TW201903936A - Ceramic member - Google Patents
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- TW201903936A TW201903936A TW107112506A TW107112506A TW201903936A TW 201903936 A TW201903936 A TW 201903936A TW 107112506 A TW107112506 A TW 107112506A TW 107112506 A TW107112506 A TW 107112506A TW 201903936 A TW201903936 A TW 201903936A
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Abstract
Description
本發明係關於由埋設有電極及發熱電阻體的陶瓷燒結體所構成的陶瓷構件。 The present invention relates to a ceramic member composed of a ceramic sintered body in which an electrode and a heating resistor are embedded.
由設置有RF電極的RF板、及設置有發熱電阻體的加熱板接合所構成的承載盤(susceptor)等陶瓷構件業已存在。 Ceramic members such as a susceptor formed by joining an RF plate provided with an RF electrode and a heating plate provided with a heating resistor are already present.
專利文獻1中記載有藉由將載置用承載盤構件、上層承載板及下層承載板在利用黏著劑或熱熔接積層的狀態下加以固定而形成承載盤的技術。而且,分別在形成於上層承載板之上面的凹狀加熱器設置空間設置有加熱器(發熱電阻體),在形成於下層承載板之上面的凹狀電極設置空間設置有可改變阻抗的電極(RF電極)。 Patent Document 1 describes a technique in which a carrier disk is formed by fixing a carrier disk member, an upper carrier plate, and a lower carrier plate in a state where an adhesive or a heat-welding layer is used. Further, a heater (heat generating resistor) is disposed in each of the concave heater installation spaces formed on the upper carrier plate, and an electrode capable of changing impedance is disposed on the concave electrode installation space formed on the upper carrier plate ( RF electrode).
載置用承載盤構件及2個承載板係由石英所構成,加熱器設置空間係和大氣連通,上層承載板與加熱器之間則存在有間隙。這是因為藉加熱器對載置於載置用承載盤構件上面之基板執行的加熱係利用紅外線進行輻射傳熱的緣故。 The carrier plate member for mounting and the two carrier plates are made of quartz, and the heater installation space is in communication with the atmosphere, and there is a gap between the upper carrier plate and the heater. This is because the heating performed by the heater on the substrate placed on the substrate on which the carrier is placed is radiated by infrared rays.
專利文獻2中則記載有在以氮化鋁等陶瓷所 構成的承載盤之內部埋設有RF電極及加熱器的技術。 Patent Document 2 describes a technique in which an RF electrode and a heater are embedded in a carrier disk made of a ceramic such as aluminum nitride.
[專利文獻1]日本專利第4347295號公報 [Patent Document 1] Japanese Patent No. 4347295
[專利文獻2]日本特開2001-274102號公報 [Patent Document 2] Japanese Patent Laid-Open Publication No. 2001-274102
然而,專利文獻1所載的承載盤中,由於必須讓紅外線穿透,故承載盤的基材被限定於石英等可讓紅外線穿透的材質。更且,因為加熱器的發熱難以經由基材傳導,故有因加熱器過度升溫而斷線之虞。 However, in the carrier disk disclosed in Patent Document 1, since the infrared rays must be penetrated, the substrate of the carrier is limited to a material such as quartz that allows infrared rays to penetrate. Further, since the heat generation of the heater is hard to be conducted through the substrate, there is a possibility that the heater is excessively heated and the wire is broken.
另一方面,如專利文獻2所載,在將氮化鋁等熱傳導率較大的材質作為基材的承載盤中埋設RF電極及加熱器時,雖加熱器所生的熱容易經由基材傳導,但隨著承載盤的使用溫度增高,氮化鋁的絕緣性會降低,而在RF電極與加熱器之間產生漏洩電流。結果,即使對加熱器供給預定的電力,載置於承載盤的基板(晶圓)也難以加熱到所期望的溫度。 On the other hand, when the RF electrode and the heater are embedded in a carrier having a material having a large thermal conductivity such as aluminum nitride as a base material, the heat generated by the heater is easily transmitted through the substrate. However, as the use temperature of the carrier is increased, the insulation of the aluminum nitride is lowered, and a leakage current is generated between the RF electrode and the heater. As a result, even if a predetermined power is supplied to the heater, it is difficult to heat the substrate (wafer) placed on the carrier to a desired temperature.
本發明係有鑑於此類情形而研發者,其目的在提供可抑制漏洩電流之發生並且容易謀求將晶圓加熱到所期望之溫度的陶瓷構件。 The present invention has been made in view of such circumstances, and an object thereof is to provide a ceramic member capable of suppressing occurrence of a leakage current and easily heating a wafer to a desired temperature.
本發明係為一種陶瓷構件,其由具有可載置晶圓的載置面且以埋設有電極之陶瓷燒結體所構成的第 1基體、及以埋設有發熱電阻體之陶瓷燒結體所構成的第2基體,在前述第1基體之載置面的相反側以隔介著空間的狀態加以接合所形成,其特徵為:與前述載置面垂直之方向的前述空間的最小高度H(mm)、接合前述第1基體與前述第2基體之部分的合計面積對順沿藉前述載置面之外緣所界定的前述載置面之平面面積的比值A、及前述電極與前述發熱電阻體之間的距離D(mm)的關係符合H/A≦1000、且H/A+(D-H)/(1-A)≧14的條件。 The present invention is a ceramic member comprising a first substrate including a ceramic sintered body in which a wafer can be placed and a ceramic sintered body in which an electrode is embedded, and a ceramic sintered body in which a heating resistor is embedded. The second base body is formed by joining the space on the opposite side of the mounting surface of the first base body, and is characterized by a minimum height H (mm) of the space perpendicular to the mounting surface. And a ratio A of a total area of the portions of the first base body and the second base member to the plane of the mounting surface defined by the outer edge of the mounting surface, and the electrode and the heating resistor The relationship between the distances D (mm) is in accordance with the conditions of H/A ≦ 1000 and H/A + (DH) / (1-A) ≧ 14.
若依本發明,藉由介存於第1基體與第2基體之間的空間,得以抑制從發熱電阻體向載置面的傳熱過度地受到阻礙的情形,並且可抑制發生流動於電極與發熱電阻體之間的漏洩電流。 According to the present invention, by interposing in a space between the first substrate and the second substrate, it is possible to suppress excessive heat transfer from the heating resistor to the mounting surface, and it is possible to suppress flow to the electrode and heat generation. Leakage current between resistors.
本發明中,前述關係較佳為符合H/A+(D-H)/(1-A)≧100的條件。 In the present invention, the above relationship is preferably a condition conforming to H/A + (D - H) / (1 - A) ≧ 100.
在此情況下,可進一步抑制發生漏洩電流流動於電極與發熱電阻體之間的情形。 In this case, it is possible to further suppress the occurrence of a leakage current flowing between the electrode and the heating resistor.
再者,本發明中,前述空間以構成為可藉熱傳導率較空氣更高的媒體至少局部地充填,或者可連結於該媒體的供給源為佳。 Furthermore, in the present invention, the space is preferably at least partially filled with a medium having a higher thermal conductivity than air, or may be connected to a supply source of the medium.
在此情況中,藉由對存在於空間內的媒體壓力進行控制,可一面抑制漏洩電流的發生,一面控制第1基體與第2基體之間的傳熱。 In this case, by controlling the pressure of the medium existing in the space, it is possible to control the heat transfer between the first substrate and the second substrate while suppressing the occurrence of the leakage current.
10‧‧‧RF板(第1基體) 10‧‧‧RF board (1st base)
11‧‧‧載置面(上面) 11‧‧‧Loading surface (above)
12‧‧‧下面 12‧‧‧ below
20‧‧‧加熱板(第2基體) 20‧‧‧heating plate (2nd base)
21‧‧‧上面 21‧‧‧above
22‧‧‧下面 22‧‧‧ below
23、24‧‧‧凹狀部 23, 24‧‧‧ concave
30‧‧‧RF電極(電極) 30‧‧‧RF electrode (electrode)
31‧‧‧供電端子 31‧‧‧Power supply terminal
40‧‧‧加熱器(發熱電阻體) 40‧‧‧heater (heating resistor)
41‧‧‧供電端子 41‧‧‧Power supply terminal
50‧‧‧軸 50‧‧‧Axis
51‧‧‧圓筒部 51‧‧‧Cylinder
52‧‧‧擴徑部 52‧‧‧Extended section
60‧‧‧連結構件 60‧‧‧Connected components
61‧‧‧上面 61‧‧‧above
62‧‧‧下面 62‧‧‧ below
100‧‧‧陶瓷加熱器(陶瓷構件) 100‧‧‧Ceramic heater (ceramic components)
S‧‧‧空間 S‧‧‧ Space
圖1為本發明實施形態之陶瓷加熱器的示意剖面 圖。 BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic cross-sectional view showing a ceramic heater according to an embodiment of the present invention.
圖2為本發明實施形態的變化例之陶瓷加熱器的示意剖面圖。 Fig. 2 is a schematic cross-sectional view showing a ceramic heater according to a modification of the embodiment of the present invention.
圖3為本發明實施形態的其他變化例之陶瓷加熱器的示意剖面圖。 Fig. 3 is a schematic cross-sectional view showing a ceramic heater according to another modification of the embodiment of the present invention.
圖4為實施例41之陶瓷加熱器的示意水平剖面圖。 Figure 4 is a schematic horizontal sectional view of a ceramic heater of Example 41.
茲參照附圖就本發明之陶瓷構件的實施形態之陶瓷加熱器100加以說明。另外,以下說明的附圖中,為了使陶瓷加熱器100的構成明確化,各構成要素係經變形(deformer),並非表示實際的比例。 A ceramic heater 100 according to an embodiment of the ceramic member of the present invention will be described with reference to the drawings. In addition, in the drawings described below, in order to clarify the configuration of the ceramic heater 100, each constituent element is deformed, and does not represent an actual ratio.
如圖1所示,陶瓷加熱器100係由RF板10及加熱板20積層所構成,RF板10具有載置面11作為上面,該載置面11係供載置作為被加熱物之未圖示晶圓(基板)。另外,RF板10係相當於本發明的第1基體,加熱板20則相當於本發明的第2基體。 As shown in Fig. 1, the ceramic heater 100 is composed of an RF board 10 and a heating plate 20, and the RF board 10 has a mounting surface 11 as an upper surface, and the mounting surface 11 is provided with a non-illustrated image as a heated object. Show wafer (substrate). Further, the RF board 10 corresponds to the first substrate of the present invention, and the heating plate 20 corresponds to the second substrate of the present invention.
RF板10中埋設有RF電極30,加熱板20中埋設有加熱器(發熱電阻體)40。RF電極30則為對晶圓施以電漿處理時所使用的高頻電極。 The RF electrode 30 is embedded in the RF panel 10, and a heater (heating resistor) 40 is embedded in the heater board 20. The RF electrode 30 is a high frequency electrode used when plasma treatment is applied to the wafer.
在本實施形態中,RF電極30係以鉬(Mo)或鎢(W)等耐熱金屬等之箔片所構成,且形成為面狀形態。但,RF電極30也可為以耐熱金屬等製成的膜、板、網片(mesh)、纖維狀等構成。 In the present embodiment, the RF electrode 30 is formed of a foil such as a heat resistant metal such as molybdenum (Mo) or tungsten (W), and is formed into a planar shape. However, the RF electrode 30 may be formed of a film, a plate, a mesh, a fiber or the like made of a heat resistant metal or the like.
RF板10及加熱板20係為以例如氧化鋁、氮 化鋁、氮化矽等陶瓷燒結體構成的陶瓷基材。RF板10及加熱板20因係將上述材料放入預定形狀的模具中加以成形且使其緻密化,故只要是藉由例如熱壓燒成等製作成圓板狀等板狀者即可。 The RF plate 10 and the heating plate 20 are ceramic base materials composed of a ceramic sintered body such as alumina, aluminum nitride or tantalum nitride. Since the RF plate 10 and the heating plate 20 are formed by inserting the above-mentioned material into a mold having a predetermined shape and densifying it, it is sufficient to form a plate shape such as a disk shape by, for example, hot press baking.
在本實施形態中,加熱器40係以鉬(Mo)或鎢(W)等耐熱金屬等之網片構成,且形成為面狀形態。但,加熱器40也可為以耐熱金屬等製成的箔、膜、板、線、纖維、線圈、緞帶狀等所構成。 In the present embodiment, the heater 40 is formed of a mesh of a heat-resistant metal such as molybdenum (Mo) or tungsten (W), and is formed into a planar shape. However, the heater 40 may be formed of a foil, a film, a plate, a wire, a fiber, a coil, a ribbon, or the like made of a heat-resistant metal or the like.
RF板10係在利用作為RF板10之陶瓷材料夾入有RF電極30的狀態下實施燒成。再者,加熱板20則在利用作為加熱板20的陶瓷材料挾入有加熱器40的狀態下實施燒成。 The RF board 10 is fired in a state in which the RF electrode 30 is sandwiched by a ceramic material as the RF board 10. In addition, the heating plate 20 is fired in a state in which the heater 40 is inserted into the ceramic material as the heating plate 20.
RF板10及加熱板20係以在各別製得後,使RF板10之下面12與加熱板20之上面21接觸的方式接合。但,RF板10之下面12與加熱板20之上面21並不是涵蓋著整面接觸,而是至少在RF板10與加熱板20之間介存著空間(間隙)S。 The RF board 10 and the heating board 20 are joined to each other so that the lower surface 12 of the RF board 10 is in contact with the upper surface 21 of the heating board 20. However, the lower surface 12 of the RF panel 10 and the upper surface 21 of the heating plate 20 do not cover the entire surface contact, but at least a space (gap) S is interposed between the RF panel 10 and the heating panel 20.
RF板10與加熱板20係藉由使用擴散接合、黏接劑、螺絲釘(screw)等固定具之機械式結合等加以固定。 The RF board 10 and the heating board 20 are fixed by mechanical bonding using a diffusion bonding, an adhesive, a screw, or the like.
更且,陶瓷加熱器100具備:用以對RF電極30供供電力的供電用端子(供電端子)31、及埋設於RF板10的未圖示的電流供給構件。 Further, the ceramic heater 100 includes a power supply terminal (power supply terminal) 31 for supplying power to the RF electrode 30, and a current supply member (not shown) embedded in the RF board 10.
再者,陶瓷加熱器100具備:用以對加熱器40供供電力的供電用端子(供電端子)41、及埋設於加熱 板20的未圖示的電流供給構件。 Further, the ceramic heater 100 includes a power supply terminal (power supply terminal) 41 for supplying power to the heater 40, and a current supply member (not shown) embedded in the heater board 20.
端子31、41與電流供給構件係分別施以硬焊或熔接。端子31、41係以桿狀或線狀的鎳(Ni)、科伐合金(Kovar,註冊商標)(Fe-Ni-Co)、鉬(Mo)、鎢(W)、或以鉬(Mo)及鎢(W)為主成分的耐熱合金等耐熱金屬所構成。電流供給構件係以鉬(Mo)或鎢(W)等所構成。另外,端子31、41與電流供給構件也可藉和端子31、41相同的耐熱金屬製連接構件加以連接。 The terminals 31, 41 and the current supply member are respectively brazed or welded. The terminals 31 and 41 are rod-shaped or linear nickel (Ni), Kovar (registered trademark) (Fe-Ni-Co), molybdenum (Mo), tungsten (W), or molybdenum (Mo). And a heat-resistant metal such as a heat-resistant alloy containing tungsten (W) as a main component. The current supply member is made of molybdenum (Mo), tungsten (W) or the like. Further, the terminals 31 and 41 and the current supply member may be connected by a heat-resistant metal connecting member which is the same as the terminals 31 and 41.
陶瓷加熱器100進一步具備連接於加熱板20之下面22之中心部的中空軸50。 The ceramic heater 100 further includes a hollow shaft 50 connected to a central portion of the lower surface 22 of the heating plate 20.
軸50為大致圓筒狀,且具有使和加熱板20接合部分之外徑較其他圓筒部51的直徑更大徑而成的擴徑部52,擴徑部52的上面即成為和加熱板20的接合面。軸50的材質雖可和加熱板20的材質同等,但為了提高隔熱性,也可使用熱傳導率比加熱板20的素材更低的素材來形成。 The shaft 50 has a substantially cylindrical shape and has an enlarged diameter portion 52 having an outer diameter larger than a diameter of the other cylindrical portion 51, and the upper surface of the enlarged diameter portion 52 serves as a heating plate. 20 joint faces. The material of the shaft 50 may be the same as the material of the heating plate 20, but in order to improve the heat insulating property, a material having a lower thermal conductivity than the material of the heating plate 20 may be used.
加熱板20之下面與軸50之上端面係藉由利用擴散接合或利用陶瓷或者玻璃等接合材料的固相接合加以接合。另外,加熱板20與軸50也可藉由螺釘固定或硬焊等加以連接。 The lower surface of the heating plate 20 and the upper end surface of the shaft 50 are joined by solid phase bonding by diffusion bonding or by using a bonding material such as ceramic or glass. Further, the heating plate 20 and the shaft 50 may be connected by screw fixing or brazing or the like.
圖1的實施形態中,在加熱板20之上面21形成有複數個凹狀部23,且在這些凹狀部23與RF板10之下面12間形成空間S。另外,也可在RF板10之下面12形成凹狀部,而且也可在RF板10之下面12與加熱板20之上面21的雙方形成凹狀部,但未予圖示。此外, 空間S可為密閉空間,也可為和外部連通的空間,且空間S可互相連通,也可不連通。 In the embodiment of Fig. 1, a plurality of concave portions 23 are formed on the upper surface 21 of the heating plate 20, and a space S is formed between the concave portions 23 and the lower surface 12 of the RF panel 10. Further, a concave portion may be formed on the lower surface 12 of the RF panel 10, and a concave portion may be formed on both the lower surface 12 of the RF panel 10 and the upper surface 21 of the heating plate 20, but it is not shown. In addition, the space S may be a closed space or a space communicating with the outside, and the spaces S may or may not be connected to each other.
藉由介存於RF板10與加熱板20之間的空間S,漏洩電流從加熱器40流到RF電極30的情形即可受到抑制。 By the space S interposed between the RF board 10 and the heating board 20, the leakage current flows from the heater 40 to the RF electrode 30 can be suppressed.
但,因必須將產生自加熱器40的熱傳熱俾將支持於載置面11的晶圓加熱,故介存於RF板10與加熱板20之間的空間S之大小不應超過所需之大小。發明人從後述的實施例及比較例中發現到:空間S在與載置面11垂直之方向的最小高度設為H[mm]、RF板10與加熱板20之接觸面積的比值設為A時,以下的關係式(1)必須成立。 However, since the heat transfer generated from the heater 40 must heat the wafer supported on the mounting surface 11, the size of the space S interposed between the RF board 10 and the heating plate 20 should not exceed the required size. The size. The inventors have found from the examples and comparative examples described later that the minimum height of the space S in the direction perpendicular to the mounting surface 11 is H [mm], and the ratio of the contact area between the RF board 10 and the heating plate 20 is set to A. When the following relational expression (1) must be established.
H/A≦1000‧‧‧(1) H/A≦1000‧‧‧(1)
另外,比值A為RF板10之下面12與加熱板20之上面21接觸部分的合計面積相對於順沿著藉由載置面11之外緣所界定的載置面11之平面面積的比。 Further, the ratio A is a ratio of a total area of the contact portion between the lower surface 12 of the RF panel 10 and the upper surface 21 of the heating plate 20 with respect to a plane area along the mounting surface 11 defined by the outer edge of the mounting surface 11.
更且,如圖3的變化例所示,在加熱板20之上面21可形成有複數個凹狀部24,在這些凹狀部24配置有軸線方向之長度大於凹狀部24之深度的銷(Pin)等連結構件60,連結構件60之上面61則和RF板10之下面11接合,連結構件60之下面62也可和凹狀部24之底面接合。另外,如圖3所示,凹狀部24之底面也可形成在較加熱器40更遠離加熱板20之上面21的位置。 Further, as shown in the variation of FIG. 3, a plurality of concave portions 24 may be formed on the upper surface 21 of the heating plate 20, and the concave portions 24 are provided with pins having a length in the axial direction larger than the depth of the concave portion 24. The connecting member 60 such as (Pin), the upper surface 61 of the connecting member 60 is joined to the lower surface 11 of the RF panel 10, and the lower surface 62 of the connecting member 60 may be joined to the bottom surface of the concave portion 24. Further, as shown in FIG. 3, the bottom surface of the concave portion 24 may be formed at a position farther from the upper surface 21 of the heater board 20 than the heater 40.
藉此方式,RF板10之下面12與加熱板20之上面21的接觸不會涵蓋整面,而是在其間形成存在於 連結構件60周圍的空間S。另外,也可在RF板10之下面12形成凹狀部,且在其底面配置連結構件60,或者,也可將連結構件60直接接合在RF板10之下面12與加熱板20之上面21的任一方或雙方的平坦面,但未予圖示。 By this means, the contact of the lower surface 12 of the RF panel 10 with the upper surface 21 of the heating plate 20 does not cover the entire surface, but forms a space S existing around the joint member 60 therebetween. Alternatively, a concave portion may be formed on the lower surface 12 of the RF panel 10, and the connecting member 60 may be disposed on the bottom surface thereof, or the connecting member 60 may be directly bonded to the lower surface 12 of the RF panel 10 and the upper surface 21 of the heating plate 20. Flat surface of either or both sides, but not shown.
另外,連結構件60雖可和RF板10及加熱板20屬於相同的材質,但也可為不同的材質。RF板10及加熱板20與連結構件60可藉擴散接合、黏接劑等手段接合。在連結構件60和RF板10及加熱板20屬於相同材質的情況中,也可利用陶瓷基材的切削加工等將連結構件60與RF板10或加熱板20一體形成。再者,連結構件60的形狀可為圓柱狀、角柱狀、圓筒狀等,其形狀並不受限定,其配置態樣也不限定於散開的點狀。 Further, the connecting member 60 may be of the same material as the RF board 10 and the heating plate 20, but may be made of different materials. The RF board 10 and the heating board 20 and the connecting member 60 can be joined by means of diffusion bonding, an adhesive, or the like. In the case where the connecting member 60, the RF plate 10, and the heating plate 20 are of the same material, the connecting member 60 may be integrally formed with the RF plate 10 or the heating plate 20 by cutting or the like of the ceramic base material. Further, the shape of the connecting member 60 may be a columnar shape, a columnar shape, a cylindrical shape, or the like, and the shape thereof is not limited, and the arrangement thereof is not limited to the scattered dot shape.
在這種情況中,連結構件60可視為構成本發明第1基體之一部分或第2基體之一部分的構件,比值A係為RF板10之下面12與連結構件60之上面61的合計接觸面積、及加熱板20之上面21與連結構件60之下面62的合計接觸面積中較少一方的面積,相對於順沿著藉由載置面11之外緣所界定的載置面11之平面面積的比值。 In this case, the connecting member 60 can be regarded as a member constituting one of the first base of the present invention or a part of the second base, and the ratio A is the total contact area of the lower surface 12 of the RF plate 10 and the upper surface 61 of the connecting member 60, And an area of the smaller one of the total contact areas of the upper surface 21 of the heating plate 20 and the lower surface 62 of the connecting member 60 with respect to the plane area along the mounting surface 11 defined by the outer edge of the mounting surface 11. ratio.
更且,隨著因加熱器40的發熱之傳熱所產生的加熱作用使RF板10及加熱板20高溫化,這些基材的絕緣性會降低。因此,產生於RF電極30與加熱器40之間的漏洩電流會增大,若漏洩電流變得過大時,對陶瓷加熱器100供電的電源容量就會不足,使溫度控制變 得非常困難。 Further, as the RF plate 10 and the heating plate 20 are heated up by the heating action by the heat transfer by the heat generated by the heater 40, the insulation properties of these substrates are lowered. Therefore, the leakage current generated between the RF electrode 30 and the heater 40 is increased, and if the leakage current becomes excessively large, the power supply capacity for supplying power to the ceramic heater 100 is insufficient, making temperature control extremely difficult.
從而,為了抑制產生於RF電極30與加熱器40之間的漏洩電流而設置了空間S。發明人從後述的實施例及比較例中發現到:與載置面11垂直之方向的空間S的最小高度設為H[mm]、RF板10與加熱板20之接觸面積的比值設為A、RF電極30和加熱器40在與載置面11垂直之鉛直方向的距離設為D[mm]時,為了抑制過大的漏洩電流,必須成立以下的關係式(2)。 Therefore, a space S is provided in order to suppress leakage current generated between the RF electrode 30 and the heater 40. The inventors found out from the examples and comparative examples described later that the minimum height of the space S in the direction perpendicular to the mounting surface 11 is H [mm], and the ratio of the contact area between the RF board 10 and the heating plate 20 is set to A. When the distance between the RF electrode 30 and the heater 40 in the vertical direction perpendicular to the mounting surface 11 is D [mm], in order to suppress an excessive leakage current, the following relational expression (2) must be established.
H/A+(D-H)/(1-A)≧14‧‧‧(2) H/A+(D-H)/(1-A)≧14‧‧‧(2)
為了進一步抑制漏洩電流,較佳為成立下述的關係式(3)。 In order to further suppress the leakage current, it is preferable to establish the following relational expression (3).
H/A+(D-H)/(1-A)≧100‧‧‧(3) H/A+(D-H)/(1-A)≧100‧‧‧(3)
另外,距離D為RF電極30與加熱器40在鉛直方向的分離長度,即使RF電極30與加熱器40在鉛直方向重疊、或未重疊皆為相同值。此外,距離D係為RF電極30之下端與加熱器40之上端在鉛直方向的距離,例如,加熱器40形成於鉛直方向的不同位置時,係指從最上層的加熱器40之上端起算的距離。 Further, the distance D is the separation length of the RF electrode 30 and the heater 40 in the vertical direction, and the RF electrode 30 and the heater 40 overlap each other in the vertical direction or do not overlap. Further, the distance D is a distance in the vertical direction from the lower end of the RF electrode 30 to the upper end of the heater 40. For example, when the heater 40 is formed at a different position in the vertical direction, it means from the upper end of the uppermost heater 40. distance.
另外,如圖3所示的變化例,不通過連結RF電極30與加熱器40之空間S的最短路徑具有與載置面11垂直之鉛直方向的重複部分時,因距離D係為RF電極30與加熱器40在鉛直方向的分離長度D1加上該重複部分的鉛直方向長度(從凹狀部24之底面至加熱器40的距離)D2的2倍所得的值,故距離D的值係如式(4)所示。 Further, in the variation shown in FIG. 3, when the shortest path connecting the space S of the RF electrode 30 and the heater 40 has a repeating portion perpendicular to the mounting surface 11 in the vertical direction, the distance D is the RF electrode 30. The value obtained by adding the length D1 of the heater 40 in the vertical direction to the length in the vertical direction of the repeating portion (the distance from the bottom surface of the concave portion 24 to the heater 40) D2 is twice, so the value of the distance D is as follows. Formula (4).
D=D1+2×D2......(4) D=D1+2×D2......(4)
而且,如圖3的變化例所示,較佳為在鉛直方向連結RF電極30與加熱器40之間介存有空間S。藉此設計,可有效抑制產生於RF電極30與加熱器40之間的漏洩電流。在此情況中,空間S也可局部地隔介於朝鉛直方向連結的RF電極30與加熱器40之間。 Further, as shown in the variation of FIG. 3, it is preferable that a space S is interposed between the RF electrode 30 and the heater 40 in the vertical direction. With this design, the leakage current generated between the RF electrode 30 and the heater 40 can be effectively suppressed. In this case, the space S may be partially interposed between the RF electrode 30 and the heater 40 connected in the vertical direction.
此外,也可將配管連接於空間S,並從和該配管連接的氣體供給源供給氦、氬、氮等氣體,且構成為可以調整空間S的氣體壓力,但未予圖示。在此情況中,可抑制漏洩電流的發生,同時藉由調整空間S的氣體壓力而輕易控制RF板10與加熱板20之間的傳熱容易度。另外,在此情況中,空間S可為密閉空間,也可為開放空間。 Further, the piping may be connected to the space S, and a gas such as helium, argon or nitrogen may be supplied from a gas supply source connected to the piping, and the gas pressure in the space S may be adjusted, but is not shown. In this case, the occurrence of the leakage current can be suppressed, and the ease of heat transfer between the RF board 10 and the heating plate 20 can be easily controlled by adjusting the gas pressure of the space S. Further, in this case, the space S may be a closed space or an open space.
更且,在加熱板20之下方也可追加埋設有反射構件的反射板,加熱板20內的加熱器40更下方也可埋設反射構件,但未予圖示。反射構件係具有藉由將來自加熱器40的輻射熱有效地反射,而抑制加熱器40之消耗電力的功效。反射構件係由例如鎳、鉬、鎢、白金、鈀、白金鈀合金等高融點金屬所構成而上面則呈鏡面的構件。 Further, a reflecting plate in which a reflecting member is embedded may be added below the heating plate 20, and a reflecting member may be embedded below the heater 40 in the heating plate 20, but is not shown. The reflecting member has an effect of suppressing the power consumption of the heater 40 by effectively reflecting the radiant heat from the heater 40. The reflecting member is made of a high-melting point metal such as nickel, molybdenum, tungsten, platinum, palladium or platinum palladium alloy, and the upper surface is a mirror-shaped member.
以下,具體舉出本發明的實施例及比較例來說明本發明。 Hereinafter, the present invention will be specifically described by way of examples and comparative examples of the invention.
實施例1至40中,係將由埋設有RF電極30之氮化 鋁(AlN)燒結體所成的RF板10、及由埋設有加熱器40之氮化鋁所成的加熱板40加以接合並積層,而製得圖1所示的陶瓷加熱器100。 In the first to fourth embodiments, the RF plate 10 made of the aluminum nitride (AlN) sintered body in which the RF electrode 30 is embedded and the heating plate 40 made of the aluminum nitride in which the heater 40 is embedded are joined. The ceramic heater 100 shown in Fig. 1 was produced by lamination.
RF板10係由直徑340mm且厚度4mm的氮化鋁燒結體所構成,在其厚度方向中間部,埋設有由厚度為0.1mm且直徑為300mm之俯視下呈圓形的Mo箔所構成的RF電極30。 The RF plate 10 is composed of an aluminum nitride sintered body having a diameter of 340 mm and a thickness of 4 mm, and an RF composed of a Mo foil having a thickness of 0.1 mm and a diameter of 300 mm and a circular shape in plan view is embedded in the intermediate portion in the thickness direction. Electrode 30.
加熱板20係以直徑340mm的氮化鋁燒結體所構成,在自其下面22起8mm的上方埋設有Mo網片製(線徑0.1mm、# 50、平織)加熱器40。如圖4所示,加熱器40具有將配置成同心圓狀的複數個圓弧狀圖樣、及將徑向鄰接的圓弧狀圖樣彼此連接的直線狀圖樣,最外周的圓弧狀圖樣之直徑為310mm。加熱板20在實施例1至34中,厚度為16mm,在實施例35至40中,厚度為26mm。氮化鋁燒結體在650℃的體積電阻率為1.0×108Ω.cm。 The heating plate 20 is composed of an aluminum nitride sintered body having a diameter of 340 mm, and a Mo mesh (wire diameter 0.1 mm, #50, plain weave) heater 40 is embedded above 8 mm from the lower surface 22 thereof. As shown in FIG. 4, the heater 40 has a plurality of arc-shaped patterns arranged in a concentric shape and a linear pattern in which arc-shaped patterns adjacent in the radial direction are connected to each other, and the diameter of the outermost arc-shaped pattern is as shown in FIG. It is 310mm. The heating plate 20 has a thickness of 16 mm in Examples 1 to 34 and a thickness of 26 mm in Examples 35 to 40. The volume resistivity of the aluminum nitride sintered body at 650 ° C is 1.0 × 10 8 Ω. Cm.
藉由使用加工機的研削加工,在加熱板20之上面21形成有複數個凹狀部23。凹狀部23的高度(亦即,空間S的最小高度)H為0.02mm至12mm,RF板10與加熱板20之接觸面積的比值A為0.001(0.1%)至0.5(50%)。 A plurality of concave portions 23 are formed on the upper surface 21 of the heating plate 20 by grinding using a processing machine. The height of the concave portion 23 (that is, the minimum height of the space S) H is 0.02 mm to 12 mm, and the ratio A of the contact area of the RF plate 10 and the heating plate 20 is 0.001 (0.1%) to 0.5 (50%).
RF板10與加熱板20之接合係藉由一邊對接合面賦予8Mpa的壓力,一邊在真空中加熱至1700℃的 擴散接合來施行。將氮化鋁燒結體所構成的軸50之上端面藉擴散接合而接合在加熱板20之下面22。此時的擴散接合係藉由一面對接合面賦予8Mpa以下的壓力一面在真空中加熱至1600℃來進行。 The joining of the RF plate 10 and the heating plate 20 was carried out by applying a pressure of 8 MPa to the joint surface and heating to 1700 °C in a vacuum. The upper end surface of the shaft 50 formed of the aluminum nitride sintered body is joined to the lower surface 22 of the heating plate 20 by diffusion bonding. The diffusion bonding at this time is performed by heating to 1600 ° C in a vacuum while applying a pressure of 8 MPa or less to the joint surface.
在軸50的接合後,將鎳製的供電端子31、41藉由在1000℃使用金硬焊材的真空硬焊而接合在RF電極30及加熱器40。 After the joining of the shaft 50, the nickel power supply terminals 31, 41 are joined to the RF electrode 30 and the heater 40 by vacuum brazing using a gold hard solder material at 1000 °C.
在陶瓷加熱器100之載置面11放置黑色化的檔片(dummy wafer),對端子41供供電力俾將加熱器40升溫,以IR相機攝像機量測檔片表面的溫度。從檔片表面溫度到達600℃的時刻起15分鐘的時間中,使供給到端子41的電力達到相同。另外,RF電極30則接地。 A blackened dummy wafer is placed on the mounting surface 11 of the ceramic heater 100, and the terminal 41 is supplied with a power supply. The heater 40 is heated, and the temperature of the surface of the blade is measured by an IR camera. The power supplied to the terminal 41 was made the same in a period of 15 minutes from the time when the surface temperature of the blade reached 600 °C. In addition, the RF electrode 30 is grounded.
量測其後的RF板10及加熱板20之溫度,求出其差值。具體而言,係在陶瓷加熱器100之中央區域預先設置在RF板10及加熱板20各自的厚度方向的中間位置具有底部的熱電對測定用孔(未圖示),藉由在熱電對測定用孔插入鎧裝(sheathed)熱電偶(K型,直徑16mm的不銹鋼護套)而量測RF板10及加熱板20之溫度。 The temperature of the subsequent RF plate 10 and the heating plate 20 was measured to determine the difference. Specifically, in the central region of the ceramic heater 100, a thermoelectric pair measurement hole (not shown) having a bottom portion at an intermediate position in the thickness direction of each of the RF plate 10 and the heating plate 20 is provided in advance, and is measured by a thermoelectric pair. The temperature of the RF plate 10 and the heating plate 20 was measured by inserting a sheathed thermocouple (K type, stainless steel sheath having a diameter of 16 mm) with a hole.
然後,量測在RF電極30與加熱器40之間發生的漏洩電流。漏洩電流係以交流電流計連接在與RF電極30連接的供電端子31和接地之間的路徑來量測。 Then, the leakage current occurring between the RF electrode 30 and the heater 40 is measured. The leakage current is measured by an AC current meter connected to a path between the power supply terminal 31 connected to the RF electrode 30 and the ground.
RF板10與加熱板20之溫度差為1.5℃至185.5℃,少到未達200℃,H/A為0.04至1000,符合關係式(1)。 The temperature difference between the RF board 10 and the heating board 20 is 1.5 ° C to 185.5 ° C, as small as less than 200 ° C, and H / A is 0.04 to 1000, which is in accordance with the relationship (1).
發生在RF電極30與加熱器40之間的漏洩電流為0.01mA至0.99mA,少到未達1mA,H/A+(D-H)/(1-A)為14.3至1010,符合關係式(2)。 The leakage current occurring between the RF electrode 30 and the heater 40 is 0.01 mA to 0.99 mA, as small as less than 1 mA, and H/A + (DH) / (1-A) is 14.3 to 1010, which is in accordance with the relationship (2). .
而且,在實施例8、12、17、18、22、26、30、34、35、38中,發生於RF電極30與加熱器40之間的漏洩電流為0.01mA至0.13mA,非常小,未達0.15mA,H/A+(D-H)/(1-A)為109至1010,符合關係式(3)。 Further, in Embodiments 8, 12, 17, 18, 22, 26, 30, 34, 35, 38, the leakage current occurring between the RF electrode 30 and the heater 40 is 0.01 mA to 0.13 mA, which is very small. It is less than 0.15 mA, and H/A+(DH)/(1-A) is 109 to 1010, which is in accordance with the relationship (3).
茲將實施例1至40的結果彙整為表1及表2。 The results of Examples 1 to 40 are summarized into Tables 1 and 2.
加熱板20之厚度為20mm,在自其下面22起8mm的上方埋設有加熱器40,同時在加熱板20之上面21未形成凹狀部23,且未設置空間S,將RF板10之下面12與加熱板20之上面21以涵蓋整面方式接合。此外,設 為和實施例1至34相同而製得陶瓷加熱器。 The thickness of the heating plate 20 is 20 mm, and the heater 40 is embedded above 8 mm from the lower surface 22 thereof, while the concave portion 23 is not formed on the upper surface 21 of the heating plate 20, and the space S is not provided, and the lower surface of the RF plate 10 is disposed. 12 is joined to the upper surface 21 of the heating plate 20 in a full-face manner. Further, ceramic heaters were prepared in the same manner as in Examples 1 to 34.
RF板10與加熱板20之溫度差係小到1.5℃,甚良好。但,產生於RF電極30與加熱器40之間的漏洩電流卻大到1.41mA,超過了1mA。 The temperature difference between the RF board 10 and the heating board 20 is as small as 1.5 ° C, which is very good. However, the leakage current generated between the RF electrode 30 and the heater 40 is as large as 1.41 mA, exceeding 1 mA.
將形成於加熱板20之上面21的凹狀部23的態樣變更成如表3所示。此外則設為和實施例1至34相同而製得陶瓷加熱器。 The aspect of the concave portion 23 formed on the upper surface 21 of the heating plate 20 was changed as shown in Table 3. Further, a ceramic heater was prepared in the same manner as in Examples 1 to 34.
RF板10與加熱板20之溫度差為1.5℃至1.8℃,少到未達200℃,H/A為0.2至2.0,符合關係式(1)。 The temperature difference between the RF board 10 and the heating board 20 is 1.5 ° C to 1.8 ° C, as small as less than 200 ° C, and H / A is 0.2 to 2.0, which is in accordance with the relationship (1).
產生於RF電極30與加熱器40之間的漏洩電流大到1.17mA至1.25mA,超過1mA。H/A+(D-H)/(1-A)為11.3至12.1,不符關係式(2)。 The leakage current generated between the RF electrode 30 and the heater 40 is as large as 1.17 mA to 1.25 mA, exceeding 1 mA. H/A+(D-H)/(1-A) is 11.3 to 12.1, which does not correspond to the relation (2).
將形成於加熱板20之上面21的凹狀部23的態樣變更成如表3所示。此外,比較例6至8係設為和實施例1至34相同,比較例9至11設為和實施例35至40相同而製得陶瓷加熱器。 The aspect of the concave portion 23 formed on the upper surface 21 of the heating plate 20 was changed as shown in Table 3. Further, Comparative Examples 6 to 8 were set to be the same as Examples 1 to 34, and Comparative Examples 9 to 11 were set to be the same as Examples 35 to 40 to obtain a ceramic heater.
產生於RF電極30與加熱器40之間的漏洩電流小到0.01mA以下,未達1mA。H/A+(D-H)/(1-A)為1208至12008,符合關係式(2)。 The leakage current generated between the RF electrode 30 and the heater 40 is as small as 0.01 mA or less, and is less than 1 mA. H/A+(D-H)/(1-A) is 1208 to 12008, which is in accordance with the relationship (2).
但,RF板10與加熱板20之溫度差卻超過200℃,H/A為1200至12000,不符關係式(1)。 However, the temperature difference between the RF board 10 and the heating board 20 exceeds 200 ° C, and the H/A ratio is 1200 to 12,000, which does not correspond to the relation (1).
將比較例1至11的結果彙整於表3。 The results of Comparative Examples 1 to 11 are summarized in Table 3.
實施例41中,除了凹狀部23之態樣與加熱器40的形狀不同外,其餘設為和實施例17至21相同而製得陶瓷加熱器。 In Example 41, except that the shape of the concave portion 23 was different from that of the heater 40, the ceramic heater was obtained in the same manner as in Examples 17 to 21.
如圖4所示,決定加熱器40的形狀,在上面視圖中未與加熱器40重疊的部分,使RF板10之下面12與加熱板20之上面21接合。亦即,如圖2所示,以RF電極30與加熱器40之間存在有空間S的方式構成陶瓷加熱器100。RF板10與加熱板20之接觸面積的比值A為0.1(10%),空間S的最小高度H為1.0mm,作為RF電極30與加熱器40在鉛直方向之分離長度的距離D為10mm。 As shown in Fig. 4, the shape of the heater 40 is determined, and the lower surface 12 of the RF panel 10 is joined to the upper surface 21 of the heating plate 20 in a portion not overlapped with the heater 40 in the upper view. That is, as shown in FIG. 2, the ceramic heater 100 is configured such that a space S exists between the RF electrode 30 and the heater 40. The ratio A of the contact area of the RF board 10 and the heating board 20 is 0.1 (10%), and the minimum height H of the space S is 1.0 mm, and the distance D which is the separation length of the RF electrode 30 and the heater 40 in the vertical direction is 10 mm.
RF板10與加熱板20之溫度差小到3.1℃,甚良好,關係式(1)及(2)的值相同,且和實施例19的3.1℃相同。 The temperature difference between the RF plate 10 and the heating plate 20 was as small as 3.1 ° C, which was very good, and the values of the relations (1) and (2) were the same, and were the same as the 3.1 ° C of Example 19.
產生於RF電極30與加熱器40之間的漏洩電流為0.3mA,非常小,即使和實施例19的0.71mA相較也很小。 The leakage current generated between the RF electrode 30 and the heater 40 was 0.3 mA, which was very small, even when compared with the 0.71 mA of Example 19.
實施例42中,如圖3所示,除了經由連結構件60將RF板10與加熱板20接合之外,其餘設為和實施例1至34相同而製得陶瓷加熱器。 In Example 42, as shown in Fig. 3, a ceramic heater was produced in the same manner as in Examples 1 to 34 except that the RF plate 10 was joined to the heating plate 20 via the joining member 60.
連結構件60係藉由將氮化鋁燒結體切削加工而和RF板10形成一體。 The joining member 60 is integrally formed with the RF sheet 10 by cutting the aluminum nitride sintered body.
RF板10及加熱板20與連結構件60之接觸面積的比值A為0.01(1%),空間S的最小高度H為1.0mm。此時,D1為5mm,D2為7mm,D為19mm。 The ratio A of the contact area between the RF board 10 and the heating board 20 and the connecting member 60 is 0.01 (1%), and the minimum height H of the space S is 1.0 mm. At this time, D1 is 5 mm, D2 is 7 mm, and D is 19 mm.
RF板10與加熱板20之溫度差小到3.1℃,甚良好,H/A為100,符合關係式(1)。 The temperature difference between the RF board 10 and the heating board 20 is as small as 3.1 ° C, which is very good, and H/A is 100, which is in accordance with the relationship (1).
產生於RF電極30與加熱器40之間的漏洩電流為0.18mA,非常小,H/A+(D-H)/(1-A)為118.1,符合關係式(3)。 The leakage current generated between the RF electrode 30 and the heater 40 was 0.18 mA, which was very small, and H/A+(D-H)/(1-A) was 118.1, which was in accordance with the relation (3).
在實施例43至46中,在和實施例18相同的陶瓷加熱器100中,將未圖示的配管連接於空間S,從連接於該配管的氦(He)供給源供給氦氣,空間S的氦氣壓力分別設為1torr、5torr、10torr、50torr。 In the ceramic heaters 100 of the same manner as in the eighteenth embodiment, the piping (not shown) is connected to the space S, and the helium gas is supplied from the helium (He) supply source connected to the piping, and the space S is provided. The helium pressures are set to 1 torr, 5 torr, 10 torr, and 50 torr, respectively.
在實施例43至46中,RF板10與加熱板20之溫度差分別小到19.7℃、17.2℃、15.2℃、12.4℃,甚良好。和空間S的氦氣壓力為0torr之實施例18的19.7℃一起觀察時,空間S的氦氣壓力越大溫度差越小。 In Examples 43 to 46, the temperature difference between the RF plate 10 and the heating plate 20 was as small as 19.7 ° C, 17.2 ° C, 15.2 ° C, and 12.4 ° C, respectively, which was very good. When the helium gas pressure of the space S was 0 Torr, the 19.7 ° C of Example 18 was observed, and the larger the helium pressure of the space S, the smaller the temperature difference.
產生於RF電極30與加熱器40之間的漏洩電流全為0.13mA,和實施例18相同,空間S的氦氣壓力不會影響漏洩電流的大小。 The leakage current generated between the RF electrode 30 and the heater 40 was all 0.13 mA, and as in Embodiment 18, the helium pressure of the space S did not affect the magnitude of the leakage current.
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