TW202210302A - A container for beverage preparation - Google Patents

A container for beverage preparation Download PDF

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TW202210302A
TW202210302A TW110125524A TW110125524A TW202210302A TW 202210302 A TW202210302 A TW 202210302A TW 110125524 A TW110125524 A TW 110125524A TW 110125524 A TW110125524 A TW 110125524A TW 202210302 A TW202210302 A TW 202210302A
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Taiwan
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layer
wall
sachet
compostable
bag
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TW110125524A
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Chinese (zh)
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克里斯多福 賽巴斯汀 保羅 黑斗
大衛 諾克維
卡洛 瑪吉
伊曼紐 克羅希爾
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瑞士商雀巢製品股份有限公司
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Publication of TW202210302A publication Critical patent/TW202210302A/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B23/00Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose
    • B32B23/04Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising such cellulosic plastic substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B23/06Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising such cellulosic plastic substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B23/00Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose
    • B32B23/04Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising such cellulosic plastic substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B23/08Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising such cellulosic plastic substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/10Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • B65D65/46Applications of disintegrable, dissolvable or edible materials
    • B65D65/466Bio- or photodegradable packaging materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/70Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for
    • B65D85/804Disposable containers or packages with contents which are mixed, infused or dissolved in situ, i.e. without having been previously removed from the package
    • B65D85/8043Packages adapted to allow liquid to pass through the contents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/70Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for
    • B65D85/804Disposable containers or packages with contents which are mixed, infused or dissolved in situ, i.e. without having been previously removed from the package
    • B65D85/8043Packages adapted to allow liquid to pass through the contents
    • B65D85/8046Pods, i.e. closed containers made only of filter paper or similar material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2270/00Resin or rubber layer containing a blend of at least two different polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/31Heat sealable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/58Cuttability
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/716Degradable
    • B32B2307/7163Biodegradable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/718Weight, e.g. weight per square meter
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • B32B2307/7242Non-permeable
    • B32B2307/7244Oxygen barrier
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • B32B2307/7242Non-permeable
    • B32B2307/7246Water vapor barrier
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/73Hydrophobic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/732Dimensional properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/75Printability
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/70Food packaging
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W90/00Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
    • Y02W90/10Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Wrappers (AREA)
  • Packages (AREA)

Abstract

A pod with an inner volume in which a beverage ingredient is stored and in which a beverage is produced when water is introduced inside, said pod (1) comprising a first wall (11) through which water is to be introduced and a second wall (14) through which the beverage is to be dispensed, the pod (1) being made of one or several compostable multilayer materials. Each of said one or several multilayer materials comprises at least one paper layer and at least one polymer barrier layer, said at least one paper layer and at least one polymer barrier layer being attached to one another by an adhesive layer such as to bind them with a bond strength at least equal to 1.6 N/15 mm at 22 DEG C, and 0.22 N /15 mm at 100 DEG C, said at least one polymer barrier layer having a thickness comprised between 10 and 100 microns.

Description

用於飲料製備的容器 Containers for beverage preparation

本發明係涉及一種用於製備飲料之包含飲料成分的囊包(pod)。 The present invention relates to a pod containing beverage ingredients for the preparation of beverages.

已知在一施配機中藉由使用含有飲料製造成分的囊包來製備飲料。囊包具有內部容積供食品或飲料成分儲存在其中,並在當水引入內部時,在其中製作飲料或飲品。 It is known to prepare beverages in a dispenser by using sachets containing beverage-making ingredients. The sachet has an interior volume for food or beverage ingredients to be stored therein, and in which the beverage or drink is made when water is introduced into the interior.

在對生態負責的方法中,一些現存的囊包係由可堆肥或生物可分解材料製成。 In an ecologically responsible approach, some existing pouches are made from compostable or biodegradable materials.

在本文件中且如下所解釋,在「可工業堆肥(industrially compostable)」與「可家庭堆肥(home compostable)」之間有所不同。 In this document and as explained below, there is a difference between " industrially compostable" and " home compostable".

材料必須擁有哪些特性才得以使其可定義為「工業上可堆肥(industrially compostable)」係藉由數個規範所建立,諸如歐洲規範(European Norm)EN 13432「對於堆肥及生物分解之包裝可回收的需求-針對包裝最後驗收的測試方案與評估標準(Requirements for packaging recoverable through composting and biodegradation-Test scheme and evaluation criteria for the final acceptance of packaging)」、 ISO18606、ASTM D6400。根據EN 13432,工業上可堆肥材料必須呈現的特性係列出於下。 What properties a material must have in order for it to be defined as "industrially compostable " is established by several specifications, such as the European Norm EN 13432 "Recyclable packaging for composting and biodegradation" Requirements-Test scheme and evaluation criteria for the final acceptance of packaging (Requirements for packaging recoverable through composting and biodegradation-Test scheme and evaluation criteria for the final acceptance of packaging) ", ISO18606, ASTM D6400. According to EN 13432, the series of properties that industrially compostable materials must exhibit are as follows.

-生物可分解性,即可堆肥材料代謝轉化為二氧化碳。驗收位準係在少於6個月且在58℃的溫度下進行而達到90%生物可分解性。 - Biodegradability, i.e. the metabolic conversion of compostable material to carbon dioxide. The acceptance level is to achieve 90% biodegradability in less than 6 months and at a temperature of 58°C.

-可崩解性(disintegrability),即在最終堆肥中的破碎化及失去可見度(不存在視覺上的污物)。將樣本與有機廢料一起在40℃與70℃之間的溫度下堆肥達3個月(由生物過程驅使)。在結束時,以2mm篩子過濾堆肥。具有大於2mm之尺寸的試驗材料之殘餘物的質量必須小於初始質量的10%。 - disintegrability, ie fragmentation and loss of visibility (absence of visual soiling) in the final compost. The samples were composted with organic waste at temperatures between 40°C and 70°C for 3 months (driven by biological processes). At the end, the compost is filtered through a 2mm sieve. The mass of the residue of the test material having dimensions greater than 2 mm must be less than 10% of the initial mass.

-對堆肥過程沒有不利影響。 - No adverse effect on the composting process.

-低位準的重金屬及對堆肥的品質沒有不利影響(例如,農業價值的減少及在植物生長上存在生態毒理效應)。 - Low levels of heavy metals and no adverse effects on compost quality (eg, reduction of agricultural value and ecotoxicological effects on plant growth).

-在所研究材料分解後必須維持不變的其他化學物理參數:pH值;鹽分含量;揮發性固體;N;P;Mg;K。 - Other chemical-physical parameters that must remain unchanged after decomposition of the material under study: pH value; salt content; volatile solids; N; P; Mg; K.

此刻並沒有國際標準去定義材料必須擁有哪些特性才得以使其可定義為「可家庭堆肥(home compostable)」。然而,一些國家規範(具體而言係認證機構的測試規程(例如TÜV AUSTRIA BELGIUM公司))定義與「工業可堆肥性(industrial compostability)」的唯一差異在於下列: At the moment there is no international standard to define what properties a material must possess in order for it to be defined as " home compostable". However, the only differences in the definition of "industrial compostability " in some national regulations (specifically the test procedures of certification bodies (eg TÜV AUSTRIA BELGIUM)) are the following:

-生物可分解性:驗收位準係在少於12個月且在28℃的溫度下進行而達到90%生物可分解性。 - Biodegradability: The acceptance level is 90% biodegradability in less than 12 months and at a temperature of 28°C.

-可崩解性:樣本在28℃的溫度下堆肥達6個月。 - Disintegrability: The samples were composted at a temperature of 28°C for 6 months.

直到現在,現存的可堆肥囊包不存在良好的機械、隔絕、及保存性質。實際上,目前最佳技術的囊包係脆弱的,且易因氧化、濕氣、壓力變化等而遭受分解。 Until now, existing compostable bags did not have good mechanical, insulating, and preservation properties. In fact, the current state-of-the-art capsules are fragile and susceptible to decomposition due to oxidation, moisture, pressure changes, and the like.

因此,本發明尋求提供一種用於製備飲料的囊包,其係可堆肥的(較佳地係可家庭堆肥),且其能夠關聯於功能結構、適當的機械、隔絕與保存性質。 Accordingly, the present invention seeks to provide a sachet for the preparation of beverages which is compostable (preferably home compostable) and which can be associated with functional structure, suitable mechanical, insulation and preservation properties.

本發明係涉及一種具有一內部容積之囊包,一飲料成分儲存在該內部容積中且當水引入內部時在其中製作一飲料,該囊包包含一第一壁及一第二壁,水透過該第一壁引入且該飲料透過該第二壁施配,該囊包係由一或數個可堆肥多層材料製成。 The present invention relates to a pouch having an inner volume in which a beverage ingredient is stored and in which a beverage is made when water is introduced into the interior, the pouch comprising a first wall and a second wall through which water is permeable Introduced by the first wall and the beverage dispensed through the second wall, the pouch is made of one or more compostable multilayer materials.

根據本發明,該一或數個多層材料之各者包含至少一紙層及至少一聚合物障壁層,該至少一紙層及該至少一聚合物障壁層係藉由一黏著劑層而彼此附接,或藉由將該障壁層擠製塗布至該紙層而彼此附接,諸如以至少等於在22℃下之1.6N/15mm及在100℃下之0.22N/15mm的一接合強度將其等接合。較佳的是使用黏著劑層。 According to the present invention, each of the one or more multilayer materials comprises at least one paper layer and at least one polymer barrier layer, the at least one paper layer and the at least one polymer barrier layer being attached to each other by an adhesive layer bonded, or attached to each other by extrusion coating the barrier layer to the paper layer, such as with a bond strength at least equal to 1.6N/15mm at 22°C and 0.22N/15mm at 100°C Wait for engagement. It is preferred to use an adhesive layer.

由於聚合物障壁層,飲料成分被良好地保存,且具體而言被良好地保護而免受由濕氣造成的氧化及分解。囊包的此組成為消費者提供良好的保存期限,以及提供杯中新鮮及高品質的產品。此外,聚合物障壁層的厚度經界定以諸如可藉由一飲料施配機的穿刺元件順意地刺穿,其中囊包經組態以用於該飲料施配機。 Due to the polymer barrier layer, the beverage ingredients are well preserved, and in particular well protected from oxidation and decomposition by moisture. This composition of the sachet provides the consumer with a good shelf life, as well as a fresh and high quality product in the cup. In addition, the thickness of the polymeric barrier layer is defined to be desirably pierceable, such as by a piercing element of a beverage dispenser for which the pouch is configured.

此外,紙呈現出消費者可輕易且迅速地辨認為可堆肥材料之優點。此可避免消費者誤丟棄囊包。 Furthermore, paper presents the advantage of being easily and quickly recognizable by consumers as a compostable material. This prevents consumers from accidentally discarding the packets.

最後,將紙層及聚合物障壁層接合的足夠強,改良了囊包的機械強度且避免囊包在儲存期間或運送期間遭受機械應力(例如導因於囊包內部之飲料成分的壓力變化或排氣(degassing))時裂開。 Finally, bonding the paper layer to the polymer barrier layer is strong enough to improve the mechanical strength of the pouch and avoid the pouch being subjected to mechanical stress during storage or during transport (eg pressure changes due to beverage ingredients inside the pouch or Cracks during degassing).

具體而言,黏著劑層在紙層與聚合物障壁層兩者之間提供良好的接合性質。 In particular, the adhesive layer provides good bonding properties between both the paper layer and the polymeric barrier layer.

在一實施例中,該黏著劑層係可家庭堆肥的。 In one embodiment, the adhesive layer is home compostable.

在一實施例中,該黏著劑層呈現均質厚度。 In one embodiment, the adhesive layer exhibits a uniform thickness.

此特徵改良紙層與聚合物障壁層之間的接合。 This feature improves the bond between the paper layer and the polymer barrier layer.

在一實施例中,該黏著劑層係以包含在2g/m2與15g/m2之間的施用重量施用。 In one embodiment, the adhesive layer is applied at an application weight comprised between 2 g/m 2 and 15 g/m 2 .

在一實施例中,該黏著劑層係由聚酯-聚胺甲酸酯彈性體製成,具體而言係可購自BASF的Epotal® ECO 3702。 In one embodiment, the adhesive layer is made of a polyester-polyurethane elastomer, specifically Epotal® ECO 3702 available from BASF.

在一實施例中,該黏著劑層呈現介於1微米與20微米之間的厚度。 In one embodiment, the adhesive layer exhibits a thickness between 1 and 20 microns.

在一實施例中,該至少一聚合物障壁層係一塑膠層壓體。 In one embodiment, the at least one polymer barrier layer is a plastic laminate.

塑膠層壓體提供所欲的機械性質,例如關於可穿孔性及可成形性。可穿孔性係一重要特徵,因為囊包係意欲在飲料施配機中被刺穿。此外,該塑膠層壓體係可拉伸的,這使得其可成形。換言之,可輕易藉由將其拉伸給予所欲形狀,而不斷裂或撕裂。 The plastic laminate provides the desired mechanical properties, eg with regard to perforability and formability. Punctability is an important feature since the pouches are intended to be pierced in a beverage dispenser. In addition, the plastic lamination system is stretchable, which makes it formable. In other words, it can be easily given a desired shape by stretching it without breaking or tearing.

有利的是可選擇各式各樣可堆肥塑膠層壓體。 Advantageously, a wide variety of compostable plastic laminates can be selected.

在一實施例中,該塑膠層壓體包含夾在兩個聚合物片材之間的一丁二醇乙烯醇(Vinyl Alcohol,BVOH)片材,該BVOH片材係以連結片材在兩側附接至該等聚合物片材,該等聚合物片材包含下列聚合物,該等聚合物係選自由以下所組成之群組:聚乳酸(polylactic acid,PLA)、聚丁二酸丁二醇酯(Polybutylene succinate,PBS)、及諸如聚己二酸對苯二甲酸丁二酯(polybutylene adipate terephthalate,PBAT)之脂肪族-芳香族聚酯,或者這些聚合物之混合物。 In one embodiment, the plastic laminate comprises a butanediol vinyl alcohol (BVOH) sheet sandwiched between two polymer sheets, the BVOH sheet being on both sides with a connecting sheet Attached to the polymer sheets, the polymer sheets comprising the following polymers selected from the group consisting of: polylactic acid (PLA), polybutylene succinate Alcohol esters (Polybutylene succinate, PBS), and aliphatic-aromatic polyesters such as polybutylene adipate terephthalate (PBAT), or mixtures of these polymers.

連結片材在BVOH片材與聚合物片材之間給予高黏著性。 The tie sheet imparts high adhesion between the BVOH sheet and the polymer sheet.

在一實施例中,該等聚合物片材係由可商購自BASF(具體而言係Ecovio® 40 FS23N1 EXP)之Ecovio®製成。 In one embodiment, the polymer sheets are made from Ecovio® commercially available from BASF, specifically Ecovio® 40 FS23N1 EXP.

在一實施例中,該連結片材係由一黏著劑樹脂製成,該黏著劑樹脂包括經酸酐改質之聚合物樹脂。 In one embodiment, the connecting sheet is made of an adhesive resin, and the adhesive resin includes an acid anhydride-modified polymer resin.

在一實施例中,該一或數個多層材料進一步包含一聚合可堆肥材料之一保護層。 In one embodiment, the one or more multilayer materials further comprise a protective layer of a polymeric compostable material.

保護層防止塑膠層壓體黏在飲料機上。 The protective layer prevents the plastic laminate from sticking to the beverage machine.

在一實施例中,該聚合可堆肥材料係再生纖維素。例如,該聚合可堆肥材料可係玻璃紙(Cellophane)。 In one embodiment, the polymeric compostable material is regenerated cellulose. For example, the polymeric compostable material may be cellophane.

在一實施例中,該一或數個多層材料進一步包含在其表面之一者上的油墨印刷。 In one embodiment, the one or more multilayer materials further comprise ink printing on one of its surfaces.

油墨印刷可係例如插圖、針對使用者的資訊、及/或可由機器讀取的代碼。 Ink printing can be, for example, illustrations, information for the user, and/or machine-readable codes.

在一實施例中,至少一多層材料包含: In one embodiment, the at least one multilayer material comprises:

-一紙層,其具有包含在40gsm與130gsm之間的一克重; - a paper layer having a gram weight comprised between 40gsm and 130gsm;

-一第一黏著劑層,其係由Epotal® ECO 3702製成,且其係以包含在2g/m2與15g/m2之間的一施用重量施用;及 - a first adhesive layer, which is made of Epotal® ECO 3702, and which is applied at an application weight comprised between 2 g/m 2 and 15 g/m 2 ; and

-一聚合物障壁層,其係由一塑膠層壓體製成,其中該聚合物片材係由Ecovio®(具體而言係Ecovio® 40 FS23N1 EXP)製成且具有包含在介於10微米與30微米之間的一厚度,該等連結片材之各者係以包含在介於2g/m2與8g/m2之間的一施用重量施用。 - a polymer barrier layer, which is made of a plastic laminate, wherein the polymer sheet is made of Ecovio® (specifically, Ecovio® 40 FS23N1 EXP) and has a thickness comprised between 10 microns and A thickness of between 30 microns, each of the joined sheets was applied at an application weight comprised between 2 g/m 2 and 8 g/m 2 .

在一實施例中,至少一多層材料進一步包含: In one embodiment, the at least one multilayer material further comprises:

-一保護層,其係由玻璃紙製成且具有包含在10微米與50微米之間的一厚度,該保護層包含在其表面之一者上的一油墨印刷;及 - a protective layer made of cellophane and having a thickness comprised between 10 and 50 microns, the protective layer comprising an ink print on one of its surfaces; and

-一第二黏著劑層,其將該紙層附接至該黏著劑層,該第二黏著劑層係由Epotal® ECO 3702製成,且係以包含在2g/m2與15g/m2之間的一施用重量施用。 - a second adhesive layer, which attaches the paper layer to the adhesive layer, the second adhesive layer is made of Epotal® ECO 3702 and is contained in 2g /m2 and 15g/ m2 One application weight between applications.

在一實施例中,該囊包包含一本體,該本體具有一底壁及一閉合蓋,水透過該底壁引入且該飲料透過該閉合蓋施配,該閉合蓋密封於該本體上並在其等之間界定該內部容積,該本體係由一第一多層材料製成且該閉合蓋係由不同於該本體之該第一多層材料的一第二多層材料製成。 In one embodiment, the sachet includes a body having a bottom wall through which water is introduced and a closure cap through which the beverage is dispensed, the closure cap being sealed on the body and being Defining the interior volume therebetween, the body is made of a first multilayer material and the closure lid is made of a second multilayer material different from the first multilayer material of the body.

在一實施例中,該本體係由該至少一多層材料製成,該至少一多層材料包含該紙層、該第一黏著劑層、及該聚合物障壁層。 該閉合蓋係由該至少一多層材料製成,該至少一多層材料進一步包含該保護層及該第二黏著劑層。 In one embodiment, the present system is made of the at least one multilayer material comprising the paper layer, the first adhesive layer, and the polymeric barrier layer. The closure cover is made of the at least one multi-layer material, and the at least one multi-layer material further comprises the protective layer and the second adhesive layer.

在一實施例中,該第一壁及該第二壁相對於彼此密封並在其等之間界定該內部容積,該第一壁及該第二壁兩者係由相同的可堆肥多層材料製成。 In one embodiment, the first wall and the second wall are sealed with respect to each other and define the interior volume therebetween, both of the first wall and the second wall being made of the same compostable multilayer material become.

這實現了對稱囊包的成形,容易製造及使用。使用者不需注意在飲料機中投入的方向。 This enables the formation of a symmetrical bag, which is easy to manufacture and use. The user does not need to pay attention to the direction of the injection into the beverage machine.

在一實施例中,該第一壁及該第二壁兩者係由該至少一多層材料製成,該至少一多層材料包含該紙層、該第一黏著劑層、及該聚合物障壁層。 In one embodiment, both the first wall and the second wall are made of the at least one multilayer material comprising the paper layer, the first adhesive layer, and the polymer barrier layer.

1:囊包、可堆肥多層材料 1: bag, compostable multi-layer material

10:本體 10: Ontology

11:第一壁、底壁 11: The first wall, the bottom wall

12:側壁 12: Sidewall

13:周圍邊緣 13: Around the edge

14:第二壁、閉合蓋 14: Second wall, closing cover

在以下參考圖式所載明的當前較佳實施例說明中,本發明之額外特徵及優點經描述且係顯而易見,圖式中: Additional features and advantages of the present invention are described and are apparent from the description of the presently preferred embodiment set forth below with reference to the accompanying drawings, in which:

〔圖1〕係根據本發明之一實施例的囊包的透視圖; [Fig. 1] is a perspective view of a bag according to an embodiment of the present invention;

〔圖2〕係圖1之囊包的透視剖面圖;及 [Fig. 2] is a perspective cross-sectional view of the bag of Fig. 1; and

〔圖3〕係根據本發明之另一實施例的囊包的透視圖。 [FIG. 3] is a perspective view of a bag according to another embodiment of the present invention.

圖1圖2繪示根據本發明之一實施例的一囊包1,且圖3繪示根據本發明之另一實施例的一囊包。 1 and 2 illustrate a pouch 1 according to an embodiment of the present invention, and FIG. 3 illustrates a pouch according to another embodiment of the present invention.

囊包1具有一內部容積,飲料成分儲存在內部容積中,且當水引入內部時在其中製作飲料。囊包1包含一第一壁11及一第二壁14,水透過該第一壁引入且飲料透過該第二壁施配。 The sachet 1 has an inner volume in which the beverage ingredients are stored and in which the beverage is made when water is introduced into the interior. The sachet 1 comprises a first wall 11 through which water is introduced and a second wall 14 through which the beverage is dispensed.

在圖式所表示的囊包1係特別設計以在內部儲存咖啡粉並透過一施配機產生咖啡飲料。然而食品或飲料成分可係另一類型,例如選自下列列表中之呈液體、半液體、或粉末形式、不論是呈不溶、可萃取或可溶形式之可溶食品或飲料成分: The sachet 1 shown in the drawings is specially designed to store coffee grounds inside and to produce coffee beverages through a dispenser. However, the food or beverage ingredient may be of another type, such as a soluble food or beverage ingredient in liquid, semi-liquid, or powder form, whether in insoluble, extractable or soluble form, selected from the following list:

-乳粉或液體濃縮物(例如,牛奶); - milk powder or liquid concentrate (eg, milk);

-巧克力類成分; - Chocolate ingredients;

-水果粉; - fruit powder;

-水果果汁粉; - fruit juice powder;

-食用可溶纖維; - eating soluble fiber;

-葉類植物(茶、薄荷、香草等); - Leafy plants (tea, mint, herbs, etc.);

-根(薑、薑黃等); - roots (ginger, turmeric, etc.);

-調味劑; - flavoring agents;

-維生素; - vitamins;

-礦物質; - Minerals;

-蛋白質; -protein;

-益生菌; -Probiotics;

或其組合。 or a combination thereof.

囊包1係由可堆肥材料製成。具體而言,囊包1係可「工業」堆肥或「家庭」堆肥的。 The bag 1 is made of compostable material. Specifically, Bag 1 is "industrial" compostable or "home" compostable.

因此囊包1係由一或數個可堆肥多層材料製成。換言之,所有囊包的壁係由相同的可堆肥多層材料製成,或不同的可堆肥多層材料係用於囊包的壁。 The bag 1 is thus made of one or several compostable multi-layer materials. In other words, the walls of all pouches are made of the same compostable multi-layer material, or different compostable multi-layer materials are used for the walls of the pouches.

一或數個多層材料包含至少一紙層及至少一聚合物障壁層。 The one or more multilayer materials include at least one paper layer and at least one polymeric barrier layer.

可取決於所欲機械性質選定用於紙層的紙材料。 The paper material for the paper layer can be selected depending on the desired mechanical properties.

紙層可選定為例如可成形的,即可拉伸的。其可係機械或化學紙。 The paper layer may be selected to be, for example, formable, ie stretchable. It can be mechanical or chemical paper.

紙層較佳地係由牛皮紙(Kraft paper)製成。除了牛皮紙的機械性質之外,因為是棕色所以其為囊包提供呈可堆肥之視覺態樣。 The paper layer is preferably made of Kraft paper. In addition to the mechanical properties of kraft paper, because it is brown, it provides the bag with a compostable visual aspect.

紙層可係食品安全的。例如,紙層可係根據BFR的食品接觸材料建議(BFR Recommendations on Food Contact Materials)的BFR-36.1。 The paper layer may be food safe. For example, the paper layer may be BFR-36.1 according to BFR Recommendations on Food Contact Materials.

亦可選擇紙層材料以順應某些溫度需求。例如,可選定紙層以實現在高溫度(60℃至100℃)下的萃取。當然,可選定相同的紙材料以實現囊包成分之冷水萃取、或環境溫度水萃取或溶解的利用。 Paper layer materials can also be selected to accommodate certain temperature requirements. For example, the paper layer can be selected to enable extraction at high temperatures (60°C to 100°C). Of course, the same paper material can be selected to enable cold water extraction of the encapsulated components, or ambient temperature water extraction or dissolution utilization.

較佳地,紙層構成囊包之一或數個多層材料的至少50%。 Preferably, the paper layer constitutes at least 50% of one or more of the multiple layers of material of the sachet.

紙層可具有例如介於40gsm與150gsm(每平方公尺克數)之間的克重。較佳地,紙層具有60gsm之克重。 The paper layer may have, for example, a grammage between 40 gsm and 150 gsm (grams per square meter). Preferably, the paper layer has a grammage of 60 gsm.

聚合物障壁層應理解為經組態以保護囊包中之飲料成分的層,並提供良好的保存期限,以及為消費者提供杯中新鮮及高品質的產品。 A polymeric barrier layer should be understood as a layer configured to protect the beverage ingredients in the sachet and provide a good shelf life, as well as provide the consumer with a fresh and high quality product in the cup.

較佳地,聚合物障壁層係對液體、氣體(具體而言氧氣)、及濕氣的障壁。此保護對於飲料成分而言是重要的,特別是對濕氣所引起的氧化及劣化非常敏感的咖啡。 Preferably, the polymer barrier layer is a barrier to liquids, gases (specifically oxygen), and moisture. This protection is important for beverage ingredients, especially coffee, which is very sensitive to moisture-induced oxidation and degradation.

聚合物障壁層具有包含在10微米與100微米之間的厚度。較佳地,聚合物障壁之厚度係包含在20微米與50微米之間。 The polymer barrier layer has a thickness comprised between 10 and 100 microns. Preferably, the thickness of the polymer barrier is comprised between 20 microns and 50 microns.

聚合物障壁之厚度經設計以在對囊包中之飲料成分的保護與對飲料製備機之穿刺元件的抵抗性之間取得平衡。確實,聚合物障壁層不應太難或太簡單被穿刺元件所刺穿。 The thickness of the polymer barrier is designed to balance the protection of the beverage ingredients in the sachet with resistance to the piercing elements of the beverage maker. Indeed, the polymer barrier layer should not be too difficult or too easy to pierce by the piercing element.

較佳地,聚合物障壁層係一塑膠層壓體。 Preferably, the polymer barrier layer is a plastic laminate.

塑膠層壓體可包含夾在兩個聚合物片材之間的丁二醇乙烯醇(Vinyl Alcohol,BVOH)片材。BVOH片材係以連結片材(tie sheet)在兩側上附接至聚合物片材。 The plastic laminate may comprise a sheet of butanediol vinyl alcohol (BVOH) sandwiched between two polymer sheets. The BVOH sheet is attached to the polymer sheet on both sides with tie sheets.

聚合物片材包含聚乳酸(polylactic acid,PLA)、聚丁二酸丁二醇酯(Polybutylene succinate,PBS)、及聚己二酸對苯二甲酸丁二酯(polybutylene adipate terephthalate,PBAT)之混合物。 The polymer sheet comprises a mixture of polylactic acid (PLA), polybutylene succinate (PBS), and polybutylene adipate terephthalate (PBAT). .

聚合物片材可由Ecovio®(可商購自BASF,具體而言係Ecovio® 40 FS23N1 EXP)製成。 The polymer sheet can be made from Ecovio® (commercially available from BASF, specifically Ecovio® 40 FS23N1 EXP).

在其他實施例中,聚合物片材可係澱粉基(starch based)的。 In other embodiments, the polymer sheet may be starch based.

BVOH片材可由Nichigo G-PolymerTM(Nippon Goshei)製成。 BVOH sheets can be made from Nichigo G-Polymer (Nippon Goshei).

「連結片材(tie sheet)」係指將聚合物片材接合至BVOH片材之聚合物層。一般使用連結片材來生產具有至少三個共擠製層或片材之材料。連結片材可由一黏著劑樹脂製成,該黏著劑樹脂包括經酸酐改質之聚合物樹脂,諸如BTR-8002P(Nippon Gohsei)。 "Tie sheet" refers to the polymer layer that joins the polymer sheet to the BVOH sheet. Linked sheets are typically used to produce materials having at least three coextruded layers or sheets. The connecting sheet can be made of an adhesive resin including an acid anhydride modified polymer resin such as BTR-8002P (Nippon Gohsei).

紙層及聚合物障壁層彼此附接以諸如在其間呈現至少等於根據標準ASTM F904之在22℃下之1.6N/15mm及在100℃下之0.22N/15mm的接合強度。 The paper layer and the polymer barrier layer are attached to each other such as to exhibit therebetween a bond strength at least equal to 1.6 N/15mm at 22°C and 0.22N/15mm at 100°C according to standard ASTM F904.

ASTM F904係稱為「用於比較由可撓性材料製成之類似層壓體的接合強度或層黏著性的標準測試方法(Standard Test Method for Comparison of Bond Strength or Ply Adhesion of Similar Laminates Made from Flexible Materials)」之標準的國際名稱。如此標準所解釋,「此測試方法涵蓋比較由可撓性材料(諸如纖維素、紙、塑膠膜、及箔)製成之類似層壓體的接合強度或層黏著性的程序。此包括藉由下列各種程序製成之層壓體:黏著劑層壓、擠製塗層、擠製層壓、及共擠製。」 ASTM F904 is called " Standard Test Method for Comparison of Bond Strength or Ply Adhesion of Similar Laminates Made from Flexible Materials". Materials) " standard international name. As explained in this standard, "This test method covers a procedure for comparing the bond strength or layer adhesion of similar laminates made of flexible materials such as cellulose, paper, plastic films, and foils. This includes the use of Laminates produced by the following procedures: adhesive lamination, extrusion coating, extrusion lamination, and coextrusion.”

1,6N/15mm之結合強度的最小值應理解為如在22℃及50%相對濕度下所測量,其對應於標準測試條件(standard test condition)。如標準中所解釋者,測試係在23±2℃(73.4±3.6℉)及50±5%相對濕度的標準實驗室大氣中所進行。 The minimum value of the bond strength of 1,6 N/15mm is to be understood as being measured at 22° C. and 50% relative humidity, which corresponds to standard test conditions. As explained in the standard, the test is performed in a standard laboratory atmosphere of 23±2°C (73.4±3.6°F) and 50±5% relative humidity.

0.22N/15mm之結合強度的最小值應理解為如在100℃及50%相對濕度下所測量。 The minimum value of the bond strength of 0.22N/15mm is understood to be as measured at 100°C and 50% relative humidity.

此外,接合強度的值應理解為用具有在標準中所呈現之參數及設定的機器所測量。具體而言,夾具距離係25,4mm,且測試速度係280mm/min±10%。 Furthermore, the value of joint strength is understood to be measured with a machine having the parameters and settings presented in the standard. Specifically, the jig distance was 25,4mm, and the test speed was 280mm/min±10%.

接合強度係預防脫層的關鍵參數。脫層可出於各種原因而發生,諸如在囊包內的過壓。過壓可由排氣產生,即由飲料成分產生氣體直到其從囊包被萃取,換言之在儲存期間內。過壓亦可為高度變化的結果。具體而言,囊包可在位於一特定高度的工廠中填充及密封,然後在一更高的高度運輸以用於銷售及/或使用。 Bond strength is a key parameter for preventing delamination. Delamination can occur for various reasons, such as overpressure within the capsule. Overpressure can be created by degassing, ie by the beverage ingredients until they are extracted from the capsule, in other words during storage. Overvoltage can also be the result of height variations. Specifically, the pouches can be filled and sealed at a factory at a specific height, and then shipped at a higher height for sale and/or use.

因此,良好的接合確保在儲存期間,若過壓發生,或者若囊包在儲存期間遭受任何類型的機械應力,該囊包不裂開。 Thus, a good engagement ensures that during storage, if overpressure occurs, or if the capsule is subjected to any type of mechanical stress during storage, the capsule does not rupture.

在一實施例中,紙層及聚合物障壁層係藉由一黏著劑層彼此附接。 In one embodiment, the paper layer and the polymer barrier layer are attached to each other by an adhesive layer.

較佳地,黏著劑層覆蓋紙層及聚合物障壁層之各者的一側。 Preferably, the adhesive layer covers one side of each of the paper layer and the polymer barrier layer.

黏著劑層呈現一均質厚度。換言之,在黏著劑層中應無過量或減少的厚度。此改善介於紙層與聚合物障壁層之間的接合。 The adhesive layer exhibits a uniform thickness. In other words, there should be no excess or reduced thickness in the adhesive layer. This improves the bond between the paper layer and the polymer barrier layer.

較佳地,黏著劑層呈現介於1微米與20微米之間的厚度。 Preferably, the adhesive layer exhibits a thickness between 1 and 20 microns.

較佳地,黏著劑層呈現聚酯-聚胺甲酸酯彈性體在水中之一濃度。 Preferably, the adhesive layer exhibits a concentration of polyester-polyurethane elastomer in water.

黏著劑層係例如以包含在2g/m2與15g/m2之間的施用重量施用。 The adhesive layer is applied, for example, at an application weight comprised between 2 g/m 2 and 15 g/m 2 .

較佳地,黏著劑層係由Epotal® ECO 3702(BASF)製成。Epotal® ECO 3702係聚酯-聚胺甲酸酯彈性體之水性分散液。在參考第WO2012/013506號中公開之PCT專利申請案揭示此類黏著劑層的組成物。 Preferably, the adhesive layer is made of Epotal® ECO 3702 (BASF). Epotal® ECO 3702 is an aqueous dispersion of polyester-polyurethane elastomer. The composition of such an adhesive layer is disclosed in the PCT patent application published with reference to No. WO2012/013506.

黏著劑層可進一步包含一硬化劑。硬化劑具體地可用於聚合物分散液。硬化劑可係例如Basonat LR 9056。 The adhesive layer may further include a hardener. Hardeners are particularly useful for polymer dispersions. The hardener can be, for example, Basonat LR 9056.

例如,黏著劑層包含Epotal® ECO 3702及以介於1%與10%之間的百分比(例如3%)添加之Basonat LR 9056。 For example, the adhesive layer comprises Epotal® ECO 3702 and Basonat LR 9056 added at a percentage between 1% and 10% (eg 3%).

可設想到其他黏著劑諸如: Other adhesives such as:

- BioTAK® S500,其係基於特別改質之聚酯共聚物的水性黏著劑; - BioTAK® S500, an aqueous adhesive based on a specially modified polyester copolymer;

- Morchem PS 255 ECO+CS-95,其係基於聚胺甲酸酯溶劑之雙組分黏著劑; - Morchem PS 255 ECO+CS-95, a two-component adhesive based on polyurethane solvent;

- ADCOTETM BL1001黏著劑/BCR 1001,其係雙組分非晶質聚合物; - ADCOTE TM BL1001 Adhesive/BCR 1001, which is a two-component amorphous polymer;

- Scitech ST6093G及ST60097,其等係水性雙組分黏著劑; - Scitech ST6093G and ST60097, which are water-based two-component adhesives;

- Epotal® P100 ECO聚酯-聚胺甲酸酯彈性體水性雙組分黏著劑。 - Epotal® P100 ECO polyester-polyurethane elastomer waterborne two-component adhesive.

一或數個可堆肥多層材料可進一步包含聚合可堆肥材料之保護層。保護層防止紙堵塞飲料機。確實,紙的小部分可能脫離並堵塞飲料機,且具體而言堵塞穿刺元件。 One or more of the compostable multilayer materials may further comprise a protective layer of polymeric compostable material. The protective layer prevents the paper from clogging the beverage machine. Indeed, a small part of the paper may come off and block the beverage maker, and in particular the piercing element.

聚合可堆肥材料可係例如再生纖維素,具體而言係CellophaneTMThe polymeric compostable material may be, for example, regenerated cellulose, specifically Cellophane .

較佳地,保護層係防潑水的。 Preferably, the protective layer is water repellent.

保護層係附接至可堆肥多層材料的其他層,且具體而言係附接至具有黏著劑層之紙層。換言之,一或數個可堆肥多層材料進一步包含一第二黏著劑層,以將保護層及紙層接合在一起。 The protective layer is attached to the other layers of the compostable multilayer material, and in particular to the paper layer with the adhesive layer. In other words, the one or more compostable multilayer materials further comprise a second adhesive layer to bond the protective layer and the paper layer together.

第二黏著劑層可與上文所述之黏著劑層相同,並將紙層與聚合物障壁層接合在一起。 The second adhesive layer can be the same as the adhesive layer described above and joins the paper layer and the polymer barrier layer together.

一或數個多層材料可進一步包含在其表面之一者上的油墨印刷。具體而言,一或數個多層材料可進一步包含在保護層上的油墨印刷。油墨印刷較佳地係食品安全的。 One or more of the multilayer materials may further include ink printing on one of its surfaces. In particular, one or more of the multilayer materials may further comprise ink printing on the protective layer. The ink printing is preferably food safe.

當然,一或數個多層材料可包含在除保護層外之層上的油墨印刷。一或數個多層材料可包含在紙層上及/或在該保護層之外部表面上的油墨印刷。 Of course, one or more of the multilayer materials may include ink printing on layers other than the protective layer. One or more multilayer materials may comprise ink printing on the paper layer and/or on the outer surface of the protective layer.

油墨印刷可例如用於供使用者適當地閱讀關於囊包及/或飲料成分的資訊之插圖印刷。 Ink printing can be used, for example, for illustration printing for the user to properly read information about the sachets and/or beverage ingredients.

油墨印刷亦可係一OID印刷(即光學識別印刷),其可由飲料機感測用於自動設定參數或類似者。 Ink printing can also be an OID printing (ie optical identification printing) which can be sensed by the beverage machine for automatic parameter setting or the like.

當然,一或數個多層材料可包含複數個及各式各樣油墨印刷,例如插圖及OID印刷兩者。 Of course, one or more of the multilayer materials may include multiple and various ink prints, such as both illustrations and OID prints.

在具有油墨印刷時使用再生纖維素作為保護層係有利的,因為纖維素擁有良好的可印刷性、透明度、及可讀性的印刷品質。 The use of regenerated cellulose as a protective layer is advantageous when printing with inks because cellulose possesses good printability, transparency, and readability print qualities.

下表根據本發明提供用於囊包的可堆肥多層材料之實施例。表的第一行(「保護層」)對應於與外部大氣接觸之囊包的外側層,而表的最後一行(「聚合物障壁層」)對應於與其中所含成分接觸之囊包的最內層。各行按從囊包壁之最外層至最內層之順序提供各種層。 The following table provides examples of compostable multilayer materials for pouches in accordance with the present invention. The first row of the table ("protective layer") corresponds to the outer layer of the capsule in contact with the external atmosphere, while the last row of the table ("polymer barrier layer") corresponds to the outermost layer of the capsule in contact with the ingredients contained therein inner layer. Each row provides the various layers in order from the outermost to the innermost layer of the capsule wall.

Figure 110125524-A0202-12-0015-1
Figure 110125524-A0202-12-0015-1

下表提供用於囊包的可能可堆肥多層材料之更具體(即特定)實例,其中用於不同層之材料係引用可購自市場之其等商業名稱。以下兩個表中的參考層對應於呈現於先前表中之實施例中的材料之具體實例。 The following table provides more specific (ie specific) examples of possible compostable multi-layer materials for the pouch, where the materials used for the different layers refer to their commercially available commercial names. The reference layers in the following two tables correspond to specific examples of materials presented in the examples in the previous tables.

可堆肥多層材料1: Compostable Multilayer Material 1:

Figure 110125524-A0202-12-0015-2
Figure 110125524-A0202-12-0015-2

Figure 110125524-A0202-12-0016-3
Figure 110125524-A0202-12-0016-3

可堆肥多層材料2: Compostable Multilayer Material 2:

Figure 110125524-A0202-12-0016-4
Figure 110125524-A0202-12-0016-4

當然,其他組合亦係可能的。此外,可移除或添加一些層,諸如保護層及印刷。 Of course, other combinations are also possible. Additionally, some layers, such as protective layers and printing, may be removed or added.

此外,在所提供之實例中,聚合物障壁多層較佳地係對稱地成形。具體而言,兩個聚合物層(在上文實例中的Ecovio®)兩者係類似的。類似地,兩個連結層(在上文實例中的BTR-8002P)兩者係類似的。然而,在另一實施例中,聚合物障壁多層可包含兩個不同的聚合物層及/或兩個不同的連結層。 Furthermore, in the examples provided, the polymeric barrier layers are preferably symmetrically shaped. Specifically, the two polymer layers (Ecovio® in the above example) are both similar. Similarly, the two tie layers (BTR-8002P in the above example) are both similar. However, in another embodiment, the polymer barrier multilayer may comprise two different polymer layers and/or two different tie layers.

如上文所述,囊包1係由一或數個可堆肥多層材料製成。可在上述表中所提供的實例(「可堆肥材料1」或「可堆肥材料2」)內選擇一或數個可堆肥多層材料。 As mentioned above, the sachet 1 is made of one or several compostable multi-layer materials. One or more compostable multi-layer materials may be selected from the examples provided in the above table ("Compostable Material 1" or "Compostable Material 2").

如進一步所述,根據圖1圖2之實施例的囊包1包含用於其不同壁的兩種不同多層材料,而根據圖3之實施例的囊包係由用於所有囊包壁的相同可堆肥多層材料製成。 As further described, the sachet 1 according to the embodiment of Figs. 1 and 2 comprises two different multilayer materials for its different walls, whereas the sachet 1 according to the embodiment of Fig. 3 is composed of one for all sachet walls. Made of the same compostable multi-layer material.

在任何情況中,囊包在其形狀上可係對稱或不對稱的,與其壁之各者的組成物無關。 In any event, the capsule may be symmetrical or asymmetrical in its shape, regardless of the composition of each of its walls.

1及圖2所表示之實施例中,囊包1包含本體10及閉合蓋14。閉合蓋14覆蓋本體10,使得囊包1完全閉合。本體10與閉合蓋14形成內部容積,飲料成分儲存在內部容積中。 In the embodiment shown in FIGS. 1 and 2 , the bag 1 includes a main body 10 and a closure cover 14 . The closure cover 14 covers the body 10 so that the bag 1 is completely closed. The body 10 and the closure lid 14 form an interior volume in which the beverage ingredients are stored.

本體10具有三維形狀。三維形狀應意指該本體「成形(formed)」,或換言之,該本體係非平坦的。主體10具有圍繞一旋轉軸延伸的截頭圓錐形狀(frustoconical shape)。 The body 10 has a three-dimensional shape. Three-dimensional shape shall mean that the body is "formed", or in other words, that the body is not flat. The main body 10 has a frustoconical shape extending around an axis of rotation.

囊包1相對於與閉合蓋14平行之平面係不對稱的。 The sachet 1 is asymmetrical with respect to a plane parallel to the closure lid 14 .

本體10具有一底壁11及一側壁12。側壁12可實質上垂直於底壁11延伸。本體10包含環繞側壁12的一周圍邊緣13。較佳地,底壁11、側壁12、及周圍邊緣13係由一單件製成。 The body 10 has a bottom wall 11 and a side wall 12 . The side wall 12 may extend substantially perpendicular to the bottom wall 11 . The body 10 includes a peripheral edge 13 surrounding the side wall 12 . Preferably, the bottom wall 11, the side walls 12, and the peripheral edge 13 are made from a single piece.

閉合蓋14係平坦的。詞「平坦(flat)」應意指閉合蓋14實質上在一個平面上延伸。換言之,閉合蓋14在一個平面上延伸,但其可在一凸平面或凹平面上變形,取決於囊包之內部與外部之間的相對壓力。具體而言,可發生的是在其中所含之成分(例如烘焙與研磨咖啡)在囊包的儲存期間內將產生氣體,諸如二氧化碳。在此情況下,過壓可在囊包內產生,其迫使(起初為平坦的)頂蓋膨向外側。亦可發生的是,例如若囊包係在接近海平面的工廠處成形、填充、及密封, 且接著所述囊包在大氣壓力較低的一較高高度運輸,則圍繞囊包的大氣壓力改變。在此類情況下,(起初為平坦的)頂蓋將以凹狀向內凹。 The closure cap 14 is flat. The word "flat" shall mean that the closure lid 14 extends substantially in one plane. In other words, the closure cap 14 extends in one plane, but it can deform in a convex or concave plane, depending on the relative pressure between the inside and the outside of the bag. In particular, it may happen that the ingredients contained therein, such as roast and ground coffee, will generate gases, such as carbon dioxide, during storage of the pouches. In this case, an overpressure can develop within the capsule, which forces the (initially flat) cap to expand outward. It can also happen, for example, if the bag is formed, filled, and sealed at a factory near sea level, And then the capsule is transported at a higher altitude where atmospheric pressure is lower, the atmospheric pressure surrounding the capsule changes. In such cases, the (initially flat) cap will be concave inward.

閉合蓋14係密封於本體10上。在所描述之實施例中,閉合蓋14係密封於周圍邊緣13上。閉合蓋14緊密地適配本體10,使得確保囊包1的完全密封。 The closing cover 14 is sealed on the main body 10 . In the described embodiment, the closure cap 14 is sealed to the peripheral edge 13 . The closure cap 14 fits tightly to the body 10 such that a complete sealing of the sachet 1 is ensured.

較佳地,本體10係由一第一可堆肥多層材料製成,且閉合蓋14係由一第二可堆肥多層材料製成。 Preferably, the body 10 is made of a first compostable multilayer material, and the closure lid 14 is made of a second compostable multilayer material.

本體10之第一可堆肥多層材料較佳地同時是允許藉由飲料機的穿刺元件適當地開口的材料也是一可拉伸材料。 The first compostable multilayer material of the body 10 is preferably also a stretchable material at the same time as the material that allows for proper opening by the piercing element of the beverage maker.

事實上,在機器中的飲料製作期間,透過主體10將水引入。水透過底壁11注入,該底壁形成如上文所定義之第一壁,或注入側。為了飲料成分(特別是咖啡)的良好萃取品質,發現到藉由機器之針頭的手段將囊包1開口必須順暢且容易。 In fact, during beverage making in the machine, water is introduced through the body 10 . Water is injected through the bottom wall 11, which forms the first wall, or injection side, as defined above. For good extraction quality of beverage ingredients (especially coffee), it was found that the opening of the sachet 1 by means of the needle of the machine must be smooth and easy.

此外,本體10係自一平坦胚料開始成形,其經拉伸並給予一形狀。使用可拉伸材料用於本體10允許在本體成形期間所需的拉伸,而不斷裂或撕裂。此外,由於可拉伸材料,對主體10給予所欲形狀及尺寸係可能的。例如,材料越可拉伸,本體越可能延長且本體之尺寸越可能延伸。 Furthermore, the body 10 is formed from a flat blank that is stretched and given a shape. The use of a stretchable material for the body 10 allows for the desired stretching during body formation without breaking or tearing. Furthermore, due to the stretchable material, it is possible to give the body 10 any desired shape and size. For example, the more stretchable the material, the more likely the body is to elongate and the more likely the dimensions of the body are to extend.

在此實施例中,囊包本體10的這些性質係由上表中所呈現的可堆肥多層材料1所提供。當然,在其他實施例中,層可由其他材料取代,具體而言係由本文件中所描述及呈現之材料取代。 In this embodiment, these properties of the pouch body 10 are provided by the compostable multilayer material 1 presented in the table above. Of course, in other embodiments, the layers may be replaced by other materials, particularly those described and presented in this document.

閉合蓋之第二可堆肥多層材料較佳地係一種能用一小的伸長(elongation)實現瞬間或突然的破裂之材料。 The second compostable multi-layer material of the closure is preferably a material capable of instantaneous or sudden rupture with a small elongation.

在機器中的飲料製作期間,飲料係透過如上文所定義之形成第二壁的封蓋14所施配。在將水注入囊包內部後,囊包內部產生水壓,促使成分膨脹及囊包內部容積擴張。囊包1之施配側(即,閉合蓋14)因此被壓向機器之施配結構。閉合蓋由例如機器之截頭角錐體所刺穿。 During beverage making in the machine, the beverage is dispensed through the lid 14 forming the second wall as defined above. After the water is injected into the inside of the bag, water pressure is generated inside the bag, which promotes the expansion of the components and the expansion of the internal volume of the bag. The dispensing side of the packet 1 (ie the closure lid 14) is thus pressed against the dispensing structure of the machine. The closure cap is pierced by eg a frustum of a machine.

為了囊包的適當開口及飲料成分(特別是咖啡)的完好,發現到施配側的開口(此處指閉合蓋)應瞬間實現(由突然的破裂所導致)。閉合蓋應在刺穿時撕裂,但不延伸。 For proper opening of the capsule and integrity of the beverage ingredients (especially coffee), it was found that the opening to the dispensing side (here the closure lid) should be instantaneous (caused by a sudden rupture). The closure cap should tear on piercing, but not extend.

閉合蓋14的這些性質係由上表中上文所呈現的多層材料2所提供。當然,在替代實施例中,層可由其他材料取代,從本文件中所描述及呈現者中選擇。 These properties of the closure cap 14 are provided by the multilayer material 2 presented above in the table above. Of course, in alternative embodiments, the layers may be replaced by other materials, selected from those described and presented in this document.

圖3之實施例中,囊包1包含一第一壁11及一第二壁14。第一壁11及所述第二壁14相對於彼此密封,並在其等之間界定內部容積。 In the embodiment of FIG. 3 , the bag 1 includes a first wall 11 and a second wall 14 . The first wall 11 and said second wall 14 are sealed relative to each other and define an internal volume therebetween.

囊包1呈現馬卡龍(macaroon)的形式。第一壁11及第二壁14之重力點的平分平面(bisector plane)因此亦為囊包1的平分平面。 The pouch 1 is in the form of a macaroon. The bisector plane of the point of gravity of the first wall 11 and the second wall 14 is therefore also the bisector plane of the bag 1 .

第一壁11及第二壁14可在形狀與組成物上彼此相同。具體而言,第一壁11及第二壁14兩者係由相同的可堆肥多層材料製成。 The first wall 11 and the second wall 14 may be identical to each other in shape and composition. Specifically, both the first wall 11 and the second wall 14 are made of the same compostable multilayer material.

較佳地,囊包1之可堆肥多層材料與參照圖1圖2之先前描述實施例中之本體10的第一材料呈現相同性質。換言之,製成圖3之囊包1的可堆肥多層材料係例如上表中所呈現的可堆肥多層材料1之一者。 Preferably, the compostable multilayer material of the sachet 1 exhibits the same properties as the first material of the body 10 in the previously described embodiment with reference to FIGS. 1 and 2 . In other words, the compostable multilayer material from which the pouch 1 of FIG. 3 is made is, for example, one of the compostable multilayer materials 1 presented in the table above.

因此,本發明提出具有令人感興趣之機械性質的一可堆肥囊包,該等機械性質具體而言係關於儲藏期間的保存、對機械應力的抵抗性、及可成形性。 Accordingly, the present invention proposes a compostable pouch having interesting mechanical properties, in particular with regard to preservation during storage, resistance to mechanical stress, and formability.

當然,在替代例中,第一壁11及第二壁14之各者的可堆肥多層材料的組成物之間可能有一些差異。 Of course, in alternative examples, there may be some differences between the composition of the compostable multilayer material of each of the first wall 11 and the second wall 14 .

應理解,對本文所述的目前較佳實施例的各種變更及修改將為所屬技術領域中具有通常知識者明顯易懂的。可在不偏離本發明的精神與範疇且不減損其伴隨之優點的情況下進行此種變更及修改。因此此種變更及修改並不脫離隨附請求項的規範。 It should be understood that various changes and modifications to the presently preferred embodiments described herein will be apparent to those of ordinary skill in the art. Such changes and modifications can be made without departing from the spirit and scope of the invention and without detracting from its attendant advantages. Therefore, such changes and modifications do not deviate from the specifications of the appended claims.

1:囊包、可堆肥多層材料 1: bag, compostable multi-layer material

10:本體 10: Ontology

11:第一壁、底壁 11: The first wall, the bottom wall

12:側壁 12: Sidewall

14:第二壁、閉合蓋 14: Second wall, closing cover

Claims (15)

一種具有一內部容積之囊包,其中一飲料成分儲存在該內部容積中且當將水引入內部時產生一飲料,該囊包(1)包含一第一壁(11)及一第二壁(14),水透過該第一壁引入且該飲料透過該第二壁施配,該囊包(1)係由一或數個可堆肥多層材料製成,其特徵在於:該一或數個多層材料之各者包含至少一紙層及至少一聚合物障壁層,該至少一紙層及該至少一聚合物障壁層係藉由一黏著劑層彼此附接,或藉由該障壁層至該紙層的擠製塗布而彼此附接,諸如以至少等於在22℃下1.6N/15mm及在100℃下0.22N/15mm的接合強度將其等接合,該至少一聚合物障壁層具有包含在10微米與100微米之間的厚度。 A sachet having an internal volume in which a beverage ingredient is stored and which produces a beverage when water is introduced into the interior, the sachet (1) comprising a first wall (11) and a second wall ( 14), the water is introduced through the first wall and the beverage is dispensed through the second wall, the sachet (1) is made of one or more compostable multi-layer materials, characterized in that: the one or more layers Each of the materials comprises at least one paper layer and at least one polymer barrier layer, the at least one paper layer and the at least one polymer barrier layer being attached to each other by an adhesive layer, or by the barrier layer to the paper Extrusion coating of layers attached to each other, such as bonding them with a bond strength at least equal to 1.6N/15mm at 22°C and 0.22N/15mm at 100°C, the at least one polymer barrier layer having a thickness of 10 Thickness between microns and 100 microns. 如請求項1之囊包,其中該黏著劑層係可家庭堆肥的(home compostable)。 The pouch of claim 1, wherein the adhesive layer is home compostable. 如請求項1或2中任一項之囊包,其中該黏著劑層係以包含在2g/m2與15g/m2之間的施用重量施用。 The sachet of any one of claims 1 or 2, wherein the adhesive layer is applied at an application weight comprised between 2 g/m 2 and 15 g/m 2 . 如請求項1至3中任一項之囊包,其中該黏著劑層係由Epotal® ECO 3702製成。 The sachet of any one of claims 1 to 3, wherein the adhesive layer is made of Epotal® ECO 3702. 如請求項1至4中任一項之囊包,其中該聚合物障壁層係一塑膠層壓體,該塑膠層壓體包含夾在兩個聚合物片材之間的丁二醇乙烯醇(Butenediol Vinyl Alcohol,BVOH)片材,該等BVOH片材係以連結片 材在兩側附接至該等聚合物片材,該等聚合物片材包含下列聚合物,該等聚合物係選自由以下所組成之群組:聚乳酸(polylactic acid,PLA)、聚丁二酸丁二醇酯(Polybutylene succinate,PBS)、及例如聚己二酸對苯二甲酸丁二酯(polybutylene adipate terephthalate,PBAT)之脂肪族-芳香族聚酯,或此等聚合物之混合物。 The sachet of any one of claims 1 to 4, wherein the polymer barrier layer is a plastic laminate comprising butylene glycol vinyl alcohol ( Butenediol Vinyl Alcohol, BVOH) sheets, these BVOH sheets are The material is attached on both sides to the polymer sheets comprising the following polymers selected from the group consisting of: polylactic acid (PLA), polybutylene Polybutylene succinate (PBS), and aliphatic-aromatic polyesters such as polybutylene adipate terephthalate (PBAT), or mixtures of these polymers. 如請求項5之囊包,其中該連結片材係由一黏著劑樹脂製成,該黏著劑樹脂包括經酸酐改質之聚合物樹脂。 The bag of claim 5, wherein the connecting sheet is made of an adhesive resin, and the adhesive resin includes an acid anhydride-modified polymer resin. 如請求項1至6中任一項之囊包,其中該一或數個多層材料進一步包含一聚合可堆肥材料之一保護層。 The sachet of any one of claims 1 to 6, wherein the one or more multilayer materials further comprise a protective layer of a polymeric compostable material. 如請求項7之囊包,其中該聚合可堆肥材料係再生纖維素。 The sachet of claim 7, wherein the polymeric compostable material is regenerated cellulose. 如請求項1至8中任一項之囊包,其中該一或數個多層材料進一步包含在其表面之一者上的一油墨印刷。 The pouch of any one of claims 1 to 8, wherein the one or more multilayer materials further comprise an ink print on one of its surfaces. 如請求項1至9中任一項之囊包,其中至少一多層材料包含: The bag of any one of claims 1 to 9, wherein at least one of the layers of material comprises: 一紙層,其具有包含在40gsm與130gsm之間的克重; a paper layer having a grammage comprised between 40gsm and 130gsm; 一第一黏著劑層,其係由Epotal® ECO 3702製成,且其係以包含在2g/m2與15g/m2之間的施用重量施用;及 a first adhesive layer, which is made of Epotal® ECO 3702, and which is applied at an application weight comprised between 2 g/m 2 and 15 g/m 2 ; and 一聚合物障壁層,其係由如請求項5或6中任一項之塑膠層壓體製成,該等聚合物片材係由Ecovio® 40 FS23N1 EXP製成且具有包含在10微米與30微米之間的厚度,該等連結片材之各者 係以包含在2g/m2與8g/m2之間的施用重量施用。 A polymer barrier layer made of a plastic laminate as claimed in any one of claims 5 or 6, the polymer sheets made of Ecovio® 40 FS23N1 EXP and having 10 microns and 30 Thicknesses between microns, each of the linked sheets is applied at an application weight comprised between 2 g/m 2 and 8 g/m 2 . 如請求項10之囊包,其中該至少一多層材料進一步包含: The bag of claim 10, wherein the at least one multilayer material further comprises: 一保護層,其係由玻璃紙(cellophane)製成且具有包含在10微米與50微米之間的厚度,該保護層包含在其表面之一者上的一油墨印刷;及 a protective layer made of cellophane and having a thickness comprised between 10 microns and 50 microns, the protective layer comprising an ink print on one of its surfaces; and 一第二黏著劑層,其將該紙層附接至該黏著劑層,該第二黏著劑層係由Epotal® ECO 3702製成,且係以包含在2g/m2與15g/m2之間的施用重量施用。 A second adhesive layer, which attaches the paper layer to the adhesive layer, the second adhesive layer is made of Epotal® ECO 3702 and is contained between 2g /m2 and 15g/ m2 between application weights. 如請求項1至11中任一項之囊包,其中該囊包(1)包含一本體(10),該本體具有一底壁(11)及一閉合蓋(14),水透過該底壁引入且該飲料透過該閉合蓋施配,該閉合蓋(14)密封於該本體上並在其等之間界定該內部容積,該本體(10)係由一第一多層材料製成且該閉合蓋(14)係由不同於該本體之該第一多層材料的一第二多層材料製成。 The bag of any one of claims 1 to 11, wherein the bag (1) comprises a body (10) having a bottom wall (11) and a closing lid (14) through which water permeates Introduced and the beverage dispensed through the closure lid (14) sealed on the body and defining the interior volume therebetween, the body (10) being made of a first multilayer material and the The closure lid (14) is made of a second multilayer material different from the first multilayer material of the body. 如請求項12之囊包,其中該本體(10)係由如請求項10之該至少一多層材料製成,且該閉合蓋(14)係由如請求項11之該至少一多層材料製成。 The bag of claim 12, wherein the body (10) is made of the at least one multilayer material of claim 10, and the closure lid (14) is made of the at least one multilayer material of claim 11 production. 如請求項1至11中任一項之囊包,其中該第一壁(11)及該第二壁(14)相對於彼此密封並在其等之間界定該內部容積,該第一壁(11)及該第二壁(14)兩者係由相同的可堆肥多層材料製成。 The sachet of any one of claims 1 to 11, wherein the first wall (11) and the second wall (14) are sealed relative to each other and define the interior volume therebetween, the first wall ( 11) and the second wall (14) are both made of the same compostable multilayer material. 如請求項14之囊包,其中該第一壁(11)及該第二壁(14)兩者係由如請求項10之該至少一多層材料製成。 The bag of claim 14, wherein both the first wall (11) and the second wall (14) are made of the at least one multilayer material of claim 10.
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