TW201900665A - Novel compound and resin composition - Google Patents

Novel compound and resin composition Download PDF

Info

Publication number
TW201900665A
TW201900665A TW107112245A TW107112245A TW201900665A TW 201900665 A TW201900665 A TW 201900665A TW 107112245 A TW107112245 A TW 107112245A TW 107112245 A TW107112245 A TW 107112245A TW 201900665 A TW201900665 A TW 201900665A
Authority
TW
Taiwan
Prior art keywords
mass
parts
resin
present
composition
Prior art date
Application number
TW107112245A
Other languages
Chinese (zh)
Inventor
行武秀明
中村総夫
佐藤文彦
井上智之
Original Assignee
日商艾迪科股份有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 日商艾迪科股份有限公司 filed Critical 日商艾迪科股份有限公司
Publication of TW201900665A publication Critical patent/TW201900665A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
    • C08K5/5333—Esters of phosphonic acids
    • C08K5/5357—Esters of phosphonic acids cyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/06—Organic materials
    • C09K21/12—Organic materials containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/14—Macromolecular materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The problem addressed by the present invention is to provide a compound having excellent heat resistance and being capable of dramatically improving the flame retardancy of a resin, especially a polyester resin, by being added in a small amount. The problem is solved by a compound represented by general formula (1). (In the formula, R1 and R3 each independently represent an optionally substituted monovalent aromatic group; X1 and X2 each independently represent a direct bond, a C1-8 alkylene group, an oxygen atom, a nitrogen atom, or a sulfur atom; an oxygen atom, nitrogen atom, or sulfur atom may be interposed between optionally adjacent carbon atoms in the C1-8 alkylene group; R2 represents a group represented by general formula (2); and n represents a number of 1-20).

Description

新穎化合物及樹脂組合物Novel compounds and resin compositions

本發明係關於一種具有特定結構之季戊四醇膦酸酯聚合物及其樹脂組合物。The present invention relates to a pentaerythritol phosphonate polymer having a specific structure and a resin composition thereof.

先前，合成樹脂因優異之化學、機械特性而廣泛地用於汽車零件、包裝材料、建材、農業用材料、家電製品、玩具等。尤其於合成樹脂中，聚丙烯樹脂、聚乙烯樹脂、聚酯樹脂、聚碳酸酯樹脂、ABS(acrylonitrile-butadiene-styrene，丙烯腈-丁二烯-苯乙烯)樹脂、苯乙烯樹脂、聚醯胺樹脂、聚苯醚樹脂等因其物性而得到廣泛使用。但，由於該等樹脂為可燃性，故而於以上述用途使用之情形時除化學、機械物性以外，亦要求對火焰之阻燃性。 作為樹脂之阻燃化方法，廣為人知有將鹵素系阻燃劑、以赤磷或聚磷酸銨等聚磷酸系阻燃劑為代表之無機磷系阻燃劑、氫氧化鎂或氫氧化鋁等金屬氫氧化物系阻燃劑、以三芳基磷酸酯化合物為代表之有機磷系阻燃劑、及作為阻燃助劑之氧化銻、三聚氰胺化合物單獨或組合使用。 然而，鹵素系阻燃劑存在於成形加工時或燃燒時產生大量之腐蝕性氣體等安全性問題，無機磷系阻燃劑就燃燒時之有毒氣體、或耐水性及耐熱性差之方面而言，於加工時之處理或成形性方面存在問題。又，金屬氫氧化物系阻燃劑存在為了獲得充分之阻燃性而需要大量添加，從而失去樹脂本來之物性之問題。 有機磷酸系阻燃劑亦作為不含有鹵素之阻燃劑而廣為人知，但由於樹脂組合物之耐熱性之降低，或阻燃劑本身之耐熱性較低，故而於加工時之處理性方面存在問題。 另一方面，對於二取代季戊四醇二膦酸酯化合物之作為阻燃劑之使用進行各種研究，記載有：具有特定結構之季戊四醇二膦酸酯可藉由在工業上有利之生產性優異之方法而製造，從而賦予阻燃性(專利文獻1、2)。然而，該季戊四醇二膦酸酯於尤其要求較高之阻燃性之聚酯系樹脂中難以獲得充分之阻燃性能。 先前技術文獻 專利文獻 專利文獻1：日本專利特開2003-267984號公報 專利文獻2：日本專利特開2004-210968號公報Previously, synthetic resins have been widely used in automobile parts, packaging materials, building materials, agricultural materials, home electric appliances, toys, and the like because of excellent chemical and mechanical properties. Especially in synthetic resins, polypropylene resin, polyethylene resin, polyester resin, polycarbonate resin, ABS (acrylonitrile-butadiene-styrene) resin, styrene resin, polyamide Resins, polyphenylene ether resins and the like are widely used due to their physical properties. However, since these resins are flammable, in the case of being used as described above, in addition to chemical and mechanical properties, flame retardancy to flames is also required. As a flame retarding method of a resin, a halogen-based flame retardant, an inorganic phosphorus-based flame retardant represented by a polyphosphoric acid-based flame retardant such as red phosphorus or ammonium polyphosphate, or a metal such as magnesium hydroxide or aluminum hydroxide is widely known. A hydroxide-based flame retardant, an organophosphorus-based flame retardant typified by a triaryl phosphate compound, and a cerium oxide or a melamine compound as a flame retardant auxiliary are used singly or in combination. However, the halogen-based flame retardant has a safety problem such as a large amount of corrosive gas during molding or burning, and the inorganic phosphorus-based flame retardant is in terms of toxic gas during combustion or poor water resistance and heat resistance. There is a problem in processing or formability at the time of processing. Further, the metal hydroxide-based flame retardant has a problem that a large amount of addition is required in order to obtain sufficient flame retardancy, thereby losing the original physical properties of the resin. The organic phosphate flame retardant is also widely known as a flame retardant containing no halogen, but there is a problem in the rationality of processing due to a decrease in heat resistance of the resin composition or a low heat resistance of the flame retardant itself. . On the other hand, various studies have been conducted on the use of a disubstituted pentaerythritol diphosphonate compound as a flame retardant, and it is described that a pentaerythritol diphosphonate having a specific structure can be industrially advantageous in productivity. It is manufactured to impart flame retardancy (Patent Documents 1 and 2). However, the pentaerythritol diphosphonate is difficult to obtain sufficient flame retardancy in a polyester resin which is particularly required to have high flame retardancy. PRIOR ART DOCUMENT PATENT DOCUMENT Patent Document 1: Japanese Patent Laid-Open Publication No. 2003-267984

因此，本發明之目的在於提供一種耐熱性及阻燃性優異之新穎之化合物。 本發明人等經過努力研究，結果發現具有季戊四醇骨架之特定之膦酸表現出優異之耐熱性及阻燃性。本發明係基於該見解而完成者。具體而言，本發明如下所述。 [發明1] 一種化合物，其係下述通式(1)所表示者， [化1](式中，R1 及R3 分別獨立表示存在具有取代基之情況之一價之芳香族基， X1 及X2 分別獨立表示直接鍵、碳數1～8之伸烷基、氧原子、氮原子或硫原子，於上述碳數1～8之伸烷基中之任意相鄰之碳原子間存在介存有氧原子、氮原子或硫原子之情況， R2 表示下述通式(2)所表示之基， n表示1～20之數) [化2](式中，m表示0～4之整數)。 [發明2] 一種組合物，其含有上述通式(1)所表示之化合物與磷酸鹽化合物。 [發明3] 如發明2之組合物，其中上述磷酸鹽化合物為焦磷酸鹽。 [發明4] 如發明2之組合物，其中上述磷酸鹽化合物為聚磷酸鹽。 [發明5] 如發明2～發明4之組合物，其中上述通式(1)所表示之化合物與磷酸鹽化合物之質量比以前者：後者計為9：1～1：9。 [發明6] 一種樹脂組合物，其含有樹脂、與相對於該樹脂100質量份為0.1～500質量份之如發明1之化合物。 [發明7] 一種樹脂組合物，其含有樹脂、與相對於該樹脂100質量份為0.1～500質量份之如發明2～5中任一項之組合物。 [發明8] 如發明6或7之樹脂組合物，其中上述樹脂包含聚酯系樹脂或聚醯胺系樹脂。 [發明9] 一種成形品，其係使如發明6～8中任一項之樹脂組合物成形而成者。Accordingly, it is an object of the present invention to provide a novel compound which is excellent in heat resistance and flame retardancy. As a result of intensive studies, the present inventors have found that a specific phosphonic acid having a pentaerythritol skeleton exhibits excellent heat resistance and flame retardancy. The present invention has been completed based on this finding. Specifically, the present invention is as follows. [Invention 1] A compound represented by the following formula (1), [Chemical Formula 1] (wherein R 1 and R 3 each independently represent an aromatic group having a valence of a substituent, and X 1 and X 2 each independently represent a direct bond, an alkylene group having 1 to 8 carbon atoms, an oxygen atom, The nitrogen atom or the sulfur atom may have an oxygen atom, a nitrogen atom or a sulfur atom interposed between any adjacent carbon atoms of the above-mentioned alkyl group having 1 to 8 carbon atoms, and R 2 represents the following formula (2) ), the base represented by n, the number of 1 to 20) [Chemical 2] (wherein m represents an integer of 0 to 4). [Invention 2] A composition comprising a compound represented by the above formula (1) and a phosphate compound. [Invention 3] The composition according to Invention 2, wherein the phosphate compound is pyrophosphate. [Invention 4] The composition according to Invention 2, wherein the phosphate compound is a polyphosphate. [Invention 5] The composition of Invention 2 to Invention 4, wherein the mass of the compound represented by the above formula (1) and the phosphate compound is higher than the former: the latter is from 9:1 to 1:9. [Invention 6] A resin composition containing a resin and a compound of Invention 1 in an amount of 0.1 to 500 parts by mass based on 100 parts by mass of the resin. [Invention 7] A resin composition comprising a resin and a composition according to any one of Inventions 2 to 5 in an amount of 0.1 to 500 parts by mass based on 100 parts by mass of the resin. [Invention 8] The resin composition according to Invention 6 or 7, wherein the resin comprises a polyester resin or a polyamide resin. [Invention 9] A molded article obtained by molding the resin composition according to any one of Inventions 6 to 8.

以下，基於本發明之較佳之實施形態對本發明進行詳細說明。 〈化合物〉 本發明之化合物係具有下述通式(1)所表示之季戊四醇骨架之化合物。 [化3](式中，R1 及R3 分別獨立表示存在具有取代基之情況之一價之芳香族基， X1 及X2 分別獨立表示直接鍵、碳數1～8之伸烷基、氧原子、氮原子或硫原子，於上述碳數1～8之伸烷基中之任意相鄰之碳原子間存在介存有氧原子、氮原子或硫原子之情況， R2 表示下述通式(2)所表示之基， [化4](式中，m表示0～4之整數) 通式(1)中，R1 及R3 分別獨立表示一價之芳香族基。作為一價之芳香族基，例如可列舉：碳原子數6～20之芳香族烴環基及碳原子數3～20之芳香族雜環基。作為上述碳原子數6～20之芳香族烴環基，例如可列舉：苯基、萘基、聯苯基、聯三苯基、茀基及芘基等。作為碳原子數3～20之芳香族雜環基，例如可列舉：呋喃基、噻吩基、苯并哌喃基、苯并噻吩基、聯呋喃基(bifuranyl)、聯三呋喃基(terfuranyl)、聯噻吩基、聯三噻吩基、硒吩基、聯硒吩基及聯三硒吩基等。 上述一價之芳香族基中，就阻燃性及對樹脂之相溶性之觀點而言，較佳為碳原子數6～20之芳香族烴環基，更佳為苯基。 於上述一價之芳香族基中之氫原子經其他基取代之情形時，作為取代基，例如可列舉：碳原子數1～8之烷基、碳原子數1～8之烷氧基等。作為碳原子數1～8之烷基，例如可列舉：甲基、乙基、丙基、異丙基、丁基、第二丁基、第三丁基、異丁基、戊基、異戊基、第三戊基、己基、2-己基、3-己基、環己基、1-甲基環己基、庚基、2-庚基、3-庚基、異庚基、第三庚基、1-辛基、異辛基及第三辛基等。於通式(1)中之R1 及/或R3 為苯基，且該苯基被取代為1個上述烷基之情形時，該烷基之取代位置可為鄰位、間位或對位之任一者，尤佳為對位。於通式(1)中之R1 及/或R3 為苯基，且該苯基被取代為2個上述烷基之情形時，該烷基之取代位置可為鄰位、間位或對位之任一者，尤佳為間位。 作為碳原子數1～8之烷氧基，例如可列舉在上述碳原子數1～8之烷基上鍵結有氧原子之基。於通式(1)中之R1 及/或R3 為苯基，且該苯基被取代為1個上述烷氧基之情形時，該烷氧基之取代位置可為鄰位、間位或對位之任一者，尤佳為對位。於通式(1)中之R1 及/或R3 為苯基，且該苯基被取代為2個上述烷氧基之情形時，該烷氧基之取代位置可為鄰位、間位或對位之任一者，尤佳為間位。 通式(1)中，X1 及X2 所表示之碳數1～8之伸烷基為直鏈或支鏈狀者。作為該伸烷基之具體例，可列舉：亞甲基、伸乙基、伸丙基、三亞甲基、四亞甲基、1,3-丁二基、2-甲基-1,3-丙二基、2-甲基-1,3-丁二基、2,4-戊二基、1,4-戊二基、3-甲基-1,4-丁二基、2-甲基-1,4-戊二基、五亞甲基、六亞甲基、七亞甲基及八亞甲基等。尤其就阻燃性及對樹脂之相溶性之觀點而言，作為該伸烷基，較佳為碳數1～6之伸烷基，進而較佳為碳數1～4之伸烷基，尤佳為作為碳數1之伸烷基之亞甲基。 於上述伸烷基中之任意相鄰之碳原子間存在介存有氧原子、氮原子或硫原子之情況。本發明之化合物存在如下情況，即，以氧原子、氮原子或硫原子不相鄰作為條件，而在伸烷基之1個部位或2個部位以上介存有選自氧原子、氮原子或硫原子中之一種或兩種以上之雜原子。 於通式(1)所表示之化合物中，較佳為R1 為苯基，且X1 為亞甲基，即，藉由R1 與X1 而形成苄基。又，於通式(1)所表示之化合物中，較佳為R3 為苯基，且X2 為亞甲基，即，藉由R3 與X2 而形成苄基。 通式(1)中，R2 表示上述通式(2)所表示之二元之芳香族基。通式(2)中之m為0～4之整數，m較佳為0～2之整數，m尤佳為0。R2 雖然係通式(2)所表示之亞甲基之位置較佳為鄰位、間位、對位之任一者，但尤佳為對位。 通式(1)中，n表示1～20之數，較佳為1～15之數，進而較佳為1～10之數，尤其就相溶性之觀點而言，較佳為1～5之數。本發明之化合物存在僅含有n為一種之單一化合物之情況，及為n不同之兩種以上之化合物之混合物之情況。本發明之化合物為混合物之情形時的n之數係設為混合物中含有最多之化合物之n之值(莫耳數基準)。n之數例如可藉由凝膠滲透層析法(GPC)或核磁共振分析(NMR)等進行測定。 此種上述通式(1)所表示之化合物可藉由依據公知之季戊四醇膦酸酯之製造方法的方法進行製造。例如，作為起始物質，使用下述通式(a)所表示之化合物、與通式(b)所表示之化合物，使該等於溶劑中在加熱下反應，而進行聚合。作為溶劑，例如可使用環丁碸等。關於聚合之停止，只要於反應系中添加通式(c)所表示之化合物即可。 [化5](式中，Ra 及Rb 分別獨立表示甲基、乙基、丙基、異丙基、丁基、第二丁基、第三丁基及異丁基等碳原子數1～4之烷基) [化6](式中，Ya 表示氯及溴等鹵素原子) [化7](式中，Ra 表示與通式(1)中之一價之芳香族基相同之基，Xa 表示與通式(1)中之碳原子數1～8之伸烷基相同之基，Yb 表示氯及溴等鹵素原子) 作為本發明之化合物，例如可列舉以下No.1～N0.4所表示之化合物，但並不特別限於該等，只要由通式(1)所表示，則亦可使用該等之衍生物。 [化8][化9][化10][化11]本發明之化合物可使用於各種添加劑。本發明之化合物由於耐熱性及阻燃性優異，故而可較佳地用作阻燃劑。於將本發明之化合物用作阻燃劑之情形時，存在單獨使用本發明之化合物之一種或兩種以上之情況，存在以含有本發明之化合物與其他成分之組合物之形態使用之情況。 〈組合物〉 其次，對本發明之組合物進行說明。 本發明之組合物係含有本發明之上述通式(1)所表示之化合物與磷酸鹽化合物者。本發明之組合物可較佳地用作對樹脂賦予阻燃性之添加劑。本發明之組合物含有一種或兩種以上本發明之化合物。藉由將本發明之化合物與磷酸鹽化合物併用，而起到優異之阻燃性能之效果。 作為本發明之組合物中所使用之磷酸鹽化合物，例如可列舉：磷酸三聚氰胺、磷酸哌𠯤等磷酸鹽；聚磷酸銨、聚磷酸三聚氰胺、聚磷酸哌𠯤等聚磷酸鹽；正磷酸三聚氰胺、正磷酸哌𠯤等正磷酸鹽；焦磷酸銨、焦磷酸三聚氰胺、焦磷酸哌𠯤等焦磷酸鹽；磷酸鈣；及磷酸鎂等以及該等之衍生物。該等磷酸鹽化合物可單獨使用一種，亦可將兩種以上組合使用。就阻燃性與加工性之觀點而言，本發明之組合物中所使用之磷酸鹽化合物較佳為含有焦磷酸鹽或聚磷酸鹽，尤佳為含有焦磷酸鹽。 本發明之組合物中之上述通式(1)所表示之化合物與磷酸鹽化合物之含有比率較佳為前者：後者以質量比計為9：1～1：9，進而較佳為3：1～1：3，尤其最佳為1：1。 如上所述，本發明之組合物可較佳地用作用以調配於樹脂中之添加劑。本發明之組合物存在除通式(1)所表示之化合物與磷酸鹽化合物以外亦含有其他添加劑之情況。 作為上述其他添加劑，只要無損本發明之效果，則可使用本發明所屬之技術領域中所使用之公知之添加劑，可以任意添加量調配公知之添加劑。作為其他添加劑，例如使用選自酚系抗氧化劑、磷系抗氧化劑、硫醚系抗氧化劑、其他抗氧化劑、受阻胺系光穩定劑、紫外線吸收劑、塑化劑、成核劑、阻燃劑、阻燃助劑、潤滑劑、填充劑、鋁碳酸鎂類、金屬皂、抗靜電劑、顏料、染料中之一種以上。 關於上述酚系抗氧化劑，例如可列舉：2,6-二第三丁基對甲酚、2,6-二苯基-4-十八烷氧基苯酚、(3,5-二第三丁基-4-羥基苯基)丙酸硬脂酯、(3,5-二第三丁基-4-羥基苄基)膦酸二硬脂酯、3,5-二第三丁基-4-羥基苄硫基乙酸十三烷基酯、硫代二伸乙基雙[(3,5-二第三丁基-4-羥基苯基)丙酸酯]、4,4'-硫代雙(6-第三丁基間甲酚)、2-辛硫基-4,6-二(3,5-二第三丁基-4-羥基苯氧基)-s-三𠯤、2,2'-亞甲基雙(4-甲基-6-第三丁基苯酚)、雙[3,3-雙(4-羥基-3-第三丁基苯基)酪酸]二醇酯、4,4'-亞丁基雙(4,6-二第三丁基苯酚)、2,2'-亞乙基雙(4,6-二第三丁基苯酚)、1,1,3-三(2-甲基-4-羥基-5-第三丁基苯基)丁烷、雙[2-第三丁基-4-甲基-6-(2-羥基-3-第三丁基-5-甲基苄基)苯基]對苯二甲酸酯、1,3,5-三(2,6-二甲基-3-羥基-4-第三丁基苄基)異氰尿酸酯、1,3,5-三(3,5-二第三丁基-4-羥基苄基)異氰尿酸酯、1,3,5-三(3,5-二第三丁基-4-羥基苄基)-2,4,6-三甲基苯、1,3,5-三[(3,5-二第三丁基-4-羥基苯基)丙醯氧基乙基]異氰尿酸酯、四[亞甲基-3-(3,5-二第三丁基-4-羥基苯基)丙酸酯]甲烷、2-第三丁基-4-甲基-6-(2-丙烯醯氧基-3-第三丁基-5-甲基苄基)苯酚、3,9-雙[2-{3-(3-第三丁基-4-羥基-5-甲基苯基)丙醯氧基}-1,1-二甲基乙基]-2,4,8,10-四氧雜螺[5.5]十一烷、三乙二醇雙[β-(3-第三丁基-4-羥基-5-甲基苯基)丙酸酯]等。該等酚系抗氧化劑可單獨使用一種，亦可將兩種以上併用。本發明之組合物中之酚系抗氧化劑之含量可設為無損本發明之效果之範圍，較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.01質量份以上之量，更佳為成為0.03質量份以上之量，較佳為成為10質量份以下之量，更佳為成為8質量份以下之量，進而較佳為成為1質量份以下之量，尤佳為成為0.8質量份以下之量。本發明之組合物中之酚系抗氧化劑之含量例如較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.01～10質量份之量，更佳為成為0.03～8質量份之量。 關於上述磷系抗氧化劑，例如可列舉：亞磷酸三苯酯、亞磷酸二異辛酯、七(二丙二醇)三亞磷酸酯、亞磷酸三異癸酯、亞磷酸二苯酯異辛酯、亞磷酸二異辛酯苯酯、亞磷酸二苯酯十三烷基酯、亞磷酸三異辛酯、亞磷酸三月桂酯、亞磷酸二苯酯、三(二丙二醇)亞磷酸酯、二異癸基季戊四醇二亞磷酸酯、亞磷酸二油烯基氫酯、三硫代亞磷酸三月桂酯、亞磷酸雙(十三烷基)酯、亞磷酸三(異癸基)酯、亞磷酸三(十三烷基)酯、亞磷酸二苯酯癸酯、亞磷酸二壬基苯酯雙(壬基苯基)酯、聚(二丙二醇)苯基亞磷酸酯、四苯基二丙二醇二亞磷酸酯、亞磷酸三(壬基苯基)酯、亞磷酸三(2,4-二第三丁基苯基)酯、亞磷酸三(2,4-二第三丁基-5-甲基苯基)酯、亞磷酸三[2-第三丁基-4-(3-第三丁基-4-羥基-5-甲基苯硫基)-5-甲基苯基]酯、亞磷酸三癸酯、亞磷酸辛酯二苯酯、亞磷酸二癸酯單苯酯、二硬脂基季戊四醇二亞磷酸酯、二硬脂基季戊四醇與硬脂酸鈣鹽之混合物、烷基(C10)雙酚A亞磷酸酯、二(十三烷基)季戊四醇二亞磷酸酯、二(壬基苯基)季戊四醇二亞磷酸酯、雙(2,4-二第三丁基苯基)季戊四醇二亞磷酸酯、雙(2,6-二第三丁基-4-甲基苯基)季戊四醇二亞磷酸酯、雙(2,4,6-三第三丁基苯基)季戊四醇二亞磷酸酯、雙(2,4-二異丙苯基苯基)季戊四醇二亞磷酸酯、四苯基-四(十三烷基)季戊四醇四亞磷酸酯、亞磷酸雙(2,4-二第三丁基-6-甲基苯基)酯乙酯、四(十三烷基)亞異丙基二苯酚二亞磷酸酯、二亞磷酸四(十三烷基)-4,4'-正亞丁酯雙(2-第三丁基-5-甲基苯酚)酯、六(十三烷基)-1,1,3-三(2-甲基-4-羥基-5-第三丁基苯基)丁烷三亞磷酸酯、二亞磷酸四(2,4-二第三丁基苯基)酯伸聯苯酯、9,10-二氫-9-氧雜-10-磷雜菲-10-氧化物、(1-甲基-1-丙烯基-3-亞基)三(1,1-二甲基乙基)-5-甲基-4,1-伸苯基)六(十三烷基)亞磷酸酯、亞磷酸2,2'-亞甲基雙(4,6-二第三丁基苯基)酯2-乙基己酯、亞磷酸2,2'-亞甲基雙(4,6-二第三丁基苯基)酯十八烷基酯、氟亞磷酸2,2'-亞乙基雙(4,6-二第三丁基苯基)酯、4,4'-亞丁基雙(3-甲基-6-第三丁基苯基二十三烷基)亞磷酸酯、三(2-[(2,4,8,10-四-第三丁基二苯并[d,f][1,3,2]二氧雜磷雜環庚烯-6-基)氧基]乙基)胺、3,9-雙(4-壬基苯氧基)-2,4,8,10-四氧雜-3,9-二磷雜螺[5,5]十一烷、2-丁基-2-乙基-1,3-丙二醇亞磷酸2,4,6-三第三丁基苯酯、聚4,4'-亞異丙基二苯酚C12-15醇亞磷酸酯等。該等磷系抗氧化劑可單獨使用一種，亦可將兩種以上併用。本發明之組合物中之磷系抗氧化劑之含量可設為無損本發明之效果之範圍，較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.01質量份以上之量，更佳為成為0.03質量份以上之量，較佳為成為10質量份以下之量，更佳為成為8質量份以下之量，進而較佳為成為1質量份以下之量，尤佳為成為0.8質量份以下之量。本發明之組合物中之磷系抗氧化劑之含量例如較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.01～10質量份之量，更佳為成為0.03～8質量份之量。 關於上述硫醚系抗氧化劑，例如可列舉：四[亞甲基-3-(月桂基硫基)丙酸酯]甲烷、雙(甲基-4-[3-正烷基(C12/C14)硫代丙醯氧基]5-第三丁基苯基)硫醚、3,3'-硫代二丙酸二(十三烷基)酯、3,3'-硫代二丙酸二月桂酯、3,3'-硫代二丙酸二肉豆蔻酯、3,3'-硫代二丙酸二硬脂酯、硫代二丙酸月桂酯/硬脂酯、4,4'-硫代雙(6-第三丁基-間甲酚)、2,2'-硫代雙(6-第三丁基-對甲酚)、二硬脂基-二硫醚。該等硫醚系抗氧化劑可單獨使用一種，亦可將兩種以上併用。本發明之組合物中之硫醚系抗氧化劑之含量可設為無損本發明之效果之範圍，較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.001質量份以上之量，更佳為成為0.005質量份以上之量，較佳為成為100質量份以下之量，更佳為成為50質量份以下之量，進而較佳為成為10質量份以下之量，尤佳為成為5質量份以下之量。本發明之組合物中之硫醚系抗氧化劑之含量例如較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.001～100質量份之量，更佳為成為0.005～50質量份之量。 關於上述受阻胺系光穩定劑，例如可列舉：硬脂酸2,2,6,6-四甲基-4-哌啶基酯、硬脂酸1,2,2,6,6-五甲基-4-哌啶基酯、苯甲酸2,2,6,6-四甲基-4-哌啶基酯、癸二酸雙(2,2,6,6-四甲基-4-哌啶基)酯、1,2,3,4-丁烷四羧酸四(2,2,6,6-四甲基-4-哌啶基)酯、1,2,3,4-丁烷四羧酸四(1,2,2,6,6-五甲基-4-哌啶基)酯、1,2,3,4-丁烷四羧酸雙(2,2,6,6-四甲基-4-哌啶基)酯二(十三烷基)酯、1,2,3,4-丁烷四羧酸雙(1,2,2,6,6-五甲基-4-哌啶基)酯二(十三烷基)酯、2-丁基-2-(3,5-二第三丁基-4-羥基苄基)丙二酸雙(1,2,2,4,4-五甲基-4-哌啶基)酯、1-(2-羥基乙基)-2,2,6,6-四甲基-4-哌啶醇/丁二酸二乙酯縮聚物、1,6-雙(2,2,6,6-四甲基-4-哌啶基胺基)己烷/2,4-二氯-6-𠰌啉-s-三𠯤縮聚物、1,6-雙(2,2,6,6-四甲基-4-哌啶基胺基)己烷/2,4-二氯-6-第三辛基胺基-均三𠯤縮聚物、1,5,8,12-四[2,4-雙(N-丁基-N-(2,2,6,6-四甲基-4-哌啶基)胺基)-均三𠯤-6-基]-1,5,8,12-四氮十二烷、1,5,8,12-四[2,4-雙(N-丁基-N-(1,2,2,6,6-五甲基-4-哌啶基)胺基)-均三𠯤-6-基]-1,5,8-12-四氮十二烷、1,6,11-三[2,4-雙(N-丁基-N-(2,2,6,6-四甲基-4-哌啶基)胺基)-均三𠯤-6-基]胺基十一烷、1,6,11-三[2,4-雙(N-丁基-N-(1,2,2,6,6-五甲基-4-哌啶基)胺基)-均三𠯤-6-基]胺基十一烷、癸二酸雙{4-(1-辛基氧基-2,2,6,6-四甲基)哌啶基}酯、碳酸雙{4-(2,2,6,6-四甲基-1-十一烷基氧基)哌啶基)酯、Ciba Specialty Chemicals公司製造之TINUVINNOR 371等。該等受阻胺系抗氧化劑可單獨使用一種，亦可將兩種以上併用。該等受阻胺系抗氧化劑之含量可設為無損本發明之效果之範圍，較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.001質量份以上之量，更佳為成為0.005質量份以上之量，較佳為成為100質量份以下之量，更佳為成為10質量份以下之量，進而較佳為成為1質量份以下之量。受阻胺系抗氧化劑之含量例如較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.001～100質量份之量，更佳為成為0.005～10質量份之量。 關於上述紫外線吸收劑，例如可列舉：2,4-二羥基二苯甲酮、5,5'-亞甲基雙(2-羥基-4-甲氧基二苯甲酮)等2-羥基二苯甲酮類；2-(2-羥基-5-甲基苯基)苯并三唑、2-(2-羥基-5-第三辛基苯基)苯并三唑、2-(2-羥基-3,5-二第三丁基苯基)-5-氯苯并三唑、2-(2-羥基-3-第三丁基-5-甲基苯基)-5-氯苯并三唑、2-(2-羥基-3,5-二異丙苯基苯基)苯并三唑、2,2'-亞甲基雙(4-第三辛基-6-苯并三唑基苯酚)、2-(2-羥基-3-第三丁基-5-羧基苯基)苯并三唑之聚乙二醇酯、2-[2-羥基-3-(2-丙烯醯氧基乙基)-5-甲基苯基]苯并三唑、2-[2-羥基-3-(2-甲基丙烯醯氧基乙基)-5-第三丁基苯基]苯并三唑、2-[2-羥基-3-(2-甲基丙烯醯氧基乙基)-5-第三辛基苯基]苯并三唑、2-[2-羥基-3-(2-甲基丙烯醯氧基乙基)-5-第三丁基苯基]-5-氯苯并三唑、2-[2-羥基-5-(2-甲基丙烯醯氧基乙基)苯基]苯并三唑、2-[2-羥基-3-第三丁基-5-(2-甲基丙烯醯氧基乙基)苯基]苯并三唑、2-[2-羥基-3-第三戊基-5-(2-甲基丙烯醯氧基乙基)苯基]苯并三唑、2-[2-羥基-3-第三丁基-5-(3-甲基丙烯醯氧基丙基)苯基]-5-氯苯并三唑、2-[2-羥基-4-(2-甲基丙烯醯氧基甲基)苯基]苯并三唑、2-[2-羥基-4-(3-甲基丙烯醯氧基-2-羥基丙基)苯基]苯并三唑、2-[2-羥基-4-(3-甲基丙烯醯氧基丙基)苯基]苯并三唑等2-(2-羥基苯基)苯并三唑類；水楊酸苯酯、間苯二酚單苯甲酸酯、3,5-二第三丁基-4-羥基苯甲酸2,4-二第三丁基苯酯、(3,5-二第三丁基-4-羥基)苯甲酸辛酯、(3,5-二第三丁基-4-羥基)苯甲酸十二烷基酯、(3,5-二第三丁基-4-羥基)苯甲酸十四烷基酯、(3,5-二第三丁基-4-羥基)苯甲酸十六烷基酯、(3,5-二第三丁基-4-羥基)苯甲酸十八烷基酯、(3,5-二第三丁基-4-羥基)苯甲酸山萮酯等苯甲酸酯類；2-乙基-2'-乙氧基草醯替苯胺、2-乙氧基-4'-十二烷基草醯替苯胺等取代草醯替苯胺類；α-氰基-β,β-二苯基丙烯酸乙酯、2-氰基-3-甲基-3-(對甲氧基苯基)丙烯酸甲酯等氰基丙烯酸酯類；各種金屬鹽、或金屬螯合物、尤其是鎳、鉻之鹽、或螯合物類等。該等紫外線吸收劑可單獨使用一種，亦可將兩種以上併用。本發明之組合物中之紫外線吸收劑之含量可設為無損本發明之效果之範圍，較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.001質量份以上之量，更佳為成為0.005質量份以上之量，較佳為成為100質量份以下之量，更佳為成為10質量份以下之量，進而較佳為成為1質量份以下之量。本發明之組合物中之紫外線吸收劑之含量例如較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.001～100質量份之量，更佳為成為0.005～10質量份之量。 關於上述塑化劑，例如可列舉：鄰苯二甲酸二丁酯、鄰苯二甲酸丁基己酯、鄰苯二甲酸二庚酯、鄰苯二甲酸二(2-乙基己基)酯、鄰苯二甲酸二異壬酯、鄰苯二甲酸二異癸酯、鄰苯二甲酸二月桂酯、鄰苯二甲酸二環己酯、對苯二甲酸二辛酯等苯二甲酸酯系塑化劑；己二酸二辛酯、己二酸二異壬酯、己二酸二異癸酯、二(二乙二醇丁醚)己二酸酯等己二酸酯系塑化劑；磷酸三苯酯、磷酸三甲苯酯、磷酸三(二甲苯)酯、磷酸三(異丙基苯基)酯、磷酸三乙酯、磷酸三丁酯、磷酸三辛酯、磷酸三(丁氧基乙基)酯、磷酸辛酯二苯酯等磷酸酯系塑化劑；使用乙二醇、二乙二醇、三乙二醇、1,3-丁二醇、1,4-丁二醇、1,5-戊二醇、1,6-己二醇、新戊二醇、三羥甲基丙烷等多元醇、與草酸、丙二酸、丁二酸、戊二酸、己二酸、庚二酸、辛二酸、壬二酸、癸二酸、鄰苯二甲酸、間苯二甲酸、對苯二甲酸、肉桂酸等二元酸並視需要將一價之醇、單羧酸(乙酸、芳香族酸等)等用作塞子之本發明以外之聚酯系塑化劑；環氧化大豆油、環氧化亞麻仁油、環氧化桐油、環氧化魚油、環氧化牛脂油、環氧化蓖麻油、環氧化紅花油、環氧化硬脂酸甲酯、環氧化硬脂酸丁酯、環氧化硬脂酸2-乙基己酯、環氧化硬脂酸硬脂酯、環氧化聚丁二烯、異氰尿酸三(環氧基丙基)酯、環氧化妥爾油脂肪酸酯、環氧化亞麻仁油脂肪酸酯、雙酚A二縮水甘油醚、乙烯環己烯二環氧化物、二環己烯二環氧化物、3,4-環氧環己基甲基、環氧環己烷羧酸酯等環氧系塑化劑；另外亦可列舉：四氫鄰苯二甲酸系塑化劑、壬二酸系塑化劑、癸二酸二(2-乙基己基)酯(DOS)、癸二酸二丁酯(DBS)等癸二酸系塑化劑、硬脂酸系塑化劑、檸檬酸系塑化劑、均苯四甲酸系塑化劑、伸聯苯基聚羧酸系塑化劑、多元醇之芳香族酸酯系塑化劑(三羥甲基丙烷之三苯甲酸酯等)等。較佳可列舉：本發明以外之聚酯系塑化劑、鄰苯二甲酸酯系塑化劑、偏苯三酸酯系塑化劑、己二酸酯系塑化劑、癸二酸系塑化劑、環氧系塑化劑。該等塑化劑可單獨使用一種，亦可將兩種以上併用。本發明之組合物中之塑化劑之含量可設為無損本發明之效果之範圍，較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為1質量份以上之量，更佳為成為10質量份以上之量，較佳為成為900質量份以下之量，更佳為成為800質量份以下之量，進而較佳為成為90質量份以下之量，尤佳為成為80質量份以下之量。本發明之組合物中之塑化劑之含量例如較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為1～900質量份之量，更佳為成為10～800質量份之量。 關於上述成核劑，例如作為上述成核劑，例如可列舉：苯甲酸鈉、4-第三丁基苯甲酸鋁鹽、己二酸鈉及雙環[2.2.1]庚烷-2,3-二甲酸二鈉等羧酸金屬鹽、磷酸雙(4-第三丁基苯基)酯鈉、磷酸2,2'-亞甲基雙(4,6-二第三丁基苯基)酯鈉及磷酸2,2'-亞甲基雙(4,6-二第三丁基苯基)酯鋰等磷酸酯金屬鹽、二亞苄基山梨醇、雙(甲基亞苄基)山梨醇、雙(對乙基亞苄基)山梨醇、及雙(二甲基亞苄基)山梨醇等多元醇衍生物、N,N',N"-三[2-甲基環己基]-1,2,3-丙烷三甲醯胺(RIKACLEARPC1)、N,N',N"-三環己基-1,3,5-苯三甲醯胺、N,N'-二環己基-萘二甲醯胺、1,3,5-三(二甲基異丙基胺基)苯等醯胺化合物等。該等成核劑可單獨使用一種，亦可將兩種以上併用。本發明之組合物中之成核劑之含量可設為無損本發明之效果之範圍，較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為1質量份以上之量，更佳為成為10質量份以上之量，較佳為成為900質量份以下之量，更佳為成為800質量份以下之量，進而較佳為成為90質量份以下之量，尤佳為成為80質量份以下之量。本發明之組合物中之成核劑之含量例如較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為1～900質量份之量，更佳為成為10～800質量份之量。 關於上述阻燃劑，例如可列舉：磷酸三苯酯、磷酸三甲苯酯、磷酸三(二甲苯)酯、磷酸甲苯基二苯酯、甲苯基-2,6-二(二甲苯基)磷酸酯、間苯二酚雙(磷酸二苯酯)、(1-甲基亞乙基)-4,1-伸苯基四苯基二磷酸酯、1,3-伸苯基四(2,6-二甲基苯基)磷酸酯、ADEKA股份有限公司製造之商品名「Adekastab FP-500」、「Adekastab FP-600」、「Adekastab FP-800」之芳香族磷酸酯、苯膦酸二乙烯酯、苯膦酸二烯丙酯、苯膦酸(1-丁烯基)酯等膦酸酯、二苯基次膦酸苯酯、二苯基次膦酸甲酯、9,10-二氫-9-氧雜-10-磷雜菲-10-氧化物衍生物等次膦酸酯、雙(2-烯丙基苯氧基)磷腈、二甲苯基磷腈等磷腈化合物、紅磷等磷系阻燃劑、氫氧化鎂、氫氧化鋁等金屬氫氧化物、溴化雙酚A型環氧樹脂、溴化酚系酚醛清漆型環氧樹脂、六溴苯、五溴甲苯、伸乙基雙(五溴苯基)、伸乙基雙四溴鄰苯二甲醯亞胺、1,2-二溴-4-(1,2-二溴乙基)環己烷、四溴環辛烷、六溴環十二烷、雙(三溴苯氧基)乙烷、溴化聚苯醚、溴化聚苯乙烯及2,4,6-三(三溴苯氧基)-1,3,5-三𠯤、三溴苯基順丁烯二醯亞胺、丙烯酸三溴苯酯、甲基丙烯酸三溴苯酯、四溴雙酚A型二甲基丙烯酸酯、丙烯酸五溴苄酯、及溴化苯乙烯等溴系阻燃劑等。該等阻燃劑可單獨使用一種，亦可將兩種以上併用。本發明之組合物中之阻燃劑之含量可設為無損本發明之效果之範圍，較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為1質量份以上之量，更佳為成為3質量份以上之量，較佳為成為900質量份以下之量，更佳為成為800質量份以下之量，進而較佳為成為90質量份以下之量，尤佳為成為80質量份以下之量。本發明之組合物中之阻燃劑之含量例如較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為1～900質量份之量，更佳為成為3～800質量份之量。 關於上述阻燃助劑，作為無機系之阻燃助劑，例如可列舉：氧化鈦、氧化鋁、氧化鎂、鋁碳酸鎂、滑石、蒙脫石等無機化合物、及其表面處理品，例如可列舉：TIPAQUER-680(氧化鈦：石原產業(股)製造)、Kyowamag 150(氧化鎂：協和化學工業(股)製造)、DHT-4A(鋁碳酸鎂：協和化學工業(股)製造)、Alcamizer 4(鋅改性鋁碳酸鎂：協和化學工業(股)製造)等無機系之阻燃助劑。作為有機系之阻燃助劑，例如可列舉：季戊四醇、二季戊四醇等。該等阻燃助劑可單獨使用一種，亦可將兩種以上併用。本發明之組合物中之阻燃助劑之含量可設為無損本發明之效果之範圍，較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.01質量份以上之量，更佳為成為0.1質量份以上之量，較佳為成為200質量份以下之量，更佳為成為100質量份以下之量，進而較佳為成為20質量份以下之量，尤佳為成為10質量份以下之量。本發明之組合物中之阻燃助劑之含量例如較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.01～200質量份之量，更佳為成為0.1～100質量份之量。 關於上述潤滑劑，例如可列舉：油醯胺、芥醯胺等不飽和脂肪醯胺；山萮醯胺、硬脂醯胺等飽和脂肪醯胺、硬脂酸丁酯、硬脂醇、硬脂酸單甘油酯、山梨醇酐單棕櫚酸酯、山梨醇酐單硬脂酸酯、甘露醇、硬脂酸、氫化蓖麻油、硬脂醯胺、油醯胺、伸乙基雙硬脂醯胺等。該等潤滑劑可單獨使用一種，亦可將兩種以上併用。本發明之組合物中之潤滑劑之含量可設為無損本發明之效果之範圍，較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.01質量份以上之量，更佳為成為0.03質量份以上之量，較佳為成為100質量份以下之量，更佳為成為10質量份以下之量，進而較佳為成為1質量份以下之量。本發明之組合物中之潤滑劑之含量例如較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.01～100質量份之量，更佳為成為0.03～10質量份之量。 關於上述填充劑，例如可列舉：滑石、雲母、碳酸鈣、氧化鈣、氫氧化鈣、碳酸鎂、氫氧化鎂、氧化鎂、硫酸鎂、氫氧化鋁、硫酸鋇、玻璃粉末、玻璃纖維、黏土、白雲石、雲母、二氧化矽、氧化鋁、鈦酸鉀晶鬚、矽灰石、纖維狀鹼式硫酸鎂等，可適宜選擇粒徑(在纖維狀之情況下為纖維直徑或纖維長度及縱橫比)而使用。又，填充劑可使用視需要進行表面處理者。該等填充劑可單獨使用一種，亦可將兩種以上併用。本發明之組合物中之填充劑之含量可設為無損本發明之效果之範圍，較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.01質量份以上之量，更佳為成為0.1質量份以上之量，更佳為成為5質量份以上之量，較佳為成為900質量份以下之量，更佳為成為500質量份以下之量，進而較佳為成為400質量份以下之量，進而更佳為成為90質量份以下之量，尤佳為成為50質量份以下之量，最佳為成為40質量份以下之量。本發明之組合物中之填充劑之含量例如較佳為相對於含有本發明之組合物之樹脂組合物中之樹脂100質量份成為0.01～900質量份之量，更佳為成為0.1～500質量份之量，進而較佳為成為5～400質量份之量。上述填充劑中，尤其較佳為含有玻璃纖維。於本發明之組合物含有玻璃纖維之情形時，就加工性之觀點而言，玻璃纖維之含量較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為10～400質量份之量，更佳為成為10～40質量份之量。 上述鋁碳酸鎂類係例如包含作為天然產物或合成產物而為人所知之鎂、鋁、羥基、碳酸基及任意結晶水之複合鹽化合物，可列舉將鎂或鋁之一部分取代為鹼金屬或鋅等其他金屬而成者或將羥基、碳酸基取代為其他陰離子基而成者，具體而言，例如可列舉將下述通式(2)所表示之鋁碳酸鎂之金屬取代為鹼金屬而成者。又，可為使結晶水脫水而成者，亦可為經硬脂酸等高級脂肪酸、油酸鹼金屬鹽等高級脂肪酸金屬鹽、十二烷基苯磺酸鹼金屬鹽等有機磺酸金屬鹽、高級脂肪醯胺、高級脂肪酸酯或蠟等被覆而成者。該等可為天然產物，又亦可為合成品，可不受結晶結構、結晶粒子等限制而使用。該等鋁碳酸鎂類可單獨使用一種，亦可將兩種以上併用。本發明之組合物中之鋁碳酸鎂類之含量可設為無損本發明之效果之範圍，較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.01質量份以上之量，更佳為成為0.1質量份以上之量，更佳為成為5質量份以上之量，較佳為成為900質量份以下之量，更佳為成為500質量份以下之量，進而較佳為成為400質量份以下之量，進而更佳為成為90質量份以下之量，尤佳為成為50質量份以下之量，最佳為成為40質量份以下之量。本發明之組合物中之鋁碳酸鎂類之含量例如較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.01～900質量份之量，更佳為成為0.1～500質量份之量，進而較佳為5～400質量份。 關於上述金屬皂，例如可列舉：鎂、鈣、鋁、鋅等金屬、與月桂酸、肉豆蔻酸、棕櫚酸、硬脂酸、山萮酸、油酸等飽和或不飽和脂肪酸之鹽。該等金屬皂可單獨使用一種，亦可將兩種以上併用。本發明之組合物中之金屬皂之含量可於無損本發明之效果之範圍內進行調配，較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.001質量份以上之量，更佳為成為0.01質量份以上之量，較佳為成為100質量份以下之量，更佳為成為50質量份以下之量，進而較佳為成為10質量份以下之量，進而較佳為成為5質量份以下之量。本發明之組合物中之金屬皂之含量例如較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.001～100質量份之量，更佳為成為0.01～50質量份之量。 關於上述抗靜電劑，例如可列舉：脂肪酸四級銨離子鹽、聚胺四級鹽等陽離子系抗靜電劑；高級醇磷酸酯鹽、高級醇EO加成物、聚乙二醇脂肪酸酯、陰離子型之烷磺酸鹽、高級醇硫酸酯鹽、高級醇環氧乙烷加成物硫酸酯鹽、高級醇環氧乙烷加成物磷酸酯鹽等陰離子系抗靜電劑；多元醇脂肪酸酯、聚二醇磷酸酯、聚氧乙烯烷基烯丙基醚等非離子系抗靜電劑；烷基二甲胺基乙酸甜菜鹼等兩性型烷基甜菜鹼、咪唑啉型兩性活性劑等兩性抗靜電劑。該等抗靜電劑可單獨使用一種，亦可將兩種以上併用。本發明之組合物中之抗靜電劑之含量可設為無損本發明之效果之範圍，較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.01質量份以上之量，更佳為成為0.03質量份以上之量，較佳為成為200質量份以下之量，更佳為成為100質量份以下之量，進而較佳為成為20質量份以下之量，進而較佳為成為10質量份以下之量。本發明之組合物中之抗靜電劑之含量例如較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.01～200質量份之量，更佳為成為0.03～100質量份之量。 關於上述顏料，例如作為顏料，亦可使用市售之顏料，例如可列舉：顏料紅1、2、3、9、10、17、22、23、31、38、41、48、49、88、90、97、112、119、122、123、144、149、166、168、169、170、171、177、179、180、184、185、192、200、202、209、215、216、217、220、223、224、226、227、228、240、254；顏料橙13、31、34、36、38、43、46、48、49、51、52、55、59、60、61、62、64、65、71；顏料黃1、3、12、13、14、16、17、20、24、55、60、73、81、83、86、93、95、97、98、100、109、110、113、114、117、120、125、126、127、129、137、138、139、147、148、150、151、152、153、154、166、168、175、180、185；顏料綠7、10、36；顏料藍15、15：1、15：2、15：3、15：4、15：5、15：6、22、24、56、60、61、62、64；顏料紫1、19、23、27、29、30、32、37、40、50等。該等顏料可單獨使用一種，亦可將兩種以上併用。本發明之組合物中之顏料之含量可設為無損本發明之效果之範圍，較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.001質量份以上之量，更佳為成為0.003質量份以上之量，較佳為成為50質量份以下之量，更佳為成為30質量份以下之量，進而較佳為成為5質量份以下之量，進而較佳為成為3質量份以下之量。本發明之組合物中之顏料之含量例如較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.001～50質量份之量，更佳為成為0.003～30質量份之量。 關於上述染料，例如可列舉：偶氮染料、蒽醌染料、靛屬染料、三芳基甲烷染料、二苯并吡喃染料、茜素染料、吖啶染料、茋染料、噻唑染料、萘酚染料、喹啉染料、硝基染料、吲達胺染料、㗁 𠯤染料、酞菁染料、花青染料等染料等。該等染料可單獨使用一種，亦可將兩種以上併用。本發明之組合物中之顏料之含量可設為無損本發明之效果之範圍，較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.001質量份以上之量，更佳為成為0.003質量份以上之量，較佳為成為50質量份以下之量，更佳為成為30質量份以下之量，進而較佳為成為5質量份以下之量，進而較佳為成為3質量份以下之量。本發明之組合物中之顏料之含量例如較佳為相對於含有本發明之組合物之樹脂組合物中所含之樹脂100質量份成為0.001～50質量份之量，更佳為成為0.003～30質量份之量。 〈樹脂組合物〉 本發明之樹脂組合物係含有樹脂、與上述通式(1)所表示之化合物之樹脂組合物。本發明之樹脂組合物中之上述通式(1)所表示之化合物之含量相對於樹脂100質量份，較佳為0.01質量份以上，更佳為0.05質量份以上，更佳為1質量份以上，較佳為500質量份以下，更佳為450質量份以下，進而較佳為300質量份以下，進而更佳為50質量份以下，尤佳為45質量份以下，最佳為成為30質量份以下之量。本發明之樹脂組合物中之上述通式(1)所表示之化合物之含量例如為相對於樹脂100質量份為0.01～500質量份、較佳為0.05～450質量份、更佳為1～300質量份之範圍。於通式(1)所表示之化合物之調配量少於0.01質量份之情形時，存在添加效果變得不充分之情況，於多於500質量份之情形時，存在有損樹脂之物性之情況。 又，本發明之樹脂組合物係含有樹脂、與本發明之組合物之樹脂組合物。本發明之樹脂組合物中之本發明之組合物之含量相對於樹脂100質量份，較佳為0.01質量份以上，更佳為0.05質量份以上，更佳為1質量份以上，較佳為500質量份以下，更佳為450質量份以下，進而較佳為300質量份以下，進而更佳為50質量份以下，尤佳為45質量份以下，最佳為成為30質量份以下之量。本發明之樹脂組合物中之本發明之組合物之含量例如為相對於樹脂100質量份為0.01～500質量份、較佳為0.05～450質量份、更佳為1～300質量份之範圍。於本發明之組合物之調配量少於0.01質量份之情形時，存在添加效果變得不充分之情況，於多於500質量份之情形時，存在有損樹脂之物性之情況。 作為本發明之樹脂組合物中所使用之樹脂，例如可列舉熱塑性樹脂、熱硬化性樹脂，可較佳地使用熱塑性樹脂。 作為熱塑性樹脂，例如可列舉：聚氯乙烯樹脂、聚乙烯樹脂、聚丙烯樹脂、聚苯乙烯樹脂、聚乙酸乙烯酯樹脂、聚胺酯樹脂、纖維素系樹脂、丙烯酸樹脂、AS(丙烯腈-苯乙烯)樹脂、ABS(丙烯腈-丁二烯-苯乙烯)樹脂、氟系樹脂、熱塑性彈性體、聚醯胺樹脂、聚縮醛樹脂、聚碳酸酯樹脂、改性聚苯醚樹脂、聚酯系樹脂(聚對苯二甲酸乙二酯樹脂、聚對苯二甲酸丁二酯樹脂、聚乳酸系樹脂)、環狀聚烯烴樹脂、聚苯硫醚樹脂等。該等樹脂可單獨使用，亦可組合兩種以上使用。該等樹脂中，較佳為聚酯系樹脂或聚醯胺系樹脂，進而較佳為聚酯系樹脂，尤佳為聚對苯二甲酸丁二酯樹脂。 於本發明之樹脂組合物中，只要無損本發明之效果，則可以任意添加量調配上述其他添加劑(例如酚系抗氧化劑、磷系抗氧化劑、硫醚系抗氧化劑、其他抗氧化劑、受阻胺系光穩定劑、紫外線吸收劑、塑化劑、成核劑、阻燃劑、阻燃助劑、潤滑劑、填充劑、鋁碳酸鎂類、金屬皂、抗靜電劑、顏料、染料等)或其他公知之樹脂添加劑。本發明之樹脂組合物中之其他添加劑之含量如上所述。 本發明之樹脂組合物之特徵在於含有上述通式(1)所表示之化合物或本發明之組合物。將上述通式(1)所表示之化合物或本發明之組合物調配於樹脂中之方法並無特別限制，可採用公知之方法。作為具體之調配方法，可列舉：使用通常之摻合機、攪拌器等進行混合之方法、使用擠出機等進行熔融混練之方法、與溶劑一併混合並進行溶液流延之方法等。 其次，對本發明之成形品進行說明。本發明之成形品係使本發明之樹脂組合物成形而成者。作為使樹脂組合物成形之方法及成形條件，並無特別限制，可採用公知之方法及成形條件。作為具體之成形方法，可列舉擠出成形、射出成形、延伸膜成形、吹塑成形等，可於公知之成形條件下實施該等成形方法。 作為使本發明之樹脂組合物成形而獲得之成形體之形狀，並無特別限定，例如可列舉：片狀、膜狀、特殊形狀者等。 所獲得之成形體之用途並無特別限定，例如可列舉：食品容器、電子零件、汽車零件、醫療賞材料、膜/片材料、纖維素材、光學素材、塗料用樹脂、油墨用樹脂、碳粉用樹脂、接著劑用樹脂等。 [實施例] 以下，根據實施例對本發明進行更詳細說明。但，本發明並不受以下實施例任何限制。 〈實施例1〉 [化合物No.1之合成] 向燒瓶中添加3,9-二丁氧基-2,4,8,10-四氧雜3,9-二磷雜螺[5,5]十一烷54.4 g(0.16 mol)、α,α'-二氯-對二甲苯34.3 g(0.13 mol)、及環丁碸150 ml，於150℃下進行5小時反應。向燒瓶中進而添加苄基氯68.4 g(0.40 mol)，於150℃下進行2小時反應。於反應後將反應液冷卻至室溫。將已冷卻至室溫之反應液移至燒杯中，添加丙酮300 ml進行過濾。將該清洗操作重複三次。將殘渣於減壓烘箱中以150℃乾燥5小時。從而獲得白色粉末。產量為53.59 g(78.2%)。所獲得之化合物之鑑定係藉由1 H-NMR、31 P-NMR(測定裝置：AVANCE III HD NMR Spectrometer，BRUKER(股)製造)而進行。所獲得之化合物No.1之1 H-NMR及31 P-NMR如下所述。化合物No.1為n不同之複數種化合物之混合物，且含有n為5之化合物最多。1 H-NMR (DMSO-d6 , 400 MHz) : δ (ppm) 7.36-7.26 (m, 30H, -ph-, -ph)、4.44-4.13 (m, 48H, -CH2 O-) 3.46-3.51 (d, br, 20H, -CH2 -)31 P-NMR (DMSO-d6 , 162 MHz) : δ (ppm) 22.94 〈比較例1〉 [比較化合物A之合成] 藉由以下所述之方法合成以下所示之比較化合物A。 [化12]向燒瓶中添加3,9-二丁氧基-2,4,8,10-四氧雜3,9-二磷雜螺[5,5]十一烷54.4 g(0.16 mol)、α,α'-二溴-對二甲苯34.3 g(0.13 mol)、及草酸二甲酯150 ml，於150℃下進行5小時反應。於反應後，將反應液冷卻至室溫。向燒瓶中進而添加溴丁烷54.71 g(0.40 mol)，升溫至溴丁烷回流而進行8小時反應。其後，精製係以與化合物No.1之合成中所進行之順序相同之順序進行。產量為39.24(68.2%)。將藉此所獲得之化合物設為比較化合物A。所獲得之化合物之鑑定係藉由1 H-NMR及31 P-NMR(測定裝置：AVANCE III HD NMR Spectrometer，BRUKER(股)製造)而進行。所獲得之比較化合物A之1 H-NMR及31 P-NMR如下所述。比較化合物A為n不同之複數種化合物之混合物，且含有n為5之比較化合物A最多。1 H-NMR (DMSO-d6 , 400 MHz) : δ (ppm) 7.26-7.20 (m, 20H, -ph-), 4.59-3.45 (m, 48H, -CH2 O-) 3.50-3.45 (d, br, 20H, ph-CH2 -), 0.91-0.87 (m, 12H, -CH2 -), 0.92-0.84 (m, 6H, -CH3 )31 P-NMR (DMSO-d6 , 162 MHz) : δ (ppm) 29.84-29.32, 23.30-22.65 [比較例2] [比較化合物B之合成] 藉由以下所述之方式合成以下所示之比較化合物B。 [化13]向燒瓶中添加3,9-二丁氧基-2,4,8,10-四氧雜3,9-二磷雜螺[5,5]十一烷54.3 g(0.16 mol)、1,4-二溴丁烷28.10 g(0.13 mol)、及碳酸乙二酯150 ml，於150℃下進行7小時反應。其後，向燒瓶中添加苄基溴66.71 g(0.39 mol)，於150℃下進行2小時反應。藉由與化合物No.1之合成中所進行之順序相同之順序而進行精製。產量為33.71 g(71.2%)。將藉此所獲得之化合物設為比較化合物B。所獲得之化合物之鑑定係藉由1 H-NMR及31 P-NMR(測定裝置：AVANCE III HD NMR Spectrometer，BRUKER(股)製造)而進行。所獲得之比較化合物B之1 H-NMR及31 P-NMR如下所述。比較化合物B為n不同之複數種化合物之混合物，且含有n為5之比較化合物B最多。1 H-NMR (DMSO-d6 , 400 MHz) : δ (ppm) 7.27-7.18 (m, 10H, ph-), 4.34-4.05 (m, 48H, -CH2 O-) 3.44, 3.39 (d, 10H, ph-CH2 -), 1.35-1.27, 0.82-0.79 (m, 40H, -CH2 -)31 P-NMR (DMSO-d6 , 162 MHz) : δ (ppm) 29.66-28.97, 23.20-22.78 [比較例3] [比較化合物C之合成] 藉由以下所述之方法合成以下所示之比較化合物C。 [化14]向燒瓶中添加3,9-二丁氧基-2,4,8,10-四氧雜3,9-二磷雜螺[5,5]十一烷54.3 g(0.16 mol)、1,4-二溴丁烷28.10 g(0.13 mol)、及碳酸丙二酯150 ml，於150℃下進行7小時反應。向燒瓶中進而添加溴丁烷53.50 g(0.39 mol)，於溴丁烷回流下進行8小時反應。藉由與化合物No.1之合成中所進行之順序相同之順序而進行精製。產量為27.12 g(65.5%)。將藉此所獲得之化合物設為比較化合物C。比較化合物C之鑑定係藉由1 H-NMRo及31 P-NMR(測定裝置：AVANCE III HD NMR Spectrometer，BRUKER(股)製造)而進行。所獲得之比較化合物B之1 H-NMR及31 P-NMR如下所述。比較化合物C為n不同之複數種化合物之混合物，且含有n為5之比較化合物C最多。1 H-NMR (DMSO-d6 , 400 MHz) : δ (ppm) 4.39-4.19 (m, 48H, -CH2 O-), 2.09-1.87, 1.51-1.36 (m, 12H, -CH2 -), 0.91-0.87 (m, 6H, -CH3 )31 P-NMR (DMSO-d6 , 162 MHz) : δ (ppm) 28.97-24.49 [比較例4] [比較化合物D之合成] 藉由以下所述之方法合成以下所示之比較化合物D。 [化15]向燒瓶中添加3,9-二丁氧基-2,4,8,10-四氧雜3,9-二磷雜螺[5,5]十一烷57.34 g(0.16 mol)及苄基溴125.6 g(0.80 mol)，於150℃下進行3小時反應。於反應結束後，於減壓下將苄基溴蒸餾去除。使所獲得之粉末分散於丙酮50 g中，並攪拌30分鐘後，對分散液進行過濾。將該清洗操作重複三次。於減壓下以150℃使之乾燥5小時。產量為55.87 g(80.1%)。將所獲得之化合物設為比較化合物D。比較化合物D之鑑定係藉由1 H-NMR及31 P-NMR(測定裝置：AVANCE III HD NMR Spectrometer，BRUKER(股)製造)而進行。所獲得之比較化合物D之1 H-NMR及31 P-NMR如下所述。1 H-NMR (CDCl3 , 400 MHz) : δ (ppm) 7.35-7.22 (m, 10H, -ph-), 4.15-4.11, 4.05-4.01, 3.74-3.66, 3.51-3.43 (Dd, Dd, Dd, Dd, 8H, -CH2 O-), 3.28, 3.23 (d, 4H, -CH2 -)31 P-NMR (DMSO-d6 , 162 MHz) : δ (ppm) 28.97-24.49 [實施例2～7及比較例5～8] 將下述表1及2所記載之原料以表1及2之調配量(質量%)進行調配而獲得樹脂組合物。使用該樹脂組合物進行阻燃性之評價。將其結果示於表1及表2。又，對實施例1及比較例1～4中所合成之化合物之耐熱性進行評價。將結果示於表3。 [阻燃性(UL-94 V)] 將樹脂組合物於280℃、5～15 MPa之條件下壓製15分鐘，藉此獲得長度127 mm、寬度12.7 mm、厚度1.6 mm之阻燃性試驗評價用試片。將所獲得之試片依據ISO1210並依據20 mm垂直燃燒試驗(UL-94 V)使試片保持垂直，使下端接觸燃燒器之火焰10秒鐘後去除火焰，測定試片所著火之火焰消失之時間。其次，在火焰消失之同時進行第2次之接觸火焰10秒鐘，藉由與第1次相同之方式測定所著火之火焰消失之時間。又，關於試片之下之棉絮是否會因所掉落之火種而著火，亦同時進行測定。基於第1次與第2次之燃燒時間、棉絮著火之有無等並根據UL-94 V標準劃分燃燒等級。燃燒等級係V-0為最高等級者，隨著變成V-1、V-2而阻燃性降低。 [表1] [表2] [耐熱性] 使用熱重量-示差熱分析裝置Thermo plus EVO(RIGAKU股份有限公司製造)，於氮氣200 ml/分鐘之氣流下以升溫速度10℃/分鐘使上述化合物No.1及比較化合物A～D自30℃升溫至450℃，而測定重量減少1%及5%之溫度。 [表3] 自表1及表2可知，含有作為本發明之通式(1)所表示之化合物之化合物No.1的實施例2及7之樹脂組合物與含有比較化合物A～D之比較例5～8之化合物相比具有良好之阻燃性。此表示本發明之通式(1)所表示之化合物可提高樹脂組合物之阻燃性。又，實施例2～4及7之樹脂組合物較實施例5及6之樹脂組合物而言阻燃性得到進一步改善。此表示藉由將化合物No.1與焦磷酸三聚氰胺或聚磷酸三聚氰胺之質量基準之含有比設為特定之比，可進而提高樹脂組合物之阻燃性。又，自表3可知，實施例1中所合成之化合物No.1與比較例1～4中所合成之比較化合物A～D相比具有良好之耐熱性。 [產業上之可利用性] 本發明之化合物之耐熱性優異，藉由少量添加，可大幅度提高樹脂、尤其是聚酯系樹脂之阻燃性。Hereinafter, the present invention will be described in detail based on preferred embodiments of the present invention. <Compound> The compound of the present invention is a compound having a pentaerythritol skeleton represented by the following formula (1). [Chemical 3](where, R1 And R3 Respectively, respectively, an aromatic group having one of the substituents in the presence of a substituent, X1 And X2 Each of which directly represents a direct bond, an alkylene group having 1 to 8 carbon atoms, an oxygen atom, a nitrogen atom or a sulfur atom, and an aerobic carrier exists between any adjacent carbon atoms in the alkylene group having 1 to 8 carbon atoms. The case of an atom, a nitrogen atom or a sulfur atom, R2 Indicates a group represented by the following formula (2), [Chemical 4](wherein m represents an integer of 0 to 4) In the formula (1), R1 And R3 A single aromatic group is independently represented. Examples of the monovalent aromatic group include an aromatic hydrocarbon ring group having 6 to 20 carbon atoms and an aromatic heterocyclic group having 3 to 20 carbon atoms. Examples of the aromatic hydrocarbon ring group having 6 to 20 carbon atoms include a phenyl group, a naphthyl group, a biphenyl group, a terphenyl group, an anthracenyl group, and an anthracenyl group. Examples of the aromatic heterocyclic group having 3 to 20 carbon atoms include a furyl group, a thienyl group, a benzopyranyl group, a benzothienyl group, a bifuranyl group, and a terfuranyl group. A thiophene group, a trithienyl group, a selenophenyl group, a bisenosyl group, and a bisselen phenyl group. Among the above-mentioned monovalent aromatic groups, from the viewpoint of flame retardancy and compatibility with the resin, an aromatic hydrocarbon ring group having 6 to 20 carbon atoms is preferable, and a phenyl group is more preferable. In the case where the hydrogen atom in the monovalent aromatic group is substituted with another group, examples of the substituent include an alkyl group having 1 to 8 carbon atoms and an alkoxy group having 1 to 8 carbon atoms. Examples of the alkyl group having 1 to 8 carbon atoms include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a second butyl group, a third butyl group, an isobutyl group, a pentyl group, and an isopenic group. Base, third amyl, hexyl, 2-hexyl, 3-hexyl, cyclohexyl, 1-methylcyclohexyl, heptyl, 2-heptyl, 3-heptyl, isoheptyl, third heptyl, 1 - octyl, isooctyl and third octyl. R in the general formula (1)1 And / or R3 In the case where it is a phenyl group and the phenyl group is substituted with one of the above alkyl groups, the substitution position of the alkyl group may be any of an ortho, meta or para position, and particularly preferably a para position. R in the general formula (1)1 And / or R3 When it is a phenyl group and the phenyl group is substituted with two of the above alkyl groups, the substitution position of the alkyl group may be either ortho, meta or para, and particularly preferably meta. Examples of the alkoxy group having 1 to 8 carbon atoms include a group having an oxygen atom bonded to the alkyl group having 1 to 8 carbon atoms. R in the general formula (1)1 And / or R3 In the case where it is a phenyl group and the phenyl group is substituted with one alkoxy group as described above, the substitution position of the alkoxy group may be any of an ortho, meta or para position, and particularly preferably a para position. R in the general formula (1)1 And / or R3 In the case where it is a phenyl group and the phenyl group is substituted with two of the above alkoxy groups, the substitution position of the alkoxy group may be any of an ortho, meta or para position, and particularly preferably a meta position. In the general formula (1), X1 And X2 The alkylene group having 1 to 8 carbon atoms represented by the formula is linear or branched. Specific examples of the alkylene group include a methylene group, an ethylidene group, a propyl group, a trimethylene group, a tetramethylene group, a 1,3-butanediyl group, and a 2-methyl-1,3- group. Propylene, 2-methyl-1,3-butanediyl, 2,4-pentanediyl, 1,4-pentanediyl, 3-methyl-1,4-butanediyl, 2-methyl -1,4-pentanediyl, pentamethylene, hexamethylene, heptamethylene and octamethylene. In particular, from the viewpoint of flame retardancy and compatibility with the resin, the alkylene group is preferably an alkylene group having 1 to 6 carbon atoms, more preferably an alkylene group having 1 to 4 carbon atoms. Preferably, it is a methylene group of a C 1 alkyl group. There is a case where an oxygen atom, a nitrogen atom or a sulfur atom is interposed between any adjacent carbon atoms in the above alkylene group. The compound of the present invention has a condition in which an oxygen atom, a nitrogen atom or a sulfur atom is not adjacent, and one or more sites of the alkylene group are selected from an oxygen atom, a nitrogen atom or One or more hetero atoms of a sulfur atom. Among the compounds represented by the formula (1), R is preferred.1 Is phenyl and X1 Methylene, ie, by R1 With X1 The benzyl group is formed. Further, among the compounds represented by the formula (1), R is preferred.3 Is phenyl and X2 Methylene, ie, by R3 With X2 The benzyl group is formed. In the general formula (1), R2 The binary aromatic group represented by the above formula (2) is represented. m in the formula (2) is an integer of 0 to 4, m is preferably an integer of 0 to 2, and m is particularly preferably 0. R2 Although the position of the methylene group represented by the formula (2) is preferably any of an ortho, meta or para position, it is particularly preferably a para position. In the formula (1), n represents a number of from 1 to 20, preferably from 1 to 15, more preferably from 1 to 10, and particularly preferably from 1 to 5 from the viewpoint of compatibility. number. The compound of the present invention may be a case where only n is a single compound, and a mixture of two or more different compounds. The number of n in the case where the compound of the present invention is a mixture is the value of n (the molar number basis) of the compound containing the most in the mixture. The number of n can be measured, for example, by gel permeation chromatography (GPC) or nuclear magnetic resonance analysis (NMR). The compound represented by the above formula (1) can be produced by a method according to a known method for producing pentaerythritol phosphonate. For example, as the starting material, a compound represented by the following formula (a) and a compound represented by the formula (b) are used, and the polymerization is carried out by heating under the same solvent as above. As the solvent, for example, cyclobutyl hydrazine or the like can be used. The suspension of the polymerization may be carried out by adding the compound represented by the formula (c) to the reaction system. [Chemical 5](where, Ra And Rb Each of which independently represents a methyl group having 1 to 4 carbon atoms such as a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a second butyl group, a third butyl group, and an isobutyl group.(in the formula, Ya Indicates a halogen atom such as chlorine or bromine.)(where, Ra Represents the same group as the aromatic group of one of the formula (1), Xa And the same as the alkyl group having 1 to 8 carbon atoms in the formula (1), Yb Examples of the compound of the present invention include the compounds represented by the following Nos. 1 to N0.4, but are not particularly limited thereto, and as long as they are represented by the formula (1), These derivatives can be used. [化8][Chemistry 9][化10][11]The compounds of the invention can be used in a variety of additives. Since the compound of the present invention is excellent in heat resistance and flame retardancy, it can be preferably used as a flame retardant. When the compound of the present invention is used as a flame retardant, one or two or more of the compounds of the present invention may be used alone, and it may be used in the form of a composition containing the compound of the present invention and other components. <Composition> Next, the composition of the present invention will be described. The composition of the present invention contains the compound represented by the above formula (1) of the present invention and a phosphate compound. The composition of the present invention can be preferably used as an additive for imparting flame retardancy to a resin. The composition of the present invention contains one or two or more compounds of the present invention. By using the compound of the present invention in combination with a phosphate compound, it has an excellent effect of flame retardancy. Examples of the phosphate compound used in the composition of the present invention include phosphates such as melamine phosphate and piperidine phosphate; polyphosphates such as ammonium polyphosphate, melamine polyphosphate, and piperidine polyphosphate; melamine orthophosphate; An orthophosphate such as guanidine phosphate; pyrophosphate such as ammonium pyrophosphate, melamine pyrophosphate or piperazine pyrophosphate; calcium phosphate; and magnesium phosphate, and the like. These phosphate compounds may be used alone or in combination of two or more. From the viewpoint of flame retardancy and processability, the phosphate compound used in the composition of the present invention preferably contains pyrophosphate or polyphosphate, and particularly preferably contains pyrophosphate. The content ratio of the compound represented by the above formula (1) to the phosphate compound in the composition of the present invention is preferably the former: the latter is 9:1 to 1:9 by mass ratio, more preferably 3:1. ~1:3, especially best 1:1. As described above, the composition of the present invention can be preferably used as an additive for formulation in a resin. The composition of the present invention may contain other additives in addition to the compound represented by the formula (1) and the phosphate compound. As the above other additives, as long as the effects of the present invention are not impaired, known additives used in the technical field to which the present invention pertains can be used, and known additives can be blended in an arbitrary amount. As other additives, for example, a phenol-based antioxidant, a phosphorus-based antioxidant, a thioether-based antioxidant, other antioxidants, a hindered amine-based light stabilizer, an ultraviolet absorber, a plasticizer, a nucleating agent, and a flame retardant are used. One or more of a flame retardant auxiliary, a lubricant, a filler, an aluminum magnesium carbonate, a metal soap, an antistatic agent, a pigment, and a dye. Examples of the phenolic antioxidant include 2,6-di-t-butyl-p-cresol, 2,6-diphenyl-4-octadecyloxyphenol, and (3,5-di-third-butadiene). Stearyl 4-hydroxyphenyl)propionate, distearyl (3,5-di-t-butyl-4-hydroxybenzyl)phosphonate, 3,5-di-t-butyl-4- Tridecyl hydroxybenzylthioacetate, thiodiethylidene bis[(3,5-di-t-butyl-4-hydroxyphenyl)propionate], 4,4'-thiobis ( 6-t-butyl m-cresol), 2-octylthio-4,6-bis(3,5-di-t-butyl-4-hydroxyphenoxy)-s-triterpene, 2,2' -methylenebis(4-methyl-6-tert-butylphenol), bis[3,3-bis(4-hydroxy-3-t-butylphenyl)butyrate]diol, 4,4 '-Butylene bis(4,6-di-t-butylphenol), 2,2'-ethylenebis(4,6-di-t-butylphenol), 1,1,3-tris(2- Methyl-4-hydroxy-5-t-butylphenyl)butane, bis[2-t-butyl-4-methyl-6-(2-hydroxy-3-t-butyl-5-- Benzyl)phenyl]terephthalate, 1,3,5-tris(2,6-dimethyl-3-hydroxy-4-tributylbenzyl)isocyanurate, 1 , 3,5-tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate, 1,3,5-tris (3,5-di third 4--4-hydroxybenzyl)-2,4,6-trimethylbenzene, 1,3,5-tri[(3,5-di-t-butyl-4-hydroxyphenyl)propoxyl Isocyanurate, tetrakis[methylene-3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate]methane, 2-tert-butyl-4-methyl -6-(2-propenyloxy-3-tert-butyl-5-methylbenzyl)phenol, 3,9-bis[2-{3-(3-tert-butyl-4-hydroxy- 5-methylphenyl)propenyloxy}-1,1-dimethylethyl]-2,4,8,10-tetraoxaspiro[5. 5] undecane, triethylene glycol bis[β-(3-tert-butyl-4-hydroxy-5-methylphenyl)propionate] and the like. These phenolic antioxidants may be used alone or in combination of two or more. The content of the phenolic antioxidant in the composition of the present invention is not limited to the range of the effect of the present invention, and is preferably 0. by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. 01 parts by mass or more, more preferably 0. The amount of 03 parts by mass or more is preferably 10 parts by mass or less, more preferably 8 parts by mass or less, still more preferably 1 part by mass or less, and particularly preferably 0. 8 parts by mass or less. The content of the phenolic antioxidant in the composition of the present invention is preferably, for example, 0 parts by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. 01 to 10 parts by mass, more preferably 0. 03 to 8 parts by mass. Examples of the phosphorus-based antioxidant include triphenyl phosphite, diisooctyl phosphite, hepta-(dipropylene glycol) triphosphite, triisodecyl phosphite, diphenyl phosphite iso-octyl ester, and sub Diisooctyl phosphate phenyl ester, diphenyl tridecyl phosphite, triisooctyl phosphite, trilauryl phosphite, diphenyl phosphite, tris(dipropylene glycol) phosphite, diisoindole Pentaerythritol diphosphite, dioleyl hydrogen phosphite, trilauryl trithiophosphate, bis(tridecyl) phosphite, tris(isodecyl) phosphite, triphosphite Tridecyl)ester, diphenyl decyl phosphite, dinonylphenyl phosphite bis(nonylphenyl) ester, poly(dipropylene glycol) phenyl phosphite, tetraphenyldipropylene glycol diphosphorous acid Ester, tris(nonylphenyl) phosphite, tris(2,4-di-t-butylphenyl) phosphite, tris(2,4-di-tert-butyl-5-methylbenzene) Ester, tris[2-t-butyl-4-(3-tert-butyl-4-hydroxy-5-methylphenylthio)-5-methylphenyl]ester, phosphorous acid tris Anthracene ester, octyl phosphite diphenyl ester, dinonyl phosphite monobenzene , distearyl pentaerythritol diphosphite, a mixture of distearyl pentaerythritol and calcium stearate, alkyl (C10) bisphenol A phosphite, di(tridecyl) pentaerythritol diphosphite, Di(nonylphenyl)pentaerythritol diphosphite, bis(2,4-di-t-butylphenyl)pentaerythritol diphosphite, bis(2,6-di-t-butyl-4-methylbenzene Pentaerythritol diphosphite, bis(2,4,6-tri-t-butylphenyl)pentaerythritol diphosphite, bis(2,4-diisopropylphenylphenyl)pentaerythritol diphosphite, Tetraphenyl-tetrakis(tridecyl)pentaerythritol tetraphosphite, bis(2,4-di-t-butyl-6-methylphenyl)ethyl phosphite, tetrakis(tridecyl) Isopropyldiphenol diphosphite, tetra(tridecyl)-4,4'-n-butylene diphosphite bis(2-tert-butyl-5-methylphenol) ester, six (thirteen) Alkyl)-1,1,3-tris(2-methyl-4-hydroxy-5-t-butylphenyl)butane triphosphite, diphosphoric acid tetrakis(2,4-di-t-butyl) Phenyl) ester extended biphenyl ester, 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, (1-methyl-1-propenyl-3-ylidene) tri 1,1-dimethylethyl)-5- Methyl-4,1-phenylene)hexatridecylphosphite, 2,2'-methylenebis(4,6-di-t-butylphenyl) 2-ethyl phosphite 2-B Hexyl hexyl ester, 2,2'-methylenebis(4,6-di-t-butylphenyl) octadecyl phosphite, 2,2'-ethylene bisphosphonate (4, 6-di-t-butylphenyl)ester, 4,4'-butylidene bis(3-methyl-6-t-butylphenyl-docosyl)phosphite, tris(2-[( 2,4,8,10-tetra-t-butyldibenzo[d,f][1,3,2]dioxaphospholene-6-yl)oxy]ethyl)amine, 3,9-bis(4-mercaptophenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5,5]undecane, 2-butyl-2 2-ethyl-1,3-propanediol phosphorous acid 2,4,6-tri-t-butylphenyl ester, poly-4,4'-isopropylidenediphenol C12-15 alcohol phosphite, and the like. These phosphorus-based antioxidants may be used alone or in combination of two or more. The content of the phosphorus-based antioxidant in the composition of the present invention is not inferior to the effect of the present invention, and is preferably 0. by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. 01 parts by mass or more, more preferably 0. The amount of 03 parts by mass or more is preferably 10 parts by mass or less, more preferably 8 parts by mass or less, still more preferably 1 part by mass or less, and particularly preferably 0. 8 parts by mass or less. The content of the phosphorus-based antioxidant in the composition of the present invention is preferably, for example, 0% by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. 01 to 10 parts by mass, more preferably 0. 03 to 8 parts by mass. Examples of the thioether-based antioxidant include tetrakis[methylene-3-(laurylthio)propionate]methane and bis(methyl-4-[3-n-alkyl (C12/C14)). Thiopropyloxy]5-t-butylphenyl) sulfide, di(tridecyl) 3,3'-thiodipropionate, dilaurate 3,3'-thiodipropionate Ester, 3,3'-thiodipropionic acid dimyristyl ester, 3,3'-thiodipropionate distearyl ester, thiodipropionate lauryl ester / stearyl ester, 4,4'-sulfur Bis(6-tert-butyl-m-cresol), 2,2'-thiobis(6-t-butyl-p-cresol), distearyl-disulfide. These thioether-based antioxidants may be used alone or in combination of two or more. The content of the thioether-based antioxidant in the composition of the present invention can be made not to detract from the effects of the present invention, and is preferably 0% by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. . More than 001 parts by mass, more preferably 0. The amount of 005 parts by mass or more is preferably 100 parts by mass or less, more preferably 50 parts by mass or less, still more preferably 10 parts by mass or less, and particularly preferably 5 parts by mass or less. the amount. The content of the thioether-based antioxidant in the composition of the present invention is preferably, for example, 0 parts by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. 001 to 100 parts by mass, more preferably 0. 005 to 50 parts by mass. Examples of the hindered amine light stabilizer include 2,2,6,6-tetramethyl-4-piperidyl stearate and 1,2,2,6,6-penta-stearic acid. 4-piperidinyl ester, 2,2,6,6-tetramethyl-4-piperidyl benzoate, bis(2,2,6,6-tetramethyl-4-piperidinate Pyridyl)ester, 1,2,3,4-butanetetracarboxylic acid tetrakis(2,2,6,6-tetramethyl-4-piperidyl) ester, 1,2,3,4-butane Tetrakis(1,2,2,6,6-pentamethyl-4-piperidinyl) tetracarboxylate, 1,2,3,4-butanetetracarboxylic acid bis(2,2,6,6- Tetramethyltrifluoro-4-piperidinyl)di(tridecyl)ester, 1,2,3,4-butanetetracarboxylic acid bis(1,2,2,6,6-pentamethyl-4 -piperidinyl) ester di(tridecyl)ester, 2-butyl-2-(3,5-di-t-butyl-4-hydroxybenzyl)malonic acid bis(1,2,2, 4,4-pentamethyl-4-piperidinyl), 1-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-piperidinol/diethyl succinate Polycondensate, 1,6-bis(2,2,6,6-tetramethyl-4-piperidinyl)hexane/2,4-dichloro-6-carboline-s-triter polycondensate 1,6-bis(2,2,6,6-tetramethyl-4-piperidinylamino)hexane/2,4-dichloro-6-th-octylamino-s-triterpene polycondensation 1,5,8,12-tetra[2,4-bis(N-butyl-N-(2,2,6,6-tetramethyl-4-piperidyl)amino)-- 𠯤-6-基]- 1,5,8,12-tetraazadecane, 1,5,8,12-tetra[2,4-bis(N-butyl-N-(1,2,2,6,6-penta 4-piperidinyl)amino)-s-tris-6-yl]-1,5,8-12-tetraazadecane, 1,6,11-tri[2,4-bis(N -butyl-N-(2,2,6,6-tetramethyl-4-piperidinyl)amino)-histylene-6-yl]aminoundecane, 1,6,11-three [2,4-bis(N-butyl-N-(1,2,2,6,6-pentamethyl-4-piperidinyl)amino)-s-tris--6-yl]amino-10 Mono-{4-(1-octyloxy-2,2,6,6-tetramethyl)piperidinyl ester of alkane, sebacic acid, double {4-(2,2,6,6- Tetramethyl-1-undecyloxy)piperidinyl), TINUVINNOR 371 manufactured by Ciba Specialty Chemicals, and the like. These hindered amine-based antioxidants may be used alone or in combination of two or more. The content of the hindered amine-based antioxidant may be such that it does not detract from the effects of the present invention, and is preferably 0. by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. More than 001 parts by mass, more preferably 0. The amount of 005 parts by mass or more is preferably 100 parts by mass or less, more preferably 10 parts by mass or less, and still more preferably 1 part by mass or less. The content of the hindered amine-based antioxidant is, for example, preferably 0. by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. 001 to 100 parts by mass, more preferably 0. 005 to 10 parts by mass. Examples of the ultraviolet absorber include 2-hydroxyl 2 such as 2,4-dihydroxybenzophenone and 5,5'-methylenebis(2-hydroxy-4-methoxybenzophenone). Benzophenones; 2-(2-hydroxy-5-methylphenyl)benzotriazole, 2-(2-hydroxy-5-th-octylphenyl)benzotriazole, 2-(2- Hydroxy-3,5-di-t-butylphenyl)-5-chlorobenzotriazole, 2-(2-hydroxy-3-t-butyl-5-methylphenyl)-5-chlorobenzo Triazole, 2-(2-hydroxy-3,5-diisopropylphenylphenyl)benzotriazole, 2,2'-methylenebis(4-th-octyl-6-benzotriazole Polyphenolate of 2-(2-hydroxy-3-t-butyl-5-carboxyphenyl)benzotriazole, 2-[2-hydroxy-3-(2-propene oxime) Benzyl)-5-methylphenyl]benzotriazole, 2-[2-hydroxy-3-(2-methylpropenyloxyethyl)-5-tert-butylphenyl]benzo Triazole, 2-[2-hydroxy-3-(2-methylpropenyloxyethyl)-5-th-octylphenyl]benzotriazole, 2-[2-hydroxy-3-(2) -Methethyloxyethyl)-5-tert-butylphenyl]-5-chlorobenzotriazole, 2-[2-hydroxy-5-(2-methylpropenyloxyethyl) Phenyl]benzotriazole, 2-[2-hydroxy-3-t-butyl-5-(2-methylpropene oxime) Ethyl)phenyl]benzotriazole, 2-[2-hydroxy-3-tripentyl-5-(2-methylpropenyloxyethyl)phenyl]benzotriazole, 2-[ 2-hydroxy-3-t-butyl-5-(3-methylpropenyloxypropyl)phenyl]-5-chlorobenzotriazole, 2-[2-hydroxy-4-(2-methyl) Acryloxymethyl)phenyl]benzotriazole, 2-[2-hydroxy-4-(3-methylpropenyloxy-2-hydroxypropyl)phenyl]benzotriazole, 2 2-(2-hydroxyphenyl)benzotriazoles such as [2-hydroxy-4-(3-methylpropenyloxypropyl)phenyl]benzotriazole; phenyl salicylate, Hydroquinone monobenzoate, 2,4-di-t-butylphenyl 3,5-di-t-butyl-4-hydroxybenzoate, (3,5-di-t-butyl-4-hydroxyl) Octyl benzoate, lauryl (3,5-di-t-butyl-4-hydroxy)benzoate, tetradecyl (3,5-di-t-butyl-4-hydroxy)benzoate Ester, cetyl (3,5-di-t-butyl-4-hydroxy)benzoate, octadecyl (3,5-di-t-butyl-4-hydroxy)benzoate, (3 Benzoate such as 5-tert-butyl-4-hydroxy)benzoic acid behenate; 2-ethyl-2'-ethoxyxantanilide, 2-ethoxy-4'-ten Substituted grasses such as dialkyl oxalic acid Benzene amines; cyanoacrylates such as α-cyano-β, β-diphenylacrylate, methyl 2-cyano-3-methyl-3-(p-methoxyphenyl)acrylate; Various metal salts, or metal chelates, especially nickel, chromium salts, or chelate compounds. These ultraviolet absorbers may be used alone or in combination of two or more. The content of the ultraviolet absorber in the composition of the present invention may be set to a range not detrimental to the effects of the present invention, and is preferably 0. by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. More than 001 parts by mass, more preferably 0. The amount of 005 parts by mass or more is preferably 100 parts by mass or less, more preferably 10 parts by mass or less, and still more preferably 1 part by mass or less. The content of the ultraviolet absorber in the composition of the present invention is, for example, preferably 0. by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. 001 to 100 parts by mass, more preferably 0. 005 to 10 parts by mass. Examples of the plasticizer include dibutyl phthalate, butylhexyl phthalate, diheptyl phthalate, di(2-ethylhexyl) phthalate, and o. Phthalate esterification of diisodecyl phthalate, diisononyl phthalate, dilauryl phthalate, dicyclohexyl phthalate, dioctyl terephthalate Agent; dioctyl adipate, diisononyl adipate, diisononyl adipate, di(diethylene glycol butyl ether) adipate and other adipate plasticizers; Phenyl ester, tricresyl phosphate, tris(xylylene) phosphate, tris(isopropylphenyl) phosphate, triethyl phosphate, tributyl phosphate, trioctyl phosphate, tris(butoxyethyl) phosphate a phosphate ester plasticizer such as ester or octyl diphenyl phosphate; using ethylene glycol, diethylene glycol, triethylene glycol, 1,3-butylene glycol, 1,4-butanediol, 1, Polyols such as 5-pentanediol, 1,6-hexanediol, neopentyl glycol, trimethylolpropane, and oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, and pimelic acid , suberic acid, azelaic acid, azelaic acid, phthalic acid, isophthalic acid a dibasic acid such as dicarboxylic acid, terephthalic acid or cinnamic acid, and a polyester-based plasticizer other than the present invention which uses a monovalent alcohol, a monocarboxylic acid (acetic acid, an aromatic acid, etc.) or the like as a stopper; Epoxidized soybean oil, epoxidized linseed oil, epoxidized tung oil, epoxidized fish oil, epoxidized tallow oil, epoxidized castor oil, epoxidized safflower oil, epoxidized methyl stearate, epoxidized butyl stearate, Ethyl 2-ethylhexyl stearate, stearyl stearate, epoxidized polybutadiene, tris(epoxypropyl) isocyanurate, epoxidized tall oil fatty acid ester, Epoxidized linseed oil fatty acid ester, bisphenol A diglycidyl ether, ethylene cyclohexene diepoxide, dicyclohexene diepoxide, 3,4-epoxycyclohexylmethyl, epoxy ring An epoxy-based plasticizer such as an alkanoic acid ester; a tetrahydrophthalic acid-based plasticizer, a sebacic acid plasticizer, and di(2-ethylhexyl) sebacate (DOS) ), adipic acid plasticizer such as dibutyl sebacate (DBS), stearic acid plasticizer, citric acid plasticizer, pyromellitic acid plasticizer, and extended biphenyl polycarboxylate An acid-based plasticizer, an aromatic acid ester-based plasticizer of a polyhydric alcohol (such as a trimethylolpropane tribenzoate), or the like. Preferably, a polyester-based plasticizer, a phthalate-based plasticizer, a trimellitate-based plasticizer, an adipate-based plasticizer, and a sebacic acid system other than the present invention are mentioned. Plasticizer, epoxy plasticizer. These plasticizers may be used alone or in combination of two or more. The content of the plasticizer in the composition of the present invention can be made not to detract from the effects of the present invention, and is preferably 1 part by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. The amount is more preferably 10 parts by mass or more, more preferably 900 parts by mass or less, still more preferably 800 parts by mass or less, and still more preferably 90 parts by mass or less. The amount is preferably 80 parts by mass or less. The content of the plasticizer in the composition of the present invention is, for example, preferably from 1 to 900 parts by mass, more preferably 10%, based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. ～800 parts by mass. Examples of the nucleating agent include, for example, sodium benzoate, aluminum 4-tert-butylbenzoate, sodium adipate, and bicyclo [2. 2. 1] metal carboxylate such as heptane-2,3-dicarboxylic acid disodium, sodium bis(4-tert-butylphenyl) phosphate, 2,2'-methylene double (4,6-di Phosphate metal salt such as sodium t-butylphenyl) ester and lithium 2,2'-methylenebis(4,6-di-t-butylphenyl) phosphate, dibenzylidene sorbitol, bis ( Methylbenzylidene) sorbitol, bis(p-ethylbenzylidene) sorbitol, and polyol derivatives such as bis(dimethylbenzylidene) sorbitol, N, N', N"-three [2 -Methylcyclohexyl]-1,2,3-propane trimethyl decylamine (RIKACLEARPC1), N, N', N"-tricyclohexyl-1,3,5-benzenetridecylamine, N, N'-di A decylamine compound such as cyclohexyl-naphthyldimethylamine or 1,3,5-tris(dimethylisopropylamino)benzene. These nucleating agents may be used alone or in combination of two or more. The content of the nucleating agent in the composition of the present invention can be made not to detract from the effects of the present invention, and is preferably 1 part by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. The amount is more preferably 10 parts by mass or more, more preferably 900 parts by mass or less, still more preferably 800 parts by mass or less, and still more preferably 90 parts by mass or less. The amount is preferably 80 parts by mass or less. The content of the nucleating agent in the composition of the present invention is, for example, preferably from 1 to 900 parts by mass, more preferably 10%, based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. ～800 parts by mass. Examples of the flame retardant include triphenyl phosphate, tricresyl phosphate, tris(xylylene) phosphate, tolyldiphenyl phosphate, and tolyl-2,6-di(xylyl) phosphate. , resorcinol bis(diphenyl phosphate), (1-methylethylidene)-4,1-phenylene tetraphenyl diphosphate, 1,3-phenylene tetra(2,6- Dimethylphenyl)phosphate, the brand name "Adekastab FP-500" manufactured by ADEKA Co., Ltd., "Adekastab FP-600", "Adekastab FP-800" aromatic phosphate, phenylphosphonic acid divinyl ester, Phosphonates such as diallyl phenylphosphonate, (1-butenyl) phenylphosphonate, phenyl diphenylphosphinate, methyl diphenylphosphinate, 9,10-dihydro-9 a phosphinic acid compound such as a phosphinic acid ester such as oxa-10-phosphaphenanthrene-10-oxide derivative, a phosphazene compound such as bis(2-allylphenoxy)phosphazene or xylylphosphazene, or a phosphorus such as red phosphorus. Flame retardant, metal hydroxide such as magnesium hydroxide or aluminum hydroxide, brominated bisphenol A epoxy resin, brominated phenol novolak epoxy resin, hexabromobenzene, pentabromotoluene, and ethyl Bis(pentabromophenyl), ethylidene bis-tetrabromophthalimide, 1,2-di -4-(1,2-dibromoethyl)cyclohexane, tetrabromocyclooctane, hexabromocyclododecane, bis(tribromophenoxy)ethane, brominated polyphenylene ether, brominated poly Styrene and 2,4,6-tris(tribromophenoxy)-1,3,5-triazine, tribromophenylbutyleneimide, tribromophenyl acrylate, tribromo methacrylate Brominated flame retardants such as phenyl ester, tetrabromobisphenol A type dimethacrylate, pentabromobenzyl acrylate, and brominated styrene. These flame retardants may be used alone or in combination of two or more. The content of the flame retardant in the composition of the present invention can be set to be in the range of the effect of the present invention, and is preferably 1 part by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. The amount is more preferably 3 parts by mass or more, more preferably 900 parts by mass or less, still more preferably 800 parts by mass or less, and still more preferably 90 parts by mass or less. The amount is preferably 80 parts by mass or less. The content of the flame retardant in the composition of the present invention is, for example, preferably from 1 to 900 parts by mass, more preferably from 3 parts by mass to 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. ～800 parts by mass. Examples of the flame retardant auxiliary agent include inorganic compounds such as titanium oxide, aluminum oxide, magnesium oxide, aluminum magnesium carbonate, talc, and montmorillonite, and surface-treated products thereof. List: TIPAQUER-680 (titanium oxide: manufactured by Ishihara Sangyo Co., Ltd.), Kyowamag 150 (magnesium oxide: manufactured by Kyowa Chemical Industry Co., Ltd.), DHT-4A (magnesium aluminum carbonate: manufactured by Kyowa Chemical Industry Co., Ltd.), Alcamizer 4 (Zinc-modified aluminum magnesium carbonate: manufactured by Xiehe Chemical Industry Co., Ltd.) and other inorganic flame retardant additives. Examples of the organic flame retardant auxiliary agent include pentaerythritol and dipentaerythritol. These flame retardant additives may be used alone or in combination of two or more. The content of the flame retardant auxiliary in the composition of the present invention may be set to be in the range of the effect of the present invention, and is preferably 0. by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. 01 parts by mass or more, more preferably 0. The amount of 1 part by mass or more is preferably 200 parts by mass or less, more preferably 100 parts by mass or less, still more preferably 20 parts by mass or less, and particularly preferably 10 parts by mass or less. the amount. The content of the flame retardant auxiliary in the composition of the present invention is, for example, preferably 0. by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. 01 to 200 parts by mass, more preferably 0. The amount is from 1 to 100 parts by mass. Examples of the lubricant include unsaturated fatty amines such as ceramide and mesaconamine; saturated fatty amides such as behenamide and stearylamine; butyl stearate, stearyl alcohol, and stearic acid; Acid monoglyceride, sorbitan monopalmitate, sorbitan monostearate, mannitol, stearic acid, hydrogenated castor oil, stearylamine, ceramide, ethyl bis-stearylamine Wait. These lubricants may be used alone or in combination of two or more. The content of the lubricant in the composition of the present invention can be set to be in the range of the effect of the present invention, and is preferably 0. by mass of the resin contained in the resin composition containing the composition of the present invention. 01 parts by mass or more, more preferably 0. The amount of the above-mentioned parts by mass is preferably 100 parts by mass or less, more preferably 10 parts by mass or less, and still more preferably 1 part by mass or less. The content of the lubricant in the composition of the present invention is preferably, for example, 0 parts by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. 01 to 100 parts by mass, more preferably 0. 03 to 10 parts by mass. Examples of the above fillers include talc, mica, calcium carbonate, calcium oxide, calcium hydroxide, magnesium carbonate, magnesium hydroxide, magnesium oxide, magnesium sulfate, aluminum hydroxide, barium sulfate, glass powder, glass fiber, and clay. , dolomite, mica, cerium oxide, aluminum oxide, potassium titanate whisker, strontium ash, fibrous basic magnesium sulphate, etc., may be suitably selected particle size (in the case of fiber, fiber diameter or fiber length and Use in aspect ratio). Further, the filler can be used if necessary for surface treatment. These fillers may be used alone or in combination of two or more. The content of the filler in the composition of the present invention can be set to be in the range which does not impair the effects of the present invention, and is preferably 0% by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. 01 parts by mass or more, more preferably 0. The amount of 1 part by mass or more is more preferably 5 parts by mass or more, more preferably 900 parts by mass or less, still more preferably 500 parts by mass or less, and still more preferably 400 parts by mass or less. The amount is more preferably 90 parts by mass or less, more preferably 50 parts by mass or less, and most preferably 40 parts by mass or less. The content of the filler in the composition of the present invention is preferably, for example, 0% by mass based on 100 parts by mass of the resin in the resin composition containing the composition of the present invention. 01 to 900 parts by mass, more preferably 0. The amount is preferably from 1 to 500 parts by mass, more preferably from 5 to 400 parts by mass. Among the above fillers, it is particularly preferred to contain glass fibers. In the case where the composition of the present invention contains glass fibers, the content of the glass fibers is preferably 10 parts by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. The amount of -400 parts by mass is more preferably 10 to 40 parts by mass. The aluminum magnesium carbonate type includes, for example, a composite salt compound of magnesium, aluminum, a hydroxyl group, a carbonate group, and any water of crystallization which is known as a natural product or a synthetic product, and a part of magnesium or aluminum is substituted with an alkali metal or In the case where the other metal such as zinc is used, or the hydroxy group or the carbonic acid group is substituted with another anionic group, for example, a metal of aluminum magnesium carbonate represented by the following formula (2) is substituted with an alkali metal. Adult. Further, in order to dehydrate the crystal water, an organic sulfonic acid metal salt such as a higher fatty acid such as stearic acid or a higher fatty acid metal salt such as an alkali metal oleate or an alkali metal salt of dodecylbenzenesulfonate may be used. It is made up of high-fat decylamine, higher fatty acid esters or waxes. These may be natural products or synthetic products, and may be used without being restricted by crystal structures, crystal particles, and the like. These aluminum magnesium carbonates may be used alone or in combination of two or more. The content of the aluminum magnesium carbonate in the composition of the present invention can be set to a range not detrimental to the effects of the present invention, and is preferably 0 parts by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. 01 parts by mass or more, more preferably 0. The amount of 1 part by mass or more is more preferably 5 parts by mass or more, more preferably 900 parts by mass or less, still more preferably 500 parts by mass or less, and still more preferably 400 parts by mass or less. The amount is more preferably 90 parts by mass or less, more preferably 50 parts by mass or less, and most preferably 40 parts by mass or less. The content of the aluminum magnesium carbonate in the composition of the present invention is preferably, for example, 0 parts by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. 01 to 900 parts by mass, more preferably 0. The amount is from 1 to 500 parts by mass, more preferably from 5 to 400 parts by mass. Examples of the metal soap include a metal such as magnesium, calcium, aluminum or zinc, and a salt of a saturated or unsaturated fatty acid such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid or oleic acid. These metal soaps may be used alone or in combination of two or more. The content of the metal soap in the composition of the present invention can be adjusted within the range which does not impair the effects of the present invention, and is preferably 0. by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. More than 001 parts by mass, more preferably 0. The amount of the first part by mass or more is preferably 100 parts by mass or less, more preferably 50 parts by mass or less, more preferably 10 parts by mass or less, and still more preferably 5 parts by mass or less. The amount. The content of the metal soap in the composition of the present invention is preferably, for example, 0 parts by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. 001 to 100 parts by mass, more preferably 0. 01 to 50 parts by mass. Examples of the antistatic agent include cationic antistatic agents such as fatty acid quaternary ammonium ion salts and polyamine quaternary salts; higher alcohol phosphate salts, higher alcohol EO adducts, and polyethylene glycol fatty acid esters. Anionic antistatic agent such as anionic alkane sulfonate, higher alcohol sulphate, higher alcohol ethylene oxide adduct sulfate, higher alcohol ethylene oxide adduct phosphate; polyol fatty acid Nonionic antistatic agents such as esters, polyglycol phosphates, polyoxyethylene alkyl allyl ethers, etc.; amphoteric alkylbetaines such as alkyldimethylaminoacetic acid betaine, imidazoline type amphoteric active agents, etc. Antistatic agent. These antistatic agents may be used alone or in combination of two or more. The content of the antistatic agent in the composition of the present invention is not limited to the range of the effect of the present invention, and is preferably 0. by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. 01 parts by mass or more, more preferably 0. The amount is preferably 200 parts by mass or less, more preferably 100 parts by mass or less, more preferably 20 parts by mass or less, and still more preferably 10 parts by mass or less. The amount. The content of the antistatic agent in the composition of the present invention is preferably, for example, 0 parts by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. 01 to 200 parts by mass, more preferably 0. 03 to 100 parts by mass. As the pigment, for example, a commercially available pigment can be used as the pigment, and for example, pigment red 1, 2, 3, 9, 10, 17, 22, 23, 31, 38, 41, 48, 49, 88, 90, 97, 112, 119, 122, 123, 144, 149, 166, 168, 169, 170, 171, 177, 179, 180, 184, 185, 192, 200, 202, 209, 215, 216, 217, 220, 223, 224, 226, 227, 228, 240, 254; Pigment Orange 13, 31, 34, 36, 38, 43, 46, 48, 49, 51, 52, 55, 59, 60, 61, 62, 64, 65, 71; pigment yellow 1, 3, 12, 13, 14, 16, 17, 20, 24, 55, 60, 73, 81, 83, 86, 93, 95, 97, 98, 100, 109, 110, 113, 114, 117, 120, 125, 126, 127, 129, 137, 138, 139, 147, 148, 150, 151, 152, 153, 154, 166, 168, 175, 180, 185; pigment green 7, 10, 36; Pigment Blue 15, 15:1, 15:2, 15:3, 15:4, 15:5, 15:6, 22, 24, 56, 60, 61, 62, 64; Pigment Violet 1, 19, 23, 27, 29, 30, 32, 37, 40, 50, etc. These pigments may be used alone or in combination of two or more. The content of the pigment in the composition of the present invention may be set to be in the range of the effect of the present invention, and is preferably 0. by mass of the resin contained in the resin composition containing the composition of the present invention. More than 001 parts by mass, more preferably 0. The amount of 003 parts by mass or more is preferably 50 parts by mass or less, more preferably 30 parts by mass or less, more preferably 5 parts by mass or less, and still more preferably 3 parts by mass or less. The amount. The content of the pigment in the composition of the present invention is preferably, for example, 0 parts by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. 001 to 50 parts by mass, more preferably 0. 003 to 30 parts by mass. Examples of the dyes include azo dyes, anthraquinone dyes, anthraquinone dyes, triarylmethane dyes, dibenzopyran dyes, alizarin dyes, acridine dyes, anthraquinone dyes, thiazole dyes, naphthol dyes, and the like. Quinoline dyes, nitro dyes, indamine dyes, anthraquinone dyes, phthalocyanine dyes, cyanine dyes, and the like. These dyes may be used alone or in combination of two or more. The content of the pigment in the composition of the present invention may be set to be in the range of the effect of the present invention, and is preferably 0. by mass of the resin contained in the resin composition containing the composition of the present invention. More than 001 parts by mass, more preferably 0. The amount of 003 parts by mass or more is preferably 50 parts by mass or less, more preferably 30 parts by mass or less, more preferably 5 parts by mass or less, and still more preferably 3 parts by mass or less. The amount. The content of the pigment in the composition of the present invention is preferably, for example, 0 parts by mass based on 100 parts by mass of the resin contained in the resin composition containing the composition of the present invention. 001 to 50 parts by mass, more preferably 0. 003 to 30 parts by mass. <Resin Composition> The resin composition of the present invention contains a resin composition of a resin and a compound represented by the above formula (1). The content of the compound represented by the above formula (1) in the resin composition of the present invention is preferably 0. by mass based on 100 parts by mass of the resin. 01 parts by mass or more, more preferably 0. 50 parts by mass or more, more preferably 1 part by mass or more, more preferably 500 parts by mass or less, still more preferably 450 parts by mass or less, still more preferably 300 parts by mass or less, still more preferably 50 parts by mass or less, and particularly preferably 45 parts by mass or less is preferably an amount of 30 parts by mass or less. The content of the compound represented by the above formula (1) in the resin composition of the present invention is, for example, 0% by mass based on 100 parts by mass of the resin. 01 to 500 parts by mass, preferably 0. It is in the range of 05 to 450 parts by mass, more preferably 1 to 300 parts by mass. The compound represented by the formula (1) is less than 0. In the case of 01 parts by mass, the effect of addition may be insufficient, and in the case of more than 500 parts by mass, the physical properties of the resin may be impaired. Further, the resin composition of the present invention contains a resin composition and a resin composition of the composition of the present invention. The content of the composition of the present invention in the resin composition of the present invention is preferably 0. by mass based on 100 parts by mass of the resin. 01 parts by mass or more, more preferably 0. 50 parts by mass or more, more preferably 1 part by mass or more, more preferably 500 parts by mass or less, still more preferably 450 parts by mass or less, still more preferably 300 parts by mass or less, still more preferably 50 parts by mass or less, and particularly preferably 45 parts by mass or less is preferably an amount of 30 parts by mass or less. The content of the composition of the present invention in the resin composition of the present invention is, for example, 0% by mass based on 100 parts by mass of the resin. 01 to 500 parts by mass, preferably 0. It is in the range of 05 to 450 parts by mass, more preferably 1 to 300 parts by mass. The composition of the composition of the invention is less than 0. In the case of 01 parts by mass, the effect of addition may be insufficient, and in the case of more than 500 parts by mass, the physical properties of the resin may be impaired. The resin to be used in the resin composition of the present invention may, for example, be a thermoplastic resin or a thermosetting resin, and a thermoplastic resin can be preferably used. Examples of the thermoplastic resin include polyvinyl chloride resin, polyethylene resin, polypropylene resin, polystyrene resin, polyvinyl acetate resin, polyurethane resin, cellulose resin, acrylic resin, and AS (acrylonitrile-styrene). Resin, ABS (acrylonitrile-butadiene-styrene) resin, fluorine resin, thermoplastic elastomer, polyamide resin, polyacetal resin, polycarbonate resin, modified polyphenylene ether resin, polyester system Resin (polyethylene terephthalate resin, polybutylene terephthalate resin, polylactic acid resin), cyclic polyolefin resin, polyphenylene sulfide resin, and the like. These resins may be used singly or in combination of two or more. Among these resins, a polyester resin or a polyamide resin is preferable, and a polyester resin is preferable, and a polybutylene terephthalate resin is preferable. In the resin composition of the present invention, as long as the effects of the present invention are not impaired, the above other additives may be blended in an optional amount (for example, a phenolic antioxidant, a phosphorus antioxidant, a thioether antioxidant, another antioxidant, or a hindered amine system). Light stabilizer, UV absorber, plasticizer, nucleating agent, flame retardant, flame retardant, lubricant, filler, aluminum magnesium carbonate, metal soap, antistatic agent, pigment, dye, etc.) or other A known resin additive. The content of the other additives in the resin composition of the present invention is as described above. The resin composition of the present invention is characterized by containing the compound represented by the above formula (1) or the composition of the present invention. The method of formulating the compound represented by the above formula (1) or the composition of the present invention in the resin is not particularly limited, and a known method can be employed. Specific examples of the preparation method include a method of mixing by a usual blender or a stirrer, a method of performing melt-kneading using an extruder or the like, a method of mixing with a solvent, and a solution casting. Next, the molded article of the present invention will be described. The molded article of the present invention is obtained by molding the resin composition of the present invention. The method and molding conditions for molding the resin composition are not particularly limited, and known methods and molding conditions can be employed. Specific examples of the molding method include extrusion molding, injection molding, stretch film molding, and blow molding, and the molding methods can be carried out under known molding conditions. The shape of the molded body obtained by molding the resin composition of the present invention is not particularly limited, and examples thereof include a sheet shape, a film shape, and a special shape. The use of the obtained molded body is not particularly limited, and examples thereof include food containers, electronic parts, automobile parts, medical materials, film/sheet materials, fiber materials, optical materials, paint resins, ink resins, and toners. A resin or a resin for an adhesive is used. [Examples] Hereinafter, the present invention will be described in more detail based on examples. However, the present invention is not limited by the following examples. <Example 1> [Compound No. Synthesis of 1] Add 3,9-dibutoxy-2,4,8,10-tetraoxa 3,9-diphosphaspiro[5,5]undecane 54 to the flask. 4 g (0. 16 mol), α, α'-dichloro-p-xylene 34. 3 g (0. 13 mol) and cyclohexane oxime 150 ml were reacted at 150 ° C for 5 hours. Further adding benzyl chloride 68 to the flask. 4 g (0. 40 mol), the reaction was carried out at 150 ° C for 2 hours. After the reaction, the reaction solution was cooled to room temperature. The reaction liquid which had been cooled to room temperature was transferred to a beaker, and 300 ml of acetone was added thereto for filtration. This cleaning operation was repeated three times. The residue was dried at 150 ° C for 5 hours in a vacuum oven. Thereby a white powder was obtained. The output is 53. 59 g (78. 2%). Identification of the obtained compound by1 H-NMR,31 P-NMR (measurement apparatus: AVANCE III HD NMR Spectrometer, manufactured by BRUKER) was carried out. Compound No. 1 obtained1 H-NMR and31 P-NMR is as follows. Compound No. 1 is a mixture of a plurality of compounds different in n, and contains a compound having n of 5 at most.1 H-NMR (DMSO-d6 , 400 MHz) : δ (ppm) 7.36-7.26 (m, 30H, -ph-, -ph), 4.44 - 4.13 (m, 48H, -CH2 O-) 3.46-3.51 (d, br, 20H, -CH2 -)31 P-NMR (DMSO-d6 162 MHz) : δ (ppm) 22.94 <Comparative Example 1> [Synthesis of Comparative Compound A] Comparative Compound A shown below was synthesized by the method described below. [化12]Adding 3,9-dibutoxy-2,4,8,10-tetraoxa 3,9-diphosphaspiro[5,5]undecane 54.4 g (0.16 mol), α, α to the flask '-Dibromo-p-xylene 34.3 g (0.13 mol) and dimethyl oxalate 150 ml were reacted at 150 ° C for 5 hours. After the reaction, the reaction solution was cooled to room temperature. Further, 54.71 g (0.40 mol) of bromobutane was further added to the flask, and the mixture was heated to reflux with bromobutane for 8 hours. Thereafter, the purification was carried out in the same order as that carried out in the synthesis of Compound No. 1. The yield was 39.24 (68.2%). The compound thus obtained was designated as Comparative Compound A. Identification of the obtained compound by1 H-NMR and31 P-NMR (measurement apparatus: AVANCE III HD NMR Spectrometer, manufactured by BRUKER) was carried out. Comparative compound A obtained1 H-NMR and31 P-NMR is as follows. Comparative Compound A is a mixture of a plurality of compounds different in n, and contains Comparative Compound A with n being 5 at most.1 H-NMR (DMSO-d6 , 400 MHz) : δ (ppm) 7.26-7.20 (m, 20H, -ph-), 4.59-3.45 (m, 48H, -CH2 O-) 3.50-3.45 (d, br, 20H, ph-CH2 -), 0.91-0.87 (m, 12H, -CH2 -), 0.92-0.84 (m, 6H, -CH3 )31 P-NMR (DMSO-d6 , 162 MHz): δ (ppm) 29.84-29.32, 23.30-22.65 [Comparative Example 2] [Comparison of Comparative Compound B] Comparative Compound B shown below was synthesized in the following manner. [Chemistry 13]To the flask was added 3,9-dibutoxy-2,4,8,10-tetraoxa 3,9-diphosphaspiro[5,5]undecane 54.3 g (0.16 mol), 1,4 -28.10 g (0.13 mol) of dibromobutane and 150 ml of ethylene carbonate were reacted at 150 ° C for 7 hours. Thereafter, 66.71 g (0.39 mol) of benzyl bromide was added to the flask, and the reaction was carried out at 150 ° C for 2 hours. Purification was carried out in the same order as that carried out in the synthesis of Compound No. 1. The yield was 33.71 g (71.2%). The compound thus obtained was designated as Comparative Compound B. Identification of the obtained compound by1 H-NMR and31 P-NMR (measurement apparatus: AVANCE III HD NMR Spectrometer, manufactured by BRUKER) was carried out. Comparative compound B obtained1 H-NMR and31 P-NMR is as follows. Comparative Compound B was a mixture of a plurality of compounds different in n, and the comparative compound B containing n was the most.1 H-NMR (DMSO-d6 , 400 MHz) : δ (ppm) 7.27-7.18 (m, 10H, ph-), 4.34-4.05 (m, 48H, -CH2 O-) 3.44, 3.39 (d, 10H, ph-CH2 -), 1.35-1.27, 0.82-0.79 (m, 40H, -CH2 -)31 P-NMR (DMSO-d6 , 162 MHz): δ (ppm) 29.66-28.97, 23.20-22.78 [Comparative Example 3] [Comparison of Comparative Compound C] Comparative Compound C shown below was synthesized by the method described below. [Chemistry 14]To the flask was added 3,9-dibutoxy-2,4,8,10-tetraoxa 3,9-diphosphaspiro[5,5]undecane 54.3 g (0.16 mol), 1,4 -28.10 g (0.13 mol) of dibromobutane and 150 ml of propylene carbonate were reacted at 150 ° C for 7 hours. Further, 53.50 g (0.39 mol) of bromobutane was added to the flask, and the reaction was carried out under reflux of bromobutane for 8 hours. Purification was carried out in the same order as that carried out in the synthesis of Compound No. 1. The yield was 27.12 g (65.5%). The compound thus obtained was designated as Comparative Compound C. Comparative compound C was identified by1 H-NMRo and31 P-NMR (measurement apparatus: AVANCE III HD NMR Spectrometer, manufactured by BRUKER) was carried out. Comparative compound B obtained1 H-NMR and31 P-NMR is as follows. Comparative Compound C is a mixture of a plurality of compounds having different n, and the comparative compound C having n is 5 is the most.1 H-NMR (DMSO-d6 , 400 MHz) : δ (ppm) 4.39-4.19 (m, 48H, -CH2 O-), 2.09-1.87, 1.51-1.36 (m, 12H, -CH2 -), 0.91-0.87 (m, 6H, -CH3 )31 P-NMR (DMSO-d6 , 162 MHz) : δ (ppm) 28.97-24.49 [Comparative Example 4] [Synthesis of Comparative Compound D] The comparative compound D shown below was synthesized by the method described below. [化15]Adding 3,9-dibutoxy-2,4,8,10-tetraoxa 3,9-diphosphaspiro[5,5]undecane 57.34 g (0.16 mol) and benzyl bromide to the flask 125.6 g (0.80 mol) was reacted at 150 ° C for 3 hours. After the end of the reaction, the benzyl bromide was distilled off under reduced pressure. The obtained powder was dispersed in 50 g of acetone and stirred for 30 minutes, and then the dispersion was filtered. This cleaning operation was repeated three times. It was dried at 150 ° C for 5 hours under reduced pressure. The yield was 55.87 g (80.1%). The obtained compound was designated as Comparative Compound D. Comparative compound D was identified by1 H-NMR and31 P-NMR (measurement apparatus: AVANCE III HD NMR Spectrometer, manufactured by BRUKER) was carried out. Comparative compound D obtained1 H-NMR and31 P-NMR is as follows.1 H-NMR (CDCl3 , 400 MHz) : δ (ppm) 7.35-7.22 (m, 10H, -ph-), 4.15-4.11, 4.05-4.01, 3.74-3.66, 3.51-3.43 (Dd, Dd, Dd, Dd, 8H, -CH2 O-), 3.28, 3.23 (d, 4H, -CH2 -)31 P-NMR (DMSO-d6 162 MHz) : δ (ppm) 28.97-24.49 [Examples 2 to 7 and Comparative Examples 5 to 8] The materials described in the following Tables 1 and 2 were blended in the amounts (% by mass) of Tables 1 and 2; A resin composition was obtained. The flame retardancy was evaluated using this resin composition. The results are shown in Tables 1 and 2. Further, the heat resistance of the compounds synthesized in Example 1 and Comparative Examples 1 to 4 was evaluated. The results are shown in Table 3. [Flame Retardancy (UL-94 V)] The resin composition was pressed at 280 ° C and 5 to 15 MPa for 15 minutes, thereby obtaining a flame retardancy test evaluation of a length of 127 mm, a width of 12.7 mm, and a thickness of 1.6 mm. Use test strips. The obtained test piece is made to be vertical according to ISO1210 and according to the 20 mm vertical burning test (UL-94 V), and the lower end is contacted with the flame of the burner for 10 seconds to remove the flame, and the flame of the fire of the test piece is determined to disappear. time. Next, the second contact flame was performed for 10 seconds while the flame disappeared, and the time when the flame of the fire disappeared was measured in the same manner as the first time. Also, whether the batt under the test piece will catch fire due to the type of fire that has fallen is also measured. The combustion level is classified according to the UL-94 V standard based on the first and second burning times, the presence or absence of the glazing. The burning level V-0 is the highest level, and the flame retardancy is lowered as it becomes V-1 and V-2. [Table 1] [Table 2] [Heat resistance] Using the thermogravimetric-differential thermal analysis device Thermo plus EVO (manufactured by RIGAKU Co., Ltd.), the above compound No. 1 and comparative compound A were heated at a temperature elevation rate of 10 ° C / min under a nitrogen gas flow rate of 200 ml / min. D was heated from 30 ° C to 450 ° C, and the weight was reduced by 1% and 5%. [table 3] It is understood from Tables 1 and 2 that the resin compositions of Examples 2 and 7 containing Compound No. 1 which is a compound represented by General Formula (1) of the present invention and Comparative Examples 5 to 8 containing Comparative Compounds A to D The compound has good flame retardancy compared to the compound. This indicates that the compound represented by the formula (1) of the present invention can improve the flame retardancy of the resin composition. Further, the resin compositions of Examples 2 to 4 and 7 were further improved in flame retardancy as compared with the resin compositions of Examples 5 and 6. This indicates that the flame retardancy of the resin composition can be further improved by setting the content ratio of the compound No. 1 to the mass ratio of melamine pyrophosphate or melamine polyphosphate to a specific ratio. Further, as is clear from Table 3, the compound No. 1 synthesized in Example 1 had good heat resistance as compared with the comparative compounds A to D synthesized in Comparative Examples 1 to 4. [Industrial Applicability] The compound of the present invention is excellent in heat resistance, and the flame retardancy of a resin, particularly a polyester resin, can be greatly improved by a small amount of addition.

Claims (9)

一種化合物，其係下述通式(1)所表示，(式中，R1 及R3 分別獨立表示存在具有取代基之情況之一價之芳香族基， X1 及X2 分別獨立表示直接鍵、碳數1～8之伸烷基、氧原子、氮原子或硫原子，於上述碳數1～8之伸烷基中之任意相鄰之碳原子間存在介存有氧原子、氮原子或硫原子之情況， R2 表示下述通式(2)所表示之基， n表示1～20之數)(式中，m表示0～4之整數)。a compound represented by the following formula (1), (wherein R 1 and R 3 each independently represent an aromatic group having a valence of a substituent, and X 1 and X 2 each independently represent a direct bond, an alkylene group having 1 to 8 carbon atoms, an oxygen atom, The nitrogen atom or the sulfur atom may have an oxygen atom, a nitrogen atom or a sulfur atom interposed between any adjacent carbon atoms of the above-mentioned alkyl group having 1 to 8 carbon atoms, and R 2 represents the following formula (2) ) the base represented by n, which represents the number from 1 to 20) (wherein m represents an integer of 0 to 4). 一種組合物，其含有如請求項1之通式(1)所表示之化合物與磷酸鹽化合物。A composition comprising a compound represented by the formula (1) of claim 1 and a phosphate compound. 如請求項2之組合物，其中上述磷酸鹽化合物為焦磷酸鹽。The composition of claim 2 wherein the phosphate compound is pyrophosphate. 如請求項2之組合物，其中上述磷酸鹽化合物為聚磷酸鹽。The composition of claim 2, wherein the phosphate compound is a polyphosphate. 如請求項2之組合物，其中上述通式(1)所表示之化合物與磷酸鹽化合物之質量比以前者：後者計為9：1～1：9。The composition of claim 2, wherein the mass of the compound represented by the above formula (1) and the phosphate compound is higher than the former: the latter is from 9:1 to 1:9. 一種樹脂組合物，其含有樹脂、與相對於該樹脂100質量份為0.1～500質量份之如請求項1之化合物。A resin composition containing a resin and 0.1 to 500 parts by mass of the compound of claim 1 with respect to 100 parts by mass of the resin. 一種樹脂組合物，其含有樹脂、與相對於該樹脂100質量份為0.1～500質量份之如請求項2之組合物。A resin composition containing a resin and a composition as claimed in claim 2 in an amount of 0.1 to 500 parts by mass based on 100 parts by mass of the resin. 如請求項6或7之樹脂組合物，其中上述樹脂包含聚酯系樹脂或聚醯胺系樹脂。The resin composition of claim 6 or 7, wherein the above resin comprises a polyester resin or a polyamide resin. 一種成形品，其係使如請求項6或7之樹脂組合物成形而成。A molded article obtained by molding the resin composition of claim 6 or 7.
TW107112245A 2017-04-14 2018-04-10 Novel compound and resin composition TW201900665A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2017080640 2017-04-14
JP2017-080640 2017-04-14

Publications (1)

Publication Number Publication Date
TW201900665A true TW201900665A (en) 2019-01-01

Family

ID=63792415

Family Applications (1)

Application Number Title Priority Date Filing Date
TW107112245A TW201900665A (en) 2017-04-14 2018-04-10 Novel compound and resin composition

Country Status (2)

Country Link
TW (1) TW201900665A (en)
WO (1) WO2018190157A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113736342A (en) * 2021-09-13 2021-12-03 沈阳先进涂层材料产业技术研究院有限公司 Environment-friendly coating and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020075519A1 (en) * 2018-10-11 2020-04-16 株式会社Adeka Flame retardant, flame retardant composition, synthetic-resin composition, and molded object

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2590377A (en) * 1976-06-29 1978-12-14 American Cyanamid Co Phosphonate flame-retardants for polymers
US4086205A (en) * 1976-09-03 1978-04-25 Monsanto Company Hydrogen phosphonates
US4217267A (en) * 1978-04-28 1980-08-12 American Cyanamid Company Polymeric pentaerythrityl phosphonates and their use as flame retardants
US4278591A (en) * 1979-12-20 1981-07-14 American Cyanamid Company Flame retardant poly(butylene terephthalate) composition
IT1251154B (en) * 1991-08-07 1995-05-04 Enichem Sintesi PENTAERITRIL PHOSPHONATES AND THEIR USE IN SELF-EXTINGUISHING THERMOPLASTIC POLYMER COMPOSITIONS
IT1269850B (en) * 1994-05-27 1997-04-15 Enichem Sintesi NEW POLI (PENTAERITRIL DIPHOSPHONATE) AND ITS USE IN SELF-EXTINGUISHING THERMOPLASTIC POLYMERIC COMPOSITIONS

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113736342A (en) * 2021-09-13 2021-12-03 沈阳先进涂层材料产业技术研究院有限公司 Environment-friendly coating and preparation method thereof

Also Published As

Publication number Publication date
WO2018190157A1 (en) 2018-10-18

Similar Documents

Publication Publication Date Title
TWI565791B (en) Salts of pyrophosphonic acid as flame retardants
US20140128516A1 (en) Flame Retardant-Stabiliser Combination For Thermoplastic Polymers
KR20160137575A (en) Dopo-based hybrid flame retardants
JPS62277394A (en) Liquid vinyl chloride resin stabilizer system based on complex of organic triphosphite and zinc chloride
JP6419348B2 (en) 3-Arylbenzofuran compounds and compositions thereof
EP3339376A1 (en) Resin additive composition and synthetic resin composition using same
KR20150130896A (en) Spiro bisphosphite based compound and uses of the same
TWI790288B (en) Method for improving storage stability of flame retardant composition
KR101578604B1 (en) Color-resistance and high heat-resistance Polycyclohexylene-dimethyleneterephtalate resin composition containing non-halogen flame retardant and non-halogen flame retardant aid
TW201900665A (en) Novel compound and resin composition
CN111051412A (en) Composition, thermoplastic resin composition using the same, and molded article thereof
JPWO2019151355A1 (en) Stabilizer composition, vinyl chloride resin composition containing the stabilizer composition, and a molded product thereof.
TW202028443A (en) Flame retardant, flame retardant composition, synthetic-resin composition, and molded object
TWI771421B (en) Flame retardant composition and flame retardant resin composition containing the same
US20210395484A1 (en) Flame retardant and preparation process thereof
CN111065674A (en) Composition, thermoplastic resin composition using the same, and molded article thereof
WO2012011519A1 (en) Fire retarding agent containing cyclic amine salt, and fire-retardant resin composition
JP6270885B2 (en) Flame retardant cellulose ester preparation
JPH03188090A (en) Phosphite compound and use thereof
CN103923120A (en) Deoxybenzoin fire retardation agent, composition containing deoxybenzoin fire retardation agent, product containing deoxybenzoin fire retardation agent, and method for reducing combustibility of polymer material by using deoxybenzoin fire retardation agent
TW201838961A (en) Nucleating agent and resin composition containing same
WO2021201085A1 (en) Flame retardant composition, flame-resistant synthetic resin composition, and molded body
TWI794364B (en) Composition and flame retardant resin composition
WO2024122297A1 (en) Flame-retardant composition, flame-retardant resin composition and molded article
TW202112942A (en) Additive composition