發明概述
本發明涉及一種頭髮調理組合物，其包含橄欖角鯊烷、蠟、酯和化妝品可接受的載體。該組合物可以不含一種或多種選自矽酮、陰離子表面活性劑、醯氨基胺、矽酮衍生物、乙氧基化乳化劑及其混合物的組分。
發明詳述
儘管本說明書以特別指出和明確要求保護本發明的請求項書結束，但相信，由下列描述將更好地理解本發明。
除非另行規定，所有百分比、份數和比率基於本發明的組合物的總重量計。除非另行規定，涉及所列成分時，所有這樣的重量基於活性水準，因此不包括市售材料中可能包含的溶劑或副產物。術語“重量百分比”在本文中可標作“重量%”。
除非另行規定，本文所用的所有分子量是作為克/摩爾表示的重均分子量。
本文所用的術語“電荷密度”是指構成聚合物的單體單元上的正電荷數與所述單體單元的分子量的比率。電荷密度乘以聚合物分子量決定了給定聚合物鏈上的帶正電荷位元點的數目。
本文中，“包含”意指可以加入的不影響最終結果的其它步驟和其它成分。該術語包括術語“由……組成”和“基本上由……組成”。本發明的組合物和方法/過程可包含本文所述的本發明的基本要素和限制以及本文所述的任何附加或任選成分、組分、步驟或限制，由它們組成和基本上由它們組成。
本文所用的術語“聚合物”應包括由一種類型的單體聚合製成或由兩種(即共聚物)或更多種類型的單體製成的材料。
本文所用的術語“固體粒子”意指不是液體或氣體的粒子。
本文所用的術語“水溶性”是指該聚合物在本組合物中可溶於水。一般而言，該聚合物應該在25℃下在水溶劑的至少0.1重量%，優選至少1%，更優選至少5%，最優選至少15%的濃度下可溶。
本文所用的術語“水不溶性”是指化合物在本組合物中不溶於水。因此，該化合物與水不混溶。
本發明的個人護理組合物包含陽離子改性澱粉聚合物、陰離子表面活性劑體系和化妝品可接受的載體。在下文中詳細描述這些基本組分以及優選的或任選的組分中的每一種。橄欖角鯊烷
本文的組合物包含橄欖角鯊烯組分。角鯊烷是一種眾所周知的化妝品成分。例如，美國專利公開號2008-0274068公開了角鯊烯以及其它油性物質，其可用於改善乾燥後的頭髮易打理性。然而，現在已經發現，特定的角鯊烷不僅與其它油性化妝品成分，而且還與衍生自不同天然來源的角鯊烷表現不同。例如，角鯊烯可衍生自甘蔗，這對於以商品名Neossance®銷售的角鯊烯來說是真實的。角鯊烷也可以衍生自動物來源，如韓國專利號KR101417029所述。相比之下，橄欖角鯊烯衍生自橄欖油，並顯示對本文組合物的益處而言必不可少的獨特特徵。在一個實施方案中，橄欖角鯊烷以組合物的約0.01重量%至約20重量%，更優選約0.03重量%至約10重量%，並且最優選約0.05重量%至約2重量%存在。蠟
本文的組合物包含一種或多種蠟組分。合適的蠟的非限制性實例包括例如微晶蠟、石蠟、微晶蠟、地蠟、聚乙烯蠟、純地蠟、蜂蠟、小燭樹蠟、巴西棕櫚蠟、紫膠蠟、羊毛脂蠟、褐煤蠟、橙蠟、檸檬蠟、月桂蠟和橄欖蠟、蜂蠟及其混合物。特別優選的蠟包括小燭樹蠟、巴西棕櫚蠟和天然或合成蜂蠟。在一個實施方案中，蠟以組合物的約0.01重量%至約20重量%，更優選約0.03重量%至約10重量%，以及最優選約0.05重量%至約2重量%存在。此外，優選蠟組分的熔點為約68.5-72.5℃。酯潤膚劑
組合物包含一種或多種用作潤膚劑的酯。當用於處理人類頭髮時，酯增強組合物的感覺。優選地，所述酯是天然酯，其選自異硬脂酸甲基庚酯、二聚體二亞油酸二異硬脂酯、蘋果酸二異硬脂酯、檸檬酸三辛酯、異硬脂酸異硬脂酯、聚甘油-2三異硬脂酸酯、聚甘油-2二異硬脂酸酯、聚甘油-2異硬脂酸酯、蓖麻油酸甘油酯、棕櫚酸異硬脂酯、辛酸/癸酸甘油三酯、芒果脂二聚體二亞油酯/二聚體二亞油酸酯共聚物、肉豆蔻酸肉豆蔻酯、芥酸油酯、聚甘油-3二異硬脂酸酯、檸檬酸三異硬脂酯、硬脂醯基硬脂酸異硬脂酯、芒果種子脂、三辛酸甘油酯、葡萄糖谷氨酸酯及其混合物。上述每一種都可以從例如Alzo International Inc以各種商品名商購。
酯可以以組合物的約0.01重量%至約20重量%，更優選約0.03重量%至約10重量%，和最優選約0.05重量%至約2重量%的水準存在。
特別優選檸檬酸三辛酯，其可以商品名Bernel EsterTM
TCC獲自Alzo International Inc。脂肪酯
用作本發明的組合物中的調理劑的其它合適的有機調理油包括具有至少10個碳原子的脂肪酯。這些脂肪酯包括具有衍生自脂肪酸或醇的烴基鏈的酯。本文的脂肪酯的烴基可包含或具有共價鍵合到其上的其它相容官能團，如醯胺和烷氧基部分（例如乙氧基或醚鍵等）。
優選的脂肪酯的具體實例包括但不限於異硬脂酸異丙酯、月桂酸己酯、月桂酸異己酯、棕櫚酸異己酯、棕櫚酸異丙酯、油酸癸酯、油酸異癸酯、硬脂酸十六烷基酯、硬脂酸癸酯、異硬脂酸異丙酯、己二酸二己基癸酯、乳酸月桂酯、乳酸肉豆蔻酯、乳酸鯨蠟酯、硬脂酸油酯、油酸油酯、肉豆蔻酸油酯、乙酸月桂酯、丙酸鯨蠟酯和己二酸油酯。
適用於本發明的組合物的其它脂肪酯是被稱作多元醇酯的那些。這樣的多元醇酯包括亞烷基二醇酯。
適用於本發明的組合物的再其它脂肪酯是甘油酯，包括但不限於單-、二-和三-甘油酯，優選二-和三-甘油酯，更優選三甘油酯。各種這些類型的材料可獲自植物和動物脂肪和油，如蓖麻油、紅花油、棉籽油、玉米油、橄欖油、魚肝油、杏仁油、鱷梨油、棕櫚油、芝麻油、羊毛脂和大豆油。合成油包括但不限於三油酸甘油酯和三硬脂酸甘油酯二月桂酸甘油酯。氟化調理化合物
適合作為有機調理油為頭髮或皮膚提供調理的氟化化合物包括全氟聚醚、全氟化烯烴和可呈流體或彈性體形式的基於氟的特種聚合物。合適的氟化化合物的具體非限制性實例包括來自Ausimont的Fomblin產品線，其包括HC/04、HC/25、HC01、HC/02、HC/03；二辛基十二烷基氟庚基檸檬酸酯，常被稱作Biosil Basics Fluoro Gerbet 3.5，由Biosil Technologies供應；和也由Biosil Technologies供應的Biosil Basics Fluorosil LF。脂肪醇
用於本發明的個人護理組合物的其它合適的有機調理油包括但不限於具有至少約10個碳原子，更優選約10至約22個碳原子，最優選約12至約16個碳原子的脂肪醇。符合下列通式的烷氧基化脂肪醇也適用於本發明的個人護理組合物：
CH3
(CH2
)n
CH2
(OCH2
CH2
)p
OH
其中n是具有約8至約20，優選約10至約14的值的正整數，且p是具有約1至約30，優選約2至約23的值的正整數。烷基葡糖苷和烷基葡糖苷衍生物
適用於本發明的個人護理組合物的有機調理油包括但不限於烷基葡糖苷和烷基葡糖苷衍生物。合適的烷基葡糖苷和烷基葡糖苷衍生物的具體的非限制性實例包括可購自Amerchol的Glucam E-10、Glucam E-20、Glucam P-10和Glucquat 125。其它調理劑 季銨化合物
適合用作本發明的個人護理組合物中的調理劑的季銨化合物包括但不限於具有含羰基部分，如醯胺部分或磷酸酯部分或類似親水部分的長鏈取代基的親水季銨化合物。
可用的親水季銨化合物的實例包括但不限於在CTFA Cosmetic Dictionary中指定為蓖麻油醯氨基丙基三甲基氯化銨、蓖麻油醯氨基三甲基銨乙基硫酸鹽、羥基硬脂醯氨基丙基三甲基銨甲基硫酸鹽和羥基硬脂醯氨基丙基三甲基氯化銨的化合物或其組合。
其它可用的季銨表面活性劑的實例包括但不限於如CTFA Dictionary中指定的Quaternium-33、Quaternium-43、異硬脂醯氨基丙基乙基二甲基銨乙基硫酸鹽、Quaternium-22和Quaternium-26或其組合。
可用於本發明的組合物的其它親水季銨化合物包括但不限於Quaternium-16、Quaternium-27、Quaternium-30、Quaternium-52、Quaternium-53、Quaternium-56、Quaternium-60、Quaternium-61、Quaternium-62、Quaternium-63、Quaternium-71及其組合。聚乙二醇
在本文中可用作調理劑的其它化合物包括具有最多約2,000,000的分子量的聚乙二醇和聚丙二醇，如CTFA名稱為PEG-200、PEG-400、PEG-600、PEG-1000、PEG-2M、PEG-7M、PEG-14M、PEG-45M的那些及其混合物。化妝品可接受的載體
本發明的個人護理組合物包含化妝品可接受的載體。載體的水準和種類根據與產品特性所需的其它組分的相容性來選擇。通常，化妝品可接受的載體以組合物的約20重量%至約95重量%的量存在。可以選擇化妝品可接受的載體，使得本發明的組合物可呈例如可傾倒的液體、凝膠、糊劑、乾燥粉末或乾燥薄膜的形式。
可用於本發明的化妝品可接受的介質包括水和低級烷基醇的水溶液。可用於本文的低級烷基醇是具有1至6個碳的一元醇，並且優選選自乙醇和異丙醇。
在純形式下測量的本發明組合物的pH優選為約3至約9，更優選約4至約8。可以包括緩衝劑和其它pH調節劑以獲得所需的pH。纖維素或瓜爾膠陽離子沉積聚合物
組合物還可包含纖維素或瓜爾膠陽離子沉積聚合物。纖維素或半乳甘露聚糖陽離子沉積聚合物是優選的。通常，這樣的纖維素或瓜爾膠陽離子沉積聚合物可以以該組合物的約0.05重量%至約5重量%的濃度存在。合適的纖維素或瓜爾膠陽離子沉積聚合物具有大於約5,000的分子量。該纖維素或瓜爾膠陽離子沉積聚合物優選具有大於約200,000的分子量。另外，這樣的纖維素或瓜爾膠沉積聚合物具有在該組合物的預期用途的pH下約0.15 meq/g至約4.0 meq/g的電荷密度，所述pH通常為約pH 3至約pH 9，優選約pH 4至約pH 8。本發明的組合物的pH在純形式下測量。
合適的纖維素或瓜爾膠陽離子聚合物包括符合下式的那些：
其中A是脫水葡萄糖殘基，如纖維素脫水葡萄糖殘基；R是亞烷基、氧亞烷基、聚氧亞烷基或羥基亞烷基或其組合；R1
、R2
和R3
獨立地為烷基、芳基、烷基芳基、芳基烷基、烷氧基烷基或烷氧基芳基，各基團含有最多約18個碳原子，且各陽離子部分的碳原子總數（即R1
、R2
和R3
中的碳原子總和）優選為約20或更少；且X是陰離子抗衡離子。這樣的抗衡離子的非限制性實例包括鹵離子（例如氯、氟、溴、碘）、硫酸根和甲基硫酸根。這些多糖聚合物中的陽離子取代度通常為約0.01至約1個陽離子基團/脫水葡萄糖單元。
在本發明的一個實施方案中，該纖維素或瓜爾膠陽離子聚合物是與三甲基銨取代的環氧化物反應的羥乙基纖維素的鹽，其在工業(CTFA)中被稱作聚季銨鹽10並可獲自Amerchol Corp. (Edison, N.J., USA)。合成陽離子沉積聚合物
儘管優選本發明的組合物不含合成成分，但包含某些合成組分而沒有性能缺點是可行的。當提及時，可以包含合成成分，但應當理解，它們對於遞送本文所公開的化妝品益處不是必需的。
例如，在一個實施方案中，組合物可包含合成陽離子沉積聚合物。通常，這樣的合成陽離子沉積聚合物可以以該組合物的約0.025重量%至約5重量%的濃度存在。這樣的合成陽離子沉積聚合物具有約1,000至約5,000,000的分子量。另外，這樣的合成陽離子沉積聚合物具有約0.1 meq/g至約5.0 meq/g的電荷密度。
合適的合成陽離子沉積聚合物包括作為水溶性或水分散性、陽離子型、非交聯調理共聚物的那些，其包含：(i) 一個或多個陽離子單體單元；和(ii) 一個或多個非離子單體單元或帶有末端負電荷的單體單元；其中所述共聚物具有淨正電荷、約0.5 meq/g至約10 meg/g的陽離子電荷密度和約1,000至約5,000,000的平均分子量。
合適的合成陽離子沉積聚合物的非限制性實例描述在授予Geary等人的美國專利申請公開US 2003/0223951 A1中。去頭屑活性劑
本發明的組合物還可含有去頭屑活性劑。去頭屑活性劑的合適的非限制性實例包括吡啶硫酮鹽、唑類、硫化硒、微粒硫、角質層分離劑及其混合物。這樣的去頭屑活性劑應該與該組合物的基本組分物理和化學相容，並且不應在其它方面不適當地損害產品穩定性、美觀性或性能。
吡啶硫酮抗微生物和去頭屑劑描述在例如美國專利號2,809,971；美國專利號3,236,733；美國專利號3,753,196；美國專利號3,761,418；美國專利號4,345,080；美國專利號4,323,683；美國專利號4,379,753；和美國專利號4,470,982中。
唑類抗微生物劑包括咪唑類，如氯咪巴唑和酮康唑。
硫化硒化合物描述在例如美國專利號2,694,668；美國專利號3,152,046；美國專利號4,089,945；和美國專利號4,885,107中。
硫也可用作本發明的抗微生物組合物中的微粒抗微生物/去頭屑劑。
本發明可進一步包含一種或多種角質層分離劑，如水楊酸。在一個優選實施方案中，水楊酸提供化學剝脫活性。
本發明的另外的抗微生物活性劑可包括白千層屬(melaleuca) (茶樹)的提取物和木炭。
當存在於該組合物中時，以該組合物的約0.01重量%至約5重量%，優選約0.1重量%至約3重量%，更優選約0.3重量%至約2重量%的量包含去頭屑活性劑。粒子
本發明的組合物任選可包含粒子。優選地，可用於本發明的粒子是分散的水不溶性粒子。可用於本發明的粒子可以是無機、合成或半合成的。在本發明的組合物中，優選併入該組合物的不多於約20重量%，更優選不多於約10重量%，甚至更優選不多於2重量%的粒子。在本發明的一個實施方案中，該粒子具有小於約300 µm的平均細微性。
無機粒子的非限制性實例包括膠體二氧化矽、熱解法二氧化矽、沉澱二氧化矽、矽膠、矽酸鎂、玻璃粒子、滑石、雲母、絹雲母和各種天然和合成粘土，包括膨潤土、水輝石和蒙脫石。
合成粒子的實例包括矽酮樹脂、聚(甲基)丙烯酸酯、聚乙烯、聚酯、聚丙烯、聚苯乙烯、聚氨酯、聚醯胺（例如Nylon®）、環氧樹脂、脲樹脂、丙烯酸系粉末等。
雜化粒子的非限制性實例包括絹雲母和交聯聚苯乙烯雜化粉末，以及雲母和二氧化矽雜化粉末。不透明劑
本發明的組合物還可含有一種或多種不透明劑。不透明劑通常用於清潔組合物以賦予該組合物所需美觀益處，如顏色或珠光。在本發明的組合物中，優選併入該組合物的不多於約20重量%，更優選不多於約10重量%，甚至更優選不多於2重量%的不透明劑。
合適的不透明劑包括例如熱解法二氧化矽、聚甲基丙烯酸甲酯、微粉化Teflon®
、氮化硼、硫酸鋇、丙烯酸酯聚合物、矽酸鋁、澱粉辛烯基琥珀酸鋁、矽酸鈣、纖維素、白堊、玉米澱粉、矽藻土、漂白土、甘油澱粉、水合二氧化矽、碳酸鎂、氫氧化鎂、氧化鎂、三矽酸鎂、麥芽糊精、微晶纖維素、米澱粉、二氧化矽、二氧化鈦、月桂酸鋅、肉豆蔻酸鋅、新癸酸鋅、松脂酸鋅、硬脂酸鋅、聚乙烯、氧化鋁、綠坡縷石、碳酸鈣、矽酸鈣、葡聚糖、尼龍、甲矽烷基化二氧化矽、蠶絲粉、大豆粉、氧化錫、氫氧化鈦、磷酸三鎂、胡桃殼粉或其混合物。上文提到的粉末可以用卵磷脂、氨基酸、礦物油或各種其它試劑獨自或組合進行表面處理，它們塗布粉末表面並使粒子在性質上疏水。
該不透明劑還可包含各種有機和無機顏料。有機顏料通常為各種芳族類型，包括偶氮、靛系、三苯基甲烷、蒽醌和黃嘌呤染料。無機顏料包括鐵氧化物、群青和鉻或氫氧化鉻色料及其混合物。助懸劑
本發明的組合物可進一步包含在有效地將水不溶性材料以分散形式懸浮在該組合物中或改變該組合物的粘度的濃度下的助懸劑。此類濃度通常為該組合物的約0.1重量%至約10重量%，優選約0.3重量%至約5.0重量%的助懸劑。
本文中可用的助懸劑包括陰離子聚合物和非離子聚合物。本文中可用的是乙烯基聚合物，如CTFA名稱為Carbomer的交聯丙烯酸聚合物。鏈烷烴
本發明的組合物可含有一種或多種鏈烷烴。適用於本發明的組合物的鏈烷烴包括已知用於頭髮護理或其它個人護理組合物的那些材料，如具有在1 atm下等於或大於約21℃（約70℉）的蒸氣壓的那些。非限制性實例包括戊烷和異戊烷。拋射劑
本發明的組合物還可含有一種或多種拋射劑。適用於本發明的組合物的拋射劑包括已知用於頭髮護理或其它化妝品組合物的那些材料，如液化氣體拋射劑和壓縮氣體拋射劑。合適的拋射劑具有在1 atm下小於約21℃（約70℉）的蒸氣壓。合適的拋射劑的非限制性實例是烷烴、異烷烴、鹵代烷、二甲醚、氮氣、一氧化二氮、二氧化碳及其混合物。其它任選組分
本發明的組合物可含有香料。
本發明的組合物還可含有水溶性和水不溶性維生素，如維生素B1、B2、B6、B12、C、泛酸、泛醯乙基醚、泛醇、生物素及其衍生物，和維生素A、D、E，及其衍生物。本發明的組合物還可含有水溶性和水不溶性氨基酸，如天冬醯胺、丙氨酸、吲哚、谷氨酸及其鹽、和酪氨酸、色胺、賴氨酸、組氨酸及其鹽。
本發明的組合物可含有一價或二價鹽，如氯化鈉。
本發明的組合物還可含有螯合劑。
本發明的組合物可進一步包含可用於預防脫髮的材料和頭髮生長刺激劑或試劑。調節劑
組合物可包含一種或多種調理劑。活性劑優選是選自澱粉、瓜爾膠、非瓜爾膠半乳甘露聚糖聚合物衍生物、植物提取物等的天然或天然衍生活性劑。
適用於該組合物的澱粉是通常來自任何植物來源的那些。非限制性實例包括玉米、馬鈴薯、燕麥、稻米、木薯、高粱、大麥或玉米。
調理活性劑優選以相對於該組合物總重量的0.01至20重量%的量使用。更優選相對於該組合物的總重量的0.05至15重量%，甚至更優選該組合物的0.1至10重量%。
該頭髮調理組合物還可包含具有在單體比單體基礎上大於2:1的甘露糖/半乳糖比率的非瓜爾膠半乳甘露聚糖聚合物衍生物，該非瓜爾膠半乳甘露聚糖聚合物衍生物選自陽離子非瓜爾膠半乳甘露聚糖聚合物衍生物和具有淨正電荷的兩性非瓜爾膠半乳甘露聚糖聚合物衍生物。本文所用的術語“陽離子非瓜爾膠半乳甘露聚糖”是指對其添加了陽離子基團的非瓜爾膠半乳甘露聚糖聚合物。術語“兩性非瓜爾膠半乳甘露聚糖”是指對其添加了陽離子基團和陰離子基團以使該聚合物具有淨正電荷的非瓜爾膠半乳甘露聚糖聚合物。非瓜爾膠半乳甘露聚糖聚合物衍生物提供改進的調理劑效力。此外，已經發現非瓜爾膠半乳甘露聚糖聚合物衍生物降低調理組合物的總粘度，這帶來改進的感覺益處。
用於製備非瓜爾膠半乳甘露聚糖聚合物衍生物的樹膠通常作為天然存在的材料，如來自植物的種子或豆子獲得。各種非瓜爾膠半乳甘露聚糖聚合物的實例包括但不限於塔拉膠（3份甘露糖/1份半乳糖）、刺槐豆或角豆（4份甘露糖/1份半乳糖）和決明膠（5份甘露糖/1份半乳糖）。優選的非瓜爾膠半乳甘露聚糖聚合物衍生物是陽離子決明膠。
該陽離子非瓜爾膠半乳甘露聚糖聚合物衍生物具有約1,000至約10,000,000的分子量。在本發明的一個實施方案中，該陽離子非瓜爾膠半乳甘露聚糖聚合物衍生物具有約5,000至約3,000,000的分子量。本文所用的術語“分子量”是指重均分子量。重均分子量可通過凝膠滲透色譜法測量。
本發明的頭髮調理組合物可包含具有約0.7 meq/g至約7 meq/g的陽離子電荷密度的非瓜爾膠半乳甘露聚糖聚合物衍生物。在本發明的一個實施方案中，該非瓜爾膠半乳甘露聚糖聚合物衍生物具有約0.9 meq/g至約7 meq/g的電荷密度。陽離子基團在非瓜爾膠半乳甘露聚糖結構上的取代度應該足以提供必要的陽離子電荷密度。
在本發明的一個實施方案中，該非瓜爾膠半乳甘露聚糖聚合物衍生物是通過非瓜爾膠半乳甘露聚糖聚合物的羥基和反應性季銨化合物之間的反應獲得的非瓜爾膠半乳甘露聚糖聚合物的陽離子衍生物。
在本發明的另一實施方案中，該非瓜爾膠半乳甘露聚糖聚合物衍生物是在陽離子非瓜爾膠半乳甘露聚糖聚合物衍生物進一步包含陰離子基團時獲得的具有淨正電荷的兩性非瓜爾膠半乳甘露聚糖聚合物衍生物。
該頭髮調理組合物可包含該組合物的約0.01重量%至約10重量%，更優選約0.05重量%至約5重量%的非瓜爾膠半乳甘露聚糖聚合物衍生物。
該組合物可進一步包含一種或多種選自纖維素醚的衍生物、瓜爾膠的季銨衍生物、DADMAC的均聚物和共聚物、MAPTAC的均聚物和共聚物以及澱粉的季銨衍生物的調理聚合物。使用CTFA名稱，具體實例包括但不限於聚季銨鹽-10、瓜爾膠羥丙基三甲基氯化銨、澱粉羥丙基三甲基氯化銨、聚季銨鹽-4、聚季銨鹽-5、聚季銨鹽-6、聚季銨鹽-7、聚季銨鹽-14、聚季銨鹽-15、聚季銨鹽-22、聚季銨鹽-24、聚季銨鹽-28、聚季銨鹽-32、聚季銨鹽-33、聚季銨鹽-36、聚季銨鹽-37、聚季銨鹽-39、聚季銨鹽-45、聚季銨鹽-47和聚甲基丙烯醯氨基丙基三甲基氯化銨及其混合物。當使用時，調理聚合物優選以0.1至10重量%，優選0.2至6重量%，最優選0.2至5重量%的濃度包含在本發明的組合物中。調理劑
該調理組合物還可包含一種或多種調理劑，如選自陽離子表面活性劑、陽離子聚合物、非揮發烴、飽和C14至C22直鏈脂肪醇、非揮發烴酯及其混合物的那些。優選的調理劑是陽離子表面活性劑、陽離子聚合物、飽和C14至C22直鏈脂肪醇和季銨鹽。植物提取物，如人參根提取物、水飛薊（silybaum marianum）提取物、余甘子果提取物等也合適。其組分可包含約0.1%至約99%，更優選約0.5%至約90%的調理劑。但是，在水性載體存在下，調理劑優選占該頭髮調理組合物的約0.1重量%至約90重量%，更優選約0.5至約60重量%，最優選約1重量%至約50重量%。
該調理組合物還包含一種或多種天然刺激劑以在施加精華組分之前刺激頭皮。示例性的天然刺激劑包括如人參和咖啡因的那些。陽離子表面活性劑
可用於該組合物的陽離子表面活性劑含有氨基或季銨部分。該陽離子表面活性劑優選，但不是必須，不溶於其組合物中。本文中可用的陽離子表面活性劑公開在下列文獻中：M.C. Publishing Co., McCutcheoris, Detergents Sc Emulsifiers, (North American edition 1979)；Schwartz等人, Surface Active Agents, Their Chemistry and Technology, New York: Interscience Publishers, 1949；1964年11月3日頒發的美國專利3,155,591, Hilfer；1975年12月30日頒發的美國專利3,929,678, Laughlin等人；1976年5月25日頒發的美國專利3,959,461, Bailey等人；和1983年6月7日頒發的美國專利4,387,090, Bolich, Jr.。本文中可用的含季銨的陽離子表面活性劑材料是具有下列通式的那些：
其中R1-R4獨立地為約1至約22個碳原子的脂族基團或具有約1至約22個碳原子的芳族基團、烷氧基、聚氧化烯、烷基醯氨基、羥烷基、芳基或烷基芳基；且X是成鹽陰離子，如選自鹵素（例如氯離子、溴離子）、乙酸根、檸檬酸根、乳酸根、乙醇酸根、磷酸根、硝酸根、硫酸根和烷基硫酸根的那些。該脂族基團除碳和氫原子外還可含有醚鍵和其它基團，如氨基。較長鏈的脂族基團，例如具有約12個碳或更高級的那些可以是飽和或不飽和的。尤其優選的是二-長鏈（例如二C12-22，優選C14-C20脂族基團，優選烷基）、二-短鏈（例如C1-C3烷基，優選C1-C2烷基）和季銨鹽。伯、仲和叔脂肪胺的鹽也是合適的陽離子表面活性劑材料。此類胺的烷基優選具有約12至約22個碳原子，並可以是取代或未取代的。本文中可用的此類胺包括硬脂醯氨基丙基二甲基胺、二乙基氨基乙基硬脂醯胺、二甲基硬脂胺、二甲基大豆胺、大豆胺、肉豆蔻胺、十三烷基胺、乙基硬脂胺、N-牛脂丙烷二胺、乙氧基化（含5摩爾環氧乙烷）硬脂胺、二羥基乙基硬脂胺和二十烷基山崳胺。合適的胺鹽包括鹵素、乙酸鹽、磷酸鹽、硝酸鹽、檸檬酸鹽、乳酸鹽和烷基硫酸鹽。此類鹽包括硬脂胺鹽酸鹽、大豆胺氯化物、硬脂胺甲酸鹽、N-牛脂丙烷二胺二氯化物和硬脂醯氨基丙基二甲基胺檸檬酸鹽。可用於本發明的那些中包括的陽離子胺表面活性劑公開在1981年6月23日頒發的美國專利4,275,055, Nachtigal等人中。陽離子表面活性劑優選以該組合物的約0.1重量%至約10重量%，更優選約0.25重量%至約5重量%，最優選約0.5重量%至約2重量%的水準使用。SUMMARY OF THE INVENTION The present invention relates to a hair conditioning composition comprising olive squalane, wax, ester and a cosmetically acceptable carrier. The composition may not contain one or more components selected from silicones, anionic surfactants, amidoamines, silicone derivatives, ethoxylated emulsifiers and mixtures thereof. Detailed Description of the Invention Although this specification ends with a claim specifically pointing out and clearly claiming the protection of the present invention, it is believed that the present invention will be better understood from the following description. Unless otherwise specified, all percentages, parts and ratios are based on the total weight of the composition of the present invention. Unless otherwise specified, when referring to the listed ingredients, all such weights are based on activity levels and therefore do not include solvents or by-products that may be contained in commercially available materials. The term "weight percent" may be designated as "weight%" herein. Unless otherwise specified, all molecular weights used herein are weight average molecular weights expressed as grams/mole. The term "charge density" as used herein refers to the ratio of the number of positive charges on the monomer units constituting the polymer to the molecular weight of the monomer units. The charge density multiplied by the polymer molecular weight determines the number of positively charged sites on a given polymer chain. Here, "comprising" means other steps and other ingredients that can be added that do not affect the final result. The term includes the terms "consisting of" and "consisting essentially of". The compositions and methods/processes of the present invention may comprise the essential elements and limitations of the present invention described herein, as well as any additional or optional ingredients, components, steps or limitations described herein, consisting of and consisting essentially of them . The term "polymer" as used herein shall include materials made by the polymerization of one type of monomer or made of two (ie, copolymers) or more types of monomers. The term "solid particles" as used herein means particles that are not liquid or gas. The term "water-soluble" as used herein means that the polymer is soluble in water in the present composition. Generally speaking, the polymer should be soluble at a concentration of at least 0.1% by weight of the water solvent at 25°C, preferably at least 1%, more preferably at least 5%, and most preferably at least 15%. The term "water-insoluble" as used herein means that the compound is insoluble in water in the present composition. Therefore, the compound is immiscible with water. The personal care composition of the present invention comprises a cationic modified starch polymer, an anionic surfactant system and a cosmetically acceptable carrier. Each of these basic components and preferred or optional components are described in detail below. Olive squalane The composition herein includes an olive squalene component. Squalane is a well-known cosmetic ingredient. For example, US Patent Publication No. 2008-0274068 discloses squalene and other oily substances, which can be used to improve the manageability of dry hair. However, it has now been discovered that specific squalane not only behaves differently from other oily cosmetic ingredients, but also from squalane derived from different natural sources. For example, squalene can be derived from sugarcane, which is true for squalene sold under the trade name Neossance®. Squalane can also be derived from animal sources, as described in Korean Patent No. KR101417029. In contrast, olive squalene is derived from olive oil and displays unique characteristics that are essential to the benefits of the compositions herein. In one embodiment, olive squalane is present at about 0.01% to about 20% by weight of the composition, more preferably about 0.03% to about 10% by weight, and most preferably about 0.05% to about 2% by weight. Wax The composition herein contains one or more wax components. Non-limiting examples of suitable waxes include, for example, microcrystalline wax, paraffin wax, microcrystalline wax, ozokerite wax, polyethylene wax, ceresin wax, beeswax, candelilla wax, carnauba wax, shellac wax, lanolin wax, Montan wax, orange wax, lemon wax, laurel wax and olive wax, beeswax and mixtures thereof. Particularly preferred waxes include candelilla wax, carnauba wax, and natural or synthetic beeswax. In one embodiment, the wax is present from about 0.01% to about 20% by weight of the composition, more preferably from about 0.03% to about 10% by weight, and most preferably from about 0.05% to about 2% by weight. In addition, it is preferable that the melting point of the wax component is about 68.5-72.5°C. Ester emollients The composition contains one or more esters that act as emollients. When used to treat human hair, the ester enhances the feel of the composition. Preferably, the ester is a natural ester selected from the group consisting of methyl heptyl isostearate, dimer dilinoleic acid diisostearyl, malate diisostearyl, trioctyl citrate, iso Isostearyl stearate, polyglyceryl-2 triisostearate, polyglyceryl-2 diisostearate, polyglyceryl-2 isostearate, glyceryl ricinoleate, isostearate palmitate Fatty ester, caprylic/capric triglyceride, mango fat dimer dilinoleate/dimer dilinoleate copolymer, myristyl myristate, erucic acid oleate, polyglycerol-3 diiso Stearate, triisostearyl citrate, isostearyl stearate, mango seed butter, tricaprylin, glucose glutamate and mixtures thereof. Each of the above is commercially available under various trade names from, for example, Alzo International Inc. The ester may be present at a level of about 0.01% to about 20% by weight of the composition, more preferably about 0.03% to about 10% by weight, and most preferably about 0.05% to about 2% by weight. Particularly preferred is trioctyl citrate, which is available from Alzo International Inc under the trade name Bernel Ester™ TCC. Fatty esters Other suitable organic conditioning oils for use as conditioning agents in the compositions of the present invention include fatty esters having at least 10 carbon atoms. These fatty esters include esters having hydrocarbyl chains derived from fatty acids or alcohols. The hydrocarbon group of the fatty ester herein may contain or have other compatible functional groups covalently bonded thereto, such as amide and alkoxy moieties (such as ethoxy or ether bonds, etc.). Specific examples of preferred fatty esters include, but are not limited to, isopropyl isostearate, hexyl laurate, isohexyl laurate, isohexyl palmitate, isopropyl palmitate, decyl oleate, isodecyl oleate , Cetyl stearate, decyl stearate, isopropyl isostearate, dihexyl decyl adipate, lauryl lactate, myristyl lactate, cetyl lactate, oil stearate Esters, oleyl oleate, oleyl myristate, lauryl acetate, cetyl propionate and oleyl adipate. Other fatty esters suitable for use in the composition of the present invention are those referred to as polyol esters. Such polyol esters include alkylene glycol esters. Still other fatty esters suitable for use in the composition of the present invention are glycerides, including but not limited to mono-, di- and tri-glycerides, preferably di- and tri-glycerides, more preferably triglycerides. A variety of these types of materials can be obtained from vegetable and animal fats and oils, such as castor oil, safflower oil, cottonseed oil, corn oil, olive oil, cod liver oil, almond oil, avocado oil, palm oil, sesame oil, lanolin and soybean oil . Synthetic oils include, but are not limited to, glyceryl trioleate and glyceryl tristearate dilaurate. Fluorinated conditioning compounds. Fluorinated compounds suitable as organic conditioning oils to provide conditioning to hair or skin include perfluoropolyethers, perfluorinated olefins, and fluorine-based specialty polymers that can be in the form of fluids or elastomers. Specific non-limiting examples of suitable fluorinated compounds include the Fomblin product line from Ausimont, which includes HC/04, HC/25, HC01, HC/02, HC/03; dioctyldodecylfluoroheptyl lemon The acid ester, often referred to as Biosil Basics Fluoro Gerbet 3.5, is supplied by Biosil Technologies; and Biosil Basics Fluorosil LF, which is also supplied by Biosil Technologies. Fatty alcohols . Other suitable organic conditioning oils for use in the personal care composition of the present invention include, but are not limited to, having at least about 10 carbon atoms, more preferably about 10 to about 22 carbon atoms, and most preferably about 12 to about 16 carbon atoms. Atomic fatty alcohol. Alkoxylated fatty alcohols conforming to the following general formula are also suitable for the personal care composition of the present invention: CH 3 (CH 2 ) n CH 2 (OCH 2 CH 2 ) p OH where n is from about 8 to about 20, preferably A positive integer having a value of about 10 to about 14, and p is a positive integer having a value of about 1 to about 30, preferably about 2 to about 23. Alkyl Glucoside and Alkyl Glucoside Derivatives Organic conditioning oils suitable for use in the personal care composition of the present invention include, but are not limited to, alkyl glucoside and alkyl glucoside derivatives. Specific non-limiting examples of suitable alkyl glucosides and alkyl glucoside derivatives include Glucam E-10, Glucam E-20, Glucam P-10, and Glucquat 125 available from Amerchol. Other conditioning agents Quaternary ammonium compounds Suitable for use as conditioning agents in the personal care composition of the present invention include, but are not limited to, long-chain substituents having carbonyl-containing moieties, such as amide moieties or phosphate moieties or similar hydrophilic moieties. The hydrophilic quaternary ammonium compound. Examples of usable hydrophilic quaternary ammonium compounds include, but are not limited to, castor oil aminopropyl trimethyl ammonium chloride, castor oil amino trimethyl ammonium ethyl sulfate, hydroxystearyl amino in the CTFA Cosmetic Dictionary. A compound of propyltrimethylammonium methyl sulfate and hydroxystearylaminopropyltrimethylammonium chloride or a combination thereof. Examples of other useful quaternary ammonium surfactants include, but are not limited to, Quaternium-33, Quaternium-43, isostearylaminopropyl ethyl dimethyl ammonium ethyl sulfate as specified in the CTFA Dictionary, Quaternium-22 and Quaternium-26 or a combination thereof. Other hydrophilic quaternary ammonium compounds that can be used in the composition of the present invention include, but are not limited to, Quaternium-16, Quaternium-27, Quaternium-30, Quaternium-52, Quaternium-53, Quaternium-56, Quaternium-60, Quaternium-61, Quaternium -62, Quaternium-63, Quaternium-71 and combinations thereof. Other compounds that polyethylene glycol can be used as a conditioning agent herein include polyethylene glycol and polypropylene glycol having a molecular weight of up to about 2,000,000, such as the CTFA names PEG-200, PEG-400, PEG-600, PEG-1000, Those of PEG-2M, PEG-7M, PEG-14M, PEG-45M, and mixtures thereof. Cosmetically acceptable carrier The personal care composition of the present invention contains a cosmetically acceptable carrier. The level and type of the carrier are selected according to the compatibility with other components required by the product characteristics. Generally, the cosmetically acceptable carrier is present in an amount of about 20% to about 95% by weight of the composition. The cosmetically acceptable carrier may be selected so that the composition of the present invention may be in the form of, for example, a pourable liquid, gel, paste, dry powder or dry film. The cosmetically acceptable medium that can be used in the present invention includes water and aqueous solutions of lower alkyl alcohols. The lower alkyl alcohols usable herein are monohydric alcohols having 1 to 6 carbons, and are preferably selected from ethanol and isopropanol. The pH of the composition of the present invention measured in its pure form is preferably from about 3 to about 9, more preferably from about 4 to about 8. Buffers and other pH adjusting agents may be included to obtain the desired pH. The cellulose or guar gum cationic deposition polymer composition may also comprise cellulose or guar gum cationic deposition polymer. Cellulose or galactomannan cationic deposition polymers are preferred. Generally, such cellulose or guar gum cationic deposition polymer may be present in a concentration of about 0.05% to about 5% by weight of the composition. Suitable cellulose or guar gum cationic deposition polymers have a molecular weight greater than about 5,000. The cellulose or guar gum cationic deposition polymer preferably has a molecular weight greater than about 200,000. In addition, such cellulose or guar gum deposition polymers have a charge density of about 0.15 meq/g to about 4.0 meq/g at the pH of the intended use of the composition, which is generally about pH 3 to about pH 9, preferably from about pH 4 to about pH 8. The pH of the composition of the invention is measured in pure form. Suitable cellulose or guar gum cationic polymers include those conforming to the following formula: Wherein A is an anhydroglucose residue, such as a cellulose anhydroglucose residue; R is an alkylene, oxyalkylene, polyoxyalkylene, or hydroxyalkylene or a combination thereof; R 1 , R 2 and R 3 are independent Ground is an alkyl group, an aryl group, an alkylaryl group, an arylalkyl group, an alkoxyalkyl group or an alkoxyaryl group, each group contains up to about 18 carbon atoms, and the total number of carbon atoms in each cation moiety ( That is, the sum of carbon atoms in R 1 , R 2 and R 3 ) is preferably about 20 or less; and X is an anionic counterion. Non-limiting examples of such counterions include halide (eg, chlorine, fluorine, bromine, iodine), sulfate, and methyl sulfate. The degree of cationic substitution in these polysaccharide polymers is generally from about 0.01 to about 1 cationic group per anhydroglucose unit. In one embodiment of the present invention, the cellulose or guar gum cationic polymer is a salt of hydroxyethyl cellulose reacted with a trimethylammonium substituted epoxide, which is called in the industry (CTFA) Polyquaternium 10 is available from Amerchol Corp. (Edison, NJ, USA). Synthetic cationic deposition polymer Although it is preferred that the composition of the present invention contains no synthetic components, it is feasible to include certain synthetic components without performance disadvantages. When mentioned, synthetic ingredients may be included, but it should be understood that they are not necessary to deliver the cosmetic benefits disclosed herein. For example, in one embodiment, the composition may include a synthetic cationic deposition polymer. Generally, such synthetic cationic deposition polymers may be present at a concentration of about 0.025% to about 5% by weight of the composition. Such synthetic cationic deposition polymers have a molecular weight of about 1,000 to about 5,000,000. In addition, such synthetic cationic deposition polymers have a charge density of about 0.1 meq/g to about 5.0 meq/g. Suitable synthetic cationic deposition polymers include those that are water-soluble or water-dispersible, cationic, non-crosslinked conditioning copolymers, which contain: (i) one or more cationic monomer units; and (ii) one or more A nonionic monomer unit or a monomer unit with a negative terminal charge; wherein the copolymer has a net positive charge, a cationic charge density of about 0.5 meq/g to about 10 meg/g, and an average of about 1,000 to about 5,000,000 Molecular weight. Non-limiting examples of suitable synthetic cationic deposition polymers are described in U.S. Patent Application Publication US 2003/0223951 Al to Geary et al. Anti-dandruff active agent The composition of the present invention may also contain an anti-dandruff active agent. Suitable non-limiting examples of anti-dandruff active agents include pyrithione salts, azoles, selenium sulfide, particulate sulfur, keratolytic agents, and mixtures thereof. Such anti-dandruff active agents should be physically and chemically compatible with the essential components of the composition, and should not improperly impair product stability, aesthetics or performance in other respects. Pyrithione antimicrobial and anti-dandruff agents are described in, for example, U.S. Patent No. 2,809,971; U.S. Patent No. 3,236,733; U.S. Patent No. 3,753,196; U.S. Patent No. 3,761,418; U.S. Patent No. 4,345,080; U.S. Patent No. 4,323,683; U.S. Patent No. 4,379,753; Patent number 4,470,982. Azole antimicrobial agents include imidazoles such as clomibazole and ketoconazole. Selenium sulfide compounds are described in, for example, U.S. Patent No. 2,694,668; U.S. Patent No. 3,152,046; U.S. Patent No. 4,089,945; and U.S. Patent No. 4,885,107. Sulfur can also be used as a particulate antimicrobial/antidandruff agent in the antimicrobial composition of the present invention. The present invention may further comprise one or more keratolytic agents, such as salicylic acid. In a preferred embodiment, salicylic acid provides chemical exfoliation activity. Additional antimicrobial active agents of the present invention may include extracts of melaleuca (tea tree) and charcoal. When present in the composition, the composition is contained in an amount of about 0.01% to about 5% by weight, preferably about 0.1% to about 3% by weight, more preferably about 0.3% to about 2% by weight of the composition. Dandruff active agent. Particles The composition of the present invention may optionally contain particles. Preferably, the particles useful in the present invention are dispersed water-insoluble particles. The particles useful in the present invention can be inorganic, synthetic or semi-synthetic. In the composition of the present invention, preferably not more than about 20% by weight, more preferably not more than about 10% by weight, and even more preferably not more than 2% by weight of particles incorporated into the composition. In one embodiment of the invention, the particles have an average fineness of less than about 300 µm. Non-limiting examples of inorganic particles include colloidal silica, fumed silica, precipitated silica, silica gel, magnesium silicate, glass particles, talc, mica, sericite and various natural and synthetic clays, including bentonite, water Pyroxene and montmorillonite. Examples of synthetic particles include silicone resin, poly(meth)acrylate, polyethylene, polyester, polypropylene, polystyrene, polyurethane, polyamide (such as Nylon®), epoxy resin, urea resin, acrylic Powder etc. Non-limiting examples of hybrid particles include sericite and cross-linked polystyrene hybrid powder, and mica and silica hybrid powder. Opacifiers The composition of the present invention may also contain one or more opacifiers. Opacifiers are commonly used in cleaning compositions to impart desired aesthetic benefits to the composition, such as color or pearlescence. In the composition of the present invention, preferably not more than about 20% by weight, more preferably not more than about 10% by weight, and even more preferably not more than 2% by weight of the opaque agent incorporated into the composition. Suitable opacifying agents include, for example, fumed silicon dioxide, polymethylmethacrylate, micronized Teflon ®, boron nitride, barium sulfate, acrylate polymers, aluminum silicate, aluminum starch octenyl succinate, silicate Calcium, cellulose, chalk, corn starch, diatomaceous earth, fuller's earth, glycerin starch, hydrated silica, magnesium carbonate, magnesium hydroxide, magnesium oxide, magnesium trisilicate, maltodextrin, microcrystalline cellulose, Rice starch, silicon dioxide, titanium dioxide, zinc laurate, zinc myristate, zinc neodecanoate, zinc rosinate, zinc stearate, polyethylene, alumina, attapulgite, calcium carbonate, calcium silicate, Dextran, nylon, silylated silica, silk powder, soybean powder, tin oxide, titanium hydroxide, trimagnesium phosphate, walnut shell powder or mixtures thereof. The above-mentioned powders can be surface-treated with lecithin, amino acids, mineral oil, or various other agents alone or in combination, which coat the surface of the powder and make the particles hydrophobic in nature. The opacifier may also contain various organic and inorganic pigments. Organic pigments are generally of various aromatic types, including azo, indigo, triphenylmethane, anthraquinone and xanthine dyes. Inorganic pigments include iron oxide, ultramarine blue, and chromium or chromium hydroxide pigments and mixtures thereof. Suspending agent The composition of the present invention may further comprise a suspending agent at a concentration effective to suspend the water-insoluble material in the composition in a dispersed form or to change the viscosity of the composition. Such concentration is generally about 0.1% to about 10% by weight of the composition, preferably about 0.3% to about 5.0% by weight of the suspending agent. Suspending agents usable herein include anionic polymers and nonionic polymers. Usable herein are vinyl polymers, such as cross-linked acrylic polymers under the CTFA name Carbomer. Paraffins The composition of the present invention may contain one or more paraffins. Alkanes suitable for use in the compositions of the present invention include those materials known for use in hair care or other personal care compositions, such as those having a vapor pressure equal to or greater than about 21°C (about 70°F) at 1 atm. Non-limiting examples include pentane and isopentane. Propellants The composition of the present invention may also contain one or more propellants. Propellants suitable for use in the composition of the present invention include those materials known to be used in hair care or other cosmetic compositions, such as liquefied gas propellants and compressed gas propellants. Suitable propellants have a vapor pressure of less than about 21°C (about 70°F) at 1 atm. Non-limiting examples of suitable propellants are alkanes, isoalkanes, halogenated alkanes, dimethyl ether, nitrogen, nitrous oxide, carbon dioxide, and mixtures thereof. Other optional components The composition of the present invention may contain perfume. The composition of the present invention may also contain water-soluble and water-insoluble vitamins, such as vitamins B1, B2, B6, B12, C, pantothenic acid, panthenyl ethyl ether, panthenol, biotin and its derivatives, and vitamins A, D , E, and its derivatives. The composition of the present invention may also contain water-soluble and water-insoluble amino acids, such as asparagine, alanine, indole, glutamic acid and its salts, and tyrosine, tryptophan, lysine, histidine And its salt. The composition of the present invention may contain monovalent or divalent salts, such as sodium chloride. The composition of the present invention may also contain a chelating agent. The composition of the present invention may further comprise materials useful for preventing hair loss and hair growth stimulators or agents. Conditioning agent The composition may contain one or more conditioning agents. The active agent is preferably a natural or naturally derived active agent selected from starch, guar gum, non-guar gum galactomannan polymer derivatives, plant extracts, and the like. Suitable starches for the composition are those generally derived from any plant source. Non-limiting examples include corn, potato, oats, rice, cassava, sorghum, barley or corn. The conditioning active agent is preferably used in an amount of 0.01 to 20% by weight relative to the total weight of the composition. More preferably, 0.05 to 15% by weight relative to the total weight of the composition, even more preferably 0.1 to 10% by weight of the composition. The hair conditioning composition may further comprise a non-guar galactomannan polymer derivative having a mannose/galactose ratio greater than 2:1 on a monomer to monomer basis, and the non-guar galactomannan The polysaccharide polymer derivatives are selected from cationic non-guar gum galactomannan polymer derivatives and amphoteric non-guar gum polymer derivatives with a net positive charge. The term "cationic non-guar galactomannan" as used herein refers to a non-guar galactomannan polymer to which cationic groups have been added. The term "amphoteric non-guar galactomannan" refers to a non-guar galactomannan polymer to which cationic groups and anionic groups are added to make the polymer have a net positive charge. Non-guar galactomannan polymer derivatives provide improved conditioning agent effectiveness. In addition, it has been found that non-guar galactomannan polymer derivatives reduce the overall viscosity of the conditioning composition, which leads to improved sensory benefits. The gums used to prepare non-guar gum galactomannan polymer derivatives are usually obtained as naturally occurring materials such as seeds or beans from plants. Examples of various non-guar gum galactomannan polymers include, but are not limited to, tara gum (3 parts mannose/1 part galactose), locust beans or carob (4 parts mannose/1 part galactose), and Cassia gum (5 parts mannose/1 part galactose). The preferred non-guar galactomannan polymer derivative is cationic cassia gum. The cationic non-guar galactomannan polymer derivative has a molecular weight of about 1,000 to about 10,000,000. In one embodiment of the present invention, the cationic non-guar galactomannan polymer derivative has a molecular weight of about 5,000 to about 3,000,000. The term "molecular weight" as used herein refers to the weight average molecular weight. The weight average molecular weight can be measured by gel permeation chromatography. The hair conditioning composition of the present invention may comprise a non-guar galactomannan polymer derivative having a cationic charge density of about 0.7 meq/g to about 7 meq/g. In one embodiment of the invention, the non-guar galactomannan polymer derivative has a charge density of about 0.9 meq/g to about 7 meq/g. The degree of substitution of cationic groups on the non-guar galactomannan structure should be sufficient to provide the necessary cationic charge density. In one embodiment of the present invention, the non-guar galactomannan polymer derivative is obtained by the reaction between the hydroxyl group of the non-guar galactomannan polymer and a reactive quaternary ammonium compound. Cationic derivative of guar galactomannan polymer. In another embodiment of the present invention, the non-guar galactomannan polymer derivative is obtained when the cationic non-guar galactomannan polymer derivative further contains an anionic group. Charged amphoteric non-guar galactomannan polymer derivative. The hair conditioning composition may comprise from about 0.01% to about 10% by weight of the composition, more preferably from about 0.05% to about 5% by weight of the non-guar galactomannan polymer derivative. The composition may further comprise one or more selected from cellulose ether derivatives, quaternary ammonium derivatives of guar gum, homopolymers and copolymers of DADMAC, homopolymers and copolymers of MAPTAC, and quaternary ammonium derivatives of starch Material conditioning polymer. Use CTFA name, specific examples include but not limited to polyquaternium-10, guar hydroxypropyltrimonium chloride, starch hydroxypropyltrimonium chloride, polyquaternium-4, polyquaternium Ammonium-5, Polyquaternium-6, Polyquaternium-7, Polyquaternium-14, Polyquaternium-15, Polyquaternium-22, Polyquaternium-24, Polyquaternium Salt-28, Polyquaternium-32, Polyquaternium-33, Polyquaternium-36, Polyquaternium-37, Polyquaternium-39, Polyquaternium-45, Polyquaternium -47 and polymethacrylamidopropyl trimethylammonium chloride and mixtures thereof. When used, the conditioning polymer is preferably included in the composition of the present invention at a concentration of 0.1 to 10% by weight, preferably 0.2 to 6% by weight, and most preferably 0.2 to 5% by weight. Conditioning agent The conditioning composition may also contain one or more conditioning agents, such as those selected from cationic surfactants, cationic polymers, non-volatile hydrocarbons, saturated C14 to C22 linear fatty alcohols, non-volatile hydrocarbon esters, and mixtures thereof. Preferred conditioning agents are cationic surfactants, cationic polymers, saturated C14 to C22 linear fatty alcohols and quaternary ammonium salts. Plant extracts such as ginseng root extract, silybaum marianum extract, emblica fruit extract, etc. are also suitable. Its components may contain about 0.1% to about 99%, more preferably about 0.5% to about 90% of the conditioning agent. However, in the presence of an aqueous carrier, the conditioning agent preferably constitutes about 0.1% to about 90% by weight of the hair conditioning composition, more preferably about 0.5 to about 60% by weight, and most preferably about 1% to about 50% by weight. The conditioning composition also contains one or more natural stimulants to stimulate the scalp before applying the essence components. Exemplary natural stimulants include those such as ginseng and caffeine. Cationic surfactants Cationic surfactants that can be used in the composition contain amino or quaternary ammonium moieties. The cationic surfactant is preferably, but not necessarily, insoluble in its composition. Cationic surfactants usable herein are disclosed in the following documents: MC Publishing Co., McCutcheoris, Detergents Sc Emulsifiers, (North American edition 1979); Schwartz et al., Surface Active Agents, Their Chemistry and Technology, New York: Interscience Publishers , 1949; U.S. Patent 3,155,591, Hilfer, issued on November 3, 1964; U.S. Patent 3,929,678, Laughlin et al., issued on December 30, 1975; U.S. Patent 3,959,461, Bailey et al., issued on May 25, 1976; and US Patent 4,387,090, Bolich, Jr., issued on June 7, 1983. The quaternary ammonium-containing cationic surfactant materials usable herein are those having the following general formula: Wherein R1-R4 are independently an aliphatic group of about 1 to about 22 carbon atoms or an aromatic group of about 1 to about 22 carbon atoms, alkoxy groups, polyoxyalkylenes, alkylamino groups, hydroxyl groups Alkyl, aryl or alkylaryl; and X is a salt-forming anion, such as selected from halogen (eg chloride, bromide), acetate, citrate, lactate, glycolate, phosphate, nitrate, sulfuric acid Radicals and alkyl sulfate radicals. In addition to carbon and hydrogen atoms, the aliphatic group may also contain ether bonds and other groups, such as amino groups. Longer chain aliphatic groups, such as those with about 12 carbons or higher, may be saturated or unsaturated. Particularly preferred are two-long chains (for example, two C12-22, preferably C14-C20 aliphatic groups, preferably alkyl), two-short chains (for example, C1-C3 alkyl, preferably C1-C2 alkyl) and quaternary Ammonium salt. Salts of primary, secondary and tertiary fatty amines are also suitable cationic surfactant materials. The alkyl groups of such amines preferably have about 12 to about 22 carbon atoms, and may be substituted or unsubstituted. Such amines usable herein include stearylaminopropyl dimethylamine, diethylaminoethylstearylamine, dimethylstearylamine, dimethyl soyamine, soyamine, myristamine, Tridecylamine, ethylstearylamine, N-tallow propane diamine, ethoxylated (containing 5 moles of ethylene oxide) stearylamine, dihydroxyethylstearylamine and eicosyl behenylamine . Suitable amine salts include halogens, acetates, phosphates, nitrates, citrates, lactates, and alkyl sulfates. Such salts include stearylamine hydrochloride, soyamine chloride, stearylamine formate, N-tallow propane diamine dichloride, and stearylaminopropyl dimethylamine citrate. Cationic amine surfactants included among those useful in the present invention are disclosed in U.S. Patent 4,275,055, Nachtigal et al., issued June 23, 1981. The cationic surfactant is preferably used at a level of about 0.1% to about 10% by weight of the composition, more preferably about 0.25% to about 5% by weight, and most preferably about 0.5% to about 2% by weight.
