TW202108257A - Sludge processing method and cement manufacturing system - Google Patents

Sludge processing method and cement manufacturing system Download PDF

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TW202108257A
TW202108257A TW109122422A TW109122422A TW202108257A TW 202108257 A TW202108257 A TW 202108257A TW 109122422 A TW109122422 A TW 109122422A TW 109122422 A TW109122422 A TW 109122422A TW 202108257 A TW202108257 A TW 202108257A
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cyclone
cement raw
sludge
mentioned
cement
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TWI826700B (en
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青松慎之介
吉永昭宏
安藤文典
凡茂樹
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日商川崎重工業股份有限公司
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • C04B7/43Heat treatment, e.g. precalcining, burning, melting; Cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/13Treatment of sludge; Devices therefor by de-watering, drying or thickening by heating
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/24Cements from oil shales, residues or waste other than slag
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • C04B7/38Preparing or treating the raw materials individually or as batches, e.g. mixing with fuel
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • C04B7/43Heat treatment, e.g. precalcining, burning, melting; Cooling
    • C04B7/434Preheating with addition of fuel, e.g. calcining
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • C04B7/43Heat treatment, e.g. precalcining, burning, melting; Cooling
    • C04B7/436Special arrangements for treating part or all of the cement kiln dust
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • C04B7/43Heat treatment, e.g. precalcining, burning, melting; Cooling
    • C04B7/44Burning; Melting
    • C04B7/4407Treatment or selection of the fuel therefor, e.g. use of hazardous waste as secondary fuel ; Use of particular energy sources, e.g. waste hot gases from other processes
    • C04B7/4423Waste or refuse used as fuel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B19/00Combinations of furnaces of kinds not covered by a single preceding main group
    • F27B19/04Combinations of furnaces of kinds not covered by a single preceding main group arranged for associated working
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D13/00Apparatus for preheating charges; Arrangements for preheating charges
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding

Abstract

This cement manufacturing system comprises: a suspension pre-heater for pre-heating a cement raw material; a calcining furnace for calcining the pre-heated cement raw material; and a firing furnace for firing the calcined cement raw material. In the cement manufacturing system, a granular material containing dried sludge is loaded into a region of the suspension pre-heater having a temperature of at least 600 DEG C and less than 800 DEG C, and the dried sludge is used as a cement raw material and fuel.

Description

汙泥之處理方法及水泥製造系統Sludge treatment method and cement manufacturing system

本發明關於汙泥之處理方法、以及利用汙泥之水泥製造系統。The present invention relates to a sludge treatment method and a cement manufacturing system using sludge.

水泥製造程序大致劃分由對水泥原料進行乾燥・粉碎・調合之原料步驟、自原料中燒成出中間製品亦即熟料之燒成步驟、以及於熟料中添加石膏且加以粉碎來製成水泥之最後加工步驟所構成。燒成步驟中,通常,水泥原料依序通過預熱器、預燒爐(分解爐)及燒成爐。作為燒成步驟之熱能量,提出利用下水汙泥或工廠廢水汙泥等汙泥之燃燒熱,進而,將其焚燒灰用作水泥原料。專利文獻1、2中,揭示有於水泥燒成步驟中利用汙泥之技術。The cement manufacturing process is roughly divided into the raw material steps of drying, pulverizing, and blending cement raw materials, the firing step of firing intermediate products, namely clinker, from the raw materials, and adding gypsum to the clinker and pulverizing to make cement. The final processing steps. In the firing step, usually, cement raw materials pass through a preheater, a pre-calcining furnace (calcining furnace), and a firing furnace in sequence. As the heat energy of the firing step, it is proposed to use the combustion heat of sewage sludge or factory wastewater sludge, and then use the incineration ash as a raw material for cement. Patent Documents 1 and 2 disclose techniques for using sludge in the cement firing step.

專利文獻1中揭示有:於包含有機物之廢棄物中,添加用以賦予流動性之溶媒,利用濕式粉碎機進行粉碎後,將該漿料狀之混合粉碎物投入至燒成步驟來製造水泥熟料。作為溶媒,提出有汙泥。又,作為漿料狀之混合粉碎物之投入部位,提出有預熱器之800℃~1000℃之高溫部。Patent Document 1 discloses that a solvent for imparting fluidity is added to waste containing organic matter, and after pulverization with a wet pulverizer, the slurry-like mixed and pulverized product is thrown into the firing step to produce cement Clinker. As the solvent, sludge is proposed. In addition, as the input location of the slurry-like mixed and crushed product, a high temperature section of 800°C to 1000°C of a preheater is proposed.

專利文獻2中揭示有:於使用預燒爐與最下段旋風器直接連接之水泥燒成裝置之情形時,將含水汙泥投入至自預燒爐之出口至最下段旋風器之出口部為止之區域,於使用預燒爐與最下段旋風器不直接連接之情形時,將含水汙泥投入至自最下段旋風器之入口部至最下段旋風器之出口部為止之區域。含水汙泥之投入部位之環境溫度為800℃以上、900℃以下。 現有技術文獻 專利文獻Patent Document 2 discloses that in the case of using a cement burning device in which the pre-burning furnace is directly connected to the lowermost cyclone, the water-containing sludge is injected from the outlet of the pre-burning furnace to the lowermost cyclone outlet. In the area, when the pre-burning furnace is not directly connected to the lowermost cyclone, the water-containing sludge is poured into the area from the inlet of the lowermost cyclone to the outlet of the lowermost cyclone. The ambient temperature of the place where the water-containing sludge is input is above 800°C and below 900°C. Prior art literature Patent literature

專利文獻1:日本特開2004-123513號公報 專利文獻2:日本特開2009-95804號公報Patent Document 1: Japanese Patent Application Publication No. 2004-123513 Patent Document 2: Japanese Patent Application Publication No. 2009-95804

[發明所欲解決之問題][The problem to be solved by the invention]

專利文獻1中,藉由漿料狀之混合粉碎物這種包含比較多水分之汙泥投入至預熱器之800℃以上之部位,來防止戴奧辛之發生。專利文獻2中,藉由將含水汙泥投入至預熱器之800℃以上之部位,來效率良好地使含水汙泥乾燥,並且減少汙泥之升溫所需要之熱量來抑制水泥燒成裝置之熱損耗。In Patent Document 1, the occurrence of dioxin is prevented by feeding sludge containing a relatively large amount of water, such as a slurry-like mixed and pulverized material, to a portion of 800°C or higher of the preheater. In Patent Document 2, the water-containing sludge can be efficiently dried by feeding the water-containing sludge to a position above 800°C of the preheater, and the heat required to raise the temperature of the sludge can be reduced to suppress the effect of the cement burning device. Heat loss.

本案申請人們於日本特願2018-006471中提出有:藉由將脫水汙泥與水泥原料混合而形成粒狀,使其與乾燥用氣體接觸而乾燥,將所獲得之粒狀之混成物投入至水泥燒成步驟之預燒爐中。由於在混成物之乾燥中利用與預燒爐之爐內溫度相比較低溫之乾燥氣體,故而乾燥後之混成物與一般之水泥原料相比,含有較多水分,又,投入至預燒爐中之混成物之溫度低於預燒爐之爐內溫度。The applicant of this case proposed in Japanese Patent Application 2018-006471: by mixing dewatered sludge with cement raw materials to form granules, contacting them with drying gas to dry, and throwing the obtained granular mixture into In the pre-burning furnace of the cement burning step. Since the dry gas at a lower temperature than the temperature in the pre-sintering furnace is used in the drying of the mixture, the dried mixture contains more moisture compared with ordinary cement raw materials, and is put into the pre-sintering furnace The temperature of the mixture is lower than the temperature in the pre-burning furnace.

若對預燒爐投入較爐內溫度而言溫度低之混成物,則擔憂燃燒狀態之擾亂或燃料消耗量之增加。又,擔憂於混成物之投入口附近產生局部之溫度下降,耐火被覆之壽命之下降或產生被膜。If a mixture whose temperature is lower than the temperature in the furnace is put into the pre-burning furnace, there is a concern that the combustion state will be disturbed or the fuel consumption will increase. In addition, there is a concern that a local temperature drop will occur near the inlet of the mixture, the life of the refractory coating will decrease, or the coating may be formed.

因此,本發明提出一種將汙泥用作水泥原料之一部分及燃料的汙泥之處理方法、以及於利用汙泥之水泥製造系統中使運轉更穩定化之技術。 [解決問題之手段]Therefore, the present invention proposes a method for treating sludge that uses sludge as a part of cement raw materials and fuel, and a technology for stabilizing operation in a cement manufacturing system using sludge. [Means to Solve the Problem]

本發明之一態樣之汙泥之處理方法係 一種利用水泥製造系統來處理汙泥之方法,上述水泥製造系統具備:對水泥原料進行預熱之懸浮預熱器、對經預熱之上述水泥原料進行預燒之預燒爐、以及對經預燒之上述水泥原料進行燒成之燒成爐; 其特徵在於:將包含乾燥汙泥之粒狀物投入至上述懸浮預熱器之600℃以上且低於800℃之溫度區域中,將上述乾燥汙泥用作水泥原料及燃料。The sludge treatment method of one aspect of the present invention is A method for treating sludge using a cement manufacturing system. The cement manufacturing system includes: a suspension preheater for preheating cement raw materials, a pre-burning furnace for pre-burning the preheated cement raw materials, and a A firing furnace for firing the above-mentioned cement raw materials; It is characterized in that the granular material containing dried sludge is put into the temperature range of 600°C or higher and lower than 800°C of the suspension preheater, and the dried sludge is used as a cement raw material and fuel.

又,本發明之一態樣之水泥製造系統之特徵在於具備: 對水泥原料進行預熱之懸浮預熱器、對經預熱之上述水泥原料進行預燒之預燒爐、以及對經預燒之上述水泥原料進行燒成之燒成爐;並且 上述懸浮預熱器具有對600℃以上且低於800℃之溫度區域投入包含乾燥汙泥之粒狀物的至少1個投入口。In addition, the cement manufacturing system of one aspect of the present invention is characterized by having: A suspension preheater for preheating cement raw materials, a pre-burning furnace for pre-burning the above-mentioned pre-heated cement raw materials, and a firing furnace for burning the above-mentioned pre-fired cement raw materials; and The above-mentioned suspension preheater has at least one input port for inputting granular materials including dried sludge into a temperature range of 600°C or higher and lower than 800°C.

上述汙泥之處理方法及水泥製造系統中,包含乾燥汙泥之粒狀物被投入至懸浮預熱器之600℃以上且低於800℃之溫度區域。該粒狀物於自向懸浮預熱器中之投入口(投入位置)移動至預燒爐之期間,與水泥原料一併升溫至向預燒爐中之投入溫度(約850℃~900℃)。In the above-mentioned sludge treatment method and cement manufacturing system, granular materials including dry sludge are fed into the temperature range of 600°C or higher and lower than 800°C of the suspension preheater. During the movement of the granular material from the input port (input position) of the suspension preheater to the pre-sintering furnace, it is heated together with the cement raw material to the input temperature into the pre-sintering furnace (approximately 850℃~900℃) .

與如專利文獻1、2般投入至800℃以上之區域中之習知情形相比,本案發明中,粒狀物於懸浮預熱器中之滯留時間長,粒狀物與水泥原料一併充分預熱後才投入至預燒爐中。因此,可抑制由向預燒爐投入低溫物而引起之燃燒狀態之擾亂或燃料消耗量之增加。藉此,於將汙泥用作水泥原料之一部分及燃料之水泥製造系統中,可有助於系統之運轉之穩定化。Compared with the conventional case of putting into the area above 800℃ as in Patent Documents 1 and 2, in the present invention, the residence time of the granular material in the suspension preheater is longer, and the granular material and the cement raw material are fully pre-prepared together. Put it into the pre-burning furnace after heating. Therefore, it is possible to suppress the disturbance of the combustion state or the increase in fuel consumption caused by the introduction of low-temperature materials into the pre-burning furnace. This can help stabilize the operation of the system in a cement manufacturing system that uses sludge as a part of the cement raw material and fuel.

進而,與上述習知情形相比,本案發明中,向懸浮預熱器中之投入口(投入位置)之環境溫度與粒狀物之溫度差小。因此,可抑制粒狀物之於投入口附近之局部之溫度下降,可抑制耐火被覆之壽命之下降或被膜之發生。 [發明效果]Furthermore, compared with the above-mentioned conventional situation, in the present invention, the temperature difference between the ambient temperature to the input port (input position) of the suspension preheater and the temperature of the granular material is small. Therefore, the temperature drop of the granular material in the vicinity of the input port can be suppressed, and the life span of the refractory coating can be suppressed or the generation of the coating can be suppressed. [Effects of the invention]

根據本發明,可提出將汙泥用作水泥原料之一部分及燃料的汙泥之處理方法、以及於利用汙泥之水泥製造系統中使運轉更穩定化之技術。According to the present invention, it is possible to propose a method for treating sludge that uses sludge as a part of cement raw material and fuel, and a technology for stabilizing operation in a cement manufacturing system using sludge.

其次,參照圖式來對本發明之實施型態進行說明。圖1係表示本發明之實施型態之水泥製造系統100之系統性的概略構成圖。Next, the implementation mode of the present invention will be described with reference to the drawings. Fig. 1 is a systematic schematic diagram showing a cement manufacturing system 100 according to an embodiment of the present invention.

水泥製造程序大致劃分由對水泥原料進行乾燥・粉碎・調合之原料步驟、自原料中燒成出中間製品亦即熟料之燒成步驟、以及於熟料中添加石膏且加以粉碎來製成水泥之最後加工步驟所構成。圖1所示之水泥製造系統100中,對其中負責燒成步驟之水泥燒成裝置2及空氣淬火冷卻器3、以及其周邊機器進行詳細記載。The cement manufacturing process is roughly divided into the raw material steps of drying, pulverizing, and blending cement raw materials, the firing step of firing intermediate products, namely clinker, from the raw materials, and adding gypsum to the clinker and pulverizing to make cement. The final processing steps. In the cement manufacturing system 100 shown in FIG. 1, the cement sintering device 2 and the air quenching cooler 3 in charge of the sintering step, and the peripheral equipment thereof are described in detail.

水泥製造系統100具備:對水泥原料進行燒成之水泥燒成裝置2、以及對自水泥燒成裝置2中輸出之燒成物進行冷卻之空氣淬火冷卻器3。The cement manufacturing system 100 includes a cement firing device 2 for firing cement raw materials, and an air quenching cooler 3 for cooling the fired product output from the cement firing device 2.

水泥燒成裝置2具有:對水泥原料進行預熱之懸浮預熱器(以下簡稱為「預熱器21」)、對經預熱之水泥原料進行預燒(分解)之預燒爐22、以及對經預熱及預燒之水泥原料進行燒成之燒成爐23。The cement firing device 2 has: a suspension preheater (hereinafter referred to as "preheater 21") for preheating cement raw materials, a precalcining furnace 22 for prefiring (decomposing) the preheated cement raw materials, and A firing furnace 23 for firing the preheated and prefired cement raw materials.

水泥燒成裝置2中,以水泥原料依序移動至預熱器21、預燒爐22及燒成爐23之方式,使其等連通。又,水泥燒成裝置2中,燒成爐23之高溫之廢氣依預燒爐22、預熱器21之順序流動。預熱器21中,連接有流出水泥燒成裝置2之廢氣之燒成裝置廢氣線9。燒成裝置廢氣線9中,鍋爐91、排風扇92、原料粉碎機93、集塵機94、排風扇95及煙囪96以該順序自廢氣之流動之上游朝向下游設置。In the cement firing device 2, the cement raw materials are sequentially moved to the preheater 21, the pre-sintering furnace 22, and the firing furnace 23 to communicate with each other. In addition, in the cement sintering device 2, the high-temperature exhaust gas of the sintering furnace 23 flows in the order of the pre-sintering furnace 22 and the preheater 21. The preheater 21 is connected to a firing device exhaust gas line 9 that flows out of the cement firing device 2. In the exhaust gas line 9 of the firing apparatus, a boiler 91, an exhaust fan 92, a raw material crusher 93, a dust collector 94, an exhaust fan 95, and a chimney 96 are installed in this order from the upstream of the flow of exhaust gas to the downstream.

圖2係表示預熱器21之概略構成之方塊圖。圖2所示之預熱器21具備串聯地連接之複數段之旋風器式集塵器。本實施型態之預熱器21具備自預燒爐22朝向上方串聯地連接之5段之旋風器單元U1~U5。但,預熱器21所具備之旋風器單元U之段數為3以上即可。FIG. 2 is a block diagram showing the schematic structure of the preheater 21. As shown in FIG. The preheater 21 shown in FIG. 2 has a plurality of cyclone-type dust collectors connected in series. The preheater 21 of this embodiment includes five cyclone units U1 to U5 connected in series from the pre-burning furnace 22 upward. However, the number of stages of the cyclone unit U included in the preheater 21 may be 3 or more.

各旋風器單元U具有:旋風器C、向旋風器C導入氣流之導管D、以及配管B,該配管B將利用旋風器C自氣流中分離之固體,向較其更下段之旋風器單元U之導管D、預燒爐22及燒成爐23中之至少一者輸送。此外,圖2中,標註於B、C、D、U後之數字表示段數。Each cyclone unit U has: a cyclone C, a duct D that introduces airflow to the cyclone C, and a pipe B. The pipe B will use the cyclone C to separate solids from the airflow to the cyclone unit U that is lower than it. At least one of the duct D, the pre-sintering furnace 22 and the firing furnace 23 is transported. In addition, in Fig. 2, the numbers after B, C, D, and U indicate the number of segments.

最下段之第1旋風器單元U1包括:第1旋風器C1、第1導管D1及第1配管B1。第1旋風器C1之氣流入口透過第1導管D1與預燒爐22之出口連接。第1旋風器C1之固體出口透過配管B1與燒成爐23和預燒爐22之連接部連接。The first cyclone unit U1 at the bottom stage includes: a first cyclone C1, a first duct D1, and a first pipe B1. The air inlet of the first cyclone C1 is connected to the outlet of the pre-burning furnace 22 through the first duct D1. The solid outlet of the first cyclone C1 is connected to the connection part of the firing furnace 23 and the pre-sintering furnace 22 through the pipe B1.

自下方起第二段之第2旋風器單元U2包括:第2旋風器C2、第2導管D2及第2配管B2。第1旋風器C1之氣體出口透過第2導管D2與第2旋風器C2之氣流入口連接。第2旋風器C2之固體出口透過配管B2與預燒爐22連接。The second cyclone unit U2 of the second stage from below includes: a second cyclone C2, a second duct D2, and a second pipe B2. The gas outlet of the first cyclone C1 is connected to the gas inlet of the second cyclone C2 through the second duct D2. The solid outlet of the second cyclone C2 is connected to the calciner 22 through the pipe B2.

自下方起第三段之第3旋風器單元U3包括:第3旋風器C3、第3導管D3及第3配管B3。第2旋風器C2之氣體出口透過第3導管D3與第3旋風器C3之氣流入口連接。第3旋風器C3之固體出口透過配管B3與第2導管D2連接。The third cyclone unit U3 of the third stage from below includes: a third cyclone C3, a third duct D3, and a third pipe B3. The gas outlet of the second cyclone C2 is connected to the gas inlet of the third cyclone C3 through the third duct D3. The solid outlet of the third cyclone C3 is connected to the second duct D2 through the pipe B3.

自下方起第四段之第4旋風器單元U4包括:第4旋風器C4、第4導管D4及第4配管B4。第3旋風器C3之氣體出口透過第4導管D4與第4旋風器C4之氣流入口連接。第4旋風器C4之固體出口透過配管B4與第3導管D3連接。The fourth cyclone unit U4 in the fourth stage from below includes: a fourth cyclone C4, a fourth duct D4, and a fourth pipe B4. The gas outlet of the third cyclone C3 is connected to the gas inlet of the fourth cyclone C4 through the fourth duct D4. The solid outlet of the fourth cyclone C4 is connected to the third duct D3 through the pipe B4.

最上段之第5旋風器單元U5包括:第5旋風器C5、第5導管D5及第5配管B5。第4旋風器C4之氣體出口透過第5導管D5與第5旋風器C5之氣流入口連接。第5旋風器C5之固體出口透過配管B5與第4導管D4連接。第5旋風器C5之氣體出口係與燒成裝置廢氣線9之上游端連接。The fifth cyclone unit U5 at the top stage includes: a fifth cyclone C5, a fifth duct D5, and a fifth pipe B5. The gas outlet of the fourth cyclone C4 is connected to the gas inlet of the fifth cyclone C5 through the fifth duct D5. The solid outlet of the fifth cyclone C5 is connected to the fourth duct D4 through the pipe B5. The gas outlet of the fifth cyclone C5 is connected to the upstream end of the exhaust gas line 9 of the burning device.

上述構成之預熱器21中,來自燒成爐23中之高溫廢氣通過預燒爐22及第1導管D1流入至第1旋風器C1中。廢氣自最下段之旋風器C1朝向最上段之旋風器C5移動。即,廢氣依序通過第1旋風器C1、第2導管D2、第2旋風器C2、第3導管D3、第3旋風器C3、第4導管D4、第4旋風器C4、第5導管D5及第5旋風器C5。In the preheater 21 of the above-mentioned structure, the high-temperature exhaust gas from the sintering furnace 23 flows into the first cyclone C1 through the pre-sintering furnace 22 and the first duct D1. The exhaust gas moves from the cyclone C1 at the bottom to the cyclone C5 at the top. That is, the exhaust gas passes through the first cyclone C1, the second duct D2, the second cyclone C2, the third duct D3, the third cyclone C3, the fourth duct D4, the fourth cyclone C4, the fifth duct D5, and The fifth cyclone C5.

於第5導管D5,設置有水泥原料供給口28。通過水泥原料供給口28,供給水泥原料至第5導管D5。供給至第5導管D5之水泥原料隨著廢氣之流動流入至第5旋風器C5。第5旋風器C5中,水泥原料自廢氣之流動中分離,水泥原料通過配管B5向第4導管D4輸送。向第4導管D4輸送之水泥原料隨著廢氣之流動向第4旋風器C4流入。第4旋風器C4中,水泥原料自廢氣之流動中分離,水泥原料通過配管B4向第3導管D3輸送。The fifth duct D5 is provided with a cement raw material supply port 28. The cement raw material is supplied to the fifth duct D5 through the cement raw material supply port 28. The cement raw material supplied to the fifth duct D5 flows into the fifth cyclone C5 along with the flow of the exhaust gas. In the fifth cyclone C5, the cement raw material is separated from the flow of the exhaust gas, and the cement raw material is transported to the fourth duct D4 through the pipe B5. The cement raw material conveyed to the fourth duct D4 flows into the fourth cyclone C4 along with the flow of the exhaust gas. In the fourth cyclone C4, the cement raw material is separated from the flow of the exhaust gas, and the cement raw material is transported to the third duct D3 through the pipe B4.

於第3導管D3,設置有後述之混成物之投入口29。投入口29與後述之混成物供給線8(搬送線84)連接。自第4旋風器C4向第3導管D3輸送之水泥原料、以及通過投入口29向第3導管D3供給之水泥原料及混成物(粒狀物)隨著廢氣之流動流入至第3旋風器C3中。第3旋風器C3中,水泥原料(包含混成物)自廢氣之流動中分離,水泥原料通過配管B3向第2導管D2輸送。向第2導管D2輸送之水泥原料隨著廢氣之流動向第2旋風器C2流入。第2旋風器C2中,水泥原料自廢氣之流動中分離,水泥原料通過配管B2向預燒爐22輸送。預燒爐22之廢氣通過第1導管D1向第1旋風器C1流入。第1旋風器C1中,水泥原料自廢氣之流動中分離,水泥原料通過配管B1向燒成爐23與預燒爐22之連接部輸送。如此,預熱器21中,水泥原料(包含混成物)自最上段之旋風器C5朝向最下段之旋風器C1依序移動。預熱器21之水泥原料隨著通過各旋風器C,藉由與預燒爐22之廢氣之熱交換而加熱。The third duct D3 is provided with an inlet 29 for the mixture to be described later. The injection inlet 29 is connected to a mixture supply line 8 (conveyance line 84) described later. The cement raw materials sent from the fourth cyclone C4 to the third duct D3, and the cement raw materials and the mixture (granular matter) supplied to the third duct D3 through the inlet 29 flow into the third cyclone C3 along with the flow of the exhaust gas. in. In the third cyclone C3, the cement raw materials (including the mixture) are separated from the flow of the exhaust gas, and the cement raw materials are transported to the second duct D2 through the pipe B3. The cement raw material conveyed to the second duct D2 flows into the second cyclone C2 along with the flow of the exhaust gas. In the second cyclone C2, the cement raw material is separated from the flow of the exhaust gas, and the cement raw material is transported to the pre-burning furnace 22 through the pipe B2. The exhaust gas of the pre-burning furnace 22 flows into the first cyclone C1 through the first duct D1. In the first cyclone C1, the cement raw material is separated from the flow of the exhaust gas, and the cement raw material is transported to the connection part of the firing furnace 23 and the pre-sintering furnace 22 through the pipe B1. In this way, in the preheater 21, the cement raw materials (including the mixture) sequentially move from the cyclone C5 of the uppermost stage to the cyclone C1 of the lowermost stage. The cement raw material of the preheater 21 is heated by heat exchange with the waste gas of the pre-burning furnace 22 as it passes through the cyclones C.

預燒爐22具備預燒爐燃燒器25。於預燒爐22,連接有自空氣淬火冷卻器3向預燒爐22中輸送廢熱之預燒爐用抽氣導管41。預燒爐22中,自預熱器21中輸出之水泥原料及混成物於約900℃之環境下進行預燒。本實施型態中,流入至第1導管D1中之廢氣之溫度約為900℃,流入至第2導管D2中之廢氣之溫度約為850℃,流入至第3導管D3中之廢氣之溫度約為750℃,流入至第4導管D4中之廢氣之溫度約為600℃,流入至第5導管D5中之廢氣之溫度約為450℃,自旋風器C5向燒成裝置廢氣線9輸出之廢氣之溫度約為310℃。但,流入至各導管D中之廢氣之溫度僅為例示。The calcining furnace 22 includes a calcining furnace burner 25. The pre-sintering furnace 22 is connected with an air extraction duct 41 for the pre-sintering furnace that conveys waste heat from the air quenching cooler 3 to the pre-sintering furnace 22. In the pre-burning furnace 22, the cement raw materials and the mixture output from the pre-heater 21 are pre-burned in an environment of about 900°C. In this embodiment, the temperature of the exhaust gas flowing into the first duct D1 is approximately 900°C, the temperature of the exhaust gas flowing into the second duct D2 is approximately 850°C, and the temperature of the exhaust gas flowing into the third duct D3 is approximately The temperature of the exhaust gas flowing into the fourth duct D4 is about 600°C, the temperature of the exhaust gas flowing into the fifth duct D5 is about 450°C, the exhaust gas output from the cyclone C5 to the exhaust gas line 9 of the burning device The temperature is about 310°C. However, the temperature of the exhaust gas flowing into each duct D is only an example.

返回至圖1,本實施型態中,燒成爐23係採用橫長之圓筒型之旋轉窯亦即旋窯。燒成爐23係形成自原料入口朝向原料出口而稍微降低之梯度來設置。燒成爐23於原料出口側具備燃燒器26。燒成爐23中,對於預熱器21及預燒爐22中經預熱・預燒之水泥原料,利用空氣淬火冷卻器3之廢熱及燃燒器26之燃燒氣體來進行燒成。Returning to Fig. 1, in this embodiment, the firing furnace 23 adopts a horizontally long cylindrical rotary kiln, that is, a rotary kiln. The firing furnace 23 is installed with a gradient slightly lowered from the raw material inlet to the raw material outlet. The firing furnace 23 includes a burner 26 on the raw material outlet side. In the firing furnace 23, the preheated and calcined cement raw materials in the preheater 21 and the calciner 22 are fired using the waste heat of the air quenching cooler 3 and the combustion gas of the burner 26.

燒成爐23之出口與空氣淬火冷卻器3之入口連接。空氣淬火冷卻器3中,使自燒成爐23中輸出之高溫之燒成物與冷風接觸,使燒成物驟冷而成為熟料。自空氣淬火冷卻器3中輸出之熟料由熟料輸送機32向熟料儲倉中輸送。The outlet of the firing furnace 23 is connected to the inlet of the air quenching cooler 3. In the air quenching cooler 3, the high-temperature fired product output from the firing furnace 23 is brought into contact with cold air, and the fired product is quenched to become clinker. The clinker output from the air quenching cooler 3 is transported to the clinker storage bin by the clinker conveyor 32.

於空氣淬火冷卻器3,連接有流出空氣淬火冷卻器3之廢熱之冷卻器廢熱線4。冷卻器廢熱線4包括:上述預燒爐用抽氣導管41、自空氣淬火冷卻器3中抽氣之高溫廢熱線42、以及自空氣淬火冷卻器3中抽出低於約200℃之廢熱的低溫廢熱線43。The air quenching cooler 3 is connected with a cooler waste heat line 4 that flows out of the waste heat of the air quenching cooler 3. The cooler waste heat line 4 includes: the exhaust duct 41 for the above-mentioned pre-combustion furnace, the high temperature waste heat line 42 that draws air from the air quenching cooler 3, and the low temperature that draws waste heat below about 200°C from the air quenching cooler 3 Waste hotline 43.

高溫廢熱線42連接於鍋爐45。通過高溫廢熱線42,空氣淬火冷卻器3之廢氣向鍋爐45輸送。The high-temperature waste heat line 42 is connected to the boiler 45. Through the high temperature waste heat line 42, the exhaust gas of the air quenching cooler 3 is sent to the boiler 45.

低溫廢熱線43中,集塵機46、排風扇47及煙囪48自廢氣之流動之上游朝向下游依序設置。本實施型態中,於低溫廢熱線43之較集塵機46更上游側連接有鍋爐45之廢氣線45a。In the low-temperature waste heat line 43, the dust collector 46, the exhaust fan 47 and the chimney 48 are arranged in sequence from the upstream of the flow of the exhaust gas to the downstream. In this embodiment, the exhaust gas line 45a of the boiler 45 is connected to the lower-temperature waste heat line 43 on the upstream side of the dust collector 46.

水泥製造系統100進一步具備:將脫水汙泥與水泥原料混合來製成粒狀之混成物之混合裝置5、藉由使混成物與乾燥用氣體接觸來使混成物乾燥之乾燥機6、將乾燥機6之廢氣向空氣淬火冷卻器3輸送之乾燥機廢氣線7、自乾燥機6向水泥燒成裝置2之預熱器21輸送經乾燥混成物之混成物供給線8、以及向乾燥機6供給乾燥用氣體之乾燥用氣體供給線61。The cement manufacturing system 100 further includes: a mixing device 5 for mixing dewatered sludge and cement raw materials to form a granular mixture, a dryer 6 for drying the mixture by contacting the mixture with a drying gas, and drying The exhaust gas line of the dryer 6 is conveyed to the air quenching cooler 3, the exhaust gas line 7 of the dryer is conveyed from the dryer 6 to the preheater 21 of the cement burning device 2, and the mixture supply line 8 of the dried mixture is conveyed to the dryer 6 A drying gas supply line 61 for supplying drying gas.

混合裝置5包括:水泥原料料斗51、脫水汙泥料斗52、以及將水泥原料與脫水汙泥一面混合一面送出之混合機53。The mixing device 5 includes a cement raw material hopper 51, a dewatered sludge hopper 52, and a mixer 53 that mixes and sends out the cement raw material and the dewatered sludge.

水泥原料料斗51中,投入於原料步驟中經乾燥・粉碎・調合之水泥原料。該水泥原料可與向預熱器21之水泥原料供給口28供給之水泥原料相同。水泥原料係使用以石灰石為主成分之公知原料,並無特別限制。若具體例示水泥原料,則通常以石灰石為主,於其中調配黏土、矽石、氧化鐵等來使用。作為一例,水泥原料之化學組成包含:12~15質量%之SiO2 、3~4質量%之Al2 O3 、1.5~2.5質量%之Fe2 O3 、43~44質量%之CaO、0.6~0.9質量%之MgO、35~37質量%之揮發成份、以及0~1質量%(剩餘部分)之其他材料。The cement raw material hopper 51 is charged with the cement raw material dried, crushed, and blended in the raw material step. The cement raw material may be the same as the cement raw material supplied to the cement raw material supply port 28 of the preheater 21. The cement raw material is a well-known raw material mainly composed of limestone, and is not particularly limited. If cement raw materials are specifically exemplified, limestone is usually the main material, and clay, silica, iron oxide, etc. are blended and used. As an example, the chemical composition of cement raw materials includes: 12-15% by mass of SiO 2 , 3-4% by mass of Al 2 O 3 , 1.5-2.5% by mass of Fe 2 O 3 , 43-44% by mass of CaO, 0.6 ~0.9% by mass of MgO, 35 to 37% by mass of volatile components, and 0 to 1% by mass (the remainder) of other materials.

於脫水汙泥料斗52中,投入脫水汙泥。脫水汙泥係對下水汙泥、工廠廢水汙泥、活性汙泥等汙泥,利用未圖示之脫水機進行脫水而殘留之固形物質(脫水泥餅)。通常作為脫水泥餅來進行處理之脫水汙泥包含60~90質量%之水分。In the dewatered sludge hopper 52, the dewatered sludge is put in. Dewatered sludge is the residual solid matter (de-cemented cake) of sewage sludge, factory wastewater sludge, activated sludge and other sludge that is dewatered by a dehydrator (not shown). The dehydrated sludge that is usually treated as a dehydrated cake contains 60 to 90% by mass of moisture.

水泥原料料斗51之出口透過水泥原料調節裝置55與混合機53之入口連接。利用水泥原料調節裝置55,對自水泥原料料斗51向混合機53輸送之水泥原料進行調節。又,脫水汙泥料斗52之出口透過汙泥調節裝置56與混合機53之入口連接。利用汙泥調節裝置56,對自脫水汙泥料斗52向混合機53輸送之脫水汙泥進行調節。混合機53中之脫水汙泥與水泥原料之混合比係脫水汙泥與水泥原料混合而成之混成物成為粒狀之情形下的脫水汙泥與水泥原料之質量比或體積比。The outlet of the cement raw material hopper 51 is connected to the inlet of the mixer 53 through the cement raw material adjusting device 55. The cement raw material adjusting device 55 adjusts the cement raw material conveyed from the cement raw material hopper 51 to the mixer 53. In addition, the outlet of the dewatered sludge hopper 52 is connected to the inlet of the mixer 53 through the sludge adjusting device 56. The sludge adjusting device 56 adjusts the dewatered sludge conveyed from the dewatered sludge hopper 52 to the mixer 53. The mixing ratio of the dewatered sludge to the cement raw material in the mixer 53 is the mass ratio or volume ratio of the dewatered sludge to the cement raw material when the mixture of the dewatered sludge and the cement raw material becomes granular.

當脫水汙泥與水泥原料之混合比於特定之範圍內時,脫水汙泥與水泥原料之混成物不經過粒化處理而成為粒狀。脫水汙泥與水泥原料之混合比並不固定,根據脫水汙泥之性狀(尤其是外在水分量或有機物之比例)、或水泥原料之性狀(尤其是內在水分量或組成)而變化。因此,脫水汙泥與水泥原料之混合比理想為每次根據脫水汙泥及水泥原料之性狀之變化之程度來設定。脫水汙泥與水泥原料之混合比之範圍例如可藉由試驗來求出。When the mixing ratio of dewatered sludge and cement raw materials is within a specific range, the mixture of dewatered sludge and cement raw materials will become granular without undergoing granulation treatment. The mixing ratio of dewatered sludge and cement raw materials is not fixed, and varies according to the properties of the dehydrated sludge (especially the proportion of external moisture or organic matter) or the properties of the cement raw materials (especially the internal moisture or composition). Therefore, the mixing ratio of dewatered sludge and cement raw materials is ideally set according to the degree of change in the properties of dewatered sludge and cement raw materials each time. The range of the mixing ratio of the dewatered sludge and the cement raw material can be determined by experiments, for example.

本實施型態中,由於採用流動層式乾燥機作為乾燥機6,故而脫水汙泥與水泥原料之混合比理想為設為混成物作為流動介質而成為適當之粒狀之值。具體而言,脫水汙泥與水泥原料之混合比係以混成物之總水分成為10質量%以上、25質量%以下,理想為13質量%以上、22質量%以下之方式,試驗性地求出並預先於控制裝置57進行設定。控制裝置57係以獲得上述脫水汙泥與水泥原料之混合比之方式,控制水泥原料調節裝置55及汙泥調節裝置56。混成物之總水分係混成物之表面附著水分亦即外在水分、與混成物之吸附水分亦即內在水分之和。混成物之總水分之測定係根據「JIS M 8812煤炭類及焦炭類-工業分析方法」中所規定之水分定量方法之煤炭類之情形來進行。In this embodiment, since a fluidized bed dryer is used as the dryer 6, the mixing ratio of the dewatered sludge and the cement raw material is desirably set as the mixture as the fluid medium to have an appropriate granular value. Specifically, the mixing ratio of dewatered sludge and cement raw materials is experimentally determined so that the total moisture content of the mixture is 10% by mass or more and 25% by mass or less, ideally 13% by mass or more and 22% by mass or less. And set in the control device 57 in advance. The control device 57 controls the cement raw material regulating device 55 and the sludge regulating device 56 to obtain the mixing ratio of the dewatered sludge and the cement raw material. The total moisture of the mixture is the sum of the attached moisture on the surface of the mixture, that is, the external moisture, and the adsorbed moisture of the mixture, that is, the internal moisture. The total moisture content of the mixture is measured in accordance with the case of coal based on the moisture quantitative method specified in "JIS M 8812 Coal and Coke-Industrial Analysis Method".

根據發明者們之試驗,若混成物之總水分為10質量%以上、25質量%以下,則確認能夠獲得混成物之粒度分佈小(即,粒徑之不均程度小),且平均粒徑為適合作為流動介質之大小的粒狀之混成物。According to the experiments of the inventors, if the total moisture content of the mixture is 10% by mass or more and 25% by mass or less, it is confirmed that the particle size distribution of the mixture is small (that is, the degree of unevenness in particle size is small), and the average particle size It is a granular mixture of the size suitable as a fluid medium.

上述中所謂「適合作為流動介質之大小」係可於層內均勻流動之粒子之直徑,係指數μm至5 mm左右之範圍。發明者們之試驗結果中,總水分為10質量%以上、25質量%以下之範圍之混成物之平均粒徑(中值粒徑d50)為0.5 mm以上、5 mm以下,係適合作為流動介質之大小。The "size suitable as a flow medium" in the above refers to the diameter of particles that can flow uniformly in the layer, and the index ranges from μm to about 5 mm. In the test results of the inventors, the average particle diameter (median particle diameter d50) of the mixture with a total water content of 10% by mass or more and 25% by mass or less is 0.5 mm or more and 5 mm or less, which is suitable as a fluid medium The size.

藉由利用混合機53將脫水汙泥與水泥原料混合而製作之混成物係向乾燥機6中供給。乾燥機6中,形成將混成物作為流動介質,且將乾燥用氣體作為流動用氣體之流動層。該乾燥機6,對形成於乾燥室之底部之混成物層內供給乾燥用氣體,藉由於混成物層中乾燥用氣體上升而混成物與乾燥用氣體接觸來乾燥混成物。如此,與其他形式之乾燥機相比乾燥效率較高(即,體積熱交換率大)之流動層式乾燥機用作乾燥機6。但,乾燥機6並不限定於流動層式乾燥機。The mixture system produced by mixing the dewatered sludge and the cement raw material by the mixer 53 is supplied to the dryer 6. In the dryer 6, a fluidized bed is formed in which the mixture is used as the fluid medium and the drying gas is used as the fluidized gas. The dryer 6 supplies a drying gas into the mixed material layer formed at the bottom of the drying chamber, and the mixed material is brought into contact with the drying gas due to the rising of the drying gas in the mixed material layer to dry the mixed material. In this way, a fluidized bed dryer with higher drying efficiency (that is, a larger volumetric heat exchange rate) compared with other types of dryers is used as the dryer 6. However, the dryer 6 is not limited to a fluidized bed dryer.

乾燥用氣體通過乾燥用氣體供給線61向乾燥機6中輸送。向乾燥機6中供給之乾燥用氣體之風量(風速)以可以獲得乾燥機6之流動層之適當之流動化狀態之方式,根據混成物之性狀(即,粒徑、水分、密度等),利用擋板或風扇等來調整。本實施型態中,作為乾燥用氣體,係利用水泥製造程序之廢氣或其熱之程序之廢氣,利用50℃以上且低於200℃之廢氣。此種廢氣中,例如提出有:空氣淬火冷卻器3之低於200℃之廢氣、利用空氣淬火冷卻器3之廢氣之鍋爐45的低於200℃之廢氣、利用來自水泥燒成裝置2之廢氣之原料粉碎機93的低於200℃之廢氣等。The drying gas is sent to the dryer 6 through the drying gas supply line 61. The air volume (wind speed) of the drying gas supplied to the dryer 6 is such that the proper fluidization state of the fluidized bed of the dryer 6 can be obtained, and according to the properties of the mixture (ie, particle size, moisture, density, etc.), Use baffle or fan to adjust. In this embodiment, as the drying gas, waste gas from the cement manufacturing process or heat from the process is used, and waste gas above 50°C and lower than 200°C is used. Among such exhaust gases, for example, the exhaust gas below 200°C from the air quenching cooler 3, the exhaust gas below 200°C from the boiler 45 using the exhaust gas of the air quenching cooler 3, and the exhaust gas from the cement burning device 2 are proposed. The waste gas of the raw material crusher 93 below 200°C, etc.

利用乾燥機6進行乾燥之混成物自乾燥室之底部排出,通過混成物供給線8向預燒爐22中供給。向預燒爐22中供給之混成物並無特別限定,含水率可為2~5質量%左右,溫度可為60~100℃左右。混成物供給線8包括:自乾燥機6中搬出經乾燥之混成物的搬送機81、82;將混成物暫時貯藏之混成物料斗83;以及對自混成物料斗83中定量排出之混成物進行搬送之搬送線84。利用混成物供給線8供給至預燒爐22中之混成物用作燃料之一部分,進而,混成物之燃燒灰用作水泥原料之一部分。The mixture dried by the dryer 6 is discharged from the bottom of the drying chamber, and is supplied to the calciner 22 through the mixture supply line 8. The mixture supplied to the pre-sintering furnace 22 is not particularly limited, and the moisture content may be about 2 to 5 mass%, and the temperature may be about 60 to 100°C. The mixture supply line 8 includes: conveyors 81 and 82 for carrying out the dried mixture from the dryer 6; a mixture hopper 83 for temporarily storing the mixture; and a quantitative discharge of the mixture from the mixture hopper 83 Transport line 84 of transport. The mixture supplied to the pre-sintering furnace 22 by the mixture supply line 8 is used as a part of the fuel, and further, the combustion ash of the mixture is used as a part of the cement raw material.

乾燥機6之廢氣通過乾燥機廢氣線7向空氣淬火冷卻器3中供給。於乾燥機廢氣線7,集塵機71、排風扇72及送風扇74自乾燥機廢氣之流動之上游朝向下游依序設置。藉由排風扇72自乾燥機6中排出之乾燥機廢氣利用集塵機71來去除相伴之粉塵。所去除之粉塵自集塵機71向混成物料斗83輸送,與貯藏於混成物料斗83中之混成物一併向預燒爐22供給。通過集塵機71之乾燥機廢氣藉由送風扇74向空氣淬火冷卻器3中供給。The exhaust gas of the dryer 6 is supplied to the air quenching cooler 3 through the exhaust gas line 7 of the dryer. In the dryer exhaust gas line 7, the dust collector 71, the exhaust fan 72 and the blowing fan 74 are arranged in sequence from the upstream of the flow of the dryer exhaust gas to the downstream. The exhaust gas of the dryer discharged from the dryer 6 by the exhaust fan 72 is used by the dust collector 71 to remove the accompanying dust. The removed dust is transported from the dust collector 71 to the mixed material hopper 83 and supplied to the pre-burning furnace 22 together with the mixed material stored in the mixed material hopper 83. The dryer exhaust gas passing through the dust collector 71 is supplied to the air quenching cooler 3 by the blower fan 74.

如以上所說明,本實施型態之水泥製造系統100具備:對水泥原料進行預熱之預熱器21、對經預熱之水泥原料進行預燒之預燒爐22、以及對經預燒之水泥原料進行燒成之燒成爐23;預熱器21具有對600℃以上且低於800℃之溫度區域投入包含乾燥汙泥之粒狀物的至少1個投入口29。As explained above, the cement manufacturing system 100 of this embodiment includes: a preheater 21 for preheating cement raw materials, a preburning furnace 22 for preburning the preheated cement raw materials, and a The sintering furnace 23 for sintering cement raw materials; the preheater 21 has at least one input port 29 for inputting granular materials containing dried sludge into a temperature range of 600°C or higher and lower than 800°C.

又,本實施型態之汙泥之處理方法係利用水泥製造系統100來處理汙泥之方法,上述水泥製造系統100具備:對水泥原料進行預熱之預熱器21、對經預熱之水泥原料進行預燒之預燒爐22、以及對經預燒之水泥原料進行燒成之燒成爐23;並且將包含乾燥汙泥之粒狀物投入至預熱器21之600℃以上且低於800℃之溫度區域中,將乾燥汙泥用作水泥原料及燃料。In addition, the sludge treatment method of this embodiment is a method of using the cement manufacturing system 100 to process sludge. The cement manufacturing system 100 is provided with a preheater 21 for preheating the cement raw materials, and a preheater for the preheated cement. The pre-burning furnace 22 for pre-burning raw materials and the burning furnace 23 for burning the pre-burned cement raw materials; and the granular material containing dry sludge is put into the preheater 21 at a temperature above 600°C and below In the temperature range of 800°C, dry sludge is used as cement raw material and fuel.

本實施型態中,上述「包含乾燥汙泥之粒狀物」係乾燥汙泥與水泥原料之混成物。因此,本實施型態之水泥製造系統100進一步具備:將脫水汙泥與水泥原料混合而獲得粒狀之混成物的混合裝置5、對混成物進行乾燥之乾燥機6、將經乾燥機6所乾燥之混成物作為粒狀物而向投入口29搬送之搬送線84。In this embodiment, the above-mentioned "granular matter containing dried sludge" is a mixture of dried sludge and cement raw materials. Therefore, the cement manufacturing system 100 of this embodiment further includes: a mixing device 5 for mixing dewatered sludge and cement raw materials to obtain a granular mixture, a dryer 6 for drying the mixture, and a drying machine 6 The conveying line 84 for conveying the dried mixture to the input port 29 as a granular substance.

但,包含乾燥汙泥之粒狀物並不限定於乾燥汙泥與水泥原料之混成物。例如,包含乾燥汙泥之粒狀物亦可為乾燥汙泥之粉碎物、或者生汙泥與乾燥汙泥之混成物等。又,粒狀物之尺寸只要為可利用來自預燒爐22之廢氣來進行氣流搬送之大小即可,亦可為粉狀、片狀或團塊狀。However, the particulate matter containing dry sludge is not limited to a mixture of dry sludge and cement raw materials. For example, the granular material containing dried sludge may be a crushed product of dried sludge, or a mixture of raw sludge and dried sludge. In addition, the size of the granular material may be such that the exhaust gas from the pre-burning furnace 22 can be used for air flow conveyance, and it may be in the form of powder, flakes, or agglomerates.

上述汙泥之處理方法及水泥製造系統100中,包含乾燥汙泥之粒狀物投入至預熱器21之600℃以上且低於800℃之溫度區域中。該粒狀物於自預熱器21中之投入口29(投入位置)移動至預燒爐22之期間,與水泥原料一併升溫至預燒爐22中之投入溫度(約850℃~900℃)。In the above-mentioned sludge processing method and cement manufacturing system 100, granular materials including dry sludge are fed into the temperature range of 600°C or higher and lower than 800°C of the preheater 21. During the movement of the granular material from the input port 29 (input position) in the preheater 21 to the pre-sintering furnace 22, it is heated together with the cement raw materials to the input temperature of the pre-sintering furnace 22 (approximately 850°C to 900°C). ).

與如專利文獻1、2所述投入至800℃以上之區域之習知情形相比,本案發明中,粒狀物於預熱器21中之滯留時間長,充分預熱後才投入至預燒爐22中。因此,可抑制由向預燒爐22投入低溫物而引起的燃燒狀態之擾亂或燃料消耗量之增加。又,與上述習知情形相比,預熱器21中之投入口29(投入位置)之環境溫度與粒狀物之溫度差小。因此,可抑制粒狀物之投入口29附近之局部之溫度下降,可抑制耐火被覆之壽命之下降或被膜之發生。其結果為,於將汙泥用作水泥原料之一部分及燃料之水泥製造系統100中,可有助於系統之運轉之穩定化。Compared with the conventional case of putting into the area above 800°C as described in Patent Documents 1 and 2, in the present invention, the granular material stays in the preheater 21 for a long time, and is put into the pre-sintering furnace after sufficient preheating 22 in. Therefore, it is possible to suppress the disturbance of the combustion state or the increase in fuel consumption caused by the introduction of low-temperature substances into the pre-burning furnace 22. Moreover, compared with the above-mentioned conventional case, the temperature difference between the ambient temperature of the input port 29 (input position) in the preheater 21 and the granular material is small. Therefore, the temperature drop in the vicinity of the granular material input port 29 can be suppressed, and the life span of the refractory coating can be suppressed or the generation of the coating can be suppressed. As a result, in the cement manufacturing system 100 that uses sludge as a part of the cement raw material and fuel, it can contribute to the stabilization of the operation of the system.

本實施型態之水泥製造系統100中,預熱器21具備自預燒爐22朝向上方串聯地連接之3段以上之旋風器單元U1~U5。旋風器單元U1~U5分別具有:旋風器C1~C5、向旋風器C1~C5中導入氣流之導管D1~D5、以及配管B1~B5,該配管B1~B5將利用旋風器C1~C5自氣流中分離之固體,向較其更下段之旋風器單元U1~U4之導管D1~D4、預燒爐22及燒成爐23中之至少一者輸送。In the cement manufacturing system 100 of the present embodiment, the preheater 21 includes three or more cyclone units U1 to U5 connected in series from the pre-sintering furnace 22 upward. The cyclone units U1~U5 respectively have: cyclones C1~C5, ducts D1~D5 for introducing airflow into the cyclones C1~C5, and pipes B1~B5. The pipes B1~B5 will use the cyclones C1~C5 to flow from the air. The solid separated in the middle is transported to at least one of the ducts D1 to D4 of the cyclone unit U1 to U4, the pre-sintering furnace 22 and the firing furnace 23 at the lower stage.

就延長於預熱器21中之滯留時間之觀點而言,投入口29理想為設置於預熱器21之600℃以上之溫度區域中的更上段之旋風器單元U之導管D。因此,本實施型態中,於自下方起第三段之旋風器單元U3之導管D3之流入口附近設置有投入口29。此外,雖然流入至自下方起第二段之旋風器單元U2之導管D2中之廢氣之溫度約為850℃,但其後溫度即刻下降而成為低於800℃,因此亦可於導管D2設置投入口29。如此,本實施型態之水泥製造系統100中,可於自下方起第二段及第三段之旋風器單元U2、U3之導管D2、D3中之至少一者設置投入口29。換言之,可對自下方起第二段及第三段之旋風器單元U2、U3之導管D2、D3中之至少一者投入粒狀物。但,投入口29之位置可依每個水泥製造系統100之預熱器21進行適當調整。From the viewpoint of extending the residence time in the preheater 21, the input port 29 is ideally provided in the duct D of the cyclone unit U at the upper stage in the temperature region of 600°C or higher of the preheater 21. Therefore, in this embodiment, an inlet 29 is provided near the inlet of the duct D3 of the cyclone unit U3 at the third stage from below. In addition, although the temperature of the exhaust gas flowing into the duct D2 of the cyclone unit U2 at the second stage from the bottom is about 850°C, the temperature drops immediately afterwards to be lower than 800°C, so it can also be installed in the duct D2.口29. In this way, in the cement manufacturing system 100 of this embodiment, at least one of the ducts D2 and D3 of the second and third stages of the cyclone unit U2 and U3 from below can be provided with an input port 29. In other words, granular materials can be injected into at least one of the ducts D2 and D3 of the cyclone units U2 and U3 in the second and third stages from below. However, the position of the input port 29 can be adjusted appropriately according to the preheater 21 of each cement manufacturing system 100.

若包含乾燥汙泥之粒狀物投入至預熱器21之低於600℃之溫度區域,自粒狀物所含之汙泥中產生之臭氣未藉由熱而分解而向燒成裝置廢氣線9中排出。因此,燒成裝置廢氣線9中需要用以將臭氣分解之裝置。又,預熱器21之800℃以上之溫度區域即大致特定為將預燒爐22與最下段之旋風器C1連接之第1導管D1。若包含乾燥汙泥之粒狀物投入至預熱器21之第1導管D1中,則粒狀物僅通過預熱器21中之第1旋風器單元U1,因此存在未充分升溫之虞,難以抑制粒狀物之投入口29附近中之局部之溫度下降。If the granular material containing dry sludge is fed into the temperature region of the preheater 21 below 600°C, the odor generated from the sludge contained in the granular material is not decomposed by heat and is transferred to the waste gas of the burning device. Line 9 is discharged. Therefore, a device for decomposing odors is required in the exhaust gas line 9 of the burning device. In addition, the temperature range of 800°C or higher of the preheater 21 is roughly specified as the first duct D1 that connects the calciner 22 and the cyclone C1 at the lowermost stage. If the granular material containing dry sludge is put into the first duct D1 of the preheater 21, the granular material only passes through the first cyclone unit U1 in the preheater 21, so there is a risk of insufficient temperature rise, making it difficult The temperature drop in the vicinity of the granular material input port 29 is suppressed.

以上已對本發明之較佳實施型態進行說明,但於不脫離本發明之思想之範圍內,對上述實施型態之具體結構及/或功能之細節加以變更者亦包含於本發明中。The preferred embodiments of the present invention have been described above, but within the scope of the idea of the present invention, changes to the specific structure and/or function details of the above embodiments are also included in the present invention.

2:水泥燒成裝置 3:空氣淬火冷卻器 4:冷卻器廢熱線 5:混合裝置 6:乾燥機 7:乾燥機廢氣線 8:混成物供給線 9:燒成裝置廢氣線 21:懸浮預熱器 22:預燒爐 23:燒成爐 25:預燒爐燃燒器 26:燃燒器 28:水泥原料供給口 29:投入口 32:熟料輸送機 41:預燒爐用抽氣導管 42:高溫廢熱線 43:低溫廢熱線 45:鍋爐 45a:廢氣線 46:集塵機 47:排風扇 48:煙囪 51:水泥原料料斗 52:脫水汙泥料斗 53:混合機 55:水泥原料調節裝置 56:汙泥調節裝置 57:控制裝置 61:乾燥用氣體供給線 71:集塵機 72:排風扇 74:送風扇 81:搬送機 82:搬送機 83:混成物料斗 84:搬送線 91:鍋爐 92:排風扇 93:原料粉碎機 94:集塵機 95:排風扇 96:煙囪 100:水泥製造系統 B、B1~B5:配管 C、C1~C5:旋風器 D、D1~D5:導管 U、U1~U5:旋風器單元2: Cement burning device 3: Air quenching cooler 4: Cooler waste heat line 5: Mixing device 6: Dryer 7: Dryer exhaust line 8: Mixture supply line 9: Exhaust gas line of burning device 21: Suspended preheater 22: pre-burning furnace 23: Firing furnace 25: Burn-in furnace burner 26: Burner 28: Cement raw material supply port 29: Put in the mouth 32: Clinker conveyor 41: Exhaust duct for pre-burning furnace 42: High temperature waste hotline 43: Low temperature waste hotline 45: boiler 45a: exhaust line 46: Dust Collector 47: Exhaust fan 48: Chimney 51: Cement raw material hopper 52: Dewatered sludge hopper 53: Mixer 55: Cement raw material regulator 56: Sludge adjustment device 57: control device 61: Gas supply line for drying 71: Dust Collector 72: Exhaust fan 74: blower fan 81: Conveyor 82: Conveyor 83: Mixed material hopper 84: transfer line 91: boiler 92: exhaust fan 93: Raw material crusher 94: Dust Collector 95: exhaust fan 96: Chimney 100: Cement manufacturing system B, B1~B5: Piping C, C1~C5: Cyclone D, D1~D5: Catheter U, U1~U5: Cyclone unit

[圖1]係表示本發明之實施型態之水泥製造系統之系統性的概略構成圖。 [圖2]係表示懸浮預熱器之概略構成的方塊圖。[Fig. 1] is a schematic structural diagram showing the systemic structure of the cement manufacturing system of the embodiment of the present invention. [Figure 2] is a block diagram showing the schematic configuration of the suspension preheater.

8:混成物供給線 8: Mixture supply line

9:燒成裝置廢氣線 9: Exhaust gas line of burning device

21:懸浮預熱器 21: Suspended preheater

22:預燒爐 22: pre-burning furnace

23:燒成爐 23: Firing furnace

25:預燒爐燃燒器 25: Burn-in furnace burner

28:水泥原料供給口 28: Cement raw material supply port

29:投入口 29: Put in the mouth

41:預燒爐用抽氣導管 41: Exhaust duct for pre-burning furnace

84:搬送線 84: transfer line

B1~B5:配管 B1~B5: Piping

C1~C5:旋風器 C1~C5: Cyclone

D1~D5:導管 D1~D5: Catheter

U1~U5:旋風器單元 U1~U5: Cyclone unit

Claims (6)

一種汙泥之處理方法,利用水泥製造系統來處理汙泥,上述水泥製造系統具備:對水泥原料進行預熱之懸浮預熱器、對經預熱之上述水泥原料進行預燒之預燒爐、以及對經預燒之上述水泥原料進行燒成之燒成爐;並且 將包含乾燥汙泥之粒狀物投入至上述懸浮預熱器之600℃以上且低於800℃之溫度區域中,將上述乾燥汙泥用作水泥原料及燃料。A method for treating sludge, using a cement manufacturing system to process sludge. The cement manufacturing system is equipped with: a suspension preheater for preheating cement raw materials, a preburning furnace for preheating the preheated cement raw materials, And a firing furnace for firing the above-mentioned pre-fired cement raw materials; and The granular material containing dried sludge is put into the temperature range of 600°C or higher and lower than 800°C of the above-mentioned suspension preheater, and the above-mentioned dried sludge is used as a cement raw material and fuel. 如請求項1之汙泥之處理方法,其中 上述懸浮預熱器具備自上述預燒爐朝向上方串聯地連接之3段以上之旋風器單元; 上述旋風器單元分別具有:旋風器、向上述旋風器中導入氣流之導管、以及配管,上述配管將利用上述旋風器自上述氣流中分離之固體,向較其更下段之上述旋風器單元之上述導管、上述預燒爐及上述燒成爐中之至少一者輸送;並且 對自下方起第二段及第三段之上述旋風器單元之上述導管中之至少一者投入上述粒狀物。Such as the treatment method of sludge in claim 1, where The above-mentioned suspension preheater is provided with three or more stages of cyclone units connected in series from the above-mentioned pre-burning furnace toward the upper side; The cyclone unit has a cyclone, a duct for introducing airflow into the cyclone, and a pipe. The pipe will use the cyclone to separate solids from the airflow to the cyclone unit lower than the solid. At least one of the catheter, the above-mentioned pre-sintering furnace and the above-mentioned firing furnace is transported; and Put the granular substance into at least one of the ducts of the cyclone unit in the second and third stages from below. 如請求項1或2之汙泥之處理方法,其中 上述粒狀物為上述乾燥汙泥與上述水泥原料之混成物。Such as the sludge treatment method of claim 1 or 2, where The granular material is a mixture of the dried sludge and the cement raw material. 一種水泥製造系統,具備:對水泥原料進行預熱之懸浮預熱器、對經預熱之上述水泥原料進行預燒之預燒爐、以及對經預燒之上述水泥原料進行燒成之燒成爐;並且 上述懸浮預熱器具有對600℃以上且低於800℃之溫度區域投入包含乾燥汙泥之粒狀物的至少1個投入口。A cement manufacturing system comprising: a suspension preheater for preheating cement raw materials, a pre-sintering furnace for pre-burning the above-mentioned pre-heated cement raw materials, and a firing for firing the pre-fired above-mentioned cement raw materials Furnace; and The above-mentioned suspension preheater has at least one input port for inputting granular materials including dried sludge into a temperature range of 600°C or higher and lower than 800°C. 如請求項4之水泥製造系統,其中 上述懸浮預熱器具備自上述預燒爐朝向上方串聯地連接之3段以上之旋風器單元; 上述旋風器單元分別具有:旋風器、向上述旋風器中導入氣流之導管、以及配管,上述配管將利用上述旋風器自上述氣流中分離之固體,向較其更下段之上述旋風器單元之上述導管、上述預燒爐及上述燒成爐中之至少一者輸送;並且 於自下方起第二段及第三段之上述旋風器單元之上述導管中之至少一者設置有上述投入口。Such as the cement manufacturing system of claim 4, where The above-mentioned suspension preheater is provided with three or more stages of cyclone units connected in series from the above-mentioned pre-burning furnace toward the upper side; The cyclone unit has a cyclone, a duct for introducing airflow into the cyclone, and a pipe. The pipe will use the cyclone to separate solids from the airflow to the cyclone unit lower than the solid. At least one of the catheter, the above-mentioned pre-sintering furnace and the above-mentioned firing furnace is transported; and At least one of the above-mentioned ducts of the above-mentioned cyclone unit in the second and third sections from below is provided with the above-mentioned input port. 如請求項4或5之水泥製造系統,其進一步具備: 混合裝置,將脫水汙泥與水泥原料混合而獲得粒狀之混成物; 乾燥機,對上述混成物進行乾燥;以及 搬送線,將經上述乾燥機所乾燥之上述混成物作為上述粒狀物而向上述投入口搬送。Such as the cement manufacturing system of claim 4 or 5, which further has: Mixing device to mix dewatered sludge with cement raw materials to obtain a granular mixture; A dryer to dry the above-mentioned mixture; and The conveying line conveys the mixture dried by the dryer as the granular material to the input port.
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