TW202210579A - Halogen-free thermosetting resin composition and use thereof - Google Patents
Halogen-free thermosetting resin composition and use thereof Download PDFInfo
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本發明是有關於一種熱固性樹脂組成物及其用途,且特別是有關於一種無鹵熱固性樹脂組成物及其用途。The present invention relates to a thermosetting resin composition and use thereof, and particularly to a halogen-free thermosetting resin composition and use thereof.
近年來,隨著通訊技術的高速發展,電子產品在輕量化與高密度化方面的需求與日俱增。電子產品在使用過程中的消耗功率將產生大量熱能,導致電子產品溫度升高,進而使基板容易損毀。同時,隨著環保意識逐漸提高,各項環保法規愈加嚴苛,材料的無鹵化成為勢在必行的趨勢。因此,在樹脂組成物開發方面,無鹵化且具有優良電氣性能的同時,還具有良好的耐熱性,為本領域技術人員亟欲發展的目標。In recent years, with the rapid development of communication technology, the demand for light weight and high density of electronic products is increasing day by day. The power consumption of an electronic product during use will generate a large amount of heat energy, which will cause the temperature of the electronic product to rise, thereby making the substrate easily damaged. At the same time, with the gradual improvement of environmental protection awareness, various environmental protection regulations have become more stringent, and halogen-free materials have become an imperative trend. Therefore, in terms of the development of resin compositions, it has no halogenation and has excellent electrical properties, and also has good heat resistance, which is an urgent development goal for those skilled in the art.
本發明提供一種無鹵熱固性樹脂組成物,樹脂中不含有鹵素,具有低介電常數、低介電損耗特性的同時,仍具有高Tg(玻璃化轉變溫度)、高耐熱性,並且可應用在銅箔基板與印刷電路板中。The invention provides a halogen-free thermosetting resin composition, the resin does not contain halogen, has the characteristics of low dielectric constant and low dielectric loss, and still has high Tg (glass transition temperature) and high heat resistance, and can be used in Copper foil substrates and printed circuit boards.
本發明的無鹵熱固性樹脂組成物包括不含有鹵素的環氧樹脂、苯乙烯馬來酸酐共聚物、氰酸酯樹脂、馬來醯亞胺樹脂以及阻燃劑。The halogen-free thermosetting resin composition of the present invention includes a halogen-free epoxy resin, a styrene maleic anhydride copolymer, a cyanate ester resin, a maleimide resin, and a flame retardant.
在本發明的一實施例中,以環氧樹脂的含量為100重量份計,苯乙烯馬來酸酐共聚物的含量為40重量份至90重量份,氰酸酯樹脂的含量為30重量份至120重量份,馬來醯亞胺樹脂的含量為20重量份至70重量份,阻燃劑的含量為20重量份至70重量份。In an embodiment of the present invention, based on the content of the epoxy resin as 100 parts by weight, the content of the styrene maleic anhydride copolymer is 40 to 90 parts by weight, and the content of the cyanate ester resin is 30 to 90 parts by weight 120 parts by weight, the content of the maleimide resin is 20 to 70 parts by weight, and the content of the flame retardant is 20 to 70 parts by weight.
在本發明的一實施例中,環氧樹脂包括酚醛環氧樹脂、三官能環氧樹脂、四官能環氧樹脂、雙環戊二烯環氧樹脂(DCPD)、雙酚型環氧樹脂、含磷環氧樹脂、鄰甲酚醛環氧樹脂、雙酚A酚醛環氧樹脂、苯酚酚醛環氧樹脂、萘環型環氧樹脂、異氰酸酯改性環氧樹脂、聯苯型環氧樹脂、含三嗪結構環氧樹脂(triazine)、含茀結構脂環氧樹脂(fulorene)或其組合。In an embodiment of the present invention, the epoxy resin includes novolac epoxy resin, trifunctional epoxy resin, tetrafunctional epoxy resin, dicyclopentadiene epoxy resin (DCPD), bisphenol epoxy resin, phosphorus-containing epoxy resin Epoxy resin, o-cresol novolac epoxy resin, bisphenol A novolac epoxy resin, phenol novolac epoxy resin, naphthalene ring epoxy resin, isocyanate modified epoxy resin, biphenyl epoxy resin, triazine-containing structure Epoxy resin (triazine), fulorene-containing epoxy resin (fulorene), or a combination thereof.
在本發明的一實施例中,苯乙烯馬來酸酐共聚物的分子量為3000至10000,且苯乙烯:馬來酸酐的莫耳比為1至8:1。In an embodiment of the present invention, the molecular weight of the styrene maleic anhydride copolymer is 3000 to 10000, and the molar ratio of styrene:maleic anhydride is 1 to 8:1.
在本發明的一實施例中,氰酸酯樹脂包括雙酚A型氰酸酯樹脂、雙環戊二烯型(DCPD)氰酸酯樹脂、雙酚F型氰酸酯樹脂、酚醛型氰酸酯樹脂或其組合。In an embodiment of the present invention, the cyanate ester resin includes bisphenol A type cyanate ester resin, dicyclopentadiene type (DCPD) cyanate ester resin, bisphenol F type cyanate ester resin, and novolac type cyanate ester resin or a combination thereof.
在本發明的一實施例中,馬來醯亞胺樹脂包括4, 4’-二苯甲烷雙馬來醯亞胺、苯甲烷馬來醯亞胺寡聚物、間-亞苯基雙馬來醯亞胺、雙酚A二苯基醚雙馬來醯亞胺、3, 3’-二甲基-5, 5’-二乙基-4, 4’-二苯基甲烷雙馬來醯亞胺、4-甲基-1, 3-亞苯基雙馬來醯亞胺、1, 6-雙馬來醯亞胺-(2, 2, 4-三甲基)己烷或其組合。In one embodiment of the present invention, the maleimide resin includes 4,4'-diphenylmethane bismaleimide, phenylmethane maleimide oligomer, m-phenylene bismaleimide Imide, bisphenol A diphenyl ether bismaleimide, 3,3'-dimethyl-5,5'-diethyl-4,4'-diphenylmethane bismaleimide amine, 4-methyl-1,3-phenylenebismaleimide, 1,6-bismaleimide-(2,2,4-trimethyl)hexane, or a combination thereof.
在本發明的一實施例中,阻燃劑為無鹵阻燃劑。In an embodiment of the present invention, the flame retardant is a halogen-free flame retardant.
在本發明的一實施例中,阻燃劑包括含磷阻燃劑。In one embodiment of the present invention, the flame retardant includes a phosphorus-containing flame retardant.
在本發明的一實施例中,含磷阻燃劑包括磷腈化合物、磷酸酯化合物、含磷環氧樹脂、含磷酚醛樹脂、含磷氰酸酯樹脂或其組合。In one embodiment of the present invention, the phosphorus-containing flame retardant includes a phosphazene compound, a phosphoric acid ester compound, a phosphorus-containing epoxy resin, a phosphorus-containing phenolic resin, a phosphorus-containing cyanate resin, or a combination thereof.
本發明提供一種預浸漬片,由上述無鹵熱固性樹脂組成物所製成,其中通過將基材含浸或塗佈無鹵熱固性樹脂組成物,並乾燥經含浸或塗佈的基材而製成。The present invention provides a prepreg made of the above-mentioned halogen-free thermosetting resin composition, which is produced by impregnating or coating a base material with the halogen-free thermosetting resin composition, and drying the impregnated or coated base material.
基於上述,本發明提供一種無鹵熱固性樹脂組成物,包括不含有鹵素的環氧樹脂,具有低介電常數、低介電損耗特性的同時,仍具有高Tg(玻璃化轉變溫度)、高耐熱性,並且可應用在銅箔基板與印刷電路板中。Based on the above, the present invention provides a halogen-free thermosetting resin composition, including a halogen-free epoxy resin, which has the characteristics of low dielectric constant and low dielectric loss, and also has high Tg (glass transition temperature) and high heat resistance. properties, and can be used in copper foil substrates and printed circuit boards.
以下,將詳細描述本發明的實施例。然而,這些實施例為例示性,且本發明揭露不限於此。Hereinafter, embodiments of the present invention will be described in detail. However, these embodiments are exemplary, and the present disclosure is not limited thereto.
在本文中,由「一數值至另一數值」表示的範圍,是一種避免在說明書中一一列舉該範圍中的所有數值的概要性表示方式。因此,某一特定數值範圍的記載,涵蓋該數值範圍內的任意數值以及由該數值範圍內的任意數值界定出的較小數值範圍,如同在說明書中說明文寫出該任意數值和該較小數值範圍一樣。As used herein, a range represented by "one value to another value" is a general representation that avoids listing all the values in the range in the specification. Accordingly, the recitation of a particular numerical range includes any numerical value within that numerical range as well as a smaller numerical range bounded by any numerical value within that numerical range, as if the arbitrary numerical value and the smaller numerical range were written in the description in the specification The range of values is the same.
本發明提出一種無鹵熱固性樹脂組成物,包括不含有鹵素的環氧樹脂、苯乙烯馬來酸酐共聚物、氰酸酯樹脂、馬來醯亞胺樹脂以及阻燃劑。更詳細而言,以環氧樹脂的含量為100重量份計,苯乙烯馬來酸酐共聚物的含量例如是40重量份至90重量份,氰酸酯樹脂的含量例如是30重量份至120重量份,馬來醯亞胺樹脂的含量例如是20重量份至70重量份,阻燃劑的含量例如是20重量份至70重量份。以下,將對上述各種組分進行詳細說明。< 環氧樹脂 > The invention provides a halogen-free thermosetting resin composition, which comprises a halogen-free epoxy resin, a styrene maleic anhydride copolymer, a cyanate ester resin, a maleimide resin and a flame retardant. More specifically, based on 100 parts by weight of the epoxy resin, the content of the styrene maleic anhydride copolymer is, for example, 40 to 90 parts by weight, and the content of the cyanate resin is, for example, 30 to 120 parts by weight. The content of the maleimide resin is, for example, 20 to 70 parts by weight, and the content of the flame retardant is, for example, 20 to 70 parts by weight. Hereinafter, the above-mentioned various components will be described in detail. < Epoxy resin >
本發明的環氧樹脂不含有鹵素,主要可包括酚醛環氧樹脂、三官能環氧樹脂、四官能環氧樹脂、雙環戊二烯環氧樹脂(DCPD)、雙酚型環氧樹脂、含磷環氧樹脂、鄰甲酚醛環氧樹脂、雙酚A酚醛環氧樹脂、苯酚酚醛環氧樹脂、萘環型環氧樹脂、異氰酸酯改性環氧樹脂、聯苯型環氧樹脂、含三嗪結構環氧樹脂(triazine)、含茀結構脂環氧樹脂(fulorene)或其組合。< 苯乙烯馬來酸酐共聚物 > The epoxy resin of the present invention does not contain halogen, and can mainly include novolac epoxy resin, trifunctional epoxy resin, tetrafunctional epoxy resin, dicyclopentadiene epoxy resin (DCPD), bisphenol epoxy resin, phosphorus-containing epoxy resin Epoxy resin, o-cresol novolac epoxy resin, bisphenol A novolac epoxy resin, phenol novolac epoxy resin, naphthalene ring epoxy resin, isocyanate modified epoxy resin, biphenyl epoxy resin, triazine-containing structure Epoxy resin (triazine), fulorene-containing epoxy resin (fulorene), or a combination thereof. < Styrene maleic anhydride copolymer >
本發明的苯乙烯馬來酸酐共聚物的分子量例如是3000至10000,且苯乙烯:馬來酸酐的莫耳比例如是1至8:1。< 氰酸酯樹脂 >. The molecular weight of the styrene maleic anhydride copolymer of the present invention is, for example, 3,000 to 10,000, and the molar ratio of styrene:maleic anhydride is, for example, 1 to 8:1. < Cyanate ester resin >.
本發明的氰酸酯樹脂可包括雙酚A型氰酸酯樹脂、雙環戊二烯型(DCPD)氰酸酯樹脂、雙酚F型氰酸酯樹脂、酚醛型氰酸酯樹脂或其組合。< 馬來醯亞胺樹脂 > The cyanate resin of the present invention may include bisphenol A type cyanate resin, dicyclopentadiene type (DCPD) cyanate resin, bisphenol F type cyanate resin, novolac type cyanate resin or a combination thereof. < Maleimide resin >
本發明的馬來醯亞胺樹脂可包括4, 4’-二苯甲烷雙馬來醯亞胺、苯甲烷馬來醯亞胺寡聚物、間-亞苯基雙馬來醯亞胺、雙酚A二苯基醚雙馬來醯亞胺、3, 3’-二甲基-5, 5’-二乙基-4, 4’-二苯基甲烷雙馬來醯亞胺、4-甲基-1, 3-亞苯基雙馬來醯亞胺、1, 6-雙馬來醯亞胺-(2, 2, 4-三甲基)己烷或其組合。< 阻燃劑 > The maleimide resin of the present invention may include 4,4'-diphenylmethanebismaleimide, phenylmethanemaleimide oligomer, m-phenylenebismaleimide, bismaleimide Phenol A diphenyl ether bismaleimide, 3,3'-dimethyl-5,5'-diethyl-4,4'-diphenylmethane bismaleimide, 4-methyl yl-1,3-phenylenebismaleimide, 1,6-bismaleimide-(2,2,4-trimethyl)hexane, or a combination thereof. < Flame retardant >
本發明的阻燃劑為無鹵阻燃劑,無鹵阻燃劑可包括但不限於含氮化合物、含磷化合物或次磷酸金屬鹽,較佳例如是含磷化合物。含磷阻燃劑可包括磷腈化合物、磷酸酯化合物、含磷環氧樹脂、含磷酚醛樹脂、含磷氰酸酯樹脂或其組合。< 其他添加劑 > The flame retardant of the present invention is a halogen-free flame retardant, and the halogen-free flame retardant may include, but is not limited to, nitrogen-containing compounds, phosphorus-containing compounds or metal hypophosphorous acid salts, preferably phosphorus-containing compounds. The phosphorus-containing flame retardant may include a phosphazene compound, a phosphoric acid ester compound, a phosphorus-containing epoxy resin, a phosphorus-containing phenolic resin, a phosphorus-containing cyanate resin, or a combination thereof. < Other additives >
本發明的無鹵熱固性樹脂組成物可進一步包括以下添加劑的至少一種:交聯劑、填料、催化劑及溶劑。The halogen-free thermosetting resin composition of the present invention may further include at least one of the following additives: a crosslinking agent, a filler, a catalyst and a solvent.
本發明的交聯劑可包括2,2'-二烯丙基雙酚A、三烯丙基異氰脲酸酯、雙(3-烯丙基-4-羥苯基)碸、活性酯(例如: DIC的HPC-8000-65T)、對苯二酚或其組合。The cross-linking agent of the present invention may include 2,2'-diallyl bisphenol A, triallyl isocyanurate, bis(3-allyl-4-hydroxyphenyl) sulfone, active ester ( For example: DIC's HPC-8000-65T), hydroquinone or a combination thereof.
本發明的填料可包括二氧化矽、氧化鋁、氧化鎂、氫氧化鎂、碳酸鈣、滑石、黏土、氮化鋁、氮化硼、氫氧化鋁、碳化鋁矽、碳化矽、碳酸鈉、二氧化鈦、氧化鋅、氧化鋯、石英、鑽石、類鑽石、石墨、鍛燒高嶺土、白嶺土、雲母、水滑石、中空二氧化矽、聚四氟乙烯(polytetrafluoroethylene,PTFE)粉末、玻璃珠、奈米碳管、奈米級無機粉體或其組合。Fillers of the present invention may include silica, alumina, magnesia, magnesium hydroxide, calcium carbonate, talc, clay, aluminum nitride, boron nitride, aluminum hydroxide, aluminum silicon carbide, silicon carbide, sodium carbonate, titanium dioxide , zinc oxide, zirconia, quartz, diamond, diamond-like, graphite, calcined kaolin, kaolin, mica, hydrotalcite, hollow silica, polytetrafluoroethylene (PTFE) powder, glass beads, nanocarbon Tubes, nanoscale inorganic powders, or a combination thereof.
本發明催化劑的種類並無特殊限制,只要其能促進環氧官能基開環、並降低樹脂組成物的固化反應溫度即可。具體而言,催化劑可選擇自以下:2-甲基咪唑、2-乙基-4-甲基咪唑、2-苯基咪唑、二甲芐胺、2-(二甲胺甲基)苯酚、2 ,4 ,6-三(二甲胺甲基)苯酚、2 ,3-二胺基吡啶、2 ,5-二胺基吡啶、2 ,6-二胺基吡啶、4-二甲基氨基吡啶、2-胺基-3-甲基吡啶、2-胺基-4-甲基吡啶、2-胺基-3-硝基吡啶、氧化鋅及其組合物。The type of the catalyst of the present invention is not particularly limited as long as it can promote ring-opening of epoxy functional groups and lower the curing reaction temperature of the resin composition. Specifically, the catalyst can be selected from the following: 2-methylimidazole, 2-ethyl-4-methylimidazole, 2-phenylimidazole, dimethylbenzylamine, 2-(dimethylaminomethyl)phenol, 2 ,4,6-Tris(dimethylaminomethyl)phenol, 2,3-diaminopyridine, 2,5-diaminopyridine, 2,6-diaminopyridine, 4-dimethylaminopyridine, 2-amino-3-methylpyridine, 2-amino-4-methylpyridine, 2-amino-3-nitropyridine, zinc oxide and combinations thereof.
本發明的溶劑的種類並無特殊限制,只要其能使樹脂組合物的黏度適中,便於操作、固化即可,本發明對此不加以限定。The type of the solvent in the present invention is not particularly limited, as long as it can make the viscosity of the resin composition moderate, and is convenient for operation and curing, which is not limited in the present invention.
本發明也提供一種預浸漬片,由上述無鹵熱固性樹脂組成物所製成,其中通過將基材含浸或塗佈無鹵熱固性樹脂組成物,並乾燥經含浸或塗佈的基材而製成。更詳細而言,基材可包括玻璃纖維補強材料(玻璃纖維織物或不織物、玻璃紙、玻璃氈等)、牛皮紙、短絨棉紙、天然纖維布、有機纖維布、液晶高分子纖維氈等。在本實施例中,例如可使用2116玻璃纖維布作為補強材(基材),並在溫度130℃至200℃下加熱乾燥2分鐘至10分鐘,從而製得半固化的預含浸片。取數片半固化的預含浸片堆疊於熱壓機中進行高溫固化,固化條件例如是在溫度160℃至280℃下固化1小時至4小時。The present invention also provides a prepreg made of the above-mentioned halogen-free thermosetting resin composition, which is produced by impregnating or coating a base material with the halogen-free thermosetting resin composition, and drying the impregnated or coated base material . In more detail, the base material may include glass fiber reinforced materials (glass fiber woven or non-woven, cellophane, glass mat, etc.), kraft paper, cotton paper, natural fiber cloth, organic fiber cloth, liquid crystal polymer fiber felt and the like. In this embodiment, for example, 2116 glass fiber cloth can be used as a reinforcing material (substrate), and the semi-cured pre-impregnated sheet can be prepared by heating and drying at a temperature of 130°C to 200°C for 2 minutes to 10 minutes. Take several semi-cured pre-impregnated sheets and stack them in a hot press for high temperature curing, for example, curing at a temperature of 160°C to 280°C for 1 hour to 4 hours.
以下,藉由實驗例來詳細說明上述本發明所提出的無鹵熱固性樹脂組成物。然而,下述實驗例並非用以限制本發明。實驗例 Hereinafter, the halogen-free thermosetting resin composition proposed by the present invention will be described in detail by means of experimental examples. However, the following experimental examples are not intended to limit the present invention. Experimental example
為了證明本發明所提出的無鹵熱固性樹脂組成物具有低介電常數、低介電損耗,同時仍具有高玻璃化轉變溫度(Tg)及高耐熱性,以下特別作此實驗例。In order to prove that the halogen-free thermosetting resin composition proposed by the present invention has low dielectric constant, low dielectric loss, and still has high glass transition temperature (Tg) and high heat resistance, the following experimental example is specially made.
依據以下表1所列出的組成比例,製備實例1至實例4以及比較例1至比較例4的樹脂組成物。使用2116玻璃纖維布作為補強材(基材),將基材含浸或塗佈樹脂組成物,並在溫度130℃至200℃下加熱乾燥2分鐘至10分鐘,從而製得半固化的預含浸片。取數片半固化的預含浸片堆疊於熱壓機中進行高溫固化,固化條件例如是在溫度160℃至280℃下固化1小時至4小時。之後,測試試片的電熱性質,並將測試結果列於以下表1中。Resin compositions of Examples 1 to 4 and Comparative Examples 1 to 4 were prepared according to the composition ratios listed in Table 1 below. Using 2116 glass fiber cloth as a reinforcing material (substrate), the substrate is impregnated or coated with a resin composition, and heated and dried at a temperature of 130°C to 200°C for 2 minutes to 10 minutes to prepare a semi-cured pre-impregnated sheet . Take several semi-cured pre-impregnated sheets and stack them in a hot press for high temperature curing, for example, curing at a temperature of 160°C to 280°C for 1 hour to 4 hours. After that, the electrothermal properties of the test pieces were tested, and the test results are listed in Table 1 below.
在以下表1中,環氧樹脂為三官能環氧樹脂、雙環戊二烯環氧樹脂、雙酚型環氧樹脂。苯乙烯馬來酸酐共聚物為苯乙烯:馬來酸酐的莫耳比例3:1至6:1。氰酸酯樹脂為雙酚A型氰酸酯樹脂。馬來醯亞胺樹脂為3, 3’-二甲基-5, 5’-二乙基-4, 4’-二苯基甲烷雙馬來醯亞胺。交聯劑為活性酯。阻燃劑為磷腈化合物。填料為二氧化矽。催化劑為2-甲基咪唑。In Table 1 below, the epoxy resins are trifunctional epoxy resins, dicyclopentadiene epoxy resins, and bisphenol-type epoxy resins. The styrene maleic anhydride copolymer is in a molar ratio of styrene:maleic anhydride from 3:1 to 6:1. The cyanate resin is a bisphenol A type cyanate resin. The maleimide resin is 3,3'-dimethyl-5,5'-diethyl-4,4'-diphenylmethane bismaleimide. The crosslinking agent is an active ester. The flame retardant is a phosphazene compound. The filler is silica. The catalyst is 2-methylimidazole.
表1
如表1所示,從實例1至實例4可以得知,當樹脂組成物的組成及含量符合本發明所提出的範圍時,固化後的樹脂組合物具有優良的熱性質與電器性質。從比較例1可以得知,未添加氰酸酯樹脂會使樹脂組合物整體性質大幅降低。從比較例2可以得知,當馬來醯亞胺樹脂添加量過高時(超出本發明所提出的範圍),會使Dk提高。從比較例3可以得知,當氰酸酯樹脂及馬來醯亞胺樹脂的含量超出本發明所提出的範圍時,會使Df提高。從比較例4可以得知,當馬來醯亞胺樹脂添加量過低時(超出本發明所提出的範圍),會使Dk提高。如此一來,可得知當樹脂組成物的組成比例符合本發明所提出的範圍時,固化後的樹脂組合物Tg可達到200℃以上高溫,且具有較佳的Dk/Df值(Dk < 4.0、Df < 0.010)。As shown in Table 1, it can be known from Examples 1 to 4 that when the composition and content of the resin composition meet the ranges proposed by the present invention, the cured resin composition has excellent thermal properties and electrical properties. As can be seen from Comparative Example 1, the lack of addition of the cyanate ester resin significantly reduces the overall properties of the resin composition. It can be known from Comparative Example 2 that when the amount of maleimide resin added is too high (beyond the range proposed by the present invention), Dk will increase. It can be known from Comparative Example 3 that when the content of cyanate resin and maleimide resin exceeds the range proposed by the present invention, Df will increase. It can be known from Comparative Example 4 that when the amount of maleimide resin added is too low (beyond the range proposed by the present invention), Dk will increase. In this way, it can be known that when the composition ratio of the resin composition conforms to the range proposed by the present invention, the Tg of the cured resin composition can reach a high temperature above 200 ° C, and has a better Dk/Df value (Dk < 4.0 , Df < 0.010).
綜上所述,本發明提供一種無鹵熱固性樹脂組成物,包括不含有鹵素的環氧樹脂、苯乙烯馬來酸酐共聚物、氰酸酯樹脂、馬來醯亞胺樹脂以及阻燃劑,且上述組成以特定比例範圍添加,因此,具有低介電常數、低介電損耗,同時仍具有高玻璃化轉變溫度(Tg)及高耐熱性,玻璃化轉變溫度(Tg)可達到200℃以上,且可應用於銅箔基板與印刷電路板。In summary, the present invention provides a halogen-free thermosetting resin composition, comprising a halogen-free epoxy resin, a styrene maleic anhydride copolymer, a cyanate ester resin, a maleimide resin and a flame retardant, and The above composition is added in a specific ratio range, so it has low dielectric constant, low dielectric loss, and still has high glass transition temperature (Tg) and high heat resistance. The glass transition temperature (Tg) can reach more than 200 ℃, And can be applied to copper foil substrates and printed circuit boards.
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