TW202130786A - Liquid crystal composition, and liquid crystal element, sensor, liquid crystal lens, optical communication device and antenna each using same - Google Patents
Liquid crystal composition, and liquid crystal element, sensor, liquid crystal lens, optical communication device and antenna each using same Download PDFInfo
- Publication number
- TW202130786A TW202130786A TW109143537A TW109143537A TW202130786A TW 202130786 A TW202130786 A TW 202130786A TW 109143537 A TW109143537 A TW 109143537A TW 109143537 A TW109143537 A TW 109143537A TW 202130786 A TW202130786 A TW 202130786A
- Authority
- TW
- Taiwan
- Prior art keywords
- group
- general formula
- liquid crystal
- diyl
- carbon atoms
- Prior art date
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
- C09K19/12—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings at least two benzene rings directly linked, e.g. biphenyls
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
- C09K19/14—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a carbon chain
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
- C09K19/14—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a carbon chain
- C09K19/16—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a carbon chain the chain containing carbon-to-carbon double bonds, e.g. stilbenes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
- C09K19/14—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a carbon chain
- C09K19/18—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a carbon chain the chain containing carbon-to-carbon triple bonds, e.g. tolans
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
- C09K19/20—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
- C09K19/24—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing nitrogen-to-nitrogen bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/32—Non-steroidal liquid crystal compounds containing condensed ring systems, i.e. fused, bridged or spiro ring systems
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/34—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/42—Mixtures of liquid crystal compounds covered by two or more of the preceding groups C09K19/06 - C09K19/40
- C09K19/44—Mixtures of liquid crystal compounds covered by two or more of the preceding groups C09K19/06 - C09K19/40 containing compounds with benzene rings directly linked
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Liquid Crystal Substances (AREA)
Abstract
Description
本發明是有關於一種液晶組成物以及使用其的液晶元件、感測器、液晶透鏡、光通訊設備及天線。The invention relates to a liquid crystal composition and a liquid crystal element, a sensor, a liquid crystal lens, an optical communication device and an antenna using the liquid crystal composition.
作為大多用於顯示器用途的液晶的新穎用途,在汽車等移動體與通訊衛星之間進行電波的收發且使用液晶的天線備受矚目。先前,衛星通訊使用拋物線天線(parabola antenna),但於在汽車等移動體中使用的情況下,必須隨時將拋物線天線朝向衛星方向,需要大的可動部。但是,使用液晶的天線藉由液晶運作,可改變電波的收發方向,因此不需要移動天線本身,天線的形狀亦可成為平面。As a novel application of liquid crystals that are mostly used for displays, antennas that use liquid crystals to transmit and receive radio waves between mobile objects such as automobiles and communication satellites are attracting attention. Previously, parabola antennas were used for satellite communications, but when used in moving objects such as cars, the parabola antenna must be directed toward the satellite at any time, requiring a large moving part. However, the antenna using liquid crystal can change the direction of radio wave transmission and reception by operating the liquid crystal, so there is no need to move the antenna itself, and the shape of the antenna can also be flat.
一般而言,對於汽車等的自動運轉而言,需要下載高精度三維(Three-dimensional,3D)地圖資訊的大量資料。但是,若為使用液晶的天線,則藉由將該天線組裝於汽車中,即便無機械可動部亦能夠自通訊衛星下載大量資料。衛星通訊中使用的頻帶約為13 GHz帶,與至今為止的液晶顯示器用途中使用的頻率大不相同。因此,對液晶的要求物性亦大不相同,天線用液晶所要求的Δn為0.4左右,運作溫度範圍為-40℃~120℃。Generally speaking, for the automatic operation of automobiles and the like, it is necessary to download a large amount of high-precision three-dimensional (3D) map information. However, in the case of an antenna using liquid crystal, by assembling the antenna in a car, a large amount of data can be downloaded from a communication satellite even if there is no mechanical movable part. The frequency band used in satellite communications is approximately the 13 GHz band, which is quite different from the frequency used in the previous liquid crystal display applications. Therefore, the required physical properties of liquid crystals are also very different. The required Δn of liquid crystals for antennas is about 0.4, and the operating temperature range is -40°C to 120°C.
另外,作為汽車等移動體的自動運轉用感測器,使用液晶的紅外線雷射圖像識別及測距裝置亦備受矚目。對該用途的液晶所要求的Δn為0.2~0.3,運作溫度範圍為-40℃~120℃。In addition, infrared laser image recognition and distance measurement devices using liquid crystals are also attracting attention as sensors for automatic operation of moving objects such as automobiles. The required Δn for liquid crystals for this purpose is 0.2 to 0.3, and the operating temperature range is -40°C to 120°C.
進而,已知構成顯示出0.2~0.4的高Δn的液晶組成物的液晶性化合物大多相容性低。因而,亦重要的是選擇相容性高的液晶性化合物。Furthermore, it is known that most of the liquid crystal compounds constituting a liquid crystal composition exhibiting a high Δn of 0.2 to 0.4 have low compatibility. Therefore, it is also important to select a liquid crystal compound with high compatibility.
對此,作為天線用液晶的技術,例如可列舉專利文獻1。In this regard, as a technique of liquid crystal for antennas, for example,
另外,於非專利文獻1中,提倡使用液晶材料作為高頻器件的構成成分。
[現有技術文獻]
[專利文獻]In addition, in Non-Patent
[專利文獻1]日本專利特開2016-37607號公報 [非專利文獻][Patent Document 1] Japanese Patent Laid-Open No. 2016-37607 [Non-Patent Literature]
[非專利文獻1]多爾菲(D.Dolfi),「電子快報(Electronics Letters)」,(英國),1993年,29卷,10號,p.926-927[Non-Patent Document 1] D. Dolfi, "Electronics Letters", (UK), 1993, Volume 29, No. 10, p.926-927
[發明所欲解決之課題]
對於天線等電磁波的相位調變中使用的液晶,要求開發能夠對微波或毫米波的電磁波進行更大的相位控制、顯示出更高的折射率各向異性(Δn)的液晶組成物。進而,於以天線為首的高頻用途的液晶組成物的領域中,亦會於室外使用或於汽車等移動媒體中驅動,因此要求進而兼具廣驅動溫度範圍與低驅動電壓的液晶材料。因此,對於該用途的液晶組成物,要求兼具用於提高驅動溫度上限溫度的高液晶相上限溫度(TNI
)、用於提高對高頻電磁波的相位調變能力的高Δn、以及用於以低電壓驅動的低臨限電壓(Vth)。然而,於所述專利文獻1記載的液晶組成物中,幾乎未示出Δn的具體值,另外,即便示出Δn,亦僅示出被認為顯示出高驅動電壓的Δε小的液晶組成物,未揭示兼具高Δn與低驅動電壓的液晶組成物。[Problems to be Solved by the Invention] Liquid crystals used in phase modulation of electromagnetic waves such as antennas require the development of greater phase control of microwave or millimeter wave electromagnetic waves and higher refractive index anisotropy (Δn ) Liquid crystal composition. Furthermore, in the field of liquid crystal compositions for high-frequency applications such as antennas, they are also used outdoors or driven in mobile media such as automobiles. Therefore, a liquid crystal material that has a wide driving temperature range and a low driving voltage is required. Therefore, for the liquid crystal composition for this purpose, it is required to have both a high liquid crystal phase upper limit temperature (T NI ) for increasing the upper limit temperature of the driving temperature, a high Δn for improving the phase modulation ability to high-frequency electromagnetic waves, and Low threshold voltage (Vth) driven by low voltage. However, the liquid crystal composition described in
因此,本發明的課題在於提供一種於能夠對微波或毫米波的電磁波進行更大的相位控制的液晶材料中,具有高TNI 、高Δn且具有用以實現元件的低驅動電壓的低Vth的向列液晶組成物、及使用其的液晶元件、感測器、液晶透鏡、光通訊設備及天線。 [解決課題之手段]Therefore, the subject of the present invention is to provide a liquid crystal material capable of greater phase control of microwave or millimeter wave electromagnetic waves, which has a high T NI , a high Δn, and a low Vth for realizing a low driving voltage of the element. Nematic liquid crystal composition, and liquid crystal element, sensor, liquid crystal lens, optical communication equipment and antenna using it. [Means to solve the problem]
本發明者等人進行努力研究的結果發現,藉由後述的液晶組成物,其含有通式(i-1)所表示的化合物的一種或兩種以上、選自通式(i-2-1a)、通式(i-2-1b)及通式(i-2-1c)中的化合物的一種或兩種以上、以及通式(ii)所表示的化合物的一種或兩種以上,可解決所述課題,從而完成本申請案發明。As a result of diligent studies conducted by the inventors, it was found that the liquid crystal composition described later contains one or two or more of the compounds represented by the general formula (i-1) selected from the general formula (i-2-1a) ), one or two or more of the compounds in the general formula (i-2-1b) and the general formula (i-2-1c), and one or two or more of the compounds represented by the general formula (ii) can be solved The above-mentioned problem has been completed to complete the invention of this application.
解決所述課題的本發明的主旨結構如下所述。The gist structure of the present invention that solves the above-mentioned problems is as follows.
本發明的液晶組成物的特徵在於含有: 下述通式(i-1)所表示的化合物的一種或兩種以上,The liquid crystal composition of the present invention is characterized by containing: One or two or more of the compounds represented by the following general formula (i-1),
[化1] [化1]
(所述通式(i-1)中, Ri1 表示碳原子數1~12的烷基、碳原子數1~8的烷氧基、碳原子數2~8的烯基、碳原子數2~8的烯氧基的任一者,該基中的一個或非鄰接的兩個以上的-CH2 -分別獨立地可由-CH=CH-、-O-、-CO-、-COO-或-OCO-取代,另外,Ri1 中存在的一個或兩個以上的氫原子分別獨立地可取代為氟原子, Ai1 、Ai2 及Ai3 分別獨立地表示選自由以下的基(a)、基(b)及基(c): (a)1,4-伸環己基(該基中存在的一個-CH2 -或非鄰接的兩個以上的-CH2 -可取代為-O-)、 (b)1,4-伸苯基(該基中存在的一個-CH=或非鄰接的兩個以上的-CH=可取代為-N=)及 (c)萘-2,6-二基、1,2,3,4-四氫萘-2,6-二基或十氫萘-2,6-二基(萘-2,6-二基或1,2,3,4-四氫萘-2,6-二基中存在的一個-CH=或非鄰接的兩個以上的-CH=可取代為-N=) 所組成的群組中的基,所述基(a)、基(b)及基(c)中的一個或兩個以上的氫原子分別獨立地可經鹵素原子、氰基或碳原子數1~6的烷基取代, mi1 表示1或2, 於Ai1 存在多個的情況下,該些可相同亦可不同); 選自下述通式(i-2-1a)、通式(i-2-1b)及通式(i-2-1c)中的化合物的一種或兩種以上,(In the general formula (i-1), R i1 represents an alkyl group having 1 to 12 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, and 2 Any one of the alkenyloxy groups of ~8, one of the groups or two or more non-adjacent -CH 2 -s may independently be -CH=CH-, -O-, -CO-, -COO- or -OCO- substitution, in addition, one or two or more hydrogen atoms present in R i1 can each independently be substituted with fluorine atoms, and A i1 , A i2 and A i3 each independently represent a group selected from the group (a), Group (b) and group (c): (a) 1,4-cyclohexylene (one -CH 2 -or two or more non-adjacent -CH 2 -in the group can be substituted with -O-) , (B) 1,4-phenylene (one -CH= or two or more non-adjacent -CH= in the group can be substituted with -N=) and (c) naphthalene-2,6-di Base, 1,2,3,4-tetrahydronaphthalene-2,6-diyl or decahydronaphthalene-2,6-diyl (naphthalene-2,6-diyl or 1,2,3,4-tetrahydronaphthalene-2,6-diyl One -CH= or two or more non-adjacent -CH= in the hydronaphthalene-2,6-diyl group can be substituted with -N=), the group (a), One or more hydrogen atoms in group (b) and group (c) may be independently substituted by halogen atoms, cyano groups or alkyl groups with 1 to 6 carbon atoms, m i1 represents 1 or 2, in A When there are multiple i1, these may be the same or different); selected from the following general formula (i-2-1a), general formula (i-2-1b) and general formula (i-2-1c) One or two or more of the compounds in
[化2] [化2]
(所述通式(i-2-1a)~通式(i-2-1c)中, R11 、R12 及R13 分別獨立地表示碳原子數2~12的炔基,該炔基中的一個或非鄰接的兩個以上的-CH2 -可取代為-O-或-S-,另外,R11 、R12 及R13 中存在的一個或兩個以上的氫原子分別獨立地可取代為氟原子或氯原子, M11 、M12 、M13 、M14 、M15 及M16 分別獨立地表示選自由以下的基(a)、基(b)及基(c):(In the general formulas (i-2-1a) to (i-2-1c), R 11 , R 12 and R 13 each independently represent an alkynyl group having 2 to 12 carbon atoms, and in the alkynyl group One or two or more non-adjacent -CH 2 -may be substituted with -O- or -S-. In addition, one or more hydrogen atoms present in R 11 , R 12 and R 13 may be independently Substituting a fluorine atom or a chlorine atom, M 11 , M 12 , M 13 , M 14 , M 15 and M 16 each independently represent a group (a), a group (b), and a group (c) selected from:
(a)1,4-伸環己基(該基中存在的一個-CH2 -或相互不鄰接的兩個以上的-CH2 -可取代為-O-或-S-)、 (b)1,4-伸苯基(該基中存在的一個-CH=或相互不鄰接的兩個以上的-CH=可取代為-N=)、3-氟-1,4-伸苯基、或3,5-二氟-1,4-伸苯基及 (c)1,4-伸環己烯基、1,4-雙環[2.2.2]伸辛基、哌啶-2,5-二基、萘-2,6-二基、1,2,3,4-四氫萘-2,6-二基、或十氫萘-2,6-二基 所組成的群組中的基, 所述基(a)、基(b)及基(c)中的一個或兩個以上的氫原子分別獨立地可經鹵素原子、氰基、三氟甲基、三氟甲氧基或碳原子數1~6的烷基取代, L11 、L12 、L13 、L14 、L15 及L16 分別獨立地表示單鍵、-COO-、-OCO-、-CH2 CH2 -、-(CH2 )4 -、-OCH2 -、-CH2 O-、-OCF2 -、-CF2 O-或-C≡C-, p、q及r分別獨立地表示0、1或2, 於M12 、M14 、M16 、L11 、L13 及/或L15 分別存在多個的情況下,該些可相同亦可不同, X11 、X12 、X13 、X14 、X15 、X16 及X17 分別獨立地表示氫原子或氟原子);以及 下述通式(ii)所表示的化合物的一種或兩種以上,(A) 1,4-cyclohexylene (one -CH 2 -existing in this group or two or more -CH 2 -not adjacent to each other can be substituted with -O- or -S-), (b) 1 ,4-phenylene (one -CH= or two or more non-adjacent -CH= in the group can be substituted with -N=), 3-fluoro-1,4-phenylene, or 3 ,5-Difluoro-1,4-phenylene and (c) 1,4-cyclohexenylene, 1,4-bicyclo[2.2.2]octylene, piperidine-2,5-diyl , Naphthalene-2,6-diyl, 1,2,3,4-tetrahydronaphthalene-2,6-diyl, or decahydronaphthalene-2,6-diyl group, the One or two or more of the hydrogen atoms in the group (a), group (b) and group (c) can be independently halogen atom, cyano group, trifluoromethyl group, trifluoromethoxy group or the number of carbon atoms. Alkyl substitution of 1 to 6, L 11 , L 12 , L 13 , L 14 , L 15 and L 16 each independently represent a single bond, -COO-, -OCO-, -CH 2 CH 2 -, -(CH 2 ) 4 -, -OCH 2 -, -CH 2 O-, -OCF 2 -, -CF 2 O- or -C≡C-, p, q and r each independently represent 0, 1 or 2, in M 12 , M 14 , M 16 , L 11 , L 13, and/or L 15 respectively exist in multiple cases, these may be the same or different, X 11 , X 12 , X 13 , X 14 , X 15 , X 16 and X 17 each independently represent a hydrogen atom or a fluorine atom); and one or two or more of the compounds represented by the following general formula (ii),
[化3] [化3]
(所述通式(ii)中, Rii1 及Rii2 分別獨立地表示氟原子、氯原子、氰基或碳原子數1~12的烷基、碳原子數1~8的烷氧基、碳原子數2~8的烯基、碳原子數2~8的烯氧基的任一者,該基中的一個或非鄰接的兩個以上的-CH2 -分別獨立地可由-CH=CH-、-C≡C-、-O-、-CO-、-COO-或-OCO-取代,另外,Rii1 及Rii2 中存在的一個或兩個以上的氫原子分別獨立地可取代為氟原子,但Rii1 及Rii2 不會同時表示選自氟原子、氯原子及氰基中的取代基, Zii1 、Zii2 及Zii3 分別獨立地表示單鍵、-OCH2 -、-CH2 O-、-C2 H4 -、-C4 H8 -、-COO-、-OCO-、-CH=CH-、-CF=CF-、-CF2 O-、-OCF2 -、-CF2 CF2 -或-C≡C-, Aii1 、Aii2 、Aii3 、Aii4 、Aii5 及Aii6 分別獨立地表示選自由以下的基(a)、基(b)及基(c): (a)1,4-伸環己基(該基中存在的一個-CH2 -或不鄰接的兩個以上的-CH2 -可取代為-O-)、 (b)1,4-伸苯基(該基中存在的一個-CH=或不鄰接的兩個以上的-CH=可取代為-N=)及 (c)萘-1,4-二基、萘-2,6-二基、1,2,3,4-四氫萘-2,6-二基或十氫萘-2,6-二基(萘-1,4-二基、萘-2,6-二基或1,2,3,4-四氫萘-2,6-二基中存在的一個-CH=或不鄰接的兩個以上的-CH=可取代為-N=) 所組成的群組中的基,所述基(a)、基(b)及基(c)中的一個或兩個以上的氫原子分別獨立地可經鹵素原子、氰基或碳原子數1~6的烷基取代, mii1 、mii2 及mii3 分別獨立地表示0或1,mii1 +mii2 +mii3 表示0或1)。(In the general formula (ii), R ii1 and R ii2 each independently represent a fluorine atom, a chlorine atom, a cyano group or an alkyl group having 1 to 12 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, and carbon Any one of an alkenyl group having 2 to 8 atoms and an alkenyloxy group having 2 to 8 carbon atoms, one of the groups or two or more non-adjacent -CH 2 -groups may be independently -CH=CH- , -C≡C- , -O-, -CO-, -COO- or -OCO- substitution, in addition, one or more hydrogen atoms present in R ii1 and R ii2 can be independently substituted with fluorine atoms , But R ii1 and R ii2 do not simultaneously represent a substituent selected from a fluorine atom, a chlorine atom and a cyano group. Z ii1 , Z ii2 and Z ii3 each independently represent a single bond, -OCH 2 -, -CH 2 O -, -C 2 H 4 -, -C 4 H 8 -, -COO-, -OCO-, -CH=CH-, -CF=CF-, -CF 2 O-, -OCF 2 -, -CF 2 CF 2 -or -C≡C-, A ii1, A ii2 , A ii3 , A ii4 , A ii5 and A ii6 each independently represent a base (a), a base (b), and a base (c) selected from the following: (A) 1,4-cyclohexylene (one -CH 2 -in the group or two or more non-adjacent -CH 2 -can be substituted with -O-), (b) 1,4-phenylene Group (one -CH= or two or more non-adjacent -CH= in the group can be substituted with -N=) and (c) naphthalene-1,4-diyl, naphthalene-2,6-diyl , 1,2,3,4-tetrahydronaphthalene-2,6-diyl or decahydronaphthalene-2,6-diyl (naphthalene-1,4-diyl, naphthalene-2,6-diyl or 1 ,2,3,4-Tetrahydronaphthalene-2,6-diyl contains one -CH= or two or more non-adjacent -CH= groups that can be substituted with -N=). , One or more of the hydrogen atoms in the group (a), group (b) and group (c) may be independently substituted by a halogen atom, a cyano group or an alkyl group having 1 to 6 carbon atoms, m ii1 , m ii2 and m ii3 each independently represent 0 or 1, and m ii1 + m ii2 + m ii3 represent 0 or 1).
另外,本發明的液晶元件及感測器的特徵在於使用所述液晶組成物。In addition, the liquid crystal element and sensor of the present invention are characterized by using the liquid crystal composition.
另外,本發明的感測器的特徵在於使用所述液晶組成物。In addition, the sensor of the present invention is characterized by using the liquid crystal composition.
另外,本發明的液晶透鏡的特徵在於使用所述液晶組成物。In addition, the liquid crystal lens of the present invention is characterized by using the liquid crystal composition.
另外,本發明的光通訊設備的特徵在於使用所述液晶組成物。In addition, the optical communication device of the present invention is characterized by using the liquid crystal composition.
另外,本發明的天線的特徵在於使用所述液晶組成物。 [發明的效果]In addition, the antenna of the present invention is characterized by using the liquid crystal composition. [Effects of the invention]
根據本發明,能夠提供一種具有高液晶相上限溫度(TNI )、高折射率各向異性(Δn),且具有用於實現元件的低驅動電壓的低臨限電壓(Vth)的向列液晶組成物,進而能夠提供一種使用其的液晶元件、感測器、液晶透鏡、光通訊設備、尤其是天線。According to the present invention, it is possible to provide a nematic liquid crystal having a high liquid crystal phase upper limit temperature (T NI ), a high refractive index anisotropy (Δn), and a low threshold voltage (Vth) for realizing a low driving voltage of the element. The composition can further provide a liquid crystal element, a sensor, a liquid crystal lens, an optical communication device, and an antenna using the same.
通式(i-1)所表示的化合物的TNI 高、Vth低,另外,Δn比較高,具有更良好的相容性。藉此,可提供常溫下穩定的液晶組成物。The compound represented by the general formula (i-1) has a high T NI and a low Vth. In addition, the Δn is relatively high and has better compatibility. Thereby, a stable liquid crystal composition at room temperature can be provided.
本發明的液晶組成物包含下述通式(i-1)所表示的化合物的一種或兩種以上。The liquid crystal composition of the present invention contains one or two or more of the compounds represented by the following general formula (i-1).
[化4] [化4]
通式(i-1)中,Ri1 表示碳原子數1~12的烷基、碳原子數1~8的烷氧基、碳原子數2~8的烯基、碳原子數2~8的烯氧基的任一者,該基中的一個或非鄰接的兩個以上的-CH2 -分別獨立地可由-CH=CH-、-O-、-CO-、-COO-或-OCO-取代,另外,Ri1 中存在的一個或兩個以上的氫原子分別獨立地可取代為氟原子。In the general formula (i-1), R i1 represents an alkyl group having 1 to 12 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, and an alkyl group having 2 to 8 carbon atoms. Any one of the alkenyloxy groups, one of the groups or two or more non-adjacent -CH 2 -s may be independently -CH=CH-, -O-, -CO-, -COO- or -OCO- Substitution, in addition, one or two or more hydrogen atoms present in R i1 can be substituted with fluorine atoms each independently.
碳原子數1~12的烷基為直鏈狀或分支狀的烷基,較佳為直鏈狀的烷基。The alkyl group having 1 to 12 carbon atoms is a linear or branched alkyl group, and preferably a linear alkyl group.
碳原子數1~12的烷基的碳原子數為1~12,較佳為1~8,較佳為1~5,較佳為2~5。The alkyl group having 1 to 12 carbon atoms has 1 to 12 carbon atoms, preferably 1 to 8, preferably 1 to 5, and more preferably 2 to 5.
作為碳原子數1~12的烷基的具體例,例如可列舉:甲基、乙基、丙基、丁基、戊基、己基、庚基、辛基、壬基、癸基、異癸基、十二烷基及2-乙基己基等。Specific examples of the alkyl group having 1 to 12 carbon atoms include, for example, methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, and isodecyl. , Dodecyl and 2-ethylhexyl, etc.
碳原子數1~8的烷氧基為直鏈狀或分支狀的烷氧基,較佳為直鏈狀的烷氧基。The alkoxy group having 1 to 8 carbon atoms is a linear or branched alkoxy group, and a linear alkoxy group is preferred.
碳原子數1~8的烷氧基的碳原子數較佳為1~8,較佳為1~5。The number of carbon atoms of the alkoxy group having 1 to 8 carbon atoms is preferably from 1 to 8, and more preferably from 1 to 5.
作為碳原子數1~8的烷氧基的具體例,例如可列舉:甲氧基、乙氧基、丙氧基、丁氧基、戊氧基、及己氧基等。Specific examples of the alkoxy group having 1 to 8 carbon atoms include, for example, a methoxy group, an ethoxy group, a propoxy group, a butoxy group, a pentoxy group, and a hexyloxy group.
碳原子數2~8的烯基為直鏈狀或分支狀的烯基,較佳為直鏈狀的烯基。The alkenyl group having 2 to 8 carbon atoms is a linear or branched alkenyl group, and a linear alkenyl group is preferred.
碳原子數2~8的烯基的碳原子數較佳為2~5,較佳為2~3。The number of carbon atoms of the alkenyl group having 2 to 8 carbon atoms is preferably from 2 to 5, and more preferably from 2 to 3.
作為碳原子數2~8的烯基的具體例,可列舉式(R1)~式(R5)所表示的基等(各式中的黑點表示環結構中的碳原子)。Specific examples of alkenyl groups having 2 to 8 carbon atoms include groups represented by formulas (R1) to (R5) (black dots in each formula represent carbon atoms in the ring structure).
[化5] [化5]
碳原子數2~8的烯氧基為直鏈狀或分支狀的烯氧基,較佳為直鏈狀的烯氧基。The alkenyloxy group having 2 to 8 carbon atoms is a linear or branched alkenyloxy group, and a linear alkenyloxy group is preferred.
碳原子數2~8的烯氧基的碳原子數較佳為2~5。The number of carbon atoms of the alkenyloxy group having 2 to 8 carbon atoms is preferably 2 to 5.
作為碳原子數2~8的烯氧基的具體例,可列舉式(R6)~式(R10)所表示的基等(各式中,黑點表示環結構中的碳原子)。Specific examples of alkenyloxy groups having 2 to 8 carbon atoms include groups represented by formulas (R6) to (R10) (in each formula, black dots indicate carbon atoms in the ring structure).
[化6] [化6]
於重視液晶組成物整體的可靠性的情況下,Ri1 較佳為碳原子數1~12的烷基,於重視液晶組成物整體的黏性降低的情況下,Ri1 較佳為碳原子數2~8的烯基。In the case where the reliability of the entire liquid crystal composition is important, R i1 is preferably an alkyl group having 1 to 12 carbon atoms, and when the reduction in the viscosity of the entire liquid crystal composition is important, R i1 is preferably the number of carbon atoms 2-8 alkenyl.
於Ri1 所鍵結的環結構為苯基(芳香族)的情況下,較佳為直鏈狀的碳原子數1~5的烷基、直鏈狀的碳原子數1~4的烷氧基及碳原子數4~5的烯基,於Ri1 所鍵結的環結構為環己烷、吡喃及二噁烷等飽和的環結構的情況下,較佳為直鏈狀的碳原子數1~5的烷基、直鏈狀的碳原子數1~4的烷氧基及直鏈狀的碳原子數2~5的烯基。When the ring structure to which R i1 is bonded is a phenyl group (aromatic), it is preferably a linear alkyl group having 1 to 5 carbon atoms, or a linear alkoxy group having 1 to 4 carbon atoms. When the ring structure to which R i1 is bonded is a saturated ring structure such as cyclohexane, pyran, and dioxane, it is preferably a linear carbon atom. An alkyl group having 1 to 5, a linear alkoxy group having 1 to 4 carbon atoms, and a linear alkenyl group having 2 to 5 carbon atoms.
另外,作為Ri1 ,為了使向列相穩定化,較佳為碳原子及存在的情況下的氧原子的合計為5以下,且較佳為直鏈狀。In addition, as R i1 , in order to stabilize the nematic phase, the total of carbon atoms and oxygen atoms when present is preferably 5 or less, and is preferably linear.
通式(i-1)中,Ai1 、Ai2 及Ai3 分別獨立地表示選自由以下的基(a)、基(b)及基(c): (a)1,4-伸環己基(該基中存在的一個-CH2 -或非鄰接的兩個以上的-CH2 -可取代為-O-)、 (b)1,4-伸苯基(該基中存在的一個-CH=或非鄰接的兩個以上的-CH=可取代為-N=)及 (c)萘-2,6-二基、1,2,3,4-四氫萘-2,6-二基或十氫萘-2,6-二基(萘-2,6-二基或1,2,3,4-四氫萘-2,6-二基中存在的一個-CH=或非鄰接的兩個以上的-CH=可取代為-N=) 所組成的群組中的基,所述基(a)、基(b)及基(c)中的一個或兩個以上的氫原子分別獨立地可經鹵素原子、氰基或碳原子數1~6的烷基取代。In the general formula (i-1), A i1 , A i2 and A i3 each independently represent a group (a), a group (b), and a group (c) selected from: (a) 1,4-cyclohexylene (One -CH 2 -existing in this group or two or more non-adjacent -CH 2 -can be substituted with -O-), (b) 1,4-phenylene (one -CH in this group = Or two or more non-adjacent -CH= can be substituted with -N=) and (c) naphthalene-2,6-diyl, 1,2,3,4-tetrahydronaphthalene-2,6-diyl Or decahydronaphthalene-2,6-diyl (naphthalene-2,6-diyl or 1,2,3,4-tetrahydronaphthalene-2,6-diyl exist one -CH= or non-contiguous Two or more -CH= can be substituted with -N=) in the group consisting of one or more hydrogen atoms in the group (a), group (b) and group (c) respectively It may be independently substituted with a halogen atom, a cyano group, or an alkyl group having 1 to 6 carbon atoms.
作為鹵素原子,可列舉氯原子、溴原子及氟原子,較佳為氟原子。Examples of the halogen atom include a chlorine atom, a bromine atom, and a fluorine atom, and a fluorine atom is preferred.
作為基(a)的具體例,可列舉以下的式(a1)~式(a5)所表示的二價的環式基等(各式中,*表示與碳原子或其他原子鍵結的鍵結鍵)。Specific examples of the group (a) include divalent cyclic groups represented by the following formulas (a1) to (a5) (in each formula, * represents a bond to a carbon atom or other atom key).
[化7] [化7]
作為基(b)的具體例,可列舉以下的式(b1)~式(b13)所表示的二價的環式基等(各式中,*表示與碳原子或其他原子鍵結的鍵結鍵)。Specific examples of the group (b) include divalent cyclic groups represented by the following formulas (b1) to (b13), etc. (in each formula, * represents a bond to a carbon atom or other atom key).
[化8] [化8]
作為基(c)的具體例,可列舉以下的式(c1)~式(c10)所表示的二價的環式基等(各式中,*表示與碳原子或其他原子鍵結的鍵結鍵)。Specific examples of the group (c) include divalent cyclic groups represented by the following formulas (c1) to (c10), etc. (in each formula, * represents a bond to a carbon atom or other atom key).
[化9] [化9]
就提高Δn的觀點而言,Ai1 、Ai2 及Ai3 分別獨立地較佳為顯示出芳香族性的二價的環式基即基(b)或基(c)。From the viewpoint of increasing Δn, A i1 , A i2 and A i3 are each independently preferably a group (b) or a group (c) which is a divalent cyclic group exhibiting aromaticity.
更具體而言,Ai1 、Ai2 及Ai3 分別獨立地較佳為(b1)~(b13)、(c1)、(c4)~(c9)的任一者,較佳為(b1)、(b3)、(b4)、(b6)、(b7)、(b10)、(b12)、(b13)、(c1)、(c5)、(c7)及(c9)的任一者,較佳為(b1)、(b6)、(b7)、(b10)、(b12)及(b13)的任一者,較佳為(b1)、(b3)、(b4)、(b6)、(b7)、(b10)、(b12)及(b13)的任一者,特佳為(b1)、(b10)及(b12)的任一者。More specifically, A i1 , A i2 and A i3 are each independently preferably any one of (b1) to (b13), (c1), (c4) to (c9), and preferably (b1), (B3), (b4), (b6), (b7), (b10), (b12), (b13), (c1), (c5), (c7) and (c9), preferably Is any one of (b1), (b6), (b7), (b10), (b12) and (b13), preferably (b1), (b3), (b4), (b6), (b7) ), (b10), (b12), and (b13), particularly preferably any one of (b1), (b10), and (b12).
關於位於分子結構的末端的Ai1 (與Ri1 鍵結的Ai1 ),亦較佳為(a1)、(a3)、(a4)、(c2)、(c3)或(c10),亦特佳為(c2)或(c10)。A i1 is located on the end of the molecular structure (A i1 R i1 and bonded), also preferably (a1), (a3), (a4), (c2), (c3) or (C10), also Laid Preferably (c2) or (c10).
Ai1 、Ai2 及Ai3 較佳為合計具有1個~5個氟原子,較佳為具有1個~4個。A i1 , A i2 and A i3 preferably have 1 to 5 fluorine atoms in total, and preferably have 1 to 4 fluorine atoms.
Ai1 、Ai2 及Ai3 較佳為合計具有0個~3個鹵素原子(氟原子除外),較佳為具有0個~2個。A i1 , A i2 and A i3 preferably have 0 to 3 halogen atoms (excluding fluorine atoms) in total, and preferably have 0 to 2 halogen atoms.
Ai1 、Ai2 及Ai3 較佳為合計具有1個~5個鹵素原子(含氟原子),更佳為具有1個~4個。A i1 , A i2 and A i3 preferably have 1 to 5 halogen atoms (fluorine atoms) in total, and more preferably have 1 to 4 halogen atoms.
本發明的通式(i-1)所表示的化合物具有與Ai3 鍵結的氰基,但除了該氰基以外,一分子中的環結構即Ai1 、Ai2 及Ai3 亦可合計具有1個~3個氰基。The compound represented by the general formula (i-1) of the present invention has a cyano group bonded to A i3 , but in addition to the cyano group, the ring structures in one molecule, namely A i1 , A i2, and A i3 may have a total of 1 to 3 cyano groups.
另外,於Ai1 存在多個的情況下,該些可相同亦可不同。In addition, when there are multiple A i1 , these may be the same or different.
mi1 表示1或2。若mi1 為1或2,則通式(i-1)所表示的化合物相當於三環~四環的液晶化合物,TNI 高,顯示出與其他液晶化合物的高相容性。此處,於重視對液晶組成物的溶解性的情況下,mi1 較佳為0,於重視Δn及TNI 的情況下較佳為1。m i1 represents 1 or 2. If m i1 is 1 or 2, the compound represented by the general formula (i-1) corresponds to a tricyclic to tetracyclic liquid crystal compound, has a high T NI , and shows high compatibility with other liquid crystal compounds. Here, in the case where the solubility to the liquid crystal composition is important, mi1 is preferably 0, and in the case where Δn and T NI are important, it is preferably 1.
就進一步提高液晶組成物的相容性的觀點而言,mi1 較佳為1。From the viewpoint of further improving the compatibility of the liquid crystal composition, mi1 is preferably 1.
所述通式(i-1)所表示的化合物較佳為以下的通式(i-1-1)所表示的化合物。The compound represented by the general formula (i-1) is preferably a compound represented by the following general formula (i-1-1).
[化10] [化10]
通式(i-1-1)中,Xi1-1 ~Xi9-1 分別獨立地表示氫原子或氟原子,但Xi1-1 與Xi2-1 不會同時表示氟原子,Xi3-1 與Xi4-1 不會同時表示氟原子,Xi5-1 與Xi6-1 不會同時表示氟原子。 通式(i-1-1)中,Ri1 與所述通式(i-1)中的Ri1 相同,較佳的基、較佳的個數亦相同,因此省略此處的說明。In the general formula (i-1-1), X i1-1 to X i9-1 each independently represent a hydrogen atom or a fluorine atom, but X i1-1 and X i2-1 do not simultaneously represent a fluorine atom, and X i3- 1 and X i4-1 do not simultaneously represent a fluorine atom, and X i5-1 and X i6-1 do not simultaneously represent a fluorine atom. In the general formula (i-1-1), the same as in the general formula R i1 (i1) R i1, preferred groups, preferred are also the same number, so description thereof is omitted here.
於Xi1-1 ~Xi9-1 中,Xi1-1 與Xi2-1 不會同時表示氟原子,Xi3-1 與Xi4-1 不會同時表示氟原子,Xi5-1 與Xi6-1 不會同時表示氟原子,因此通式(i-1-1)所表示的液晶化合物的介電常數各向異性(Δε)容易顯示0以上,對低Vth化較佳。In X i1-1 to X i9-1 , X i1-1 and X i2-1 do not represent fluorine atoms at the same time, X i3-1 and X i4-1 do not represent fluorine atoms at the same time, X i5-1 and X i6-1 does not simultaneously represent a fluorine atom, and therefore the dielectric constant anisotropy (Δε) of the liquid crystal compound represented by the general formula (i-1-1) tends to show 0 or more, which is preferable for low Vth.
就增大正介電常數各向異性的值的觀點而言,較佳為Xi2-1 、Xi4-1 、Xi5-1 及Xi6-1 的至少一個以上表示氟原子。另外,若於環結構的側位導入氟原子等鹵素原子,則相容性提高,因此較佳。藉由使用通式(i-1-1)所表示的化合物,容易確保常溫保存穩定性。From the viewpoint of increasing the value of the positive dielectric constant anisotropy, it is preferable that at least one of X i2-1 , X i4-1 , X i5-1 and X i6-1 represents a fluorine atom. In addition, if a halogen atom such as a fluorine atom is introduced into the side position of the ring structure, the compatibility is improved, which is preferable. By using the compound represented by the general formula (i-1-1), it is easy to ensure the storage stability at room temperature.
通式(i-1-1)所表示的化合物的一分子中的環結構,即三個苯環較佳為合計具有1個~5個氟原子,更佳為具有1個~4個。The ring structure in one molecule of the compound represented by general formula (i-1-1), that is, three benzene rings, preferably has 1 to 5 fluorine atoms in total, and more preferably has 1 to 4 fluorine atoms.
另外,作為Xi1-1 ~Xi9-1 中的組合,可列舉Xi4-1 表示氟原子,Xi1-1 ~Xi3-1 、Xi5-1 ~Xi9-1 表示氫原子的組合。In addition, as combinations of X i1-1 to X i9-1 , X i4-1 represents a fluorine atom, and X i1-1 to X i3-1 and X i5-1 to X i9-1 represent a combination of hydrogen atoms. .
所述通式(i-1)所表示的化合物較佳為以下的通式(i-1-2)所表示的化合物。The compound represented by the general formula (i-1) is preferably a compound represented by the following general formula (i-1-2).
[化11] [化11]
通式(i-1-2)中,Xi1-2 ~Xi3-2 、Xi5-2 ~Xi7-2 及Xi9-2 分別獨立地表示氫原子或氟原子,但Xi1-2 與Xi2-2 不會同時表示氟原子,Xi5-2 與Xi6-2 不會同時表示氟原子。 通式(i-1-2)中,Ri1 與所述通式(i-1)中的Ri1 相同,較佳的基、較佳的個數亦相同,因此省略此處的說明。In the general formula (i-1-2), X i1-2 to X i3-2 , X i5-2 to X i7-2, and X i9-2 each independently represent a hydrogen atom or a fluorine atom, but X i1-2 X i2-2 and X i2-2 do not simultaneously represent a fluorine atom, and X i5-2 and X i6-2 do not simultaneously represent a fluorine atom. In the general formula (i-1-2), the same as in the general formula R i1 (i1) R i1, preferred groups, preferred are also the same number, so description thereof is omitted here.
於Xi1-2 ~Xi3-2 、Xi5-2 ~Xi7-2 及Xi9-2 中,Xi1-2 與Xi2-2 不會同時表示氟原子,Xi5-2 與Xi6-2 不會同時表示氟原子,因此通式(i-1-2)所表示的液晶化合物的介電常數各向異性(Δε)容易顯示0以上,對低Vth化較佳。In X i1-2 ~X i3-2 , X i5-2 ~X i7-2 and X i9-2 , X i1-2 and X i2-2 do not simultaneously represent fluorine atoms, X i5-2 and X i6 Since -2 does not simultaneously represent a fluorine atom, the dielectric constant anisotropy (Δε) of the liquid crystal compound represented by the general formula (i-1-2) tends to show 0 or more, which is preferable for low Vth.
就增大正介電常數各向異性的值的觀點而言,較佳為Xi2-1 、Xi5-1 及Xi6-1 的至少一個以上表示氟原子。另外,若於環結構的側位導入氟原子等鹵素原子,則相容性提高,因此較佳。藉由使用通式(i-1-2)所表示的化合物,容易確保常溫保存穩定性。From the viewpoint of increasing the value of the positive dielectric constant anisotropy, it is preferable that at least one of X i2-1 , X i5-1 and X i6-1 represents a fluorine atom. In addition, if a halogen atom such as a fluorine atom is introduced into the side position of the ring structure, the compatibility is improved, which is preferable. By using the compound represented by the general formula (i-1-2), it is easy to ensure the storage stability at room temperature.
通式(i-1-2)所表示的化合物的一分子中的環結構,即一個吡啶環以及兩個苯環較佳為合計具有1個~5個氟原子,更佳為具有1個~4個。The ring structure in one molecule of the compound represented by the general formula (i-1-2), that is, one pyridine ring and two benzene rings, preferably have 1 to 5 fluorine atoms in total, more preferably 1 to 5 fluorine atoms in total. 4.
所述通式(i-1)所表示的化合物較佳為以下的通式(i-1-3)所表示的化合物。The compound represented by the general formula (i-1) is preferably a compound represented by the following general formula (i-1-3).
[化12] [化12]
通式(i-1-3)中,Xi1-3 ~Xi9-3 分別獨立地表示氫原子或氟原子,但Xi1-3 與Xi2-3 不會同時表示氟原子,Xi3-3 與Xi4-3 不會同時表示氟原子,Xi5-3 與Xi6-3 不會同時表示氟原子。In the general formula (i-1-3), X i1-3 to X i9-3 each independently represent a hydrogen atom or a fluorine atom, but X i1-3 and X i2-3 do not simultaneously represent a fluorine atom, and X i3- 3 and X i4-3 do not simultaneously represent a fluorine atom, and X i5-3 and X i6-3 do not simultaneously represent a fluorine atom.
通式(i-1-3)中,Ri1 與所述通式(i-1)中的Ri1 相同,較佳的基、較佳的個數亦相同,因此省略此處的說明。In the general formula (i-1-3), the same as in the general formula R i1 (i1) R i1, preferred groups, preferred are also the same number, so description thereof is omitted here.
於Xi1-3 ~Xi9-3 中,Xi1-3 與Xi2-3 不會同時表示氟原子,Xi3-3 與Xi4-3 不會同時表示氟原子,Xi5-3 與Xi6-3 不會同時表示氟原子,因此通式(i-1-3)所表示的液晶化合物的介電常數各向異性(Δε)容易顯示0以上,對低Vth化較佳。In X i1-3 to X i9-3 , X i1-3 and X i2-3 do not represent fluorine atoms at the same time, X i3-3 and X i4-3 do not represent fluorine atoms at the same time, X i5-3 and X Since i6-3 does not simultaneously represent a fluorine atom, the dielectric constant anisotropy (Δε) of the liquid crystal compound represented by the general formula (i-1-3) tends to show 0 or more, which is preferable for low Vth.
就增大正介電常數各向異性的值的觀點而言,較佳為Xi2-3 、Xi4-3 、Xi6-3 、Xi7-3 、Xi8-3 及Xi9-3 的至少一個以上表示氟原子。另外,若於環結構的側位導入氟原子等鹵素原子,則相容性提高,因此較佳。藉由使用通式(i-1-3)所表示的化合物,容易確保常溫保存穩定性。From the viewpoint of increasing the value of the positive dielectric constant anisotropy, it is preferably at least X i2-3 , X i4-3 , X i6-3 , X i7-3 , X i8-3 and X i9-3 One or more represents a fluorine atom. In addition, if a halogen atom such as a fluorine atom is introduced into the side position of the ring structure, the compatibility is improved, which is preferable. By using the compound represented by the general formula (i-1-3), it is easy to ensure the storage stability at room temperature.
通式(i-1-3)所表示的化合物的一分子中的環結構,即一個萘環以及兩個苯環較佳為合計具有1個~5個氟原子,更佳為具有1個~4個。The ring structure in one molecule of the compound represented by the general formula (i-1-3), that is, one naphthalene ring and two benzene rings, preferably have 1 to 5 fluorine atoms in total, more preferably 1 to 5 fluorine atoms. 4.
所述通式(i-1)所表示的化合物較佳為以下的通式(i-1-4)所表示的化合物。The compound represented by the general formula (i-1) is preferably a compound represented by the following general formula (i-1-4).
[化13] [化13]
通式(i-1-4)中,Xi2-4 ~Xi9-4 分別獨立地表示氫原子或氟原子,但Xi3-4 與Xi4-4 不會同時表示氟原子,Xi5-4 與Xi6-4 不會同時表示氟原子。In the general formula (i-1-4), X i2-4 to X i9-4 each independently represent a hydrogen atom or a fluorine atom, but X i3-4 and X i4-4 do not simultaneously represent a fluorine atom, and X i5- 4 and X i6-4 do not simultaneously represent a fluorine atom.
通式(i-1-4)中,Ri1 與所述通式(i-1)中的Ri1 相同,較佳的基、較佳的個數亦相同,因此省略此處的說明。In the general formula (i-1-4), the same as in the general formula R i1 (i1) R i1, preferred groups, preferred are also the same number, so description thereof is omitted here.
於Xi2-4 ~Xi9-4 中,Xi3-4 與Xi4-4 不會同時表示氟原子,Xi5-4 與Xi6-4 不會同時表示氟原子,因此通式(i-1-4)所表示的液晶化合物的介電常數各向異性(Δε)容易顯示0以上,對低Vth化較佳。In X i2-4 to X i9-4 , X i3-4 and X i4-4 do not simultaneously represent fluorine atoms, and X i5-4 and X i6-4 do not simultaneously represent fluorine atoms. Therefore, the general formula (i- 1-4) The dielectric constant anisotropy (Δε) of the liquid crystal compound represented is easy to show 0 or more, and it is preferable to lower the Vth.
就增大正介電常數各向異性的值的觀點而言,較佳為Xi2-4 、Xi4-4 、Xi6-4 、Xi7-4 、Xi8-4 及Xi9-4 的至少一個以上表示氟原子。另外,若於環結構的側位導入氟原子等鹵素原子,則相容性提高,因此較佳。藉由使用通式(i-1-4)所表示的化合物,容易確保常溫保存穩定性。From the viewpoint of increasing the value of the positive dielectric constant anisotropy, it is preferably at least X i2-4 , X i4-4 , X i6-4 , X i7-4 , X i8-4 and X i9-4 One or more represents a fluorine atom. In addition, if a halogen atom such as a fluorine atom is introduced into the side position of the ring structure, the compatibility is improved, which is preferable. By using the compound represented by the general formula (i-1-4), it is easy to ensure the storage stability at room temperature.
通式(i-1-4)所表示的化合物的一分子中的環結構,即一個四氫萘環以及兩個苯環較佳為合計具有1個~5個氟原子,更佳為具有1個~4個。The ring structure in one molecule of the compound represented by the general formula (i-1-4), that is, one tetralin ring and two benzene rings, preferably have 1 to 5 fluorine atoms in total, more preferably 1 ~4.
作為通式(i-1-1)的具體結構,可列舉下述結構式(i-1-1.1)~結構式(i-1-1.6)所表示的化合物。As a specific structure of general formula (i-1-1), the compound represented by the following structural formula (i-1-1.1)-structural formula (i-1-1.6) is mentioned.
[化14] [化14]
作為通式(i-1-2)的具體結構,可列舉下述結構式(i-1-2.1)~結構式(i-1-2.4)所表示的化合物。As a specific structure of general formula (i-1-2), the compound represented by the following structural formula (i-1-2.1)-structural formula (i-1-2.4) is mentioned.
[化15] [化15]
通式(i-1)、通式(i-1-1)~通式(i-1-4)、結構式(i-1-1.1)~結構式(i-1-1.6)或結構式(i-1-2.1)~結構式(i-1-2.4)所表示的化合物可單獨使用,或者亦可組合使用兩種以上。能夠組合的化合物的種類並無特別限制,對應於介電常數各向異性、常溫下的溶解性、轉變溫度、雙折射率等所期望的性能適宜組合使用。General formula (i-1), general formula (i-1-1) ~ general formula (i-1-4), structural formula (i-1-1.1) ~ structural formula (i-1-1.6) or structural formula The compounds represented by (i-1-2.1) to structural formula (i-1-2.4) may be used alone, or two or more of them may be used in combination. The types of compounds that can be combined are not particularly limited, and they are suitably used in combination in accordance with desired properties such as dielectric anisotropy, solubility at room temperature, transition temperature, and birefringence.
所使用的通式(i-1)、通式(i-1-1)~通式(i-1-4)、結構式(i-1-1.1)~結構式(i-1-1.6)或結構式(i-1-2.1)~結構式(i-1-2.4)所表示的化合物的種類為一種、兩種、三種、四種、五種、六種、七種、八種、九種、十種以上。Used general formula (i-1), general formula (i-1-1) ~ general formula (i-1-4), structural formula (i-1-1.1) ~ structural formula (i-1-1.6) Or the types of compounds represented by structural formula (i-1-2.1) to structural formula (i-1-2.4) are one, two, three, four, five, six, seven, eight, nine More than ten kinds.
通式(i-1)、通式(i-1-1)~通式(i-1-4)、結構式(i-1-1.1)~結構式(i-1-1.6)或結構式(i-1-2.1)~結構式(i-1-2.4)所表示的化合物於液晶組成物100質量%中的合計含量的下限值較佳為1質量%,較佳為2質量%,較佳為5質量%,較佳為8質量%,較佳為10質量%,較佳為13質量%,較佳為15質量%,較佳為18質量%,較佳為20質量%,較佳為22質量%,較佳為25質量%,較佳為30質量%,較佳為40質量%,較佳為50質量%,較佳為55質量%,較佳為60質量%,較佳為65質量%,較佳為70質量%。General formula (i-1), general formula (i-1-1) ~ general formula (i-1-4), structural formula (i-1-1.1) ~ structural formula (i-1-1.6) or structural formula The lower limit of the total content of the compound represented by (i-1-2.1) to structural formula (i-1-2.4) in 100% by mass of the liquid crystal composition is preferably 1% by mass, more preferably 2% by mass, Preferably it is 5% by mass, more preferably 8% by mass, more preferably 10% by mass, more preferably 13% by mass, more preferably 15% by mass, more preferably 18% by mass, more preferably 20% by mass, more Preferably it is 22% by mass, more preferably 25% by mass, more preferably 30% by mass, preferably 40% by mass, more preferably 50% by mass, more preferably 55% by mass, more preferably 60% by mass, more preferably It is 65% by mass, preferably 70% by mass.
若含量多則會引起析出等問題,因此通式(i-1)、通式(i-1-1)~通式(i-1-4)、結構式(i-1-1.1)~結構式(i-1-1.6)或結構式(i-1-2.1)~結構式(i-1-2.4)所表示的化合物於液晶組成物100質量%中的合計含量的上限值較佳為85質量%,較佳為80質量%,較佳為75質量%,較佳為70質量%,較佳為65質量%,較佳為55質量%,較佳為45質量%,較佳為35質量%,較佳為30質量%,較佳為28質量%,較佳為25質量%,較佳為23質量%,較佳為20質量%,較佳為18質量%,較佳為15質量%。If the content is too large, it will cause problems such as precipitation, so general formula (i-1), general formula (i-1-1) ~ general formula (i-1-4), structural formula (i-1-1.1) ~ structure The upper limit of the total content of the compound represented by formula (i-1-1.6) or structural formula (i-1-2.1) to structural formula (i-1-2.4) in 100% by mass of the liquid crystal composition is preferably 85% by mass, preferably 80% by mass, preferably 75% by mass, preferably 70% by mass, preferably 65% by mass, preferably 55% by mass, preferably 45% by mass, preferably 35 Mass%, preferably 30% by mass, preferably 28% by mass, preferably 25% by mass, preferably 23% by mass, preferably 20% by mass, preferably 18% by mass, preferably 15% by mass %.
通式(i-1)、通式(i-1-1)~通式(i-1-4)、結構式(i-1-1.1)~結構式(i-1-1.6)或結構式(i-1-2.1)~結構式(i-1-2.4)所表示的化合物於液晶組成物100質量%中的合計含量較佳為5質量%~55質量%,較佳為10質量%~50質量%。General formula (i-1), general formula (i-1-1) ~ general formula (i-1-4), structural formula (i-1-1.1) ~ structural formula (i-1-1.6) or structural formula (I-1-2.1) ~ The total content of the compound represented by the structural formula (i-1-2.4) in 100% by mass of the liquid crystal composition is preferably 5 mass% to 55% by mass, more preferably 10 mass% to 50% by mass.
另外,通式(i-1-1)所表示的化合物於液晶組成物100質量%中的合計含量較佳為5質量%~55質量%,較佳為10質量%~50質量%。In addition, the total content of the compound represented by the general formula (i-1-1) in 100% by mass of the liquid crystal composition is preferably 5% by mass to 55% by mass, more preferably 10% by mass to 50% by mass.
通式(i-1)、通式(i-1-1)~通式(i-1-4)、結構式(i-1-1.1)~結構式(i-1-1.6)或結構式(i-1-2.1)~結構式(i-1-2.4)所表示的化合物可藉由公知的方法進行製造。General formula (i-1), general formula (i-1-1) ~ general formula (i-1-4), structural formula (i-1-1.1) ~ structural formula (i-1-1.6) or structural formula The compound represented by (i-1-2.1) to structural formula (i-1-2.4) can be produced by a known method.
本發明的液晶組成物包含一種或兩種以上的下述通式(i-2-1a)、通式(i-2-1b)及通式(i-2-1c)所表示的化合物。The liquid crystal composition of the present invention contains one or two or more compounds represented by the following general formula (i-2-1a), general formula (i-2-1b), and general formula (i-2-1c).
[化16] [化16]
所述通式(i-2-1a)~通式(i-2-1c)中,R11 、R12 及R13 分別獨立地表示碳原子數2~12的炔基,該炔基中的一個或非鄰接的兩個以上的-CH2 -可取代為-O-或-S-,另外,R11 、R12 及R13 中存在的一個或兩個以上的氫原子分別獨立地可取代為氟原子或氯原子。In the general formulas (i-2-1a) to (i-2-1c), R 11 , R 12 and R 13 each independently represent an alkynyl group having 2 to 12 carbon atoms. One or two or more non-adjacent -CH 2 -can be substituted with -O- or -S-, and one or more hydrogen atoms in R 11 , R 12 and R 13 can be substituted independently. It is a fluorine atom or a chlorine atom.
碳原子數2~12的炔基為直鏈狀或分支狀的炔基,較佳為直鏈狀的炔基。The alkynyl group having 2 to 12 carbon atoms is a linear or branched alkynyl group, and a linear alkynyl group is preferred.
碳原子數2~12的炔基的碳原子數較佳為2~8。The alkynyl group having 2 to 12 carbon atoms preferably has 2 to 8 carbon atoms.
作為碳原子數2~12的炔基的具體例,可列舉式(R11)~式(R15)所表示的基等(各式中的黑點表示環結構中的碳原子)。Specific examples of the alkynyl group having 2 to 12 carbon atoms include groups represented by formulas (R11) to (R15) (black dots in each formula represent carbon atoms in the ring structure).
[化17] [化17]
M11 、M12 、M13 、M14 、M15 及M16 分別獨立地表示選自由下述的基(a)、基(b)及基(c): (a)1,4-伸環己基(該基中存在的一個-CH2 -或相互不鄰接的兩個以上的-CH2 -可取代為-O-或-S-)、 (b)1,4-伸苯基(該基中存在的一個-CH=或相互不鄰接的兩個以上的-CH=可取代為-N=)、3-氟-1,4-伸苯基、或3,5-二氟-1,4-伸苯基及 (c)1,4-伸環己烯基、1,4-雙環[2.2.2]伸辛基、哌啶-2,5-二基、萘-2,6-二基、1,2,3,4-四氫萘-2,6-二基、或十氫萘-2,6-二基所組成的群組中的基,所述基(a)、基(b)及基(c)中的一個或兩個以上的氫原子分別獨立地可經鹵素原子、氰基、三氟甲基或三氟甲氧基或碳原子數1~6的烷基取代。M 11 , M 12 , M 13 , M 14 , M 15 and M 16 each independently represent a group selected from the following groups (a), group (b), and group (c): (a) 1,4- extension ring Hexyl (one -CH 2 -existing in the group or two or more -CH 2 -not adjacent to each other can be substituted with -O- or -S-), (b) 1,4-phenylene (the group One -CH= or two or more -CH= that are not adjacent to each other can be substituted with -N=), 3-fluoro-1,4-phenylene, or 3,5-difluoro-1,4 -Phenylene and (c) 1,4-cyclohexenylene, 1,4-bicyclo[2.2.2]octylene, piperidine-2,5-diyl, naphthalene-2,6-diyl , 1,2,3,4-tetrahydronaphthalene-2,6-diyl, or decahydronaphthalene-2,6-diyl group consisting of a group, the group (a), group (b One or two or more hydrogen atoms in the group (c) and group (c) may be independently substituted with a halogen atom, a cyano group, a trifluoromethyl group or a trifluoromethoxy group, or an alkyl group having 1 to 6 carbon atoms.
作為鹵素原子,可列舉:氯原子、溴原子、氟原子。Examples of the halogen atom include a chlorine atom, a bromine atom, and a fluorine atom.
L11 、L12 、L13 、L14 、L15 及L16 分別獨立地表示單鍵、-COO-、-OCO-、-CH2 CH2 -、-(CH2 )4 -、-OCH2 -、-CH2 O-、-OCF2 -、-CF2 O-或-C≡C-, p、q、r分別獨立地表示0、1或2。L 11 , L 12 , L 13 , L 14 , L 15 and L 16 each independently represent a single bond, -COO-, -OCO-, -CH 2 CH 2 -, -(CH 2 ) 4 -, -OCH 2 -, -CH 2 O-, -OCF 2 -, -CF 2 O- or -C≡C-, p, q, and r each independently represent 0, 1, or 2.
於M12 、M14 、M16 、L11 、L13 及/或L15 分別存在多個的情況下,該些可相同亦可不同, X11 、X12 、X13 、X14 、X15 、X16 及X17 分別獨立地表示氫原子或氟原子。When there are a plurality of M 12 , M 14 , M 16 , L 11 , L 13 and/or L 15 respectively, these may be the same or different, X 11 , X 12 , X 13 , X 14 , X 15 , X 16 and X 17 each independently represent a hydrogen atom or a fluorine atom.
所述通式(i-2-1a)所表示的化合物較佳為以下的通式(i-2-1a-1)所表示的化合物。藉由使用通式(i-2-1a-1)所表示的化合物,可獲得實現高Δn,同時具有廣溫度範圍的液晶相、黏性小、低溫下的溶解性良好、比電阻或電壓保持率高、對熱或光穩定的組成物。The compound represented by the general formula (i-2-1a) is preferably a compound represented by the following general formula (i-2-1a-1). By using the compound represented by the general formula (i-2-1a-1), it is possible to achieve high Δn, while having a wide temperature range of liquid crystal phase, low viscosity, good solubility at low temperatures, specific resistance or voltage retention It is a composition with high efficiency and stable to heat or light.
[化18] [化18]
通式(i-2-1a-1)中,X18 ~X20 分別獨立地表示氫原子或氟原子,但X18 與X20 不會同時表示氟原子。In the general formula (i-2-1a-1), X 18 to X 20 each independently represent a hydrogen atom or a fluorine atom, but X 18 and X 20 do not simultaneously represent a fluorine atom.
另外,較佳為X11 、X12 及/或X18 的至少一個為氟原子,且X19 及X20 為氫原子。In addition, it is preferable that at least one of X 11 , X 12 and/or X 18 is a fluorine atom, and X 19 and X 20 are hydrogen atoms.
通式(i-2-1a-1)中,R1 、X11 及X12 與所述通式(i-2-1a)中的R11 、X11 及X12 相同,因此省略此處的說明。In the general formula (i-2-1a-1), R 1 , X 11 and X 12 are the same as R 11 , X 11 and X 12 in the general formula (i-2-1a), so the description here is omitted illustrate.
另外,作為X11 ~X12 、X18 ~X20 的組合,可列舉:X18 表示氟原子,X11 ~X12 、X19 ~X20 表示氫原子的組合;X11 ~X12 、X18 ~X20 表示氫原子的組合。In addition, examples of combinations of X 11 to X 12 and X 18 to X 20 include: X 18 represents a fluorine atom, X 11 to X 12 , and X 19 to X 20 represent a combination of hydrogen atoms; X 11 to X 12 , X 18 to X 20 represent a combination of hydrogen atoms.
作為通式(i-2-1a-1)的具體結構,可列舉下述結構式(i-2-1a-1.1)~結構式(i-2-1a-1.12)所表示的化合物。As a specific structure of general formula (i-2-1a-1), the compound represented by the following structural formula (i-2-1a-1.1)-structural formula (i-2-1a-1.12) is mentioned.
[化19] [化19]
本發明的液晶組成物較佳為含有至少一種或兩種以上的通式(i-2-1a)~通式(i-2-1c)、通式(i-2-1a-1)或結構式(i-2-1a-1.1)~結構式(i-2-1a-1.12)所表示的化合物,較佳為含有兩種~八種。The liquid crystal composition of the present invention preferably contains at least one or two or more of general formula (i-2-1a) to general formula (i-2-1c), general formula (i-2-1a-1) or structure The compounds represented by formula (i-2-1a-1.1) to structural formula (i-2-1a-1.12) preferably contain two to eight types.
於本發明的液晶組成物中,通式(i-2-1a)~通式(i-2-1c)、通式(i-2-1a-1)或結構式(i-2-1a-1.1)~結構式(i-2-1a-1.12)所表示的化合物於液晶組成物100質量%中的合計含量的下限值較佳為1質量%,較佳為2質量%,較佳為3質量%,較佳為5質量%,較佳為7質量%,較佳為8質量%,較佳為9質量%,較佳為10質量%,較佳為12質量%,較佳為13質量%,較佳為15質量%,較佳為17質量%,較佳為18質量%,較佳為20質量%,較佳為25質量%,較佳為30質量%,較佳為35質量%,較佳為40質量%。In the liquid crystal composition of the present invention, the general formula (i-2-1a) to the general formula (i-2-1c), the general formula (i-2-1a-1) or the structural formula (i-2-1a- 1.1) ~ The lower limit of the total content of the compound represented by the structural formula (i-2-1a-1.12) in 100% by mass of the liquid crystal composition is preferably 1% by mass, more preferably 2% by mass, more preferably 3 mass%, preferably 5 mass%, preferably 7 mass%, preferably 8 mass%, preferably 9 mass%, preferably 10 mass%, preferably 12 mass%, preferably 13 Mass%, preferably 15 mass%, preferably 17 mass%, preferably 18 mass%, preferably 20 mass%, preferably 25 mass%, preferably 30 mass%, preferably 35 mass% %, preferably 40% by mass.
另外,於本發明的液晶組成物中,通式(i-2-1a)~通式(i-2-1c)、通式(i-2-1a-1)或結構式(i-2-1a-1.1)~結構式(i-2-1a-1.12)所表示的化合物於液晶組成物100質量%中的合計含量的上限值較佳為60質量%,較佳為50質量%,較佳為40質量%,較佳為35質量%,較佳為30質量%,較佳為25質量%,較佳為20質量%,較佳為18質量%,較佳為15質量%,較佳為13質量%,較佳為10質量%,較佳為5質量%,較佳為3質量%。In addition, in the liquid crystal composition of the present invention, the general formula (i-2-1a) to the general formula (i-2-1c), the general formula (i-2-1a-1) or the structural formula (i-2- 1a-1.1) ~ The upper limit of the total content of the compound represented by the structural formula (i-2-1a-1.12) in 100% by mass of the liquid crystal composition is preferably 60% by mass, more preferably 50% by mass, and Preferably it is 40% by mass, more preferably 35% by mass, more preferably 30% by mass, more preferably 25% by mass, more preferably 20% by mass, more preferably 18% by mass, more preferably 15% by mass, more preferably It is 13% by mass, preferably 10% by mass, preferably 5% by mass, and preferably 3% by mass.
通式(i-2-1a)~通式(i-2-1c)、通式(i-2-1a-1)或結構式(i-2-1a-1.1)~結構式(i-2-1a-1.12)所表示的化合物於液晶組成物100質量%中的合計含量具體而言較佳為20質量%~55質量%,較佳為25質量%~50質量%。General formula (i-2-1a) ~ general formula (i-2-1c), general formula (i-2-1a-1) or structural formula (i-2-1a-1.1) ~ structural formula (i-2 The total content of the compound represented by -1a-1.12) in 100% by mass of the liquid crystal composition is specifically preferably 20% by mass to 55% by mass, and more preferably 25% by mass to 50% by mass.
另外,通式(i-2-1a-1)所表示的化合物於液晶組成物100質量%中的合計含量較佳為20質量%~55質量%,較佳為25質量%~50質量%。In addition, the total content of the compound represented by the general formula (i-2-1a-1) in 100% by mass of the liquid crystal composition is preferably 20% by mass to 55% by mass, more preferably 25% by mass to 50% by mass.
通式(i-2-1a)~通式(i-2-1c)、通式(i-2-1a-1)或結構式(i-2-1a-1.1)~結構式(i-2-1a-1.12)所表示的化合物可藉由公知的方法進行製造。General formula (i-2-1a) ~ general formula (i-2-1c), general formula (i-2-1a-1) or structural formula (i-2-1a-1.1) ~ structural formula (i-2 The compound represented by -1a-1.12) can be produced by a known method.
本發明的液晶組成物包含下述通式(ii)所表示的化合物的一種或兩種以上。The liquid crystal composition of the present invention contains one or two or more of the compounds represented by the following general formula (ii).
[化20] [化20]
通式(ii)所表示的化合物具有高TNI 及高Δn。與所述通式(i-1)、通式(i-2-1a)、通式(i-2-1b)及通式(i-2-1c)所表示的化合物的相容性優異,藉由組合通式(i-1)、通式(i-2-1a)、通式(i-2-1b)及通式(i-2-1c)所表示的化合物與通式(ii)所表示的化合物,可提供兼具高TNI 、高Δn以及低Vth的液晶組成物。The compound represented by the general formula (ii) has high T NI and high Δn. It has excellent compatibility with the compounds represented by the general formula (i-1), the general formula (i-2-1a), the general formula (i-2-1b) and the general formula (i-2-1c), By combining compounds represented by general formula (i-1), general formula (i-2-1a), general formula (i-2-1b) and general formula (i-2-1c) with general formula (ii) The compound shown can provide a liquid crystal composition having high T NI , high Δn, and low Vth.
通式(ii)中,Rii1 及Rii2 分別獨立地表示氟原子、氯原子、氰基、碳原子數1~12的烷基、碳原子數1~8的烷氧基、碳原子數2~8的烯基、碳原子數2~8的烯氧基的任一者,該基中的一個或非鄰接的兩個以上的-CH2 -分別獨立地可由-CH=CH-、-C≡C-、-O-、-CO-、-COO-或-OCO-取代,另外,Rii1 及Rii2 中存在的一個或兩個以上的氫原子分別獨立地可取代為氟原子,但Rii1 及Rii2 不會同時表示選自氟原子、氯原子及氰基中的取代基。In the general formula (ii), R ii1 and R ii2 each independently represent a fluorine atom, a chlorine atom, a cyano group, an alkyl group having 1 to 12 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, and 2 Any one of the alkenyl group of to 8 and the alkenyloxy group having 2 to 8 carbon atoms, one of the groups or two or more non-adjacent -CH 2 -groups may be independently set by -CH=CH-, -C ≡C-, -O-, -CO-, -COO- or -OCO- substitution, in addition, one or two or more hydrogen atoms present in R ii1 and R ii2 can be independently substituted with fluorine atoms, but R ii1 and R ii2 do not simultaneously represent a substituent selected from a fluorine atom, a chlorine atom, and a cyano group.
碳原子數1~12的烷基為直鏈狀或分支狀的烷基,較佳為直鏈狀的烷基。The alkyl group having 1 to 12 carbon atoms is a linear or branched alkyl group, and preferably a linear alkyl group.
碳原子數1~12的烷基的碳原子數為1~12,較佳為1~8,較佳為1~5,較佳為2~5。The alkyl group having 1 to 12 carbon atoms has 1 to 12 carbon atoms, preferably 1 to 8, preferably 1 to 5, and more preferably 2 to 5.
作為碳原子數1~12的烷基的具體例,例如可列舉:甲基、乙基、丙基、丁基、戊基、己基、庚基、辛基、壬基、癸基、異癸基、十二烷基及2-乙基己基等。Specific examples of the alkyl group having 1 to 12 carbon atoms include, for example, methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, and isodecyl. , Dodecyl and 2-ethylhexyl, etc.
碳原子數1~8的烷氧基為直鏈狀或分支狀的烷氧基,較佳為直鏈狀的烷氧基。The alkoxy group having 1 to 8 carbon atoms is a linear or branched alkoxy group, and a linear alkoxy group is preferred.
碳原子數1~8的烷氧基的碳原子數較佳為1~5。The number of carbon atoms of the alkoxy group having 1 to 8 carbon atoms is preferably 1 to 5.
作為碳原子數1~8的烷氧基的具體例,例如可列舉:甲氧基、乙氧基、丙氧基、丁氧基、戊氧基、及己氧基等。Specific examples of the alkoxy group having 1 to 8 carbon atoms include, for example, a methoxy group, an ethoxy group, a propoxy group, a butoxy group, a pentoxy group, and a hexyloxy group.
碳原子數2~8的烯基為直鏈狀或分支狀的烯基,較佳為直鏈狀的烯基。The alkenyl group having 2 to 8 carbon atoms is a linear or branched alkenyl group, and a linear alkenyl group is preferred.
碳原子數2~8的烯基的碳原子數較佳為2~5,較佳為2~3。The number of carbon atoms of the alkenyl group having 2 to 8 carbon atoms is preferably from 2 to 5, and more preferably from 2 to 3.
作為碳原子數2~8的烯基的具體例,可列舉式(R1)~式(R5)所表示的基等(各式中的黑點表示環結構中的碳原子)。Specific examples of alkenyl groups having 2 to 8 carbon atoms include groups represented by formulas (R1) to (R5) (black dots in each formula represent carbon atoms in the ring structure).
[化21] [化21]
碳原子數2~8的烯氧基為直鏈狀或分支狀的烯氧基,較佳為直鏈狀的烯氧基。The alkenyloxy group having 2 to 8 carbon atoms is a linear or branched alkenyloxy group, and a linear alkenyloxy group is preferred.
碳原子數2~8的烯氧基的碳原子數較佳為2~5。The number of carbon atoms of the alkenyloxy group having 2 to 8 carbon atoms is preferably 2 to 5.
作為碳原子數2~8的烯氧基的具體例,可列舉式(R6)~式(R10)所表示的基等(各式中,黑點表示環結構中的碳原子)。Specific examples of alkenyloxy groups having 2 to 8 carbon atoms include groups represented by formulas (R6) to (R10) (in each formula, black dots indicate carbon atoms in the ring structure).
[化22] [化22]
於重視液晶組成物整體的可靠性的情況下,Rii1 較佳為碳原子數1~12的烷基,於重視液晶組成物整體的黏性降低的情況下,Rii1 較佳為碳原子數2~8的烯基。In the case where the reliability of the entire liquid crystal composition is important, R ii1 is preferably an alkyl group having 1 to 12 carbon atoms, and when the reduction in the viscosity of the entire liquid crystal composition is important, R ii1 is preferably the number of carbon atoms 2-8 alkenyl.
另外,於Rii1 所鍵結的環結構為苯基(芳香族)的情況下,較佳為直鏈狀的碳原子數1~5的烷基、直鏈狀的碳原子數1~4的烷氧基及碳原子數4~5的烯基,於Rii1 所鍵結的環結構為環己烷、吡喃及二噁烷等飽和的環結構的情況下,較佳為直鏈狀的碳原子數1~5的烷基、直鏈狀的碳原子數1~4的烷氧基及直鏈狀的碳原子數2~5的烯基。In addition, when the ring structure to which R ii1 is bonded is a phenyl group (aromatic), it is preferably a linear alkyl group having 1 to 5 carbon atoms, or a linear alkyl group having 1 to 4 carbon atoms. Alkoxy and alkenyl having 4 to 5 carbon atoms, when the ring structure bonded to R ii1 is a saturated ring structure such as cyclohexane, pyran, and dioxane, it is preferably linear A C1-C5 alkyl group, a linear C1-C4 alkoxy group, and a linear C2-C5 alkenyl group.
另外,作為Rii1 ,為了使向列相穩定化,較佳為碳原子及存在的情況下的氧原子的合計為5以下,且較佳為直鏈狀。In addition, as R ii1 , in order to stabilize the nematic phase, the total of carbon atoms and oxygen atoms when present is preferably 5 or less, and is preferably linear.
於通式(ii)所表示的化合物是Δε為正的所謂的p型化合物的情況下,Rii2 較佳為氟原子、氰基、三氟甲基或三氟甲氧基,較佳為氟原子或氰基。When the compound represented by the general formula (ii) is a so-called p-type compound in which Δε is positive, R ii2 is preferably a fluorine atom, a cyano group, a trifluoromethyl group or a trifluoromethoxy group, and is preferably a fluorine atom. Atom or cyano.
於通式(ii)所表示的化合物是Δε幾乎為0的所謂的非極性化合物(non-polar compound)的情況下,Rii2 表示與Rii1 相同的含義,Rii2 與Rii1 可相同亦可不同。Compounds of the general formula (ii) is represented by the case where Δε is almost non-polar compounds (non-polar compound) of a so-called 0, R ii2 represents the same meaning as R ii1, R ii2 and may be identical or R ii1 different.
通式(ii)中,Zii1 、Zii2 及Zii3 分別獨立地表示單鍵、-OCH2 -、-CH2 O-、-C2 H4 -、-C4 H8 -、-COO-、-OCO-、-CH=CH-、-CF=CF-、-CF2 O-、-OCF2 -、-CF2 CF2 -或-C≡C-。In the general formula (ii), Z ii1 , Z ii2 and Z ii3 each independently represent a single bond, -OCH 2 -, -CH 2 O-, -C 2 H 4 -, -C 4 H 8 -, -COO- , -OCO-, -CH=CH-, -CF=CF-, -CF 2 O-, -OCF 2 -, -CF 2 CF 2 -or -C≡C-.
此處,Zii1 ~Zii3 較佳為單鍵。Here, Z ii1 to Z ii3 are preferably single bonds.
通式(ii)中,Aii1 、Aii2 、Aii3 、Aii4 、Aii5 及Aii6 分別獨立地表示選自由以下的基(a)、基(b)及基(c): (a)1,4-伸環己基(該基中存在的一個-CH2 -或不鄰接的兩個以上的-CH2 -可取代為-O-) (b)1,4-伸苯基(該基中存在的一個-CH=或不鄰接的兩個以上的-CH=可取代為-N=) (c)萘-1,4-二基、萘-2,6-二基、1,2,3,4-四氫萘-2,6-二基或十氫萘-2,6-二基(萘-1,4-二基、萘-2,6-二基或1,2,3,4-四氫萘-2,6-二基中存在的一個-CH=或不鄰接的兩個以上的-CH=可取代為-N=) 所組成的群組中的基,所述基(a)、基(b)及基(c)中的一個或兩個以上的氫原子分別獨立地可經鹵素原子、氰基或碳原子數1~6的烷基取代。In the general formula (ii), A ii1 , A ii2 , A ii3 , A ii4 , A ii5 and A ii6 each independently represent a group (a), a group (b), and a group (c) selected from: (a) 1,4-cyclohexylene (one -CH 2 -existing in this group or two or more non-adjacent -CH 2 -can be substituted with -O-) (b) 1,4-phenylene (this group One -CH= or two or more non-adjacent -CH= can be substituted with -N=) (c) naphthalene-1,4-diyl, naphthalene-2,6-diyl, 1,2, 3,4-Tetrahydronaphthalene-2,6-diyl or decahydronaphthalene-2,6-diyl (naphthalene-1,4-diyl, naphthalene-2,6-diyl or 1,2,3, In 4-tetrahydronaphthalene-2,6-diyl group, one -CH= or two or more non-adjacent -CH= groups can be substituted with -N=). The group ( a) One or two or more hydrogen atoms in the group (b) and the group (c) may be independently substituted with a halogen atom, a cyano group, or an alkyl group having 1 to 6 carbon atoms.
作為鹵素原子,可列舉氯原子、溴原子及氟原子,較佳為氟原子。Examples of the halogen atom include a chlorine atom, a bromine atom, and a fluorine atom, and a fluorine atom is preferred.
於要求提高Δn的情況下,Aii1 ~Aii6 分別獨立地較佳為顯示出芳香族性的二價的環式基即基(b)或基(c),為了改善響應速度,較佳為脂肪族的二價的環式基即基(a),分別獨立地較佳為表示下述結構的任一者:In the case where an increase in Δn is required, A ii1 to A ii6 are each independently preferably a divalent cyclic group showing aromaticity, that is, group (b) or group (c). In order to improve the response speed, it is preferably The aliphatic divalent cyclic group (a), each independently preferably represents any one of the following structures:
[化23] [化23]
(R表示碳原子數1~6的烷基), 較佳為1,4-伸苯基、萘-2,6-二基及四氫萘-2,6-二基的任一者,該些1,4-伸苯基、萘-2,6-二基及四氫萘-2,6-二基中的一個或兩個以上的氫原子分別獨立地可由氟原子或碳原子數1~6的烷基取代。(R represents an alkyl group having 1 to 6 carbon atoms), Preferably, it is any one of 1,4-phenylene, naphthalene-2,6-diyl and tetrahydronaphthalene-2,6-diyl, these 1,4-phenylene, naphthalene-2,6 One or two or more hydrogen atoms in the -diyl group and tetrahydronaphthalene-2,6-diyl group may be independently substituted with a fluorine atom or an alkyl group having 1 to 6 carbon atoms.
就提高Δn的觀點而言,特佳為Aii2 表示選自由以下的基(d)~基(f):From the viewpoint of increasing Δn, it is particularly preferable that A ii2 represents a group selected from the following groups (d) to (f):
[化24] [化24]
(Xiid1 、Xiid2 、Xiie1 、Xiie2 、Xiif1 及Xiif2 分別獨立地表示氫原子或氟原子) 所組成的群組中的基。另外,就與其他液晶化合物的相容性的觀點而言,較佳為表示基(f)。(X iid1 , X iid2 , X iie1 , X iie2 , X iif1 and X iif2 each independently represent a hydrogen atom or a fluorine atom) A group in the group consisting of. In addition, from the viewpoint of compatibility with other liquid crystal compounds, it is preferable to represent the group (f).
另外,為了提高與其他液晶組成物的相容性,較佳為Aii1 ~Aii6 的至少一個表示由碳原子數1~6的烷基取代的1,4-伸苯基,更佳為表示經伸乙基取代的1,4-伸苯基。In addition, in order to improve compatibility with other liquid crystal compositions, it is preferable that at least one of A ii1 to A ii6 represents 1,4-phenylene substituted with an alkyl group having 1 to 6 carbon atoms, and more preferably represents 1,4-phenylene substituted by ethylidene.
所述通式(ii)中,mii1 、mii2 及mii3 分別獨立地表示0或1,mii1 +mii2 +mii3 表示0或1。In the general formula (ii), m ii1 , m ii2 and m ii3 each independently represent 0 or 1, and m ii1 +m ii2 +m ii3 represent 0 or 1.
此處,於重視對液晶組成物的溶解性的情況下,mii1 較佳為0,於重視Δn及TNI 的情況下較佳為1。Here, when the solubility to the liquid crystal composition is important, m ii1 is preferably 0, and when Δn and T NI are important, it is preferably 1.
另外,mii1 +mii2 +mii3 較佳為0。In addition, m ii1 +m ii2 +m ii3 is preferably zero.
本發明的通式(ii)所表示的化合物的一分子中的環結構,即Aii1 ~Aii6 較佳為合計具有1個~5個氟原子,更佳為具有1個~4個。The ring structure in one molecule of the compound represented by the general formula (ii) of the present invention, that is, A ii1 to A ii6 preferably has 1 to 5 fluorine atoms in total, and more preferably has 1 to 4 fluorine atoms.
本發明的通式(ii)所表示的化合物一分子中的環結構,即Aii1 ~Aii6 較佳為合計具有0個~3個鹵素原子(氟原子除外),更佳為具有0個~2個。The ring structure in one molecule of the compound represented by the general formula (ii) of the present invention, that is, A ii1 to A ii6 preferably has 0 to 3 halogen atoms (excluding fluorine atoms) in total, and more preferably has 0 to 2 pcs.
本發明的通式(ii)所表示的化合物一分子中的環結構,即Aii1 ~Aii6 較佳為合計具有1個~5個鹵素原子(含氟原子),更佳為具有1個~4個。The ring structure in one molecule of the compound represented by the general formula (ii) of the present invention, that is, A ii1 to A ii6 preferably has a total of 1 to 5 halogen atoms (fluorine-containing atoms), more preferably 1 to 4.
所述通式(ii)所表示的化合物較佳為以下的通式(ii-1)所表示的化合物。The compound represented by the general formula (ii) is preferably a compound represented by the following general formula (ii-1).
[化25] [化25]
(所述通式(ii-1)中,Rii1 、Rii2 、Zii1 、Zii2 、Zii3 、Aii1 、Aii2 、Aii4 、Aii6 、mii1 、mii2 及mii3 分別表示與所述通式(ii)中的Rii1 、Rii2 、Zii1 、Zii2 、Zii3 、Aii1 、Aii2 、Aii4 、Aii6 、mii1 、mii2 及mii3 相同的含義, Aii3-1 及Aii5-1 分別獨立地表示1,4-伸苯基(該基中存在的一個-CH=或不鄰接的兩個以上的-CH=可取代為-N=),該基中的一個或兩個以上的氫原子分別獨立地可經鹵素原子、氰基或碳原子數1~6的烷基取代。(In the general formula (ii-1), R ii1 , R ii2 , Z ii1 , Z ii2 , Z ii3 , A ii1 , A ii2 , A ii4 , A ii6 , m ii1 , m ii2 and m ii3 respectively represent and R ii1 , R ii2 , Z ii1 , Z ii2 , Z ii3 , A ii1 , A ii2 , A ii4 , A ii6 , m ii1 , m ii2 and m ii3 in the general formula (ii) have the same meaning, and A ii3 -1 and A ii5-1 each independently represent 1,4-phenylene (one -CH= or two or more non-adjacent -CH= in this group can be substituted with -N=), in this group One or two or more hydrogen atoms of may be independently substituted with a halogen atom, a cyano group, or an alkyl group having 1 to 6 carbon atoms.
所述通式(ii-1)中,Rii1 、Rii2 、Zii1 、Zii2 、Zii3 、Aii1 、Aii2 、Aii4 、Aii6 、mii1 、mii2 及mii3 分別與所述通式(ii)中的Rii1 、Rii2 、Zii1 、Zii2 、Zii3 、Aii1 、Aii2 、Aii4 、Aii6 、mii1 、mii2 及mii3 相同,較佳的基、較佳的個數亦相同,因此省略此處的說明。In the general formula (ii-1), R ii1 , R ii2 , Z ii1 , Z ii2 , Z ii3 , A ii1 , A ii2 , A ii4 , A ii6 , m ii1 , m ii2 and m ii3 are respectively the same as those described above R ii1 , R ii2 , Z ii1 , Z ii2 , Z ii3 , A ii1 , A ii2 , A ii4 , A ii6 , m ii1 , m ii2 and m ii3 in the general formula (ii) are the same. The preferred number is also the same, so the description here is omitted.
所述通式(ii)所表示的化合物較佳為以下的通式(ii-2)所表示的化合物。The compound represented by the general formula (ii) is preferably a compound represented by the following general formula (ii-2).
[化26] [化26]
(所述通式(ii-2)中,Rii1 、Rii2 、Zii1 、Zii2 、Zii3 、Aii1 、Aii2 、Aii4 、Aii6 、mii1 、mii2 及mii3 分別表示與所述通式(ii)中的Rii1 、Rii2 、Zii1 、Zii2 、Zii3 、Aii1 、Aii2 、Aii4 、Aii6 、mii1 、mii2 及mii3 相同的含義。(In the general formula (ii-2), R ii1 , R ii2 , Z ii1 , Z ii2 , Z ii3 , A ii1 , A ii2 , A ii4 , A ii6 , m ii1 , m ii2 and m ii3 respectively represent and R ii1 , R ii2 , Z ii1 , Z ii2 , Z ii3 , A ii1 , A ii2 , A ii4 , A ii6 , m ii1 , m ii2 and m ii3 in the general formula (ii) have the same meaning.
Aii3-2 表示1,4-伸苯基(該基中存在的一個-CH=或不鄰接的兩個以上的-CH=可取代為-N=),所述基中的一個或兩個以上的氫原子分別獨立地可經鹵素原子、氰基或碳原子數1~6的烷基取代。A ii3-2 represents 1,4-phenylene (one -CH= or two or more non-adjacent -CH= in the group can be substituted with -N=), one or two of the groups The above hydrogen atoms may be independently substituted with a halogen atom, a cyano group, or an alkyl group having 1 to 6 carbon atoms.
Aii5-2 表示萘-1,4-二基、萘-2,6-二基、1,2,3,4-四氫萘-2,6-二基或十氫萘-2,6-二基(萘-1,4-二基、萘-2,6-二基或1,2,3,4-四氫萘-2,6-二基中存在的一個-CH=或不鄰接的兩個以上的-CH=可取代為-N=),該基中的一個或兩個以上的氫原子分別獨立地可經鹵素原子、氰基或碳原子數1~6的烷基取代。A ii5-2 represents naphthalene-1,4-diyl, naphthalene-2,6-diyl, 1,2,3,4-tetrahydronaphthalene-2,6-diyl or decahydronaphthalene-2,6- Diyl (naphthalene-1,4-diyl, naphthalene-2,6-diyl or 1,2,3,4-tetrahydronaphthalene-2,6-diyl exist one -CH= or not adjacent Two or more -CH= may be substituted with -N=), and one or two or more hydrogen atoms in the group may be independently substituted by a halogen atom, a cyano group, or an alkyl group having 1 to 6 carbon atoms.
所述通式(ii-2)中,Rii1 、Rii2 、Zii1 、Zii2 、Zii3 、Aii1 、Aii2 、Aii4 、Aii6 、mii1 、mii2 及mii3 與所述通式(ii)中的Rii1 、Rii2 、Zii1 、Zii2 、Zii3 、Aii1 、Aii2 、Aii4 、Aii6 、mii1 、mii2 及mii3 相同,較佳的基、較佳的個數亦相同,因此省略此處的說明。In the general formula (ii-2), R ii1 , R ii2 , Z ii1 , Z ii2 , Z ii3 , A ii1 , A ii2 , A ii4 , A ii6 , m ii1 , m ii2 and m ii3 are the same as those described above. In formula (ii), R ii1 , R ii2 , Z ii1 , Z ii2 , Z ii3 , A ii1 , A ii2 , A ii4 , A ii6 , m ii1 , m ii2 and m ii3 are the same, the preferred bases are more preferred The number of is also the same, so the description here is omitted.
所述通式(ii)所表示的化合物較佳為以下的通式(ii-3)所表示的化合物。The compound represented by the general formula (ii) is preferably a compound represented by the following general formula (ii-3).
[化27] [化27]
通式(ii-3)中,Rii1 、Rii2 、Zii1 、Zii2 、Zii3 、Aii1 、Aii2 、Aii4 、Aii6 、mii1 、mii2 及mii3 分別表示與所述通式(ii)中的Rii1 、Rii2 、Zii1 、Zii2 、Zii3 、Aii1 、Aii2 、Aii4 、Aii6 、mii1 、mii2 及mii3 相同的含義。In the general formula (ii-3), R ii1 , R ii2 , Z ii1 , Z ii2 , Z ii3 , A ii1 , A ii2 , A ii4 , A ii6 , m ii1 , m ii2 and m ii3 respectively represent the same In formula (ii), R ii1 , R ii2 , Z ii1 , Z ii2 , Z ii3 , A ii1 , A ii2 , A ii4 , A ii6 , m ii1 , m ii2 and m ii3 have the same meaning.
Aii3-3 表示萘-1,4-二基、萘-2,6-二基、1,2,3,4-四氫萘-2,6-二基或十氫萘-2,6-二基(萘-1,4-二基、萘-2,6-二基或1,2,3,4-四氫萘-2,6-二基中存在的一個-CH=或不鄰接的兩個以上的-CH=可取代為-N=),該基中的一個或兩個以上的氫原子分別獨立地可經鹵素原子、氰基或碳原子數1~6的烷基取代。A ii3-3 represents naphthalene-1,4-diyl, naphthalene-2,6-diyl, 1,2,3,4-tetrahydronaphthalene-2,6-diyl or decahydronaphthalene-2,6- Diyl (naphthalene-1,4-diyl, naphthalene-2,6-diyl or 1,2,3,4-tetrahydronaphthalene-2,6-diyl exist one -CH= or not adjacent Two or more -CH= may be substituted with -N=), and one or two or more hydrogen atoms in the group may be independently substituted by a halogen atom, a cyano group, or an alkyl group having 1 to 6 carbon atoms.
Aii5-3 表示1,4-伸苯基(該基中存在的一個-CH=或不鄰接的兩個以上的-CH=可取代為-N=),所述基中的一個或兩個以上的氫原子分別獨立地可經鹵素原子、氰基或碳原子數1~6的烷基取代。A ii5-3 represents 1,4-phenylene (one -CH= or two or more non-adjacent -CH= in the group can be substituted with -N=), one or two of the groups The above hydrogen atoms may be independently substituted with a halogen atom, a cyano group, or an alkyl group having 1 to 6 carbon atoms.
通式(ii-3)中,Rii1 、Rii2 、Zii1 、Zii2 、Zii3 、Aii1 、Aii2 、Aii4 、Aii6 、mii1 、mii2 及mii3 與所述通式(ii)中的Rii1 、Rii2 、Zii1 、Zii2 、Zii3 、Aii1 、Aii2 、Aii4 、Aii6 、mii1 、mii2 及mii3 相同,較佳的基、較佳的個數亦相同,因此省略此處的說明。In the general formula (ii-3), R ii1 , R ii2 , Z ii1 , Z ii2 , Z ii3 , A ii1 , A ii2 , A ii4 , A ii6 , m ii1 , m ii2 and m ii3 and the general formula ( ii) R ii1 , R ii2 , Z ii1 , Z ii2 , Z ii3 , A ii1 , A ii2 , A ii4 , A ii6 , m ii1 , m ii2 and m ii3 are the same, the preferred base, the preferred one The numbers are also the same, so the description here is omitted.
作為本發明的通式(ii-1)的具體結構,就進一步提高液晶組成物的相容性的觀點而言,較佳為以下的通式(ii-1-1)~通式(ii-1-22)所表示的三環或四環的化合物。As a specific structure of the general formula (ii-1) of the present invention, from the viewpoint of further improving the compatibility of the liquid crystal composition, the following general formula (ii-1-1) to general formula (ii- 1-22) The represented tricyclic or tetracyclic compound.
[化28] [化28]
[化29] [化29]
[化30] [化30]
[化31] [化31]
[化32] [化32]
所述通式(ii-1-1)~通式(ii-1-22)中,Aii2-1 分別獨立地表示下述結構式。In the general formulas (ii-1-1) to (ii-1-22), A ii2-1 each independently represents the following structural formula.
[化33] [化33]
所述通式(ii-1-1)~通式(ii-1-22)中,mii1-1 、mii2-1 及mii3-1 分別獨立地表示0或1,mii1-1 +mii2-1 +mii3-1 表示0或1。In the general formulas (ii-1-1) to (ii-1-22), m ii1-1 , m ii2-1 and m ii3-1 each independently represent 0 or 1, and m ii1-1 + m ii2-1 +m ii3-1 represents 0 or 1.
所述通式(ii-1-1)~通式(ii-1-22)中,Zii1-1 、Zii2-1 及Zii3-1 分別獨立地表示單鍵、-COO-、-CF=CF-、-CF2 O-、-OCF2 -或-C≡C-。In the general formulas (ii-1-1) to (ii-1-22), Z ii1-1 , Z ii2-1 and Z ii3-1 each independently represent a single bond, -COO-, -CF =CF-, -CF 2 O-, -OCF 2 -or -C≡C-.
所述通式(ii-1-1)~通式(ii-1-22)中,Aii1-1 、Aii4-1 及Aii6-1 分別獨立地表示1,4-伸苯基(該基中存在的一個-CH=或不鄰接的兩個以上的-CH=可取代為-N=),該基中的一個或兩個以上的氫原子分別獨立地可經鹵素原子、氰基或碳原子數1~6的烷基取代。In the general formulas (ii-1-1) to (ii-1-22), A ii1-1 , A ii4-1 and A ii6-1 each independently represent 1,4-phenylene (the One -CH= or two or more non-adjacent -CH= in the group can be substituted with -N=), and one or two or more hydrogen atoms in the group can be independently halogen atom, cyano group or Substitution with an alkyl group having 1 to 6 carbon atoms.
所述通式(ii-1-1)~通式(ii-1-22)中,Rii1 、Rii2 與所述通式(ii)中的Rii1 、Rii2 相同,較佳的基、較佳的個數亦相同,因此省略此處的說明。In the general formula (ii-1-1) ~ In the general formula (ii-1-22), R ii1 , R ii2 in the above general formula (ii) R ii1, the same as R ii2, preferred groups, The preferred number is also the same, so the description here is omitted.
作為本發明的通式(ii-2)的具體結構,較佳為以下的通式(ii-2-1)~通式(ii-2-3)所表示的化合物。As a specific structure of the general formula (ii-2) of the present invention, compounds represented by the following general formulas (ii-2-1) to (ii-2-3) are preferred.
[化34] [化34]
所述通式(ii-2-1)~通式(ii-2-3)中,Aii2-2 分別獨立地表示下述結構式。In the general formulas (ii-2-1) to (ii-2-3), A ii2-2 each independently represents the following structural formula.
[化35] [化35]
所述通式(ii-2-1)~通式(ii-2-3)中,mii1-2 、mii2-2 及mii3-2 分別獨立地表示0或1,mii1-2 +mii2-2 +mii3-2 表示0或1。In the general formulas (ii-2-1) to (ii-2-3), m ii1-2 , m ii2-2 and m ii3-2 each independently represent 0 or 1, and m ii1-2 + m ii2-2 +m ii3-2 represents 0 or 1.
所述通式(ii-2-1)~通式(ii-2-3)中,Zii1-2 、Zii2-2 及Zii3-2 分別獨立地表示單鍵、-COO-、-CF=CF-、-CF2 O-、-OCF2 -或-C≡C-。In the general formulas (ii-2-1) to (ii-2-3), Z ii1-2 , Z ii2-2, and Z ii3-2 each independently represent a single bond, -COO-, -CF =CF-, -CF 2 O-, -OCF 2 -or -C≡C-.
所述通式(ii-2-1)~通式(ii-2-3)中,Aii1-2 、Aii4-1 及Aii6-2 分別獨立地表示1,4-伸苯基(該基中存在的一個-CH=或不鄰接的兩個以上的-CH=可取代為-N=),該基中的一個或兩個以上的氫原子分別獨立地可經鹵素原子、氰基或碳原子數1~6的烷基取代。In the general formulas (ii-2-1) to (ii-2-3), A ii1-2 , A ii4-1, and A ii6-2 each independently represent 1,4-phenylene (the One -CH= or two or more non-adjacent -CH= in the group can be substituted with -N=), and one or two or more hydrogen atoms in the group can be independently halogen atom, cyano group or Substitution with an alkyl group having 1 to 6 carbon atoms.
所述通式(ii-2-1)~通式(ii-2-3)中,Rii1 、Rii2 與所述通式(ii)中的Rii1 、Rii2 相同,較佳的基、較佳的個數亦相同,因此省略此處的說明。In the general formula (ii-2-1) ~ In the general formula (ii-2-3), R ii1 , R ii2 in the above general formula (ii) R ii1, the same as R ii2, preferred groups, The preferred number is also the same, so the description here is omitted.
作為本發明的通式(ii-3)的具體結構,較佳為以下的通式(ii-3-1)所表示的化合物。As a specific structure of the general formula (ii-3) of the present invention, a compound represented by the following general formula (ii-3-1) is preferred.
[化36] [化36]
所述通式(ii-3-1)中,Aii2-3 分別獨立地表示下述結構式。In the general formula (ii-3-1), A ii2-3 each independently represents the following structural formula.
[化37] [化37]
所述通式(ii-3-1)中,mii1-3 、mii2-3 及mii3-3 分別獨立地表示0或1,mii1-3 +mii2-3 +mii3-3 表示0或1。In the general formula (ii-3-1), m ii1-3 , m ii2-3 and m ii3-3 independently represent 0 or 1, respectively, and m ii1-3 +m ii2-3 +m ii3-3 represent 0 or 1.
所述通式(ii-3-1)中,Zii1-3 、Zii2-3 及Zii3-3 分別獨立地表示單鍵、-COO-、-CF=CF-、-CF2 O-、-OCF2 -或-C≡C-。In the general formula (ii-3-1), Z ii1-3 , Z ii2-3 and Z ii3-3 each independently represent a single bond, -COO-, -CF=CF-, -CF 2 O-, -OCF 2 -or -C≡C-.
所述通式(ii-3-1)中,Aii1-3 、Aii4-3 及Aii6-2 分別獨立地表示1,4-伸苯基(該基中存在的一個-CH=或不鄰接的兩個以上的-CH=可取代為-N=),該基中的一個或兩個以上的氫原子分別獨立地可經鹵素原子、氰基或碳原子數1~6的烷基取代。In the general formula (ii-3-1), A ii1-3 , A ii4-3 and A ii6-2 each independently represent 1,4-phenylene (the presence of one -CH= or not Two or more adjacent -CH= can be substituted with -N=), one or more of the hydrogen atoms in this group can be independently substituted by halogen atoms, cyano groups or alkyl groups with 1 to 6 carbon atoms .
所述通式(ii-3-1)中,Rii1 、Rii2 與所述通式(ii)中的Rii1 、Rii2 相同,較佳的基、較佳的個數亦相同,因此省略此處的說明。In the general formula (ii-3-1), R ii1 , R ii2 in the above general formula (ii) R ii1, the same as R ii2, preferred groups are also the same number of preferred, omitted Instructions here.
作為通式(ii-1-1)~通式(ii-1-22)的具體結構,可列舉下述結構式(ii-1.1)~結構式(ii-1.98)所表示的化合物。As a specific structure of general formula (ii-1-1)-general formula (ii-1-22), the compound represented by the following structural formula (ii-1.1)-structural formula (ii-1.98) is mentioned.
[化38] [化38]
[化39] [化39]
[化40] [化40]
[化41] [化41]
式中,X分別獨立地表示氫原子、氟原子或碳原子數1~6的烷基。In the formula, X each independently represents a hydrogen atom, a fluorine atom, or an alkyl group having 1 to 6 carbon atoms.
[化42] [化42]
式中,X分別獨立地表示氫原子、氟原子或碳原子數1~6的烷基。In the formula, X each independently represents a hydrogen atom, a fluorine atom, or an alkyl group having 1 to 6 carbon atoms.
[化43] [化43]
所述結構式(ii-1.1)~結構式(ii-1.98)所表示的化合物中,較佳為(ii-1.2)~(ii-1.8)、(ii-1.12)~(ii-1.18)、(ii-1.22)~(ii-1.28)、(ii-1.32)~(ii-1.38)、(ii-1.42)~(ii-1.44)、(ii-1.46)~(ii.48)、(ii-1.50)~(ii-1.52)、(ii-1.54)~(ii-1.56)、(ii-1.58)~(ii-1.60)、(ii-1.62)~(ii-1.64)、(ii-1.66)~(ii-1.68)、(ii-1.70)~(ii-1.72)、(ii-1.74)~(ii-1.76)、(ii-1.78)~(ii-1.80)、(ii-1.82)~(ii-1.84)及(ii-1.86)~(ii-1.88)、(ii-1.90)~(ii-1.98)。Among the compounds represented by the structural formulas (ii-1.1) to (ii-1.98), preferably (ii-1.2) to (ii-1.8), (ii-1.12) to (ii-1.18), (Ii-1.22)~(ii-1.28), (ii-1.32)~(ii-1.38), (ii-1.42)~(ii-1.44), (ii-1.46)~(ii.48), (ii -1.50)~(ii-1.52), (ii-1.54)~(ii-1.56), (ii-1.58)~(ii-1.60), (ii-1.62)~(ii-1.64), (ii-1.66 )~(ii-1.68), (ii-1.70)~(ii-1.72), (ii-1.74)~(ii-1.76), (ii-1.78)~(ii-1.80), (ii-1.82)~ (Ii-1.84) and (ii-1.86) ~ (ii-1.88), (ii-1.90) ~ (ii-1.98).
通式(ii)、通式(ii-1)~通式(ii-3)、通式(ii-1-1)~通式(ii-1-22)、通式(ii-2-1)~通式(ii-2-3)、通式(ii-3-1)或結構式(ii-1.1)~結構式(ii-1.98)所表示的化合物可單獨使用,或者亦可組合使用兩種以上。能夠組合的化合物的種類並無特別限制,對應於介電常數各向異性、常溫下的溶解性、轉變溫度、雙折射率等所期望的性能適宜組合使用。General formula (ii), general formula (ii-1) to general formula (ii-3), general formula (ii-1-1) to general formula (ii-1-22), general formula (ii-2-1) )~The compounds represented by general formula (ii-2-3), general formula (ii-3-1) or structural formula (ii-1.1)~structural formula (ii-1.98) can be used alone or in combination Two or more. The types of compounds that can be combined are not particularly limited, and they are suitably used in combination in accordance with desired properties such as dielectric anisotropy, solubility at room temperature, transition temperature, and birefringence.
例如作為本發明的一個實施形態,所使用的通式(ii)、通式(ii-1)~通式(ii-3)、通式(ii-1-1)~通式(ii-1-22)、通式(ii-2-1)~通式(ii-2-3)、通式(ii-3-1)或結構式(ii-1.1)~結構式(ii-1.98)所表示的化合物的種類為一種、兩種、三種、四種、五種、六種、七種、八種、九種、十種以上。For example, as an embodiment of the present invention, general formula (ii), general formula (ii-1) to general formula (ii-3), general formula (ii-1-1) to general formula (ii-1) used -22), general formula (ii-2-1) ~ general formula (ii-2-3), general formula (ii-3-1) or structural formula (ii-1.1) ~ structural formula (ii-1.98) The types of compounds shown are one, two, three, four, five, six, seven, eight, nine, ten or more.
相對於本發明的液晶組成物的總量,通式(ii)、通式(ii-1)~通式(ii-3)、通式(ii-1-1)~通式(ii-1-22)、通式(ii-2-1)~通式(ii-2-3)、通式(ii-3-1)或結構式(ii-1.1)~結構式(ii-1.98)所表示的化合物於液晶組成物100質量%中的合計含量的下限值較佳為1質量%,較佳為2質量%,較佳為5質量%,較佳為8質量%,較佳為10質量%,較佳為13質量%,較佳為15質量%,較佳為18質量%,較佳為20質量%,較佳為22質量%,較佳為25質量%,較佳為30質量%,較佳為40質量%,較佳為50質量%,較佳為55質量%,較佳為60質量%,較佳為65質量%,較佳為70質量%。With respect to the total amount of the liquid crystal composition of the present invention, general formula (ii), general formula (ii-1) to general formula (ii-3), general formula (ii-1-1) to general formula (ii-1) -22), general formula (ii-2-1) ~ general formula (ii-2-3), general formula (ii-3-1) or structural formula (ii-1.1) ~ structural formula (ii-1.98) The lower limit of the total content of the compound represented in 100% by mass of the liquid crystal composition is preferably 1% by mass, more preferably 2% by mass, more preferably 5% by mass, preferably 8% by mass, and preferably 10 % By mass, preferably 13% by mass, preferably 15% by mass, preferably 18% by mass, preferably 20% by mass, preferably 22% by mass, preferably 25% by mass, preferably 30% by mass %, preferably 40% by mass, preferably 50% by mass, preferably 55% by mass, preferably 60% by mass, preferably 65% by mass, and preferably 70% by mass.
若含量多則會引起析出等問題,因此相對於本發明的液晶組成物的總量,通式(ii)、通式(ii-1)~通式(ii-3)、通式(ii-1-1)~通式(ii-1-22)、通式(ii-2-1)~通式(ii-2-3)、通式(ii-3-1)或結構式(ii-1.1)~結構式(ii-1.98)所表示的化合物於液晶組成物100質量%中的合計含量的上限值較佳為70質量%,較佳為65質量%,較佳為55質量%,較佳為45質量%,較佳為35質量%,較佳為30質量%,較佳為28質量%,較佳為25質量%,較佳為23質量%,較佳為20質量%,較佳為18質量%,較佳為15%質量%。If the content is large, problems such as precipitation will occur. Therefore, the general formula (ii), general formula (ii-1) to general formula (ii-3), and general formula (ii- 1-1) ~ general formula (ii-1-22), general formula (ii-2-1) ~ general formula (ii-2-3), general formula (ii-3-1) or structural formula (ii- 1.1) The upper limit of the total content of the compound represented by the structural formula (ii-1.98) in 100% by mass of the liquid crystal composition is preferably 70% by mass, more preferably 65% by mass, more preferably 55% by mass, Preferably it is 45% by mass, more preferably 35% by mass, more preferably 30% by mass, preferably 28% by mass, preferably 25% by mass, preferably 23% by mass, preferably 20% by mass, more It is preferably 18% by mass, and more preferably 15% by mass.
通式(ii)、通式(ii-1)~通式(ii-3)、通式(ii-1-1)~通式(ii-1-22)、通式(ii-2-1)~通式(ii-2-3)、通式(ii-3-1)或結構式(ii-1.1)~結構式(ii-1.98)所表示的化合物於液晶組成物100質量%中的合計含量具體而言較佳為5質量%~45質量%,較佳為10質量%~40質量%。General formula (ii), general formula (ii-1) to general formula (ii-3), general formula (ii-1-1) to general formula (ii-1-22), general formula (ii-2-1) ) ~ General formula (ii-2-3), general formula (ii-3-1) or structural formula (ii-1.1) ~ structural formula (ii-1.98) in 100% by mass of the compound represented by the liquid crystal composition Specifically, the total content is preferably 5% by mass to 45% by mass, and more preferably 10% by mass to 40% by mass.
另外,通式(ii-1)所表示的化合物於液晶組成物100質量%中的合計含量較佳為5質量%~45質量%,較佳為10質量%~50質量%。In addition, the total content of the compound represented by the general formula (ii-1) in 100% by mass of the liquid crystal composition is preferably 5% to 45% by mass, more preferably 10% to 50% by mass.
通式(ii)、通式(ii-1)~通式(ii-3)、通式(ii-1-1)~通式(ii-1-22)、通式(ii-2-1)~通式(ii-2-3)、通式(ii-3-1)或結構式(ii-1.1)~結構式(ii-1.98)所表示的化合物可藉由公知的方法進行製造。General formula (ii), general formula (ii-1) to general formula (ii-3), general formula (ii-1-1) to general formula (ii-1-22), general formula (ii-2-1) The compound represented by the general formula (ii-2-3), the general formula (ii-3-1), or the structural formula (ii-1.1) to the structural formula (ii-1.98) can be produced by a known method.
本發明的液晶組成物包含一種或兩種以上的下述通式(2a)~通式(2c)所表示的化合物。The liquid crystal composition of the present invention contains one or two or more compounds represented by the following general formulas (2a) to (2c).
[化44] [化44]
所述通式(2a)~通式(2c)中, R2a 及R2b 分別獨立地表示碳原子數1~12的烷基、碳原子數1~8的烷氧基、碳原子數2~8的烯基、碳原子數2~8的烯氧基、氰基的任一者,該基中的一個或非鄰接的兩個以上的-CH2 -分別獨立地可由-O-、-CH=CH-、-CH=CF-、-CF=CH-、-CF=CF-或-C≡C-取代,另外,該基中存在的一個或兩個以上的氫原子分別獨立地可經氟原子、三氟甲氧基、碳原子數1~6的烷基的任一者取代。In the general formulas (2a) to (2c), R 2a and R 2b each independently represent an alkyl group having 1 to 12 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, and a carbon number of 2 to Any of the alkenyl group of 8, the alkenyloxy group having 2 to 8 carbon atoms, and the cyano group, one of the groups or two or more non-adjacent -CH 2 -groups may independently be -O-, -CH =CH-, -CH=CF-, -CF=CH-, -CF=CF- or -C≡C- substitution, in addition, one or more hydrogen atoms present in the group can be independently fluorine Atom, trifluoromethoxy, and C1-C6 alkyl group are substituted.
碳原子數1~12的烷基為直鏈狀或分支狀的烷基,較佳為直鏈狀的烷基。The alkyl group having 1 to 12 carbon atoms is a linear or branched alkyl group, and preferably a linear alkyl group.
碳原子數1~12的烷基的碳原子數較佳為1~8,較佳為1~5,較佳為2~5。The number of carbon atoms of the alkyl group having 1 to 12 carbon atoms is preferably 1-8, preferably 1-5, and more preferably 2-5.
作為碳原子數1~12的烷基的具體例,例如可列舉:甲基、乙基、丙基、丁基、戊基、己基、庚基、辛基、壬基、癸基、異癸基、十二烷基及2-乙基己基等。Specific examples of the alkyl group having 1 to 12 carbon atoms include, for example, methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, and isodecyl. , Dodecyl and 2-ethylhexyl, etc.
碳原子數1~8的烷氧基為直鏈狀或分支狀的烷氧基,較佳為直鏈狀的烷氧基。The alkoxy group having 1 to 8 carbon atoms is a linear or branched alkoxy group, and a linear alkoxy group is preferred.
碳原子數1~8的烷氧基的碳原子數較佳為1~5。The number of carbon atoms of the alkoxy group having 1 to 8 carbon atoms is preferably 1 to 5.
作為碳原子數1~8的烷氧基的具體例,例如可列舉:甲氧基、乙氧基、丙氧基、丁氧基、戊氧基、及己氧基等。Specific examples of the alkoxy group having 1 to 8 carbon atoms include, for example, a methoxy group, an ethoxy group, a propoxy group, a butoxy group, a pentoxy group, and a hexyloxy group.
碳原子數2~8的烯基為直鏈狀或分支狀的烯基,較佳為直鏈狀的烯基。The alkenyl group having 2 to 8 carbon atoms is a linear or branched alkenyl group, and a linear alkenyl group is preferred.
碳原子數2~8的烯基的碳原子數較佳為2~5,較佳為2~3。The number of carbon atoms of the alkenyl group having 2 to 8 carbon atoms is preferably from 2 to 5, and more preferably from 2 to 3.
作為碳原子數2~8的烯基的具體例,可列舉式(R1)~式(R5)所表示的基等(各式中的黑點表示環結構中的碳原子)。Specific examples of alkenyl groups having 2 to 8 carbon atoms include groups represented by formulas (R1) to (R5) (black dots in each formula represent carbon atoms in the ring structure).
[化45] [化45]
碳原子數2~8的烯氧基為直鏈狀或分支狀的烯氧基,較佳為直鏈狀的烯氧基。The alkenyloxy group having 2 to 8 carbon atoms is a linear or branched alkenyloxy group, and a linear alkenyloxy group is preferred.
碳原子數2~8的烯氧基的碳原子數為2~8,較佳為2~5。The number of carbon atoms of the alkenyloxy group having 2 to 8 carbon atoms is 2-8, preferably 2-5.
作為碳原子數2~8的烯氧基的具體例,可列舉式(R6)~式(R10)所表示的基等(各式中,黑點表示環結構中的碳原子)。Specific examples of alkenyloxy groups having 2 to 8 carbon atoms include groups represented by formulas (R6) to (R10) (in each formula, black dots indicate carbon atoms in the ring structure).
[化46] [化46]
所述通式(2a)~通式(2c)中,環A、環B、環C及環D分別獨立地表示選自由以下的基(a)、基(b)、基(c)及基(d): (a)1,4-伸環己基(該基中存在的一個-CH2 -或非鄰接的兩個以上的-CH2 -可取代為-O-)、 (b)1,4-伸苯基(該基中存在的一個-CH=或非鄰接的兩個以上的-CH=可取代為-N=)及 (c)萘-2,6-二基、1,2,3,4-四氫萘-2,6-二基或十氫萘-2,6-二基(萘-2,6-二基或1,2,3,4-四氫萘-2,6-二基中存在的一個-CH=或非鄰接的兩個以上的-CH=可取代為-N=)、 (d)1,4-伸環己烯基、1,3-二噁烷-反式-2,5-二基、嘧啶-2,5-二基或吡啶-2,5-二基 所組成的群組中的基,所述基(a)、基(b)、基(c)及基(d)中的一個或兩個以上的氫原子分別獨立地可經鹵素原子、氰基或碳原子數1~6的烷基取代。In the general formulas (2a) to (2c), ring A, ring B, ring C, and ring D each independently represent a group selected from the group (a), group (b), group (c) and group (D): (a) 1,4-cyclohexylene (one -CH 2 -or two or more non-adjacent -CH 2 -in the group can be substituted with -O-), (b) 1, 4-Phenylene (one -CH= or two or more non-adjacent -CH= in the group can be substituted with -N=) and (c) naphthalene-2,6-diyl, 1,2, 3,4-Tetrahydronaphthalene-2,6-diyl or decahydronaphthalene-2,6-diyl (naphthalene-2,6-diyl or 1,2,3,4-tetrahydronaphthalene-2,6 -One -CH= or two or more non-adjacent -CH= present in the diyl group can be substituted with -N=), (d) 1,4-cyclohexenylene, 1,3-dioxane- The group consisting of trans-2,5-diyl, pyrimidine-2,5-diyl or pyridine-2,5-diyl, said group (a), group (b), group ( One or two or more hydrogen atoms in c) and group (d) may be independently substituted with a halogen atom, a cyano group, or an alkyl group having 1 to 6 carbon atoms.
作為鹵素原子,可列舉氯原子、溴原子及氟原子,較佳為氟原子。Examples of the halogen atom include a chlorine atom, a bromine atom, and a fluorine atom, and a fluorine atom is preferred.
所述通式(2a)~通式(2c)中,L2a 、L2b 及L2c 分別獨立地表示單鍵、-CH2 CH2 -、-CH(CH3 )CH2 -、-CH2 CH(CH3 )-、-CH2 CH2 CH2 CH2 -、-COO-、-OCO-、-OCF2 -、-CF2 O-、-CH=CH-、-CH=CF-、-CF=CH-、-CF=CF-、-C≡C-或-CH=N-N=CH-。In the general formulas (2a) to (2c), L 2a , L 2b and L 2c each independently represent a single bond, -CH 2 CH 2 -, -CH(CH 3 )CH 2 -, -CH 2 CH(CH 3 )-, -CH 2 CH 2 CH 2 CH 2 -, -COO-, -OCO-, -OCF 2 -, -CF 2 O-, -CH=CH-, -CH=CF-,- CF=CH-, -CF=CF-, -C≡C- or -CH=NN=CH-.
其中,自通式(1a)~通式(1c)所表示的化合物中將通式(i-1)、通式(i-2-1a)、通式(i-2-1b)及通式(i-2-1c)所表示的化合物除外。Among them, the general formula (i-1), general formula (i-2-1a), general formula (i-2-1b) and general formula (I-2-1c) Except for the compounds shown.
所述通式(2a)所表示的化合物較佳為以下的通式(2a-1.1)~通式(2a-1.8)所表示的化合物。The compound represented by the general formula (2a) is preferably a compound represented by the following general formula (2a-1.1) to (2a-1.8).
[化47] [化47]
通式(2a-1.1)~通式(2a-1.8)中,R2a 及R2b 與所述通式(2a)中的R2a 及R2b 相同,較佳的基、較佳的個數亦相同,因此省略此處的說明。Of (2a-1.8) of the general formula (2a-1.1) ~ Formula, the R 2a and R 2b in the general formula (. 2A) the same as R 2a and R 2b, preferred groups, the preferred number is also The same, so the description here is omitted.
所述通式(2b)所表示的化合物較佳為以下的通式(2b-1.1)~通式(2b-1.15)所表示的化合物。The compound represented by the general formula (2b) is preferably a compound represented by the following general formulas (2b-1.1) to (2b-1.15).
[化48] [化48]
[化49] [化49]
通式(2b-1.1)~通式(2b-1.15)中,R2a 及R2b 與所述通式(2b)中的R2a 及R2b 相同,較佳的基、較佳的個數亦相同,因此省略此處的說明。In (2b-1.15) of the general formula (2b-1.1) ~ formula, R 2a and R 2b in the formula (2b) R 2a and R 2b same preferred groups, the preferred number is also The same, so the description here is omitted.
所述通式(2c)所表示的化合物較佳為以下的通式(2c-1.1)~通式(2c-1.7)所表示的化合物。The compound represented by the general formula (2c) is preferably a compound represented by the following general formula (2c-1.1) to (2c-1.7).
[化50] [化50]
通式(2c-1)~通式(2c-6)中,R2a 及R2b 與所述通式(2a)中的R2a 及R2b 相同,較佳的基、較佳的個數亦相同,因此省略此處的說明。In the general formula (2c-1) ~ formula (2c-6), the R 2a and R 2b in the general formula (. 2A) the same as R 2a and R 2b, preferred groups, the preferred number is also The same, so the description here is omitted.
作為通式(2a)所表示的化合物的具體例,例如可列舉以下的通式(2a-2.1)~通式(2a-2.9)及通式(2a-3.1)~通式(2a-3.8)所表示的化合物。As specific examples of the compound represented by the general formula (2a), for example, the following general formula (2a-2.1) to general formula (2a-2.9) and general formula (2a-3.1) to general formula (2a-3.8) can be cited The compound represented.
[化51] [化51]
[化52] [化52]
通式(2a-2.1)~通式(2a-2.9)及通式(2a-3.1)~通式(2a-3.8)中,R2a 及R2b 與所述通式(2a)中的R2a 及R2b 相同,較佳的基、較佳的個數亦相同,因此省略此處的說明。In general formula (2a-2.1) to general formula (2a-2.9) and general formula (2a-3.1) to general formula (2a-3.8), R 2a and R 2b are the same as R 2a in the general formula (2a) It is the same as R 2b , and the preferred base and the preferred number are also the same, so the description here is omitted.
作為通式(2b)所表示的化合物的具體例,例如可列舉以下的通式(2b-2.1)~通式(2b-2.11)及通式(2b-3.1)~通式(2b-3.9)所表示的化合物。As specific examples of the compound represented by the general formula (2b), for example, the following general formula (2b-2.1) to general formula (2b-2.11) and general formula (2b-3.1) to general formula (2b-3.9) can be cited The compound represented.
[化53] [化53]
[化54] [化54]
[化55] [化55]
通式(2b-2.1)~通式(2a-2.11)及通式(2b-3.1)~通式(2b-3.13)中,R2a 及R2b 與所述通式(2a)中的R2a 及R2b 相同,較佳的基、較佳的個數亦相同,因此省略此處的說明。In general formula (2b-2.1) to general formula (2a-2.11) and general formula (2b-3.1) to general formula (2b-3.13), R 2a and R 2b are the same as R 2a in general formula (2a) It is the same as R 2b , and the preferred base and the preferred number are also the same, so the description here is omitted.
作為通式(2c)所表示的化合物的具體例,例如可列舉以下的通式(2c-2.1)及通式(2c-3.1)所表示的化合物。As a specific example of the compound represented by general formula (2c), the compound represented by the following general formula (2c-2.1) and general formula (2c-3.1) is mentioned, for example.
[化56] [化56]
通式(2c-2.1)及通式(2c-3.1)中,R2a 及R2b 與所述通式(2a)中的R2a 及R2b 相同,較佳的基、較佳的個數亦相同,因此省略此處的說明。In the general formula (2c-2.1) and the general formula (2c-3.1), the R 2a and R 2b in the general formula (. 2A) the same as R 2a and R 2b, preferred groups, the preferred number is also The same, so the description here is omitted.
本發明的液晶組成物較佳為含有至少一種選自由通式(2a)~通式(2c)、通式(2a-1.1)~通式(2a-1.8)、通式(2b-1.1)~通式(2b-1.15)、通式(2c-1.1)~通式(2c-1.7)、通式(2a-2.1)~通式(2a-2.9)、通式(2a-3.1)~通式(2a-3.8)、通式(2b-2.1)~通式(2b-2.11)、通式(2b-3.1)~通式(2b-3.13)、通式(2c-2.1)或通式(2c-3.1)所表示的化合物所組成的群組中的化合物,較佳為含有兩種~八種。The liquid crystal composition of the present invention preferably contains at least one selected from general formula (2a) to general formula (2c), general formula (2a-1.1) to general formula (2a-1.8), general formula (2b-1.1) to General formula (2b-1.15), general formula (2c-1.1) ~ general formula (2c-1.7), general formula (2a-2.1) ~ general formula (2a-2.9), general formula (2a-3.1) ~ general formula (2a-3.8), general formula (2b-2.1) to general formula (2b-2.11), general formula (2b-3.1) to general formula (2b-3.13), general formula (2c-2.1) or general formula (2c) The compound in the group consisting of -3.1) preferably contains two to eight kinds of compounds.
於本發明的液晶組成物中,通式(2a)~通式(2c)、通式(2a-1.1)~通式(2a-1.8)、通式(2b-1.1)~通式(2b-1.15)、通式(2c-1.1)~通式(2c-1.7)、通式(2a-2.1)~通式(2a-2.9)、通式(2a-3.1)~通式(2a-3.8)、通式(2b-2.1)~通式(2b-2.11)、通式(2b-3.1)~通式(2b-3.13)、通式(2c-2.1)或通式(2c-3.1)所表示的化合物於液晶組成物100質量%中的合計含量的下限值較佳為0質量%,較佳為0.5質量%,較佳為1質量%,較佳為1.5質量%,較佳為2質量%,較佳為2.5質量%,較佳為3質量%,較佳為5質量%。In the liquid crystal composition of the present invention, general formula (2a) to general formula (2c), general formula (2a-1.1) to general formula (2a-1.8), general formula (2b-1.1) to general formula (2b- 1.15), general formula (2c-1.1) ~ general formula (2c-1.7), general formula (2a-2.1) ~ general formula (2a-2.9), general formula (2a-3.1) ~ general formula (2a-3.8) , General formula (2b-2.1) ~ general formula (2b-2.11), general formula (2b-3.1) ~ general formula (2b-3.13), general formula (2c-2.1) or general formula (2c-3.1) represented The lower limit of the total content of the compound in 100% by mass of the liquid crystal composition is preferably 0% by mass, preferably 0.5% by mass, preferably 1% by mass, preferably 1.5% by mass, and preferably 2% by mass %, preferably 2.5% by mass, preferably 3% by mass, more preferably 5% by mass.
於本發明的液晶組成物中,通式(2a)~通式(2c)、通式(2a-1.1)~通式(2a-1.8)、通式(2b-1.1)~通式(2b-1.15)、通式(2c-1.1)~通式(2c-1.7)、及/或更具體而言通式(2a-2.1)~通式(2a-2.9)、通式(2a-3.1)~通式(2a-3.8)、通式(2b-2.1)~通式(2b-2.11)、通式(2b-3.1)~通式(2b-3.13)、通式(2c-2.1)、通式(2c-3.1)所表示的化合物於液晶組成物100質量%中的合計含量的上限值較佳為50質量%,較佳為45質量%,較佳為38質量%,較佳為35質量%,較佳為25質量%,較佳為15質量%,較佳為10質量%,較佳為8質量%,較佳為5質量%。In the liquid crystal composition of the present invention, general formula (2a) to general formula (2c), general formula (2a-1.1) to general formula (2a-1.8), general formula (2b-1.1) to general formula (2b- 1.15), general formula (2c-1.1) ~ general formula (2c-1.7), and/or more specifically general formula (2a-2.1) ~ general formula (2a-2.9), general formula (2a-3.1) ~ General formula (2a-3.8), general formula (2b-2.1) ~ general formula (2b-2.11), general formula (2b-3.1) ~ general formula (2b-3.13), general formula (2c-2.1), general formula The upper limit of the total content of the compound represented by (2c-3.1) in 100% by mass of the liquid crystal composition is preferably 50% by mass, more preferably 45% by mass, more preferably 38% by mass, more preferably 35% by mass %, preferably 25% by mass, preferably 15% by mass, preferably 10% by mass, preferably 8% by mass, and preferably 5% by mass.
通式(2a)~通式(2c)、具體而言通式(2a-1.1)~通式(2a-1.8)、通式(2b-1.1)~通式(2b-1.15)、通式(2c-1.1)~通式(2c-1.7)、及/或更具體而言通式(2a-2.1)~通式(2a-2.9)、通式(2a-3.1)~通式(2a-3.8)、通式(2b-2.1)~通式(2b-2.11)、通式(2b-3.1)~通式(2b-3.13)、通式(2c-2.1)、通式(2c-3.1)所表示的化合物於液晶組成物100質量%中的合計含量具體而言較佳為5質量%~30質量%,較佳為5質量%~20質量%。General formula (2a) to general formula (2c), specifically general formula (2a-1.1) to general formula (2a-1.8), general formula (2b-1.1) to general formula (2b-1.15), general formula ( 2c-1.1) ~ general formula (2c-1.7), and/or more specifically general formula (2a-2.1) ~ general formula (2a-2.9), general formula (2a-3.1) ~ general formula (2a-3.8 ), general formula (2b-2.1) ~ general formula (2b-2.11), general formula (2b-3.1) ~ general formula (2b-3.13), general formula (2c-2.1), general formula (2c-3.1) Specifically, the total content of the represented compound in 100% by mass of the liquid crystal composition is preferably 5 mass% to 30 mass%, and more preferably 5 mass% to 20 mass%.
通式(2a)~通式(2c)、通式(2a-1.1)~通式(2a-1.8)、通式(2b-1.1)~通式(2b-1.15)、通式(2c-1.1)~通式(2c-1.7)、通式(2a-2.1)~通式(2a-2.9)、通式(2a-3.1)~通式(2a-3.8)、通式(2b-2.1)~通式(2b-2.11)、通式(2b-3.1)~通式(2b-3.13)、通式(2c-2.1)或通式(2c-3.1)所表示的化合物可藉由公知的方法進行製造。General formula (2a) to general formula (2c), general formula (2a-1.1) to general formula (2a-1.8), general formula (2b-1.1) to general formula (2b-1.15), general formula (2c-1.1) ) ~ General formula (2c-1.7), general formula (2a-2.1) ~ general formula (2a-2.9), general formula (2a-3.1) ~ general formula (2a-3.8), general formula (2b-2.1) ~ The compounds represented by general formula (2b-2.11), general formula (2b-3.1) to general formula (2b-3.13), general formula (2c-2.1) or general formula (2c-3.1) can be carried out by a known method manufacture.
於本發明的液晶組成物中,於重視對液晶組成物的溶解性的情況下,較佳為含有至少一種通式(2a)所表示的化合物,於重視Δn及TNI 的情況下,較佳為含有至少一種通式(2b)或通式(2c)所表示的化合物。In the liquid crystal composition of the present invention, when the solubility to the liquid crystal composition is important, at least one compound represented by the general formula (2a) is preferably contained, and when Δn and T NI are important, it is preferable It contains at least one compound represented by general formula (2b) or general formula (2c).
本發明的液晶組成物較佳為更含有至少一種通式(iii)所表示的化合物。The liquid crystal composition of the present invention preferably further contains at least one compound represented by general formula (iii).
[化57] [化57]
所述通式(iii)中,Riii1 表示碳原子數1~12的烷基、碳原子數1~8的烷氧基、碳原子數2~8的烯基、鹵化烷基的任一者,該烷基中的一個或非鄰接的兩個以上的-CH2 -或者該鹵化烷基中的一個或非鄰接的兩個以上的二級碳原子亦可經-O-、-CH=CH-、或-C≡C-取代。In the general formula (iii), R iii1 represents any of an alkyl group having 1 to 12 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, and a halogenated alkyl group , One or two or more non-adjacent -CH 2 -in the alkyl group, or one or more than two non-adjacent secondary carbon atoms in the halogenated alkyl group can also pass through -O-, -CH=CH -, or -C≡C- substitution.
碳原子數1~12的烷基為直鏈狀或分支狀的烷基,較佳為直鏈狀的烷基。The alkyl group having 1 to 12 carbon atoms is a linear or branched alkyl group, and preferably a linear alkyl group.
碳原子數1~12的烷基的碳原子數為1~12,較佳為1~8,較佳為1~5,較佳為2~5。The alkyl group having 1 to 12 carbon atoms has 1 to 12 carbon atoms, preferably 1 to 8, preferably 1 to 5, and more preferably 2 to 5.
作為碳原子數1~12的烷基的具體例,例如可列舉:甲基、乙基、丙基、丁基、戊基、己基、庚基、辛基、壬基、癸基、異癸基、十二烷基及2-乙基己基等。Specific examples of the alkyl group having 1 to 12 carbon atoms include, for example, methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, and isodecyl. , Dodecyl and 2-ethylhexyl, etc.
碳原子數1~8的烷氧基為直鏈狀或分支狀的烷氧基,較佳為直鏈狀的烷氧基。The alkoxy group having 1 to 8 carbon atoms is a linear or branched alkoxy group, and a linear alkoxy group is preferred.
碳原子數1~8的烷氧基的碳原子數較佳為1~5。The number of carbon atoms of the alkoxy group having 1 to 8 carbon atoms is preferably 1 to 5.
作為碳原子數1~8的烷氧基的具體例,例如可列舉:甲氧基、乙氧基、丙氧基、丁氧基、戊氧基、及己氧基等。Specific examples of the alkoxy group having 1 to 8 carbon atoms include, for example, a methoxy group, an ethoxy group, a propoxy group, a butoxy group, a pentoxy group, and a hexyloxy group.
碳原子數2~8的烯基為直鏈狀或分支狀的烯基,較佳為直鏈狀的烯基。The alkenyl group having 2 to 8 carbon atoms is a linear or branched alkenyl group, and a linear alkenyl group is preferred.
碳原子數2~8的烯基的碳原子數較佳為2~5,較佳為2~3。The number of carbon atoms of the alkenyl group having 2 to 8 carbon atoms is preferably from 2 to 5, and more preferably from 2 to 3.
作為碳原子數2~8的烯基的具體例,可列舉式(R1)~式(R5)所表示的基等(各式中的黑點表示環結構中的碳原子)。Specific examples of alkenyl groups having 2 to 8 carbon atoms include groups represented by formulas (R1) to (R5) (black dots in each formula represent carbon atoms in the ring structure).
[化58] [化58]
所述通式(iii)中,miii1 表示0、1或2的整數。In the general formula (iii), m iii1 represents an integer of 0, 1, or 2.
所述通式(iii)中,Aiii1 ~Aiii3 分別獨立地表示選自由下述基(a)~基(c): (a)1,4-伸環己基(該基中存在的一個-CH2 -或非鄰接的兩個以上的-CH2 -可取代為-O-或-S-)、 (b)1,4-伸苯基(該基中存在的一個-CH=或非鄰接的兩個以上的-CH=可取代為-N=)、 (c)萘-2,6-二基、1,2,3,4-四氫萘-2,6-二基或十氫萘-2,6-二基(萘-2,6-二基或1,2,3,4-四氫萘-2,6-二基中存在的一個-CH=或非鄰接的兩個以上的-CH=可取代為-N=) 所組成的群組中的基,所述基(a)、基(b)及基(c)中的一個或兩個以上的氫原子分別獨立地可取代為鹵素原子、碳原子數1~10的烷基或鹵化烷基。In the general formula (iii), A iii1 to A iii3 each independently represent a group selected from the following groups (a) to (c): (a) 1,4-cyclohexylene (one of the groups- CH 2 -or two or more non-adjacent -CH 2 -can be substituted with -O- or -S-), (b) 1,4-phenylene (one -CH= or non-adjacent Two or more of -CH= can be substituted with -N=), (c) naphthalene-2,6-diyl, 1,2,3,4-tetrahydronaphthalene-2,6-diyl or decahydronaphthalene -2,6-diyl (naphthalene-2,6-diyl or 1,2,3,4-tetrahydronaphthalene-2,6-diyl with one -CH= or two or more non-adjacent -CH= can be substituted with -N=) in the group consisting of one or more hydrogen atoms in the group (a), group (b) and group (c) are independently replaceable It is a halogen atom, an alkyl group having 1 to 10 carbon atoms, or a halogenated alkyl group.
作為鹵素原子,可列舉:氯原子、溴原子、氟原子。Examples of the halogen atom include a chlorine atom, a bromine atom, and a fluorine atom.
於Aiii1 存在多個的情況下,Aiii1 分別可相同亦可不同。 When there are multiple A iii1 , A iii1 may be the same or different.
Ziii1 及Ziii2 分別獨立地表示單鍵、-C≡C-、-CH=CH-、-CF=CF-或-C(Riiia )=N-N=C(Riiib )-,Riiia 及Riiib 分別獨立地表示氫原子、鹵素原子或者碳原子數1~10的直鏈或分支的烷基或鹵化烷基。Z iii1 and Z iii2 each independently represent a single bond, -C≡C-, -CH=CH-, -CF=CF- or -C(R iiia )=NN=C(R iiib )-, R iiia and R iiib each independently represents a hydrogen atom, a halogen atom, or a linear or branched alkyl group or halogenated alkyl group having 1 to 10 carbon atoms.
關於Ziii1 及Ziii2 ,於miii1 為0的情況下,較佳為Ziii2 為-C≡C-,於miii1 為1或2的情況下,較佳為Ziii1 及Ziii2 的至少一個為-C≡C-。即,於所述通式(iii)中,較佳為Ziii2 及存在0以上且2以下的Ziii1 中的至少一個表示-C≡C-。Regarding Z iii1 and Z iii2 , when m iii1 is 0, Z iii2 is preferably -C≡C-, and when m iii1 is 1 or 2, it is preferably at least one of Z iii1 and Z iii2 It is -C≡C-. That is, in the general formula (iii), it is preferable that at least one of Z iii2 and Z iii1 where 0 or more and 2 or less is present represents -C≡C-.
作為鹵素原子,可列舉:氯原子、溴原子、氟原子。Examples of the halogen atom include a chlorine atom, a bromine atom, and a fluorine atom.
於Ziii1 存在多個的情況下,Ziii1 分別可相同亦可不同。 When there are a plurality of Z iii1 , Z iii1 may be the same or different.
所述通式(iii)所表示的化合物較佳為以下的通式(iii-1)~通式(iii-6)所表示的化合物。The compound represented by the general formula (iii) is preferably a compound represented by the following general formulas (iii-1) to (iii-6).
[化59] [化59]
所述通式(iii-1)~通式(iii-6)中,Xiii1 ~Xiii6 分別獨立地表示氫原子、氟原子或氯原子。In the general formulas (iii-1) to (iii-6), X iii1 to X iii6 each independently represent a hydrogen atom, a fluorine atom, or a chlorine atom.
通式(iii-1)~通式(iii-6)中,Riii1 與所述通式(iii)中的Riii1 相同,較佳的基、較佳的個數亦相同,因此省略此處的說明。Formula (iii1) ~ In the general formula (iii-6), R iii1 as in the general formula (iii) R iii1 same preferred groups, preferred are also the same number, and therefore will be omitted here instruction of.
通式(iii)或通式(iii-1)~通式(iii-6)所表示的化合物於液晶組成物100質量%中的合計含量的下限值較佳為1.7質量%,較佳為2質量%,較佳為4質量%,較佳為4.3質量%,較佳為5質量%,較佳為5.7質量%,較佳為6質量%。The lower limit of the total content of the compounds represented by general formula (iii) or general formula (iii-1) to general formula (iii-6) in 100% by mass of the liquid crystal composition is preferably 1.7% by mass, more preferably 2% by mass, preferably 4% by mass, preferably 4.3% by mass, preferably 5% by mass, preferably 5.7% by mass, and preferably 6% by mass.
若合計含量多則會引起析出等問題,因此通式(iii)或通式(iii-1)~通式(iii-6)所表示的化合物於液晶組成物100質量%中的合計含量的上限值較佳為23質量%,較佳為20質量%,較佳為18質量%,較佳為14質量%,較佳為13質量%,較佳為10質量%,較佳為8質量%,較佳為5質量%。If the total content is large, problems such as precipitation may occur. Therefore, the compound represented by general formula (iii) or general formula (iii-1) to general formula (iii-6) is higher than the total content in 100% by mass of the liquid crystal composition. The limit is preferably 23% by mass, more preferably 20% by mass, more preferably 18% by mass, more preferably 14% by mass, more preferably 13% by mass, preferably 10% by mass, more preferably 8% by mass , Preferably 5 mass%.
通式(iii)或通式(iii-1)~通式(iii-6)所表示的化合物於液晶組成物100質量%中的合計含量具體而言較佳為2質量%~20質量%,較佳為4質量%~15質量%,較佳為6質量%~12質量%。The total content of the compounds represented by general formula (iii) or general formula (iii-1) to general formula (iii-6) in 100% by mass of the liquid crystal composition is specifically preferably 2% by mass to 20% by mass, It is preferably 4% by mass to 15% by mass, and more preferably 6% by mass to 12% by mass.
於本發明的液晶組成物中,所述通式(i-1)所表示的化合物、所述通式(i-2-1a)、通式(i-2-1b)及通式(i-2-1c)所表示的化合物及所述通式(ii)所表示的化合物於液晶組成物100質量%中的總量較佳為50質量%~100質量%,較佳為75質量%~100質量%。In the liquid crystal composition of the present invention, the compound represented by the general formula (i-1), the general formula (i-2-1a), the general formula (i-2-1b), and the general formula (i- The total amount of the compound represented by 2-1c) and the compound represented by the general formula (ii) in 100% by mass of the liquid crystal composition is preferably 50% by mass to 100% by mass, preferably 75% by mass to 100 quality%.
於本發明的液晶組成物中,所述通式(i-1-1)所表示的化合物、所述通式(i-2-1a-1)所表示的化合物及所述通式(ii-1)所表示的化合物於液晶組成物100質量%中的總量較佳為50質量%~100質量%,較佳為75質量%~100質量%。In the liquid crystal composition of the present invention, the compound represented by the general formula (i-1-1), the compound represented by the general formula (i-2-1a-1), and the general formula (ii- 1) The total amount of the represented compound in 100% by mass of the liquid crystal composition is preferably 50% by mass to 100% by mass, more preferably 75% by mass to 100% by mass.
於本發明的液晶組成物中,所述通式(i-1)所表示的化合物、所述通式(i-2-1a)、通式(i-2-1b)及通式(i-2-1c)所表示的化合物於液晶組成物100質量%中的總量較佳為50質量%~95質量%,較佳為55質量%~90質量%。In the liquid crystal composition of the present invention, the compound represented by the general formula (i-1), the general formula (i-2-1a), the general formula (i-2-1b), and the general formula (i- The total amount of the compound represented by 2-1c) in 100% by mass of the liquid crystal composition is preferably 50% to 95% by mass, and more preferably 55% to 90% by mass.
於本發明的液晶組成物中,所述通式(i-1-1)所表示的化合物、所述通式(i-2-1a-1)所表示的化合物於液晶組成物100質量%中的總量較佳為50質量%~95質量%,較佳為55質量%~90質量%。In the liquid crystal composition of the present invention, the compound represented by the general formula (i-1-1) and the compound represented by the general formula (i-2-1a-1) are in 100% by mass of the liquid crystal composition The total amount of is preferably 50% by mass to 95% by mass, more preferably 55% by mass to 90% by mass.
於本發明的液晶組成物中,所述通式(i-1)所表示的化合物及所述通式(ii)所表示的化合物於液晶組成物100質量%中的總量較佳為45質量%~70質量%,較佳為50質量%~65質量%。In the liquid crystal composition of the present invention, the total amount of the compound represented by the general formula (i-1) and the compound represented by the general formula (ii) in 100% by mass of the liquid crystal composition is preferably 45 mass % To 70% by mass, preferably 50% to 65% by mass.
於本發明的液晶組成物中,所述通式(i-1-1)所表示的化合物及所述通式(ii-1)所表示的化合物於液晶組成物100質量%中的總量較佳為45質量%~70質量%,較佳為50質量%~65質量%。In the liquid crystal composition of the present invention, the total amount of the compound represented by the general formula (i-1-1) and the compound represented by the general formula (ii-1) in 100% by mass of the liquid crystal composition is greater than It is preferably from 45% by mass to 70% by mass, and more preferably from 50% by mass to 65% by mass.
於本發明的液晶組成物中,所述通式(i-2-1a)、通式(i-2-1b)及通式(i-2-1c)所表示的化合物及所述通式(ii)所表示的化合物於液晶組成物100質量%中的總量較佳為50質量%~85質量%,較佳為55質量%~80質量%。In the liquid crystal composition of the present invention, the compound represented by the general formula (i-2-1a), the general formula (i-2-1b), and the general formula (i-2-1c) and the general formula ( ii) The total amount of the represented compound in 100% by mass of the liquid crystal composition is preferably 50% to 85% by mass, and more preferably 55% to 80% by mass.
於本發明的液晶組成物中,所述通式(i-2-1a)所表示的化合物及所述通式(ii-1)所表示的化合物於液晶組成物100質量%中的總量較佳為50質量%~85質量%,較佳為55質量%~80質量%。In the liquid crystal composition of the present invention, the total amount of the compound represented by the general formula (i-2-1a) and the compound represented by the general formula (ii-1) in 100% by mass of the liquid crystal composition is greater than It is preferably from 50% by mass to 85% by mass, and more preferably from 55% by mass to 80% by mass.
本發明的液晶組成物亦可根據使用態樣而適宜包含公知的穩定劑、公知的聚合性液晶化合物或公知的聚合化合物等添加劑。The liquid crystal composition of the present invention may suitably contain additives such as a known stabilizer, a known polymerizable liquid crystal compound, or a known polymer compound, depending on the mode of use.
作為穩定劑,例如可列舉:氫醌類、氫醌單烷基醚類、第三丁基兒茶酚類、鄰苯三酚類、噻吩類、硝基化合物類、β-萘胺類、β-萘酚類、伸硝基化合物類、受阻酚類、受阻胺類等。Examples of stabilizers include hydroquinones, hydroquinone monoalkyl ethers, tertiary butylcatechols, pyrogallols, thiophenes, nitro compounds, β-naphthylamines, β -Naphthols, nitroxide compounds, hindered phenols, hindered amines, etc.
使用穩定劑的情況下的穩定劑於液晶組成物100質量%中的合計含量較佳為0.005質量%~1質量%,較佳為0.02質量%~0.5質量%,較佳為0.03質量%~0.1質量%。In the case of using a stabilizer, the total content of the stabilizer in 100% by mass of the liquid crystal composition is preferably 0.005% by mass to 1% by mass, preferably 0.02% by mass to 0.5% by mass, and preferably 0.03% by mass to 0.1 quality%.
液晶組成物的液晶相上限溫度(TNI )是液晶組成物自向列相向各向同性相發生相轉變的溫度,TNI 越高,則即便於高溫下亦可維持向列相,因此可擴大驅動溫度範圍。TNI 較佳為130℃以上,較佳為130℃~200℃,較佳為130℃~180℃。The upper limit temperature of the liquid crystal phase (T NI ) of the liquid crystal composition is the temperature at which the liquid crystal composition undergoes a phase transition from the nematic phase to the isotropic phase. The higher the T NI , the nematic phase can be maintained even at high temperatures, so it can be expanded Drive temperature range. T NI is preferably 130°C or higher, preferably 130°C to 200°C, more preferably 130°C to 180°C.
本發明的液晶組成物於25℃、589 nm下的Δn(折射率各向異性)較佳為0.2以上,較佳為0.2~0.6,較佳為0.25~0.6,較佳為0.3~0.6,較佳為0.35~0.5。可見光區域的Δn與幾十GHz帶的Δε相關,Δn越高,則可使GHz帶的介電常數的變化越大。因此,若液晶組成物的589 nm下的Δn為0.3以上,則可增大GHz帶的介電常數的變化,因此適合作為感測器或天線用的液晶組成物。The Δn (refractive index anisotropy) of the liquid crystal composition of the present invention at 25° C. and 589 nm is preferably 0.2 or more, preferably 0.2 to 0.6, preferably 0.25 to 0.6, preferably 0.3 to 0.6, more Preferably, it is 0.35 to 0.5. The Δn in the visible light region is related to the Δε in the tens of GHz band. The higher the Δn, the greater the change in the dielectric constant of the GHz band. Therefore, if the Δn at 589 nm of the liquid crystal composition is 0.3 or more, the change in the dielectric constant in the GHz band can be increased, and therefore, it is suitable as a liquid crystal composition for sensors or antennas.
此處,於相位差Re、液晶層的厚度d(單元間隙)與Δn之間,式:Δn=Re/d的關係成立,於本說明書中,根據相位差測定裝置求出Δn。更具體而言,於帶聚醯亞胺配向膜的玻璃單元中注入本發明的液晶組成物的樣品,利用相位差膜-光學材料檢查裝置RETS-100(大塚電子股份有限公司製造)測定測定溫度25℃、589 nm下的面內的延遲(相位差Re)。再者,使用玻璃基板間的單元間隙為3.0 μm、聚醯亞胺配向膜的摩擦方向平行的玻璃單元。Here, between the phase difference Re, the thickness d (cell gap) of the liquid crystal layer, and Δn, the relationship of the formula: Δn=Re/d holds. In this specification, Δn is obtained from the phase difference measuring device. More specifically, a sample of the liquid crystal composition of the present invention is injected into a glass cell with a polyimide alignment film, and the measurement temperature is measured using a retardation film-optical material inspection device RETS-100 (manufactured by Otsuka Electronics Co., Ltd.) In-plane retardation (phase difference Re) at 25°C and 589 nm. In addition, a glass cell in which the cell gap between the glass substrates is 3.0 μm and the rubbing direction of the polyimide alignment film is parallel was used.
另外,亦可利用阿貝折射計測定液晶組成物的ne、no,算出Δn。In addition, it is also possible to measure ne and no of the liquid crystal composition with an Abbe refractometer to calculate Δn.
本發明的液晶組成物的25℃、1 kHz下的Δε(介電常數各向異性)較佳為10以上,較佳為10~30,較佳為12~25,較佳為14~20。Δε與Vth密切相關,Δε越高,越可降低Vth。The Δε (dielectric constant anisotropy) at 25°C and 1 kHz of the liquid crystal composition of the present invention is preferably 10 or more, more preferably 10-30, more preferably 12-25, more preferably 14-20. Δε is closely related to Vth, the higher the Δε, the lower the Vth.
本發明的液晶組成物的25℃下的臨限電壓(Vth)較佳為2.2 V以下,較佳為1.3 V~2.2 V,較佳為1.5 V~2.15 V,較佳為1.7 V~2.1 V。Vth表示液晶驅動的最低電壓,Vth低的液晶組成物即便於低電壓下亦可驅動液晶,因此可降低作為元件的驅動電壓。The threshold voltage (Vth) at 25°C of the liquid crystal composition of the present invention is preferably 2.2 V or less, preferably 1.3 V to 2.2 V, preferably 1.5 V to 2.15 V, preferably 1.7 V to 2.1 V . Vth represents the lowest voltage for driving the liquid crystal. A liquid crystal composition with a low Vth can drive liquid crystal even at a low voltage, and therefore can reduce the driving voltage as an element.
以下,對使用本發明的液晶組成物的液晶元件,更具體而言,對液晶元件、感測器、液晶透鏡、光通訊設備、天線進行說明。Hereinafter, the liquid crystal element using the liquid crystal composition of the present invention, more specifically, the liquid crystal element, the sensor, the liquid crystal lens, the optical communication device, and the antenna will be described.
本發明的液晶元件的特徵在於使用所述液晶組成物,較佳為以主動矩陣方式或被動矩陣方式驅動。The liquid crystal element of the present invention is characterized by using the liquid crystal composition, and is preferably driven by an active matrix method or a passive matrix method.
另外,本發明的液晶元件較佳為藉由可逆地改變所述液晶組成物的液晶分子的配向方向,從而可逆地切換介電常數的液晶元件。In addition, the liquid crystal element of the present invention is preferably a liquid crystal element that reversibly switches the dielectric constant by reversibly changing the alignment direction of the liquid crystal molecules of the liquid crystal composition.
本發明的感測器的特徵在於使用所述液晶組成物,例如,作為其態樣,可列舉:利用電磁波、可見光或紅外光的測距感測器;利用溫度變化的紅外線感測器;利用膽固醇型液晶的間距變化引起的反射光波長變化的溫度感測器;利用反射光波長變化的壓力感測器;利用組成變化引起的反射光波長變化的紫外線感測器;利用電壓、電流引起的溫度變化的電感測器;利用伴隨放射線粒子的徑跡的溫度變化的放射線感測器;利用超音波的機械振動引起的液晶分子排列變化的超音波感測器;利用溫度變化引起的反射光波長變化或電場引起的液晶分子排列變化的電磁感測器等。 作為測距感測器,較佳為使用光源的光達(Light Detection And Ranging,LiDAR)用感測器。 作為LiDAR,較佳為人造衛星用、飛機用、無人飛機(無人機)用、汽車用、鐵路用、船舶用。 作為汽車用,特佳為自動駕駛汽車用。 光源較佳為發光二極體(light-emitting diode,LED)或雷射,較佳為雷射。 用於LiDAR的光較佳為紅外光,波長較佳為800 nm~2000 nm。 特佳為905 nm或1550 nm的波長的紅外雷射。 於重視所使用的光檢測器的成本或全天候的感度的情況下,較佳為905 nm的紅外雷射,於重視與人的視覺相關的安全性的情況下,較佳為1550 nm的紅外雷射。 本發明的液晶組成物顯示出高Δn,因此可提供可見光、紅外光及電磁波區域的相位調變力大、檢測感度優異的感測器。The sensor of the present invention is characterized in that the liquid crystal composition is used. For example, as its aspect, it may be a distance measuring sensor using electromagnetic waves, visible light or infrared light; an infrared sensor using temperature changes; A temperature sensor that changes the wavelength of reflected light caused by a change in the pitch of the cholesteric liquid crystal; a pressure sensor that uses a change in the wavelength of reflected light; an ultraviolet sensor that uses a change in the wavelength of reflected light caused by a change in composition; Inductive sensors for temperature changes; radiation sensors that use temperature changes that accompany the tracks of radiation particles; ultrasonic sensors that use the changes in the arrangement of liquid crystal molecules caused by the mechanical vibration of ultrasonic waves; use the wavelength of reflected light caused by temperature changes Electromagnetic sensors that change the arrangement of liquid crystal molecules caused by changes or electric fields. As the ranging sensor, a sensor for LiDAR (Light Detection And Ranging, LiDAR) using a light source is preferable. LiDAR is preferably used for artificial satellites, airplanes, unmanned aircraft (unmanned aerial vehicles), automobiles, railways, and ships. As for cars, it is especially good for self-driving cars. The light source is preferably a light-emitting diode (LED) or a laser, preferably a laser. The light used for LiDAR is preferably infrared light, and the wavelength is preferably 800 nm to 2000 nm. Especially preferred is an infrared laser with a wavelength of 905 nm or 1550 nm. In the case of attaching importance to the cost of the photodetector used or the sensitivity of all-weather, the infrared laser of 905 nm is preferred, and in the case of attaching importance to the safety related to human vision, the infrared laser of 1550 nm is preferred. shoot. The liquid crystal composition of the present invention exhibits a high Δn, and therefore can provide a sensor with high phase modulation power in the visible light, infrared light, and electromagnetic wave regions and excellent detection sensitivity.
本發明的液晶透鏡的特徵在於使用所述液晶組成物,例如,作為其態樣之一,包括:第一透明電極層、第二透明電極層、設置於所述第一透明電極層及所述第二透明電極層之間的含有所述液晶組成物的液晶層、設置於所述第二透明電極層及所述液晶層之間的絕緣層、以及設置於所述絕緣層及所述液晶層之間的高電阻層。本發明的液晶透鏡例如用作二維(Two-dimensional,2D)、3D的切換透鏡、照相機的焦點調節用透鏡等。The liquid crystal lens of the present invention is characterized by using the liquid crystal composition. For example, as one of its aspects, it includes: a first transparent electrode layer, a second transparent electrode layer, the first transparent electrode layer, and the A liquid crystal layer containing the liquid crystal composition between the second transparent electrode layers, an insulating layer disposed between the second transparent electrode layer and the liquid crystal layer, and the insulating layer and the liquid crystal layer Between the high resistance layers. The liquid crystal lens of the present invention is used, for example, as a two-dimensional (2D) or 3D switching lens, a lens for focus adjustment of a camera, and the like.
本發明的光通訊設備的特徵在於使用所述液晶組成物,例如,作為其態樣之一,可列舉如下結構的矽上液晶(Liquid crystal on silicon,LCOS),其於反射層(電極)上具有液晶層,所述液晶層中二維狀地配置有構成多個畫素的各個的液晶。本發明的光通訊設備例如用作空間相位調變器。The optical communication device of the present invention is characterized by using the liquid crystal composition. For example, as one of its aspects, liquid crystal on silicon (LCOS) with the following structure can be cited, which is on the reflective layer (electrode) It has a liquid crystal layer in which liquid crystals constituting a plurality of pixels are arranged two-dimensionally. The optical communication device of the present invention is used as a spatial phase modulator, for example.
本發明的天線的特徵在於使用所述液晶組成物。 更具體而言,本發明的天線包括:具有多個槽(slot)的第一基板、與所述第一基板相向且設置有供電部的第二基板、設置於所述第一基板與所述第二基板之間的第一電介質層、與所述多個槽對應地配置的多個貼片電極(patch electrode)、設置有所述貼片電極的第三基板、以及設置於所述第一基板與所述第三基板之間的液晶層,且所述液晶層含有所述液晶組成物。The antenna of the present invention is characterized by using the liquid crystal composition. More specifically, the antenna of the present invention includes: a first substrate having a plurality of slots, a second substrate opposite to the first substrate and provided with a power supply unit, and a second substrate provided on the first substrate and the A first dielectric layer between the second substrates, a plurality of patch electrodes arranged corresponding to the plurality of grooves, a third substrate provided with the patch electrodes, and a third substrate provided with the patch electrodes, and A liquid crystal layer between the substrate and the third substrate, and the liquid crystal layer contains the liquid crystal composition.
藉由利用含有所述通式(i-1)所表示的化合物的一種或兩種以上、選自通式(i-2-1a)、通式(i-2-1b)及通式(i-2-1c)中的化合物的一種或兩種以上、以及所述通式(ii)所表示的化合物的一種或兩種以上的液晶層,可提供顯示出大介電常數各向異性(Δε)、高液晶相上限溫度(TNI )、低臨限電壓(Vth),具有高折射率各向異性(Δn),且向列液晶溫度範圍廣,常溫下穩定,進而對熱等外部刺激具有高可靠性的天線。藉此,可提供一種能夠對微波或毫米波的電磁波進行更大的相位控制的天線。By using one or two or more of the compounds represented by the general formula (i-1), selected from the general formula (i-2-1a), the general formula (i-2-1b), and the general formula (i-1) -2-1c) One or two or more of the compounds and one or two or more of the compounds represented by the general formula (ii) can provide a liquid crystal layer exhibiting a large dielectric constant anisotropy (Δε ), high liquid crystal phase upper limit temperature (T NI ), low threshold voltage (Vth), with high refractive index anisotropy (Δn), and nematic liquid crystal temperature range is wide, stable at room temperature, and then has the ability to heat and other external stimuli Highly reliable antenna. Thereby, it is possible to provide an antenna capable of greater phase control of electromagnetic waves of microwaves or millimeter waves.
以下,使用圖式對本發明的天線進行說明。Hereinafter, the antenna of the present invention will be described using drawings.
如圖1所示,連結有四個天線單元1的天線組裝體11安裝於車輛(汽車)2的車頂部。天線單元1為平面型天線,且安裝於車頂部,因此天線單元1始終朝向通訊衛星方向。藉此,可進行雙方均能收發的衛星通訊。As shown in FIG. 1, an
再者,本說明書中的「天線」包括天線單元1或連結多個天線單元1的天線組裝體11。Furthermore, the “antenna” in this specification includes an
本發明的天線較佳為於用於衛星通訊的Ka帶頻率或者K帶頻率或Ku帶頻率下運作。The antenna of the present invention preferably operates at Ka-band frequency or K-band frequency or Ku-band frequency used for satellite communications.
接著,圖2中示出天線單元1的構成要素的實施形態的一例。圖2是圖1所示的天線單元1的分解圖。具體而言,天線單元1的結構包括:天線本體10;控制板4,控制天線本體10;殼體3,具有能夠收容天線本體10及控制板4的凹部;以及上蓋5,將殼體3封閉。Next, an example of an embodiment of the constituent elements of the
控制板4中設置有發送機及/或接收機。發送機具有如下機構:藉由資訊源編碼處理,對語音或圖像等資料之類的來自訊號源的資訊,例如進行語音編碼或圖像編碼等,並藉由傳輸線路編碼處理進行糾錯編碼後,進行調變而作為電波傳輸。另一方面,接收機具有如下機構:對入射電波進行調變,藉由傳輸線路解碼處理進行糾錯後,藉由資訊源解碼處理,例如經過語音解碼或圖像解碼,轉換為語音或圖像等資料之類的資訊。另外,控制板4由公知的微電腦即中央處理單元(Central Processing Unit,CPU)、隨機存取記憶體(Random Access Memory,RAM)、唯讀記憶體(Read Only Memory,ROM)等構成,統一控制天線本體1、發送機及/或接收機的各部的運作。藉由將預先保存於控制板4所具備的CPU或ROM中的各種程式讀出至RAM中執行,來執行規定的處理。控制板4具備以下部件等的功能:儲存部,儲存各種設定資訊或控制程式;運算部,執行與向天線本體1內的液晶層施加的電壓量及電壓方向有關的各種運算、與電波的發送有關的各種運算、以及/或者電波的接收中的各種運算;檢測部,進行接收電波或發送電波的檢測或者對液晶層的施加電壓的檢測。The control board 4 is provided with a transmitter and/or a receiver. The transmitter has the following mechanism: through the information source encoding process, the information from the signal source such as voice or image data, such as voice encoding or image encoding, etc., and error correction encoding through the transmission line encoding process After that, it is modulated and transmitted as an electric wave. On the other hand, the receiver has the following mechanism: modulate the incident radio wave, perform error correction through the transmission line decoding process, and convert it into voice or image through the information source decoding process, such as speech decoding or image decoding. Information such as data. In addition, the control board 4 is composed of a well-known microcomputer, namely a central processing unit (Central Processing Unit, CPU), a random access memory (Random Access Memory, RAM), a read only memory (Read Only Memory, ROM), etc., and the unified control The operation of each part of the
圖2中,作為能夠收容圓盤型的天線本體1的殼體3的一例,記載有六稜柱型的殼體3及上蓋5,但可根據天線本體1的形狀將殼體3及上蓋5適宜變更為圓柱狀、八稜柱狀、三稜柱狀等公知的形狀。In FIG. 2, as an example of the housing 3 capable of accommodating the disc-shaped
為了說明天線本體10的結構,以下使用圖3~圖10進行說明。圖3是對天線本體10的構成要素進行了分解的概略圖。In order to describe the structure of the antenna
如圖3所示,天線本體10包括槽陣列部6及貼片陣列部7。而且,於槽陣列部6中,於圓板狀的導體P面上形成有多個槽(切口部)8,於槽陣列部6的中心部的內部設置有供電部12。另外,於貼片陣列部7中,作為一例,於圓板體Q形成有多個長度為L、寬度為W的方形的貼片(patch)9。而且,天線本體10具有如下結構:包括形成有多個槽8的圓板狀的導體P即槽陣列部6、及形成有多個貼片的圓板狀的貼片陣列部7,並且貼片陣列部7與槽陣列部6以相對於該圓板狀的導體P的表面上所形成的各個槽8而將貼片9相對配置的方式貼合。As shown in FIG. 3, the
槽陣列部6是將圓板狀的導體P面上空出的切口部(以下為槽8)用作放射元件(或入射元件)的天線部。而且,槽陣列部6包括槽8及設置於圓板狀的導體P的中心部的供電部12。一般而言,槽陣列部6具有於傳輸線路的前端直接激勵、或者經由設置於槽背面的空腔進行激勵的機構。而且,槽陣列部6可用於自利用底板的天線或微帶線(microstrip line)等經由槽向貼片天線供電等。圖3中,作為槽陣列部6的一例,記載了徑向線槽陣列的形態,但本發明的範圍並不限定於此。The
圖4中示出圖3的槽陣列部6的俯視圖。以下,使用圖4來說明槽陣列部6。槽陣列部6具有藉由設置於其中心部的同軸線來進行供電的結構。因此,於圖4所示的槽陣列部6的中心部設置有供電部12。另外,槽陣列部6於圓板狀的導體P的表面上形成有多個成組的槽8(以下稱為「槽對」)。槽對8具有兩個長方形形狀的切口部配置為「八」字的結構。更詳細而言,兩個長方體形狀的槽8以正交的方式配置,槽對8的其中一個槽相對於另一個槽間隔1/4波長地配置。藉此,可根據天線的方位角而收發具有不同的旋轉方向的圓極化波。FIG. 4 shows a plan view of the
再者,本說明書中,將兩個槽8稱為槽對8,將一個槽8簡稱為槽8,將槽及槽對的總稱稱為槽(對)8。In addition, in this specification, two
槽對8自圓板狀的導體基板P的中心部朝向放射方向外側以螺旋狀形成有多個。而且,槽對8以沿著螺旋相鄰的槽對8間的距離均固定的方式形成於圓盤型的基板表面。藉此,可使相位在槽陣列部6的正面一致而增強電磁場,且可在正面形成筆型波束(pencil beam)。A plurality of groove pairs 8 are formed spirally from the center of the disc-shaped conductive substrate P toward the outside in the radial direction. In addition, the
再者,圖3及圖4中,將槽8的形狀的一例表示為長方體的形狀,但本發明的槽8的形狀並不限定於長方體,可採用圓形、橢圓形、多邊形等公知的形狀。另外,圖3及圖4中,作為槽8的一例,示出了槽對的態樣,但本發明的槽8並不限定於槽對。進而,示出了使圓板狀的導體基板P的表面的槽8的配置為螺旋狀的例子,但槽8的配置並不限定於螺旋狀,亦可將槽8配置為例如後述的圖8所示般的同心圓狀。In addition, in FIGS. 3 and 4, an example of the shape of the
本發明的供電部12具有接收電磁波及/或放射電磁波的功能。而且,本發明的供電部12只要是將由作為放射元件或入射元件的貼片9捕捉電波而產生的高頻電力向接收機傳輸的部分,或者為了供給高頻電力而連接放射元件與供電線的部分,則並無特別限制,可利用公知的供電部及供電線。圖3及圖4中示出同軸供電部作為一例。The
如圖3所示,貼片陣列部7包括:圓板體Q,具有多個長度為L、寬度為W的方形形狀的貼片9;以及液晶層(未圖示),填充在與槽陣列部6之間。本實施形態的貼片陣列部7是所謂的微帶天線的結構,是以長度L與1/2波長的整數倍一致的頻率共振的共振器。As shown in FIG. 3, the patch array portion 7 includes: a disc body Q, a plurality of square-shaped
再者,圖3中,作為貼片9的一例,示出了長度為L、寬度為W的方形形狀的貼片9,但貼片9的形狀並不限定於四邊形,亦可為圓形形狀的貼片9。圖5中示出了圓形形狀的貼片9的實施形態作為本發明的另一實施形態。Furthermore, in FIG. 3, as an example of the
圖5是本發明的天線本體10的俯視圖,更詳細而言,是於自貼片陣列部7觀察天線本體10的情況下,相對於圓板體Q的主面而垂直投影貼片9、供電部12、槽對8的圖。因此,由虛線表示貼片9、供電部12及槽對8。另外,於貼片9的形狀為圓形形狀的情況下,一般而言,可以被稱為TM11
模式的電磁場分佈來運作。如圖5所示,貼片9的投影體與槽對8的投影體重合,因此可理解設置於圓板體Q上的貼片9相對於圓板狀的導體P的表面上所形成的各個槽8相對配置的狀態。如上所述,藉由利用相對於各個槽8對應地配置各個貼片9的結構,可藉由電磁耦合供電方式自槽8向貼片9供電,或者自貼片9向槽8傳播入射電波。因此,可提供能夠發送及/或接收電波的天線。5 is a plan view of the
一般而言,使用同軸線等一般的傳輸線路或平面型傳輸線路來對貼片陣列部7的放射元件(例如貼片9)進行供電的方法大致分為直接連接供電方式及電磁耦合供電方式兩種。因此,作為本發明的供電方式,可列舉:直接連接供電方式,其是藉由將傳輸線路直接連接於貼片9(放射元件)來激勵放射元件的方法;以及電磁耦合供電方式,其是不直接連接傳輸線路與貼片電極(放射元件),而藉由在終端開放或短路的供電線路的周圍產生的電磁場來激勵貼片電極(放射元件)的方法。本發明中,示出電磁耦合供電方式的態樣。Generally speaking, the method of using a general transmission line such as a coaxial line or a planar transmission line to supply power to the radiating element (for example, the patch 9) of the patch array section 7 is roughly divided into a direct connection power supply method and an electromagnetic coupling power supply method. kind. Therefore, as the power supply method of the present invention, a direct connection power supply method, which is a method of exciting a radiation element by directly connecting a transmission line to the patch 9 (radiation element), and an electromagnetic coupling power supply method, which are not The transmission line and the patch electrode (radiation element) are directly connected, and the patch electrode (radiation element) is excited by the electromagnetic field generated around the power supply line whose terminal is open or short-circuited. In the present invention, the aspect of the electromagnetic coupling power supply method is shown.
本實施形態中,利用(同軸)供電部12的供電線路為終端開放,因此產生該供電線路的終端與節點一致的電流駐波。藉此,產生包圍該供電線路((同軸)供電部12)般的磁場,藉由該磁場入射至槽8,而將槽(對)8激勵。而且,藉由因槽(對)8的激勵而產生的磁場入射至貼片9,而將貼片9激勵。由於激勵強度最大是入射至槽8的磁場最大時,因此較佳為於自供電線路((同軸)供電部12)產生的磁場最大的位置(電流駐波的波腹)形成槽(對)8。In the present embodiment, the power supply line using the (coaxial)
本發明的天線的較佳態樣是將徑向線槽陣列與貼片天線陣列組合而成的結構。The preferred aspect of the antenna of the present invention is a structure formed by combining a radial slot array and a patch antenna array.
接著,使用圖5所示的天線本體10的剖面圖即圖6來說明天線本體10的實施形態。圖6理所當然是表示天線的結構的概略圖。Next, an embodiment of the
如圖6所示,天線本體10包括:圓板狀的第二基板14、自中心部朝向放射方向外側形成有多個槽(對)8的圓板狀的第一基板13(與圓板狀的導體P對應;亦稱為槽陣列基板)、設置於第二基板14及第一基板13之間的第一電介質層17、設置於圓板狀的第一基板13及圓板狀的第二基板14的中心部的供電部12、圓板狀的第三基板15(與圓板體Q對應;亦稱為貼片基板)、安裝於第三基板15的貼片9(放射元件或入射元件)、以及設置於第三基板15及第一基板13之間的液晶層16。另外,供電部12經由供電線12a與設置於控制基板的發送機及/或接收機電性連接。而且,各個貼片9對應於各個槽對8。As shown in FIG. 6, the
此處所謂的「(各)貼片9對應於(各)槽對8」,是指如所述圖5的說明所示,相對於第二基板14的主面而垂直投影貼片9的投影面與槽(對)8重合。換言之,是指相對於第三基板15的主面而垂直投影槽(對)8的投影面與貼片9重合。The so-called "(each)
另外,第一基板13、第二基板14及第三基板15較佳為具有相同面積的圓板體。In addition, the
於圖6中,描述了由(同軸)供電部12供電的電波(箭頭)成為圓筒波而在第一電介質層17內向放射方向外側傳播的期間,自槽(對)8向液晶層16傳輸的情況。而且,若如圖4所示,槽(對)8被配置成使所謂的「八」字型的正交的兩個槽錯開1/4波長,則可產生圓極化波。如上所述,藉由電磁耦合供電方式而將槽(對)8激勵,藉此自槽(對)8產生的磁場入射至貼片9而將貼片9激勵。其結果,貼片9可放射出指向性高的電波。In FIG. 6, it is described that the radio wave (arrow) supplied by the (coaxial)
另一方面,於接收入射電波的情況下,根據收發可逆的定理,與所述相反地,貼片9接收到入射電波後,經由設置於該貼片9正下方的槽(對)8而將入射電波傳播至供電部12。On the other hand, in the case of receiving incident radio waves, according to the reversible theorem of transmission and reception, in contrast to the above, the
圓極化波與線性極化波不同,是電場方向隨著時間經過而旋轉的電波,分類為在全球定位系統(global positioning system,GPS)或電子收費(electronic toll collection,ETC)中使用的右旋圓極化波、及在衛星無線電廣播等中使用的左旋圓極化波,本發明的天線中,任一極化波均可接收。Circularly polarized waves are different from linearly polarized waves. They are electric waves in which the direction of the electric field rotates with the passage of time. They are classified into the right ones used in the global positioning system (GPS) or electronic toll collection (ETC). For the circularly polarized wave and the left-handed circularly polarized wave used in satellite radio broadcasting, etc., any polarized wave can be received in the antenna of the present invention.
藉由向貼片9與第一基板13之間的液晶層16施加電壓,可改變液晶層16的液晶分子的配向方向。其結果,液晶層16的介電常數發生變化,因此槽(對)8的靜電電容發生變化,結果可控制槽(對)8的電抗及共振頻率。換言之,藉由控制液晶層16的介電常數,可調節槽8的電抗及共振頻率,因此可控制藉由調節槽(對)8及貼片9的激勵而進行的對各貼片9的供電。藉此,能夠調節經由液晶層16的放射電波。因此,例如,亦可設置薄膜電晶體(thin film transistor,TFT)等調節向液晶層16施加的電壓的施加電壓調節部件。另外,藉由改變液晶層16的液晶分子的配向方向,折射率發生變化,作為其結果,透過液晶層16的電磁波的相位發生偏移,作為其綜合結果,能夠進行相位陣列控制。By applying a voltage to the
第一基板13及第二基板14的材料只要為銅等導體則並無特別限制。另外,第三基板15的材料並無特別限制,根據使用態樣,可使用玻璃基板、亞克力基板、陶瓷(氧化鋁)、矽、玻璃布(glass cloth)鐵氟龍(Teflon)(註冊商標)(聚四氟乙烯(polytetrafluoroethylene,PTFE))等公知的材料。第一電介質層17的材料可根據所期望的相對介電常數適宜選擇公知的材料,亦可為真空。進而,貼片9的材料只要為銅、銀等導體則並無特別限制。The material of the
接著,使用圖7來說明天線本體10的另一實施形態。圖7中所示的實施形態是天線本體10的槽陣列部6的部分與圖6所示的實施形態不同的態樣。於圖7中,天線本體10包括:於其中一個表面形成有多個槽(對)8的中空體的第一基板13;收容於該中空體的第一基板13的內部的圓板狀的第二基板14、第一電介質層17及供電部12;圓板狀的第三基板15;安裝於第三基板15的貼片9;以及設置於第三基板15及第一基板13之間的液晶層16,且供電部12設置於第一基板13的另一個未形成多個槽(對)8的表面與第二基板14之間,並且設置於第一基板13及圓板狀的第二基板14的中心部。另外,供電部12經由供電線12a與設置於控制基板的發送機及/或接收機電性連接。而且,各個貼片9對應於各個槽對8。另外,於圖7中,中空體的第一基板13的兩側面部向中空體的外側突出,具體而言,具有相對於水平方向成45°的傾斜面。Next, another embodiment of the
如圖7中所示,由(同軸)供電部12供電的電波(箭頭)成為圓筒波而在第一電介質層17內向放射方向外側傳播。而且,傳播的圓筒波被中空體的第一基板13的兩側面部反射,藉此繞過第二基板14的圓筒波被變換為自圓板狀的第一基板13的外周朝向中心的行進波(箭頭),於第一電介質層17內傳播。此時,行進波自槽(對)8傳輸至液晶層16。藉此,與圖6所示的實施形態同樣地,貼片9被激勵,可放射出指向性高的電波。As shown in FIG. 7, the electric wave (arrow) fed by the (coaxial)
另一方面,於接收到入射電波的情況下亦同樣地,貼片9接收到入射電波後,經由設置於該貼片9正下方的槽(對)8而將入射電波傳播至供電部12。
接著,使用圖8~圖10來對天線本體10的又一實施形態進行說明。於以上所述的圖5~圖7的天線本體10的實施形態中,對在第一基板13與第三基板15之間均勻地設置液晶層16的天線本體10的結構進行了說明。另一方面,於圖8~圖10的實施形態中,對在分別配置有貼片9與槽8的空間內(以下為密閉區域20)填充有液晶層16的天線本體10的結構進行說明。On the other hand, when the incident radio wave is received, the
圖8是表示本發明的天線本體10的實施形態的一例的俯視圖。更詳細而言,圖8是於自貼片陣列部7觀察天線本體10的情況下,相對於圓板體Q的主面而垂直投影貼片9、供電部12、槽8的圖。因此,與圖5同樣地,由虛線表示貼片9、供電部12及槽8。圖8中,方形形狀的貼片9與一個長方體形狀的槽8分別對應於密閉區域20而配置。另外,如圖8所示,貼片9的投影體與槽8的投影體重合,因此於貼片9的正下方形成有槽8。藉此,圖8所示的天線本體10的實施形態可藉由電磁耦合供電方式自槽8向貼片9供電,或者自貼片9向槽8傳播入射電波。因此,可提供能夠發送及/或接收電波的天線。Fig. 8 is a plan view showing an example of an embodiment of the
另外,如圖8中所示,於本實施形態中,貼片9及槽8自圓板體Q的中心朝向圓板體Q的外周方向配置成同心圓狀。因此,藉由同軸模式供電,會出現圓錐波束,因此於圓板體Q的正面相位一致,電磁場可相互增強。In addition, as shown in FIG. 8, in this embodiment, the
接著,使用圖8所示的天線本體10的剖面圖即圖9來說明天線本體10的實施形態。再者,圖9理所當然是表示天線的結構的概略圖。Next, an embodiment of the
如圖9所示,天線本體10包括:圓板狀的第二基板14;多個槽8自中心部朝向放射方向外側形成為同心軸狀的圓板狀的第一基板13;設置於第二基板14側的第一基板13表面的緩衝層22;設置於緩衝層22與第二基板14之間的第一電介質層17;設置於圓板狀的第一基板13及圓板狀的第二基板14的中心部,且以與第一電介質層17接觸的方式設置的供電部12;圓板狀的第三基板15;安裝於第三基板15的貼片9(放射元件或入射元件);以及由第三基板15及第一基板13之間的密封壁24隔離,且以與貼片9接觸的方式將設置有貼片9的多個密閉區域20內填充的液晶層16。另外,供電部12經由供電線12a與設置於控制基板的發送機及/或接收機電性連接。而且,各個貼片9對應於各個槽8,於各密閉區域20內存在至少一個貼片9、至少一個槽8及液晶層16,多個密閉區域20的各個經由密封壁21、密封壁23、密封壁24而被隔離。As shown in FIG. 9, the
圖9中雖未示出,但根據需要,亦可於各密閉區域20內,例如於第一基板13上設置控制液晶層16的電壓的TFT(薄膜電晶體)。藉此,可以主動方式控制液晶層16的電壓的施加。另外,視需要,亦可於各密閉區域20內設置配向膜,用以固定構成液晶層16的液晶分子的配向方向。作為所述配向膜,可於第一基板13與液晶層16間設置容易向液晶分子的垂直方向配向的垂直配向膜或者容易向液晶分子的水平方向配向的均勻配向膜。例如可列舉聚醯亞胺配向膜、光配向膜等。Although not shown in FIG. 9, if necessary, a TFT (Thin Film Transistor) for controlling the voltage of the
接著,使用圖8所示的天線本體10的沿B-B線切斷的剖面圖即圖10來說明本實施形態的密閉區域20。再者,圖10理所當然是表示密閉區域20的概略圖。Next, the
如圖10所示,密閉區域20是由密封壁24、緩衝層22及第一基板13與第三基板15將上下四方包圍的密閉空間,在內部至少一個貼片9與至少一個槽8以相對的方式設置於同一密閉空間內,且填充有液晶層16。於本實施形態中,密封壁24可由公知的絕緣體等形成。另外,緩衝層22可由公知的電介質材料等形成。As shown in FIG. 10, the sealed
圖10中雖未示出,但根據需要,亦可於密閉區域20內,例如於第一基板13上設置控制液晶層16的電壓的TFT(薄膜電晶體)。藉此,可以主動方式控制液晶層16的電壓的施加。若對該利用主動方式的驅動方法進行更詳細的說明,則例如可列舉:以貼片9為共用電極,且以第一基板13為畫素電極,藉由形成於第一基板13上的TFT來控制貼片9與第一基板13之間的電壓,從而控制液晶層16的液晶分子的配向的方法;或者,以第一基板13為畫素電極,且於第一基板13上形成電極層及TFT,控制貼片9與第一基板13之間的電壓,從而控制液晶層16的液晶分子的配向的方法;進而,於第一基板13上設置梳齒電極及TFT,藉由該TFT來控制液晶層16的液晶分子的配向的方法等。再者,以主動方式控制液晶層16的電壓的施加的方法並不限定於所述方法。另外,此時,亦可於各密閉區域20內設置配向膜,用以固定構成液晶層16的液晶分子的配向方向。作為所述配向膜,可於第一基板13與液晶層16之間設置容易向液晶分子的垂直方向配向的垂直配向膜或者容易向液晶分子的水平方向配向的均勻配向膜。Although not shown in FIG. 10, if necessary, a TFT (Thin Film Transistor) for controlling the voltage of the
為了使液晶層16同步,可對向貼片9與第一基板13之間的液晶層16施加的電壓進行調變。例如,如上所述,藉由使用主動方式控制對液晶層16的施加電壓,槽8的靜電電容發生變化,結果可控制槽8的電抗及共振頻率。槽8的共振頻率與自在線路中傳播的電波放射的能量具有相關關係。因此,藉由調整槽8的共振頻率,槽8實質上不與來自供電部12的圓筒波能量耦合,或者與圓筒波能量耦合並放射至自由空間。此種槽8的電抗及共振頻率的控制可在形成有多個的密閉區域20的各個中進行。換言之,藉由控制液晶層16的介電常數,可藉由TFT來控制對各密閉區域20內的貼片9的供電。因此,可控制發送電波的貼片9及不發送電波的貼片,因此能夠調節經由液晶層16的放射電波的發送及接收。
[實施例]In order to synchronize the
以下,列舉實施例來更詳細地說明本發明,但本發明並不受下述實施例的任何限定。以下實施例及比較例的組成物以表中的比例含有各化合物,含量以「質量%」記載。於實施例中,對化合物的記載使用以下的略號。另外,表中,「n.d.」表示無資料。 <環結構>Hereinafter, examples are given to illustrate the present invention in more detail, but the present invention is not limited to the following examples at all. The composition of the following Examples and Comparative Examples contains each compound in the ratio in the table, and the content is described as "mass %". In the examples, the following abbreviations are used for the description of the compounds. In addition, in the table, "n.d." means no data. <Ring structure>
[化60] [化60]
於以下的實施例中,只要並無特別說明,則可採取順式體與反式體的化合物表示反式體。 <末端結構>In the following examples, as long as there is no special description, a compound that can take the cis-body and the trans-body means the trans-body. <Terminal structure>
[表1]
(其中,表中的n為自然數) <連結結構>(Among them, n in the table is a natural number) <Link structure>
[表2]
(其中,表中的n為自然數) <物性值> TNI (℃):液晶組成物自向列相向各向同性相轉變的溫度 Δn:液晶組成物的25℃、589 nm下的折射率各向異性 Δε:液晶組成物的25℃、1 kHz下的介電常數各向異性 Vth:液晶組成物的25℃下的臨限電壓(8.3 μm間隙TN單元) (實施例1) 製作實施例1的液晶組成物,測定其物性值。以下示出液晶組成物的結構及物性值的結果。(Where n in the table is a natural number) <Physical property value> T NI (°C): the temperature at which the liquid crystal composition transforms from the nematic phase to the isotropic phase Δn: the refractive index of the liquid crystal composition at 25°C and 589 nm Anisotropy Δε: Dielectric constant at 25°C and 1 kHz of the liquid crystal composition Anisotropy Vth: Threshold voltage (8.3 μm gap TN cell) at 25°C of the liquid crystal composition (Example 1) Production Example The liquid crystal composition of 1 was measured for its physical properties. The results of the structure and physical properties of the liquid crystal composition are shown below.
[表3]
(實施例2) 製作實施例2的液晶組成物,測定其物性值。以下示出液晶組成物的結構及物性值的結果。(Example 2) The liquid crystal composition of Example 2 was produced, and its physical properties were measured. The results of the structure and physical properties of the liquid crystal composition are shown below.
[表4]
(實施例3) 製作實施例3的液晶組成物,測定其物性值。以下示出液晶組成物的結構及物性值的結果。(Example 3) The liquid crystal composition of Example 3 was produced, and its physical properties were measured. The results of the structure and physical properties of the liquid crystal composition are shown below.
[表5]
(實施例4) 製作實施例4的液晶組成物,測定其物性值。以下示出液晶組成物的結構及物性值的結果。(Example 4) The liquid crystal composition of Example 4 was produced, and its physical properties were measured. The results of the structure and physical properties of the liquid crystal composition are shown below.
[表6]
(實施例5) 製作實施例5的液晶組成物,測定其物性值。以下示出液晶組成物的結構及物性值的結果。(Example 5) The liquid crystal composition of Example 5 was produced, and its physical properties were measured. The results of the structure and physical properties of the liquid crystal composition are shown below.
[表7]
(實施例6) 製作實施例6的液晶組成物,測定其物性值。以下示出液晶組成物的結構及物性值的結果。(Example 6) The liquid crystal composition of Example 6 was produced, and its physical properties were measured. The results of the structure and physical properties of the liquid crystal composition are shown below.
[表8]
(比較例1) 製作比較例1的液晶組成物,測定其物性值。以下示出液晶組成物的結構及物性值的結果。(Comparative example 1) The liquid crystal composition of Comparative Example 1 was produced, and its physical properties were measured. The results of the structure and physical properties of the liquid crystal composition are shown below.
[表9]
(比較例2) 製作比較例2的液晶組成物,測定其物性值。以下示出液晶組成物的結構及物性值的結果。(Comparative example 2) The liquid crystal composition of Comparative Example 2 was produced, and its physical properties were measured. The results of the structure and physical properties of the liquid crystal composition are shown below.
[表10]
(比較例3) 製作比較例3的液晶組成物,測定其物性值。以下示出液晶組成物的結構及物性值的結果。(Comparative example 3) The liquid crystal composition of Comparative Example 3 was produced, and its physical properties were measured. The results of the structure and physical properties of the liquid crystal composition are shown below.
[表11]
根據實施例1~實施例6得知,組合使用規定的化合物的液晶組成物的TNI 為130℃以上,Δn為0.2以上,Vth為2.2以下,因此兼具高液晶相上限溫度(TNI )、高折射率各向異性(Δn)及低臨限電壓(Vth),藉此使GHz帶的介電常數大幅變化,顯示出低驅動電壓,是適合天線等元件的液晶組成物。According to Examples 1 to 6, the liquid crystal composition using a combination of predetermined compounds has a T NI of 130° C. or more, Δn of 0.2 or more, and Vth of 2.2 or less. Therefore, both have a high liquid crystal phase upper limit temperature (T NI ). , High refractive index anisotropy (Δn) and low threshold voltage (Vth), thereby greatly changing the dielectric constant in the GHz band, showing a low driving voltage, and is a liquid crystal composition suitable for antennas and other elements.
另一方面,未組合使用規定的化合物的液晶組成物的TNI 未滿130℃,或者Vth超過2.2 V,不具有所期望的性能。 [產業上之可利用性]On the other hand, a liquid crystal composition in which no predetermined compound is used in combination has a T NI of less than 130° C. or a Vth of more than 2.2 V, which does not have the desired performance. [Industrial availability]
本發明的液晶組成物可用於液晶顯示元件、感測器、液晶透鏡、光通訊設備及天線。The liquid crystal composition of the present invention can be used for liquid crystal display elements, sensors, liquid crystal lenses, optical communication equipment and antennas.
1:天線單元
2:車輛
3:殼體
4:控制板
5:上蓋
6:槽陣列部
7:貼片陣列部
8:槽
9:貼片
10:天線本體
11:天線組裝體
12:供電部
12a:供電線
13:第一基板
14:第二基板
15:第三基板
16:液晶層
17:第一電介質層
20:密閉區域
21、23、24:密封壁
22:緩衝層
A-A、B-B、C-C:剖線
L:長度
P:導體
Q:圓板體
W:寬度1: Antenna unit
2: Vehicle
3: shell
4: control panel
5: Upper cover
6: Slot array section
7: Patch array department
8: Slot
9: Patch
10: Antenna body
11: Antenna assembly
12:
圖1是搭載有本發明的天線的車輛的概要圖的一例。 圖2是本發明的天線的分解圖的一例。 圖3是本發明的天線本體的分解圖的一例。 圖4是本發明的槽陣列(slot array)部的俯視圖的一例。 圖5是本發明的天線本體的投影圖的俯視圖的一例。 圖6是沿A-A線切斷圖5的天線本體的剖面圖的一形態。 圖7是沿A-A線切斷圖5的天線本體的剖面圖的另一形態。 圖8是示出本發明的天線本體的投影圖的俯視圖的另一例。 圖9是沿C-C線切斷圖8的天線本體的剖面圖。 圖10是沿B-B線切斷圖8的天線本體的剖面圖。FIG. 1 is an example of a schematic diagram of a vehicle equipped with the antenna of the present invention. Fig. 2 is an example of an exploded view of the antenna of the present invention. Fig. 3 is an example of an exploded view of the antenna body of the present invention. Fig. 4 is an example of a plan view of a slot array portion of the present invention. Fig. 5 is an example of a plan view of a projection view of the antenna body of the present invention. Fig. 6 is a form of a cross-sectional view of the antenna body of Fig. 5 cut along the line A-A. Fig. 7 is another form of a cross-sectional view of the antenna body of Fig. 5 cut along the line A-A. Fig. 8 is another example of a plan view showing a projection view of the antenna body of the present invention. Fig. 9 is a cross-sectional view of the antenna body of Fig. 8 cut along the line C-C. Fig. 10 is a cross-sectional view of the antenna body of Fig. 8 cut along the line B-B.
6:槽陣列部6: Slot array section
7:貼片陣列部7: Patch array department
8:槽8: Slot
9:貼片9: Patch
10:天線本體10: Antenna body
12:供電部12: Power Supply Department
L:長度L: length
P:導體P: Conductor
Q:圓板體Q: Disc body
W:寬度W: width
Claims (13)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2020-019700 | 2020-02-07 | ||
JP2020019700 | 2020-02-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
TW202130786A true TW202130786A (en) | 2021-08-16 |
Family
ID=77199890
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW109143537A TW202130786A (en) | 2020-02-07 | 2020-12-10 | Liquid crystal composition, and liquid crystal element, sensor, liquid crystal lens, optical communication device and antenna each using same |
Country Status (3)
Country | Link |
---|---|
JP (1) | JP6954493B1 (en) |
TW (1) | TW202130786A (en) |
WO (1) | WO2021157189A1 (en) |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5740840B2 (en) * | 2010-05-13 | 2015-07-01 | Dic株式会社 | Azobenzene derivative and liquid crystal composition containing the same |
JP5885017B2 (en) * | 2011-10-31 | 2016-03-15 | Dic株式会社 | Azobenzene derivative and liquid crystal composition containing the same |
JP5853617B2 (en) * | 2011-11-11 | 2016-02-09 | Dic株式会社 | Azobenzene derivative and liquid crystal composition containing the same |
US10913895B2 (en) * | 2015-07-02 | 2021-02-09 | Dic Corporation | Liquid crystal composition and liquid crystal display device |
CN109477992B (en) * | 2016-07-15 | 2021-11-23 | 夏普株式会社 | Scanning antenna |
CN109477986B (en) * | 2016-07-19 | 2021-11-02 | 夏普株式会社 | Liquid crystal panel and scanning antenna |
TWI800646B (en) * | 2018-05-16 | 2023-05-01 | 德商馬克專利公司 | Liquid-crystalline medium |
-
2020
- 2020-12-10 WO PCT/JP2020/045959 patent/WO2021157189A1/en active Application Filing
- 2020-12-10 JP JP2021512585A patent/JP6954493B1/en active Active
- 2020-12-10 TW TW109143537A patent/TW202130786A/en unknown
Also Published As
Publication number | Publication date |
---|---|
WO2021157189A1 (en) | 2021-08-12 |
JPWO2021157189A1 (en) | 2021-08-12 |
JP6954493B1 (en) | 2021-10-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP7088422B1 (en) | Liquid crystal composition and liquid crystal display elements, sensors, liquid crystal lenses, optical communication devices and antennas using the same. | |
TW202219251A (en) | Liquid crystal composition and liquid crystal display element, sensor, liquid crystal lens, optical communication machine and antenna using the same having a liquid crystal phase having a wide temperature range, high refractive index anisotropy, and good room temperature stability | |
JP6973684B1 (en) | Liquid crystal compositions, liquid crystal elements, sensors, liquid crystal lenses, optical communication devices and antennas, and compounds. | |
JP2019520738A (en) | Antenna with high RF tuning, wide temperature operating range, and low viscosity radio frequency liquid crystal (RFLC) mixture | |
Fritzsch et al. | 77‐1: Invited Paper: Liquid Crystals beyond Displays: Smart Antennas and Digital Optics | |
JP7484991B2 (en) | Compound and liquid crystal composition | |
JP6904498B1 (en) | Liquid crystal composition, liquid crystal element, sensor, liquid crystal lens, optical communication equipment and antenna | |
TW202116981A (en) | Liquid crystal composition, liquid crystal element, sensor, liquid crystal lens, optical communication device, and antenna | |
US11345854B2 (en) | Liquid crystal dielectric applicable to high-frequency electromagnetic wave modulation, and component thereof | |
TW202130786A (en) | Liquid crystal composition, and liquid crystal element, sensor, liquid crystal lens, optical communication device and antenna each using same | |
JP6886590B1 (en) | Liquid crystal composition, liquid crystal element, sensor, liquid crystal lens, optical communication equipment and antenna | |
US20240228878A1 (en) | Compound, liquid crystal composition, as well as liquid crystal display element, sensor, liquid crystal lens, optical communication equipment, and antenna each using the same | |
JP7460040B1 (en) | Compound, liquid crystal composition, and liquid crystal display element, sensor, liquid crystal lens, optical communication device, and antenna using the same | |
JP7428302B1 (en) | Compounds, liquid crystal compositions, liquid crystal display elements, sensors, liquid crystal lenses, optical communication equipment, and antennas using the same | |
WO2024090213A1 (en) | Compound, liquid crystal composition, and liquid crystal display element, sensor, liquid crystal lens, optical communication equipment and antenna each using same | |
Jost et al. | 64‐3: Invited Paper: Latest Developments Liquid Crystals for RF Applications | |
JP7281134B2 (en) | OPTICAL ELEMENT MANUFACTURING METHOD AND OPTICAL ELEMENT | |
WO2024134973A1 (en) | Compound, and liquid crystal composition, liquid crystal display element, sensor, liquid crystal lens, optical communication device and antenna each using same |