的支撐面21a向正面側突出的大致柱狀。刷頭基座部21的支撐面21a是與寬度方向及插入方向平行的平面。支撐面21a配置於厚度方向上的細絲23的基端位置。細絲23的基端側是剖面為大致三角形狀的大致三角柱狀,前端側是自大致三角柱延長且尖端變細的三角錐狀。作為細絲23的剖面形狀,除大致三角形以外,可選擇大致四邊形等大致多邊形、或大致圓形、大致星形、大致木鏟形等。細絲23除前端的尖端變細的錐形形狀以外,亦可為呈筆直狀地延長的結構、或自基端起尖端變細的錐形形狀。The
細絲23的沿著刷毛成形體20的寬度方向排列的行以於插入方向上鄰接的行彼此錯開半個間距的方式,沿著插入方向設置有多行。即,細絲23配置成鋸齒狀。The rows of the
圖5是自後端側觀察刷毛成形體20的圖。
如圖5所示,多根細絲23具有位於寬度方向的中央的細絲群(第一細絲群)F1及位於細絲群F1的寬度方向兩側的細絲群F2。作為一例,細絲群F1較細絲群F2更高。
作為細絲23的最大長度,較佳為7 mm以上,更佳為9 mm以上。
作為細絲23的最大長度,較佳為15 mm以下,更佳為13 mm以下。
另外,作為細絲23的最大長度,較佳為7 mm以上且15 mm以下,更佳為9 mm以上且13 mm以下。
於細絲23的最大長度未滿7 mm的情況下,存在口腔內的清掃性下降的可能性。於細絲23的最大長度超過15 mm的情況下,藉由射出成形來使刷毛成形體20成形時的脫模性下降。藉由將細絲23的最大長度設為7 mm以上且15 mm以下,可確保口腔內的清掃性及成形時的脫模性。
FIG. 5 : is the figure which looked at the bristle molded
作為細絲23的基端的剖面面積,較佳為0.8 mm
2以下,更佳為0.6 mm
2以下。於細絲23的基端的剖面面積超過0.8 mm
2的情況下,存在細絲23變得難以撓曲,齒間或齒頸部等的間隙清掃性下降的可能性。藉由將細絲23的基端的剖面面積設為0.8 mm
2以下,可確保齒間或齒頸部等的間隙清掃性。
The cross-sectional area of the proximal end of the
作為多根細絲23的基端的總剖面面積相對於刷頭基座部21的支撐面21a的面積的比例,較佳為10%以上且50%以下。於細絲23的基端的總剖面面積的比例未滿10%的情況下,存在口腔內的清掃性下降的可能性。於細絲23的基端的總剖面面積的比例超過50%的情況下,藉由射出成形來使刷毛成形體20成形時的脫模性下降。藉由將細絲23的基端的總剖面面積的比例設為10%以上且50%以下,可確保口腔內的清掃性及成形時的脫模性。The ratio of the total cross-sectional area of the proximal ends of the plurality of
細絲群F1構成多根細絲23的一部分,由第一樹脂組成物形成。細絲群F2由多根細絲23中的細絲群F1以外的細絲23構成,由與第一樹脂組成物不同的第二樹脂組成物形成。
考慮到牙刷1的使用感、外觀性(設計性),能夠適宜選擇上文所述的軟質樹脂作為第一樹脂組成物及第二樹脂組成物。例如,於考慮到牙刷1的使用感而兼顧按摩性與刷掃感的情況下,可使用硬度不同的所述軟質樹脂。另外,於考慮到外觀性的情況下,亦能夠將所述軟質樹脂作為基材,添加母料等著色劑,使細絲群F1與細絲群F2成為不同的顏色。
The filament group F1 constitutes a part of the plurality of
刷頭基座部21具有支撐座部30及嵌合孔22。
支撐座部30自下側支撐細絲群F1的基端。如圖3所示,支撐座部30是包含細絲群F1的大小的正面觀察矩形形狀的長方體狀。如圖4所示,支撐座部30的上表面與支撐面21a共面。即,支撐座部30的上表面構成支撐面21a的一部分。以下,關於支撐座部30的上表面亦適宜稱為支撐面21a。
The brush
支撐座部30位於較嵌合孔22更靠正面側的位置。形成刷頭基座部21的一部分。支撐座部30由第一樹脂組成物形成。支撐座部30與細絲群F1構成利用第一樹脂組成物一體成形的預成形體40。The
嵌合孔22沿插入方向延伸而於後端側(其中一側)的端面21b上開口。圖6是包含嵌合孔22的與支撐面21a平行的面上的剖面圖。如圖6所示,嵌合孔22具有於端面21b開口的第一部分33及位於較第一部分33更靠裏側的第二部分34。如圖4所示,第一部分33與第二部分34分別與刷頭基座部21的背面21c及支撐座部30的背面分離配置。The
刷頭基座部21具有位於嵌合孔22的插入方向的大致中央、即第一部分33與第二部分34之間的突起35。突起35設置於嵌合孔22的寬度方向的兩側。突起35於柄體10的嵌合突部12(參照圖7,後述)插入至嵌合孔22中時,分別設置於與凹處15(後述)嵌合的位置。突起35是於寬度方向上在外側具有圓弧中心且向內側凸出的圓弧形狀。The brush
突起35彼此的最短距離L35較第一部分33的寬度L33及第二部分34的寬度L34更短。作為突起35相對於第二部分34的向寬度方向內側的突出量,作為一例為1 mm。突起35相對於第二部分34的突出量是將刷毛成形體20的注射成形時使嵌合孔22成形的模具(滑動芯)向後端側拔出時的咬邊量。The shortest distance L35 between the
刷毛成形體20中,除支撐座部30以外的刷頭基座部21由第二樹脂組成物形成。刷毛成形體20中,除支撐座部30以外的刷頭基座部21與細絲群F2構成利用第二樹脂組成物一體成形的基座本體成形體50。刷毛成形體20為將預成形體40與基座本體成形體50一體成形的成形體。於此情況下,藉由將利用第一樹脂組成物一次成形的預成形體40設置於模具內的模腔中,向模腔中填充第二樹脂組成物進行二次成形(嵌入成形)來使成形體成形。In the bristle molded
返回圖5,於與刷頭基座部21的長度方向正交的剖面上,作為支撐座部30的厚度t1,自0.5 mm~2.5 mm中選擇。作為支撐座部30的背面與嵌合孔22內部的正面側的面之間的厚度t2,自0 mm~2.5 mm中選擇。於支撐座部30的背面與嵌合孔22的內部的正面側的面共面的情況下,支撐座部30的背面與嵌合孔22的內部的正面側的面的厚度t2為0 mm。即,能夠選擇支撐座部30的背面露出至嵌合孔22而相對的結構。於此情況下,支撐座部30的寬度方向的側面黏接固定於基座本體成形體50上。Returning to FIG. 5 , in the cross section perpendicular to the longitudinal direction of the brush
作為嵌合孔22內部的正面側的面與支撐面21a之間的厚度t1+t2,自0.5 mm~3.5 mm中選擇。作為嵌合孔22的厚度方向的長度t3,自1.0 mm~3.0 mm中選擇。作為嵌合孔22內部的背面側的面與刷頭基座部21的背面21c之間的厚度t4,自0.3 mm~2.0 mm中選擇。The thickness t1+t2 between the surface on the front side inside the
於與刷頭基座部21的長度方向正交的剖面上,若將支撐座部30的剖面面積設為S1,將位於嵌合孔22內部的正面側的面與支撐面21a之間的厚度t1+t2的區域的剖面面積設為S,則由S1/S表示的值於設有嵌合孔22的整個區域中較佳為0.1以上。
由S1/S表示的值較佳為0.6以下,更佳為0.5以下,進而佳為0.4以下。
由S1/S表示的值較佳為0.1以上且0.6以下,更佳為0.1以上且0.5以下,進而佳為0.1以上且0.4以下。
In a cross-section perpendicular to the longitudinal direction of the brush
於具有嵌合孔22的刷毛成形體20中,由嵌合孔22內部的正面側的面與支撐面21a之間的厚度t1+t2所定義的區域的剖面面積S、及支撐座部30的剖面面積S1給細絲23的成形性帶來大的影響。關於多色成形,於一次側的成形後,藉由切換模具的可動側(或固定側)來使二次側以後成形,因此於在模腔內殘留著一次側的成形體的狀態下進行成形。二次側以後的能夠流動的區域進一步變小。因此,多色成形與單色成形不同,有二次側以後的樹脂流動性不足的傾向,細絲的成形變得困難。於此情況下,無法確保充分的填充速度、保持壓力,因此容易發生縮痕或氣泡等成形不良。具體而言,於由所述S1/S表示的值超過0.6的情況下,細絲23容易發生成形不良。於本實施方式中,藉由將由S1/S表示的值設為0.6以下,可抑制細絲23的成形不良。再者,就確保一次側的支撐座部30及細絲群F1的成形性的觀點而言,較佳為將由S1/S表示的值設為0.1以上。In the bristle molded
於與刷頭基座部21的長度方向正交的剖面上,若將嵌合孔22的剖面面積設為SV,將包含嵌合孔22的剖面面積SV的刷頭基座部21的剖面面積設為SW,則由SV/(SW-S1)表示的值較佳為於設有嵌合孔22的整個區域中為0.1以上。由SV/(SW-S1)表示的值較佳為0.5以下,更佳為0.4以下,進而佳為0.3以下。由SV/(SW-S1)表示的值較佳為0.1以上且0.5以下,更佳為0.1以上且0.4以下,進而佳為0.1以上且0.3以下。On a cross section perpendicular to the longitudinal direction of the brush
於一次側以外的成形、即基座本體成形體50的成形中,除了先前成形的一次側的預成形體40的存在以外,用於形成嵌合孔22的滑動芯的存在亦給樹脂流動帶來大的影響。若滑動芯的佔有小,則樹脂於模腔內容易流動,細絲23的成形性提高。反之,於由表示滑動芯的佔有率的SV/(SW-S1)表示的值超過0.5的情況下,存在如下的可能性:於基座本體成形體50的成形時樹脂流動受到限制,而發生二次側以後的細絲23(細絲群F2)的成形不良。於本實施方式中,藉由將由SV/(SW-S1)表示的值設為0.5以下,可抑制細絲23的成形不良。再者,就確保滑動芯的強度的觀點而言,較佳為將由所述SV/(SW-S1)表示的值設為0.1以上。In the molding other than the primary side, that is, the molding of the
若將自厚度方向的正面側觀察的正面觀察時的刷頭基座部21的面積(投影面積)設為P,將該正面觀察時的支撐座部30的面積設為P1,則由P1/P表示的值較佳為0.1以上,更佳為0.2以上。由P1/P表示的值較佳為0.5以下,更佳為0.4以下。另外,由P1/P表示的值較佳為0.1以上且0.5以下,更佳為0.1以上且0.4以下,進而佳為0.2以上且0.4以下。When the area (projected area) of the brush
作為提高一次側以外的細絲23(細絲群F2)的成形性的手段,沿相對於支撐面21a平行的方向流動的樹脂流動亦重要。尤其是,於如側澆口般澆口位於刷毛成形體20的長度方向的端部的情況下,起到顯著作用。因此,於由P1/P表示的值超過0.5的情況下,存在如下的可能性:由於一次側的預成形體40對模腔區域的佔有,樹脂流動受到阻礙,而於二次側以後的基座本體成形體50的成形時發生細絲23的成形不良。另一方面,於由P1/P表示的值未滿0.1的情況下,存在細絲群F1的佔有率降低而無法確保功能性(例如、清掃性)的可能性。於本實施方式中,藉由將由P1/P表示的值設為0.1以上且0.5以下,可於確保細絲群F1的功能性的同時,抑制細絲23的成形不良。As means for improving the formability of the filaments 23 (filament group F2 ) other than the primary side, the flow of the resin flowing in the direction parallel to the
刷頭基座部21的支撐面21a與背面21c的最大距離(最大厚度)、即自細絲23的基端至背面21c為止的最大距離T較佳為2.0 mm以上且4.5 mm以下。於最大距離T未滿2.0 mm的情況下,存在如下的可能性:支撐面21a與嵌合孔22的支撐面21a側的面之間的間隙、或者背面21c與嵌合孔22的背面21c側的面之間的間隙變小,於基座本體成形體50的成形時熔融樹脂的流動性下降,因此未被填充樹脂。另外,於最大距離T未滿2.0 mm的情況下,不得不減小嵌合孔22的支撐面21a側的面與支撐座部30之間的間隙,而導致於基座本體成形體50的成形時熔融樹脂的流動性下降。於最大距離T超過4.5 mm的情況下,存在將刷毛成形體20插入口腔內時的操作性下降的可能性。於本實施方式中,藉由將最大距離T設為2.0 mm以上且4.5 mm以下,可確保樹脂的填充性及將刷毛成形體20插入口腔內時的操作性。The maximum distance (maximum thickness) between the
若將自細絲23的基端至刷頭基座部21的背面21c為止的最大距離設為T,將支撐座部30的厚度方向的厚度設為t1,則由t1/T表示的值較佳為0.5以下,更佳為0.4以下。於由t1/T表示的值超過0.5的情況下,為了確保使一次側以外的基座本體成形體50成形時的樹脂流動,刷毛成形體20整體變厚,而導致口腔內操作性下降。於本實施方式中,藉由將由t1/T表示的值設為0.5以下,對於二次側以後的基座本體成形體50的成形時的成形性與使用性的兼顧起到有利的作用。再者,就確保一次側的成形性及一次側支撐座部30的側面對刷頭基座部21的黏接性的觀點而言,較佳為將由t1/T表示的值設為0.1以上。If the maximum distance from the base end of the
另外,關於所述厚度t1、及與嵌合孔22內部的正面側的面之間的厚度t2,由t1/(t1+t2)表示的值較佳為0.2以上,更佳為0.3以上。由t1/(t1+t2)表示的值較佳為0.8以下,更佳為0.7以下。另外,由t1/(t1+t2)表示的值較佳為0.2以上且0.8以下,更佳為0.3以上且0.7以下。於由t1/(t1+t2)表示的值超過0.8的情況下,存在如下的可能性:於一次側的背面(支撐座部30的背面)與滑動芯之間無法確保供樹脂流動的充分的空間,因此變得依賴於支撐座部30的側面側的樹脂流動,而導致一次側以外(基座本體成形體50)的成形性下降。進而,存在一次側的支撐座部30與二次側的基座本體成形體50的樹脂黏接性不穩定的可能性。於由t1/(t1+t2)表示的值未滿0.2的情況下,存在無法確保一次側的支撐座部30的成形性的可能性。於本實施方式中,藉由將由t1/(t1+t2)表示的值設為0.2以上且0.8以下,可確保一次側的支撐座部30及二次側的基座本體成形體50的成形性,並且可使支撐座部30與基座本體成形體50的樹脂黏接性穩定。The thickness t1 and the thickness t2 between the thickness t1 and the surface on the front side inside the
再者,若厚度t2為0.3 mm以上,則即便為寬度寬的刷頭的規格,成形性亦不易產生問題。作為厚度t2,較佳為0.5 mm以上,更佳為0.8 mm以上。In addition, if the thickness t2 is 0.3 mm or more, even if it is the specification of a wide brush head, the problem of formability is less likely to occur. As thickness t2, 0.5 mm or more is preferable, and 0.8 mm or more is more preferable.
若將細絲群F1中的細絲的根數設為FM,將支撐座部30與基座本體成形體50黏接的面積設為Q1(mm
2),則作為由FM/Q1表示的值,較佳為1.0(根/mm
2)以下,更佳為0.8(根/mm
2)以下。細絲23於成形後的脫模時於因模腔表面的脫模阻力被拉伸的同時脫離。於由FM/Q1表示的值超過1.0(根/mm
2)的情況下,存在如下可能性:於多色成形中,於二次成形後使預成形體40與基座本體成形體50的成形體脫模時,由於細絲群F1的脫模阻力,預成形體40相對於基座本體成形體50剝離。於本實施方式中,藉由將由FM/Q1表示的值設為1.0(根/mm
2)以下,可抑制二次成形後預成形體40相對於基座本體成形體50剝離。再者,於相對於支撐座部30的佔有面積而無法充分確保細絲群F1的根數的情況下,當考慮到一次側細絲F1的功能性下降的可能性時,較佳為將由FM/Q1表示的值設為0.2(根/mm
2)以上。
Assuming that the number of filaments in the filament group F1 is FM, and the area where the
就抑制所述二次成形後預成形體40相對於基座本體成形體50剝離的觀點而言,較佳為於支撐座部30與基座本體成形體50的黏接界面設置一個以上的凹凸結構。藉由支撐座部30與基座本體成形體50的黏接界面不平滑,設置凹凸結構,可於確保成形性的同時增加黏接面積,從而提高一次側的預成形體40的黏接性。作為凹凸結構的配置,配置於支撐座部30的背面、側面均可,但與側面相比,配置於背面容易增大凹凸的高度或寬度,因此對增加黏接面積而言有效。於在支撐座部30的側面配置凹凸結構的情況下,只要考慮支撐座部30的厚度或使預成形體40成形時的咬邊即可。凹凸結構的高度(最高~最低)例如可例示0.1 mm~0.5 mm左右,凹凸結構的間距例如可例示0.5 mm~3.0 mm左右。From the viewpoint of suppressing the peeling of the
如圖4所示,若將長度方向的刷頭基座部21的最大長度設為L1,將嵌合孔22的最大長度設為L2,則由L2/L1表示的值較佳為0.30以上,更佳為0.40以上,進而佳為0.45以上。由L2/L1表示的值較佳為0.70以下,更佳為0.60以下,進而佳為0.55以下。另外,由L2/L1表示的值較佳為0.30以上且0.70以下,更佳為0.40以上且0.60以下,進而佳為0.45以上且0.55以下。As shown in FIG. 4 , if the maximum length of the brush
於由L2/L1表示的值未滿0.30的情況下,存在如下的可能性:由硬質樹脂形成的柄體10的不存在嵌合突部12的區域變大,因此刷毛成形體20的前方容易彎曲,而導致作為牙刷1的使用性下降。於L2/L1超過0.70的情況下,於成形時形成嵌合孔22的模具(滑動芯)所佔有的體積變大,樹脂流動受到限制,因此細絲23的成形性下降。藉由將由L2/L1表示的值設為0.30以上且0.70以下,可抑制細絲23的成形性下降,並抑制牙刷1的使用性下降。When the value represented by L2/L1 is less than 0.30, there is a possibility that the area where the
[柄體10]
圖7是柄體10的正面圖。
如圖7所示,柄體10包括棒狀的柄部11、及設置於柄部11的前端的朝柄部11的長度方向前端側突出的嵌合突部12。嵌合突部12裝卸自如地嵌合於刷毛成形體20的嵌合孔22。於牙刷1中,將柄體10的嵌合突部12插入至上文所述的刷毛成形體20內的嵌合孔22中,藉此使刷毛成形體20覆蓋嵌合突部12來安裝。
[Handle body 10]
FIG. 7 is a front view of the
本實施方式的柄部11的正面視形狀以如下方式曲線式地變化:寬度自前端側朝後端側逐漸地變窄後,以固定的寬度延長,其後寬度逐漸地變寬後變窄。柄部11的正面視形狀的後端部成為大致半圓形狀。The front-view shape of the
柄部11的側視形狀如圖2所示,自前端側朝後端側以固定的寬度延長後,寬度逐漸地變寬直至成為手指接觸部的最大厚度為止。柄部11的側視形狀以寬度自最大厚度的手指接觸部朝後端側逐漸地變窄的方式曲線式地變化。柄部11的側視形狀的後端部成為大致半圓形狀。As shown in FIG. 2 , the side view shape of the
再者,於本發明中,柄部的形狀並不限定於所述例子的形狀,可考慮強度、操作性、設計性等而適宜設定。
柄部11的尺寸並無特別限定,可適宜設定。例如,可將柄部11的長度設為100 mm~200 mm。
In addition, in this invention, the shape of a handle|steering-wheel part is not limited to the shape of the said example, It can set suitably in consideration of intensity|strength, operability, designability, etc..
The size of the
嵌合突部12是於已將刷毛成形體20安裝在柄體10的狀態下由刷毛成形體20包覆的部分。嵌合突部12的後端是於柄體10安裝有刷毛成形體20的狀態下的刷毛成形體20的後端位置。The
圖8是將嵌合突部12放大的正面圖。圖9是將嵌合突部12放大的側面圖。
如圖8所示,嵌合突部12具有設置於柄部11的前端側的基部13、及設置於基部13的前端的前端部14。如圖9所示,基部13與前端部14於正面側及背面側的兩側,相對於柄部11具有段差,以較柄部11更薄的同一厚度來形成。
FIG. 8 is an enlarged front view of the
基部13於俯視時為大致矩形形狀。基部13於寬度方向兩側相對於柄部11具有段差,以較柄部11的前端側的最大寬度L11更窄的寬度L13來形成(L13<L11)。前端部14於俯視時為將寬度方向作為長徑方向的大致橢圓形狀。前端部14是於大致橢圓形狀的寬度方向兩側,利用與嵌合突部12的插入方向平行的直線切開側緣而成的形狀。前端部14於寬度方向兩側相對於基部13具有段差,以較基部13的寬度L13更窄的寬度L14來形成。The
嵌合突部12於插入方向的大致中央,即基部13與前端部14之間具有凹處15。凹處15設置於寬度方向的兩側。凹處15是於寬度方向上,在外側具有圓弧中心,朝內側凹下的圓弧形狀。凹處15彼此的最短距離L15較基部13的寬度L13及前端部14的寬度L14更短。作為相對於在前端部14中規定寬度L14的端緣的凹處15的凹陷量,作為一例為1 mm。The
柄體10由硬質樹脂形成。
作為硬質樹脂的一例,可例示彎曲彈性模數(日本工業標準(Japanese Industrial Standards,JIS)K7171)為1500 MPa以上且3000 MPa以下的樹脂。具體而言,例如可例示:聚丙烯樹脂(Polypropylene,PP)、聚縮醛樹脂(聚甲醛(Polyoxymethylene,POM))、聚酯樹脂(聚(1,4-伸環己基二亞甲基對苯二甲酸)(Poly(l,4-cyclohexanedimethylene terephthalic acid),PCTA))、聚對苯二甲酸乙二酯共聚物(聚(對苯二甲酸乙二酯-1,4-環己二烯二亞甲基對苯二甲酸酯)(Poly(ethylene terephthalateco-1,4-cylclohexylenedimethylene terephthalate),PETG))、高密度聚乙烯(High Density Polyethylene,HDPE)。該些樹脂之中,若考慮成本方面,則作為通用樹脂的PP亦較佳。
The
刷頭基座部21的後端側(端面21b)的最大寬度L21與柄部11的前端側的最大寬度大致相同。
嵌合孔22的正面視形狀與嵌合突部12的正面視形狀大致相同。第一部分33的寬度L33是嵌合突部12中的基部13可插入的長度,與基部13的最大寬度L13大致相同。第二部分34的寬度L34是嵌合突部12中的前端部14可插入的長度,與前端部14的最大寬度L14大致相同。突起35彼此的最短距離L35為嵌合突部12中的前端部14及凹處15可插入的長度,與凹處15彼此的最短距離L15大致相同。
The maximum width L21 of the rear end side (end
接著,參照圖10至圖12說明使所述刷毛成形體20成形的順序。圖10是簡略地表示使刷毛成形體20中的預成形體40成形的模具MD的一例的寬度方向的剖面圖。Next, the procedure for forming the
模具MD包括於開閉方向(圖10中,上下方向)上進行相對移動的第一模具MD1與一次成形用的第二模具MD2。第一模具MD1與第二模具MD2將與支撐面21a共面的分離面PL作為接合面來合模。作為一例,第一模具MD1是固定模,第二模具MD2是可動模。The mold MD includes a first mold MD1 that relatively moves in the opening and closing direction (up-down direction in FIG. 10 ), and a second mold MD2 for primary molding. The first mold MD1 and the second mold MD2 are clamped using the separation surface PL coplanar with the
第一模具MD1安裝於射出成形機的例如固定側,被自射出成形機填充熔融樹脂。第二模具MD2安裝於射出成形機的例如可動側,相對於第一模具MD1在所述開閉方向上移動,藉此進行模具MD的開閉。The first mold MD1 is attached to, for example, the fixed side of the injection molding machine, and is filled with molten resin from the injection molding machine. The second mold MD2 is attached to, for example, the movable side of the injection molding machine, and moves in the opening and closing direction relative to the first mold MD1, whereby the mold MD is opened and closed.
第一模具MD1具有於被合模而與第二模具MD2接合時供支撐面21a成形的成形面21aM、供細絲群F1成形的模腔F1M、及供細絲群F2成形的模腔F2M。模腔F1M與模腔F2M於第一模具MD1的分離面PL上開口。The first mold MD1 has a molding surface 21aM for molding the
第二模具MD2具有於被合模而與第一模具MD1接合時供支撐座部30成形的模腔30M。模腔30M於模腔F1M開口。模腔30M於模腔F2M中未開口。模腔F2M的開口被第二模具MD2的分離面PL堵塞。於模腔30M中設置有未圖示的澆口部。作為澆口部,例如可使用側澆口方式,亦可使用針點澆口方式、隧道形澆口方式。The second mold MD2 has a
於所述模具MD中,於第一模具MD1與第二模具MD2被合模的狀態下自澆口部G導入至模腔30M中的、熔融的第一樹脂組成物被填充至模腔30M及模腔F1M中。另一方面,模腔30M未在模腔F2M中開口,模腔F2M的開口被第二模具MD2的分離面PL堵塞,因此未被填充第一樹脂組成物。之後,藉由在第一模具MD1與第二模具MD2被合模的狀態下冷卻,使具有細絲群F1及支撐座部30的由第一樹脂組成物形成的預成形體40成形。In the mold MD, the molten first resin composition introduced into the
圖11是簡略地表示使刷毛成形體20中的基座本體成形體50成形的二次成形用的模具MD的一例的寬度方向的剖面圖。圖12是簡略地表示二次成形用的模具MD的一例的長度方向的剖面圖。FIG. 11 is a cross-sectional view in the width direction schematically showing an example of a mold MD for secondary molding for molding the base body molding 50 in the
模具MD包括沿開閉方向相對移動的第一模具MD1與第二模具MD12。第一模具MD1是不使已成形的預成形體40脫模地進行保持的所述第一模具MD1。再者,亦可使包含模腔F1M及模腔F2M的所述一次成形用的第一模具MD1的一部分脫離,安裝於二次成形用的第一模具MD1上。The mold MD includes a first mold MD1 and a second mold MD12 that relatively move in the opening and closing direction. The 1st metal mold|die MD1 is the said 1st metal mold|die MD1 which hold|maintains the preformed
第二模具MD12具有:模腔21M,於被合模而與第一模具MD1接合時供刷頭基座部21成形;澆口部G,於模腔21M的前端側開口,朝模腔21M導入熔融樹脂;以及抵接面21eM,於插入方向上設置於端面21b的位置,與插入方向正交。如圖11所示,供細絲群F2成形的模腔F2M於模腔21M開口。作為澆口部G,例如可使用側澆口方式,但亦可使用針點澆口方式、隧道形澆口方式。抵接面21eM於第二模具MD2中,自使刷頭基座部21中的背面成形的位置朝與PL面分離的方向延長。The second mold MD12 has a
於第二模具MD12設置有滑動芯SL。滑動芯SL具有:供嵌合孔22成形的芯部22M、及芯部22M突出並與插入方向正交的成形面21bM。如圖11所示,於合模前,成形面21bM與抵接面21eM分離。當已將第一模具MD1與第二模具MD12合模時,如圖11所示,滑動芯SL的成形面21bM的一部分與抵接面21eM抵接,芯部22M被定位於插入模腔21M中的位置。成形面21bM之中,不與抵接面21eM抵接而面對模腔21M的區域是使端面21b成形的區域。另外,當已將第一模具MD1與第二模具MD12開模時,滑動芯SL以芯部22M不對已成形的刷毛成形體20的脫模帶來障礙的方式,於芯部22M自模腔21M脫離的方向上移動。為了避免由自重所引起的難以預測的移動,滑動芯SL的移動方向較佳為水平方向。The slide core SL is provided in the 2nd metal mold|die MD12. The slide core SL has a
於所述模具MD中,於第一模具MD1與第二模具MD12被合模的狀態下自澆口部G導入至模腔21M的、熔融的第二樹脂組成物被填充至模腔21M及模腔F2M中。填充至模腔21M中的第二樹脂組成物包覆支撐座部30的側面及背面且與支撐座部30黏接。之後,於第一模具MD1與第二模具MD12被合模的狀態下進行冷卻,使其自模具MD脫模,藉此獲得如下成形體,所述成形體包括:預成形體40,具有細絲群F1及支撐座部30且由第一樹脂組成物形成;以及基座本體成形體50,具有刷頭基座部21與多根細絲23中的預成形體40以外的部位,由第二樹脂組成物成形,且預成形體40與基座本體成形體50一體成形。In the mold MD, the molten second resin composition introduced into the
即,獲得細絲23與刷頭基座部21一體成形的刷毛成形體20作為成形體,所述細絲23具有由第一樹脂組成物形成的細絲群F1及由第二樹脂組成物形成的細絲群F2,所述刷頭基座部21包含由第一樹脂組成物形成的支撐座部30且由第二樹脂組成物形成。That is, the bristle molded
對於已成形的刷毛成形體20,藉由將柄體10的嵌合突部12插入並嵌合於嵌合孔22,而獲得刷毛成形體20與柄體10一體化的牙刷1。另外,藉由將柄體10的嵌合突部12自嵌合孔22拔出,可使刷毛成形體20自柄體10脫離而進行更換。The
如以上所說明般,本實施方式的刷毛成形體20中,具有由第一樹脂組成物的軟質樹脂形成的細絲群F1及由第二樹脂組成物的軟質樹脂形成的細絲群F2,因此藉由根據目的適宜選擇第一樹脂組成物及第二樹脂組成物,可獲得具有柔軟的觸感且可提高牙刷1的使用感、外觀性的刷毛成形體以及牙刷。As described above, the bristle molded
[刷毛成形體20第二實施方式]
繼而,參照圖13說明刷毛成形體20的第二實施方式。於該些圖中,對與圖1至圖12所示的第一實施方式的構成元件相同的元件標注相同的符號,並省略其說明。
於所述第一實施方式中,例示了預成形體40由一種樹脂組成物成形的結構,但於第二實施方式中,對由多種樹脂組成物成形的結構進行說明。
[Second embodiment of the bristle molded body 20]
Next, a second embodiment of the bristle molded
圖13是第二實施方式的刷毛成形體20的寬度方向的剖面圖。
如圖13所示,本實施方式的預成形體40具有配置於寬度方向的中央的細絲群(第二細絲群)F3、分別配置於細絲群F3的寬度方向兩側的細絲群F1、支撐細絲群F3的基部的第二支撐座部31、及支撐細絲群F1的基部的支撐座部30。細絲群F3由與第一樹脂組成物及第二樹脂組成物不同的第三樹脂組成物成形。細絲群F1、細絲群F3由沿刷頭基座部21的長度方向排列的多根細絲23形成。第三樹脂組成物自所述軟質樹脂中適宜選擇。
FIG. 13 is a cross-sectional view in the width direction of the formed bristle
第二支撐座部31由第三樹脂組成物成形。第二支撐座部31的寬度方向的側面和背面與支撐座部30黏接。第二支撐座部31的正面側的面與支撐面21a共面。本實施方式的預成形體40是由第三樹脂組成物成形的細絲群F3及第二支撐座部31、與由第一樹脂組成物成形的細絲群F1及支撐座部30一體成形的成形體。The second
作為一例,預成形體40是藉由在一次成形中利用第三樹脂組成物使細絲群F3及第二支撐座部31成形,在二次成形中利用第一樹脂組成物使細絲群F1及支撐座部30成形的雙色成形而獲得。或者,藉由使用設置有利用第三樹脂組成物成形的細絲群F3及第二支撐座部31的模具,利用第一樹脂組成物使細絲群F1及支撐座部30成形的嵌入成形而獲得。As an example, the
而且,本實施方式的刷毛成形體20是藉由在一次成形中利用第三樹脂組成物使細絲群F3及第二支撐座部31成形,在二次成形中利用第一樹脂組成物使細絲群F1及支撐座部30成形,在三次成形中利用第二樹脂組成物使細絲群F2及刷頭基座部21成形的三色成形而獲得。或者,藉由使用設置有預先成形的預成形體40的模具,利用第二樹脂組成物使細絲群F2及刷頭基座部21成形的嵌入成形而獲得。In addition, in the bristle molded
所述結構的刷毛成形體20不僅可獲得與所述第一實施方式的刷毛成形體20同樣的作用效果,而且可使用與牙刷1的規格相應的更多種類的樹脂組成物來提供一種具有多種附加價值的牙刷1。The bristle molded
[刷毛成形體20的第三實施方式]
接著,參照圖14及圖15說明刷毛成形體20的第三實施方式。於該些圖中,對與圖13所示的第二實施方式的構成元件相同的元件標注相同的符號,並省略其說明。
再者,於本實施方式中,將細絲群簡略地示出為配置有該細絲群的區域。
[Third embodiment of the bristle molded body 20]
Next, a third embodiment of the bristle molded
圖14是第三實施方式的刷毛成形體20的正面圖。圖15是第三實施方式的刷毛成形體20的寬度方向的剖面圖。
如圖14所示,於本實施方式中,細絲群F1分別設置於細絲群F3的寬度方向兩側與長度方向兩側。細絲群F1配置成包圍細絲群F3的周圍的0字狀。
Fig. 14 is a front view of the bristle molded
如圖15所示,第二支撐座部31的側面黏接於支撐座部30上。第二支撐座部31沿厚度方向貫通支撐座部30。第二支撐座部31的背面與支撐座部30的背面共面。
其他結構與所述第二實施方式相同。
As shown in FIG. 15 , the side surface of the second
於本實施方式中,不僅可獲得與所述第二實施方式同樣的作用效果,而且可藉由將細絲23除直線狀以外二維地配置,從而根據牙刷1的規格使用更多種類的樹脂組成物來提供一種具有多種附加價值的牙刷1。In the present embodiment, not only the same functions and effects as those of the second embodiment can be obtained, but also by arranging the
再者,作為將細絲23二維地配置的結構,例如可為如下結構,即:如圖16的正面圖及圖17的長度方向的剖面圖所示,細絲群F1及支撐座部30與細絲群F3及第二支撐座部31沿長度方向排列配置。In addition, as a structure in which the
[刷毛成形體20的第四實施方式]
接著,參照圖18說明刷毛成形體20的第四實施方式。於該圖中,對與圖1至圖12所示的第一實施方式的構成元件相同的元件標注相同的符號,並省略其說明。
[Fourth embodiment of the bristle molded body 20]
Next, a fourth embodiment of the bristle molded
圖18是第四實施方式的刷毛成形體20的寬度方向的剖面圖。
如圖18所示,本實施方式的預成形體40中的細絲群F1具有多根細絲23的全部。
其他結構與所述第一實施方式相同。
FIG. 18 is a cross-sectional view in the width direction of the formed bristle
於所述結構的刷毛成形體20中,與第一實施方式同樣,細絲群F1與刷頭基座部21由不同的樹脂組成物成形,因此可獲得一種具有溫柔的觸感且可提高牙刷1的使用感、外觀性的刷毛成形體以及牙刷。In the bristle molded
於所述結構的刷毛成形體20中,預成形體40具有細絲23的全部,因此使刷毛成形體20自模具脫模時的預成形體40的脫模阻力變大。因此,如上所述,較佳為採用細絲的根數FM和支撐座部30與基座本體成形體50黏接的面積Q1的關係、及設置於支撐座部30與基座本體成形體50的黏接界面上的凹凸結構中的至少一種。Since the
[實施例] 以下表示實施例來對本發明進行詳細說明,但本發明並不限定於以下的實施例,可於不脫離其主旨的範圍內適宜變更來實施。 [Example] Hereinafter, the present invention will be described in detail with reference to Examples, but the present invention is not limited to the following Examples, and can be implemented with appropriate modifications within a range that does not deviate from the gist.
(實施例1~實施例8、比較例1) 將[表1]所示的項目中的至少一個不同的牙刷設為實施例1~實施例8、比較例1的樣品。將構成各樣品的樹脂設為聚胺基甲酸酯。 (Example 1 to Example 8, Comparative Example 1) At least one different toothbrush among the items shown in [Table 1] was used as the samples of Examples 1 to 8 and Comparative Example 1. Let the resin constituting each sample be polyurethane.
[評價方法] 對於實施例1~實施例8、比較例1的各樣品,分別評價細絲的成形性、口腔內整體的刷掃容易性、一次成形側的預成形體的黏接性。 [Evaluation method] For each of the samples of Examples 1 to 8 and Comparative Example 1, the formability of filaments, the ease of brushing the entire oral cavity, and the adhesiveness of the preform on the primary molding side were evaluated, respectively.
(1)細絲的成形性的評價方法 利用以下的基準來評價藉由同一條件來成形的五個刷毛成形體。 5分:完全看不到外觀的不良。 4分:細絲前端於脫模時變形(由於未被充分地施加壓力,因此因脫模時的外力而彎曲)。 3分:細絲前端的粗度較設計值更細。 2分:細絲的長度較設計值更短(所有細絲為全長的一半以上)。 1分:細絲的長度較設計值更短(存在未滿全長的一半的細絲)。 而且,求出五個評價分的平均值,利用以下的四個等級進行評價。 ◎(雙圓標記(double circle mark)):4.5分以上且5.0分以下。 ○(圓形標記(circle mark)):3.5分以上且未滿4.5分。 △(三角形標記(triangle mark)):2.5分以上且未滿3.5分。 ×(交叉標記(cross mark)):未滿2.5分。 (1) Evaluation method of filament formability Five bristle molded bodies molded under the same conditions were evaluated by the following criteria. 5 points: Defects in appearance were not seen at all. 4 points: The tip of the filament was deformed at the time of demolding (because the pressure was not sufficiently applied, it was bent by the external force at the time of demolding). 3 points: The thickness of the tip of the filament is thinner than the design value. 2 points: The length of the filament is shorter than the design value (all filaments are more than half of the full length). 1 point: The length of the filament is shorter than the design value (there is a filament less than half of the full length). And the average value of five evaluation points was calculated|required, and it evaluated by the following four grades. ◎ (double circle mark): 4.5 points or more and 5.0 points or less. ○ (circle mark): 3.5 points or more and less than 4.5 points. △ (triangle mark): 2.5 points or more and less than 3.5 points. × (cross mark): less than 2.5 points.
(2)口腔內整體的刷掃容易性的評價方法 由10人的專門小組成員進行官能評價,利用以下的基準來評價刷掃時的口腔內整體的刷掃容易性(特別重視臼齒的刷掃容易性)。 5分:非常容易刷掃。 4分:稍微容易刷掃。 3分:兩者皆非。 2分:稍微難以刷掃。 1分:非常難以刷掃。 然後,求出10人的專門小組成員的評價分的平均值,利用以下的四個等級進行評價。 ◎:4.5分以上且5.0分以下。 ○:3.5分以上且未滿4.5分。 △:2.5分以上且未滿3.5分。 ×:未滿2.5分。 (2) Method for evaluating the ease of brushing the entire oral cavity The sensory evaluation was performed by 10 panelists, and the ease of brushing the entire oral cavity at the time of brushing was evaluated by the following criteria (particular attention was paid to the ease of brushing of the molars). 5 points: Very easy to brush. 4 points: It is slightly easy to brush. 3 points: Neither. 2 points: Slightly difficult to brush. 1 point: Very difficult to brush. Then, the average value of the evaluation points of 10 panelists was obtained, and the evaluation was performed using the following four levels. ⊚: 4.5 points or more and 5.0 points or less. ○: 3.5 points or more and less than 4.5 points. △: 2.5 points or more and less than 3.5 points. ×: Less than 2.5 points.
(3)一次成形側的預成形體的黏接性的評價方法 利用以下的基準來評價藉由同一條件成形的五個刷毛成形體。 5分:完全看不到外觀的不良。 4分:一次側基座部因脫模時的脫模阻力而變形(刷毛面不再平滑的狀態)。 3分:外觀上未看到剝離,但施加外力時在樹脂邊界確認到剝離。 2分:脫模時一次側基座部的一部分剝離,一部分連接。 1分:一次側整體剝離,且自刷毛成形體分離(一次側殘留於模具上的狀態)。 然後,求出五個評價分的平均值,利用以下的四個等級進行評價。 ◎:4.5分以上且5.0分以下。 ○:3.5分以上且未滿4.5分。 △:2.5分以上且未滿3.5分。 ×:未滿2.5分。 (3) Method for evaluating the adhesion of the preform on the primary molding side Five bristle molded bodies molded under the same conditions were evaluated by the following criteria. 5 points: Defects in appearance were not seen at all. 4 points: The primary side base portion is deformed by the demolding resistance at the time of demolding (the state where the bristle surface is no longer smooth). 3 points: No peeling was observed in appearance, but peeling was observed at the resin boundary when an external force was applied. 2 points: At the time of mold release, a part of the primary side base part was peeled off, and a part was connected. 1 point: The entire primary side was peeled off and separated from the bristle molded body (state where the primary side remained on the mold). Then, the average value of the five evaluation points was obtained, and the evaluation was performed on the following four levels. ⊚: 4.5 points or more and 5.0 points or less. ○: 3.5 points or more and less than 4.5 points. △: 2.5 points or more and less than 3.5 points. ×: Less than 2.5 points.
[表1]
如[表1]所示,對於支撐座部30的剖面面積S1與位於嵌合孔22內部的正面側的面和支撐面21a之間的區域的剖面面積S之比,即由S1/S表示的值為0.6以下的實施例1~實施例8的樣品實施例1,細絲的成形性、口腔內整體的刷掃容易性、一次成形側的預成形體的黏接性全部獲得了良好的結果。相對於此,於由S1/S表示的值超過0.6的比較例1的樣品中,關於細絲的成形性,無法獲得良好的評價。As shown in [Table 1], the ratio of the cross-sectional area S1 of the
若設為實施例1所示的條件,則對於細絲的成形性、口腔內整體的刷掃容易性、及一次側預成形體的黏接性均獲得了良好的結果。Under the conditions shown in Example 1, favorable results were obtained with respect to the formability of the filament, the ease of brushing the entire oral cavity, and the adhesiveness of the primary side preform.
若設為實施例2所示的條件,則隨著一次側支撐座部的擴張,由S1/S表示的值變大。藉此,二次側以後的樹脂流動下降,結果細絲的成形性較實施例1的樣品差。另外,第一細絲群的根數FM隨著一次側支撐座部的擴張而增加,但支撐座部的黏接面積Q1亦增大,因此一次側預成形體的黏接性與實施例1的樣品相等。When the conditions shown in Example 2 are set, the value represented by S1/S becomes larger as the primary side support seat portion expands. As a result, the flow of the resin on the secondary side and later was reduced, and as a result, the formability of the filament was inferior to that of the sample of Example 1. In addition, the number FM of the first filament group increases with the expansion of the primary side support seat, but the adhesion area Q1 of the support seat also increases, so the adhesion of the primary side preform is the same as that of Example 1. samples are equal.
若設為實施例3所示的條件,則隨著滑動芯的厚壁化,由SV/(SW-S1)表示的值變大。藉此,基座本體成形體成形時的樹脂流動下降,結果二次側以後的細絲的成形性較實施例1的樣品差。When the conditions shown in Example 3 are used, the value represented by SV/(SW-S1 ) increases as the thickness of the sliding core increases. As a result, the resin flow during molding of the base body molded body was reduced, and as a result, the moldability of the filaments on the secondary side and onwards was inferior to that of the sample of Example 1.
實施例4及實施例5的樣品均為刷頭厚度變厚,結果口腔內整體的刷掃容易性較實施例1的樣品差。另外,實施例5的樣品的支撐座部亦同時變厚,因此,由t1/T表示的值變大,使基座本體成形體成形時的樹脂流動較實施例4的樣品下降,結果細絲的成形性較實施例1的樣品差。In the samples of Examples 4 and 5, the thickness of the brush head was thickened, and as a result, the overall ease of brushing in the oral cavity was inferior to that of the sample of Example 1. In addition, the support seat portion of the sample of Example 5 also became thick at the same time, so the value represented by t1/T became larger, and the resin flow during the molding of the base body molded body was reduced compared with that of the sample of Example 4. As a result, filaments The formability is worse than that of the sample in Example 1.
於實施例6及實施例8所示的條件下,均為由t1/(t1+t2)表示的值變大,無法確保樹脂於一次側支撐座部的背面與滑動芯之間流動的充分的空間,樹脂流動下降,結果細絲的成形性較實施例1的樣品差。但是,實施例8的樣品與實施例6的樣品相比,支撐座部的背面側的面未露出至嵌合孔內部的正面側的面上,因此一次側預成形體的黏接性未下降。Under the conditions shown in Example 6 and Example 8, the value represented by t1/(t1+t2) became large, and it was not possible to ensure sufficient resin flow between the back surface of the primary side support seat and the sliding core. space, the resin flow decreased, and as a result, the formability of the filament was inferior to that of the sample of Example 1. However, in the sample of Example 8, as compared with the sample of Example 6, the back side surface of the support seat portion is not exposed to the front side surface inside the fitting hole, so the adhesiveness of the primary side preform does not decrease. .
若設為實施例7所示的條件,則第一細絲群的根數FM與實施例1相比增加,但支撐座部的黏接面積Q1未變化,因此FM/Q1變大,結果一次側預成形體的黏接性較實施例1的樣品差。Under the conditions shown in Example 7, the number FM of the first filament group was increased compared with Example 1, but the adhesion area Q1 of the support seat did not change, so FM/Q1 became large, and as a result one time The adhesion of the side preforms was inferior to that of the sample of Example 1.
以上,一面參照隨附圖式,一面對本發明的適宜的實施方式進行了說明,但本發明當然不限定於所述例子。所述例子中所示的各構成構件的各種形狀或組合等為一例,可於不脫離本發明的主旨的範圍內,根據設計要求等而進行各種變更。The preferred embodiments of the present invention have been described above with reference to the accompanying drawings, but it goes without saying that the present invention is not limited to the examples. The various shapes, combinations, and the like of the respective constituent members shown in the above examples are examples, and various changes can be made in accordance with design requirements and the like without departing from the gist of the present invention.
例如,於所述實施方式中,例示出了如下結構:藉由牙刷1包含分別成形的刷毛成形體20與柄體10,使柄體10的嵌合突部12嵌合於刷毛成形體20的嵌合孔22中,而將刷毛成形體20安裝於柄體10上,但並不限定於此結構。例如,亦可設為如下結構:於設置有預成形體的模具上,代替滑動芯SL而設置柄體10的嵌合突部12,於二次成形時利用第二樹脂組成物進行嵌入成形。藉由該嵌入成形,可獲得作為將嵌合突部12嵌合於嵌合孔22中且刷毛成形體20與柄體10一體成形的成形體的牙刷1。For example, in the above-described embodiment, the
另外,於所述實施方式中,例示了柄體10由硬質樹脂形成的結構,但並不限定於該結構,例如亦可為柄體10的一部分(柄部11等)由軟質樹脂包覆的結構。於採用該結構的情況下,可提高裝飾性及握緊性。
[產業上的可利用性]
In addition, in the above-mentioned embodiment, the structure in which the
本發明可應用於刷毛成形體以及牙刷。The present invention can be applied to a bristle molded body and a toothbrush.
1:牙刷 10:柄體 11:柄部 12:嵌合突部 13:基部 14:前端部 15:凹處 20:刷毛成形體 21:刷頭基座部 21a:支撐面 21aM:成形面 21b:端面 21bM:成形面 21c:背面 21eM:抵接面 21M、30M、F1M、F2M:模腔 22:嵌合孔 22M:芯部 23:細絲 30:支撐座部 31:第二支撐座部 33:第一部分 34:第二部分 35:突起 40:預成形體 50:基座本體成形體 F1:細絲群(第一細絲群) F2:細絲群 F3:細絲群(第二細絲群) G:澆口部 L1:長度方向的刷頭基座部21的最大長度 L2:嵌合孔22的最大長度 L11:柄部11的前端側的最大寬度 L13:基部13的寬度L13 L14:前端部14的寬度L14 L15:凹處15彼此的最短距離 L21:刷頭基座部21的後端側(端面21b)的最大寬度 L33:第一部分33的寬度 L34:第二部分34的寬度 L35:突起35彼此的最短距離 MD:模具 MD1:第一模具 MD2:第二模具 MD12:第二模具 PL:分離面 SL:滑動芯 T:最大距離 t1:支撐座部30的厚度 t2:支撐座部30的背面與嵌合孔22的內部的正面側的面的厚度 t3:嵌合孔22的厚度方向的長度 t4:嵌合孔22內部的背面側的面與刷頭基座部21的背面21c之間的厚度 1: toothbrush 10: Handle body 11: Handle 12: Fitting protrusions 13: Base 14: Front end 15: Recess 20: Bristle forming body 21: Brush head base 21a: Support surface 21aM: Forming surface 21b: End face 21bM: Forming Surface 21c: Back 21eM: abutment surface 21M, 30M, F1M, F2M: Mould cavity 22: Fitting hole 22M: core 23: Filament 30: Support seat 31: Second support seat 33: Part One 34: Part Two 35: Protrusions 40: Preform 50: base body forming body F1: Filament group (first filament group) F2: Filament group F3: Filament group (second filament group) G: gate part L1: Maximum length of the brush head base portion 21 in the longitudinal direction L2: Maximum length of fitting hole 22 L11: Maximum width of the front end side of the shank 11 L13: Width L13 of base 13 L14: Width L14 of front end portion 14 L15: The shortest distance between the recesses 15 L21: Maximum width of the rear end side (end surface 21b) of the brush head base portion 21 L33: The width of the first part 33 L34: The width of the second part 34 L35: The shortest distance between the protrusions 35 MD: Mold MD1: The first mold MD2: Second mold MD12: Second mold PL: separation plane SL: sliding core T: maximum distance t1: Thickness of the support seat 30 t2: The thickness of the back surface of the support seat 30 and the surface on the front side inside the fitting hole 22 t3: Length in the thickness direction of the fitting hole 22 t4: Thickness between the back side surface inside the fitting hole 22 and the back surface 21c of the brush head base portion 21
圖1是本發明的實施方式的刷毛成形體20以及牙刷1的正面圖。
圖2是該刷毛成形體20以及牙刷1的側面圖。
圖3是刷毛成形體20的正面圖。
圖4是圖3中的A-A剖面圖。
圖5是自後端側觀察刷毛成形體20的圖。
圖6是包含嵌合孔22的與支撐面21a平行的面上的剖面圖。
圖7是柄體10的正面圖。
圖8是將嵌合突部12放大的正面圖。
圖9是將嵌合突部12放大的側面圖。
圖10是簡略地表示刷毛成形體20中使預成形體40成形的模具MD的一例的寬度方向的剖面圖。
圖11是簡略地表示刷毛成形體20中使基座本體成形體50成形的模具MD的一例的寬度方向的剖面圖。
圖12是簡略地表示二次成形用模具MD的一例的長度方向的剖面圖。
圖13是第二實施方式的刷毛成形體20的寬度方向的剖面圖。
圖14是第三實施方式的刷毛成形體20的正面圖。
圖15是第三實施方式的刷毛成形體20的寬度方向的剖面圖。
圖16是表示第三實施方式的刷毛成形體20的變形例的正面圖。
圖17是表示第三實施方式的刷毛成形體20的變形例的長度方向的剖面圖。
圖18是第四實施方式的刷毛成形體20的寬度方向的剖面圖。
1 : is a front view of the
1:牙刷 1: toothbrush
10:柄體 10: Handle body
11:柄部 11: Handle
20:刷毛成形體 20: Bristle forming body
Claims (16)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2020214798 | 2020-12-24 | ||
JP2020-214798 | 2020-12-24 |
Publications (1)
Publication Number | Publication Date |
---|---|
TW202228554A true TW202228554A (en) | 2022-08-01 |
Family
ID=82159765
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW110148035A TW202228554A (en) | 2020-12-24 | 2021-12-22 | Brush molded body, and toothbrush |
Country Status (5)
Country | Link |
---|---|
JP (1) | JPWO2022138650A1 (en) |
KR (1) | KR20230125166A (en) |
CN (1) | CN116648169A (en) |
TW (1) | TW202228554A (en) |
WO (1) | WO2022138650A1 (en) |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61207233A (en) | 1985-03-13 | 1986-09-13 | Kubota Ltd | Traveling gear |
WO2000049911A1 (en) * | 1999-02-24 | 2000-08-31 | Susumu Inoue | Rubber-nylon-mixture bristle toothbrush |
JP2002199938A (en) * | 2000-12-28 | 2002-07-16 | Lion Corp | Toothbrush |
JP4778166B2 (en) * | 2001-08-24 | 2011-09-21 | 花王株式会社 | Brush and brush manufacturing method |
JP3138318U (en) * | 2007-10-16 | 2007-12-27 | ライオン株式会社 | toothbrush |
JP5401162B2 (en) * | 2009-04-27 | 2014-01-29 | ライオン株式会社 | Toothbrush bristle and toothbrush |
-
2021
- 2021-12-21 JP JP2022571506A patent/JPWO2022138650A1/ja active Pending
- 2021-12-21 WO PCT/JP2021/047339 patent/WO2022138650A1/en active Application Filing
- 2021-12-21 CN CN202180086992.2A patent/CN116648169A/en active Pending
- 2021-12-21 KR KR1020237003401A patent/KR20230125166A/en unknown
- 2021-12-22 TW TW110148035A patent/TW202228554A/en unknown
Also Published As
Publication number | Publication date |
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WO2022138650A1 (en) | 2022-06-30 |
JPWO2022138650A1 (en) | 2022-06-30 |
CN116648169A (en) | 2023-08-25 |
KR20230125166A (en) | 2023-08-29 |
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