TW201946879A - Capacitive deionization control method and automatic control system thereof - Google Patents

Capacitive deionization control method and automatic control system thereof Download PDF

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TW201946879A
TW201946879A TW107116792A TW107116792A TW201946879A TW 201946879 A TW201946879 A TW 201946879A TW 107116792 A TW107116792 A TW 107116792A TW 107116792 A TW107116792 A TW 107116792A TW 201946879 A TW201946879 A TW 201946879A
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aqueous solution
signal
module
capacitor
discharge
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TW107116792A
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TWI670237B (en
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范振軒
陳皇彬
鄭詠紜
侯嘉洪
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國立臺灣大學
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Abstract

A CDI control method and an automatic control system thereof are provided. The automatic control system comprises an automatic server and a CDI device. The CDI device applies voltage to electrode plates for adsorbing ions in aqueous solution according to a charging signal transmitted from the automatic control server. After the electrode plates adsorb ions and reaches a specific status, the CDI device executes a resting procedure according to a resting signal transmitted from the automatic control server, and grounds the electrode plates for releasing attached ions. After a specific period, the CDI device elutes the electrode plates via aqueous solution for recovering the electrode plates according to an eluting signal transmitted from the automatic control server.

Description

電容去離子控制方法以及其自動控制系統    Capacitive deionization control method and automatic control system thereof   

本發明係關於電容去離子控制技術;更具體而言,本發明係關於電容去離子自動控制方法及其自動控制系統。 The present invention relates to a capacitor deionization control technology; more specifically, the present invention relates to a capacitor deionization automatic control method and an automatic control system thereof.

電容去離子(Capacitive deionization,CDI)技術是一種新式水處理技術,主要可用於移除水體中之帶電荷汙染物質或離子。相較於高能耗、低回收率之傳統去離子程序(例如:逆滲透去離子),CDI裝置具有低能耗、高回收率之優勢。更者,由於CDI裝置去離子之過程具有可逆性,且無二次污染物的問題,因此,CDI技術亦同時被視為一種清淨節能之創新技術。 Capacitive deionization (CDI) technology is a new type of water treatment technology, which can be used to remove charged pollutants or ions in water. Compared with traditional deionization procedures with high energy consumption and low recovery rate (such as reverse osmosis deionization), CDI devices have the advantages of low energy consumption and high recovery rate. Furthermore, because the deionization process of the CDI device is reversible and there is no problem of secondary pollutants, the CDI technology is also considered as a clean and energy-saving innovative technology.

詳細來說,CDI處理程序包含充電吸附以及放電脫附二階段。於充電吸附階段中,水溶液通過CDI裝置時,離子因電場作用力以及濃度梯度被吸附於電極,因而淨化出離子濃度較低之水溶液。而於放電脫附階段中,將水溶液以固定的流量持續通入CDI裝置,俾電極釋出吸附之離子,直到電極中離子濃度與流道中之水溶液之離子濃度達到平衡,方完成電極之再生。 In detail, the CDI processing program includes two stages of charge adsorption and discharge desorption. In the charge adsorption stage, when the aqueous solution passes through the CDI device, ions are adsorbed on the electrode due to the force of the electric field and the concentration gradient, so the aqueous solution with a lower ion concentration is purified. In the discharge and desorption stage, the aqueous solution is continuously passed into the CDI device at a fixed flow rate, and the ions are released by the osmium electrode until the ion concentration in the electrode and the ion concentration of the aqueous solution in the flow channel reach equilibrium before the electrode regeneration is completed.

然而,習知之CDI裝置,皆由批次操作或人工判斷之 方式完成相關之水溶液去離子程序,因此,目前之CDI技術除了人力資源之浪費外,結果精準度不穩亦是值得改善之問題。更者,CDI處理程序之放電脫附步驟中,如何減少完成電極再生所需通入CDI裝置之水溶液水量,亦是值得改善之議題。 However, the conventional CDI devices all complete the deionization procedure of the aqueous solution by batch operation or manual judgment. Therefore, in addition to the waste of human resources, the current CDI technology is unstable and the accuracy is also a problem worth improving. Furthermore, in the discharge desorption step of the CDI processing program, how to reduce the amount of water in the aqueous solution that is passed into the CDI device to complete the electrode regeneration is also an issue worth improving.

有鑑於此,如何改良前述習知CDI技術程序之缺點,降低模組操作之人力需求、提升操作精準度、並提高水資源之回收效率,乃為業界急待解決之問題。 In view of this, how to improve the shortcomings of the conventional CDI technical procedures, reduce the manpower requirements of module operation, improve the operation accuracy, and improve the efficiency of water resource recovery are urgent issues for the industry.

為解決前述問題,本發明揭露一種用於自動控制系統之電容去離子(Capacitive deionization,CDI)控制方法。自動控制系統包含自動控制伺服器以及CDI裝置。自動控制伺服器與CDI裝置間透過網路連線通訊。自動控制伺服包含處理器以及通訊模組。CDI裝置包含控制模組以及容置主體,容置主體設有水溶液幫浦、輸入閥門、輸出閥門、輸出溶液導電度感測器以及電極板模組。 In order to solve the foregoing problem, the present invention discloses a capacitive deionization (CDI) control method for an automatic control system. The automatic control system includes an automatic control server and a CDI device. The automatic control server communicates with the CDI device through a network connection. The automatic control servo includes a processor and a communication module. The CDI device includes a control module and a containing body. The containing body is provided with an aqueous solution pump, an input valve, an output valve, an output solution conductivity sensor, and an electrode plate module.

CDI控制方法包含下列步驟:處理器透過通訊模組傳送充電訊號至CDI裝置。其中,充電訊號用以通知控制模組開啟水溶液幫浦,俾水溶液自輸入閥門流入容置主體並自輸出閥門流出。另一方面,充電訊號用以通知控制模組施加電壓予電極板模組,以吸附水溶液之離子。接著,處理器透過通訊模組自CDI裝置接收控制模組之放電訊號。其中,控制模組判斷輸出溶液導電度感測器偵測之水溶液之導電度上升至等於充電門檻值後產生放電訊號。 The CDI control method includes the following steps: the processor sends a charging signal to the CDI device through the communication module. Among them, the charging signal is used to notify the control module to turn on the aqueous pump, and the tritium aqueous solution flows from the input valve into the accommodating body and flows out from the output valve. On the other hand, the charging signal is used to notify the control module to apply a voltage to the electrode plate module to adsorb the ions in the aqueous solution. Then, the processor receives the discharge signal of the control module from the CDI device through the communication module. Among them, the control module judges that the conductivity of the aqueous solution detected by the output solution conductivity sensor rises to equal to the charging threshold and generates a discharge signal.

隨後,處理器根據放電訊號,透過通訊模組傳送靜置訊號至CDI裝置。其中,靜置訊號用以通知控制模組關閉水溶液幫浦,俾水溶液於該容置主體中靜置。另一方面,靜置訊號用以通知控制模組將電極板模組接地。而處理器於時間區間後,透過通訊模組傳送沖提訊號至CDI裝置。其中,沖提訊號用以通知控制模組開啟水溶液幫浦,俾水溶液自輸入閥門流入容置主體並自輸出閥門流出。 Subsequently, the processor transmits a static signal to the CDI device through the communication module according to the discharge signal. The stationary signal is used to notify the control module to turn off the aqueous pump, and the tritium aqueous solution is allowed to stand in the housing body. On the other hand, the static signal is used to notify the control module to ground the electrode plate module. After the time interval, the processor sends the extraction signal to the CDI device through the communication module. Among them, the flushing signal is used to notify the control module to turn on the aqueous pump, and the tritium aqueous solution flows from the input valve into the containing body and flows out from the output valve.

為達到上述目的,本發明又揭露一種自動控制系統。自動控制系統包含自動控制伺服器以及CDI裝置。自動控制伺服器與CDI裝置間透過網路連線通訊。CDI裝置包含控制模組以及容置主體,容置主體設有水溶液幫浦、輸入閥門、輸出閥門、輸出溶液導電度感測器以及電極板模組。 To achieve the above object, the present invention further discloses an automatic control system. The automatic control system includes an automatic control server and a CDI device. The automatic control server communicates with the CDI device through a network connection. The CDI device includes a control module and a containing body. The containing body is provided with an aqueous solution pump, an input valve, an output valve, an output solution conductivity sensor, and an electrode plate module.

自動控制伺服包含處理器以及通訊模組,處理器透過通訊模組傳送充電訊號至CDI裝置。其中,充電訊號用以通知控制模組開啟水溶液幫浦,俾水溶液自輸入閥門流入容置主體並自輸出閥門流出。另一方面,充電訊號用以通知控制模組施加電壓予電極板模組,以吸附水溶液之離子。接著,處理器透過通訊模組自CDI裝置接收控制模組之放電訊號。其中,控制模組判斷輸出溶液導電度感測器偵測之水溶液之導電度上升至等於充電門檻值後產生放電訊號。 The automatic control servo includes a processor and a communication module. The processor transmits a charging signal to the CDI device through the communication module. Among them, the charging signal is used to notify the control module to turn on the aqueous pump, and the tritium aqueous solution flows from the input valve into the accommodating body and flows out from the output valve. On the other hand, the charging signal is used to notify the control module to apply a voltage to the electrode plate module to adsorb the ions in the aqueous solution. Then, the processor receives the discharge signal of the control module from the CDI device through the communication module. Among them, the control module judges that the conductivity of the aqueous solution detected by the output solution conductivity sensor rises to equal to the charging threshold and generates a discharge signal.

隨後,處理器根據放電訊號,透過通訊模組傳送靜置訊號至CDI裝置。其中,靜置訊號用以通知控制模組關閉水溶液幫 浦,俾水溶液於該容置主體中靜置。另一方面,靜置訊號用以通知控制模組將電極板模組接地。而處理器於時間區間後,透過通訊模組傳送沖提訊號至CDI裝置。其中,沖提訊號用以通知控制模組開啟水溶液幫浦,俾水溶液自輸入閥門流入容置主體並自輸出閥門流出。 Subsequently, the processor transmits a static signal to the CDI device through the communication module according to the discharge signal. Among them, the stationary signal is used to notify the control module to turn off the aqueous solution pump, and the tritium aqueous solution is left to stand in the containing body. On the other hand, the static signal is used to notify the control module to ground the electrode plate module. After the time interval, the processor sends the extraction signal to the CDI device through the communication module. Among them, the flushing signal is used to notify the control module to turn on the aqueous pump, and the tritium aqueous solution flows from the input valve into the containing body and flows out from the output valve.

在參閱圖式及隨後描述之實施方式後,此技術領域具有通常知識者便可瞭解本發明之其他目的,以及本發明之技術手段及實施態樣。 After referring to the drawings and the embodiments described later, those with ordinary knowledge in the technical field can understand other objectives of the present invention, as well as technical means and implementation modes of the present invention.

11‧‧‧自動控制伺服器 11‧‧‧Automatic control server

111‧‧‧處理器 111‧‧‧ processor

113‧‧‧通訊模組 113‧‧‧Communication Module

13‧‧‧電容去離子裝置 13‧‧‧Capacitive deionization device

131‧‧‧控制模組 131‧‧‧control module

133‧‧‧容置主體 133‧‧‧accommodating subject

133a‧‧‧水溶液幫補 133a‧‧‧Aqueous solution tonic

133b‧‧‧輸入閥門 133b‧‧‧input valve

133c‧‧‧輸出閥門 133c‧‧‧Output valve

133d‧‧‧電極板模組 133d‧‧‧electrode plate module

133e‧‧‧輸出溶液導電度感測器 133e‧‧‧ output solution conductivity sensor

133f‧‧‧輸入溶液導電度感測器 133f‧‧‧ input solution conductivity sensor

S1‧‧‧充電訊號 S1‧‧‧Charging signal

S2‧‧‧放電訊號 S2‧‧‧discharge signal

S3‧‧‧靜置訊號 S3‧‧‧ static signal

S4‧‧‧沖提訊號 S4‧‧‧ Rush signal

S5‧‧‧放電結束訊號 S5‧‧‧ Discharge end signal

201~210‧‧‧步驟 201 ~ 210‧‧‧step

第1A圖係本發明第一實施例之CDI自動控制系統之示意圖;第1B圖係本發明第一實施例之自動控制伺服器與CDI裝置之方塊圖;第1C~1E圖係本發明第一實施例之CDI控制操作示意圖;第1F~1J圖係本發明第一實施例之CDI自動控制系統於特定條件下操作之實驗數據圖;以及第2A~2B圖係本發明第二實施例之CDI控制方法之流程圖。 Figure 1A is a schematic diagram of the CDI automatic control system of the first embodiment of the present invention; Figure 1B is a block diagram of the automatic control server and CDI device of the first embodiment of the present invention; Figures 1C to 1E are the first of the present invention Schematic diagram of the CDI control operation of the embodiment; Figures 1F ~ 1J are experimental data diagrams of the CDI automatic control system operating under specific conditions of the first embodiment of the present invention; and Figures 2A ~ 2B are CDI of the second embodiment of the present invention Flow chart of control method.

下將透過實施方式來解釋本發明之內容。須說明者,本發明的實施例並非用以限制本發明須在如實施例所述之任何特定的環境、應用或特殊方式方能實施。因此,有關實施例之說明僅為闡釋本發明之目的,而非用以限制本發明,且本案所請求之範 圍,以申請專利範圍為準。除此之外,於以下實施例及圖式中,與本發明非直接相關之元件已省略而未繪示,且以下圖式中各元件間之尺寸關係僅為求容易瞭解,非用以限制實際比例。 The content of the present invention will be explained below through embodiments. It should be noted that the embodiments of the present invention are not intended to limit the present invention to be implemented in any particular environment, application, or special manner as described in the embodiments. Therefore, the description of the embodiments is only for the purpose of explaining the present invention, and is not intended to limit the present invention, and the scope of the present application is subject to the scope of patent application. In addition, in the following embodiments and drawings, components that are not directly related to the present invention have been omitted and not shown, and the dimensional relationship between the components in the following drawings is only for easy understanding and is not intended to limit Actual proportion.

請先參考第1A-1B圖。第1A圖係本發明第一實施例之一電容去離子(Capacitive deionization,CDI)自動控制系統1之示意圖。CDI自動控制系統1包含一自動控制伺服器11以及一CDI裝置13。自動控制伺服器11與CDI裝置13透過網路連線通訊。 Please refer to Figures 1A-1B first. FIG. 1A is a schematic diagram of a capacitive deionization (CDI) automatic control system 1 according to a first embodiment of the present invention. The CDI automatic control system 1 includes an automatic control server 11 and a CDI device 13. The automatic control server 11 communicates with the CDI device 13 through a network connection.

第1B圖係本發明第一實施例之自動控制伺服器11與CDI裝置13之方塊圖。其中,自動控制伺服器11包含一處理器111以及一通訊模組113,CDI裝置13包含一控制模組131以及一容置主體133。容置主體133設有一水溶液幫浦133a、一輸入閥門133b、一輸出閥門133c、一電極板模組133d、一輸出溶液導電度感測器133e以及一輸入溶液導電度感測器133f。元件間之互動將於下文中進一步闡述。 FIG. 1B is a block diagram of the automatic control server 11 and the CDI device 13 according to the first embodiment of the present invention. The automatic control server 11 includes a processor 111 and a communication module 113, and the CDI device 13 includes a control module 131 and a receiving body 133. The accommodating body 133 is provided with an aqueous solution pump 133a, an input valve 133b, an output valve 133c, an electrode plate module 133d, an output solution conductivity sensor 133e, and an input solution conductivity sensor 133f. The interaction between the components will be further explained below.

請一併參考第1C-1E圖,其係本發明第一實施例之CDI控制操作示意圖。首先,於CDI控制操作程序起始時,自動控制伺服器11之處理器111自動地透過通訊模組113,傳送一充電訊號S1至CDI裝置13。隨後,如第1C圖所繪示,控制模組131便根據充電訊號S1開啟水溶液幫浦133a,俾水溶液自輸入閥門133a流入容置主體133,並自輸出閥門133c流出,同時,控制模組131施加電壓予電極板模組133d,以吸附水溶液之離子。 Please refer to Figs. 1C-1E together, which are schematic diagrams of the CDI control operation of the first embodiment of the present invention. First, at the beginning of the CDI control operation procedure, the processor 111 of the automatic control server 11 automatically transmits a charging signal S1 to the CDI device 13 through the communication module 113. Subsequently, as shown in FIG. 1C, the control module 131 turns on the aqueous solution pump 133a according to the charging signal S1. The tritium solution flows from the input valve 133a into the containing body 133, and flows out from the output valve 133c. A voltage is applied to the electrode plate module 133d to adsorb ions in the aqueous solution.

接著,電極板模組133d持續吸附水溶液之離子,使得 水溶液之導電度先下降至一導電度低點,接著,由於電極板模組133d將隨時間逐漸達到離子吸附飽和之狀態,因此,電極板模組133d所能吸附之離子數將隨時間遞減,使得輸出閥門133c處之水溶液之導電度從前述之導電度低點逐漸上升。據此,當控制模組131判斷設置於輸出閥門133c附近之輸出溶液導電度感測器133e感測之水溶液之導電度,上升至一充電門檻值後,將產生一放電訊號S2,並自動地將放電訊號S2回傳至自動控制伺服器11。 Next, the electrode plate module 133d continues to adsorb the ions of the aqueous solution, so that the conductivity of the aqueous solution first drops to a low conductivity point. Then, since the electrode plate module 133d will gradually reach the state of ion adsorption saturation over time, the electrode plate The number of ions that can be adsorbed by the module 133d will decrease with time, so that the conductivity of the aqueous solution at the output valve 133c gradually increases from the aforementioned low point of conductivity. According to this, when the control module 131 judges that the conductivity of the aqueous solution sensed by the output solution conductivity sensor 133e located near the output valve 133c rises to a charging threshold value, a discharge signal S2 will be generated and automatically The discharge signal S2 is transmitted to the automatic control server 11.

換言之,前述「水溶液之導電度上升至充電門檻值」之詳細狀況為:水溶液之導電度因水中離子持續被吸附至電極板模組而先降低,並會持續下降至特定低點。隨後,在電極板模組之電離子吸附狀況隨時間趨於飽和之過程中,水溶液之導電度將自特定低點上升至充電門檻值。 In other words, the detailed situation of the aforementioned "the conductivity of the aqueous solution rises to the charging threshold" is that the conductivity of the aqueous solution first decreases due to the ions in the water being continuously adsorbed to the electrode plate module, and will continue to drop to a specific low point. Subsequently, in a process in which the ion adsorption state of the electrode plate module tends to be saturated with time, the conductivity of the aqueous solution will rise from a specific low point to the charging threshold.

另一方面,自動控制伺服器11之處理器111透過通訊模組113,自CDI裝置13接收控制模組131之放電訊號S2後,便自動地透過通訊模組113傳送一靜置訊號S3至CDI裝置13。隨即,如第1D圖所示,CDI裝置13之控制模組131根據靜置訊號S3關閉水溶液幫浦133a,俾水溶液停止流動,並於容置主體133中靜置,同時,控制模組131將電極板模組133d接地,俾電極板模組133d於靜置過程中釋出吸附之離子。 On the other hand, after the processor 111 of the automatic control server 11 receives the discharge signal S2 of the control module 131 from the CDI device 13 through the communication module 113, it automatically transmits a stationary signal S3 to the CDI through the communication module 113.装置 13。 Device 13. Then, as shown in FIG. 1D, the control module 131 of the CDI device 13 closes the aqueous solution pump 133a according to the static signal S3, the tritium aqueous solution stops flowing, and is left in the containing body 133. At the same time, the control module 131 will The electrode plate module 133d is grounded, and the rhenium electrode plate module 133d releases adsorbed ions during the standing process.

接著,自動控制伺服器11之處理器111於一時間區間之水溶液靜置後,自動地透過通訊模組傳送一沖提訊號S4至CDI裝置13。隨即,如第1E圖所示,CDI裝置13之控制模組131根據沖提 訊號S4開啟水溶液幫浦133a,俾水溶液再次自輸入閥門133b流入容置主體133,並自輸出閥門133c流出,如此,便可將具有高濃度離子之水溶液排出,同時利用水溶液進一步地沖提(elute)電極板模組133d,以協助釋放其餘吸附之離子,並於釋放完畢後完成一次水溶液去離子循環。 Then, after the processor 111 of the automatic control server 11 is left to stand in the aqueous solution in a time interval, it automatically sends a flush signal S4 to the CDI device 13 through the communication module. Then, as shown in FIG. 1E, the control module 131 of the CDI device 13 opens the aqueous solution pump 133a according to the extraction signal S4, and the tritium aqueous solution flows from the input valve 133b into the containing body 133 again, and flows out from the output valve 133c. The aqueous solution with high-concentration ions can be discharged, and the aqueous solution is further used to elute the electrode plate module 133d to help release the remaining adsorbed ions, and complete the aqueous solution deionization cycle after the release is completed.

需進一步強調,於沖提之實施細節中,由於電極板模組133d持續釋放離子至水溶液中,因此,自輸出閥門133c排放之水溶液之離子濃度,將較輸入閥門133b輸入之水溶液之離子濃度高,且輸出閥門133c處之水溶液之導電度會先達到一導電度高點。而隨沖提時間增加,於電極板模組133d之離子逐漸釋放之過程中,輸出閥門133c處之水溶液之導電度將隨釋放離子之減少降低。據此,當控制模組131判斷設在置於輸出閥門133c附近之輸入溶液導電度感測器133f偵測之水溶液之導電度,下降至一放電門檻值後,將產生一放電結束訊號S5,並將放電結束訊號S5傳送至自動控制伺服器11。 It should be further emphasized that in the implementation details of the extraction, since the electrode plate module 133d continuously releases ions into the aqueous solution, the ion concentration of the aqueous solution discharged from the output valve 133c will be higher than the ion concentration of the aqueous solution input through the input valve 133b. And the conductivity of the aqueous solution at the output valve 133c will reach a high conductivity first. As the rinsing time increases, during the gradual release of ions from the electrode plate module 133d, the conductivity of the aqueous solution at the output valve 133c will decrease with the decrease of the released ions. According to this, when the control module 131 judges that the conductivity of the aqueous solution detected by the input solution conductivity sensor 133f located near the output valve 133c drops to a discharge threshold value, it will generate a discharge end signal S5, The discharge end signal S5 is transmitted to the automatic control server 11.

換言之,前述「水溶液之導電度下降至放電門檻值」之詳細狀況為:水溶液之導電度因導電板模組持續釋放離子而先上升至特定高點。隨後,在電極板模組之電離子釋放隨時間趨緩之過程中,水溶液之導電度將自特定高點下降至放電門檻值。 In other words, the detailed situation of the aforementioned "conductivity of the aqueous solution falling to the discharge threshold" is that the conductivity of the aqueous solution first rises to a specific high point due to the continuous release of ions by the conductive plate module. Subsequently, in the process that the ion release of the electrode plate module slows down with time, the conductivity of the aqueous solution will drop from a certain high point to the discharge threshold.

另一方面,當自動控制伺服器11之處理器111透過通訊模組113接收放電結束訊號S5後,表示CDI裝置13已完成一次水溶液去離子循環,因此,自動控制伺服器11之處理器111便再次自 動地透過通訊模組113,傳送充電訊號S1至CDI裝置13,藉以重新進行新的水溶液去離子循環。 On the other hand, when the processor 111 of the automatic control server 11 receives the discharge end signal S5 through the communication module 113, it indicates that the CDI device 13 has completed an aqueous solution deionization cycle. Therefore, the processor 111 of the automatic control server 11 will Through the communication module 113 again, the charging signal S1 is automatically transmitted to the CDI device 13 so as to perform a new deionization cycle of the aqueous solution.

須另外詳細說明,在某些實施態樣中,充電門檻值係為可變設定值。其中,可變設定值可由使用者自行根據環境所需進行調整。另一方面,於某些實施態樣中,充電門檻值係等於輸入溶液導電度感測器133f偵測之水溶液之導電度,如此一來,當控制模組131判斷輸出溶液導電度感測器133e偵測之水溶液之導電度,上升至輸入溶液導電度感測器113f偵測之水溶液之導電度時,代表流入容置主體133之水溶液並無離子被電極板模組133d吸附便流出容置主體133,換言之,即電極板模組133d已達吸附飽和狀態,因此,控制模組131產生放電訊號S2。 It must be further specified that in some implementations, the charging threshold is a variable set value. Among them, the variable setting value can be adjusted by the user according to the needs of the environment. On the other hand, in some embodiments, the charging threshold is equal to the conductivity of the aqueous solution detected by the input solution conductivity sensor 133f. In this way, when the control module 131 judges the output solution conductivity sensor When the conductivity of the aqueous solution detected by 133e rises to the conductivity of the aqueous solution detected by the input solution conductivity sensor 113f, it means that the aqueous solution flowing into the containing body 133 is not adsorbed by the electrode plate module 133d and then flows out of the containing The main body 133, in other words, the electrode plate module 133d has reached the adsorption saturation state, so the control module 131 generates a discharge signal S2.

同樣地,某些實施態樣中,放電門檻值可為由使用者自行調整之可變設定值,亦可等於輸入溶液導電度感測器133f偵測之水溶液之導電度,如此一來,當控制模組131判斷輸出溶液導電度感測器133e偵測之水溶液之導電度,下降至輸入溶液導電度感測器133f之水溶液之導電度時,代表電極板模組133d已無針對流入容置主體133之水溶液釋放離子,換言之,即電極板模組133d已放電完畢,因此,控制模組131產生放電結束訊號S5。 Similarly, in some implementations, the discharge threshold value can be a variable setting value adjusted by the user, and can also be equal to the conductivity of the aqueous solution detected by the input solution conductivity sensor 133f. In this way, when When the control module 131 judges the conductivity of the aqueous solution detected by the output solution conductivity sensor 133e and decreases to the conductivity of the aqueous solution of the input solution conductivity sensor 133f, it means that the electrode plate module 133d has no room for inflow. The aqueous solution of the main body 133 releases ions, in other words, the electrode plate module 133d has been discharged, so the control module 131 generates a discharge end signal S5.

另需特別強調,為求較佳之導電度偵測之精準度,前述輸入溶液導電度感測器以及輸出溶液導電度感測器可分別設置於輸入閥門以及輸出閥門上,惟其並非用以限制設置之位置。本領域技術人員應可根據本發明之技術揭露,針對溶液導電度感測器 之設置位置進行調整,亦可理解如何於不同使用狀況中調整充電門檻值以及放電門檻值之大小,前述之說明同樣非用以限制充電門檻值以及放電門檻值之實施態樣。 It should also be emphasized that for better accuracy of conductivity detection, the aforementioned input solution conductivity sensor and output solution conductivity sensor can be set on the input valve and the output valve respectively, but it is not intended to limit the setting. Its location. Those skilled in the art should be able to adjust the installation position of the solution conductivity sensor according to the technical disclosure of the present invention, and also understand how to adjust the size of the charging threshold and the discharging threshold in different use conditions. The foregoing description is the same. It is not used to limit the implementation of the charging threshold and the discharging threshold.

另外,本領域技術人員同樣應可理解,輸入閥門以及輸出閥門可視情況分別連接複數水溶液輸入管線及複數水溶液輸出管線。舉例而言,CDI裝置於一般使用狀況時,可直接利用待去離子之水溶液作為放電程序之沖提液,惟於其他實施態樣中,為進一步提高電極板模組之再生效率,輸入閥門可視必要,藉由切換開關選擇不同之前端輸入管線(例如:將待去離子之水溶液輸入管線切換為用於沖提之低離子濃度水溶液管線),如此一來,由於沖提液具有較低之離子濃度,沖提電極板模組之離子之效率亦將提升。 In addition, those skilled in the art should also understand that the input valve and the output valve may be respectively connected to a plurality of aqueous solution input lines and a plurality of aqueous solution output lines according to circumstances. For example, the CDI device can directly use the aqueous solution to be deionized as the eluent for the discharge process in general use conditions. However, in other implementations, in order to further improve the regeneration efficiency of the electrode plate module, the input valve is visible. Necessary, select a different front-end input line (for example: switch the input line of the aqueous solution to be deionized to a low-ion-concentration aqueous solution line by means of a switch). As a result, the eluent has lower ion Concentration, the efficiency of ion extraction from the electrode plate module will also be improved.

另一方面,輸出閥門亦可藉由切換開關連接不同後端輸出管線,以將去離子之水溶液以及高濃度離子之水溶液分別藉由不同管線輸出,如此一來,便可明確地將去離子之水溶液以及沖提後之高離子濃度之水溶液分開輸出。 On the other hand, the output valve can also be connected to different back-end output pipelines through the switch to output the deionized aqueous solution and high-concentration ion aqueous solution respectively through different pipelines. In this way, the deionized The aqueous solution and the high ion concentration aqueous solution after the extraction are output separately.

另外須強調的是,本發明前述水溶液靜置之程序,將可使放電程序中,沖提時之水溶液離子之濃度大幅提升,以降低沖堤所需之水溶液水量,進而提升水回收效率。其中,隨著靜置之時間區間不同,將使得放電程序中,沖提時之水溶液離子濃度提高程度亦有所不同。本領域技術人員可就實際使用情況以及需求決定靜置之時間區間之長短。 In addition, it should be emphasized that the above-mentioned procedure for standing the aqueous solution in the present invention can greatly increase the concentration of the aqueous solution ions during the flushing in the discharge procedure, so as to reduce the amount of aqueous solution water required for flushing the bank, thereby improving the water recovery efficiency. Among them, with the different time interval of standing, the degree of increase of the ion concentration of the aqueous solution during the extraction process will be different in the discharge process. A person skilled in the art can determine the length of the time period for standing based on actual use conditions and requirements.

以實例而言,操作條件如下:(1)CDI裝置之電極板 模組使用之電極板尺寸為20公分×20公分,並以商用活性碳製作電極;(2)針對濃度為10毫莫耳/升之氯化鈉水溶液(鹽水)進行去離子(脫鹽)處理:(3)控制模組施加予電極板模組之電壓為1.2伏特;(4)水溶液幫浦將水溶液以10毫升/分鐘之流量通入容置主體。 For example, the operating conditions are as follows: (1) the electrode plate module used in the CDI device has a size of 20 cm x 20 cm, and the electrode is made of commercial activated carbon; Lithium sodium chloride aqueous solution (brine) is subjected to deionization (desalting) treatment: (3) the voltage applied by the control module to the electrode plate module is 1.2 volts; (4) the aqueous solution pumps the aqueous solution at a flow rate of 10 ml / min Access the accommodation body.

據此,透過前述環境,若將靜置之時間區間分別設定為5分鐘、10分鐘、20分鐘、與30分鐘,藉以讓電極板孔洞中之離子傳輸至容置主體之水溶液中時,放電程序之導電度數據變化情形整理如第1F~1I圖所示。其中,透過圖示可理解,靜置之時間區間越長,後續放電程序中,沖提初始排放之水溶液之最高濃度越高。 According to this, through the foregoing environment, if the standing time intervals are set to 5 minutes, 10 minutes, 20 minutes, and 30 minutes, respectively, so that the ions in the hole of the electrode plate are transmitted to the aqueous solution containing the main body, the discharge procedure The change of the conductivity data is shown in Figures 1F ~ 1I. It can be understood from the illustration that the longer the time period for standing, the higher the highest concentration of the aqueous solution initially discharged in the subsequent discharge process.

明顯地,靜置時間區間越長,自電極板模組孔洞中擴散至容置主體之離子量就越多,如此便可大幅地提升放電時之沖提效率。另外,由第1F~1I圖之數據變化可一併理解,當靜置時間區間較長,放電沖提使電極板模組完全釋放離子之時間(即導電度下降至正常狀態之時間)亦變得較短。換句話說,即代表電極板模組再生之速度亦可大幅提升,以較少水溶液水量完成電極再生程序。 Obviously, the longer the standing time interval, the more the amount of ions diffused from the hole of the electrode plate module to the accommodating body, so that the charging efficiency during discharge can be greatly improved. In addition, from the data changes in Figures 1F ~ 1I, it can be understood together that when the standing time interval is longer, the time during which the discharge flushing makes the electrode plate module completely release ions (that is, the time when the conductivity drops to normal state) also changes Get shorter. In other words, it means that the regeneration speed of the electrode plate module can also be greatly improved, and the electrode regeneration process can be completed with less aqueous water.

再者,由第1J圖所示數據可知,水回收率隨著靜置時間之增加而顯著地上升。其中,靜置時間5分鐘之水回收率為49.3%,靜置時間10分鐘之水回收率為66.3%,靜置時間20分鐘之水回收率為83.2%,靜置時間30分鐘之水回收率為83.4%。如此一 來,透過實際數據可知,靜置程序對於CDI裝置整體之處理效率確實有大幅度之改善。 In addition, from the data shown in Figure 1J, it can be seen that the water recovery rate increases significantly with the increase of the standing time. Among them, the water recovery rate of 5 minutes was 49.3%, the water recovery rate of 10 minutes was 66.3%, the water recovery rate of 20 minutes was 83.2%, and the water recovery rate was 30 minutes It was 83.4%. In this way, according to the actual data, it can be seen that the standing process has indeed greatly improved the overall processing efficiency of the CDI device.

本發明之第二實施例係為CDI控制方法,其流程圖請參考第2A圖。第二實施例之方法係用於一CDI自動控制系統(例如前述實施例之CDI自動控制系統),CDI自動控制系統包含一自動控制伺服器以及一CDI裝置。自動控制伺服器與CDI裝置透過網路連線通訊。 The second embodiment of the present invention is a CDI control method. Please refer to FIG. 2A for the flowchart. The method of the second embodiment is applied to a CDI automatic control system (such as the CDI automatic control system of the foregoing embodiment). The CDI automatic control system includes an automatic control server and a CDI device. The automatic control server communicates with the CDI device through a network connection.

同樣地,自動控制伺服器包含一處理器以及一通訊模組,CDI裝置包含一控制模組以及一容置主體。容置主體設有一水溶液幫浦、一輸入閥門、一輸出閥門、一輸出溶液導電度感測器、一輸入溶液導電度感測器以及一電極板模組。第二實施例之詳細步驟如下所述。 Similarly, the automatic control server includes a processor and a communication module, and the CDI device includes a control module and a receiving body. The accommodating body is provided with an aqueous solution pump, an input valve, an output valve, an output solution conductivity sensor, an input solution conductivity sensor, and an electrode plate module. The detailed steps of the second embodiment are as follows.

首先,執行步驟201,自動控制伺服器之處理器透過通訊模組傳送一充電訊號至CDI裝置。執行步驟202,CDI裝置之控制模組根據充電訊號開啟水溶液幫浦,俾水溶液自輸入閥門流入容置主體並自輸出閥門流出,同時,控制模組根據充電訊號施加電壓予電極板模組,以吸附水溶液之離子。 First, step 201 is executed, the processor of the automatic control server sends a charging signal to the CDI device through the communication module. Step 202 is executed. The control module of the CDI device turns on the water pump according to the charging signal. The tritium water solution flows from the input valve into the accommodating body and flows out from the output valve. Adsorb ions in aqueous solution.

接著,執行步驟203,CDI裝置之控制模組於判斷輸出溶液導電度感測器偵測之水溶液之導電度上升至一充電門檻值後,產生一放電訊號,並將放電訊號傳送至自動控制伺服器。執行步驟204,自動控制伺服器之處理器透過通訊模組自CDI裝置接收放電訊號。執行步驟205,自動控制伺服器之處理器根據放電訊號, 透過通訊模組傳送一靜置訊號至CDI裝置。 Then, step 203 is executed. After the control module of the CDI device judges that the conductivity of the aqueous solution detected by the conductivity sensor of the output solution rises to a charging threshold, it generates a discharge signal and transmits the discharge signal to the automatic control servo. Device. Step 204 is executed, the processor of the automatic control server receives the discharge signal from the CDI device through the communication module. Step 205 is executed, and the processor of the automatic control server transmits a static signal to the CDI device through the communication module according to the discharge signal.

同樣地,前述「水溶液之導電度上升至充電門檻值」之詳細狀況為:水溶液之導電度因水中離子持續被吸附至電極板模組而先降低,並會持續下降至特定低點。隨後,在電極板模組之電離子吸附狀況隨時間趨於飽和之過程中,水溶液之導電度將自特定低點上升至充電門檻值。 Similarly, the detailed status of the aforementioned "conductivity of the aqueous solution rises to the charging threshold" is that the conductivity of the aqueous solution first decreases due to the ions in the water being continuously adsorbed to the electrode plate module, and will continue to drop to a specific low point. Subsequently, in a process in which the ion adsorption state of the electrode plate module tends to be saturated with time, the conductivity of the aqueous solution will rise from a specific low point to the charging threshold.

隨後,執行步驟206,CDI裝置之控制模組根據靜置訊號關閉水溶液幫浦,俾水溶液於容置主體中靜置,同時,控制模組將電極板模組接地。執行步驟207,自動控制伺服器之處理器於一時間區間後,透過通訊模組傳送一沖提訊號至CDI裝置。 Subsequently, step 206 is executed, the control module of the CDI device turns off the aqueous solution pump according to the static signal, the tritium aqueous solution is left standing in the containing body, and at the same time, the control module grounds the electrode plate module. Step 207 is executed. After a time interval, the processor of the automatic control server sends a flush signal to the CDI device through the communication module.

接著,執行步驟208,CDI裝置之控制模組根據沖提訊號開啟水溶液幫浦,俾水溶液自輸入閥門流入容置主體並自輸出閥門流出。如此,便可將具有高濃度離子之水溶液排出,同時利用水溶液進一步地沖提電極板模組,以協助釋放其餘吸附之離子,並於釋放完畢後完成一次水溶液去離子循環。 Next, step 208 is executed, the control module of the CDI device turns on the aqueous solution pump according to the extraction signal, and the tritium aqueous solution flows from the input valve into the accommodating body and flows out from the output valve. In this way, the aqueous solution with high concentration of ions can be discharged, and at the same time, the electrode plate module is further flushed with the aqueous solution to help release the remaining adsorbed ions, and after the release is completed, the aqueous solution deionization cycle is completed.

需特別強調,類似地,若考慮進一步之實施態樣,請同時參考第2B圖。詳言之,於沖提之實施細節中,可進一步執行步驟209,CDI裝置之控制模組於判斷輸出閥門之水溶液之導電度下降至一放電門檻值後,將產生一放電結束訊號,並將放電結束訊號傳送至自動控制伺服器。 It should be particularly emphasized that, similarly, if further implementation is considered, please also refer to Figure 2B. In detail, in the implementation details of the extraction, step 209 can be further performed. After the control module of the CDI device judges that the conductivity of the aqueous solution of the output valve drops to a discharge threshold value, it will generate a discharge end signal, and Discharge end signal is sent to the automatic control server.

類似地,前述「水溶液之導電度下降至放電門檻值」之詳細狀況為:水溶液之導電度因導電板模組持續釋放離子而先 上升至特定高點。隨後,在電極板模組之電離子釋放隨時間趨緩之過程中,水溶液之導電度將自特定高點下降至放電門檻值。 Similarly, the detailed situation of the aforementioned “conductivity of the aqueous solution falling to the discharge threshold” is that the conductivity of the aqueous solution first rises to a specific high point due to the continuous release of ions by the conductive plate module. Subsequently, in the process that the ion release of the electrode plate module slows down with time, the conductivity of the aqueous solution will drop from a certain high point to the discharge threshold.

據此,執行步驟210,自動控制伺服器之處理器透過通訊模組接收放電結束訊號後,表示CDI裝置已完成一次水溶液去離子循環,因此,自動控制伺服器之處理器便再次自動地透過通訊模組,傳送充電訊號至CDI裝置,藉以回到步驟201,重新進行新的水溶液去離子循環。 According to this, step 210 is executed. After the processor of the automatic control server receives the end-of-discharge signal through the communication module, it indicates that the CDI device has completed an aqueous solution deionization cycle. Therefore, the processor of the automatic control server automatically automatically communicates again through communication. The module sends a charging signal to the CDI device, and then returns to step 201 to perform a new aqueous solution deionization cycle.

同樣地,就第二實施例之CDI控制方法觀之,於某些實施態樣中,充電門檻值係為可變設定值。其中,可變設定值可由使用者自行根據環境所需進行調整。另一方面,於某些實施態樣中,充電門檻值係等於輸入溶液導電度感測器偵測之水溶液之導電度,如此一來,當CDI裝置之控制模組判斷輸出溶液導電度感測器偵測之水溶液之導電度上升至輸入溶液導電度感測器偵測之水溶液之導電度時,代表流入容置主體之水溶液並無離子被電極板模組吸附便流出容置主體,換言之,即電極板模組已達吸附飽和狀態,因此,控制模組產生放電訊號。 Similarly, regarding the CDI control method of the second embodiment, in some implementation aspects, the charging threshold value is a variable set value. Among them, the variable setting value can be adjusted by the user according to the needs of the environment. On the other hand, in some embodiments, the charging threshold is equal to the conductivity of the aqueous solution detected by the input solution conductivity sensor. In this way, when the control module of the CDI device judges the output solution conductivity sensing When the conductivity of the aqueous solution detected by the sensor rises to the conductivity of the aqueous solution detected by the input solution conductivity sensor, it means that the aqueous solution flowing into the accommodating body is flowed out of the accommodating body without being adsorbed by the electrode plate module, in other words, That is, the electrode plate module has reached the adsorption saturation state, so the control module generates a discharge signal.

另一方面,於某些實施態樣中,放電門檻值同樣可為由使用者自行調整之可變設定值,亦可等於輸入溶液導電度感測器偵測之水溶液之導電度,如此一來,當控制模組判斷輸出溶液導電度感測器偵測之水溶液之導電度下降至輸入溶液導電度感測器偵測之水溶液之導電度時,代表電極板模組已無針對流入容置主體之水溶液釋放離子,換言之,即電極板模組已放電完畢,因此, 控制模組產生放電結束訊號。 On the other hand, in some implementations, the discharge threshold value can also be a variable set value adjusted by the user, and can also be equal to the conductivity of the aqueous solution detected by the input solution conductivity sensor. When the control module judges that the conductivity of the aqueous solution detected by the conductivity sensor of the output solution drops to the conductivity of the aqueous solution detected by the conductivity sensor of the input solution, it means that the electrode plate module has not been directed to flow into the accommodating body. The aqueous solution releases ions, in other words, the electrode plate module has been discharged, so the control module generates an end-of-discharge signal.

綜合上述,本發明所提供CDI控制方法及其自動控制系統,可透過自動化之偵測以及訊號傳遞,完成CDI裝置之整體流程,如此一來,便可節省人力資源並提高結果之精準度。更者,本發明所提供之CDI控制方法及其自動控制系統中具有創新之放電程序,而透過實驗數據可知此改善後之程序可有效地加快CDI沖提效率,並大幅地提升水回收率。 To sum up, the CDI control method and the automatic control system provided by the present invention can complete the overall process of the CDI device through automated detection and signal transmission. In this way, human resources can be saved and the accuracy of the results can be improved. Furthermore, the CDI control method and the automatic control system provided by the present invention have an innovative discharge program, and it can be known from the experimental data that the improved program can effectively accelerate the CDI extraction efficiency and greatly improve the water recovery rate.

惟上述實施例僅為例示性明本發明之實施態樣,以及闡釋本發明之技術特徵,並非用來限制本發明之保護範疇。任何熟悉此技藝之人士可輕易完成之改變或均等性之安排均屬於本發明所主張之範圍,本發明之權利保護範圍應以申請專利範圍為準。 However, the above-mentioned embodiments are merely for exemplifying the implementation aspects of the present invention and explaining the technical features of the present invention, and are not intended to limit the protection scope of the present invention. Any change or equivalence arrangement that can be easily accomplished by those skilled in the art belongs to the scope claimed by the present invention, and the scope of protection of the rights of the present invention shall be subject to the scope of patent application.

Claims (24)

一種用於自動控制伺服器之電容電容去離子控制方法,該自動控制伺服器與一電容去離子裝置間透過網路連線通訊,該自動控制伺服包含一處理器以及一通訊模組,該電容去離子裝置包含一控制模組以及一容置主體,該容置主體設有一水溶液幫浦、一輸入閥門、一輸出閥門、一輸出溶液導電度感測器以及一電極板模組,該電容電容去離子控制方法包含下列步驟:該處理器透過該通訊模組傳送一充電訊號至該電容去離子裝置,其中,該充電訊號用以通知該控制模組:開啟該水溶液幫浦,俾水溶液自該輸入閥門流入該容置主體並自該輸出閥門流出;以及施加電壓予該電極板模組,以吸附水溶液之離子;該處理器透過該通訊模組自該電容去離子裝置接收該控制模組之一放電訊號,其中,該控制模組判斷該輸出溶液導電度感測器偵測之水溶液之導電度上升至一充電門檻值後,產生該放電訊號;該處理器根據該放電訊號,透過該通訊模組傳送一靜置訊號至該電容去離子裝置,其中,該靜置訊號用以通知該控制模組:關閉該水溶液幫浦,俾水溶液於該容置主體中靜置;以及將該電極板模組接地;該處理器於一時間區間後,透過該通訊模組傳送一沖提訊號至該電容去離子裝置,其中,該沖提訊號用以通知該控制模組:開啟該水溶液幫浦,俾水溶液自該輸入閥門流入該容置主體並自該輸出閥門流出。     A capacitor and capacitor deionization control method for an automatic control server. The automatic control server and a capacitor deionization device communicate through a network connection. The automatic control server includes a processor and a communication module. The capacitor The deionization device includes a control module and an accommodation body. The accommodation body is provided with an aqueous solution pump, an input valve, an output valve, an output solution conductivity sensor, and an electrode plate module. The capacitor capacitor The deionization control method includes the following steps: the processor transmits a charging signal to the capacitive deionization device through the communication module, wherein the charging signal is used to notify the control module: turning on the aqueous solution pump, An input valve flows into the accommodating body and flows out from the output valve; and a voltage is applied to the electrode plate module to adsorb the ions of the aqueous solution; the processor receives the control module from the capacitor deionization device through the communication module. A discharge signal, wherein the control module determines that the conductivity of the aqueous solution detected by the output solution conductivity sensor is increased After a charging threshold value, the discharge signal is generated; the processor transmits a static signal to the capacitor deionization device through the communication module according to the discharge signal, wherein the static signal is used to notify the control module: The water pump is closed, the tritium water solution is left to stand in the housing body; and the electrode plate module is grounded; after a time interval, the processor sends an extraction signal to the capacitor deionization through the communication module. The device, wherein the flushing signal is used to notify the control module: the aqueous solution pump is turned on, the tritium aqueous solution flows from the input valve into the containing body and flows out from the output valve.     如請求項1所述之電容去離子控制方法,其中,該充電門檻值係為可變 設定值。     The capacitor deionization control method according to claim 1, wherein the charging threshold value is a variable set value.     如請求項1所述之電容去離子控制方法,其中,該容置主體更包含一輸入溶液導電度感測器,該充電門檻值係等於該輸入溶液導電度感測器偵測之水溶液之導電度。     The capacitive deionization control method according to claim 1, wherein the containing body further comprises an input solution conductivity sensor, and the charging threshold is equal to the conductivity of the aqueous solution detected by the input solution conductivity sensor. degree.     如請求項1所述之電容去離子控制方法,其中,該處理器更用以透過該通訊模組自該電容去離子裝置接收該控制模組之一放電結束訊號,其中,該控制模組判斷該輸出溶液導電度感測器偵測之水溶液之導電度下降至一放電門檻值後產生該放電結束訊號。     The capacitor deionization control method according to claim 1, wherein the processor is further configured to receive a discharge end signal of one of the control modules from the capacitor deionization device through the communication module, wherein the control module determines The discharge end signal is generated when the conductivity of the aqueous solution detected by the output solution conductivity sensor drops to a discharge threshold.     如請求項4所述之電容去離子控制方法,其中,該放電門檻值係為可變設定值。     The capacitor deionization control method according to claim 4, wherein the discharge threshold value is a variable set value.     如請求項4所述之電容去離子控制方法,其中,該容置主體更包含一輸入溶液導電度感測器,該放電門檻值係等於該輸入溶液導電度感測器偵測之水溶液之導電度。     The capacitive deionization control method according to claim 4, wherein the accommodating body further comprises an input solution conductivity sensor, and the discharge threshold is equal to the conductivity of the aqueous solution detected by the input solution conductivity sensor. degree.     一種自動控制伺服器,與一電容去離子裝置間透過網路連線通訊,該電容去離子裝置包含一控制模組以及一容置主體,該容置主體設有一水溶液幫浦、一輸入閥門、一輸出閥門、一輸出溶液導電度感測器以及一電極板模組,該自動控制伺服器包含:一處理器;以及一通訊模組;其中,該處理器透過該通訊模組傳送一充電訊號至該電容去離子裝置,其中,該充電訊號用以通知該控制模組:開啟該水溶液幫浦,俾水溶液自該輸入閥門流入該容置主體並自該輸出閥門流出;以及施加電壓予該電極板模組,以吸附水溶液之離子; 該處理器透過該通訊模組自該電容去離子裝置接收該控制模組之一放電訊號,其中,該控制模組判斷該輸出溶液導電度感測器偵測之水溶液之導電度上升至一充電門檻值後,產生該放電訊號;該處理器根據該放電訊號,透過該通訊模組傳送一靜置訊號至該電容去離子裝置,其中,該靜置訊號用以通知該控制模組:關閉該水溶液幫浦,俾水溶液於該容置主體中靜置;以及將該電極板模組接地;該處理器於一時間區間後,透過該通訊模組傳送一沖提訊號至該電容去離子裝置,其中,該沖提訊號用以通知該控制模組:開啟該水溶液幫浦,俾水溶液自該輸入閥門流入該容置主體並自該輸出閥門流出。     An automatic control server communicates with a capacitor deionization device through a network connection. The capacitor deionization device includes a control module and a receiving body. The receiving body is provided with an aqueous solution pump, an input valve, An output valve, an output solution conductivity sensor, and an electrode plate module. The automatic control server includes: a processor; and a communication module; wherein the processor transmits a charging signal through the communication module. To the capacitor deionization device, wherein the charging signal is used to notify the control module: the aqueous solution pump is turned on, the tritium solution flows from the input valve into the accommodating body and flows out from the output valve; and applying a voltage to the electrode A board module to adsorb the ions of the aqueous solution; the processor receives a discharge signal of the control module from the capacitive deionization device through the communication module, wherein the control module judges the output solution conductivity sensor to detect When the measured conductivity of the aqueous solution rises to a charging threshold, the discharge signal is generated; the processor passes the communication mode according to the discharge signal The group sends a static signal to the capacitor deionization device, wherein the static signal is used to notify the control module: shut down the aqueous solution pump, and the tritium aqueous solution is left to stand in the housing body; and the electrode plate mold The group is grounded; after a time interval, the processor sends a flush signal to the capacitive deionization device through the communication module, wherein the flush signal is used to notify the control module: turn on the aqueous pump, 俾The aqueous solution flows from the input valve into the accommodating body and flows out from the output valve.     如請求項7所述之自動控制伺服器,其中,該充電門檻值係為可變設定值。     The automatic control server according to claim 7, wherein the charging threshold value is a variable setting value.     如請求項7所述之自動控制伺服器,其中,該容置主體更包含一輸入溶液導電度感測器,該充電門檻值係等於該輸入溶液導電度感測器偵測之水溶液之導電度。     The automatic control server according to claim 7, wherein the containing body further comprises an input solution conductivity sensor, and the charging threshold is equal to the conductivity of the aqueous solution detected by the input solution conductivity sensor. .     如請求項7所述之自動控制伺服器,其中,該處理器更用以透過該通訊模組自該電容去離子裝置接收該控制模組之一放電結束訊號,其中,該控制模組判斷該輸出溶液導電度感測器偵測之水溶液之導電度下降至一放電門檻值後產生該放電結束訊號。     The automatic control server according to claim 7, wherein the processor is further configured to receive a discharge end signal of one of the control modules from the capacitive deionization device through the communication module, wherein the control module determines the When the conductivity of the aqueous solution detected by the output solution conductivity sensor drops to a discharge threshold, the discharge end signal is generated.     如請求項10所述之自動控制伺服器,其中,該放電門檻值係可變設定值。     The automatic control server according to claim 10, wherein the discharge threshold value is a variable setting value.     如請求項10所述之自動控制伺服器,其中,該容置主體更包含一輸入溶液導電度感測器,該放電門檻值係等於該輸入溶液導電度感測器偵測 之水溶液之導電度。     The automatic control server according to claim 10, wherein the accommodating body further comprises an input solution conductivity sensor, and the discharge threshold is equal to the conductivity of the aqueous solution detected by the input solution conductivity sensor. .     一種用於電容去離子自動控制系統之電容去離子控制方法,該電容去離子自動控制系統包含一自動控制伺服器以及一電容去離子裝置,該自動控制伺服器與該電容去離子裝置間透過網路連線通訊,該自動控制伺服器包含一處理器以及一通訊模組,該電容去離子裝置包含一控制模組以及一容置主體,該容置主體設有一水溶液幫浦、一輸入閥門、一輸出閥門、一輸出溶液導電度感測器以及一電極板模組,該電容去離子控制方法包含下列步驟:該處理器透過該通訊模組傳送一充電訊號至該電容去離子裝置;該控制模組根據該充電訊號,用以:開啟該水溶液幫浦,俾水溶液自該輸入閥門流入該容置主體並自該輸出閥門流出;以及施加電壓予該電極板模組,以吸附水溶液之離子;該控制模組判斷該輸出溶液導電度感測器偵測之水溶液之導電度上升至一充電門檻值後,產生該放電訊號;該處理器透過該通訊模組自該電容去離子裝置接收該控制模組之該放電訊號;該處理器根據該放電訊號,透過該通訊模組傳送一靜置訊號至該電容去離子裝置;該控制模組根據該靜置訊號,用以:關閉該水溶液幫浦,俾水溶液於該容置主體中靜置;以及將該電極板模組接地;該處理器於一時間區間後,透過該通訊模組傳送一沖提訊號至該電容去離子裝置; 該控制模組根據該沖提訊號,用以:開啟該水溶液幫浦,俾水溶液自該輸入閥門流入該容置主體並自該輸出閥門流出。     A capacitor deionization control method for an automatic capacitor deionization control system. The automatic capacitor deionization control system includes an automatic control server and a capacitor deionization device. The automatic control server and the capacitor deionization device pass through a network. Communication, the automatic control server includes a processor and a communication module, the capacitor deionization device includes a control module and a receiving body, the receiving body is provided with an aqueous solution pump, an input valve, An output valve, an output solution conductivity sensor, and an electrode plate module, the capacitor deionization control method includes the following steps: the processor transmits a charging signal to the capacitor deionization device through the communication module; the control According to the charging signal, the module is used to: turn on the aqueous solution pump, the tritium aqueous solution flows from the input valve into the accommodating body and flows out from the output valve; and a voltage is applied to the electrode plate module to adsorb the ions of the aqueous solution; The control module determines that the conductivity of the aqueous solution detected by the output solution conductivity sensor rises to a charging door After the value is generated, the discharge signal is generated; the processor receives the discharge signal of the control module from the capacitive deionization device through the communication module; the processor transmits a static signal through the communication module according to the discharge signal To the capacitor deionization device; according to the stationary signal, the control module is used to: turn off the aqueous solution pump, and place the tritium aqueous solution in the housing body; and ground the electrode plate module; the processor at After a time interval, a communication signal is transmitted to the capacitor deionization device through the communication module; the control module is used to: turn on the water pump, and the tritium water solution flows into the container from the input valve according to the communication signal. Set the main body and flow out from the output valve.     如請求項13所述之電容去離子控制方法,其中,該充電門檻值係為可變設定值。     The capacitor deionization control method according to claim 13, wherein the charging threshold value is a variable set value.     如請求項13所述之電容去離子控制方法,其中,該容置主體更包含一輸入溶液導電度感測器,該充電門檻值係等於該輸入溶液導電度感測器偵測之水溶液之導電度。     The capacitive deionization control method according to claim 13, wherein the containing body further comprises an input solution conductivity sensor, and the charging threshold is equal to the conductivity of the aqueous solution detected by the input solution conductivity sensor. degree.     如請求項13所述之電容去離子控制方法,其中,該處理器更用以透過該通訊模組自該電容去離子裝置接收該控制模組之一放電結束訊號,其中,該控制模組判斷該輸出溶液導電度感測器偵測之水溶液之導電度下降至一放電門檻值後產生該放電結束訊號。     The capacitor deionization control method according to claim 13, wherein the processor is further configured to receive a discharge end signal of one of the control modules from the capacitor deionization device through the communication module, wherein the control module determines The discharge end signal is generated when the conductivity of the aqueous solution detected by the output solution conductivity sensor drops to a discharge threshold.     如請求項16所述之電容去離子控制方法,其中,該放電門檻值係可變設定值。     The capacitive deionization control method according to claim 16, wherein the discharge threshold value is a variable set value.     如請求項16所述之電容去離子控制方法,其中,該容置主體更包含一輸入溶液導電度感測器,該放電門檻值係等於該輸入溶液導電度感測器偵測之水溶液之導電度。     The capacitive deionization control method according to claim 16, wherein the containing body further comprises an input solution conductivity sensor, and the discharge threshold is equal to the conductivity of the aqueous solution detected by the input solution conductivity sensor. degree.     一種電容去離子自動控制系統,包含:一自動控制伺服器,包含:一處理器;以及一通訊模組;一電容去離子裝置,與該自動控制伺服器間透過網路連線通訊,包含:一控制模組;以及 一容置主體,設有一水溶液幫浦、一輸入閥門、一輸出閥門、一輸出溶液導電度感測器以及一電極板模組;其中,該處理器透過該通訊模組傳送一充電訊號至該電容去離子裝置;該控制模組根據該充電訊號,用以:開啟該水溶液幫浦,俾水溶液自該輸入閥門流入該容置主體並自該輸出閥門流出;以及施加電壓予該電極板模組,以吸附水溶液之離子;該控制模組判斷該輸出溶液導電度感測器偵測之水溶液之導電度上升至一充電門檻值後,產生該放電訊號;該處理器透過該通訊模組自該電容去離子裝置接收該控制模組之該放電訊號;該處理器根據該放電訊號,透過該通訊模組傳送一靜置訊號至該電容去離子裝置;該控制模組根據該靜置訊號,用以:關閉該水溶液幫浦,俾水溶液於該容置主體中靜置;以及將該電極板模組接地;該處理器於一時間區間後,透過該通訊模組傳送一沖提訊號至該電容去離子裝置;該控制模組根據該沖提訊號,用以:開啟該水溶液幫浦,俾水溶液自該輸入閥門流入該容置主體並自該輸出閥門流出。     An automatic capacitor deionization control system includes: an automatic control server including: a processor; and a communication module; a capacitor deionization device communicates with the automatic control server through a network connection and includes: A control module; and a housing body provided with an aqueous solution pump, an input valve, an output valve, an output solution conductivity sensor, and an electrode plate module; wherein the processor passes the communication module Sending a charging signal to the capacitor deionization device; the control module is used to: turn on the aqueous solution pump, the tritium aqueous solution flows from the input valve into the containing body and flows out of the output valve; and the applied voltage The electrode plate module is used to adsorb the ions of the aqueous solution; the control module judges that the conductivity of the aqueous solution detected by the output solution conductivity sensor rises to a charging threshold value, and generates the discharge signal; the processor passes The communication module receives the discharge signal of the control module from the capacitor deionization device; the processor passes the communication according to the discharge signal The module sends a static signal to the capacitor deionization device; the control module is used to: shut down the aqueous solution pump, the tritium aqueous solution is left in the housing body according to the static signal; and the electrode plate mold The group is grounded; after a time interval, the processor sends an extraction signal to the capacitor deionization device through the communication module; the control module is used to: turn on the aqueous solution pump, and rinse the aqueous solution according to the extraction signal Flow from the input valve into the receiving body and flow out from the output valve.     如請求項19所述之電容去離子自動控制系統,其中,該充電門檻值係可變設定值。     The automatic capacitor deionization control system according to claim 19, wherein the charging threshold value is a variable set value.     如請求項19所述之電容去離子自動控制系統,其中,該容置主體更包含一輸入溶液導電度感測器,該充電門檻值係等於該輸入溶液導電度感測器偵測之水溶液之導電度。     The automatic capacitor deionization control system according to claim 19, wherein the accommodating body further comprises an input solution conductivity sensor, and the charging threshold value is equal to that of the aqueous solution detected by the input solution conductivity sensor. Electrical conductivity.     如請求項19所述之電容去離子自動控制系統,其中,該處理器更用以透過該通訊模組自該電容去離子裝置接收該控制模組之一放電結束訊號,其中,該控制模組判斷該輸出溶液導電度感測器偵測之水溶液之導電度下降至一放電門檻值後產生該放電結束訊號。     The automatic capacitor deionization control system according to claim 19, wherein the processor is further configured to receive a discharge end signal of one of the control modules from the capacitor deionization device through the communication module, wherein the control module It is judged that the discharge end signal is generated after the conductivity of the aqueous solution detected by the output solution conductivity sensor drops to a discharge threshold.     如請求項22所述之電容去離子自動控制系統,其中,該放電門檻值係可變設定值。     The automatic capacitor deionization control system according to claim 22, wherein the discharge threshold value is a variable set value.     如請求項22.所述之電容去離子自動控制系統,其中,該容置主體更包含一輸入溶液導電度感測器,該放電門檻值係等於該輸入溶液導電度感測器偵測之水溶液之導電度。     The capacitive deionization automatic control system according to claim 22., wherein the containing body further comprises an input solution conductivity sensor, and the discharge threshold is equal to the aqueous solution detected by the input solution conductivity sensor Of electrical conductivity.    
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