TW202004282A - Liquid crystal panel and liquid crystal display device - Google Patents

Liquid crystal panel and liquid crystal display device Download PDF

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TW202004282A
TW202004282A TW108120227A TW108120227A TW202004282A TW 202004282 A TW202004282 A TW 202004282A TW 108120227 A TW108120227 A TW 108120227A TW 108120227 A TW108120227 A TW 108120227A TW 202004282 A TW202004282 A TW 202004282A
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liquid crystal
polarizer
anisotropic element
retardation
wavelength
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TW108120227A
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TWI801602B (en
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林大輔
有賀草平
飯田敏行
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日商日東電工股份有限公司
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133528Polarisers
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/13363Birefringent elements, e.g. for optical compensation

Abstract

A liquid crystal panel (101) is provided with a liquid crystal cell (20), a first polarizer (30), a second polarizer (40), and an optically anisotropic element (50). The liquid crystal cell is provided with a liquid crystal layer including liquid crystal molecules in a homogeneous alignment in the absence of an electric field, and a color filter (22) disposed on a first principal surface of the liquid crystal layer. The slow-axis direction (53) of the optically anisotropic element (50) and the absorption axis direction (45) of the second polarizer are parallel. The thickness-direction retardation of the optically anisotropic element and the thickness-direction retardation of the color filter of the liquid crystal cell satisfy a predetermined relationship for each of a wavelength of 550 nm and a wavelength of 650 nm.

Description

液晶面板及液晶顯示裝置Liquid crystal panel and liquid crystal display device

本發明係關於一種於液晶單元與偏光件之間具備光學各向異性元件之液晶面板。又,本發明係關於一種使用有上述液晶面板之液晶顯示裝置。The invention relates to a liquid crystal panel provided with an optically anisotropic element between a liquid crystal cell and a polarizer. Furthermore, the present invention relates to a liquid crystal display device using the above liquid crystal panel.

液晶面板於一對偏光件之間具備液晶單元。液晶單元於一對基板間具備液晶層,於一般的液晶單元中,於配置於液晶層之視認側之基板(彩色濾光片基板)設置有彩色濾光片,於配置於光源側之基板(TFT(thin-film transistor,薄膜電晶體)基板)設置有像素電極、及TFT元件等。The liquid crystal panel includes a liquid crystal cell between a pair of polarizers. The liquid crystal cell is provided with a liquid crystal layer between a pair of substrates. In a general liquid crystal cell, a color filter is provided on a substrate (color filter substrate) arranged on the viewing side of the liquid crystal layer, and a substrate arranged on the light source side ( A TFT (thin-film transistor, thin film transistor) substrate) is provided with pixel electrodes, TFT elements, and the like.

橫向電場效應(IPS,In-Plane Switching)方式之液晶單元中,於無電場狀態下,液晶分子於與基板面大致平行之方向平行配向,藉由橫方向之電場施加使液晶分子於與基板面平行之面內旋轉,控制光之透過(白顯示)與遮蔽(黑顯示)。如IPS方式般,於無電場狀態下液晶分子平行配向之橫向電場方式之液晶面板之視角特性優異。In the liquid crystal cell of the horizontal electric field effect (IPS, In-Plane Switching) method, in the state of no electric field, the liquid crystal molecules are aligned in a direction substantially parallel to the substrate surface, and the liquid crystal molecules are applied to the substrate surface by the application of the horizontal electric field Rotate in parallel planes to control light transmission (white display) and shadowing (black display). Like the IPS method, the liquid crystal panel in the horizontal electric field method in which liquid crystal molecules are aligned in parallel in the absence of an electric field has excellent viewing angle characteristics.

IPS方式之液晶顯示裝置根據液晶單元之無電場狀態下之液晶分子之配向方向(以下,有記載為「初始配向方向」之情形)、與配置於液晶單元之正背之偏光件之吸收軸方向之關係,大致分為O模式與E模式。於O模式下,配置於液晶單元之光源側之偏光件之吸收軸方向、與液晶之初始配向方向平行。於E模式下,配置於液晶單元之光源側之偏光件之吸收軸方向、與液晶之初始配向方向正交。The liquid crystal display device of the IPS method is based on the alignment direction of the liquid crystal molecules in the state of no electric field of the liquid crystal cell (hereinafter referred to as the "initial alignment direction"), and the absorption axis direction of the polarizer disposed on the front and back of the liquid crystal cell The relationship is roughly divided into O mode and E mode. In the O mode, the absorption axis direction of the polarizer disposed on the light source side of the liquid crystal cell is parallel to the initial alignment direction of the liquid crystal. In the E mode, the absorption axis direction of the polarizer disposed on the light source side of the liquid crystal cell is orthogonal to the initial alignment direction of the liquid crystal.

IPS方式之液晶顯示裝置於在相對於偏光件之吸收軸成45度之角度(方位角45度、135度、225度、315度)自傾斜方向視認之情形時,黑顯示之漏光較大,易產生對比度之降低或色移。該漏光係因自傾斜方向視認之情形時,配置於液晶單元之正背之偏光件之於「表觀上之吸收軸方向」所成的角度自90°偏移所致。When the IPS liquid crystal display device is viewed from an oblique direction at an angle of 45 degrees (azimuth angle 45 degrees, 135 degrees, 225 degrees, 315 degrees) with respect to the absorption axis of the polarizer, the light leakage of the black display is large, Easy to reduce the contrast or color shift. The light leakage is caused by the angle formed by the polarizer disposed on the front and back of the liquid crystal cell in the "apparent absorption axis direction" shifting from 90° when viewed from the oblique direction.

以降低自傾斜方向視認時之漏光為目的,提出於液晶單元與偏光件之間配置光學各向異性元件(相位差板)之方法。例如,專利文獻1中,提出於液晶單元與一偏光件之間,配置具有nx>nz>ny之折射率各向異性之光學各向異性元件。nx為面內遲相軸方向之折射率,ny為面內進相軸方向之折射率,nz為厚度方向(法線方向)之折射率。For the purpose of reducing light leakage when viewing from an oblique direction, a method of disposing an optically anisotropic element (retardation plate) between a liquid crystal cell and a polarizer is proposed. For example, Patent Document 1 proposes to arrange an optically anisotropic element having a refractive index anisotropy of nx>nz>ny between a liquid crystal cell and a polarizer. nx is the refractive index in the direction of the in-plane slow phase axis, ny is the refractive index in the direction of the in-plane progressive phase axis, and nz is the refractive index in the thickness direction (normal direction).

就補償偏光件之表觀上之吸收軸方向之角度偏移之觀點而言,較理想為光學各向異性元件之延遲為波長之1/2,且以Nz=(nx-nz)/(nx-ny)表示之Nz係數為0.5(參照圖5之龐加萊球)。光學各向異性元件之延遲根據波長而不同。於使用有光學各向異性元件之液晶顯示裝置之光學補償中,一般以使比視感度較高之綠色光(波長550 nm附近)之漏光變小之方式進行光學設計。因此,為了補償偏光件之表觀上之軸方向之角度偏移,使用波長550 nm之延遲為275 nm左右之光學各向異性元件即可。From the viewpoint of compensating the angular deviation of the apparent absorption axis direction of the polarizer, it is more ideal that the retardation of the optically anisotropic element is 1/2 of the wavelength, and Nz=(nx-nz)/(nx -Ny) indicates that the Nz coefficient is 0.5 (refer to Poincare sphere in FIG. 5). The retardation of the optically anisotropic element varies according to the wavelength. In the optical compensation of a liquid crystal display device using an optically anisotropic element, optical design is generally performed in such a way that leakage light of green light (wavelength near 550 nm) with higher visual sensitivity is reduced. Therefore, in order to compensate for the angular deviation of the apparent axial direction of the polarizer, it is sufficient to use an optically anisotropic element with a retardation at a wavelength of 550 nm of about 275 nm.

除偏光件之表觀上之軸方向之偏移外,其他光學元件之特性亦會成為黑顯示時之漏光之原因。例如,專利文獻2中,提出考慮於偏光件之液晶單元側之表面作為保護膜設置之三乙醯纖維素(TAC)膜之雙折射,調整用於光學補償之光學各向異性元件之光學特性。專利文獻3中,作為設置於偏光件表面之保護膜,提出使用原冰片烯系樹脂膜等低雙折射膜。 [先前技術文獻] [專利文獻]In addition to the apparent axial deviation of the polarizer, the characteristics of other optical elements will also cause light leakage during black display. For example, Patent Document 2 proposes to consider the birefringence of a triacetyl cellulose (TAC) film provided on the surface of the polarizer on the liquid crystal cell side as a protective film to adjust the optical characteristics of the optical anisotropic element used for optical compensation . In Patent Document 3, as a protective film provided on the surface of the polarizer, it is proposed to use a low birefringence film such as an original norbornene-based resin film. [Prior Technical Literature] [Patent Literature]

[專利文獻1]日本專利特開平4-371903號公報 [專利文獻2]日本專利特開2001-258041號公報 [專利文獻3]日本專利特開2004-4641號公報[Patent Document 1] Japanese Patent Laid-Open No. 4-371903 [Patent Document 2] Japanese Patent Laid-Open No. 2001-258041 [Patent Document 3] Japanese Patent Laid-Open No. 2004-4641

[發明所欲解決之問題][Problems to be solved by the invention]

設置於液晶單元之基板之彩色濾光片之面內延遲大致為0,但於厚度方向上具有數nm~數十nm之延遲。如上所述,於配置於偏光件與液晶單元之間之光學元件具有雙折射之情形時,藉由考慮其光學特性調整光學各向異性元件之光學特性,可進而降低自傾斜方向視認時之漏光。The in-plane retardation of the color filter provided on the substrate of the liquid crystal cell is approximately 0, but it has a retardation of several nm to several tens of nm in the thickness direction. As described above, when the optical element disposed between the polarizer and the liquid crystal cell has birefringence, by adjusting the optical characteristics of the optically anisotropic element by considering its optical characteristics, light leakage when viewed from the oblique direction can be further reduced .

如上所述,液晶面板之光學補償針對比視感度較高之綠色(波長550 nm附近)光實現最佳化。因此,於黑顯示時,光學設計自最佳值之偏移較大之波長之光洩漏,畫面著色而被視認到。於光學設計上,難以使自傾斜方向視認時之色相為完全中性,故於黑顯示時,根據產生有漏光之光之波長,畫面稍許著色而被視認到。藍色(波長450 nm附近)相較紅色(波長650 nm附近)之比視感度低,故黑顯示之色相有喜好藍色系之傾向。As described above, the optical compensation of the liquid crystal panel is optimized for green (higher than 550 nm wavelength) light with higher visual sensitivity. Therefore, in black display, light with a wavelength shifted from the optimal value by a large amount of light leaks, and the picture is colored to be recognized. In terms of optical design, it is difficult to make the hue when viewed from the oblique direction completely neutral. Therefore, when displaying in black, the screen is slightly colored and recognized depending on the wavelength of light with light leakage. Blue (near wavelength 450 nm) has a lower visual sensitivity than red (near wavelength 650 nm), so the hue of black display tends to prefer the blue color.

根據本發明者等人之研究,於特定構成之液晶面板中,考慮彩色濾光片之厚度方向延遲之影響,以使綠色之漏光成為最小之方式進行光學各向異性元件之設計之情形時,判明有如下傾向,即,紅色之光之漏光較大,自傾斜方向視認時黑顯示之畫面以紅色系之色相被視認到。具體而言,發現如下問題,即,於配置於液晶單元之光源側之偏光件之吸收軸方向、與光學各向異性元件之遲相軸方向正交之情形時,若考慮彩色濾光片之厚度方向延遲之影響而以綠色之漏光變小之方式進行光學設計,則有亦抑制紅色之漏光之傾向。另一方面,於配置於液晶單元之光源側之偏光件之吸收軸方向、與光學各向異性元件之遲相軸方向平行之情形時,若考慮彩色濾光片之厚度方向延遲之影響而以綠色之漏光成為最小之方式進行光學設計,則紅色之漏光較大,黑顯示容易成為紅色系之色相。According to the research of the present inventors and others, in the case of a liquid crystal panel with a specific structure, considering the influence of the retardation in the thickness direction of the color filter, the design of the optical anisotropic element is performed in such a way as to minimize the green light leakage, It is found that there is a tendency that the light leakage of red light is large, and the black-displayed picture is recognized in the hue of red when viewed from the oblique direction. Specifically, the following problem was found, when the absorption axis direction of the polarizer disposed on the light source side of the liquid crystal cell is orthogonal to the direction of the slow phase axis of the optical anisotropic element, if the color filter is considered The effect of retardation in the thickness direction and optical design in such a way that the green light leakage becomes smaller, also tends to suppress the red light leakage. On the other hand, in the case where the absorption axis direction of the polarizer disposed on the light source side of the liquid crystal cell is parallel to the direction of the retardation axis of the optical anisotropic element, if the influence of the thickness direction delay of the color filter is considered, Green light leakage becomes the smallest way for optical design, then red light leakage is larger, and black display is easy to become the hue of the red system.

本發明之目的在於提供一種圖像顯示裝置,於光源側偏光件之吸收軸方向與光學各向異性元件之遲相軸方向平行配置之液晶面板中,考慮彩色濾光片之影響而降低自傾斜方向視認時之黑顯示之漏光,並且降低黑顯示時之紅色著色,視認性優異。 [解決問題之技術手段]The object of the present invention is to provide an image display device in a liquid crystal panel in which the absorption axis direction of the light source side polarizer is parallel to the retardation axis direction of the optical anisotropic element, and the self-tilt is reduced in consideration of the influence of the color filter Light leakage in black display during direction recognition and reduced red coloration in black display are excellent in visibility. [Technical means to solve the problem]

本發明之液晶面板具備:液晶單元,其具備包含於無電場狀態下平行配向之液晶分子之液晶層、及配置於液晶層之第一主面(視認側)之彩色濾光片;第一偏光件,其配置於液晶單元之第一主面(視認側);及第二偏光件,其配置於液晶單元之第二主面(光源側)。第一偏光件之吸收軸方向、與第二偏光件之吸收軸方向正交。The liquid crystal panel of the present invention includes: a liquid crystal cell including a liquid crystal layer including liquid crystal molecules aligned in parallel in a state without an electric field, and a color filter disposed on a first main surface (viewing side) of the liquid crystal layer; first polarized light The device is arranged on the first main surface (viewing side) of the liquid crystal cell; and the second polarizer is arranged on the second main surface (light source side) of the liquid crystal cell. The direction of the absorption axis of the first polarizer is orthogonal to the direction of the absorption axis of the second polarizer.

彩色濾光片至少具有綠色透過區域及紅色透過區域。彩色濾光片之綠色透過區域較佳為,波長550 nm之厚度方向延遲Ct550 為50 nm以下。彩色濾光片之紅色區域較佳為,波長650 nm之厚度方向延遲Ct650 為50 nm以下。Ct550 及Ct650 均大於0。Ct550 及Ct650 例如可為1 nm以上、3 nm以上或5 nm以上。The color filter has at least a green transmission area and a red transmission area. The green transmission region of the color filter preferably has a thickness direction retardation Ct 550 of 50 nm or less at a wavelength of 550 nm. The red region of the color filter preferably has a thickness direction retardation Ct 650 with a wavelength of 650 nm of 50 nm or less. Both Ct 550 and Ct 650 are greater than zero. Ct 550 and Ct 650 may be, for example, 1 nm or more, 3 nm or more, or 5 nm or more.

本發明之液晶面板具備配置於第一偏光件與第二偏光件之間之光學各向異性元件。光學各向異性元件之遲相軸方向與第二偏光件之吸收軸方向平行。光學各向異性元件之波長650 nm之正面延遲Re650 與厚度方向延遲Rt650 之比Rt650 /Re650 為0.2~0.8。The liquid crystal panel of the present invention includes an optically anisotropic element disposed between the first polarizer and the second polarizer. The direction of the slow phase axis of the optically anisotropic element is parallel to the direction of the absorption axis of the second polarizer. Wavelength 650 nm of the optically anisotropic element of the front retardation Re 650 retardation Rt in the thickness direction of the ratio Rt 650 650 / Re 650 of 0.2 to 0.8.

較佳為,光學各向異性元件之波長650 nm之厚度方向延遲Rt650 (nm)與彩色濾光片之紅色透過區域之波長650 nm之厚度方向延遲Ct650 (nm)滿足下述式(1a)或(2a): Rt650 ≧0.37(Ct650 )+116...(1a) Rt650 ≦-0.44(Ct650 )+116...(2a)。Preferably, the thickness direction retardation Rt 650 (nm) of the optical anisotropic device at a wavelength of 650 nm and the thickness direction retardation Ct 650 (nm) of the wavelength of 650 nm at the red transmission region of the color filter satisfy the following formula (1a) ) Or (2a): Rt 650 ≧0.37(Ct 650 )+116...(1a) Rt 650 ≦-0.44(Ct 650 )+116...(2a).

本發明之第一實施形態之液晶面板為O模式,液晶單元之無電場狀態下之液晶分子之配向方向(初始配向方向)、與第二偏光件之吸收軸方向平行。O模式之液晶面板中,於液晶單元與第一偏光件之間、即液晶單元之視認側,配置有光學各向異性元件。The liquid crystal panel of the first embodiment of the present invention is in the O mode, and the alignment direction (initial alignment direction) of the liquid crystal molecules in the liquid crystal cell in an electric field-free state is parallel to the absorption axis direction of the second polarizer. In the O-mode liquid crystal panel, an optically anisotropic element is arranged between the liquid crystal cell and the first polarizer, that is, on the viewing side of the liquid crystal cell.

第一實施形態中,較佳為光學各向異性元件之波長550 nm之厚度方向延遲Rt550 (nm)與彩色濾光片之綠色透過區域之波長550 nm之厚度方向延遲Ct550 (nm)滿足下述式(3a): 0.97(Ct550 )+73≦Rt550 ≦0.49(Ct550 )+205...(3a)。In the first embodiment, it is preferable that the retardation Rt 550 (nm) in the thickness direction of the wavelength of the optical anisotropic element at 550 nm and the retardation Ct 550 (nm) in the thickness direction of the wavelength of 550 nm in the green transmission region of the color filter satisfy The following formula (3a): 0.97(Ct 550 )+73≦Rt 550 ≦0.49(Ct 550 )+205...(3a).

本發明之第二實施形態之液晶面板為E模式,液晶單元之液晶分子之初始配向方向、與第二偏光件之吸收軸方向正交。E模式之液晶面板中,於液晶單元與第二偏光件之間、即於液晶單元之光源側,配置有光學各向異性元件。The liquid crystal panel of the second embodiment of the present invention is in the E mode, and the initial alignment direction of the liquid crystal molecules of the liquid crystal cell is orthogonal to the absorption axis direction of the second polarizer. In the E-mode liquid crystal panel, an optically anisotropic element is arranged between the liquid crystal cell and the second polarizer, that is, on the light source side of the liquid crystal cell.

第二實施形態中,較佳為光學各向異性元件之波長550 nm之厚度方向延遲Rt550 (nm)與彩色濾光片之綠色透過區域之波長550 nm之厚度方向延遲Ct550 (nm)滿足下述式(8a): 0.69(Ct550 )+70≦Rt550 ≦1.35(Ct550 )+200...(8a)。In the second embodiment, it is preferable that the retardation Rt 550 (nm) in the thickness direction of the wavelength 550 nm of the optical anisotropic element and the retardation Ct 550 (nm) in the thickness direction of the wavelength 550 nm of the green transmission region of the color filter satisfy The following formula (8a): 0.69(Ct 550 )+70≦Rt 550 ≦1.35(Ct 550 )+200...(8a).

本發明之液晶顯示裝置具備配置於上述液晶面板之第二主面側之光源。 [發明之效果]The liquid crystal display device of the present invention includes a light source disposed on the second main surface side of the liquid crystal panel. [Effect of invention]

根據本發明,可提供一種液晶顯示裝置,藉由考慮彩色濾光片之雙折射進行光學設計,可降低自傾斜方向視認時之黑亮度,並且抑制黑顯示之紅色著色,視認性優異。According to the present invention, it is possible to provide a liquid crystal display device which is optically designed by considering the birefringence of a color filter, can reduce black brightness when viewed from an oblique direction, suppresses red coloration of black display, and has excellent visibility.

[液晶面板整體之概略] 圖1係表示第一實施形態之液晶面板101中之光學元件之配置之構成概念圖。圖2係包含液晶面板101與光源110之液晶顯示裝置201之模式剖視圖。圖3係表示第二實施形態之液晶面板102中之光學元件之配置之構成概念圖。圖4係包含液晶面板102與光源110之液晶顯示裝置202之模式剖視圖。[Overview of the entire LCD panel] FIG. 1 is a conceptual diagram showing the configuration of the arrangement of optical elements in the liquid crystal panel 101 of the first embodiment. 2 is a schematic cross-sectional view of a liquid crystal display device 201 including a liquid crystal panel 101 and a light source 110. 3 is a conceptual diagram showing the configuration of the arrangement of optical elements in the liquid crystal panel 102 of the second embodiment. 4 is a schematic cross-sectional view of a liquid crystal display device 202 including a liquid crystal panel 102 and a light source 110.

液晶面板具備配置於液晶單元20之第一主面(視認側)之第一偏光件30、及配置於液晶單元20之第二主面(光源側)之第二偏光件40。第一偏光件30之吸收軸方向35與第二偏光件40之吸收軸方向45正交。The liquid crystal panel includes a first polarizer 30 disposed on the first main surface (viewing side) of the liquid crystal cell 20 and a second polarizer 40 disposed on the second main surface (light source side) of the liquid crystal cell 20. The absorption axis direction 35 of the first polarizer 30 is orthogonal to the absorption axis direction 45 of the second polarizer 40.

第一實施形態之液晶面板101及液晶顯示裝置201為O模式,配置於液晶單元20之光源110側之第二偏光件40之吸收軸方向45、與液晶層10之液晶分子之初始配向方向11平行。第二實施形態之液晶面板102及液晶顯示裝置202為E模式,配置於液晶單元20之光源110側之第二偏光件40之吸收軸方向45、與液晶層10之液晶分子之初始配向方向11正交。The liquid crystal panel 101 and the liquid crystal display device 201 of the first embodiment are in the O mode, and the absorption axis direction 45 of the second polarizer 40 disposed on the light source 110 side of the liquid crystal cell 20 and the initial alignment direction 11 of the liquid crystal molecules of the liquid crystal layer 10 parallel. The liquid crystal panel 102 and the liquid crystal display device 202 of the second embodiment are in the E mode, and the absorption axis direction 45 of the second polarizer 40 disposed on the light source 110 side of the liquid crystal cell 20 and the initial alignment direction 11 of the liquid crystal molecules of the liquid crystal layer 10 Orthogonal.

本發明之液晶面板於第一偏光件30與第二偏光件40之間具備光學各向異性元件。第一實施形態之O模式之液晶面板101於液晶單元20與第一偏光件30之間具備光學各向異性元件50。第二實施形態之E模式之液晶面板102於液晶單元20與第二偏光件40之間具備光學各向異性元件60。任一形態下,第二偏光件40之吸收軸方向45、與光學各向異性元件50、60之遲相軸方向53、63均平行。The liquid crystal panel of the present invention includes an optically anisotropic element between the first polarizer 30 and the second polarizer 40. The O-mode liquid crystal panel 101 of the first embodiment includes an optically anisotropic element 50 between the liquid crystal cell 20 and the first polarizer 30. The E-mode liquid crystal panel 102 of the second embodiment includes an optically anisotropic element 60 between the liquid crystal cell 20 and the second polarizer 40. In either form, the absorption axis direction 45 of the second polarizer 40 is parallel to the retardation axis directions 53, 63 of the optically anisotropic elements 50, 60.

再者,本說明書中,所謂「正交」不僅指完全正交之情形,還包含實質上正交,其角度一般為90±2°之範圍,較佳為90±1°,更佳為90±0.5之範圍。同樣地,所謂「平行」不僅指完全平行,還包含實質上平行,其角度一般為±2°以內,較佳為±1°以內,更佳為±0.5°以內。In addition, in this specification, the term "orthogonal" refers not only to the situation of complete orthogonality, but also includes substantially orthogonality, and its angle is generally within the range of 90±2°, preferably 90±1°, more preferably 90 ±0.5 range. Similarly, the term "parallel" refers to not only perfect parallel, but also substantially parallel, and its angle is generally within ±2°, preferably within ±1°, and more preferably within ±0.5°.

[液晶單元] 液晶單元20於第一基板21與第二基板25之間具備液晶層10。在配置於液晶層之視認側之第一基板21(彩色濾光片基板)設置有彩色濾光片22。彩色濾光片22至少具有綠色透過區域22G及紅色透過區域22R。在配置於液晶層10之光源側之第二基板25(TFT基板),設置有用以控制液晶之配向方向之切換元件(一般為TFT元件)等。[LCD unit] The liquid crystal cell 20 includes a liquid crystal layer 10 between the first substrate 21 and the second substrate 25. A color filter 22 is provided on the first substrate 21 (color filter substrate) disposed on the viewing side of the liquid crystal layer. The color filter 22 has at least a green transmission region 22G and a red transmission region 22R. The second substrate 25 (TFT substrate) disposed on the light source side of the liquid crystal layer 10 is provided with a switching element (generally a TFT element) for controlling the alignment direction of the liquid crystal.

於彩色濾光片22之綠色透過區域22G,設置有對於波長500~600 nm附近之光具有相對較高之透過率之綠色濾光片。綠色濾光片較佳為於波長500~600 nm附近具有極大透過率。綠色透過區域之波長550 nm之透過率例如為30%以上。綠色透過區域之波長450 nm之透過率較佳為10%以下。綠色透過區域之波長650 nm之透過率較佳為10%以下,更佳為5%以下。In the green transmission region 22G of the color filter 22, a green filter having a relatively high transmittance for light near a wavelength of 500 to 600 nm is provided. The green filter preferably has a maximum transmittance near a wavelength of 500 to 600 nm. The transmittance of the green transmission region at a wavelength of 550 nm is, for example, 30% or more. The transmittance of the wavelength 450 nm in the green transmission region is preferably 10% or less. The transmittance of the green transmission region at a wavelength of 650 nm is preferably 10% or less, and more preferably 5% or less.

於紅色透過區域22R,設置有對於相較波長600 nm更長波長之可見光具有相對較高之透過率之紅色濾光片。紅色透過區域之波長650 nm之透過率例如為30%以上。紅色透過區域之波長550 nm之透過率及波長450 nm之透過率均較佳為10%以下,更佳為5%以下。In the red transmission region 22R, a red filter having a relatively high transmittance for visible light with a longer wavelength than the wavelength of 600 nm is provided. The transmittance at a wavelength of 650 nm in the red transmission region is, for example, 30% or more. The transmittance at a wavelength of 550 nm and the transmittance at a wavelength of 450 nm in the red transmission region are preferably 10% or less, and more preferably 5% or less.

彩色濾光片22亦可包含除綠色透過區域22G及紅色透過區域22R以外之區域,一般而言,包含藍色透過區域22B。藍色透過區域22B設置有對於相較波長500 nm更短波長之可見光具有相對較高之透過率之藍色濾光片。藍色透過區域之波長450 nm之透過率例如為30%以上。藍色透過區域之波長550 nm之透過率及波長650 nm之透過率均較佳為10%以下,更佳為5%以下。The color filter 22 may include regions other than the green transmission region 22G and the red transmission region 22R, and generally includes the blue transmission region 22B. The blue transmission region 22B is provided with a blue filter having a relatively high transmittance for visible light having a shorter wavelength than the wavelength of 500 nm. The transmittance of the wavelength 450 nm in the blue transmission region is, for example, 30% or more. The transmittance at a wavelength of 550 nm and the transmittance at a wavelength of 650 nm in the blue transmission region are preferably 10% or less, and more preferably 5% or less.

彩色濾光片亦可進而具有相對於除上述以外之特定之波長區域具有相對較高之透光率之透光區域。較佳為於鄰接之透過區域之分界設置有黑矩陣。The color filter may further have a light-transmitting region having a relatively high light transmittance relative to a specific wavelength region other than the above. It is preferable that a black matrix is provided at the boundary between adjacent transmission regions.

液晶層10包含於無電場狀態下平行配向之液晶分子。所謂平行配向之液晶分子係指液晶分子之配向向量相對於基板平面平行且均勻地配向之狀態者。再者,液晶分子之配向向量亦可相對於基板平面稍許傾斜(預傾斜)。液晶單元之預傾斜角一般為3°以下,較佳為1°以下,更佳為0.5°以下。The liquid crystal layer 10 includes liquid crystal molecules aligned in parallel under the state of no electric field. The so-called parallel alignment of liquid crystal molecules refers to the state in which the alignment vectors of the liquid crystal molecules are aligned parallel and uniformly with respect to the plane of the substrate. Furthermore, the alignment vector of the liquid crystal molecules may also be slightly tilted (pretilt) relative to the substrate plane. The pretilt angle of the liquid crystal cell is generally 3° or less, preferably 1° or less, and more preferably 0.5° or less.

作為包含於無電解狀態下平行配向之液晶分子之液晶單元,可列舉橫向電場效應(IPS)模式、邊緣場切換(FFS,Fringe- field Switching)模式、鐵電性液晶(FLC,Ferroelectric Liquid Crystal)模式等。作為液晶分子,可使用向列型液晶或層列型液晶等。一般而言,IPS模式及FFS模式之液晶單元中使用向列型液晶,FLC模式之液晶單元中使用層列型液晶。Examples of liquid crystal cells including liquid crystal molecules aligned in parallel in an electroless state include lateral electric field effect (IPS) mode, fringe-field switching (FFS) mode, and ferroelectric liquid crystal (FLC). Mode etc. As the liquid crystal molecules, nematic liquid crystal or smectic liquid crystal can be used. Generally speaking, nematic liquid crystals are used in the IPS mode and FFS mode liquid crystal cells, and smectic liquid crystals are used in the FLC mode liquid crystal cells.

[偏光件] 於液晶單元20之第一主面側配置有第一偏光件30,於第二主面側配置有第二偏光件40。偏光件係將自然光或任意之偏光轉換為直線偏光者。作為第一偏光件30及第二偏光件40,根據目的而可採用任意適當之偏光件。例如,可列舉使碘或二色性染料等二色性物質吸附於聚乙烯醇系膜、部分縮甲醛化聚乙烯醇系膜、乙烯-乙酸乙烯酯共聚物系部分皂化膜等親水性高分子膜並進行單軸延伸而成者、聚乙烯醇之脫水處理物或聚氯乙烯之脫氯化氫處理物等多烯系配向膜等。[Polarizer] The first polarizer 30 is disposed on the first main surface side of the liquid crystal cell 20, and the second polarizer 40 is disposed on the second main surface side. The polarizer converts natural light or arbitrary polarized light into linear polarized light. As the first polarizer 30 and the second polarizer 40, any appropriate polarizer can be used according to the purpose. For example, hydrophilic polymers such as adsorbed dichroic substances such as iodine and dichroic dyes on polyvinyl alcohol-based films, partially formalized polyvinyl alcohol-based films, and ethylene-vinyl acetate copolymer-based partially saponified films can be cited. Uniaxially stretched film, polyene-based alignment film such as polyvinyl alcohol dehydration treatment or polyvinyl chloride dehydrochlorination treatment, etc.

該等偏光件中,就具有較高之偏光度之觀點而言,可較佳地使用使碘或二色性染料等二色性物質吸附於聚乙烯醇、部分縮甲醛化聚乙烯醇等聚乙烯醇系膜且配向於特定方向之聚乙烯醇(PVA,polyvinyl alcohol)系偏光件。例如,藉由對聚乙烯醇系膜實施碘染色及延伸而可獲得PVA系偏光件。Among these polarizers, from the viewpoint of having a high degree of polarization, a polychromatic substance such as iodine or a dichroic dye adsorbed to polyvinyl alcohol or partially formalized polyvinyl alcohol can be preferably used. A polyvinyl alcohol (PVA, polyvinyl alcohol) polarizer with a vinyl alcohol film and oriented in a specific direction. For example, a PVA-based polarizer can be obtained by performing iodine dyeing and stretching on a polyvinyl alcohol-based film.

作為PVA系偏光件,亦可使用厚度為10 μm以下之薄型偏光件。作為薄型偏光件,例如可列舉記載於日本專利特開昭51-069644號公報、日本專利特開2000-338329號公報、WO2010/100917號手冊、專利第4691205號說明書、專利第4751481號說明書等中之薄型偏光膜。此種薄型偏光件例如藉由包含將PVA系樹脂層與延伸用樹脂基材以積層體之狀態延伸之步驟、及碘染色之步驟之製法而獲得。As the PVA-based polarizer, a thin polarizer with a thickness of 10 μm or less can also be used. Examples of thin polarizers include those described in Japanese Patent Laid-Open No. 51-069644, Japanese Patent Laid-Open No. 2000-338329, WO2010/100917 manual, Patent No. 4691205, and Patent No. 4571481. Thin polarizing film. Such a thin polarizer is obtained by, for example, a manufacturing method including a step of extending a PVA-based resin layer and an extending resin base material in a state of a laminate, and a step of iodine dyeing.

[光學各向異性元件] 光學各向異性元件50、60係面內之遲相軸方向之折射率nx、面內之進相軸方向之折射率ny、及厚度方向之折射率nz滿足nx>nz>ny之相位差膜。配置於液晶單元20之上下之偏光件30、40以吸收軸方向35、45正交之方式而配置,但若自傾斜方向視認液晶面板,則偏光件30、40之於表觀上之吸收軸方向所成之角大於90°(產生自正交偏光之偏移),故產生漏光。[Optical Anisotropic Element] The optically anisotropic elements 50 and 60 are in-plane refractive index nx in the direction of the retardation axis, in-plane refractive index ny in the direction of the advancement axis, and refractive index nz in the thickness direction satisfying nx>nz>ny . The polarizers 30 and 40 arranged above and below the liquid crystal cell 20 are arranged in such a way that the absorption axis directions 35 and 45 are orthogonal, but if the liquid crystal panel is viewed from the oblique direction, the apparent absorption axis of the polarizers 30 and 40 is The angle formed by the direction is greater than 90° (offset from orthogonal polarized light), so light leakage occurs.

藉由於液晶單元20與偏光件30、40之間配置滿足nx>nz>ny之相位差膜,可補償偏光件之表觀上之軸偏移,減少自傾斜方向視認畫面時之漏光。尤其相對於偏光件之吸收軸成45度之角度(方位角45度、135度、225度、315度)上之黑亮度降低,對比度提高。By disposing a phase difference film satisfying nx>nz>ny between the liquid crystal cell 20 and the polarizers 30 and 40, the apparent axial shift of the polarizer can be compensated, and light leakage when viewing the picture from the oblique direction can be reduced. In particular, the black brightness at an angle of 45 degrees (azimuth angles of 45 degrees, 135 degrees, 225 degrees, and 315 degrees) relative to the absorption axis of the polarizer decreases, and the contrast improves.

第一實施形態之O模式之液晶面板101中,於液晶單元20與視認側之第一偏光件30之間配置有光學各向異性元件50。第二實施形態之E模式之液晶面板102中,於液晶單元20與光源側之第二偏光件40之間配置有光學各向異性元件60。In the O-mode liquid crystal panel 101 of the first embodiment, an optically anisotropic element 50 is arranged between the liquid crystal cell 20 and the first polarizer 30 on the viewing side. In the E-mode liquid crystal panel 102 of the second embodiment, an optically anisotropic element 60 is arranged between the liquid crystal cell 20 and the second polarizer 40 on the light source side.

光學各向異性元件50、60之波長550 nm之正面延遲Re550 較佳為150~400 nm,更佳為180~370 nm,進而佳為200~350 nm。光學各向異性元件之波長550 nm之厚度方向延遲Rt550 較佳為75~200 nm,更佳為90~185 nm,進而佳為100~175 nm。再者,正面延遲Re、及厚度方向延遲Rt使用面內之遲相軸方向之折射率nx、面內之進相軸方向之折射率ny、及厚度方向之折射率nz以如下般定義: Re=(nx-ny)×d Rt=(nx-nz)×d。The front retardation Re 550 of the optical anisotropic elements 50 and 60 at a wavelength of 550 nm is preferably 150 to 400 nm, more preferably 180 to 370 nm, and still more preferably 200 to 350 nm. The thickness direction retardation Rt 550 of the optical anisotropic device at a wavelength of 550 nm is preferably from 75 to 200 nm, more preferably from 90 to 185 nm, and even more preferably from 100 to 175 nm. In addition, the front retardation Re and the thickness direction retardation Rt use the in-plane retardation axis direction refractive index nx, the in-plane advancement axis direction refractive index ny, and the thickness direction refractive index nz are defined as follows: Re = (Nx-ny) × d Rt = (nx-nz) × d.

關於考慮彩色濾光片之厚度方向延遲之光學各向異性元件之Re及Rt之範圍,將於以下詳細敍述。The range of Re and Rt of the optically anisotropic element considering the retardation in the thickness direction of the color filter will be described in detail below.

光學各向異性元件50、60較佳為,以Nz=(nx-nz)/(nx-ny)定義之Nz係數為0.2~0.8。根據上述Re及Rt之定義,亦可表示為Nz=Rt/Re。本說明書中,Nz係數係根據波長650 nm之折射率而算出。即,Nz係數為波長650 nm之正面延遲Re650 與厚度方向延遲Rt650 之比Rt650 /Re650 。因此,光學各向異性元件較佳為,Rt650 /Re650 為0.2~0.8。再者,藉由聚合物膜之延伸而製作之相位差膜中,一般而言,根據波長550 nm之折射率算出之Nz係數、與根據波長650 nm之折射率算出之Nz係數大致相同。The optically anisotropic elements 50 and 60 preferably have an Nz coefficient defined by Nz=(nx-nz)/(nx-ny) of 0.2 to 0.8. According to the above definitions of Re and Rt, it can also be expressed as Nz=Rt/Re. In this specification, the Nz coefficient is calculated based on the refractive index at a wavelength of 650 nm. That is, Nz coefficient and retardation Re 650 retardation Rt in the thickness direction of the ratio Rt 650 650 / Re 650 is a wavelength of 650 nm positive. Therefore, the optically anisotropic element preferably has Rt 650 /Re 650 of 0.2 to 0.8. In addition, in the retardation film produced by extending the polymer film, generally, the Nz coefficient calculated from the refractive index at a wavelength of 550 nm is substantially the same as the Nz coefficient calculated from the refractive index at a wavelength of 650 nm.

光學各向異性元件之Nz係數更佳為0.3~0.7,進而佳為0.4~0.6。有如下傾向,即,Nz係數越接近0.5,則於較廣視角範圍漏光越降低。The Nz coefficient of the optically anisotropic element is more preferably 0.3 to 0.7, further preferably 0.4 to 0.6. There is a tendency that the closer the Nz coefficient is to 0.5, the lower the light leakage in a wider viewing angle range.

作為構成光學各向異性元件之材料,可列舉聚碳酸酯系樹脂、聚對苯二甲酸乙二酯或聚萘二甲酸乙二酯等聚酯系樹脂、聚芳酯系樹脂、聚碸、聚醚碸等碸系樹脂、聚苯硫醚等硫系樹脂、聚醯亞胺系樹脂、環狀聚烯烴系(聚降冰片烯系)樹脂、聚醯胺樹脂、聚乙烯或聚丙烯等聚烯烴系樹脂、纖維素酯類等。亦可使用液晶材料作為光學各向異性元件之材料。Examples of the material constituting the optically anisotropic element include polycarbonate resins, polyester resins such as polyethylene terephthalate and polyethylene naphthalate, polyarylate resins, polyphenols, and poly Ether resins such as ether resins, sulfur resins such as polyphenylene sulfide, polyimide resins, cyclic polyolefin (polynorbornene) resins, polyamide resins, polyolefins such as polyethylene or polypropylene Resins, cellulose esters, etc. Liquid crystal materials can also be used as materials for optically anisotropic elements.

於使用聚合物材料之情形時,藉由使聚合物膜朝至少一方向延伸或收縮而可提高特定方向之分子配向性,從而製作光學各向異性元件(相位差膜)。將聚合物膜與熱收縮性膜積層之狀態下,一面朝一方向延伸,一面利用熱收縮性膜之收縮力使膜朝與延伸方向正交之方向收縮,藉此可獲得具有nx>nz>ny之折射率各向異性之光學各向異性元件。In the case of using a polymer material, by extending or shrinking the polymer film in at least one direction, the molecular alignment in a specific direction can be improved, thereby manufacturing an optically anisotropic element (retardation film). In the state where the polymer film and the heat-shrinkable film are stacked, one side extends in one direction, and the other side uses the shrinking force of the heat-shrinkable film to shrink the film in a direction orthogonal to the extension direction, thereby obtaining nx>nz>ny Anisotropic optical anisotropic element of refractive index.

光學各向異性元件之厚度根據構成光學各向異性元件之材料等而可適當選擇。於使用聚合物材料之情形時,光學各向異性元件之厚度一般為3 μm~200 μm左右。於使用液晶材料之情形時,光學各向異性元件之厚度(液晶層之厚度)一般為0.1 μm~20 μm左右。The thickness of the optically anisotropic element can be appropriately selected according to the material and the like constituting the optically anisotropic element. When using polymer materials, the thickness of the optically anisotropic element is generally about 3 μm to 200 μm. In the case of using liquid crystal materials, the thickness of the optically anisotropic element (thickness of the liquid crystal layer) is generally about 0.1 μm to 20 μm.

光學各向異性元件具有特定之Re及Rt即可,光學各向異性元件之材料、厚度及製作方法並不限定於以上所述。The optical anisotropic element only needs to have specific Re and Rt, and the material, thickness and manufacturing method of the optical anisotropic element are not limited to the above.

[光學各向異性元件之光學補償原理] 本發明中,藉由根據彩色濾光片之雙折射設定光學各向異性元件之光學特性,而可光學性補償偏光件之表觀上之軸方向之偏移、與彩色濾光片之雙折射之影響之兩者,獲得自傾斜方向視認時之漏光較少、且黑顯示之色相為中性之液晶顯示裝置。具體而言,以如下方式設定光學各向異性元件之光學特性,即,彩色濾光片22之綠色透過區域22G之波長550 nm之厚度方向延遲Ct550 、與光學各向異性元件50、60之波長550 nm之厚度方向延遲Rt550 滿足特定之關係;且彩色濾光片22之紅色透過區域22R中之波長650 nm之厚度方向延遲Ct650 、與光學各向異性元件50、60之波長650 nm之厚度方向延遲Rt650 滿足特定之關係。[Optical Compensation Principle of Optical Anisotropic Element] In the present invention, by setting the optical characteristics of the optical anisotropic element according to the birefringence of the color filter, the apparent axial direction of the polarizer can be optically compensated Both the offset and the influence of the birefringence of the color filter obtain a liquid crystal display device with less light leakage when viewed from an oblique direction and a neutral hue of black display. Specifically, the optical characteristics of the optical anisotropic element are set in such a manner that the thickness direction of the green transmission region 22G of the color filter 22 at a wavelength of 550 nm is delayed by Ct 550 and the optical anisotropic elements 50 and 60 The thickness direction retardation Rt 550 at a wavelength of 550 nm satisfies a specific relationship; and the thickness direction retardation Ct 650 at a wavelength of 650 nm in the red transmission region 22R of the color filter 22 and the wavelength 650 nm at the wavelength of the optically anisotropic elements 50, 60 The thickness direction delay Rt 650 satisfies a specific relationship.

<未考慮彩色濾光片之雙折射之情形時之光學補償> 首先,參照圖5,對使用具有nx>nz>ny之折射率各向異性之光學各向異性元件補償偏光件之表觀上之軸方向偏移之原理進行說明。圖5中,利用龐加萊球說明藉由光學各向異性元件50補償圖1所示之O模式之液晶面板101之偏光件30、40之表觀上之軸方向偏移之狀況。<Optical compensation when the birefringence of the color filter is not considered> First, referring to FIG. 5, the principle of using an optically anisotropic element having a refractive index anisotropy of nx>nz>ny to compensate the apparent axial shift of the polarizer will be described. In FIG. 5, the Poincaré sphere is used to explain the situation where the apparent axial direction deviation of the polarizers 30 and 40 of the O-mode liquid crystal panel 101 shown in FIG. 1 is compensated by the optical anisotropic element 50.

透過光源側偏光件40之光為直線偏光,自正面視認液晶顯示裝置之情形時,透過偏光件之光以龐加萊球之赤道上之點P0 表示。視認側偏光件30之吸收軸方向35與光源側偏光件40之吸收軸方向45正交,故透過視認側偏光件30之光以龐加萊球之赤道上之點P1 表示。The light passing through the light source side polarizer 40 is linearly polarized. When the liquid crystal display device is viewed from the front, the light passing through the polarizer is represented by a point P 0 on the equator of the Poincare sphere. The absorption axis direction 35 of the viewing side polarizer 30 is orthogonal to the absorption axis direction 45 of the light source side polarizer 40, so light passing through the viewing side polarizer 30 is represented by a point P 1 on the equator of the Poincaré sphere.

液晶單元20中之液晶分子之初始配向方向11與偏光件40之吸收軸方向45平行,故透過偏光件40之光之偏光狀態於透過液晶單元之後亦不會變化。即,透過液晶單元之光之偏光狀態不會自龐加萊球上之點P0 移動。透過液晶單元20之光P0 、與透過視認側偏光件30之光P1 為相互正交之直線偏光,故透過液晶單元20之光全部由視認側偏光件30吸收,可實現黑顯示。The initial alignment direction 11 of the liquid crystal molecules in the liquid crystal cell 20 is parallel to the absorption axis direction 45 of the polarizer 40, so the polarization state of the light transmitted through the polarizer 40 does not change after passing through the liquid crystal cell. That is, the polarization state of the light transmitted through the liquid crystal cell does not move from the point P 0 on the Poincare sphere. Light passing through P 0 of the liquid crystal cell 20 of, and transmitted light 30 of the P visible side polarizer member 1 mutually linearly orthogonal to the polarization, it is fully absorbed by the viewer side polarizer 30 light transmitted through the liquid crystal cell 20, the can achieve black display.

若以偏光件之吸收軸方向為基準自方位角45°、以畫面之法線方向為基準之斜率(極角)θ之方向視認液晶顯示裝置,則光源側偏光件40之表觀上之軸方向自P0 移動至P'0 ,視認側偏光件30之表觀上之軸方向自P1 移動至P'1 。極角θ越大,則偏光件之表觀上之軸方向之變化越大。If the liquid crystal display device is viewed from the direction of the azimuth angle 45° and the slope (polar angle) θ based on the normal direction of the screen based on the absorption axis direction of the polarizer, the apparent axis of the light source side polarizer 40 0 from direction P to P '0, the visible side of the polarization axis direction of the member 30 of an apparent from the mobile. 1 to P P' 1. The greater the polar angle θ, the greater the change in the apparent axial direction of the polarizer.

透過光源側偏光件40之光P'0 與透過視認側偏光件30之光P'1 不存在正交關係,故產生黑顯示之漏光。為防止由此種表觀上之軸方向之偏移導致之漏光,必需使透過液晶單元20之後之光之偏光狀態為與透過視認側偏光件30之光P'1 正交之直線偏光PAThe light 40 P '0 and the light 30 transmitted through the viewer side polarizer P' is absent orthogonal relation via a light source side polarizer, so that light leakage generation of black display. In order to prevent light leakage caused by such apparent axial shift, it is necessary to make the polarization state of the light after passing through the liquid crystal cell 20 to be linearly polarized light P A orthogonal to the light P′ 1 passing through the viewing side polarizer 30 .

圖1所示之O模式之液晶面板101中,光源側偏光件40之吸收軸方向45、與液晶單元20之初始配向方向11平行,故自傾斜方向視認時之表觀上之初始配向方向11與光源側偏光件之吸收軸方向45同樣地移動。因此,透過偏光件40之光之偏光狀態於透過液晶單元之後亦未變化,未自龐加萊球上之點P'0 移動。In the O-mode liquid crystal panel 101 shown in FIG. 1, the absorption axis direction 45 of the light source side polarizer 40 is parallel to the initial alignment direction 11 of the liquid crystal cell 20, so the apparent initial alignment direction 11 when viewed from the oblique direction It moves in the same way as the absorption axis direction 45 of the light source side polarizer. Therefore, the polarization state of the light transmitted through the polarizer 40 does not change after passing through the liquid crystal cell, and does not move from the point P′ 0 on the Poincare sphere.

透過液晶單元20之光入射至光學各向異性元件50。Nz係數為0.5之光學各向異性元件50無論自哪個角度視認,表觀上之光學軸方向均不會變化,在連結P0 與P1 之線上存在遲相軸。光學各向異性元件50之正面延遲(相對於法線方向之光之延遲)Re為波長λ之1/2。於Nz=0.5之情形時,即使光之透過方向產生變化,表觀上之延遲亦不會變化,以λ/2固定。λ/2之延遲對應於相位差π,故透過液晶單元20之光P'0 藉由透過光學各向異性元件50而以軸P0 -P1 為中心於龐加萊球上順時針方向旋轉180°,移動至點PAThe light transmitted through the liquid crystal cell 20 enters the optically anisotropic element 50. The optically anisotropic element 50 with an Nz coefficient of 0.5 does not change in the direction of the apparent optical axis no matter what angle it is viewed from, and there is a slow phase axis on the line connecting P 0 and P 1 . The front retardation (retardation of light with respect to the normal direction) Re of the optical anisotropic element 50 is 1/2 of the wavelength λ. In the case of Nz = 0.5, even if the transmission direction of light changes, the apparent delay will not change, and is fixed at λ/2. The retardation of λ/2 corresponds to the phase difference π, so the light P′ 0 transmitted through the liquid crystal cell 20 rotates clockwise on the Poincaré sphere around the axis P 0 -P 1 by passing through the optical anisotropic element 50 180 °, is moved to the point P A.

如上所述,直線偏光PA 係與透過視認側偏光件30之光P'1 正交之直線偏光,故偏光狀態藉由光學各向異性元件50而變化之光PA 由視認側偏光件30吸收,可實現黑顯示。As described above, P A linearly polarized light 30 transmitted through the system and the viewer side polarizer P 'perpendicular to the linearly polarized light 1, it polarization state by the optically anisotropic element 50 is changed by the light of P A viewer side polarizer 30 Absorption, black display can be achieved.

如圖6所示,第二偏光件40之吸收軸方向45與光學各向異性元件50之遲相軸方向53正交的O模式之液晶面板106中,利用光學各向異性元件50進行之偏光狀態之轉換於龐加萊球上成為順時針方向轉半圈,故如圖5之單點鏈線所示,龐加萊球上之軌跡穿過南半球。由於旋轉角度為180°,故與圖1所示之液晶面板之情形同樣地,透過光學各向異性元件50之光之偏光狀態由龐加萊球上之點PA 表示,且由視認側偏光件30吸收,故可實現黑顯示。As shown in FIG. 6, in the O-mode liquid crystal panel 106 where the absorption axis direction 45 of the second polarizer 40 is orthogonal to the retardation axis direction 53 of the optical anisotropic element 50, the polarized light by the optical anisotropic element 50 The state transition becomes a half-turn clockwise on the Poincaré ball, so as shown by the single-dot chain line in Figure 5, the trajectory on the Poincaré ball passes through the southern hemisphere. Since the rotation angle is 180 °, so that the case of the liquid crystal panel shown in the same manner as in FIG. 1, the polarization state of light transmitted through the optical anisotropy of the element 50 is represented by a point on the Poincare sphere P A, and when the viewing-side polarizer The piece 30 absorbs, so a black display can be realized.

於圖3所示之E模式之液晶面板102中,液晶單元20之液晶分子之初始配向方向11與光源側偏光件40之吸收軸方向45正交,故自傾斜方向視認時之表觀上之初始配向方向11與光源側偏光件40之吸收軸方向45產生自90°之偏移。因此,於光源側偏光件40與液晶單元20之間配置光學各向異性元件60,使透過光源側偏光件40之直線偏光P'0 藉由光學各向異性元件60而移動至龐加萊球上之點PA 。如此,將來自光源側偏光件40之直線偏光P'0 藉由光學各向異性元件60轉換成直線偏光PA 之後入射至液晶單元20,藉此透過液晶單元之光之偏光狀態並未自PA 變化,由視認側偏光件30吸收,故可實現黑顯示。In the E-mode liquid crystal panel 102 shown in FIG. 3, the initial alignment direction 11 of the liquid crystal molecules of the liquid crystal cell 20 is orthogonal to the absorption axis direction 45 of the light source side polarizer 40, so the apparent appearance when viewed from the oblique direction The initial alignment direction 11 is offset from the absorption axis direction 45 of the light source side polarizer 40 by 90°. Therefore, the optical anisotropic element 60 is arranged between the light source side polarizer 40 and the liquid crystal cell 20, so that the linearly polarized light P′ 0 transmitted through the light source side polarizer 40 is moved to the Poincare sphere by the optical anisotropic element 60 the point P A. Thus, from the light source side of the polarizer 40 linearly polarized light P '0, after linearly polarized light is converted into P A by the optically anisotropic element 60 enters the liquid crystal cell 20, whereby the polarization state of light transmitted through the liquid crystal cell is not from the P The change in A is absorbed by the polarizer 30 on the viewing side, so that a black display can be realized.

如圖7所示,第二偏光件40之吸收軸方向45與光學各向異性元件60之遲相軸方向63正交之E模式之液晶面板107中,於利用光學各向異性元件60進行之偏光狀態之轉換之於龐加萊球上的軌跡成為北半球抑或南半球之點不同,但光學補償之原理與圖3所示之液晶面板102相同。As shown in FIG. 7, in the E-mode liquid crystal panel 107 in which the absorption axis direction 45 of the second polarizer 40 is orthogonal to the retardation axis direction 63 of the optical anisotropic element 60, the optical anisotropic element 60 is used The point where the transition of the polarization state on the Poincaré sphere becomes the northern or southern hemisphere is different, but the principle of optical compensation is the same as that of the liquid crystal panel 102 shown in FIG. 3.

如上所述,於未考慮彩色濾光片之雙折射之影響之情形時,光學各向異性元件之光學設計並不依存於光學各向異性元件之光軸方向與偏光件之光軸方向所成之角(平行抑或正交)、及液晶單元之初始配向方向與偏光件之光軸方向所成之角(為O模式抑或為E模式)。As described above, when the effect of the birefringence of the color filter is not considered, the optical design of the optical anisotropic element does not depend on the optical axis direction of the optical anisotropic element and the optical axis direction of the polarizer The angle (parallel or orthogonal), and the angle formed by the initial alignment direction of the liquid crystal cell and the optical axis direction of the polarizer (O mode or E mode).

<彩色濾光片之厚度方向延遲> 如上所述,於液晶單元20中設置於液晶層10之視認側之彩色濾光片22之面內之延遲大致為0,但厚度方向具有數nm~數十nm之延遲。於綠色透過區域22G,相對於透過率最高之波長550 nm附近之光之厚度方向延遲對視認性造成影響。同樣之理由,於紅色透過區域22R,相對於透過率較高之波長650 nm附近之光之厚度方向延遲對視認性造成影響。因此,於評估彩色濾光片之厚度方向延遲時,適當的是對於綠色透過區域(綠的彩色濾光片),使用波長550 nm之厚度方向延遲Ct550 進行評估,對於紅色透過區域(紅的彩色濾光片),使用波長650 nm之厚度方向延遲Ct650 進行評估。<Retardation in the thickness direction of the color filter> As described above, the retardation in the plane of the color filter 22 provided on the viewing side of the liquid crystal layer 10 in the liquid crystal cell 20 is approximately 0, but the thickness direction has several nm to several Ten nm delay. In the green transmission region 22G, the retardation in the thickness direction relative to the light near the wavelength with the highest transmittance of 550 nm affects the visibility. For the same reason, in the red transmission region 22R, the retardation in the thickness direction of light at a wavelength near 650 nm with a high transmittance affects visibility. Therefore, when evaluating the retardation in the thickness direction of the color filter, it is appropriate to use the thickness direction retardation Ct 550 with a wavelength of 550 nm for the green transmission region (green color filter), and for the red transmission region (red Color filter), using the thickness direction retardation Ct 650 with a wavelength of 650 nm for evaluation.

為了抑制自傾斜方向視認時之漏光,較佳為彩色濾光片之厚度方向延遲較小。綠色透過區域之波長550 nm之厚度方向延遲Ct550 較佳為50 nm以下,更佳為40 nm以下,進而佳為35 nm以下,特佳為30 nm以下。彩色濾光片之紅色區域之波長650 nm之厚度方向延遲Ct650 較佳為50 nm以下,更佳為40 nm以下,進而佳為35 nm以下,特佳為30 nm以下。彩色濾光片之厚度方向延遲較理想為0,但難以使彩色濾光片之厚度方向延遲完全為0。因此,Ct550 及Ct650 大於0。Ct550 及Ct650 例如可為1 nm以上、3 nm以上或5 nm以上。In order to suppress light leakage when viewed from an oblique direction, it is preferable that the retardation in the thickness direction of the color filter is small. The thickness direction retardation Ct 550 of the wavelength of 550 nm in the green transmission region is preferably 50 nm or less, more preferably 40 nm or less, further preferably 35 nm or less, and particularly preferably 30 nm or less. The thickness direction retardation Ct 650 of the red region of the color filter at a wavelength of 650 nm is preferably 50 nm or less, more preferably 40 nm or less, further preferably 35 nm or less, and particularly preferably 30 nm or less. The retardation in the thickness direction of the color filter is preferably 0, but it is difficult to make the retardation in the thickness direction of the color filter completely zero. Therefore, Ct 550 and Ct 650 are greater than zero. Ct 550 and Ct 650 may be, for example, 1 nm or more, 3 nm or more, or 5 nm or more.

<考慮彩色濾光片之雙折射之光學補償之原理> 首先,參照圖8A,對圖1所示之O模式之液晶面板101之彩色濾光片之厚度方向延遲之影響、及考慮其之光學補償進行說明。自傾斜方向視認之情形時,透過液晶單元20之液晶層10之後之光之偏光狀態由龐加萊球上之點P'0 表示,此與未考慮彩色濾光片之雙折射之情形(圖5)相同。<Principle of optical compensation considering the birefringence of the color filter> First, referring to FIG. 8A, the influence of the thickness direction delay of the color filter of the O-mode liquid crystal panel 101 shown in FIG. 1 and its optical consideration The compensation is explained. When the case where the visibility from the oblique direction, the polarization state of light after transmitted through the liquid crystal layer 10 of liquid crystal cell 20 '0 represented by point P on the Poincare sphere, and this does not consider the case of birefringent color filters (FIG. 5) Same.

透過液晶層之光入射至彩色濾光片22。彩色濾光片之正面延遲大致為0,且具有特定之厚度方向延遲,故可作為具有nx=ny>nz之折射率各向異性之負C板逼近。傾斜方向之光因負C板之厚度方向延遲之影響而使偏光狀態變化,沿龐加萊球上之經線自點P'0 南下而移動至點PCThe light transmitted through the liquid crystal layer enters the color filter 22. The front retardation of the color filter is approximately 0, and has a specific thickness retardation, so it can be approximated as a negative C plate with a refractive index anisotropy of nx=ny>nz. Effect of light due to the oblique direction of the thickness direction retardation of the negative C plate of the polarization state changes from a point on the meridian along the Poincare sphere P '0 south moved to the point P C.

與圖5之情形同樣地,於光學各向異性元件之相位差為π之情形(於龐加萊球上旋轉180°之情形)時,透過光學各向異性元件之光之偏光狀態由圖8A之點P'A 表示,位於龐加萊球之北半球。為了使透過光學各向異性元件50之後之光為赤道上之點PA 表示之直線偏光,必需使由光學各向異性元件所致之於龐加萊球上之旋轉角度大於180°。即,若考慮彩色濾光片之雙折射之影響,則於圖1所示之O模式之液晶面板101上,為了使透過光學各向異性元件50之後之光為直線偏光,必需使光學各向異性元件50之相位差大於π。As in the case of FIG. 5, when the phase difference of the optical anisotropic element is π (the case of 180° rotation on the Poincaré sphere), the polarization state of the light passing through the optical anisotropic element is shown in FIG. 8A the point P 'A represents, located in the northern hemisphere of the Poincare sphere. In order to make the light 50 after transmitted through the optically anisotropic element of the linearly polarized light of a point on the equator represents P A, it is necessary that the optically anisotropic element caused by the rotation angle of the Poincare sphere is greater than 180 °. That is, if the influence of the birefringence of the color filter is considered, in the O-mode liquid crystal panel 101 shown in FIG. 1, in order to make the light passing through the optical anisotropic element 50 linearly polarized, it is necessary to make the optical anisotropy The phase difference of the opposite element 50 is greater than π.

圖8B表示第二偏光件40之吸收軸方向45與光學各向異性元件50之遲相軸方向53正交之圖6之O模式之液晶面板106之光學補償的狀況。透過作為負C板逼近之彩色濾光片22之後之光之偏光狀態與圖8A之情形同樣地,由龐加萊球之南半球之點PC 表示。於光學各向異性元件之相位差為π之情形時,若自點PC 於龐加萊球上順時針方向旋轉半圈而旋轉180°,則通過赤道而到達北半球之點P'A 。為了使透過光學各向異性元件50之後之光為由赤道上之點PA 表示之直線偏光,必需使由光學各向異性元件所致之於龐加萊球上之旋轉角度小於180°。即,若考慮彩色濾光片之雙折射之影響,則於圖6所示之O模式之液晶面板106中,為了使透過光學各向異性元件50之後之光為直線偏光,必需使光學各向異性元件50之相位差小於π。8B shows the state of optical compensation of the O-mode liquid crystal panel 106 of FIG. 6 in which the absorption axis direction 45 of the second polarizer 40 is orthogonal to the retardation axis direction 53 of the optical anisotropic element 50. The polarization state of the light after passing through the color filter 22 approaching as the negative C plate is the same as the case of FIG. 8A, and is represented by the point P C of the southern hemisphere of the Poincare sphere. When the phase difference of the optically anisotropic element of π is the case, if the point P C from the half turn in the clockwise direction of rotation on the Poincare sphere is rotated 180 °, it reaches the point in the northern hemisphere of P 'A by the equator. In order for the light passing through the optical anisotropic element 50 to be linearly polarized light represented by the point P A on the equator, the rotation angle on the Poincaré sphere caused by the optical anisotropic element must be less than 180°. That is, if the influence of the birefringence of the color filter is considered, in the O-mode liquid crystal panel 106 shown in FIG. 6, in order to make the light passing through the optical anisotropic element 50 linearly polarized, it is necessary to make the optical anisotropy The phase difference of the opposite element 50 is less than π.

圖9A表示第二偏光件40之吸收軸方向45與光學各向異性元件60之遲相軸方向63正交之圖7之E模式之液晶面板107之光學補償的狀況。與圖8A及圖8B之情形同樣地,若透過液晶單元之後之光PL 透過作為負C板逼近之彩色濾光片22,則偏光狀態變化,沿龐加萊球上之經線南下。為了使透過彩色濾光片之後之光為直線偏光PA 且由視認側偏光件30吸收,必需使透過液晶單元之後之光PL 位於龐加萊球上之北半球。9A shows the state of optical compensation of the liquid crystal panel 107 in the E mode of FIG. 7 in which the absorption axis direction 45 of the second polarizer 40 is orthogonal to the slow phase axis direction 63 of the optical anisotropic element 60. As in the case of FIGS. 8A and 8B, if the light PL after passing through the liquid crystal cell passes through the color filter 22 approaching as a negative C plate, the polarization state changes and goes south along the meridian on the Poincare sphere. In order that the light transmitted through the color filters after the linearly polarized light 30 is absorbed by the P A and visible side polarizer, it is necessary that on the northern hemisphere of the Poincare sphere of light transmitted through the liquid crystal cell after the P L.

與圖5之情形同樣地,光學各向異性元件之相位差為π,若使透過光源側偏光件之直線偏光P'0 藉由光學各向異性元件而移動至龐加萊球上之點PA ,則透過液晶單元之光之偏光狀態未自PA 變化。然而,透過液晶單元之後之光因彩色濾光片之厚度方向延遲之影響而沿龐加萊球上之經線南下,故透過彩色濾光片之後之光成為位於南半球之橢圓偏光,未由視認側偏光件30吸收之光作為漏光而被視認到。As in the case of FIG. 5, the phase difference of the optical anisotropic element is π. If the linearly polarized light P′ 0 passing through the polarizer on the light source side is moved to the point P on the Poincare sphere by the optical anisotropic element A, the polarization state of light transmitted through the liquid crystal cell does not change from the P A. However, the light after passing through the liquid crystal cell goes south along the meridian on the Poincare sphere due to the retardation of the thickness direction of the color filter, so the light after passing through the color filter becomes elliptically polarized light in the southern hemisphere, which is not recognized The light absorbed by the side polarizer 30 is recognized as light leakage.

圖7所示之E模式之液晶面板107中,如圖9A所示,藉由使光學各向異性元件60之相位差小於π(使由光學各向異性元件所致之於龐加萊球上之旋轉角度小於180°)而能夠進行適當之光學補償。透過相位差小於π之光學各向異性元件之光之偏光狀態由龐加萊球之南半球上之點PR 表示。偏光狀態因液晶層10之相位差之影響而轉換,以軸PA -P'1 為中心於龐加萊球上順時針方向旋轉,故透過液晶層10之後之光之偏光狀態由龐加萊球之北半球上之點PL 表示。如上所述,若透過液晶單元之後之光PL 透過彩色濾光片22,則沿龐加萊球上之經線南下,到達赤道上之點PA 。因此,透過彩色濾光片之後之光PA 由視認側偏光件30適當吸收,從而可防止漏光。In the E-mode liquid crystal panel 107 shown in FIG. 7, as shown in FIG. 9A, by making the phase difference of the optical anisotropic element 60 smaller than π (so that the optical anisotropic element is caused on the Poincare sphere The angle of rotation is less than 180°) and can be properly optically compensated. The polarization state of light transmitted through the phase difference is less than π of the optically anisotropic element is represented by a point on the southern hemisphere of the Poincare sphere P R. Polarization state due to the influence of the retardation of the liquid crystal layer 10 is converted to the axis P A -P '1 in the clockwise direction of rotation as the center on the Poincare sphere, so that the polarization state of light after transmitted through the liquid crystal layer 10 by the Poincare The point P L on the northern hemisphere of the ball indicates. As described above, if the light P L after passing through the liquid crystal cell passes through the color filter 22, it travels south along the meridian on the Poincaré sphere and reaches the point P A on the equator. Thus, the light transmitted through the color filter after P A suitable visible side is absorbed by the polarizer 30, so as to prevent light leakage.

圖9B表示第二偏光件40之吸收軸方向45與光學各向異性元件60之遲相軸方向63平行之圖3之E模式之液晶面板102之光學補償的狀況。液晶面板102中,若使光學各向異性元件60之相位差大於π(使由光學各向異性元件所致之於龐加萊球上之旋轉角度大於180°),則透過光學各向異性元件之後之光之偏光狀態位於龐加萊球之南半球上之點PR 。以後,與圖9A之情形同樣地,藉由透過液晶層10而移動至北半球上之點PL ,藉由透過彩色濾光片22而到達赤道上之點PA ,故透過彩色濾光片之後之光PA 由視認側偏光件30適當吸收。9B shows the state of optical compensation of the liquid crystal panel 102 in the E mode of FIG. 3 in which the absorption axis direction 45 of the second polarizer 40 is parallel to the slow phase axis direction 63 of the optical anisotropic element 60. In the liquid crystal panel 102, if the phase difference of the optical anisotropic element 60 is greater than π (the rotation angle on the Poincare sphere due to the optical anisotropic element is greater than 180°), the optical anisotropic element is transmitted after the polarization state of light of a point located on the southern hemisphere of the Poincare sphere P R. Later, as in the case of FIG. 9A, by moving through the liquid crystal layer 10 to the point P L on the northern hemisphere, by passing through the color filter 22 to reach the point P A on the equator, so after passing through the color filter P A suitable light absorbed by the viewer side polarizer 30.

如上所述,為了藉由光學各向異性元件以抵消彩色濾光片之雙折射之影響之方式進行光學補償,必需根據彩色濾光片之厚度方向延遲之大小而調整光學各向異性元件之相位差。於光源側偏光件之吸收軸方向與光學各向異性元件之遲相軸方向平行之情形時,即,圖1所示之O模式之液晶面板101(參照圖8A)、及圖3所示之E模式之液晶面板102(參照圖9B)中,為進行適當之光學補償,必需使光學各向異性元件之相位差大於π(使延遲大於λ/2)。另一方面,於光源側偏光件之吸收軸方向與光學各向異性元件之遲相軸方向正交之情形時,即,圖6所示之O模式之液晶面板106(參照圖8B)、及圖7所示之E模式之液晶面板107(參照圖9A)中,為進行適當之光學補償,必需使光學各向異性元件之相位差小於π(使延遲小於λ/2)。As described above, in order to compensate optically by the optical anisotropic element in a manner that counteracts the effect of the birefringence of the color filter, it is necessary to adjust the phase of the optical anisotropic element according to the magnitude of the retardation in the thickness direction of the color filter difference. When the absorption axis direction of the light source side polarizer is parallel to the retardation axis direction of the optically anisotropic element, that is, the O-mode liquid crystal panel 101 shown in FIG. 1 (refer to FIG. 8A), and shown in FIG. 3 In the E-mode liquid crystal panel 102 (see FIG. 9B), in order to perform appropriate optical compensation, it is necessary to make the phase difference of the optically anisotropic element greater than π (make the retardation greater than λ/2). On the other hand, in the case where the absorption axis direction of the light source side polarizer is orthogonal to the retardation axis direction of the optically anisotropic element, that is, the O-mode liquid crystal panel 106 shown in FIG. 6 (see FIG. 8B), and In the E-mode liquid crystal panel 107 shown in FIG. 7 (see FIG. 9A), in order to perform appropriate optical compensation, it is necessary to make the phase difference of the optical anisotropic element smaller than π (to make the retardation smaller than λ/2).

[光學各向異性元件之光學設計] 以下,對與液晶單元之彩色濾光片之厚度方向延遲對應之光學各向異性元件之較佳光學特性,夾雜光學模擬之研究結果進行說明。[Optical Design of Optical Anisotropic Components] In the following, the research results of the inclusion optical simulation on the preferable optical characteristics of the optical anisotropic element corresponding to the retardation in the thickness direction of the color filter of the liquid crystal cell are described.

於光學模擬中,使用Shintec公司製造之液晶顯示器用模擬器「LCD MASTER Ver.8.1.0.3」,並使用LCD Master之擴展功能,求出方位角45°、極角60°之方向上之黑顯示之亮度、及黑顯示之CIE1976色空間之色度(u',v')。In the optical simulation, the LCD monitor simulator "LCD MASTER Ver.8.1.0.3" manufactured by Shintec is used, and the extended function of the LCD Master is used to obtain the black display in the direction of azimuth angle 45° and polar angle 60° The brightness, and the chromaticity of the CIE1976 color space of the black display (u', v').

O模式之液晶顯示裝置之模擬中,如圖2所示,將自光源110側依序積層光源側偏光件40、於液晶層10之視認側具備彩色濾光片22之IPS液晶單元20、光學各向異性元件50、及視認側偏光件30而成者作為模擬模型。於E模式之液晶顯示裝置之模擬中,如圖4所示,將自光源110側依序積層光源側偏光件40、光學各向異性元件60、於液晶層10之視認側具備彩色濾光片22之IPS液晶單元20、及視認側偏光件30而成者作為模擬模型。In the simulation of the O-mode liquid crystal display device, as shown in FIG. 2, the light source side polarizer 40 is sequentially stacked from the light source 110 side, the IPS liquid crystal cell 20 having the color filter 22 on the viewing side of the liquid crystal layer 10, and the optical The anisotropic element 50 and the polarizer 30 on the viewing side are used as a simulation model. In the simulation of the E-mode liquid crystal display device, as shown in FIG. 4, the light source side polarizer 40, the optical anisotropic element 60, and the color filter on the viewing side of the liquid crystal layer 10 are sequentially stacked from the light source 110 side The IPS liquid crystal cell 20 of 22 and the polarizer 30 on the viewing side are used as a simulation model.

於模擬中,IPS液晶單元之液晶層之正面延遲設為339 nm,預傾斜角設為0°。光學各向異性元件之Nz係數設為0.5,延遲之波長色散設為Re650 /Re550 =Rt650 /Rt550 =0.95,將Rt650 變更為各種值。彩色濾光片於0~60 nm之範圍按5 nm刻度變更綠色透過區域之波長550 nm之厚度方向延遲Ct550 、及紅色透過區域之波長650 nm之厚度方向延遲Ct650In the simulation, the front retardation of the liquid crystal layer of the IPS liquid crystal cell was set to 339 nm, and the pretilt angle was set to 0°. The Nz coefficient of the optically anisotropic element is set to 0.5, the retarded wavelength dispersion is set to Re 650 /Re 550 =Rt 650 /Rt 550 =0.95, and Rt 650 is changed to various values. The color filter changes the retardation Ct 550 in the thickness direction of the wavelength 550 nm in the green transmission region, and the retardation Ct 650 in the thickness direction of the wavelength 650 nm in the red transmission region in the range of 0 to 60 nm according to the 5 nm scale.

於O模式之液晶面板中,將使Ct650 及Rt650 變更為各種值時之黑顯示之色度示於圖10A及圖10B。於E模式之液晶面板中,將使Ct650 及Rt650 變更為各種值時之黑顯示之色度示於圖11A及圖11B。In the O-mode liquid crystal panel, the chromaticity of black display when Ct 650 and Rt 650 are changed to various values is shown in FIGS. 10A and 10B. In the E-mode liquid crystal panel, the chromaticity of the black display when Ct 650 and Rt 650 are changed to various values is shown in FIGS. 11A and 11B.

圖10A係如圖1所示光源側偏光件40之吸收軸方向45與光學各向異性元件50之遲相軸方向53平行之液晶面板101(關於光學補償原理參照圖8A)之模擬結果。圖10B係如圖6所示光源側偏光件40之吸收軸方向45與光學各向異性元件50之遲相軸方向53正交之液晶面板106(關於光學補償原理參照圖8B)之模擬結果。圖11A係如圖7所示光源側偏光件40之吸收軸方向45與光學各向異性元件60之遲相軸方向63正交之液晶面板107(關於光學補償原理參照圖9A)之模擬結果。圖11B係如圖3所示光源側偏光件40之吸收軸方向45與光學各向異性元件60之遲相軸方向63平行之液晶面板102(關於光學補償原理參照圖9B)之模擬結果。10A is a simulation result of the liquid crystal panel 101 (see FIG. 8A for the principle of optical compensation) in which the absorption axis direction 45 of the light source side polarizer 40 is parallel to the retardation axis direction 53 of the optical anisotropic element 50 as shown in FIG. 1. FIG. 10B is a simulation result of the liquid crystal panel 106 (see FIG. 8B for the principle of optical compensation) in which the absorption axis direction 45 of the light source side polarizer 40 is orthogonal to the retardation axis direction 53 of the optical anisotropic element 50 as shown in FIG. 6. 11A is a simulation result of the liquid crystal panel 107 (see FIG. 9A for the principle of optical compensation) in which the absorption axis direction 45 of the light source side polarizer 40 is orthogonal to the slow phase axis direction 63 of the optical anisotropic element 60 as shown in FIG. 7. 11B is a simulation result of the liquid crystal panel 102 in which the absorption axis direction 45 of the light source side polarizer 40 is parallel to the retardation axis direction 63 of the optical anisotropic element 60 as shown in FIG. 3 (refer to FIG. 9B for the principle of optical compensation).

如圖10B及圖11A所示,於光源側偏光件之吸收軸方向與光學各向異性元件之遲相軸方向正交之情形時,發現隨著彩色濾光片之紅色透過區域之厚度方向延遲Ct650 變大,使光學各向異性元件之厚度方向延遲Rt650 變化時之u'之最大值變小的傾向。又,於Ct650 為0~60 nm之範圍中,不管光學各向異性元件之厚度方向延遲Rt650 之值如何,u'均不會超過0.35。即,可知於光源側偏光件之吸收軸方向與光學各向異性元件之遲相軸方向正交之情形時,圖6所示之O模式之液晶面板106及圖7所示之E模式之液晶面板107之任一者,自傾斜方向視認時黑顯示之畫面均未顯著地著色成紅色。As shown in FIGS. 10B and 11A, when the absorption axis direction of the light source side polarizer is orthogonal to the retardation axis direction of the optical anisotropic element, it is found that the thickness direction of the red transmission region of the color filter is retarded As Ct 650 becomes larger, the maximum value of u′ when the retardation of Rt 650 changes in the thickness direction of the optical anisotropic element tends to be smaller. In addition, in the range of Ct 650 from 0 to 60 nm, regardless of the value of the retardation Rt 650 in the thickness direction of the optically anisotropic element, u'will not exceed 0.35. That is, when the absorption axis direction of the light source side polarizer is orthogonal to the retardation axis direction of the optical anisotropic element, the O-mode liquid crystal panel 106 shown in FIG. 6 and the E-mode liquid crystal shown in FIG. 7 When any one of the panels 107 is viewed from the oblique direction, the black-displayed picture is not significantly colored red.

另一方面,如圖10A及圖11B所示,於光源側偏光件之吸收軸方向與光學各向異性元件之遲相軸方向平行之情形時,發現隨著彩色濾光片之紅色透過區域之厚度方向延遲Ct650 變大,使光學各向異性元件之厚度方向延遲Rt650 變化時之u'之最大值變大傾的向。又,圖10A及圖11B中,與圖10B及圖11A相比,u'依存於彩色濾光片之紅色透過區域之厚度方向延遲Ct650 及光學各向異性元件之厚度方向延遲Rt650 而較大地變化,且亦發現超過0.35之情形。On the other hand, as shown in FIGS. 10A and 11B, when the absorption axis direction of the light source side polarizer is parallel to the retardation axis direction of the optically anisotropic element, it is found that The thickness direction retardation Ct 650 becomes larger, so that the thickness direction of the optical anisotropic element retards the maximum value of u′ when the Rt 650 changes. In addition, in FIGS. 10A and 11B, compared with FIGS. 10B and 11A, u′ depends on the thickness direction retardation Ct 650 of the red transmission region of the color filter and the thickness direction retardation Rt 650 of the optical anisotropic element. The earth changed, and it was found to exceed 0.35.

根據該等結果可知,於光源側偏光件之吸收軸方向與光學各向異性元件之遲相軸方向平行之情形時,圖1所示之O模式之液晶面板101及圖3所示之E模式之液晶面板102之任一者,均因彩色濾光片之紅色透過區域之雙折射之影響,而自傾斜方向視認時,黑顯示著色成紅色。即,可知於光源側偏光件之吸收軸方向與光學各向異性元件之遲相軸方向平行之液晶面板中,於考慮彩色濾光片之雙折射之影響而進行光學補償之情形時,除減小綠色之漏光而提高對比度之外,還需以降低因紅色之漏光導致之黑顯示之著色之方式進行光學各向異性元件之光學設計。From these results, it can be seen that the O-mode liquid crystal panel 101 shown in FIG. 1 and the E-mode shown in FIG. 3 when the absorption axis direction of the light source side polarizer is parallel to the slow phase axis direction of the optically anisotropic element Any one of the liquid crystal panels 102 is affected by the birefringence of the red transmission area of the color filter, and when viewed from the oblique direction, the black display is colored red. That is, in a liquid crystal panel in which the absorption axis direction of the light source side polarizer is parallel to the retardation axis direction of the optically anisotropic element, when the optical compensation is performed considering the effect of the birefringence of the color filter, the reduction In addition to the small green light leakage to improve the contrast, the optical design of the optically anisotropic element needs to be carried out in a manner that reduces the coloration of the black display caused by the red light leakage.

<第一實施形態:O模式之液晶面板之光學設計> (色度之調整) 圖12係根據圖1所示之O模式之液晶面板101之模擬結果,將黑顯示之色度成為特定值之條件繪圖而成之曲線圖。橫軸為彩色濾光片之紅色透過區域之波長650 nm之厚度方向延遲Ct650 ,縱軸為光學各向異性元件之波長650 nm之厚度方向延遲Rt650 。於各個Ct650 ,將方位角45°、極角60°之方向上之黑顯示之色度u'成為0.35之點以塗黑之圓標記及塗黑之三角標記表示。於Rt650 位於塗黑之圓標記與塗黑之三角標記之間之情形時,u'超過0.35,黑顯示著色成紅色而被視認到。於Rt650 位於相較塗黑之圓標記更靠上側、或相較塗黑之三角標記更靠下側之情形時,u'未達0.35,可抑制黑顯示之紅色著色。<First embodiment: Optical design of O-mode liquid crystal panel> (Adjustment of chromaticity) FIG. 12 is based on the simulation results of the O-mode liquid crystal panel 101 shown in FIG. 1, and the chromaticity of the black display becomes a specific value Conditional drawing. The horizontal axis is the thickness direction retardation Ct 650 of the wavelength 650 nm of the red transmission region of the color filter, and the vertical axis is the thickness direction retardation Rt 650 of the optical anisotropic element at the wavelength 650 nm. At each Ct 650 , the point where the chromaticity u'of the black display in the direction of the azimuth angle 45° and the polar angle 60° becomes 0.35 is indicated by a black circle mark and a black triangle mark. When Rt 650 is located between the black circle mark and the black triangle mark, u'exceeds 0.35, and the black display is colored red and is recognized. When Rt 650 is on the upper side of the black circle mark or on the lower side of the black triangle mark, u'does not reach 0.35, which can suppress the red coloration of black display.

由圖12可理解,u'=0.35之分界之上限側及下限側均能以直線逼近。曲線圖中之直線由下述之式(1)及式(2)表示: Rt650 =0.37(Ct650 )+116...(1) Rt650 =-0.44(Ct650 )+116...(2)。It can be understood from FIG. 12 that both the upper limit side and the lower limit side of the boundary of u′=0.35 can be approached with a straight line. The straight line in the graph is represented by the following formula (1) and formula (2): Rt 650 = 0.37 (Ct 650 ) +116... (1) Rt 650 = -0.44 (Ct 650 ) +116... (2 ).

因此,彩色濾光片22之紅色透過區域22R之波長650 nm之厚度方向延遲Ct650 、與光學各向異性元件50之波長650 nm厚度方向延遲Rt650 滿足下述式(1a)或(2a)之情形時,u'成為0.35以下,可實現紅色調經降低之黑顯示。 Rt650 ≧0.37(Ct650 )+116...(1a) Rt650 ≦-0.44(Ct650 )+116...(2a)。Therefore, the red-transmissive region 22R of the color filter 22 has a thickness direction retardation Ct 650 at a wavelength of 650 nm, and the wavelength anisotropy element 50 has a thickness direction retardation Rt 650 at a wavelength of 650 nm that satisfies the following formula (1a) or (2a) In this case, u'becomes 0.35 or less, and black display with reduced red tone can be realized. Rt 650 ≧0.37(Ct 650 )+116...(1a) Rt 650 ≦-0.44(Ct 650 )+116...(2a).

圖12之塗白之圓標記及塗白之三角標記表示黑顯示之色度u'成為0.314之點。於Rt650 位於塗白之圓標記與塗黑之圓標記之間之情形時,u'為0.314~0.35,於Rt650 位於相較塗白之圓標記更靠上側之情形時,u'小於0.314。同樣地,於Rt650 位於塗白之三角標記與塗黑之三角標記之間之情形時,u'為0.314~0.35,於Rt650 位於相較塗白之三角標記更靠下側之情形時,u'小於0.314。The white-coated circle mark and the white-coated triangle mark in FIG. 12 indicate the point where the chromaticity u′ of the black display becomes 0.314. When Rt 650 is located between the white circle mark and the black circle mark, u'is 0.314~0.35, and when Rt 650 is located above the white circle mark, u'is less than 0.314 . Similarly, when Rt 650 is located between the white triangle mark and the black triangle mark, u'is 0.314 to 0.35, and when Rt 650 is positioned lower than the white triangle mark, u'is less than 0.314.

由塗白之圓標記表示之u'=0.314之分界能以與上述式(1)平行之直線:Rt650 =0.37(Ct650 )+121逼近。由塗白之三角標記表示之u'=0.314之分界能以與上述式(2)平行之直線:Rt650 =-0.44(Ct650 )+108逼近。The boundary of u'=0.314 represented by the white circle mark can be approximated by a straight line parallel to the above formula (1): Rt 650 = 0.37(Ct 650 )+121. The boundary of u'=0.314 represented by the white triangle mark can be approximated by a straight line parallel to the above formula (2): Rt 650 =-0.44(Ct 650 )+108.

因此,於彩色濾光片之紅色透過區域之波長650 nm之厚度方向延遲Ct650 、與光學各向異性元件之波長650 nm之厚度方向延遲Rt650 滿足下述式(1b)或(2b)之情形時,u'成為0.314以下,可實現紅色調經進一步降低之黑顯示。 Rt650 ≧0.37(Ct650 )+121...(1b) Rt650 ≦-0.44(Ct650 )+108...(2b)。Therefore, the retardation Ct 650 in the thickness direction of the wavelength 650 nm in the red transmission region of the color filter and the retardation Rt 650 in the thickness direction of the wavelength 650 nm of the optical anisotropic element satisfy the following formula (1b) or (2b) In this case, u'becomes 0.314 or less, and black display with a further reduction in red tone can be realized. Rt 650 ≧0.37(Ct 650 )+121...(1b) Rt 650 ≦-0.44(Ct 650 )+108...(2b).

根據上述結果,可謂於圖1所示之O模式之液晶面板中,於Ct650 與Rt650 滿足下述式(1c)或(2c)之情形時,可實現紅色調經降低之黑顯示。 Rt650 ≧0.37(Ct650 )+C1 ...(1c) Rt650 ≦-0.44(Ct650 )+C2 ...(2c)。Based on the above results, it can be said that in the O-mode liquid crystal panel shown in FIG. 1, when Ct 650 and Rt 650 satisfy the following formula (1c) or (2c), black display with a reduced red tone can be realized. Rt 650 ≧0.37(Ct 650 )+C 1 ...(1c) Rt 650 ≦-0.44(Ct 650 )+C 2 ...(2c).

如上所述,將u'=0.35作為分界之情形時,式(1c)之C1 為116 nm,式(2c)之C2 為116 nm。換言之,於以滿足u'≦0.35之方式設定條件之情形時,如上述式(1a)及式(2a)般,使C1 =116 nm、C2 =116 nm即可。根據相同之觀點,於以滿足u'≦0.314之方式設定條件之情形時,如上述式(1b)及式(2b)般,使C1 =121 nm、C2 =108 nm即可。為了進一步減小黑顯示之u',將C1 較大地設定,且將C2 較小地設定即可。As described above, when u'=0.35 is used as the boundary, C 1 in equation (1c) is 116 nm, and C 2 in equation (2c) is 116 nm. In other words, in the case where the condition is set in a manner satisfying u′≦0.35, it is sufficient to set C 1 =116 nm and C 2 =116 nm as in the above formula (1a) and formula (2a). From the same point of view, when the condition is set in such a way that u'≦0.314 is satisfied, it is sufficient to set C 1 =121 nm and C 2 =108 nm as in the above formula (1b) and formula (2b). In order to further reduce the u'of the black display, it is sufficient to set C 1 larger and C 2 smaller.

式(1c)之C1 可為116以上之任意之數。C1 亦可為116 nm、121 nm、124 nm、126 nm、128 nm、130 nm、132 nm、134 nm、136 nm、138 nm、或140 nm。同樣地,式(2c)之C2 可為116以下之任意之數。C2 亦可為116 nm、112 nm、108 nm、105 nm、102 nm、100 nm、98 nm、96 nm、94 nm、92 nm、或90 nm。C 1 in formula (1c) can be any number above 116. C 1 may also be 116 nm, 121 nm, 124 nm, 126 nm, 128 nm, 130 nm, 132 nm, 134 nm, 136 nm, 138 nm, or 140 nm. Similarly, C 2 in formula (2c) may be any number below 116. C 2 may also be 116 nm, 112 nm, 108 nm, 105 nm, 102 nm, 100 nm, 98 nm, 96 nm, 94 nm, 92 nm, or 90 nm.

就減小自傾斜方向視認時之黑顯示之色度u'之觀點而言,光學各向異性元件50之波長650 nm之Rt650 若滿足上述式(1c)或(2c),則其上限或下限並未特別限定。然而,如下所述,若考慮用以使黑亮度降低之Rt550 之範圍、及光學各向異性元件50之延遲之波長色散Rt650 /Rt550 ,則Rt650 之上限及下限自然會被決定。From the viewpoint of reducing the chromaticity u'of black display when viewed from the oblique direction, if the Rt 650 of the optical anisotropic element 50 at a wavelength of 650 nm satisfies the above formula (1c) or (2c), the upper limit or The lower limit is not particularly limited. However, as will be described below, if the range of Rt 550 for reducing the black brightness and the wavelength dispersion Rt 650 /Rt 550 of the retardation of the optical anisotropic element 50 are considered, the upper and lower limits of Rt 650 will naturally be determined.

(亮度之調整) 如上所述,藉由根據彩色濾光片之厚度方向延遲Ct650 調整光學各向異性元件之Rt650 而抑制紅色之漏光,從而可降低黑顯示之u'。另一方面,為了使黑顯示時之漏光量(黑亮度)降低,較佳為以使比視感度較高之綠色光之漏光變小之方式進行光學設計。(Adjustment of Brightness) As described above, by adjusting the Rt 650 of the optically anisotropic element according to the thickness direction retardation Ct 650 of the color filter, red light leakage is suppressed, thereby reducing the u'of black display. On the other hand, in order to reduce the amount of light leakage (black brightness) at the time of black display, it is preferable to perform optical design in such a manner that the light leakage of green light having a higher specific visual sensitivity is reduced.

圖13係根據圖1所示之O模式之液晶面板101之模擬結果,將黑亮度成為特定值之條件繪圖而成之曲線圖。橫軸為彩色濾光片之綠色透過區域之波長550 nm之厚度方向延遲Ct550 ,縱軸為光學各向異性元件之波長550 nm之厚度方向延遲Rt550 。於各個Ct550 ,將方位角45°、極角60°之方向上之黑亮度具有相同之Ct550 、且成為未使用光學各向異性元件之液晶顯示裝置之一半之點以塗黑之圓標記及塗黑之三角標記表示。於Rt550 位於塗黑之圓標記與塗黑之三角標記之間之情形時,與不具有光學各向異性元件之情形相比,自傾斜方向視認時之黑亮度降低至一半以下。FIG. 13 is a graph obtained by plotting the condition that the black brightness becomes a specific value according to the simulation result of the O-mode liquid crystal panel 101 shown in FIG. 1. The horizontal axis is the thickness direction retardation Ct 550 at the wavelength of 550 nm in the green transmission region of the color filter, and the vertical axis is the thickness direction retardation Rt 550 at the wavelength 550 nm of the optically anisotropic element. For each Ct 550 , the black brightness in the direction of the azimuth angle 45° and the polar angle 60° has the same Ct 550 , and it is a half of the point of the liquid crystal display device that does not use the optical anisotropic element is marked with a black circle And the black triangle mark indicates. In the case where Rt 550 is located between the blackened round mark and the blackened triangular mark, the black brightness when viewed from the oblique direction is reduced to less than half compared to the case without an optically anisotropic element.

由圖13而可理解,與未使用光學各向異性元件之情形相比,黑亮度成為1/2之區域之分界之上限側及下限側均能以直線逼近。曲線圖中之直線由下述式(3)及式(4)表示: Rt550 =0.97(Ct550 )+73...(3) Rt550 =0.49(Ct550 )+205...(4)。As can be understood from FIG. 13, compared with the case where the optical anisotropic element is not used, both the upper limit side and the lower limit side of the boundary of the region where the black brightness becomes 1/2 can be approached with a straight line. The straight line in the graph is represented by the following formula (3) and formula (4): Rt 550 = 0.97 (Ct 550 ) + 73... (3) Rt 550 = 0.49 (Ct 550 ) + 205 ... (4).

因此,於彩色濾光片22之綠色透過區域22G之波長550 nm之厚度方向延遲Ct550 、與光學各向異性元件50之波長550 nm之厚度方向延遲Rt550 滿足下述式(3a)之情形時,與未使用光學各向異性元件之情形相比,傾斜方向之黑亮度成為1/2以下。 0.97(Ct550 )+73≦Rt550 ≦0.49(Ct550 )+205...(3a)。Therefore, the retardation Ct 550 in the thickness direction of the wavelength 550 nm of the green transmission region 22G of the color filter 22 and the retardation Rt 550 in the thickness direction of the wavelength 550 nm of the optical anisotropic element 50 satisfy the following formula (3a) When compared with the case where no optical anisotropic element is used, the black luminance in the oblique direction becomes 1/2 or less. 0.97(Ct 550 )+73≦Rt 550 ≦0.49(Ct 550 )+205...(3a).

圖13之塗白之圓標記及塗白之三角標記表示黑亮度成為未使用光學各向異性元件之液晶顯示裝置之黑亮度之1/5之點。於Rt550 位於塗白之圓標記與塗白之三角標記之間之情形時,與不具有光學各向異性元件之情形相比,黑亮度降低至1/5以下。The white-coated circle mark and the white-coated triangle mark in FIG. 13 indicate that the black brightness becomes 1/5 of the black brightness of the liquid crystal display device that does not use the optically anisotropic element. In the case where Rt 550 is located between the white-coated round mark and the white-coated triangular mark, the black brightness is reduced to less than 1/5 compared to the case without an optically anisotropic element.

以塗白之圓標記表示之分界能以與上述式(3)平行之直線:Rt550 =0.97(Ct550 )+98逼近。以塗白之三角標記表示之分界能以與上述式(4)平行之直線:Rt550 =0.49(Ct550 )+180逼近。因此,於彩色濾光片之綠色透過區域之波長550 nm之厚度方向延遲Ct550 、與光學各向異性元件之波長550 nm之厚度方向延遲Rt550 滿足下述式(3b)之情形時,與未使用光學各向異性元件之情形相比較,可使黑亮度降低至1/5以下,實現對比度較高之顯示。 0.97(Ct550 )+98≦Rt550 ≦0.49(Ct550 )+180...(3b)。The boundary indicated by the white circle mark can be approximated by a straight line parallel to the above formula (3): Rt 550 = 0.97 (Ct 550 ) + 98. The boundary indicated by the white triangle mark can be approximated by a straight line parallel to the above formula (4): Rt 550 = 0.49 (Ct 550 ) + 180. Therefore, when the retardation Ct 550 in the thickness direction of the wavelength 550 nm in the green transmission region of the color filter and the retardation Rt 550 in the thickness direction of the wavelength 550 nm of the optical anisotropic element satisfy the following formula (3b), and Compared with the case where no optical anisotropic element is used, the black brightness can be reduced to less than 1/5, and a display with higher contrast can be realized. 0.97(Ct 550 )+98≦Rt 550 ≦0.49(Ct 550 )+180...(3b).

根據上述結果,可謂於圖1所示之O模式之液晶面板中,於Ct550 與Rt550 滿足下述式(3c)之情形時,可消除彩色濾光片之雙折射之影響,實現傾斜方向之黑亮度經降低之顯示。 0.97(Ct550 )+C3 ≦Rt550 ≦0.49(Ct550 )+C4 ...(3c)Based on the above results, it can be said that in the O-mode liquid crystal panel shown in FIG. 1, when Ct 550 and Rt 550 satisfy the following formula (3c), the influence of the birefringence of the color filter can be eliminated and the tilt direction can be achieved The display with reduced black brightness. 0.97(Ct 550 )+C 3 ≦Rt 550 ≦0.49(Ct 550 )+C 4 ...(3c)

如上所述,將黑亮度設為未使用光學各向異性元件之液晶顯示裝置之黑亮度之1/2以下之情形時,如上述式(3a)般,設為C3 =73 nm、C4 =205 nm即可。根據相同之觀點,將黑亮度設為未使用光學各向異性元件之液晶顯示裝置之黑亮度之1/5以下之情形時,如上述式(3b)般,設為C3 =98、C4 =180 nm即可。為了進一步減小傾斜方向之黑亮度,將C3 較大地設定,且將C4 較小地設定即可。式(3c)之C3 可為73以上之任意之數。C3 亦可為73 nm、88 nm、98 nm、108 nm、113 nm、118 nm、123 nm、或128 nm。同樣地,式(3c)之C4 可為205以下之任意之數。C4 亦可為205 nm、190 nm、180 nm、173 nm、168 nm、163 nm、158 nm、153 nm、或148 nm。As described above, when the black brightness is set to be 1/2 or less of the black brightness of the liquid crystal display device not using the optical anisotropic element, as in the above formula (3a), C 3 = 73 nm, C 4 = 205 nm. From the same point of view, when the black brightness is set to 1/5 or less of the black brightness of the liquid crystal display device that does not use an optically anisotropic element, as in the above formula (3b), C 3 =98, C 4 = 180 nm. In order to further reduce the black brightness in the oblique direction, it is sufficient to set C 3 to a large value, and to set C 4 to a small value. C 3 in formula (3c) can be any number above 73. C 3 may also be 73 nm, 88 nm, 98 nm, 108 nm, 113 nm, 118 nm, 123 nm, or 128 nm. Similarly, C 4 in formula (3c) can be any number below 205. C 4 can also be 205 nm, 190 nm, 180 nm, 173 nm, 168 nm, 163 nm, 158 nm, 153 nm, or 148 nm.

如圖13所示,彩色濾光片之厚度方向延遲Ct550 越大,則用以使自傾斜方向視認時之黑亮度降低之光學各向異性元件之Rt550 之最佳值越大。此亦可根據圖8A所示之光學補償之原理而理解。彩色濾光片之厚度方向延遲Ct550 較大,此對應於圖8A中P'0 與PC 之距離較大(PC 之南緯較大)。PC 之南緯越較大地偏離赤道,為了使透過光學各向異性元件50之後之光移動至龐加萊球之赤道上,必需使光學各向異性元件之相位差越大。因此,如圖13所示,Ct550 越大,為了使黑亮度降低而必需使Rt550 越大。As shown in FIG. 13, the greater the thickness direction delay Ct 550 of the color filter, the greater the optimal value of Rt 550 of the optically anisotropic element for reducing the black brightness when viewed from the oblique direction. This can also be understood according to the principle of optical compensation shown in FIG. 8A. The color filter of the thickness direction retardation larger Ct 550, this corresponds to P '(P C of greater latitude) from 0 to P C of greater FIG 8A. P C deviates significantly from the latitude of the equator, then in order to make the light transmitted through the optical anisotropy of the element 50 moves to the equator on the Poincare sphere, it is necessary that the retardation of the optically anisotropic element increases. Therefore, as shown in FIG. 13, the larger Ct 550 is, the larger Rt 550 must be in order to reduce the black luminance.

(黑亮度降低與色度之兼顧) 為了降低自傾斜方向視認時之黑亮度,根據彩色濾光片之厚度方向延遲Ct550 ,以滿足上述式(3c)之方式設定光學各向異性元件之Rt550 ,且以滿足上述式(1c)或(2c)之方式設定光學各向異性元件之Rt650 即可。然而,Rt550 及Rt650 並非可個別地設定各者,Rt650 /Rt550 為與光學各向異性元件之延遲之波長色散對應之固定之值。(Both black brightness reduction and chromaticity are combined) In order to reduce the black brightness when viewed from the oblique direction, the Ct 550 is retarded according to the thickness direction of the color filter to set the Rt of the optically anisotropic element in a manner satisfying the above formula (3c) 550 , and the Rt 650 of the optically anisotropic element may be set in a manner satisfying the above formula (1c) or (2c). However, Rt 550 and Rt 650 cannot be individually set, and Rt 650 /Rt 550 is a fixed value corresponding to the wavelength dispersion of the retardation of the optically anisotropic element.

例如,於彩色濾光片之綠色透過區域之厚度方向延遲Ct550 為10 nm之情形時,若光學各向異性元件之Rt550 為130 nm,則自傾斜方向視認時之黑亮度較小,能實現高對比度之顯示。如上述模擬中所設定,於光學各向異性元件具有Rt650 /Rt550 =0.95之波長色散之情形時,若Rt550 =130 nm,則Rt650 =124 nm。For example, when the Ct 550 retardation in the thickness direction of the green transmission region of the color filter is 10 nm, if the Rt 550 of the optically anisotropic element is 130 nm, the black brightness when viewed from the oblique direction is small, and Achieve high-contrast display. As set in the above simulation, when the optically anisotropic element has a wavelength dispersion of Rt 650 /Rt 550 =0.95, if Rt 550 =130 nm, then Rt 650 =124 nm.

由於紅色彩色濾光片與綠色彩色濾光片之材料不同,故兩者之Rth不同,有紅色彩色濾光片之Ct650 大於綠色彩色濾光片之Ct550 之情形。例如,若彩色濾光片22之紅色透過區域22R之厚度方向延遲Ct650 為30 nm,則於Rt650 =124 nm之情形時,均不滿足上述式(1a)及式(1b)之任一者,自傾斜方向視認時之色度u'超過0.35,黑顯示著色成紅色而被視認到。Since the materials of the red color filter and the green color filter are different, the Rth of the two is different. In some cases, the Ct 650 of the red color filter is greater than the Ct 550 of the green color filter. For example, if the retardation Ct 650 in the thickness direction of the red transmission region 22R of the color filter 22 is 30 nm, then in the case of Rt 650 = 124 nm, neither of the above formulas (1a) and (1b) is satisfied In addition, the chromaticity u′ when viewed from the oblique direction exceeds 0.35, and the black display is colored red and is recognized.

由上述例而可理解,於圖1所示之O模式之液晶面板中,即便以黑亮度變小之方式進行光學各向異性元件之光學設計,亦有黑顯示之色度u'變大,黑顯示著色成紅色之情形。相對於此,考慮彩色濾光片之厚度方向延遲Ct550 及Ct650 、以及光學各向異性元件之延遲之波長色散Rt650 /Rt550 ,以滿足上述式(3c)(此處,C3 為73 nm以上,C4 為205 nm以下)、且滿足上述式(1c)或(2c)之方式(此處,C1 為116 nm以上,C2 為116 nm以下)設定光學各向異性元件之厚度方向延遲即可。It can be understood from the above example that in the O-mode liquid crystal panel shown in FIG. 1, even if the optical design of the optical anisotropic element is performed in such a manner that the black brightness becomes smaller, the chromaticity u'of the black display becomes larger, Black shows the coloring of red. On the other hand, consider the retardation in the thickness direction of the color filter Ct 550 and Ct 650 , and the retardation wavelength dispersion Rt 650 /Rt 550 of the optical anisotropic element to satisfy the above formula (3c) (here, C 3 is 73 nm or more, C 4 is 205 nm or less), and satisfies the above formula (1c) or (2c) (here, C 1 is 116 nm or more, C 2 is 116 nm or less) to set the optical anisotropic element The thickness direction can be delayed.

再者,相位差膜之厚度方向延遲之波長色散Rt650 /Rt550 一般與正面延遲之波長色散Re650 /Re550 大致相等,為0.8~1.2之範圍內。若考慮一般的波長色散之範圍,則於Ct650 為10 nm以上之情形時,Rt550 滿足式(3c),且Rt650 滿足式(2c)之情形較少。因此,較佳為以使Rt550 滿足上述式(3c),且Rt650 滿足上述式(1c)之方式設定光學各向異性元件之延遲。In addition, the wavelength dispersion Rt 650 /Rt 550 retarded in the thickness direction of the retardation film is generally substantially equal to the wavelength dispersion Re 650 /Re 550 retarded in the front side, and is in the range of 0.8 to 1.2. Considering the general range of wavelength dispersion, when Ct 650 is above 10 nm, Rt 550 satisfies equation (3c), and Rt 650 satisfies equation (2c) rarely. Therefore, it is preferable to set the retardation of the optically anisotropic element such that Rt 550 satisfies the above formula (3c) and Rt 650 satisfies the above formula (1c).

光學各向異性元件50之正面延遲Re550 及Re650 以使Rt550 及Rt650 成為上述範圍之方式設定即可。如上所述,光學各向異性元件50之厚度方向延遲Rt相對於正面延遲Re之比Nz=Rt/Re為0.2~0.8,故於該約束條件下,根據光學各向異性元件之厚度方向延遲Rt550 及Rt650 、以及Nz係數而設定正面延遲Re550 及Re650The front retardation Re 550 and Re 650 of the optical anisotropic element 50 may be set so that Rt 550 and Rt 650 fall within the above range. As described above, the ratio of the thickness direction retardation Rt of the optical anisotropic element 50 to the front retardation Re is Nz=Rt/Re of 0.2 to 0.8, so under this constraint, the thickness direction retardation Rt of the optical anisotropic element 550 and Rt 650 and the Nz coefficient set the positive retardation Re 550 and Re 650 .

具體而言,光學各向異性元件50之波長650 nm之正面延遲Re650 較佳為Rt650 之2倍左右。因此,Re650 較佳為滿足下述式(1d)或(2d)。 Re650 ≧0.74(Ct650 )+C11 ...(1d) Re650 ≦-0.88(Ct650 )+C12 ...(2d)。Specifically, the front retardation Re 650 of the optical anisotropic element 50 at a wavelength of 650 nm is preferably about twice the Rt 650 . Therefore, Re 650 preferably satisfies the following formula (1d) or (2d). Re 650 ≧0.74(Ct 650 )+C 11 ...(1d) Re 650 ≦-0.88(Ct 650 )+C 12 ...(2d).

C11 為C1 之2倍,具體而言,C11 為232 nm以上。C11 亦可為232 nm、236 nm、242 nm、248 nm、252 nm、256 nm、260 nm、264 nm、268 nm、272 nm、276 nm、或280 nm。C12 為C2 之2倍,具體而言,C12 為232 nm以下。C12 亦可為232 nm、224 nm、216 nm、210 nm、204 nm、200 nm、196 nm、192 nm、188 nm、184 nm、或180 nm。若考慮光學各向異性元件之延遲之波長色散,則光學各向異性元件50之Re650 較佳為滿足上述式(1d)。C 11 is twice that of C 1 , specifically, C 11 is 232 nm or more. C 11 may also be 232 nm, 236 nm, 242 nm, 248 nm, 252 nm, 256 nm, 260 nm, 264 nm, 268 nm, 272 nm, 276 nm, or 280 nm. C 12 is twice that of C 2 , specifically, C 12 is 232 nm or less. C 12 can also be 232 nm, 224 nm, 216 nm, 210 nm, 204 nm, 200 nm, 196 nm, 192 nm, 188 nm, 184 nm, or 180 nm. Considering the delayed wavelength dispersion of the optical anisotropic element, Re 650 of the optical anisotropic element 50 preferably satisfies the above formula (1d).

光學各向異性元件50之波長550 nm之正面延遲Re550 較佳為Rt550 之2倍左右。因此,Re550 較佳為滿足下述式(3d): 1.94(Ct550 )+C13 ≦Re550 ≦0.98(Ct550 )+C14 ...(3d)。The front retardation Re 550 of the optical anisotropic element 50 at a wavelength of 550 nm is preferably about twice the Rt 550 . Therefore, Re 550 preferably satisfies the following formula (3d): 1.94 (Ct 550 ) + C 13 ≦ Re 550 ≦ 0.98 (Ct 550 ) + C 14 ... (3d).

C13 為C3 之2倍,具體而言,C13 為146 nm以上。C13 亦可為145 nm、175 nm、185 nm、215 nm、225 nm、235 nm、245 nm、或255 nm。C14 為C4 之2倍,具體而言,C14 為410 nm以下。C14 亦可為410 nm、380 nm、360 nm、345 nm、335 nm、325 nm、315 nm、305 nm、或295 nm。C 13 is twice that of C 3 , specifically, C 13 is 146 nm or more. C 13 may also be 145 nm, 175 nm, 185 nm, 215 nm, 225 nm, 235 nm, 245 nm, or 255 nm. C 14 is twice that of C 4. Specifically, C 14 is 410 nm or less. C 14 may also be 410 nm, 380 nm, 360 nm, 345 nm, 335 nm, 325 nm, 315 nm, 305 nm, or 295 nm.

<第二實施形態:E模式之液晶面板之光學設計> 圖14係根據圖3所示之E模式之液晶面板102之模擬結果,將黑顯示之色度成為特定值之條件繪圖而成之曲線圖。與圖12同樣地,將方位角45°、極角60°之方向上之黑顯示之色度u'成為0.35之點以塗黑之圓標記及塗黑之三角標記表示,將黑顯示之色度u'成為0.314之點以塗白之圓標記及塗白之三角標記表示。<Second Embodiment: Optical Design of E-mode LCD Panel> FIG. 14 is a graph obtained by plotting the condition that the chromaticity of the black display becomes a specific value according to the simulation result of the E-mode liquid crystal panel 102 shown in FIG. 3. As in FIG. 12, the point where the chromaticity u'of the black display in the direction of the azimuth angle 45° and the polar angle 60° becomes 0.35 is indicated by the black circle mark and the black triangle mark, and the black display color The point where the degree u'becomes 0.314 is indicated by a white circle mark and a white triangle mark.

與圖12之情形同樣地,圖14中u'=0.35之分界亦能以下述式(6)及式(7)表示之直線逼近: Rt650 =0.37(Ct650 )+116...(6) Rt650 =-0.44(Ct650 )+120...(7)。As in the case of FIG. 12, the boundary of u′=0.35 in FIG. 14 can also be approximated by a straight line expressed by the following formula (6) and formula (7): Rt 650 =0.37(Ct 650 )+116...(6) Rt 650 = -0.44 (Ct 650 ) + 120... (7).

因此,於液晶面板102中,於彩色濾光片22之紅色透過區域22R之波長650 nm之厚度方向延遲Ct650 、與光學各向異性元件50之波長650 nm之厚度方向延遲Rt650 滿足下述式(6a)或(7a)之情形時,u'成為0.35以下,可實現紅色調經降低之黑顯示。 Rt650 ≧0.37(Ct650 )+116...(6a) Rt650 ≦-0.44(Ct650 )+120...(7a)。Therefore, in the liquid crystal panel 102, the thickness direction retardation Ct 650 at the wavelength 650 nm of the red transmission region 22R of the color filter 22 and the thickness direction retardation Rt 650 at the wavelength 650 nm of the optical anisotropic element 50 satisfy the following In the case of formula (6a) or (7a), u'becomes 0.35 or less, and a black display with a reduced red tone can be realized. Rt 650 ≧0.37(Ct 650 )+116...(6a) Rt 650 ≦-0.44(Ct 650 )+120...(7a).

再者,式(6)與關於O模式之液晶面板101之式(1)相同。式(7)以與關於O模式之液晶面板101之式(2)平行之直線表示。圖14中,作為參考,以虛線表示式(2)之直線。Furthermore, equation (6) is the same as equation (1) for the liquid crystal panel 101 of the O mode. Equation (7) is expressed by a straight line parallel to Equation (2) of the liquid crystal panel 101 of the O mode. In FIG. 14, as a reference, a straight line of formula (2) is indicated by a broken line.

以塗白之圓標記表示之u'=0.314之分界能以與上述式(6)平行之直線:Rt650 =0.37(Ct650 )+121逼近。以塗白之三角標記表示之u'=0.314之分界能以與上述式(2)平行之直線:Rt650 =-0.44(Ct650 )+108逼近。The boundary of u'=0.314 represented by the white circle mark can be approximated by a straight line parallel to the above formula (6): Rt 650 = 0.37(Ct 650 )+121. The boundary of u'=0.314 represented by the white triangle mark can be approximated by a straight line parallel to the above formula (2): Rt 650 =-0.44(Ct 650 )+108.

因此,於彩色濾光片之紅色透過區域之波長650 nm之厚度方向延遲Ct650 、與光學各向異性元件之波長650 nm之厚度方向延遲Rt650 滿足下述式(6b)或(7b)之情形時,u'成為0.314以下,可實現紅色調經進一步降低之黑顯示。 Rt650 ≧0.37(Ct650 )+121...(6b) Rt650 ≦-0.44(Ct650 )+108...(7b)。Therefore, the retardation Ct 650 in the thickness direction of the wavelength 650 nm in the red transmission region of the color filter and the retardation Rt 650 in the thickness direction of the wavelength 650 nm of the optical anisotropic element satisfy the following formula (6b) or (7b) In this case, u'becomes 0.314 or less, and black display with a further reduction in red tone can be realized. Rt 650 ≧0.37(Ct 650 )+121...(6b) Rt 650 ≦-0.44(Ct 650 )+108...(7b).

根據上述結果,可謂於圖3所示之E模式之液晶面板102中,於Ct650 與Rt650 滿足下述式(6c)或(7c)之情形時,可實現紅色調經降低之黑顯示。 Rt650 ≧0.37(Ct650 )+C6 ...(6c) Rt650 ≦-0.44(Ct650 )+C7 ...(7c)。Based on the above results, it can be said that in the E-mode liquid crystal panel 102 shown in FIG. 3, when Ct 650 and Rt 650 satisfy the following formula (6c) or (7c), black display with a reduced red tone can be realized. Rt 650 ≧0.37(Ct 650 )+C 6 ...(6c) Rt 650 ≦-0.44(Ct 650 )+C 7 ...(7c).

於以滿足u'≦0.35之方式設定條件之情形時,如上述之式(6a)及式(7a)般,使C6 =116 nm、C7 =120 nm即可,於以滿足u'≦0.314之方式設定條件之情形時,如上述之式(6b)及式(7b)般,使C6 =121 nm、C7 =108 nm即可。為了進而減小黑顯示之u',將C6 較大地設定,且將C7 較小地設定即可。When the conditions are set in a way that satisfies u'≦0.35, as in the above equations (6a) and (7a), C 6 =116 nm and C 7 =120 nm are sufficient to satisfy u′≦ When the conditions are set by the 0.314 method, as in the above equations (6b) and (7b), C 6 =121 nm and C 7 =108 nm may be used. In order to further reduce the u'of the black display, it is sufficient to set C 6 larger and C 7 smaller.

式(6c)之C6 可為116以上之任意之數。C6 可為與上述C1 同等之數值,C6 亦可為116 nm、118 nm、121 nm、124 nm、126 nm、128 nm、130 nm、132 nm、134 nm、136 nm、138 nm、或140 nm。同樣地,式(7c)之C7 可為120以下之任意之數。C7 可為與上述C2 同等之數值,亦可為121 nm、116 nm、112 nm、108 nm、105 nm、102 nm、100 nm、98 nm、96 nm、94 nm、92 nm、或90 nm。若考慮光學各向異性元件之延遲之波長色散,則光學各向異性元件60之Rt650 較佳為滿足上述式(6c)。C 6 in formula (6c) can be any number above 116. C 6 can be the same value as C 1 above, C 6 can also be 116 nm, 118 nm, 121 nm, 124 nm, 126 nm, 128 nm, 130 nm, 132 nm, 134 nm, 136 nm, 138 nm, Or 140 nm. Similarly, C 7 in formula (7c) can be any number below 120. C 7 may be the same value as C 2 above, or 121 nm, 116 nm, 112 nm, 108 nm, 105 nm, 102 nm, 100 nm, 98 nm, 96 nm, 94 nm, 92 nm, or 90 nm. Considering the delayed wavelength dispersion of the optical anisotropic element, the Rt 650 of the optical anisotropic element 60 preferably satisfies the above formula (6c).

就減小自傾斜方向視認時之黑顯示之色度u'之觀點而言,光學各向異性元件60之波長650 nm之Rt650 若滿足上述之式(6c)或(7c),則其上限或下限並未特別限定。然而,關於第一實施形態如上所述,若考慮用以使黑亮度降低之Rt550 之範圍、及光學各向異性元件60之延遲之波長色散Rt650 /Rt550 ,則Rt650 之上限及下限自然會被決定。From the viewpoint of reducing the chromaticity u'of black display when viewed from the oblique direction, the Rt 650 of the optical anisotropic element 60 at a wavelength of 650 nm satisfies the above formula (6c) or (7c), the upper limit Or the lower limit is not particularly limited. However, regarding the first embodiment, as described above, if the range of Rt 550 for reducing black brightness and the wavelength dispersion of retardation Rt 650 /Rt 550 of the optical anisotropic element 60 are considered, the upper and lower limits of Rt 650 Naturally will be decided.

圖15係根據圖3所示之E模式之液晶面板102之模擬結果,將黑亮度成為特定值之條件繪圖而成之曲線圖。與圖13同樣地,將方位角45°、極角60°之方向上之黑亮度成為未使用光學各向異性元件之液晶顯示裝置之一半的點以塗黑之圓標記及塗黑之三角標記表示,將黑亮度成為未使用光學各向異性元件之液晶顯示裝置之1/5之點以塗白之圓標記及塗白之三角標記表示。FIG. 15 is a graph plotting the condition that the black luminance becomes a specific value according to the simulation results of the E-mode liquid crystal panel 102 shown in FIG. 3. As in FIG. 13, the black brightness in the direction of azimuth angle 45° and polar angle 60° becomes one half of the dots of the liquid crystal display device that does not use the optically anisotropic element are marked with black circles and black triangles It shows that the point where the black brightness becomes 1/5 of the liquid crystal display device that does not use an optically anisotropic element is indicated by a white circle mark and a white triangle mark.

與圖13之情形同樣地,圖15中,與未使用光學各向異性元件之情形相比較,黑亮度成為1/2之區域之分界能以直線逼近,曲線圖中之直線由下述之式(8)及式(9)表示: Rt550 =0.69(Ct550 )+70...(8) Rt550 =1.35(Ct550 )+200...(9)。As in the case of FIG. 13, in FIG. 15, compared with the case where the optical anisotropic element is not used, the boundary of the region where the black brightness becomes 1/2 can be approximated by a straight line. The straight line in the graph is represented by the following formula (8) and formula (9) show: Rt 550 = 0.69 (Ct 550 ) + 70... (8) Rt 550 = 1.35 (Ct 550 ) + 200 ... (9).

因此,液晶面板102中,於彩色濾光片22之綠色透過區域22G之波長550 nm之厚度方向延遲Ct550 、與光學各向異性元件50之波長550 nm之厚度方向延遲Rt550 滿足下述式(8a)之情形時,與未使用光學各向異性元件之情形相比,黑亮度成為1/2以下。 0.69(Ct550 )+70≦Rt550 ≦1.35(Ct550 )+200...(8a)。Therefore, in the liquid crystal panel 102, the thickness direction retardation Ct 550 at the wavelength 550 nm of the green transmission region 22G of the color filter 22 and the thickness direction retardation Rt 550 at the wavelength 550 nm of the optical anisotropic element 50 satisfy the following formula In the case of (8a), compared with the case where no optical anisotropic element is used, the black luminance becomes 1/2 or less. 0.69(Ct 550 )+70≦Rt 550 ≦1.35(Ct 550 )+200...(8a).

以塗白之三角標記表示之點能以與上述式(8)平行之直線:Rt550 =0.69(Ct550 )+98逼近。以塗白之圓標記表示之點能以與上述式(9)平行之直線:Rt550 =1.35(Ct550 )+180逼近。因此,於Ct550 與Rt550 滿足下述式(8b)之情形時,與未使用光學各向異性元件之情形相比,黑亮度成為1/5以下。 0.69(Ct550 )+98≦Rt550 ≦1.35(Ct550 )+171...(8b)。The point represented by the white triangle mark can be approximated by a straight line parallel to the above formula (8): Rt 550 = 0.69 (Ct 550 ) + 98. The point indicated by the white circle mark can be approximated by a straight line parallel to the above formula (9): Rt 550 = 1.35 (Ct 550 ) + 180. Therefore, in the case where Ct 550 and Rt 550 satisfy the following formula (8b), the black luminance becomes 1/5 or less compared to the case where the optical anisotropic element is not used. 0.69(Ct 550 )+98≦Rt 550 ≦1.35(Ct 550 )+171...(8b).

根據上述結果,可謂於圖3所示之E模式之液晶面板102中,於Ct550 與Rt550 滿足下述式(8c)之情形時,可消除彩色濾光片之雙折射之影響,實現自傾斜方向視認時之黑亮度降低之顯示。 0.69(Ct550 )+C8 ≦Rt550 ≦1.35(Ct550 )+C9 ...(8c)。Based on the above results, it can be said that in the E-mode liquid crystal panel 102 shown in FIG. 3, when the Ct 550 and Rt 550 satisfy the following formula (8c), the influence of the birefringence of the color filter can be eliminated, and A display with reduced black brightness when viewed obliquely. 0.69(Ct 550 )+C 8 ≦Rt 550 ≦1.35(Ct 550 )+C 9 ...(8c).

於將傾斜方向之黑亮度設為未使用光學各向異性元件時之1/2以下之情形時,如上述式(8a)般,使C8 =70 nm、C9 =200 nm即可。根據相同之觀點,於將傾斜方向之黑亮度設為未使用光學各向異性元件時之1/5以下之情形時,如上述式(8b)般,使C3 =98、C4 =171 nm即可。為了進而減小傾斜方向之黑亮度,將C8 較大地設定,且將C9 較小地設定即可。When the black luminance in the oblique direction is 1/2 or less when the optical anisotropic element is not used, it is sufficient to set C 8 =70 nm and C 9 =200 nm as in the above formula (8a). From the same point of view, when the black brightness in the oblique direction is 1/5 or less when no optical anisotropic element is used, as in the above formula (8b), C 3 =98 and C 4 =171 nm That's it. In order to further reduce the black brightness in the oblique direction, it is sufficient to set C 8 to a large value, and to set C 9 to a small value.

式(8c)之C8 可為70以上之任意之數。C8 亦可為78 nm、88 nm、98 nm、108 nm、113 nm、118 nm、123 nm、或128 nm。同樣地,式(8c)之C9 可為200以下之任意之數。C9 亦可為200 nm、190 nm、180 nm、173 nm、168 nm、163 nm、158 nm、153 nm、或148 nm。C 8 in formula (8c) can be any number above 70. C 8 may also be 78 nm, 88 nm, 98 nm, 108 nm, 113 nm, 118 nm, 123 nm, or 128 nm. Similarly, C 9 in formula (8c) can be any number below 200. C 9 may also be 200 nm, 190 nm, 180 nm, 173 nm, 168 nm, 163 nm, 158 nm, 153 nm, or 148 nm.

如圖15所示,彩色濾光片之厚度方向延遲Ct550 越大,則用以使自傾斜方向視認時之黑亮度降低之光學各向異性元件之Rt550 之最佳值越大。此亦可根據圖9B所示之光學補償之原理而理解。As shown in FIG. 15, the greater the thickness direction delay Ct 550 of the color filter, the greater the optimal value of Rt 550 of the optically anisotropic element for reducing the black brightness when viewed from the oblique direction. This can also be understood according to the principle of optical compensation shown in FIG. 9B.

於圖3所示之E模式之液晶面板102中,為了降低自傾斜方向視認時之黑亮度,根據彩色濾光片之厚度方向延遲Ct550 ,以滿足上述式(8c)之方式設定光學各向異性元件之Rt550 ,且以滿足上述式(6c)或(7c)之方式設定光學各向異性元件之Rt650 即可。In the E-mode liquid crystal panel 102 shown in FIG. 3, in order to reduce the black brightness when viewed from the oblique direction, the retardation of Ct 550 according to the thickness direction of the color filter is set to satisfy the above formula (8c) to set the optical direction Rt 550 of the anisotropic element, and Rt 650 of the optically anisotropic element may be set in a manner satisfying the above formula (6c) or (7c).

與對O模式之液晶面板之例所作之說明同樣地,若考慮光學各向異性元件之波長色散Rt650 /Rt550 ,則於Ct650 為10 nm以上之情形時,Rt550 滿足式(8c)、且Rt650 滿足式(7c)之情形較少。因此,較佳為以使Rt550 滿足上述式(8c)、且Rt650 滿足上述式(6c)之方式設定光學各向異性元件60之延遲。As with the description of the example of the O-mode liquid crystal panel, if the wavelength dispersion Rt 650 /Rt 550 of the optically anisotropic element is considered, when the Ct 650 is 10 nm or more, Rt 550 satisfies the formula (8c) And, Rt 650 rarely meets equation (7c). Therefore, it is preferable to set the retardation of the optical anisotropic element 60 such that Rt 550 satisfies the above formula (8c) and Rt 650 satisfies the above formula (6c).

光學各向異性元件60之正面延遲Re550 及Re650 以使Rt550 及Rt650 成為上述範圍之方式設定即可。光學各向異性元件60之波長650 nm之正面延遲Re650 較佳為Rt650 之2倍左右。因此,Re650 較佳為滿足下述式(6d)或(7d): Re650 ≧0.74(Ct650 )+C16 ...(6d) Re650 ≦-0.88(Ct650 )+C17 ...(7d)。The front retardation Re 550 and Re 650 of the optical anisotropic element 60 may be set so that Rt 550 and Rt 650 fall within the above range. The front retardation Re 650 of the optical anisotropic element 60 at a wavelength of 650 nm is preferably about twice the Rt 650 . Therefore, Re 650 preferably satisfies the following formula (6d) or (7d): Re 650 ≧0.74 (Ct 650 ) + C 16 ... (6d) Re 650 ≦-0.88 (Ct 650 ) + C 17 ... ( 7d).

C16 為C6 之2倍,具體而言,C16 為232 nm以上。C16 亦可為232 nm、236 nm、242 nm、248 nm、252 nm、256 nm、260 nm、264 nm、268 nm、272 nm、276 nm、或280 nm。C17 為C7 之2倍,具體而言,C17 為240 nm以下。C12 亦可為240 nm、232 nm、224 nm、216 nm、210 nm、204 nm、200 nm、196 nm、192 nm、188 nm、184 nm、或180 nm。若考慮光學各向異性元件之延遲之波長色散,則光學各向異性元件60之Re650 較佳為滿足上述式(6d)。C 16 is twice that of C 6 , specifically, C 16 is 232 nm or more. C 16 can also be 232 nm, 236 nm, 242 nm, 248 nm, 252 nm, 256 nm, 260 nm, 264 nm, 268 nm, 272 nm, 276 nm, or 280 nm. C 17 is twice that of C 7 , specifically, C 17 is 240 nm or less. C 12 can also be 240 nm, 232 nm, 224 nm, 216 nm, 210 nm, 204 nm, 200 nm, 196 nm, 192 nm, 188 nm, 184 nm, or 180 nm. Considering the delayed wavelength dispersion of the optical anisotropic element, Re 650 of the optical anisotropic element 60 preferably satisfies the above formula (6d).

光學各向異性元件60之波長550 nm之正面延遲Re550 較佳為Rt550 之2倍左右。因此,Re550 較佳為滿足下述式(8d): 1.38(Ct550 )+C18 ≦Re550 ≦2.70(Ct550 )+C19 ...(8d)。The front retardation Re 550 of the optical anisotropic element 60 at a wavelength of 550 nm is preferably about twice the Rt 550 . Therefore, Re 550 preferably satisfies the following formula (8d): 1.38 (Ct 550 ) + C 18 ≦ Re 550 ≦ 2.70 (Ct 550 ) + C 19 ... (8d).

C18 為C8 之2倍,具體而言,C18 為140 nm以上。C18 亦可為155 nm、175 nm、185 nm、215 nm、225 nm、235 nm、245 nm、或255 nm。C19 為C9 之2倍,具體而言,C19 為400 nm以下。C19 亦可為400 nm、380 nm、360 nm、345 nm、335 nm、325 nm、315 nm、305 nm、或295 nm。C 18 is twice that of C 8 , specifically, C 18 is 140 nm or more. C 18 may also be 155 nm, 175 nm, 185 nm, 215 nm, 225 nm, 235 nm, 245 nm, or 255 nm. C 19 is twice that of C 9 , specifically, C 19 is 400 nm or less. C 19 may also be 400 nm, 380 nm, 360 nm, 345 nm, 335 nm, 325 nm, 315 nm, 305 nm, or 295 nm.

[各光學構件之配置] 如上所述,第一實施形態之液晶面板101以使配置於液晶單元20之視認側之光學各向異性元件50對應於彩色濾光片22之厚度方向延遲Ct550 及Ct650 而具有特定之光學特性之方式進行光學設計。第二實施形態之液晶面板102以使配置於液晶單元20之光源側之光學各向異性元件60對應於Ct550 及Ct650 而具有特定之光學特性之方式進行光學設計。[Arrangement of each optical member] As described above, in the liquid crystal panel 101 of the first embodiment, the optically anisotropic element 50 disposed on the viewing side of the liquid crystal cell 20 corresponds to the thickness direction retardation Ct 550 of the color filter 22 and Ct 650 has optical design with specific optical characteristics. The liquid crystal panel 102 of the second embodiment is optically designed so that the optically anisotropic element 60 disposed on the light source side of the liquid crystal cell 20 corresponds to Ct 550 and Ct 650 and has specific optical characteristics.

第一實施形態之液晶面板101於視認側偏光件30與光學各向異性元件50之間、或於光源側偏光件40與液晶單元20之間,亦可具備光學等向性膜作為偏光件保護膜。第二實施形態之液晶面板102於視認側偏光件30與液晶單元20之間、或於光源側偏光件40與光學各向異性元件60之間,亦可具備光學等向性膜作為偏光件保護膜。藉由於偏光件之表面設置偏光件保護膜而可提高偏光件之耐久性。The liquid crystal panel 101 of the first embodiment may be provided with an optically isotropic film as a polarizer for protection between the polarizer 30 on the viewing side and the optically anisotropic element 50 or between the polarizer 40 on the light source side and the liquid crystal cell 20 membrane. The liquid crystal panel 102 of the second embodiment may be provided with an optically isotropic film as a polarizer for protection between the polarizer 30 on the viewing side and the liquid crystal cell 20 or between the polarizer 40 on the light source side and the optical anisotropic element 60 membrane. By providing a polarizer protective film on the surface of the polarizer, the durability of the polarizer can be improved.

用作偏光件保護膜之光學等向性膜係指對於透過法線方向及傾斜方向之任一方向之光,實質上均未將其偏光狀態轉換者。具體而言,光學等向性膜中,正面延遲Re較佳為10 nm以下,厚度方向延遲Rt較佳為20 nm以下。光學等向性膜之正面延遲更佳為5 nm以下。光學等向性膜之厚度方向延遲更佳為10 nm以下,進而佳為5 nm以下。The optical isotropic film used as the protective film of the polarizer refers to a light that has passed through either the normal direction and the oblique direction and has not substantially converted its polarization state. Specifically, in the optically isotropic film, the front retardation Re is preferably 10 nm or less, and the thickness direction retardation Rt is preferably 20 nm or less. The front retardation of the optical isotropic film is more preferably 5 nm or less. The retardation in the thickness direction of the optical isotropic film is more preferably 10 nm or less, and further preferably 5 nm or less.

液晶面板亦可包含除上述以外之光學層或其他構件。例如,較佳為於偏光件30、40之外表面(未與液晶單元20對向之面)設置偏光件保護膜。設置於偏光件之外表面之偏光件保護膜可為光學等向性,亦可為具有光學各向異性者。另一方面,設置於視認側偏光件30之液晶單元20側之面、及光源側偏光件40之液晶單元20側之偏光件保護膜要求如上所述為光學等向性。The liquid crystal panel may include an optical layer or other members other than the above. For example, it is preferable to provide a polarizer protective film on the outer surfaces of the polarizers 30 and 40 (the surface not facing the liquid crystal cell 20). The polarizer protective film provided on the outer surface of the polarizer may be optically isotropic or may have optical anisotropy. On the other hand, the polarizer protective film provided on the surface of the viewing side polarizer 30 on the liquid crystal cell 20 side and the light source side polarizer 40 on the liquid crystal cell 20 side is required to be optically isotropic as described above.

第一實施形態之液晶面板101較佳為於視認側偏光件與液晶單元20之間,不包含除光學各向異性元件50以外之光學各向異性元件,且於光源側偏光件40與液晶單元20之間,較佳為不包含光學各向異性元件。第二實施形態之液晶面板102於光源側偏光件與液晶單元20之間,較佳為不包含除光學各向異性元件60以外之光學各向異性元件,且於視認側偏光件30與液晶單元20之間,較佳為不包含光學各向異性元件。The liquid crystal panel 101 of the first embodiment is preferably between the viewing side polarizer and the liquid crystal cell 20, does not include optical anisotropic elements other than the optical anisotropic element 50, and is on the light source side polarizer 40 and the liquid crystal cell Between 20, it is preferable not to include an optically anisotropic element. The liquid crystal panel 102 of the second embodiment is preferably between the light source side polarizer and the liquid crystal cell 20, and preferably does not include an optical anisotropic element other than the optical anisotropic element 60, and is on the viewing side polarizer 30 and the liquid crystal cell Between 20, it is preferable not to include an optically anisotropic element.

藉由將液晶單元與上述各光學構件積層而形成液晶面板。於其形成過程中,可將各構件依序個別地積層於液晶單元上,亦可使用預先將若干個構件積層而成者。該等光學構件之積層順序並未特別限制。亦可將偏光件與光學各向異性元件積層而預先形成積層偏光板,且將該積層偏光板經由黏著劑(未圖示)而與液晶單元貼合。如上所述,亦可於偏光件之表面設置偏光件保護膜。於偏光件與光學各向異性元件之間,亦可設置光學等向性膜作為偏光件保護膜。A liquid crystal panel is formed by laminating a liquid crystal cell and the above-mentioned optical members. In the formation process, each member may be sequentially laminated on the liquid crystal cell individually, or a plurality of members may be laminated in advance. The stacking order of these optical components is not particularly limited. The polarizer and the optically anisotropic element may be laminated to form a laminated polarizing plate in advance, and the laminated polarizing plate may be bonded to the liquid crystal cell via an adhesive (not shown). As described above, a polarizer protective film may also be provided on the surface of the polarizer. Between the polarizer and the optically anisotropic element, an optical isotropic film can also be provided as a polarizer protective film.

於各構件之積層中,可較佳地使用接著劑或黏著劑。作為接著劑或黏著劑,可適當選擇使用以丙烯酸系聚合物、聚矽氧系聚合物、聚酯、聚胺基甲酸酯、聚醯胺、聚乙烯醚、乙酸乙烯酯/氯乙烯聚合物、改性聚烯烴、環氧系聚合物、氟系聚合物、橡膠系聚合物等為基礎聚合物者。In the lamination of each member, an adhesive or an adhesive can be preferably used. As an adhesive or an adhesive, acrylic polymers, polysiloxane polymers, polyesters, polyurethanes, polyamides, polyvinyl ethers, vinyl acetate/vinyl chloride polymers can be appropriately selected and used. , Modified polyolefin, epoxy polymer, fluorine polymer, rubber polymer, etc. as the base polymer.

[液晶顯示裝置] 藉由於上述液晶面板之第二主面側(偏光件40側)配置光源110而形成液晶顯示裝置。於液晶面板與光源之間,亦可設置增亮膜(未圖示)。增亮膜亦可與光源側偏光件一體設置。例如,可使用將增亮膜經由接著劑層而貼合於第二偏光件之外表面(光源側之面)者。又,於偏光件與增亮膜之間,亦可設置偏光件保護膜。[Liquid crystal display device] The liquid crystal display device is formed by arranging the light source 110 on the second main surface side (the polarizer 40 side) of the liquid crystal panel. A brightness enhancing film (not shown) can also be provided between the liquid crystal panel and the light source. The brightness enhancement film can also be integrated with the polarizer on the light source side. For example, those in which the brightness enhancement film is bonded to the outer surface (surface on the light source side) of the second polarizer through the adhesive layer can be used. In addition, a polarizer protective film may also be provided between the polarizer and the brightness enhancing film.

10‧‧‧液晶層 11‧‧‧初始配向方向 20‧‧‧液晶單元 21‧‧‧彩色濾光片基板 22‧‧‧TFT基板 22B‧‧‧藍色透過區域 22G‧‧‧綠色透過區域 22R‧‧‧紅色透過區域 25‧‧‧TFT基板 30‧‧‧偏光件 35‧‧‧吸收軸(方向) 40‧‧‧偏光件 45‧‧‧吸收軸(方向) 50‧‧‧光學各向異性元件(相位差板) 53‧‧‧遲相軸(方向) 60‧‧‧光學各向異性元件(相位差板) 63‧‧‧遲相軸(方向) 101‧‧‧液晶面板 102‧‧‧液晶面板 106‧‧‧液晶面板 107‧‧‧液晶面板 110‧‧‧光源 201‧‧‧液晶顯示裝置 202‧‧‧液晶顯示裝置 P0‧‧‧點 P1‧‧‧點 P'0‧‧‧光 P'1‧‧‧光 PA‧‧‧點 P'A‧‧‧點 PC‧‧‧點 PL‧‧‧光 PR‧‧‧點 θ‧‧‧極角10‧‧‧Liquid crystal layer 11‧‧‧Initial alignment direction 20‧‧‧Liquid crystal cell 21‧‧‧Color filter substrate 22‧‧‧TFT substrate 22B‧‧‧Blue transmission area 22G‧‧‧Green transmission area 22R ‧‧‧ Red transmission area 25‧‧‧TFT substrate 30‧‧‧ Polarizer 35‧‧‧ Absorption axis (direction) 40‧‧‧ Polarizer 45‧‧‧ Absorption axis (direction) 50‧‧‧ Optical anisotropy Element (phase difference plate) 53‧‧‧Phase phase axis (direction) 60‧‧‧Optical anisotropic element (phase difference plate) 63‧‧‧Phase phase axis (direction) 101‧‧‧LCD panel 102‧‧‧ 106‧‧‧ crystal panel The liquid crystal panel of the liquid crystal panel 110‧‧‧ 107‧‧‧ source 201‧‧‧ liquid crystal display device liquid crystal display device 202‧‧‧ P 0 ‧‧‧ point P 1 ‧‧‧ point P '0 ‧‧ ‧ light P '1 ‧‧‧ light P A ‧‧‧ point P' A ‧‧‧ point P C ‧‧‧ point P L ‧‧‧ light P R ‧‧‧ point polar angle θ‧‧‧

圖1係第一實施形態之液晶面板(O模式)之構成概念圖。 圖2係第一實施形態之液晶顯示裝置(O模式)之模式剖視圖。 圖3係第二實施形態之液晶面板(E模式)之構成概念圖。 圖4係第二實施形態之液晶顯示裝置(E模式)之模式剖視圖。 圖5係利用龐加萊球說明藉由光學各向異性元件對偏光件之表觀上之軸方向偏移進行光學補償之狀況的說明圖。 圖6係參考例之液晶面板(O模式)之構成概念圖。 圖7係參考例之液晶面板(E模式)之構成概念圖。 圖8A、B係利用龐加萊球說明O模式之液晶面板之光學補償之狀況的說明圖。 圖9A、B係利用龐加萊球說明E模式之液晶面板之光學補償之狀況的說明圖。 圖10A、B係O模式之液晶顯示裝置之黑顯示之色度之模擬結果。 圖11A、B係E模式之液晶顯示裝置之黑顯示之色度之模擬結果。 圖12係將O模式之液晶顯示裝置之黑顯示之色度u'成為特定值之條件繪圖而成之曲線圖。 圖13係將O模式之液晶顯示裝置之黑顯示之亮度成為特定值之條件繪圖而成之曲線圖。 圖14係將E模式之液晶顯示裝置之黑顯示之色度u'成為特定值之條件繪圖而成之曲線圖。 圖15係將E模式之液晶顯示裝置之黑顯示之亮度成為特定值以下之條件繪圖而成之曲線圖。FIG. 1 is a conceptual diagram of the configuration of the liquid crystal panel (O mode) of the first embodiment. 2 is a schematic cross-sectional view of the liquid crystal display device (O mode) of the first embodiment. 3 is a conceptual diagram of the configuration of the liquid crystal panel (E mode) of the second embodiment. 4 is a schematic cross-sectional view of a liquid crystal display device (E mode) of a second embodiment. FIG. 5 is an explanatory diagram illustrating a state of optically compensating the apparent axial deviation of the polarizer by the optical anisotropic element using the Poincare sphere. 6 is a conceptual diagram of the configuration of a liquid crystal panel (O mode) of a reference example. 7 is a conceptual diagram of a configuration of a liquid crystal panel (E mode) of a reference example. 8A and 8B are explanatory diagrams illustrating the state of optical compensation of an O-mode liquid crystal panel using a Poincaré sphere. 9A and 9B are explanatory diagrams illustrating the state of optical compensation of the E-mode liquid crystal panel using Poincaré balls. 10A and B are the simulation results of the chromaticity of the black display of the O-mode liquid crystal display device. 11A and B are the simulation results of the chromaticity of the black display of the E mode liquid crystal display device. 12 is a graph obtained by plotting the condition that the chromaticity u′ of the black display of the O-mode liquid crystal display device becomes a specific value. 13 is a graph obtained by plotting the condition that the brightness of the black display of the O-mode liquid crystal display device becomes a specific value. 14 is a graph obtained by plotting the condition that the chromaticity u′ of the black display of the E-mode liquid crystal display device becomes a specific value. 15 is a graph obtained by plotting the condition that the brightness of the black display of the liquid crystal display device of the E mode becomes below a specific value.

10‧‧‧液晶層 10‧‧‧Liquid crystal layer

11‧‧‧初始配向方向 11‧‧‧Initial alignment direction

20‧‧‧液晶單元 20‧‧‧LCD unit

30‧‧‧偏光件 30‧‧‧ Polarizer

35‧‧‧吸收軸(方向) 35‧‧‧absorption axis (direction)

40‧‧‧偏光件 40‧‧‧ Polarizer

45‧‧‧吸收軸(方向) 45‧‧‧absorption axis (direction)

50‧‧‧光學各向異性元件(相位差板) 50‧‧‧Optical anisotropic element (phase difference plate)

53‧‧‧遲相軸(方向) 53‧‧‧Phase axis (direction)

101‧‧‧液晶面板 101‧‧‧ LCD panel

Claims (7)

一種液晶面板,其具備: 液晶單元,其具備包含於無電場狀態下平行配向之液晶分子之液晶層、及配置於上述液晶層之第一主面且至少具有綠色透過區域及紅色透過區域之彩色濾光片; 第一偏光件,其配置於上述液晶單元之第一主面; 第二偏光件,其配置於上述液晶單元之第二主面;及 光學各向異性元件,其配置於上述第一偏光件與第二偏光件之間;且 上述第一偏光件之吸收軸方向與上述第二偏光件之吸收軸方向正交, 上述光學各向異性元件之遲相軸方向與上述第二偏光件之吸收軸方向平行, 上述光學各向異性元件中,波長650 nm之正面延遲Re650 與厚度方向延遲Rt650 之比Rt650 /Re650 為0.2~0.8, 上述彩色濾光片之綠色透過區域中,波長550 nm之厚度方向延遲Ct550 大於0且為50 nm以下, 上述彩色濾光片之紅色透過區域中,波長650 nm之厚度方向延遲Ct650 大於0且為50 nm以下, 上述液晶單元之無電場狀態下之上述液晶分子之配向方向、與上述第二偏光件之吸收軸方向平行, 上述光學各向異性元件配置於上述液晶單元與上述第一偏光件之間, 上述光學各向異性元件之波長550 nm之厚度方向延遲Rt550 (nm)與上述Ct550 (nm)滿足下述式(3a): 0.97(Ct550 )+73≦Rt550 ≦0.49(Ct550 )+205...(3a) 上述Rt650 (nm)與上述Ct650 (nm)滿足下述式(1a)或(2a): Rt650 ≧0.37(Ct650 )+116...(1a) Rt650 ≦-0.44(Ct650 )+116...(2a)。A liquid crystal panel comprising: a liquid crystal cell having a liquid crystal layer including liquid crystal molecules aligned in parallel in a state without electric field, and a color arranged on the first main surface of the liquid crystal layer and having at least a green transmission region and a red transmission region Filter; the first polarizer, which is arranged on the first main surface of the liquid crystal cell; the second polarizer, which is arranged on the second main surface of the liquid crystal cell; and the optical anisotropic element, which is arranged on the first Between a polarizer and a second polarizer; and the direction of the absorption axis of the first polarizer is orthogonal to the direction of the absorption axis of the second polarizer, and the direction of the slow phase axis of the optical anisotropic element is the same as the second polarizer The absorption axis direction of the device is parallel. In the above optically anisotropic device, the ratio of the front retardation Re 650 at a wavelength of 650 nm to the thickness direction retardation Rt 650 is Rt 650 /Re 650 from 0.2 to 0.8, and the green transmission area of the color filter Medium, the thickness direction retardation Ct 550 at a wavelength of 550 nm is greater than 0 and below 50 nm. In the red transmission region of the above color filter, the thickness direction retardation Ct 650 at a wavelength of 650 nm is greater than 0 and below 50 nm, the liquid crystal cell The alignment direction of the liquid crystal molecules in an electric field-free state is parallel to the absorption axis direction of the second polarizer, the optical anisotropic element is disposed between the liquid crystal cell and the first polarizer, the optical anisotropy The thickness direction retardation Rt 550 (nm) of the device at a wavelength of 550 nm and the above Ct 550 (nm) satisfy the following formula (3a): 0.97(Ct 550 )+73≦Rt 550 ≦0.49(Ct 550 )+205...(3a ) The above Rt 650 (nm) and the above Ct 650 (nm) satisfy the following formula (1a) or (2a): Rt 650 ≧0.37(Ct 650 )+116...(1a) Rt 650 ≦-0.44(Ct 650 ) +116...(2a). 如請求項1之液晶面板,其中上述Rt550 與上述Ct550 滿足下述式(3b): 0.97(Ct550 )+98≦Rt550 ≦0.49(Ct550 )+180...(3b)。The liquid crystal panel according to claim 1, wherein the Rt 550 and the Ct 550 satisfy the following formula (3b): 0.97(Ct 550 )+98≦Rt 550 ≦0.49(Ct 550 )+180...(3b). 如請求項1或2之液晶面板,其中上述Rt650 與上述Ct650 滿足下述式(1b)或(2b): Rt650 ≧0.37(Ct650 )+121...(1b) Rt650 ≦-0.44(Ct650 )+108...(2b)。The liquid crystal panel according to claim 1 or 2, wherein the above Rt 650 and the above Ct 650 satisfy the following formula (1b) or (2b): Rt 650 ≧0.37(Ct 650 )+121...(1b) Rt 650 ≦-0.44 (Ct 650 ) + 108... (2b). 一種液晶面板,其具備: 液晶單元,其具備包含於無電場狀態下平行配向之液晶分子之液晶層、及配置於上述液晶層之第一主面且至少具有綠色透過區域及紅色透過區域之彩色濾光片; 第一偏光件,其配置於上述液晶單元之第一主面; 第二偏光件,其配置於上述液晶單元之第二主面;及 光學各向異性元件,其配置於上述第一偏光件與第二偏光件之間;且 上述第一偏光件之吸收軸方向、與上述第二偏光件之吸收軸方向正交, 上述光學各向異性元件之遲相軸方向、與上述第二偏光件之吸收軸方向平行, 對於上述光學各向異性元件,波長650 nm之正面延遲Re650 與厚度方向延遲Rt650 之比Rt650 /Re650 為0.2~0.8, 對於上述彩色濾光片之綠色透過區域,波長550 nm之厚度方向延遲Ct550 為50 nm以下, 對於上述彩色濾光片之紅色透過區域,波長650 nm之厚度方向延遲Ct650 大於0且為50 nm以下, 上述液晶單元之無電場狀態下之上述液晶分子之配向方向、與上述第二偏光件之吸收軸方向正交, 上述光學各向異性元件配置於上述液晶單元與上述第二偏光件之間, 上述光學各向異性元件之波長550 nm之厚度方向延遲Rt550 (nm)與上述Ct550 (nm)滿足下述式(8a): 0.69(Ct550 )+70≦Rt550 ≦1.35(Ct550 )+200...(8a) 上述Rt650 (nm)與上述Ct650 (nm)滿足下述式(6a)或(7a): Rt650 ≧0.37(Ct650 )+116...(6a) Rt650 ≦-0.44(Ct650 )+120...(7a)。A liquid crystal panel comprising: a liquid crystal cell having a liquid crystal layer including liquid crystal molecules aligned in parallel in a state without electric field, and a color arranged on the first main surface of the liquid crystal layer and having at least a green transmission region and a red transmission region Filter; the first polarizer, which is arranged on the first main surface of the liquid crystal cell; the second polarizer, which is arranged on the second main surface of the liquid crystal cell; and the optical anisotropic element, which is arranged on the first Between a polarizer and a second polarizer; and the direction of the absorption axis of the first polarizer is orthogonal to the direction of the absorption axis of the second polarizer, and the direction of the slow phase axis of the optically anisotropic element is The absorption axis directions of the two polarizers are parallel. For the above optical anisotropic element, the ratio of the front retardation Re 650 at a wavelength of 650 nm to the thickness direction retardation Rt 650 is Rt 650 /Re 650 from 0.2 to 0.8. For the above color filter In the green transmission region, the thickness direction retardation Ct 550 at a wavelength of 550 nm is 50 nm or less. For the red transmission region of the color filter above, the thickness direction retardation Ct 650 at a wavelength of 650 nm is greater than 0 and is 50 nm or less. The alignment direction of the liquid crystal molecules in an electric field-free state is orthogonal to the absorption axis direction of the second polarizer, the optical anisotropic element is disposed between the liquid crystal cell and the second polarizer, the optical anisotropy The thickness direction retardation Rt 550 (nm) of the device at a wavelength of 550 nm and the above Ct 550 (nm) satisfy the following formula (8a): 0.69(Ct 550 )+70≦Rt 550 ≦1.35(Ct 550 )+200...(8a ) The above Rt 650 (nm) and the above Ct 650 (nm) satisfy the following formula (6a) or (7a): Rt 650 ≧0.37(Ct 650 )+116...(6a) Rt 650 ≦-0.44(Ct 650 ) +120...(7a). 如請求項4之液晶面板,其中上述Rt550 與上述Ct550 滿足下述式(8b): 0.69(Ct550 )+98≦Rt550 ≦1.35(Ct550 )+171...(8b)。The liquid crystal panel according to claim 4, wherein the Rt 550 and the Ct 550 satisfy the following formula (8b): 0.69 (Ct 550 )+98≦Rt 550 ≦1.35(Ct 550 )+171...(8b). 如請求項4或5之液晶面板,其中上述Rt650 與上述Ct650 滿足下述式(6b)或(7b): Rt650 ≧0.37(Ct650 )+121...(6b) Rt650 ≦-0.44(Ct650 )+108...(7b)。The liquid crystal panel according to claim 4 or 5, wherein the Rt 650 and the Ct 650 satisfy the following formula (6b) or (7b): Rt 650 ≧0.37(Ct 650 )+121...(6b) Rt 650 ≦-0.44 (Ct 650 ) + 108... (7b). 一種液晶顯示裝置,其具備:如請求項1至6中任一項之液晶面板、及配置於上述液晶面板之第二主面側之光源。A liquid crystal display device comprising: the liquid crystal panel according to any one of claims 1 to 6; and a light source arranged on the second main surface side of the liquid crystal panel.
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