TW201910893A - Light emitting direction controlling sheet - Google Patents
Light emitting direction controlling sheet Download PDFInfo
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Description
本發明涉及一種入射的光束中,僅透過具有特定的入射角的光線的光透過方向控制片。更詳細而言,本發明涉及一種在設置於照明、各種資訊顯示裝置的顯示畫面等時,能夠實現窄視角的光透過方向控制片。 The present invention relates to a light transmission direction control sheet that transmits only light having a specific incident angle among incident light beams. More specifically, the present invention relates to a light transmission direction control sheet capable of realizing a narrow viewing angle when installed on illumination, display screens of various information display devices, and the like.
(專利文獻1)公開了一種防窺體,其設置在行動資訊終端、自動存取款機等資訊顯示裝置的顯示畫面,無需損傷來自顯示畫面跟前側的辨認性,就能夠防止來自左右側及對面側的窺視。該防窺體形成由下述層所層疊的三層構造,即:光透過帶和遮光帶交替設置的防眩層、設置在該防眩層的一個表面上的透光性的黏貼層以及設置在與該黏貼層相反側的防眩層的另一個表面上的透光層。黏貼層黏貼在資訊顯示裝置的顯示畫面上使用。 (Patent Document 1) discloses a sneak-proof body which is provided on a display screen of an information display device such as an action information terminal or an automatic depositing and dispensing machine, and can prevent the left and right sides from being damaged without damaging the visibility from the front side of the display screen. Peek on the opposite side. The anti-puncture body is formed into a three-layer structure in which the layers are laminated, that is, an anti-glare layer in which the light-transmitting belt and the light-shielding belt are alternately disposed, a translucent adhesive layer provided on one surface of the anti-glare layer, and a setting. a light transmissive layer on the other surface of the antiglare layer on the side opposite to the adhesive layer. The adhesive layer is pasted on the display screen of the information display device.
專利文獻1:日本國專利第3675752號公報 Patent Document 1: Japanese Patent No. 3675752
通過將光透過方向控制片(防窺體)裝入行動資訊終端的內部,從而需要提高用戶的便利性。由於專利文獻1的防窺體所具備的透光層出於提高防窺體的剛性的目的而具有足夠的厚度,因此,不適合裝入狹窄的終端內部的用途。在出於薄型化目的而除去上述防窺體的透光層時,在防眩層的表面會露出製造時不可避免地形成的微小凹凸。由於光通過該凹凸而亂反射,因此,存在霧度值變高,而不能清楚地辨認透過防眩層的圖像以及不能清楚地辨認防眩層本身之類的問題。 By incorporating the light transmission direction control sheet (anti-peeping body) into the inside of the mobile information terminal, it is necessary to improve user convenience. Since the light-transmitting layer provided in the anti-spy material of Patent Document 1 has a sufficient thickness for the purpose of improving the rigidity of the anti-peeping body, it is not suitable for use in a narrow terminal. When the light-transmitting layer of the above-described anti-puncture body is removed for the purpose of thinning, minute irregularities which are inevitably formed at the time of manufacture are exposed on the surface of the anti-glare layer. Since the light is reflected by the irregularities, the haze value becomes high, and the image transmitted through the anti-glare layer and the problem that the anti-glare layer itself cannot be clearly recognized cannot be clearly recognized.
如果將該防窺體黏接在顯示畫面上,就能夠抑制上述光的亂反射,但由於難以透視(透過而看到)黏接前的防窺體,因此,存在難以進行防窺體的品質檢查的問題。 When the anti-spying body is adhered to the display screen, it is possible to suppress the random reflection of the light. However, since it is difficult to see through (see through) the anti-peeping body before the bonding, it is difficult to perform the quality of the anti-peeping body. Check the problem.
另外,在以往的防窺體中,由於構成透光層的透明樹脂的折射率和構成防眩層的透明樹脂的折射率不同,因此,也存在因折射率不同而導致光透過率下降的問題。 Further, in the conventional anti-puncture body, since the refractive index of the transparent resin constituting the light-transmitting layer is different from the refractive index of the transparent resin constituting the anti-glare layer, there is a problem that the light transmittance is lowered due to the difference in refractive index. .
本發明是鑒於上述問題而完成的,目的在於提供具有優異的光透過率,能夠通過目視進行品質檢查的光透過方向控制片。 The present invention has been made in view of the above problems, and it is an object of the invention to provide a light transmission direction control sheet which has excellent light transmittance and can be visually inspected for quality.
[1]一種光透過方向控制片,具備:反復交替設置有光透過帶和遮光帶的格柵層;設置在上述格柵層的第一面的第一透明樹脂層;設置在上述格柵層的第二面的第二透明樹脂層,上述光透過帶的折射率和上述第一透明樹脂層 的折射率之差、以及上述光透過帶的折射率和上述第二透明樹脂層的折射率之差均小於0.1。 [1] A light transmission direction control sheet comprising: a grid layer in which a light transmission belt and a light shielding tape are alternately arranged; a first transparent resin layer provided on a first surface of the grid layer; and a grid layer disposed on the grid layer a second transparent resin layer on the second surface, a difference between a refractive index of the light transmission band and a refractive index of the first transparent resin layer, and a refractive index of the light transmission band and a refractive index of the second transparent resin layer The difference is less than 0.1.
[2]根據[1]記載的光透過方向控制片,其中,上述第一透明樹脂層的外表面和上述第二透明樹脂層的外表面中至少一者的外表面的算術平均粗糙度Ra為0μm至3.0μm。 [2] The light transmission direction control sheet according to [1], wherein an arithmetic mean roughness Ra of an outer surface of at least one of an outer surface of the first transparent resin layer and an outer surface of the second transparent resin layer is 0 μm to 3.0 μm.
[3]根據[1]記載的光透過方向控制片,其中,上述光透過帶、上述第一透明樹脂層以及上述第二透明樹脂層由矽橡膠形成。 [3] The light transmission direction control sheet according to [1], wherein the light transmission belt, the first transparent resin layer, and the second transparent resin layer are formed of tantalum rubber.
[4]根據[2]記載的光透過方向控制片,其中,上述光透過帶、上述第一透明樹脂層以及上述第二透明樹脂層由矽橡膠形成。 [4] The light transmission direction control sheet according to [2], wherein the light transmission band, the first transparent resin layer, and the second transparent resin layer are formed of tantalum rubber.
[5]根據[1]至[4]中任一項記載的光透過方向控制片,其中,上述格柵層的厚度是150μm至500μm,上述第一透明樹脂層的厚度是10μm至20μm,上述第二透明樹脂層的厚度是10μm至20μm。 [5] The light transmission direction control sheet according to any one of [1] to [4] wherein the thickness of the grid layer is 150 μm to 500 μm, and the thickness of the first transparent resin layer is 10 μm to 20 μm, The thickness of the second transparent resin layer is from 10 μm to 20 μm.
根據本發明的光透過方向控制片,由於格柵層和第一及第二透明樹脂層之界面中的界面反射下降,因而具有優異的光透過率。由此,能夠抑制所設置的顯示畫面的亮度的下降,即使在設定較低背光亮度的情況下,也能夠得到足夠明亮的顯示畫面。此外,能夠實現背光的低功耗。進而,由於具有優異的光透過率,因此能夠通過目視容易進行品質檢查。即使在將本發明的光透過方向控制 片實現薄型化的情況下,也能夠充分發揮這些優異的效果,因此,能夠容易地裝入資訊顯示裝置的內部。 According to the light transmission direction control sheet of the present invention, since the interface reflection in the interface between the grid layer and the first and second transparent resin layers is lowered, the light transmittance is excellent. Thereby, it is possible to suppress a decrease in the brightness of the displayed display screen, and it is possible to obtain a sufficiently bright display screen even when a low backlight brightness is set. In addition, low power consumption of the backlight can be achieved. Further, since it has excellent light transmittance, it is possible to easily perform quality inspection by visual observation. Even when the light transmission direction control sheet of the present invention is made thinner, these excellent effects can be sufficiently exhibited, and therefore, it can be easily incorporated into the inside of the information display device.
1‧‧‧格柵層 1‧‧‧ Grid layer
2‧‧‧光透過帶 2‧‧‧Light transmission belt
3‧‧‧遮光帶 3‧‧‧Lighting tape
4‧‧‧第一透明樹脂層 4‧‧‧First transparent resin layer
4a‧‧‧第一透明樹脂層的外表面 4a‧‧‧ outer surface of the first transparent resin layer
5‧‧‧第二透明樹脂層 5‧‧‧Second transparent resin layer
5a‧‧‧第二透明樹脂層的外表面 5a‧‧‧ outer surface of the second transparent resin layer
10‧‧‧光透過方向控制片 10‧‧‧Light transmission direction control film
20‧‧‧光透過方向控制片 20‧‧‧Light transmission direction control film
21‧‧‧第一透明樹脂層 21‧‧‧First transparent resin layer
22‧‧‧第一格柵層 22‧‧‧First grid layer
23‧‧‧第三透明樹脂層 23‧‧‧ Third transparent resin layer
24‧‧‧第二格柵層 24‧‧‧Second grid layer
25‧‧‧第二透明樹脂層 25‧‧‧Second transparent resin layer
26‧‧‧光透過帶 26‧‧‧Light transmission belt
27‧‧‧遮光帶 27‧‧‧Lighting tape
28‧‧‧光透過帶 28‧‧‧Light transmission belt
29‧‧‧遮光帶 29‧‧‧Lighting tape
第1圖是示出本發明的光透過方向控制片的一例的截面圖。 Fig. 1 is a cross-sectional view showing an example of a light transmission direction control sheet of the present invention.
第2圖是示出本發明的光透過方向控制片的另一例的立體圖。 Fig. 2 is a perspective view showing another example of the light transmission direction control sheet of the present invention.
如第1圖所示,本發明的光透過方向控制片10具備:反復交替設置有光透過帶2和遮光帶3的格柵層1;設置在格柵層1的第一面的第一透明樹脂層4;設置在格柵層1的第二面的第二透明樹脂層5。 As shown in Fig. 1, the light transmission direction control sheet 10 of the present invention includes: a grid layer 1 in which the light transmission belt 2 and the light shielding tape 3 are alternately arranged; and a first transparent surface provided on the first surface of the grid layer 1 a resin layer 4; a second transparent resin layer 5 provided on the second surface of the grid layer 1.
各個光透過帶2及各個遮光帶3係沿著格柵層1的厚度方向形成。換言之,光透過帶2及遮光帶3在格柵層1的寬度方向(與厚度方向的垂直的方向)反復交替設置。在格柵層1中,光通過夾在遮光帶3之間的光透過帶2,沿格柵層1的厚度方向,亦即沿光透過方向控制片10的厚度方向透過。 Each of the light transmission bands 2 and the respective light shielding tapes 3 are formed along the thickness direction of the grating layer 1. In other words, the light transmission band 2 and the light shielding tape 3 are alternately arranged alternately in the width direction (the direction perpendicular to the thickness direction) of the grid layer 1. In the grid layer 1, light is transmitted through the light-transmitting belt 2 sandwiched between the light-shielding belts 3 in the thickness direction of the grid layer 1, that is, in the thickness direction of the light-transmitting direction control sheet 10.
在光透過方向控制片10中,格柵層1的第一面支撐薄片的第一主面,格柵層1的第二面支撐薄片的第二主面,第一面和第二面是彼此對置的面。 In the light transmission direction control sheet 10, the first surface of the grid layer 1 supports the first main surface of the sheet, and the second surface of the grid layer 1 supports the second main surface of the sheet, the first side and the second side are each other Opposite face.
光透過方向控制片10的大小沒有特別限定,可以列舉例如:在平面圖中為長1mm至1500mm, 寬1mm至1500mm左右的矩形的大小。對於光透過方向控制片10的厚度,將在後面記載。 The size of the light transmission direction control sheet 10 is not particularly limited, and may be, for example, a size of a rectangle having a length of 1 mm to 1500 mm and a width of 1 mm to 1500 mm in plan view. The thickness of the light transmission direction control sheet 10 will be described later.
在光透過方向控制片10中,光透過帶2的折射率和第一透明樹脂層4的折射率之差、以及光透過帶2的折射率和第二透明樹脂層5的折射率之差分別小於0.1。在此,各折射率之差均為絕對值。 In the light transmission direction controlling sheet 10, the difference between the refractive index of the light transmitting belt 2 and the refractive index of the first transparent resin layer 4, and the difference between the refractive index of the light transmitting belt 2 and the refractive index of the second transparent resin layer 5 are respectively Less than 0.1. Here, the difference in refractive index is an absolute value.
在本發明中,“折射率”是該構件在真空中的折射率,是指絕對折射率。該折射率按照JIS K 7142:2014(ISO489:1999)“塑料-折射率的測定方法”的A法測定。 In the present invention, "refractive index" is the refractive index of the member in a vacuum, and refers to an absolute refractive index. This refractive index is measured in accordance with the method A of JIS K 7142:2014 (ISO 489:1999) "Method for measuring plastic-refractive index".
光透過帶2的折射率和第一透明樹脂層4的折射率之差小於0.1,以小於0.01為佳,以實質上的差為零者更佳,由此,格柵層1和第一透明樹脂層4之界面的界面反射下降,光透過率提高。同樣地,光透過帶2的折射率和第二透明樹脂層5的折射率之差小於0.1,以小於0.05為佳,以小於0.02更佳,以實質上的差為零者最佳,由此,格柵層1和第二透明樹脂層5之界面的界面反射下降,光透過率提高。其結果,光透過方向控制片10具有優異的光透過性。 The difference between the refractive index of the light transmitting strip 2 and the refractive index of the first transparent resin layer 4 is less than 0.1, preferably less than 0.01, and substantially less than zero, whereby the grid layer 1 and the first transparent The interface reflection at the interface of the resin layer 4 is lowered, and the light transmittance is improved. Similarly, the difference between the refractive index of the light transmitting belt 2 and the refractive index of the second transparent resin layer 5 is less than 0.1, preferably less than 0.05, more preferably less than 0.02, and most preferably substantially zero. The interface reflection at the interface between the grid layer 1 and the second transparent resin layer 5 is lowered, and the light transmittance is improved. As a result, the light transmission direction control sheet 10 has excellent light transmittance.
在未設置透明樹脂層而格柵層1的表面露出的情況下,由於在該露出面上出現光的亂反射,因此,難以透過格柵層1通過目視確認構成格柵層1的光透過帶2和遮光帶3有規則地排列的情況。另一方面,通過設置第一透明樹脂層4及第二透明樹脂層5,從而透過光透過方 向控制片10進行觀察,能夠通過目視確認構成格柵層1的光透過帶2和遮光帶3有規則地排列的情況。由此,能夠容易地進行品質管理。 When the transparent resin layer is not provided and the surface of the grid layer 1 is exposed, since light scattering occurs on the exposed surface, it is difficult to visually confirm the light transmission band constituting the grid layer 1 through the grid layer 1. 2 and the case where the light shielding tape 3 is regularly arranged. On the other hand, by providing the first transparent resin layer 4 and the second transparent resin layer 5, the light transmitting direction control sheet 10 is observed, and it is possible to visually confirm that the light transmitting tape 2 and the light shielding tape 3 constituting the grating layer 1 have Regularly arranged. Thereby, quality management can be easily performed.
第一透明樹脂層4的外表面(面向外側的表面)4a及第二透明樹脂層5的外表面5a中之至少一者的外表面的算術平均粗糙度Ra係以0μm至3.0μm為佳,以0.0μm至0.5μm更佳,以0.0μm至0.2μm又更佳。 The arithmetic mean roughness Ra of the outer surface of at least one of the outer surface (outward facing surface) 4a of the first transparent resin layer 4 and the outer surface 5a of the second transparent resin layer 5 is preferably 0 μm to 3.0 μm. More preferably, it is from 0.0 μm to 0.5 μm, more preferably from 0.0 μm to 0.2 μm.
如果在上述範圍內,則該外表面具有與鏡面最後加工同等的平滑性,可進一步抑制該外表面的光的散射。由此,透過第一透明樹脂層4及第二透明樹脂層5,通過目視確認構成格柵層1的光透過帶2和遮光帶3有規則地排列的情況變得更容易。也就是說,可以更容易進行品質管理。進而,能夠提高光透過方向控制片10的光透過性等光學特性。 If it is within the above range, the outer surface has smoothness equivalent to the final processing of the mirror surface, and scattering of light on the outer surface can be further suppressed. Thus, it is easier to visually confirm that the light-transmitting belt 2 and the light-shielding belt 3 constituting the grid layer 1 are regularly arranged to pass through the first transparent resin layer 4 and the second transparent resin layer 5. In other words, quality management is easier. Further, optical characteristics such as light transmittance of the light transmission direction control sheet 10 can be improved.
另外,在本說明書中,“下限值至上限值”的數值範圍,只要沒有特別說明具有其他含義,就是指“下限值以上,上限值以下”的數值範圍。 In the present specification, the numerical range of the "lower limit value to the upper limit value" means a numerical value range of "the lower limit value or more and the upper limit value or less" unless otherwise specified.
從提高光透過方向控制片10的透明性的觀點,第一透明樹脂層4的外表面4a及第二透明樹脂層5的外表面5a兩者的外表面的算術平均粗糙度(Ra)以在上述適合的範圍內為佳。 From the viewpoint of improving the transparency of the light transmission direction control sheet 10, the arithmetic mean roughness (Ra) of the outer surfaces of both the outer surface 4a of the first transparent resin layer 4 and the outer surface 5a of the second transparent resin layer 5 is The above suitable range is preferred.
在本發明中,“算術平均粗糙度(Ra)”係根據JIS B 0601:2013(ISO4287:1997)“產品幾何技術規範”測定。 In the present invention, "arithmetic mean roughness (Ra)" is measured in accordance with JIS B 0601:2013 (ISO4287:1997) "Product Geometric Specifications".
構成格柵層1的光透過帶2的材料,只要滿足上述折射率的關係,則沒有特別限定,例如,適合透明性高的樹脂。具體而言,僅針對格柵層1的光透過帶2,使光透過格柵層1的厚度方向時的光透過率(光線透過率)為75%以上、以85%以上之具有高透明性的樹脂材料為佳。此外,光透過率的上限值沒有特別限定,例如可以是99.99%以下。作為上述樹脂材料,例如可使用透明性高的熱塑性樹脂或熱固性樹脂,具體例係可列舉:纖維素類樹脂、聚烯烴類樹脂、聚酯類樹脂、矽樹脂、聚苯乙烯樹脂、聚氯乙烯樹脂、丙烯酸樹脂、聚碳酸酯樹脂等。其中,以矽樹脂為佳,在耐熱性方面,以矽橡膠為特佳。矽橡膠可以是包含矽樹脂以外的成分的組成物。 The material of the light transmitting belt 2 constituting the grid layer 1 is not particularly limited as long as it satisfies the relationship of the above refractive index, and is suitable, for example, for a resin having high transparency. Specifically, the light transmittance (light transmittance) when the light is transmitted through the width direction of the grid layer 1 is 75% or more, and the transparency is 85% or more, only the light transmission band 2 of the grid layer 1 is high. The resin material is preferred. Further, the upper limit of the light transmittance is not particularly limited, and may be, for example, 99.99% or less. As the resin material, for example, a thermoplastic resin or a thermosetting resin having high transparency can be used, and specific examples thereof include a cellulose resin, a polyolefin resin, a polyester resin, an anthracene resin, a polystyrene resin, and a polyvinyl chloride. Resin, acrylic resin, polycarbonate resin, and the like. Among them, enamel resin is preferred, and ruthenium rubber is particularly preferred in terms of heat resistance. The ruthenium rubber may be a composition containing a component other than ruthenium resin.
作為矽橡膠,例如可以列舉:由分子鏈末端被羥基矽基或乙烯矽基封端的二有機聚矽氧烷和有機過氧化物所構成的,通常被稱為混煉橡膠的矽橡膠組成物;對分子中至少有2個與矽原子結合的乙烯基的二有機聚矽氧烷,混合分子中至少有3個與矽原子結合的氫原子(=SiH鍵)的有機氫聚矽氧烷和鉑系催化劑的、所謂加成反應型的有機矽橡膠組成物等。 Examples of the ruthenium rubber include a ruthenium rubber composition generally composed of a kneaded rubber, and a diorganopolysiloxane having an end of a molecular chain terminated with a hydroxy fluorenyl group or an ethylene sulfhydryl group, and an organic peroxide; a diorganopolyoxy siloxane having at least two vinyl groups bonded to a ruthenium atom in a molecule, an organic hydrogen polyoxy siloxane having at least three hydrogen atoms (=SiH bond) bonded to a ruthenium atom in a mixed molecule, and platinum A so-called addition reaction type organic ruthenium rubber composition which is a catalyst.
構成格柵層1的遮光帶3的材料沒有特別限定,例 如,作為光透過帶2的材料,適合的是,以上述列舉的樹脂為基材,對其添加顏料或染料等著色劑而成的著色樹脂。構成光透過帶2的樹脂材料和作為遮光帶3的基材的樹脂材料可以相同,也可以不同,但從易使光透過帶2和遮光帶3的黏接性良好的觀點,以兩者的樹脂材料相同者為佳。 The material of the light-shielding tape 3 constituting the grid layer 1 is not particularly limited. For example, as the material of the light-transmitting tape 2, it is preferable to add a coloring agent such as a pigment or a dye to the above-mentioned resin as a base material. Colored resin. The resin material constituting the light transmitting belt 2 and the resin material as the base material of the light shielding tape 3 may be the same or different, but from the viewpoint of easy adhesion of the light transmitting tape 2 and the light shielding tape 3, The same resin material is preferred.
遮光帶3的色調,只要能夠得到足夠的遮光性即可,例如可列舉:黑、紅、黃、綠、藍色、淺藍色等。遮光帶3的色調及遮光性可以通過著色劑的種類及添加量來調整。具體而言,僅針對格柵層1的遮光帶3,更佳者係具有在格柵層1的厚度方向照射光時的光透過率為20%以下、以5%以下為佳的遮光性。光透過率可以是0%。此外,由於遮光帶的色調為觀察格柵層1時被識別的色調,因此,以考量裝飾性而進行設計者為佳。 The color tone of the light-shielding tape 3 is sufficient as long as it can obtain sufficient light-shielding property, and examples thereof include black, red, yellow, green, blue, and light blue. The color tone and light blocking property of the light-shielding tape 3 can be adjusted by the kind and addition amount of a coloring agent. Specifically, it is preferable that the light-shielding tape 3 of the grid layer 1 has a light transmittance of 20% or less and preferably 5% or less when the light is irradiated in the thickness direction of the grid layer 1. The light transmittance can be 0%. Further, since the color tone of the light-shielding tape is the color tone recognized when the grid layer 1 is observed, it is preferable to carry out the design in consideration of the decorative property.
作為著色劑的具體例,可以列舉:碳黑、氧化鐵、氧化鈦、黃氧化鐵、雙偶氮黃、酞青藍等一般的有機顏料或無機顏料。著色劑可以使用一種,也可以使用兩種以上。此外,在不使用黑色顏料的情況下,為了得到良好的遮光性,以併用白色顏料者為佳。 Specific examples of the colorant include general organic pigments or inorganic pigments such as carbon black, iron oxide, titanium oxide, yellow iron oxide, disazo yellow, and indigo blue. The coloring agent may be used singly or in combination of two or more. Further, in the case where a black pigment is not used, in order to obtain good light-shielding properties, it is preferred to use a white pigment in combination.
光透過帶2和遮光帶3的寬度(第1圖的橫向的厚度)能夠自由設定。格柵層1的光透過率可以通過光透過帶2的寬度/遮光帶3的寬度的比率來調整。視角(可視角度) 的範圍可以通過光透過率2的寬度及格柵層1的厚度來調整。 The width of the light transmission band 2 and the light shielding tape 3 (the thickness in the lateral direction of Fig. 1) can be freely set. The light transmittance of the grid layer 1 can be adjusted by the ratio of the width of the light transmission belt 2 / the width of the light shielding tape 3. The range of the viewing angle (visual angle) can be adjusted by the width of the light transmittance 2 and the thickness of the grid layer 1.
如果考慮使防窺視和顯示畫面的良好辨認性並存,則光透過帶2的寬度係以50至200μm為佳,以100至150μm更佳。此外,遮光帶3的寬度以1至50μm為佳,以10至30μm更佳。將各寬度調整至上述範圍時,則可得到例如光透過率80%以上、視角30至120°的光透過方向控制片10。 If it is considered that the peep prevention and the good visibility of the display screen coexist, the width of the light transmission band 2 is preferably 50 to 200 μm, more preferably 100 to 150 μm. Further, the width of the light-shielding tape 3 is preferably from 1 to 50 μm, more preferably from 10 to 30 μm. When the respective widths are adjusted to the above range, for example, the light transmission direction control sheet 10 having a light transmittance of 80% or more and a viewing angle of 30 to 120° can be obtained.
以遮光帶3的寬度/光透過帶2的寬度表示的比率,係以0.005至1為佳,以0.06至0.3更佳。 The ratio expressed by the width of the light-shielding tape 3 / the width of the light-transmitting tape 2 is preferably 0.005 to 1, more preferably 0.06 to 0.3.
第一透明樹脂層4及第二透明樹脂層5的材料,只要滿足上述折射率的關係,就沒有特別限定,例如,上述樹脂適合作為光透過帶2的材料。以各透明樹脂層的厚度方向的光透過率在75%以上的材料為佳,以光透過率在85%以上的材料更佳。上述光透過率的上限沒有特別限定,例如可以設為99.99%以下。 The material of the first transparent resin layer 4 and the second transparent resin layer 5 is not particularly limited as long as it satisfies the relationship of the above refractive index. For example, the above resin is suitable as the material of the light transmission belt 2. A material having a light transmittance of 75% or more in the thickness direction of each transparent resin layer is preferable, and a material having a light transmittance of 85% or more is more preferable. The upper limit of the light transmittance is not particularly limited, and may be, for example, 99.99% or less.
作為上述透明樹脂層的材料,具體而言,例如可以列舉:纖維素類樹脂、聚烯烴類樹脂(特別是環烯烴聚合物)、聚酯類樹脂、矽樹脂、聚苯乙烯樹脂、聚氯乙烯樹脂、丙烯酸樹脂、聚碳酸酯樹脂等。作為適合的矽橡膠,可舉出在上述光透過帶的例示。 Specific examples of the material of the transparent resin layer include a cellulose resin, a polyolefin resin (particularly a cycloolefin polymer), a polyester resin, an anthracene resin, a polystyrene resin, and a polyvinyl chloride. Resin, acrylic resin, polycarbonate resin, and the like. As a suitable enamel rubber, the above-mentioned light transmission belt is exemplified.
在上述之中,以比聚碳酸酯或PET(折射率=1.59至 1.60)等熱塑性樹脂更接近空氣的折射率(1.0003),且通過界面反射的光透過率的損失少的矽樹脂(折射率=1.43)為佳,在耐熱性方面,以矽橡膠(折射率=1.40至1.43)更佳。透明樹脂層4、5為矽橡膠時,則透明樹脂層的外表面4a、5a的緊貼性會顯著提高(能夠帶來膠黏感),因此,能夠使透明樹脂層緊貼在顯示畫面的表面,從而能夠容易地設置光透過方向控制片10。 Among the above, a resin having a refractive index (1.0003) closer to that of a thermoplastic resin such as polycarbonate or PET (refractive index = 1.59 to 1.60) and having a small loss of light transmittance reflected by an interface (refractive index) It is preferable that the heat resistance is 矽 rubber (refractive index = 1.40 to 1.43). When the transparent resin layers 4 and 5 are ruthenium rubber, the adhesion between the outer surfaces 4a and 5a of the transparent resin layer is remarkably improved (adhesiveness can be brought about), so that the transparent resin layer can be closely attached to the display screen. The surface is thus able to easily set the light transmission direction control sheet 10.
構成各透明樹脂層的樹脂,根據需要,出於提高耐候性、改進設計性等目的,可以含有紫外線吸收劑、紅外線吸收劑、著色劑等樹脂薄膜領域中的公知的添加劑。 The resin constituting each of the transparent resin layers may contain a known additive in the field of a resin film such as an ultraviolet absorber, an infrared ray absorbing agent, or a coloring agent, for the purpose of improving weather resistance and designing properties, as needed.
第一透明樹脂層4的材料和第二透明樹脂層5的材料可以相同,也可以不同,但從容易滿足上述折射率的關係的觀點,以材料相同者為佳。此外,從相同的觀點,以第一透明樹脂層4及第二透明樹脂層5的材料、和格柵層1的光透過帶2的材料相同者更佳。 The material of the first transparent resin layer 4 and the material of the second transparent resin layer 5 may be the same or different, but from the viewpoint of easily satisfying the relationship of the above refractive index, it is preferable that the materials are the same. Further, from the same viewpoint, the materials of the first transparent resin layer 4 and the second transparent resin layer 5 are preferably the same as those of the light transmitting tape 2 of the grid layer 1.
優選格柵層1的厚度以100μm至5000μm為佳,以150μm至1000μm更佳,以150μm至500μm又更佳。格柵層1的厚度在上述範圍時,則視角(可視角度)的控制變得容易。 Preferably, the thickness of the grid layer 1 is preferably from 100 μm to 5000 μm, more preferably from 150 μm to 1000 μm, still more preferably from 150 μm to 500 μm. When the thickness of the grid layer 1 is in the above range, the control of the viewing angle (visual angle) becomes easy.
第一透明樹脂層4及第二透明樹脂層5的厚度各自獨立,以1μm至100μm為佳,以5μm至50μm更佳,以10μm至20μm又更佳。第一透明樹脂層4及第二透 明樹脂層5的厚度分別在上述範圍內,則能夠取得光透過方向控制片10的剛度和薄型化的平衡。 The thicknesses of the first transparent resin layer 4 and the second transparent resin layer 5 are each independent, preferably 1 μm to 100 μm, more preferably 5 μm to 50 μm, still more preferably 10 μm to 20 μm. When the thicknesses of the first transparent resin layer 4 and the second transparent resin layer 5 are within the above ranges, the balance between the rigidity and the thickness of the light transmission direction control sheet 10 can be obtained.
格柵層1、第一透明樹脂層4及第二透明樹脂層5的合計厚度以100μm至5200μm為佳,以150μm至1200μm更佳,以200μm至700μm又更佳。 The total thickness of the grid layer 1, the first transparent resin layer 4, and the second transparent resin layer 5 is preferably 100 μm to 5200 μm, more preferably 150 μm to 1200 μm, still more preferably 200 μm to 700 μm.
各層的合計厚度在上述範圍的下限值以上時,則光透過方向控制片10的剛度增加,設置在資訊顯示裝置的顯示畫面的附近時的操作性提高,並且視角(可視角度)的控制變得容易。 When the total thickness of each layer is equal to or greater than the lower limit of the above range, the rigidity of the light transmission direction control sheet 10 is increased, the operability at the time of setting in the vicinity of the display screen of the information display device is improved, and the control of the viewing angle (visual angle) is changed. It's easy.
各層的合計厚度在上述範圍的上限值以下時,則光透過方向控制片10的薄型化可充分實現,裝入資訊顯示裝置的內部變得容易。 When the total thickness of each layer is equal to or less than the upper limit of the above range, the thinning of the light transmission direction control sheet 10 can be sufficiently achieved, and it becomes easy to fit inside the information display device.
另外,在本說明書中,“厚度”是使用顯微鏡觀察測量對象的截面,測定5處的厚度並對其進行平均的值。 In addition, in the present specification, the "thickness" is a value obtained by observing a cross section of a measurement object using a microscope, measuring the thickness at five places, and averaging them.
可以在第一透明樹脂層4的外表面4a及第二透明樹脂層5的外表面5a的至少一者設置任意的透明層、透明薄膜等透明構件,例如,公知的膠黏層、黏接層、透明薄膜、保護片等。 Any transparent member such as a transparent layer or a transparent film may be provided on at least one of the outer surface 4a of the first transparent resin layer 4 and the outer surface 5a of the second transparent resin layer 5, for example, a known adhesive layer or adhesive layer. , transparent film, protective sheet, etc.
作為上述膠黏層的材料,例如可列舉:彈性體類膠黏劑、丙烯酸類膠黏劑、聚胺酯類膠黏劑、橡膠類膠黏劑等。作為上述彈性體類膠黏劑,例如可列舉包含矽橡膠、矽凝膠、聚胺酯橡膠、聚胺酯凝膠等的膠黏劑。在 使用彈性體類膠黏劑時,為提高其透明性,以在膠黏層的表面進行公知的鏡面加工者為佳。 Examples of the material of the adhesive layer include an elastomer-based adhesive, an acrylic adhesive, a polyurethane adhesive, and a rubber adhesive. Examples of the elastomer-based adhesive include an adhesive such as ruthenium rubber, ruthenium gel, polyurethane rubber, or polyurethane gel. When an elastomer-based adhesive is used, in order to improve the transparency, it is preferred to perform a known mirror finish on the surface of the adhesive layer.
從使光透過方向控制片10的光學特性變得優異的觀點,上述任意透明層、透明薄膜等透明構件的折射率、和光透過帶2、第一透明樹脂層4、第二透明樹脂層5的各構成材料的折射率之差以小於0.1為佳,以小於0.02更佳,實質上為零又更佳。 From the viewpoint of excellent optical characteristics of the light transmission direction control sheet 10, the refractive index of the transparent member such as any of the transparent layer and the transparent film, and the light transmitting tape 2, the first transparent resin layer 4, and the second transparent resin layer 5 are The difference in refractive index of each constituent material is preferably less than 0.1, more preferably less than 0.02, and substantially zero and more preferably.
另外,從使光透過方向控制片10的光學特性變得優異,使薄片構造變得簡單的觀點,以在第一透明樹脂層4及第二透明樹脂層5的外表面未設置其它透明構件者為佳。 In addition, from the viewpoint of making the optical characteristics of the light transmission direction control sheet 10 excellent and simplifying the sheet structure, the other transparent members are not provided on the outer surfaces of the first transparent resin layer 4 and the second transparent resin layer 5. It is better.
構成光透過方向控制片10的格柵層1例如可以通過下述方法製造。首先,交替層疊由光透過帶2的構成材料構成的多張所需厚度的第一薄片、和由遮光帶3的構成材料構成的多張所需厚度的第二薄片,對其進行加熱加壓,從而形成由這些多張薄片一體而成的塊體。 The grid layer 1 constituting the light transmission direction control sheet 10 can be manufactured, for example, by the following method. First, a plurality of first sheets of a desired thickness composed of a constituent material of the light-transmitting belt 2, and a plurality of second sheets of a desired thickness composed of constituent materials of the light-shielding belt 3 are alternately laminated and heated and pressurized. Thereby, a block body in which the plurality of sheets are integrally formed is formed.
接下來,通過在垂直於薄片表面的截斷面上對塊體進行切片而得到格柵層1。切片時的厚度(切片寬度)相當於格柵層1的厚度。通過在相對於薄片表面傾斜的面上對塊體進行切片,從而能夠調整格柵層1的表面和遮光帶3所構成的角度。 Next, the grid layer 1 is obtained by slicing the block on a section perpendicular to the surface of the sheet. The thickness (slice width) at the time of slicing corresponds to the thickness of the grid layer 1. By slicing the block on the surface inclined with respect to the surface of the sheet, the angle formed by the surface of the grid layer 1 and the light shielding tape 3 can be adjusted.
層疊格柵層1和各透明樹脂層4、5,使其成 為一體的方法沒有特別限定,可以適當使用公知的方法。 The method of laminating the grid layer 1 and the respective transparent resin layers 4 and 5 so as to be integrated is not particularly limited, and a known method can be suitably used.
作為一個例子,可以舉出:通過在格柵層1的第一面塗布形成第一透明樹脂層4的材料,並對其進行固化,從而形成第一透明樹脂層4的方法。利用同樣的方法,可以在格柵層1的第二面形成第二透明樹脂層5。 As an example, a method of forming the first transparent resin layer 4 by coating a material forming the first transparent resin layer 4 on the first surface of the grid layer 1 and curing it is exemplified. The second transparent resin layer 5 can be formed on the second surface of the grid layer 1 by the same method.
通過層疊格柵層1和各透明樹脂層4、5,使一體化的層疊體形成為所需的形狀,從而能夠得到光透過方向控制片10。光透過方向控制片10的平面形狀沒有特別限定,適當採用矩形、多邊形、圓形、橢圓形等形狀而與所設置的顯示畫面的形狀匹配即可。 By laminating the grid layer 1 and the respective transparent resin layers 4 and 5, the integrated laminate is formed into a desired shape, whereby the light transmission direction control sheet 10 can be obtained. The planar shape of the light transmission direction control sheet 10 is not particularly limited, and a shape such as a rectangle, a polygon, a circle, or an ellipse may be appropriately used to match the shape of the displayed display screen.
在上述中,對本發明的光透過方向控制片具有一層格柵層的情況進行說明。本發明的光透過方向控制片也可以具備兩層格柵層。以下,參照第2圖,對層疊有兩層格柵層的光透過方向控制片20的結構進行說明。 In the above, the case where the light transmission direction control sheet of the present invention has one grid layer will be described. The light transmission direction control sheet of the present invention may have two layers of grid layers. Hereinafter, a configuration of the light transmission direction control sheet 20 in which two layers of the grid layers are laminated will be described with reference to Fig. 2 .
第2圖是放大光透過方向控制片20的一部分並示意性地示出的立體圖。在第2圖中,將光透過方向控制片20的厚度方向設為Z方向,向該薄片20中入射的光的光源側為Z1側,透過該薄片20的光射出的照射側(辨認側)為Z2側。另外,分別將與Z方向垂直的面內的互相垂直的兩個方向設為X方向、Y方向。 Fig. 2 is a perspective view schematically showing a part of the light transmission direction control sheet 20 and schematically shown. In the second drawing, the thickness direction of the light transmission direction control sheet 20 is set to the Z direction, and the light source side of the light incident on the sheet 20 is the Z1 side, and the irradiation side (recognition side) through which the light of the sheet 20 is emitted is emitted. For the Z2 side. Further, two directions perpendicular to each other in the plane perpendicular to the Z direction are referred to as an X direction and a Y direction, respectively.
光透過方向控制片20在厚度方向上,從Z1側按照順序層疊第一透明樹脂層21、第一格柵層22、第三透明樹脂層23、第二格柵層24及第二透明樹脂層25,從而形成彼此一體化。 The light transmission direction control sheet 20 laminates the first transparent resin layer 21, the first grid layer 22, the third transparent resin layer 23, the second grid layer 24, and the second transparent resin layer in this order from the Z1 side in the thickness direction. 25, thereby forming an integration with each other.
第一透明樹脂層21設置在第一格柵層22的Z1側的表面(第一面),第二透明樹脂層25設置在第二格柵層24的Z2側的表面(第二面),第三透明樹脂層23設置在第一格柵層22的Z2側的表面(第二面),亦即第二格柵層24的Z1側的表面(第一面)上。 The first transparent resin layer 21 is disposed on the surface (first surface) on the Z1 side of the first grid layer 22, and the second transparent resin layer 25 is disposed on the surface (second surface) on the Z2 side of the second grid layer 24, The third transparent resin layer 23 is provided on the surface (second surface) on the Z2 side of the first grid layer 22, that is, on the surface (first surface) on the Z1 side of the second grid layer 24.
X-Y平面(與Z方向垂直的面)內的光透過方向控制片的整體平面形狀例如為矩形,但可以根據所設置處的形狀適當變更。 The overall planar shape of the light transmission direction control piece in the X-Y plane (the surface perpendicular to the Z direction) is, for example, a rectangle, but may be appropriately changed depending on the shape of the installation.
在光透過方向控制片20中,光透過帶26的折射率和第一透明樹脂層22的折射率之差、光透過帶26的折射率和第三透明樹脂層23的折射率之差、第三透明樹脂層23和光透過帶28的折射率之差以及光透過帶28的折射率和第二透明樹脂層25的折射率之差分別小於0.1。在此,各折射率之差是絕對值。 In the light transmission direction control sheet 20, the difference between the refractive index of the light transmission band 26 and the refractive index of the first transparent resin layer 22, the difference between the refractive index of the light transmission band 26 and the refractive index of the third transparent resin layer 23, The difference in refractive index between the three transparent resin layers 23 and the light transmitting belt 28 and the difference between the refractive index of the light transmitting belt 28 and the refractive index of the second transparent resin layer 25 are each less than 0.1. Here, the difference in refractive index is an absolute value.
在第一格柵層22中,光透過帶26和遮光帶27在Y方向上反復交替。光透過帶26和遮光帶27均為沿X方向延伸的帶狀,在其Y方向上的寬度分別是均勻且恒定的。多個光透過帶26彼此寬度相同,多個遮光帶27彼此寬度相同。 In the first grid layer 22, the light transmitting belt 26 and the light shielding belt 27 are alternately alternated in the Y direction. The light transmission belt 26 and the light shielding belt 27 are both strip-shaped in the X direction, and the widths in the Y direction are uniform and constant, respectively. The plurality of light transmission bands 26 have the same width and the plurality of light shielding bands 27 have the same width.
在第二格柵層24中,光透過帶28和遮光帶29在X方向上反復交替。光透過帶28和遮光帶29均為沿Y方向延伸的帶狀,在其X方向上的寬度分別是均勻且恒定的。多個光透過帶28彼此寬度相同,多個遮光帶29彼此寬度相同。 In the second grid layer 24, the light transmitting belt 28 and the light shielding belt 29 are alternately alternated in the X direction. The light transmission band 28 and the light shielding tape 29 are both strip-like shapes extending in the Y direction, and the widths in the X direction are uniform and constant, respectively. The plurality of light transmission bands 28 have the same width and the plurality of light shielding bands 29 have the same width.
在第2圖所示的光透過方向控制片20中,由兩個層所層疊的各格柵層22、24的遮光帶的夾角設置成以平面圖觀察時彼此約呈90°。在此,上述夾角可以是90°以外的角度,也可以是從0至90°選擇的任意角度。第一格柵層22和第二格柵層24的厚度及各格柵層的光透過帶及遮光帶的厚度獨立地設定,可以彼此相同,也可以不同。 In the light transmission direction control sheet 20 shown in Fig. 2, the angles of the light shielding bands of the respective grid layers 22 and 24 laminated by the two layers are set to be approximately 90° with each other when viewed in a plan view. Here, the above-mentioned included angle may be an angle other than 90°, or may be any angle selected from 0 to 90°. The thickness of the first grid layer 22 and the second grid layer 24 and the thickness of the light transmission band and the light shielding tape of each grid layer are independently set and may be the same as or different from each other.
第2圖的光透過方向控制片20是將第1圖的兩個光透過方向控制片10重疊成兩層,在上側和下側的各個光透過方向控制片10上共有第三透明樹脂層23的構成。由於各格柵層22、24和各透明樹脂層21、23、25的折射率之差係如上所述,因此各格柵層和各透明樹脂層的界面中的界面反射下降,光透過率提高。其結果,光透過方向控制片20具有優異的光透過性。進而,在光透過方向控制片20中,第一格柵層22控制沿Y方向的視角,第二格柵層24控制沿X方向的視角,因此,通過一張光透過方向控制片20而能夠同時控制兩個方向的視角。 In the light transmission direction control sheet 20 of Fig. 2, the two light transmission direction control sheets 10 of Fig. 1 are stacked in two layers, and the third transparent resin layer 23 is shared by the light transmission direction control sheets 10 on the upper side and the lower side. Composition. Since the difference in refractive index between each of the grid layers 22 and 24 and each of the transparent resin layers 21, 23, and 25 is as described above, the interface reflection at the interface between each of the grid layers and the respective transparent resin layers is lowered, and the light transmittance is improved. . As a result, the light transmission direction control sheet 20 has excellent light transmittance. Further, in the light transmission direction control sheet 20, the first grid layer 22 controls the angle of view in the Y direction, and the second grid layer 24 controls the angle of view in the X direction, and therefore, it is possible to control the sheet 20 by a light transmission direction. Simultaneously control the viewing angle in both directions.
光透過方向控制片20的製造方法,只要是層疊各格柵層22、24及各透明樹脂層21、23、25,並使其一體化的方法,就沒有特別限定。例如,通過在第一格柵層22的第一面塗布形成第一透明樹脂層21的材料,並對其進行固化,從而形成第一透明樹脂層21。此後,在第一格柵層22的第二面塗布形成第三透明樹脂層23的固化性材料,在完全固化前的塗膜上載置第二格柵層24,使上述塗膜固化。由此,能夠形成第三透明樹脂層23,並且 借助第三透明樹脂層23黏接第一格柵層22和第二格柵層24。接下來,與第一透明樹脂層21的形成同樣地,在第二格柵層24的第二面形成第二透明樹脂層25,從而能夠得到光透過方向控制片20。 The method for producing the light transmission direction control sheet 20 is not particularly limited as long as the grid layers 22 and 24 and the transparent resin layers 21, 23 and 25 are laminated and integrated. For example, the first transparent resin layer 21 is formed by coating a material forming the first transparent resin layer 21 on the first surface of the first grid layer 22 and curing it. Thereafter, a curable material forming the third transparent resin layer 23 is applied to the second surface of the first grid layer 22, and the second grid layer 24 is placed on the coating film before the complete curing to cure the coating film. Thereby, the third transparent resin layer 23 can be formed, and the first grid layer 22 and the second grid layer 24 are bonded by the third transparent resin layer 23. Next, similarly to the formation of the first transparent resin layer 21, the second transparent resin layer 25 is formed on the second surface of the second grid layer 24, whereby the light transmission direction control sheet 20 can be obtained.
在資訊顯示裝置的顯示畫面的附近,通過以覆蓋該顯示畫面的方式設置光透過方向控制片10,從而能夠防止所謂的窺視。作為設置方法,例如可以列舉:使成形為矩形的光透過方向控制片10的第一透明樹脂層4的外表面4a或第二透明樹脂層5的外表面5a緊貼在構成資訊顯示裝置的顯示畫面的透明基板的設置方法。光透過方向控制片10可以設置在裝置的外表面以露出於外部的狀態設置,也可以設置在裝置的內部以難以從外部識別的狀態設置。在光透過方向控制片10裝入資訊顯示裝置的內部的情況下,例如較佳者係第一透明樹脂層4的外表面4a緊貼並固定在構成裝置內部的顯示畫面的透明基板上,第二透明樹脂層5的外表面5a緊貼並固定在構成裝置的外表面(箱體的一部分)的透明基板上。也就是說,較佳者係在資訊顯示裝置所具有的彼此分離並對置的兩個透明基板之間,以緊貼並被夾著的狀態設置光透過方向控制片10。當這樣設置時,由於空氣層未介入資訊顯示裝置的兩個透明基板和光透過方向控制片10的透明樹脂層4、5之間,因此,能夠抑制光透過率的下降。 By providing the light transmission direction control sheet 10 so as to cover the display screen in the vicinity of the display screen of the information display device, it is possible to prevent so-called peek. As an installation method, for example, the outer surface 4a of the first transparent resin layer 4 or the outer surface 5a of the second transparent resin layer 5 of the light transmission direction control sheet 10 formed into a rectangular shape is closely attached to the display constituting the information display device. The method of setting the transparent substrate of the screen. The light transmission direction control sheet 10 may be provided on the outer surface of the device to be exposed to the outside, or may be provided inside the device to be difficult to recognize from the outside. In the case where the light transmission direction control sheet 10 is incorporated in the inside of the information display device, for example, it is preferable that the outer surface 4a of the first transparent resin layer 4 is in close contact with and fixed to the transparent substrate constituting the display screen inside the device, The outer surface 5a of the second transparent resin layer 5 is in close contact with and fixed to the transparent substrate constituting the outer surface of the device (a part of the case). In other words, it is preferable to provide the light transmission direction control sheet 10 in a state of being closely attached to and sandwiched between the two transparent substrates which are separated from each other and which are provided by the information display device. When it is installed in this way, since the air layer is not interposed between the two transparent substrates of the information display device and the transparent resin layers 4 and 5 of the light transmission direction control sheet 10, the decrease in the light transmittance can be suppressed.
設置的光透過方向控制片10的光透過帶2(以及遮光帶3)的延伸方向和顯示畫面框架的邊可以平行,也可以不平行。為防止疊紋的發生,也可以使光透過帶2的延伸方向相對於顯示畫面框架傾斜(可增加偏斜角)。 The extending direction of the light transmission band 2 (and the light shielding tape 3) of the light transmission direction control sheet 10 and the side of the display screen frame may or may not be parallel. In order to prevent the occurrence of moiré, the direction in which the light transmission band 2 is extended may be inclined with respect to the display frame (the skew angle may be increased).
以上,作為使用本發明的光透過方向控制片的方法,對光透過方向控制片10的情況進行說明,光透過方向控制片20的情況也可以和上述同樣地使用。 As described above, the light transmission direction control sheet 10 will be described as a method of using the light transmission direction control sheet of the present invention, and the light transmission direction control sheet 20 may be used in the same manner as described above.
以下列舉實施例,但本發明並不由這些實施例所限定。 The examples are enumerated below, but the invention is not limited by the examples.
製造第1圖所示的光透過方向控制片10。 The light transmission direction control sheet 10 shown in Fig. 1 was produced.
首先,準備由折射率約為1.43的透明矽橡膠(信越化學工業股份有限公司製造、商品名:KE-153-U)構成的厚度為125μm的第一薄片作為光透過帶2的材料。 First, a first sheet having a thickness of 125 μm composed of a transparent tantalum rubber (manufactured by Shin-Etsu Chemical Co., Ltd., trade name: KE-153-U) having a refractive index of about 1.43 was prepared as a material of the light-transmitting belt 2.
此外,準備由對100質量份透明矽橡膠(信越化學工業股份有限公司製造、商品名:KE-153-U)添加有15質量份碳黑的材料所構成的厚度為10μm的第二薄片作為遮光帶3的材料。 In addition, a second sheet having a thickness of 10 μm composed of a material in which 15 parts by mass of carbon black is added to 100 parts by mass of a transparent enamel rubber (manufactured by Shin-Etsu Chemical Co., Ltd., trade name: KE-153-U) is prepared as a shading With 3 materials.
交替層疊多張第一薄片和多張第二薄片,並對其進行加熱、硫化以及加壓,從而形成了使這些多張薄片一體而成的塊體。 A plurality of first sheets and a plurality of second sheets are alternately laminated, and are heated, vulcanized, and pressurized to form a block in which the plurality of sheets are integrally formed.
通過在與薄片表面垂直的截斷面將塊體切成 厚度310μm的薄片,從而製得格柵層1。 The grid layer 1 was obtained by cutting a block into a sheet having a thickness of 310 μm in a cross section perpendicular to the surface of the sheet.
由於格柵層1的表面被切片加工而粗糙,因而在表面會產生光的亂反射,看上去模糊不清。因此,難以透過單獨的格柵層1觀察,由此無法通過目視確認光透過帶2及遮光帶3是否有規則地排列。 Since the surface of the grid layer 1 is roughened by slicing, a disordered reflection of light is generated on the surface, which is blurred. Therefore, it is difficult to observe through the individual grid layers 1, and it is not possible to visually confirm whether or not the light-transmitting belt 2 and the light-shielding belt 3 are regularly arranged.
接下來,使用絲網印刷機在被實施過鏡面加工的PET薄膜的表面以約20μm的厚度塗布折射率約1.43的液狀矽橡膠(信越化學工業股份有限公司製造、商品名:KE-1987),將該塗布面載置在格柵層1的第一面,並對其進行加熱硫化黏接。此後,通過剝離PET薄膜,從而形成了由矽橡膠構成的第一透明樹脂層4。通過同樣的方法,在格柵層1的第二面形成由矽橡膠構成的第二透明樹脂層5,從而得到了光透過方向控制片10。 Next, a liquid ruthenium rubber having a refractive index of about 1.43 was applied to the surface of the PET film subjected to the mirror processing using a screen printing machine at a thickness of about 20 μm (manufactured by Shin-Etsu Chemical Co., Ltd., trade name: KE-1987). The coated surface is placed on the first surface of the grid layer 1 and is vulcanized by heat vulcanization. Thereafter, the first transparent resin layer 4 composed of ruthenium rubber was formed by peeling off the PET film. By the same method, the second transparent resin layer 5 made of ruthenium rubber is formed on the second surface of the grid layer 1, whereby the light transmission direction control sheet 10 is obtained.
透過剝離PET薄膜前的光透過方向控制片10而以目視進行觀察,構成格柵層1的光透過帶2及遮光帶3有規則地排列著,可以容易地確認這是沒有缺陷的佳品。 The light transmitting direction control sheet 10 before peeling off the PET film is visually observed, and the light transmitting tape 2 and the light shielding tape 3 constituting the grating layer 1 are regularly arranged, and it can be easily confirmed that this is a good product without defects.
此外,當存在缺陷時,能夠通過目視容易地確認不規則地分佈著黑點或白點。 Further, when there is a defect, it is possible to easily confirm irregular distribution of black spots or white spots by visual observation.
使用表面粗糙度測量儀(小阪研究所股份有限公司製造、商品名:SE600)測量了剝離上述PET薄膜而得到的光透過方向控制片10的各透明樹脂層4、5的外表面的算術平均值(Ra),兩個表面之Ra均為0.1μm,都是和實施過鏡面加工的PET薄膜的表面同樣的平滑的鏡面。 The arithmetic mean value of the outer surfaces of the respective transparent resin layers 4 and 5 of the light transmission direction control sheet 10 obtained by peeling off the PET film was measured using a surface roughness measuring instrument (manufactured by Kosaka Research Institute Co., Ltd., trade name: SE600). (Ra), the Ra of both surfaces was 0.1 μm, and both were the same smooth mirror surface as the surface of the mirror-finished PET film.
使用霧度儀(日本電飾工業股份有限公司製造、商品名:NDH2000)測量了光透過方向控制片10的光透過性,全光線透過率為80%,霧度為3。在此,霧度是通過公式“霧度(%)=Td/Tt×100”求出的。式中,Td表示擴散透過率,Tt表示全光線透過率。 The light transmittance of the light transmission direction control sheet 10 was measured using a haze meter (manufactured by Nippon Denshi Kogyo Co., Ltd., trade name: NDH2000), and the total light transmittance was 80%, and the haze was 3. Here, the haze is obtained by the formula "haze (%) = Td / Tt × 100". In the formula, Td represents the diffuse transmittance, and Tt represents the total light transmittance.
光透過方向控制片10的視角在相對於延伸設置有格柵層1的光透過帶2及遮光帶3的長度方向垂直的平面上,約為65°。 The angle of view of the light transmission direction control sheet 10 is about 65° on a plane perpendicular to the longitudinal direction of the light transmission belt 2 and the light shielding belt 3 on which the grid layer 1 is extended.
除了使用粗面加工的PET薄膜以外,與實施例1同樣地,製作了光透過方向控制片10’。 A light transmission direction control sheet 10' was produced in the same manner as in Example 1 except that the rough-faced PET film was used.
透過剝離PET薄膜前的光透過方向控制片10’而以目視進行觀察,構成格柵層1的光透過帶2及遮光帶3有規則地排列著,可以容易地確認這是沒有缺陷的佳品。 The light transmitting direction control sheet 10' before peeling off the PET film is visually observed, and the light transmitting tape 2 and the light shielding tape 3 constituting the grating layer 1 are regularly arranged, and it can be easily confirmed that this is a good product without defects.
此外,當存在缺陷時,能夠通過目視容易地確認不規則地分佈著黑點或白點。 Further, when there is a defect, it is possible to easily confirm irregular distribution of black spots or white spots by visual observation.
與實施例1同樣地,對剝離上述PET薄膜而得到的實施例2的光透過方向控制片10’的各透明樹脂層4、5的外表面的算術平均粗糙度(Ra)、光透過性、霧度、視角進行測量,Ra=2.6μm,全光線透過率=73%,霧度=41、視角=約為65°。與實施例1相比,霧度值變高,全光線透過率下降。 In the same manner as in the first embodiment, the arithmetic mean roughness (Ra) and light transmittance of the outer surfaces of the transparent resin layers 4 and 5 of the light transmission direction control sheet 10' of the second embodiment obtained by peeling off the PET film were The haze and the viewing angle were measured, Ra = 2.6 μm, total light transmittance = 73%, haze = 41, and viewing angle = about 65 °. Compared with Example 1, the haze value was high and the total light transmittance was lowered.
除了使用未實施鏡面加工的PET薄膜以外,與實施例1同樣地製作了光透過方向控制片10”。 A light transmission direction control sheet 10" was produced in the same manner as in Example 1 except that a PET film which was not subjected to mirror processing was used.
透過剝離PET薄膜前的光透過方向控制片10”而以目視進行觀察,構成格柵層1的光透過帶2及遮光帶3有規則地排列著,可以容易地確認這是沒有缺陷的佳品。 By visually observing the light transmission direction control sheet 10" before peeling off the PET film, the light transmission tape 2 and the light shielding tape 3 constituting the grid layer 1 are regularly arranged, and it can be easily confirmed that this is a good product without defects.
此外,當存在缺陷時,能夠通過目視容易地確認不規則地分佈著黑點或白點。 Further, when there is a defect, it is possible to easily confirm irregular distribution of black spots or white spots by visual observation.
與實施例1同樣地,對剝離上述PET薄膜而得到的實施例3的光透過方向控制片10”的各透明樹脂層4、5的外表面的算術平均粗糙度(Ra)、光透過性、霧度、視角進行測量,Ra=0.2μm,全光線透過率=78%,霧度=6、視角=約65°。 In the same manner as in the first embodiment, the arithmetic mean roughness (Ra) and light transmittance of the outer surfaces of the transparent resin layers 4 and 5 of the light transmission direction control sheet 10" of the third embodiment obtained by peeling off the PET film were The haze and the viewing angle were measured, Ra = 0.2 μm, total light transmittance = 78%, haze = 6, and viewing angle = about 65 °.
在通過實施例1製作的格柵層1的雙面分別塗布厚度10μm的環氧類黏接劑(折射率:約1.55),通過各個面的黏接劑層,分別黏接對外表面實施過鏡面加工的厚度30μm的聚碳酸酯薄膜(折射率:約1.58)。 An epoxy-based adhesive having a thickness of 10 μm (refractive index: about 1.55) was applied to both sides of the grid layer 1 produced in Example 1, and the outer surface was respectively mirror-coated by the adhesive layer of each surface. A processed polycarbonate film having a thickness of 30 μm (refractive index: about 1.58).
通過以上步驟,得到比較例的光透過方向控制片,其在格柵層1的雙面的每個面均具備黏接劑層及聚碳酸酯薄膜。 Through the above steps, a light transmission direction control sheet of a comparative example was obtained, which was provided with an adhesive layer and a polycarbonate film on each of both sides of the grid layer 1.
透過在雙面具備聚碳酸酯薄膜的上述光透過方向控制片而以目視進行觀察,構成格柵層1的光透過帶2及遮光帶3有規則地排列著,可以容易地確認這是沒有缺陷的佳品。 By visually observing the light-transmitting direction control sheet having a polycarbonate film on both sides, the light-transmitting tape 2 and the light-shielding tape 3 constituting the grid layer 1 are regularly arranged, and it is possible to easily confirm that there is no defect. The best.
此外,當存在缺陷時,能夠通過目視容易地確認不規則地分佈著黑點或白點。 Further, when there is a defect, it is possible to easily confirm irregular distribution of black spots or white spots by visual observation.
然而,如下述結果所示,若與實施例1的光透過方向控制片10相比較,則光學特性變差。作為其原因,可以考慮是在格柵層1、黏接劑層、聚碳酸酯薄膜的各個界面產生了大的界面反射的緣故。 However, as shown in the results below, when compared with the light transmission direction control sheet 10 of the first embodiment, the optical characteristics are deteriorated. For this reason, it is conceivable that large interface reflection occurs at each interface of the grid layer 1, the adhesive layer, and the polycarbonate film.
與實施例1同樣地,對比較例1的光透過方向控制片的各聚碳酸酯薄膜的外表面的算術平均粗糙度(Ra)、光透過性、霧度、視角進行測量,Ra=0.1μm,全光線透過率=77%,霧度=6、視角=約65°。 In the same manner as in Example 1, the arithmetic mean roughness (Ra), light transmittance, haze, and viewing angle of the outer surface of each polycarbonate film of the light transmission direction control sheet of Comparative Example 1 were measured, and Ra = 0.1 μm. , total light transmittance = 77%, haze = 6, viewing angle = about 65 °.
與實施例1相比,霧度值變高,全光線透過率下降。 Compared with Example 1, the haze value was high and the total light transmittance was lowered.
除了使用糙面加工的聚碳酸酯薄膜(折射率:約1.58)以外,與比較例1同樣地製作光透過方向控制片。 A light transmission direction control sheet was produced in the same manner as in Comparative Example 1, except that a matte processed polycarbonate film (refractive index: about 1.58) was used.
透過在雙面具備聚碳酸酯薄膜的上述光透過方向控制片而以目視進行觀察,構成格柵層1的光透過帶2及遮光帶3有規則地排列著,可以容易地確認這是沒有缺陷的佳品。 By visually observing the light-transmitting direction control sheet having a polycarbonate film on both sides, the light-transmitting tape 2 and the light-shielding tape 3 constituting the grid layer 1 are regularly arranged, and it is possible to easily confirm that there is no defect. The best.
此外,當存在缺陷時,能夠通過目視容易地確認不規 則地分佈著黑點或白點。 Further, when there is a defect, it is possible to easily confirm irregular distribution of black spots or white spots by visual observation.
然而,如表1的結果所示,若與實施例1的光透過方向控制片10相比較,光學特性變差。作為其原因,可以考慮是在格柵層1、黏接劑層、聚碳酸酯薄膜的各個界面產生了大的界面反射的緣故。 However, as shown in the results of Table 1, the optical characteristics were deteriorated as compared with the light transmission direction controlling sheet 10 of Example 1. For this reason, it is conceivable that large interface reflection occurs at each interface of the grid layer 1, the adhesive layer, and the polycarbonate film.
以下,摘錄示出實施例1至3及比較例1至2的結果。表1中,“折射率之差”,在實施例中是指光透過帶的折射率(1.43)和第一透明樹脂層的折射率(1.43)之差,在比較例中是指光透過帶的折射率(1.43)和環氧類黏接劑的折射率(1.55)之差。另外,“Ra”在實施例中是指第一透明樹脂層的外表面的算術平均粗糙度,在比較例中是指聚碳酸酯薄膜的外表面的算術平均粗糙度。 The results of Examples 1 to 3 and Comparative Examples 1 to 2 are shown below. In Table 1, "the difference in refractive index" means, in the embodiment, the difference between the refractive index of the light transmission band (1.43) and the refractive index of the first transparent resin layer (1.43), and in the comparative example, the light transmission band The difference between the refractive index (1.43) and the refractive index of the epoxy-based adhesive (1.55). Further, "Ra" means, in the examples, the arithmetic mean roughness of the outer surface of the first transparent resin layer, and in the comparative example, the arithmetic mean roughness of the outer surface of the polycarbonate film.
根據表1的結果可知,光透過方向控制片的外表面的算術平均粗糙度Ra越低,光學特性越提高。進而,根據Ra相同的實施例1和比較例1的結果可知,折 射率之差小於0.1時,光學特性會提高。 According to the results of Table 1, the lower the arithmetic mean roughness Ra of the outer surface of the light transmission direction control sheet, the higher the optical characteristics. Further, from the results of Example 1 and Comparative Example 1 in which Ra is the same, it is understood that the optical characteristics are improved when the difference in refractive index is less than 0.1.
以上,通過具體的實施例對本發明進行說明,但毫無疑問,本發明的技術範圍不受上述實施例所記載的範圍限定。本領域技術人員清楚地知道,可以對上述實施例進行多種變更或改進。另外,顯而易見,根據申請專利範圍的記載,進行過這樣的變更或改良的方式也包含在本發明的技術範圍內。 The present invention has been described above by way of specific examples, but the technical scope of the present invention is not limited by the scope described in the above embodiments. It will be apparent to those skilled in the art that various changes and modifications can be made to the above-described embodiments. In addition, it is obvious that such a modification or improvement is also included in the technical scope of the present invention in accordance with the description of the scope of the patent application.
本發明的光透過方向控制片,例如能夠設置在各種資訊顯示裝置的顯示畫面上而作為防止窺視的薄片使用,或安裝在照明裝置或傳感器裝置中而作為濾光器使用。 The light transmission direction control sheet of the present invention can be used, for example, as a sheet for preventing peeping on a display screen of various information display devices, or can be used as a filter in an illumination device or a sensor device.
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