TW202112434A - System and method for feeding immersed membrane units - Google Patents
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本發明係關於浸沒薄膜過濾器及操作其等之方法。The present invention relates to submerged membrane filters and methods of operating them.
薄膜通常呈平板、管或中空纖維之形式。在一浸沒薄膜單元中,多個薄膜元件被一起組裝成模組或匣且浸沒在一開放式槽中。滲透物藉由由重力產生之吸力或連接至薄膜之一內表面之一滲透泵自模組抽出。典型應用包含過濾地表水以產生飲用水,在一薄膜生物反應器(MBR)中處理廢水或在一三級過濾應用中處理二級流出物。在此等應用中,薄膜通常具有在微濾或超濾範圍中之孔。Films are usually in the form of flat plates, tubes or hollow fibers. In an immersion film unit, multiple film elements are assembled together into modules or cassettes and immersed in an open tank. The permeate is drawn from the module by suction generated by gravity or an osmotic pump connected to an inner surface of the membrane. Typical applications include filtering surface water to produce drinking water, treating wastewater in a membrane bioreactor (MBR) or treating secondary effluent in a tertiary filtration application. In these applications, membranes usually have pores in the microfiltration or ultrafiltration range.
在美國專利5,639,373中描述浸沒中空纖維薄膜單元之一些實例。在此等中空纖維薄膜單元中,中空纖維薄膜在上灌封頭與下灌封頭之間延伸。在其他實例中,僅存在一個灌封頭及/或薄膜水平延伸。在美國專利6,287,467中描述浸沒平板薄膜單元之一些實例。在平板薄膜單元中,在框架或間隔件上方將平板薄膜對組裝在一起以形成元件。許多此等元件被平行放置於一匣中。匣可具有一薄膜殼,替代地稱為一護罩,該薄膜殼在元件周圍形成一垂直定向管。一組曝氣器可附接至匣。在一些情況中,在匣下方之一擴散器殼在一垂直定向管中含有一組曝氣器。曝氣器產生沖刷薄膜之表面之氣泡且亦產生使水向上循環通過薄膜之一氣昇(air lift)。類似結構配備平板狀陶瓷薄膜。在美國公開案第US 2017/0095773號中描述具有在無內框或間隔件之情況下組裝之波紋狀薄膜板之一替代平板浸沒薄膜單元,該案以引用的方式併入本文中。Some examples of submerged hollow fiber membrane units are described in US Patent 5,639,373. In these hollow fiber membrane units, the hollow fiber membrane extends between the upper potting head and the lower potting head. In other examples, there is only one potting head and/or the film extends horizontally. Some examples of submerged flat sheet membrane units are described in US Patent 6,287,467. In the flat film unit, a flat film pair is assembled together over a frame or spacer to form an element. Many of these components are placed in parallel in a box. The cassette may have a membrane shell, alternatively referred to as a shield, which forms a vertically oriented tube around the element. A set of aerators can be attached to the cassette. In some cases, a diffuser shell below the cassette contains a set of aerators in a vertically oriented tube. The aerator generates bubbles that wash the surface of the film and also generates an air lift that circulates water upward through the film. A similar structure is equipped with a flat ceramic film. In U.S. Publication No. US 2017/0095773, it is described that one of the corrugated film panels assembled without inner frames or spacers replaces the flat immersed film unit, which is incorporated herein by reference.
在薄膜過濾系統中,一或多個浸沒薄膜單元通常被放置於一開放式(即,具有一無水表面)薄膜槽中。在一薄膜生物反應器(MBR)中,薄膜過濾系統可如同一活性污泥程序中之二次淨化器(clarifier)般起作用。在此情況中,在薄膜槽上游之處理槽中處理水以產生流動至薄膜槽之混合液體。透過薄膜單元抽出滲透物,從而將活性污泥留在薄膜槽中。活性污泥自薄膜槽抽出且被劃分成廢棄活性污泥(WAS)及回流活性污泥(RAS)。RAS回流至處理槽且變為活性污泥之部分。流入物(原始廢水)流速(Q)大致由滲透物流速及WAS流速之總和平衡。RAS流速通常在2Q至5Q之範圍中。In membrane filtration systems, one or more submerged membrane units are usually placed in an open (ie, with a water-free surface) membrane tank. In a membrane bioreactor (MBR), the membrane filtration system can function as a secondary clarifier in the same activated sludge process. In this case, the water is treated in a treatment tank upstream of the film tank to produce a mixed liquid that flows to the film tank. The permeate is drawn through the membrane unit, thereby leaving the activated sludge in the membrane tank. The activated sludge is drawn from the membrane tank and divided into waste activated sludge (WAS) and return activated sludge (RAS). RAS returns to the treatment tank and becomes part of the activated sludge. The flow rate (Q) of the influent (raw wastewater) is roughly balanced by the sum of the permeate flow rate and the WAS flow rate. The RAS flow rate is usually in the range of 2Q to 5Q.
此發明內容旨在向讀者介紹本發明及下文之詳細描述而非限制或定義本發明。This summary of the invention is intended to introduce the reader to the invention and the detailed description below, rather than to limit or define the invention.
在一浸沒薄膜系統中,一流入物流動至一開放式薄膜槽中,透過薄膜移除滲透物,且一濃縮物流出薄膜槽。發明者已觀察到,儘管使用氣泡均等地沖刷各薄膜單元,然積垢率可在一槽之不同部分中之薄膜單元之間不同。例如,在其中薄膜單元以一線沿著一窄槽分佈,且槽使用流入物自一端饋送之一系統中,最下游薄膜單元積垢最多。此可至少部分由沿著槽之長度發展之一固體(或其他污垢)濃度梯度引起。然而,薄膜單元通常全部連接至共同滲透物及反沖洗管且使用相同滲透及清潔協定操作。因此,任一上游薄膜單元非有效地操作或下游薄膜單元過量地積垢。然而,此構形在許多浸沒薄膜設備(包含薄膜生物反應器(MBR))中使用,此係尤其因為其促進產生具有多個平行薄膜槽之大系統。因此,已經存在具有窄槽之浸沒薄膜系統之一大安裝基底。In an immersed membrane system, an influent flows into an open membrane tank, the permeate is removed through the membrane, and a concentrate flows out of the membrane tank. The inventors have observed that although air bubbles are used to flush each membrane unit equally, the fouling rate can vary between membrane units in different parts of a tank. For example, in a system in which the membrane units are distributed along a narrow groove in a line, and the grooves are fed from one end with influent, the most downstream membrane unit fouls the most. This can be caused at least in part by a solid (or other dirt) concentration gradient that develops along the length of the tank. However, the membrane units are usually all connected to the common permeate and backwash pipes and operate using the same permeation and cleaning protocol. Therefore, any upstream membrane unit is operated inefficiently or the downstream membrane unit is excessively fouled. However, this configuration is used in many submerged membrane equipment (including membrane bioreactors (MBR)), especially because it facilitates the creation of large systems with multiple parallel membrane tanks. Therefore, there has been a large mounting base for immersed film systems with narrow grooves.
本說明書描述具有一或多個浸沒薄膜單元之一開放式薄膜槽。各薄膜單元可具有一或多個匣或含有過濾薄膜之其他結構。視情況,薄膜單元沿著槽之長度間隔。視情況,浸沒薄膜單元可具有可定位於一薄膜殼內之平板薄膜元件。在槽之一端上(視情況在槽之底部附近)提供一入口。提供用於將入口連接至一或多個浸沒薄膜單元之一或多個導管。在一些實例中,一導管具有各連接至一不同薄膜單元之多個開口。視情況,開口具有可經選擇以幫助等化混合液體至不同薄膜單元之流動之不同大小。視情況,導管可具有在一薄膜單元下方之一水平延伸擋板。在一些情況中,薄膜槽係一薄膜生物反應器之部分。This specification describes an open film tank with one or more submerged film units. Each membrane unit may have one or more cassettes or other structures containing filter membranes. Optionally, the film units are spaced along the length of the groove. Optionally, the immersion membrane unit may have flat membrane elements that can be positioned in a membrane shell. An entrance is provided at one end of the tank (near the bottom of the tank as the case may be). Provided for connecting the inlet to one or more ducts of one or more immersed membrane units. In some examples, a conduit has multiple openings each connected to a different membrane unit. Optionally, the openings have different sizes that can be selected to help equalize the flow of the mixed liquid to different membrane units. Optionally, the duct may have a horizontally extending baffle under a membrane unit. In some cases, the membrane tank is part of a membrane bioreactor.
本說明書亦描述操作一浸沒薄膜過濾系統(例如,一MBR之開放式薄膜槽)之一程序。在程序中,將至一薄膜槽中之一流入物流引導至一或多個浸沒薄膜單元之底部。視情況,可將混合液體流劃分為多個部分。在一些情況中,多個部分之各者之流速在多個部分之一平均流速之10%內。視情況,將流入物進一步向上引導通過一浸沒薄膜單元。在一些情況中,可提供通過薄膜單元之一直流或垂直塞流形態(regime)。流入物可係(例如)如在一MBR中之混合液體或如在三級過濾中之二級流出物。This manual also describes a procedure for operating an immersed membrane filtration system (for example, an open membrane tank of an MBR). In the procedure, an inflow into a film tank is directed to the bottom of one or more submerged film units. Optionally, the mixed liquid stream can be divided into multiple parts. In some cases, the flow rate of each of the multiple parts is within 10% of the average flow rate of one of the multiple parts. Optionally, the inflow is directed further upwards through a submerged membrane unit. In some cases, a direct current or vertical plug flow regime through one of the membrane units can be provided. The influent can be, for example, a mixed liquid as in an MBR or a secondary effluent as in a tertiary filtration.
本文中描述之薄膜槽及程序導致流入物通常被直接饋送至一或多個浸沒薄膜單元。此有助於防止流入物(例如,被饋送至一下游薄膜單元之流入物)由其他薄膜單元預濃縮。視情況,系統亦可經構形使得通過各種浸沒薄膜單元之流入物之流速大體上相等。將流入物按其原始濃度視情況以大體上相等流速提供至不同浸沒薄膜單元可導致系統作為一整體生產力更高及/或更容易操作。此外,向上迫使流入物通過薄膜單元。向上通過一薄膜單元之流入物流可有助於迫使鄰近薄膜彼此分開,抑制薄膜單元中之污泥之脫水或保留及/或將新鮮流入物分散遍及薄膜單元。以此方式,至一浸沒薄膜槽中之流入物流可用於幫助防止薄膜單元中之積垢或污泥附著及/或降低薄膜清潔頻率。在一MBR之情況中,再循環RAS中涉及之一些能量可以液體速度或脈衝之形式回收。The film tanks and procedures described herein result in the inflow being usually fed directly to one or more submerged film units. This helps prevent the inflow (for example, the inflow being fed to a downstream membrane unit) from being pre-concentrated by other membrane units. Optionally, the system can also be configured so that the flow rate of the inflow through the various submerged membrane units is substantially equal. Providing the influent to different immersion membrane units at substantially equal flow rates depending on the situation at its original concentration can lead to higher productivity and/or easier operation of the system as a whole. In addition, the inflow is forced upward through the membrane unit. The influx flowing upward through a membrane unit can help force adjacent membranes to separate from each other, inhibit the dehydration or retention of sludge in the membrane unit and/or disperse fresh inflow throughout the membrane unit. In this way, the influent stream to a submerged membrane tank can be used to help prevent fouling or sludge adhesion in the membrane unit and/or reduce the frequency of membrane cleaning. In the case of an MBR, some of the energy involved in recirculating RAS can be recovered in the form of liquid velocity or pulses.
圖1展示使用一活性污泥程序之一薄膜生物反應器(MBR) 100。廢水102 (例如,工業廢水或城市污水)經收集且行進通過一粗篩104及視情況,一細篩106。細篩106可具有(例如) 2 mm至5 mm之開口且可在MBR 100中定位為比在圖1中展示之位置進一步下游。經網篩廢水102流動通過一初級處理單元108 (諸如一淨化器或旋轉帶式過濾器)。初級處理單元108產生初級污泥110及初級流出物112。Figure 1 shows a membrane bioreactor (MBR) 100 using an activated sludge process. Waste water 102 (for example, industrial wastewater or urban sewage) is collected and travels through a
初級流出物112流動至一或多個處理槽114。在一些實例中,存在一個好氧處理槽114。在其他實例中,可存在含有好氧、缺氧及/或厭氧處理區之一系列兩個或兩個以上處理槽114。處理槽114中之微生物消化初級流出物112且產生混合液體116。混合液體116被傳送至一薄膜槽70。在所展示實例中,混合液體116被泵送至薄膜槽70。在其他實例中,混合液體藉由重力流動至薄膜槽70。The
薄膜槽70含有一或多個導管80及一或多個薄膜單元120。一或多個導管80自薄膜槽70之一入口86延伸至薄膜單元120之底部。一導管80提供混合液體116在薄膜槽70中流動通過其以到達一或多個薄膜單元120之一充氣室。混合液體116接著向上流動通過薄膜單元120且至薄膜單元120外部之薄膜槽70中。一滲透物泵122在混合液體116行進通過薄膜單元120時自混合液體116抽出滲透物124。因此,混合液體116在薄膜單元中濃縮且作為活性污泥126離開薄膜單元。活性污泥126 (例如)藉由泵抽或重力自薄膜槽70被抽出且被劃分成廢棄活性污泥(WAS) 128及回流(或回收)活性污泥(RAS) 130。The
在圖1中,薄膜槽70係一MBR 100之部分。廢水102至一MBR 100中之流速習知地被稱為Q。RAS 130之流速可係(例如)在1Q至5Q之範圍中。混合液體116之流速可係(例如) 2Q至6Q。因此,大量能量被施加至一MBR 100中之再循環RAS。此可導致混合液體116以一大流速及/或能量含量流動至薄膜槽70中。然而,在一些情況中,薄膜槽70可係另一過濾系統(諸如旨在產生飲用水或工業程序用水之一地表水或地下水過濾系統或旨在精製(polish)已藉由另一程序處理之廢水之一三級過濾系統)之部分。In FIG. 1, the
薄膜槽70在圖2中之側視圖及圖3中之端視圖中展示。薄膜槽70可具有係薄膜槽70之寬度之2倍或更多或4倍或更多之一長度。薄膜槽70之壁與薄膜單元120之正面、側面及背面之間之間距可比所展示之實例中更接近。The
在所展示實例中,一導管80部分由薄膜槽70之底部形成。側壁82自薄膜槽70之底部向上延伸至薄膜單元120之底部。導管80在薄膜單元120下方沿著槽70之長度延伸。導管80之下游端由一端壁84封閉。導管80之頂部由板88形成。板88不連續,從而提供在長度及寬度上與薄膜單元120之水平尺寸大體上相等之間隙89。In the example shown, a
導管80視情況具有擋板90。在所展示實例中,擋板90自板88向下延伸,使得流動通過擋板90之水可在進入薄膜單元120之前分散遍及間隙89之整個區域。一間隙89可具有係其上方之一薄膜單元120之水平橫截面面積之至少80%之一面積。擋板90亦在一匣90之底部下方水平延伸至少半程(視情況全程)。擋板90之水平延伸界定一開口92。視情況,開口92具有相對於彼此不同之大小以幫助提供至薄膜單元120之總流入物混合液體流之一選定劃分。一擋板90在一薄膜單元120之底部之實質上全部(即,80%或更多或90%或更多)或全部上方但向下移位至導管80之頂部之水平延伸趨於產生流入物流在薄膜單元120當中在一更廣範圍之流入物流速內之一選定分佈。在不旨在受理論限制之情況下,此可部分係因為開口92之面積相對於間隙89小(即,50%或更小)或係因為開口92面向間隙89上游之流入物流中。The
在所展示實例中,與一第一(上游)擋板90相關聯之一開口92之高度由第一擋板90與板88之間之垂直距離界定。與一中間擋板90相關聯之一開口92之高度由中間擋板90與第一擋板90之間之垂直距離界定。用於最下游薄膜單元120之一擋板90由槽70之底板之部分及導管80之端84提供。用於最下游薄膜單元120之一開口92界定於中間擋板90與槽70之底部之間。替代地,可為各薄膜單元120提供一單獨導管80,但預期此將需要額外材料及製造且可能增加(若干)導管80之整體高差損失(head loss)。在所展示實例中,導管80在開口92與間隙89之間之部分提供供混合液體自導管80流動至薄膜單元120之底部中之路徑。In the example shown, the height of an
薄膜單元120視情況包含一薄膜殼(替代地稱為一護罩),該薄膜殼係提供含有薄膜自身之一垂直延伸導管之一結構。薄膜殼可係一單獨結構或可與薄膜單元120之其他部分一體地形成。薄膜單元120視情況包含在具備來自一鼓風機134之空氣時產生氣泡之曝氣器132。在一些情況中,曝氣器132與薄膜單元120整合,(例如)定位於薄膜殼內。在其他情況中,曝氣器可被放置於薄膜單元120下方,視情況在提供將導管80與一薄膜單元120連接之一垂直延伸導管之一護罩或曝氣器殼中。若薄膜在一薄膜殼內,則薄膜較佳經配置以提供供液體向上流經薄膜通過薄膜單元之垂直通道。例如,薄膜可係平板薄膜或平坦陶瓷薄膜。The
在一些實例中,導管80與混合液體入口86之間之連接及導管80與薄膜單元120之底部之間之連接通常係液密的。除至入口86及薄膜單元120之連接之外,導管80通常係一封閉充氣室。若被使用,則薄膜及曝氣器殼通常係封閉管。以此方式,至薄膜槽70之流入物通常被直接提供至薄膜單元120。實質上不存在薄膜槽70中之先前濃縮流入物與透過導管80饋送至薄膜單元之流入物之混合。然而,由於此等係大型土木工程,故不預期完美液密連接或完美封閉導管或薄膜殼。例如,一導管80之一彎曲板金屬凸緣與一薄膜槽70之混凝土壁或底板或一匣50之框架之間之連接可在某一程度上洩漏,且導管80自身可由未使用完美液密連接連接在一起之多個件製成。然而,一開放式薄膜槽70及浸沒薄膜單元120之使用容許大系統有關一完全密封系統之更經濟構造。In some instances, the connection between the
儘管在習知地操作為一攪拌槽反應器之一開放式薄膜槽70中,然在圖2及圖3之實例中,薄膜單元120可在更如同一直流橫流之一流動形態下操作。較佳地,進入薄膜槽70之流入物之至少90%或至少95%被引導穿過導管80至薄膜單元120,且與自入口86至薄膜槽70之流入物相反,向上流動通過薄膜單元120之不多於10%或不多於5%之流入物係來自導管80外部之薄膜槽70之流入物。視情況,導管80及至其及來自其之連接充分封閉且密封,使得在薄膜單元120之底部處之流入物之總懸浮固體(TSS)濃度比流入物之TSS濃度高不多於5%或不多於3%。藉此,到達薄膜槽70之不同部分中之薄膜單元120之流入物之濃度亦大體上等化。導管80亦有助於提供流至薄膜槽70之不同部分中之薄膜單元120之一大體上均勻分佈。在其中薄膜單元120包含薄膜殼(及若曝氣器132在薄膜單元下方,則曝氣器殼)之實例中,離開薄膜單元120之水之濃度亦大體上等化。例如,在如圖1中之一MBR 100中,在薄膜單元120之頂部處之水(濃縮物)之總懸浮固體(TSS)濃度比整個薄膜槽120中之活性污泥126之TSS濃度小不多於5%。在其中混合液體116及活性污泥126之固體含量高之一MBR 100之情況中,減小薄膜單元120之間之固體濃度之一差可減小薄膜清潔頻率且可增加薄膜單元120之平均通量。Although in the conventionally operated as an
流入物(即,混合液體116)以在很大程度上由流入物流速及薄膜單元之薄膜殼之開放式水平橫截面面積判定之一平均速度自導管80向上流動通過薄膜單元120之薄膜殼。在通過一薄膜單元120的一個遍次中達成顯著流入物濃度之能力(此有助於避免過量RAS再循環率或6Q或更多)在很大程度上由薄膜單元120相對於其等水平橫截面面積(佔據面積)之填充密度判定。在平坦形式(即,平板或平坦陶瓷)之薄膜中之高佔據面積可係藉由緊密間距及/或多個板堆疊。例如,薄膜之間之淨垂直空間(即,面對面分離)可係5 mm或更少、3 mm或更少或2 mm或更少。薄膜單元120可使用垂直堆疊之2或3或更多個模組製成。The influent (ie, the mixed liquid 116) flows upward from the
在於一MBR中使用四個薄膜單元120 (各薄膜單元120呈如圖11中展示之一匣50之形式,其中在薄膜板之間具有1.5 mm之面對面間距)之一個試驗中,2.78Q之一RAS再循環率在匣50中產生0.023 m/s之一平均(向上)液體速度。將RAS再循環率增加至5Q及5.6Q分別產生0.035及0.046 m/s之平均(向上)液體速度。考量匣中之淨空間之水平面積(即,在個別薄膜之間之多個1.5 mm寬垂直延伸間隙之累積面積)及至各匣之底部中之流入物流速但在不調整被提供至匣中之氣泡之情況下,計算平均液體速度。在以0.023 m/s之一速度操作時,在於四個匣之頂部處收集之水中存在最大與最小混合液體懸浮固體(MLSS)濃度之間之一20%之差(即,自平均值之約一10%之變動),且四個匣之兩者具有高於其他兩個匣之一積垢率。在以0.046 m/s操作時,在於四個匣之頂部處收集之水中僅存在最大與最小混合液體懸浮固體(MLSS)濃度之間之一10%之差(即,自平均值之約一5%之變動),且全部四個匣具有類似低積垢率。以0.035 m/s之一速度之操作亦產生在全部四個匣中具有類似低積垢率之可持續操作。在不旨在受理論限制之情況下,以最低速度之相對較差結果可歸因於低速度自身,在低RAS回收率下在此特定導管(其具有不同開口大小但使用非如圖2及圖3中展示之一擋板設計)中發生之四個匣之間之總流入物流之不相等分佈,或兩者之一組合。In an experiment using four
視情況,一薄膜單元中之平均液體速度係0.025 m/s或更多或0.03 m/s或更多。在修改一或多個參數(例如,RAS再循環率)的情況下,可達成高達0.05 m/s、高達0.7 m/s或高達0.1 m/s之更高平均液體速度。此等速度遠低於在習知密封系統(即,板框系統、向內/向外中空纖維系統或管狀薄膜系統)中之交叉流過濾中通常使用之速度,該速度在過濾大體上清潔流入物時通常係約0.2 m/s或更大,且在過濾混合液體時為1.0 m/s或更大。在不旨在受理論限制之情況下,由於涉及遠更低速度,在本文中描述之系統及程序中,在薄膜表面上方流動之液體之剪切力在流體剪切係典型交叉流過濾系統中之材料之相同意義上可係無效的。然而,透過多個匣以一大體上一致流體速度提供新鮮混合液體似乎有利地提供匣當中之一致條件,此藉此避免具有由比其他匣更快速地積垢之一或多個匣判定之系統之清潔及操作協定。此外,液體之強制流動可提供一或多個效應,例如,迫使薄膜分開或迫使固體自薄膜之間之初始累積,其不與剪切力相關而係使用流動流入物之能量以幫助避免以非由通過匣之液體之一氣泡引發(即,氣昇)流提供之一方式積垢或污泥附著。Depending on the circumstances, the average liquid velocity in a membrane unit is 0.025 m/s or more or 0.03 m/s or more. In the case of modifying one or more parameters (for example, RAS recirculation rate), higher average liquid velocities of up to 0.05 m/s, up to 0.7 m/s, or up to 0.1 m/s can be achieved. These speeds are much lower than those commonly used in cross-flow filtration in conventional sealing systems (ie, plate and frame systems, inward/outward hollow fiber systems, or tubular membrane systems), which generally clean inflow in the filter The material time is usually about 0.2 m/s or more, and 1.0 m/s or more when filtering mixed liquids. Without intending to be bound by theory, due to the much lower speed involved, in the systems and procedures described in this article, the shear force of the liquid flowing above the membrane surface is in the fluid shear system typical of cross-flow filtration systems The same meaning of the material can be invalid. However, providing fresh mixed liquid at substantially uniform fluid velocity through multiple cassettes seems to advantageously provide consistent conditions in the cassettes, thereby avoiding the cleaning of a system that is determined by fouling one or more cassettes faster than the other cassettes. And operating agreement. In addition, the forced flow of the liquid can provide one or more effects, for example, forcing the film to separate or forcing the initial accumulation of solids from between the films, which is not related to shear force but uses the energy of the flowing inflow to help avoid undesirable effects. The flow initiated by one of the bubbles of the liquid passing through the cassette (ie, air lift) provides a way for fouling or sludge adhesion.
圖4至圖11描述一匣50之一實例,或其之各種部分。匣50可單獨或以一組多個匣50使用以提供一薄膜單元120。Figures 4 to 11 illustrate an example of a
圖4展示一薄膜板10 (替代地稱為一元件)之一實例。薄膜板10由兩個基材板12構成,該兩個基材板12經形成且結合在一起以提供內部通道14。基材板12之外部塗佈有一多孔分離層16。可藉由在基材板12上方鑄造一薄膜形成塗料且接著在一淬火浴中固化塗料而製造分離層16。此程序根據非溶劑引發之相位分離(NIPS)方法產生通常在超濾或微濾範圍中之孔。兩個基材板12之間之一中心板18係選用的但可視需要經添加以提供一更剛性薄膜板10。在其他實例中,元件可由在一框架或間隔件上方(例如)以Kubota或Microdyn Nadir元件之方式附接在一起之兩個平板薄膜製成。在其他實例中,元件可由板形式陶瓷製成。Fig. 4 shows an example of a film plate 10 (alternatively referred to as an element). The
圖5展示一薄膜模組20。模組20具有一或多個薄膜板10。薄膜板10之敞開至內部通道14之邊緣(即,圖1中展示之邊緣)經灌封於集管(header) 22 (替代地稱為灌封頭或滲透物收集器)中。當在使用中時,集管22大體上垂直地定向且內部通道14係大體上水平的。例如藉由泵或虹吸管施加至集管22之滲透物埠24之吸力引起滲透物26在內部通道14中產生且流動通過集管22。視情況,滲透物可自薄膜板10之一端或兩端抽出。一模組20通常具有多個平行薄膜板10。鄰近薄膜板10由具有大體上相等寬度(例如,1.5 mm寬與4 mm寬之間)之垂直間隙分離。在一個實例中,一模組20係約1900 mm寬,約800 mm高且約60 mm厚且含有跨其厚度大體上相等地間隔之16個薄膜板10。在此實例中,集管22及外薄膜板10形成一薄膜殼。在其他實例中,一模組可由一單獨薄膜殼包圍。FIG. 5 shows a
當用於一薄膜生物反應器(MBR)或一過濾設備中時,自模組20下方提供之氣泡28幫助所過濾液體30向上流動通過模組20,包含通過鄰近薄膜板10之間之間隙。When used in a membrane bioreactor (MBR) or a filtration device, bubbles 28 provided from below the
圖6展示經切開以進一步繪示液體30通過模組20之流動之一模組20之一示意圖。薄膜板10之起伏形狀在液體30上升時在液體30中產生紊流。薄膜板10可在液體30及氣泡28在其等之間移動時振動。除了輔助液體流動之外,氣泡28亦可提供薄膜板10之某一直接沖刷。FIG. 6 shows a schematic diagram of a
圖7展示三個模組20之一堆疊32。模組20彼此垂直地上下堆疊。一下模組之滲透物埠24配裝於一上模組之集管22中之插口(不可見)中。最下模組20中之插口被插塞。最高模組之滲透物埠24可連接至一滲透物抽出管且用於自全部三個模組20抽出滲透物。堆疊32亦可使用兩個、四個或其他數目個模組20製造。由於臨近模組之集管22垂直對準且連續,故饋送液體可垂直流動通過整個堆疊32而不被集管22阻礙。FIG. 7 shows a
圖8展示在一框架42中含有複數個模組20之一區塊40。模組20並排放置於框架42中。一模組20可垂直地滑入或滑出框架42。當在框架42中時,在所展示實例中,模組20之集管22配裝至由附接至框架42之塑膠模製件44提供之對應槽中。框架42較佳由不鏽鋼製成,但亦可使用其他材料。側板45覆蓋框架之平行於模組20之側。集管22各包含多個模組20且鄰近集管22彼此觸碰,或接近觸碰,例如,彼此分開小於10 mm或彼此分開小於5 mm。側板45及集管22藉此形成界定通過區塊40之一垂直延伸流體通道之一整合式薄膜殼。FIG. 8 shows a
圖9展示一區塊40之頂部之一放大視圖。在區塊40之頂部處之一凸緣46及在區塊40之底部上之一類似凸緣(圖9中未展示)可用於支撐一上或下區塊40且容許一堆疊中之區塊40被緊固在一起。模組20之滲透物埠24突出至凸緣46上方以容許在如圖4中描述之一堆疊中之模組20之間之滲透物連接。Figure 9 shows an enlarged view of the top of a
圖10展示區塊40之部分之一水平截面之一放大視圖。集管22含有由集管22、薄膜板10之邊緣及薄膜板10之間之灌封樹脂27界定之一滲透物腔室23。滲透物腔室23與滲透物埠24及插口流體連通。為了將一模組20固持於框架42中,一螺栓48行進通過框架42且經螺合至附著至集管22之一螺母25中,或與塑膠模製集管22一體地模製,如展示。FIG. 10 shows an enlarged view of a horizontal section of a portion of the
圖11展示彼此垂直地上下堆疊在一起之三個區塊40構成之一匣50。視情況,所製成之一匣50具有一個、兩個、四個或另一數目個區塊40。上區塊40之滲透物埠24視情況透過連接器管52連接至一滲透物集管箱管54,如展示。區塊40之框架42藉由支柱58彼此連接,在所展示實例中,該等支柱58係在其等端上具有螺母之螺紋桿。支柱58亦將上區塊40附接至一匣框架56,該匣框架56可用於將匣50懸垂於一槽中。空氣供應管60將空氣帶至匣之底部以饋送至最下區塊40下方之一組曝氣器(不可見)。垂直鄰近區塊40之模製件44及側板45形成供流體流動通過匣50之一連續垂直延伸通道。藉此,匣50作為一整體具有一整合式薄膜殼。替代地,可提供一單獨薄膜殼。FIG. 11 shows that three
可藉由附接至匣框架56之一起重機或吊機將匣50放低至一薄膜槽70中或自薄膜槽70提起。匣框架56可擱置於薄膜槽70之凸緣上。在所展示實例中,匣50具有84個模組20。按體積之填充密度係450至500 m2
/m3
。按佔據面積之填充密度係約850 m2
/m3
。在一個實例中,各模組20係約7至10 cm寬。模組20可以自1至5個模組20高之一垂直堆疊配置於一匣50中。匣50中之模組20之各堆疊在堆疊中之最下模組20下方具有約3至6 cm寬之一個曝氣器。The
描述適合薄膜板、模組、區塊及匣之額外資訊可見於以下公開案中:由Fibracast Ltd.在2017年4月6日發表之Method of Operating Membrane Filter之美國公開案第US 2017/0095773號;由Fibracast Ltd.在2013年4月25日發表之Coating Device and Process for Coating Formed Sheet Membrane Element之國際公開案第WO 2013/056373號;及由Fibracast Ltd.在2011年10月27日發表之Formed Sheet Membrane Element and Filtration System之國際公開案第WO 2011/130853號,該等案以引用的方式併入本文中。Additional information describing suitable film boards, modules, blocks and cassettes can be found in the following public case: Method of Operating Membrane Filter published by Fibracast Ltd. on April 6, 2017, US Publication No. US 2017/0095773 ; International Publication No. WO 2013/056373 of Coating Device and Process for Coating Formed Sheet Membrane Element published by Fibracast Ltd. on April 25, 2013; and Formed published by Fibracast Ltd. on October 27, 2011 International Publication No. WO 2011/130853 of Sheet Membrane Element and Filtration System, these cases are incorporated herein by reference.
圖12及圖13展示另一導管80之兩個視圖。在此實例中,導管80將流入物引導至各具有一個匣50之兩個薄膜單元120。一擋板90由連接至定位於一板88下方之一垂直板96之水平板製成。一上游擋板之開口92之面積由導管80之寬度乘以水平板94在導管80之頂部下方之位移界定。一下游擋板之開口92之面積由導管80之寬度乘以水平板94在薄膜槽70之底板上方之位移界定。Figures 12 and 13 show two views of another
圖14展示在三個薄膜單元120下方延伸之另一導管80。第一薄膜單元120具有三個匣50。第二及第三薄膜單元120各具有兩個匣50。FIG. 14 shows another
如在一MBR中使用般使用運算流體動力學模型化旨在用於與以一列在遠離一入口的下游延伸之具有相等大小之5個薄膜單元一起使用之一導管之另一實例。導管80大體上如圖12及圖13中展示般建構但具有更多擋板90及開口92。各中間開口92之面積在面積上由導管80之寬度乘以當前擋板之水平板94在一上游擋板90之水平板94下方之位移界定。The use of computational fluid dynamics modeling as used in an MBR is intended to be another example of using a conduit with a row of 5 membrane elements of equal size extending downstream away from an inlet. The
表1展示混合液體通過具有相等開口大小之上述模型化實例中之開口之平均速度。如表1中指示,具有相等開口大小,通過不同開口之混合液體速度類似但彼此不相同。
表1
表2展示混合液體通過具有經調整(不相等)開口大小之上述模型化實例中之開口之平均速度。如表2中指示,可藉由調整擋板及/或開口而實質上等化流體通過開口之速度。進一步調整可實質上等化通過薄膜單元之平均液體速度。視情況,可使流動通過各薄膜單元之液體之速度在按一選定流入物流速(例如,一平均或峰值設計流速)通過全部薄膜單元之一平均速度之10%內。一般言之,可期望相等速度,此係因為具有極大地低於平均值之速度之一薄膜單元將曝露至在薄膜單元之頂部處之更濃縮混合液體及/或將由移動液體較不有效地清潔。
表2
一實驗性MBR具有帶兩個匣之一單獨薄膜槽,如圖11中。槽顯著大於匣。回流活性污泥(RAS)回收率係4Q。薄膜槽最初在不使用一導管之情況下操作。薄膜槽隨後如圖12及圖13中展示般使用一導管80操作。在不增加跨膜壓力(TMP)之情況下(其在使用及不使用一導管操作時係2 psi),在添加導管時,滲透物產量增加一倍以上。An experimental MBR has a separate film tank with one of two cassettes, as shown in Figure 11. The slot is significantly larger than the cassette. The return rate of activated sludge (RAS) is 4Q. The film tank was initially operated without the use of a catheter. The film tank is then operated using a
10:薄膜板 12:基材板 14:內部通道 16:多孔分離層 18:中心板 20:薄膜模組 22:集管 23:滲透物腔室 24:滲透物埠 25:螺母 26:滲透物 27:灌封樹脂 28:氣泡 30:液體 32:堆疊 40:區塊 42:框架 44:塑膠模製件 45:側板 46:凸緣 48:螺栓 50:匣 52:連接器管 54:滲透物集管箱管 56:匣框架 58:支柱 60:空氣供應管 70:薄膜槽 80:導管 82:側壁 84:端壁 86:混合液體入口 88:板 89:間隙 90:擋板 92:開口 94:水平板 96:垂直板 100:薄膜生物反應器(MBR) 102:廢水 104:粗篩 106:細篩 108:初級處理單元 110:初級污泥 112:初級流出物 114:處理槽 116:混合液體 120:薄膜單元 122:滲透物泵 124:滲透物 126:活性污泥 128:廢棄活性污泥(WAS) 130:回流活性污泥(RAS) 132:曝氣器 134:鼓風機10: Membrane board 12: Substrate board 14: internal channel 16: Porous separation layer 18: Center plate 20: Thin film module 22: header 23: Permeate Chamber 24: Permeate Port 25: Nut 26: Permeate 27: potting resin 28: bubbles 30: liquid 32: Stack 40: block 42: Frame 44: Plastic molded parts 45: side panel 46: flange 48: Bolt 50: box 52: connector tube 54: Permeate header box tube 56: box frame 58: Pillar 60: Air supply pipe 70: film tank 80: Catheter 82: side wall 84: end wall 86: Mixed liquid inlet 88: Board 89: gap 90: bezel 92: opening 94: horizontal board 96: vertical plate 100: Membrane Bioreactor (MBR) 102: Wastewater 104: Coarse Sieve 106: fine sieve 108: Primary processing unit 110: Primary sludge 112: Primary effluent 114: processing tank 116: mixed liquid 120: film unit 122: Permeate Pump 124: Penetration 126: Activated sludge 128: Waste activated sludge (WAS) 130: Return activated sludge (RAS) 132: Aerator 134: Blower
圖1係一薄膜生物反應器之一示意圖。Figure 1 is a schematic diagram of a thin film bioreactor.
圖2係圖1之薄膜生物反應器之一薄膜槽之一示意性側視圖,其中一側被移除,從而展示一導管。Figure 2 is a schematic side view of a membrane tank of the membrane bioreactor of Figure 1 with one side removed to show a catheter.
圖3係圖2之薄膜槽之一示意性端視圖,其中槽之前部被移除。Fig. 3 is a schematic end view of the film groove of Fig. 2 with the front part of the groove removed.
圖4展示一薄膜板之一邊緣視圖。Figure 4 shows an edge view of a film plate.
圖5展示一薄膜模組之一立視圖,其包含如圖4中之一薄膜板。FIG. 5 shows an elevation view of a thin film module, which includes a thin film plate as shown in FIG. 4.
圖6係一切開模組之一示意性透視圖,其展示饋送液體及滲透物流動方向。Figure 6 is a schematic perspective view of one of the split modules, which shows the flow direction of the feed liquid and the permeate.
圖7展示堆疊在一起之圖5之三個模組之一立視圖。Figure 7 shows an elevation view of the three modules of Figure 5 stacked together.
圖8係含有圖5之若干模組之一區塊之一等角視圖。FIG. 8 is an isometric view of a block containing the modules of FIG. 5. FIG.
圖9係圖8之區塊之部分之一放大視圖。FIG. 9 is an enlarged view of part of the block of FIG. 8. FIG.
圖10係圖8之區塊之一區段之一放大視圖。Fig. 10 is an enlarged view of a section of the block of Fig. 8;
圖11係具有堆疊在一起之圖8之三個區塊之一匣之一等角視圖。Figure 11 is an isometric view of one of the three blocks of Figure 8 stacked together.
圖12係另一導管之一等角視圖。Figure 12 is an isometric view of another catheter.
圖13係在圖12之導管之頂部上之如圖11中之兩個匣之部分之一等角視圖。Figure 13 is an isometric view of one of the parts of the two cassettes in Figure 11 on the top of the catheter of Figure 12.
圖14係在安裝於一槽中之另一導管之頂部上之如圖11中之七個匣之部分之一等角部分剖視圖。Figure 14 is an isometric partial cross-sectional view of one of the seven cassettes in Figure 11 on the top of another conduit installed in a slot.
70:薄膜槽 70: film tank
80:導管 80: Catheter
86:混合液體入口 86: Mixed liquid inlet
100:薄膜生物反應器(MBR) 100: Membrane Bioreactor (MBR)
102:廢水 102: Wastewater
104:粗篩 104: Coarse Sieve
106:細篩 106: fine sieve
108:初級處理單元 108: Primary processing unit
110:初級污泥 110: Primary sludge
112:初級流出物 112: Primary effluent
114:處理槽 114: processing tank
116:混合液體 116: mixed liquid
120:薄膜單元 120: film unit
122:滲透物泵 122: Permeate Pump
126:活性污泥 126: Activated sludge
128:廢棄活性污泥(WAS) 128: Waste activated sludge (WAS)
130:回流活性污泥(RAS) 130: Return activated sludge (RAS)
Claims (16)
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US62/874,626 | 2019-07-16 |
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