TW202127915A - Loudspeaker vibrating diaphragm with low halogen content and manufacturing method thereof capable of reducing halogen content to meet regulations but maintaining certain heat resistance and robustness - Google Patents
Loudspeaker vibrating diaphragm with low halogen content and manufacturing method thereof capable of reducing halogen content to meet regulations but maintaining certain heat resistance and robustness Download PDFInfo
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本發明是涉及一種喇叭振動片及其製造方法,特別是一種低鹵素含量的喇叭振動片及其製造方法。The invention relates to a horn vibrating plate and a manufacturing method thereof, in particular to a horn vibrating plate with low halogen content and a manufacturing method thereof.
請參考圖1及圖2所示,圖1是喇叭構造的示意圖,圖2是振膜1A、彈波1B和懸邊1C等三種喇叭振動片的立體圖。一般典型的動圈式喇叭1包括有振膜1A、懸掛系統及動力系統。振膜1A的作用是移動空氣,一般為錐形或半球形的音盆。懸掛系統則是由彈波1B與懸邊1C等結構組成,用來負責牽引振膜1A的定向移動。動力系統包括有音圈1D及永久磁鐵1E,並且能夠讓振膜1A產生振動,從而使空氣振動而發出音頻傳送到人耳,達到聲音還原供人聆聽的目的,實現了電能到聲能的轉換。Please refer to FIG. 1 and FIG. 2. FIG. 1 is a schematic diagram of the horn structure, and FIG. 2 is a three-dimensional view of three types of horn vibrating plates, including the
一般喇叭1內部所包含的非金屬零件有多種是採用布材製成者,其主要原因在於經過特殊處理的布材具備適當的彈性與強度,能提供喇叭作動時所要功能的要求,例如:振膜1A、彈波1B、懸邊1C或者小型喇叭中的鼓紙(圖未示)等均屬之,此類非金屬零件統稱為喇叭振動片。Generally, the non-metal parts contained in the
習用的喇叭振動片製造方法包含下列步驟:準備步驟:準備複數條紗線;編織步驟:一布材由該等紗線編織而成;含浸步驟:布材含浸一樹脂溶液;乾燥步驟:將布材乾燥,以形成一層樹脂固形層;成形步驟:在布材上熱壓成形出一喇叭振動片的預定形狀;以及裁切步驟:裁切布材上的喇叭振動片的預定形狀,所切下的喇叭振動片的預定形狀即為一喇叭振動片(例如圖2所示的振膜1A、彈波1B、懸邊1C或小型喇叭中的鼓紙)。喇叭振動片的成本佔據整組喇叭的成本比例極小,但是對於喇叭的音質扮演著關鍵性的角色。The conventional horn vibrating plate manufacturing method includes the following steps: preparation step: preparing a plurality of yarns; knitting step: a cloth material is woven from the yarns; impregnation step: cloth material is impregnated with a resin solution; drying step: cloth The material is dried to form a solid resin layer; the forming step: hot-press forming a predetermined shape of the horn vibrating plate on the cloth; and the cutting step: cutting the predetermined shape of the horn vibrating plate on the cloth, and cut The predetermined shape of the horn vibrating plate is a horn vibrating plate (for example, the
環保意識逐漸抬頭,各大廠開始注意無鹵環保,因在製程中材料有含鹵素(氟、氯、溴、碘)在加工時可能降解產生鹵化氫,腐蝕設備、難以回收利用、燃燒時可能釋放出致癌物質。因此現在很多廠商都要求使用無鹵素材料。Environmental awareness is gradually rising, and major factories have begun to pay attention to halogen-free environmental protection. Because the materials in the manufacturing process contain halogens (fluorine, chlorine, bromine, iodine), they may degrade to produce hydrogen halides during processing, which will corrode equipment, be difficult to recycle, and may be burned. Releases carcinogens. Therefore, many manufacturers now require the use of halogen-free materials.
目前最新的環保趨勢已開始朝向無鹵素產品,國際間各大廠包括紛紛聲明將自 2008 年開始導入無鹵素材料。2008年即將開始實施的挪威PoHS法令中,已明確規範十八種必須排除的有害物質,因此繼歐盟的 RoHS指令要求之後,國際間將陸續掀起訂定無鹵素產品限制使用的相關法律。無鹵素材料的導入已經成為各家大廠下一階段的綠化目標,並開始制定無鹵素產品的量產時程表。At present, the latest environmental protection trend has begun to move towards halogen-free products, and major international manufacturers including one after another have declared that they will start introducing halogen-free materials in 2008. The Norwegian PoHS Act, which is about to be implemented in 2008, has clearly regulated 18 hazardous substances that must be excluded. Therefore, following the EU's RoHS directive, international laws will be set up to restrict the use of halogen-free products. The introduction of halogen-free materials has become the next stage of greening goals for major factories, and the mass production schedule of halogen-free products has begun to be formulated.
芳香族聚醯胺纖維(簡稱芳綸)是一種耐熱且強力的合成纖維,相當適合作為喇叭振動片的材料。芳香族聚醯胺纖維的製備方法如下:Aromatic polyamide fiber (abbreviated as aramid fiber) is a heat-resistant and strong synthetic fiber, which is quite suitable as a material for horn vibrating plate. The preparation method of aromatic polyamide fiber is as follows:
一、以對氨基甲醯氯鹽酸鹽或間氨基苯甲醯氯鹽酸鹽或對亞硫醯胺基苯甲醯氯為原料,在含氯化鋰的有機極性溶劑(如二甲基乙醯胺)中,經底本溶液縮聚而得。1. Using p-aminoformyl chloride hydrochloride or meta-aminobenzyl chloride hydrochloride or p-thionylaminobenzyl chloride as raw materials, in an organic polar solvent containing lithium chloride (such as dimethyl ethyl Amide), which is obtained by condensation polymerization of the base solution.
二、以吡啶的N-磷酸鹽為催化劑,在含氯化鋰的有機極性溶劑中,由對氨基甲苯酸直接縮聚而得。2. Using the N-phosphate of pyridine as a catalyst, it is obtained by direct condensation polymerization of p-aminotoluic acid in an organic polar solvent containing lithium chloride.
所得的聚合物液可直接紡絲,或將高聚物沉澱,分離,製成粉末狀高聚物後,在溶於含氯化鋰的醯胺系溶劑(如二甲基乙醯胺)中配成各向異性紡絲液,再經乾法、濕法或乾濕法紡絲。初生纖維經水洗、乾燥後,在500~600℃熱管中加張力熱處理,即得到對氨基苯甲酸縮聚成的纖維,相對密度1.45,強度1.50~1.94N/tex,伸長率約2%,模量88.30~91.83N/tex,熔融溫度約為500℃,耐熱性好,在300℃中暴露75小時後,強度保持率為67%,模量保持率為92%,可作複合材料的增強體。The resulting polymer liquid can be spun directly, or the polymer can be precipitated and separated into a powdered polymer, and then dissolved in a lithium chloride-containing amide solvent (such as dimethylacetamide) It is formulated into anisotropic spinning solution, and then spins by dry, wet or dry-wet method. After the nascent fiber is washed and dried, it is heat-treated with tension in a heat pipe at 500~600℃ to obtain a fiber made by polycondensation of para-aminobenzoic acid. The relative density is 1.45, the strength is 1.50~1.94N/tex, the elongation is about 2%, and the modulus is about 2%. 88.30~91.83N/tex, melting temperature is about 500℃, good heat resistance, after exposure to 300℃ for 75 hours, the strength retention rate is 67%, and the modulus retention rate is 92%. It can be used as a reinforcement for composite materials.
以間氨基苯甲醯氯鹽酸鹽為單體,二甲基乙醯胺為溶劑,經低溫溶液縮聚,乾法或濕法紡絲製得的纖維,強度0.51N/tex,伸長率10%,模量10.41N/tex,耐熱性熱穩定性良好,300℃的強度0.26N/tex,伸長率7.5%,模量7.85伸長率,在300℃下放置數周或在400℃下加熱1小時後仍穩定,在500℃下加熱1分鐘後,強度不變,零強度溫度480℃,此外,還具有良好的耐腐蝕和耐輻射性能。The fiber is made by using m-aminobenzyl chloride hydrochloride as the monomer and dimethylacetamide as the solvent through low-temperature solution polycondensation, dry or wet spinning. The strength is 0.51N/tex, and the elongation is 10%. , Modulus 10.41N/tex, good heat resistance and thermal stability, strength at 300℃ 0.26N/tex, elongation 7.5%, modulus 7.85 elongation, placed at 300℃ for several weeks or heated at 400℃ for 1 hour It is still stable after heating. After heating at 500°C for 1 minute, the strength does not change, and the zero-strength temperature is 480°C. In addition, it also has good corrosion resistance and radiation resistance.
由上可知,芳香族聚醯胺纖維的製造過程中,材料含有鹵素,使得製成的芳香族聚醯胺纖維含有鹵素。因此,以芳香族聚醯胺纖維作為材料的喇叭振動片也會含有鹵素。It can be seen from the above that during the manufacturing process of the aromatic polyamide fiber, the material contains halogen, so that the prepared aromatic polyamide fiber contains halogen. Therefore, horn diaphragms made of aromatic polyamide fibers also contain halogens.
由於芳香族聚醯胺纖維的耐熱性和強韌度是其他纖維無可匹敵的,為喇叭振動片的材料首選,但芳香族聚醯胺纖維所含有的鹵素是無法去除的,又令廠商望而卻步。Because the heat resistance and toughness of aromatic polyamide fiber are unmatched by other fibers, it is the first choice for the material of horn diaphragm, but the halogen contained in aromatic polyamide fiber cannot be removed, which discourages manufacturers. .
另外,由於多條不同種類的纖維以混捻的方式形成的複絲線體(亦可稱為撚紗、合紗、複絲、複線體或者多股腺體),需要特別訂製,所以價格較為昂貴,使得由複絲線體編織而成的喇叭振動片的價格特別昂貴。In addition, the multifilament yarn (also called twisted yarn, combined yarn, multifilament, multifilament or multi-stranded gland) formed by mixing and twisting multiple different types of fibers requires special customization, so the price is relatively high. Expensive, making the price of the horn vibrating piece woven from the multifilament wire body is particularly expensive.
又,如果喇叭振動片由複數條複絲線體編織而成,一旦想要更換喇叭振動片的組成物,就必須另外訂製由多條不同種類的纖維以混捻的方式形成的複絲線體,增加製造成本。In addition, if the horn vibrating plate is woven from a plurality of multifilament yarns, once the composition of the horn vibrating plate is to be changed, it is necessary to order a multifilament yarn formed by mixing and twisting multiple different types of fibers. Increase manufacturing costs.
本發明的主要目的在於提供一種低鹵素含量的喇叭振動片及其製造方法,鹵素含量降低至符合各國規範,還可保有一定的耐熱性和強韌度。The main purpose of the present invention is to provide a horn vibrating plate with low halogen content and a manufacturing method thereof, the halogen content is reduced to conform to the standards of various countries, and a certain degree of heat resistance and toughness can be maintained.
本發明的另一目的在於提供一種低鹵素含量的喇叭振動片及其製造方法,全部紗線都是單絲線體,具有價格低廉的優勢。Another object of the present invention is to provide a horn vibrating plate with low halogen content and a manufacturing method thereof. All the yarns are monofilament yarns, which has the advantage of low price.
本發明的又一目的在於提供一種低鹵素含量的喇叭振動片及其製造方法,依照需求選擇纖維的種類,達到調整組成物的效果,降低製造成本。Another object of the present invention is to provide a low-halogen horn vibrating plate and a manufacturing method thereof. The type of fiber is selected according to requirements, so as to achieve the effect of adjusting the composition and reduce the manufacturing cost.
為了達成前述的目的,本發明提供一種低鹵素含量的喇叭振動片製造方法,包括下列步驟:In order to achieve the foregoing objective, the present invention provides a method for manufacturing a horn vibrating plate with low halogen content, which includes the following steps:
準備步驟:準備複數條第一紗線與複數條第二紗線,各第一紗線為單條芳香族聚醯胺纖維組成的單絲線體,各第二紗線為單條其他纖維組成的單絲線體。Preparation steps: prepare a plurality of first yarns and a plurality of second yarns, each first yarn is a monofilament yarn composed of a single aromatic polyamide fiber, and each second yarn is a monofilament yarn composed of a single other fiber body.
編織步驟:一布材由該等第一紗線與該等第二紗線編織而成,該等第一紗線的總條數佔據布材的全部紗線的條數的25%以下,該等第二紗線的總條數佔據布材的全部紗線的條數的75%以上。Knitting step: a cloth material is woven by the first yarns and the second yarns, and the total number of the first yarns occupies less than 25% of the total number of yarns in the cloth material. The total number of second yarns occupies more than 75% of the total number of yarns in the cloth material.
含浸步驟:布材含浸於一樹脂溶液中。Impregnation step: the cloth material is impregnated in a resin solution.
乾燥步驟:將布材乾燥,以形成一層樹脂固形層在布材上。Drying step: drying the cloth material to form a solid resin layer on the cloth material.
成形步驟:在布材上熱壓成形出一喇叭振動片的預定形狀。Forming step: hot-press forming a predetermined shape of a horn vibrating plate on the cloth material.
裁切步驟:裁切布材上的喇叭振動片的預定形狀,所切下的喇叭振動片的預定形狀即為一低鹵素含量的喇叭振動片。Cutting step: cutting the predetermined shape of the horn vibrating plate on the cloth material, and the cut out the predetermined shape of the horn vibrating plate is a horn vibrating plate with low halogen content.
較佳地,其他纖維係選自竹子纖維、棉纖維、絲纖維、麻纖維、毛纖維、聚酯纖維、壓克力纖維、聚乙烯環烷纖維、嫘縈纖維、橡膠纖維、尼龍纖維、彈性纖維、醋酸纖維的其中之一或其組合。Preferably, other fibers are selected from bamboo fibers, cotton fibers, silk fibers, hemp fibers, wool fibers, polyester fibers, acrylic fibers, polyethylene naphthene fibers, rayon fibers, rubber fibers, nylon fibers, and elastic fibers. One of fiber, acetate fiber, or a combination thereof.
較佳地,該等第一紗線全部為經紗或緯紗,部分第二紗線為經紗,部分第二紗線為緯紗。Preferably, all the first yarns are warp yarns or weft yarns, some of the second yarns are warp yarns, and some of the second yarns are weft yarns.
較佳地,部分第一紗線為經紗,部分第一紗線為緯紗,部分第二紗線為經紗,部分第二紗線為緯紗。Preferably, part of the first yarn is warp yarn, part of the first yarn is weft yarn, part of the second yarn is warp yarn, and part of the second yarn is weft yarn.
較佳地,作為該等第二紗線的其他纖維的種類全部相同或全部相異或部分相同部分相異。Preferably, the types of the other fibers as the second yarns are all the same or all are different, or some are the same and some are different.
為了達成前述的目的,本發明提供一種低鹵素含量的喇叭振動片,其係藉由所述的低鹵素含量的喇叭振動片製造方法所製成者,包括一本體以及一樹脂固形層。In order to achieve the foregoing objective, the present invention provides a low halogen content horn vibrating plate, which is manufactured by the low halogen content horn vibrating plate manufacturing method, and includes a body and a resin solid layer.
本體由複數條第一紗線與複數條第二紗線編織而成,各第一紗線為單條芳香族聚醯胺纖維組成的單絲線體,各第二紗線為單條其他纖維組成的單絲線體,該等第一紗線的總條數佔據本體的全部紗線的條數的25%以下,該等第二紗線的總條數佔據本體的全部紗線的條數的75%以上。The main body is woven from a plurality of first yarns and a plurality of second yarns. Each first yarn is a monofilament yarn composed of a single aromatic polyamide fiber, and each second yarn is a single monofilament composed of a single other fiber. Silk body, the total number of the first yarns occupies less than 25% of the total number of yarns in the main body, and the total number of the second yarns occupies more than 75% of the total number of yarns in the main body .
樹脂固形層設置於本體。The resin solid layer is arranged on the body.
較佳地,其他纖維係選自竹子纖維、棉纖維、絲纖維、麻纖維、毛纖維、聚酯纖維、壓克力纖維、聚乙烯環烷纖維、嫘縈纖維、橡膠纖維、尼龍纖維、彈性纖維、醋酸纖維的其中之一或其組合。Preferably, other fibers are selected from bamboo fibers, cotton fibers, silk fibers, hemp fibers, wool fibers, polyester fibers, acrylic fibers, polyethylene naphthene fibers, rayon fibers, rubber fibers, nylon fibers, and elastic fibers. One of fiber, acetate fiber, or a combination thereof.
較佳地,該等第一紗線全部為經紗或緯紗,部分第二紗線為經紗,部分第二紗線為緯紗。Preferably, all the first yarns are warp yarns or weft yarns, some of the second yarns are warp yarns, and some of the second yarns are weft yarns.
較佳地,部分第一紗線為經紗,部分第一紗線為緯紗,部分第二紗線為經紗,部分第二紗線為緯紗。Preferably, part of the first yarn is warp yarn, part of the first yarn is weft yarn, part of the second yarn is warp yarn, and part of the second yarn is weft yarn.
較佳地,作為該等第二紗線的其他纖維的種類全部相同或全部相異或部分相同部分相異。Preferably, the types of the other fibers as the second yarns are all the same or all are different, or some are the same and some are different.
本發明的功效在於,本發明藉由將布材中的芳香族聚醯胺纖維的總條數限制在布材的全部纖維的條數的25%以下,其他纖維的總條數限制在布材的全部纖維的條數的75%以上,使得本發明的低鹵素含量的喇叭振動片的本體中的芳香族聚醯胺纖維的總條數限制在本體的全部纖維的條數的25%以下,其他纖維的總條數限制在本體的全部纖維的條數的75%以上,從而本發明的低鹵素含量的喇叭振動片的鹵素含量降低至符合各國規範,還可保有一定的耐熱性和強韌度。The effect of the present invention is that by limiting the total number of aromatic polyamide fibers in the cloth to less than 25% of the total number of fibers in the cloth, the total number of other fibers is limited to the cloth. 75% or more of the total number of fibers of the present invention, so that the total number of aromatic polyamide fibers in the main body of the low halogen content horn vibrating plate of the present invention is limited to 25% or less of the total number of fibers in the main body, The total number of other fibers is limited to more than 75% of the total number of fibers in the body, so that the halogen content of the low halogen content horn vibrating plate of the present invention is reduced to comply with national standards, and it can also maintain a certain degree of heat resistance and toughness. Spend.
再者,本發明的低鹵素含量的喇叭振動片的本體的該等第一紗線和該等第二紗線全部是單絲線體,單絲線體則在市場上普遍流通,價格較為低廉,故本發明的低鹵素含量的喇叭振動片具有價格低廉的優勢。Furthermore, the first yarns and the second yarns of the main body of the low halogen content horn vibrating plate of the present invention are all monofilament yarns, and the monofilament yarns are generally circulated in the market and the price is relatively low. The horn vibrating piece with low halogen content of the present invention has the advantage of low price.
此外,本發明可依照需求選擇作為第二紗線的其他纖維的種類,達到調整本發明的低鹵素含量的喇叭振動片的組成物的效果,降低製造成本。In addition, in the present invention, the types of other fibers as the second yarn can be selected according to requirements, so as to achieve the effect of adjusting the composition of the low halogen content horn vibrating plate of the present invention and reduce the manufacturing cost.
以下配合圖式及元件符號對本發明的實施方式做更詳細的說明,俾使熟習該項技藝者在研讀本說明書後能據以實施。The following describes the embodiments of the present invention in more detail with the drawings and component symbols, so that those who are familiar with the art can implement it after studying this specification.
請參閱圖3至圖4C,分別是本發明的製造方法的流程圖、第一實施例的製造方法的示意圖、第一實施例的布材20的示意圖和第一實施例的低鹵素含量的喇叭振動片的示意圖。本發明提供一種低鹵素含量的喇叭振動片製造方法,包括下列步驟:Please refer to FIGS. 3 to 4C, which are a flowchart of the manufacturing method of the present invention, a schematic diagram of the manufacturing method of the first embodiment, a schematic diagram of the
準備步驟S1:準備複數條第一紗線11與複數條第二紗線12,各第一紗線11為單條芳香族聚醯胺纖維組成的單絲線體,各第二紗線12為單條其他纖維組成的單絲線體。所述單絲線體又可稱為單紗、單絲、單線體或者單股線體。其他纖維顧名思義為芳香族聚醯胺纖維以外的纖維。較佳地,其他纖維係選自竹子纖維、棉纖維、絲纖維、麻纖維、毛纖維、聚酯纖維、壓克力纖維、聚乙烯環烷纖維、嫘縈纖維、橡膠纖維、尼龍纖維、彈性纖維、醋酸纖維的其中之一或其組合。然不以此為限,芳香族聚醯胺纖維以外的任何適合作為喇叭振動片的纖維均可為所述其他纖維。Preparation step S1: prepare a plurality of
編織步驟S2:一布材20由該等第一紗線11與該等第二紗線12編織而成,該等第一紗線11的總條數佔據布材20的全部紗線的條數的25%以下,該等第二紗線12的總條數佔據布材20的全部紗線的條數的75%以上。換言之,芳香族聚醯胺纖維的總條數佔據布材20的全部纖維的條數的25%以下,其他纖維的總條數佔據布材20的全部纖維的條數的75%以上。Knitting step S2: a
含浸步驟S3:布材20含浸於一樹脂溶液31中。更明確地說,一樹脂槽30內裝有樹脂溶液31,布材20係含浸於此樹脂槽30內之樹脂溶液31中,使該等第一紗線11和該等第二紗線12吸附及黏著樹脂。樹脂內含有酒精、水份等之固形物,含量佔液態樹脂量50%以上。樹脂的成分係選自酚醛樹脂、環氧樹脂、聚酯樹脂、橡膠、矽膠的其中之一或其組合,或是其他具有相同性質的樹脂材料。Impregnation step S3: the
乾燥步驟S4:將布材20乾燥,以形成一層樹脂固形層21在布材20上。更明確地說,布材20移動至一烘乾裝置40中,使布材20上的樹脂中的水分被烘乾而形成樹脂固形層21,進而讓布材20具備適當硬度、彈性與韌性。Drying step S4: drying the
成形步驟S5:在布材20上熱壓成形出一喇叭振動片的預定形狀22。更詳而言之,布材20移動至一熱壓成形裝置50中,熱壓成形裝置50包含一加熱結構(圖未示)及一成形模具52,成形模具52包含一上模521及一下模522,加熱結構對成形模具52的上模521和下模522加熱,使成形模具52的上模521和下模522對布材20加壓加熱,以在布材20上熱壓成形出喇叭振動片的預定形狀22。Forming step S5: forming a
裁切步驟S6:裁切布材20上的喇叭振動片的預定形狀22,所切下的喇叭振動片的預定形狀22即為一低鹵素含量的喇叭振動片70。更清楚地說,布材20移動至一裁切裝置60,裁切裝置60包含一上切具61及一下切具62,上切具61和下切具62將喇叭振動片的預定形狀22從布材20上切下,使得喇叭振動片的預定形狀22與布材20分離。Cutting step S6: cutting the
如圖4C所示,本發明提供一種低鹵素含量的喇叭振動片70,係由所述的低鹵素含量的喇叭振動片製造方法所製成者,包括一本體71以及一樹脂固形層72。As shown in FIG. 4C, the present invention provides a low halogen content
本體71由複數條第一紗線11與複數條第二紗線12編織而成,各第一紗線11為單條芳香族聚醯胺纖維組成的單絲線體,各第二紗線12為單條其他纖維組成的單絲線體,該等第一紗線11的總條數佔據本體71的全部紗線的條數的25%以下,該等第二紗線12的總條數佔據本體71的全部紗線的條數的75%以上。換言之,芳香族聚醯胺纖維的總條數佔據本體71的全部纖維的條數的25%以下,其他纖維的總條數佔據本體71的全部纖維的條數的75%以上。所述單絲線體又可稱為單紗、單絲、單線體或者單股線體。其他纖維顧名思義為芳香族聚醯胺纖維以外的纖維。較佳地,其他纖維係選自竹子纖維、棉纖維、絲纖維、麻纖維、毛纖維、聚酯纖維、壓克力纖維、聚乙烯環烷纖維、嫘縈纖維、橡膠纖維、尼龍纖維、彈性纖維、醋酸纖維的其中之一或其組合。然不以此為限,芳香族聚醯胺纖維以外的任何適合作為本發明的低鹵素含量的喇叭振動片70的纖維均可為所述其他纖維。The
樹脂固形層72設置在本體71。具體來說,樹脂固形層72的成分係選自酚醛樹脂、環氧樹脂、聚酯樹脂、橡膠、矽膠等其中之一或者其組合,或是其他具有相同性質的樹脂材料。The resin
如圖4A所示,在第一實施例的準備步驟S1中,50%的經紗選用第一紗線11,50%的經紗選用第二紗線12,全部的緯紗選用第二紗線12,作為該等第二紗線12的其他纖維的種類可以全部相同或全部相異或部分相同部分相異。如圖4B所示,編織而成的布材20中,50%的經紗是第一紗線11,50%的經紗是第二紗線12,全部的緯紗是第二紗線12。因此,該等第一紗線11的總條數佔據布材20的全部紗線的條數的25%,該等第二紗線12的總條數佔據布材20的全部紗線的條數的75%。換言之,芳香族聚醯胺纖維的總條數佔據布材20的全部纖維的條數的25%,其他纖維的總條數佔據布材20的全部纖維的條數的75%。As shown in Figure 4A, in the preparation step S1 of the first embodiment, 50% of the warp yarns use the
如圖4C所示,在第一實施例所製成的低鹵素含量的喇叭振動片70中,50%的經紗是第一紗線11,50%的經紗是第二紗線12,全部的緯紗是第二紗線12,作為該等第二紗線12的其他纖維的種類可以全部相同或全部相異或部分相同部分相異。因此,該等第一紗線11的總條數佔據本體71的全部紗線的條數的25%,該等第二紗線12的總條數佔據本體71的全部紗線的條數的75%。換言之,芳香族聚醯胺纖維的總條數佔據本體71的全部纖維的條數的25%,其他纖維的總條數佔據本體71的全部纖維的條數的75%。As shown in FIG. 4C, in the low halogen content
在其他實施例的準備步驟S1中,50%的緯紗選用第一紗線11,50%的緯紗選用第二紗線12,全部的經紗選用第二紗線12,作為該等第二紗線12的其他纖維的種類可以全部相同或全部相異或部分相同部分相異,亦可得到和第一實施例相同的結果。In the preparation step S1 of other embodiments, the
在其他實施例的準備步驟S1中,25%的經紗選用第一紗線11,75%的經紗選用第二紗線12,25%的緯紗選用第一紗線11,75%的緯紗選用第二紗線12,作為該等第二紗線12的其他纖維的種類可以全部相同或全部相異或部分相同部分相異,亦可得到和第一實施例相同的結果。In the preparation step S1 of other embodiments, 25% of the warp yarns are selected as the
請參閱圖5A,圖5A是本發明的第二實施例的製造方法的示意圖,並請配合圖3。在第二實施例的準備步驟S1中,33.33%的經紗選用第一紗線11,66.67%的經紗選用第二紗線12、12A,全部的緯紗選用第二紗線12、12A,作為該等第二紗線12、12A的其他纖維的種類總共有兩種。請參閱圖5B,圖5B是本發明的第二實施例的布材20A的示意圖。編織而成的布材20A中,33.33%的經紗是第一紗線11,66.67%的經紗是第二紗線12、12A,全部的緯紗是第二紗線12、12A,作為該等第二紗線12、12A的其他纖維的種類總共有兩種。因此,該等第一紗線11的總條數佔據布材20A的全部紗線的條數的16.67%,該等第二紗線12、12A的總條數佔據布材20A的全部紗線的條數的83.33%。換言之,芳香族聚醯胺纖維的總條數佔據布材20A的全部纖維的條數的16.67%,其他纖維的總條數佔據布材20A的全部纖維的條數的83.33%。Please refer to FIG. 5A. FIG. 5A is a schematic diagram of the manufacturing method of the second embodiment of the present invention, and please cooperate with FIG. 3. In the preparation step S1 of the second embodiment, 33.33% of the warp yarns are selected as the
請參閱圖5C,圖5C是本發明的第二實施例的低鹵素含量的喇叭振動片70A的示意圖。在第二實施例所製成的低鹵素含量的喇叭振動片70A中,33.33%的經紗是第一紗線11,66.67%的經紗是第二紗線12、12A,全部的緯紗是第二紗線12、12A,作為該等第二紗線12、12A的其他纖維的種類總共有兩種。因此,該等第一紗線11的總條數佔據本體71A的全部紗線的條數的16.67%,該等第二紗線12、12A的總條數佔據本體71A的全部紗線的條數的83.33%。換言之,芳香族聚醯胺纖維的總條數佔據本體71A的全部纖維的條數的16.67%,其他纖維的總條數佔據本體71A的全部纖維的條數的83.33%。Please refer to FIG. 5C. FIG. 5C is a schematic diagram of a
在其他實施例的準備步驟S1中,33.33%的緯紗選用第一紗線11,66.67%的緯紗選用第二紗線12、12A,全部的經紗選用第二紗線12、12A,作為該等第二紗線12、12A的其他纖維的種類可以全部相同或全部相異或部分相同部分相異,亦可得到和第二實施例相同的結果。In the preparation step S1 of other embodiments, 33.33% of the weft yarns use the
在其他實施例的準備步驟S1中,16.67%的經紗選用第一紗線11,83.33%的經紗選用第二紗線12、12A,16.67%的緯紗選用第一紗線11,83.33%的緯紗選用第二紗線12、12A,作為該等第二紗線12、12A的其他纖維的種類可以全部相同或全部相異或部分相同部分相異,亦可得到和第二實施例相同的結果。In the preparation step S1 of other embodiments, 16.67% of the warp yarns are selected as the
請參閱圖6A,圖6A是本發明的第三實施例的製造方法的示意圖,並且配合圖3。在第三實施例的準備步驟S1中,25%的經紗選用第一紗線11,75%的經紗選用第二紗線12、12A、12B,全部的緯紗選用第二紗線12、12A、12B,作為該等第二紗線12、12A、12B的其他纖維的種類總共有三種。請參閱圖6B,圖6B是本發明的第三實施例的布材20B示意圖。編織而成的布材20B中,25%的經紗是第一紗線11,75%的經紗是第二紗線12、12A、12B,全部的緯紗是第二紗線12、12A、12B,作為該等第二紗線12、12A、12B的其他纖維的種類總共有三種。因此,該等第一紗線11的總條數佔據布材20B的全部紗線的條數的12.5%,該等第二紗線12、12A、12B的總條數佔據布材20B的全部紗線的條數的87.5%。換言之,芳香族聚醯胺纖維的總條數佔據布材20B的全部纖維的條數的12.5%,其他纖維的總條數佔據布材20B的全部纖維的條數的87.5%。Please refer to FIG. 6A. FIG. 6A is a schematic diagram of the manufacturing method of the third embodiment of the present invention, and matches FIG. 3. In the preparation step S1 of the third embodiment, 25% of the warp yarns are selected from the
請參閱圖6C,圖6C是本發明的第三實施例的低鹵素含量的喇叭振動片70B的示意圖。在第三實施例所製成的低鹵素含量的喇叭振動片70B中,25%的經紗是第一紗線11,75%的經紗是第二紗線12、12A、12B,全部的緯紗是第二紗線12、12A、12B,作為該等第二紗線12、12A、12B的其他纖維的種類總共有三種。因此,該等第一紗線11的總條數佔據本體71B的全部紗線的條數的12.5%,該等第二紗線12、12A、12B的總條數佔據本體71B的全部紗線的條數的87.5%。換言之,芳香族聚醯胺纖維的總條數佔據本體71B的全部纖維的條數的12.5%,其他纖維的總條數佔據本體71B的全部纖維的條數的87.5%。Please refer to FIG. 6C. FIG. 6C is a schematic diagram of a
本發明的低鹵素含量的喇叭振動片70、70A、70B可為動圈式喇叭的振膜、彈波、懸邊或小型喇叭中的鼓紙等屬於喇叭振動片系統的構件。The
綜上所述,本發明藉由將布材20、20A、20B中的芳香族聚醯胺纖維的總條數限制在布材20、20A、20B的全部纖維的條數的25%以下,其他纖維的總條數限制在布材20、20A、20B的全部纖維的條數的75%以上,使得本發明的低鹵素含量的喇叭振動片70、70A、70B的本體71、71A、71B中的芳香族聚醯胺纖維的總條數限制在本體71、71A、71B的全部纖維的條數的25%以下,其他纖維的總條數限制在本體71、71A、71B的全部纖維的條數的75%以上,從而本發明的低鹵素含量的喇叭振動片70、70A、70B的鹵素含量降低至符合各國規範,還可保有一定的耐熱性和強韌度。In summary, the present invention limits the total number of aromatic polyamide fibers in
再者,本發明的低鹵素含量的喇叭振動片70、70A、70B的本體71、71A、71B的該等第一紗線11和該等第二紗線12、12A、12B全部是單絲線體,單絲線體則在市場上普遍流通,價格較為低廉,故本發明的低鹵素含量的喇叭振動片70、70A、70B具有價格低廉的優勢。Furthermore, the
此外,本發明可依照需求選擇作為第二紗線12、12A、12B的其他纖維的種類,達到調整本發明的低鹵素含量的喇叭振動片70、70A、70B的組成物的效果,降低製造成本。In addition, the present invention can select the types of other fibers as the
以上所述者僅為用以解釋本發明的較佳實施例,並非企圖據以對本發明做任何形式上的限制,是以,凡有在相同的發明精神下所作有關本發明的任何修飾或變更,皆仍應包括在本發明意圖保護的範疇。The above descriptions are only used to explain the preferred embodiments of the present invention, and are not intended to restrict the present invention in any form. Therefore, any modification or change related to the present invention is made under the same spirit of the invention. , Should still be included in the scope of the invention's intention to protect.
1:動圈式喇叭
1A:振膜
1B:彈波
1C:懸邊
1D:音圈
1E:永久磁鐵
S1:準備步驟
S2:編織步驟
S3:含浸步驟
S4:乾燥步驟
S5:熱壓成形步驟
S6:裁切步驟
11:第一紗線
12,12A,12B:第二紗線
20,20A,20B:布材
21:樹脂固形層
22:喇叭振動片的預定形狀
30:樹脂槽
31:樹脂溶液
40:烘乾裝置
50:熱壓成形裝置
52:成形模具
521:上模
522:下模
60:裁切裝置
61:上切具
62:下切具
70,70A,70B:喇叭振動片
71,71A,71B:本體
72:樹脂固形層1: Moving
圖1是喇叭構造的示意圖。 圖2是振膜、彈波和懸邊等三種喇叭振動片的立體圖。 圖3是本發明的製造方法的流程圖。 圖4A是本發明的第一實施例的製造方法的示意圖。 圖4B是本發明的第一實施例的布材的示意圖。 圖4C是本發明的第一實施例的低鹵素含量的喇叭振動片的示意圖。 圖5A是本發明的第二實施例的製造方法的示意圖。 圖5B是本發明的第二實施例的布材的示意圖。 圖5C是本發明的第二實施例的低鹵素含量的喇叭振動片的示意圖。 圖6A是本發明的第三實施例的製造方法的示意圖。 圖6B是本發明的第三實施例的布材示意圖。 圖6C是本發明的第三實施例的低鹵素含量的喇叭振動片的示意圖。Figure 1 is a schematic diagram of the horn structure. Figure 2 is a three-dimensional view of three types of horn vibrating plates, such as diaphragm, elastic wave and suspension. Fig. 3 is a flowchart of the manufacturing method of the present invention. Fig. 4A is a schematic diagram of the manufacturing method of the first embodiment of the present invention. Fig. 4B is a schematic diagram of the cloth material of the first embodiment of the present invention. Fig. 4C is a schematic diagram of the horn vibrating piece with low halogen content according to the first embodiment of the present invention. Fig. 5A is a schematic diagram of the manufacturing method of the second embodiment of the present invention. Fig. 5B is a schematic diagram of the cloth material of the second embodiment of the present invention. Fig. 5C is a schematic diagram of a horn vibrating piece with a low halogen content according to a second embodiment of the present invention. Fig. 6A is a schematic diagram of the manufacturing method of the third embodiment of the present invention. Fig. 6B is a schematic diagram of the cloth material of the third embodiment of the present invention. Fig. 6C is a schematic diagram of a horn vibrating piece with a low halogen content according to a third embodiment of the present invention.
S1:準備步驟S1: Preparation steps
S2:編織步驟S2: Weaving step
S3:含浸步驟S3: impregnation step
S4:乾燥步驟S4: drying step
S5:熱壓成形步驟S5: Hot press forming step
S6:裁切步驟S6: Cutting steps
11:第一紗線11: The first yarn
12:第二紗線12: Second yarn
20:布材20: Cloth
22:喇叭振動片的預定形狀22: The predetermined shape of the horn vibrating plate
30:樹脂槽30: Resin tank
31:樹脂溶液31: Resin solution
40:烘乾裝置40: Drying device
50:熱壓成形裝置50: Hot press forming device
52:成形模具52: Forming mold
521:上模521: upper die
522:下模522: lower die
60:裁切裝置60: Cutting device
61:上切具61: Upper cutter
62:下切具62: lower cutter
70:喇叭振動片70: Horn vibrating plate
Claims (10)
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TW109101266A TWI791136B (en) | 2020-01-14 | 2020-01-14 | Horn vibrating piece with low halogen content and manufacturing method thereof |
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TW202127915A true TW202127915A (en) | 2021-07-16 |
TWI791136B TWI791136B (en) | 2023-02-01 |
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TW200904227A (en) * | 2007-07-06 | 2009-01-16 | Hiroshi Ohara | Structure of loudspeaker vibrating piece |
TWI642312B (en) * | 2017-07-26 | 2018-11-21 | Horn vibrating piece for controlling the number of specific types of fibers and manufacturing method thereof |
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